Wisconsin Administrative Code
Department of Natural Resources
NR 400-499 - Environmental Protection - Air Pollution Control
Chapter NR 440 - Standards of performance for new stationary sources
Subchapter II - Standards of Performance
Section NR 440.54 - Phosphate rock plants
Universal Citation: WI Admin Code ยง NR 440.54
Current through August 26, 2024
(1) APPLICABILITY AND DESIGNATION OF AFFECTED FACILITY.
(a) The provisions of this section
are applicable to the following affected facilities used in phosphate rock
plants which have a maximum plant production capacity greater than 3.6
megagrams per hour (4 tons/hr): dryers, calciners, grinders, and ground rock
handling and storage facilities, except those facilities producing or preparing
phosphate rock solely for consumption in elemental phosphorus
production.
(b) Any facility under
par. (a) which commences construction, modification or reconstruction after
September 21, 1979, is subject to the requirements of this section.
(2) DEFINITIONS. As used in this section, terms not defined in this subsection have the meanings given in s. NR 440.02.
(a)
"Beneficiation" means the process of washing the rock to remove impurities or
to separate size fractions.
(b)
"Calciner" means a unit in which the moisture and organic matter of phosphate
rock is reduced within a combustion chamber.
(c) "Dryer" means a unit in which the
moisture content of phosphate rock is reduced by contact with a heated gas
stream.
(d) "Grinder" means a unit
which is used to pulverize dry phosphate rock to the final product size used in
the manufacture of phosphate fertilizer and does not include crushing devices
used in mining.
(e) "Ground
phosphate rock handling and storage system" means a system which is used for
the conveyance and storage of ground phosphate rock from grinders at phosphate
rock plants.
(f) "Phosphate rock
feed" means all material entering the process unit including moisture and
extraneous material as well as the following ore minerals: fluorapatite,
hydroxylapatite, chlorapatite and carbonateapatite.
(g) "Phosphate rock plant" means any plant
which produces or prepares phosphate rock product by any or all of the
following processes: mining, beneficiation, crushing, screening, cleaning,
drying, calcining and grinding.
(3) STANDARD FOR PARTICULATE MATTER.
(a) On and after the date on which the
performance test required to be conducted by s.
NR 440.08 is
completed, no owner or operator subject to the provisions of this section may
cause to be discharged into the atmosphere:
1. From any phosphate rock dryer any gases
which:
a. Contain particulate matter in excess
of 0.030 kilogram per megagram of phosphate rock feed (0.060 lb/ton),
or
b. Exhibit greater than 10%
opacity.
2. From any
phosphate rock calciner processing unbeneficiated rock or blends of
beneficiated and unbeneficiated rock, any gases which:
a. Contain particulate matter in excess of
0.12 kilogram per megagram of phosphate rock feed (0.23 lb/ton), or
b. Exhibit greater than 10%
opacity.
3. From any
phosphate rock calciner processing beneficiated rock any gases which:
a. Contain particulate matter in excess of
0.055 kilogram per megagram of phosphate rock feed (0.11 lb/ton), or
b. Exhibit greater than 10%
opacity.
4. From any
phosphate rock grinder any gases which:
a.
Contain particulate matter in excess of 0.006 kilogram per megagram of
phosphate rock feed (0.012 lb/ton), or
b. Exhibit greater than zero percent
opacity.
5. From any
ground phosphate rock handling and storage system any gases which exhibit
greater than zero percent opacity.
(4) MONITORING OF EMISSIONS AND OPERATIONS.
(a) Any owner or operator subject to the
provisions of this section shall install, calibrate, maintain and operate a
continuous monitoring system, except as provided in pars. (b) and (c), to
monitor and record the opacity of the gases discharged into the atmosphere from
any phosphate rock dryer, calciner or grinder. The span of this system shall be
set at 40% opacity.
(b) For ground
phosphate rock storage and handling systems, continuous monitoring systems for
measuring opacity are not required.
(c) The owner or operator of any affected
phosphate rock facility using a wet scrubbing emission control device will not
be subject to the requirements in par. (a), but shall install, calibrate,
maintain and operate the following continuous monitoring devices:
1. A monitoring device for the continuous
measurement of the pressure loss of the gas stream through the scrubber. The
monitoring device shall be certified by the manufacturer to be accurate within
"250 pascals ("one inch water) gauge pressure.
2. A monitoring device for the continuous
measurement of the scrubbing liquid supply pressure to the control device. The
monitoring device shall be accurate within " 5% of design scrubbing liquid
supply pressure.
(d) For
the purpose of conducting a performance test under s.
NR 440.08, the
owner or operator of any phosphate rock plant subject to the provisions of this
section shall install, calibrate, maintain and operate a device for measuring
the phosphate rock feed to any affected dryer, calciner or grinder. The
measuring device used shall be accurate to within " 5% of the mass rate over
its operating range.
(e) For the
purpose of reports required under s.
NR 440.07(3), periods of excess
emissions that shall be reported are defined as all 6-minute periods during
which the average opacity of the plume from any phosphate rock dryer, calciner
or grinder subject to par. (a) exceeds the applicable opacity limit.
(f) Any owner or operator subject to the
requirements under par. (c) shall report on a frequency specified in s.
NR 440.07(3) all measurement results
that are less than 90% of the average levels maintained during the most recent
performance test conducted under s.
NR 440.08 in
which the affected facility demonstrated compliance with the standard under
sub. (3).
(5) TEST METHODS AND PROCEDURES.
(a) In conducting the
performance tests required in s.
NR 440.08, the
owner or operator shall use as reference methods and procedures the test
methods in Appendix A of 40 CFR part 60, incorporated by reference in s.
NR 440.17, or other methods and procedures as specified
in this subsection, except as provided for in s.
NR 440.08(2).
(b) The owner or operator shall determine
compliance with the particulate matter standards in sub. (3) as follows:
1. The emission rate (E) of particulate
matter shall be computed for each run using the following equation:
where:
E is the emission rate of particulate matter kg/Mg (lb/ton) of phosphate rock feed
cs is the concentration of particulate matter, g/dscm (g/dscf)
Qsd is the volumetric flow rate of effluent gas, dscm/hr (dscf/hr)
P is the phosphate rock feed rate, Mg/hr (ton/hr)
K is the conversion factor, 1000 g/kg (453.6 g/lb)
2. Method 5 shall be used to
determine the particulate matter concentration (cs) and
volumetric flow rate (Qsd) of the effluent gas. The
sampling time and sample volume for each run shall be at least 60 minutes and
0.85 dscm (30 dscf).
3. The device
of sub. (4) (d) shall be used to determine the phosphate rock feed rate (P) for
each run.
4. Method 9 and the
procedures in s.
NR 440.11 shall be used to determine opacity.
(c) To comply with sub. (4) (f),
if applicable, the owner or operator shall use the monitoring devices in sub.
(4) (c) 1. and 2. to determine the average pressure loss of the gas stream
through the scrubber and the average scrubbing supply pressure during the
particulate matter runs.
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