Federal Implementation Plan for the Billings/Laurel, Montana, Sulfur Dioxide Area, 39259-39278 [06-6096]
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Federal Register / Vol. 71, No. 133 / Wednesday, July 12, 2006 / Proposed Rules
This proposed rule also does not have
tribal implications because it will not
have a substantial direct effect on one or
more Indian tribes, on the relationship
between the Federal Government and
Indian tribes, or on the distribution of
power and responsibilities between the
Federal Government and Indian tribes,
as specified by Executive Order 13175
(65 FR 67249, November 9, 2000). This
action also does not have Federalism
implications because it does not have
substantial direct effects on the States,
on the relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government, as specified in
Executive Order 13132 (64 FR 43255,
August 10, 1999). This action merely
proposes to approve a state rule
implementing a Federal standard, and
does not alter the relationship or the
distribution of power and
responsibilities established in the Clean
Air Act. This proposed rule also is not
subject to Executive Order 13045
‘‘Protection of Children from
Environmental Health Risks and Safety
Risks’’ (62 FR 19885, April 23, 1997),
because it is not economically
significant.
In reviewing SIP submissions, EPA’s
role is to approve state choices,
provided that they meet the criteria of
the Clean Air Act. In this context, in the
absence of a prior existing requirement
for the State to use voluntary consensus
standards (VCS), EPA has no authority
to disapprove a SIP submission for
failure to use VCS. It would thus be
inconsistent with applicable law for
EPA, when it reviews a SIP submission,
to use VCS in place of a SIP submission
that otherwise satisfies the provisions of
the Clean Air Act. Thus, the
requirements of section 12(d) of the
National Technology Transfer and
Advancement Act of 1995 (15 U.S.C.
272 note) do not apply. This proposed
rule does not impose an information
collection burden under the provisions
of the Paperwork Reduction Act of 1995
(44 U.S.C. 3501 et seq.).
List of Subjects in 40 CFR Part 52
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Environmental protection, Air
pollution control, Intergovernmental
relations, Particulate matter, Reporting
and recordkeeping requirements.
Authority: 42 U.S.C. 7401 et seq.
Dated: June 30, 2006.
Alexis Strauss,
Acting Regional Administrator, Region IX.
[FR Doc. 06–6111 Filed 7–11–06; 8:45 am]
BILLING CODE 6560–50–P
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ENVIRONMENTAL PROTECTION
AGENCY
[EPA–R08–OAR–2006–0098; FRL–8191–7]
40 CFR Part 52
RIN 2008–AA00
Federal Implementation Plan for the
Billings/Laurel, Montana, Sulfur
Dioxide Area
Environmental Protection
Agency (EPA).
ACTION: Proposed rule.
AGENCY:
SUMMARY: The Environmental Protection
Agency (EPA) proposes to promulgate a
Federal Implementation Plan (FIP)
containing emission limits and
compliance determining methods for
several sources located in Billings and
Laurel, Montana. EPA is proposing a FIP
because of our previous partial and
limited disapprovals of the Billings/
Laurel Sulfur Dioxide (SO2) SIP. The
intended effect of this action is to assure
attainment of the SO2 national ambient
air quality standard (NAAQS) in the
Billings/Laurel, Montana area. EPA is
taking this action under sections 110
and 307 of the Clean Air Act (Act).
DATES: Comments: Comments on the
proposal must be received on or before
September 11, 2006.
Public Hearing: If requested by July
26, 2006, EPA will hold a public hearing
on August 10, 2006. If a public hearing
is requested, EPA will hold the public
hearing at the following time and
location: 9 a.m. to 2 p.m. at the Lewis
and Clark Room, MSU—Billings, 1500
University Drive, Billings, Montana. The
purpose of such a hearing would be for
EPA to receive comments and ask
clarifying questions. The hearing would
not be an opportunity for questioning of
EPA officials or employees. Call the
individual listed in the FOR FURTHER
INFORMATION CONTACT if you would like
to request a hearing, schedule time to
speak at the hearing, or confirm whether
a hearing will occur. If a hearing is held,
speakers will be limited to 10 minutes.
It would be helpful, but it is not
required, if speakers bring a written
copy of their comments to leave with us.
ADDRESSES: Submit your comments,
identified by Docket ID No. EPA–R08–
OAR–2006–0098, by one of the
following methods:
• https://www.regulations.gov. Follow
the on-line instructions for submitting
comments.
• E-mail: long.richard@epa.gov and
ostrand.laurie@epa.gov.
• Fax: (303) 312–6064 (please alert
the individual listed in the FOR FURTHER
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39259
INFORMATION CONTACT if you are faxing
comments).
• Mail: Richard R. Long, Director, Air
and Radiation Program, Environmental
Protection Agency (EPA), Region 8,
Mailcode 8P–AR, 999 18th Street, Suite
200, Denver, Colorado 80202–2466.
• Hand Delivery: Richard R. Long,
Director, Air and Radiation Program,
Environmental Protection Agency
(EPA), Region 8, Mailcode 8P–AR, 999
18th Street, Suite 300, Denver, Colorado
80202–2466. Such deliveries are only
accepted Monday through Friday, 8 a.m.
to 4:55 p.m., excluding Federal
holidays. Special arrangements should
be made for deliveries of boxed
information.
Instructions: Direct your comments to
Docket ID No. EPA–R08–OAR–2006–
0098. EPA’s policy is that all comments
received will be included in the public
docket without change and may be
made available online at https://
www.regulations.gov, including any
personal information provided, unless
the comment includes information
claimed to be Confidential Business
Information (CBI) or other information
whose disclosure is restricted by statute.
Do not submit information that you
consider to be CBI or otherwise
protected through https://
www.regulations.gov or e-mail. The
https://www.regulations.gov Web site is
an ‘‘anonymous access’’ systems, which
means EPA will not know your identity
or contact information unless you
provide it in the body of your comment.
If you send an e-mail comment directly
to EPA, without going through https://
www.regulations.gov your e-mail
address will be automatically captured
and included as part of the comment
that is placed in the public docket and
made available on the Internet. If you
submit an electronic comment, EPA
recommends that you include your
name and other contact information in
the body of your comment and with any
disk or CD–ROM you submit. If EPA
cannot read your comment due to
technical difficulties and cannot contact
you for clarification, EPA may not be
able to consider your comment.
Electronic files should avoid the use of
special characters, any form of
encryption, and be free of any defects or
viruses. For additional information
about EPA’s public docket visit the EPA
Docket Center homepage at https://
www.epa.gov/epahome/dockets.htm.
For additional instructions on
submitting comments, go to Section I.
General Information of the
SUPPLEMENTARY INFORMATION section of
this document.
Docket: All documents in the docket
are listed in the https://
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www.regulations.gov index. Although
listed in the index, some information is
not publicly available, e.g., CBI or other
information whose disclosure is
restricted by statute. Certain other
material, such as copyrighted material,
will be publicly available only in hard
copy. Publicly available docket
materials are available either
electronically in https://
www.regulations.gov or in hard copy at
the Air and Radiation Program,
Environmental Protection Agency
(EPA), Region 8, 999 18th Street, Suite
300, Denver, Colorado 80202–2466. EPA
requests that if at all possible, you
contact the individual listed in the FOR
FURTHER INFORMATION CONTACT section to
view the hard copy of the docket. You
may view the hard copy of the docket
Monday through Friday, 8 a.m. to 4
p.m., excluding Federal holidays.
FOR FURTHER INFORMATION CONTACT:
Laurie Ostrand, Air and Radiation
Program, Mailcode 8P–AR,
Environmental Protection Agency
(EPA), Region 8, 999 18th Street, Suite
200, Denver, Colorado 80202–2466,
(303) 312–6437, ostrand.laurie@epa.gov.
SUPPLEMENTARY INFORMATION:
Table of Contents
Definitions
I. General Information
II. Background
A. General Background
B. SIP Background
C. FIP Background
III. FIP Proposal
A. Flare Requirements Applicable to All
Sources
B. CHS Inc.
C. ConocoPhillips
D. ExxonMobil
E. Montana Sulphur & Chemical Company
IV. Request for Public Comment
V. Statutory and Executive Order Reviews
A. Executive Order 12866, Regulatory
Planning Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act
D. Unfunded Mandates Reform Act
E. Executive Order 13132, Federalism
F. Executive Order 13175, Coordination
With Indian Tribal Governments
G. Executive Order 13045, Protection of
Children From Environmental Health
Risks and Safety Risks
H. Executive Order 13211, Actions That
Significantly Affect Energy Supply,
Distribution, or Use
I. National Technology Transfer and
Advancement Act
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Definitions
For the purpose of this document, we
are giving meaning to certain words or
initials as follows:
(i) The words or initials Act or CAA
mean or refer to the Clean Air Act,
unless the context indicates otherwise.
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(ii) The initials CEMS mean or refer to
continuous emission monitoring system.
(iii) The initials CO mean or refer to
carbon monoxide.
(iv) The words EPA, we, us or our
mean or refer to the United States
Environmental Protection Agency.
(v) The initials FIP mean or refer to
Federal Implementation Plan.
(vi) The initials H2S mean or refer to
hydrogen sulfide.
(vii) The initials MBER mean or refer
to the Montana Board of Environmental
Review.
(viii) The initials MDEQ mean or refer
to the Montana Department of
Environmental Quality.
(ix) The initials MSCC mean or refer
to the Montana Sulphur & Chemical
Company.
(x) The initials NAAQS mean or refer
to National Ambient Air Quality
Standards.
(xi) The initials SIP mean or refer to
State Implementation Plan.
(xii) The initials SO2 mean or refer to
sulfur dioxide.
(xiii) The words state or Montana
mean the State of Montana, unless the
context indicates otherwise.
(xiv) The initials SRU mean or refer
to sulfur recovery unit.
(xv) The initials SWS mean or refer to
sour water stripper.
I. General Information
A. What Should I Consider as I Prepare
My Comments for EPA?
1. Submitting CBI. Do not submit this
information to EPA through https://
www.regulations.gov or e-mail. Clearly
mark the part or all of the information
that you claim to be CBI. For CBI
information in a disk or CD ROM that
you mail to EPA, mark the outside of the
disk or CD ROM as CBI and then
identify electronically within the disk or
CD ROM the specific information that is
claimed as CBI. In addition to one
complete version of the comment that
includes information claimed as CBI, a
copy of the comment that does not
contain the information claimed as CBI
must be submitted for inclusion in the
public docket. Information so marked
will not be disclosed except in
accordance with procedures set forth in
40 CFR part 2.
2. Tips for Preparing Your Comments.
When submitting comments, remember
to:
a. Identify the rulemaking by docket
number and other identifying
information (subject heading, Federal
Register date and page number).
b. Follow directions—The agency may
ask you to respond to specific questions
or organize comments by referencing a
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Code of Federal Regulations (CFR) part
or section number.
c. Explain why you agree or disagree;
suggest alternatives and substitute
language for your requested changes.
d. Describe any assumptions and
provide any technical information and/
or data that you used.
e. If you estimate potential costs or
burdens, explain how you arrived at
your estimate in sufficient detail to
allow for it to be reproduced.
f. Provide specific examples to
illustrate your concerns, and suggest
alternatives.
g. Explain your views as clearly as
possible, avoiding the use of profanity
or personal threats.
h. Make sure to submit your
comments by the comment period
deadline identified.
II. Background
A. General Background
Billings and Laurel are situated in the
Yellowstone River Valley in southcentral Montana. The Yellowstone River
Valley runs from southwest to northeast
and is the dominant topographical
feature influencing airflow over the
area. Windroses 1 for the area reflect the
valley orientation. Southwest winds are
the most common, followed by
northeast winds.
The terrain in the vicinity of Billings
and Laurel is upland bench which is
steeply cut by the Yellowstone River
and its tributaries. The bench lies at an
elevation of 4000 feet while the valley
in Billings is approximately 3000 feet
above sea level (asl) and in Laurel is
approximately 3300 feet asl. A
constriction in the Yellowstone Valley
occurs between central Billings and the
Lockwood area located to the east. The
valley is generally 3 or 4 miles wide but
narrows to a little over a mile wide at
the constriction. Nearby terrain, such as
the Sacrifice Cliff to the southeast of
Billings and the Rimrocks to the north,
rises abruptly and is often higher than
the tallest smoke stack. Laurel is located
within the Yellowstone Valley
approximately 15 miles southwest of
Billings. The valley near Laurel is 3 or
4 miles wide. Nearby terrain to the
northwest and southeast of Laurel rises
abruptly and is often higher than the
tallest smoke stack.
The major sulfur dioxide (SO2)
emitting industries in the Billings area
are the ConocoPhillips 2 and
1 A windrose is a diagram showing the relative
frequency or frequency and strength of winds from
different directions (Websters 9th New Collegiate
Dictionary).
2 When the state originally adopted the Billings/
Laurel SO2 SIP, the ConocoPhillips Refinery was
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ExxonMobil 3 Petroleum Refineries,
Western Sugar Company, the PPL
Montana, LLC J.E. Corette Power Plant,4
Montana Sulphur & Chemical Company
(MSCC) (gas processing plant, sulfur
recovery and sulfur products), and
Yellowstone Energy Limited Partnership
(YELP) (cogeneration power plant). The
major SO2 emitting industry in the
Laurel area is the CHS Inc. Petroleum
Refinery.5 Although Laurel and Billings
are 15 miles apart, the industries in
Billings have some impact on the air
quality in Laurel and the industry in
Laurel has some impact on the air
quality in Billings.
On March 3, 1978 (43 FR 8962), the
Laurel area was designated as
nonattainment for the primary SO2
national ambient air quality standard
(NAAQS). See also 40 CFR 81.327. The
nonattainment area consists of an area
with a two-kilometer radius around CHS
Inc. This designation was based on
measured and modeled violations of the
NAAQS. EPA reaffirmed this
nonattainment designation on
September 11, 1978 (43 FR 40412). The
1990 Clean Air Act Amendments,
enacted November 15, 1990, again
reaffirmed the nonattainment
designation of Laurel with respect to the
primary SO2 NAAQS. Since the Laurel
nonattainment area had a fully
approved part D plan, the state was not
required to submit a revised plan for the
area under the 1990 Amendments (see
sections 191 and 192 of the Act).
On March 3, 1978 (43 FR 8962), those
areas in the state that had not been
identified as not meeting the SO2
NAAQS were designated as ‘‘Better
Than National Standards.’’ The Billings
area was in that portion of the state that
was designated as ‘‘Better Than National
Standards.’’
The Act requires EPA to establish
NAAQS which protect public health
and welfare. NAAQS have been
established for SO2. The Act also
requires states to prepare and gain EPA
approval of a plan, termed a State
known as the Conoco Refinery. Throughout this
document we will refer to the refinery as
ConocoPhillips.
3 When the state originally adopted the Billings/
Laurel SO2 SIP, the ExxonMobil Refinery was
known as the Exxon Refinery. Throughout this
document we will refer to the refinery as
ExxonMobil.
4 When the state originally adopted the Billings/
Laurel SO2 SIP, the PPL Montana, LLC J.E. Corette
Power Plant was known as the Montana Power
Company, J.E. Corrette Plant. Throughout this
document we will refer to the power plant as the
Corette Power Plant.
5 When the state originally adopted the Billings/
Laurel SO2 SIP, CHS Inc. Petroleum Refinery was
known as the Cenex Petroleum Refinery.
Throughout this document we will refer to the
refinery as CHS Inc.
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Implementation Plan (SIP), to assure
that the NAAQS are attained and
maintained. Dispersion modeling
completed in 1991 and 1993 for the
Billings/Laurel area of Montana
predicted that the SO2 NAAQS were not
being attained.6 As a result, EPA
(pursuant to sections 110(a)(2)(H) and
110(k)(5) of the Act) requested the State
of Montana to revise its previously
approved SIP for the Billings/Laurel
area. In response, the State submitted
revisions to the SIP on September 6,
1995, August 27, 1996, April 2, 1997,
July 29, 1998, and May 4, 2000.
1. SIP Call
We issued a request that the State of
Montana revise the Billings/Laurel area
SO2 SIP by letter to the Governor of
Montana, dated March 4, 1993 (see
reference document Z). The request
letter reflected our preliminary finding
regarding the SIP’s substantial
inadequacy, and was published in the
Federal Register on August 4, 1993 (58
FR 41430) (see reference document Y).
We sometimes refer to such a request as
a SIP Call. In the request letter, we
declared that the SIP Call would become
final agency action when we made a
binding determination regarding the
State of Montana’s response to the SIP
Call. We made such a binding
determination regarding the SIP Call
when we partially and limitedly
approved and partially and limitedly
disapproved the Billings/Laurel SO2 SIP
revisions submitted by the State of
Montana in response to the request
letter.7 See 67 FR 22168, 22173 (May 2,
2002) (see reference document AA).
6 See the study for the Billings Gasification, Inc.
(BGI) (now YELP) permit in 1991 and the
GeoResearch, Inc. (GRI) study commissioned by the
Billings City Council in 1993 (document #’s II.G–
13 and II.G–12, respectively, in Docket #R8–99–01).
7 In some cases, a SIP rule may contain certain
provisions that meet the applicable requirements of
the Act, but that are inseparable from other
provisions that do not meet all the requirements.
Although the submittal may not meet all of the
applicable requirements, we may consider whether
the rule, as a whole, has a strengthening effect on
the SIP. If this is the case, limited approval may be
used to approve a rule that strengthens the existing
SIP as representing an improvement over what is
currently in the SIP and as meeting some of the
applicable requirements of the Act. At the same
time we would disapprove the rule for not meeting
all of the applicable requirements of the Act. Under
a limited approval/disapproval action, we
simultaneously approve and disapprove the entire
rule even though parts of the rule satisfy, and parts
do not satisfy, requirements under the Act. The
disapproval only concerns the failure of the rule to
meet a specific requirement of the Act and does not
affect incorporation of the rule as part of the
approved, federally enforceable SIP. We use this
mechanism when the rule, despite its flaws, will
strengthen the federally enforceable SIP.
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2. SIPs Submitted in Response to SIP
Call
Our 1993 SIP Call called for the State
of Montana to submit a SIP revision for
the Billings/Laurel area by September 4,
1994. On September 6, 1995, the
Governor of Montana submitted a SIP
revision in response to the SIP Call. The
SIP was later amended with revisions
submitted on August 27, 1996, April 2,
1997, July 29, 1998, and May 4, 2000.
Copies of the complete SIP revisions are
contained in the docket for our action
on the SIP. (See docket #R8–99–01.)
3. EPA’s Actions on State’s Billings/
Laurel SO2 SIP
B. SIP Background
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(a) EPA’s May 2, 2002, final action.
On May 2, 2002 (67 FR 22168) 8 (see
reference document AA), we partially
approved, partially disapproved,
limitedly approved and limitedly
disapproved provisions of the Billings/
Laurel SO2 SIP.9 Specifically:
(i) We disapproved the following
provisions of the Billings/Laurel SO2
SIP: 10
• The escape clause (paragraph 22 in
the ExxonMobil and MSCC 1998
stipulations, and paragraph 20 in the
CHS Inc., ConocoPhillips, Corette Power
Plant, Western Sugar, and YELP 1998
stipulations.)
• The MSCC stack height credit and
emission limits on the sulfur recovery
unit (SRU) 100-meter stack (paragraph 1
of the ExxonMobil 1998 stipulation,
paragraphs 1 and 2 of the MSCC 1998
stipulation, and sections 3(A)(1)(a) and
In other cases, a SIP rule may contain certain
provisions that meet applicable requirements of the
Act, but that are separable from other provisions
that do not meet applicable requirements. Where a
separable portion of the submittal meets applicable
requirements, partial approval may be used to
approve that part of the submittal and partial
disapproval to disapprove the provisions that do
not meet applicable requirements of the Act.
EPA’s interpretation of the Act regarding
approving and disapproving SIPs is discussed
further in a July 9, 1992, memorandum title
‘‘Processing of State Implementation Plan (SIP)
Submittals,’’ from John Calcagni to Regional Air
Division Directors. (See reference document A.)
8 See also June 7, 2002 corrections notice (67 FR
39473) (reference document KKK).
9 See footnote #7.
10 The SIP was submitted in the form of orders,
stipulations, exhibits and attachments for each
source covered by the plan. The majority of the
requirements are contained in the exhibits.
Throughout this document when we refer to an
exhibit, we mean exhibit A to the stipulation for the
specified source. For purposes of our May 2, 2002,
SIP action the stipulations and exhibits to which we
refer were adopted by the Montana Board of
Environmental Review (MBER) on June 12, 1998.
MBER adopted revised stipulations and exhibits for
some sources on March 17, 2000. To distinguish
between the two sets of stipulations and exhibits,
we refer to either the 1998 stipulation or exhibit for
a particular source, or the 2000 stipulation or
exhibit.
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(b) and 3(A)(3) of the MSCC 1998
exhibit).
• The emission limit on MSCC’s
auxiliary vent stacks, section 3(A)(4) of
MSCC’s 1998 exhibit.
• The attainment demonstration,
because of improper stack height credit
and emission limits at MSCC.
• The attainment demonstration for
lack of flare emission limits at CHS Inc.,
ConocoPhillips, ExxonMobil, and
MSCC.
• The attainment demonstration,
because of the disapproval of the
emission limit for MSCC’s auxiliary
vent stacks.
• The Reasonably Available Control
Measures (RACM) (including
Reasonably Available Control
Technology (RACT)) and Reasonable
Further Progress (RFP) requirements for
CHS Inc.
• The provisions that allow sour
water stripper overheads to be burned in
the flare at CHS Inc. and ExxonMobil
(i.e., the following phrase from section
3(B)(2) of CHS Inc.’s 1998 exhibit and
section 3(E)(4) of ExxonMobil’s 1998
exhibit: ‘‘or in the flare’’; the following
phrases in section 4(D) of CHS Inc.’s
1998 exhibit and section 4(E) of
ExxonMobil’s 1998 exhibit: ‘‘or in the
flare’’ and ‘‘or the flare’’.)
(ii) We limitedly approved and
limitedly disapproved the following
provision:
• The emission limit for the 30-meter
stack at MSCC (section 3(A)(2) of
MSCC’s 1998 exhibit) because it lacked
a reliable compliance monitoring
method.
(iii) We did not act on the following
provisions:
• The provisions in section 6(B)(3) of
MSCC’s 1998 exhibit that require certain
monitoring equipment to support the
variable emission limit.11
• YELP’s emission limits (in sections
3(A)(1) through (3) of YELP’s 1998
exhibit).
• ExxonMobil’s coker CO-boiler
emission limitation (in section 3(B)(1) of
ExxonMobil’s 1998 exhibit).
• ExxonMobil’s F–2 crude/vacuum
heater stack emission limits and
attendant compliance monitoring
methods (sections 3(A)(2), 3(B)(3), 4(E)
and method #6A of attachment #2 of
ExxonMobil’s 1998 exhibit; and the
following phrase from section 3(E)(4) of
ExxonMobil’s 1998 exhibit ‘‘except that
the sour water stripper overheads may
11 Since we disapproved MSCC’s variable
emission limit, we did not believe it made sense to
approve section 6(B)(3) of MSCC’s 1998 exhibit,
which requires MSCC to install certain monitoring
equipment to support the use of the variable limit.
Section 6(B)(3) would be needed only if we
approved MSCC’s variable emission limit.
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be burned in the F–1 Crude Furnace
(and exhausted through the F–2 Crude/
Vacuum Heater stack) or in the flare
during periods when the FCC CO Boiler
is unable to burn the sour water stripper
overheads, provided that: (a) such
periods do not exceed 55 days per
calendar year and 65 days for any two
consecutive calendar years, and (b)
during such periods the sour water
stripper system is operating in a two
tower configuration.’’)
• ExxonMobil’s fuel gas combustion
emission limits and attendant
compliance monitoring methods (in
sections 3(A)(1), 3(B)(2), 4(B), and
6(B)(3) of ExxonMobil’s 1998 exhibit).
• CHS Inc.’s combustion sources
emission limitations and attendant
compliance monitoring methods
(sections 3(A)(1)(d), 4(B), 4(D) and
method #6A of attachment #2 of CHS
Inc.’s 1998 exhibit; and the following
phrase from section 3(B)(2) of CHS Inc.’s
1998 exhibit ‘‘except that those sour
water stripper overheads may be burned
in the main crude heater (and exhausted
through the main crude heater stack) or
in the flare during periods when the
FCC CO boiler is unable to burn the sour
water stripper overheads from the ‘‘old’’
SWS, provided that such periods do not
exceed 55 days per calendar year and 65
days for any two consecutive calendar
years.’’)
(iv) In a separate action published on
May 2, 2002 (67 FR 22242) 12 (see
reference document BB), we proposed
action on some provisions of the
Billings/Laurel SO2 SIP submitted on
July 29, 1998, and May 4, 2000.13 We
later finalized action on these
provisions on May 22, 2003 (68 FR
27908) (see discussion below and
reference document CC).
(v) We approved the following
provisions:
• All provisions of the SIP that were
not partially disapproved, limitedly
disapproved, omitted from our action,
or addressed in our May 2, 2002,
proposal.
(b) EPA’s May 22, 2003, final action.
12 See also June 14, 2002 correction notice (67 FR
40897) (reference document LLL).
13 On July 28, 1999 (64 FR 40791), we proposed
to conditionally approve certain provisions of the
SIP based on the Governor’s commitment to address
concerns we had raised. The Governor submitted a
SIP revision on May 4, 2000, which was intended
to fulfill the commitments. Since the Governor
submitted a SIP revision to fulfill the
commentments, we did not finalize our proposed
conditional approval and instead proposed separate
action on parts of the July 29, 1998, submittal (i.e.,
those parts we proposed to conditionally approve
on July 28, 1999) and all of the May 4, 2000,
submission (which in some cases modified the
provisions of the July 29, 1998, submittal).
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On May 22, 2003 (68 FR 27908) 14 (see
reference document CC), we partially
approved, limitedly approved, and
limitedly disapproved provisions of the
Billings/Laurel SO2 SIP. Specifically:
(i) We approved the following
provisions:
• YELP’s emission limits in sections
3(A)(1) through (3) and reporting
requirements in section 7(C)(1)(b) of
YELP’s 2000 exhibit.
• Provisions related to the burning of
SWS overheads in the F–1 Crude
Furnace (and exhausted through the F–
2 Crude/Vacuum Heater stack) at
ExxonMobil in sections 3(E)(4) and 4(E)
(excluding ‘‘or in the flare’’ and ‘‘or the
flare’’ in both sections), 3(A)(2), and
3(B)(3) of ExxonMobil’s 1998 exhibit,
and method #6A–1 of attachment #2 of
ExxonMobil’s 2000 exhibit.
• Minor changes in sections 3, 3(A),
and 3(B) (only the introductory
paragraphs); and sections 3(E)(3),
6(B)(7), 7(B)(1)(d), 7(B)(1)(j), 7(C)(1)(b),
7(C)(1)(d), 7(C)(1)(f), and 7(C)(1)(l) of
ExxonMobil’s 2000 exhibit.
(ii) We limitedly approved and
limitedly disapproved the following
provisions:
• Provisions related to the fuel gas
combustion emission limits at
ExxonMobil in sections 3(B)(2), 4(B),
and 6(B)(3) of ExxonMobil’s 1998
exhibit, and section 3(A)(1) of
ExxonMobil’s 2000 exhibit.
• Provisions related to ExxonMobil’s
coker CO-boiler emission limit in
sections 2(A)(11)(d), 3(B)(1), and 4(C) of
ExxonMobil’s 2000 exhibit.
• Provisions related to the burning of
SWS overheads at CHS Inc. in sections
3(B)(2) and 4(D) (excluding ‘‘or in the
flare’’ and ‘‘or the flare’’ in both
sections), 3(A)(1)(d), and 4(B) of CHS
Inc.’s 1998 exhibit, and method #6A–1
of attachment #2 of CHS Inc.’s 2000
exhibit.
4. Appeal of EPA’s Action on Billings/
Laurel SO2 SIP
On June 10, 2002, MSCC petitioned
the United States Court of Appeals for
the Ninth Circuit for review of EPA’s
May 2, 2002, final SIP action.
Subsequently, MSCC and EPA agreed to
a stay of the litigation pending EPA’s
final action on this FIP. The case is
captioned Montana Sulphur & Chemical
Company v. United States
Environmental Protection Agency, No.
02–71657. No petitions for judicial
review were filed regarding EPA’s May
22, 2003, SIP action.
14 See also June 2, 2003 correction notice (68 FR
32799) (reference document MMM).
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C. FIP Background
Under section 110(c) of the Act,
whenever we disapprove a SIP in whole
or in part we are required to promulgate
a FIP. Specifically, section 110(c)
provides:
‘‘(1) The Administrator shall promulgate a
Federal implementation plan at any time
within 2 years after the Administrator—
(A) finds that a State has failed to make a
required submission or finds that the plan or
plan revision submitted by the State does not
satisfy the minimum criteria established
under [section 110(k)(1)(A)] 15, or
(B) disapproves a State implementation
plan submission in whole or in part, unless
the State corrects the deficiency, and the
Administrator approves the plan or plan
revision, before the Administrator
promulgates such Federal implementation
plan.’’
Thus, because we disapproved
portions of the Billings/Laurel SO2 SIP,
and the attainment demonstration, we
are required to promulgate a FIP.
Section 302(y) defines the term
‘‘Federal implementation plan’’ in
pertinent part, as:
‘‘[A] plan (or portion thereof) promulgated
by the Administrator to fill all or a portion
of a gap or otherwise correct all or a portion
of an inadequacy in a State implementation
plan, and which includes enforceable
emission limitations or other control
measures, means or techniques (including
economic incentives, such as marketable
permits or auctions or emissions allowances)
* * *’’
More simply, a FIP is ‘‘a set of
enforceable federal regulations that
stand in the place of deficient portions
of a SIP.’’ McCarthy v. Thomas, 27 F.3d
1363, 1365 (9th Cir. 1994). As the Court
of Appeals for the D.C. Circuit noted in
a 1995 case, FIPs are powerful tools to
remedy deficient state action:
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‘‘The FIP provides an additional incentive
for state compliance because it rescinds state
authority to make the many sensitive
technical and political choices that a
pollution control regime demands. The FIP
provision also ensures that progress toward
NAAQS attainment will proceed
notwithstanding inadequate action at the
state level.’’
Natural Resources Defense Council, Inc. v.
Browner, 57 F.3d 1122, 1124 (D.C. Cir. 1995).
When EPA promulgates a FIP, courts
have not required EPA to demonstrate
explicit authority for specific measures:
‘‘We are inclined to construe Congress’
broad grant of power to the EPA as
including all enforcement devices
reasonably necessary to the achievement
15 Section 110(k)(1)(A) requires the Administrator
to promulgate minimum criteria that any plan
submission must meet before EPA is required to act
on the submission. These completeness criteria are
set forth at 40 CFR 51, Appendix V.
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and maintenance of the goals
established by the legislation.’’ South
Terminal Corp. v. EPA, 504 F.2d 646,
669 (1st Cir. 1974). As the Ninth Circuit
stated in a case involving a FIP with farreaching consequences in Los Angeles:
‘‘The authority to regulate pollution
carries with it the power to do so in a
manner reasonably calculated to reach
that end.’’ City of Santa Rosa v. EPA,
534 F.2d 150, 155 (9th Cir. 1976),
vacated and remanded on other grounds
sub nom. Pacific Legal Foundation v.
EPA, 429 U.S. 990 (1976).
In addition to giving EPA remedial
authority, section 110(c) enables EPA to
assume the powers that the state would
have to protect air quality, when the
state fails to adequately discharge its
planning responsibility. As the Ninth
Circuit held, when EPA acts to fill in the
gaps in an inadequate state plan under
section 110(c), EPA ‘‘ ‘stands in the
shoes of the defaulting State, and all of
the rights and duties that would
otherwise fall to the State accrue instead
to EPA.’ ’’ Central Arizona Water
Conservation District v. EPA, 990 F.2d
1531, 1541 (9th Cir. 1993). As the First
Circuit held in an early case:
‘‘[T]he Administrator must promulgate
promptly regulations setting forth ‘an
implementation plan for a State’ should the
state itself fail to propose a satisfactory one
* * *. The statutory scheme would be
unworkable were it read as giving to EPA,
when promulgating an implementation plan
for a state, less than those necessary
measures allowed by Congress to a state to
accomplish federal clean air goals. We do not
adopt any such crippling interpretation.’’
South Terminal Corp. v. EPA, supra, at 668
(citing previous version of section 110(c)).
III. FIP Proposal
As discussed above, in this proposed
rulemaking, EPA is fulfilling its
mandatory duty under section 110(c) of
the Act to propose FIP provisions for the
Billings/Laurel, Montana area because
of our limited and partial disapproval of
portions of the Billings/Laurel SO2 SIP
submitted by Montana. Our proposed
FIP would not replace the SIP entirely,
but instead would only replace elements
of the SIP or fill gaps in the SIP as
necessary to ensure attainment and
maintenance of the SO2 NAAQS. In
cases where the provisions of the FIP
would address emissions activities
differently or establish different
requirements than provisions of the SIP,
the provisions of the FIP would take
precedence.
Our proposed FIP only impacts four
stationary sources: CHS Inc.,
ConocoPhillips, ExxonMobil and
Montana Sulphur & Chemical Company
(MSCC). We caution that if any of these
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sources are subject to more stringent
requirements under other provisions of
the Act (e.g., section 111 or 112, part C,
or SIP-approved permit programs under
Part A), our proposal of any FIP
requirement would not excuse any of
these sources from meeting other more
stringent requirements. Also, our
proposed FIP is not meant to imply any
sort of applicability determination
under other provisions of the Act (e.g.,
section 111 or 112, part C, or SIPapproved permit programs under Part
A).
A. Flare Requirements Applicable to All
Sources
We disapproved the Billings/Laurel
SO2 SIP as it applied to the attainment
demonstration because the SIP lacked
enforceable emission limits for flares,
while the SIP submission took credit for
such emission limits. See our May 2,
2002, final rulemaking action at 67 FR
22168. Because of this disapproval we
are proposing emission limits and
compliance determining methods for
flares at CHS Inc., ConocoPhillips
(including Jupiter Sulfur),16
ExxonMobil, and MSCC. The flare
emission limits and compliance
determining methods are being
proposed for the purpose of assuring
attainment and maintenance of the SO2
NAAQS.
Since the state’s attainment
demonstration assumed that the main
flares at each source were limited to 150
pounds of SO2 per three hour period,
and that the Jupiter Sulfur SRU flare
would share an emission limit of 75
pounds of SO2 per three hour period
with the Jupiter Sulfur SRU/ATS stack,
we are proposing to promulgate flare
emission limits that reflect the state’s
assumption that emissions from these
points would not exceed these levels.
More specific detail regarding each of
the sources’ emission limits is provided
below in sections III. B, C, D, and E.
While we are proposing that 150
pounds of SO2 per three hour period be
the limit for the main flares, we are
soliciting input on whether we should
instead limit the main flares to 500
pounds of SO2 per calendar day. This
value is consistent with a trigger point
for certain analyses contained in
settlements between the United States
and CHS Inc., ConocoPhillips, and
ExxonMobil. For purposes of our
attainment demonstration, we have
assumed that the 500 pounds would be
emitted from the four main flares over
a three-hour period rather than a
16 The ConocoPhillips Billings Refinery also
includes the Jupiter Sulfur Recovery Facility (see
reference document S).
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calendar day. Our evaluation shows that
even under these conditions, the 3-hour
SO2 NAAQS would be attained.
Note that if we adopted the 500
pound value for this FIP, we would
impose it as an enforceable emission
limit, not just a trigger point for further
analyses.
We are proposing that the flare limits
will apply at all times without
exception. We recognize that flares are
sometimes used as emergency devices at
refineries and that it may be difficult to
comply with these flare limits during
malfunctions. However, under our
interpretations of the Clean Air Act, it
is not appropriate to create automatic
exemptions from SIP limits needed to
demonstrate attainment. (See reference
document RRR, September 20, 1999
memorandum titled ‘‘State
Implementation Plans: Policy Regarding
Excess Emissions During Malfunctions,
Startup, and Shutdown,’’ from Steven
A. Herman and Robert Perciasepe, to
Regional Administrators (referred to
hereafter as ‘‘1999 policy statement’’).)
We do interpret the CAA to allow
owners and operators of sources to
assert an affirmative defense to penalties
in appropriate circumstances, but
normally we would not view such an
affirmative defense as appropriate in
areas where a single source or small
group of sources has the potential to
cause an exceedance of the NAAQS. See
1999 policy statement. We solicit
comment on whether it would be
appropriate to include in our final FIP
the ability to assert an affirmative
defense to penalties only (not injunctive
relief) for violations of the flare limits.
If we were to establish such a provision,
we anticipate it would closely follow
the guidance contained in our 1999
policy statement.
We are also proposing that
compliance with the emission limits be
determined by measurement of the total
sulfur concentration and volumetric
flow rate of the gas stream to the flare(s),
followed by calculation, using
appropriate equations, of SO2 emitted
per 3-hour period. The assumption is
that when the gas stream is combusted
in a flare, all of the sulfur in the gas
stream converts to SO2 and is emitted to
the atmosphere. Also, by knowing the
volumetric flow rate of the gas stream to
the flare(s) we can determine the SO2
emitted to the atmosphere over a
specified timeframe.
With respect to the volumetric flow
rate monitoring systems, we developed
our proposed approach considering
volumetric flow rate monitoring
requirements established at refinery
flares in California and Texas, vendor
literature, technical articles, and
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information gathered from discussions
with vendors. (See reference documents
KK (Bay Area Air Quality Management
District (BAAQMD)—documents related
to consideration of proposed new
regulation 12, Rule 11 Flare Monitoring
at Petroleum Refineries); LL (final
version of BAAQMD Regulation 12,
Miscellaneous Standards of
Performance, Rule 11, Flare Monitoring
at Petroleum Refineries); BBB (South
Coast Area Air Quality Management
District (SCAQMD)—documents related
to consideration of revisions to rule
1118, Control of Emissions From
Refinery Flares); CCC (final version of
SCAQMD Rule 1118, Control of
Emissions From Refinery Flares); MM
(Texas Natural Resource Conservation
Commission, Chapter 115—Control of
Air Pollution from Volatile Organic
Compounds, Subchapter H: HighlyReactive Volatile Organic Compounds,
Division 1: Vent Gas Control); NN (Fluid
Components International LLC (FCI),
vendor literature from
www.fluidcomponents.com); OO (GE
Sensing, vendor literature); PP (‘‘Why
and How to measure flare gas’’ from
Flowmeter Directory
(www.flowmeterdirectory.com)); QQ
(‘‘Transit-time Ultrasonic Flowmeters
for Gases’’ Presented at and Published
in Part in the Proc. 41st Annual CGA
(Canadian Gas Association) Gas
Measurement School, Grand Okanagan,
Kelowna BC, Canada, June 4–6, 2002);
RR (‘‘Flare Measurement ‘Best Practices’
To Comply With National & Provincial
Regulations’’); SS (‘‘Ultrasonic
Flowmeter Market is Expected to Grow
Strongly’’); TT (Note to Billings/Laurel
SO2 FIP File, April 7, 2004 Discussion
with Peter Klorer, GE Infrastructure,
Regarding Panametrics Mass
Flowmeter); HHH (Note to Billings/
Laurel SO2 FIP File, April 20, 2006
Discussion with Paul Calef, GE Sensing,
Regarding Flare Flowmeter).) Based on
what is required elsewhere and what we
have learned from vendors and
literature, we have determined that
there is reliable technology available to
continuously monitor and record the
volumetric flow rate of the gas stream to
a flare. Therefore, we are proposing that
sources install, calibrate, maintain and
operate a continuous flow monitoring
system capable of measuring the total
volumetric flow of the gas stream that is
combusted in a flare in accordance with
the specifications described below. The
flow monitoring system may require one
or more flow monitoring devices or flow
measurements at one or more header
locations if one monitor cannot measure
all of the volumetric flow to a flare.
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We are proposing the following
volumetric flow monitoring
specifications:
(1) The minimum detectible velocity
of the flow monitoring device(s) shall be
0.1 feet per second (fps);
(2) The device(s) shall continuously
measure the range of flow rates
corresponding to velocities from 0.5 to
275 fps and have a manufacturer’s
specified accuracy of ±5% over the
range of 1 to 275 fps;
(3) For correcting flow rate to
standard conditions (defined as 68°F
and 760 millimeters of mercury
(mmHg)), temperature and pressure
shall be monitored continuously;
(4) The temperature and pressure
shall be monitored in the same location
as the flow monitoring device(s) and
shall be calibrated to meet accuracy
specifications as follows: temperature
shall be calibrated annually to within
±2.0% at absolute temperature and the
pressure monitor shall be calibrated
annually to within ±5.0 mmHg;
(5) Flow monitoring device(s) shall be
initially calibrated, prior to installation,
to demonstrate accuracy to within 5.0%
at flow rates equivalent to 30%, 60%
and 90% of monitor full scale; and
(6) After installation, the flow
monitoring devices shall be calibrated
annually according to manufacturer’s
specifications.17
With respect to measuring the total
sulfur concentration, we developed our
proposed approach considering
concentration monitoring requirements
established at refinery flares in
California, vendor iterature, and
information gathered from discussions
with vendors. (See reference documents
UU (Note to Billings/Laurel SO2 FIP
File, May 11, 2004 Discussion with
Robert Hornberger, Galvanic Applied
Sciences); VV (Galvanic Applied
Sciences Inc., H2S & Total Sulfur
Analyzers, vendor literature printed
from www.galvanic.ab.ac); KK (Bay Area
Air Quality Management District
(BAAQMD)—documents related to
consideration of proposed new
regulation 12, Rule 11, Flare Monitoring
17 Volumetric flow monitors meeting the
proposed volumetric flow monitoring specifications
above should be able to measure the majority of
volumetric flow in the gas streams to the flare.
However, in rare events (e.g., such as upset
conditions) the flow to the flare may exceed the
range of the monitor. EPA is not suggesting that
multiple monitors be installed to measure extreme
flow rates that rarely occur. Rather, in the rare event
that the range of the monitor is exceeded, reliable
flow estimation parameters may be used to
determine the volumetric flow rate to the flare.
Flow determined through reliable estimation
parameters will be used to calculate SO2 emissions.
In quarterly reports, sources shall indicate when
reliable estimation parameters are used and how
such parameters were derived.
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at Petroleum Refineries); BBB (South
Coast Area Air Quality Management
District (SCAQMD)—documents related
to consideration of revisions to rule
1118, Control of Emissions From
Refinery Flares); CCC (final version of
SCAQMD Rule 1118, Control of
Emissions From Refinery Flares); XX
(Note to Billings/Laurel SO2 FIP File,
May 10 and May 31, 2006 Discussions
with Tom Kimbel, Analytical Systems
International, Regarding Total Sulfur
Analyzers); YY (Analytical Systems
International, Continuous Sulfur
Analyzer, vendor literature printed from
www.ASIWebPage.com); III (Note to
Billings/Laurel SO2 FIP File, April 19,
2006 Discussion with Bob Kinsella,
ThermoElectron, Regarding Total Sulfur
Analyzer); JJJ (Note to Billings/Laurel
SO2 FIP File, May 12, 2006, and June 7,
2006 Discussions with Eugene Teszler,
South Coast Air Quality Management
District, regarding Total Sulfur
Analyzer).) Based on what is required
elsewhere and what we have learned
from vendors, we have determined that
there is reliable technology available to
continuously monitor and record the
total sulfur concentration of the gas
stream to a flare. Also, we are proposing
that the total sulfur concentrations,
rather than just H2S concentrations, be
monitored continuously. This is because
we believe there are other sulfur
compounds in the gas stream to a flare.
The total sulfur analyzer system may
require one or more total sulfur
analyzers or total sulfur concentration
measurements at one or more header
locations if one analyzer cannot
measure all of the total sulfur
concentration to a flare.
Therefore, we are proposing that
sources install, calibrate, maintain and
operate an on-line analyzer system
capable of continuously determining the
total sulfur concentration of the gas
stream sent to a flare. We are proposing
that the continuous monitoring occur at
a location(s) that is (are) representative
of the gas combusted in the flare and be
capable of measuring the expected range
of total sulfur expected in the gas stream
to the flare. Vendor literature and
discussions with vendors indicates this
is feasible. The total sulfur analyzer
shall be installed, certified (on a
concentration basis), and operated in
accordance with 40 CFR part 60,
Appendix B, Performance Specification
5, and be subject to and meet the quality
assurance and quality control
requirements (on a concentration basis)
of 40 CFR part 60, Appendix F. The
source shall notify EPA in writing of
each Relative Accuracy Test Audit a
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minimum of twenty-five (25) working
days prior to the actual testing.
We are proposing that the volumetric
flow and total sulfur concentrations
determined by the above procedures be
used in calculations to determine the
hourly and three hour SO2 emissions
from the flare(s).
We are proposing that each source
submit for EPA review and approval a
flare monitoring plan prior to
establishing continuous monitors on the
flare(s). Also, we are proposing that
each source submit for EPA review a
quality assurance/quality control (QA/
QC) plan for each of the continuous
monitors.
Finally, we are proposing certain
quarterly reporting requirements. The
quarterly reporting requirements are
similar to the reporting requirements
contained in the Billings/Laurel SO2 SIP
and those contained in 40 CFR 60.7(c).
B. CHS Inc.
1. Flare Requirements
The state’s attainment demonstration
and our subsequent attainment
modeling for the FIP assume that CHS
Inc.’s flare is limited to 150 pounds of
SO2 per three hour period.18, 19 This is
the limit we are proposing for CHS
Inc.’s flare. Compliance with the flare
emission limit will be determined as
discussed in Section III.A, above.
2. Combustion Sources Emission Limits.
Three of the emission limits
contained in CHS Inc.’s portion of the
Billings/Laurel SO2 SIP are combined
emission limits for combustion sources.
The emission limits, contained in CHS
Inc.’s 1998 exhibit, are in pounds of SO2
per 3-hour, 24-hour and one-year
averaging periods.20 Compliance with
the emission limits is determined by
measuring the sulfur and H2S content of
the fuels combusted (oil and fuel gas)
and the flow of the fuels to the
combustion sources. The state’s
assumption is that when the sulfur/H2S
in the fuel is combusted, all the sulfur/
H2S converts to SO2 and is emitted to
the atmosphere. By measuring sulfur/
H2S content of the fuel and the flow of
the fuel to the combustion sources, the
amount of SO2 emitted per 3-hour, 24hour and one-year averaging periods can
be calculated. CHS Inc.’s 1998 exhibit
also allows sour water stripper (SWS)
overheads (ammonia (NH3) and H2S
18 See Modeling discussion in Section III.E.5,
below.
19 Our FIP assumes that CHS Inc. has only one
operational flare. See reference documents PPP and
QQQ.
20 Section 3(A)(1)(d) of CHS Inc.’s 1998 exhibit.
(See reference document DD for a copy of the
exhibit.)
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gases removed from the sour water in
the sour water stripper), to be
combusted in the main crude heater.
When the SWS overheads are
combusted in the main crude heater,
compliance with the combustion source
emission limits is determined by
summing the SO2 emissions calculated
from the combustion of the fuels and
SWS overheads. The SO2 emissions
from the SWS overheads are determined
by measuring the sulfur compounds in,
and the flow of, the sour water.
We were concerned that the method
the state established to measure the
amount of sulfur compounds in the sour
water at CHS Inc. would not measure all
the sulfur compounds in the sour
water.21 Specifically, we concluded that
the analytical method submitted in the
SIP would not measure all of the sulfur
compounds in the sour water because of
the potentially high concentrations of
sulfur compounds; there would not be
enough preservative in the sample
container to prevent the loss of the
sulfur compounds during sampling and
analysis. (See reference document X.)
Therefore, the emissions of SO2 from the
combustion of SWS overheads in the
main crude heater could be
underestimated. We concluded that the
combustion source emission limits were
not enforceable under all scenarios and,
therefore, did not meet the requirements
of section 110(a)(2)(A) of the Act. On
May 22, 2003 (68 FR 27908), we
limitedly approved and limitedly
disapproved the combustion source
emission limits and method used to
measure the sulfur compounds in the
sour water.
After the state adopted CHS Inc.’s
1998 and 2000 exhibits as part of the
SIP, the state modified CHS Inc.’s air
quality permit to prohibit the burning of
‘‘old’’ sour water stripper overheads in
the FCC CO boiler and the main crude
heater. See Air Quality Permit #1821–
11, provision II.C.1. (See reference
document B.) The state has not modified
the SIP to correspond to the changes in
CHS Inc.’s air quality permit.22
21 For measuring the sulfur compounds in the
sour water, the state established Method #6A–1
contained in attachment #2 of CHS Inc.’s 2000
exhibit. (See reference document EE for a copy of
the exhibit.)
22 Page 11 of the State’s CHS Inc. Permit Analysis,
attached to Permit #1821–11 (see reference
document B) discusses the SWS and indicates that
a new SWS stripper was constructed, which
replaced the operation of the older existing SWS.
The old SWS cannot be removed, however, and
functions only as the back-up unit. The Permit
Analysis further indicates that the stripper
overhead gas containing H2S and NH3, is sent to the
new SRU for sulfur recovery and incineration of
NH3. This was confirmed in a conversation with the
DEQ (see reference document DDD).
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To address our limited disapproval of
the combustion source emission limits
in the SIP, we are proposing a
prohibition in the FIP on the burning of
SWS overheads in the main crude
heater. Prohibiting the burning of SWS
overheads in the main crude heater will
eliminate our concern regarding the
method used to measure the amount of
sulfur compounds in the sour water. We
believe it is reasonable to make this
proposal because the state and CHS Inc.
have already agreed to such restrictions
in CHS Inc.’s air quality permit.
Compliance with the prohibition to
not burn SWS overheads in the main
crude heater will be based on methods
similar to those contained in CHS Inc.’s
1998 exhibit. Specifically, section
3(B)(3) of the 1998 exhibit requires CHS
Inc. to install a chain and lock on the
valve that supplies sour water stripper
overheads from the ‘‘old’’ SWS to the
main crude heater to insure that the
valve cannot be opened unless the chain
and lock are removed. Under our
proposed FIP, CHS Inc. would be
required to maintain the chain and lock
in place and keep the valve closed at all
times. CHS Inc. would be required to log
and report any noncompliance with this
provision.
C. ConocoPhillips
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1. Flare Requirements
The state’s attainment demonstration
and our subsequent attainment
modeling for the FIP assume that
ConocoPhillips’ main refinery flare is
limited to 150 pounds of SO2 per three
hour period.23 We understand that
ConocoPhillips actually has two main
flares—a north main flare and a south
main flare—but only operates one at a
time and that Jupiter Sulfur,
ConocoPhillips’ sulfur recovery unit
(SRU), also has one flare.
Correspondence from ConocoPhillips,
dated February 4, 2004, indicates that
the north flare is currently in use but the
south flare has been used in alternating
4-year cycles, with switches at full plant
turnarounds. (See reference document
C.) Conversations with the MDEQ on
September 1, 2004, confirm that only
one flare is used at a time and that a
section of the pipe going to the unused
flare is removed during the turnaround.
(See reference document W.) Therefore,
with respect to ConocoPhillips, in lieu
of establishing a separate emission limit
for each main flare, we are proposing
one emission limit for the main flare. At
any one time, ConocoPhillips may only
use either the north or south main flare.
23 See Modeling discussion in Section III.E.5,
below.
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We are proposing that compliance
with the main flare emission limit at
ConocoPhillips be determined by
measuring the total sulfur concentration
and volumetric flow rate of the gas
stream to the flare. To the extent that a
single monitoring location cannot be
used for both the north and south main
flare, ConocoPhillips will need to
monitor flow and measure total sulfur
concentration at more than one location
to determine compliance with the main
flare emission limit.
Regarding the flare at the Jupiter
Sulfur Recovery facility located at
ConocoPhillips, the SRU flare and SRU/
ATS 24 stack, which are roughly the
same height, share an emission limit in
Montana’s air quality permit for
ConocoPhillips; the Jupiter SRU/ATS
stack and the SRU flare each have an
SO2 emission limit of 25.00 lb/hr and
0.300 tons/day. Emissions from the SRU
flare are only permitted during times
that the ATS plant is not operating. See
Air Quality Permit #2619–19, dated May
27, 2004, section II.B.1.a and b. (See
reference document S.)
However, the Billings/Laurel SO2 SIP
is not clear with respect to the
relationship between the SRU flare and
SRU/ATS stack. The SIP contains
emission limits on the Jupiter Sulfur
SRU stack but does not indicate that the
limits are shared between the SRU flare
and SRU/ATS stack.25 Since the SIP is
not clear, we are proposing to clarify in
the FIP that emissions can only be
vented from the SRU flare when
emissions are not being vented from the
SRU/ATS stack. We believe that our
proposal is consistent with what the
state and ConocoPhillips intended in
the SIP. First, the SRU flare and SRU/
ATS stack were modeled as one point in
the state’s attainment demonstration.
Second, Air Quality Permit #2619–19,
dated May 27, 2004, indicates that
emissions from the SRU flare can only
occur during times that the ATS plant
is not operating.
We are proposing that compliance
with the SRU flare emission limit, when
Jupiter Sulfur vents emissions to the
SRU flare rather than the SRU/ATS
stack, be determined by measuring the
total sulfur concentration and
volumetric flow rate of the gas stream to
the flare.26 Our proposal regarding the
SRU flare supports our attainment
demonstration.
stands for Ammonium Thiosulfate.
section 3(A)(3) of ConocoPhillips’ 1998
exhibit. (See document FF for a copy of the exhibit.)
26 Note that the SRU/ATS stack has an SO CEMS
2
and flow monitor to determine compliance when
emissions are vented through that stack.
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25 See
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D. ExxonMobil
1. Flare Requirements
The state’s attainment demonstration
and our subsequent attainment
modeling for the FIP assume that
ExxonMobil’s primary process and
turnaround flares are limited to 150
pounds of SO2 per three hour period.27
From correspondence from ExxonMobil,
dated February 4, 2004, we understand
that ExxonMobil has a turnaround flare
that is only used about 30–40 days every
five to six years, when the facility’s
major SO2 source, the fluid catalytic
cracking unit, is not normally operating.
(See reference document E.) Therefore,
in lieu of establishing a separate
emission limit for the turnaround flare,
we are proposing one combined
emission limit for the primary process
and turnaround flares.
Our assumption is that the flow and
concentration monitoring devices
installed to measure the gas stream to
the primary process flare will also be
able to measure the gas stream to the
turnaround flare. To the extent that a
single monitoring location cannot be
used to measure the gas stream to both
the primary process flare and the
turnaround flare, we may allow
alternative measures to determine
volumetric flow rate and total sulfur
concentrations of the gas stream to the
turnaround flare if the turnaround flare
is used infrequently—e.g., only for
refinery turnarounds once every five to
six years. Such alternative measures
could include using good engineering
judgment to determine volumetric flow
rate to the flare or manually sampling
the gas stream to the flare to determine
total sulfur concentrations.
2. Compliance Monitoring of Refinery
Fuel Gas Combustion Emission Limits
Two of the emission limits contained
in the ExxonMobil portion of the
Billings/Laurel SO2 SIP are combined
emission limits for refinery fuel gas
combustion sources. The emission
limits, contained in ExxonMobil’s 1998
and 2000 exhibits, are in pounds of SO2
per 3-hour and 24-hour averaging
periods.28 Compliance with the
emission limits is determined by
measuring the H2S content of the
refinery fuel gas combusted and the
flow of the fuel gas to the combustion
27 See Modeling discussion in Section III.E.5,
below.
28 See sections 3(A)(1) and 3(B)(2) of
ExxonMobil’s 1998 and 2000 exhibits. (See
reference documents GG and HH for copies of the
exhibits.)
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sources.29 The state’s assumption is that
when the fuel is combusted, all the H2S
converts to SO2 and is emitted to the
atmosphere. By measuring H2S content
of the fuel and the flow of the fuel to
the combustion sources, the amount of
SO2 emitted per 3-hour and 24-hour
averaging periods can be calculated.
We were concerned that the method
the state established to measure the H2S
concentration was not adequate under
all scenarios. Specifically, we
determined that the H2S concentrations
in refinery fuel gas could exceed the
levels which the H2S continuous
emission monitoring system (CEMS)
would be able to monitor.30 Therefore,
the emissions of SO2 from the refinery
fuel gas combustion sources could be
underestimated. We concluded that the
refinery fuel gas combustion sources
emission limits were not enforceable
under all scenarios and, therefore, did
not meet the requirements of section
110(a)(2)(A) of the Act. On May 22, 2003
(68 FR 27908), we limitedly approved
and limitedly disapproved the refinery
fuel gas combustion emission limits and
method used to measure the H2S in the
refinery fuel gas.
Because of this limited disapproval,
we are proposing a new method for
measuring the H2S concentrations in the
refinery fuel gas when the H2S
concentrations in the refinery fuel gas
exceed the range of the H2S CEMS. The
method we are proposing is identical to
the method included in CHS Inc.’s 1998
exhibit.31
Specifically, we are proposing that
within 4 hours of the initial
determination that the H2S
concentrations in the refinery fuel gas
stream exceed the upper range of the
H2S CEMS, ExxonMobil shall initiate
sampling of the refinery fuel gas stream
at the fuel header on a once-per-threehour-period frequency using the
Tutwiler method in 40 CFR 60.648. The
Tutwiler method will determine the H2S
concentration in the refinery fuel gas.
We are also proposing that the Tutwilerderived H2S refinery fuel gas
concentration be used in calculations to
determine the hourly, 3-hour and 2429 See section 4(B) of ExxonMobil’s 1998 exhibit.
(See reference document GG for a copy of the
exhibit.)
30 Section 6(B)(3) of ExxonMobil’s 1998 exhibit
indicates that ExxonMobil shall insure that the H2S
concentration monitor at the refinery fuel header is
capable of measuring H2S concentrations in the
range of 0–1200 ppmv. (See document GG for a
copy of the exhibit.) The information available to
us indicated that the H2S concentrations in the
refinery fuel gas could exceed 1200 ppmv. (See
reference document JJ.)
31 See section 6(B)(3) of CHS Inc.’s 1998 exhibit.
(See reference document DD for a copy of the
exhibit.)
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hour SO2 emission rates, in pounds,
from refinery fuel gas combustion.
These emission rates would then be
used to determine compliance with the
refinery fuel gas combustion emission
limits in ExxonMobil’s 1998 and 2000
exhibits when the H2S concentrations in
the refinery fuel gas stream exceed the
upper range of the H2S CEMS.32
We are also proposing reporting
requirements similar to the
requirements adopted by the state for
CHS Inc. and those contained in 40 CFR
60.7(c).
3. Compliance Monitoring of Coker COBoiler Emission Limits
Two of the emission limits contained
in the ExxonMobil portion of the
Billings/Laurel SO2 SIP are emission
limits on the coker CO-boiler stack. The
emission limits contained in
ExxonMobil’s 2000 exhibit are in
pounds of SO2 per 3-hour and 24-hour
averaging periods.33 In the SIP,
compliance with the emission limits is
based on an equation that was derived
from historical testing and CEMS data,
whereby one can determine pounds of
SO2 emitted from the coker CO-boiler by
multiplying a constant by the coker
fresh feed rate (in barrels/day).34
We had three concerns with the
state’s empirical method for
determining compliance with
ExxonMobil’s coker CO-boiler stack
emission limits and they were as
follows: (1) The empirical method did
not apply, and hence there was no
compliance monitoring method, when
the sulfur content of the reactor feed
exceeded 5.11 percent by weight. We
believed the SIP should contain a
compliance monitoring method for all
operating scenarios; (2) The compliance
monitoring equation was basically the
‘‘best fit’’ line through the test data. To
be more conservative, we believed the
compliance monitoring equation should
be the upper bound of the 95%
confidence level of the equation; and (3)
Finally, since a feed-rate meter for the
coker unit was required for the
compliance monitoring method, the
feed-rate meter should have been
subject to Quality Assurance/Quality
Control (QA/QC) requirements similar
to those for the FCC feed-rate meter.
Therefore, we concluded that the
32 See sections 3(A)(1) and 3(B)(2) of
ExxonMobil’s 1998 and 2000 exhibits. (See
reference documents GG and HH for copies of the
exhibits.)
33 See section 3(B)(1) of ExxonMobil’s 2000
exhibit. (See reference document HH for a copy of
the exhibit.)
34 See section 4(c) of ExxonMobil’s 2000 exhibit.
(See reference document HH for a copy of the
exhibit.)
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emission limits under section 3(B)(1) of
ExxonMobil’s 2000 exhibit were
enforceable under some but not all
scenarios and did not satisfy the
requirements of section 110(a)(2)(A) of
the Act. (See 67 FR 22242, at 22244, col.
2 (May 2, 2002).) On May 22, 2003 (68
FR 27908), we limitedly approved and
limitedly disapproved the coker COboiler stack emission limits and method
used to monitor compliance.
ExxonMobil’s 1998 exhibit requires
ExxonMobil to install portable CEMS to
monitor the SO2 and flow to the coker
CO-boiler stack or implement an
Alternative Monitoring Plan approved
by the Department and EPA if
ExxonMobil exhausts coker unit flue gas
through the coker CO-boiler stack more
than 336 hours in a calendar quarter.35
ExxonMobil exceeded the 336 hours per
calendar quarter, and on March 20,
2002, the state required ExxonMobil to
install SO2 and flow CEMS on the coker
CO-boiler stack. On October 21, 2002,
the state sent a letter to ExxonMobil
indicating that the reported test results
of the monitors demonstrated that the
SO2 CEMS and flow monitors met the
testing requirements. (See reference
documents T & U, respectively.)
Since SO2 and flow CEMS have
already been installed on the coker COboiler stack, we are proposing that these
CEMS, in conjunction with the
appropriate calculations mentioned
below, be used to determine compliance
with the emission limits established in
section 3(B)(1) of ExxonMobil’s 2000
exhibit. Specifically, we are proposing
that ExxonMobil operate and maintain
CEMS to measure SO2 concentrations
from the coker CO-boiler stack and a
continuous stack flow rate monitor to
measure stack gas flow rates from the
coker CO-boiler stack. We are proposing
that the SO2 and flow rate CEMS meet
the CEM Performance Specifications
contained in sections 6(C) and (D),
respectively, of ExxonMobil’s 1998
exhibit, except that ExxonMobil shall
notify EPA in writing of each annual
Relative Accuracy Test Audit a
minimum of twenty five (25) working
days prior to actual testing.
We are proposing that compliance
with ExxonMobil’s coker CO boiler
emission limits 36 be determined using
the data from the CEMS mentioned
above and in accordance with the
appropriate calculations described in
35 See section 6(B)(4) of ExxonMobil’s 1998
exhibit (See reference document GG for a copy of
the exhibit.)
36 See section 3(B)(1) of ExxonMobil’s 2000. (See
reference document HH for a copy of the exhibit.)
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ExxonMobil’s 1998 exhibit.37 We are
also proposing reporting requirements
similar to the requirements adopted in
the Billings/Laurel SO2 SIP and those
contained in 40 CFR 60.7(c).
E. Montana Sulphur & Chemical
Company (MSCC)
1. Flare Requirements
The state’s attainment demonstration
and our subsequent attainment
modeling for the FIP assume that
MSCC’s flares are limited to a combined
total of 150 pounds of SO2 per threehour period.38 We understand that
MSCC actually has three flares at the
plant that serve a common flare system.
Correspondence from MSCC, dated
February 4, 2004, indicates that there is
an 80-foot west flare, 125-foot east flare,
and 100-meter flare. (See reference
document H.) In discussions with MSCC
on March 9, 2004, we confirmed that
MSCC understood that the state’s 150
lbs of SO2/3-hour limit was intended to
be a ‘‘bubble’’ or combined limit for all
three flares. (See reference document V.)
Therefore, in lieu of establishing a
separate emission limit for each of the
three flares, we are proposing one
combined emission limit for the three
flares. Compliance with the flare
emission limit will be determined as
discussed in Section III.A, above. In the
event MSCC cannot monitor all three
flares from a single monitoring location,
MSCC will need to establish multiple
monitoring locations.
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2. SRU 100-Meter Stack
On May 2, 2002, EPA disapproved SIP
emission limits the state established for
the sulfur recovery unit (SRU) 100meter stack because of improper stack
height credit (see 67 FR 22168).39
Because we disapproved the emission
limits, we are proposing the following
emission limits for the SRU 100-meter
stack: emissions of SO2 shall not exceed
(a) 3,003.1 pounds per three-hour
period, (b) 24,025.0 pounds per calendar
day, and (c) 9,088,000.0 pounds per
calendar year.40 The emission limits for
the SRU 100-meter stack are based on
modeling conducted by EPA to show
attainment of the SO2 NAAQS in the
Billings/Laurel area. A detailed
37 See sections 2(A)(1), (8), (11)(a), and (16) of
ExxonMobil’s 1998 exhibit. (See reference
document GG for a copy of the exhibit.)
38 See Modeling discussion in Section III.E.5,
below.
39 The emission limits were contained in sections
3(A)(1)(a) and (b) and 3(A)(3) of MSCC’s 1998
exhibit. (See reference document II for a copy of the
exhibit.)
40 Our FIP proposes to retain the calendar year
emission limit contained in section 3(A)(1)(a)(iv) of
MSCC’s 1998 exhibit. (See reference document II.)
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discussion of the modeling is contained
in Section III.E.5 of this document.
We are also proposing that
compliance with the above emission
limits be determined according to the
methods established in MSCC’s 1998
exhibit. Finally, we are proposing
certain quarterly reporting
requirements. The quarterly reporting
requirements are similar to the reporting
requirements contained in the Billings/
Laurel SO2 SIP and those contained in
40 CFR 60.7(c).
In the Billings/Laurel SO2 SIP, the
State of Montana adopted variable
emission limits for several sources,
including MSCC’s SRU 100-meter stack,
which depend on the ‘‘buoyancy flux’’
of the SO2 gas plume as it exits the
stack. Buoyancy flux is a function of gas
flow rate and gas temperature in the
stack, which varies within certain
parameters. While we approved variable
emission limits for several sources,
other than MSCC, we did so with
reservations. (See our July 28, 1999,
proposed rulemaking action on the
Billings/Laurel SO2 SIP, 64 FR 40791,
starting at 64 FR 40794, col. 3, and our
May 2, 2002, final rulemaking action, 67
FR 22168, starting 67 FR 22206, col. 2,
for a full discussion of our concerns
with the variable emission limit
concept.) We are proposing fixed
emission limits, rather than variable
emission limits, on MSCC’s SRU 100meter stack because they are less
complicated to model, monitor, and
enforce. For example, the state’s original
modeling effort to determine emissions
limits that included three variable
emission limited sources required a
total of 1320 modeling runs. A
conventional SIP modeling analysis
with fixed emission limits for each
source requires only a single modeling
run. Additionally, based on actual
emissions data for MSCC’s SRU 100meter stack for 2003, 2004 and 2005,
MSCC can meet the fixed 3-hour and 24hour emission limits we are proposing
(see reference documents FFF and
GGG).
3. SRU 30-Meter Stack
On May 2, 2002, EPA limitedly
approved and limitedly disapproved the
SRU 30-meter stack emission limits
because the SIP did not adequately limit
the fuel burned in the boilers and
heaters that exhaust through the SRU
30-meter stack, and did not provide a
monitoring method that would make the
emission limits practically enforceable
(see 67 FR 22168, at 22171).41
41 The emission limit is contained in section
3(A)(2) of MSCC’s 1998 exhibit. (See reference
document II for a copy of the exhibit.)
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Because of this limited disapproval,
we are proposing that H2S
concentrations in the fuel gas burned in
the boilers and heaters while any boiler
or heater is exhausting through the SRU
30-meter stack be limited to 100 ppm or
less, averaged over a three-hour period.
Our information indicates that limiting
H2S concentrations to this level should
assure compliance with the SRU 30meter stack emission limits. Worst-case
conditions would be when all the
heaters and boilers are exhausting to the
SRU 30-meter stack, operating at
maximum heat input capacity, and
using fuel with the lowest nominal fuel
gas value. Under these conditions,
MSCC would be using the maximum
volume of fuel, and potential emissions
of SO2 from the SRU 30-meter stack
would be greatest.
Using a heat input capacity value of
83 MM Btu/hour and a nominal fuel gas
value of 350 Btu/scf, we determined that
a limit of 100 ppm H2S would just
ensure compliance with the SRU 30meter stack’s 12.0 pounds of SO2/3-hour
limit.42 43 Since the daily and annual
limits are merely multiples of the 3-hour
limit, this concentration limit would
also ensure compliance with the daily
and annual limits.
To determine compliance with the
100 ppm H2S limit, we are proposing
that any time fuel other than natural gas
is burned in a heater or boiler that
exhausts to the SRU 30-meter stack,
MSCC must measure the H2S content of
the fuel burned within one hour from
when a heater or boiler begins
exhausting to the SRU 30-meter stack
and on a once-per-three-hour-period
frequency until no heater or boiler is
exhausting to the SRU 30-meter stack.
We are proposing that MSCC use a
portable H2S monitor to determine the
H2S content of the fuel burned. The
monitor must have a range of 0–500
ppm of H2S and an accuracy of +/¥2%
of full scale (i.e., the design range of the
monitor—in this case 500 ppm). (See
42 See reference documents TTT and UUU.
Reference document TTT contains information
supplied by MDEQ, including heat input capacities
for the various heaters and boilers, and nominal
fuel gas values. These are the values we used in our
calculations in reference document UUU.
43 The state’s technical review document for
MSCC’s Title V operating permit indicates that the
maximum heat input capacity for some of the
heaters and boilers could be greater than their
‘‘Bigelow’’ ratings (see reference document VVV).
To ensure attainment even at potentially higher
heat input capacities, we modeled the SRU 30meter stack at an emission rate of 15 lbs of SO2/
3-hours (0.63 g/s), 25% higher than the 12 lbs of
SO2/3-hour emission limit. At 0.63 g/s, we still
modeled attainment of the 3-hour and 24-hour SO2
NAAQS. Thus, the 100 ppm H2S concentration
would be consistent with attainment even if the
total heat input capacity of the heaters and boilers
were significantly higher.
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reference documents ZZ and AAA for
vendor literature and discussion notes
with vendor.)
While we are proposing the foregoing
approach for determining compliance
with the SRU 30-meter stack emission
limits, we are soliciting input on
whether we should promulgate a
different compliance determining
method. One alternative approach
would involve the measurement of H2S
concentrations as described above, but
would not create a concentration limit.
MSCC would be required to install a
fuel gas flow rate monitor that would
measure the flow of all the fuel burned
in the heaters and boilers, and keep logs
of (a) the dates and time periods that
emissions were exhausted through the
SRU 30-meter stack, (b) the heaters and
boilers exhausting to the SRU 30-meter
stack, (c) all the heaters and boilers
operating during such periods, and (d)
the type of fuel that is burned in any
heater or boiler at the time that
emissions were exhausted to the SRU
30-meter stack.
SO2 emissions from the SRU 30-meter
stack would be calculated based on the
H2S content of the fuel burned and the
flow of the fuel to the heaters and
boilers. Since the fuel flow meter would
be installed in the fuel gas header and
would measure all the fuel gas burned
regardless of whether or not all the
heaters or boilers were exhausting to the
SRU 30-meter stack, the calculations of
SO2 emissions from the SRU 30-meter
stack would be pro-rated based on the
estimated percentage of fuel burned in
the heaters and boilers exhausting to the
SRU 30-meter stack versus fuel burned
in all operating heaters and boilers.
We envision that one way to calculate
this pro-ration factor would be to divide
the maximum heat input capacity of the
heaters and boilers exhausting to the
SRU 30-meter stack by the maximum
heat input capacity of all operating
heaters and boilers during such periods.
In order to ensure compliance with the
three-hour emission limits, this proration factor would have to be
calculated on an hourly or, at most,
three-hourly basis.
We solicit input on other possible
approaches for determining compliance
with the SRU 30-meter stack emission
limits.
Finally, we are proposing quarterly
reporting requirements. The quarterly
reporting requirements are similar to the
reporting requirements contained in the
Billings/Laurel SO2 SIP and those
contained in 40 CFR 60.7(c).
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4. Combined SO2 Emission Limit From
the Auxiliary Vent Stacks
On May 2, 2002, EPA disapproved the
combined SO2 emission limit from the
auxiliary vent stacks because the SIP
did not restrict the sulfur content of the
fuel burned in the heaters and boilers
when they exhaust through the auxiliary
vent stacks, and lacked a monitoring
method that would make the emission
limit practically enforceable (see 67 FR
22168, at 22171).44 Because of this
disapproval, we are proposing
combined SO2 emission limits for the
auxiliary vent stacks and a method for
determining compliance with the
emission limits.
The emission limits we are proposing
are based on the emission limit in
MSCC’s 1998 exhibit 45 and apply to the
auxiliary vent stacks associated with the
Railroad Boiler, the H–1 Unit, the H1–
A Unit, the H1–1 Unit, and the H1–2
Unit. The issues associated with
monitoring compliance with these
limits are essentially the same as those
associated with monitoring compliance
with the SRU 30-meter stack emission
limits (see 67 FR 22168, at 22202, May
2, 2002, reference document AA). Thus,
we are proposing the same approach for
monitoring compliance with these
emission limits as we describe in
section III.E.3, above—H2S
concentrations in the fuel gas burned in
the boilers and heaters while any boiler
or heater is exhausting to the auxiliary
vent stacks would be limited to 100
ppm or less, averaged over a three-hour
period, and the same monitoring
requirements would apply. Similarly,
we are soliciting input on whether we
should promulgate a different
compliance determining method, as
described in section III.E.3 above.
Finally, we are proposing quarterly
reporting requirements. The quarterly
reporting requirements are similar to
reporting requirements contained in the
Billings/Laurel SO2 SIP and those
contained in 40 CFR 60.7(c).
5. Modeling To Support Emission
Limits
To establish MSCC’s SRU 100-meter
stack emission limits, EPA re-ran
Montana’s 1996 SIP modeling analysis
with some modifications explained
below. Our intent was to retain the
state’s original attainment modeling
analysis (which supports the emission
limits established for sources in the
44 The emission limits are contained in section
3(A)(4) of MSCC’s 1998 exhibit. (See document II
for a copy of the exhibit.)
45 The emission limit is contained in section
3(A)(4) of MSCC’s 1998 exhibit. (See document II
for a copy of the exhibit.)
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Billings/Laurel SO2), but modify the
files as necessary to establish SO2
emission limits at MSCC’s SRU 100meter stack based on a 65 meter stack
height credit and a fixed buoyancy flux.
We used the same dispersion model that
the state used (per EPA 1996 modeling
guidance (i.e., ISC2/Complex1)) and the
same meteorological data.
There were several minor modeling
input changes made for some of the
sources. In December 2003, EPA sent
letters (pursuant to section 114 of the
Act) to all of the sources in the Billings/
Laurel area requesting clarification on
the appropriate emission point
parameters for modeling. (See reference
documents L through R.) Based on the
responses to the 114 letters, we
modified some of the emission point
modeling parameters contained in the
state’s modeling analysis. The June 2006
Technical Support Document titled
‘‘Dispersion Modeling to Support Sulfur
Dioxide (SO2) Emission Limits in
Federal Implementation Plan (FIP) for
Billings/Laurel, Montana’’ (see reference
document WW) identifies the emission
point modeling parameters used in our
modeling analysis. The document also
identifies changes that were
recommended by sources but for various
reasons were not incorporated into
EPA’s modeling. An electronic record
(CD) of EPA’s modeling input and
output files is contained in the docket
(see reference document EEE).
In the state’s 1996 modeling, MSCC’s
SRU 100-meter stack was modeled with
a 97 meter stack height credit and a
variable emission limit linked to 10
stack buoyancy flux values. We
modeled MSCC’s SRU 100-meter stack
with a 65 meter stack height credit and
a single representative buoyancy flux
value. Buoyancy flux is a function of gas
flow rate and temperature in the stack.
The stack temperature we used in our
modeling, 540.0°K, was the mean stack
temperature measured with CEMS from
October 1, 2001, to September 30, 2003.
The mean stack velocity we used in our
modeling, 14.0 m/s, was back-calculated
from the buoyancy flux equation using
the buoyancy flux and temperature
values from October 1, 2001, to
September 30, 2003.46 47 It is EPA’s
modeling practice to select mean values
from historical data because, unless
there is some change in plant
46 The buoyancy flux (F) is defined as: F = (2.45
VD2 (Ts-T))/Ts. Where: F = buoyancy flux in m4/m3;
V = stack gas exit velocity in meters per second at
actual conditions; D = inside stack-top diameter in
meters (1.07 m); Ts = stack gas temperature in
Kelvin; and T = ambient air temperature in Kelvin
(assumed at 281.2 °K). (See reference document II)
47 See reference document FFF for temperature
and buoyancy flux values.
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configuration, future operations are
likely to reflect similar values.
It should be noted that with the
changes mentioned above, the 24-hour
highest receptor point modeled showed
the 24-hour and 3-hour SO2 highsecond-high (HSH) values to be 365 µg/
m3 and 1243.6 µg/m3, respectively. The
3-hour highest receptor point modeled
showed the 3-hour SO2 HSH value to be
1291.5 µg/m3. The SO2 24-hour and 3hour SO2 NAAQS are 365 µg/m3 and
1300 µg/m3, respectively. Therefore, the
FIP shows attainment of the NAAQS.
When we modeled the four process
flares at 500 lbs/3-hour period instead of
150 lbs/3-hour period, the 3-hour HSH
concentration at the highest 3-hour
receptor point only increased by 2 µg/
m3, to 1293.5 µg/m3. This means that
even if the four process flares were
allowed to emit SO2 at 500 lbs/3-hour
period, the FIP would still show
attainment of the 3-hour NAAQS. (We
modeled this alternative emissions rate
because, as discussed earlier, we are
inviting comment on whether we
should consider an emissions limit for
the process flares of 500 lbs SO2/
calendar day instead of 150 lbs/3-hour
period. We modeled the 500 pounds of
SO2 emissions over a 3-hour period to
ensure attainment of the 3-hour SO2
NAAQS.)
In the state’s modeling analysis
submitted with the SIP, the highest
receptor point modeled had 24-hour and
3-hour HSH SO2 values of 354 µg/m3
and 1245 µg/m3, respectively. This
difference in FIP and SIP modeling
outputs is due largely to the fact that
EPA modeled MSCC’s 100-meter SRU
stack at 65 meters. In addition, in their
responses to the section 114 letters
mentioned above, some sources
provided updated locations of emission
points. (It was not that emission points
had moved; the technology used to
describe the emission point locations
had changed.) Therefore, peak receptor
locations changed in the FIP versus SIP
modeling.
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IV. Request for Public Comment
EPA is soliciting public comment on
all aspects of this proposed FIP.
Interested parties should submit
comments according to the procedures
outlined earlier in the ADDRESSES
section and in Part (I)(A) of the
SUPPLEMENTARY INFORMATION section.
Comments received on or before
September 11, 2006 will be considered
in the final action taken by EPA.
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V. Statutory and Executive Order
Reviews
A. Executive Order 12866, Regulatory
Planning and Review
Under Executive Order 12866, 58 FR
51735 (October 4, 1993), all ‘‘regulatory
actions’’ that are ‘‘significant’’ are
subject to Office of Management and
Budget (OMB) review and the
requirements of the Executive Order. A
‘‘regulatory action’’ is defined as ‘‘any
substantive action by an agency
(normally published in the Federal
Register) that promulgates or is
expected to result in the promulgation
of a final rule or regulation, including
* * * notices of proposed rulemaking.’’
A ‘‘regulation or rule’’ is defined as ‘‘an
agency statement of general
applicability and future effect, * * *’’
The proposed FIP is not subject to
OMB review under E.O. 12866 because
it applies to only four specifically
named facilities and is therefore not a
rule of general applicability. Thus, it is
not a ‘‘regulatory action’’ under E.O.
12866, and was not submitted to OMB
for review.
B. Paperwork Reduction Act
Under the Paperwork Reduction Act,
44 U.S.C. 3501 et seq., OMB must
approve all ‘‘collections of information’’
by EPA. The Act defines ‘‘collection of
information’’ as a requirement for
‘‘answers to * * * identical reporting or
recordkeeping requirements imposed on
ten or more persons * * *’’ 44 U.S.C.
3502(3)(A). Because the proposed FIP
only applies to four companies, the
Paperwork Reduction Act does not
apply.
C. Regulatory Flexibility Act
Under the Regulatory Flexibility Act
(RFA), 5 U.S.C. section 601 et seq., EPA
generally must prepare a regulatory
flexibility analysis of any rule subject to
notice and comment rulemaking
requirements unless EPA certifies that
the rule will not have a significant
economic impact on a substantial
number of small entities. Small entities
include small businesses, small not-forprofit enterprises, and small
governmental jurisdictions. 5 U.S.C.
§§ 603, 604 and 605(b).
This proposed FIP will not have a
significant economic impact on a
substantial number of small entities
because this proposed FIP applies to
only four sources (CHS Inc.,
ConocoPhillips, ExxonMobil and
MSCC) in the Billings/Laurel, Montana
area. Therefore, I certify that this action
will not have a significant economic
impact on a substantial number of small
entities.
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D. Unfunded Mandates Reform Act
Title II of the Unfunded Mandates
Reform Act of 1995, Public Law 04–4,
establishes requirements for federal
agencies to assess the effects of their
regulatory actions on state, local, and
tribal governments and the private
sector. Under section 202 of UMRA,
EPA generally must prepare a written
statement, including a cost-benefit
analysis, for proposed rules and for final
rules for which EPA published a notice
of proposed rulemaking, if those rules
contain ‘‘federal mandates’’ that may
result in the expenditure by state, local,
and tribal governments, in the aggregate,
or by the private sector, of $100 million
or more in any one year. If section 202
requires a written statement, section 205
of UMRA generally requires EPA to
identify and consider a reasonable
number of regulatory alternatives.
Under section 205, EPA must adopt the
least costly, most cost-effective, or least
burdensome alternative that achieves
the objectives of the rule, unless the
Administrator publishes with the final
rule an explanation why EPA did not
adopt that alternative. The provisions of
section 205 do not apply when they are
inconsistent with applicable law.
Section 204 of UMRA requires EPA to
develop a process to allow elected
officers of state, local, and tribal
governments (or their designated,
authorized employees), to provide
meaningful and timely input in the
development of EPA regulatory
proposals containing significant Federal
intergovernmental mandates.
EPA has determined that the
proposed FIP contains no federal
mandates on state, local or tribal
governments, because it will not impose
any enforceable duties on any of these
entities. EPA further has determined
that the proposed FIP will not result in
the expenditure of $100 million or more
by the private sector in any one year.
Although the proposed FIP would
impose enforceable duties on entities in
the private sector, the costs are expected
to be less than $100 million in any one
year. Consequently, sections 202, 204,
and 205 of UMRA do not apply to the
proposed FIP.
Before EPA establishes any regulatory
requirements that might significantly or
uniquely affect small governments, it
must have developed under section 203
of UMRA a small government agency
plan. The plan must provide for
notifying potentially affected small
governments, enabling officials of
affected small governments to have
meaningful and timely input in the
development of EPA regulatory
proposals with significant Federal
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intergovernmental mandates, and
informing, educating, and advising
small governments on compliance with
the regulatory requirements.
EPA has determined that the
proposed FIP will not significantly or
uniquely affect small governments,
because it imposes no requirements on
small governments. Therefore, the
requirements of section 203 do not
apply to the proposed FIP.
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E. Executive Order 13132, Federalism
Executive Order 13132, Federalism
(64 FR 43255, August 10, 1999), revokes
and replaces Executive Orders 12612
(Federalism) and 12875 (Enhancing the
Intergovernmental Partnership).
Executive Order 13132 requires EPA to
develop an accountable process to
ensure ‘‘meaningful and timely input by
State and local officials in the
development of regulatory policies that
have federalism implications.’’ ‘‘Policies
that have federalism implications’’
include regulations that have
‘‘substantial direct effects on the States,
on the relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government.’’
The proposed rule does not have
federalism implications. This FIP will
not have substantial direct effects on the
states, on the relationship between the
national government and the states, or
on the distribution of power and
responsibilities among the various
levels of government, as specified in
Executive Order 13132. This rule
proposes standards appropriate for four
companies in the Billings/Laurel,
Montana area, and thus does not
directly affect any state or local
government. It does not alter the
relationship or the distribution of power
and responsibilities established by the
Clean Air Act. Thus, Executive Order
13132 does not apply to this rule.
In the spirit of Executive Order 13132,
and consistent with EPA policy to
promote communication between EPA
and State and local governments, EPA
specifically solicits comments on the
proposed rule from State and local
officials.
F. Executive Order 13175, Coordination
With Indian Tribal Governments
Executive Order 13175, entitled
‘‘Consultation and Coordination with
Indian Tribal Governments’’ (65 FR
67249, November 9, 2000), requires EPA
to develop an accountable process to
ensure ‘‘meaningful and timely input by
tribal officials in the development of
regulatory policies that have tribal
implications.’’
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This proposed rule does not have
tribal implications, as specified in
Executive Order 13175. It will not have
substantial direct effects on tribal
governments, on the relationship
between the Federal government and
Indian tribes, or on the distribution of
power and responsibilities between the
Federal government and Indian tribes as
specified in Executive Order 13175.
This Action does not involve or impose
any requirements that affect Indian
Tribes. Thus, Executive Order 13175
does not apply to this rule.
EPA specifically solicits comment on
this proposed rule from tribal officials.
G. Executive Order 13045, Protection of
Children From Environmental Health
Risks and Safety Risks
Protection of Children from
Environmental Health Risks and Safety
Risks (62 FR 19885, April 23, 1997),
applies to any rule that: (1) Is
determined to be ‘‘economically
significant’’ as defined under Executive
Order 12866, and (2) concerns an
environmental health or safety risk that
EPA has reason to believe may have a
disproportionate effect on children. If
the regulatory action meets both criteria,
the Agency must evaluate the
environmental health or safety effects of
the planned rule on children, and
explain why the planned regulation is
preferable to other potentially effective
and reasonably feasible alternatives
considered by the Agency.
This proposed FIP is not subject to the
Executive Order because it is not
economically significant as defined in
Executive Order 12866. Further, EPA
interprets Executive Order 13045 as
applying only to those regulatory
actions that are based on health or safety
risks, such that the analysis required
under section 5–501 of the Order has
the potential to influence the regulation.
This proposed FIP is not subject to
Executive Order 13045 because it
implements a previously promulgated
health and safety based Federal
standard.
H. Executive Order 13211, Actions That
Significantly Affect Energy Supply,
Distribution, or Use
This rule is not subject to Executive
Order 13211, ‘‘Actions Concerning
Regulations That Significantly Affect
Energy Supply, Distribution, or Use’’ (66
FR 28355, May 22, 2001) because it is
not a significant regulatory action under
Executive Order 12866.
I. National Technology Transfer and
Advancement Act
Section 12(d) of the National
Technology Transfer and Advancement
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Act (NTTAA) of 1995, Public Law No.
104–113 (15 U.S.C. 272 note), directs
EPA to use voluntary consensus
standards in its regulatory activities
unless to do so would be inconsistent
with applicable law or otherwise
impractical. Voluntary consensus
standards are technical standards (e.g.,
materials specifications, test methods,
sampling procedures, business
practices) that are developed or adopted
by voluntary consensus standards
bodies. The NTTAA directs EPA to
provide Congress, through OMB,
explanations when the Agency decides
not to use available and applicable
voluntary standards.
While the proposed rulemaking
involves technical standards, no
voluntary consensus standards have
been identified. EPA welcomes
comments on this aspect of the
proposed FIP and, specifically, invites
the public to identify potentiallyapplicable voluntary consensus
standards and to explain why such
standards should be used in this
regulation.
List of Subjects in 40 CFR Part 52
Environmental protection, Air
pollution control, Intergovernmental
relations, Reporting and recordkeeping
requirements, Sulfur oxides.
Authority: 42 U.S.C. 7401 et seq.
Dated: June 29, 2006.
Kerrigan G. Clough,
Acting Regional Administrator, Region 8.
For reasons stated in the preamble, 40
CFR part 52 is proposed to be amended
as follows:
PART 52—[AMENDED]
1. The authority citation for part 52
continues to read as follows:
Authority: 42 U.S.C. 7401 et seq.
Subpart BB—Montana
2. Subpart BB is proposed to be
amended by adding § 52.1392 to read as
follows:
§ 52.1392. Federal Implementation Plan for
the Billings/Laurel Area.
(a) Applicability. This section applies
to the owner(s) or operator(s), including
any new owner(s) or operator(s) in the
event of a change in ownership or
operation, of the following facilities in
the Billings/Laurel, Montana area: CHS
Inc. Petroleum Refinery, Laurel
Refinery, 803 Highway 212 South,
Laurel, MT; ConocoPhillips Petroleum
Refinery, Billings Refinery, 401 South
23rd St., Billings, MT; ExxonMobil
Petroleum Refinery, 700 ExxonMobil
Road, Billings, MT; and Montana
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Sulphur & Chemical Company, 627
Exxon Road, Billings, MT.
(b) Scope. The facilities listed in
paragraph (a) of this section are also
subject to the Billings/Laurel SO2 SIP, as
approved at 40 CFR 52.1370(c)(46) and
(52). In cases where the provisions of
this FIP address emissions activities
differently or establish a different
requirement than the provisions of the
approved SIP, the provisions of this FIP
take precedence.
(c) Definitions. For the purpose of this
section, we are defining certain words
or initials as described in this
paragraph. Terms not defined below
that are defined in the Clean Air Act or
regulations implementing the Clean Air
Act, shall have the meaning set forth in
the Clean Air Act or such regulations.
(1) Annual Emissions means the
amount of SO2 emitted in a calendar
year, expressed in pounds per year
rounded to the nearest pound.
Where:
Annual emissions = S Daily emissions
within the calendar year.
(2) Calendar Day means a 24-hour
period starting at 12:00 midnight and
ending at 12:00 midnight, 24 hours
later.
(3) Clock Hour means a twenty-fourth
(1/24) of a calendar day; specifically any
of the standard 60-minute periods in a
day that are identified and separated on
a clock by the whole numbers one
through twelve.
(4) Continuous Emission Monitoring
System or CEMS means all continuous
concentration and volumetric flow rate
monitors, associated data acquisition
equipment, and all other equipment
necessary to meet the requirements of
this section for continuous monitoring.
(5) Daily Emissions (i) means the
amount of SO2 emitted in a calendar
day, expressed in pounds per day
rounded to the nearest tenth of a pound.
Where:
Daily emissions = S Three hour
emissions within a calendar day.
(ii) Each calendar day is comprised of
eight non-overlapping three-hour
periods. The three hour emissions from
all the three-hour periods in a calendar
day shall be used to determine the day’s
emissions.
(6) Exhibit means for a given facility
named in 40 CFR 52.1392(a), exhibit A
to the stipulation of the Montana
Department of Environmental Quality
and that facility, adopted by the
Montana Board of Environmental
Review on either June 12, 1998 or
March 17, 2000.
(7) 1998 Exhibit means for a given
facility named in 40 CFR 52.1392(a), the
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exhibit adopted by the Montana Board
of Environmental Review on June 12,
1998.
(8) 2000 Exhibit means for a given
facility named in 40 CFR 52.1392(a), the
exhibit adopted by the Montana Board
of Environmental Review on March 17,
2000.
(9) Flare means a combustion device
that uses an open flame to burn
combustible gases with combustion air
provided by uncontrolled ambient air
around the flame. This term includes
both ground and elevated flares.
(10) The initials Hg mean mercury.
(11) Hourly means or refers to each
clock hour in a calendar day.
(12) Hourly Average means an
arithmetic average of all valid and
complete 15-minute data blocks in a
clock hour. Four (4) valid and complete
15-minute data blocks are required to
determine an hourly average for each
CEMS and source per clock hour.
Exclusive of the above definition, an
hourly average may be determined with
two valid and complete 15-minute data
blocks, for two of the 24 hours in any
calendar day.
A complete 15-minute data block for
each CEMS shall have a minimum of
one (1) data point value; however, each
CEMS shall be operated such that all
valid data points acquired in any 15minute block shall be used to determine
the 15-minute block’s reported
concentration and flow rate.
(13) Hourly Emissions means the
pounds per clock hour of SO2 emissions
from a source (flare, stack, fuel oil
system, sour water system, or fuel gas
system) determined using hourly
averages and rounded to the nearest
tenth of a pound.
(14) The initials H2S mean hydrogen
sulfide.
(15) The initials MBER mean the
Montana Board of Environmental
Review.
(16) The initials MDEQ mean the
Montana Department of Environmental
Quality.
(17) The initials mm mean
millimeters.
(18) The initials MSCC mean the
Montana Sulphur & Chemical Company.
(19) The initials ppm mean parts per
million.
(20) The initials SCFH mean standard
cubic feet per hour.
(21) The initials SCFM mean standard
cubic feet per minute.
(22) Standard Conditions means (a) 20
°C (293.2 °K, 527.7 °R, or 68.0 °F) and
1 atmosphere pressure (29.92 inches Hg
or 760 mm Hg) for stack and flare gas
emission calculations, and (b) 15.6 °C
(288.7 °K, 520.0 °R, or 60.3 °F) and 1
atmosphere pressure (29.92 inches Hg or
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760 mm Hg) for refinery fuel gas
emission calculations.
(23) The initials SO2 mean sulfur
dioxide.
(24) The initials SWS mean sour water
stripper.
(25) Three hour emissions means the
amount of SO2 emitted in each of the
eight non-overlapping three-hour
periods in a calendar day, expressed in
pounds and rounded to the nearest
tenth of a pound.
Where:
Three hour emissions = S Hourly
emissions within the three hour
period.
(26) Three hour period means any of
the eight non-overlapping three-hour
periods in a calendar day: midnight to
3 a.m., 3 a.m. to 6 a.m., 6 a.m. to 9 a.m.,
9 a.m. to noon, noon to 3 p.m., 3 p.m.
to 6 p.m., 6 p.m. to 9 p.m., 9 p.m. to
midnight.
(27) Turnaround means a planned
activity involving shutdown and startup
of one or several process units for the
purpose of performing periodic
maintenance, repair, replacement of
equipment or installation of new
equipment.
(28) Valid means data that is obtained
from a monitor or meter serving as a
component of a CEMS which meets the
applicable specifications, operating
requirements, and quality assurance and
control requirements of section 6 of
ConocoPhillips’, CHS Inc.’s,
ExxonMobil’s, and MSCC’s 1998
exhibits, respectively, and 40 CFR
52.1392.
(d) CHS Inc. emission limits and
compliance determining methods.
(1) Introduction: The provisions for
CHS Inc. cover the following units:
(i) The flare.
(ii) Combustion sources, which
consist of those sources identified in the
combustion sources emission limit in
section 3(A)(1)(d) of CHS Inc.’s 1998
exhibit.
(2) Flare requirements: (i) Emission
limit: The total emissions of SO2 from
the flare shall not exceed 150.0 pounds
per three hour period.
(ii) Compliance determining method:
Compliance with the emission limit in
40 CFR 52.1392(d)(2)(i) shall be
determined in accordance with 40 CFR
52.1392(h).
(3) Combustion sources: (i)
Restrictions: Sour water stripper
overheads (ammonia (NH3) and H2S
gases removed from the sour water in
the sour water stripper) shall not be
burned in the main crude heater. At all
times, CHS Inc. shall keep a chain and
lock on the valve that supplies sour
water stripper overheads from the old
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sour water stripper to the main crude
heater and shall keep such valve closed.
(ii) Compliance determining method:
CHS Inc. shall log and report any
noncompliance with the requirements
of 40 CFR 52.1392(d)(3)(i).
(4) Data reporting requirements: (i)
CHS Inc. shall submit quarterly reports
beginning with the first calendar quarter
following [DATE 30 DAYS AFTER
PUBLICATION OF THE FINAL RULE
IN THE Federal Register]. The quarterly
reports shall be submitted within 30
days of the end of each calendar quarter.
The quarterly reports shall be submitted
to the Air Program Contact at EPA’s
Montana Operations Office, Federal
Building, 10 West 15th Street, Suite
3200, Helena, MT 59626. The quarterly
report shall be certified for accuracy in
writing by a responsible CHS Inc.
official. The quarterly report format
shall consist of both a comprehensive
electronic-magnetic report and a written
hard copy data summary report.
(ii) The electronic report submitted to
the EPA shall be on magnetic or optical
media, and such submittal shall follow
the reporting format of electronic data
being submitted to the MDEQ. The EPA
may modify the reporting format
delineated in this section, and thereafter
CHS Inc. shall follow the revised format.
In addition to submitting the electronic
quarterly reports to the EPA, CHS Inc.
shall also record, organize and archive
for at least five years the same data, and
upon request by the EPA, CHS Inc. shall
provide the EPA with any data archived
in accordance with this provision. The
electronic report shall contain the
following:
(A) Hourly average total sulfur
concentrations in ppm in the gas stream
to the flare;
(B) Hourly average volumetric flow
rates in SCFH of the gas stream to the
flare;
(C) Hourly average temperature (in (F)
and pressure (in mm or inches of Hg) of
the gas stream to the flare;
(D) Hourly emissions from the flare in
pounds per clock hour; and
(E) Daily calibration data for flare
CEMS.
(iii) The quarterly written report
format submitted to the EPA shall
contain the following information:
(A) Three hour emissions in pounds
per three hour period from the flare;
(B) The results of the quarterly
Cylinder Gas Audits (CGA) or Relative
Accuracy Audits (RAA) required by 40
CFR part 60, Appendix F, and the
annual Relative Accuracy Test Audit
(RATA) for the total sulfur analyzer(s);
(C) For all periods of flare volumetric
flow rate monitoring system or total
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sulfur analyzer system downtime, the
written report shall identify:
(1) Dates and times of downtime;
(2) Reasons for downtime; and
(3) Corrective actions taken to
mitigate downtime;
(D) For each three hour period in
which the flare emission limit is
exceeded, the written report shall
identify:
(1) The date, start time, and end time
of the excess emissions;
(2) Total hours of operation with
excess emissions, the hourly emissions,
and the three hour emissions;
(3) All information regarding reasons
for operating with excess emissions; and
(4) Corrective actions taken to
mitigate excess emissions.
(E) For all periods that the range of
the volumetric flare flow rate monitor(s)
is (are) exceeded, the quarterly written
report shall identify:
(1) Date and time when the range of
the flare volumetric flow monitor(s) is
(are) exceeded and
(2) The reliable estimation parameters
used to determine flow in the gas stream
to the flare and how the estimation
parameters were derived.
(F) The date and time of any
noncompliance with the requirements
of 40 CFR 52.1392(d)(3)(i).
(G) When no excess emissions have
occurred or the continuous monitoring
system(s) have not been inoperative,
repaired, or adjusted, such information
shall be stated in the report.
(e) ConocoPhillips emission limits
and compliance determining methods.
(1) Introduction: The provisions for
ConocoPhillips cover the following
units:
(i) The main flare, which consists of
two flares—the north flare and the south
flare—that are operated on alternating
schedules. These flares are referred to
herein as the north main flare and south
main flare, or generically as the main
flare.
(ii) The Jupiter Sulfur SRU flare,
which is the flare at Jupiter Sulfur,
ConocoPhillips’ sulfur recovery unit.
(2) Flare requirements: (i) Emission
limits: (A) Emissions of SO2 from the
main flare (which can be emitted from
either the north or south main flare, but
not both at the same time) shall not
exceed 150.0 pounds three hour period.
(B) Emissions of SO2 from the Jupiter
Sulfur SRU flare and the Jupiter Sulfur
SRU/ATS stack (also referred to as the
Jupiter Sulfur SRU stack) shall not
exceed 75.0 pounds per three hour
period, 600.0 pounds per calendar day,
and 219,000 pounds per calendar year.
At any one time, ConocoPhillips may
only vent emissions from either the
Jupiter Sulfur SRU flare or the Jupiter
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Sulfur SRU/ATS stack, but not both
simultaneously.
(ii) Compliance determining method:
(A) Compliance with the emission limit
in 40 CFR 52.1392(e)(2)(i)(A) shall be
determined in accordance with 40 CFR
52.1392(h). In the event that a single
monitoring location cannot be used for
both the north and south main flare,
ConocoPhillips shall monitor the flow
and measure the total sulfur
concentration at more than one location
in order to determine compliance with
the main flare emission limit.
ConocoPhillips shall log and report any
instances when emissions are vented
from the north main flare and south
main flare simultaneously.
(B) Compliance with the emission
limits and requirements in 40 CFR
52.1392(e)(2)(i)(B) shall be determined
pursuant to ConocoPhillips’ 1998
exhibit (see section 4(A) of the exhibit)
for the Jupiter Sulfur SRU/ATS stack
and in accordance with 40 CFR
52.1392(h) for the Jupiter Sulfur SRU
flare. ConocoPhillips shall log and
report any instances when emissions are
vented from the Jupiter Sulfur SRU flare
and the Jupiter Sulfur SRU/ATS stack
simultaneously.
(3) Data reporting requirements: (i)
ConocoPhillips shall submit quarterly
reports on a calendar year basis,
beginning with the first calendar quarter
following [DATE 30 DAYS AFTER
PUBLICATION OF THE FINAL RULE
IN THE Federal Register]. The quarterly
reports shall be submitted within 30
days of the end of each calendar quarter.
The quarterly reports shall be submitted
to the Air Program Contact at EPA’s
Montana Operations Office, Federal
Building, 10 West 15th Street, Suite
3200, Helena, MT 59626. The quarterly
report shall be certified for accuracy in
writing by a responsible ConocoPhillips
official. The quarterly report format
shall consist of both a comprehensive
electronic-magnetic report and a written
hard copy data summary report.
(ii) The electronic report submitted to
the EPA shall be on magnetic or optical
media, and such submittal shall follow
the reporting format of electronic data
being submitted to the MDEQ. The EPA
may modify the reporting format
delineated in this section, and thereafter
ConocoPhillips shall follow the revised
format. In addition to submitting the
electronic quarterly reports to the EPA,
ConocoPhillips shall also record,
organize and archive for at least five
years the same data, and upon request
by the EPA, ConocoPhillips shall
provide the EPA with any data archived
in accordance with this provision. The
electronic report shall contain the
following:
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(A) Hourly average total sulfur
concentrations in ppm in the gas stream
to the ConocoPhillips main flare and
Jupiter Sulfur SRU flare;
(B) Hourly average volumetric flow
rates in SCFH of the gas streams to the
ConocoPhillips main flare and Jupiter
Sulfur SRU flare;
(C) Hourly average temperature (in °F)
and pressure (in mm or inches of Hg) of
the gas streams to the ConocoPhillips
main flare and Jupiter Sulfur SRU flare;
(D) Hourly emissions in pounds per
clock hour from the ConocoPhillips
main flare and Jupiter Sulfur SRU flare;
and
(E) Daily calibration data for the flare
CEMS.
(iii) The quarterly written report
submitted to the EPA shall contain the
following information:
(A) Three hour emissions in pounds
per three hour period from the
ConocoPhillips main flare and Jupiter
Sulfur SRU flare;
(B) The results of the quarterly
Cylinder Gas Audits (CGA) or Relative
Accuracy Audits (RAA) required by 40
CFR part 60, Appendix F, and the
annual Relative Accuracy Test Audit
(RATA) for total sulfur analyzer(s);
(C) For all periods of flare volumetric
flow rate monitoring system or total
sulfur analyzer system downtime, the
written report shall identify:
(1) Dates and times of downtime;
(2) Reasons for downtime; and
(3) Corrective actions taken to
mitigate downtime;
(D) For each three hour period in
which a flare emission limit is
exceeded, the written report shall
identify:
(1) The date, start time, and end time
of the excess emissions;
(2) Total hours of operation with
excess emissions, the hourly emissions,
and the three hour emissions;
(3) All information regarding reasons
for operating with excess emissions; and
(4) Corrective actions taken to
mitigate excess emissions.
(E) For all periods that the range of
the volumetric flare flow rate monitor(s)
is (are) exceeded, the quarterly written
report shall identify:
(1) Date and time when the range of
the flare volumetric flow monitor(s) is
(are) exceeded and
(2) The reliable estimation parameters
used to determine flow in the gas
stream(s) to the flare and how the
estimation parameters were derived.
(F) Identification of dates, times, and
duration of any instances when
emissions are vented from the north and
south main flares simultaneously or
from the Jupiter Sulfur SRU flare and
the Jupiter Sulfur SRU/ATS stack
simultaneously.
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(G) When no excess emissions have
occurred or the continuous monitoring
system(s) have not been inoperative,
repaired, or adjusted, such information
shall be stated in the report.
(f) ExxonMobil emission limits and
compliance determining methods:
(1) Introduction: The provisions for
ExxonMobil cover the following units:
(i) The Primary process flare and the
Turnaround flare. The Primary process
flare is the flare normally used by
ExxonMobil. The Turnaround flare is
the flare ExxonMobil uses for about 30–
40 days every five to six years when the
facility’s major SO2 source, the fluid
catalytic cracking unit, is not normally
operating.
(ii) The following refinery fuel gas
combustion units: the FCC CO boiler, F–
2 crude/vacuum heater, F–3 unit, F–3X
unit, F–5 unit, F–700 unit, F–201 unit,
F–202 unit, F–402 unit, F–551 unit, F–
651 unit, standby boiler house (B–8
boiler), and coker CO-boiler (only when
the Yellowstone Energy Limited
Partnership (YELP) facility is receiving
ExxonMobil coker unit flue gas or
whenever the ExxonMobil coker is not
operating).
(iii) Coker CO-boiler stack.
(2) Flare requirements: (i) Emission
limit: The total combined emissions of
SO2 from the Primary process and
Turnaround refinery flares shall not
exceed 150.0 pounds per three hour
period.
(ii) Compliance determining method:
Compliance with the emission limit in
40 CFR 52.1392(f)(2)(i) shall be
determined in accordance with 40 CFR
52.1392(h). If volumetric flow
monitoring device(s) installed and
concentration monitoring methods used
to measure the gas stream to the Primary
Process flare cannot measure the gas
stream to the Turnaround flare,
ExxonMobil may apply to EPA for
alternative measures to determine the
volumetric flow rate and total sulfur
concentration of the gas stream to the
Turnaround flare. Before EPA will
approve such alternative measures,
ExxonMobil must agree that the
Turnaround flare will be used only
during refinery turnarounds of limited
duration and frequency—no more than
60 days once every five years—which
restriction shall be considered an
enforceable part of this FIP. Such
alternative measures may consist of
reliable flow estimation parameters to
estimate volumetric flow rate and
manual sampling of the gas stream to
the flare to determine total sulfur
concentrations, or such other measures
that EPA finds will provide accurate
estimations of SO2 emissions from the
Turnaround flare.
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(3) Refinery fuel gas combustion
requirements: (i) Emission limits: The
applicable emission limits are contained
in section 3(A)(1) of ExxonMobil’s 2000
exhibit and section 3(B)(2) of
ExxonMobil’s 1998 exhibit.
(ii) Compliance determining method:
For the limits referenced in 40 CFR
52.1392(f)(3)(i), the compliance
determining methods specified in
section 4(B) of ExxonMobil’s 1998
exhibit shall be followed except when
the H2S concentration in the refinery
fuel gas stream exceeds 1200 ppmv as
measured by the H2S CEMS required by
section 6(B)(3) of ExxonMobil’s 1998
exhibit (the H2S CEMS.) When such
value is exceeded, the following
compliance monitoring method shall be
employed:
(A) ExxonMobil shall measure the
H2S concentration in the refinery fuel
gas according to the procedures in 40
CFR 52.1392(f)(3)(ii)(B) and calculate
the emissions according to the equations
in 40 CFR 52.1392(f)(3)(ii)(C).
(B) Within 4 hours after the H2S
CEMS measures an H2S concentration in
the fuel gas stream greater than 1200
ppmv, ExxonMobil shall initiate
sampling of the fuel gas stream at the
fuel header on a once-per-three-hourperiod frequency using the Tutwiler
method contained in 40 CFR 60.648.
ExxonMobil shall continue to use the
Tutwiler method at this frequency until
the H2S CEMS measures an H2S
concentration in the fuel gas stream
equal to or less than 1200 ppmv
continuously over a three-hour period.
(C) When the Tutwiler method is
required, SO2 emissions from refinery
fuel gas combustion shall be calculated
as follows: the Hourly emissions shall
be calculated using equation 1, Three
hour emissions shall be calculated using
equation 2, and the Daily emissions
shall be calculated using equation 3.
Equation 1: EH = K* CH*QH
Where:
EH = Refinery fuel gas combustion hourly
emissions in pounds per hour, rounded
to the nearest tenth of a pound;
K = 1.688 × 10¥7 in (pounds/standard cubic
feet (SCF))/parts per million (ppm);
CH = Fuel gas H2S concentration in ppm
determined by the Tutwiler method as
required by 40 CFR 52.1392(f)(3)(ii)(B)
(since only one sample is taken every
three (3) hours, the value for such
sample shall be substituted for each hour
of the 3-hour period during which the
sample is taken); and
QH = actual fuel gas firing rate in standard
cubic feet per hour (SCFH), as measured
by the monitor required by section
6(B)(8) of ExxonMobil’s 1998 exhibit.
Equation 2: (Refinery fuel gas combustion
three hour emissions) = S (Hourly
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emissions within the three-hour period
as determined by equation 1).
Equation 3: (Refinery fuel gas combustion
daily emissions) = S (Three hour
emissions within the day as determined
by equation 2).
(4) Coker CO-boiler stack
requirements.
(i) Emission limits: When
ExxonMobil’s coker unit is operating
and coker unit flue gases are burned in
the coker CO-boiler, the applicable
emission limits are contained in section
3(B)(1) of ExxonMobil’s 2000 exhibit.
(ii) Compliance determining method:
(A) Compliance with the emission limits
referenced in 40 CFR 52.1392(f)(4)(i)
shall be determined by measuring the
SO2 concentration and flow rate in the
coker CO-boiler stack according to the
procedures in 40 CFR
52.1392(f)(4)(ii)(B) and (C) and
calculating emissions according to the
equations in 40 CFR 52.1392(f)(4)(ii)(D).
(B) Beginning on [DATE 30 DAYS
AFTER PUBLICATION OF THE FINAL
RULE IN THE Federal Register],
ExxonMobil shall at all times operate
and maintain a CEMS to measure sulfur
dioxide concentrations in the coker COboiler stack. This CEMS shall achieve a
temporal sampling resolution of at least
one concentration measurement per
minute, meet the requirements
expressed in the definition of ‘‘hourly
average’’ in 40 CFR 52.1392(c)(12), and
meet the CEMS Performance
Specifications contained in section 6(C)
of ExxonMobil’s 1998 exhibit, except
that ExxonMobil shall also notify EPA
in writing of each annual Relative
Accuracy Test Audit a minimum of
twenty-five (25) working days prior to
actual testing.
(C) Beginning on [DATE 30 DAYS
AFTER PUBLICATION OF THE FINAL
RULE IN THE Federal Register],
ExxonMobil shall at all times operate
and maintain a continuous stack flow
rate monitor to measure the stack gas
flow rates in the coker CO-boiler stack.
This CEMS shall achieve a temporal
sampling resolution of at least one flow
rate measurement per minute, meet the
requirements expressed in the definition
of ‘‘hourly average’’ in 40 CFR
52.1392(c)(12), and meet the Stack Gas
Flow Rate Monitor Performance
Specifications of section 6(D) of
ExxonMobil’s 1998 exhibit, except that
ExxonMobil shall also notify EPA in
writing of each annual Relative
Accuracy Test Audit a minimum of
twenty-five (25) working days prior to
actual testing.
(D) SO2 emissions from the coker COboiler stack shall be determined in
accordance with the equations in
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sections 2(A)(1), (8), (11)(a) and (16) of
ExxonMobil’s 1998 exhibit.
(5) Data reporting requirements: (i)
ExxonMobil shall submit quarterly
reports beginning with the first calendar
quarter following [DATE 30 DAYS
AFTER PUBLICATION OF THE FINAL
RULE IN THE Federal Register]. The
quarterly reports shall be submitted
within 30 days of the end of each
calendar quarter. The quarterly reports
shall be submitted to the Air Program
Contact at EPA’s Montana Operations
Office, Federal Building, 10 West 15th
Street, Suite 3200, Helena, MT 59626.
The quarterly report shall be certified
for accuracy in writing by a responsible
ExxonMobil official. The quarterly
report format shall consist of both a
comprehensive electronic-magnetic
report and a written hard copy data
summary report.
(ii) The electronic report submitted to
the EPA shall be on magnetic or optical
media, and such submittal shall follow
the reporting format of electronic data
being submitted to the MDEQ. The EPA
may modify the reporting format
delineated in this section, and thereafter
ExxonMobil shall follow the revised
format. In addition to submitting the
electronic quarterly reports to the EPA,
ExxonMobil shall also record, organize
and archive for at least five years the
same data, and upon request by the
EPA, ExxonMobil shall provide the EPA
with any data archived in accordance
with this provision. The electronic
report shall contain the following:
(A) Hourly average total sulfur
concentrations in ppm in the gas stream
to the flare(s);
(B) Hourly average SO2 concentrations
in ppm from the coker CO-boiler stack;
(C) Hourly average volumetric flow
rates in SCFH in the gas stream to the
flare(s) and in the coker CO-boiler stack;
(D) Hourly average H2S
concentrations in ppm from the refinery
fuel gas system;
(E) Hourly average refinery fuel gas
combustion units’ actual fuel firing rate
in SCFH;
(F) Hourly average temperature (in °F)
and pressure (in mm or inches of Hg) of
the gas stream to the flare(s);
(G) Hourly emissions in pounds per
clock hour from the flare(s), coker COboiler stack, and refinery fuel gas
combustion system;
(H) Daily calibration data for the
CEMS required by 40 CFR
52.1392(f)(2)(ii), (f)(3)(ii) and (f)(4)(ii).
(iii) The quarterly written report
submitted to the EPA shall contain the
following information:
(A) Three hour emissions in pounds
per three hour period from the flares,
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coker CO-boiler stack, and refinery fuel
gas combustion system;
(B) Daily emissions in pounds per
calendar day from the coker CO-boiler
stack and refinery fuel gas combustion
system;
(C) The results of the quarterly
Cylinder Gas Audits (CGA) or Relative
Accuracy Audits (RAA) required by 40
CFR part 60, Appendix F, and the
annual Relative Accuracy Test Audit
(RATA) for the CEMS required by 40
CFR 52.1392(f)(2)(ii) (total sulfur
analyzer(s) only), (f)(3)(ii) and (f)(4)(ii);
(D) For all periods of flare volumetric
flow rate monitoring system or
concentration analyzer system
downtime, coker CO-boiler stack CEMS
downtime, or refinery fuel gas
combustion system CEMS downtime,
the written report shall identify:
(1) Dates and times of downtime;
(2) Reasons for downtime; and
(3) Corrective actions taken to
mitigate downtime;
(E) For each three hour period and
calendar day in which the flare
emission limits, the coker CO-boiler
stack emission limits, or the fuel gas
combustion system emission limits are
exceeded, the written report shall
identify:
(1) The date, start time, and end time
of the excess emissions;
(2) Total hours of operation with
excess emissions, the hourly emissions,
the three hour emissions, and the daily
emissions;
(3) All information regarding reasons
for operating with excess emissions; and
(4) Corrective actions taken to
mitigate excess emissions.
(F) For all periods that the range of
the volumetric flare flow rate monitor(s)
is (are) exceeded, the quarterly written
report shall identify:
(1) Date and time when the range of
the flare volumetric flow monitor(s) is
(are) exceeded and
(2) The reliable estimation parameters
used to determine flow in the gas stream
to the flare and how the estimation
parameters were derived.
(G) When no excess emissions have
occurred or the continuous monitoring
system(s) have not been inoperative,
repaired, or adjusted, such information
shall be stated in the report.
(g) Montana Sulphur & Chemical
Company (MSCC) emission limits and
compliance determining methods: (1)
Introduction: The provisions for MSCC
cover the following units:
(i) The flares, which consist of the 80
foot west flare, 125 foot east flare, and
100-meter flare.
(ii) The SRU 100-meter stack.
(iii) The auxiliary vent stacks which
consist of the vent stacks associated
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with the Railroad Boiler, the H–1 Unit,
the H1-A unit, the H1–1 unit and the
H1–2 unit.
(iv) The SRU 30-meter stack. The
units that can exhaust through the SRU
30-meter stack are identified in section
3(A)(2)(d) and (e) of MSCC’s 1998
exhibit.
(2) Flare requirements: (i) Emission
limit: Total combined emissions of SO2
from the 80 foot west flare, 125 foot east
flare and 100-meter flare shall not
exceed 150.0 pounds per three hour
period.
(ii) Compliance determining method:
Compliance with the emission limit in
40 CFR 52.1392(g)(2)(i) shall be
determined in accordance with 40 CFR
52.1392(h). In the event MSCC cannot
monitor all three flares from a single
location, MSCC shall establish multiple
monitoring locations.
(3) SRU 100-meter stack
requirements: (i) Emission limits:
Emissions of SO2 from the SRU 100meter stack shall not exceed:
(A) 3,003.1 pounds per three hour
period,
(B) 24,025.0 pounds per calendar day,
and
(C) 9,088,000 pounds per calendar
year.
(ii) Compliance determining method.
(A) Compliance with the emission limits
contained in 40 CFR 52.1392(g)(3)(i)
shall be determined by the CEMS and
emission testing methods required by
sections 6(B)(1) and (2) and section 5,
respectively, of MSCC’s 1998 exhibit.
(B) MSCC shall notify EPA in writing
of each annual source test a minimum
of 25 working days prior to actual
testing.
(C) The CEMS referenced in 40 CFR
52.1392(g)(3)(ii)(A) shall achieve a
temporal sampling resolution of at least
one concentration and flow rate
measurement per minute, meet the
requirements expressed in the definition
of ‘‘hourly average’’ in 40 CFR
52.1392(c)(12), and meet the CEM
Performance Specifications in sections
6(C) and (D) of MSCC’s 1998 exhibit,
except that MSCC shall also notify EPA
in writing of each annual Relative
Accuracy Test Audit at least twenty five
(25) working days prior to actual testing.
(4) Auxiliary vent stacks: (i) Emission
limits: (A) Total combined emissions of
SO2 from the auxiliary vent stacks shall
not exceed 12.0 pounds per three hour
period,
(B) Total combined emissions of SO2
from the auxiliary vent stacks shall not
exceed 96.0 pounds per calendar day,
(C) Total combined emissions of SO2
from the auxiliary vent stacks shall not
exceed 35,040 pounds per calendar
year, and
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(D) The H2S concentration in the fuel
gas burned in the Railroad Boiler, the
H–1 Unit, the H1–A unit, the H1–1 unit,
and the H1–2 unit while any of these
units is exhausting to the auxiliary vent
stacks shall not exceed 100 ppm per
three hour period.
(ii) Compliance determining method:
(A) Compliance with the emission limits
in 40 CFR 52.1392(g)(4)(i) shall be
determined by measuring the H2S
concentration of the fuel burned in the
Railroad Boiler, the H–1 Unit, the H1–
A unit, the H1–1 unit, and the H1–2
unit (when fuel other than natural gas
is burned in one or more of these units)
according to the procedures in 40 CFR
52.1392(g)(4)(ii)(C).
(B) Beginning [DATE 60 DAYS
AFTER PUBLICATION OF THE FINAL
RULE IN THE Federal Register], MSCC
shall maintain logs of
(1) The dates and time periods that
emissions are exhausted through the
auxiliary vent stacks;
(2) The heaters and boilers that are
exhausting to the auxiliary vent stacks
during such time periods; and
(3) The type of fuel burned in the
heaters and boilers during such time
periods.
(C) Beginning [DATE 60 DAYS
AFTER PUBLICATION OF THE FINAL
RULE IN THE Federal Register], MSCC
shall measure the H2S content of the
fuel burned when fuel other than
natural gas is burned in a heater or
boiler that is exhausting to an auxiliary
vent stack. MSCC shall begin measuring
the H2S content of the fuel at the fuel
header within one hour from when a
heater or boiler begins exhausting to an
auxiliary vent stack and on a once-perthree-hour period frequency until no
heater or boiler is exhausting to an
auxiliary vent stack. To determine the
H2S content of the fuel burned, MSCC
shall use a portable H2S monitor with a
range of 0—500 ppm of H2S and an
accuracy of ( 2% of 500 ppm. H2S
concentrations shall be measured on an
actual wet basis in ppm.
(5) SRU 30-meter stack: (i) Emission
limits: (A) Emissions of SO2 from the
SRU 30-meter stack shall not exceed
12.0 pounds per three hour period,
(B) Emissions of SO2 from the SRU
30-meter stack shall not exceed 96.0
pounds per calendar day,
(C) Emissions of SO2 from the SRU
30-meter stack shall not exceed 35,040
pounds per calendar year, and
(D) The H2S concentration in the fuel
gas burned in the heaters and boilers
identified in 40 CFR 52.1392(g)(1)(iv)
while any of these units is exhausting to
the SRU 30-meter stack shall not exceed
100 ppm per three hour period.
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(ii) Compliance determining method:
(A) Compliance with the emission limits
in 40 CFR 52.1392(g)(5)(i) shall be
determined by measuring the H2S
concentration of the fuel burned in the
heaters and boilers identified in 40 CFR
52.1392(g)(1)(iv) (when fuel other than
natural gas is burned in one or more of
these heaters or boilers) according to the
procedures in 40 CFR
52.1392(g)(5)(ii)(C).
(B) Beginning [DATE 60 DAYS
AFTER PUBLICATION OF THE FINAL
RULE IN THE Federal Register], MSCC
shall maintain logs of
(1) The dates and time periods that
emissions are exhausted through the
SRU 30-meter stack;
(2) The heaters and boilers that are
exhausting to the SRU 30-meter stack
during such time periods; and
(3) The type of fuel burned in the
heaters and boilers during such time
periods.
(C) Beginning [DATE 60 DAYS
AFTER PUBLICATION OF THE FINAL
RULE IN THE Federal Register], MSCC
shall measure the H2S content of the
fuel burned when fuel other than
natural gas is burned in a heater or
boiler that is exhausting to the SRU 30meter stack. MSCC shall begin
measuring the H2S content of the fuel at
the fuel header within one hour from
when any heater or boiler begins
exhausting to the SRU 30-meter stack
and on a once-per-three-hour period
frequency until no heater or boiler is
exhausting to the SRU 30-meter stack.
To determine the H2S content of the fuel
burned, MSCC shall use a portable H2S
monitor with a range of 0—500 ppm of
H2S and an accuracy of +/-2% of 500
ppm. H2S concentrations shall be
measured on an actual wet basis in
ppm.
(6) Data reporting requirements: (i)
MSCC shall submit quarterly reports
beginning with the first calendar quarter
following [DATE 30 DAYS AFTER
PUBLICATION OF THE FINAL RULE
IN THE Federal Register]. The quarterly
reports shall be submitted within 30
days of the end of each calendar quarter.
The quarterly reports shall be submitted
to Air Program Contact at EPA’s
Montana Operations Office, Federal
Building, 10 West 15th Street, Suite
3200, Helena, MT 59626. The quarterly
report shall be certified for accuracy in
writing by a responsible MSCC official.
The quarterly report format shall consist
of both a comprehensive electronicmagnetic report and a written hard copy
data summary report.
(ii) The electronic report submitted to
the EPA shall be on magnetic or optical
media, and such submittal shall follow
the reporting format of electronic data
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being submitted to the MDEQ. The EPA
may modify the reporting format
delineated in this section, and
thereafter, MSCC shall follow the
revised format. In addition to submitting
the electronic quarterly reports to the
EPA, MSCC shall also record, organize
and archive for at least five years the
same data, and upon request by the
EPA, MSCC shall provide the EPA with
any data archived in accordance with
this provision. The electronic report
shall contain the following:
(A) Hourly average total sulfur
concentrations in ppm, in the gas stream
to the flare(s);
(B) Hourly average SO2 concentrations
in ppm from the SRU 100-meter stack.
(C) Hourly average volumetric flow
rates in SCFH in the gas stream to the
flare(s) and in the SRU 100-meter stack;
(D) Hourly average temperature (in °F)
and pressure (in mm or inches of Hg) in
the gas stream to the flare(s);
(E) Hourly emissions in pounds per
clock hour from the flare(s) and SRU
100-meter stack;
(F) Daily calibration data for flare
CEMS, and the SRU 100-meter stack
CEMS;
(iii) The quarterly written report
submitted to the EPA shall contain the
following information:
(A) Three hour emissions in pounds
per three hour period from the flares
and SRU 100-meter stack, and three
hour H2S concentrations in the fuel gas
burned in the heaters and boilers
identified in 40 CFR 52.1392(g)(1)(iii)
and (iv) while any of these units is
exhausting to the SRU 30-meter stack or
auxiliary vent stacks and burning fuel
other than natural gas;
(B) Daily emissions in pounds per
calendar day from the SRU 100-meter
stack;
(C) Annual emissions of SO2 in
pounds per calendar year from the SRU
100-meter stack;
(D) The results of the quarterly
Cylinder Gas Audits (CGA) or Relative
Accuracy Audits (RAA) required by 40
CFR part 60, Appendix F, the annual
Relative Accuracy Test Audit (RATA)
for total sulfur analyzer(s) and for the
SRU 100-meter stack CEMS;
(E) For all periods of flare volumetric
flow rate monitoring system or
concentration analyzer system
downtime, SRU 100-meter CEMS
downtime, or failure to obtain an H2S
concentration sample as required by 40
CFR 52.1392(g)(4)(ii)(C) and (g)(5)(ii)(C),
the written report shall identify:
(1) Dates and times of downtime or
failure;
(2) Reasons for downtime or failure;
and
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18:09 Jul 11, 2006
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(3) Corrective actions taken to
mitigate downtime or failure;
(F) For each three hour period and
calendar day in which the flare
emission limit, the SRU 100-meter stack
emission limits, the SRU 30-meter stack
emission limits, or auxiliary vent stack
emission limits are exceeded, the
written report shall identify:
(1) The date, start time, and end time
of the excess emissions;
(2) Total hours of operation with
excess emissions, the hourly emissions,
the three hour emissions, and the daily
emissions;
(3) All information regarding reasons
for operating with excess emissions; and
(4) Corrective actions taken to
mitigate excess emissions.
(G) For all periods that the range of
the volumetric flare flow rate monitor(s)
is (are) exceeded, the quarterly written
report shall identify:
(1) Date and time when the range of
the flare volumetric flow monitor(s) is
(are) exceeded and
(2) The reliable estimation parameters
used to determine flow in the gas stream
to the flare and how the estimation
parameters were derived.
(H) Identification of dates:
(1) The dates and time periods that
emissions are exhausted through the
auxiliary vent stacks or the 30-meter
stack;
(2) The heaters and boilers that are
exhausting to the auxiliary vent stacks
or 30-meter stack during such time
periods; and
(3) The type of fuel burned in the
heaters and boilers during such time
periods.
(I) When no excess emissions have
occurred, the continuous monitoring
system(s) have not been inoperative,
repaired, or adjusted, or all H2S
concentration samples for the heaters
and boilers have been taken as required,
such information shall be stated in the
report.
(h) Flare compliance determining
method:
(1) Compliance with the emission
limits in 40 CFR 52.1392(d)(2)(i),
(e)(2)(i), (f)(2)(i) and (g)(2)(i) shall be
determined by measuring the total
sulfur concentration and volumetric
flow rate of the gas stream to the flare(s)
(corrected to 1 atmosphere pressure and
68 °F) and using the methods contained
in the flare monitoring plan required by
40 CFR 52.1392(h)(5). Volumetric gas
stream flow rate to the flare(s) shall be
determined in accordance with the
requirements in 40 CFR 52.1392(h)(2)
and the total sulfur concentration of the
gas stream to the flare(s) shall be
determined in accordance with 40 CFR
52.1392(h)(3).
PO 00000
Frm 00043
Fmt 4702
Sfmt 4702
39277
(2) Flare flow monitoring: (i) Within
180 days after receiving EPA approval of
the flare monitoring plan required by 40
CFR 52.1392(h)(5), each facility named
in 40 CFR 52.1392(a) shall install and
calibrate, and thereafter calibrate,
maintain and operate, a continuous flow
monitoring system capable of measuring
the total volumetric flow of the gas
stream to the flare(s) over the full range
of operation. The flow monitoring
system may require one or more flow
monitoring devices or flow
measurements at one or more locations
if one monitor cannot measure the total
volumetric flow to each flare.
(ii) Volumetric flow monitors meeting
the proposed volumetric flow
monitoring specifications below should
be able to measure the majority of
volumetric flow in the gas streams to the
flare. However, in rare events (e.g., such
as upset conditions) it is possible for the
flow to the flare to exceed the range of
the monitor. In such cases, reliable flow
estimation parameters may be used to
determine the volumetric flow rate to
the flare, which shall then be used to
calculate SO2 emissions. In quarterly
reports, sources shall indicate when
reliable estimation parameters are used
and how such parameters were derived.
(iii) The flare gas stream volumetric
flow rate shall be measured on an actual
wet basis in SCFH. The minimum
detectable velocity of the flow
monitoring device(s) shall be 0.1 feet
per second (fps). The flow monitoring
device(s) shall continuously measure
the range of flow rates corresponding to
velocities from 0.5 to 275 fps and have
a manufacturer’s specified accuracy of
±5% over the range of 1 to 275 fps. The
volumetric flow monitor(s) shall feature
automated daily calibrations at low and
high ranges. The volumetric flow
monitors shall be calibrated annually
according to manufacturer’s
specifications.
(iv) For correcting flow rate to
standard conditions (defined as 68 °F
and 760 mm, or 29.92 inches, of Hg)),
temperature and pressure shall be
monitored continuously. The
temperature and pressure shall be
monitored in the same location as the
flow monitoring device(s) and shall be
calibrated to meet accuracy
specifications as follows: temperature
shall be calibrated annually to within
±2.0% at absolute temperature and the
pressure monitor shall be calibrated
annually to within ±5.0 mmHg.
(v) The flow monitoring device(s)
shall be initially calibrated, prior to
installation, to demonstrate accuracy to
within 5.0% at flow rates equivalent to
30%, 60% and 90% of monitor full
scale.
E:\FR\FM\12JYP1.SGM
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wwhite on PROD1PC61 with PROPOSALS
39278
Federal Register / Vol. 71, No. 133 / Wednesday, July 12, 2006 / Proposed Rules
(vi) Each flow monitoring device shall
achieve a temporal sampling resolution
of at least one flow rate measurement
per minute, meet the requirements
expressed in the definition of hourly
average in 40 CFR 52.1392(c)(12), and
be installed in a manner and at a
location that will allow for accurate
measurements of the total volume of the
gas stream going to each flare.
(3) Flare concentration monitoring:
(i) Within 180 days after receiving
EPA approval of the flare monitoring
plan required by 40 CFR 52.1392(h)(5),
each facility named in 40 CFR
52.1392(a) shall install and calibrate,
and thereafter calibrate, maintain and
operate, a continuous total sulfur
concentration monitoring system
capable of measuring the total sulfur
concentration of the gas stream to each
flare. Continuous monitoring shall occur
at a location(s) that is (are)
representative of the gas combusted in
the flare and be capable of measuring
the expected range of total sulfur in the
gas stream to the flare. The
concentration monitoring system may
require one or more concentration
monitoring devices or concentration
measurements at one or more locations
if one monitor cannot measure the total
sulfur concentration to each flare.
(ii) The total sulfur analyzer(s) shall
achieve a temporal sampling resolution
of at least one concentration
measurement per fifteen minutes, meet
the requirements expressed in the
definition of ‘‘hourly average’’ in 40
CFR 52.1392(c)(12), be installed,
certified (on a concentration basis), and
operated in accordance with 40 CFR
part 60, Appendix B, Performance
Specification 5, and be subject to and
meet the quality assurance and quality
control requirements (on a
concentration basis) of 40 CFR part 60,
Appendix F.
(iii) Each affected facility named in 40
CFR 52.1392(a) shall notify the Air
Program Contact at EPA’s Montana
Operations Office, Federal Building, 10
West 15th Street, Suite 3200, Helena,
MT 59626, in writing of each Relative
Accuracy Test Audit a minimum of
twenty-five (25) working days prior to
the actual testing.
(4) Calculation of SO2 emissions from
flares. Methods for calculating hourly
and three hour SO2 emissions from
flares shall be submitted with the flare
monitoring plan discussed in 40 CFR
52.1392(h)(5).
(5) By [DATE 180 DAYS AFTER
PUBLICATION OF THE FINAL RULE
IN THE Federal Register], each facility
named in 40 CFR 52.1392(a) shall
submit a flare monitoring plan. Each
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18:09 Jul 11, 2006
Jkt 208001
flare monitoring plan shall include, at a
minimum, the following:
(i) A facility plot plan showing the
location of each flare in relation to the
general plant layout;
(ii) Information regarding pilot and
purge gas for each flare; what is used for
pilot and purge gas and how the
concentration and volumetric flow rate
monitors are analyzing the pilot and
purge gases.
(iii) Drawing(s) with dimensions,
preferably to scale, and an as built
process flow diagram of the flare(s)
identifying major components, such as
flare header, flare stack, flare tip(s) or
burner(s), purge gas system, pilot gas
system, ignition system, assist system,
water seal, knockout drum and
molecular seal.
(iv) A representative flow diagram
showing the interconnections of the
flare system(s) with vapor recovery
system(s), process units and other
equipment as applicable.
(v) A complete description of the
assist system process control, flame
detection system and pilot ignition
system.
(vi) A complete description of the gas
flaring process for an integrated gas
flaring system that describes the method
of operation of the flares.
(vii) A complete description of the
vapor recovery system(s) which have
interconnection to a flare, such as
compressor description(s), design
capacities of each compressor and the
vapor recovery system, and the method
currently used to determine and record
the amount of vapors recovered.
(viii) Drawing(s) with dimensions,
preferably to scale, showing the
following information for proposed flare
gas stream monitoring system:
(A) Sampling locations; and
(B) Flow monitoring device and total
sulfur analyzer locations and the
methods used to determine the
locations.
(ix) A detailed description of
manufacturer’s specifications, including
but not limited to, make, model, type,
range, precision, accuracy, calibration,
maintenance, a quality assurance
procedure and any other relevant
specifications and information
referenced in 40 CFR 52.1392(h)(2) and
(3) for all existing and proposed flow
monitoring devices and total sulfur
analyzers.
(x) A complete description of the
proposed data recording, collection and
management and any other relevant
specifications and information
referenced in 40 CFR 52.1392(h)(2) and
(3) for each flare monitoring system.
(xi) A complete description of the
proposed method to determine, monitor
PO 00000
Frm 00044
Fmt 4702
Sfmt 4702
and record total volume and total sulfur
concentration of gases combusted in the
flare.
(xii) A complete description of the
method and equations used to calculate
the amount of total sulfur, including all
conversion factors. The total sulfur
concentrations will be used in the
methods referenced in 40 CFR
52.1392(h)(4) to determine compliance
with the three-hour emission limit.
(xiii) A schedule for the installation
and operation of each flare monitoring
system consistent with the deadline in
40 CFR 52.1392(h)(2).
(xiv) A complete description of the
methods to be used to estimate flare
emissions when either the flow
monitoring device or total sulfur
analyzer are not working or the
operating range of the monitor or
analyzer is exceeded.
(xv) A complete description of the
methods to be used for calculating, and
hourly and three-hour SO2 emission
from flares.
(6) Thirty days prior to installing the
continuous monitors required by 40
CFR 52.1392(h)(2) and (3), each facility
named in 40 CFR 52.1392(a) shall
submit for EPA review a quality
assurance/quality control (QA/QC) plan
for each monitor being installed.
[FR Doc. 06–6096 Filed 7–11–06; 8:45 am]
BILLING CODE 6560–50–P
FEDERAL COMMUNICATIONS
COMMISSION
47 CFR Part 73
[DA 06–1308; MB Docket No. 04–318; RM–
11040]
Radio Broadcasting Services; Culebra
and Vieques, Puerto Rico
Federal Communications
Commission.
ACTION: Proposed rule; denial.
AGENCY:
SUMMARY: We deny the petition for rule
making filed by Western New Life, Inc.,
proposing the substitution of Channel
291A for Channel 254A at Culebra,
Puerto Rico. To accommodate the
substitution, Petitioner also proposed
the deletion of vacant Channel 291B at
Vieques, Puerto Rico. We find that
neither the deletion of Channel 291B,
nor the alternative downgrade and
substitution of Channel 254A for
Channel 291B at Vieques, is in the
public interest. Specifically, expressions
of interest have been filed to retain the
Vieques vacant channel as a Class B
allotment.
E:\FR\FM\12JYP1.SGM
12JYP1
Agencies
[Federal Register Volume 71, Number 133 (Wednesday, July 12, 2006)]
[Proposed Rules]
[Pages 39259-39278]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: 06-6096]
-----------------------------------------------------------------------
ENVIRONMENTAL PROTECTION AGENCY
[EPA-R08-OAR-2006-0098; FRL-8191-7]
40 CFR Part 52
RIN 2008-AA00
Federal Implementation Plan for the Billings/Laurel, Montana,
Sulfur Dioxide Area
AGENCY: Environmental Protection Agency (EPA).
ACTION: Proposed rule.
-----------------------------------------------------------------------
SUMMARY: The Environmental Protection Agency (EPA) proposes to
promulgate a Federal Implementation Plan (FIP) containing emission
limits and compliance determining methods for several sources located
in Billings and Laurel, Montana. EPA is proposing a FIP because of our
previous partial and limited disapprovals of the Billings/Laurel Sulfur
Dioxide (SO2) SIP. The intended effect of this action is to
assure attainment of the SO2 national ambient air quality
standard (NAAQS) in the Billings/Laurel, Montana area. EPA is taking
this action under sections 110 and 307 of the Clean Air Act (Act).
DATES: Comments: Comments on the proposal must be received on or before
September 11, 2006.
Public Hearing: If requested by July 26, 2006, EPA will hold a
public hearing on August 10, 2006. If a public hearing is requested,
EPA will hold the public hearing at the following time and location: 9
a.m. to 2 p.m. at the Lewis and Clark Room, MSU--Billings, 1500
University Drive, Billings, Montana. The purpose of such a hearing
would be for EPA to receive comments and ask clarifying questions. The
hearing would not be an opportunity for questioning of EPA officials or
employees. Call the individual listed in the FOR FURTHER INFORMATION
CONTACT if you would like to request a hearing, schedule time to speak
at the hearing, or confirm whether a hearing will occur. If a hearing
is held, speakers will be limited to 10 minutes. It would be helpful,
but it is not required, if speakers bring a written copy of their
comments to leave with us.
ADDRESSES: Submit your comments, identified by Docket ID No. EPA-R08-
OAR-2006-0098, by one of the following methods:
https://www.regulations.gov. Follow the on-line
instructions for submitting comments.
E-mail: long.richard@epa.gov and ostrand.laurie@epa.gov.
Fax: (303) 312-6064 (please alert the individual listed in
the FOR FURTHER INFORMATION CONTACT if you are faxing comments).
Mail: Richard R. Long, Director, Air and Radiation
Program, Environmental Protection Agency (EPA), Region 8, Mailcode 8P-
AR, 999 18th Street, Suite 200, Denver, Colorado 80202-2466.
Hand Delivery: Richard R. Long, Director, Air and
Radiation Program, Environmental Protection Agency (EPA), Region 8,
Mailcode 8P-AR, 999 18th Street, Suite 300, Denver, Colorado 80202-
2466. Such deliveries are only accepted Monday through Friday, 8 a.m.
to 4:55 p.m., excluding Federal holidays. Special arrangements should
be made for deliveries of boxed information.
Instructions: Direct your comments to Docket ID No. EPA-R08-OAR-
2006-0098. EPA's policy is that all comments received will be included
in the public docket without change and may be made available online at
https://www.regulations.gov, including any personal information
provided, unless the comment includes information claimed to be
Confidential Business Information (CBI) or other information whose
disclosure is restricted by statute. Do not submit information that you
consider to be CBI or otherwise protected through https://
www.regulations.gov or e-mail. The https://www.regulations.gov Web site
is an ``anonymous access'' systems, which means EPA will not know your
identity or contact information unless you provide it in the body of
your comment. If you send an e-mail comment directly to EPA, without
going through https://www.regulations.gov your e-mail address will be
automatically captured and included as part of the comment that is
placed in the public docket and made available on the Internet. If you
submit an electronic comment, EPA recommends that you include your name
and other contact information in the body of your comment and with any
disk or CD-ROM you submit. If EPA cannot read your comment due to
technical difficulties and cannot contact you for clarification, EPA
may not be able to consider your comment. Electronic files should avoid
the use of special characters, any form of encryption, and be free of
any defects or viruses. For additional information about EPA's public
docket visit the EPA Docket Center homepage at https://www.epa.gov/
epahome/dockets.htm. For additional instructions on submitting
comments, go to Section I. General Information of the SUPPLEMENTARY
INFORMATION section of this document.
Docket: All documents in the docket are listed in the https://
[[Page 39260]]
www.regulations.gov index. Although listed in the index, some
information is not publicly available, e.g., CBI or other information
whose disclosure is restricted by statute. Certain other material, such
as copyrighted material, will be publicly available only in hard copy.
Publicly available docket materials are available either electronically
in https://www.regulations.gov or in hard copy at the Air and Radiation
Program, Environmental Protection Agency (EPA), Region 8, 999 18th
Street, Suite 300, Denver, Colorado 80202-2466. EPA requests that if at
all possible, you contact the individual listed in the FOR FURTHER
INFORMATION CONTACT section to view the hard copy of the docket. You
may view the hard copy of the docket Monday through Friday, 8 a.m. to 4
p.m., excluding Federal holidays.
FOR FURTHER INFORMATION CONTACT: Laurie Ostrand, Air and Radiation
Program, Mailcode 8P-AR, Environmental Protection Agency (EPA), Region
8, 999 18th Street, Suite 200, Denver, Colorado 80202-2466, (303) 312-
6437, ostrand.laurie@epa.gov.
SUPPLEMENTARY INFORMATION:
Table of Contents
Definitions
I. General Information
II. Background
A. General Background
B. SIP Background
C. FIP Background
III. FIP Proposal
A. Flare Requirements Applicable to All Sources
B. CHS Inc.
C. ConocoPhillips
D. ExxonMobil
E. Montana Sulphur & Chemical Company
IV. Request for Public Comment
V. Statutory and Executive Order Reviews
A. Executive Order 12866, Regulatory Planning Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act
D. Unfunded Mandates Reform Act
E. Executive Order 13132, Federalism
F. Executive Order 13175, Coordination With Indian Tribal
Governments
G. Executive Order 13045, Protection of Children From
Environmental Health Risks and Safety Risks
H. Executive Order 13211, Actions That Significantly Affect
Energy Supply, Distribution, or Use
I. National Technology Transfer and Advancement Act
Definitions
For the purpose of this document, we are giving meaning to certain
words or initials as follows:
(i) The words or initials Act or CAA mean or refer to the Clean Air
Act, unless the context indicates otherwise.
(ii) The initials CEMS mean or refer to continuous emission
monitoring system.
(iii) The initials CO mean or refer to carbon monoxide.
(iv) The words EPA, we, us or our mean or refer to the United
States Environmental Protection Agency.
(v) The initials FIP mean or refer to Federal Implementation Plan.
(vi) The initials H2S mean or refer to hydrogen sulfide.
(vii) The initials MBER mean or refer to the Montana Board of
Environmental Review.
(viii) The initials MDEQ mean or refer to the Montana Department of
Environmental Quality.
(ix) The initials MSCC mean or refer to the Montana Sulphur &
Chemical Company.
(x) The initials NAAQS mean or refer to National Ambient Air
Quality Standards.
(xi) The initials SIP mean or refer to State Implementation Plan.
(xii) The initials SO2 mean or refer to sulfur dioxide.
(xiii) The words state or Montana mean the State of Montana, unless
the context indicates otherwise.
(xiv) The initials SRU mean or refer to sulfur recovery unit.
(xv) The initials SWS mean or refer to sour water stripper.
I. General Information
A. What Should I Consider as I Prepare My Comments for EPA?
1. Submitting CBI. Do not submit this information to EPA through
https://www.regulations.gov or e-mail. Clearly mark the part or all of
the information that you claim to be CBI. For CBI information in a disk
or CD ROM that you mail to EPA, mark the outside of the disk or CD ROM
as CBI and then identify electronically within the disk or CD ROM the
specific information that is claimed as CBI. In addition to one
complete version of the comment that includes information claimed as
CBI, a copy of the comment that does not contain the information
claimed as CBI must be submitted for inclusion in the public docket.
Information so marked will not be disclosed except in accordance with
procedures set forth in 40 CFR part 2.
2. Tips for Preparing Your Comments. When submitting comments,
remember to:
a. Identify the rulemaking by docket number and other identifying
information (subject heading, Federal Register date and page number).
b. Follow directions--The agency may ask you to respond to specific
questions or organize comments by referencing a Code of Federal
Regulations (CFR) part or section number.
c. Explain why you agree or disagree; suggest alternatives and
substitute language for your requested changes.
d. Describe any assumptions and provide any technical information
and/or data that you used.
e. If you estimate potential costs or burdens, explain how you
arrived at your estimate in sufficient detail to allow for it to be
reproduced.
f. Provide specific examples to illustrate your concerns, and
suggest alternatives.
g. Explain your views as clearly as possible, avoiding the use of
profanity or personal threats.
h. Make sure to submit your comments by the comment period deadline
identified.
II. Background
A. General Background
Billings and Laurel are situated in the Yellowstone River Valley in
south-central Montana. The Yellowstone River Valley runs from southwest
to northeast and is the dominant topographical feature influencing
airflow over the area. Windroses \1\ for the area reflect the valley
orientation. Southwest winds are the most common, followed by northeast
winds.
---------------------------------------------------------------------------
\1\ A windrose is a diagram showing the relative frequency or
frequency and strength of winds from different directions (Websters
9th New Collegiate Dictionary).
---------------------------------------------------------------------------
The terrain in the vicinity of Billings and Laurel is upland bench
which is steeply cut by the Yellowstone River and its tributaries. The
bench lies at an elevation of 4000 feet while the valley in Billings is
approximately 3000 feet above sea level (asl) and in Laurel is
approximately 3300 feet asl. A constriction in the Yellowstone Valley
occurs between central Billings and the Lockwood area located to the
east. The valley is generally 3 or 4 miles wide but narrows to a little
over a mile wide at the constriction. Nearby terrain, such as the
Sacrifice Cliff to the southeast of Billings and the Rimrocks to the
north, rises abruptly and is often higher than the tallest smoke stack.
Laurel is located within the Yellowstone Valley approximately 15 miles
southwest of Billings. The valley near Laurel is 3 or 4 miles wide.
Nearby terrain to the northwest and southeast of Laurel rises abruptly
and is often higher than the tallest smoke stack.
The major sulfur dioxide (SO2) emitting industries in
the Billings area are the ConocoPhillips \2\ and
[[Page 39261]]
ExxonMobil \3\ Petroleum Refineries, Western Sugar Company, the PPL
Montana, LLC J.E. Corette Power Plant,\4\ Montana Sulphur & Chemical
Company (MSCC) (gas processing plant, sulfur recovery and sulfur
products), and Yellowstone Energy Limited Partnership (YELP)
(cogeneration power plant). The major SO2 emitting industry
in the Laurel area is the CHS Inc. Petroleum Refinery.\5\ Although
Laurel and Billings are 15 miles apart, the industries in Billings have
some impact on the air quality in Laurel and the industry in Laurel has
some impact on the air quality in Billings.
---------------------------------------------------------------------------
\2\ When the state originally adopted the Billings/Laurel
SO2 SIP, the ConocoPhillips Refinery was known as the
Conoco Refinery. Throughout this document we will refer to the
refinery as ConocoPhillips.
\3\ When the state originally adopted the Billings/Laurel
SO2 SIP, the ExxonMobil Refinery was known as the Exxon
Refinery. Throughout this document we will refer to the refinery as
ExxonMobil.
\4\ When the state originally adopted the Billings/Laurel
SO2 SIP, the PPL Montana, LLC J.E. Corette Power Plant
was known as the Montana Power Company, J.E. Corrette Plant.
Throughout this document we will refer to the power plant as the
Corette Power Plant.
\5\ When the state originally adopted the Billings/Laurel
SO2 SIP, CHS Inc. Petroleum Refinery was known as the
Cenex Petroleum Refinery. Throughout this document we will refer to
the refinery as CHS Inc.
---------------------------------------------------------------------------
On March 3, 1978 (43 FR 8962), the Laurel area was designated as
nonattainment for the primary SO2 national ambient air
quality standard (NAAQS). See also 40 CFR 81.327. The nonattainment
area consists of an area with a two-kilometer radius around CHS Inc.
This designation was based on measured and modeled violations of the
NAAQS. EPA reaffirmed this nonattainment designation on September 11,
1978 (43 FR 40412). The 1990 Clean Air Act Amendments, enacted November
15, 1990, again reaffirmed the nonattainment designation of Laurel with
respect to the primary SO2 NAAQS. Since the Laurel
nonattainment area had a fully approved part D plan, the state was not
required to submit a revised plan for the area under the 1990
Amendments (see sections 191 and 192 of the Act).
On March 3, 1978 (43 FR 8962), those areas in the state that had
not been identified as not meeting the SO2 NAAQS were
designated as ``Better Than National Standards.'' The Billings area was
in that portion of the state that was designated as ``Better Than
National Standards.''
The Act requires EPA to establish NAAQS which protect public health
and welfare. NAAQS have been established for SO2. The Act
also requires states to prepare and gain EPA approval of a plan, termed
a State Implementation Plan (SIP), to assure that the NAAQS are
attained and maintained. Dispersion modeling completed in 1991 and 1993
for the Billings/Laurel area of Montana predicted that the
SO2 NAAQS were not being attained.\6\ As a result, EPA
(pursuant to sections 110(a)(2)(H) and 110(k)(5) of the Act) requested
the State of Montana to revise its previously approved SIP for the
Billings/Laurel area. In response, the State submitted revisions to the
SIP on September 6, 1995, August 27, 1996, April 2, 1997, July 29,
1998, and May 4, 2000.
---------------------------------------------------------------------------
\6\ See the study for the Billings Gasification, Inc. (BGI) (now
YELP) permit in 1991 and the GeoResearch, Inc. (GRI) study
commissioned by the Billings City Council in 1993 (document
's II.G-13 and II.G-12, respectively, in Docket
R8-99-01).
---------------------------------------------------------------------------
B. SIP Background
1. SIP Call
We issued a request that the State of Montana revise the Billings/
Laurel area SO2 SIP by letter to the Governor of Montana,
dated March 4, 1993 (see reference document Z). The request letter
reflected our preliminary finding regarding the SIP's substantial
inadequacy, and was published in the Federal Register on August 4, 1993
(58 FR 41430) (see reference document Y). We sometimes refer to such a
request as a SIP Call. In the request letter, we declared that the SIP
Call would become final agency action when we made a binding
determination regarding the State of Montana's response to the SIP
Call. We made such a binding determination regarding the SIP Call when
we partially and limitedly approved and partially and limitedly
disapproved the Billings/Laurel SO2 SIP revisions submitted
by the State of Montana in response to the request letter.\7\ See 67 FR
22168, 22173 (May 2, 2002) (see reference document AA).
---------------------------------------------------------------------------
\7\ In some cases, a SIP rule may contain certain provisions
that meet the applicable requirements of the Act, but that are
inseparable from other provisions that do not meet all the
requirements. Although the submittal may not meet all of the
applicable requirements, we may consider whether the rule, as a
whole, has a strengthening effect on the SIP. If this is the case,
limited approval may be used to approve a rule that strengthens the
existing SIP as representing an improvement over what is currently
in the SIP and as meeting some of the applicable requirements of the
Act. At the same time we would disapprove the rule for not meeting
all of the applicable requirements of the Act. Under a limited
approval/disapproval action, we simultaneously approve and
disapprove the entire rule even though parts of the rule satisfy,
and parts do not satisfy, requirements under the Act. The
disapproval only concerns the failure of the rule to meet a specific
requirement of the Act and does not affect incorporation of the rule
as part of the approved, federally enforceable SIP. We use this
mechanism when the rule, despite its flaws, will strengthen the
federally enforceable SIP.
In other cases, a SIP rule may contain certain provisions that
meet applicable requirements of the Act, but that are separable from
other provisions that do not meet applicable requirements. Where a
separable portion of the submittal meets applicable requirements,
partial approval may be used to approve that part of the submittal
and partial disapproval to disapprove the provisions that do not
meet applicable requirements of the Act.
EPA's interpretation of the Act regarding approving and
disapproving SIPs is discussed further in a July 9, 1992, memorandum
title ``Processing of State Implementation Plan (SIP) Submittals,''
from John Calcagni to Regional Air Division Directors. (See
reference document A.)
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2. SIPs Submitted in Response to SIP Call
Our 1993 SIP Call called for the State of Montana to submit a SIP
revision for the Billings/Laurel area by September 4, 1994. On
September 6, 1995, the Governor of Montana submitted a SIP revision in
response to the SIP Call. The SIP was later amended with revisions
submitted on August 27, 1996, April 2, 1997, July 29, 1998, and May 4,
2000. Copies of the complete SIP revisions are contained in the docket
for our action on the SIP. (See docket R8-99-01.)
3. EPA's Actions on State's Billings/Laurel SO2 SIP
(a) EPA's May 2, 2002, final action.
On May 2, 2002 (67 FR 22168) \8\ (see reference document AA), we
partially approved, partially disapproved, limitedly approved and
limitedly disapproved provisions of the Billings/Laurel SO2
SIP.\9\ Specifically:
---------------------------------------------------------------------------
\8\ See also June 7, 2002 corrections notice (67 FR 39473)
(reference document KKK).
\9\ See footnote 7.
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(i) We disapproved the following provisions of the Billings/Laurel
SO2 SIP: \10\
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\10\ The SIP was submitted in the form of orders, stipulations,
exhibits and attachments for each source covered by the plan. The
majority of the requirements are contained in the exhibits.
Throughout this document when we refer to an exhibit, we mean
exhibit A to the stipulation for the specified source. For purposes
of our May 2, 2002, SIP action the stipulations and exhibits to
which we refer were adopted by the Montana Board of Environmental
Review (MBER) on June 12, 1998. MBER adopted revised stipulations
and exhibits for some sources on March 17, 2000. To distinguish
between the two sets of stipulations and exhibits, we refer to
either the 1998 stipulation or exhibit for a particular source, or
the 2000 stipulation or exhibit.
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The escape clause (paragraph 22 in the ExxonMobil and MSCC
1998 stipulations, and paragraph 20 in the CHS Inc., ConocoPhillips,
Corette Power Plant, Western Sugar, and YELP 1998 stipulations.)
The MSCC stack height credit and emission limits on the
sulfur recovery unit (SRU) 100-meter stack (paragraph 1 of the
ExxonMobil 1998 stipulation, paragraphs 1 and 2 of the MSCC 1998
stipulation, and sections 3(A)(1)(a) and
[[Page 39262]]
(b) and 3(A)(3) of the MSCC 1998 exhibit).
The emission limit on MSCC's auxiliary vent stacks,
section 3(A)(4) of MSCC's 1998 exhibit.
The attainment demonstration, because of improper stack
height credit and emission limits at MSCC.
The attainment demonstration for lack of flare emission
limits at CHS Inc., ConocoPhillips, ExxonMobil, and MSCC.
The attainment demonstration, because of the disapproval
of the emission limit for MSCC's auxiliary vent stacks.
The Reasonably Available Control Measures (RACM)
(including Reasonably Available Control Technology (RACT)) and
Reasonable Further Progress (RFP) requirements for CHS Inc.
The provisions that allow sour water stripper overheads to
be burned in the flare at CHS Inc. and ExxonMobil (i.e., the following
phrase from section 3(B)(2) of CHS Inc.'s 1998 exhibit and section
3(E)(4) of ExxonMobil's 1998 exhibit: ``or in the flare''; the
following phrases in section 4(D) of CHS Inc.'s 1998 exhibit and
section 4(E) of ExxonMobil's 1998 exhibit: ``or in the flare'' and ``or
the flare''.)
(ii) We limitedly approved and limitedly disapproved the following
provision:
The emission limit for the 30-meter stack at MSCC (section
3(A)(2) of MSCC's 1998 exhibit) because it lacked a reliable compliance
monitoring method.
(iii) We did not act on the following provisions:
The provisions in section 6(B)(3) of MSCC's 1998 exhibit
that require certain monitoring equipment to support the variable
emission limit.\11\
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\11\ Since we disapproved MSCC's variable emission limit, we did
not believe it made sense to approve section 6(B)(3) of MSCC's 1998
exhibit, which requires MSCC to install certain monitoring equipment
to support the use of the variable limit. Section 6(B)(3) would be
needed only if we approved MSCC's variable emission limit.
---------------------------------------------------------------------------
YELP's emission limits (in sections 3(A)(1) through (3) of
YELP's 1998 exhibit).
ExxonMobil's coker CO-boiler emission limitation (in
section 3(B)(1) of ExxonMobil's 1998 exhibit).
ExxonMobil's F-2 crude/vacuum heater stack emission limits
and attendant compliance monitoring methods (sections 3(A)(2), 3(B)(3),
4(E) and method 6A of attachment 2 of ExxonMobil's
1998 exhibit; and the following phrase from section 3(E)(4) of
ExxonMobil's 1998 exhibit ``except that the sour water stripper
overheads may be burned in the F-1 Crude Furnace (and exhausted through
the F-2 Crude/Vacuum Heater stack) or in the flare during periods when
the FCC CO Boiler is unable to burn the sour water stripper overheads,
provided that: (a) such periods do not exceed 55 days per calendar year
and 65 days for any two consecutive calendar years, and (b) during such
periods the sour water stripper system is operating in a two tower
configuration.'')
ExxonMobil's fuel gas combustion emission limits and
attendant compliance monitoring methods (in sections 3(A)(1), 3(B)(2),
4(B), and 6(B)(3) of ExxonMobil's 1998 exhibit).
CHS Inc.'s combustion sources emission limitations and
attendant compliance monitoring methods (sections 3(A)(1)(d), 4(B),
4(D) and method 6A of attachment 2 of CHS Inc.'s 1998
exhibit; and the following phrase from section 3(B)(2) of CHS Inc.'s
1998 exhibit ``except that those sour water stripper overheads may be
burned in the main crude heater (and exhausted through the main crude
heater stack) or in the flare during periods when the FCC CO boiler is
unable to burn the sour water stripper overheads from the ``old'' SWS,
provided that such periods do not exceed 55 days per calendar year and
65 days for any two consecutive calendar years.'')
(iv) In a separate action published on May 2, 2002 (67 FR 22242)
\12\ (see reference document BB), we proposed action on some provisions
of the Billings/Laurel SO2 SIP submitted on July 29, 1998, and May 4,
2000.\13\ We later finalized action on these provisions on May 22, 2003
(68 FR 27908) (see discussion below and reference document CC).
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\12\ See also June 14, 2002 correction notice (67 FR 40897)
(reference document LLL).
\13\ On July 28, 1999 (64 FR 40791), we proposed to
conditionally approve certain provisions of the SIP based on the
Governor's commitment to address concerns we had raised. The
Governor submitted a SIP revision on May 4, 2000, which was intended
to fulfill the commitments. Since the Governor submitted a SIP
revision to fulfill the commentments, we did not finalize our
proposed conditional approval and instead proposed separate action
on parts of the July 29, 1998, submittal (i.e., those parts we
proposed to conditionally approve on July 28, 1999) and all of the
May 4, 2000, submission (which in some cases modified the provisions
of the July 29, 1998, submittal).
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(v) We approved the following provisions:
All provisions of the SIP that were not partially
disapproved, limitedly disapproved, omitted from our action, or
addressed in our May 2, 2002, proposal.
(b) EPA's May 22, 2003, final action.
On May 22, 2003 (68 FR 27908) \14\ (see reference document CC), we
partially approved, limitedly approved, and limitedly disapproved
provisions of the Billings/Laurel SO2 SIP. Specifically:
---------------------------------------------------------------------------
\14\ See also June 2, 2003 correction notice (68 FR 32799)
(reference document MMM).
---------------------------------------------------------------------------
(i) We approved the following provisions:
YELP's emission limits in sections 3(A)(1) through (3) and
reporting requirements in section 7(C)(1)(b) of YELP's 2000 exhibit.
Provisions related to the burning of SWS overheads in the
F-1 Crude Furnace (and exhausted through the F-2 Crude/Vacuum Heater
stack) at ExxonMobil in sections 3(E)(4) and 4(E) (excluding ``or in
the flare'' and ``or the flare'' in both sections), 3(A)(2), and
3(B)(3) of ExxonMobil's 1998 exhibit, and method 6A-1 of
attachment 2 of ExxonMobil's 2000 exhibit.
Minor changes in sections 3, 3(A), and 3(B) (only the
introductory paragraphs); and sections 3(E)(3), 6(B)(7), 7(B)(1)(d),
7(B)(1)(j), 7(C)(1)(b), 7(C)(1)(d), 7(C)(1)(f), and 7(C)(1)(l) of
ExxonMobil's 2000 exhibit.
(ii) We limitedly approved and limitedly disapproved the following
provisions:
Provisions related to the fuel gas combustion emission
limits at ExxonMobil in sections 3(B)(2), 4(B), and 6(B)(3) of
ExxonMobil's 1998 exhibit, and section 3(A)(1) of ExxonMobil's 2000
exhibit.
Provisions related to ExxonMobil's coker CO-boiler
emission limit in sections 2(A)(11)(d), 3(B)(1), and 4(C) of
ExxonMobil's 2000 exhibit.
Provisions related to the burning of SWS overheads at CHS
Inc. in sections 3(B)(2) and 4(D) (excluding ``or in the flare'' and
``or the flare'' in both sections), 3(A)(1)(d), and 4(B) of CHS Inc.'s
1998 exhibit, and method 6A-1 of attachment 2 of CHS
Inc.'s 2000 exhibit.
4. Appeal of EPA's Action on Billings/Laurel SO2 SIP
On June 10, 2002, MSCC petitioned the United States Court of
Appeals for the Ninth Circuit for review of EPA's May 2, 2002, final
SIP action. Subsequently, MSCC and EPA agreed to a stay of the
litigation pending EPA's final action on this FIP. The case is
captioned Montana Sulphur & Chemical Company v. United States
Environmental Protection Agency, No. 02-71657. No petitions for
judicial review were filed regarding EPA's May 22, 2003, SIP action.
[[Page 39263]]
C. FIP Background
Under section 110(c) of the Act, whenever we disapprove a SIP in
whole or in part we are required to promulgate a FIP. Specifically,
section 110(c) provides:
``(1) The Administrator shall promulgate a Federal
implementation plan at any time within 2 years after the
Administrator--
(A) finds that a State has failed to make a required submission
or finds that the plan or plan revision submitted by the State does
not satisfy the minimum criteria established under [section
110(k)(1)(A)] \15\, or
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\15\ Section 110(k)(1)(A) requires the Administrator to
promulgate minimum criteria that any plan submission must meet
before EPA is required to act on the submission. These completeness
criteria are set forth at 40 CFR 51, Appendix V.
---------------------------------------------------------------------------
(B) disapproves a State implementation plan submission in whole
or in part, unless the State corrects the deficiency, and the
Administrator approves the plan or plan revision, before the
Administrator promulgates such Federal implementation plan.''
Thus, because we disapproved portions of the Billings/Laurel
SO2 SIP, and the attainment demonstration, we are required
to promulgate a FIP.
Section 302(y) defines the term ``Federal implementation plan'' in
pertinent part, as:
``[A] plan (or portion thereof) promulgated by the Administrator
to fill all or a portion of a gap or otherwise correct all or a
portion of an inadequacy in a State implementation plan, and which
includes enforceable emission limitations or other control measures,
means or techniques (including economic incentives, such as
marketable permits or auctions or emissions allowances) * * *''
More simply, a FIP is ``a set of enforceable federal regulations
that stand in the place of deficient portions of a SIP.'' McCarthy v.
Thomas, 27 F.3d 1363, 1365 (9th Cir. 1994). As the Court of Appeals for
the D.C. Circuit noted in a 1995 case, FIPs are powerful tools to
remedy deficient state action:
``The FIP provides an additional incentive for state compliance
because it rescinds state authority to make the many sensitive
technical and political choices that a pollution control regime
demands. The FIP provision also ensures that progress toward NAAQS
attainment will proceed notwithstanding inadequate action at the
state level.''
Natural Resources Defense Council, Inc. v. Browner, 57 F.3d
1122, 1124 (D.C. Cir. 1995).
When EPA promulgates a FIP, courts have not required EPA to
demonstrate explicit authority for specific measures: ``We are inclined
to construe Congress' broad grant of power to the EPA as including all
enforcement devices reasonably necessary to the achievement and
maintenance of the goals established by the legislation.'' South
Terminal Corp. v. EPA, 504 F.2d 646, 669 (1st Cir. 1974). As the Ninth
Circuit stated in a case involving a FIP with far-reaching consequences
in Los Angeles: ``The authority to regulate pollution carries with it
the power to do so in a manner reasonably calculated to reach that
end.'' City of Santa Rosa v. EPA, 534 F.2d 150, 155 (9th Cir. 1976),
vacated and remanded on other grounds sub nom. Pacific Legal Foundation
v. EPA, 429 U.S. 990 (1976).
In addition to giving EPA remedial authority, section 110(c)
enables EPA to assume the powers that the state would have to protect
air quality, when the state fails to adequately discharge its planning
responsibility. As the Ninth Circuit held, when EPA acts to fill in the
gaps in an inadequate state plan under section 110(c), EPA `` `stands
in the shoes of the defaulting State, and all of the rights and duties
that would otherwise fall to the State accrue instead to EPA.' ''
Central Arizona Water Conservation District v. EPA, 990 F.2d 1531, 1541
(9th Cir. 1993). As the First Circuit held in an early case:
``[T]he Administrator must promulgate promptly regulations
setting forth `an implementation plan for a State' should the state
itself fail to propose a satisfactory one * * *. The statutory
scheme would be unworkable were it read as giving to EPA, when
promulgating an implementation plan for a state, less than those
necessary measures allowed by Congress to a state to accomplish
federal clean air goals. We do not adopt any such crippling
interpretation.''
South Terminal Corp. v. EPA, supra, at 668 (citing previous version
of section 110(c)).
III. FIP Proposal
As discussed above, in this proposed rulemaking, EPA is fulfilling
its mandatory duty under section 110(c) of the Act to propose FIP
provisions for the Billings/Laurel, Montana area because of our limited
and partial disapproval of portions of the Billings/Laurel
SO2 SIP submitted by Montana. Our proposed FIP would not
replace the SIP entirely, but instead would only replace elements of
the SIP or fill gaps in the SIP as necessary to ensure attainment and
maintenance of the SO2 NAAQS. In cases where the provisions
of the FIP would address emissions activities differently or establish
different requirements than provisions of the SIP, the provisions of
the FIP would take precedence.
Our proposed FIP only impacts four stationary sources: CHS Inc.,
ConocoPhillips, ExxonMobil and Montana Sulphur & Chemical Company
(MSCC). We caution that if any of these sources are subject to more
stringent requirements under other provisions of the Act (e.g., section
111 or 112, part C, or SIP-approved permit programs under Part A), our
proposal of any FIP requirement would not excuse any of these sources
from meeting other more stringent requirements. Also, our proposed FIP
is not meant to imply any sort of applicability determination under
other provisions of the Act (e.g., section 111 or 112, part C, or SIP-
approved permit programs under Part A).
A. Flare Requirements Applicable to All Sources
We disapproved the Billings/Laurel SO2 SIP as it applied
to the attainment demonstration because the SIP lacked enforceable
emission limits for flares, while the SIP submission took credit for
such emission limits. See our May 2, 2002, final rulemaking action at
67 FR 22168. Because of this disapproval we are proposing emission
limits and compliance determining methods for flares at CHS Inc.,
ConocoPhillips (including Jupiter Sulfur),\16\ ExxonMobil, and MSCC.
The flare emission limits and compliance determining methods are being
proposed for the purpose of assuring attainment and maintenance of the
SO2 NAAQS.
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\16\ The ConocoPhillips Billings Refinery also includes the
Jupiter Sulfur Recovery Facility (see reference document S).
---------------------------------------------------------------------------
Since the state's attainment demonstration assumed that the main
flares at each source were limited to 150 pounds of SO2 per
three hour period, and that the Jupiter Sulfur SRU flare would share an
emission limit of 75 pounds of SO2 per three hour period
with the Jupiter Sulfur SRU/ATS stack, we are proposing to promulgate
flare emission limits that reflect the state's assumption that
emissions from these points would not exceed these levels. More
specific detail regarding each of the sources' emission limits is
provided below in sections III. B, C, D, and E.
While we are proposing that 150 pounds of SO2 per three
hour period be the limit for the main flares, we are soliciting input
on whether we should instead limit the main flares to 500 pounds of
SO2 per calendar day. This value is consistent with a
trigger point for certain analyses contained in settlements between the
United States and CHS Inc., ConocoPhillips, and ExxonMobil. For
purposes of our attainment demonstration, we have assumed that the 500
pounds would be emitted from the four main flares over a three-hour
period rather than a
[[Page 39264]]
calendar day. Our evaluation shows that even under these conditions,
the 3-hour SO2 NAAQS would be attained.
Note that if we adopted the 500 pound value for this FIP, we would
impose it as an enforceable emission limit, not just a trigger point
for further analyses.
We are proposing that the flare limits will apply at all times
without exception. We recognize that flares are sometimes used as
emergency devices at refineries and that it may be difficult to comply
with these flare limits during malfunctions. However, under our
interpretations of the Clean Air Act, it is not appropriate to create
automatic exemptions from SIP limits needed to demonstrate attainment.
(See reference document RRR, September 20, 1999 memorandum titled
``State Implementation Plans: Policy Regarding Excess Emissions During
Malfunctions, Startup, and Shutdown,'' from Steven A. Herman and Robert
Perciasepe, to Regional Administrators (referred to hereafter as ``1999
policy statement'').) We do interpret the CAA to allow owners and
operators of sources to assert an affirmative defense to penalties in
appropriate circumstances, but normally we would not view such an
affirmative defense as appropriate in areas where a single source or
small group of sources has the potential to cause an exceedance of the
NAAQS. See 1999 policy statement. We solicit comment on whether it
would be appropriate to include in our final FIP the ability to assert
an affirmative defense to penalties only (not injunctive relief) for
violations of the flare limits. If we were to establish such a
provision, we anticipate it would closely follow the guidance contained
in our 1999 policy statement.
We are also proposing that compliance with the emission limits be
determined by measurement of the total sulfur concentration and
volumetric flow rate of the gas stream to the flare(s), followed by
calculation, using appropriate equations, of SO2 emitted per
3-hour period. The assumption is that when the gas stream is combusted
in a flare, all of the sulfur in the gas stream converts to
SO2 and is emitted to the atmosphere. Also, by knowing the
volumetric flow rate of the gas stream to the flare(s) we can determine
the SO2 emitted to the atmosphere over a specified
timeframe.
With respect to the volumetric flow rate monitoring systems, we
developed our proposed approach considering volumetric flow rate
monitoring requirements established at refinery flares in California
and Texas, vendor literature, technical articles, and information
gathered from discussions with vendors. (See reference documents KK
(Bay Area Air Quality Management District (BAAQMD)--documents related
to consideration of proposed new regulation 12, Rule 11 Flare
Monitoring at Petroleum Refineries); LL (final version of BAAQMD
Regulation 12, Miscellaneous Standards of Performance, Rule 11, Flare
Monitoring at Petroleum Refineries); BBB (South Coast Area Air Quality
Management District (SCAQMD)--documents related to consideration of
revisions to rule 1118, Control of Emissions From Refinery Flares); CCC
(final version of SCAQMD Rule 1118, Control of Emissions From Refinery
Flares); MM (Texas Natural Resource Conservation Commission, Chapter
115--Control of Air Pollution from Volatile Organic Compounds,
Subchapter H: Highly-Reactive Volatile Organic Compounds, Division 1:
Vent Gas Control); NN (Fluid Components International LLC (FCI), vendor
literature from www.fluidcomponents.com); OO (GE Sensing, vendor
literature); PP (``Why and How to measure flare gas'' from Flowmeter
Directory (www.flowmeterdirectory.com)); QQ (``Transit-time Ultrasonic
Flowmeters for Gases'' Presented at and Published in Part in the Proc.
41st Annual CGA (Canadian Gas Association) Gas Measurement School,
Grand Okanagan, Kelowna BC, Canada, June 4-6, 2002); RR (``Flare
Measurement `Best Practices' To Comply With National & Provincial
Regulations''); SS (``Ultrasonic Flowmeter Market is Expected to Grow
Strongly''); TT (Note to Billings/Laurel SO2 FIP File, April
7, 2004 Discussion with Peter Klorer, GE Infrastructure, Regarding
Panametrics Mass Flowmeter); HHH (Note to Billings/Laurel
SO2 FIP File, April 20, 2006 Discussion with Paul Calef, GE
Sensing, Regarding Flare Flowmeter).) Based on what is required
elsewhere and what we have learned from vendors and literature, we have
determined that there is reliable technology available to continuously
monitor and record the volumetric flow rate of the gas stream to a
flare. Therefore, we are proposing that sources install, calibrate,
maintain and operate a continuous flow monitoring system capable of
measuring the total volumetric flow of the gas stream that is combusted
in a flare in accordance with the specifications described below. The
flow monitoring system may require one or more flow monitoring devices
or flow measurements at one or more header locations if one monitor
cannot measure all of the volumetric flow to a flare.
We are proposing the following volumetric flow monitoring
specifications:
(1) The minimum detectible velocity of the flow monitoring
device(s) shall be 0.1 feet per second (fps);
(2) The device(s) shall continuously measure the range of flow
rates corresponding to velocities from 0.5 to 275 fps and have a
manufacturer's specified accuracy of 5% over the range of 1
to 275 fps;
(3) For correcting flow rate to standard conditions (defined as
68[deg]F and 760 millimeters of mercury (mmHg)), temperature and
pressure shall be monitored continuously;
(4) The temperature and pressure shall be monitored in the same
location as the flow monitoring device(s) and shall be calibrated to
meet accuracy specifications as follows: temperature shall be
calibrated annually to within 2.0% at absolute temperature
and the pressure monitor shall be calibrated annually to within 5.0 mmHg;
(5) Flow monitoring device(s) shall be initially calibrated, prior
to installation, to demonstrate accuracy to within 5.0% at flow rates
equivalent to 30%, 60% and 90% of monitor full scale; and
(6) After installation, the flow monitoring devices shall be
calibrated annually according to manufacturer's specifications.\17\
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\17\ Volumetric flow monitors meeting the proposed volumetric
flow monitoring specifications above should be able to measure the
majority of volumetric flow in the gas streams to the flare.
However, in rare events (e.g., such as upset conditions) the flow to
the flare may exceed the range of the monitor. EPA is not suggesting
that multiple monitors be installed to measure extreme flow rates
that rarely occur. Rather, in the rare event that the range of the
monitor is exceeded, reliable flow estimation parameters may be used
to determine the volumetric flow rate to the flare. Flow determined
through reliable estimation parameters will be used to calculate
SO2 emissions. In quarterly reports, sources shall
indicate when reliable estimation parameters are used and how such
parameters were derived.
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With respect to measuring the total sulfur concentration, we
developed our proposed approach considering concentration monitoring
requirements established at refinery flares in California, vendor
iterature, and information gathered from discussions with vendors. (See
reference documents UU (Note to Billings/Laurel SO2 FIP
File, May 11, 2004 Discussion with Robert Hornberger, Galvanic Applied
Sciences); VV (Galvanic Applied Sciences Inc., H2S & Total
Sulfur Analyzers, vendor literature printed from www.galvanic.ab.ac);
KK (Bay Area Air Quality Management District (BAAQMD)--documents
related to consideration of proposed new regulation 12, Rule 11, Flare
Monitoring
[[Page 39265]]
at Petroleum Refineries); BBB (South Coast Area Air Quality Management
District (SCAQMD)--documents related to consideration of revisions to
rule 1118, Control of Emissions From Refinery Flares); CCC (final
version of SCAQMD Rule 1118, Control of Emissions From Refinery
Flares); XX (Note to Billings/Laurel SO2 FIP File, May 10
and May 31, 2006 Discussions with Tom Kimbel, Analytical Systems
International, Regarding Total Sulfur Analyzers); YY (Analytical
Systems International, Continuous Sulfur Analyzer, vendor literature
printed from www.ASIWebPage.com); III (Note to Billings/Laurel SO2 FIP
File, April 19, 2006 Discussion with Bob Kinsella, ThermoElectron,
Regarding Total Sulfur Analyzer); JJJ (Note to Billings/Laurel
SO2 FIP File, May 12, 2006, and June 7, 2006 Discussions
with Eugene Teszler, South Coast Air Quality Management District,
regarding Total Sulfur Analyzer).) Based on what is required elsewhere
and what we have learned from vendors, we have determined that there is
reliable technology available to continuously monitor and record the
total sulfur concentration of the gas stream to a flare. Also, we are
proposing that the total sulfur concentrations, rather than just
H2S concentrations, be monitored continuously. This is
because we believe there are other sulfur compounds in the gas stream
to a flare. The total sulfur analyzer system may require one or more
total sulfur analyzers or total sulfur concentration measurements at
one or more header locations if one analyzer cannot measure all of the
total sulfur concentration to a flare.
Therefore, we are proposing that sources install, calibrate,
maintain and operate an on-line analyzer system capable of continuously
determining the total sulfur concentration of the gas stream sent to a
flare. We are proposing that the continuous monitoring occur at a
location(s) that is (are) representative of the gas combusted in the
flare and be capable of measuring the expected range of total sulfur
expected in the gas stream to the flare. Vendor literature and
discussions with vendors indicates this is feasible. The total sulfur
analyzer shall be installed, certified (on a concentration basis), and
operated in accordance with 40 CFR part 60, Appendix B, Performance
Specification 5, and be subject to and meet the quality assurance and
quality control requirements (on a concentration basis) of 40 CFR part
60, Appendix F. The source shall notify EPA in writing of each Relative
Accuracy Test Audit a minimum of twenty-five (25) working days prior to
the actual testing.
We are proposing that the volumetric flow and total sulfur
concentrations determined by the above procedures be used in
calculations to determine the hourly and three hour SO2
emissions from the flare(s).
We are proposing that each source submit for EPA review and
approval a flare monitoring plan prior to establishing continuous
monitors on the flare(s). Also, we are proposing that each source
submit for EPA review a quality assurance/quality control (QA/QC) plan
for each of the continuous monitors.
Finally, we are proposing certain quarterly reporting requirements.
The quarterly reporting requirements are similar to the reporting
requirements contained in the Billings/Laurel SO2 SIP and
those contained in 40 CFR 60.7(c).
B. CHS Inc.
1. Flare Requirements
The state's attainment demonstration and our subsequent attainment
modeling for the FIP assume that CHS Inc.'s flare is limited to 150
pounds of SO2 per three hour period.18, 19 This
is the limit we are proposing for CHS Inc.'s flare. Compliance with the
flare emission limit will be determined as discussed in Section III.A,
above.
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\18\ See Modeling discussion in Section III.E.5, below.
\19\ Our FIP assumes that CHS Inc. has only one operational
flare. See reference documents PPP and QQQ.
---------------------------------------------------------------------------
2. Combustion Sources Emission Limits.
Three of the emission limits contained in CHS Inc.'s portion of the
Billings/Laurel SO2 SIP are combined emission limits for
combustion sources. The emission limits, contained in CHS Inc.'s 1998
exhibit, are in pounds of SO2 per 3-hour, 24-hour and one-
year averaging periods.\20\ Compliance with the emission limits is
determined by measuring the sulfur and H2S content of the
fuels combusted (oil and fuel gas) and the flow of the fuels to the
combustion sources. The state's assumption is that when the sulfur/
H2S in the fuel is combusted, all the sulfur/H2S
converts to SO2 and is emitted to the atmosphere. By
measuring sulfur/H2S content of the fuel and the flow of the
fuel to the combustion sources, the amount of SO2 emitted
per 3-hour, 24-hour and one-year averaging periods can be calculated.
CHS Inc.'s 1998 exhibit also allows sour water stripper (SWS) overheads
(ammonia (NH3) and H2S gases removed from the
sour water in the sour water stripper), to be combusted in the main
crude heater. When the SWS overheads are combusted in the main crude
heater, compliance with the combustion source emission limits is
determined by summing the SO2 emissions calculated from the
combustion of the fuels and SWS overheads. The SO2 emissions
from the SWS overheads are determined by measuring the sulfur compounds
in, and the flow of, the sour water.
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\20\ Section 3(A)(1)(d) of CHS Inc.'s 1998 exhibit. (See
reference document DD for a copy of the exhibit.)
---------------------------------------------------------------------------
We were concerned that the method the state established to measure
the amount of sulfur compounds in the sour water at CHS Inc. would not
measure all the sulfur compounds in the sour water.\21\ Specifically,
we concluded that the analytical method submitted in the SIP would not
measure all of the sulfur compounds in the sour water because of the
potentially high concentrations of sulfur compounds; there would not be
enough preservative in the sample container to prevent the loss of the
sulfur compounds during sampling and analysis. (See reference document
X.) Therefore, the emissions of SO2 from the combustion of
SWS overheads in the main crude heater could be underestimated. We
concluded that the combustion source emission limits were not
enforceable under all scenarios and, therefore, did not meet the
requirements of section 110(a)(2)(A) of the Act. On May 22, 2003 (68 FR
27908), we limitedly approved and limitedly disapproved the combustion
source emission limits and method used to measure the sulfur compounds
in the sour water.
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\21\ For measuring the sulfur compounds in the sour water, the
state established Method 6A-1 contained in attachment
2 of CHS Inc.'s 2000 exhibit. (See reference document EE
for a copy of the exhibit.)
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After the state adopted CHS Inc.'s 1998 and 2000 exhibits as part
of the SIP, the state modified CHS Inc.'s air quality permit to
prohibit the burning of ``old'' sour water stripper overheads in the
FCC CO boiler and the main crude heater. See Air Quality Permit
1821-11, provision II.C.1. (See reference document B.) The
state has not modified the SIP to correspond to the changes in CHS
Inc.'s air quality permit.\22\
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\22\ Page 11 of the State's CHS Inc. Permit Analysis, attached
to Permit 1821-11 (see reference document B) discusses the
SWS and indicates that a new SWS stripper was constructed, which
replaced the operation of the older existing SWS. The old SWS cannot
be removed, however, and functions only as the back-up unit. The
Permit Analysis further indicates that the stripper overhead gas
containing H2S and NH3, is sent to the new SRU
for sulfur recovery and incineration of NH3. This was
confirmed in a conversation with the DEQ (see reference document
DDD).
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[[Page 39266]]
To address our limited disapproval of the combustion source
emission limits in the SIP, we are proposing a prohibition in the FIP
on the burning of SWS overheads in the main crude heater. Prohibiting
the burning of SWS overheads in the main crude heater will eliminate
our concern regarding the method used to measure the amount of sulfur
compounds in the sour water. We believe it is reasonable to make this
proposal because the state and CHS Inc. have already agreed to such
restrictions in CHS Inc.'s air quality permit.
Compliance with the prohibition to not burn SWS overheads in the
main crude heater will be based on methods similar to those contained
in CHS Inc.'s 1998 exhibit. Specifically, section 3(B)(3) of the 1998
exhibit requires CHS Inc. to install a chain and lock on the valve that
supplies sour water stripper overheads from the ``old'' SWS to the main
crude heater to insure that the valve cannot be opened unless the chain
and lock are removed. Under our proposed FIP, CHS Inc. would be
required to maintain the chain and lock in place and keep the valve
closed at all times. CHS Inc. would be required to log and report any
noncompliance with this provision.
C. ConocoPhillips
1. Flare Requirements
The state's attainment demonstration and our subsequent attainment
modeling for the FIP assume that ConocoPhillips' main refinery flare is
limited to 150 pounds of SO2 per three hour period.\23\ We
understand that ConocoPhillips actually has two main flares--a north
main flare and a south main flare--but only operates one at a time and
that Jupiter Sulfur, ConocoPhillips' sulfur recovery unit (SRU), also
has one flare. Correspondence from ConocoPhillips, dated February 4,
2004, indicates that the north flare is currently in use but the south
flare has been used in alternating 4-year cycles, with switches at full
plant turnarounds. (See reference document C.) Conversations with the
MDEQ on September 1, 2004, confirm that only one flare is used at a
time and that a section of the pipe going to the unused flare is
removed during the turnaround. (See reference document W.) Therefore,
with respect to ConocoPhillips, in lieu of establishing a separate
emission limit for each main flare, we are proposing one emission limit
for the main flare. At any one time, ConocoPhillips may only use either
the north or south main flare.
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\23\ See Modeling discussion in Section III.E.5, below.
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We are proposing that compliance with the main flare emission limit
at ConocoPhillips be determined by measuring the total sulfur
concentration and volumetric flow rate of the gas stream to the flare.
To the extent that a single monitoring location cannot be used for both
the north and south main flare, ConocoPhillips will need to monitor
flow and measure total sulfur concentration at more than one location
to determine compliance with the main flare emission limit.
Regarding the flare at the Jupiter Sulfur Recovery facility located
at ConocoPhillips, the SRU flare and SRU/ATS \24\ stack, which are
roughly the same height, share an emission limit in Montana's air
quality permit for ConocoPhillips; the Jupiter SRU/ATS stack and the
SRU flare each have an SO2 emission limit of 25.00 lb/hr and
0.300 tons/day. Emissions from the SRU flare are only permitted during
times that the ATS plant is not operating. See Air Quality Permit
2619-19, dated May 27, 2004, section II.B.1.a and b. (See
reference document S.)
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\24\ ATS stands for Ammonium Thiosulfate.
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However, the Billings/Laurel SO2 SIP is not clear with
respect to the relationship between the SRU flare and SRU/ATS stack.
The SIP contains emission limits on the Jupiter Sulfur SRU stack but
does not indicate that the limits are shared between the SRU flare and
SRU/ATS stack.\25\ Since the SIP is not clear, we are proposing to
clarify in the FIP that emissions can only be vented from the SRU flare
when emissions are not being vented from the SRU/ATS stack. We believe
that our proposal is consistent with what the state and ConocoPhillips
intended in the SIP. First, the SRU flare and SRU/ATS stack were
modeled as one point in the state's attainment demonstration. Second,
Air Quality Permit 2619-19, dated May 27, 2004, indicates that
emissions from the SRU flare can only occur during times that the ATS
plant is not operating.
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\25\ See section 3(A)(3) of ConocoPhillips' 1998 exhibit. (See
document FF for a copy of the exhibit.)
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We are proposing that compliance with the SRU flare emission limit,
when Jupiter Sulfur vents emissions to the SRU flare rather than the
SRU/ATS stack, be determined by measuring the total sulfur
concentration and volumetric flow rate of the gas stream to the
flare.\26\ Our proposal regarding the SRU flare supports our attainment
demonstration.
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\26\ Note that the SRU/ATS stack has an SO2 CEMS and
flow monitor to determine compliance when emissions are vented
through that stack.
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D. ExxonMobil
1. Flare Requirements
The state's attainment demonstration and our subsequent attainment
modeling for the FIP assume that ExxonMobil's primary process and
turnaround flares are limited to 150 pounds of SO2 per three
hour period.\27\ From correspondence from ExxonMobil, dated February 4,
2004, we understand that ExxonMobil has a turnaround flare that is only
used about 30-40 days every five to six years, when the facility's
major SO2 source, the fluid catalytic cracking unit, is not
normally operating. (See reference document E.) Therefore, in lieu of
establishing a separate emission limit for the turnaround flare, we are
proposing one combined emission limit for the primary process and
turnaround flares.
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\27\ See Modeling discussion in Section III.E.5, below.
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Our assumption is that the flow and concentration monitoring
devices installed to measure the gas stream to the primary process
flare will also be able to measure the gas stream to the turnaround
flare. To the extent that a single monitoring location cannot be used
to measure the gas stream to both the primary process flare and the
turnaround flare, we may allow alternative measures to determine
volumetric flow rate and total sulfur concentrations of the gas stream
to the turnaround flare if the turnaround flare is used infrequently--
e.g., only for refinery turnarounds once every five to six years. Such
alternative measures could include using good engineering judgment to
determine volumetric flow rate to the flare or manually sampling the
gas stream to the flare to determine total sulfur concentrations.
2. Compliance Monitoring of Refinery Fuel Gas Combustion Emission
Limits
Two of the emission limits contained in the ExxonMobil portion of
the Billings/Laurel SO2 SIP are combined emission limits for
refinery fuel gas combustion sources. The emission limits, contained in
ExxonMobil's 1998 and 2000 exhibits, are in pounds of SO2
per 3-hour and 24-hour averaging periods.\28\ Compliance with the
emission limits is determined by measuring the H2S content
of the refinery fuel gas combusted and the flow of the fuel gas to the
combustion
[[Page 39267]]
sources.\29\ The state's assumption is that when the fuel is combusted,
all the H2S converts to SO2 and is emitted to the
atmosphere. By measuring H2S content of the fuel and the
flow of the fuel to the combustion sources, the amount of
SO2 emitted per 3-hour and 24-hour averaging periods can be
calculated.
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\28\ See sections 3(A)(1) and 3(B)(2) of ExxonMobil's 1998 and
2000 exhibits. (See reference documents GG and HH for copies of the
exhibits.)
\29\ See section 4(B) of ExxonMobil's 1998 exhibit. (See
reference document GG for a copy of the exhibit.)
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We were concerned that the method the state established to measure
the H2S concentration was not adequate under all scenarios.
Specifically, we determined that the H2S concentrations in
refinery fuel gas could exceed the levels which the H2S
continuous emission monitoring system (CEMS) would be able to
monitor.\30\ Therefore, the emissions of SO2 from the
refinery fuel gas combustion sources could be underestimated. We
concluded that the refinery fuel gas combustion sources emission limits
were not enforceable under all scenarios and, therefore, did not meet
the requirements of section 110(a)(2)(A) of the Act. On May 22, 2003
(68 FR 27908), we limitedly approved and limitedly disapproved the
refinery fuel gas combustion emission limits and method used to measure
the H2S in the refinery fuel gas.
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\30\ Section 6(B)(3) of ExxonMobil's 1998 exhibit indicates that
ExxonMobil shall insure that the H2S concentration
monitor at