Wisconsin Administrative Code
Department of Natural Resources
NR 400-499 - Environmental Protection - Air Pollution Control
Chapter NR 421 - Control Of Organic Compound Emissions From Chemical, Coatings And Rubber Products Manufacturing
Section NR 421.05 - Synthetic resin manufacturing
Universal Citation: WI Admin Code ยง NR 421.05
Current through August 26, 2024
(1) APPLICABILITY.
(a) Effective October 1, 1986, subs. (2) and
(3) (a) and (b) apply to reaction tanks, thinning tanks, blending tanks, and
other process vessels used in any synthetic resin manufacturing facility which
has maximum theoretical emissions of VOCs from the processes greater than or
equal to 100 tons per year and which is located in the county of Kenosha,
Milwaukee, Ozaukee, Racine, Washington, or Waukesha.
(b) Effective January 1, 1994, subs. (2) and
(3) (a) and (b) apply to reaction tanks, thinning tanks, blending tanks, and
other process vessels used in any synthetic resin manufacturing facility which
has maximum theoretical emissions of VOCs from the processes greater than or
equal to one of the following:
1. 25 tons per
year for a facility located in the county of Kenosha, Milwaukee, Ozaukee,
Racine, Washington, or Waukesha.
2.
100 tons per year for a facility located in the county of Door, Kewaunee,
Manitowoc, Sheboygan, or Walworth.
(c) Subsections (2m), (3) (c), and (4) apply
to facilities with synthetic resin manufacturing operations as described in
par. (a) located in the county of Kenosha, Milwaukee, Ozaukee, Racine,
Sheboygan, Washington, or Waukesha if VOC emissions from all industrial
cleaning operations, before consideration of controls, equal or exceed 3 tons
per year on a 12 consecutive month rolling basis.
Note: "Maximum theoretical emissions" has the meaning given in s. NR 419.02(11).
(2) EMISSION CONTROL REQUIREMENTS. The owner or operator of a synthetic resin manufacturing facility shall:
(a) Equip each vent from reaction tanks, and
all blending tanks and thinning tanks, with an emission control system which
meets one of the conditions listed in this paragraph. Any equally effective
control method or equivalent system approved by the department under this
paragraph shall be submitted to, and will not become effective for federal
purposes until approved by, the administrator or designee as a source-specific
revision to the department's state implementation plan for ozone. The emission
control system shall be one of the following:
1. A surface condenser, or equally effective
control device approved by the department, and a vapor recovery or control
system that reduces emissions from the surface condenser or equally effective
device by 85%.
2. An equivalent
system or approach demonstrated to reliably control emissions from a process
that does not include a condenser by not less than 90% as approved by the
department.
(b) If a
surface condenser is used, continuously record the condenser outlet gas
temperature, and prevent the condenser outlet gas temperature from exceeding
32°C (90°F).
(c) Enclose
all centrifuges, rotary vacuum filters, and any other filters having an exposed
liquid surface, where the liquid contains VOCs.
(d) Install covers on all in-process tanks
that contain a VOC at any time. Covers shall be closed except for necessary
operator access during production, sampling, maintenance or
inspection.
(e) Monitor each valve,
pump, sealed agitator, compressor, flange, and relief valve used with a process
stream which contains at least 10.0% VOCs by weight using Method 21 of Appendix
A, 40 CFR part 60, incorporated by reference in s.
NR 484.04. The monitoring schedule shall be as follows:
1. Monitor each valve, pump, sealed agitator,
compressor, and relief valve that is located withi n 2.0 meters (6.6 feet) of a
permanent support surface once during each calendar quarter.
2. Monitor all other valves, pumps, sealed
agitators, compressors, and relief valves, and all flanges, once during each
calendar year.
3. Notwithstanding
subd. 1., if less than or equal to 2% of the valves monitored pursuant to subd.
1. are found to leak for 5 consecutive quarters, monitoring of valves under
subd. 1. will not be required for the following 3 consecutive quarters.
Monitoring shall be conducted during the next quarter and every fourth quarter
thereafter. If, during monitoring required under this subdivision, more than 2%
of valves monitored are found to leak, quarterly monitoring under subd. 1.
shall be reinstituted in the next quarter.
(f) Check bimonthly by visual inspection each
valve, pump, sealed agitator, compressor, flange, and relief valve for
indications of dripping liquid.
(g)
Repair all leaks detected as soon as practicable, but not later than 15
calendar days after leak detection unless the repair is technically infeasible
without a process unit shutdown. In the case of such infeasibility, repair
shall occur before the end of the next process unit shutdown.
(h) Document to the department all repairs of
detectable leaks of VOCs for each calendar quarter. This documentation is to
include a description of the equipment that leaked, date of detection, date of
repair, dates of follow-up inspection, and an explanation of what caused the
leak. This documentation is to be submitted to the department within one month
after the close of the calendar quarter during which the leaks were detected
and repaired.
(2m) INDUSTRIAL CLEANING OPERATIONS.
(a) Except as
provided in par. (b), the owner or operator of a facility subject to this
subsection shall use any of the following methods when cleaning mixing vats,
high dispersion mills, grinding mills, tote tanks, and roller mills:
1. Use a solvent or solvent solution that
either contains less than 0.20 kilograms of VOC per liter (1.67 pounds per
gallon) or has a VOC composite partial vapor pressure of less than or equal to
8 mm of Hg at 20ºC. The solvent or solvent solution shall be collected and
stored in closed containers.
2.
Implement the following work practices:
a.
Maintain the equipment being cleaned as leak free.
b. Drain VOC-containing cleaning materials
from the cleaned equipment upon completion of cleaning.
c. Store or dispose of VOC-containing
cleaning materials, including waste solvent, in a manner that will prevent
evaporation into the atmosphere.
d.
Store all VOC-containing cleaning materials in closed containers.
3. Collect and vent the emissions
from equipment cleaning to an emission control system that has an overall
control efficiency of 80% or more on a mass basis. If incineration is used to
control emissions, at least 90% of the organic carbon shall be oxidized to
carbon dioxide.
4. Use no more than
228 liters (60 gallons) of virgin solvent per month. Solvent or solvent
solution that is reused or recycled (either onsite or offsite), for further use
in equipment cleaning or the manufacture of coating is not included in this
limit.
(b) The owner or
operator of a facility engaged in wipe cleaning may not use open containers for
the storage of solvent or solvent solution used for cleaning or for the storage
or disposal of any material impregnated with solvent or solvent solution used
for cleaning.
(3) COMPLIANCE SCHEDULE.
(a) Paragraph (b) applies
only to a synthetic resin manufacturing facility which is in existence on
January 1, 1994 and which meets one of the following criteria:
1. The facility is located in the county of
Door, Kewaunee, Manitowoc, Sheboygan, or Walworth.
2. The facility is located in the county of
Kenosha, Milwaukee, Ozaukee, Racine, Washington, or Waukesha and was not
subject to this section prior to January 1, 1994.
(b) The owner or operator of any source
identified under par. (a) shall:
1. Notify
the department's bureau of air management in writing by April 1, 1994. This
notification shall provide the name and location of the affected facility and
include VOC emission data if necessary to support eligibility under this
subsection.
2. Achieve final
compliance with the requirements of this section no later than May 31,
1995.
(c) The owner or
operator of a synthetic resin manufacturing facility subject to sub. (2m) shall
achieve final compliance with sub. (2m) no later than February 1,
2013.
(4) RECORDKEEPING.
(a) Except as provided in par. (c) and in
addition to the applicable recordkeeping requirements in s.
NR 439.04, the owner or operator of a synthetic resins
manufacturing facility subject to sub. (2m) shall collect and record the
following information, as applicable:
1.
Total volume of virgin solvent used per month.
2. VOC content in kilograms per liter or
pounds per gallon.
3. VOC composite
partial vapor pressure in mm of Hg at 20ºC.
(b) The owner or operator of a synthetic
resins manufacturing facility shall maintain the information under par. (a) at
the facility for a minimum of 5 years and shall make the information available
to an authorized department representative at any time during normal working
hours. (c) The provisions of par. (a) do not apply to solvent or solvent
solution which is used to clean or flush a mill or vat during the manufacture
of a synthetic resin and which is subsequently incorporated into the same
batch.
Disclaimer: These regulations may not be the most recent version. Wisconsin may have more current or accurate information. We make no warranties or guarantees about the accuracy, completeness, or adequacy of the information contained on this site or the information linked to on the state site. Please check official sources.
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