(2) Monitoring requirements for disinfection
byproducts.
(a) TTHMs and HAA5s
(i) Routine monitoring. Systems must monitor
at the frequency indicated in the following:
(A) If a system elects to sample more
frequently than the minimum required, at least 25 percent of all samples
collected each quarter (including those taken in excess of the required
frequency) must be taken at locations that represent the maximum residence time
of the water in the distribution system. The remaining samples must be taken at
locations representative of at least average residence time in the distribution
system.
(B) Surface water systems
serving at least 10,000 persons shall take four water samples per quarter per
treatment plant. At least 25 percent of all samples collected each quarter
shall be at locations representing maximum residence time. The remaining
samples taken at locations representative of at least average residence time in
the distribution system and representing the entire distribution system, taking
into account number of persons served, different sources of water, and
different treatment methods.
(C)
Surface water systems serving from 500 to 9,999 persons shall take one water
sample per quarter per treatment plant at a locations representing maximum
residence time.
(D) Surface water
systems serving fewer than 500 persons shall take one sample per year per
treatment plant during month of warmest water temperature at a location
representing maximum residence time. If the sample (or average of annual
samples, if more than one sample is taken) exceeds the MCL, the system must
increase monitoring to one sample per treatment plant per quarter, taken at a
point reflecting the maximum residence time in the distribution system, until
the system meets reduced monitoring criteria in paragraph (2)(a)(v) of this
section.
(E) Systems using only
ground water not under direct influence of surface water using chemical
disinfectant and serving at least 10,000 persons shall take one water sample
per quarter per treatment plant at a locations representing maximum residence
time.
(F) Systems using only ground
water not under direct influence of surface water using chemical disinfectant
and serving fewer than 10,000 persons shall take one sample per year per
treatment plant during month of warmest water temperature at a location
representing maximum residence time. If the sample (or average of annual
samples, if more than one sample is taken) exceeds the MCL, the system must
increase monitoring to one sample per treatment plant per quarter, taken at a
point reflecting the maximum residence time in the distribution system, until
the system meets criteria in paragraph (2) (a)(v) of this section for reduced
monitoring.
(ii) Systems
may reduce monitoring, except as otherwise provided, if the system has
monitored for at least one year and is in accordance with the following
paragraphs. Any Surface water system serving fewer than 500 persons may not
reduce its monitoring to less than one sample per treatment plant per year.
(A) A surface water system serving at least
10,000 persons which has a source water annual average TOC level, before any
treatment, of less than or equal to 4.0 mg/L and has a TTHM annual average of
less than or equal to 0.040 mg/L and has a HAA5 annual average of less than or
equal to 0.030 mg/L may reduce monitoring to one sample per treatment plant per
quarter at a distribution system location reflecting maximum residence
time.
(B) A surface water system
serving from 500 to 9,999 persons which has a source water annual average TOC
level, before any treatment, of less than or equal to 4.0 mg/L and has a TTHM
annual average of less than or equal to 0.040 mg/L and has a HAA5 annual
average of less than or equal to 0.030 mg/L may reduce monitoring to one sample
per treatment plant per year at a distribution system location reflecting
maximum residence time during the month of warmest water temperature.
(C) A system using only ground water not
under direct influence of surface water using chemical disinfectant and serving
at least 10,000 persons that has a TTHM annual average of less than or equal to
0.040 mg/L and has a HAA5 annual average of less than or equal to 0.030 mg/L
may reduce monitoring to one sample per treatment plant per year at a
distribution system location reflecting maximum residence time during the month
of warmest water temperature.
(D) A
system using only ground water not under direct influence of surface water
using chemical disinfectant and serving fewer than 10,000 persons that has a
TTHM annual average of less than or equal to 0.040 mg/L and has a HAA5 annual
average of less than or equal to 0.030 mg/L for two consecutive years or has a
TTHM annual average of less than or equal to 0.020 mg/L and has a HAA5 annual
average of less than or equal to 0.015mg/L for one year may reduce monitoring
to one sample per treatment plant per three year monitoring cycle at a
distribution system location reflecting maximum residence time during the month
of warmest water temperature, with the three-year cycle beginning on January 1
following the quarter in which the system qualifies for reduced
monitoring.
(iii)
Monitoring requirements for source water TOC in order to qualify for reduced
monitoring for TTHM and HAA5 under paragraph (2)(a)(ii) of this section,
surface water systems not monitoring under the provisions of paragraph (d) of
this section must take monthly TOC samples every 30 days at a location prior to
any treatment, beginning April 1, 2008 or earlier, if specified by the
Director. In addition to meeting other criteria for reduced monitoring in
paragraph (2)(a)(ii) of this section, the source water TOC running annual
average must be equal to or less than 4.0 mg/L (based on the most recent four
quarters of monitoring) on a continuing basis at each treatment plant to reduce
or remain on reduced monitoring for TTHM and HAA5. Once qualified for reduced
monitoring for TTHM and HAA5 under paragraph (2)(a)(ii) of this section, a
system may reduce source water TOC monitoring to quarterly TOC samples taken
every 90 days at a location prior to any treatment.
(iv) Systems on a reduced monitoring schedule
may remain on that reduced schedule as long as the average of all samples taken
in the year (for systems which must monitor quarterly) or the result of the
sample (for systems which must monitor no more frequently than annually) is no
more than 0.060 mg/L and 0.045 mg/L for TTHMs and HAA5, respectively. Systems
that do not meet these levels must resume monitoring at the frequency
identified in paragraph (2)(a)(i) of this section in the quarter immediately
following the monitoring period in which the system exceeds 0.060 mg/L or 0.045
mg/L for TTHM or HAA5, respectively. For systems using only ground water not
under the direct influence of surface water and serving fewer than 10,000
persons, if either the TTHM annual average is greater than 0.080 mg/L or the
HAA5 annual average is greater than 0.060 mg/L, the system must go to the
increased monitoring identified in paragraph (2)(a)(i) of this section in the
quarter immediately following the monitoring period in which the system exceeds
0.080 mg/L or 0.060 mg/L for TTHMs or HAA5 respectively.
(v) Systems on increased monitoring may
return to routine monitoring if, after at least one year of monitoring their
TTHM annual average is less than or equal to 0.060 mg/L and their HAA5 annual
average is less than or equal to 0.045 mg/L.
(vi) The Director may return a system to
routine monitoring when appropriate to protect public health.
(b) Chlorite. Community and
non-transient non-community water systems using chlorine dioxide, for
disinfection or oxidation, must conduct monitoring for chlorite.
(i) Routine monitoring.
(A) Daily monitoring. Systems must take daily
samples at the entrance to the distribution system. For any daily sample that
exceeds the chlorite MCL, the system must take additional samples in the
distribution system the following day at the locations required by paragraph
(2)(b)(ii) of this section, in addition to the sample required at the entrance
to the distribution system.
(B)
Monthly monitoring. Systems must take a three-sample set each month in the
distribution system. The system must take one sample at each of the following
locations: near the first customer, at a location representative of average
residence time, and at a location reflecting maximum residence time in the
distribution system. Any additional routine sampling must be conducted in the
same manner (as three-sample sets, at the specified locations). The system may
use the results of additional monitoring conducted under paragraph (2)(b)(ii)
of this section to meet the requirement for monitoring in this
paragraph.
(ii)
Additional monitoring. On each day following a routine sample monitoring result
that exceeds the chlorite MCL at the entrance to the distribution system, the
system is required to take three chlorite distribution system samples at the
following locations: as close to the first customer as possible, in a location
representative of average residence time, and as close to the end of the
distribution system as possible (reflecting maximum residence time in the
distribution system).
(iii) Reduced
monitoring.
(A) Chlorite monitoring at the
entrance to the distribution system required by paragraph (2)(b)(i)(A) of this
section may not be reduced.
(B)
Chlorite monitoring in the distribution system required by paragraph
(2)(b)(i)(B) of this section may be reduced to one three-sample set per quarter
after one year of monitoring where no individual chlorite sample taken in the
distribution system under paragraph (2)(b)(i)(B) of this section has exceeded
the chlorite MCL and the system has not been required to conduct monitoring
under paragraph (2)(b)(ii) of this section. The system may remain on the
reduced monitoring schedule until either any of the three individual chlorite
samples taken monthly in the distribution system under paragraph (2)(b)(i)(B)
of this section exceeds the chlorite MCL or the system is required to conduct
monitoring under paragraph (2)(b)(ii) of this section, at which time the system
must revert to routine monitoring.
(c) Bromate.
(i) Routine monitoring. Community and
nontransient noncommunity systems using ozone, for disinfection or oxidation,
must take one sample per month for each treatment plant in the system using
ozone. Systems must take samples monthly at the entrance to the distribution
system while the ozonation system is operating under normal
conditions.
(ii) Reduced
monitoring.
(A) Until March 31, 2009, systems
required to analyze for bromate may reduce monitoring from monthly to once per
quarter, if the system demonstrates that the average source water bromide
concentration is less than 0.05 mg/L based upon representative monthly bromide
measurements for one year. The system may remain on reduced bromate monitoring
until the running annual average source water bromide concentration, computed
quarterly, is equal to or greater than 0.05 mg/L based upon representative
monthly measurements. If the running annual average source water bromide
concentration is greater than or equal to 0.05 mg/L, the system must resume
routine monitoring required by paragraph (2)(c)(i) of this section in the
following month.
(B) Beginning
April 1, 2009, systems may no longer use the provisions of paragraph
(2)(c)(ii)(A) of this section to qualify for reduced monitoring. A system
required to analyze for bromate may reduce monitoring from monthly to
quarterly, if the system's running annual average bromate concentration is
equal to or less than 0.0025 mg/L based on monthly bromate measurements under
paragraph (2)(c) (i) of this section for the most recent four quarters, with
samples analyzed using Method 317.0 Revision 2.0, 326.0 or 321.8. If a system
has qualified for reduced bromate monitoring under paragraph (2)(c)(ii)(A) of
this section, that system may remain on reduced monitoring as long as the
running annual average of quarterly bromate samples is less than or equal to
0.0025 mg/L based on samples analyzed using Method 317.0 Revision 2.0, 326.0 or
321.8. If the running annual average bromate concentration is greater than
0.0025 mg/L, the system must resume routine monitoring required by (2)(c)(i) of
this section.