(1) MONITORING REQUIREMENTS FOR GROSS ALPHA
PARTICLE ACTIVITY, RADIUM-226, RADIUM-228 AND URANIUM.
(a)
Detection limits. For
the purposes of monitoring for gross alpha particle activity, radium-226,
radium-228, uranium and beta particle and photon radioactivity in drinking
water, "detection limit" is defined in s.
NR 809.52(4).
(b)
Applicability and sampling
location. Community water system applicability and sampling location
requirements shall be as follows:
1.
Applicability and sampling location for existing community water systems or
sources. All water suppliers for existing community water systems shall sample
at every entry point to the distribution system that is representative of all
sources being used, under normal operating conditions. The water supplier shall
take each sample at the same location unless conditions make another location
more representative of each source or the department has designated a
distribution system location, in accordance with par. (c) 2. c.
2. Applicability and sampling location for
new community water systems or sources. Water suppliers for all new community
water systems or community water systems that use a new source of water shall
begin to conduct initial monitoring for the new source within the first quarter
after initiating use of the source. Water suppliers shall conduct more frequent
monitoring when ordered by the department in the event of possible
contamination or when changes in the distribution system or treatment processes
occur which may increase the concentration of radionuclides in finished
water.
(c)
Initial monitoring. Water suppliers for community water
systems shall conduct initial monitoring for gross alpha particle activity,
radium-226, radium-228 and uranium as follows:
1. Except as provided in subd. 2., water
suppliers shall collect 4 consecutive quarterly samples at all sampling points
before December 31, 2007.
2. As an
alternative to the requirement of subd. 1., water suppliers may use historical
monitoring data collected at a sampling point to satisfy the initial monitoring
requirements for that sampling point for the following situations:
a. To satisfy initial monitoring
requirements, a water supplier for a community water system having only one
entry point to the distribution system may use the monitoring data from the
last compliance monitoring period that began between June 1, 2000 and December
8, 2003.
b. To satisfy initial
monitoring requirements, a water supplier for a community water system with
multiple entry points and having appropriate historical monitoring data for
each entry point to the distribution system may use the monitoring data from
the last compliance monitoring period that began between June 1, 2000 and
December 8, 2003.
c. To satisfy
initial monitoring requirements, a water supplier for a community water system
with appropriate historical data for a representative point in the distribution
system may use the monitoring data from the last compliance monitoring period
that began between June 1, 2000 and December 8, 2003, provided that the
department finds that the historical data satisfactorily demonstrate that each
entry point to the distribution system is expected to be in compliance based
upon the historical data and reasonable assumptions about the variability of
contaminant levels between entry points. The department shall make a written
finding indicating how the data conforms to these requirements.
3. For gross alpha particle
activity, uranium, radium-226 and radium-228 monitoring, the department may
waive the final 2 quarters of initial monitoring for a sampling point if the
results of the samples from the previous 2 quarters are below the detection
limit.
4. If the average of the
initial monitoring results for a sampling point is above the MCL, the water
supplier for a community water system shall collect and analyze quarterly
samples at that sampling point until the water supplier has results from 4
consecutive quarters that are at or below the MCL, unless the water supplier
enters into another schedule as part of a formal compliance agreement with the
department.
(d)
Reduced monitoring. Upon completion of initial monitoring the
department may allow monitoring once every 3 years, once every 6 years, or once
every 9 years, for each sampling point based on the following criteria:
1. If the average of the initial monitoring
results for each contaminant, i.e., gross alpha particle activity, uranium,
radium-226 or radium-228, is below the detection limit specified in s.
NR 809.52(2), Table O, the water
supplier for a community water system shall collect and analyze for that
contaminant using at least one sample at that sampling point every 9
years.
2. For gross alpha particle
activity and uranium, if the average of the initial monitoring results for each
contaminant is at or above the detection limit but at or below one-half the
MCL, the water supplier for a community water system shall collect and analyze
for that contaminant using at least one sample at that sampling point every 6
years. For combined radium-226 and radium-228, the analytical results shall be
combined. If the average of the combined initial monitoring results for
radium-226 and radium-228 is at or above the detection limit but at or below
one-half the MCL, the water supplier for a community water system shall collect
and analyze for that contaminant using at least one sample at that sampling
point every 6 years.
3. For gross
alpha particle activity and uranium, if the average of the initial monitoring
results for each contaminant is above one-half the MCL but at or below the MCL,
the water supplier for a community water system shall collect and analyze at
least one sample at that sampling point every 3 years. For combined radium-226
and radium-228, the analytical results shall be combined. If the average of the
combined initial monitoring results for radium-226 and radium-228 is above
one-half the MCL, but at or below the MCL, the water supplier for a community
water system shall collect and analyze at least one sample at that sampling
point every 3 years.
4. Results of
samples collected during a reduced monitoring period shall be used to determine
the monitoring frequency for subsequent monitoring periods.
5. If a community water system has a
monitoring result that exceeds the MCL while on reduced monitoring, the water
supplier for a community water system shall collect and analyze quarterly
samples at that sampling point until the community water system has results
from 4 consecutive quarters that are below the MCL, unless the water supplier
for a community water system enters into another schedule as part of a formal
compliance agreement with the department.
(e)
Compositing. To fulfill
quarterly monitoring requirements for gross alpha particle activity,
radium-226, radium-228 or uranium, a water supplier for a community water
system may composite up to 4 consecutive quarterly samples from a single entry
point if analysis is done within a year of the first sample. The department
will treat analytical results from the composited results as the average
analytical result to determine compliance with the MCLs and the future
monitoring frequency. If the analytical result from the composited sample is
greater than one-half the MCL, the department may direct the water supplier to
take additional quarterly samples before allowing the water supplier to sample
under a reduced monitoring schedule.
(f)
Gross alpha particle activity
measurement substitutions. A gross alpha particle activity measurement
may be substituted for the required radium-226 measurement provided that the
measured gross alpha particle activity does not exceed 5 pCi/l. A gross alpha
particle activity measurement may be substituted for the required uranium
measurement provided that the measured gross alpha particle activity does not
exceed 15 pCi/l. The gross alpha measurement shall have a confidence interval
of 95% confidence level, 1.65 ó where ó is the standard deviation
of the net counting rate of the sample for radium-226 and uranium. When a water
supplier for a community water system uses a gross alpha particle activity
measurement in lieu of a measurement for radium-226 or uranium, or both, the
gross alpha particle activity analytical result shall be used to determine the
future monitoring frequency for radium-226 or uranium, or both. If the gross
alpha particle activity result is less than detection, one-half the detection
limit shall be used to determine compliance and the future monitoring
frequency.
(2)
MONITORING REQUIREMENTS FOR BETA PARTICLE AND PHOTON RADIOACTIVITY. To
determine compliance with the maximum contaminant levels in s.
NR 809.51 for beta particle and photon radioactivity, a
water supplier for a community water system shall monitor at a frequency as
follows:
(a) Community water systems
designated by the department as vulnerable, shall be sampled for beta particle
and photon radioactivity. Water suppliers for community water systems shall
collect quarterly samples for beta emitters and annual samples for tritium and
strontium-90 at each entry point to the distribution system, no later than one
quarter after being notified by the department. Community water systems already
designated by the department shall continue to be sampled until the department
reviews and either reaffirms or removes the designation.
1. If the gross beta particle activity minus
the naturally occurring potassium-40 beta particle activity at an entry point
has a running annual average, computed quarterly, less than or equal to 50
pCi/l, the department may reduce the frequency of monitoring at that entry
point to once every 3 years. Water suppliers for community water systems shall
collect all samples required in this subsection during the reduced monitoring
period.
2. For community water
systems in the vicinity of a nuclear facility, the department may allow the
water supplier for the community water system to utilize environmental
surveillance data collected by the nuclear facility in lieu of monitoring at
the community water system's entry points, if the department determines that
the data is applicable to a particular community water system. If there is a
release from a nuclear facility, water suppliers for community water systems
which are using surveillance data shall begin monitoring at the community water
system's entry points in accordance with this subsection.
3. At the discretion of the department, water
suppliers for the community water systems utilizing only groundwater may be
required to monitor for manmade radioactivity.
(b) Water suppliers for community water
systems designated by the department as utilizing waters contaminated by
effluents from nuclear facilities shall sample for beta particle and photon
radioactivity. Water suppliers shall collect quarterly samples for beta
emitters and iodine-131 and annual samples for tritium and strontium-90 at each
entry point to the distribution system, beginning no later than one quarter
after being notified by the department. Water suppliers for community water
systems already designated by the department as community water systems using
water contaminated by effluents from nuclear facilities shall continue to
sample until the department reviews and either reaffirms or removes the
designation.
1. Quarterly monitoring for gross
beta particle activity shall be based on the analysis of monthly samples or the
analysis of a composite of 3 monthly samples.
Note: Quarterly monitoring for gross beta
particle activity based on the analysis of monthly samples is
recommended.
2. For
iodine-131, a composite of 5 consecutive daily samples shall be analyzed once
each quarter. As ordered by the department, more frequent monitoring shall be
conducted when iodine-131 is identified in the finished water.
3. Annual monitoring for strontium-90 and
tritium shall be conducted by means of the analysis of a composite of 4
consecutive quarterly samples or analysis of 4 quarterly samples.
Note: Annual monitoring for strontium-90 and
tritium by means of the analysis of a composite of 4 consecutive quarterly
samples is recommended.
4.
If the gross beta particle activity minus the naturally occurring potassium-40
beta particle activity at a sampling point has a running annual average,
computed quarterly, less than or equal to 15 pCi/l, the department may reduce
the frequency of monitoring at that sampling point to once every 3 years. Water
suppliers for community water systems shall collect all samples required in
this paragraph during the reduced monitoring period.
5. For community water systems in the
vicinity of a nuclear facility, the department may allow the water supplier for
community water system to utilize environmental surveillance data collected by
the nuclear facility in lieu of monitoring at the community water system's
entry points, if the department determines that the data is applicable to a
particular community water system. If there is a release from a nuclear
facility, water suppliers for community water systems which are using
surveillance data shall begin monitoring at the community water system's entry
points in accordance with this paragraph.
(c) Water suppliers for community water
systems designated by the department to monitor for beta particle and photon
radioactivity may not apply to the department for a waiver from the monitoring
frequencies specified in either par. (a) or (b).
(d) Water suppliers for community water
systems may analyze for naturally occurring potassium-40 beta particle activity
from the same or equivalent sample used for the gross beta particle activity
analysis. Water suppliers for community water systems may subtract the
potassium-40 beta particle activity value from the total gross beta particle
activity value to determine if 50 pCi/l is exceeded. The potassium-40 beta
particle activity shall be calculated by multiplying elemental potassium
concentrations, in mg/l, by a factor of 0.82.
(e) If the gross beta particle activity minus
the naturally occurring potassium-40 beta particle activity exceeds 50 pCi/l,
an analysis of the sample shall be performed to identify the major radioactive
constituents present in the sample and the appropriate doses shall be
calculated and summed to determine compliance with s.
NR 809.51(1) using the formula in s.
NR 809.51(2). Doses shall also be
calculated and combined for measured levels of tritium and strontium to
determine compliance.
(f) Water
suppliers for community water systems shall monitor monthly at the sampling
points that exceed the maximum contaminant level in s.
NR 809.51 beginning the month after the exceedance
occurs. Water suppliers shall continue monthly monitoring until the water
supplier has established, by a rolling average of 3 monthly samples, that the
MCL is being met. Water suppliers for community water systems that establish
that the MCL is being met shall return to quarterly monitoring until the
requirements in par. (a) 1. or (b) 4. are met.
(3) GENERAL MONITORING AND COMPLIANCE
REQUIREMENTS FOR RADIONUCLIDES.
(a) The
department may require more frequent monitoring than specified in subs. (1) and
(2), or may require confirmation samples at its discretion. The results of the
initial and confirmation samples shall be averaged for use in compliance
determinations.
(b) Water
suppliers for each public water system shall monitor at the time designated by
the department during each compliance period.
(c) Compliance with ss.
NR 809.50(1) and 809.51(1) shall be
determined based on the analytical results obtained at each sampling point. If
one sampling point is in violation of an MCL, the community water system is in
violation of the MCL. In addition:
1. For
community water systems monitored more than once per year, compliance with the
MCL is determined by using a running annual average calculated for each
sampling point. If the average of any sampling point is greater than the MCL,
the community water system is out of compliance with the MCL.
2. For community water systems monitored more
than once per year, if any sample result will cause the running annual average
to exceed the MCL at any sample point, the community water system is out of
compliance with the MCL immediately.
3. For community water systems on reduced
monitoring where monitoring results exceed an MCL, and a community water system
is placed on quarterly monitoring as required by sub. (1) (d) 5., compliance
with the MCL is determined based on a running annual average at each sample
point, as required by sub. (3) (c) 1. if sample results exceed the
MCL.
4. Water suppliers for
community water systems shall include all samples taken and analyzed under this
section in determining compliance, even if that number is greater than the
minimum required.
5. If a water
supplier for a community water system does not collect all required samples
when compliance is based on a running annual average of quarterly samples,
compliance shall be based on the running average of the samples
collected.
6. If a sample result is
less than the detection limit, zero will be used to calculate the annual
average, unless a gross alpha particle activity is being used in lieu of
radium-226 or uranium, or both. If the gross alpha particle activity result is
less than detection, 1/2 the detection limit shall be used to calculate the
annual average.
(d) The
department may delete results of obvious sampling or analytic
errors.