Current through August 26, 2024
(1)
APPLICABILITY.
(a) The affected facility to
which this section applies is each steam generating unit that commences
construction, modification, or reconstruction after June 19, 1984, and that has
a heat input capacity from fuels combusted in the steam generating unit of more
than 29 MW (100 million Btu/hour).
(b) Any affected facility meeting the
applicability requirements under par. (a) and commencing construction,
modification, or reconstruction after June 19, 1984, but on or before June 19,
1986, is subject to the following standards:
1. Coal-fired affected facilities having a
heat input capacity between 29 and 73 MW (100 and 250 million Btu/hour),
inclusive, are subject to the particulate matter and nitrogen oxides standards
under this section.
2. Coal-fired
affected facilities having a heat input capacity greater than 73 MW (250
million Btu/hour) and meeting the applicability requirements under s.
NR 440.19 (standards of performance for fossil fuel-fired
steam generators) are subject to the particulate matter and nitrogen oxides
standards under this section and to the sulfur dioxide standards in s.
NR 440.19(4).
3. Oil-fired affected facilities having a
heat input capacity between 29 and 73 MW (100 and 250 million Btu/hour),
inclusive, are subject to the nitrogen oxides standards in this
section.
4. Oil-fired affected
facilities having a heat input capacity greater than 73 MW (250 million
Btu/hour) and meeting the applicability requirements in s.
NR 440.19 (standards of performance for fossil fuel-fired
steam generators) are also subject to the nitrogen oxides standards in this
section and the particulate matter and sulfur dioxide standards in s.
NR 440.19(3) and (4).
(c) Affected facilities which also
meet the applicability requirements under s.
NR 440.26
(standards of performance for petroleum refineries) are subject to the
particulate matter and nitrogen oxides standards under this section and the
sulfur dioxide standards under s.
NR 440.26(5).
(d) Affected facilities which also meet the
applicability requirements in s.
NR 440.21 (standards of performance for incinerators) are
subject to the nitrogen oxides and particulate matter standards in this
section.
(e) Steam generating units
meeting the applicability requirements in s.
NR 440.20 (standards of performance for electric utility
steam generating units) are not subject to this section.
(f) Any change to an existing steam
generating unit for the sole purpose of combusting gases containing TRS as
defined in s.
NR 440.45(2) is not considered a
modification under s.
NR 440.14 and the steam generating unit is not subject to
this section.
(g) Affected
facilities which meet the applicability requirements under s.
NR 440.216(1) are not subject to this
section.
(h) Unless and until s.
NR 440.50
is revised to extend the applicability of s.
NR 440.50
to steam generator units subject to this section, this section will continue to
apply to combined cycle gas turbines that are capable of combusting more than
29 MW (100 million Btu/hour) heat input of fossil fuel in the steam generator.
Only emissions resulting from combustion of fuels in the steam generating unit
are subject to this section. (The gas turbine emissions are subject to s.
NR 440.50.)
(2) DEFINITIONS. As used in this section,
terms not defined in this subsection have the meanings given in s.
NR 440.02.
(a) "Annual
capacity factor" means the ratio between the actual heat input to a steam
generating unit from the fuels listed in sub. (3) (a), (4) (a) or (5) (a), as
applicable, during a calendar year and the potential heat input to the steam
generating unit had it been operated for 8,760 hours at the maximum steady
state design heat input capacity. In the case of steam generating units that
are rented or leased, the actual heat input shall be determined based on the
combined heat input from all operations of the affected facility in a calendar
year.
(b) "Byproducts/waste" means
any liquid or gaseous substance produced at chemical manufacturing plants,
petroleum refineries or pulp and paper mills (except natural gas, distillate
oil, or residual oil) and combusted in a steam generating unit for heat
recovery or for disposal. Gaseous substances with carbon dioxide levels greater
than 50% or carbon monoxide levels greater than 10% are not byproduct/waste for
the purposes of this section.
(c)
"Chemical manufacturing plants" means industrial plants which are classified by
the department of commerce under SIC code 28 in the Standard Industrial
Classification Manual, incorporated by reference in s.
NR 440.17.
(d) "Coal" means all solid fuels classified
as an anthracite, bituminous, subbituminous, or lignite by the American Society
for Testing and Materials in ASTM D388-99 (reapproved 2004), Standard
Specification for Classification of Coals by Rank, incorporated by reference in
s.
NR 440.17(2) (a) 12., coal refuse, and
petroleum coke. Coal-derived synthetic fuels, including but not limited to
solvent refined coal, gasified coal, coal-oil mixtures, and coal-water
mixtures, are also included in this definition for the purposes of this
section.
(e) "Coal refuse" means
any byproduct of coal mining or coal cleaning operations with an ash content
greater than 50%, by weight, and a heating value less than 13,900 kJ/kg (6,000
Btu/lb) on a dry basis.
(f)
"Combined cycle system" means a system where a separate source, such as a gas
turbine, internal combustion engine, kiln, etc., provides exhaust gas to a heat
recovery steam generating unit.
(g)
"Conventional technology" means wet flue gas desulfurization (FGD) technology,
dry FGD technology, atmospheric fluidized bed combustion technology, and oil
hydrodesulfurization technology.
(h) "Distillate oil" means fuel oils which
contai n 0.05 weight percent nitrogen or less and comply with the
specifications for fuel oils number 1 and 2, as defined by the American Society
for Testing and Materials in ASTM D396-98, Standard Specification for Fuel
Oils, incorporated by reference in s.
NR 440.17(2) (a) 13.
(i) "Dry flue gas desulfurization technology"
means a sulfur dioxide control system that is located downstream of the steam
generating unit and removes sulfur oxides from the combustion gases of the
steam generating unit by contacting the combustion gases with an alkaline
slurry or solution and forming a dry powder material. This definition includes
devices where the dry powder material is subsequently converted to another
form. Alkaline slurries or solutions used in dry flue gas desulfurization
technology include but are not limited to lime and sodium.
(j) "Duct burner" means a device that
combusts fuel and that is placed in the exhaust duct from another source, such
as a stationary gas turbine, internal combustion engine, kiln, etc., to allow
the firing of additional fuel to heat the exhaust gases before the exhaust
gases enter a heat recovery steam generating unit.
(k) "Emerging technology" means any sulfur
dioxide control system that is not defined as a conventional technology under
this subsection, and for which the owner or operator of the facility has
applied to the administrator and received approval to operate as an emerging
technology under sub. (10) (a) 4.
(m) "Fluidized bed combustion technology"
means combustion of fuel in a bed or series of beds (including but not limited
to bubbling bed units and circulating bed units) of limestone aggregate (or
other sorbent materials) in which these materials are forced upward by the flow
of combustion air and the gaseous products of combustion.
(n) "Fuel pretreatment" means a process that
removes a portion of the sulfur in a fuel before combustion of the fuel in a
steam generating unit.
(o) "Full
capacity" means operation of the steam generating unit at 90% or more of the
maximum steady-state design heat input capacity.
(p) "Heat input" means heat derived from
combustion of fuel in a steam generating unit and does not include the heat
input from preheated combustion air, recirculated flue gases, or exhaust gases
from other sources, such as gas turbines, internal combustion engines, kilns,
etc.
(q) "Heat release rate" means
the steam generating unit design heat input capacity (in MW or Btu/hour)
divided by the furnace volume (in cubic meters or cubic feet); the furnace
volume is that volume bounded by the front furnace wall where the burner is
located, the furnace side waterwall, and extending to the level just below or
in front of the first row of convection pass tubes.
(r) "Heat transfer medium" means any material
that is used to transfer heat from one point to another point.
(s) "High heat release rate" means a heat
release rate greater than 730,000 J/sec-m3 (70,000 Btu/hour-ft3).
(t) "Lignite" means a type of coal classified
as lignite A or lignite B by the American Society for Testing and Materials in
ASTM D388-99 (reapproved 2004), Standard Specification for Classification of
Coals by Rank, incorporated by reference in s.
NR 440.17(2) (a) 12.
(u) "Low heat release rate" means a heat
release rate of 730,000 J/sec-m3 (70,000 Btu/hour-ft3) or less.
(v) "Mass-feed stoker steam generating unit"
means a steam generating unit where solid fuel is introduced directly into a
retort or is fed directly onto a grate where it is combusted.
(w) "Maximum heat input capacity" means the
ability of a steam generating unit to combust a stated maximum amount of fuel
on a steady state basis, as determined by the physical design and
characteristics of the steam generating unit.
(x) "Municipal-type solid waste" means
refuse, more than 50% of which is waste consisting of a mixture of paper, wood,
yard wastes, food wastes, plastics, leather, rubber, and other combustible
materials, and noncombustible materials such as glass and rock.
(y) "Natural gas" means:
1. A naturally occurring mixture of
hydrocarbon and nonhydrocarbon gases found in geologic formations beneath the
earth's surface, of which the principal hydrocarbon constituent is methane;
or
2. Liquid petroleum gas, as
defined by the American Society for Testing and Materials in ASTM D1835-03a,
Standard Specification for Liquid Petroleum Gases, incorporated by reference in
s.
NR 440.17(2) (a) 22.
(z) "Noncontinental area" means
the state of Hawaii, the Virgin Islands, Guam, American Samoa, the commonwealth
of Puerto Rico, or the Northern Mariana Islands.
(za) "Oil" means crude oil or petroleum or a
liquid fuel derived from crude oil or petroleum, including distillate and
residual oil.
(zb) "Petroleum
refinery" means industrial plants as classified by the department of commerce
under SIC code 29 in the Standard Industrial Classification Manual,
incorporated by reference in s.
NR 440.17.
(zc) "Potential sulfur dioxide emission rate"
means the theoretical sulfur dioxide emissions (ng/J, lb/million Btu heat
input) that would result from combusting fuel in an uncleaned state and without
using emission control systems.
(zd) "Process heater" means a device that is
primarily used to heat a material to initiate or promote a chemical reaction in
which the material participates as a reactant or catalyst.
(zdm) "Pulp and paper mills" means industrial
plants which are classified under code 26 of the Standard Industrial
Classification Manual, 1987 or under code 322 of the North American Industry
Classification System, United States 2002, incorporated by reference in s.
NR 440.17(2) (i) 1. and 3.
respectively.
(ze) "Pulverized
coal-fired steam generating unit" means a steam generating unit in which
pulverized coal is introduced into an air stream that carries the coal to the
combustion chamber of the steam generating unit where it is fired in
suspension. This includes both conventional pulverized coal-fired and
micropulverized coal-fired steam generating units.
(zf) "Residual oil" means crude oil, fuel oil
numbers 1 and 2 that have a nitrogen content greater than 0.05 weight percent,
and all fuel oil numbers 4, 5 and 6, as defined by the American Society for
Testing and Materials in ASTM D396-98, Standard Specifications for Fuel Oils,
incorporated by reference in s.
NR 440.17(2) (a) 13.
(zg) "Spreader stoker steam generating unit"
means a steam generating unit in which solid fuel is introduced to the
combustion zone by a mechanism that throws the fuel onto a grate from above and
in which combustion takes place both in suspension and on the grate.
(zh) "Steam generating unit" means a device
that combusts any fuel or byproduct/waste to produce steam or to heat water or
any other heat transfer medium. This term includes any municipal-type solid
waste incinerator with a heat recovery steam generating unit or any steam
generating unit that combusts fuel and is part of a cogeneration system or a
combined cycle system. This term does not include process heaters as they are
defined in this section.
(zi)
"Steam generating unit operating day" means a 24-hour period between 12:00
midnight and the following midnight during which any fuel is combusted at
anytime in the steam generating unit. It is not necessary for fuel to be
combusted continuously for the entire 24-hour period.
(zj) "Very low sulfur oil" means an oil that
contains no more than 0.50 weight percent sulfur or that, when combusted
without sulfur dioxide emission control, has a sulfur dioxide emission rate
equal to or less than 215 ng/J (0.50 lb/million Btu) heat input.
(zk) "Wet flue gas desulfurization
technology" means a sulfur dioxide control system that is located downstream of
the steam generating unit and removes sulfur oxides from the combustion gases
of the steam generating unit by contacting the combustion gas with an alkaline
slurry or solution and forming a liquid material. This definition applies to
devices where the aqueous liquid material product of this contact is
subsequently converted to other forms. Alkaline reagents used in wet flue gas
desulfurization technology include, but are not limited to, lime, limestone,
and sodium.
(zL) "Wet scrubber
system" means any emission control device that mixes an aqueous stream or
slurry with the exhaust gases from a steam generating unit to control emissions
of particulate matter or sulfur dioxide.
(zm) "Wood" means wood, wood residue, bark,
or any derivative fuel or residue thereof, in any form, including, but not
limited to, sawdust, sanderdust, wood chips, scraps, slabs, millings, shavings,
and processed pellets made from wood or other forest residues.
(3) STANDARD FOR SULFUR DIOXIDE.
(a) Except as provided in par. (b), (c), (d),
or (j) on and after the date on which the performance test is completed or
required to be completed under s.
NR 440.08,
whichever date comes first, no owner or operator of an affected facility that
combusts coal or oil may cause to be discharged into the atmosphere any gases
that contain sulfur dioxide in excess of 10% (0.10) of the potential sulfur
dioxide emission rate (90% reduction) and that contain sulfur dioxide in excess
of the emission limit determined according to the following formula:
Es = (KaHa+ KbHb)/(Ha+ Hb)
where:
Es is the sulfur dioxide emission limit, in ng/J or
lb/million Btu heat input
Ka is 520 ng/J (or 1.2 lb/million Btu)
Kb is 340 ng/J (or 0.80 lb/million Btu)
Ha is the heat input from the combustion of coal, in J
(million Btu)
Hb is the heat input from the combustion of oil, in J
(million Btu)
Only the heat input supplied to the affected facility from
the combustion of coal and oil is counted under this subsection. No credit is
provided for the heat input to the affected facility from the combustion of
natural gas, wood, municipal-type solid waste, or other fuels or heat input to
the affected facility from exhaust gases from another source, such as gas
turbines, internal combustion engines, kilns, etc.
(b) On and after the date on which the
performance test is completed or required to be completed under s.
NR 440.08,
whichever comes first, no owner or operator of an affected facility that
combusts coal refuse alone in a fluidized bed combustion steam generating unit
may cause to be discharged into the atmosphere any gases that contain sulfur
dioxide in excess of 20% of the potential sulfur dioxide emission rate (80%
reduction) and that contain sulfur dioxide in excess of 520 ng/J (1.2
lb/million Btu) heat input. If coal or oil is fired with coal refuse, the
affected facility is subject to par. (a) or (d), as applicable.
(c) On and after the date on which the
performance test is completed or is required to be completed under s.
NR 440.08,
whichever comes first, no owner or operator of an affected facility that
combusts coal or oil, either alone or in combination with any other fuel, and
that uses an emerging technology for the control of sulfur dioxide emissions,
may cause to be discharged into the atmosphere any gases that contain sulfur
dioxide in excess of 50% of the potential sulfur dioxide emission rate (50%
reduction) and that contain sulfur dioxide in excess of the emission limit
determined according to the following formula:
E=(KcHc +
KdHd)/(Hc
+ Hd)
where:
Es is the sulfur dioxide emission limit, expressed in ng/J
or lb/million Btu heat input
Kc is 260 ng/J (or 0.60 lb/million Btu)
Kd is 170 ng/J (or 0.40 lb/million Btu)
Hc is the heat input from the combustion of coal, in J
(million Btu)
Hd is the heat input from the combustion of oil, in J
(million Btu)
Only the heat input supplied to the affected facility from
the combustion of coal and oil is counted under this subsection. No credit is
provided for the heat input to the affected facility from the combustion of
natural gas, wood, municipal-type solid waste, or other fuels, or from the heat
input to the affected facility from exhaust gases from another source, such as
gas turbines, internal combustion engines, kilns, etc.
(d) On and after the date on which the
performance test is completed or required to be completed under s.
NR 440.08,
whichever comes first, no owner or operator of an affected facility listed in
subd. 1., 2. or 3. may cause to be discharged into the atmosphere any gases
that contain sulfur dioxide in excess of 520 ng/J (1.2 lb/million Btu) heat
input if the affected facility combusts coal, or 215 ng/J (0.50 lb/million Btu)
heat input if the affected facility combusts oil other than very low sulfur
oil. Percent reduction requirements are not applicable to affected facilities
under this paragraph.
1. Affected facilities
that have an annual capacity factor for coal and oil of 30% (0.30) or less and
are subject to a federally enforceable permit limiting the operation of the
affected facility to an annual capacity factor for coal and oil to 30% (0.30)
or less;
2. Affected facilities
located in a noncontinental area; or
3. Affected facilities combusting coal or
oil, alone or in combination with any other fuel, in a duct burner as part of a
combined cycle system where 30% (0.30) or less of the heat input to the steam
generating unit is from combustion of coal and oil in the duct burner and 70%
(0.70) or more of the heat input to the steam generating unit is from the
exhaust gases entering the duct burner.
(e) Except as provided in par. (f),
compliance with the emission limits, fuel oil sulfur limits, and/or percent
reduction requirements under this subsection are determined on a 30-day rolling
average basis.
(f) Except as
provided for in par. (j) 2., compliance with the emission limits or fuel oil
sulfur limits under this subsection is determined on a 24-hour average basis
for affected facilities that:
1. Have a
federally enforceable permit limiting the annual capacity factor for oil to 10%
or less;
2. Combust only very low
sulfur oil; and
3. Do not combust
any other fuel.
(g)
Except as provided in par. (i), the sulfur dioxide emission limits and percent
reduction requirements under this subsection apply at all times, including
periods of startup, shutdown, and malfunction.
(h) Reductions in the potential sulfur
dioxide emission rate through fuel pretreatment are not credited toward the
percent reduction requirement under par. (c) unless:
1. Fuel pretreatment results in a 50% or
greater reduction in potential sulfur dioxide emissions and
2. Emissions from the pretreated fuel
(without combustion or post combustion sulfur dioxide control) are equal to or
less than the emission limits specified in par. (c).
(i) An affected facility subject to par. (a),
(b), or (c) may combust very low sulfur oil or natural gas when the sulfur
dioxide control system is not being operated because of malfunction or
maintenance of the sulfur dioxide control system.
(j) Percent reduction requirements are not
applicable to affected facilities combusting only very low sulfur oil. The
owner or operator of an affected facility combusting very low sulfur oil shall
demonstrate that the oil meets the definition of very low sulfur oil by:
1. Following the performance testing
procedures as described in sub. (6) (c) or (d), and following the monitoring
procedures as described in sub. (8) (a) or (b) to determine sulfur dioxide
emission rate or fuel oil sulfur content; or
2. Maintaining fuel receipts as described in
sub. (10) (r).
(4) STANDARD FOR PARTICULATE MATTER.
(a) On and after the date on which the
initial performance test is completed or is required to be completed under s.
NR 440.08,
whichever comes first, no owner or operator of an affected facility which
combusts coal or combusts mixtures of coal with other fuels, may cause to be
discharged into the atmosphere from that affected facility any gases which
contain particulate matter in excess of the following emission limits:
1. 22 ng/J (0.051 lb/million Btu) heat input;
a. If the affected facility combusts only
coal, or
b. If the affected
facility combusts coal and other fuels and has an annual capacity factor for
the other fuels of 10% (0.10) or less.
2. 43 ng/J (0.10 lb/million Btu) heat input
if the affected facility combusts coal and other fuels and has an annual
capacity factor for the other fuels greater than 10% (0.10) and is subject to a
federally enforceable requirement limiting operation of the affected facility
to an annual capacity factor greater than 10% (0.10) for fuels other than
coal.
3. 86 ng/J (0.20 lb/million
Btu) heat input if the affected facility combusts coal or coal and other fuels
and:
a. Has an annual capacity factor for
coal or coal and other fuels of 30% (0.30) or less,
b. Has a maximum heat input capacity of 73 MW
(250 million Btu/hour) or less,
c.
Has a federally enforceable requirement limiting operation of the affected
facility to an annual capacity factor 30% (0.30) or less for coal or coal and
other solid fuels, and
d.
Construction of the affected facility commenced after June 19, 1984 and before
November 25, 1986.
(b) On or after the date on which the
performance test is completed or required to be completed under s.
NR 440.08,
whichever date comes first, no owner or operator of an affected facility that
combusts oil, or mixtures of oil with other fuels, and uses a conventional or
emerging technology to reduce sulfur dioxide emissions may discharge into the
atmosphere from that affected facility any gases that contain particulate
matter in excess of 43 ng/J (0.10 lb/million Btu) heat input.
(c) On and after the date on which the
initial performance test is completed or is required to be completed under s.
NR 440.08,
whichever date comes first, no owner or operator of an affected facility that
combusts wood, or wood with other fuels, except coal, may cause to be
discharged from that affected facility any gases that contain particulate
matter in excess of the following emission limits:
1. 43 ng/J (0.10 lb/million Btu) heat input
if the affected facility has an annual capacity factor greater than 30% (0.30)
for wood.
2. 86 ng/J (0.20
lb/million Btu) heat input if:
a. The
affected facility has an annual capacity factor of 30% (0.30) or less for
wood,
b. Is subject to a federally
enforceable requirement limiting operation of the affected facility to an
annual capacity factor 30% (0.30) or less for wood, and:
c. Has a maximum heat input capacity of 73 MW
(250 million Btu/hour) or less.
(d) On and after the date on which the
initial performance test is completed or is required to be completed under s.
NR 440.08,
whichever date comes first, no owner or operator of an affected facility that
combusts municipal-type solid waste or mixtures of municipal-type solid waste
with other fuels, may cause to be discharged into the atmosphere from that
affected facility any gases that contain particulate matter in excess of the
following emission limits:
1. 43 ng/J (0.10
lb/million Btu) heat input if;
a. The affected
facility combusts only municipal-type solid waste, or
b. The affected facility combusts
municipal-type solid waste and other fuels and has an annual capacity factor
for the other fuels of 10% (0.10) or less.
2. 86 ng/J (0.20 lb/million Btu) heat input
if the affected facility combusts municipal-type solid waste or municipal-type
solid waste and other fuels; and
a. Has an
annual capacity factor for municipal-type solid waste and other fuels of 30%
(0.30) or less,
b. Has a maximum
heat input capacity of 73 MW (250 million Btu/hour) or less,
c. Has a federally enforceable requirement
limiting operation of the affected facility to an annual capacity factor of 30%
(0.30) for municipal-type solid waste, or municipal-type solid waste and other
fuels, and
d. Construction of the
affected facility commenced after June 19, 1984, but before November 25,
1986.
(e) For
the purposes of this subsection, the annual capacity factor is determined by
dividing the actual heat input to the steam generating unit during the calendar
year from the combustion of coal, wood, or municipal- type solid waste, and
other fuels, as applicable, by the potential heat input to the steam generating
unit if the steam generating unit had been operated for 8,760 hours at the
maximum design heat input capacity.
(f) On and after the date on which the
initial performance test is completed or is required to be completed under s.
NR 440.08,
whichever date comes first, no owner or operator of an affected facility that
combusts coal, oil, wood or mixtures of these fuels with any other fuels may
cause to be discharged into the atmosphere any gases that exhibit greater than
20% opacity (6-minute average), except for one 6-minute period per hour of not
more than 27% opacity.
(g) The
particulate matter and opacity standards apply at all times, except during
periods of startup, shutdown or malfunction.
(5) STANDARD FOR NITROGEN OXIDES.
(a) Except as provided under pars. (k) and
(L), on and after the date on which the initial performance test is completed
or is required to be completed under s.
NR 440.08,
whichever date comes first, no owner or operator of an affected facility that
is subject to the provisions of this subsection and that combusts only coal,
oil or natural gas may cause to be discharged into the atmosphere from that
affected facility any gases that contain nitrogen oxides (expressed as NO2) in
excess of the following emission limits:
Fuel/Steam Generating Unit Type
|
Nitrogen Oxide Emission Limits ng/J
(lb/million Btu)
(expressed as NO2)
Heat Input
|
1. |
Natural gas and distillate oil, except 4.: |
a. Low heat release rate |
43 (0.10) |
b. High heat release rate |
86 (0.20) |
2. |
Residual oil: |
a. Low heat release rate |
130 (0.30) |
b. High heat release rate |
170 (0.40) |
3. |
Coal: |
a. Mass-feed stoker |
210 (0.50) |
b. Spreader stoker and fluidized bed combustion
|
260 (0.60) |
c. Pulverized coal |
300 (0.70) |
d. Lignite, except e. |
260 (0.60) |
e. Lignite mined in North Dakota, South Dakota, or
Montana and combusted in a slag tap furnace |
340 (0.80) |
f. Coal-derived synthetic fuels |
210 (0.50) |
4. |
Duct burner used in a combined cycle |
ystem: |
a. Natural gas and distillate oil |
86 (0.20) |
b. Residual oil |
170 (0.40) |
(b) Except as provided under pars. (k) and
(L), on and after the date on which the initial performance test is completed
or is required to be completed under s.
NR 440.08,
whichever date comes first, no owner or operator of an affected facility that
simultaneously combusts mixtures of coal, oil or natural gas may cause to be
discharged into the atmosphere from that affected facility any gases that
contain nitrogen oxides in excess of a limit determined by use of the following
formula:
See
PDF for diagram
where:
En is the nitrogen oxides emission limit (expressed as
NO2), ng/J (lb/million Btu)
ELgo is the appropriate emission limit from the table in
par. (a) for combustion of natural gas or distillate oil, ng/J (lb/million
Btu)
Hgo is the heat input from combustion of natural gas or
distillate oil, J (million Btu)
ELro is the appropriate emission limit from the table in
par. (a) for combustion of residual oil
Hro is the heat input from combustion of residual oil, J
(million Btu)
ELc is the appropriate emission limit from the table in
par. (a) for combustion of coal
Hc is the heat input from combustion of coal, J (million
Btu)
(c) Except as provided
under par. (L), on and after the date on which the initial performance test is
completed or is required to be completed under s.
NR 440.08,
whichever comes first, no owner or operator of an affected facility that
simultaneously combusts coal or oil, or a mixture of these fuels with natural
gas, and wood, municipal-type solid waste or any other fuel may cause to be
discharged into the atmosphere any gases that contain nitrogen oxides in excess
of the emission limit for the coal or oil, or mixture of these fuels with
natural gas, combusted in the affected facility, as determined pursuant to par.
(a) or (b), unless the affected facility has an annual capacity factor for coal
or oil, or mixture of these fuels with natural gas of 10% (0.10) or less and is
subject to a federally enforceable requirement that limits operation of the
affected facility to an annual capacity factor of 10% (0.10) or less for coal,
oil or a mixture of these fuels with natural gas.
(d) On and after the date on which the
initial performance test is completed or is required to be completed under s.
NR 440.08,
whichever date comes first, no owner or operator of an affected facility that
simultaneously combusts natural gas with wood, municipal-type solid waste, or
other solid fuel, except coal, may cause to be discharged into the atmosphere
from that affected facility any gases that contain nitrogen oxides in excess of
130 ng/J (0.30 lb/million Btu) heat input unless the affected facility has an
annual capacity factor for natural gas of 10% (0.10) or less and is subject to
a federally enforceable requirement that limits operation of the affected
facility to an annual capacity factor of 10% (0.10) or less for natural
gas.
(e) Except as provided under
par. (L), on and after the date on which the initial performance test is
completed or is required to be completed under s.
NR 440.08,
whichever date comes first, no owner or operator of an affected facility that
simultaneously combusts coal, oil or natural gas with byproduct/waste may cause
to be discharged into the atmosphere from that affected facility any gases that
contain nitrogen oxides in excess of an emission limit determined by the
following formula unless the affected facility has an annual capacity factor
for coal, oil and natural gas of 10% (0.10) or less and is subject to a
federally enforceable requirement which limits operation of the affected
facility to an annual capacity factor of 10% (0.10) or less: -
See PDF for
diagram where:
En is the nitrogen oxides emission limit (expressed as
NO2), ng/J (lb/million Btu)
ELgo is the appropriate emission limit from the table in
par. (a) for combustion of natural gas or distillate oil, ng/J (lb/million
Btu)
Hgo is the heat input from combustion of natural gas,
distillate oil and gaseous byproduct/waste, J (million Btu)
ELro is the appropriate emission limit from the table in
par. (a) for combustion of residual oil, ng/J (lb/million Btu)
Hro is the heat input from combustion of residual oil or
liquid byproduct/waste, J (million Btu)
ELc is the appropriate emission limit from the table in
par. (a) for combustion of coal
Hc is the heat input from combustion of coal, J (million
Btu)
(f) Any owner or
operator of an affected facility that combusts byproduct/waste with either
natural gas or oil may petition the administrator within 180 days of the
initial startup of the affected facility to establish a nitrogen oxide emission
limit which shall apply specifically to that affected facility when the
byproduct/waste is combusted. The petition shall include sufficient and
appropriate data, as determined by the administrator, such as nitrogen oxides
emissions from the affected facility, waste composition (including nitrogen
content), and combustion conditions to allow the administrator to confirm that
the affected facility is unable to comply with the emission limits in par. (e)
and to determine the appropriate emission limit for the affected facility.
1. Any owner or operator of an affected
facility petitioning for a facility-specific nitrogen oxides emission limit
under this subsection shall:
a. Demonstrate
compliance with the emission limits in the par. (a) table for natural gas and
distillate oil or for residual oil as appropriate, by conducting a 30-day
performance test as provided in sub. (7) (e). During the performance test only
natural gas, distillate oil, or residual oil shall be combusted in the affected
facility; and
b. Demonstrate that
the affected facility is unable to comply with the emission limits in the par.
(a) table for natural gas and distillate oil or for residual oil as
appropriate, when gaseous or liquid byproduct/waste is combusted in the
affected facility under the same conditions and using the same technological
system of emission reduction applied when demonstrating compliance under subd.
1. a.
2. The nitrogen
oxides emission limits in the par. (a) table for natural gas or distillate oil
or for residual oil, as appropriate, shall be applicable to the affected
facility until and unless the petition is approved by the administrator. If the
petition is approved by the administrator, a facility-specific nitrogen oxides
emission limit will be established at the nitrogen oxides emission level
achievable when the affected facility is combusting oil or natural gas and
byproduct/waste in a manner which the administrator determines to be consistent
with minimizing nitrogen oxides emissions.
(g) Any owner or operator of an affected
facility that combusts hazardous waste, as defined by 40 CFR part 261 or 40 CFR
part 761, as in effect on July 1, 1994, with natural gas or oil may petition
the administrator within 180 days of the initial startup of the affected
facility for a waiver from compliance with the nitrogen oxides emission limit
which applies specifically to that affected facility. The petition shall
include sufficient and appropriate data, as determined by the administrator, on
nitrogen oxides emissions from the affected facility, waste destruction
efficiencies, waste composition (including nitrogen content), the quantity of
specific wastes to be combusted and combustion conditions, to allow the
administrator to determine if the affected facility is able to comply with the
nitrogen oxides emission limits required by this subsection. The owner or
operator of the affected facility shall demonstrate that when hazardous waste
is combusted in the affected facility, thermal destruction efficiency
requirements for hazardous waste specified in an applicable federally
enforceable requirement preclude compliance with the nitrogen oxides emission
limits of this subsection. The nitrogen oxides emission limits in the par. (a)
table for natural gas or distillate oil or for residual oil, as appropriate,
are applicable to the affected facility until and unless the petition is
approved by the administrator.
Note: See
40
CFR 761.70 for regulations applicable to the
incineration of materials containing polychlorinated biphenyls (PCBs).
(h) For purposes of par. (i), the
nitrogen oxide standards under this subsection apply at all times including
periods of startup, shutdown or malfunction.
(i) Except as provided under par. (j),
compliance with the emission limits under this subsection is determined on a
30-day rolling average basis.
(j)
Compliance with the emission limits under this subsection is determined on a
24-hour average basis for the initial performance test and on a 3-hour average
basis for subsequent performance tests for any affected facilities that:
1. Combust, alone or in combination, only
natural gas, distillate oil or residual oil with a nitrogen content of 0.30
weight percent or less;
2. Have a
combined annual capacity factor of 10% or less for natural gas, distillate oil
and residual oil with a nitrogen content of 0.30 weight percent or less,
and
3. Are subject to a federally
enforceable requirement limiting operation of the affected facility to the
firing of natural gas, distillate oil and/or residual oil with a nitrogen
content of 0.30 weight percent or less and limiting operation of the affected
facility to a combined annual capacity factor of 10% or less for natural gas,
distillate oil and residual oil and a nitrogen content of 0.30 weight percent
or less.
(k) Affected
facilities that meet the criteria described in par. (j) 1., 2., and 3., and
that have a heat input capacity of 73 MW (250 million Btu/hour) or less, are
not subject to the nitrogen oxides emission limits under this subsection.
(L) On and after the date on which
the initial performance test is completed or is required to be completed under
s.
NR 440.08,
whichever date comes first, no owner or operator of an affected facility which
commenced construction, modification or reconstruction after July 9, 1997 may
cause to be discharged into the atmosphere from that affected facility any
gases that contain nitrogen oxides (expressed as NO2) in excess of one of the
following limits:
1. If the affected facility
combusts coal, oil or natural gas, or a mixture of these fuels, or with any
other fuels: a limit of 86 ng/J (0.20 lb/million Btu) heat input unless the
affected facility has an annual capacity factor for coal, oil and natural gas
of 10% (0.10) or less and is subject to a federally enforceable requirement
that limits operation of the facility to an annual capacity factor of 10%
(0.10) or less for coal, oil and natural gas.
2. If the affected facility has a low heat
release rate and combusts natural gas or distillate oil in excess of 30% of the
heat input from the combustion of all fuels, a limit determined by use of the
following formula:
En = [(0.10 * Hgo) + (0.20 * Hr)]/(Hgo + Hr)
where:
En is the NOx emission limit, (lb/million Btu)
Hgo is the heat input from combustion of natural gas or
distillate oil
Hr is the heat input from combustion of any other fuel
(6)
COMPLIANCE AND PERFORMANCE TEST METHODS AND PROCEDURES FOR SULFUR DIOXIDE.
(a) The sulfur dioxide emission standards
under sub. (3) apply at all times.
(b) In conducting the performance tests
required under s.
NR 440.08, the
owner or operator shall use the cited methods and procedures in Appendix A of
40 CFR part 60, incorporated by reference in s.
NR 440.17, or the methods and procedures as specified in
this subsection, except as provided in s.
NR 440.08(2). Section
NR 440.08(6) does not apply to this
subsection. The 30-day notice required in s.
NR 440.08(4) applies only to the initial
performance test unless otherwise specified by the department.
(c) The owner or operator of an affected
facility shall conduct performance tests to determine compliance with the
percent of potential sulfur dioxide emission rate (%Ps) and the sulfur dioxide
emission rate (Es) pursuant to sub. (3) following the procedures listed below,
except as provided under par. (d).
1. The
initial performance test shall be conducted over the first 30 consecutive
operating days of the steam generating unit. Compliance with the sulfur dioxide
standards shall be determined using a 30-day average. The first operating day
included in the initial performance test shall be scheduled within 30 days
after achieving the maximum production rate at which the affected facility will
be operated, but not later than 180 days after initial startup of the
facility.
2. If only coal or only
oil is combusted, the following procedures are used:
a. The procedures in Method 19, Appendix A of
40 CFR part 60, incorporated by reference in s.
NR 440.17, shall be used to determine the hourly sulfur
dioxide emission rate (Eho) and the 30-day average emission rate (Eao). The
hourly averages used to compute the 30-day averages are obtained from the
continuous emission monitoring system of sub. (8) (a) or (b).
b. The percent of potential sulfur dioxide
emission rate (%Ps) emitted to the atmosphere is computed using the following
formula:
See
PDF for diagram
where:
%Rg is the sulfur dioxide removal efficiency of the
control device as determined by Method 19
%Rf is the sulfur dioxide removal efficiency of fuel
pretreatment as determined by Method 19
3. If coal or oil is combusted with other
fuels, the same procedures required in subd. 2. are used, except as provided in
the following:
a. An adjusted hourly sulfur
dioxide emission rate (Ehoo) is used in equation 19-19 of Method 19 to compute
an adjusted 30-day average emission rate (Eaoo). The Ehoo is computed using the
following formula:
See
PDF for diagram
where:
Ehoo is the adjusted hourly sulfur dioxide emission rate,
ng/J (lb/million Btu)
Eho is the hourly sulfur dioxide emission rate, ng/J
(lb/million Btu)
Ew is the sulfur dioxide concentration in fuels other than
coal and oil combusted in the affected facility, as determined by the fuel
sampling and analysis procedures in Method 19, ng/J (lb/million Btu). The value
Ew for each fuel lot is used for each hourly average during the time that the
lot is being combusted.
Xk is the fraction of total heat input from fuel
combustion derived from coal, oil, or coal and oil, as determined by applicable
procedures in Method 19
b.
To compute the percent of potential sulfur dioxide emission rate (%Ps), an
adjusted %Rg (%Rgo) is computed from the adjusted Eaoo from subd. 3. a. and an
adjusted average sulfur dioxide inlet rate (Eaio) using the following formula:
See
PDF for diagram
To compute Eai°, an adjusted hourly sulfur dioxide
inlet rate (Ehi°) is used. The Ehi° is computed using the following
formula:
See
PDF for diagram
where:
Ehi° is the adjusted hourly sulfur dioxide inlet rate,
ng/J (lb/million Btu)
Ehi is the hourly sulfur dioxide inlet rate, ng/J
(lb/million Btu)
4. The owner or operator of an affected
facility subject to subd. 3. does not have to measure parameters Ew or Xk if
the owner or operator elects to assume that Xk = 1.0. Owners or operators of
affected facilities who assume Xk = 1.0 shall determine %Ps, following the
procedures in subd. 2., and sulfur dioxide emissions (Es) shall be considered
to be in compliance with sulfur dioxide emission limits under sub.
(3).
5. The owner or operator of an
affected facility that qualifies under the provisions of sub. (3) (d) does not
have to measure parameters Ew or Xk under subd. 3. if the owner or operator of
the affected facility elects to measure sulfur dioxide emission rates of the
coal or oil following the fuel sampling and analysis procedures under Method
19.
(d) Except as
provided in par. (j), the owner or operator of an affected facility that
combusts only very low sulfur oil, has an annual capacity factor for oil of 10%
(0.10) or less, and is subject to a federally enforceable requirement limiting
operation of the affected facility to an annual capacity factor for oil of 10%
(0.10) or less shall:
1. Conduct the initial
performance test over 24 consecutive steam generating unit operating hours at
full load;
2. Determine compliance
with the standards after the initial performance test based on the arithmetic
average of the hourly emissions data during each steam generating unit
operating day if a continuous emission monitoring system (CEMS) is used, or
based on a daily average if Method 6B, Appendix A of 40 CFR part 60,
incorporated by reference in s.
NR 440.17, or fuel sampling and analysis procedures under
Method 19, Appendix A of 40 CFR part 60, incorporated by reference in s.
NR 440.17, are used.
(e) The owner or operator of an affected
facility subject to sub. (3) (d) 1., shall demonstrate the maximum design
capacity of the steam generating unit by operating the facility at maximum
capacity for 24 hours. This demonstration will be made during the initial
performance test and a subsequent demonstration may be requested at any other
time. If the 24-hour average firing rate for the affected facility is less than
the maximum design capacity provided by the manufacturer of the affected
facility, the 24-hour average firing rate shall be used to determine the
capacity utilization rate for the affected facility, otherwise the maximum
design capacity provided by the manufacturer shall be used.
(f) For the initial performance test required
under s.
NR 440.08,
compliance with the sulfur dioxide emission limits and percent reduction
requirements under sub. (3) is based on the average emission rates and the
average percent reduction for sulfur dioxide for the first 30 consecutive steam
generating unit operating days, except as provided under par. (d). The initial
performance test is the only test for which at least 30 days prior notice is
required unless otherwise specified by the department. The initial performance
test is to be scheduled so that the first steam generating unit operating day
of the 30 successive steam generating unit operating days is completed within
30 days after achieving the maximum production rate at which the affected
facility will be operated, but not later than 180 days after initial startup of
the facility. The boiler load during the 30-day period does not have to be the
maximum design load, but shall be representative of future operating conditions
and include at least one 24-hour period at full load.
(g) After the initial performance test
required under s.
NR 440.08,
compliance with the sulfur dioxide emission limits and percent reduction
requirements under sub. (3) is based on the average emission rates and the
average percent reduction for sulfur dioxide for 30 successive steam generating
unit operating days, except as provided under par. (d). A separate performance
test shall be completed at the end of each steam generating unit operating day
after the initial performance test, and a new 30-day average emission rate and
percent reduction for sulfur dioxide shall be calculated to show compliance
with the standard.
(h) Except as
provided under par. (i), the owner or operator of an affected facility shall
use all valid sulfur dioxide emissions data in calculating %Ps and Eho under
par. (c), whether or not the minimum emissions data requirements under sub. (7)
are achieved. All valid emissions data, including valid sulfur dioxides
emission data collected during periods of startup, shutdown and malfunctions,
shall be used in calculating %Ps and Eho pursuant to par. (c).
(i) During periods of malfunction or
maintenance of the sulfur dioxide control systems when oil is combusted as
provided under sub. (3) (i), emission data are not used to calculate %Ps or Es
under sub. (3) (a), (b) or (c). However, the emissions data are used to
determine compliance with the emission limit under sub. (3) (i).
(j) The owner or operator of an affected
facility that combusts very low sulfur oil is not subject to the compliance and
performance testing requirements of this subsection if the owner or operator
obtains fuel receipts as described in sub. (10) (r).
(7) COMPLIANCE AND PERFORMANCE TEST METHODS
AND PROCEDURES FOR PARTICULATE MATTER AND NITROGEN OXIDES.
(a) The particulate matter emission standards
and opacity limits under sub. (4) apply at all times except during periods of
startup, shutdown, or malfunction. The nitrogen oxides emission standards under
sub. (5) apply at all times.
(b)
Compliance with the particulate matter emission standards under sub. (4) shall
be determined through performance testing as described in par. (d).
(c) Compliance with the nitrogen oxides
emission standards under sub. (5) shall be determined through performance
testing under par. (e) or (f), or under pars. (g) and (h), as
applicable.
(d) To determine
compliance with the standards for particulate matter emission limits and
opacity limits under sub. (4), the owner or operator of an affected facility
shall conduct an initial performance test as required under s.
NR 440.08 using
the following procedures and reference methods. These reference methods and
procedures are in 40 CFR part 60, Appendix A, which is incorporated by
reference in s.
NR 440.17.
1. Method 3B
is used for gas analysis when applying Method 5 or Method 17.
2. Method 5, Method 5B, or Method 17 shall be
used to measure the concentration of particulate matter as follows:
a. Method 5 shall be used at affected
facilities without wet flue gas desulfurization (FGD) systems; and
b. Method 17 may be used at facilities with
or without wet scrubber systems provided the stack gas temperature does not
exceed a temperature of 160°C (320°F). The procedures of ss. 2.1 and
2.3 of Method 5B may be used in Method 17 only if it is used after a wet FGD
system. Do not use Method 17 after wet FGD systems if the effluent is saturated
or laden with water droplets.
c.
Method 5B is to be used only after wet FGD systems.
3. Method 1 is used to select the sampling
site and the number of traverse sampling points. The sampling time for each run
shall be at least 120 minutes and the minimum sampling volume is 1.7 dscm (60
dscf) except that smaller sampling times or volumes may be approved by the
department when necessitated by process variables or other factors.
4. For Method 5, the temperature of the
sample gas in the probe and filter holder is monitored and is maintained at 160
± 14°C (320 ± 25°F).
5. For determination of particulate
emissions, the oxygen or carbon dioxide sample is obtained simultaneously with
each run of Method 5, Method 5B or Method 17 by traversing the duct at the
sampling location.
6. For each run
using Method 5, Method 5B or Method 17, the emission rate expressed in
nanograms per joule heat input is determined using:
a. The oxygen or carbon dioxide measurements
and particulate matter measurements obtained under this subsection,
b. The dry basis F factor, and
c. The dry basis emission rate calculation
procedure contained in Method 19.
7. Method 9 is used for determining the
opacity of stack emissions.
(e) To determine compliance with the emission
limits for nitrogen oxides required under sub. (5), the owner or operator of an
affected facility shall conduct the performance test as required under s.
NR 440.08 using
the continuous system for monitoring nitrogen oxides under sub. (9).
1. For the initial compliance test, nitrogen
oxides from the steam generating unit shall be monitored for 30 successive
steam generating unit operating days and the 30-day average emission rate is
used to determine compliance with the nitrogen oxides emission standards under
sub. (5). The 30-day average emission rate is calculated as the average of all
hourly emissions data recorded by the monitoring system during the 30-day test
period.
2. Following the date on
which the initial performance test is completed or is required to be completed
under s.
NR 440.08,
whichever date comes first, the owner or operator of an affected facility which
combusts coal or which combusts residual oil having a nitrogen content greater
than 0.30 weight % shall determine compliance with the nitrogen oxides emission
standards under sub. (5) on a continuous basis through the use of a 30-day
rolling average emission rate. A new 30-day rolling average emission rate is
calculated each steam generating unit operating day as the average of all of
the hourly nitrogen oxides emission data for the preceding 30 steam generating
unit operating days.
3. Following
the date on which the initial performance test is completed or is required to
be completed under s.
NR 440.08,
whichever date comes first, the owner or operator of an affected facility which
has a heat input capacity greater than 73 MW (250 million Btu/hour) and which
combusts natural gas, distillate oil, or residual oil having a nitrogen content
of 0.30 weight % or less shall determine compliance with the nitrogen oxides
standards under sub. (5) on a continuous basis through the use of a 30-day
rolling average emission rate. A new 30-day rolling average emission rate is
calculated each steam generating unit operating day as the average of all of
the hourly nitrogen oxides emission data for the preceding 30 steam generating
unit operating days.
4. Following
the date on which the initial performance test is completed or required to be
completed under s.
NR 440.08,
whichever date comes first, the owner or operator of an affected facility which
has a heat input capacity of 73 MW (250 million Btu/hour) or less and which
combusts natural gas, distillate oil, or residual oil having a nitrogen content
of 0.30 weight % or less shall, upon request, determine compliance with the
nitrogen oxides standards under sub. (5) through the use of a 30-day
performance test. During periods when performance tests are not requested,
nitrogen oxides emissions data collected pursuant to sub. (9) (g) 1. or 2. are
used to calculate a 30-day rolling average emission rate on a daily basis and
used to prepare excess emission reports, but will not be used to determine
compliance with the nitrogen oxides emission standards. A new 30-day rolling
average emission rate is calculated each steam generating unit operating day as
the average of all of the hourly nitrogen oxides emission data for the
preceding 30 steam generating unit operating days.
5. If the owner or operator of an affected
facility which combusts residual oil does not sample and analyze the residual
oil for nitrogen content, as specified in sub. (10) (e), the requirements of
subd. 2. apply and the provisions of subd. 4. are inapplicable.
(f) To determine compliance with
the emission limit for NOx required by sub. (5) (a) 4. or (L) for duct burners
used in combined cycle systems, either of the procedures described in subd. 1.
or 2. may be used:
1. The owner or operator
of an affected facility shall conduct the performance test required under s.
NR 440.08 as
follows:
a. The emissions rate (E) of NOx
shall be computed using Equation 1 of this section:
E = Esg + (Hg/Hb)(E sg - Eg) Equation 1
where:
E is the emissions rate of NOx from the duct burner, ng/J
(lb/million Btu) heat input
Esg is the combined effluent emissions rate, in ng/J
(lb/million Btu) heat input using appropriate F-Factor as described in Method
19
Hg is the heat input rate to the combustion turbine, in
Joules/hour (million Btu/hour)
Hb is the heat input rate to the duct burner, in
Joules/hour (million Btu/hour)
Eg is the emissions rate from the combustion turbine, in
ng/J (lb/million Btu) heat input calculated using appropriate F-Factor as
described in Method 19
b.
Method 7E shall be used to determine the NOx concentrations. Method 3A or 3B
shall be used to determine oxygen concentration.
c. The owner or operator shall identify and
demonstrate to the department's satisfaction suitable methods to determine the
average hourly heat input rate to the combustion turbine and the average hourly
heat input rate to the affected duct burner.
d. Compliance with the emissions limits under
sub. (5) (a) 4. or (L) shall be determined by the 3-run average (nominal 1-hour
runs) for the initial and subsequent performance tests.
2. The owner or operator of an affected
facility may elect to determine compliance on a 30-day rolling average basis by
using the continuous emission monitoring system specified under sub. (9) for
measuring NOx and oxygen and meet the requirements of sub. (9). The sampling
site shall be located at the outlet from the steam generating unit. The NOx
emissions rate at the outlet from the steam generating unit shall constitute
the NOx emissions rate from the duct burner of the combined cycle
system.
(g) The owner or
operator of an affected facility described in sub. (5) (j) or (k) shall
demonstrate the maximum heat input capacity of the steam generating unit by
operating the facility at maximum capacity for 24 hours. The owner or operator
of an affected facility shall determine the maximum heat input capacity using
the heat loss method described in Sections 5 and 7.3 of the ASME Power Test
Codes 4.1, incorporated by reference in s.
NR 440.17. This demonstration of maximum heat input
capacity shall be made during the initial performance test for affected
facilities that meet the criteria of sub. (5) (j). It shall be made within 60
days after achieving the maximum production rate at which the affected facility
will be operated, but not later than 180 days after initial startup of each
facility, for affected facilities meeting the criteria of sub. (5) (k).
Subsequent demonstrations may be required by the department at any other time.
If this demonstration indicates that the maximum heat input capacity of the
affected facility is less than that stated by the manufacturer of the affected
facility, the maximum heat input capacity determined during this demonstration
shall be used to determine the capacity utilization rate for the affected
facility. Otherwise, the maximum heat input capacity provided by the
manufacturer is used.
(h) The owner
or operator of an affected facility described in sub. (5) (j) that has a heat
input capacity greater than 73 MW (250 million Btu/hour) shall:
1. Conduct an initial performance test as
required under s.
NR 440.08 over
a minimum of 24 consecutive steam generating unit operating hours at maximum
heat input capacity to demonstrate compliance with the nitrogen oxides emission
standards under sub. (5) using Method 7, 7A or 7E of 40 CFR part 60, Appendix
A, incorporated by reference in s.
NR 440.17, or other approved reference methods;
and
2. Conduct subsequent
performance tests once per calendar year or every 400 hours or operation
(whichever comes first) to demonstrate compliance with the nitrogen oxides
emission standards under sub. (5) over a minimum of 3 consecutive steam
generating unit operating hours at maximum heat input capacity using Method 7,
7A, 7E or other approved reference methods.
(8) EMISSION MONITORING FOR SULFUR DIOXIDE.
(a) Except as provided in pars. (b) and (f),
the owner or operator of an affected facility subject to the sulfur dioxide
standards under sub. (3) shall install, calibrate, maintain, and operate
continuous emission monitoring systems (CEMS) for measuring sulfur dioxide
concentrations and either oxygen (O2) or carbon dioxide (CO2) concentrations
and shall record the output of the systems. The sulfur dioxide and either
oxygen or carbon dioxide concentrations shall both be monitored at the inlet
and outlet of the sulfur dioxide control device.
(b) As an alternative to operating CEMS as
required under par. (a), an owner or operator may elect to determine the
average sulfur dioxide emissions and percent reduction by:
1. Collecting coal or oil samples in an
as-fired condition at the inlet to the steam generating unit and analyzing them
for sulfur and heat content according to Method 19 of Appendix A, 40 CFR part
60, incorporated by reference in s.
NR 440.17. Method 19 provides procedures for converting
these measurements into the format to be used in calculating the average sulfur
dioxide input rate, or
2. Measuring
sulfur dioxide according to Method 6B of Appendix A, 40 CFR part 60,
incorporated by reference in s.
NR 440.17, at the inlet or outlet to the sulfur dioxide
control system. An initial stratification test is required to verify the
adequacy of the Method 6B sampling location. The stratification test shall
consist of 3 paired runs of a suitable sulfur dioxide and carbon dioxide
measurement train operated at the candidate location and a second similar train
operated according to the procedures in Sectio n 3.2 and the applicable
procedures in Section 7 of Performance Specification 2 of Appendix B, 40 CFR
part 60, incorporated by reference in s.
NR 440.17. Method 6B, Method 6A, or a combination of
Methods 6 and 3 or 3B or Methods 6C and 3A, all in Appendix A of 40 CFR part
60, incorporated by reference in s.
NR 440.17, are suitable measurement techniques. If Method
6B is used for the second train, sampling time and timer operation may be
adjusted for the stratification test as long as an adequate sample volume is
collected; however, both sampling trains are to be operated similarly. For the
location to be adequate for Method 6B 24-hour tests, the mean of the absolute
difference between the 3 paired runs shall be less than 10%.
3. A daily sulfur dioxide emission rate, ED,
shall be determined using the procedure described in Method 6A, Sectio n 7.6.2
(equation 6A-8) and stated in ng/J (lb/million Btu) heat input.
4. The mean 30-day emission rate is
calculated using the daily measured values in ng/J (lb/million Btu) for 30
successive steam generating unit operating days using equation 19-20 of Method
19.
(c) The owner or
operator of an affected facility shall obtain emission data for at least 75% of
the operating hours in at least 22 out of 30 successive boiler operating days.
If this minimum data requirement is not met with a single monitoring system,
the owner or operator of the affected facility shall supplement the emission
data with data collected with other monitoring systems as approved by the
department or the reference methods and procedures as described in par.
(b).
(d) The 1-hour average sulfur
dioxide emission rates measured by the CEMS required by par. (a) and required
under s.
NR 440.13(8) shall be expressed in ng/J
or lb/million Btu heat input and shall be used to calculate the average
emission rates under sub. (3). Each 1-hour average sulfur dioxide emission rate
shall be based on more than 30 minutes of steam generating unit operation and
include at least 2 data points with each representing a 15-minute period.
Hourly sulfur dioxide emission rates are not calculated if the affected
facility is operated less than 30 minutes in a 1-hour period and are not
counted toward determination of a steam generating unit operating day.
(e) The procedures in s.
NR 440.13
shall be followed for installation, evaluation, and operation of the CEMS.
1. All CEMS shall be operated in accordance
with the applicable procedures under Performance Specifications 1, 2, and 3,
Appendix B, 40 CFR part 60, incorporated by reference in s.
NR 440.17.
2.
Quarterly accuracy determinations and daily calibration drift tests shall be
performed in accordance with Procedure 1 of Appendix F, 40 CFR part 60,
incorporated by reference in s.
NR 440.17.
3.
For affected facilities combusting coal or oil, alone or in combination with
other fuels, the span value of the sulfur dioxide CEMS at the inlet to the
sulfur dioxide control device shall be 125% of the maximum estimated hourly
potential sulfur dioxide emissions of the fuel combusted, and the span value of
the CEMS at the outlet to the sulfur dioxide control device shall be 50% of the
maximum estimated hourly potential sulfur dioxide emissions of the fuel
combusted.
(f) The owner
or operator of an affected facility that combusts very low sulfur oil is not
subject to the emission monitoring requirements of this subsection if the owner
or operator obtains fuel receipts as described in sub. (10) (r).
(9) EMISSION MONITORING FOR
PARTICULATE MATTER AND NITROGEN OXIDES.
(a)
The owner or operator of an affected facility subject to the opacity standard
under sub. (4) shall install, calibrate, maintain, and operate a continuous
monitoring system for measuring the opacity of emissions discharged to the
atmosphere and record the output of the system.
(b) Except as provided under pars. (g), (h)
and (i), the owner or operator of an affected facility shall comply with one of
the following:
1. Install, calibrate,
maintain and operate a continuous monitoring system, and record the output of
the system, for measuring nitrogen oxides emissions discharged to the
atmosphere.
2. If the owner or
operator has installed a nitrogen oxides emission rate continuous emission
monitoring system (CEMS) to meet the requirements of 40 CFR part 75 and is
continuing to meet the ongoing requirements of 40 CFR part 75, that CEMS may be
used to meet the requirements of this subsection, except that the owner or
operator shall also meet the requirements of sub. (10). Data reported to meet
the requirements of sub. (10) may not include data substituted using the
missing data procedures in 40 CFR part 75, subpart D, nor shall the data have
been bias adjusted according to the procedures of 40 CFR part 75.
(c) The continuous monitoring
systems required under par. (b) shall be operated and data recorded during all
periods of operation of the affected facility except for continuous monitoring
system breakdowns and repairs. Data shall be recorded during calibration
checks, and zero and span adjustments.
(d) The 1-hour average nitrogen oxides
emission rates measured by the continuous nitrogen oxides monitor required by
par. (b) and required under s.
NR 440.13
shall be expressed in ng/J or lb/million Btu heat input and shall be used to
calculate the average emission rates under sub. (5). The 1-hour averages shall
be calculated using the data points required under s.
NR 440.13(2). At least 2 data points
shall be used to calculate each 1-hour average.
(e) The procedures under s.
NR 440.13
shall be followed for installation, evaluation, and operation of the continuous
monitoring systems.
1. For affected
facilities combusting coal, wood or municipal-type solid waste, the span value
for a continuous monitoring system for measuring opacity shall be between 60
and 80%.
2. For affected facilities
combusting coal, oil, or natural gas, the span value for nitrogen oxides is
determined as follows:
Fuel
|
Span values for nitrogen oxides (ppm)
|
a. |
Natural gas |
500 |
b. |
Oil |
500 |
c. |
Coal |
1,000 |
d. |
Combination |
500 (x + y) + 1,000z |
where:
x is the fraction of total heat input derived from natural
gas
y is the fraction of total heat input derived from oil
z is the fraction of total heat input derived from coal
3. All span values
computed under subd. 2. for combusting mixtures of regulated fuels shall be
rounded to the nearest 500 PPM.
(f) When nitrogen oxides emission data are
not obtained because of continuous monitoring system breakdowns, repairs,
calibration checks and zero and span adjustments, emission data will be
obtained by using standby monitoring systems, Method 7 or 7A of Appendix A, 40
CFR part 60, incorporated by reference in s.
NR 440.17, or other approved reference methods to provide
emission data for a minimum of 75% of the operating hours in each steam
generating unit operating day, in at least 22 out of 30 successive steam
generating unit operating days.
(g)
The owner or operator of an affected facility that has a heat input capacity of
73 MW (250 million Btu/hour) or less, and which has an annual capacity factor
for residual oil having a nitrogen content of 0.30 weight % or less, natural
gas, distillate oil, or any mixture of these fuels, greater than 10% (0.10)
shall:
1. Comply with the provisions of pars.
(b), (c), (d), (e) 2., (e) 3., and (f), or
2. Monitor steam generating unit operating
conditions and predict nitrogen oxides emission rates as specified in a plan
submitted pursuant to sub. (10) (c).
(h) The owner or operator of a duct burner,
as described in sub. (2) (j), which is subject to the NOx standards of sub. (5)
(a) 4. or (L), is not required to install or operate a continuous emissions
monitoring system to measure NOx emissions.
(i) The owner or operator of an affected
facility described under sub. (5) (j) or (k) is not required to install or
operate a continuous monitoring system for measuring nitrogen oxide
emissions.
(10)
REPORTING AND RECORDKEEPING REQUIREMENTS.
(a)
The owner or operator of each affected facility shall submit notification of
the date of initial startup, as provided by s.
NR 440.07. This notification shall include:
1. The design heat input capacity of the
affected facility and identification of the fuels to be combusted in the
affected facility,
2. If
applicable, a copy of any federally enforceable requirement that limits the
annual capacity factor for any fuel or mixture of fuels under subs. (3) (d) 1.,
(4) (a) 2., 3. c., (c) 2. b., (d) 2. c., (5) (c), (d), (e), (i), (j) or (k),
(6) (d), (7) (g) or (h), or (9) (i),
3. The annual capacity factor at which the
owner or operator anticipates operating the facility based on all fuels fired
and based on each individual fuel fired, and
4. Notification that an emerging technology
will be used for controlling emissions of sulfur dioxide. The administrator
will examine the description of the emerging technology and will determine
whether the technology qualifies as an emerging technology. In making this
determination, the administrator may require the owner or operator of the
affected facility to submit additional information concerning the control
device. The affected facility is subject to the provisions of sub. (3) (a)
unless and until this determination is made by the administrator.
(b) The owner or operator of each
affected facility subject to the sulfur dioxide, particulate matter, or
nitrogen oxides emission limits under subs. (3), (4), and (5) shall submit to
the department the performance test data from the initial performance test and
the performance evaluation of the CEMS using the applicable performance
specifications in Appendix B, 40 CFR part 60, incorporated by reference in s.
NR 440.17. The owner or operator of each affected
facility described in sub. (5) (j) or (k) shall submit to the department the
maximum heat input capacity data from the demonstration of the maximum heat
input capacity of the affected facility.
(c) The owner or operator of each affected
facility subject to the nitrogen oxides standard of sub. (5) who seeks to
demonstrate compliance with those standards through the monitoring of steam
generating unit operating conditions under the provisions of sub. (9) (g) 2.
shall submit to the department for approval a plan that identifies the
operating conditions to be monitored under sub. (9) (g) 2. and the records to
be maintained under par. (j). This plan shall be submitted to the department
for approval within 360 days of the initial startup of the affected facility.
The plan shall:
1. Identify the specific
operating conditions to be monitored and the relationship between these
operating conditions and nitrogen oxides emission rates (i.e., ng/J or
lbs/million Btu heat input). Steam generating unit operating conditions
include, but are not limited to, the degree of staged combustion (i.e., the
ratio of primary air to secondary and/or tertiary air) and the level of excess
air (i.e., flue gas oxygen level);
2. Include the data and information that the
owner or operator used to identify the relationship between nitrogen oxides
emission rates and these operating conditions;
3. Identify how these operating conditions,
including steam generating unit load, will be monitored under sub. (9) (g) on
an hourly basis by the owner or operator during the period of operation of the
affected facility; the quality assurance procedures or practices that will be
employed to ensure that the data generated by monitoring these operating
conditions will be representative and accurate; and the type and format of the
records of these operating conditions, including steam generating unit load,
that will be maintained by the owner or operator under par. (j). If the plan is
approved, the owner or operator shall maintain records of predicted nitrogen
oxide emission rates and the monitored operating conditions, including steam
generating unit load, identified in the plan.
(d) The owner or operator of an affected
facility shall record and maintain records of the amounts of each fuel
combusted during each day and calculate the annual capacity factor individually
for coal, distillate oil, residual oil, natural gas, wood, and municipal-type
solid waste for the reporting period. The annual capacity factor is determined
on a 12-month rolling average basis with a new annual capacity factor
calculated at the end of each calendar month.
(e) For an affected facility that combusts
residual oil and meets the criteria under sub. (5) (j) or (k) or (7) (e) 4.,
the owner or operator shall maintain records of the nitrogen content of the
residual oil combusted in the affected facility and calculate the average fuel
nitrogen content for the reporting period. The nitrogen content shall be
determined using ASTM method D3431-80 (reapproved 1987), Test Method for Trace
Nitrogen in Liquid Petroleum Hydrocarbons, incorporated by reference in s.
NR 440.17(2) (a) 48., or fuel
specification data obtained from fuel suppliers. If residual oil blends are
being combusted, fuel nitrogen specifications may be prorated based on the
ratio of residual oils of different nitrogen content in the fuel
blend.
(f) For facilities subject
to the opacity standard under sub. (4), the owner or operator shall maintain
records of opacity.
(g) Except as
provided under par. (p), the owner or operator of an affected facility subject
to nitrogen oxides standards under sub. (5) shall maintain records of the
following information for each steam generating unit operating day:
1. Calendar date.
2. The average hourly nitrogen oxides
emission rates (expressed as NO2) (ng/J or lb/million Btu heat input) measured
or predicted.
3. The 30-day average
nitrogen oxides emission rates (ng/J or lb/million Btu heat input) calculated
at the end of each steam generating unit operating day from the measured or
predicted hourly nitrogen oxide emission rates for the preceding 30 steam
generating unit operating days.
4.
Identification of the steam generating unit operating days when the calculated
30-day average nitrogen oxides emission rates are in excess of the nitrogen
oxides emissions standards under sub. (5), with the reasons for such excess
emissions as well as a description of corrective actions taken.
5. Identification of the steam generating
unit operating days for which pollutant data have not been obtained, including
reasons for not obtaining sufficient data and a description of corrective
actions taken.
6. Identification of
the times when emission data have been excluded from the calculation of average
emission rates and the reasons for excluding data.
7. Identification of "F" factor used for
calculations, method of determination, and type of fuel combusted.
8. Identification of the times when the
pollutant concentration exceeded full span of the continuous monitoring
system.
9. Description of any
modifications to the continuous monitoring system that could affect the ability
of the continuous monitoring system to comply with Performance Specification 2
or 3 of Appendix B, 40 CFR part 60, incorporated by reference in s.
NR 440.17.
10. Results of daily CEMS drift tests and
quarterly accuracy assessments as required under 40 CFR part 60, Appendix F,
Procedure 1, incorporated by reference in s.
NR 440.17.
(h) The owner or operator of any affected
facility in any category listed in subd. 1. or 2. is required to submit excess
emission reports to the department for any excess emissions which occurred
during the reporting period.
1. Any affected
facility subject to the opacity standards under sub. (4) (f) or to the
operating parameter monitoring requirements under s.
NR 440.13(9)
(a).
2. Any affected facility which is subject to
the nitrogen oxides standard of sub. (5), and that:
a. Combusts natural gas, distillate oil, or
residual oil with a nitrogen content of 0.3 weight % or less, or
b. Has a heat input capacity of 73 MW (250
million Btu/hour) or less and is required to monitor nitrogen oxides emissions
on a continuous basis under sub. (9) (g) 1. or steam generating unit operating
conditions under sub. (9) (g) 2.
3. For the purpose of sub. (4), excess
emissions are defined as all 6-minute periods during which the average opacity
exceeds the opacity standards under sub. (4) (f).
4. For purposes of sub. (9) (g) 1., excess
emissions are defined as any calculated 30-day rolling average nitrogen oxides
emission rate, as determined under sub. (7) (e), which exceeds the applicable
emission limits in sub. (5).
(i) The owner or operator of any affected
facility subject to the continuous monitoring requirements for nitrogen oxides
under sub. (9) shall submit reports to the department containing the
information recorded under par. (g).
(j) The owner or operator of any affected
facility subject to the sulfur dioxide standards under sub. (3) shall submit
reports to the department.
(k) For
each affected facility subject to the compliance and performance testing
requirements of sub. (6) and the reporting requirement in par. (j) the
following information shall be reported to the department:
1. Calendar dates covered in the reporting
period.
2. Each 30-day average
sulfur dioxide emission rate (ng/J or lb/million Btu heat input) measured
during the reporting period, ending with the last 30-day period; reasons for
noncompliance with the emission standards; and a description of corrective
actions taken.
3. Each 30-day
average percent reduction in sulfur dioxide emissions calculated during the
reporting period, ending with the last 30-day period; reasons for noncompliance
with the emission standards; and a description of corrective actions
taken.
4. Identification of the
steam generating unit operating days that coal or oil was combusted and for
which sulfur dioxide or diluent (oxygen or carbon dioxide) data have not been
obtained by an approved method for at least 75% of the operating hours in the
steam generating unit operating day; justification for not obtaining sufficient
data; and description of corrective action taken.
5. Identification of the times when emissions
data have been excluded from the calculation of average emission rates;
justification for excluding data; and description of corrective action taken if
data have been excluded for periods other than those during which coal or oil
were not combusted in the steam generating unit.
6. Identification of "F" factor used for
calculations, method of determination, and type of fuel combusted.
7. Identification of times when hourly
averages have been obtained based on manual sampling methods.
8. Identification of the times when the
pollutant concentration exceeded full span of the CEMS.
9. Description of any modifications to the
CEMS that could affect the ability of the CEMS to comply with Performance
Specification 2 or 3 of Appendix B, 40 CFR part 60, incorporated by reference
in s.
NR 440.17.
10. Results of daily CEMS drift tests and
quarterly accuracy assessments as required under 40 CFR part 60, Appendix F,
Procedure 1, incorporated by reference in s.
NR 440.17.
11. The annual capacity factor of each fuel
fired as provided under par. (d).
(L) For each affected facility subject to the
compliance and performance testing requirements of sub. (6) (d) and the
reporting requirements of par. (j), the following information shall be reported
to the department:
1. Calendar dates when the
facility was in operation during the reporting period;
2. The 24-hour average sulfur dioxide
emission rate measured for each steam generating unit operating day during the
reporting period that coal or oil was combusted, ending in the last 24-hour
period in the quarter; reasons for noncompliance with the emission standards;
and a description of corrective actions taken;
3. Identification of the steam generating
unit operating days that coal or oil was combusted for which sulfur dioxide or
diluent (oxygen or carbon dioxide) data have not been obtained by an approved
method for at lest 75% of the operating hours; justification for not obtaining
sufficient data; and description of corrective action taken.
4. Identification of the times when emissions
data have been excluded from the calculation of average emission rates;
justification of excluding data, and description of corrective action taken if
data have been excluded for periods other than those during which coal or oil
were not combusted in the steam generating unit.
5. Identification of "F" factor used for
calculations, method of determination and type of fuel combusted.
6. Identification of times when hourly
averages have been obtained based on manual sampling methods.
7. Identification of the times when the
pollutant concentration exceeded full span of the CEMS.
8. Description of any modifications to the
CEMS which could affect the ability of the CEMS to comply with Performance
Specification 2 or 3 of Appendix B, 40 CFR part 60, incorporated by reference
in s.
NR 440.17.
9.
Results of daily CEMS drift tests and quarterly accuracy assessments as
required under 40 CFR part 60, Appendix F, Procedure 1, incorporated by
reference in s.
NR 440.17.
(m) For each affected facility subject to the
sulfur dioxide standards under sub. (3) for which the minimum amount of data
required under sub. (8) (f) were not obtained during the reporting period, the
following information is reported to the department in addition to that
required under par. (k).
1. The number of
hourly averages available for outlet emission rates and inlet emission
rates.
2. The standard deviation of
hourly averages for outlet emission rates and inlet emission rates, as
determined in Method 19, Section 7 of Appendix A, 40 CFR part 60, incorporated
by reference in s.
NR 440.17.
3.
The lower confidence limit for the mean outlet emission rate and the upper
confidence limit for the mean inlet emission rate, as calculated in Method 19,
Section 7.
4. The ratio of the
lower confidence limit for the mean outlet emission rate and the allowable
emission rate, as determined in Method 19, Section 7.
(n) If a percent removal efficiency by fuel
pretreatment (%Rf) is used to determine the overall percent reduction (%Ro)
under sub. (6), the owner or operator of the affected facility shall submit a
signed statement with the report:
1.
Indicating what removal efficiency by fuel pretreatment (%Rf) was credited
during the reporting period.
2.
Listing the quantity, heat content, and date each pretreated fuel shipment was
received during the reporting period; the name and location of the fuel
pretreatment facility; and the total quantity and total heat content of all
fuels received at the affected facility during the reporting period;
3. Documenting the transport of the fuel from
the fuel pretreatment facility to the steam generating unit.
4. Including a signed statement from the
owner or operator of the fuel pretreatment facility certifying that the percent
removal efficiency achieved by fuel pretreatment was determined in accordance
with the provisions of Method 19 of Appendix A, 40 CFR part 60, incorporated by
reference in s.
NR 440.17, and listing the heat content and sulfur
content of each fuel before and after fuel pretreatment.
(o) All records required under this
subsection shall be maintained by the owner or operator of the affected
facility for a period of 2 years following the date of the record.
(p) The owner or operator of an affected
facility described in sub. (5) (j) or (k) shall maintain records of the
following information for each steam generating unit operating day:
1. Calendar date,
2. The number of hours of operation,
and
3. A record of the hourly steam
load.
(q) The owner or
operator of an affected facility described in sub. (5) (j) or (k) shall submit
to the department a report containing all of the following:
1. The annual capacity factor over the
previous 12 months,
2. The average
fuel nitrogen content during the reporting period, if residual oil was
fired.
3. If the affected facility
meets the criteria described in sub. (5) (j), the results of any nitrogen
oxides emission tests required during the reporting period, the hours of
operation during the reporting period and the hours of operation since the last
nitrogen oxides emission test.
(r) The owner or operator of an affected
facility who elects to demonstrate that the affected facility combusts only
very low sulfur oil under sub. (3) (j) 2. shall obtain and maintain at the
affected facility fuel receipts from the fuel supplier which certify that the
oil meets the definition of distillate oil as defined in sub. (2). For the
purposes of this subsection, the oil need not meet the fuel nitrogen content
specification in the definition of distillate oil. Reports shall be submitted
to the department certifying that only very low sulfur oil meeting this
definition was combusted in the affected facility during the reporting
period.
(s) The owner or operator
of an affected facility may submit electronic quarterly reports for SO2, NOx
and opacity in lieu of submitting the written reports required under par. (h),
(i), (j), (k) or (L). The format of each quarterly electronic report shall be
coordinated with the department. The electronic report shall be submitted no
later than 30 days after the end of the calendar quarter and shall be
accompanied by a certification statement from the owner or operator, indicating
whether compliance with the applicable emission standards and minimum data
requirement of this section was achieved during the reporting period. Before
submitting reports in the electronic format, the owner or operator shall
coordinate with the department to obtain agreement to submit reports in this
alternative format.
(t) The
reporting period for the reports required under this section is each 6-month
period. All reports shall be submitted to the department and shall be
postmarked by the 30th day following the end of the reporting period.