Notice of Requests for Approval of Alternative Means of Emission Limitation, 18034-18042 [2018-08575]
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[FR Doc. 2018–08611 Filed 4–24–18; 8:45 am]
BILLING CODE 6717–01–P
ENVIRONMENTAL PROTECTION
AGENCY
[EPA–HQ–OAR–2014–0738 and EPA–HQ–
OAR–2010–0682; FRL–9976–29–OAR]
Notice of Requests for Approval of
Alternative Means of Emission
Limitation
Environmental Protection
Agency (EPA).
ACTION: Notice; request for comments.
AGENCY:
This action provides public
notice and solicits comment on the
alternative means of emission limitation
(AMEL) requests from ExxonMobil
Corporation; Marathon Petroleum
Company, LP (for itself and on behalf of
its subsidiary, Blanchard Refining, LLC);
and Chalmette Refining, LLC, under the
Clean Air Act (CAA), to operate flares at
several refineries in Texas and
Louisiana, as well as the AMEL request
from LACC, LLC to operate flares at a
chemical plant in Louisiana.
DATES: Comments. Comments must be
received on or before June 11, 2018.
Public Hearing. If a public hearing is
requested by April 30, 2018, then we
will hold a public hearing on May 10,
2018 at the location described in the
ADDRESSES section. The last day to preregister in advance to speak at the
public hearing will be May 8, 2018.
ADDRESSES: Comments. Submit your
comments, identified by Docket ID No.
EPA–HQ–OAR–2014–0738, at https://
www.regulations.gov. Follow the online
instructions for submitting comments.
Once submitted, comments cannot be
edited or removed from Regulations.gov,
Regulations.gov is our preferred method
of receiving comments. However, other
submission methods are accepted. To
ship or send mail via the United States
Postal Service, use the following
address: U.S. Environmental Protection
Agency, EPA Docket Center, Docket ID
No. EPA–HQ–OAR–2014–0738, Mail
Code 28221T, 1200 Pennsylvania
SUMMARY:
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Avenue NW, Washington, DC 20460.
Use the following Docket Center address
if you are using express mail,
commercial delivery, hand delivery, or
courier: EPA Docket Center, EPA WJC
West Building, Room 3334, 1301
Constitution Avenue NW, Washington,
DC 20004. Delivery verification
signatures will be available only during
regular business hours.
Do not submit electronically any
information you consider to be
Confidential Business Information (CBI)
or other information whose disclosure is
restricted by statue. See the
SUPPLEMENTARY INFORMATION section of
this preamble for instructions on
submitting CBI.
The EPA may publish any comment
received to its public docket.
Multimedia submissions (audio, video,
etc.) must be accompanied by a written
comment. The written comment is
considered the official comment and
should include discussion of all points
you wish to make. The EPA will
generally not consider comments or
comment contents located outside of the
primary submission (i.e., on the Web,
cloud, or other file sharing system). For
additional submission methods, the full
EPA public comment policy,
information about CBI or multimedia
submissions, and general guidance on
making effective comments, please visit
https://www2.epa.gov/dockets/
commenting-epa-dockets.
Public Hearing. If a public hearing is
requested, it will be held at EPA
Headquarters, EPA WJC East Building,
1201 Constitution Avenue NW,
Washington, DC 20004. If a public
hearing is requested, then we will
provide details about the public hearing
on our website at: https://
www3.epa.gov/ttn/atw/groundflares/
groundflarespg.html. The EPA does not
intend to publish another document in
the Federal Register announcing any
updates on the request for a public
hearing. Please contact Ms. Virginia
Hunt of the Sector Policies and
Programs Division (E143–01), Office of
Air Quality Planning and Standards,
Environmental Protection Agency,
Research Triangle Park, NC 27711;
telephone number: (919) 541–0832;
email address: hunt.virginia@epa.gov; to
request a public hearing, to register to
speak at the public hearing, or to inquire
as to whether or not a public hearing
will be held.
The EPA will make every effort to
accommodate all speakers who arrive
and register. If a hearing is held at a U.S.
government facility, individuals
planning to attend should be prepared
to show a current, valid state- or federalapproved picture identification to the
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security staff in order to gain access to
the meeting room. An expired form of
identification will not be permitted.
Please note that the Real ID Act, passed
by Congress in 2005, established new
requirements for entering federal
facilities. If your driver’s license is
issued by a noncompliant state, you
must present an additional form of
identification to enter a federal facility.
Acceptable alternative forms of
identification include: Federal
employee badge, passports, enhanced
driver’s licenses, and military
identification cards. Additional
information on the Real ID Act is
available at https://www.dhs.gov/realid-frequently-asked-questions. In
addition, you will need to obtain a
property pass for any personal
belongings you bring with you. Upon
leaving the building, you will be
required to return this property pass to
the security desk. No large signs will be
allowed in the building, cameras may
only be used outside of the building,
and demonstrations will not be allowed
on federal property for security reasons.
FOR FURTHER INFORMATION CONTACT: For
questions about this action, contact Ms.
Angie Carey, Sector Policies and
Programs Division (E143–01), Office of
Air Quality Planning and Standards
(OAQPS), U.S. Environmental
Protection Agency, Research Triangle
Park, North Carolina 27711; telephone
number: (919) 541–2187; fax number:
(919) 541–0516; and email address:
carey.angela@epa.gov.
SUPPLEMENTARY INFORMATION:
Docket. The EPA has established a
docket for this rulemaking under Docket
ID No. EPA–HQ–OAR–2014–0738. All
documents in the docket are listed in
the Regulations.gov index. Although
listed in the index, some information is
not publicly available, e.g., CBI or other
information whose disclosure is
restricted by statute. Certain other
material, such as copyrighted material,
is not placed on the internet and will be
publicly available only in hard copy.
Publicly available docket materials are
available either electronically in
Regulations.gov or in hard copy at the
EPA Docket Center, Room 3334, EPA
WJC West Building, 1301 Constitution
Avenue NW, Washington, DC. The
Public Reading Room is open from 8:30
a.m. to 4:30 p.m., Monday through
Friday, excluding legal holidays. The
telephone number for the Public
Reading Room is (202) 566–1744, and
the telephone number for the EPA
Docket Center is (202) 566–1742.
Instructions. Direct your comments to
Docket ID No. EPA–HQ–OAR–2014–
0738. The EPA’s policy is that all
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comments received will be included in
the public docket without change and
may be made available online at https://
www.regulations.gov, including any
personal information provided, unless
the comment includes information
claimed to be CBI or other information
whose disclosure is restricted by statute.
Do not submit information that you
consider to be CBI or otherwise
protected through https://
www.regulations.gov or email. This type
of information should be submitted by
mail as discussed below. The https://
www.regulations.gov website site is an
‘‘anonymous access’’ system, which
means the EPA will not know your
identity or contact information unless
you provide it in the body of your
comment. If you send an email
comment directly to the EPA without
going through https://
www.regulations.gov, your email
address will be automatically captured
and included as part of the comment
that is placed in the public docket and
made available on the internet. If you
submit an electronic comment, the EPA
recommends that you include your
name and other contact information in
the body of your comment and with any
disk or CD–ROM you submit. If the EPA
cannot read your comment due to
technical difficulties and cannot contact
you for clarification, the EPA may not
be able to consider your comment.
Electronic files should not include
special characters or any form of
encryption and be free of any defects or
viruses. For additional information
about the EPA’s public docket, visit the
EPA Docket Center homepage at https://
www.epa.gov/dockets.
Submitting CBI. Do not submit
information containing CBI to the EPA
through https://www.regulations.gov or
email. Clearly mark the part or all of the
information that you claim to be CBI.
For CBI information on a disk or CD–
ROM that you mail to the EPA, mark the
outside of the disk or CD–ROM as CBI
and then identify electronically within
the disk or CD–ROM the specific
information that is claimed as CBI. In
addition to one complete version of the
comments that includes information
claimed as CBI, you must submit a copy
of the comments that does not contain
the information claimed as CBI for
inclusion in the public docket. If you
submit a CD–ROM or disk that does not
contain CBI, mark the outside of the
disk or CD–ROM clearly that it does not
contain CBI. Information not marked as
CBI will be included in the public
docket and the EPA’s electronic public
docket without prior notice. Information
marked as CBI will not be disclosed
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except in accordance with procedures
set forth in 40 CFR part 2. Send or
deliver information identified as CBI
only to the following address: OAQPS
Document Control Officer (C404–02),
OAQPS, U.S. Environmental Protection
Agency, Research Triangle Park, North
Carolina 27711, Attention Docket ID No.
EPA–HQ–OAR–2014–0738.
Acronyms and Abbreviations. We use
multiple acronyms and terms in this
notice. While this list may not be
exhaustive, to ease the reading of this
notice and for reference purposes, the
EPA defines the following terms and
acronyms here:
AMEL alternative means of emission
limitation
BTU/scf British thermal units per standard
cubic foot
CAA Clean Air Act
CBI Confidential Business Information
CFR Code of Federal Regulations
EPA Environmental Protection Agency
Eqn equation
HAP hazardous air pollutants
LFL lower flammability limit
LFLcz lower flammability limit of
combustion zone gas
LFLvg lower flammability limit of flare vent
gas
LRGO linear relief gas oxidizer
MPGF multi-point ground flares
NESHAP national emission standards for
hazardous air pollutants
NHV net heating value
NHVcz net heating value of combustion
zone gas
NHVvg net heating value of flare vent gas
NSPS new source performance standards
OAQPS Office of Air Quality Planning and
Standards
scf standard cubic feet
SKEC steam-assisted kinetic energy
combustor
VOC volatile organic compounds
Organization of This Document. The
information in this notice is organized
as follows:
I. Background
A. Regulatory Flare Requirements and
AMEL Requests
II. Requests for AMEL
A. ExxonMobil Corporation Baytown
Refinery Flexicoker Flare
B. Marathon Petroleum Company
Garyville, Louisiana, and Blanchard
Refining’s Galveston Bay Refinery
MPGFs
C. Chalmette Refinery Request
D. LACC, LLC Request
E. Information Supporting Flare AMEL
Requests
III. AMEL for the Flares
IV. Request for Comments
I. Background
A. Regulatory Flare Requirements and
AMEL Requests
In this action, the U.S. Environmental
Protection Agency (EPA) is soliciting
comment on all aspects of these AMEL
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requests and the corresponding
operating conditions that would
demonstrate that the requested AMEL
would achieve a reduction in emissions
of volatile organic compounds (VOC)
and hazardous air pollutants (HAP) at
least equivalent to the reduction in
emissions required by various standards
in 40 Code of Federal Regulations (CFR)
parts 60, 61, and 63 that apply to
emission sources controlled by these
flares. These standards incorporate the
flare design and operating requirements
in the parts 60 and 63 General
Provisions (i.e., 40 CFR 60.18(b) and
63.11(b)) into the individual new source
performance standards (NSPS) and
maximum achievable control
technology (MACT) subparts, except for
the Petroleum Refinery MACT, 40 CFR
part 63, subpart CC, which specifies its
flare requirements within the subpart
(i.e., 40 CFR 63.670). Four of the
requests are for flares located at
petroleum refineries, while the request
from LACC, LLC is for a flare design at
a chemical manufacturing facility. None
of the flares located at petroleum
refineries can meet the flare tip velocity
limits in the Petroleum Refinery MACT,
40 CFR part 63, subpart CC. In addition,
flares at these refineries and at LACC’s
chemical plant that are subject to other
part 60 and 63 standards cannot meet
the flare tip velocity limits contained in
the applicable General Provisions to
part 60 and 63. Based on our review of
these requests and their supporting
information, we conclude that, by
following the conditions specified in
this notice, the proposed flares will
achieve at least equivalent emissions
reductions as flares complying with the
requirements of 40 CFR 60.18(b),
63.11(b) and/or 63.670(d), whichever is
applicable.1
Alternative Means of Emission
Limitation requests were submitted to
the EPA for flares that cannot comply
with the applicable flare tip velocity
requirements in the Petroleum Refinery
MACT, 40 CFR part 63, subpart CC and
General Provisions to parts 60 and 63.
These maximum flare tip velocity
requirements ensure that the flame does
not ‘‘lift off’’ or separate from the flare
tip, which could cause flame instability
and/or potentially result in a portion of
the flare gas being released without
proper combustion. Proper combustion
for flares is considered to be 98-percent
destruction efficiency or greater for
organic HAP and VOC. The flares in
these requests are designed to operate
with tip exit velocities greater than
those allowed in 40 CFR 60.18, 63.11,
and 63.670 while achieving ≥96.5percent combustion efficiency and 98percent destruction efficiency. Requests
from ExxonMobil Corporation,
Marathon Petroleum Company, LP,
Blanchard Refining, LLC, and Chalmette
Refining, LLC were submitted to the
EPA on November 7, 2017; October 7,
2016; September 20, 2017; and August
10, 2017, respectively. These requests,
which seek AMEL for flares to be used
at certain refineries subject to the
Petroleum Refinery MACT, 40 CFR part
63, subpart CC, followed the AMEL
framework specified in 40 CFR part 63,
subpart CC at 40 CFR 63.670(r).2 On
May 7, 2017, LACC, LLC submitted an
AMEL request for flares to be used at a
chemical plant in Louisiana according
to the framework for pressure assisted
multi-point ground flares (MPGFs) that
was published in the Federal Register
on April 21, 2016 (see 81 FR 23486).
The flare designs in these requests vary
from a single tip design that is gasassisted to multi-point tip designs
which employ large numbers of tips at
varying heights from close to ground
level (these are termed multi-point
ground flares [MPGF]) to an elevated
multi-point design. The EPA has
reviewed these requests and deemed
them to be complete.
The ExxonMobil Corporation
Baytown Refinery in Baytown, Texas, is
seeking an AMEL to operate a gasassisted flare during periods of startup,
shutdown, upsets, and emergency
events, as well as during fuel gas
imbalance events. Marathon Petroleum
Company, LP’s Garyville, Louisiana
Refinery, and Blanchard Refining, LLC’s
Galveston Bay Refinery (GBR) in Texas
City, Texas, are seeking AMELs to
operate their flares only during periods
of startup, shutdown, upsets, and
emergency events. Chalmette Refining,
LLC in Chalmette, Louisiana, is seeking
an AMEL to operate its flare during
periods of upset and emergency events.
LACC, LLC is seeking an AMEL to
operate flares at its chemical plant in
Lake Charles, Louisiana, during
startups, shutdowns, upsets, and
emergency events. See Table 1 for a list
of regulations, by subparts, that each
refinery and chemical plant has
identified as applicable to the flares
described above.
TABLE 1—SUMMARY OF APPLICABLE RULES THAT MAY APPLY TO STREAMS CONTROLLED BY FLARES
Exxon
Mobil
Baytown,
Texas
Flare 26
Marathon
Garyville, LA
MPGF
Blanchard
Refining
GBR
MPGF
Chalmette
No. 1 Flare
LACC
Rule citation from Title 40
CFR that allow for use of a
flare
NSPS Subpart VV ................
NSPS Subpart VVa ..............
NSPS Subpart NNN .............
NSPS Subpart QQQ ............
NSPS Subpart RRR .............
NSPS Subpart Kb ................
NESHAP Subpart V .............
................
................
................
................
................
................
................
x
x
x
x
x
x
x
x
x
x
x
x
x
x
......................
......................
x
......................
......................
......................
......................
................
x
x
................
x
x
x
60.482–10(d) ...........................
60.482–10a(d) .........................
60.662(b) .................................
60.692–5(c) .............................
60.702(b) .................................
60.112b(a)(3)(ii) ......................
61.242–11(d) ...........................
NESHAP Subpart J ..............
................
......................
..................
......................
x
61.242–11(d) ...........................
NESHAP Subpart Y .............
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Applicable rules with vent
streams going to control
device(s)
................
x
x
......................
................
61.271–(c)(2) ...........................
NESHAP Subpart BB ...........
................
x
x
......................
................
61.302(c) .................................
NESHAP Subpart FF ...........
NESHAP Subpart F .............
................
................
x
x
x
x
......................
......................
x
x
61.349(a)(2) ............................
63.103(a) .................................
1 Per 40 CFR 63.640(s), flares that are subject to
the provisions of 40 CFR 63.670 are required only
to comply with 40 CFR 63.670 and not the General
Provisions at 40 CFR 60.18 and 63.11.
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2 Although the Marathon, Blanchard, and
Chalmette refineries are subject to other national
emission standards for hazardous air pollutants
(NESHAP) and NSPS (and, therefore, the General
Provisions at 40 CFR 60.18 and 63.11) in addition
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Provisions for alternative
means of emission limitation
60.484(a)–(f).
60.484a(a)–(f).
CAA section 111(h)(3).
42 U.S.C. 7411(h)(3).
CAA section 111(h)(3).
60.114b.
40 CFR 63.6(g); 42 U.S.C.
7412(h)(3).
40 CFR 63.6(g); 42 U.S.C.
7412(h)(3).
40 CFR 63.6(g); 40 CFR
61.273; 42 U.S.C.
7412(h)(3).
40 CFR 63.6(g); 42 U.S.C.
7412(h)(3).
61.353(a); also see 61.12(d).
63.6(g); 42 U.S.C. 7412(h)(3).
to NESHAP subpart CC, 40 CFR 63.640(s) of subpart
CC allows flares that are subject to flare
requirements in both subpart CC and General
Provisions to elect to comply only with the subpart
CC flare requirements at 40 CFR 63.670.
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TABLE 1—SUMMARY OF APPLICABLE RULES THAT MAY APPLY TO STREAMS CONTROLLED BY FLARES—Continued
Exxon
Mobil
Baytown,
Texas
Flare 26
Marathon
Garyville, LA
MPGF
Blanchard
Refining
GBR
MPGF
Chalmette
No. 1 Flare
LACC
NESHAP Subpart G .............
................
x
x
......................
x
NESHAP
NESHAP
NESHAP
NESHAP
NESHAP
H .............
SS ...........
CC ..........
UU ..........
YY ...........
................
................
x
................
................
x
x
x
......................
......................
x
x
x
..................
..................
......................
......................
x
......................
......................
x
x
................
x
x
NESHAP Subpart EEEE ......
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Applicable rules with vent
streams going to control
device(s)
................
x
x
......................
................
Subpart
Subpart
Subpart
Subpart
Subpart
The provisions in each NSPS and
NESHAP cited above, which ensure that
flares meet certain specific operating
requirements when used to satisfy the
requirements of the NSPS or NESHAP
were established as work practice
standards pursuant to CAA sections
111(h)(1) or 112(h)(1). For standards
established according to these
provisions, CAA sections 111(h)(3) and
112(h)(3) allow the EPA to permit the
use of an AMEL by a source if, after
notice and opportunity for comment,3 it
is established to the Administrator’s
satisfaction that such an AMEL will
achieve emissions reductions at least
equivalent to the reductions required
under the applicable CAA section
111(h)(1) or 112(h)(1) standards. As
noted in Table 1, many of the identified
NSPS and NESHAP also include
specific regulatory provisions allowing
sources to request an AMEL.
ExxonMobil, Marathon, Blanchard,
Chalmette, and LACC submitted AMEL
requests to operate above the applicable
maximum permitted velocity
requirements for flares in the General
Provisions in 40 CFR parts 60 and 63
and/or in 40 CFR 63.670. ExxonMobil,
Marathon, Blanchard, Chalmette, and
LACC provided information that the
flare designs achieve a reduction in
emissions at least equivalent to the
reduction in emissions for flares
complying with the applicable General
Provisions and/or MACT subpart CC
requirements. For further information
on ExxonMobil’s, Marathon’s,
Blanchard’s, Chalmette’s, and LACC’s
AMEL requests, see supporting
materials from ExxonMobil, Marathon,
Blanchard, Chalmette, and LACC at
Docket ID No. EPA–HQ–OAR–2010–
0682 and EPA–HQ–OAR–2014–0738.
3 CAA section 111(h)(3) requires that the EPA
provide an opportunity for a hearing.
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Jkt 244001
Rule citation from Title 40
CFR that allow for use of a
flare
Provisions for alternative
means of emission limitation
63.113(a)(1)(i), 63.116(a)(2),
63.116(a)(3), 63.119(e),
63.120(e)(1) through (4),
63.126(b)(2)(i), 63.128(b),
63.139(c)(3), 63.139(d)(3),
63.145(j).
63.172(d), 63.180(e) ...............
63.982(b) .................................
63.643(a)(1) ............................
63.1034 ...................................
Table 7 to 63.1103(e) crossreferences to NESHAP subpart SS above.
63.2378(a), 63.2382, 63.2398
63.6(g); 42 U.S.C. 7412(h)(3).
II. Requests for AMEL
A. ExxonMobil Corporation Baytown
Refinery Flexicoker Flare
ExxonMobil submitted an AMEL for
Flare 26 at the ExxonMobil Baytown
Refinery. Flare 26 is an elevated flare,
with an approximate height of 284 feet.
Flare 26 will be modified to install a 52inch gas-assisted flare tip. Gas-assisted
means that natural gas is discharged
near or at the flare tip exit and is used
to improve the combustion efficiency in
the combustion zone, but it is not part
of the vent gas, and, as such, does not
contribute to the vent gas volume that
determines the exit tip velocity. Still,
this flare cannot meet the exit velocity
limitation in 40 CFR 63.670(d). Flare 26
receives low BTU gas (LBG) from
episodic and maintenance events from
the Flexicoking LBG system during
startup, shutdown, and other nonroutine operations. Flare 26 will also
accept flow from the Flexicoking LBG
system during normal operations where
there is a fuel gas imbalance.
B. Marathon Petroleum Company
Garyville, Louisiana, and Blanchard
Refining’s Galveston Bay Refinery
MPGFs
Marathon submitted an AMEL for
their two MPGFs at their Garyville
refinery and also for one MPGF at their
subsidiary, Blanchard Refining’s GBR.
These three MPGFs were included in a
single AMEL request because the
principle is the same for each MPGF.
All three MPGFs are designed to operate
with tip exit velocities greater than
those allowed in 40 CFR 60.18, 63.11,
and 63.670, while achieving >96.5percent combustion efficiency and 98percent destruction efficiency. The
scope of the AMELs include steamassisted steam kinetic energy
combustors (SKEC burners) at Garyville,
pressure-assisted linear relief gas
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63.177; 42 U.S.C. 7412(h)(3).
CAA section 112(h)(3).
63.670(r).
63.1021(a)–(d).
63.1113.
63.6(g); 42 U.S.C. 7412(h)(3).
oxidizers (LRGO burners) at Garyville
and GBR, and an air-assisted burner (LH
burner) at GBR. All three of the MPGFs
covered in this AMEL request were
manufactured by John Zink Company,
LLC (John Zink). Marathon is seeking
AMELs to operate these flares during
periods of startup, shutdown, upsets,
and emergency events.
C. Chalmette Refinery Request
Chalmette Refining, LLC submitted an
AMEL for their No. 1 Flare. The No. 1
Flare was designed by John Zink and
constructed in 1982. The flare is an 8stage candelabra style raised pressureassisted flare with multiple flare tips
comprised of two designs. The flare is
elevated 171.92 feet above ground. Stage
one is equipped with John Zink LRGOSpider model burners. All other stages
have John Zink model LRGO–FF
burners. The gases being flared can
range in composition and flow, but the
flare only operates during upset and
emergency conditions.
D. LACC, LLC Request
LACC, LLC submitted an AMEL for
two MPGF operating in series. This
system consists of an enclosed ground
flare and a high-pressure ground flare
that operates as a cascading system
whereby the enclosed ground flare
serves as the primary relief control
device and the high-pressure ground
flare serves as the secondary relief
control device should the enclosed
ground flare approach burner utilization
capacity. The high-pressure header
portion of these ground flares are MPGF
and utilize two different types of
pressure assisted burners; LRGO–HC
(both flares) and INDAIR (enclosed
ground flare only). Both are designed
and produced by John Zink. The
high-pressure header MPGFs will be
used for destruction of vent streams
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Federal Register / Vol. 83, No. 80 / Wednesday, April 25, 2018 / Notices
during startups, shutdowns, upsets, and
emergency events.
E. Information Supporting Flare AMEL
Requests
As mentioned above, ExxonMobil,
Marathon, Blanchard, and Chalmette
provided the information specified in
the flare AMEL framework at 40 CFR
63.670(r) to support their AMEL
requests. LACC provided the
information specified in the flare AMEL
framework finalized on April 21, 2016
(81 FR 23486), to support its AMEL
request. The information specified in
both frameworks includes, but is not
limited to: (1) Details on the project
scope and background; (2) information
on regulatory applicability; (3) flare test
data on destruction efficiency/
combustion efficiency; (4) flare stability
testing data; (5) flare cross-light testing
data; (6) information on flare reduction
considerations; and (7) information on
appropriate flare monitoring and
operating conditions. (For further
information on the supporting materials
provided, see Docket ID No. EPA–HQ–
OAR–2010–0682 and EPA–HQ–OAR–
2014–0738.)
Information supplied by these
companies indicates that the flares can
achieve adequate combustion efficiency
if operated under certain conditions.
Generally, testing of burners for the vent
gas mixture determined to be
representative of the flare operation was
used to set the appropriate combustion
zone net heating value (NHVcz)
minimum limit. Exxon Mobil conducted
a series of combustion efficiency tests
over a range of operating conditions and
vent gas velocities to establish limits on
a representative gas-assisted burner.
Marathon and Blanchard submitted
combustion efficiency test data for all
three different types of burners to
establish their minimum NHVcz.
Burners in these flares include steam
assisted (SKEC) and non-assisted
(LRGO) burners at Garyville and an airassisted (LH) and non-assisted (LRGO)
at the Blanchard GBR. At the Garyville
Refinery, the MPGFs are operated in
series such that the flare gas is directed
to the SKEC burners in stages 1 through
4, and then to the LRGO burners in
stages 5 through 11. Therefore, we
selected an operating limit of the higher
of 600 BTU/standard cubic feet (scf)
NHVcz or the NHVcz value resulting from
the equation of the line presented in
Table 2 appropriate for the SKEC
burner. At the Blanchard GBR, we
selected a value of 600 BTU/scf NHVcz
based on the successful combustion
efficiency test at 600 BTU/scf for the
representative waste gas. The LRGO
operating limit is limiting because the
LRGO burners follow the air-assisted LH
burner at the GBR.
Chalmette Refining submitted
required information and requested a
minimum NHVcz of 1000 BTU/scf or a
maximum lower flammability limit
(LFL) of less than or equal to 6.5
percent, based on the conditions that
were demonstrated to cross light flare
stage 8A from adjacent stages 5 and 7
and stage 8B from stages 6 and 7. Stages
8A and B are not equipped with pilots,
and, therefore, lighting of these stages
relies on lighting from adjacent stages.
Chalmette also requested that video
records be used to show that cross
lighting is successful, even if the NHVcz
or LFL conditions are not met. However,
we do not intend to allow an alternate
compliance method based on visual
indication and have not included this in
the proposed alternatives.
Finally, LACC requested two separate
limits to account for the two sets of
burners on their MPGF, LRGO, and
INDAIR burners operating on waste gas
from ethylene and downstream
chemical manufacturing (ethylene oxide
and monoethylene glycol) processes.
LACC cited previous combustion
efficiency information for the LRGO
burners and successful cross light and
stability at 800 BTU/scf for the
representative waste gas composition.
The combustion efficiencies for the
INDAIR burners testing showed that a
minimum of 1,067 BTU/scf for NHVcz
was necessary to achieve the desired
combustion efficiency. For process
control, LACC requested a minimum
limit of 1,075 BTU/scf for these burners.
It is also important to note that LACC
has the ability to lock out the stages
containing the four INDAIR burners so
that they can meet the 800 BTU/scf
minimum for the LRGO burners only.
III. AMEL for the Flares
Based upon our review of the AMEL
requests, we have concluded that, by
complying with the proposed AMEL
specified in Table 2 and accompanying
paragraphs, the flares will achieve
emission reductions at least equivalent
to reduction in emissions being
controlled by flares complying with the
flare requirements under the applicable
NESHAP and NSPS identified in Table
1. We are seeking the public’s input on
the requests that the EPA approve
AMELs for these flares. Specifically, the
EPA seeks the public’s input on the
conditions specified in this document in
the following paragraphs. The EPA’s
proposed AMEL for Chalmette Refining
does not include the requested
provision to allow a source not to meet
the limits in Table 2 as long as evidence
of cross light and combustion exists.
TABLE 2—PROPOSED ALTERNATIVE OPERATING CONDITIONS
Company
Affected facilities
Flare type(s)
Proposed alternative operating conditions.
11/7/17 ..................
ExxonMobil ...........
≥270 BTU/scf NHVcz and velocity <361 feet per second
(ft/sec).
Marathon ...............
Baytown, TX
Flexicoker Flare
26.
Garyville, LA .........
Elevated gas-assist
flare.
10/7/17 ..................
2 MPGFs ..............
10/7/17 ..................
Marathon/ Blanchard Refining.
Chalmette Refining
GBR (Texas City,
TX).
Chalmette, LA .......
When both SKEC and LRGO burners are being used, the
higher of ≥600 BTU/scf NHVcz or ≥127.27 ln(vvg)–
110.87 NHVcz. When only the SKEC burner is being
used ≥127.27 ln(vvg)–110.87 NHVcz.
≥600 BTU/scf NHVcz.
9/19/17 ..................
sradovich on DSK3GMQ082PROD with NOTICES
AMEL submitted
5/1/17 ....................
LACC ....................
Lake Charles, LA ..
(1) All flares must be operated such
that the combustion zone gas net
heating value (NHVcz) or the lower
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MPGF ...................
Elevated multipoint flare.
2 MPGFs ..............
≥1000 BTU/scf NHVcz or LFLcz≤6.5 vol%.
≥1075 BTU/scf NHVcz for INDAIR Burners; ≥800 BTU/scf
NHVcz for LRGO only.
flammability in the combustion zone
(LFLcz) as specified in Table 2 is met.
Owners or operators must demonstrate
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compliance with the applicable NHVcz
or LFLcz specified in Table 2 on a 15minute block average. Owners or
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operators must calculate and monitor
for the NHVcz or LFLcz according to the
following:
(a) Calculation of NHVcz
18039
(i) If an owner or operator elects to
use a monitoring system capable of
continuously measuring (i.e., at least
once every 15 minutes), calculating, and
recording the individual component
concentrations present in the flare vent
gas, NHVvg shall be calculated using the
following equation:
Where:
NHVvg = Net heating value of flare vent gas,
BTU/scf. Flare vent gas means all gas
found just prior to the tip. This gas
includes all flare waste gas (i.e., gas from
facility operations that is directed to a
flare for the purpose of disposing the
gas), flare sweep gas, flare purge gas, and
flare supplemental gas, but does not
include pilot gas.
i = Individual component in flare vent gas.
n = Number of components in flare vent gas.
xi = Concentration of component i in flare
vent gas, volume fraction.
NHVi = Net heating value of component i
determined as the heat of combustion
where the net enthalpy per mole of
offgas is based on combustion at 25
degrees Celsius (°C) and 1 atmosphere
(or constant pressure) with water in the
gaseous state from values published in
the literature, and then the values
converted to a volumetric basis using 20
°C for ‘‘standard temperature.’’ Table 3
summarizes component properties
including net heating values.
(ii) If the owner or operator uses a
continuous net heating value monitor,
the owner or operator may, at their
discretion, install, operate, calibrate,
and maintain a monitoring system
capable of continuously measuring,
calculating, and recording the hydrogen
concentration in the flare vent gas. The
owner or operator shall use the
following equation to determine NHVvg
for each sample measured via the net
heating value monitoring system.
Where:
NHVvg = Net heating value of flare vent gas,
BTU/scf.
NHVmeasured = Net heating value of flare vent
gas stream as measured by the
continuous net heating value monitoring
system, BTU/scf.
xH2 = Concentration of hydrogen in flare vent
gas at the time the sample was input into
the net heating value monitoring system,
volume fraction.
938 = Net correction for the measured
heating value of hydrogen (1,212–274),
BTU/scf.
(iii) For non-assisted flare burners,
NHVvg = NHVcz. For assisted burners,
such as the Marathon Garyville MPGF
SKEC burners, the Blanchard Refining
MPGF LH burner, and the ExxonMobil
gas-assisted burner, NHVcz should be
calculated using Equation 3.
Where:
NHVcz = Net heating value of combustion
zone gas, BTU/scf.
NHVvg = Net heating value of flare vent gas
for the 15-minute block period as
determined according to (1)(a)(i), BTU/
scf.
Qvg = Cumulative volumetric flow of flare
vent gas during the 15-minute block
period, scf.
Qag = Cumulative volumetric flow of assist
gas during the 15-minute block period,
standard cubic feet flow rate, scf.
NHVag = Net heating value of assist gas, BTU/
scf; this is zero for air or for steam.
(b) Calculation of LFLcz
(c) Calculation of Vtip
For the ExxonMobil flexicoker flare
(F–26), the owner or operator shall
calculate the 15-minute block average
Vtip by using the following equation:
EN25AP18.003
(ii) For non-assisted flare burners,
LFLvg = LFLcz.
EN25AP18.002
component i as determined using values
published by the U.S. Bureau of Mines
(Zabetakis, 1965), vol %. All inerts,
including nitrogen, are assumed to have
an infinite LFL (e.g., LFLN2 = ∞, so that
cN2LFLN2 = 0). LFL values for common
flare vent gas components are provided
in Table 3.
EN25AP18.001
Where:
LFLvg = Lower flammability limit of flare vent
gas, volume percent (vol %).
n = Number of components in the vent gas.
i = Individual component in the vent gas.
ci = Concentration of component i in the vent
gas, vol %.
LFLi = Lower flammability limit of
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EN25AP18.000
sradovich on DSK3GMQ082PROD with NOTICES
EN25AP18.004
(i) The owner or operator shall
determine LFLcz from compositional
analysis data by using the following
equation:
18040
Federal Register / Vol. 83, No. 80 / Wednesday, April 25, 2018 / Notices
(d) For all flare systems specified in
this document, the operator shall install,
operate, calibrate, and maintain a
monitoring system capable of
Where:
Qvol = Volumetric flow rate, scf/sec.
Qmass = Mass flow rate, pounds per sec.
385.3 = Conversion factor, scf per poundmole.
MWt = Molecular weight of the gas at the
flow monitoring location, pounds per
pound-mole.
continuously measuring the volumetric
flow rate of flare vent gas (Qvg), the
volumetric flow rate of total assist steam
(Qs), the volumetric flow rate of total
assist air (Qa), and the volumetric flow
rate of total assist gas (Qag).
(i) The flow rate monitoring systems
must be able to correct for the
temperature and pressure of the system
and output parameters in standard
conditions (i.e., a temperature of 20 °C
(68 °Fahrenheit) and a pressure of 1
atmosphere).
(ii) Mass flow monitors may be used
for determining volumetric flow rate of
flare vent gas provided the molecular
weight of the flare vent gas is
determined using compositional
analysis so that the mass flow rate can
be converted to volumetric flow at
standard conditions using the following
equation:
(e) For each measurement produced
by the monitoring system used to
comply with (1)(a)(ii), the operator shall
determine the 15-minute block average
as the arithmetic average of all
measurements made by the monitoring
system within the 15-minute period.
Where:
Vtip = Flare tip velocity, ft/sec.
Qvg = Cumulative volumetric flow of vent gas
over 15-minute block average period, scf.
Area = Unobstructed area of the flare tip,
square ft.
900 = Conversion factor, seconds per 15minute block average.
(f) The operator must follow the
calibration and maintenance procedures
according to Table 4. Maintenance
periods, instrument adjustments, or
checks to maintain precision and
accuracy and zero and span adjustments
may not exceed 5 percent of the time the
flare is receiving regulated material.
TABLE 3—INDIVIDUAL COMPONENT PROPERTIES
MWi
(pounds per
pound-mole)
Component
Molecular
formula
Acetylene ........................................................
Benzene ..........................................................
1,2-Butadiene ..................................................
1,3-Butadiene ..................................................
iso-Butane .......................................................
n-Butane ..........................................................
cis-Butene .......................................................
iso-Butene .......................................................
trans-Butene ....................................................
Carbon Dioxide ...............................................
Carbon Monoxide ............................................
Cyclopropane ..................................................
Ethane .............................................................
Ethylene ..........................................................
Hydrogen .........................................................
Hydrogen Sulfide ............................................
Methane ..........................................................
Methyl-Acetylene .............................................
Nitrogen ...........................................................
Oxygen ............................................................
Pentane+ (C5+) ..............................................
Propadiene ......................................................
Propane ...........................................................
Propylene ........................................................
Water ...............................................................
C2H2 ...............................................................
C6H6 ...............................................................
C4H6 ...............................................................
C4H6 ...............................................................
C4H10 .............................................................
C4H10 .............................................................
C4H8 ...............................................................
C4H8 ...............................................................
C4H8 ...............................................................
CO2 ................................................................
CO ..................................................................
C3H6 ...............................................................
C2H6 ...............................................................
C2H4 ...............................................................
H2 ...................................................................
H2S .................................................................
CH4 .................................................................
C3H4 ...............................................................
N2 ...................................................................
O2 ...................................................................
C5H12 .............................................................
C3H4 ...............................................................
C3H8 ...............................................................
C3H6 ...............................................................
H2O ................................................................
26.04
78.11
54.09
54.09
58.12
58.12
56.11
56.11
56.11
44.01
28.01
42.08
30.07
28.05
2.02
34.08
16.04
40.06
28.01
32.00
72.15
40.06
44.10
42.08
18.02
NHVi
(BTU/scf)
1,404
3,591
2,794
2,690
2,957
2,968
2,830
2,928
2,826
0
316
2,185
1,595
1,477
* 1,212
587
896
2,088
0
0
3,655
2,066
2,281
2,150
0
LFLi
(volume %)
2.5
1.3
2.0
2.0
1.8
1.8
1.6
1.8
1.7
∞
12.5
2.4
3.0
2.7
4.0
4.0
5.0
1.7
∞
∞
1.4
2.16
2.1
2.4
∞
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sradovich on DSK3GMQ082PROD with NOTICES
* The theoretical net heating value for hydrogen is 274 BTU/scf, but for the purposes of the flare requirement in this subpart, a net heating
value of 1,212 BTU/scf shall be used.
Federal Register / Vol. 83, No. 80 / Wednesday, April 25, 2018 / Notices
18041
TABLE 4—ACCURACY AND CALIBRATION REQUIREMENTS
Parameter
Accuracy requirements
Calibration requirements
Flare Vent Gas Flow
Rate
±20 percent of flow rate at velocities
ranging from 0.1 to 1 foot per second
±5 percent of flow rate at velocities
greater than 1 foot per second.
Flow Rate for All
Flows Other Than
Flare Vent Gas
±5 percent over the normal range of
flow measured or 1.9 liters per
minute (0.5 gallons per minute),
whichever is greater, for liquid flow.
±5 percent over the normal range of
flow measured or 280 liters per
minute (10 cubic feet per minute),
whichever is greater, for gas flow.
±5 percent over the normal range
measured for mass flow.
Performance evaluation biennially (every 2 years) and following any period of
more than 24 hours throughout which the flow rate exceeded the maximum
rated flow rate of the sensor, or the data recorder was off scale. Checks of
all mechanical connections for leakage monthly. Visual inspections and
checks of system operation every 3 months, unless the system has a redundant flow sensor.
Select a representative measurement location where swirling flow or abnormal
velocity distributions due to upstream and downstream disturbances at the
point of measurement are minimized.
Conduct a flow sensor calibration check at least biennially (every 2 years); conduct a calibration check following any period of more than 24 hours throughout which the flow rate exceeded the manufacturer’s specified maximum
rated flow rate or install a new flow sensor.
At least quarterly, inspect all components for leakage, unless the continuous
parameter monitoring system (CPMS) has a redundant flow sensor.
±5 percent over the normal range
measured or 0.12 kilopascals (0.5
inches of water column), whichever is
greater.
Pressure
±2 percent of span ................................
Net Heating Value
by Gas Chromatograph
As specified in Performance Standard
(PS) 9 of 40 CFR part 60, appendix
B.
Hydrogen Analyzer
sradovich on DSK3GMQ082PROD with NOTICES
Net Heating Value
by Calorimeter
±2 percent over the concentration
measured, or 0.1 volume, percent,
whichever is greater.
(2) The flare system shall be operated
with a flame present at all times when
in use. Additionally, each stage that
cross-lights must have at least two pilots
with a continuously lit pilot flame,
except for Chalmette Refining, which
has one pilot for each stage, excluding
stages 8A and 8B. Each pilot flame must
be continuously monitored by a
thermocouple or any other equivalent
device used to detect the presence of a
flame. The time, date, and duration of
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Jkt 244001
Record the results of each calibration check and inspection.
Locate the flow sensor(s) and other necessary equipment (such as straightening vanes) in a position that provides representative flow; reduce swirling
flow or abnormal velocity distributions due to upstream and downstream disturbances.
Review pressure sensor readings at least once a week for straight-line (unchanging) pressure and perform corrective action to ensure proper pressure
sensor operation if blockage is indicated.
Performance evaluation annually and following any period of more than 24
hours throughout which the pressure exceeded the maximum rated pressure
of the sensor, or the data recorder was off scale. Checks of all mechanical
connections for leakage monthly. Visual inspection of all components for integrity, oxidation, and galvanic corrosion every 3 months, unless the system
has a redundant pressure sensor.
Select a representative measurement location that minimizes or eliminates pulsating pressure, vibration, and internal and external corrosion.
Calibration requirements should follow manufacturer’s recommendations at a
minimum.
Temperature control (heated and/or cooled as necessary) the sampling system
to ensure proper year-round operation.
Where feasible, select a sampling location at least 2 equivalent diameters
downstream from and 0.5 equivalent diameters upstream from the nearest
disturbance. Select the sampling location at least 2 equivalent duct diameters
from the nearest control device, point of pollutant generation, air in-leakages,
or other point at which a change in the pollutant concentration or emission
rate occurs.
Follow the procedure in PS 9 of 40 CFR part 60, appendix B, except that a single daily mid-level calibration check can be used (rather than triplicate analysis), the multi-point calibration can be conducted quarterly (rather than
monthly), and the sampling line temperature must be maintained at a minimum temperature of 60 °C (rather than 120 °C).
Specify calibration requirements in your site specific CPMS monitoring plan.
Calibration requirements should follow manufacturer’s recommendations at a
minimum.
Specify the sampling location at least 2 equivalent duct diameters from the
nearest control device, point of pollutant generation, air in-leakages, or other
point at which a change in the pollutant concentration occurs.
any complete loss of pilot flame on any
of the burners must be recorded. Each
monitoring device must be maintained
or replaced at a frequency in accordance
with the manufacturer’s specifications.
(3) Flares at refineries shall comply
with the requirements of 40 CFR
63.670(h). For LACC, LLC, the flare
system shall be operated with no visible
emissions except for periods not to
exceed a total of 5 minutes during any
2 consecutive hours. A video camera
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that is capable of continuously
recording (i.e., at least one frame every
15 seconds with time and date stamps)
images of the flare flame and a
reasonable distance above the flare
flame at an angle suitable for visible
emissions observations must be used to
demonstrate compliance with this
requirement. The owner or operator
must provide real-time video
surveillance camera output to the
control room or other continuously
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18042
Federal Register / Vol. 83, No. 80 / Wednesday, April 25, 2018 / Notices
manned location where the video
camera images may be viewed at any
time.
(4) For the MPGF and the Chalmette
elevated multi-point flare, the operator
of a flare system shall install and
operate pressure monitor(s) on the main
flare header, as well as a valve position
indicator monitoring system capable of
monitoring and recording the position
for each staging valve to ensure that the
flare operates within the range of tested
conditions or within the range of the
manufacturer’s specifications. The
pressure monitor shall meet the
requirements in Table 4. Maintenance
periods, instrument adjustments or
checks to maintain precision and
accuracy, and zero and span
adjustments may not exceed 5 percent
of the time the flare is receiving
regulated material.
(5) Recordkeeping Requirements
(a) All data must be recorded and
maintained for a minimum of 3 years or
for as long as required under applicable
rule subpart(s), whichever is longer.
(6) Reporting Requirements
(a) The information specified in
section III (6)(b) and (c) below must be
reported in the timeline specified by the
applicable rule subpart(s) for which the
flare will control emissions.
(b) Owners or operators shall include
the final AMEL operating requirements
for each flare in their initial Notification
of Compliance status report.
(c) The owner or operator shall notify
the Administrator of periods of excess
emissions in their Periodic Reports. The
notification shall include:
(i) Records of each 15-minute block
for all flares during which there was at
least 1 minute when regulated material
was routed to the flare and a complete
loss of pilot flame on a stage of burners
occurred, and for all flares, records of
each 15-minute block during which
there was at least 1 minute when
regulated material was routed to the
flare and a complete loss of pilot flame
on an individual burner occurred.
(ii) Records of visible emissions
events (including the time and date
stamp) that exceed more than 5 minutes
in any 2-hour consecutive period.
(iii) Records of each 15-minute block
period for which an applicable
combustion zone operating limit (i.e.,
NHVcz or LFLcz) is not met for the flare
when regulated material is being
combusted in the flare. Indicate the date
and time for each period, the NHVcz
and/or LFLcz operating parameter for the
period, the type of monitoring system
used to determine compliance with the
operating parameters (e.g., gas
chromatograph or calorimeter), and also
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indicate which high-pressure stages
were in use.
(iv) Records of when the pressure
monitor(s) on the main flare header
show the flare burners are operating
outside the range of tested conditions or
outside the range of the manufacturer’s
specifications. Indicate the date and
time for each period, the pressure
measurement, the stage(s) and number
of flare burners affected, and the range
of tested conditions or manufacturer’s
specifications.
(v) Records of when the staging valve
position indicator monitoring system
indicates a stage of the flare should not
be in operation and is or when a stage
of the flare should be in operation and
is not. Indicate the date and time for
each period, whether the stage was
supposed to be open, but was closed, or
vice versa, and the stage(s) and number
of flare burners affected.
IV. Request for Comments
We solicit comments on all aspects of
ExxonMobil’s, Marathon’s, Blanchard’s,
Chalmette’s, and LACC’s requests for
approval of an AMEL for flares to be
used to comply with the standards
specified in Table 1. We specifically
seek comment regarding whether or not
the alternative operating requirements
listed in section III above will achieve
emission reductions at least equivalent
to emissions being controlled by flares
complying with the applicable flare
requirements in 40 CFR 60.18(b),
63.11(b), and/or 63.670.
Dated: April 18, 2018.
Panagiotis Tsirigotis,
Director, Office of Air Quality Planning and
Standards.
[FR Doc. 2018–08575 Filed 4–24–18; 8:45 am]
BILLING CODE 6560–50–P
ENVIRONMENTAL PROTECTION
AGENCY
[EPA–HQ–OAR–2017–0427; FRL–9975–48–
OAR]
RIN 2060–AT73
National Emission Standards for
Hazardous Air Pollutants for Asbestos:
Request for Approval of an Alternative
Work Practice for Asbestos Cement
Pipe Replacement
Environmental Protection
Agency (EPA).
ACTION: Notification of request for
comments.
AGENCY:
This action provides public
notice and solicits comment on an
alternative work practice (AWP) request
under the Clean Air Act, to use new
SUMMARY:
PO 00000
Frm 00050
Fmt 4703
Sfmt 4703
technology and work practices
developed for removal and replacement
of asbestos cement (A/C) pipe. In this
action, the Environmental Protection
Agency (EPA) is soliciting comment on
all aspects of this request for an AWP
that, in order to be approved, should be
at least environmentally equivalent to
the existing work practices in the
National Emission Standards for
Hazardous Air Pollutants for Asbestos
(Asbestos NESHAP), which applies to
the removal and replacement of A/C
pipe.
DATES:
Comments. The EPA must receive
written comments on or before June 25,
2018.
Public Hearing. If a public hearing is
requested by April 30, 2018, then we
will hold a public hearing on May 10,
2018 at the EPA William Jefferson
Clinton (WJC) East Building, 1201
Constitution Avenue NW, Washington,
DC 20004. If a public hearing is
requested, then we will provide
additional details about the public
hearing on our website at https://
www.epa.gov/stationary-sources-airpollution/asbestos-national-emissionstandards-hazardous-air-pollutants. To
request a hearing, to register to speak at
a hearing, or to inquire if a hearing will
be held, please contact Aimee St. Clair
at (919) 541–1063 or by email at
stclair.aimee@epa.gov. The EPA does
not intend to publish any future notices
in the Federal Register regarding a
public hearing on this proposed action
and directs all inquiries regarding a
hearing to the website and contact
person identified above. The last day to
pre-register in advance to speak at the
public hearing will be May 8, 2018.
ADDRESSES: Comments. Submit your
comments, identified by Docket ID No.
EPA–HQ–OAR–2017–0427, at https://
www.regulations.gov. Follow the online
instructions for submitting comments.
Once submitted, comments cannot be
edited or removed from Regulations.gov.
Regulations.gov is our preferred method
of receiving comments. However, other
submission formats are accepted. To
ship or send mail via the United States
Postal Service, use the following
address: U.S. Environmental Protection
Agency, EPA Docket Center, Docket ID
No. EPA–HQ–OAR–2017–0427, Mail
Code 28221T, 1200 Pennsylvania
Avenue NW, Washington, DC 20460.
Use the following Docket Center address
if you are using express mail,
commercial delivery, hand delivery, or
courier. EPA Docket Center, WJC West
Building, Room 3334, 1301 Constitution
Avenue NW, Washington, DC 20004.
Delivery verification signatures will be
E:\FR\FM\25APN1.SGM
25APN1
Agencies
[Federal Register Volume 83, Number 80 (Wednesday, April 25, 2018)]
[Notices]
[Pages 18034-18042]
From the Federal Register Online via the Government Publishing Office [www.gpo.gov]
[FR Doc No: 2018-08575]
=======================================================================
-----------------------------------------------------------------------
ENVIRONMENTAL PROTECTION AGENCY
[EPA-HQ-OAR-2014-0738 and EPA-HQ-OAR-2010-0682; FRL-9976-29-OAR]
Notice of Requests for Approval of Alternative Means of Emission
Limitation
AGENCY: Environmental Protection Agency (EPA).
ACTION: Notice; request for comments.
-----------------------------------------------------------------------
SUMMARY: This action provides public notice and solicits comment on the
alternative means of emission limitation (AMEL) requests from
ExxonMobil Corporation; Marathon Petroleum Company, LP (for itself and
on behalf of its subsidiary, Blanchard Refining, LLC); and Chalmette
Refining, LLC, under the Clean Air Act (CAA), to operate flares at
several refineries in Texas and Louisiana, as well as the AMEL request
from LACC, LLC to operate flares at a chemical plant in Louisiana.
DATES: Comments. Comments must be received on or before June 11, 2018.
Public Hearing. If a public hearing is requested by April 30, 2018,
then we will hold a public hearing on May 10, 2018 at the location
described in the ADDRESSES section. The last day to pre-register in
advance to speak at the public hearing will be May 8, 2018.
ADDRESSES: Comments. Submit your comments, identified by Docket ID No.
EPA-HQ-OAR-2014-0738, at https://www.regulations.gov. Follow the online
instructions for submitting comments. Once submitted, comments cannot
be edited or removed from Regulations.gov, Regulations.gov is our
preferred method of receiving comments. However, other submission
methods are accepted. To ship or send mail via the United States Postal
Service, use the following address: U.S. Environmental Protection
Agency, EPA Docket Center, Docket ID No. EPA-HQ-OAR-2014-0738, Mail
Code 28221T, 1200 Pennsylvania Avenue NW, Washington, DC 20460. Use the
following Docket Center address if you are using express mail,
commercial delivery, hand delivery, or courier: EPA Docket Center, EPA
WJC West Building, Room 3334, 1301 Constitution Avenue NW, Washington,
DC 20004. Delivery verification signatures will be available only
during regular business hours.
Do not submit electronically any information you consider to be
Confidential Business Information (CBI) or other information whose
disclosure is restricted by statue. See the SUPPLEMENTARY INFORMATION
section of this preamble for instructions on submitting CBI.
The EPA may publish any comment received to its public docket.
Multimedia submissions (audio, video, etc.) must be accompanied by a
written comment. The written comment is considered the official comment
and should include discussion of all points you wish to make. The EPA
will generally not consider comments or comment contents located
outside of the primary submission (i.e., on the Web, cloud, or other
file sharing system). For additional submission methods, the full EPA
public comment policy, information about CBI or multimedia submissions,
and general guidance on making effective comments, please visit https://www2.epa.gov/dockets/commenting-epa-dockets.
Public Hearing. If a public hearing is requested, it will be held
at EPA Headquarters, EPA WJC East Building, 1201 Constitution Avenue
NW, Washington, DC 20004. If a public hearing is requested, then we
will provide details about the public hearing on our website at:
https://www3.epa.gov/ttn/atw/groundflares/groundflarespg.html. The EPA
does not intend to publish another document in the Federal Register
announcing any updates on the request for a public hearing. Please
contact Ms. Virginia Hunt of the Sector Policies and Programs Division
(E143-01), Office of Air Quality Planning and Standards, Environmental
Protection Agency, Research Triangle Park, NC 27711; telephone number:
(919) 541-0832; email address: [email protected]; to request a
public hearing, to register to speak at the public hearing, or to
inquire as to whether or not a public hearing will be held.
The EPA will make every effort to accommodate all speakers who
arrive and register. If a hearing is held at a U.S. government
facility, individuals planning to attend should be prepared to show a
current, valid state- or federal-approved picture identification to the
[[Page 18035]]
security staff in order to gain access to the meeting room. An expired
form of identification will not be permitted. Please note that the Real
ID Act, passed by Congress in 2005, established new requirements for
entering federal facilities. If your driver's license is issued by a
noncompliant state, you must present an additional form of
identification to enter a federal facility. Acceptable alternative
forms of identification include: Federal employee badge, passports,
enhanced driver's licenses, and military identification cards.
Additional information on the Real ID Act is available at https://www.dhs.gov/real-id-frequently-asked-questions. In addition, you will
need to obtain a property pass for any personal belongings you bring
with you. Upon leaving the building, you will be required to return
this property pass to the security desk. No large signs will be allowed
in the building, cameras may only be used outside of the building, and
demonstrations will not be allowed on federal property for security
reasons.
FOR FURTHER INFORMATION CONTACT: For questions about this action,
contact Ms. Angie Carey, Sector Policies and Programs Division (E143-
01), Office of Air Quality Planning and Standards (OAQPS), U.S.
Environmental Protection Agency, Research Triangle Park, North Carolina
27711; telephone number: (919) 541-2187; fax number: (919) 541-0516;
and email address: [email protected].
SUPPLEMENTARY INFORMATION:
Docket. The EPA has established a docket for this rulemaking under
Docket ID No. EPA-HQ-OAR-2014-0738. All documents in the docket are
listed in the Regulations.gov index. Although listed in the index, some
information is not publicly available, e.g., CBI or other information
whose disclosure is restricted by statute. Certain other material, such
as copyrighted material, is not placed on the internet and will be
publicly available only in hard copy. Publicly available docket
materials are available either electronically in Regulations.gov or in
hard copy at the EPA Docket Center, Room 3334, EPA WJC West Building,
1301 Constitution Avenue NW, Washington, DC. The Public Reading Room is
open from 8:30 a.m. to 4:30 p.m., Monday through Friday, excluding
legal holidays. The telephone number for the Public Reading Room is
(202) 566-1744, and the telephone number for the EPA Docket Center is
(202) 566-1742.
Instructions. Direct your comments to Docket ID No. EPA-HQ-OAR-
2014-0738. The EPA's policy is that all comments received will be
included in the public docket without change and may be made available
online at https://www.regulations.gov, including any personal
information provided, unless the comment includes information claimed
to be CBI or other information whose disclosure is restricted by
statute. Do not submit information that you consider to be CBI or
otherwise protected through https://www.regulations.gov or email. This
type of information should be submitted by mail as discussed below. The
https://www.regulations.gov website site is an ``anonymous access''
system, which means the EPA will not know your identity or contact
information unless you provide it in the body of your comment. If you
send an email comment directly to the EPA without going through https://www.regulations.gov, your email address will be automatically captured
and included as part of the comment that is placed in the public docket
and made available on the internet. If you submit an electronic
comment, the EPA recommends that you include your name and other
contact information in the body of your comment and with any disk or
CD-ROM you submit. If the EPA cannot read your comment due to technical
difficulties and cannot contact you for clarification, the EPA may not
be able to consider your comment. Electronic files should not include
special characters or any form of encryption and be free of any defects
or viruses. For additional information about the EPA's public docket,
visit the EPA Docket Center homepage at https://www.epa.gov/dockets.
Submitting CBI. Do not submit information containing CBI to the EPA
through https://www.regulations.gov or email. Clearly mark the part or
all of the information that you claim to be CBI. For CBI information on
a disk or CD-ROM that you mail to the EPA, mark the outside of the disk
or CD-ROM as CBI and then identify electronically within the disk or
CD-ROM the specific information that is claimed as CBI. In addition to
one complete version of the comments that includes information claimed
as CBI, you must submit a copy of the comments that does not contain
the information claimed as CBI for inclusion in the public docket. If
you submit a CD-ROM or disk that does not contain CBI, mark the outside
of the disk or CD-ROM clearly that it does not contain CBI. Information
not marked as CBI will be included in the public docket and the EPA's
electronic public docket without prior notice. Information marked as
CBI will not be disclosed except in accordance with procedures set
forth in 40 CFR part 2. Send or deliver information identified as CBI
only to the following address: OAQPS Document Control Officer (C404-
02), OAQPS, U.S. Environmental Protection Agency, Research Triangle
Park, North Carolina 27711, Attention Docket ID No. EPA-HQ-OAR-2014-
0738.
Acronyms and Abbreviations. We use multiple acronyms and terms in
this notice. While this list may not be exhaustive, to ease the reading
of this notice and for reference purposes, the EPA defines the
following terms and acronyms here:
AMEL alternative means of emission limitation
BTU/scf British thermal units per standard cubic foot
CAA Clean Air Act
CBI Confidential Business Information
CFR Code of Federal Regulations
EPA Environmental Protection Agency
Eqn equation
HAP hazardous air pollutants
LFL lower flammability limit
LFLcz lower flammability limit of combustion zone gas
LFLvg lower flammability limit of flare vent gas
LRGO linear relief gas oxidizer
MPGF multi-point ground flares
NESHAP national emission standards for hazardous air pollutants
NHV net heating value
NHVcz net heating value of combustion zone gas
NHVvg net heating value of flare vent gas
NSPS new source performance standards
OAQPS Office of Air Quality Planning and Standards
scf standard cubic feet
SKEC steam-assisted kinetic energy combustor
VOC volatile organic compounds
Organization of This Document. The information in this notice is
organized as follows:
I. Background
A. Regulatory Flare Requirements and AMEL Requests
II. Requests for AMEL
A. ExxonMobil Corporation Baytown Refinery Flexicoker Flare
B. Marathon Petroleum Company Garyville, Louisiana, and
Blanchard Refining's Galveston Bay Refinery MPGFs
C. Chalmette Refinery Request
D. LACC, LLC Request
E. Information Supporting Flare AMEL Requests
III. AMEL for the Flares
IV. Request for Comments
I. Background
A. Regulatory Flare Requirements and AMEL Requests
In this action, the U.S. Environmental Protection Agency (EPA) is
soliciting comment on all aspects of these AMEL
[[Page 18036]]
requests and the corresponding operating conditions that would
demonstrate that the requested AMEL would achieve a reduction in
emissions of volatile organic compounds (VOC) and hazardous air
pollutants (HAP) at least equivalent to the reduction in emissions
required by various standards in 40 Code of Federal Regulations (CFR)
parts 60, 61, and 63 that apply to emission sources controlled by these
flares. These standards incorporate the flare design and operating
requirements in the parts 60 and 63 General Provisions (i.e., 40 CFR
60.18(b) and 63.11(b)) into the individual new source performance
standards (NSPS) and maximum achievable control technology (MACT)
subparts, except for the Petroleum Refinery MACT, 40 CFR part 63,
subpart CC, which specifies its flare requirements within the subpart
(i.e., 40 CFR 63.670). Four of the requests are for flares located at
petroleum refineries, while the request from LACC, LLC is for a flare
design at a chemical manufacturing facility. None of the flares located
at petroleum refineries can meet the flare tip velocity limits in the
Petroleum Refinery MACT, 40 CFR part 63, subpart CC. In addition,
flares at these refineries and at LACC's chemical plant that are
subject to other part 60 and 63 standards cannot meet the flare tip
velocity limits contained in the applicable General Provisions to part
60 and 63. Based on our review of these requests and their supporting
information, we conclude that, by following the conditions specified in
this notice, the proposed flares will achieve at least equivalent
emissions reductions as flares complying with the requirements of 40
CFR 60.18(b), 63.11(b) and/or 63.670(d), whichever is applicable.\1\
---------------------------------------------------------------------------
\1\ Per 40 CFR 63.640(s), flares that are subject to the
provisions of 40 CFR 63.670 are required only to comply with 40 CFR
63.670 and not the General Provisions at 40 CFR 60.18 and 63.11.
---------------------------------------------------------------------------
Alternative Means of Emission Limitation requests were submitted to
the EPA for flares that cannot comply with the applicable flare tip
velocity requirements in the Petroleum Refinery MACT, 40 CFR part 63,
subpart CC and General Provisions to parts 60 and 63. These maximum
flare tip velocity requirements ensure that the flame does not ``lift
off'' or separate from the flare tip, which could cause flame
instability and/or potentially result in a portion of the flare gas
being released without proper combustion. Proper combustion for flares
is considered to be 98-percent destruction efficiency or greater for
organic HAP and VOC. The flares in these requests are designed to
operate with tip exit velocities greater than those allowed in 40 CFR
60.18, 63.11, and 63.670 while achieving >=96.5-percent combustion
efficiency and 98-percent destruction efficiency. Requests from
ExxonMobil Corporation, Marathon Petroleum Company, LP, Blanchard
Refining, LLC, and Chalmette Refining, LLC were submitted to the EPA on
November 7, 2017; October 7, 2016; September 20, 2017; and August 10,
2017, respectively. These requests, which seek AMEL for flares to be
used at certain refineries subject to the Petroleum Refinery MACT, 40
CFR part 63, subpart CC, followed the AMEL framework specified in 40
CFR part 63, subpart CC at 40 CFR 63.670(r).\2\ On May 7, 2017, LACC,
LLC submitted an AMEL request for flares to be used at a chemical plant
in Louisiana according to the framework for pressure assisted multi-
point ground flares (MPGFs) that was published in the Federal Register
on April 21, 2016 (see 81 FR 23486). The flare designs in these
requests vary from a single tip design that is gas-assisted to multi-
point tip designs which employ large numbers of tips at varying heights
from close to ground level (these are termed multi-point ground flares
[MPGF]) to an elevated multi-point design. The EPA has reviewed these
requests and deemed them to be complete.
---------------------------------------------------------------------------
\2\ Although the Marathon, Blanchard, and Chalmette refineries
are subject to other national emission standards for hazardous air
pollutants (NESHAP) and NSPS (and, therefore, the General Provisions
at 40 CFR 60.18 and 63.11) in addition to NESHAP subpart CC, 40 CFR
63.640(s) of subpart CC allows flares that are subject to flare
requirements in both subpart CC and General Provisions to elect to
comply only with the subpart CC flare requirements at 40 CFR 63.670.
---------------------------------------------------------------------------
The ExxonMobil Corporation Baytown Refinery in Baytown, Texas, is
seeking an AMEL to operate a gas-assisted flare during periods of
startup, shutdown, upsets, and emergency events, as well as during fuel
gas imbalance events. Marathon Petroleum Company, LP's Garyville,
Louisiana Refinery, and Blanchard Refining, LLC's Galveston Bay
Refinery (GBR) in Texas City, Texas, are seeking AMELs to operate their
flares only during periods of startup, shutdown, upsets, and emergency
events. Chalmette Refining, LLC in Chalmette, Louisiana, is seeking an
AMEL to operate its flare during periods of upset and emergency events.
LACC, LLC is seeking an AMEL to operate flares at its chemical plant in
Lake Charles, Louisiana, during startups, shutdowns, upsets, and
emergency events. See Table 1 for a list of regulations, by subparts,
that each refinery and chemical plant has identified as applicable to
the flares described above.
Table 1--Summary of Applicable Rules That May Apply to Streams Controlled by Flares
--------------------------------------------------------------------------------------------------------------------------------------------------------
Exxon
Mobil Marathon Blanchard Rule citation from Provisions for
Applicable rules with vent streams Baytown, Garyville, LA Refining Chalmette No. LACC Title 40 CFR that alternative means of
going to control device(s) Texas MPGF GBR MPGF 1 Flare allow for use of a emission limitation
Flare 26 flare
--------------------------------------------------------------------------------------------------------------------------------------------------------
NSPS Subpart VV...................... .......... x x .............. .......... 60.482-10(d)......... 60.484(a)-(f).
NSPS Subpart VVa..................... .......... x x .............. x 60.482-10a(d)........ 60.484a(a)-(f).
NSPS Subpart NNN..................... .......... x x x x 60.662(b)............ CAA section
111(h)(3).
NSPS Subpart QQQ..................... .......... x x .............. .......... 60.692-5(c).......... 42 U.S.C. 7411(h)(3).
NSPS Subpart RRR..................... .......... x x .............. x 60.702(b)............ CAA section
111(h)(3).
NSPS Subpart Kb...................... .......... x x .............. x 60.112b(a)(3)(ii).... 60.114b.
NESHAP Subpart V..................... .......... x x .............. x 61.242-11(d)......... 40 CFR 63.6(g); 42
U.S.C. 7412(h)(3).
NESHAP Subpart J..................... .......... .............. ........... .............. x 61.242-11(d)......... 40 CFR 63.6(g); 42
U.S.C. 7412(h)(3).
NESHAP Subpart Y..................... .......... x x .............. .......... 61.271-(c)(2)........ 40 CFR 63.6(g); 40
CFR 61.273; 42
U.S.C. 7412(h)(3).
NESHAP Subpart BB.................... .......... x x .............. .......... 61.302(c)............ 40 CFR 63.6(g); 42
U.S.C. 7412(h)(3).
NESHAP Subpart FF.................... .......... x x .............. x 61.349(a)(2)......... 61.353(a); also see
61.12(d).
NESHAP Subpart F..................... .......... x x .............. x 63.103(a)............ 63.6(g); 42 U.S.C.
7412(h)(3).
[[Page 18037]]
NESHAP Subpart G..................... .......... x x .............. x 63.113(a)(1)(i), 63.6(g); 42 U.S.C.
63.116(a)(2), 7412(h)(3).
63.116(a)(3),
63.119(e),
63.120(e)(1) through
(4),
63.126(b)(2)(i),
63.128(b),
63.139(c)(3),
63.139(d)(3),
63.145(j).
NESHAP Subpart H..................... .......... x x .............. x 63.172(d), 63.180(e). 63.177; 42 U.S.C.
7412(h)(3).
NESHAP Subpart SS.................... .......... x x .............. x 63.982(b)............ CAA section
112(h)(3).
NESHAP Subpart CC.................... x x x x .......... 63.643(a)(1)......... 63.670(r).
NESHAP Subpart UU.................... .......... .............. ........... .............. x 63.1034.............. 63.1021(a)-(d).
NESHAP Subpart YY.................... .......... .............. ........... .............. x Table 7 to 63.1103(e) 63.1113.
cross-references to
NESHAP subpart SS
above.
NESHAP Subpart EEEE.................. .......... x x .............. .......... 63.2378(a), 63.2382, 63.6(g); 42 U.S.C.
63.2398. 7412(h)(3).
--------------------------------------------------------------------------------------------------------------------------------------------------------
The provisions in each NSPS and NESHAP cited above, which ensure
that flares meet certain specific operating requirements when used to
satisfy the requirements of the NSPS or NESHAP were established as work
practice standards pursuant to CAA sections 111(h)(1) or 112(h)(1). For
standards established according to these provisions, CAA sections
111(h)(3) and 112(h)(3) allow the EPA to permit the use of an AMEL by a
source if, after notice and opportunity for comment,\3\ it is
established to the Administrator's satisfaction that such an AMEL will
achieve emissions reductions at least equivalent to the reductions
required under the applicable CAA section 111(h)(1) or 112(h)(1)
standards. As noted in Table 1, many of the identified NSPS and NESHAP
also include specific regulatory provisions allowing sources to request
an AMEL.
---------------------------------------------------------------------------
\3\ CAA section 111(h)(3) requires that the EPA provide an
opportunity for a hearing.
---------------------------------------------------------------------------
ExxonMobil, Marathon, Blanchard, Chalmette, and LACC submitted AMEL
requests to operate above the applicable maximum permitted velocity
requirements for flares in the General Provisions in 40 CFR parts 60
and 63 and/or in 40 CFR 63.670. ExxonMobil, Marathon, Blanchard,
Chalmette, and LACC provided information that the flare designs achieve
a reduction in emissions at least equivalent to the reduction in
emissions for flares complying with the applicable General Provisions
and/or MACT subpart CC requirements. For further information on
ExxonMobil's, Marathon's, Blanchard's, Chalmette's, and LACC's AMEL
requests, see supporting materials from ExxonMobil, Marathon,
Blanchard, Chalmette, and LACC at Docket ID No. EPA-HQ-OAR-2010-0682
and EPA-HQ-OAR-2014-0738.
II. Requests for AMEL
A. ExxonMobil Corporation Baytown Refinery Flexicoker Flare
ExxonMobil submitted an AMEL for Flare 26 at the ExxonMobil Baytown
Refinery. Flare 26 is an elevated flare, with an approximate height of
284 feet. Flare 26 will be modified to install a 52-inch gas-assisted
flare tip. Gas-assisted means that natural gas is discharged near or at
the flare tip exit and is used to improve the combustion efficiency in
the combustion zone, but it is not part of the vent gas, and, as such,
does not contribute to the vent gas volume that determines the exit tip
velocity. Still, this flare cannot meet the exit velocity limitation in
40 CFR 63.670(d). Flare 26 receives low BTU gas (LBG) from episodic and
maintenance events from the Flexicoking LBG system during startup,
shutdown, and other non-routine operations. Flare 26 will also accept
flow from the Flexicoking LBG system during normal operations where
there is a fuel gas imbalance.
B. Marathon Petroleum Company Garyville, Louisiana, and Blanchard
Refining's Galveston Bay Refinery MPGFs
Marathon submitted an AMEL for their two MPGFs at their Garyville
refinery and also for one MPGF at their subsidiary, Blanchard
Refining's GBR. These three MPGFs were included in a single AMEL
request because the principle is the same for each MPGF. All three
MPGFs are designed to operate with tip exit velocities greater than
those allowed in 40 CFR 60.18, 63.11, and 63.670, while achieving
>96.5-percent combustion efficiency and 98-percent destruction
efficiency. The scope of the AMELs include steam-assisted steam kinetic
energy combustors (SKEC burners) at Garyville, pressure-assisted linear
relief gas oxidizers (LRGO burners) at Garyville and GBR, and an air-
assisted burner (LH burner) at GBR. All three of the MPGFs covered in
this AMEL request were manufactured by John Zink Company, LLC (John
Zink). Marathon is seeking AMELs to operate these flares during periods
of startup, shutdown, upsets, and emergency events.
C. Chalmette Refinery Request
Chalmette Refining, LLC submitted an AMEL for their No. 1 Flare.
The No. 1 Flare was designed by John Zink and constructed in 1982. The
flare is an 8-stage candelabra style raised pressure-assisted flare
with multiple flare tips comprised of two designs. The flare is
elevated 171.92 feet above ground. Stage one is equipped with John Zink
LRGO-Spider model burners. All other stages have John Zink model LRGO-
FF burners. The gases being flared can range in composition and flow,
but the flare only operates during upset and emergency conditions.
D. LACC, LLC Request
LACC, LLC submitted an AMEL for two MPGF operating in series. This
system consists of an enclosed ground flare and a high-pressure ground
flare that operates as a cascading system whereby the enclosed ground
flare serves as the primary relief control device and the high-pressure
ground flare serves as the secondary relief control device should the
enclosed ground flare approach burner utilization capacity. The high-
pressure header portion of these ground flares are MPGF and utilize two
different types of pressure assisted burners; LRGO-HC (both flares) and
INDAIR (enclosed ground flare only). Both are designed and produced by
John Zink. The high[hyphen]pressure header MPGFs will be used for
destruction of vent streams
[[Page 18038]]
during startups, shutdowns, upsets, and emergency events.
E. Information Supporting Flare AMEL Requests
As mentioned above, ExxonMobil, Marathon, Blanchard, and Chalmette
provided the information specified in the flare AMEL framework at 40
CFR 63.670(r) to support their AMEL requests. LACC provided the
information specified in the flare AMEL framework finalized on April
21, 2016 (81 FR 23486), to support its AMEL request. The information
specified in both frameworks includes, but is not limited to: (1)
Details on the project scope and background; (2) information on
regulatory applicability; (3) flare test data on destruction
efficiency/combustion efficiency; (4) flare stability testing data; (5)
flare cross-light testing data; (6) information on flare reduction
considerations; and (7) information on appropriate flare monitoring and
operating conditions. (For further information on the supporting
materials provided, see Docket ID No. EPA-HQ-OAR-2010-0682 and EPA-HQ-
OAR-2014-0738.)
Information supplied by these companies indicates that the flares
can achieve adequate combustion efficiency if operated under certain
conditions. Generally, testing of burners for the vent gas mixture
determined to be representative of the flare operation was used to set
the appropriate combustion zone net heating value (NHVcz) minimum
limit. Exxon Mobil conducted a series of combustion efficiency tests
over a range of operating conditions and vent gas velocities to
establish limits on a representative gas-assisted burner. Marathon and
Blanchard submitted combustion efficiency test data for all three
different types of burners to establish their minimum NHVcz. Burners in
these flares include steam assisted (SKEC) and non-assisted (LRGO)
burners at Garyville and an air-assisted (LH) and non-assisted (LRGO)
at the Blanchard GBR. At the Garyville Refinery, the MPGFs are operated
in series such that the flare gas is directed to the SKEC burners in
stages 1 through 4, and then to the LRGO burners in stages 5 through
11. Therefore, we selected an operating limit of the higher of 600 BTU/
standard cubic feet (scf) NHVcz or the NHVcz value resulting from the
equation of the line presented in Table 2 appropriate for the SKEC
burner. At the Blanchard GBR, we selected a value of 600 BTU/scf NHVcz
based on the successful combustion efficiency test at 600 BTU/scf for
the representative waste gas. The LRGO operating limit is limiting
because the LRGO burners follow the air-assisted LH burner at the GBR.
Chalmette Refining submitted required information and requested a
minimum NHVcz of 1000 BTU/scf or a maximum lower flammability limit
(LFL) of less than or equal to 6.5 percent, based on the conditions
that were demonstrated to cross light flare stage 8A from adjacent
stages 5 and 7 and stage 8B from stages 6 and 7. Stages 8A and B are
not equipped with pilots, and, therefore, lighting of these stages
relies on lighting from adjacent stages. Chalmette also requested that
video records be used to show that cross lighting is successful, even
if the NHVcz or LFL conditions are not met. However, we do not intend
to allow an alternate compliance method based on visual indication and
have not included this in the proposed alternatives.
Finally, LACC requested two separate limits to account for the two
sets of burners on their MPGF, LRGO, and INDAIR burners operating on
waste gas from ethylene and downstream chemical manufacturing (ethylene
oxide and monoethylene glycol) processes. LACC cited previous
combustion efficiency information for the LRGO burners and successful
cross light and stability at 800 BTU/scf for the representative waste
gas composition. The combustion efficiencies for the INDAIR burners
testing showed that a minimum of 1,067 BTU/scf for NHVcz was necessary
to achieve the desired combustion efficiency. For process control, LACC
requested a minimum limit of 1,075 BTU/scf for these burners. It is
also important to note that LACC has the ability to lock out the stages
containing the four INDAIR burners so that they can meet the 800 BTU/
scf minimum for the LRGO burners only.
III. AMEL for the Flares
Based upon our review of the AMEL requests, we have concluded that,
by complying with the proposed AMEL specified in Table 2 and
accompanying paragraphs, the flares will achieve emission reductions at
least equivalent to reduction in emissions being controlled by flares
complying with the flare requirements under the applicable NESHAP and
NSPS identified in Table 1. We are seeking the public's input on the
requests that the EPA approve AMELs for these flares. Specifically, the
EPA seeks the public's input on the conditions specified in this
document in the following paragraphs. The EPA's proposed AMEL for
Chalmette Refining does not include the requested provision to allow a
source not to meet the limits in Table 2 as long as evidence of cross
light and combustion exists.
Table 2--Proposed Alternative Operating Conditions
----------------------------------------------------------------------------------------------------------------
Proposed
alternative
AMEL submitted Company Affected facilities Flare type(s) operating
conditions.
----------------------------------------------------------------------------------------------------------------
11/7/17.................... ExxonMobil.......... Baytown, TX Elevated gas-assist >=270 BTU/scf NHV
Flexicoker Flare flare. and velocity <361
26. feet per second
(ft/sec).
10/7/17.................... Marathon............ Garyville, LA...... 2 MPGFs............ When both SKEC and
LRGO burners are
being used, the
higher of >=600
BTU/scf NHVcz or
>=127.27 ln(v)-
110.87 NHVcz. When
only the SKEC
burner is being
used >=127.27
ln(v)-110.87
NHVcz.
10/7/17.................... Marathon/ Blanchard GBR (Texas City, MPGF............... >=600 BTU/scf NHV.
Refining. TX).
9/19/17.................... Chalmette Refining.. Chalmette, LA...... Elevated multi- >=1000 BTU/scf NHV
point flare. or LFL<=6.5 vol%.
5/1/17..................... LACC................ Lake Charles, LA... 2 MPGFs............ >=1075 BTU/scf NHV
for INDAIR
Burners; >=800 BTU/
scf NHV for LRGO
only.
----------------------------------------------------------------------------------------------------------------
(1) All flares must be operated such that the combustion zone gas
net heating value (NHVcz) or the lower flammability in the combustion
zone (LFLcz) as specified in Table 2 is met. Owners or operators must
demonstrate compliance with the applicable NHVcz or LFLcz specified in
Table 2 on a 15-minute block average. Owners or
[[Page 18039]]
operators must calculate and monitor for the NHVcz or LFLcz according
to the following:
(a) Calculation of NHVcz
(i) If an owner or operator elects to use a monitoring system
capable of continuously measuring (i.e., at least once every 15
minutes), calculating, and recording the individual component
concentrations present in the flare vent gas, NHVvg shall be calculated
using the following equation:
[GRAPHIC] [TIFF OMITTED] TN25AP18.000
Where:
NHVvg = Net heating value of flare vent gas, BTU/scf. Flare vent gas
means all gas found just prior to the tip. This gas includes all
flare waste gas (i.e., gas from facility operations that is directed
to a flare for the purpose of disposing the gas), flare sweep gas,
flare purge gas, and flare supplemental gas, but does not include
pilot gas.
i = Individual component in flare vent gas.
n = Number of components in flare vent gas.
xi = Concentration of component i in flare vent gas, volume
fraction.
NHVi = Net heating value of component i determined as the heat of
combustion where the net enthalpy per mole of offgas is based on
combustion at 25 degrees Celsius ([deg]C) and 1 atmosphere (or
constant pressure) with water in the gaseous state from values
published in the literature, and then the values converted to a
volumetric basis using 20 [deg]C for ``standard temperature.'' Table
3 summarizes component properties including net heating values.
(ii) If the owner or operator uses a continuous net heating value
monitor, the owner or operator may, at their discretion, install,
operate, calibrate, and maintain a monitoring system capable of
continuously measuring, calculating, and recording the hydrogen
concentration in the flare vent gas. The owner or operator shall use
the following equation to determine NHVvg for each sample measured via
the net heating value monitoring system.
[GRAPHIC] [TIFF OMITTED] TN25AP18.001
Where:
NHVvg = Net heating value of flare vent gas, BTU/scf.
NHVmeasured = Net heating value of flare vent gas stream as measured
by the continuous net heating value monitoring system, BTU/scf.
xH2 = Concentration of hydrogen in flare vent gas at the time the
sample was input into the net heating value monitoring system,
volume fraction.
938 = Net correction for the measured heating value of hydrogen
(1,212-274), BTU/scf.
(iii) For non-assisted flare burners, NHVvg = NHVcz. For assisted
burners, such as the Marathon Garyville MPGF SKEC burners, the
Blanchard Refining MPGF LH burner, and the ExxonMobil gas-assisted
burner, NHVcz should be calculated using Equation 3.
[GRAPHIC] [TIFF OMITTED] TN25AP18.002
Where:
NHVcz = Net heating value of combustion zone gas, BTU/scf.
NHVvg = Net heating value of flare vent gas for the 15-minute block
period as determined according to (1)(a)(i), BTU/scf.
Qvg = Cumulative volumetric flow of flare vent gas during the 15-
minute block period, scf.
Qag = Cumulative volumetric flow of assist gas during the 15-minute
block period, standard cubic feet flow rate, scf.
NHVag = Net heating value of assist gas, BTU/scf; this is zero for
air or for steam.
(b) Calculation of LFLcz
(i) The owner or operator shall determine LFLcz from compositional
analysis data by using the following equation:
[GRAPHIC] [TIFF OMITTED] TN25AP18.003
Where:
LFLvg = Lower flammability limit of flare vent gas, volume percent
(vol %).
n = Number of components in the vent gas.
i = Individual component in the vent gas.
[chi]i = Concentration of component i in the vent gas, vol %.
LFLi = Lower flammability limit of component i as determined using
values published by the U.S. Bureau of Mines (Zabetakis, 1965), vol
%. All inerts, including nitrogen, are assumed to have an infinite
LFL (e.g., LFLN2 = [infin], so that [chi]N2LFLN2 = 0). LFL values
for common flare vent gas components are provided in Table 3.
(ii) For non-assisted flare burners, LFLvg = LFLcz.
(c) Calculation of Vtip
For the ExxonMobil flexicoker flare (F-26), the owner or operator
shall calculate the 15-minute block average Vtip by using the following
equation:
[GRAPHIC] [TIFF OMITTED] TN25AP18.004
[[Page 18040]]
Where:
Vtip = Flare tip velocity, ft/sec.
Qvg = Cumulative volumetric flow of vent gas over 15-minute block
average period, scf.
Area = Unobstructed area of the flare tip, square ft.
900 = Conversion factor, seconds per 15-minute block average.
(d) For all flare systems specified in this document, the operator
shall install, operate, calibrate, and maintain a monitoring system
capable of continuously measuring the volumetric flow rate of flare
vent gas (Qvg), the volumetric flow rate of total assist steam (Qs),
the volumetric flow rate of total assist air (Qa), and the volumetric
flow rate of total assist gas (Qag).
(i) The flow rate monitoring systems must be able to correct for
the temperature and pressure of the system and output parameters in
standard conditions (i.e., a temperature of 20 [deg]C (68
[deg]Fahrenheit) and a pressure of 1 atmosphere).
(ii) Mass flow monitors may be used for determining volumetric flow
rate of flare vent gas provided the molecular weight of the flare vent
gas is determined using compositional analysis so that the mass flow
rate can be converted to volumetric flow at standard conditions using
the following equation:
[GRAPHIC] [TIFF OMITTED] TN25AP18.005
Where:
Qvol = Volumetric flow rate, scf/sec.
Qmass = Mass flow rate, pounds per sec.
385.3 = Conversion factor, scf per pound-mole.
MWt = Molecular weight of the gas at the flow monitoring location,
pounds per pound-mole.
(e) For each measurement produced by the monitoring system used to
comply with (1)(a)(ii), the operator shall determine the 15-minute
block average as the arithmetic average of all measurements made by the
monitoring system within the 15-minute period.
(f) The operator must follow the calibration and maintenance
procedures according to Table 4. Maintenance periods, instrument
adjustments, or checks to maintain precision and accuracy and zero and
span adjustments may not exceed 5 percent of the time the flare is
receiving regulated material.
Table 3--Individual Component Properties
----------------------------------------------------------------------------------------------------------------
MW (pounds per
Component Molecular formula pound-mole) NHV (BTU/scf) LFL (volume %)
----------------------------------------------------------------------------------------------------------------
Acetylene............................. C2H2.................... 26.04 1,404 2.5
Benzene............................... C6H6.................... 78.11 3,591 1.3
1,2-Butadiene......................... C4H6.................... 54.09 2,794 2.0
1,3-Butadiene......................... C4H6.................... 54.09 2,690 2.0
iso-Butane............................ C4H10................... 58.12 2,957 1.8
n-Butane.............................. C4H10................... 58.12 2,968 1.8
cis-Butene............................ C4H8.................... 56.11 2,830 1.6
iso-Butene............................ C4H8.................... 56.11 2,928 1.8
trans-Butene.......................... C4H8.................... 56.11 2,826 1.7
Carbon Dioxide........................ CO2..................... 44.01 0 [infin]
Carbon Monoxide....................... CO...................... 28.01 316 12.5
Cyclopropane.......................... C3H6.................... 42.08 2,185 2.4
Ethane................................ C2H6.................... 30.07 1,595 3.0
Ethylene.............................. C2H4.................... 28.05 1,477 2.7
Hydrogen.............................. H2...................... 2.02 * 1,212 4.0
Hydrogen Sulfide...................... H2S..................... 34.08 587 4.0
Methane............................... CH4..................... 16.04 896 5.0
Methyl-Acetylene...................... C3H4.................... 40.06 2,088 1.7
Nitrogen.............................. N2...................... 28.01 0 [infin]
Oxygen................................ O2...................... 32.00 0 [infin]
Pentane+ (C5+)........................ C5H12................... 72.15 3,655 1.4
Propadiene............................ C3H4.................... 40.06 2,066 2.16
Propane............................... C3H8.................... 44.10 2,281 2.1
Propylene............................. C3H6.................... 42.08 2,150 2.4
Water................................. H2O..................... 18.02 0 [infin]
----------------------------------------------------------------------------------------------------------------
* The theoretical net heating value for hydrogen is 274 BTU/scf, but for the purposes of the flare requirement
in this subpart, a net heating value of 1,212 BTU/scf shall be used.
[[Page 18041]]
Table 4--Accuracy and Calibration Requirements
------------------------------------------------------------------------
Accuracy Calibration
Parameter requirements requirements
------------------------------------------------------------------------
Flare Vent Gas Flow Rate 20 Performance
percent of flow evaluation
rate at biennially (every 2
velocities years) and following
ranging from 0.1 any period of more
to 1 foot per than 24 hours
second throughout which the
5 flow rate exceeded
percent of flow the maximum rated
rate at flow rate of the
velocities sensor, or the data
greater than 1 recorder was off
foot per second. scale. Checks of all
mechanical
connections for
leakage monthly.
Visual inspections
and checks of system
operation every 3
months, unless the
system has a
redundant flow
sensor.
Select a
representative
measurement location
where swirling flow
or abnormal velocity
distributions due to
upstream and
downstream
disturbances at the
point of measurement
are minimized.
Flow Rate for All Flows Other 5 Conduct a flow sensor
Than Flare Vent Gas percent over the calibration check at
normal range of least biennially
flow measured or (every 2 years);
1.9 liters per conduct a
minute (0.5 calibration check
gallons per following any period
minute), of more than 24
whichever is hours throughout
greater, for which the flow rate
liquid flow. exceeded the
manufacturer's
specified maximum
rated flow rate or
install a new flow
sensor.
5 At least quarterly,
percent over the inspect all
normal range of components for
flow measured or leakage, unless the
280 liters per continuous parameter
minute (10 cubic monitoring system
feet per (CPMS) has a
minute), redundant flow
whichever is sensor.
greater, for gas
flow.
5 Record the results of
percent over the each calibration
normal range check and
measured for inspection.
mass flow. Locate the flow
sensor(s) and other
necessary equipment
(such as
straightening vanes)
in a position that
provides
representative flow;
reduce swirling flow
or abnormal velocity
distributions due to
upstream and
downstream
disturbances.
Pressure 5 Review pressure
percent over the sensor readings at
normal range least once a week
measured or 0.12 for straight-line
kilopascals (0.5 (unchanging)
inches of water pressure and perform
column), corrective action to
whichever is ensure proper
greater. pressure sensor
operation if
blockage is
indicated.
Performance
evaluation annually
and following any
period of more than
24 hours throughout
which the pressure
exceeded the maximum
rated pressure of
the sensor, or the
data recorder was
off scale. Checks of
all mechanical
connections for
leakage monthly.
Visual inspection of
all components for
integrity,
oxidation, and
galvanic corrosion
every 3 months,
unless the system
has a redundant
pressure sensor.
Select a
representative
measurement location
that minimizes or
eliminates pulsating
pressure, vibration,
and internal and
external corrosion.
Net Heating Value by 2 Calibration
Calorimeter percent of span. requirements should
follow
manufacturer's
recommendations at a
minimum.
Temperature control
(heated and/or
cooled as necessary)
the sampling system
to ensure proper
year-round
operation.
Where feasible,
select a sampling
location at least 2
equivalent diameters
downstream from and
0.5 equivalent
diameters upstream
from the nearest
disturbance. Select
the sampling
location at least 2
equivalent duct
diameters from the
nearest control
device, point of
pollutant
generation, air in-
leakages, or other
point at which a
change in the
pollutant
concentration or
emission rate
occurs.
Net Heating Value by Gas As specified in Follow the procedure
Chromatograph Performance in PS 9 of 40 CFR
Standard (PS) 9 part 60, appendix B,
of 40 CFR part except that a single
60, appendix B. daily mid-level
calibration check
can be used (rather
than triplicate
analysis), the multi-
point calibration
can be conducted
quarterly (rather
than monthly), and
the sampling line
temperature must be
maintained at a
minimum temperature
of 60 [deg]C (rather
than 120 [deg]C).
Hydrogen Analyzer 2 Specify calibration
percent over the requirements in your
concentration site specific CPMS
measured, or 0.1 monitoring plan.
volume, percent, Calibration
whichever is requirements should
greater. follow
manufacturer's
recommendations at a
minimum.
Specify the sampling
location at least 2
equivalent duct
diameters from the
nearest control
device, point of
pollutant
generation, air in-
leakages, or other
point at which a
change in the
pollutant
concentration
occurs.
------------------------------------------------------------------------
(2) The flare system shall be operated with a flame present at all
times when in use. Additionally, each stage that cross-lights must have
at least two pilots with a continuously lit pilot flame, except for
Chalmette Refining, which has one pilot for each stage, excluding
stages 8A and 8B. Each pilot flame must be continuously monitored by a
thermocouple or any other equivalent device used to detect the presence
of a flame. The time, date, and duration of any complete loss of pilot
flame on any of the burners must be recorded. Each monitoring device
must be maintained or replaced at a frequency in accordance with the
manufacturer's specifications.
(3) Flares at refineries shall comply with the requirements of 40
CFR 63.670(h). For LACC, LLC, the flare system shall be operated with
no visible emissions except for periods not to exceed a total of 5
minutes during any 2 consecutive hours. A video camera that is capable
of continuously recording (i.e., at least one frame every 15 seconds
with time and date stamps) images of the flare flame and a reasonable
distance above the flare flame at an angle suitable for visible
emissions observations must be used to demonstrate compliance with this
requirement. The owner or operator must provide real-time video
surveillance camera output to the control room or other continuously
[[Page 18042]]
manned location where the video camera images may be viewed at any
time.
(4) For the MPGF and the Chalmette elevated multi-point flare, the
operator of a flare system shall install and operate pressure
monitor(s) on the main flare header, as well as a valve position
indicator monitoring system capable of monitoring and recording the
position for each staging valve to ensure that the flare operates
within the range of tested conditions or within the range of the
manufacturer's specifications. The pressure monitor shall meet the
requirements in Table 4. Maintenance periods, instrument adjustments or
checks to maintain precision and accuracy, and zero and span
adjustments may not exceed 5 percent of the time the flare is receiving
regulated material.
(5) Recordkeeping Requirements
(a) All data must be recorded and maintained for a minimum of 3
years or for as long as required under applicable rule subpart(s),
whichever is longer.
(6) Reporting Requirements
(a) The information specified in section III (6)(b) and (c) below
must be reported in the timeline specified by the applicable rule
subpart(s) for which the flare will control emissions.
(b) Owners or operators shall include the final AMEL operating
requirements for each flare in their initial Notification of Compliance
status report.
(c) The owner or operator shall notify the Administrator of periods
of excess emissions in their Periodic Reports. The notification shall
include:
(i) Records of each 15-minute block for all flares during which
there was at least 1 minute when regulated material was routed to the
flare and a complete loss of pilot flame on a stage of burners
occurred, and for all flares, records of each 15-minute block during
which there was at least 1 minute when regulated material was routed to
the flare and a complete loss of pilot flame on an individual burner
occurred.
(ii) Records of visible emissions events (including the time and
date stamp) that exceed more than 5 minutes in any 2-hour consecutive
period.
(iii) Records of each 15-minute block period for which an
applicable combustion zone operating limit (i.e., NHVcz or LFLcz) is
not met for the flare when regulated material is being combusted in the
flare. Indicate the date and time for each period, the NHVcz and/or
LFLcz operating parameter for the period, the type of monitoring system
used to determine compliance with the operating parameters (e.g., gas
chromatograph or calorimeter), and also indicate which high-pressure
stages were in use.
(iv) Records of when the pressure monitor(s) on the main flare
header show the flare burners are operating outside the range of tested
conditions or outside the range of the manufacturer's specifications.
Indicate the date and time for each period, the pressure measurement,
the stage(s) and number of flare burners affected, and the range of
tested conditions or manufacturer's specifications.
(v) Records of when the staging valve position indicator monitoring
system indicates a stage of the flare should not be in operation and is
or when a stage of the flare should be in operation and is not.
Indicate the date and time for each period, whether the stage was
supposed to be open, but was closed, or vice versa, and the stage(s)
and number of flare burners affected.
IV. Request for Comments
We solicit comments on all aspects of ExxonMobil's, Marathon's,
Blanchard's, Chalmette's, and LACC's requests for approval of an AMEL
for flares to be used to comply with the standards specified in Table
1. We specifically seek comment regarding whether or not the
alternative operating requirements listed in section III above will
achieve emission reductions at least equivalent to emissions being
controlled by flares complying with the applicable flare requirements
in 40 CFR 60.18(b), 63.11(b), and/or 63.670.
Dated: April 18, 2018.
Panagiotis Tsirigotis,
Director, Office of Air Quality Planning and Standards.
[FR Doc. 2018-08575 Filed 4-24-18; 8:45 am]
BILLING CODE 6560-50-P