Illinois Administrative Code
Title 35 - ENVIRONMENTAL PROTECTION
Part 742 - TIERED APPROACH TO CORRECTIVE ACTION OBJECTIVES
Subpart L - BUILDING CONTROL TECHNOLOGIES
Appendix C - Tier 2 Illustrations and Tables
Table E - Default Physical and Chemical Parameters

Universal Citation: 35 IL Admin Code ยง E
Current through Register Vol. 48, No. 38, September 20, 2024

CAS No.

Chemical

Solubility in Water (S) (mg/L)

Diffusivity in Air (Di) (cm2/s)

Diffusivity in Water (Dw) (cm2/s)

Dimensionless Henry's Law Constant (H') (25°C)

Dimensionless Henry's Law Constant (H') (13°C)

For the indoor inhalation exposure route

Organic Carbon Partition Coefficient (Koc) (L/kg)

First Order Degradation Constant ([LAMBDA])(d-1)

Vapor Pressure (mm/Hg)

Neutral Organics

83-32-9

Acenaphthene

3.60E+00

4.76E-02

7.69E-06

6.60E-03

-------b

6.30E+03

3.40E-03

2.50E-03

67-64-1

Acetone

1.00E+06

1.24E-01

1.14E-05

1.60E-03

9.73E-04

7.80E-01

4.95E-02

2.30E+02

15972-60-8

Alachlor

2.40E+02

2.13E-02

5.28E-06

3.40E-06

-------b

3.20E+03

No Data

2.20E-05

116-06-3

Aldicarb

6.03E+03

3.18E-02

7.24E-06

5.90E-08

-------b

1.29E+01

1.09E-03

3.47E-05

309-00-2

Aldrin

1.70E-02

1.96E-02

4.86E-06

7.00E-03

-------b

2.50E+05

5.90E-04

6.00E-06

120-12-7

Anthracene

4.30E-02

3.85E-02

7.74E-06

2.70E-03

-------b

2.50E+04

7.50E-04

2.70E-06

1912-24-9

Atrazine

7.00E+01

2.59E-02

6.67E-06

9.68E-08

-------b

3.63E+02

No Data

2.70E-07

71-43-2

Benzene

1.80E+03

8.80E-02

1.02E-05

2.30E-01

1.34E-01

5.00E+01

9.00E-04

9.50E+01

56-55-3

Benzo(a)anthracene

9.40E-03

5.10E-02

9.00E-06

1.39E-04

-------b

4.00E+05

5.10E-04

1.10E-07

205-99-2

Benzo(b)fluoranthene

1.50E-03

2.23E-02

5.56E-06

4.55E-03

-------b

1.05E+06

5.70E-04

5.00E-07

207-08-9

Benzo(k)fluoranthene

8.00E-04

2.23E-02

5.56E-06

3.40E-05

-------b

1.00E+06

1.60E-04

2.00E-09

65-85-0

Benzoic Acid

3.40E+03

7.02E-02

7.97E-06

1.56E-06

-------b

1.21E+00d

No Data

7.00E-04

50-32-8

Benzo(a)pyrene

1.60E-03

4.30E-02

9.49E-06

4.50E-05

-------b

7.90E+05

6.50E-04

5.50E-09

111-44-4

Bis(2-chloroethyl) ether

1.72E+04

4.13E-02

7.53E-06

7.40E-04

2.94E-04

1.26E+01

1.90E-03

1.55E+00

117-81-7

Bis(2-ethylhexyl)phthalate

3.40E-01

3.51E-02

3.66E-06

4.10E-06

-------b

1.00E+05

1.80E-03

6.80E-08

75-27-4

Bromodichloromethane

6.70E+03

5.61E-02

1.06E-05

6.60E-02

3.71E-02

5.00E+01

No Data

5.00E+01

75-25-2

Bromoform

3.10E+03

1.49E-02

1.03E-05

2.19E-02

1.06E-02

9.12E+01

1.90E-03

5.51E+00

71-36-3

Butanol

7.40E+04

8.00E-02

9.30E-06

3.61E-04

1.55E-04

6.00E+00

1.28E-02

7.00E+00

78-93-3

2-Butanone (MEK)

2.20E+05

8.08E-02

9.8E-06

2.30E-03

1.32E-03

2.00E+00

4.95E-02

9.50E+01

85-68-7

Butyl Benzyl Phthalate

2.70E+00

1.99E-02

4.89E-06

5.30E-05

-------b

6.30E+04

3.85E-03

8.30E-06

86-74-8

Carbazole

1.20E+00

4.17E-02

7.45E-06

3.60E-06

-------b

4.00E+03

No Data

7.00E-04

1563-66-2

Carbofuran

3.20E+02

2.37E-02

5.95E-06

1.27E-07

-------b

1.91E+02

No Data

4.85E-06

75-15-0

Carbon Disulfide

1.20E+03

1.04E-01

1.00E-05

1.23E+00

8.06E-01

6.30E+01

No Data

3.60E+02

56-23-5

Carbon Tetrachloride

7.90E+02

7.80E-02

8.80E-06

1.23E+00

7.48E-01

2.00E+02

1.90E-03

1.20E+02

57-74-9

Chlordane

5.60E-02

1.79E-02

4.37E-06

2.00E-03

-------b

2.50E+05

2.50E-04

9.80E-06

106-47-8

p-Chloroaniline

5.30E+03

6.99E-02

1.01E-05

4.76E-05

-------b

6.31E+01

No Data

1.23E-02

108-90-7

Chlorobenzene

4.70E+02

7.30E-02

8.70E-06

1.50E-01

7.93E-02

2.00E+02

2.30E-03

1.20E+01

124-48-1

Chlorodibromomethane

2.60E+03

3.66E-02

1.05E-05

3.20E-02

2.07E-02

6.92E+01

3.85E-03

4.90E+00

67-66-3

Chloroform

7.90E+03

1.04E-01

1.00E-05

1.50E-01

9.18E-02

5.00E+01

3.90E-04

2.00E+02

95-57-8

2-Chlorophenol

2.20E+04

6.61E-02

9.46E-06

1.60E-02

7.28E-03

5.93E+01d

No Data

2.34E+00

218-01-9

Chrysene

6.30E-03

2.44E-02

6.21E-06

3.90E-03

-------b

4.00E+05

3.50E-04

6.20E-09

94-75-7

2,4-D

6.77E+02

5.88E-02

6.49E-06

4.18E-07

-------b

5.75E+02

3.85E-03

6.00E-07

72-54-8

4,4'-DDD

9.00E-02

2.27E-02

5.79E-06

1.60E-04

-------b

7.90E+05

6.20E-05

6.70E-07

72-55-9

4,4'-DDE

1.20E-01

2.38E-02

5.87E-06

8.60E-04

-------b

4.00E+05

6.20E-05

6.00E-06

50-29-3

4,4'-DDT

2.50E-02

1.99E-02

4.95E-06

3.30E-04

-------b

2.00E+06

6.20E-05

1.60E-07

75-99-0

Dalapon

9.00E+05

6.08E-02

9.45E-06

2.64E-06

NA

4.80E+00

5.78E-03

1.90E-01

53-70-3

Dibenzo(a,h)anthracene

2.50E-03

2.11E-02

5.24E-06

6.10E-07

-------b

2.50E+06

3.70E-04

1.00E-10

96-12-8

1,2-Dibromo-3-chloropropane

1.20E+03

2.68E-02

7.02E-06

6.20E-03c

NA

7.90E+01

1.93E-03

5.80E-01

106-93-4

1,2-Dibromoethane

4.00E+03

4.37E-02

8.44E-06

3.00E-02

1.54E-02

5.00E+01

5.78E-03

1.30E+01

84-74-2

Di-n-butyl Phthalate

1.10E+01

4.38E-02

7.86E-06

7.40E-05

-------a

4.00E+04

3.01E-02

7.30E-05

1918-00-9

Dicamba

4.50E+03

2.37E-02

5.95E-06

2.18E-09

-------a

2.95E+00

No Data

3.38E-05

95-50-1

1,2-Dichlorobenzene

1.56E+02

6.90E-02

7.90E-06

7.79E-02

3.56E-02

5.75E+02

1.90E-03

1.36E+00

106-46-7

1,4-Dichlorobenzene

7.90E+01

6.90E-02

7.90E-06

9.80E-02

4.69E-02

7.90E+02

1.90E-03

1.00E+00

91-94-1

3,3-Dichlorobenzidine

3.10E+00

2.59E-02

6.74E-06

1.60E-07

-------a

2.82E+03

1.90E-03

3.71E-08

75-71-8

Dichlorodifluoromethane

2.80E+02

7.60E-02

1.08E-05

1.41E+01

8.14E+00

6.17E+01

1.92E-03

4.85E+03

75-34-3

1,1-Dichloroethane

5.10E+03

7.42E-02

1.05E-05

2.30E-01

1.42E-01

3.20E+01

1.90E-03

2.30E+02

107-06-2

1,2-Dichloroethane

8.50E+03

1.04E-02

9.90E-06

4.00E-02

2.29E-02

2.00E+01

1.90E-03

7.90E+01

75-35-4

1,1-Dichloroethylene

2.30E+03

9.00E-02

1.04E-05

1.10E+00

7.10E-01

5.00E+01

5.30E-03

6.00E+02

156-59-2

cis-1,2-Dichloroethylene

3.50E+03

8.86E-02

1.13E-05

1.70E-01

1.00E-01

4.00E+01

2.40E-04

2.00E+02

156-60-5

trans-1,2-Dichloroethylene

6.30E+03

7.03E-02

1.19E-05

3.90E-01

2.43E-01

5.00E+01

2.40E-04

3.30E+02

120-83-2

2,4-Dichlorophenol

4.50E+03

4.89E-02

8.77E-06

1.30E-04

-------a

7.32E+02d

2.70E-04

6.70E-02

78-87-5

1,2-Dichloropropane

2.80E+03

7.82E-02

8.73E-06

1.10E-01

6.52E-02

5.00E+01

2.70E-04

5.20E+01

542-75-6

1,3-Dichloropropylene (cis + trans)

2.80E+03

6.26E-02

1.00E-05

7.40E-01

3.98E-01

2.00E+01

6.10E-02

3.40E+01

60-57-1

Dieldrin

2.00E-01

1.92E-02

4.74E-06

6.2E-04

-------a

2.50E+04

3.20E-04

5.9E-06

84-66-2

Diethyl Phthalate

1.10E+03

2.49E-02

6.35E-06

1.80E-05

-------a

3.20E+02

6.19E-03

1.60E-03

105-67-9

2,4-Dimethylphenol

7.90E+03

6.43E-02

8.69E-06

8.20E-05

-------a

2.00E+02

4.95E-02

9.80E-02

75-71-8

1,3-Dinitrobenzene

8.60E+02

4.55E-02

8.46E-06

2.30E-07

-------a

3.20E+01

1.92E-03

9.00E-04

51-28-5

2,4-Dinitrophenol

2.79E+03

2.73E-02

9.06E-06

1.82E-05

-------a

3.24E+01

1.32E-03

5.10E-03

121-14-2

2,4-Dinitrotoluene

2.70E+02

2.03E-01

7.06E-06

3.80E-06

-------a

8.90E+01

1.92E-03

1.47E-04

606-20-2

2,6-Dinitrotoluene

1.82E+02

3.70E-02

7.76E-06

3.06E-05

-------a

4.90E+01

1.92E-03

5.67E-04

88-85-7

Dinoseb

5.20E+01

2.45E-02

6.25E-06

1.87E-05

-------a

9.17E+01d

2.82E-03

7.50E-05

117-84-0

Di-n-octyl Phthalate

2.00E-02

1.73E-02

4.17E-06

2.74E-03

-------a

1.30E+05

1.90E-03

2.60E-06

123-91-1

p-Dioxane

1.00E+06

2.29E-01

1.02E-05

1.97E-04

1.07E-04

7.20E-01

1.92E-03

3.81E+01

115-29-7

Endosulfan

5.10E-01

1.85E-02

4.55E-06

4.51E-04

-------a

5.00E+03

7.63E-02

1.00E-05

145-73-3

Endothall

2.10E+04

2.91E-02

8.07E-06

1.58E-14

-------a

7.59E+01

No Data

1.57E-10

72-20-8

Endrin

2.50E-01

1.92E-02

4.74E-6

3.08E-04

-------a

3.20E+04

3.20E-04

3.00E-06

100-41-4

Ethylbenzene

1.70E+02

7.50E-02

7.80E-06

3.24E-01

1.64E-01

3.20E+02

3.00E-03

9.60E+00

206-44-0

Fluoranthene

2.06E-01

2.51E-02

6.35E-06

6.60E-04

-------a

7.40E+04

1.90E-04

1.23E-08

86-73-7

Fluorene

2.00E+00

4.40E-02

7.88E-06

2.62E-03

-------a

1.30E+04

6.91E-04

6.30E-04

76-44-8

Heptachlor

1.80E-01

2.23E-02

5.69E-06

6.07E-02

1.73E-02

3.00E+03

1.30E-01

4.00E-04

1024-57-3

Heptachlor epoxide

2.00E-01

2.19E-02

5.57E-06

3.90E-04

-------a

2.00E+05

6.30E-04

1.90E-05

118-74-1

Hexachlorobenzene

6.20E-03

5.42E-02

5.91E-06

5.33E-02

1.35E-02

2.00E+04

1.70E-04

1.80E-05

319-84-6

Alpha-HCH (alpha-BHC)

2.00E+00

2.04E-02

5.04E-06

4.51E-04

-------a

5.00E+03

2.50E-03

4.50E-05

58-89-9

Gamma-HCH (Lindane)

7.30E+00

2.75E-02

7.34E-06

5.74E-04

-------a

3.00E+03

2.90E-03

4.10E-04

2691-41-0

High Melting Explosive, Octogen (HMX)

5.00E+00

2.69E-02

7.15E-06

8.67E-10

3.55E-08

1.40E+00

No Data

3.30E-14

77-47-4

Hexachlorocyclo-

pentadiene

1.80E+00

2.79E-02

7.21E-06

1.11E+00

4.22E-01

1.20E+04

1.20E-02

5.96E-02

67-72-1

Hexachloroethane

5.00E+01

2.50E-03

6.80E-06

1.59E-01

7.26E-02

1.50E+03

1.92E-03

2.10E-01

193-39-5

Indeno(1,2,3-c,d)pyrene

2.20E-05

2.25E-02

5.66E-06

6.56E-05

-------a

3.10E+06

4.70E-04

1.00E-10

78-59-1

Isophorone

1.20E+04

6.23E-02

6.76E-06

2.72E-04

1.12E-04

2.50E+01

1.24E-02

4.38E-01

98-82-8

Isopropylbenzene (Cumene)

6.10E+01

6.50E-02

7.10E-06

4.92E+01

2.10E+01

1.02E+03

4.33E-02

4.50E+00

93-65-2

Mecoprop (MCPP)

8.95E+02

2.40E-02

6.05E-06

7.70E-09

-------a

1.84E+01d

3.85E-03

2.44E-05

7439-97-6

Mercury

6.00E-02

7.14E-02

3.01E-05

4.51E-01

1.59E-01

8.70E+03

No Data

2.00E-03

72-43-5

Methoxychlor

4.50E-02

1.84E-02

4.46E-06

6.56E-04

-------a

5.00E+04

1.90E-03

6.00E-07

74-83-9

Methyl Bromide

1.50E+04

7.28E-02

1.21E-05

2.56E-01

1.79E-01

1.00E+01

1.82E-02

1.62E+03

1634-04-4

Methyl tertiary-butyl ether

5.10E+04

8.59E-02

1.10E-05

2.42E-02

1.50E-02

1.00E+01

No Data

2.50E+02

75-09-2

Methylene Chloride

1.30E+04

1.01E-01

1.17E-05

9.02E-02

5.70E-02

1.30E+01

1.20E-02

4.30E+02

93-65-2

2-Methylnaphthalene

2.50E+01

5.22E-02

7.75E-06

2.10E-02

6.95E-03

1.60E+03

No Data

6.80E-02

95-48-7

2-Methylphenol (o-cresol)

2.60E+04

7.40E-02

8.30E-06

4.92E-05

2.00E-05

4.20E+01

4.95E-02

2.99E-01

91-20-3

Naphthalene

3.10E+01

5.90E-02

7.50E-06

1.97E-02

8.29E-03

5.00E+02

2.70E-03

8.50E-02

98-95-3

Nitrobenzene

2.09E+03

7.60E-02

8.60E-06

9.84E-04

3.99E-04

4.00E+01

1.76E-03

2.40E-01

86-30-6

N-Nitrosodiphenylamine

3.50E+01

2.83E-02

7.19E-06

2.10E-04

-------a

1.00E+03

1.00E-02

6.70E-04

621-64-7

N-Nitrosodi-n-propylamine

9.89E+03

5.87E-02

8.17E-06

9.20E-05

5.48E-05

1.45E+01

1.90E-03

1.30E-01

87-86-5

Pentachlorophenol

2.00E+03

5.60E-02

6.10E-06

9.84E-07

-------a

2.77E+03d

4.50E-04

3.20E-05

108-95-2

Phenol

8.30E+04

8.20E-02

9.10E-06

1.64E-05

6.67E-06

2.00E+01

9.90E-02

2.80E-01

1918-02-1

Picloram

4.30E+02

2.26E-02

5.64E-06

2.19E-12

-------a

2.00E+00

No Data

7.21E-11

1336-36-3

Polychlorinated biphenyls (PCBs)

-------a

-------a

-------a

-------a

-------a

-------a

-------a

-------a

129-00-0

Pyrene

1.40E+00

2.77E-02

7.24E-06

4.51E-04

-------a

6.31E+04

1.80E-04

4.60E-06

121-82-4

Royal Demolition Explosive, Cyclonite (RDX)

5.97E+01

3.11E-02

8.49E-06

2.01E-11

-------a

7.20E+00

No Data

4.10E-09

122-34-9

Simazine

6.20E+00

2.48E-02

6.28E-06

3.80E-08

-------a

1.32E+02

No Data

2.21E-08

100-42-5

Styrene

3.10E+02

7.10E-02

8.00E-06

1.11E-01

5.48E-03

3.16E+02

3.30E-03

6.10E+00

93-72-1

2,4,5-TP (Silvex)

7.10E+01

2.30E-02

5.83E-06

3.71E-07

-------a

5.50E+03

No Data

9.97E-06

127-18-4

Tetrachloroethylene

2.00E+02

7.20E-02

8.20E-06

7.38E-01

4.00E-01

6.31E+02

9.60E-04

1.90E+01

108-88-3

Toluene

5.30E+02

8.70E-02

8.60E-06

2.71E-01

1.49E-01

1.58E+02

1.10E-02

2.80E+01

8001-35-2

Toxaphene

7.40E-01

2.16E-02

5.51E-06

2.46E-04

-------a

5.01E+04

No Data

9.80E-07

120-82-1

1,2,4-Trichlorobenzene

3.50E+01

3.00E-02

8.23E-06

5.74E-02

2.38E-02

1.58E+03

1.90E-03

4.30E-01

71-55-6

1,1,1-Trichloroethane

1.30E+03

7.80E-02

8.80E-06

6.97E-01

4.21E-01

1.26E+02

1.30E-03

1.20E+02

79-00-5

1,1,2-Trichloroethane

4.40E+03

7.80E-02

8.80E-06

3.73E-02

1.98E-02

5.01E+01

9.50E-04

2.30E+01

79-01-6

Trichloroethylene

1.50E+03

7.90E-02

9.10E-06

4.10E-01

2.41E-01

1.00E+02

4.20E-04

7.30E+01

75-69-4

Trichlorofluoromethane

1.10E+03

8.70E-02

9.70E-06

3.98E+00

2.69E+00

1.30E+02

9.63E-04

8.00E+02

95-95-4

2,4,5-Trichlorophenol

1.20E+03

2.91E-02

7.03E-06

1.78E-04

-------a

2.68E+03d

3.80E-04

2.40E-02

88-06-2

2,4,6-Trichlorophenol

8.00E+02

2.61E-02

6.36E-06

3.53E-04

-------a

8.78E+02 d

3.80E-04

2.00E-02

108-05-4

Vinyl Acetate

2.00E+04

8.50E-02

9.20E-06

2.09E-02

1.18E-02

4.57E+00

No Data

9.00E+01

99-35-4

1,3,5-Trinitrobenzene

2.80E+02

2.41E-02

6.08E-06

3.30E-10

-------a

1.60E+01

No Data

6.40E-06

118-96-7

2,4,6-Trinitrotoluene (TNT)

1.24E+02

2.94E-02

7.90E-06

4.87E-09

-------a

3.72E+01

1.92E-03

2.02E-06

57-01-4

Vinyl Chloride

8.80E+03

1.06E-01

1.23E-06

1.11E+00

8.14E-01

1.58E+01

2.40E-04

3.00E+03

108-38-3

m-Xylene

1.60E+02

7.00E-02

7.80E-06

2.99E-01

1.52E-01

3.98E+02

1.90E-03

8.50E+00

95-47-6

o-Xylene

1.80E+02

8.70E-02

1.00E-05

2.13E-01

1.07E-01

3.16E+02

1.90E-03

6.60E+00

106-42-3

p-Xylene

1.60E+02

7.69E-02

8.44E-06

3.16E-01

1.59E-01

3.16E+02

1.90E-03

8.90E+00

1330-20-7

Xylenes (total)

1.10E+02

7.35E-02

9.23E-06

2.71E-01

NA

3.98E+02

1.90E-03

8.00E+00

Chemical Abstracts Service (CAS) registry number. This number in the format xxx-xx-x, is unique for each chemical and allows efficient searching on computerized data bases.

a Soil remediation objectives are determined pursuant to 40 CFR 761, as incorporated by reference at Section 742.210(b) (the USEPA "PCB Spill Cleanup Policy"), for most sites; persons remediating sites should consult with BOL if calculation of Tier 2 or 3 remediation objectives is desired. PCBs are a mixture of different congeners. The appropriate values to use for the physical/chemical parameters depend on congeners present at the site.

b Dimensionless Henry's Law Constant at 13°C is not calculated because the chemical is not volatile and does not require evaluation under the indoor inhalation exposure route.

c Dimensionless Henry's Law Constant = 20°C

d These chemicals are ionizing and its Koc value will change with pH. The Koc values listed in this table is the effective Koc at pH of 6.8. If the site-specific pH is values other than 6.8, the Koc value listed Appendix C, Table I should be used.

e The values in this table were taken from the following sources (in order of preference): SCDMS online database (http://www.epa.gov/superfund/sites/npl/hrsres/tools/scdm.htm); CHEMFATE online database (http://www.srcinc.com/what-we-do/databaseforms.aspx?id=381); PhysProp online database (http://www.srcinc.com/what-we-do/databaseforms.aspx?id-386); Water (http://www.epa.gov/ttn/chief/software/water/) for diffusivity values; and Handbook of Environmental Degradation Rates by P.H. Howard (1991) for first order degradation constant values.

Disclaimer: These regulations may not be the most recent version. Illinois may have more current or accurate information. We make no warranties or guarantees about the accuracy, completeness, or adequacy of the information contained on this site or the information linked to on the state site. Please check official sources.
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