Current through Register Vol. 48, No. 38, September 20, 2024
Analytical methods are from documents incorporated by
reference in Section 611.102. The substantive rules
mostly reference these by a short name Section
611.102(a)
defines. Section 611.101 defines other
abbreviations.
a) A certified
laboratory must conduct analyses for contaminants in this Section using the
indicated methods or an alternative method the Agency approved under Section
611.480. USEPA Technical Notes,
incorporated by reference in Section 611.102, includes criteria for analyzing
arsenic, barium, beryllium, cadmium, calcium, chloride, chromium, copper, lead,
nickel, selenium, sodium, sulfate, and thallium with digestion or directly
without digestion, and other analytical procedures.
BOARD NOTE: Because a laboratory determines MDLs it reports
under USEPA 200.7 (94) and
USEPA 200.9 (94)
using a 2a preconcentration step during sample digestion, MDLs the laboratory
determines analyzing samples by direct analysis (i.e., no sample digestion) are
higher. For direct analysis of cadmium and arsenic using USEPA
200.7 (94) and
arsenic using SM 3120 B (89), SM 3120 B (93), or SM 3120 B (99), it may be
necessary to engage in sample preconcentration using pneumatic nebulization to
achieve lower detection limits. Direct analysis of antimony, lead, and thallium
using USEPA 200.9 (94);
antimony and lead using SM 3113 B (89), SM 3113 B (99), or SM 3113 B (10); and
lead using ASTM D3559-96 D, ASTM D3559-03 D, ASTM D3559-08 D, or ASTM D3559-15
D may require preconcentration, unless the laboratory makes multiple in-furnace
depositions.
1) Alkalinity
A) Titrimetric. ASTM D1067-92 B, ASTM
D1067-02 B, ASTM D1067-06 B, ASTM D1067-11 B, ASTM D1067-16 B, SM 2320 B (91),
or SM 2320 B (97).
B) Electrometric
Titration. USGS I-1030-85.
2) Antimony
A) Inductively Coupled Plasma-Mass
Spectrometry. USEPA 200.8
(94).
B) Atomic Absorption, Hydride Technique. ASTM
D3697-92, ASTM D3697-02, ASTM D3697-07, ASTM D3697-12, or ASTM
D3697-17.
C) Atomic Absorption,
Platform Furnace Technique. USEPA
200.9
(94).
D) Atomic Absorption, Furnace Technique. SM
3113 B (89), SM 3113 B (93), SM 3113 B (99), SM 3113 B (04), or SM 3113 B
(10).
E) Axially Viewed Inductively
Coupled Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5
(03).
3) Arsenic
BOARD NOTE: If the laboratory uses ultrasonic nebulization in
determining arsenic using USEPA
200.8 (94), the
arsenic must be in the pentavalent state to provide uniform signal response.
For direct analysis of arsenic with USEPA
200.8 (94)
using ultrasonic nebulization, samples and standards must contain one mg/L of
sodium hypochlorite.
A) Inductively
Coupled Plasma-Mass Spectrometry. USEPA
200.8
(94).
B) Atomic Absorption, Platform Furnace
Technique. USEPA 200.9
(94).
C) Atomic Absorption, Furnace Technique. ASTM
D2972-97 C, ASTM D2972-03 C, ASTM D2972-08 C, ASTM D2972-15 C, SM 3113 B (89),
SM 3113 B (93), 3113 B (99), 3113 B (04), or 3113 B (10).
D) Atomic Absorption, Hydride Technique. ASTM
D2972-97 B, ASTM D2972-03 B, ASTM D2972-08 B, ASTM D2972-15 B, SM 3114 B (89),
SM 3114 B (93), SM 3114 B (97), SM 3114 B (04), or SM 3114 B (09).
E) Axially Viewed Inductively Coupled
Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5
(94).
4) Asbestos. Transmission Electron
Microscopy. USEPA 100.1 (83) or
USEPA 100.2
(94).
5) Barium
A) Inductively Coupled Plasma. USEPA
200.7(94), SM
3120 B (83), SM 3120 B (93), or SM 3120 B (99).
B) Inductively Coupled Plasma-Mass
Spectrometry. USEPA 200.8
(94).
C) Atomic Absorption, Direct Aspiration
Technique. SM 3111 D (89), SM 3111 D (93), or SM 3111 D (99).
D) Atomic Absorption, Furnace Technique. SM
3113 B (89), SM 3113 B (93), SM 3113 B (99), SM 3113 B (04), and SM 3113 B
(10).
E) Axially Viewed Inductively
Coupled Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5
(03).
6) Beryllium
A) Inductively Coupled Plasma. USEPA
200.7(94), SM
3120 B (83), SM 3120 B (93), or SM 3120 B (99).
B) Inductively Coupled Plasma-Mass
Spectrometry. USEPA 200.8
(94).
C) Atomic Absorption, Platform Furnace
Technique. USEPA 200.9
(94).
D) Atomic Absorption, Furnace Technique. ASTM
D3645-97 B, ASTM D3645-03 B, ASTM D3645-08 B, ASTM D3645-15 B, SM 3113 B (89),
SM 3113 B (93), SM 3113 B (99), SM 3113 B (04), or SM 3113 B (10).
E) Axially Viewed Inductively Coupled
Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5
(03).
7) Cadmium
A) Inductively Coupled Plasma Arc Furnace.
USEPA 200.7
(94).
B) Inductively Coupled Plasma-Mass
Spectrometry. USEPA 200.8
(94).
C) Atomic Absorption, Platform Furnace
Technique. USEPA 200.9
(94).
D) Atomic Absorption, Furnace Technique. SM
3113 B (89), SM 3113 B (93), SM 3113 B (99), SM 3113 B (04), and SM 3113 B
(10).
E) Axially Viewed Inductively
Coupled Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5
(03).
8) Calcium
A) EDTA Titrimetric. ASTM D511-93 A, ASTM
D511-03 A, ASTM D511-09 A, ASTM D511-14 A, SM 3500-Ca B (97), or 3500-Ca D
(91).
B) Atomic Absorption, Direct
Aspiration. ASTM D511-93 B, ASTM D511-03 B, ASTM D511-09 B, ASTM D511-14 B, SM
3111 B (89), SM 3111 B (93), or SM 3111 B (99).
C) Inductively Coupled Plasma. USEPA
200.7(94), SM
3120 B (83), SM 3120 B (93), or SM 3120 B (99).
D) Ion Chromatography. ASTM D6919-03, ASTM
D6919-09, or ASTM D6919-17.
E)
Axially Viewed Inductively Coupled Plasma-Atomic Emission Spectrometry
(AVICP-AES). USEPA 200.5
(03).
9) Chloride. Ion Chromatography. ASTM
D4327-17.
10) Chromium
A) Inductively Coupled Plasma. USEPA
200.7(94), SM
3120 B (83), SM 3120 B (93), or SM 3120 B (99).
B) Inductively Coupled Plasma-Mass
Spectrometry. USEPA 200.8
(94).
C) Atomic Absorption, Platform Furnace
Technique. USEPA 200.9
(94).
D) Atomic Absorption, Furnace Technique. SM
3113 B (89), SM 3113 B (93), SM 3113 B (99), SM 3113 B (04), and SM 3113 B
(10).
E) Axially Viewed Inductively
Coupled Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5(03).
11) Copper
A) Atomic Absorption, Furnace Technique. ASTM
D1688-95 C, ASTM D1688-02 C, ASTM D1688-07 C, ASTM D1688-12 C, ASTM D1688-17 C,
SM 3113 B (89), SM 3113 B (93), SM 3113 B (99), SM 3113 B (04), and SM 3113 B
(10).
B) Atomic Absorption, Direct
Aspiration. ASTM D1688-95 A, ASTM D1688-02 A, ASTM D1688-07 A, ASTM D1688-12 A,
ASTM D1688-17 A, SM 3111 B (89), SM 3111 B (93), or SM 3111 B (99).
C) Inductively Coupled Plasma. USEPA
200.7(94), SM
3120 B (83), SM 3120 B (93), or SM 3120 B (99).
D) Inductively Coupled Plasma-Mass
Spectrometry. USEPA 200.8
(94).
E) Atomic Absorption, Platform Furnace
Technique. USEPA 200.9
(94).
F) Axially Viewed Inductively Coupled
Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5
(03).
G) Colorimetric. Hach 8026 (15) or Hach 10272
(15).
12) Conductivity;
Conductance. ASTM D1125-95 (1999) A, ASTM D1125-14 A, SM 2510 B (91), or SM
2510 B (97).
13) Cyanide
A) Manual Distillation with
MgCl2. (ASTM D2036-98 A, ASTM D2036-06 A, SM
4500-CN- C (90), SM
4500-CN- C (97), SM
4500-CN- C (99), or SM
4500-CN- C (16)), followed by spectrophotometric,
amenable (ASTM D2036-98 B, ASTM D2036-06 B, SM
4500-CN- G (90), SM
4500-CN- G (97), SM
4500-CN- G (99), or SM
4500-CN- G (16)).
B) Manual Distillation with
MgCl2. Distillation (ASTM D2036-98 A or ASTM D2036-06 A
or SM 4500-CN- C (90), SM
4500-CN- C (97), SM
4500-CN- C (99), or SM
4500-CN- C (16)), followed by Spectrophotometric,
Manual (ASTM D2036-98 A, ASTM D2036-06 A, SM
4500-CN- E (90), 4500-CN-
E (97), 4500-CN- E (99),
4500-CN- E (16), or USGS I-3300-85).
C) Spectrophotometric, Semiautomated. USEPA
335.4
(93).
D) Selective Electrode. SM
4500-CN- F (90), SM
4500-CN- F (97), SM
4500-CN- F (99), or SM
4500-CN- F (16).
E) UV/Distillation/Spectrophotometric. Kelada
01 (01).
F) Microdistillation/Flow
Injection/Spectrophotometric. QuikChem 10-204-00-1-X (00).
G) Ligand Exchange and Amperometry. ASTM
D6888-04 or OIA-1677 DW (04).
H)
Gas Chromatography-Mass Spectrometry Headspace. ME355.01
(09).
14) Fluoride
A) Ion Chromatography. USEPA
300.0 (93),
USEPA 300.1 (97),
ASTM D4327-97, ASTM D4327-03, ASTM D4327-11, ASTM D4327-17, SM 4110 B (90), SM
4110 B (91), SM 4110 B (97), or SM 4110 B (00).
B) Manual Distillation, Colorimetric SPADNS.
SM 4500-F- B (88), SM
4500-F- B (94), SM
4500-F- B (97), SM
4500-F-, D (88), SM
4500-F- B (94), or SM
4500-F- B (97).
C) Manual Electrode. ASTM D1179-93 B, ASTM
D1179-99 B, ASTM D1179-04 B, ASTM D1179-10 B, ASTM D1179-16 B, SM
4500-F- C (88), SM
4500-F- C (94), or SM
4500-F- C (97).
D) Automated Electrode. Technicon # 380-75WE
(76).
E) Automated Alizarin. SM
4500-F- E (88), SM
4500-F- E (94), SM
4500-F- E (97), or Technicon #129-71W.
F) Arsenite-Free Colorimetric SPADNS. Hach
10225 (11) (SPADNS 2).
G) Capillary
Ion Electrophoresis. ASTM D6508-00.
BOARD NOTE: On March 12, 2007 (at 72 Fed. Reg. 11200), USEPA
amended the entry for fluoride to add capillary ion electrophoresis in the
table at corresponding 40
CFR 141.23(k)(1) to allow
the use of "Waters Method D6508, Rev. 2". The Board cited the ASTM Method
D6508-00 (2005). On May 2, 2012 (at 77 Fed. Reg. 26072, 26096-97; in
corrections to UCMR 3), USEPA changed the entries for nitrate, nitrite, and
orthophosphate to ASTM D6508-00.
15) Lead
A)
Atomic Absorption, Furnace Technique. ASTM D3559-96 D, ASTM D3559-03 D, ASTM
D3559-08 D, ASTM D3559-15 D, SM 3113 B (89), SM 3113 B (93), SM 3113 B (99), SM
3113 B (04), or SM 3113 B (10).
B)
Inductively Coupled Plasma-Mass Spectrometry. USEPA
200.8
(94).
C) Atomic Absorption, Platform Furnace
Technique. USEPA 200.9
(94).
D) Differential Pulse Anodic Stripping
Voltammetry. Palintest 1001 (99).
E) Axially Viewed Inductively Coupled
Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5
(03).
F) Differential Pulse Anode Stripping
Voltametry. Palintest 1001 (20).
16) Magnesium
A) Atomic Absorption. ASTM D511-93 B, ASTM
D511-03 B, ASTM D511-09 B, ASTM D511-14 B, SM 3111 B (89), SM 3111 B (93), or
SM 3111 B (99).
B) Inductively
Coupled Plasma. USEPA
200.7 (94), SM
3120 B (89), SM 3120 B (93), or SM 3120 B (99).
C) Complexation Titrimetric. ASTM D511-93 A,
ASTM D511-03 A, ASTM D511-09 A, ASTM D511-14 A, SM 3500-Mg B (97), SM 3500-Mg E
(90), or SM 3500-Mg E (91).
D) Ion
Chromatography. ASTM D6919-03, ASTM D6919-09, or ASTM D6919-17.
E) Axially Viewed Inductively Coupled
Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5
(03).
17) Mercury
A) Manual Cold Vapor Technique. ASTM
D3223-97, ASTM D3223-02, ASTM D3223-12, ASTM D3223-17, SM 3112 B (88), SM 3112
B (93), SM 3112 B (99), SM 3112 B (09), or USEPA
245.1
(91).
B) Automated Cold Vapor Technique. USEPA
245.2
(74).
C) Inductively Coupled Plasma-Mass
Spectrometry. USEPA 200.8
(94).
18) Nickel
A) Inductively Coupled Plasma. SM 3120 B
(89), SM 3120 B (93), SM 3120 B (99), or USEPA
200.7
(94).
B) Inductively Coupled Plasma-Mass
Spectrometry. USEPA 200.8
(94).
C) Atomic Absorption, Platform Furnace
Technique. USEPA 200.9
(94).
D) Atomic Absorption, Direct Aspiration
Technique. SM 3111 B (89), 3111 B (93), or 3111 B (99).
E) Atomic Absorption, Furnace Technique. SM
3113 B (89), SM 3113 B (93), SM 3113 B (99), SM 3113 B (04), or SM 3113 B
(10).
F) Axially Viewed Inductively
Coupled Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5(03).
19) Nitrate
A) Ion Chromatography. ASTM D4327-97, ASTM
D4327-03, ASTM D4327-11, ASTM D4327-17, SM 4110 B (90), SM 4110 B (97), SM 4110
B (00), USEPA 300.0 (93),
USEPA 300.1 (97), or
Waters B-1011 (87).
B) Automated
Cadmium Reduction. ASTM D3867-90 A; SM
4500-NO3- F (88),
4500-NO3- F (93),
4500-NO3- F (97),
4500-NO3- F (00),
4500-NO3- F (16), or USEPA
353.2
(93).
C) Ion Selective Electrode. ATI Orion
Technical Bulletin 601 (94), SM
4500-NO3- D (88), SM
4500-NO3- D (93), SM
4500-NO3- D (97), SM
4500-NO3- D (00), or SM
4500-NO3- D (16).
D) Manual Cadmium Reduction. ASTM D3867-90 B,
SM 4500-NO3- E (88), SM
4500-NO3- E (93), SM
4500-NO3- E (97), SM
4500-NO3- E (00), or SM
4500-NO3- E (16).
E) Capillary Ion Electrophoresis. ASTM
D6508-00 or ASTM D6508-15.
F)
Reduction-Colorimetric. Systea Easy (1-Reagent) (09) or NECi Nitrate-Reductase
(06).
G) Direct Colorimetric. Hach
10206 (TNTplus 835/836).
20) Nitrite
A) Ion Chromatography. ASTM D4327-97, ASTM
D4327-03, ASTM D4327-11, ASTM D4327-17, SM 4110 B (90), SM 4110 B (97), SM 4110
B (00), USEPA 300.0 (93),
USEPA 300.1 (97), or
Waters B-1011 (87).
B) Automated
Cadmium Reduction. ASTM D3867-90 A, SM
4500-NO3- F (93),
4500-NO3- F (97),
4500-NO3- F (00),
4500-NO3- F (16), or USEPA
353.2
(93).
C) Manual Cadmium Reduction. ASTM D3867-90 B,
SM 4500-NO3- E (93),
4500-NO3- E (97),
4500-NO3- E (00), or
4500-NO3- E (16).
D) Spectrophotometric. SM
4500-NO2- B (88),
4500-NO2- B (93), or
4500-NO2- B (00).
E) Capillary Ion Electrophoresis. ASTM
D6508-00 or ASTM D6508-15.
F)
Reduction-Colorimetric. Systea Easy (1-Reagent) (09) or NECi Nitrate-Reductase
(06).
21) Orthophosphate
(unfiltered, without digestion or hydrolysis)
A) Automated Colorimetric, Ascorbic Acid. SM
4500-P F (88), SM 4500-P F (93), SM 4500-P F (97), SM 4500-P F (99), SM 4500-P
F (05), Thermo-Fisher Discrete Analyzer (16), or USEPA
365.1
(93).
B) Single-Reagent Colorimetric, Ascorbic
Acid. ASTM D515-88 A, SM 4500-P E (88), 4500-P E (93), 4500-P E (97), or 4500-P
E (99), or 4500-P E (05).
C)
Colorimetric, Phosphomolybdate. USGS I-1601-85.
D) Phosphorus, Orthophosphate, Colorimetry,
Phosphomolybdate, Automated-Segmented Flow. USGS I-2601-90.
E) Colorimetric, Phosphomolybdate, Automated
Discrete. USGS I-2598-85.
F) Ion
Chromatography. ASTM D4327-97, ASTM D4327-03, ASTM D4327-11, ASTM D4327-17, SM
4110 B (90), SM 4110 B (91), SM 4110 B (97), SM 4110 B (00), USEPA
300.0 (93), or
USEPA 300.1
(97).
G) Capillary Ion Electrophoresis. ASTM
D6508-00 or ASTM D6508-15.
22) pH, Electrometric. ASTM D1293-95, ASTM
D1293-99, ASTM D1293-12, ASTM D1293-18, SM 4500-H+ B
(90), SM 4500-H+ B (96), SM
4500-H+ B (00), USEPA
150.1 (71),
USEPA 150.2 (82), or
USEPA 150.3
(13).
23) Selenium
A) Atomic Absorption, Hydride. ASTM D3859-98
A, ASTM D3859-03 A, ASTM D3859-08 A, ASTM D3859-15 A, SM 3114 B (89), SM 3114
(93), SM 3114 (97), or SM 3114 (09).
B) Inductively Coupled Plasma-Mass
Spectrometry. USEPA 200.8
(94).
C) Atomic Absorption, Platform Furnace
Technique. USEPA 200.9
(94).
D) Atomic Absorption, Furnace Technique. ASTM
D3859-98 B, ASTM D3859-03 B, ASTM D3859-08 B, ASTM D3859-15 B, SM 3113 B (89),
SM 3113 B (93), SM 3113 B (99), SM 3113 B (04), or SM 3113 B (10).
E) Axially Viewed Inductively Coupled
Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5
(03).
24) Silica
A) Colorimetric, Molybdate Blue. USGS
I-1700-85.
B) Colorimetric,
Molybdate Blue, Automated-Segmented Flow. USGS I-2700-85.
C) Colorimetric. ASTM D859-94, ASTM D859-00,
ASTM D859-05, ASTM D859-10, or ASTM D859-16.
D) Molybdosilicate. SM 4500-Si D (88), SM
4500-Si D (93), or SM 4500-SiO2 C (97).
E) Heteropoly Blue. SM 4500-Si E (88), SM
4500-Si E (93), or SM 4500-SiO2 D (97).
F) Automated Method for Molybdate-Reactive
Silica. SM 4500-Si F (88), SM 4500-Si F (93), or SM
4500-SiO2 E (97).
G) Inductively Coupled Plasma. SM 3120 B
(89), SM 3120 B (93), SM 3120 B (99), or USEPA
200.7
(94).
H) Axially Viewed Inductively Coupled
Plasma-Atomic Emission Spectrometry (AVICP-AES). USEPA
200.5
(03).
25) Sodium
A) Inductively Coupled Plasma. USEPA
200.7(94).
B) Atomic Absorption, Direct Aspiration. SM
3111 B (89), SM 3111 B (93), or SM 3111 B (99).
C) Ion Chromatography. ASTM D6919-03, ASTM
D6919-09, or ASTM D6919-17.
D)
Axially Viewed Inductively Coupled Plasma-Atomic Emission Spectrometry
(AVICP-AES). USEPA 200.5
(03).
26) Sulfate. Ion Chromatography. ASTM
D4327-17.
27) Temperature;
Thermometric. SM 2550 (88), SM 2550 (93), SM 2550 (00), or SM 2550
(10).
28) Thallium
A) Inductively Coupled Plasma-Mass
Spectrometry. USEPA 200.8
(94).
B) Atomic Absorption, Platform Furnace
Technique. USEPA 200.9
(94).
b) The supplier must use specific sample
preservation, container, and maximum holding time procedures when collecting
samples for antimony, arsenic, asbestos, barium, beryllium, cadmium, chromium,
cyanide, fluoride, mercury, nickel, nitrate, nitrite, selenium, and thallium
under Sections 611.600 through
611.604:
BOARD NOTE: For cyanide determinations, the supplier must
adjust samples to pH 12 with sodium hydroxide to pH 12 when collecting them.
When a sample needs chilling, the supplier must ship and store the sample at
4° C or less. The supplier may acidify nitrate or metals samples using a
concentrated acid or a dilute (50% by volume) solution of the concentrated
acid. USEPA encourages acidifying samples for metals analysis and that the
laboratory acidify, rather than at the time of sampling, provided the supplier
follows the shipping time and other instructions in Section
8.3 of USEPA
200.7 (94),
USEPA 200.8 (94), or
USEPA 200.9
(94).
1) Antimony
A) Preservative: Concentrated nitric acid to
pH less than 2.
B) Plastic or glass
(hard or soft).
C) Holding Time.
Samples must be analyzed as soon after collection as possible, but in any event
within six months.
2)
Arsenic
A) Preservative: Concentrated nitric
acid to pH less than 2.
B) Plastic
or glass (hard or soft).
C) Holding
Time. Samples must be analyzed as soon after collection as possible, but in any
event within six months.
3) Asbestos
A) Preservative: Cool to 4° C.
B) Plastic or glass (hard or soft).
C) Holding Time. Samples must be analyzed as
soon after collection as possible, but in any event within 48 hours.
4) Barium
A) Preservative: Concentrated nitric acid to
pH less than 2.
B) Plastic or glass
(hard or soft).
C) Holding Time.
Samples must be analyzed as soon after collection as possible, but in any event
within six months.
5)
Beryllium
A) Preservative: Concentrated nitric
acid to pH less than 2.
B) Plastic
or glass (hard or soft).
C) Holding
Time. Samples must be analyzed as soon after collection as possible, but in any
event within six months.
6) Cadmium
A) Preservative: Concentrated nitric acid to
pH less than 2.
B) Plastic or glass
(hard or soft).
C) Holding Time.
Samples must be analyzed as soon after collection as possible, but in any event
within six months.
7)
Chromium
A) Preservative: Concentrated nitric
acid to pH less than 2.
B) Plastic
or glass (hard or soft).
C) Holding
Time. Samples must be analyzed as soon after collection as possible, but in any
event within six months.
8) Cyanide
A) Preservative: Cool to 4° C. Add sodium
hydroxide to pH greater than 12. See the analytical methods for information on
sample preservation.
B) Plastic or
glass (hard or soft).
C) Holding
Time. Samples must be analyzed as soon after collection as possible, but in any
event within 14 days.
9)
Fluoride
A) Preservative: None.
B) Plastic or glass (hard or soft).
C) Holding Time. Samples must be analyzed as
soon after collection as possible, but in any event within one month.
10) Mercury
A) Preservative: Concentrated nitric acid to
pH less than 2.
B) Plastic or glass
(hard or soft).
C) Holding Time.
Samples must be analyzed as soon after collection as possible, but in any event
within 28 days.
11)
Nickel
A) Preservative: Concentrated nitric
acid to pH less than 2.
B) Plastic
or glass (hard or soft).
C) Holding
Time. Samples must be analyzed as soon after collection as possible, but in any
event within six months.
12) Nitrate, Chlorinated
A) Preservative: Cool to 4° C.
B) Plastic or glass (hard or soft).
C) Holding Time. Samples must be analyzed as
soon after collection as possible, but in any event within 14 days.
13) Nitrate, Non-Chlorinated
A) Preservative: Concentrated sulfuric acid
to pH less than 2.
B) Plastic or
glass (hard or soft).
C) Holding
Time. Samples must be analyzed as soon after collection as possible, but in any
event within 14 days.
14) Nitrite
A) Preservative: Cool to 4° C.
B) Plastic or glass (hard or soft).
C) Holding Time. Samples must be analyzed as
soon after collection as possible, but in any event within 48 hours.
15) Selenium
A) Preservative: Concentrated nitric acid to
pH less than 2.
B) Plastic or glass
(hard or soft).
C) Holding Time.
Samples must be analyzed as soon after collection as possible, but in any event
within six months.
16)
Thallium
A) Preservative: Concentrated nitric
acid to pH less than 2.
B) Plastic
or glass (hard or soft).
C) Holding
Time. Samples must be analyzed as soon after collection as possible, but in any
event within six months.
BOARD NOTE: Derived from
40 CFR
141.23(k) and appendix A to
subpart C of 40 CFR 141 (2017).