Illinois Administrative Code
Title 35 - ENVIRONMENTAL PROTECTION
Part 742 - TIERED APPROACH TO CORRECTIVE ACTION OBJECTIVES
Subpart L - BUILDING CONTROL TECHNOLOGIES
Appendix B - Tier 1 Illustrations and Tables
Table H - Tier 1 Soil Gas and Groundwater Remediation Objectives for the Indoor Inhalation Exposure Route - Diffusion and Advectionj

Universal Citation: 35 IL Admin Code ยง H
Current through Register Vol. 48, No. 38, September 20, 2024

Qsoil equals 83.33 cm3/seca

Soil Gas

Groundwater

CAS No.

Chemical Name

Residential

(mg/m3)

Industrial/

Commercial

(mg/m3)

Residential

(mg/L)

Industrial/

Commercial (mg/L)

67-64-1

Acetone

750,000f

750,000f

1,000,000g

1,000,000g

71-43-2

Benzene

0.37c

2.8c

0.11c

0.41c

111-44-4

Bis(2-chloroethyl)ether

0.014c

0.087c

0.083c

0.43c

75-27-4

Bromodichloromethane

450,000f

450,000f

6,700g

6,700g

75-25-2

Bromoform

11c

52c

3.1c

12c

71-36-3

Butanol

29,000f

29,000f

74,000g

74,000g

78-93-3

2-Butanone (MEK)

6,400b

40,000b

10,000b

48,000b

75-15-0

Carbon disulfide

780b

5,300b

67b

210b

56-23-5

Carbon tetrachloride

0.21c

1.5c

0.020c

0.076c

108-90-7

Chlorobenzene

69b

420b

26b

82b

124-48-1

Chlorodibromomethane

57,000f

57,000f

2,600g

2,600g

67-66-3

Chloroform

0.11c

0.92c

0.07i

0.15c

95-57-8

2-Chlorophenol

17,000f

17,000f

22,000g

22,000g

75-99-0

Dalapone

1,500f

1,500f

900,000g

900,000g

96-12-8

1,2-Dibromo-3-chloropropanee

0.0012c

0.0062c

0.00065c

0.0027c

106-93-4

1,2-Dibromoethane

0.0078c

0.048c

0.0035c

0.014c

95-50-1

1,2-Dichlorobenzene

290b

1,700b

140b

160g

106-46-7

1,4-Dichlorobenzene

1,200b

6,800b

79g

79g

75-71-8

Dichlorodifluoromethane

270b

1,700b

3.0b

9.2b

75-34-3

1,1-Dichloroethane

690b

4,200b

180b

580b

107-06-2

1,2-Dichloroethane

0.099c

0.81c

0.054c

0.22c

75-35-4

1,1-Dichloroethylene

240b

1,600b

24b

74b

156-59-2

cis-1,2-Dichloroethylene

1,100,000f

1,100,000f

3,500g

3,500g

156-60-5

trans-1,2-Dichloroethylene

85b

510b

16b

51b

78-87-5

1,2-Dichloropropane

0.31c

2.3c

0.12c

0.48c

542-75-6

1,3-Dichloropropylene (cis + trans)

0.90c

6.2c

0.14c

0.52c

123-91-1

p-Dioxane

0.22c

2.3c

2.9c

25c

100-41-4

Ethylbenzene

1,3c

9.3c

0.37c

1.4c

76-44-8

Heptachlor

0.0063c

0.032c

0.0025c

0.0096c

118-74-1

Hexachlorobenzene

0.0087c

0.057c

0.0059c

0.0062g

77-47-4

Hexachlorocyclopentadiene

0.58b

2.6b

0.084b

0.26b

67-72-1

Hexachloroethane

2,800f

2,800f

50g

50g

78-59-1

Isophorone

2,900b

3,400f

12,000g

12,000g

98-82-8

Isopropylbenzene (Cumene)

600b

3,500b

2.7b

8.4b

7439-97-6

Mercuryh

0.42b

2.5b

0.053b

0.060g

74-83-9

Methyl bromide

6.9b

42b

1.5b

4.8b

1634-04-4

Methyl tertiary-butyl ether

3,700b

24,000b

1,900b

6,800b

75-09-2

Methylene chloride

5.6c

45c

2.1c

8.2c

91-57-6

2-Methylnaphthalene

530f

530f

25g

25g

95-48-7

2-Methylphenol (o-cresol)

600b

1,800f

26,000g

26,000g

91-20-3

Naphthalene

0.11c

0.75c

0.075c

0.32c

98-95-3

Nitrobenzene

0.077c

0.57c

0.34c

2.0c

621-64-7

n-Nitrosodi-n-propylamine

0.0016c

0.012c

0.044c

0.27c

108-95-2

Phenol

140b

1,300b

28,000b

83,000g

1336-36-3

Polychlorinated biphenyls (PCBs)

---d

---d

---d

---d

100-42-5

Styrene

1,400b

8,500b

310g

310g

127-18-4

Tetrachloroethylene

0.55c

4.0c

0.091c

0.34c

108-88-3

Toluene

6,200b

40,000b

530g

530g

120-82-1

1,2,4-Trichlorobenzene

5.4b

25b

1.8b

5.9b

71-55-6

1,1,1-Trichloroethane

6,600b

41,000b

1,000b

1,300g

79-00-5

1,1,2-Trichloroethane

170,000f

170,000f

4,400g

4,400g

79-01-6

Trichloroethylene

1.5c

12c

0.34c

1.3c

75-69-4

Trichlorofluoromethane

860b

5,600b

26b

82b

108-05-4

Vinyl acetate

250b

1,600b

160b

550b

75-01-4

Vinyl chloride

0.29c

4.8c

0.028c

0.21c

108-38-3

m-Xylene

140b

850b

43b

130b

95-47-6

o-Xylene

120b

790b

40b

130b

106-42-3

p-Xylene

130b

820b

38b

120b

1330-20-7

Xylenes (total)e

140b

840b

30b

93b

Chemical Name and Remediation Objective Notations

a Compliance is determined by meeting either the soil gas remediation objectives or the groundwater remediation objectives. See Sections 742.505 and 742.515.

b Calculated values correspond to a target hazard quotient of 1.

c Calculated values correspond to a cancer risk level of 1 in 1,000,000.

d PCBs are a mixture of different congeners. The appropriate values to use for the physical/chemical and toxicity parameters depend on the congeners present at the site. Persons remediating sites should consult with BOL if calculation of Tier 2 or 3 remediation objectives is desired.

e Groundwater remediation objective calculated at 25°C. For Dalapon and 1,2-Dibromo-3-chloropropane, the critical temperature (Tc) and enthalpy of vaporization at the normal boiling point (Hv,b) are not available. For Xylenes (total), the enthalpy of vaporization at the normal boiling point (Hv,b) is not available.

f The value shown is the Cvsat value of the chemical in soil gas. The Cvsat of the chemical becomes the remediation objective if the calculated value exceeds the Cvsat value or if there are no toxicity criteria available for the inhalation route of exposure.

g The value shown is the solubility of the chemical in water. The solubility of the chemical becomes the remediation objective if the calculated value exceeds the solubility or if there are no toxicity criteria available for the ingestion route of exposure.

h Value for the inhalation exposure route is based on Reference Concentration for elemental Mercury (CAS No. 7439-97-6). Inhalation remediation objectives only apply at sites where elemental Mercury is a contaminant of concern.

i The value shown is the Groundwater Remediation Objective listed in Appendix B, Table E.

j Calculated values for the remediation objectives in this table are based on the assumption that the existing or potential building has a full concrete slab-on-grade, though the remediation objectives in this table are also considered protective of occupants of buildings with full concrete basement floors and walls. This table applies only when the existing or potential building has a full concrete slab-on-grade or a full concrete basement floor and walls. Institutional controls under Subpart J are required to use remediation objectives in this table. This table does not apply when the existing or potential building has neither a full concrete slab-on-grade nor a full concrete basement floor and walls, such as a building with an earthen crawl space, an earthen floor, a stone foundation, a partial concrete floor, or a sump. In such cases, site evaluators have the option of excluding the indoor inhalation exposure route under Section 742.312, meeting the building control technology requirements under Subpart L, or proposing an alternative approach under Tier 3.

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