Specific requirements regarding storage and handling are
provided in the sections covering the particular chemical. Storage and handling
installations shall meet the following general requirements:
(1) STORAGE FACILITIES. Storage facilities
shall meet the following requirements:
(a)
Space shall be provided for at least 30 days of chemical supply, convenient and
efficient handling, dry storage conditions, and a minimum of 1.5 truck loads
storage volume where purchase is by truck load.
(b) Covered or unopened shipping containers
shall be provided for storage unless the chemical is transferred into an
approved covered storage unit. Solution tanks shall have overlapping or
threaded covers that provide sanitary protection for the chemical being stored.
Large tanks shall be covered and those with top access openings shall have
either threaded covers or the openings shall be curbed and fitted with
overlapping covers. Grommets, pipe seals, or other sanitary means shall be
provided to create a sanitary seal where tubes, hoses, and pipes pass through
the walls or covers of chemical storage tanks.
(c) Solution storage or day tanks supplying
chemical feeders directly shall have at a minimum sufficient capacity for one
day of operation. If the chemical solution is prepared from a powder or slurry,
2 solution tanks shall be required if necessary to assure continuity of
feed.
(cm) Graduated lines may not
be used to determine daily chemical usage when the daily use is less than 5
percent of the tank capacity.
(d)
Solution storage or day tanks supplying feeders directly shall have a maximum
capacity such that daily chemical solution usage is a minimum of 5 percent of
the tank capacity. The department may approve chemical container storage
volumes that will allow daily chemical solution usage less than 5 percent of
the tank capacity if supporting information is provided to the department and
the chemical storage container is placed on a scale, or another department
approved method is installed, to accurately determine daily chemical usage.
Graduated lines shall not be used to determine daily chemical usage in cases
when the daily use is less than 5 percent of the tank capacity. The maximum
storage volume shall not exceed 45 days for sodium hypochlorite and 60 days for
all other chemicals.
(e) Storage
facilities shall be constructed of, or lined with, materials compatible with
the chemical being handled.
(f)
Mixing equipment shall be provided where necessary to assure a uniform chemical
solution strength. Continuous mixing shall be provided to maintain slurries in
suspension.
(g) Means shall be
provided to accurately determine the amount of chemical applied in accordance
with s.
NR 811.39 (6).
(h) For non-bulk tanks, suction lines shall
extend into the tank through the tank cover. Chemical feed pumps shall be
installed at a height above the maximum liquid level in the chemical storage
tank. Flooded suctions, for bulk tanks and if necessary to prevent loss of
prime, may be approved by the department on a case-by-case basis.
(i) Adequate means of draining tanks shall be
provided, but there may be no direct connection between any drain piping and a
sanitary sewer. Chemicals shall not be discharged directly to a storm sewer.
Drain piping shall terminate at least 2 pipe diameters, but not less than 3
inches, above the overflow rim of a receiving sump, conduit or waste
receptacle.
(j) Overflow pipes, if
provided, shall be turned downward, provided with a 24-mesh corrosion resistant
screen, have a free air break discharge, and be located in a conspicuous
location.
(k) If subsurface
locations for solution or storage tanks are approved by the department, the
tanks shall be free from sources of possible contamination and located to
assure positive drainage for groundwater, accumulated water, chemical spills,
and overflows.
(l) Chemicals shall
be stored in accordance with the following requirements:
1. Each chemical shall be provided with its
own secondary leakage containment.
2. Each of the following chemicals shall be
stored in a separate room with no other chemicals:
a. Fluoride.
b. Ammonia.
c. Powders.
d. Gases.
(m) All buried chemical solution lines and
gas lines shall be installed within protective conduit piping. Each chemical
solution line shall be placed in its own protective conduit piping.
Note: When the chemical feed equipment will
not be installed near the point of chemical application it is recommended that
chemical solution piping be installed within protective conduit from the
chemical feed equipment to the point of chemical application.
(n) Gases from feeders, storage, and
equipment exhausts shall be conveyed to the exterior of the building above
grade and remote from air intakes to reduce the health and safety risk to
operators and reduce corrosion of equipment and facilities from chemical
vapors. Chemical vapor ventilation systems shall meet the following
requirements as applicable:
1. Fluoride and
ammonia liquid storage tanks shall be vented to the exterior of the building
but not through vents in common with day tanks.
2. Chemical tank vents, when provided, shall
be vented to the exterior of the building and terminate downward facing with a
24-mesh corrosion resistant screen. The tank vent shall terminate as high as
practical, but a minimum of 24 inches above surrounding grade.
(o) Permanent signs identifying
the chemical for each fill tube shall be posted at chemical offloading areas.
Permanent signs identifying the tank contents shall be posted adjacent to or on
chemical storage tanks.
(p)
Compliance with local, state, and federal safety codes, including department of
safety and professional services and OSHA codes, for other applicable chemical
safety and handling requirements is required.
(2) HANDLING FACILITIES. Handling facilities
shall meet the following requirements:
(a)
Equipment shall be provided for measuring quantities of chemicals used to
prepare feed solutions.
(b) Piping
for chemicals shall be compatible with the chemical being conveyed.
(c) The following equipment shall be provided
for each installation where chemicals are handled:
1. Where the eyes or body of any person may
be exposed to injurious corrosive materials, suitable facilities for quick
drenching or flushing of the eyes and body shall be provided as required in s.
SPS 332.15.
2.
Rubber gloves, protective clothing, and safety goggles that form a tight seal
with the face shall be provided for each operator who prepares chemical
solutions.
3. A dust respirator of
the prescribed type shall be provided for handling dry chemicals if required in
the respective material safety data sheet or s.
SPS 332.15.
(d) Provision shall be made for the transfer
of dry chemicals from shipping containers to storage bins or hoppers in such a
way as to minimize the quantity of dust generated. Control shall be provided by
use of one of the following:
1. Vacuum
pneumatic equipment or closed conveyor systems.
2. Facilities for emptying shipping
containers in special containers.
3. Exhaust fans and dust filters which place
the hoppers or bins under negative pressure.
(e) Carts, elevators, or other appropriate
means shall be provided for lifting chemical containers to minimize lifting by
operators.
(f) Electrical equipment
shall be used which will prevent explosions, particularly when using sodium
chlorite and activated carbon. Equipment shall comply with ch. SPS
316.
(g) Procedures for disposing
of empty bags, drums, carboys, or barrels shall minimize exposure to dusts or
chemicals.
(h) Acids shall be kept
in closed, acid-resistant shipping containers, or storage units. Transfer from
shipping containers to solution or day tanks shall be through acid resistant
hose or pipe by means of a transfer pump.
(3) CHEMICALS. All chemicals used to treat or
produce potable water shall meet the following requirements:
(a) Shipping containers shall be fully
labeled to include chemical name, purity, applicable NSF/ANSI standard approval
in conformance with par. (b), concentration and supplier name and
address.
(b) Chemicals shall meet
the requirements of s.
NR 810.09 (1).