New York Codes, Rules and Regulations
Title 6 - DEPARTMENT OF ENVIRONMENTAL CONSERVATION
Chapter X - DIVISION OF WATER RESOURCES
Appendices
Appendix 29

Current through Register Vol. 46, No. 39, September 25, 2024

(cf. Subpart 373-3)

EXAMPLES OF POTENTIALLY INCOMPATIBLE WASTE

Many hazardous wastes, when mixed with other waste or materials at a hazardous waste facility, can produce effects which are harmful to human health and the environment, such as (1) heat or pressure, (2) fire or explosion, (3) violent reaction, (4) toxic dusts, mists, fumes or gases, or (5) flammable fumes or gases.

Below are examples of potentially incompatible wastes, waste components, and materials, along with the harmful consequences which result from mixing materials in one group with materials in another group. The list is intended as a guide to owners or operators of treatment, storage and disposal facilities, and to enforcement and permit-granting officials, to indicate the need for special precautions when managing these potentially incompatible waste materials or components.

This list is not intended to be exhaustive. An owner or operator must, as the regulation requires, adequately analyze his wastes so that he can avoid creating uncontrolled substances or reactions of the type listed below, whether they are listed below or not.

It is possible for potentially incompatible wastes to be mixed in a way that precludes a reaction (e.g,adding acid to water rather than water to acid) or that neutralizes them (e.g., a strong acid mixed with a strong base), or that controls substances produced (e.g., by generating flammable gases in a closed tank equipped so that ignition cannot occur, and burning the gases in an incinerator).

In the lists below, the mixing of a Group A material with a Group B material may have the potential consequence as noted.

Group 1-A Group 1-B
Acetylene sludge Acid sludge
Alkaline caustic liquids Acid and water
Alkaline cleaner Battery acid
Alkaline corrosive liquids Chemical cleaners
Alkaline corrosive battery fluid Electrolyte, acid
Caustic waste water Etching acid liquid or solvent
Lime sludge and other corrosive alkalies Pickling liquor and other corrosive acids
Lime waste water Spent acid
Lime and water Spent mixed acid
Spent caustic Spent sulfuric acid
Potential consequences: Heat generation; violent reaction.

Group 2-A Group 2-B
Aluminum Any waste in Group 1-A or 1-B
Beryllium
Calcium
Lithium
Magnesium
Potassium
Sodium
Zinc powder
Other reactive metals and metal hydrides
Potential consequences: Fire or explosion; generation of flammable hydrogen gas.

Group 3-A Group 3-B
Alcohols Any concentrated waste in Group 1-A or 1-B
Water Calcium
Lithium
Metal hydrides
Potassium
SO2Cl2SOCl2PCl3CH3SiCl 3
Other water reactive waste
Potential consequences: Fire, explosion, or heat generation; generation of flammable or toxic gases.

Group 4-A Group 4-B
Alcohols Concentrated Group 1-A or 1-B wastes
Aldehydes
Halogenated hydrocarbons Group 2-A wastes
Nitrated hydrocarbons
Unsaturated hydrocarbons
Other reactive organic components and solvents
Potential consequences: Fire, explosion, or violent reaction.

Group 5-A Group 5-B
Spent cyanide and sulfide solutions Group 1-B wastes
Potential consequences: Generation of toxic hydrogen cyanide or hydrogen sulfide gas.

Group 6-A Group 6-B
Chlorates Acetic acid and other organic acids
Chlorine
Chlorites Concentrated mineral acids
Chromic acid
Hydrochlorites Group 2-A wastes
Nitrates Group 4-A wastes
Nitric acid, fuming Other flammable and combustible wastes
Perchlorates
Permanganates
Peroxides
Other strong oxidizers
Potential consequences: Fire, explosion, or violent reaction.
Source: Law, Regulations and Guidelines for Handling of Hazardous Waste, California Department of Health, February 1975.

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