New Jersey Administrative Code
Title 7 - ENVIRONMENTAL PROTECTION
Chapter 31 - TOXIC CATASTROPHE PREVENTION ACT PROGRAM
Subchapter 6 - EXTRAORDINARILY HAZARDOUS SUBSTANCES
Section 7:31-6.2 - Threshold quantity determination
Current through Register Vol. 56, No. 18, September 16, 2024
(a) If an EHS is listed as a toxic substance in 7:31-6.3(a) Table I, Part A and Part B, the lower threshold quantity shall apply as the threshold quantity throughout this chapter.
(b) If an EHS is listed in 7:31-6.3(a) as a toxic substance in Table I, Part A or B and as a flammable substance in Part C, the lower threshold quantity shall apply as the threshold quantity throughout this chapter.
(c) If a toxic EHS listed in 7:31-6.3(a) Table I, Part A is present in a mixture at a concentration which is lower than the acute toxicity concentration (ATC), the amount of the EHS in the mixture shall not be considered in determining if the threshold quantity is present at a facility.
(d) For mixtures of EHS listed in 7:31-6.3(a) Table I, Parts A or D, Group I, for which no concentration is specified, the threshold quantity shall be calculated using the weight percent of EHS contained in the mixture. When the weight of the total mixture times the weight percent is equal to or greater than the threshold quantity for that EHS, the owner or operator must comply with this chapter.
(e) For a toxic EHS listed in 7:31-6.3(a) Table I, Part B, threshold quantity shall be determined in accordance with 40 CFR 68.115(b) with changes specified at 7:31-6.1(c)3 and 4.
(f) For mixtures containing toxic EHSs listed in 7:31-6.3(a) Table I, Part B, the weight of the pure EHS shall be considered in determining whether a threshold quantity is present at a facility.
(g) For intentional mixtures involving one or more functional groups listed on 7:31-6.3(a) Table I, Part D, Group II, the threshold quantity shall be based on the heat of reaction ([DELTA]H[R]) as determined in accordance with 7:31-6.3(b)1 through 6 and shall be derived from Table II at 7:31-6.3(c).
(h) For the purpose of determining whether a threshold quantity of an RHS mixture is present at a facility, the maximum capacity of the process vessel containing the RHS mixture shall be used assuming that the vessel is filled to capacity with the reactive ingredients of the RHS mixture. The maximum capacity of each individual process vessel containing an RHS mixture shall be compared to the threshold quantity to determine applicability. Administrative controls that limit the maximum quantity in the process vessel shall not be taken into account; however, if the total quantity of reactant ingredients used in the RHS mixture present at the facility is less than the amount of the vessel capacity, that total quantity may be used for threshold quantity determination.
(i) An owner or operator may request EHS equipment containing an RHS mixture that would otherwise meet the threshold quantity at (h) above to not be considered in determining if the threshold quantity is present at the facility. In the request for exemption, the owner or operator shall demonstrate to the satisfaction of the Department that there is no possibility of a runaway reaction, overpressurization, and accidental EHS release during either normal or abnormal conditions based on an evaluation, using calorimetry testing or other scientific analyses, of the reaction chemistry of the RHS mixture, and in accordance with the following: