Wisconsin Administrative Code
Department of Natural Resources
NR 200-299 - Environmental Protection - Wisconsin Pollutant Discharge Elimination System
Chapter NR 279 - Petroleum refining
Section NR 279.23 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT)
Current through August 26, 2024
(1) Except as provided in 40 CFR 125.30- 125.32, any existing point source subject to this subcategory shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable:
BAT effluent limitations
Pollutant or pollutant property |
Maximum for any 1 day |
Average of daily values for 30 consecutive days |
Metric units (kilograms per 1,000 m3 of feedstock |
||
COD1 |
210.0 |
109.0 |
Ammonia as N |
18.8 |
8.5 |
Sulfide |
0.18 |
0.082 |
English units (pounds per 1,000 bbl of feedstock) |
||
COD1 |
74.0 |
38.4 |
Ammonia as N |
6.6 |
3.0 |
Sulfide |
0.065 |
0.029 |
1 See footnote following table in s. NR 279.13(4).
(2) The limits set forth in sub. (1) shall be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for 30 consecutive days:
1000 bbl. of feedstock per stream day |
Size factor |
Less than 24.9 |
0.91 |
25.0 to 49.9 |
0.95 |
50.0 to 74.9 |
1.04 |
75.0 to 99.9 |
1.13 |
100.0 to 124.9 |
1.23 |
125.0 to 149.9 |
1.35 |
150.0 or greater |
1.41 |
Process configuration |
Process factor |
Less than 2.49 |
0.58 |
2.5 to 3.49 |
0.63 |
3.5 to 4.49 |
0.74 |
4.5 to 5.49 |
0.88 |
5.5 to 5.99 |
1.0 |
6.0 to 6.49 |
1.09 |
6.5 to 6.99 |
1.19 |
7.0 to 7.49 |
1.29 |
7.5 to 7.99 |
1.41 |
8.0 to 8.49 |
1.53 |
8.5 to 8.99 |
1.67 |
9.0 to 9.49 |
1.82 |
9.5 or greater |
1.89 |
Note: See the comprehensive example in s. NR 279.42(2) (c).
(3)
Note: Applicable production processes are presented in Appendix A by process type, the process identification numbers presented in this Appendix A are for the convenience of the reader. They may be cross referenced in the Development Document for Effluent Limitations Guidelines, New Source Performances Standards, and Pretreatment Standards for the Petroleum Refining Point Source Category (EPA 440/1-82/014. Table 111-7, pp. 49-54.
40 CFR 122.45(b) reads as follows: The calculation of any permit limitations, standards, or prohibitions which are based on production (or other measure of operation) shall be based not upon the designed production capacity but rather upon a reasonable measure of actual production of the facility, such as the production during the high month of the previous year, or the monthly average for the highest of the previous 5 years. For new sources or new dischargers, actual production shall be estimated using projected production. The time period of the measure of production shall correspond to the time period of the calculated permit limitations; for example, monthly production shall be used to calculate average monthly discharge limitations.
BAT Effluent Limitations Factor |
||
Pollutant or pollutant property and process type |
Maximum for any 1 day |
Average of daily values for 30 consecutive days |
Metric units (kilograms per 1,000 m3 of feedstock) |
||
Phenolic compounds (4AAP): |
||
Crude |
0.037 |
0.009 |
Cracking and coking |
0.419 |
0.102 |
Asphalt |
0.226 |
0.055 |
Lube |
1.055 |
0.257 |
Reforming and alkylation |
0.377 |
0.092 |
Total chromium: |
||
Crude |
0.03 |
0.011 |
Cracking and coking |
0.34 |
0.118 |
Asphalt |
0.183 |
0.064 |
Lube |
0.855 |
0.297 |
Reforming and alkylation |
0.305 |
0.106 |
Hexavalent chromium: |
||
Crude |
0.0019 |
0.0009 |
Cracking and coking |
0.0218 |
0.0098 |
Asphalt |
0.0117 |
0.0053 |
Lube |
1.0549 |
0.0248 |
Reforming and alkylation |
0.0196 |
0.0088 |
English units (pounds per 1,000 bbl of feedstock) |
||
Phenolic compounds (4AAP): |
||
Crude |
0.013 |
0.003 |
Cracking and coking |
0.147 |
0.036 |
Asphalt |
0.079 |
0.019 |
Lube |
0.369 |
0.09 |
Reforming and alkylation |
0.132 |
0.032 |
Total chromium: |
||
Crude |
0.011 |
0.004 |
Cracking and coking |
0.119 |
0.041 |
Asphalt |
0.064 |
0.022 |
Lube |
0.299 |
0.104 |
Reforming and alkylation |
0.107 |
0.037 |
Hexavalent chromium: |
||
Crude |
0.0007 |
0.0003 |
Cracking and coking |
0.0076 |
0.0034 |
Asphalt |
0.0041 |
0.0019 |
Lube |
0.0192 |
0.0087 |
Reforming and alkylation |
0.0089 |
0.0031 |
Note: See the comprehensive example in s. NR 279.43(3) (b).
(4) The provisions of s. NR 279.13(4) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subcategory.
(5) The quantity and quality of pollutants or pollutant properties controlled by this subsection, attributable to once-through cooling water, are excluded from the discharge allowed by sub. (2). Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l.
(6) The following effluent limitations constitute the quantity and quality of pollutants or pollutant properties controlled by this subsection and attributable to contaminated runoff, which may be discharged after the application of the best available technology economically achievable by a point source subject to this subcategory.
BAT effluent limitations |
||
Pollutant or pollutant property |
Maximum for any 1 day |
Average of daily values for 30 consecutive days |
Metric units (kilograms per 1,000 cubic meters of flow) |
||
Phenolic compounds (4AAP) |
0.35 |
0.17 |
Total chromium |
0.6 |
0.21 |
Hexavalent chromium |
0.062 |
0.028 |
COD1 |
360.0 |
180.0 |
English units (pounds per 1,000 gallons of flow) |
||
Phenolic compounds (4AAP) |
.0029 |
.0014 |
Total chromium |
.005 |
.0018 |
Hexavalent chromium |
.00052 |
.00023 |
COD1 |
3.0 |
1.5 |
1 In any case in which the applicant can demonstrate that the chloride ion concentration in the effluent exceeds 1000 mg/l (1000 ppm), the department may substitute TOC as a parameter in lieu of COD. A TOC effluent limitation shall be based on effluent data from the particular refinery which correlates TOC to BOD5. If in the judgment of the department, adequate correlation data are not available, the effluent limitations for TOC shall be established at a ratio of 2.2 to 1 to the applicable effluent limitations for BOD5.