Receipt of Several Pesticide Petitions Filed for Residues of Pesticide Chemicals In or On Various Commodities, 31581-31585 [2016-11835]
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Federal Register / Vol. 81, No. 97 / Thursday, May 19, 2016 / Proposed Rules
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12.2.1 Calculate the equivalent
concentration Ci,eff using Equation 4:
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12.4.4 Calculate the zero CD as a percent
of span for an IP–CEMS as:
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11.0
Calculations and Data Analysis. * * *
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PS–18 Appendix A Standard Addition
Procedures
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3. In appendix F to part 60, revise
Sections 4.1.5, 4.1.5.1, 4.1.5.3, and
5.2.4.2 in Procedure 6 to read as follows:
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Appendix F to Part 60—Quality
Assurance Procedures
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5.2.4.2 Calculate results as described in
section 6.4. To determine CEMS accuaracy
you must calculate the dynamic spiking error
(DSE) for each of the two upscale audit gases
using equation A5 in appendix A to PS–18
and Equation 6–3 in section 6.4 of Procedure
6 appendix B to this part.
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Procedure 6. Quality Assurance
Requirements for Gaseous Hyrogen Chloride
(HCl) Continuous Emission Monitoring
Systems Used for Compliance Determination
at Stationary Sources
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11.2.3 If you determine your spike
dilution factor using an independent stable
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[FR Doc. 2016–10990 Filed 5–18–16; 8:45 am]
BILLING CODE 6560–50–P
ENVIRONMENTAL PROTECTION
AGENCY
4.0 Daily Data Quality Assurance
Requirements and Measurement
Standardization Procedures
40 CFR Part 180
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Receipt of Several Pesticide Petitions
Filed for Residues of Pesticide
Chemicals In or On Various
Commodities
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[EPA–HQ–OPP–2015–0032; FRL–9946–02]
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4.1.5 Additional Quality Assurance for
Data above Span. Unless otherwise specified
in an applicable rule or permit, this
procedure must be used to assure data
quality and may be used when significant
data above span is being collected.
4.1.5.1 Any time the average measured
concentration of HCl exceeds 150 percent of
the span value for two consecutive 1-hour
averages, conduct the following ‘above span’
CEMS response check.
asabaliauskas on DSK3SPTVN1PROD with PROPOSALS
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4.1.5.3 Unless otherwise specified in an
applicable rule or permit, if the ‘above span’
response check is conducted during the
period when measured emissions are above
span and there is a failure to collect at least
one data point in an hour due to the response
check duration, then determine the emissions
average for that missed hour as the average
of hourly averages for the hour preceding the
missed hour and the hour following the
missed hour
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Data Accuracy Assessment
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Environmental Protection
Agency (EPA).
ACTION: Notice of filing of petitions and
request for comment.
AGENCY:
This document announces
EPA’s receipt of several initial filings of
pesticide petitions requesting the
establishment or modification of
regulations for residues of pesticide
chemicals in or on various commodities.
DATES: Comments must be received on
or before June 20, 2016.
ADDRESSES: Submit your comments,
identified by the Docket Identification
(ID) Number and the Pesticide Petition
Number (PP) of interest as shown in the
body of this document, by one of the
following methods:
• Federal eRulemaking Portal: https://
www.regulations.gov. Follow the online
SUMMARY:
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tracer that is present in the native source
emissions, calculate the dilution factor for
dynamic spiking using equation A3:
instructions for submitting comments.
Do not submit electronically any
information you consider to be
Confidential Business Information (CBI)
or other information whose disclosure is
restricted by statute.
• Mail: OPP Docket, Environmental
Protection Agency Docket Center (EPA/
DC), (28221T), 1200 Pennsylvania Ave.
NW., Washington, DC 20460–0001.
• Hand Delivery: To make special
arrangements for hand delivery or
delivery of boxed information, please
follow the instructions at https://
www.epa.gov/dockets/contacts.html.
Additional instructions on commenting
or visiting the docket, along with more
information about dockets generally, is
available at https://www.epa.gov/
dockets.
FOR FURTHER INFORMATION CONTACT:
Susan Lewis, Registration Division
(7505P), Office of Pesticide Programs,
Environmental Protection Agency, 1200
Pennsylvania Ave. NW., Washington,
DC 20460–0001; main telephone
number: (703) 305–7090; email address:
RDFRNotices@epa.gov.
SUPPLEMENTARY INFORMATION:
I. General Information
A. Does this action apply to me?
You may be potentially affected by
this action if you are an agricultural
producer, food manufacturer, or
pesticide manufacturer. The following
list of North American Industrial
Classification System (NAICS) codes is
not intended to be exhaustive, but rather
provides a guide to help readers
determine whether this document
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Federal Register / Vol. 81, No. 97 / Thursday, May 19, 2016 / Proposed Rules
asabaliauskas on DSK3SPTVN1PROD with PROPOSALS
applies to them. Potentially affected
entities may include:
• Crop production (NAICS code 111).
• Animal production (NAICS code
112).
• Food manufacturing (NAICS code
311).
• Pesticide manufacturing (NAICS
code 32532).
If you have any questions regarding
the applicability of this action to a
particular entity, consult the person
listed under FOR FURTHER INFORMATION
CONTACT.
B. What should I consider as I prepare
my comments for EPA?
1. Submitting CBI. Do not submit this
information to EPA through
regulations.gov or email. Clearly mark
the part or all of the information that
you claim to be CBI. For CBI
information in a disk or CD–ROM that
you mail to EPA, mark the outside of the
disk or CD–ROM as CBI and then
identify electronically within the disk or
CD–ROM the specific information that
is claimed as CBI. In addition to one
complete version of the comment that
includes information claimed as CBI, a
copy of the comment that does not
contain the information claimed as CBI
must be submitted for inclusion in the
public docket. Information so marked
will not be disclosed except in
accordance with procedures set forth in
40 CFR part 2.
2. Tips for preparing your comments.
When preparing and submitting your
comments, see the commenting tips at
https://www.epa.gov/dockets/
comments.html.
3. Environmental justice. EPA seeks to
achieve environmental justice, the fair
treatment and meaningful involvement
of any group, including minority and/or
low-income populations, in the
development, implementation, and
enforcement of environmental laws,
regulations, and policies. To help
address potential environmental justice
issues, EPA seeks information on any
groups or segments of the population
who, as a result of their location,
cultural practices, or other factors, may
have atypical or disproportionately high
and adverse human health impacts or
environmental effects from exposure to
the pesticides discussed in this
document, compared to the general
population.
II. What action is EPA taking?
EPA is announcing its receipt of
several pesticide petitions filed under
section 408 of the Federal Food, Drug,
and Cosmetic Act (FFDCA), 21 U.S.C.
346a, requesting the establishment or
modification of regulations in 40 CFR
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part 180 for residues of pesticide
chemicals in or on various food
commodities. EPA is taking public
comment on the requests before
responding to the petitioners. EPA is not
proposing any particular action at this
time. EPA has determined that the
pesticide petitions described in this
document contain the data or
information prescribed in FFDCA
section 408(d)(2), 21 U.S.C. 346a(d)(2);
however, EPA has not fully evaluated
the sufficiency of the submitted data at
this time or whether the data support
granting of the pesticide petitions. After
considering the public comments, EPA
intends to evaluate whether and what
action may be warranted. Additional
data may be needed before EPA can
make a final determination on these
pesticide petitions.
Pursuant to 40 CFR 180.7(f), a
summary of each of the petitions that
are the subject of this document,
prepared by the petitioner, is included
in a docket EPA has created for each
rulemaking. The docket for each of the
petitions is available at https://
www.regulations.gov.
As specified in FFDCA section
408(d)(3), 21 U.S.C. 346a(d)(3), EPA is
publishing notice of the petitions so that
the public has an opportunity to
comment on these requests for the
establishment or modification of
regulations for residues of pesticides in
or on food commodities. Further
information on the petitions may be
obtained through the petition
summaries referenced in this unit.
New Tolerances
1. PP 5E8376. (EPA–HQ–OPP–2015–
0679). Bayer CropScience LP, P.O. Box
12014, 2 T.W. Alexander Dr., Research
Triangle Park, NC 27709, requests to
establish a tolerance in 40 CFR 180.641
for residues of the insecticide
spirotetramat in or on asparagus at 0.10
parts per million (ppm). Liquid
chromatography/triple stage quadruple
mass spectrometry (LC/MS/MS) is used
to measure and evaluate residues of the
chemical spirotetramat.
2. PP 5E8422. (EPA–HQ–OPP–2015–
0829). Interregional Research Project
Number 4 (IR–4), Rutgers University,
500 College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests to
establish tolerances in 40 CFR 180.599
for residues of the insecticide
acequinocyl in or on avocado at 0.4
ppm; bean, dry, seed at 0.03 ppm;
vegetable, cucurbit, group 9 at 0.2 ppm;
tea, plucked leaves at 40 ppm; cherry
subgroup 12–12A at 1.0 ppm; fruit,
citrus, group 10–10 at 0.20 ppm; fruit,
pome, group 11–10 at 0.40 ppm; nut,
tree, group 14–12 at 0.02 ppm; and
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vegetable, fruiting, group 8–10 at 0.70
ppm. The analytical method to
quantitate residues of acequinocyl and
acequinocyl-OH in/on fruit crops
utilizes high pressure liquid
chromatography (HPLC) using mass
spectrometric (MS/MS) detection. The
target limit of quantitation (LOQ) is 0.01
ppm.
3. PP 5E8428. (EPA–HQ–OPP–2016–
0013). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests to
establish tolerances in 40 CFR 180.613
for residues of the insecticide
flonicamid, N-(cyanomethyl)-4(trifluoromethyl)-3pyridinecarboxamide, and its
metabolites, TFNA (4trifluoromethylnicotinic acid), TFNA–
AM (4-trifluoromethylnicotinamide),
and TFNG, N-(4trifluoromethylnicotinoyl)glycine,
calculated as the stoichiometric
equivalent of flonicamid, in or on pea
and bean, dried shelled, except soybean,
subgroup 6C at 3.0 ppm; pea and bean,
succulent shelled, subgroup 6B at 6.0
ppm; and vegetable, legume, edible
podded, subgroup 6A at 4.0 ppm. The
analytical methodology used to measure
and evaluate residues of flonicamid in
various crops includes an initial
extraction, typically with acetonitrile/
deionized water, followed by a liquidliquid partition with ethyl acetate. The
final sample solution is quantitated
using a liquid chromatograph equipped
with a reverse phase column and a
triple quadruple mass spectrometer.
4. PP 5E8434. (EPA–HQ–OPP–2016–
0064). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests to
establish tolerances in 40 CFR 180.579
for residues of fenamidone (4Himidazol-4-one, 3,5-dihydro-5-methyl2-(methylthio)-5-phenyl-3(phenylamino)-, (S)-) in or on the raw
agricultural commodities basil, fresh
leaves at 30 ppm; and basil, dried leaves
at 200 ppm. Additionally, tolerances are
proposed for the crops in the proposed
crop subgroup 4–15A, leafy greens
subgroup at 60.0 ppm, including
amaranth, Chinese; amaranth, leafy;
aster, Indian; blackjack; cat’s whiskers;
chervil, fresh leaves; cham-chwi; chamna-mul; chipilin; chrysanthemum,
garland; cilantro, fresh leaves; corn
salad; cosmos; dandelion; dang-gwi;
dillweed; dock; dol-nam-mul; ebolo;
endive; escarole; fameflower; feather
cockscomb; good king henry;
huauzontle; jute, leaves; lettuce, bitter;
lettuce, head; lettuce, leaf; orach;
parsley, fresh leaves; plantain,
buckhorn; primrose, English; purslane,
garden; purslane, winter; radicchio;
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spinach; spinach, malabar; spinach,
New Zealand; spinach, tanier; swiss
chard; and violet, Chinese; the crops in
the proposed crop subgroup 4–15B,
Brassica leafy greens subgroup at 55
ppm, including arugula; broccoli raab;
broccoli, Chinese; cabbage, Abyssinian;
cabbage, seakale; Chinese cabbage, bok
choy; collards; cress, garden; cress,
upland; hanover salad; kale; maca;
mizuna; mustard greens; radish, leaves;
rape greens; rocket, wild; shepherd’s
purse; turnip greens; and watercress; the
crops in the proposed crop subgroup
22B, leaf petiole vegetable subgroup at
60 ppm, including cardoon; celery;
celery, Chinese; fuki; rhubarb; udo; and
zuiki; the crops in the proposed crop
group 5–15 (Brassica head and stem
vegetable) at 5.0 ppm, including
broccoli; brussels sprouts; cabbage;
cabbage, Chinese, napa; and cauliflower;
cottonseed subgroup 20C at 0.02 ppm;
kohlrabi at 5.0 ppm; celtuce at 60 ppm;
and fennel, Florence, fresh leaves and
stalk at 60 ppm. Residues are quantified
by HPLC with tandem mass
spectrometric detection (LC/MS/MS).
The method LOQ is 0.02 ppm or lower
for fenamidone in all raw agricultural
commodities and processed fractions.
5. PP 5E8437. (EPA–HQ–OPP–2016–
0049). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests to
establish tolerances in 40 CFR 180.685
for residues of the fungicide
oxathiapiprolin, 1-[4-[4-[5-(2,6difluorophenyl)-4,5-dihydro-3isoxazolyl]-2-thiazolyl]-1-piperidinyl]-2[5-methyl-3-(trifluoromethyl)-1Hpyrazol-1-yl]-ethanone, including its
metabolites and degradates, in or on
basil, fresh leaves at 10.0 ppm; basil,
dried leaves at 80 ppm; caneberry
subgroup 13–07A at 0.5 ppm; and, as
designated in the November 14, 2014,
proposed rule ‘‘Tolerance Crop
Grouping Program IV’’ (79 FR 68153):
(i) All individual crops in the
proposed leafy greens subgroup 4–14A
at 15 ppm, including amaranth,
Chinese; amaranth, leafy; aster, Indian;
blackjack; cat’s whiskers; chervil, fresh
leaves; cham-chwi; cham-na-mul;
chipilin; chrysanthemum, garland;
cilantro, fresh leaves; corn salad;
cosmos; dandelion; dang-gwi; dillweed;
dock; dol-nam-mul; ebolo; endive;
escarole; fameflower; feather
cockscomb; good king henry;
huauzontle; jute, leaves; lettuce, bitter;
lettuce, head; lettuce, leaf; orach;
parsley, fresh leaves; plantain,
buckhorn; primrose, English; purslane,
garden; purslane, winter; radicchio;
spinach; spinach, malabar; spinach,
New Zealand; spinach, tanier; swiss
chard; and violet, Chinese;
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(ii) All individual crops in the
proposed Brassica leafy greens subgroup
4–14B at 10 ppm, including arugula;
broccoli raab; broccoli, Chinese;
cabbage, Abyssinian; cabbage, seakale;
Chinese cabbage, bok choy; collards;
cress, garden; cress, upland; hanover
salad; kale; maca; mizuna; mustard
greens; radish, leaves; rape greens;
rocket, wild; shepherd’s purse; turnip
greens; and watercress;
(iii) All individual crops in the
proposed Brassica head and stem
vegetable group 5–14 at 1.5 ppm,
including broccoli; brussels sprouts;
cabbage; cabbage, Chinese, napa; and
cauliflower; and
(iv) All individual crops in the
proposed stalk and stem vegetable
subgroup 22A at 2 ppm, including
agave; aloe vera; asparagus; bamboo,
shoots; celtuce; fennel, Florence, fresh
leaves and stalk; fern, edible; kale, sea;
kohlrabi; palm hearts; prickly pear,
pads; and prickly pear, Texas, pads.
The analytical methodology, high
pressure liquid chromatography with
tandem mass spectrometry (MS/MS)
detection, is used to measure and
evaluate oxathiapiprolin residues.
6. PP 5F8429. (EPA–HQ–OPP–2016–
0029). Gowan Co., P.O. Box 5569,
Yuma, AZ 85366–5569, requests to
establish a tolerance in 40 CFR 180.632
for residues of the miticide/insecticide
fenazaquin (4-[2-[4-(1,1,-dimethylethyl)
phenyl] ethoxy] quinazoline) in or on
the raw commodities for tree nut crop
group 14–12 at 0.02 ppm. The LC/MS/
MS with positive-ion electrospray
ionization tandem mass spectrometry is
used to measure and evaluate the
chemical fenazaquin.
7. PP 5F8441. (EPA–HQ–OPP–2016–
0049). Syngenta Crop Protection LLC,
410 Swing Rd., P.O. Box 18300,
Greensboro, NC 27419–8300, requests to
establish tolerances in 40 CFR 180.685
for residues of the fungicide
oxathiapiprolin in or on citrus fruit crop
group 10–10 at 0.06 ppm; citrus oil at
2.0 ppm; citrus pulp at 0.09 ppm; and
potato, wet peel at 0.07 ppm. The
analytical method using high pressure
liquid chromatography with MS/MS
detection is used to measure and
evaluate the chemical residues of
oxathiapiprolin.
8. PP 6E8446. (EPA–HQ–OPP–2016–
0128). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests to
establish a tolerance in 40 CFR 180.620
for residues of the insecticide
etofenprox (2-(4-ethoxyphenyl)-2methylpropyl 3-phenoxybenzyl ether) in
or on fungi, edible, group 21 at 3.0 ppm.
The analytical method consisting of
liquid chromatography with tandem
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mass spectrometry (LC/MS/MS) is used
to measure and evaluate the chemical
etofenprox.
9. PP 6E8449. (EPA–HQ–OPP–2016–
0160). ISK Biosciences Corp., 7470
Auburn Rd., Suite A, Concord, OH
44077, requests to establish a tolerance
in 40 CFR 180.574 for residues of
fluazinam, including its metabolites and
degradates, in or on the raw agricultural
commodity dried tea at 5.0 ppm.
Analytical methods using gas
chromatography with electron capture
detector for the determination of
fluazinam on dried tea have been
developed and validated.
10. PP 6E8452. (EPA–HQ–OPP–2016–
0166). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests to
establish tolerances in 40 CFR 180.653
for residues of the herbicide indaziflam
(N-[(1R,2S)-2,3-dihydro-2,6-dimethyl1H-inden-1-yl]-6-(1-fluoroethyl)-1,3,5triazine-2,4-diamine) in or on
bushberry, subgroup 13–07B at 0.01
ppm; caneberry, subgroup 13–07A at
0.01 ppm; coffee, green bean at 0.01
ppm; fruit, small, vine climbing, except
fuzzy kiwifruit, subgroup 13–07F at 0.01
ppm; hop, dried cones at 0.03 ppm;
fruit, stone, group 12–12 at 0.01 ppm;
and nut, tree, group 14–12 at 0.01 ppm.
Additionally, tolerances are proposed
for the crops in the proposed crop
subgroup 23A (small fruit, edible peel
subgroup) at 0.01 ppm, including
acerola; African plum; agritos,
almondette; appleberry; arbutus berry;
bayberry, red; bignay; breadnut;
cabeluda; carandas-plum; Ceylon iron
wood; Ceylon olive; cherry-of-the-RioGrande; Chinese olive, black; Chinese
olive, white; chirauli-nut; cocoplum;
desert-date; false sandalwood; fragrant
manjack; gooseberry, Abyssinian;
gooseberry, Ceylon; gooseberry,
otaheite; governor’s plum; grumichama;
guabiroba; guava berry; guava, Brazilian;
guava, Costa Rican; guayabillo; illawarra
plum; Indian-plum; Jamaica-cherry;
jambolan; kaffir-plum; kakadu plum;
kapundung; karnada; lemon aspen;
mombin, yellow; monos plum;
mountain cherry; olive; persimmon,
black; pitomba; plum-of-Martinique;
rukam; rumberry; sea grape; setecapotes; silver aspen; water apple; water
pear; water berry; and wax jambu. The
analytical method consisting of high
pressure liquid chromatography with
triple stage quadrupole mass
spectrometry (LC/MS/MS) is used to
measure and evaluate the chemical
indaziflam.
11. PP 6E8454. (EPA–HQ–OPP–2016–
0171). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests to
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establish a tolerance in 40 CFR 180.659
for residues of pyroxasulfone (3-[[[5(difluoromethoxy)-1-methyl-3(trifluoromethyl)-1H-pyrazol-4yl]methyl]sulfonyl]-4,5-dihydro-5,5dimethylisoxazole) and its metabolites
(5-(difluoromethoxy)-1-methyl-3(trifluoromethyl)-1H-pyrazol-4carboxylic acid (M–3); 5(difluoromethoxy)-3-(trifluoromethyl)1H-pyrazol-4-yl]methanesulfonic acid
(M–25); 3-[1-carboxy-2-(5,5-dimethyl4,5-dihydroisoxazol-3ylthio)ethylamino]-3-oxopropanoic acid
(M–28); and 5-(difluoromethoxy)-1methyl-3-(trifluoromethyl)-1H-pyrazol4-yl]methanesulfonic acid (M–1))
calculated as the stoichiometric
equivalent of pyroxasulfone in or on the
raw agricultural commodity sunflower
subgroup 20B at 0.2 ppm. EPA has
approved an analytical enforcement
methodology including liquid
chromatography, mass spectrometry,
and mass spectrometry (LC/MS/MS) to
enforce the tolerance expression for
pyroxasulfone.
12. PP 6F8455. (EPA–HQ–OPP–2016–
0218). Syngenta Crop Protection LLC,
410 Swing Rd., P.O. Box 18300,
Greensboro, NC 27419–8300 and
Canyon Group LLC, 370 S. Main St.,
Yuma, AZ 85364, request to establish
tolerances in 40 CFR 180.481 for
residues of the herbicide prosulfuron
(N-[[(4-methoxy-6-methyl-1,3,5-triazin2-yl)amino]carbonyl]-2-(3,3,3trifluoropropyl)benzenesulfonamide) in
or on the raw agricultural commodities
grain, cereal, forage, fodder, and straw,
group 16, fodder at 0.01 ppm; grain,
cereal, forage, fodder, and straw, group
16, forage at 0.1 ppm; grain, cereal,
forage, fodder, and straw, group 16, hay
at 0.2 ppm; grain, cereal, forage, fodder,
and straw, group 16, straw at 0.02 ppm;
and grain, cereal, group 15 at 0.01 ppm.
Analytical method AG–590C has been
submitted for the detection and
measurement of residue levels of
prosulfuron in or on plant commodities.
The method is based on cleanup
procedures followed by determination
by high performance liquid
chromatography with ultraviolet (UV)
detection. The LOQ is 0.01 ppm. A more
recent analytical method, Syngenta Crop
Protection Analytical Method REM
137.14, is being submitted for the
determination of prosulfuron residues
in crops based on cleanup procedures
followed by analysis via LC/MS/MS.
The LOQ is 0.01 ppm.
Amended Tolerances
1. PP 5E8422. (EPA–HQ–OPP–2015–
0829). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests, upon
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establishment of the tolerances
referenced above under ‘‘New
Tolerances’’ for PP 5E8422, to remove
existing tolerances in 40 CFR 180.599
for residues of the insecticide
acequinocyl in or on the following raw
agricultural commodities: cucumber at
0.15 ppm; melon, subgroup 9A at 0.15
ppm; cherry, sweet at 0.50 ppm; cherry,
tart at 1.0 ppm; fruit, citrus, group 10 at
0.20 ppm; fruit, pome, group 11 at 0.40
ppm; nut, tree, group 14 at 0.02 ppm;
pistachio at 0.02 ppm; vegetable,
fruiting, group 8 at 0.70 ppm; and okra
at 0.70 ppm. The analytical method to
quantitate residues of acequinocyl and
acequinocyl-OH in/on fruit crops
utilizes HPLC using MS/MS detection.
The target LOQ is 0.01 ppm.
2. PP 5E8428. (EPA–HQ–OPP–2016–
0013). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests to
increase the established tolerance in 40
CFR 180.613 for residues of the
insecticide flonicamid, N(cyanomethyl)-4-(trifluoromethyl)-3pyridinecarboxamide, and its
metabolites, TFNA (4trifluoromethylnicotinic acid), TFNA–
AM (4-trifluoromethylnicotinamide),
and TFNG, N-(4trifluoromethylnicotinoyl)glycine,
calculated as the stoichiometric
equivalent of flonicamid, in or on
vegetable, fruiting, group 8–10 from 0.40
ppm to 1.50 ppm. The analytical
methodology used to measure and
evaluate residues of flonicamid in
various crops includes an initial
extraction, typically with acetonitrile/
deionized water, followed by a liquidliquid partition with ethyl acetate. The
final sample solution is quantitated
using a liquid chromatograph equipped
with a reverse phase column and a
triple quadruple mass spectrometer.
3. PP 5E8434. (EPA–HQ–OPP–2016–
0064). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests, upon
establishment of the tolerances
referenced above under ‘‘New
Tolerances’’ for PP 5E8434, to remove
existing tolerances in 40 CFR 180.579
for residues of fenamidone (4Himidazol-4-one, 3,5-dihydro-5-methyl2-(methylthio)-5-phenyl-3(phenylamino)-, (S)-) in or on the
following raw agricultural commodities:
Brassica, head and stem, subgroup 5A at
5.0 ppm; Brassica, leafy greens,
subgroup 5B at 55 ppm; cotton,
undelinted seed at 0.02 ppm; cilantro,
leaves at 60 ppm; and vegetable, leafy,
except Brassica, group 4 at 60 ppm.
Residues are quantified by HPLC with
LC/MS/MS. The method LOQ is 0.02
ppm or lower for fenamidone in all raw
PO 00000
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Fmt 4702
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agricultural commodities and processed
fractions.
4. PP 5E8437. (EPA–HQ–OPP–2016–
0049). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests to amend
40 CFR 180.685 by removing the
established tolerances for the residues of
the fungicide oxathiapiprolin, 1-[4-[4-[5(2,6-difluorophenyl)-4,5-dihydro-3isoxazolyl]-2-thiazolyl]-1-piperidinyl]-2[5-methyl-3-(trifluoromethyl)-1Hpyrazol-1-yl]-ethanone, including its
metabolites and degradates, in or on
leafy greens, subgroup 4A at 15 ppm;
and Brassica, head and stem, subgroup
5A at 1.5 ppm upon establishment of
the proposed tolerances referenced
above under ‘‘New Tolerances’’ for PP
5E8437. Adequate analytical
methodology, high pressure liquid
chromatography with MS/MS detection,
is available for enforcement purposes.
5. PP 5F8414. (EPA–HQ–OPP–2015–
0791). Valent U.S.A. Corp., 1600 Riviera
Ave., Suite 200, Walnut Creek, CA
94596, requests to amend the tolerances
in 40 CFR 180.627 for residues of the
fungicide fluopicolide in or on
vegetables, tuberous and corm
(subgroup 1C) at 0.10 ppm; and potato
processed waste at 0.25 ppm. Practical
analytical methods for detecting and
measuring levels of fluopicolide and its
metabolites have been developed,
validated, and submitted for all
appropriate plant and animal matrices.
6. PP 5F8429. (EPA–HQ–OPP–2016–
0029). Gowan Co., P.O. Box 5569,
Yuma, AZ 85366–5569, requests to
amend 40 CFR 180.632 by removing the
established tolerance for residues of the
miticide/insecticide fenazaquin (4-[2-[4(1,1,-dimethylethyl) phenyl] ethoxy]
quinazoline) in or on the raw
commodity almond at 0.02 ppm upon
establishment of the proposed tolerance
referenced above under ‘‘New
Tolerances’’ for PP 5F8429.
7. PP 5F8441. (EPA–HQ–OPP–2016–
0049). Syngenta Crop Protection LLC,
410 Swing Rd., P.O. Box 18300,
Greensboro, NC 27419–8300, requests to
amend the tolerance in 40 CFR 180.685
for residues of the fungicide
oxathiapiprolin in or on tuberous and
corm vegetables, subgroup 1C at 0.04
ppm. The analytical method using high
pressure liquid chromatography with
MS/MS detection is used to measure
and evaluate the chemical residues of
oxathiapiprolin.
8. PP 6E8446. (EPA–HQ–OPP–2016–
0128). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests to amend
the tolerances in 40 CFR 180.620 for
residues of the insecticide etofenprox
(2-(4-ethoxyphenyl)-2-methylpropyl 3-
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Federal Register / Vol. 81, No. 97 / Thursday, May 19, 2016 / Proposed Rules
asabaliauskas on DSK3SPTVN1PROD with PROPOSALS
phenoxybenzyl ether) in or on all food
commodities (including feed
commodities) not otherwise listed from
5.0 ppm to 0.40 ppm. This amendment
may potentially impact/reduce the
tolerances established in or on livestock
commodities. The analytical method
consisting of LC/MS/MS is used to
measure and evaluate the chemical
etofenprox.
9. PP 6E8452. (EPA–HQ–OPP–2016–
0166). IR–4, Rutgers University, 500
College Rd. East, Suite 201 W,
Princeton, NJ 08540, requests, upon
establishment of the tolerances
referenced above under ‘‘New
Tolerances’’ for PP 6E8452, to remove
existing tolerances in 40 CFR 180.653
for residues of the herbicide indaziflam
(N-[(1R,2S)-2,3-dihydro-2,6-dimethyl1H-inden-1-yl]-6-(1-fluoroethyl)-1,3,5triazine-2,4-diamine) in or on fruit,
stone, group 12 at 0.01 ppm; nut, tree,
group 14 at 0.01 ppm; grape at 0.01
VerDate Sep<11>2014
17:52 May 18, 2016
Jkt 238001
ppm; and pistachio at 0.01 ppm. The
analytical method consisting of LC/MS/
MS is used to measure and evaluate the
chemical indaziflam.
New Tolerance Exemptions
1. PP IN–10891. (EPA–HQ–OPP–
2016–0123). BASF Corp., 26 Davis Dr.,
Research Triangle Park, NC 27709,
requests to establish an exemption from
the requirement of a tolerance for
residues of Bacillus simplex strain
BU288 when used as a pesticide inert
ingredient (emulsifier) applied to
growing crops and raw agricultural
commodities after harvest under 40 CFR
180.910. The petitioner believes no
analytical method is needed because it
is not required for an exemption from
the requirement of a tolerance.
2. PP IN–10907. (EPA–HQ–OPP–
2016–0201). Keller and Heckman, LLP,
1001 G St. NW., Suite 500 West,
Washington, DC 20001 (on behalf of
PO 00000
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Sfmt 9990
31585
Trinseo LLC, 1000 Chesterbrook Blvd.,
Berwyn, PA 19312–1084), requests to
establish an exemption from the
requirement of a tolerance for residues
of butanedioic acid, 2-methylene-,
polymer with 1,3-butadiene,
ethenylbenzene and 2-hydroxyethyl 2propenoate (CAS Reg. No. 36089–06–2)
when used as an inert ingredient
(emulsifier or binder) in pesticide
formulations under 40 CFR 180.960.
The petitioner believes no analytical
method is needed because it is not
required for an exemption from the
requirement of a tolerance.
Authority: 21 U.S.C. 346a.
Dated: May 6, 2016.
Robert C. McNally,
Director, Biopesticides and Pollution
Prevention Division, Office of Pesticide
Programs.
[FR Doc. 2016–11835 Filed 5–18–16; 8:45 am]
BILLING CODE 6560–50–P
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Agencies
[Federal Register Volume 81, Number 97 (Thursday, May 19, 2016)]
[Proposed Rules]
[Pages 31581-31585]
From the Federal Register Online via the Government Publishing Office [www.gpo.gov]
[FR Doc No: 2016-11835]
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ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 180
[EPA-HQ-OPP-2015-0032; FRL-9946-02]
Receipt of Several Pesticide Petitions Filed for Residues of
Pesticide Chemicals In or On Various Commodities
AGENCY: Environmental Protection Agency (EPA).
ACTION: Notice of filing of petitions and request for comment.
-----------------------------------------------------------------------
SUMMARY: This document announces EPA's receipt of several initial
filings of pesticide petitions requesting the establishment or
modification of regulations for residues of pesticide chemicals in or
on various commodities.
DATES: Comments must be received on or before June 20, 2016.
ADDRESSES: Submit your comments, identified by the Docket
Identification (ID) Number and the Pesticide Petition Number (PP) of
interest as shown in the body of this document, by one of the following
methods:
Federal eRulemaking Portal: https://www.regulations.gov.
Follow the online instructions for submitting comments. Do not submit
electronically any information you consider to be Confidential Business
Information (CBI) or other information whose disclosure is restricted
by statute.
Mail: OPP Docket, Environmental Protection Agency Docket
Center (EPA/DC), (28221T), 1200 Pennsylvania Ave. NW., Washington, DC
20460-0001.
Hand Delivery: To make special arrangements for hand
delivery or delivery of boxed information, please follow the
instructions at https://www.epa.gov/dockets/contacts.html. Additional
instructions on commenting or visiting the docket, along with more
information about dockets generally, is available at https://www.epa.gov/dockets.
FOR FURTHER INFORMATION CONTACT: Susan Lewis, Registration Division
(7505P), Office of Pesticide Programs, Environmental Protection Agency,
1200 Pennsylvania Ave. NW., Washington, DC 20460-0001; main telephone
number: (703) 305-7090; email address: RDFRNotices@epa.gov.
SUPPLEMENTARY INFORMATION:
I. General Information
A. Does this action apply to me?
You may be potentially affected by this action if you are an
agricultural producer, food manufacturer, or pesticide manufacturer.
The following list of North American Industrial Classification System
(NAICS) codes is not intended to be exhaustive, but rather provides a
guide to help readers determine whether this document
[[Page 31582]]
applies to them. Potentially affected entities may include:
[emsp14]Crop production (NAICS code 111).
[emsp14]Animal production (NAICS code 112).
[emsp14]Food manufacturing (NAICS code 311).
[emsp14]Pesticide manufacturing (NAICS code 32532).
If you have any questions regarding the applicability of this
action to a particular entity, consult the person listed under FOR
FURTHER INFORMATION CONTACT.
B. What should I consider as I prepare my comments for EPA?
1. Submitting CBI. Do not submit this information to EPA through
regulations.gov or email. Clearly mark the part or all of the
information that you claim to be CBI. For CBI information in a disk or
CD-ROM that you mail to EPA, mark the outside of the disk or CD-ROM as
CBI and then identify electronically within the disk or CD-ROM the
specific information that is claimed as CBI. In addition to one
complete version of the comment that includes information claimed as
CBI, a copy of the comment that does not contain the information
claimed as CBI must be submitted for inclusion in the public docket.
Information so marked will not be disclosed except in accordance with
procedures set forth in 40 CFR part 2.
2. Tips for preparing your comments. When preparing and submitting
your comments, see the commenting tips at https://www.epa.gov/dockets/comments.html.
3. Environmental justice. EPA seeks to achieve environmental
justice, the fair treatment and meaningful involvement of any group,
including minority and/or low-income populations, in the development,
implementation, and enforcement of environmental laws, regulations, and
policies. To help address potential environmental justice issues, EPA
seeks information on any groups or segments of the population who, as a
result of their location, cultural practices, or other factors, may
have atypical or disproportionately high and adverse human health
impacts or environmental effects from exposure to the pesticides
discussed in this document, compared to the general population.
II. What action is EPA taking?
EPA is announcing its receipt of several pesticide petitions filed
under section 408 of the Federal Food, Drug, and Cosmetic Act (FFDCA),
21 U.S.C. 346a, requesting the establishment or modification of
regulations in 40 CFR part 180 for residues of pesticide chemicals in
or on various food commodities. EPA is taking public comment on the
requests before responding to the petitioners. EPA is not proposing any
particular action at this time. EPA has determined that the pesticide
petitions described in this document contain the data or information
prescribed in FFDCA section 408(d)(2), 21 U.S.C. 346a(d)(2); however,
EPA has not fully evaluated the sufficiency of the submitted data at
this time or whether the data support granting of the pesticide
petitions. After considering the public comments, EPA intends to
evaluate whether and what action may be warranted. Additional data may
be needed before EPA can make a final determination on these pesticide
petitions.
Pursuant to 40 CFR 180.7(f), a summary of each of the petitions
that are the subject of this document, prepared by the petitioner, is
included in a docket EPA has created for each rulemaking. The docket
for each of the petitions is available at https://www.regulations.gov.
As specified in FFDCA section 408(d)(3), 21 U.S.C. 346a(d)(3), EPA
is publishing notice of the petitions so that the public has an
opportunity to comment on these requests for the establishment or
modification of regulations for residues of pesticides in or on food
commodities. Further information on the petitions may be obtained
through the petition summaries referenced in this unit.
New Tolerances
1. PP 5E8376. (EPA-HQ-OPP-2015-0679). Bayer CropScience LP, P.O.
Box 12014, 2 T.W. Alexander Dr., Research Triangle Park, NC 27709,
requests to establish a tolerance in 40 CFR 180.641 for residues of the
insecticide spirotetramat in or on asparagus at 0.10 parts per million
(ppm). Liquid chromatography/triple stage quadruple mass spectrometry
(LC/MS/MS) is used to measure and evaluate residues of the chemical
spirotetramat.
2. PP 5E8422. (EPA-HQ-OPP-2015-0829). Interregional Research
Project Number 4 (IR-4), Rutgers University, 500 College Rd. East,
Suite 201 W, Princeton, NJ 08540, requests to establish tolerances in
40 CFR 180.599 for residues of the insecticide acequinocyl in or on
avocado at 0.4 ppm; bean, dry, seed at 0.03 ppm; vegetable, cucurbit,
group 9 at 0.2 ppm; tea, plucked leaves at 40 ppm; cherry subgroup 12-
12A at 1.0 ppm; fruit, citrus, group 10-10 at 0.20 ppm; fruit, pome,
group 11-10 at 0.40 ppm; nut, tree, group 14-12 at 0.02 ppm; and
vegetable, fruiting, group 8-10 at 0.70 ppm. The analytical method to
quantitate residues of acequinocyl and acequinocyl-OH in/on fruit crops
utilizes high pressure liquid chromatography (HPLC) using mass
spectrometric (MS/MS) detection. The target limit of quantitation (LOQ)
is 0.01 ppm.
3. PP 5E8428. (EPA-HQ-OPP-2016-0013). IR-4, Rutgers University, 500
College Rd. East, Suite 201 W, Princeton, NJ 08540, requests to
establish tolerances in 40 CFR 180.613 for residues of the insecticide
flonicamid, N-(cyanomethyl)-4-(trifluoromethyl)-3-pyridinecarboxamide,
and its metabolites, TFNA (4-trifluoromethylnicotinic acid), TFNA-AM
(4-trifluoromethylnicotinamide), and TFNG, N-(4-
trifluoromethylnicotinoyl)glycine, calculated as the stoichiometric
equivalent of flonicamid, in or on pea and bean, dried shelled, except
soybean, subgroup 6C at 3.0 ppm; pea and bean, succulent shelled,
subgroup 6B at 6.0 ppm; and vegetable, legume, edible podded, subgroup
6A at 4.0 ppm. The analytical methodology used to measure and evaluate
residues of flonicamid in various crops includes an initial extraction,
typically with acetonitrile/deionized water, followed by a liquid-
liquid partition with ethyl acetate. The final sample solution is
quantitated using a liquid chromatograph equipped with a reverse phase
column and a triple quadruple mass spectrometer.
4. PP 5E8434. (EPA-HQ-OPP-2016-0064). IR-4, Rutgers University, 500
College Rd. East, Suite 201 W, Princeton, NJ 08540, requests to
establish tolerances in 40 CFR 180.579 for residues of fenamidone (4H-
imidazol-4-one, 3,5-dihydro-5-methyl- 2-(methylthio)-5-phenyl-3-
(phenylamino)-, (S)-) in or on the raw agricultural commodities basil,
fresh leaves at 30 ppm; and basil, dried leaves at 200 ppm.
Additionally, tolerances are proposed for the crops in the proposed
crop subgroup 4-15A, leafy greens subgroup at 60.0 ppm, including
amaranth, Chinese; amaranth, leafy; aster, Indian; blackjack; cat's
whiskers; chervil, fresh leaves; cham-chwi; cham-na-mul; chipilin;
chrysanthemum, garland; cilantro, fresh leaves; corn salad; cosmos;
dandelion; dang-gwi; dillweed; dock; dol-nam-mul; ebolo; endive;
escarole; fameflower; feather cockscomb; good king henry; huauzontle;
jute, leaves; lettuce, bitter; lettuce, head; lettuce, leaf; orach;
parsley, fresh leaves; plantain, buckhorn; primrose, English; purslane,
garden; purslane, winter; radicchio;
[[Page 31583]]
spinach; spinach, malabar; spinach, New Zealand; spinach, tanier; swiss
chard; and violet, Chinese; the crops in the proposed crop subgroup 4-
15B, Brassica leafy greens subgroup at 55 ppm, including arugula;
broccoli raab; broccoli, Chinese; cabbage, Abyssinian; cabbage,
seakale; Chinese cabbage, bok choy; collards; cress, garden; cress,
upland; hanover salad; kale; maca; mizuna; mustard greens; radish,
leaves; rape greens; rocket, wild; shepherd's purse; turnip greens; and
watercress; the crops in the proposed crop subgroup 22B, leaf petiole
vegetable subgroup at 60 ppm, including cardoon; celery; celery,
Chinese; fuki; rhubarb; udo; and zuiki; the crops in the proposed crop
group 5-15 (Brassica head and stem vegetable) at 5.0 ppm, including
broccoli; brussels sprouts; cabbage; cabbage, Chinese, napa; and
cauliflower; cottonseed subgroup 20C at 0.02 ppm; kohlrabi at 5.0 ppm;
celtuce at 60 ppm; and fennel, Florence, fresh leaves and stalk at 60
ppm. Residues are quantified by HPLC with tandem mass spectrometric
detection (LC/MS/MS). The method LOQ is 0.02 ppm or lower for
fenamidone in all raw agricultural commodities and processed fractions.
5. PP 5E8437. (EPA-HQ-OPP-2016-0049). IR-4, Rutgers University, 500
College Rd. East, Suite 201 W, Princeton, NJ 08540, requests to
establish tolerances in 40 CFR 180.685 for residues of the fungicide
oxathiapiprolin, 1-[4-[4-[5-(2,6-difluorophenyl)-4,5-dihydro-3-
isoxazolyl]-2-thiazolyl]-1-piperidinyl]-2-[5-methyl-3-
(trifluoromethyl)-1H-pyrazol-1-yl]-ethanone, including its metabolites
and degradates, in or on basil, fresh leaves at 10.0 ppm; basil, dried
leaves at 80 ppm; caneberry subgroup 13-07A at 0.5 ppm; and, as
designated in the November 14, 2014, proposed rule ``Tolerance Crop
Grouping Program IV'' (79 FR 68153):
(i) All individual crops in the proposed leafy greens subgroup 4-
14A at 15 ppm, including amaranth, Chinese; amaranth, leafy; aster,
Indian; blackjack; cat's whiskers; chervil, fresh leaves; cham-chwi;
cham-na-mul; chipilin; chrysanthemum, garland; cilantro, fresh leaves;
corn salad; cosmos; dandelion; dang-gwi; dillweed; dock; dol-nam-mul;
ebolo; endive; escarole; fameflower; feather cockscomb; good king
henry; huauzontle; jute, leaves; lettuce, bitter; lettuce, head;
lettuce, leaf; orach; parsley, fresh leaves; plantain, buckhorn;
primrose, English; purslane, garden; purslane, winter; radicchio;
spinach; spinach, malabar; spinach, New Zealand; spinach, tanier; swiss
chard; and violet, Chinese;
(ii) All individual crops in the proposed Brassica leafy greens
subgroup 4-14B at 10 ppm, including arugula; broccoli raab; broccoli,
Chinese; cabbage, Abyssinian; cabbage, seakale; Chinese cabbage, bok
choy; collards; cress, garden; cress, upland; hanover salad; kale;
maca; mizuna; mustard greens; radish, leaves; rape greens; rocket,
wild; shepherd's purse; turnip greens; and watercress;
(iii) All individual crops in the proposed Brassica head and stem
vegetable group 5-14 at 1.5 ppm, including broccoli; brussels sprouts;
cabbage; cabbage, Chinese, napa; and cauliflower; and
(iv) All individual crops in the proposed stalk and stem vegetable
subgroup 22A at 2 ppm, including agave; aloe vera; asparagus; bamboo,
shoots; celtuce; fennel, Florence, fresh leaves and stalk; fern,
edible; kale, sea; kohlrabi; palm hearts; prickly pear, pads; and
prickly pear, Texas, pads.
The analytical methodology, high pressure liquid chromatography
with tandem mass spectrometry (MS/MS) detection, is used to measure and
evaluate oxathiapiprolin residues.
6. PP 5F8429. (EPA-HQ-OPP-2016-0029). Gowan Co., P.O. Box 5569,
Yuma, AZ 85366-5569, requests to establish a tolerance in 40 CFR
180.632 for residues of the miticide/insecticide fenazaquin (4-[2-[4-
(1,1,-dimethylethyl) phenyl] ethoxy] quinazoline) in or on the raw
commodities for tree nut crop group 14-12 at 0.02 ppm. The LC/MS/MS
with positive-ion electrospray ionization tandem mass spectrometry is
used to measure and evaluate the chemical fenazaquin.
7. PP 5F8441. (EPA-HQ-OPP-2016-0049). Syngenta Crop Protection LLC,
410 Swing Rd., P.O. Box 18300, Greensboro, NC 27419-8300, requests to
establish tolerances in 40 CFR 180.685 for residues of the fungicide
oxathiapiprolin in or on citrus fruit crop group 10-10 at 0.06 ppm;
citrus oil at 2.0 ppm; citrus pulp at 0.09 ppm; and potato, wet peel at
0.07 ppm. The analytical method using high pressure liquid
chromatography with MS/MS detection is used to measure and evaluate the
chemical residues of oxathiapiprolin.
8. PP 6E8446. (EPA-HQ-OPP-2016-0128). IR-4, Rutgers University, 500
College Rd. East, Suite 201 W, Princeton, NJ 08540, requests to
establish a tolerance in 40 CFR 180.620 for residues of the insecticide
etofenprox (2-(4-ethoxyphenyl)-2-methylpropyl 3-phenoxybenzyl ether) in
or on fungi, edible, group 21 at 3.0 ppm. The analytical method
consisting of liquid chromatography with tandem mass spectrometry (LC/
MS/MS) is used to measure and evaluate the chemical etofenprox.
9. PP 6E8449. (EPA-HQ-OPP-2016-0160). ISK Biosciences Corp., 7470
Auburn Rd., Suite A, Concord, OH 44077, requests to establish a
tolerance in 40 CFR 180.574 for residues of fluazinam, including its
metabolites and degradates, in or on the raw agricultural commodity
dried tea at 5.0 ppm. Analytical methods using gas chromatography with
electron capture detector for the determination of fluazinam on dried
tea have been developed and validated.
10. PP 6E8452. (EPA-HQ-OPP-2016-0166). IR-4, Rutgers University,
500 College Rd. East, Suite 201 W, Princeton, NJ 08540, requests to
establish tolerances in 40 CFR 180.653 for residues of the herbicide
indaziflam (N-[(1R,2S)-2,3-dihydro-2,6-dimethyl-1H-inden-1-yl]-6-(1-
fluoroethyl)-1,3,5-triazine-2,4-diamine) in or on bushberry, subgroup
13-07B at 0.01 ppm; caneberry, subgroup 13-07A at 0.01 ppm; coffee,
green bean at 0.01 ppm; fruit, small, vine climbing, except fuzzy
kiwifruit, subgroup 13-07F at 0.01 ppm; hop, dried cones at 0.03 ppm;
fruit, stone, group 12-12 at 0.01 ppm; and nut, tree, group 14-12 at
0.01 ppm. Additionally, tolerances are proposed for the crops in the
proposed crop subgroup 23A (small fruit, edible peel subgroup) at 0.01
ppm, including acerola; African plum; agritos, almondette; appleberry;
arbutus berry; bayberry, red; bignay; breadnut; cabeluda; carandas-
plum; Ceylon iron wood; Ceylon olive; cherry-of-the-Rio-Grande; Chinese
olive, black; Chinese olive, white; chirauli-nut; cocoplum; desert-
date; false sandalwood; fragrant manjack; gooseberry, Abyssinian;
gooseberry, Ceylon; gooseberry, otaheite; governor's plum; grumichama;
guabiroba; guava berry; guava, Brazilian; guava, Costa Rican;
guayabillo; illawarra plum; Indian-plum; Jamaica-cherry; jambolan;
kaffir-plum; kakadu plum; kapundung; karnada; lemon aspen; mombin,
yellow; monos plum; mountain cherry; olive; persimmon, black; pitomba;
plum-of-Martinique; rukam; rumberry; sea grape; sete-capotes; silver
aspen; water apple; water pear; water berry; and wax jambu. The
analytical method consisting of high pressure liquid chromatography
with triple stage quadrupole mass spectrometry (LC/MS/MS) is used to
measure and evaluate the chemical indaziflam.
11. PP 6E8454. (EPA-HQ-OPP-2016-0171). IR-4, Rutgers University,
500 College Rd. East, Suite 201 W, Princeton, NJ 08540, requests to
[[Page 31584]]
establish a tolerance in 40 CFR 180.659 for residues of pyroxasulfone
(3-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-
yl]methyl]sulfonyl]-4,5-dihydro-5,5-dimethylisoxazole) and its
metabolites (5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-
pyrazol-4-carboxylic acid (M-3); 5-(difluoromethoxy)-3-
(trifluoromethyl)-1H-pyrazol-4-yl]methanesulfonic acid (M-25); 3-[1-
carboxy-2-(5,5-dimethyl-4,5-dihydroisoxazol-3-ylthio)ethylamino]-3-
oxopropanoic acid (M-28); and 5-(difluoromethoxy)-1-methyl-3-
(trifluoromethyl)-1H-pyrazol-4-yl]methanesulfonic acid (M-1))
calculated as the stoichiometric equivalent of pyroxasulfone in or on
the raw agricultural commodity sunflower subgroup 20B at 0.2 ppm. EPA
has approved an analytical enforcement methodology including liquid
chromatography, mass spectrometry, and mass spectrometry (LC/MS/MS) to
enforce the tolerance expression for pyroxasulfone.
12. PP 6F8455. (EPA-HQ-OPP-2016-0218). Syngenta Crop Protection
LLC, 410 Swing Rd., P.O. Box 18300, Greensboro, NC 27419-8300 and
Canyon Group LLC, 370 S. Main St., Yuma, AZ 85364, request to establish
tolerances in 40 CFR 180.481 for residues of the herbicide prosulfuron
(N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]-2-(3,3,3-
trifluoropropyl)benzenesulfonamide) in or on the raw agricultural
commodities grain, cereal, forage, fodder, and straw, group 16, fodder
at 0.01 ppm; grain, cereal, forage, fodder, and straw, group 16, forage
at 0.1 ppm; grain, cereal, forage, fodder, and straw, group 16, hay at
0.2 ppm; grain, cereal, forage, fodder, and straw, group 16, straw at
0.02 ppm; and grain, cereal, group 15 at 0.01 ppm. Analytical method
AG-590C has been submitted for the detection and measurement of residue
levels of prosulfuron in or on plant commodities. The method is based
on cleanup procedures followed by determination by high performance
liquid chromatography with ultraviolet (UV) detection. The LOQ is 0.01
ppm. A more recent analytical method, Syngenta Crop Protection
Analytical Method REM 137.14, is being submitted for the determination
of prosulfuron residues in crops based on cleanup procedures followed
by analysis via LC/MS/MS. The LOQ is 0.01 ppm.
Amended Tolerances
1. PP 5E8422. (EPA-HQ-OPP-2015-0829). IR-4, Rutgers University, 500
College Rd. East, Suite 201 W, Princeton, NJ 08540, requests, upon
establishment of the tolerances referenced above under ``New
Tolerances'' for PP 5E8422, to remove existing tolerances in 40 CFR
180.599 for residues of the insecticide acequinocyl in or on the
following raw agricultural commodities: cucumber at 0.15 ppm; melon,
subgroup 9A at 0.15 ppm; cherry, sweet at 0.50 ppm; cherry, tart at 1.0
ppm; fruit, citrus, group 10 at 0.20 ppm; fruit, pome, group 11 at 0.40
ppm; nut, tree, group 14 at 0.02 ppm; pistachio at 0.02 ppm; vegetable,
fruiting, group 8 at 0.70 ppm; and okra at 0.70 ppm. The analytical
method to quantitate residues of acequinocyl and acequinocyl-OH in/on
fruit crops utilizes HPLC using MS/MS detection. The target LOQ is 0.01
ppm.
2. PP 5E8428. (EPA-HQ-OPP-2016-0013). IR-4, Rutgers University, 500
College Rd. East, Suite 201 W, Princeton, NJ 08540, requests to
increase the established tolerance in 40 CFR 180.613 for residues of
the insecticide flonicamid, N-(cyanomethyl)-4-(trifluoromethyl)-3-
pyridinecarboxamide, and its metabolites, TFNA (4-
trifluoromethylnicotinic acid), TFNA-AM (4-
trifluoromethylnicotinamide), and TFNG, N-(4-
trifluoromethylnicotinoyl)glycine, calculated as the stoichiometric
equivalent of flonicamid, in or on vegetable, fruiting, group 8-10 from
0.40 ppm to 1.50 ppm. The analytical methodology used to measure and
evaluate residues of flonicamid in various crops includes an initial
extraction, typically with acetonitrile/deionized water, followed by a
liquid-liquid partition with ethyl acetate. The final sample solution
is quantitated using a liquid chromatograph equipped with a reverse
phase column and a triple quadruple mass spectrometer.
3. PP 5E8434. (EPA-HQ-OPP-2016-0064). IR-4, Rutgers University, 500
College Rd. East, Suite 201 W, Princeton, NJ 08540, requests, upon
establishment of the tolerances referenced above under ``New
Tolerances'' for PP 5E8434, to remove existing tolerances in 40 CFR
180.579 for residues of fenamidone (4H-imidazol-4-one, 3,5-dihydro-5-
methyl- 2-(methylthio)-5-phenyl-3-(phenylamino)-, (S)-) in or on the
following raw agricultural commodities: Brassica, head and stem,
subgroup 5A at 5.0 ppm; Brassica, leafy greens, subgroup 5B at 55 ppm;
cotton, undelinted seed at 0.02 ppm; cilantro, leaves at 60 ppm; and
vegetable, leafy, except Brassica, group 4 at 60 ppm. Residues are
quantified by HPLC with LC/MS/MS. The method LOQ is 0.02 ppm or lower
for fenamidone in all raw agricultural commodities and processed
fractions.
4. PP 5E8437. (EPA-HQ-OPP-2016-0049). IR-4, Rutgers University, 500
College Rd. East, Suite 201 W, Princeton, NJ 08540, requests to amend
40 CFR 180.685 by removing the established tolerances for the residues
of the fungicide oxathiapiprolin, 1-[4-[4-[5-(2,6-difluorophenyl)-4,5-
dihydro-3-isoxazolyl]-2-thiazolyl]-1-piperidinyl]-2-[5-methyl-3-
(trifluoromethyl)-1H-pyrazol-1-yl]-ethanone, including its metabolites
and degradates, in or on leafy greens, subgroup 4A at 15 ppm; and
Brassica, head and stem, subgroup 5A at 1.5 ppm upon establishment of
the proposed tolerances referenced above under ``New Tolerances'' for
PP 5E8437. Adequate analytical methodology, high pressure liquid
chromatography with MS/MS detection, is available for enforcement
purposes.
5. PP 5F8414. (EPA-HQ-OPP-2015-0791). Valent U.S.A. Corp., 1600
Riviera Ave., Suite 200, Walnut Creek, CA 94596, requests to amend the
tolerances in 40 CFR 180.627 for residues of the fungicide fluopicolide
in or on vegetables, tuberous and corm (subgroup 1C) at 0.10 ppm; and
potato processed waste at 0.25 ppm. Practical analytical methods for
detecting and measuring levels of fluopicolide and its metabolites have
been developed, validated, and submitted for all appropriate plant and
animal matrices.
6. PP 5F8429. (EPA-HQ-OPP-2016-0029). Gowan Co., P.O. Box 5569,
Yuma, AZ 85366-5569, requests to amend 40 CFR 180.632 by removing the
established tolerance for residues of the miticide/insecticide
fenazaquin (4-[2-[4-(1,1,-dimethylethyl) phenyl] ethoxy] quinazoline)
in or on the raw commodity almond at 0.02 ppm upon establishment of the
proposed tolerance referenced above under ``New Tolerances'' for PP
5F8429.
7. PP 5F8441. (EPA-HQ-OPP-2016-0049). Syngenta Crop Protection LLC,
410 Swing Rd., P.O. Box 18300, Greensboro, NC 27419-8300, requests to
amend the tolerance in 40 CFR 180.685 for residues of the fungicide
oxathiapiprolin in or on tuberous and corm vegetables, subgroup 1C at
0.04 ppm. The analytical method using high pressure liquid
chromatography with MS/MS detection is used to measure and evaluate the
chemical residues of oxathiapiprolin.
8. PP 6E8446. (EPA-HQ-OPP-2016-0128). IR-4, Rutgers University, 500
College Rd. East, Suite 201 W, Princeton, NJ 08540, requests to amend
the tolerances in 40 CFR 180.620 for residues of the insecticide
etofenprox (2-(4-ethoxyphenyl)-2-methylpropyl 3-
[[Page 31585]]
phenoxybenzyl ether) in or on all food commodities (including feed
commodities) not otherwise listed from 5.0 ppm to 0.40 ppm. This
amendment may potentially impact/reduce the tolerances established in
or on livestock commodities. The analytical method consisting of LC/MS/
MS is used to measure and evaluate the chemical etofenprox.
9. PP 6E8452. (EPA-HQ-OPP-2016-0166). IR-4, Rutgers University, 500
College Rd. East, Suite 201 W, Princeton, NJ 08540, requests, upon
establishment of the tolerances referenced above under ``New
Tolerances'' for PP 6E8452, to remove existing tolerances in 40 CFR
180.653 for residues of the herbicide indaziflam (N-[(1R,2S)-2,3-
dihydro-2,6-dimethyl-1H-inden-1-yl]-6-(1-fluoroethyl)-1,3,5-triazine-
2,4-diamine) in or on fruit, stone, group 12 at 0.01 ppm; nut, tree,
group 14 at 0.01 ppm; grape at 0.01 ppm; and pistachio at 0.01 ppm. The
analytical method consisting of LC/MS/MS is used to measure and
evaluate the chemical indaziflam.
New Tolerance Exemptions
1. PP IN-10891. (EPA-HQ-OPP-2016-0123). BASF Corp., 26 Davis Dr.,
Research Triangle Park, NC 27709, requests to establish an exemption
from the requirement of a tolerance for residues of Bacillus simplex
strain BU288 when used as a pesticide inert ingredient (emulsifier)
applied to growing crops and raw agricultural commodities after harvest
under 40 CFR 180.910. The petitioner believes no analytical method is
needed because it is not required for an exemption from the requirement
of a tolerance.
2. PP IN-10907. (EPA-HQ-OPP-2016-0201). Keller and Heckman, LLP,
1001 G St. NW., Suite 500 West, Washington, DC 20001 (on behalf of
Trinseo LLC, 1000 Chesterbrook Blvd., Berwyn, PA 19312-1084), requests
to establish an exemption from the requirement of a tolerance for
residues of butanedioic acid, 2-methylene-, polymer with 1,3-butadiene,
ethenylbenzene and 2-hydroxyethyl 2-propenoate (CAS Reg. No. 36089-06-
2) when used as an inert ingredient (emulsifier or binder) in pesticide
formulations under 40 CFR 180.960. The petitioner believes no
analytical method is needed because it is not required for an exemption
from the requirement of a tolerance.
Authority: 21 U.S.C. 346a.
Dated: May 6, 2016.
Robert C. McNally,
Director, Biopesticides and Pollution Prevention Division, Office of
Pesticide Programs.
[FR Doc. 2016-11835 Filed 5-18-16; 8:45 am]
BILLING CODE 6560-50-P