Current through August 26, 2024
(1) APPLICABILITY AND DESIGNATION OF AFFECTED
FACILITY.
(a) The affected facility to which
this section applies is each electric utility steam generating unit:
1. That is capable of combusting more than 73
megawatts (250 million Btu/hour) heat input of fossil fuel, either alone or in
combination with any other fuel; and
2. For which construction or modification is
commenced after September 18, 1978.
(b) Unless and until s.
NR 440.50
extends the applicability of s.
NR 440.50
to electric utility steam generators, this section applies to electric utility
combined cycle gas turbines that are capable of combusting more than 73
megawatts (250 million Btu/hour) heat input of fossil fuel in the steam
generator. Only emissions resulting from combustion of fuels in the steam
generating unit are subject to this section.
Note: The gas turbine emissions are subject to s.
NR 440.50.
(c) Any change to an existing
fossil-fuel-fired steam generating unit to accommodate the use of combustible
materials, other than fossil fuels, will not bring that unit under the
applicability of this section.
(d)
Any change to an existing steam generating unit originally designed to fire
gaseous or liquid fossil fuels, to accommodate the use of any other fuel
(fossil or nonfossil) will not bring that unit under the applicability of this
section.
(2)
DEFINITIONS. As used in this section, terms not defined in this subsection have
the meanings given in s.
NR 440.02.
(a) "24-hour
period" means the period of time between 12:01 a.m. and 12:00
midnight.
(b) "Anthracite" means
coal that is classified as anthracite according to the ASTM Standard
Specification for Classification of Coals by Rank, D388-99 (reapproved 2004),
incorporated by reference in s.
NR 440.17(2) (a) 12.
(c) "Available purchase power" means the
lesser of the following:
1. The sum of
available system capacity in all neighboring companies.
2. The sum of the rated capacities of the
power interconnection devices between the principal company and all neighboring
companies, minus the sum of the electric power load on these
interconnections.
3. The rated
capacity of the power transmission lines between the power interconnection
devices and the electric generating units (the unit in the principal company
that has the malfunctioning flue gas desulfurization system and the unit or
units in the neighboring company supplying replacement electrical power) less
the electric power load on these transmission lines.
(d) "Available system capacity" means the
capacity determined by subtracting the system load and the system emergency
reserves from the net system capacity.
(e) "Boiler operating day" means a 24-hour
period during which fossil fuel is combusted in a steam generating unit for the
entire 24 hours.
(f) "Coal refuse"
means waste products of coal mining, physical coal cleaning, and coal
preparation operations (e.g. culm, gob, etc.) containing coal, matrix material,
clay, and other organic and inorganic material.
(g) "Combined cycle gas turbine" means a
stationary turbine combustion system where heat from the turbine exhaust gases
is recovered by a steam generating unit.
(gr) "Duct burner" means a device that
combusts fuel and that is placed in the exhaust duct from another source, such
as a stationary gas turbine, internal combustion engine or kiln, to allow the
firing of additional fuel to heat the exhaust gases before the exhaust gases
enter a heat recovery steam generating unit.
(h) "Electric utility combined cycle gas
turbine" means any combined cycle gas turbine used for electric generation that
is constructed for the purpose of supplying more than one-third of its
potential electric output capacity and more than 25 MW electrical output to any
utility power distribution system for sale. Any steam distribution system that
is constructed for the purpose of providing steam to a steam-electric generator
that would produce electrical power for sale is also considered in determining
the electrical energy output capacity of the affected facility.
(i) "Electric utility company" means the
largest interconnected organization, business or governmental entity that
generates electric power for sale (e.g., a holding company with operating
subsidiary companies).
(j)
"Electric utility steam generating unit" means any steam electric generating
unit that is constructed for the purpose of supplying more than one-third of
its potential electric output capacity and more than 25 MW electrical output to
any utility power distribution system for sale. Any steam supplied to a steam
distribution system for the purpose of providing steam to a steam-electric
generator that would produce electrical energy for sale is also considered in
determining the electrical energy output capacity of the affected
facility.
(k) "Emergency condition"
means that period of time when:
1. The
electric generation output of an affected facility with a malfunctioning flue
gas desulfurization system cannot be reduced or electrical output must be
increased because:
a. All available system
capacity in the principal company interconnected with the affected facility is
being operated, and
b. All
available purchase power interconnected with the affected facility is being
obtained, or
2. The
electric generation demand is being shifted as quickly as possible from an
affected facility with a malfunctioning flue gas desulfurization system to one
or more electrical generating units held in reserve by the principal company or
by a neighboring company, or
3. An
affected facility with a malfunctioning flue gas desulfurization system becomes
the only available unit to maintain a part or all of the principal company's
system emergency reserves and the unit is operated in spinning reserve at the
lowest practical electric generation load consistent with not causing
significant physical damage to the unit. If the unit is operated at a higher
load to meet load demand, an emergency condition would not exist unless the
conditions under subd. 1. apply.
(L) "Fossil fuel" means natural gas,
petroleum, coal, and any form of solid, liquid or gaseous fuel derived from
such material for the purpose of creating useful heat.
(Lm) "Gross output" means the gross useful
work performed by the steam generated. For units generating only electricity,
the gross useful work performed is the gross electrical output from the turbine
or generator set. For cogeneration units, the gross useful work performed is
the gross electrical output plus one half the useful thermal output (that is,
steam delivered to an industrial process).
(m) "Interconnected" means that 2 or more
electric generating units are electrically tied together by a network of power
transmission lines, and other power transmission equipment.
(n) "Lignite" means coal that is classified
as lignite A or B according to the ASTM Standard Specification for
Classification of Coals by Rank, D388-99 (reapproved 2004), incorporated by
reference in s.
NR 440.17(2) (a) 12.
(o) "Neighboring company" means any one of
those electric utility companies with one or more electric power
interconnections to the principal company and which have geographically
adjoining service areas.
(p) "Net
system capacity" means the sum of the net electric generating capability (not
necessarily equal to rated capacity) of all electric generating equipment owned
by an electric utility company (including steam generating units, internal
combustion engines, gas turbines, nuclear units, hydroelectric units, and all
other electric generating equipment) plus firm contractual purchases that are
interconnected to the affected facility that has the malfunctioning flue gas
desulfurization system. The electric generating capability of equipment under
multiple ownership is prorated based on ownership unless the proportional
entitlement to electric output is otherwise established by contractual
arrangement.
(q) "Potential
combustion concentration" means the theoretical emissions (ng/J, lb/million Btu
heat input) that would result from combustion of a fuel in an uncleaned state
without emission control systems) and:
1. For
particulate matter is:
a. 3,000 ng/J (7.0
lb/million Btu) heat input for solid fuel; and
b. 73 ng/J (0.17 lb/million Btu) heat input
for liquid fuels.
2. For
sulfur dioxide is determined under sub. (9) (b).
3. For nitrogen oxides is:
a. 290 ng/J (0.67 lb/million Btu) heat input
for gaseous fuels;
b. 310 ng/J
(0.72 lb/million Btu) heat input for liquid fuels; and
c. 990 ng/J (2.30 lb/million Btu) heat input
for solid fuels.
(r) "Potential electrical output capacity"
means 33% of the maximum design heat input capacity of the system generating
unit (e.g., a steam generating unit with a 100-MW (340 million Btu/hr)
fossil-fuel heat input capacity would have a 33-MW potential electrical output
capacity). For electric utility combined cycle gas turbines the potential
electrical output capacity is determined on the basis of the fossil-fuel firing
capacity of the steam generator exclusive of the heat input and electrical
power contribution by the gas turbine.
(s) "Principal company" means the electric
utility company which owns the affected facility.
(t) "Resource recovery unit" means a facility
that combusts more than 75% nonfossil fuel on a quarterly (calendar) heat input
basis.
(u) "Solid-derived fuel"
means any solid, liquid or gaseous fuel derived from solid fuel for the purpose
of creating useful heat and includes, but is not limited to, solvent refined
coal, liquified coal and gasified coal.
(v) "Spare flue gas desulfurization system
module" means a separate system of sulfur dioxide emission control equipment
capable of treating an amount of flue gas equal to the total amount of flue gas
generated by an affected facility when operated at maximum capacity divided by
the total number of nonspare flue gas desulfurization modules in the
system.
(w) "Spinning reserve"
means the sum of the unutilized net generating capability of all units of the
electric utility company that are synchronized to the power distribution system
and that are capable of immediately accepting additional load. The electric
generating capability of equipment under multiple ownership shall be prorated
based on ownership unless the proportional entitlement to electric output is
otherwise established by contractual arrangement.
(x) "Steam generating unit" means any
furnace, boiler, or other device used for combusting fuel for the purpose of
producing steam including fossil-fuel-fired steam generators associated with
combined cycle gas turbines but nuclear steam generators are not
included.
(y) "Subbituminous coal"
means coal that is classified as subbituminous A, B or C according to the ASTM
Standard Specification for Classification of Coals by Rank, D388-99 (reapproved
2004), incorporated by reference in s.
NR 440.17(2) (a) 12.
(z) "System emergency reserves" means an
amount of electric generating capacity equivalent to the rated capacity of the
single largest electric generating unit in the electric utility company
(including steam generating units, internal combustion engines, gas turbines,
nuclear units, hydroelectric units and all other electric generating equipment)
which is interconnected with the affected facility that has the malfunctioning
flue gas desulfurization system. The electric generating capability of
equipment under multiple ownership shall be prorated based on ownership unless
the proportional entitlement to electric output is otherwise established by
contractual arrangement.
(zm)
"System load" means the entire electric demand of an electric utility company's
service area interconnected with the affected facility that has the
malfunctioning flue gas desulfurization system plus firm contractual sales to
other electric utility companies. Sales to other electric utility companies
(e.g., emergency power) not on a firm contractual basis may also be included in
the system load when no available system capacity exists in the electric
utility company to which the power is supplied for sale.
(3) STANDARD FOR PARTICULATE MATTER.
(a) On and after the date on which the
performance test required to be conducted under s.
NR 440.08 is
completed, no owner or operator subject to the provisions of this section may
cause to be discharged into the atmosphere from any affected facility any gases
which contain particulate matter in excess of:
1. 13 ng/J (0.03 lb/million Btu) heat input
derived from the combustion of solid, liquid or gaseous fuel;
2. One percent of the potential combustion
concentration (99% reduction) when combusting solid fuel; and
3. 30% of potential combustion concentration
(70% reduction) when combusting liquid fuel.
(b) On and after the date the particulate
matter performance test required to be conducted under s.
NR 440.08 is
completed, no owner or operator subject to the provisions of this section may
cause to be discharged into the atmosphere from any affected facility any gases
which exhibit greater than 20% opacity (6-minute average), except for one
6-minute period per hour of not more than 27% opacity.
(4) STANDARD FOR SULFUR DIOXIDE.
(a) On and after the date on which the
initial performance test required to be conducted under s.
NR 440.08 is
completed, no owner or operator subject to the provisions of this section may
cause to be discharged into the atmosphere from any affected facility which
combusts solid fuel or solid-derived fuel, except as provided under par. (c),
(d), (f) or (h), any gases which contain sulfur dioxide in excess of:
1. 520 ng/J (1.20 lb/million Btu) heat input
and 10% of the potential combustion concentration (90% reduction), or
2. 30% of the potential combustion
concentration (70% reduction), when emissions are less than 260 ng/J (0.60
lb/million Btu) heat input.
(b) On and after the date on which the
initial performance test required to be conducted under s.
NR 440.08 is
completed, no owner or operator subject to the provisions of this section may
cause to be discharged into the atmosphere from any affected facility which
combusts liquid or gaseous fuels (except for liquid or gaseous fuels derived
from solid fuels and as provided under par. (h)), any gases which contain
sulfur dioxide in excess of:
1. 340 ng/J
(0.80 lb/million Btu) heat input and 10% of the potential combustion
concentration (90% reduction), or
2. 100% of the potential combustion
concentration (zero percent reduction) when emissions are less than 86 ng/J
(0.20 lb/million Btu) heat input.
(c) On and after the date on which the
initial performance test required to be conducted under s.
NR 440.08 is
complete, no owner or operator subject to the provisions of this section may
cause to be discharged into the atmosphere from any affected facility which
combusts solid solvent refined coal (SRC-I) any gases which contain sulfur
dioxide in excess of 520 ng/J (1.20 lb/million Btu) heat input and 15% of the
potential combustion concentration (85% reduction) except as provided under
par. (f); compliance with the emission limitation is determined on a 30-day
rolling average basis and compliance with the percent reduction requirement is
determined on a 24-hour basis.
(d)
Sulfur dioxide emissions shall be limited to no more than 520 ng/J (1.20
lb/million Btu) heat input from any affected facility which:
1. Combusts 100% anthracite, or
2. Is classified as a resource recovery
unit.
(f) The emission
reduction requirements under this subsection do not apply to any affected
facility that is operated under an SO2 commercial demonstration permit issued
by the administrator in accordance with the provisions of
40 CFR
60.47Da.
(g) Compliance with the emission limitation
and percent reduction requirements under this subsection are both determined on
a 30-day rolling average basis except as provided under par. (c).
(h) When different fuels are combusted
simultaneously, the applicable standard is determined by proration using the
following formula:
1. If emissions of sulfur
dioxide to the atmosphere are greater than 260 ng/J (0.60 lb/million Btu) heat
input:
Es = [340 x + 520 y]/100
and
%Ps = 10
2. If emissions of sulfur dioxide to the
atmosphere are equal to or less than 260 ng/J (0.60 lb/million Btu) heat input:
Es = [340 x + 520 y]/100
and
%Ps = [10 x + 30 y]/100
where:
Es is the prorated sulfur dioxide
emission limit (ng/J heat input)
%Ps is the percentage of potential
sulfur dioxide emission allowed
x is the percentage of total heat input derived from the
combustion of liquid or gaseous fuels, excluding solid-derived fuels
y is the percentage of total heat input derived from the
combustion of solid fuel, including solid-derived fuels
(5) STANDARD FOR
NITROGEN OXIDES.
(a) On and after the date on
which the initial performance test required to be conducted under s.
NR 440.08 is
completed, no owner or operator subject to the provisions of this section may
cause to be discharged into the atmosphere from any affected facility, except
as provided under pars. (b) and (d), any gases which contain nitrogen oxides,
expressed as NO2, in excess of the following emission
limits, based on a 30-day rolling average, except as provided under sub. (6)
(j) 1.:
1. NOx
emission limits.
Emission limit for heat
input
|
Fuel type
|
ng/J
|
(lb/million Btu)
|
a. |
Gaseous fuels: |
Coal-derived fuels . |
210 |
0.50 |
All other fuels . . . . |
86 |
0.20 |
b. |
Liquid fuels: |
Coal-derived fuels . |
210 |
0.50 |
Shale oil ......... |
210 |
0.50 |
All other fuels . . . . |
130 |
0.30 |
Coal-derived fuels . |
210 |
0.50 |
Any fuel containing more than 25%, by weight, coal
refuse ........ |
(1) |
(1) |
c. |
Solid fuels: |
Any fuel containing more than 25%, by weight,
lignite if the lignite is mined in North Dakota, South Dakota, or Montana, and
is combusted in a slag tap furnace2 ...... |
340 |
0.80 |
Any fuel containing more than 25%, by weight,
lignite not subject to the 340 ng/J heat input emission
limit2 ......... |
260 |
0.60 |
Subbituminous coal .......... |
210 |
0.50 |
Bituminous coal . . . |
260 |
0.60 |
Anthracite coal . . . . |
260 |
0.60 |
All other fuels . . . . |
260 |
0.60 |
1 Exempt from
NOx standards and NOx monitoring
requirements.
2 Any fuel containing less than
25%, by weight, lignite is not prorated but its percentage is added to the
percentage of the predominant fuel.
2. NOx reduction
requirements.
Percent reduction of
|
potential combustion
|
Fuel type
|
concentration
|
a. |
Gaseous fuels ........... |
25 |
b. |
Liquid fuels ............. |
30 |
c. |
Solid fuels .............. |
65 |
(b) The emission limitations under par. (a)
do not apply to any affected facility which is combusting coal-derived liquid
fuel and is operating under a commercial demonstration permit issued by the
administrator in accordance with the provisions of
40 CFR
60.47Da.
(c) Except as provided under par. (d), when 2
or more fuels are combusted simultaneously, the applicable standard is
determined by proration using the following formula:
En = [86 w + 130 x + 210 y + 260 z
+ 340 v] /100
where:
En is the applicable standard for
nitrogen oxides when multiple fuels are combusted simultaneously (ng/J heat
input)
w is the percentage of total heat input derived from the
combustion of fuels subject to the 86 ng/J heat input standard
x is the percentage of total heat input derived from the
combustion of fuels subject to the 130 ng/J heat input standard
y is the percentage of total heat input derived from the
combustion of fuels subject to the 210 ng/J heat input standard
z is the percentage of total heat input derived from the
combustion of fuels subject to the 260 ng/J heat input standard
v is the percentage of total heat input delivered from the
combustion of fuels subject to the 340 ng/J heat input standard
(d)
1. On and after the date on which the initial
performance test required to be conducted under s.
NR 440.08 is
completed, no new source owner or operator subject to the provisions of this
section may cause to be discharged into the atmosphere from any affected
facility for which construction commenced after July 9, 1997 any gases which
contain nitrogen oxides, expressed as NO2, in excess of
200 nanograms per joule (1.6 pounds per megawatt-hour) gross energy output,
based on a 30-day rolling average, except as provided under sub. (6) (k)
1.
2. On and after the date on
which the initial performance test required to be conducted under s.
NR 440.08 is
completed, no existing source owner or operator subject to the provisions of
this section may cause to be discharged into the atmosphere from any affected
facility for which construction commenced after July 9, 1997 any gases which
contain nitrogen oxides, expressed as NO2, in excess of
65 nanograms per joule (0.15 pounds per million Btu) heat input, based on a
30-day rolling average.
(6) COMPLIANCE PROVISIONS.
(a)
Percent reduction requirement for
particulate matter. Compliance with the particulate matter emission
limitation under sub. (3) (a) 1. constitutes compliance with the percent
reduction requirements for particulate matter under sub. (3) (a) 2. and
3.
(b)
Percent reduction
requirement for NOx. Compliance with the
nitrogen oxides emission limitation under sub. (5) (a) 1. constitutes
compliance with the percent reduction requirements under sub. (5) (a)
2.
(c)
Compliance
exception. The particulate matter emissions standards under sub. (3)
and the nitrogen oxides emission standards under sub. (5) apply at all times
except during periods of startup, shutdown or malfunction. The sulfur dioxide
emission standards under sub. (4) apply at all times except during periods of
startup, shutdown or when both emergency conditions exist and the procedures
under par. (d) are implemented.
(d)
Operation with malfunctioning flue gas desulfurization. During
emergency conditions in the principal company, an affected facility with a
malfunctioning flue gas desulfurization system may be operated if sulfur
dioxide emissions are minimized by:
1.
Operating all operable flue gas desulfurization system modules, and bringing
back into operation any malfunctioned module as soon as repairs are
completed.
2. Bypassing flue gases
around only those flue gas desulfurization system modules that have been taken
out of operation because they were incapable of any sulfur dioxide emission
reduction or which would have suffered significant physical damage if they had
remained in operation, and
3.
Designing, constructing and operating a spare flue gas desulfurization system
module for an affected facility larger than 365 MW (1,250 million Btu/hr) heat
input (approximately 125 MW electrical output capacity). The department may at
its discretion require the owner or operator within 60 days of notification to
demonstrate spare module capability. To demonstrate this capability, the owner
or operator shall demonstrate compliance with the appropriate requirements
under sub. (4) (a), (b), (d) and (h) for any period of operation lasting from
24 hours to 30 days when:
a. Any one flue gas
desulfurization module is not operated.
b. The affected facility is operating at the
maximum heat input rate,
c. The
fuel fired during the 24-hour to 30-day period is representative of the type
and average sulfur content of fuel used over a typical 30-day period,
and
d. The owner or operator has
given the department at least 30 days notice of the date and period of time
over which the demonstration will be performed.
(e)
Compliance after the initial
performance test. After the initial performance test required under s.
NR 440.08,
compliance with the sulfur dioxide emission limitations and percentage
reduction requirements under sub. (4) and the nitrogen oxides emission
limitations under sub. (5) shall be based on the average emission rate for 30
successive boiler operating days. A separate performance test is completed at
the end of each boiler operating day after the initial performance test, and a
new 30-day average emission rate for both sulfur dioxide and nitrogen oxides
and a new percent reduction of sulfur dioxide are calculated to show compliance
with the standards.
(f)
Initial performance test. For the initial performance test
required under s.
NR 440.08,
compliance with the sulfur dioxide emission limitations and percent reduction
requirements under sub. (4) and the nitrogen oxides emission limitation under
sub. (5) shall be based on the average emission rates for sulfur dioxide,
nitrogen oxides, and percent reduction for sulfur dioxide for the first 30
successive boiler operating days. The initial performance test is the only test
in which at least 30 days prior notice is required unless otherwise specified
by the department. The initial performance test shall be scheduled so that the
first boiler operating day of the 30 successive boiler operating days is
completed within 60 days after achieving the maximum production rate at which
the affected facility will be operated, but not later than 180 days after
initial startup of the facility.
(g)
Compliance calculations for
SO2 and NOx. Compliance
shall be determined by calculating the arithmetic average of all hourly
emission rates for SO2 and NOx
for the 30 successive boiler operating days, except for data obtained during
startup, shutdown, malfunction (NOx only) or emergency
conditions (SO2 only). Compliance with the percentage
reduction requirement for SO2 shall be determined based
on the average inlet and average outlet SO2 emission
rates for the 30 successive boiler operating days.
(h)
Quantity of emission data below
minimum. If an owner or operator has not obtained the minimum quantity
of emission data as required under sub. (7), compliance of the affected
facility with the emission requirements under subs. (4) and (5) for the day on
which the 30-day period ends may be determined by the department by following
the applicable procedures in section 7.0 of Method 19, 40 CFR part 60, Appendix
A, incorporated by reference in s.
NR 440.17.
(i)
Compliance provisions for sources
subject to sub. (5) (d) 1. The owner or operator of an affected
facility subject to sub. (5) (d) 1. (new source constructed after July 7, 1997)
shall calculate NOx emissions by multiplying the average
hourly NOx output concentration measured according to
the provisions of sub. (7) (c) by the average hourly flow rate measured
according to the provisions of sub. (7) (L) and divided by the average hourly
gross energy output measured according to the provisions of sub. (7)
(k).
(j)
Compliance
provisions for duct burners subject to sub. (5) (a) 1. To determine
compliance with the emissions limits for NOx required by
sub. (5) (a) for duct burners used in combined cycle systems, the owner or
operator of an affected duct burner shall use one of the following procedures:
1. Conduct the performance test required
under s.
NR 440.08 using
the appropriate methods in 40 CFR part 60, Appendix A, incorporated by
reference in s.
NR 440.17(1). Compliance with the
emissions limits under sub. (5) (a) 1. shall be determined on the average of 3
(nominal 1-hour) runs for the initial and subsequent performance tests. During
the performance test, one sampling site shall be located in the exhaust of the
turbine prior to the duct burner. A second sampling site shall be located at
the outlet from the heat recovery steam generating unit. Measurements shall be
taken at both sampling sites during the performance test.
2. Use the continuous emission monitoring
system specified under sub. (7) for measuring NOx and
oxygen and meet the requirements of sub. (7). Data from a CEMS certified or
recertified according to the provisions of
40 CFR
75.20, meeting the QA and QC requirements of
40 CFR
75.21, and validated according to
40 CFR
75.23, may be used. The sampling site shall
be located at the outlet from the steam generating unit. The
NOx emission rate at the outlet from the steam
generating unit shall constitute the NOx emission rate
from the duct burner of the combined cycle system.
(k)
Compliance provisions for duct
burners subject to sub. (5) (d) 1. To determine compliance with the
emissions limits for NOx required by sub. (5) (d) 1. for
duct burners used in combined cycle systems, either of the procedures described
in subd. 1. or 2. shall be used.
1.
a. Compute the emission rate (E) of
NOx using the following equation:
See
PDF for diagram
where
E is the emission rate of NOx from
the duct burner, ng/J (lb/Mwh) gross output
Csg is the average hourly
concentration of NOx exiting the steam generating unit,
ng/dscm (lb/dscf)
Cte is the average hourly
concentration of NOx in the turbine exhaust upstream
from duct burner, ng/dscm (lb/dscf)
Qsg is the average hourly
volumetric flow rate of exhaust gas from steam generating unit, dscm/hr
(dscf/hr)
Qte is the average hourly
volumetric flow rate of exhaust gas from combustion turbine, dscm/hr (dscf/hr)
Osg is the average hourly gross
energy output from steam generating unit, J (Mwh)
h is the average hourly fraction of the total heat input
to the steam generating unit derived from the combustion of fuel in the
affected duct burner
b.
Use Method 7E in 40 CFR part 60, Appendix A, incorporated by reference in s.
NR 440.17(1), to determine the
NOx concentrations (Csg and Cte). Use Method 2, 2F or 2G
in 40 CFR part 60, Appendix A, as appropriate, to determine the volumetric flow
rates (Qsg and Qte) of the exhaust gases. The volumetric flow rate measurements
shall be taken at the same time as the concentration measurements.
c. Develop, demonstrate and provide
information satisfactory to the department to determine the average hourly
gross energy output from the steam generating unit, and the average hourly
percentage of the total heat input to the steam generating unit derived from
the combustion of fuel in the affected duct burner.
d. Determine compliance with the emissions
limits under sub. (5) (d) 1. by the 3-run average (nominal 1-hour runs) for the
initial and subsequent performance tests.
2. Use a 30-day rolling average basis by
doing all of the following:
a. Compute the
emission rate (E) of NOx using the following equation:
See
PDF for diagram
where:
E is the emission rate of NOx from
the duct burner, ng/J (lb/Mwh) gross output
Csg is the average hourly
concentration of NOx exiting the steam generating unit,
ng/dscm (lb/dscf)
Qsg is the average hourly
volumetric flow rate of exhaust gas from steam generating unit, dscm/hr
(dscf/hr)
Occ is the average hourly gross energy output from entire
combined cycle unit, J (Mwh)
b. Use the continuous emissions monitoring
system specified under sub. (7) for measuring NOx and
oxygen to determine the average hourly NOx
concentrations (Csg). The continuous flow monitoring system specified in sub.
(7) (L) shall be used to determine the volumetric flow rate (Qsg) of the
exhaust gas. The sampling site shall be located at the outlet from the steam
generating unit. Data from a continuous flow monitoring system certified or
recertified following procedures specified in
40 CFR
75.20, meeting the quality assurance and
quality control requirements of
40 CFR
75.21 and validated according to
40 CFR
75.23 may be used.
c. Use the continuous monitoring system
specified under sub. (7) (k) for measuring and determining gross energy output
to determine the average hourly gross energy output from the entire combined
cycle unit (Occ), which is the combined output from the combustion turbine and
the steam generating unit.
d. The
owner or operator may, in lieu of installing, operating and recording data from
the continuous flow monitoring system specified in sub. (7) (L), determine the
mass rate (lb/hr) of NOx emissions by installing,
operating and maintaining continuous fuel flow meters following the appropriate
measurements procedures specified in 40 CFR part 75, Appendix D, incorporated
by reference in s.
NR 440.17(1). If this compliance option
is selected, the emission rate (E) of NOx shall be
computed using the following equation:
See
PDF for diagram
where:
E is the emission rate of NOx from
the duct burner, ng/J (lb/Mwh) gross output
ERsg is the average hourly emission
rate of NOx exiting the steam generating unit heat input
calculated using appropriate F-factor as described in Method 19 in 40 CFR part
60, Appendix A, incorporated by reference in s.
NR 440.17(1), ng/J (lb/million Btu)
Hcc is the average hourly heqt input rate of entire
combined cycle unit, J/hr (million Btu/hr)
Occ is the average hourly gross energy output from entire
combined cycle unit, J(Mwh)
3. When an affected duct burner steam
generating unit utilizes a common steam turbine with one or more affected duct
burner steam generating units, the owner or operator shall do one of the
following:
a. Determine compliance with the
applicable NOx emissions limits by measuring the
emissions combined with the emissions from the other units utilizing the common
steam turbine.
b. Develop,
demonstrate and provide information satisfactory to the department on methods
for apportioning the combined gross energy output from the steam turbine for
each of the affected duct burners. The department may approve a demonstrated
substitute method for apportioning the combined gross energy output measured at
the steam turbine whenever the demonstration ensures accurate estimation of
emissions regulated under this section.
(7) EMISSION MONITORING.
(a) The owner or operator of an affected
facility shall install, calibrate, maintain and operate a continuous monitoring
system, and record the output of the system, for measuring the opacity of
emissions discharged to the atmosphere, except where gaseous fuel is the only
fuel combusted. If opacity interference due to water droplets exists in the
stack (for example, from the use of a flue gas desulfurization (FGD) system),
the opacity shall be monitored upstream of the interference (at the inlet to
the FGD system). If opacity interference is experienced at all locations (both
at the inlet and outlet of the sulfur dioxide control system), alternate
parameters indicative of the particulate matter control system's performance
shall be monitored (subject to the approval of the department).
(b) The owner or operator of an affected
facility shall install, calibrate, maintain and operate a continuous monitoring
system, and record the output of the system, for measuring sulfur dioxide
emissions, except where natural gas is the only fuel combusted, as follows:
1. Sulfur dioxide emissions shall be
monitored at both the inlet and outlet of the sulfur dioxide control
device.
2. For a facility which
qualifies under the provisions of sub. (4) (d), sulfur dioxide emissions shall
only be monitored as discharged to the atmosphere.
3. An "as fired" fuel monitoring system
(upstream of coal pulverizers) meeting the requirements of Method 19, 40 CFR
part 60, Appendix A, incorporated by reference in s.
NR 440.17, may be used to determine potential sulfur
dioxide emissions in place of a continuous sulfur dioxide emission monitor at
the inlet to the sulfur dioxide control device as required under subd.
1.
(c)
1. The owner or operator of an affected
facility shall install, calibrate, maintain and operate a continuous monitoring
system, and record the output of the system for measuring nitrogen oxides
emissions discharged to the atmosphere, except as provided in subd.
2.
2. If the owner or operator has
installed a nitrogen oxides emission rate continuous emission monitoring system
(CEMS) to meet the requirements of 40 CFR part 75 and is continuing to meet the
ongoing requirements of 40 CFR part 75, that CEMS may be used to meet the
requirement of this paragraph, except that the owner or operator shall also
meet the requirements of sub. (9). Data reported to meet the requirements of
sub. (9) may not include data substituted using the missing data procedures in
40 CFR part 75, subpart D, nor shall the data have been bias adjusted according
to the procedures of 40 CFR part 75.
(d) The owner or operator of an affected
facility shall install, calibrate, maintain and operate a continuous monitoring
system, and record the output of the system, for measuring the oxygen or carbon
dioxide content of the flue gases at each location where sulfur dioxide or
nitrogen oxides emissions are monitored.
(e) The continuous monitoring systems under
pars. (b), (c) and (d) shall be operated and data recorded during all periods
of operation of the affected facility including periods of startup, shutdown,
malfunction or emergency conditions, except for continuous monitoring system
breakdowns, repairs, calibration checks and zero and span
adjustments.
(f) The owner or
operator shall obtain emission data for at least 18 hours in at least 22 out of
30 successive boiler operating days. If this minimum data requirement cannot be
met with a continuous monitoring system, the owner or operator shall supplement
emission data with other monitoring systems approved by the department or the
reference methods and procedures as described in par. (h).
(g) The one-hour averages required under s.
NR 440.13(8) shall be expressed in ng/J
(lbs/million Btu) heat input and used to calculate the average emission rates
under sub. (6). The one-hour averages shall be calculated using the data points
required under s.
NR 440.13(2). At least 2 data points
shall be used to calculate the one-hour averages.
(h) When it becomes necessary to supplement
continuous monitoring system data to meet the minimum data requirements in par.
(f), the owner or operator shall use the reference methods and procedures as
specified in this paragraph. Acceptable alternative methods and procedures are
given in par. (j).
1. Method 6 shall be used
to determine the SO2 concentration at the same location
as the SO2 monitor. Samples shall be taken at 60 minute
intervals. The sampling time and sample volume for each sample shall be at
least 20 minutes and 0.020 dscm (0.71 dscf). Each sample represents a 1-hour
average.
2. Method 7 shall be used
to determine the NOx concentration at the same location
as the NOx monitor. Samples shall be taken at 30-minute
intervals. The arithmetic average of 2 consecutive samples represent a 1-hour
average.
3. The emission rate
correction factor, integrated bag sampling and analysis procedure of Method 3B
shall be used to determine the O2 or
CO2 concentration at the same location as the
O2 or CO2 monitor. Samples shall
be taken for at least 30 minutes in each hour. Each sample represents a 1-hour
average.
4. The procedures in
Method 19 shall be used to compute each 1-hour average concentration in ng/J
(lb/million Btu) heat input.
(i) The owner or operator shall use methods
and procedures in this paragraph to conduct monitoring system performance
evaluations under s.
NR 440.13(3) and calibration checks
under s.
NR 440.13(4). Acceptable alternative
methods and procedures are given in par. (j).
1. Methods 3B, 6 and 7 shall be used to
determine O2, SO2 and
NOx concentrations, respectively.
2. SO2 or
NOx (NO), as applicable, shall be used for preparing the
calibration gas mixtures (in N2, as applicable) under Performance Specification
2 of Appendix B of 40 CFR part 60, incorporated by reference in s.
NR 440.17.
3.
For affected facilities burning only fossil fuel, the span value for a
continuous monitoring system for measuring opacity shall be between 60 and 80%
and for a continuous monitoring system measuring nitrogen oxides shall be
determined as follows:
Fossil fuel
|
Span value for nitrogen oxides (ppm)
|
a. |
Gas .................. |
500 |
b. |
Liquid ................ |
500 |
c. |
Solid ................. |
1,000 |
d. |
Combination ........... |
500(x+ y)+ 1,000z |
where:
x is the fraction of total heat input derived from gaseous
fossil fuel
y is the fraction of total heat input derived from liquid
fossil fuel
z is the fraction of total heat input derived from solid
fossil fuel
4. All span
values computed under par. (b) 3. for burning combinations of fossil fuels
shall be rounded to the nearest 500 ppm.
5. For affected facilities burning fossil
fuel, alone or in combination with nonfossil fuel, the span value of the sulfur
dioxide continuous monitoring system at the inlet to the sulfur dioxide control
device shall be 125% of the maximum estimated hourly potential emissions of the
fuel fired, and the outlet of the sulfur dioxide control device shall be 50% of
maximum estimated hourly potential emissions of the fuel fired.
(j) The owner or operator may use
the following as alternatives to the reference methods and procedures specified
in this subsection. All test methods are in Appendix A of 40 CFR part 60,
incorporated by reference in s.
NR 440.17.
1. For Method
6, Method 6A or 6B (whenever Methods 6 and 3 or 3B data are used) or 6C may be
used. Each Method 6B sample obtained over 24 hours represents 24 1-hour
averages. If Method 6A or 6B is used under par. (i), the conditions under s.
NR 440.19(7) (d) 1. apply; these
conditions do not apply under par. (h).
2. For Method 7, Method 7A, 7C, 7D or 7E may
be used. If Method 7C, 7D or 7E is used, the sampling time for each run shall
be 1 hour.
3. For Method 3, Method
3A may be used if the sampling time is 1 hour.
4. For Method 3B, Method 3A may be
used.
(k) The procedures
specified in subds. 1. to 3. shall be used to determine gross output for
sources demonstrating compliance with the output-based standard under sub. (5)
(d) 1.
1. The owner or operator of an
affected facility with electricity generation shall install, calibrate,
maintain and operate a wattmeter; measure gross electrical output in
megawatt-hours on a continuous basis and record the output of the
monitor.
2. The owner or operator
of an affected facility with process steam generation shall install, calibrate,
maintain and operate meters for steam flow, temperature and pressure; measure
gross process steam output in joules per hour (Btu per hour) on a continuous
basis and record the output of the monitor.
3. For affected facilities generating process
steam in combination with electrical generation, the gross energy output is
determined from the gross electrical output measured in accordance with subd.
1. plus 50% of the gross thermal output of the process steam measured in
accordance with subd. 2.
(L) The owner or operator of an affected
facility demonstrating compliance with the output-based standard under sub. (5)
(d) 1. shall do one of the following:
1.
Install, certify, operate and maintain a continuous flow monitoring system
meeting the requirements of Performance Specification 6 in 40 CFR part 60,
Appendix B, and Procedure 1 in 40 CFR part 60, Appendix F, both incorporated by
reference in s.
NR 440.17(1), and record the output of
the system for measuring the flow of exhaust gases discharged to the
atmosphere.
2. Use data from a
continuous flow monitoring system certified according to the requirements of
40 CFR
75.20, meeting the applicable quality control
and quality assurance requirement of
40 CFR
75.21 and validated according to
40 CFR
75.23.
(m) The owner or operator of an affected unit
that qualifies as a gas-fired or oil-fired unit, as defined in
40
CFR 72.2, may use, as an alternative to the
requirements specified in either par. (L) 1. or 2., a fuel flow monitoring
system certified and operated according to the requirements of 40 CFR part 75,
Appendix D, incorporated by reference in s.
NR 440.17(1).
(n) The owner or operator of a duct burner
which is subject to the NOx standards of sub. (5) (a) 1.
or (d) 1. is not required to install or operate a continuous emissions
monitoring system to measure NOx emissions; a wattmeter
to measure gross electrical output; meters to measure steam flow, temperature
and pressure; and a continuous flow monitoring system to measure the flow of
exhaust gases discharged to the atmosphere.
(8) COMPLIANCE DETERMINATION PROCEDURES AND
METHODS.
(a) In conducting the performance
tests required in s.
NR 440.08, the
owner or operator shall use as reference methods and procedures the methods in
Appendix A of 40 CFR part 60, incorporated by reference in s.
NR 440.17, or the methods and procedures as specified in
this subsection, except as provided in s.
NR 440.08(2). Section
NR 440.08(6) does not apply to this
subsection for SO2 and NOx.
Acceptable alternative methods are given in par. (e).
(b) The owner or operator shall determine
compliance with the particulate matter standards in sub. (3) as follows:
1. The dry basis F factor
(O2) procedures in Method 19 shall be used to compute
the emission rate of particulate matter.
2. For the particulate matter concentration,
Method 5 shall be used at affected facilities without wet FGD systems and
Method 5B shall be used after wet FGD systems.
a. The sampling time and sample volume for
each run shall be at least 120 minutes and 1.70 dscm (60 dscf). The probe and
filter holder heating system in the sampling train may be set to provide an
average gas temperature of no greater than 160"14°C
(320"25°F).
b. For each
particulate run, the emission rate correction factor, integrated or grab
sampling and analysis procedures of Method 3B shall be used to determine the
O2 concentration. The O2 sample
shall be obtained simultaneously with, and at the same traverse points as, the
particulate run. If the particulate run has more than 12 traverse points, the
O2 simultaneous traverse points may be reduced to 12
provided that Method 1 is used to locate the 12 O2
traverse points. If the grab sampling procedure is used, the
O2 concentration for the run shall be the arithmetic
mean of the sample O2 concentrations at all traverse
points.
3. Method 9 and
the procedures in s.
NR 440.11 shall be used to determine opacity.
(c) The owner or operator shall
determine compliance with the SO2 standards in sub. (4)
as follows:
1. The percent of potential
SO2 emissions (% Ps) to the atmosphere shall be computed
using the following equation:
% Ps = [(100 - %Rf) (100 - %R
g)]/100
where:
%Ps is the percent of potential
SO2 emissions, percent
%Rf is the percent reduction from
fuel pretreatment, percent
%Rg is the percent reduction by
SO2 control system, percent
2. The procedures in Method 19 may be used to
determine percent reduction (%Rf) of sulfur by such processes as fuel
pretreatment (physical coal cleaning, hydrodesulfurization of fuel oil, etc.),
coal pulverizers, and bottom and flyash interactions. This determination is
optional.
3. The procedures in
Method 19 shall be used to determine the percent SO2
reduction (%Rg) of any SO2 control system.
Alternatively, a combination of an`as fired' fuel monitor and emission rates
measured after the control system, following the procedures in Method 19, may
be used if the percent reduction is calculated using the average emission rate
from the SO2 control device and the average
SO2 input rate from the `as fired' fuel analysis for 30
successive boiler operating days.
4. The appropriate procedures in Method 19
shall be used to determine the emission rate.
5. The continuous monitoring system in sub.
(7) (b) and (d) shall be used to determine the concentrations of
SO2 and CO2 or
O2.
(d) The owner or operator shall determine
compliance with the NOx standard in sub. (5) as follows:
1. The appropriate procedures in Method 19
shall be used to determine the emission rate of NOx.
2. The continuous monitoring system in sub.
(7) (c) and (d) shall be used to determine the concentrations of
NOx and CO2 or
O2.
(e) The owner or operator may use the
following as alternatives to the reference methods and procedures specified in
this subsection:
1. For Method 5 or 5B, Method
17 may be used at facilities with or without wet FGD systems if the stack
temperature at the sampling location does not exceed an average temperature of
160°C (320 °F). The procedures of sections 2.1 and 2.3 of Method 5B may
be used in Method 17 only if it is used after wet FGD systems. Method 17 may
not be used after wet FGD systems if the effluent is saturated or laden with
water droplets.
2. The Fc factor
(CO2) procedures in Method 19 may be used to compute the emission rate of
particulate matter under the stipulations of s.
NR 440.19(7) (d) 1. The CO2 shall be
determined in the same manner as the O2 concentration.
(f) Electric utility combined cycle gas
turbines are performance tested for particulate matter, sulfur dioxide and
nitrogen oxides using the procedures of Method 19 of 40 CFR part 60, Appendix
A, incorporated by reference in s.
NR 440.17(1). The sulfur dioxide and
nitrogen oxides emission rates from the gas turbine used in Method 19
calculations are determined when the gas turbine is performance tested under s.
NR 440.50. The potential uncontrolled particulate matter
emission rate from a gas turbine is defined as 17 ng/J (0.04 lb/million Btu)
heat input.
(9)
REPORTING REQUIREMENTS.
(a) For sulfur
dioxide, nitrogen oxides and particulate matter emissions, the performance test
data from the initial performance test and from the performance evaluation of
the continuous monitors (including the transmissometer) shall be submitted to
the department.
(b) For sulfur
dioxide and nitrogen oxides the following information shall be reported to the
department for each 24-hour period.
1.
Calendar date.
2. The average
sulfur dioxide and nitrogen oxide emission rates (ng/J or lb/million Btu) for
each 30 successive boiler operating days, ending with the last 30-day period in
the quarter; reasons for noncompliance with the emission standards; and
description of corrective actions taken.
3. Percent reduction of the potential
combustion concentration of sulfur dioxide for each 30 successive boiler
operating days, ending with the last 30-day period in the quarter; reasons for
noncompliance with the standard; and description of corrective actions
taken.
4. Identification of the
boiler operating days for which pollutant or diluent data have not been
obtained by an approved method for at least 18 hours of operation of the
facility; justification for not obtaining sufficient data; and description of
corrective actions taken.
5.
Identification of the times when emissions data have been excluded from the
calculation of average emission rates because of startup, shutdown, malfunction
(NOx only), emergency conditions (SO2 only) or other reasons, and justification
for excluding data for reasons other than startup, shutdown, malfunction or
emergency conditions.
6.
Identification of "F" factor used for calculations, method of determination and
type of fuel combusted.
7.
Identification of times when hourly averages have been obtained based on manual
sampling methods.
8. Identification
of the times when the pollutant concentration exceeded full span of the
continuous monitoring system.
9.
Description of any modifications to the continuous monitoring system which
could affect the ability of the continuous monitoring system to comply with
Performance Specification 2 or 3 of 40 CFR part 60, Appendix B, incorporated by
reference in s.
NR 440.17.
(c) If the minimum quantity of emission data
as required by sub. (7) is not obtained for any 30 successive boiler operating
days, the following information obtained under the requirements of sub. (6) (h)
shall be reported to the department for that 30-day period:
1. The number of hourly averages available
for outlet emissions rates (no) and inlet emission rates (ni), as
applicable.
2. The standard
deviation of hourly averages for outlet emission rates
(So) and inlet emission rates
(Si), as applicable.
3. The lower confidence limit for the mean
outlet emission rate (Eo*) and the upper confidence limit for the mean inlet
emission rate (Eo*), as applicable.
4. The applicable potential combustion
concentration.
5. The ratio of the
upper confidence limit for the mean outlet emission rate (Eo*) and the
allowable emission rate (Estd), as applicable.
(d) If any standards under sub. (4) are
exceeded during emergency conditions because of control system malfunction, the
owner or operator of the affected facility shall submit a signed statement:
1. Indicating if emergency conditions existed
and requirements under sub. (6) (d) were met during each period, and
2. Listing the following information:
a. Time periods the emergency condition
existed;
b. Electrical output and
demand on the owner or operator's electric utility system and the affected
facility;
c. Amount of power
purchased from interconnected neighboring utility companies during the
emergency period;
d. Percent
reduction in emissions achieved;
e.
Atmospheric emission rate (ng/J) of the pollutant discharged; and
f. Actions taken to correct control system
malfunction.
(e) If fuel pretreatment credit toward the
sulfur dioxide emission standard under sub. (4) is claimed, the owner or
operator of the affected facility shall submit a signed statement:
1. Indicating what percentage cleaning credit
was taken for the calendar quarter, and whether the credit was determined in
accordance with the provisions of sub. (8) and Method 19 of 40 CFR part 60,
Appendix A, incorporated by reference in s.
NR 440.17; and
2. Listing the quantity, heat content, and
date each pretreated fuel shipment was received during the previous quarter;
the name and location of the fuel pretreatment facility; and the total quantity
and total heat content of all fuels received at the affected facility during
the previous quarter.
(f) For any periods for which opacity, sulfur
dioxide or nitrogen oxides emissions data are not available, the owner or
operator of the affected facility shall submit a signed statement indicating if
any changes were made in operation of the emission control system during the
period of data unavailability. Operations of the control system and affected
facility during periods of data unavailability are to be compared with
operation of the control system and affected facility before and following the
period of data unavailability.
(g)
The owner or operator of the affected facility shall submit a signed statement
indicating whether:
1. The required
continuous monitoring system calibration, span, and drift checks or other
periodic audits have or have not been performed as specified.
2. The data used to show compliance was or
was not obtained in accordance with approved methods and procedures of this
chapter and is representative of plant performance.
3. The minimum data requirements have or have
not been met; or, the minimum data requirements have not been met for errors
that were unavoidable.
4.
Compliance with the standards has or has not been achieved during the reporting
period.
(h) For the
purposes of the reports required under s.
NR 440.07, periods of excess emissions are defined as all
6-minute periods during which the average opacity exceeds the applicable
opacity standards under sub. (3) (b). Opacity levels in excess of the
applicable opacity standard and the date of such excesses shall be submitted to
the department each calendar quarter.
(i) The owner or operator of an affected
facility shall submit the written reports required under this subsection and
ss.
NR 440.01
to 440.15 to the department semiannually
for each 6-month period. All semiannual reports shall be postmarked by the 30th
day following the end of each 6-month period.
(j) The owner or operator of an affected
facility may submit electronic quarterly reports for
SO2, NOx and opacity in lieu of
submitting the written reports required under pars. (b) and (h). The format of
each quarterly electronic report shall be coordinated with the department. The
electronic report shall be submitted no later than 30 days after the end of the
calendar quarter and shall be accompanied by a certification statement from the
owner or operator, indicating whether compliance with the applicable emission
standards and minimum data requirements of this section was achieved during the
reporting period. Before submitting reports in the electronic format, the owner
or operator shall coordinate with the department to obtain agreement to submit
reports in this alternative format.