(3) A tank, surface impoundment or container
is exempt from the standards in ss.
NR 664.1084 to 664.1087, as applicable, provided
that the waste management unit is one of the following:
(a) A tank, surface impoundment or container
for which all hazardous waste entering the unit has an average VO concentration
at the point of waste origination of less than 500 parts per million by weight
(ppmw). Determine the average VO concentration using the procedures in s.
NR 664.1083(1). Review and update, as
necessary, this determination at least once every 12 months following the date
of the initial determination for the hazardous waste streams entering the
unit.
(b) A tank, surface
impoundment or container for which the organic content of all the hazardous
waste entering the waste management unit has been reduced by an organic
destruction or removal process that achieves any one of the following
conditions:
1. A process that removes or
destroys the organics contained in the hazardous waste to a level such that the
average VO concentration of the hazardous waste at the point of waste treatment
is less than the exit concentration limit (Ct) established for the process.
Determine the average VO concentration of the hazardous waste at the point of
waste treatment and the exit concentration limit for the process using the
procedures in s.
NR 664.1083(2).
2. A process that removes or destroys the
organics contained in the hazardous waste to a level such that the organic
reduction efficiency (R) for the process is equal to or greater than 95%, and
the average VO concentration of the hazardous waste at the point of waste
treatment is less than 100 ppmw. Determine the organic reduction efficiency for
the process and the average VO concentration of the hazardous waste at the
point of waste treatment using the procedures in s.
NR 664.1083(2).
3. A process that removes or destroys the
organics contained in the hazardous waste to a level such that the actual
organic mass removal rate (MR) for the process is equal to or greater than the
required organic mass removal rate (RMR) established for the process. Determine
the required organic mass removal rate and the actual organic mass removal rate
for the process using the procedures in s.
NR 664.1083(2).
4. A biological process that destroys or
degrades the organics contained in the hazardous waste, such that any of the
following conditions is met:
a. The organic
reduction efficiency (R) for the process is equal to or greater than 95%, and
the organic biodegradation efficiency (Rbio) for the process is equal to or
greater than 95%. Determine the organic reduction efficiency and the organic
biodegradation efficiency for the process using the procedures in s.
NR 664.1083(2).
b. The total actual organic mass
biodegradation rate (MRbio) for all hazardous waste treated by the process is
equal to or greater than the required organic mass removal rate (RMR).
Determine the required organic mass removal rate and the actual organic mass
biodegradation rate for the process using the procedures in s.
NR 664.1083(2).
5. A process that removes or destroys the
organics contained in the hazardous waste and meets all of the following
conditions:
a. From the point of waste
origination through the point where the hazardous waste enters the treatment
process, the hazardous waste is managed continuously in waste management units
which use air emission controls according to the standards in ss.
NR 664.1084 to 664.1087, as applicable to the waste
management unit.
b. From the point
of waste origination through the point where the hazardous waste enters the
treatment process, any transfer of the hazardous waste is accomplished through
continuous hard-piping or other closed system transfer that does not allow
exposure of the waste to the atmosphere. A drain system that meets 40 CFR part
63, subpart RR-National Emission Standards for Individual Drain Systems is a
closed system.
c. The average VO
concentration of the hazardous waste at the point of waste treatment is less
than the lowest average VO concentration at the point of waste origination
determined for each of the individual waste streams entering the process or 500
ppmw, whichever value is lower. Determine the average VO concentration of each
individual waste stream at the point of waste origination using the procedures
in s.
NR 664.1083(1). Determine the average VO
concentration of the hazardous waste at the point of waste treatment using the
procedures in s.
NR 664.1083(2).
6. A process that removes or destroys the
organics contained in the hazardous waste to a level such that the organic
reduction efficiency (R) for the process is equal to or greater than 95% and
the owner or operator certifies that the average VO concentration at the point
of waste origination for each of the individual waste streams entering the
process is less than 10,000 ppmw. Determine the organic reduction efficiency
for the process and the average VO concentration of the hazardous waste at the
point of waste origination using the procedures in s.
NR 664.1083(2) and
(1), respectively.
7. A hazardous waste incinerator for which
any of the following conditions has been met:
a. The owner or operator has been issued an
operating license under ch. NR 670 which implements subch. O.
b. The owner or operator has designed and
operates the incinerator according to the interim license requirements of
subch. O of ch. NR 665.
8. A boiler or industrial furnace for which
any of the following conditions has been met:
a. The owner or operator has been issued an
operating license under ch. NR 670 which implements subch. H of ch. NR
666.
b. The owner or operator has
designed and operates the boiler or industrial furnace according to the interim
license requirements of subch. H of ch. NR 666.
9. For the purpose of determining the
performance of an organic destruction or removal process according to subds. 1.
to 6., the owner or operator shall account for VO concentrations determined to
be below the limit of detection of the analytical method using the following VO
concentration:
a. If Method 25D in appendix A
of 40 CFR part 60, incorporated by reference in s.
NR 660.11, is used for the analysis, one-half the blank
value determined in the method at section 4.4, or a value of 25 ppmw, whichever
is less.
b. If any other analytical
method is used, one-half the sum of the limits of detection established for
each organic constituent in the waste that has a Henry's law constant value at
least 0.1 mole-fraction-in-the-gas-phase/mole-fraction-in-the-liquid-phase (0.1
Y/X) [which can also be expressed as 1.8 x 10-6 atmospheres/gram-mole/m 3] at
25°C.
(c)
A tank or surface impoundment used for biological treatment of hazardous waste
according to par. (b) 4.
(d) A
tank, surface impoundment or container for which all hazardous waste placed in
the unit meets any of the following conditions:
1. The waste meets the numerical
concentration limits for organic hazardous constituents, applicable to the
hazardous waste, as specified in ch. NR 668- Hazardous Waste Land Disposal
Restrictions under Table "Treatment Standards for Hazardous Waste" in s.
NR 668.40.
2.
The organic hazardous constituents in the waste have been treated by the
treatment technology established by the department for the waste in s.
NR 668.42(1), or have been removed or
destroyed by an equivalent method of treatment approved by EPA pursuant to
40 CFR
268.42(b).
(e) A tank used for bulk feed of
hazardous waste to a waste incinerator and all of the following conditions are
met:
1. The tank is located inside an
enclosure vented to a control device that is designed and operated according to
all applicable requirements in 40 CFR part 61, subpart FF-National Emission
Standards for Benzene Waste Operations, for a facility at which the total
annual benzene quantity from the facility waste is equal to or greater than 10
megagrams per year.
2. The
enclosure and control device serving the tank were installed and began
operation prior to June 1, 1998.
3.
The enclosure is designed and operated according to the criteria for a
permanent total enclosure in Method 204- "Criteria for and Verification of a
Permanent or Temporary Total Enclosure" of appendix M of 40 CFR part 51, incorporated by reference in s.
NR 660.11. The enclosure may have permanent or temporary
openings to allow worker access, passage of material into or out of the
enclosure by conveyor, vehicles or other mechanical or electrical equipment or
to direct air flow into the enclosure. Perform the verification procedure for
the enclosure in Section 8 of Method 204 annually.