Hexythiazox; Pesticide Tolerances, 19891-19896 [2016-07661]
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Federal Register / Vol. 81, No. 66 / Wednesday, April 6, 2016 / Rules and Regulations
control number and adding, in its place,
‘‘2900–0219’’.
The addition reads as follows:
§ 17.903
Payme.
(a)(1) * * * For those services or
benefits covered by §§ 17.900 through
17.905 but not covered by CHAMPVA
we will use payment methodologies the
same or similar to those used for
equivalent services or benefits provided
to veterans.
*
*
*
*
*
§ 17.904
[Amended]
5. Amend § 17.904 by, at the end of
the section, removing ‘‘2900–0578’’
from the notice of the Office of
Management and Budget control
number and adding, in its place, ‘‘2900–
0219’’.
■
[FR Doc. 2016–07897 Filed 4–5–16; 8:45 am]
BILLING CODE 8320–01–P
ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Part 180
[EPA–HQ–OPP–2015–0338 and EPA–HQ–
OPP–2015–0339; FRL–9942–32]
Hexythiazox; Pesticide Tolerances
Environmental Protection
Agency (EPA).
ACTION: Final rule.
AGENCY:
This regulation amends
tolerances for residues of hexythiazox in
or on citrus and cotton. Gowan
Company requested these tolerances
under the Federal Food, Drug, and
Cosmetic Act (FFDCA).
DATES: This regulation is effective April
6, 2016. Objections and requests for
hearings must be received on or before
June 6, 2016, and must be filed in
accordance with the instructions
provided in 40 CFR part 178 (see also
Unit I.C. of the SUPPLEMENTARY
INFORMATION).
SUMMARY:
The dockets for this action,
identified by docket identification (ID)
number EPA–HQ–OPP–2015–0338 and
EPA–HQ–OPP–2015–0339, are available
at https://www.regulations.gov or at the
Office of Pesticide Programs Regulatory
Public Docket (OPP Docket) in the
Environmental Protection Agency
Docket Center (EPA/DC), West William
Jefferson Clinton Bldg., Rm. 3334, 1301
Constitution Ave. NW., Washington, DC
20460–0001. The Public Reading Room
is open from 8:30 a.m. to 4:30 p.m.,
Monday through Friday, excluding legal
holidays. The telephone number for the
Public Reading Room is (202) 566–1744,
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ADDRESSES:
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and the telephone number for the OPP
Docket is (703) 305–5805. Please review
the visitor instructions and additional
information about the docket available
at https://www.epa.gov/dockets.
FOR FURTHER INFORMATION CONTACT:
Susan Lewis, Registration Division
(7505P), Office of Pesticide Programs,
Environmental Protection Agency, 1200
Pennsylvania Ave. NW., Washington,
DC 20460–0001; main telephone
number: (703) 305–7090; email address:
RDFRNotices@epa.gov.
SUPPLEMENTARY INFORMATION:
I. General Information
A. Does this action apply to me?
You may be potentially affected by
this action if you are an agricultural
producer, food manufacturer, or
pesticide manufacturer. The following
list of North American Industrial
Classification System (NAICS) codes is
not intended to be exhaustive, but rather
provides a guide to help readers
determine whether this document
applies to them. Potentially affected
entities may include:
• Crop production (NAICS code 111).
• Animal production (NAICS code
112).
• Food manufacturing (NAICS code
311).
• Pesticide manufacturing (NAICS
code 32532).
B. How can I get electronic access to
other related information?
You may access a frequently updated
electronic version of EPA’s tolerance
regulations at 40 CFR part 180 through
the Government Printing Office’s e-CFR
site at https://www.ecfr.gov/cgi-bin/textidx?&c=ecfr&tpl=/ecfrbrowse/Title40/
40tab_02.tpl.
C. How can I file an objection or hearing
request?
Under FFDCA section 408(g), 21
U.S.C. 346a, any person may file an
objection to any aspect of this regulation
and may also request a hearing on those
objections. You must file your objection
or request a hearing on this regulation
in accordance with the instructions
provided in 40 CFR part 178. To ensure
proper receipt by EPA, you must
identify docket ID number EPA–HQ–
OPP–2015–0338 and EPA–HQ–OPP–
2015–0339 in the subject line on the
first page of your submission. All
objections and requests for a hearing
must be in writing, and must be
received by the Hearing Clerk on or
before June 6, 2016. Addresses for mail
and hand delivery of objections and
hearing requests are provided in 40 CFR
178.25(b).
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19891
In addition to filing an objection or
hearing request with the Hearing Clerk
as described in 40 CFR part 178, please
submit a copy of the filing (excluding
any Confidential Business Information
(CBI)) for inclusion in the public docket.
Information not marked confidential
pursuant to 40 CFR part 2 may be
disclosed publicly by EPA without prior
notice. Submit the non-CBI copy of your
objection or hearing request, identified
by docket ID number EPA–HQ–OPP–
2015–0338 and EPA–HQ–OPP–2015–
0339, by one of the following methods:
• Federal eRulemaking Portal: https://
www.regulations.gov. Follow the online
instructions for submitting comments.
Do not submit electronically any
information you consider to be CBI or
other information whose disclosure is
restricted by statute.
• Mail: OPP Docket, Environmental
Protection Agency Docket Center
(EPA/DC), (28221T), 1200 Pennsylvania
Ave. NW., Washington, DC 20460–0001.
• Hand Delivery: To make special
arrangements for hand delivery or
delivery of boxed information, please
follow the instructions at https://
www.epa.gov/dockets/contacts.html.
Additional instructions on commenting
or visiting the docket, along with more
information about dockets generally, is
available at https://www.epa.gov/
dockets.
II. Summary of Petitioned-for Tolerance
In the Federal Register of July 17,
2015 (80 FR 42462) (FRL–9929–13),
EPA issued a document pursuant to
FFDCA section 408(d)(3), 21 U.S.C.
346a(d)(3), announcing the filing of
pesticide petitions (PP 5F8346 and PP
5F8356) by Gowan Company, P.O. Box
5569, Yuma, AZ 85366–5569. The
petitions requested that tolerances
currently listed in 40 CFR 180.448 be
amended for residues of the insecticide
hexythiazox and its metabolites
containing the (4-chlorophenyl)-4methyl-2-oxo-3-thiazolidine moiety, in
or on citrus, dried pulp at 0.6 parts per
million (ppm); citrus, oil at 26 ppm;
fruit, citrus, group 10 at 0.6 ppm; cotton
gin byproducts at 15 ppm; and cotton,
undelinted seed at 0.5 ppm. That
document referenced a summary of the
petitions prepared by Gowan Company,
the registrant, which is available in the
docket, https://www.regulations.gov.
There were no comments received in
response to the notice of filing.
Based upon review of the data
supporting the petition, EPA has
revoked citrus, dried pulp tolerance as
it is covered by the recommended fruit,
citrus, group 10–10 tolerance. For citrus
oil, EPA revised the tolerance to 25 ppm
and for cotton undelinted seed to 0.4
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ppm. The reasons for these changes are
explained in Unit IV.C.
III. Aggregate Risk Assessment and
Determination of Safety
Section 408(b)(2)(A)(i) of FFDCA
allows EPA to establish a tolerance (the
legal limit for a pesticide chemical
residue in or on a food) only if EPA
determines that the tolerance is ‘‘safe.’’
Section 408(b)(2)(A)(ii) of FFDCA
defines ‘‘safe’’ to mean that ‘‘there is a
reasonable certainty that no harm will
result from aggregate exposure to the
pesticide chemical residue, including
all anticipated dietary exposures and all
other exposures for which there is
reliable information.’’ This includes
exposure through drinking water and in
residential settings, but does not include
occupational exposure. Section
408(b)(2)(C) of FFDCA requires EPA to
give special consideration to exposure
of infants and children to the pesticide
chemical residue in establishing a
tolerance and to ‘‘ensure that there is a
reasonable certainty that no harm will
result to infants and children from
aggregate exposure to the pesticide
chemical residue. . . .’’
Consistent with FFDCA section
408(b)(2)(D), and the factors specified in
FFDCA section 408(b)(2)(D), EPA has
reviewed the available scientific data
and other relevant information in
support of this action. EPA has
sufficient data to assess the hazards of
and to make a determination on
aggregate exposure for hexythiazox
including exposure resulting from the
tolerances established by this action.
EPA’s assessment of exposures and risks
associated with hexythiazox follows.
A. Toxicological Profile
EPA has evaluated the available
toxicity data and considered its validity,
completeness, and reliability as well as
the relationship of the results of the
studies to human risk. EPA has also
considered available information
concerning the variability of the
sensitivities of major identifiable
subgroups of consumers, including
infants and children. Hexythiazox has
low acute toxicity by oral, dermal and
inhalation routes of exposure. It is not
a dermal irritant, is negative for dermal
sensitization and produces only mild
eye irritation. Hexythiazox is associated
with toxicity of the liver and adrenals
following subchronic and chronic
exposure to dogs, rats and mice, with
the dog being the most sensitive species.
The prenatal developmental studies in
rabbits and rats and the two-generation
reproduction study in rats showed no
indication of increased susceptibility to
in utero or postnatal exposure to
hexythiazox. Reproductive toxicity was
not observed. There is no concern for
immunotoxicity or neurotoxicity
following exposure to hexythiazox. The
toxicology database for hexythiazox
does not show any evidence of
treatment-related effects on the immune
system. Hexythiazox is classified as
‘‘likely to be carcinogenic to humans;’’
however, the weight of evidence
indicates that assessing chronic risk
using the chronic population adjusted
dose will be protective for any potential
carcinogenic effects. Since the effects
seen in the study that serves as the basis
for the chronic PAD occurred at doses
substantially below the lowest dose that
induced tumors, the chronic PAD is
considered protective of all chronic
effects including potential
carcinogenicity.
Specific information on the studies
received and the nature of the adverse
effects caused by hexythiazox as well as
the no-observed-adverse-effect-level
(NOAEL) and the lowest-observedadverse-effect-level (LOAEL) from the
toxicity studies can be found at https://
www.regulations.gov in the document:
Hexythiazox. Human Health Risk
Assessment to Support Amended Uses
on Cotton and Citrus in docket ID
number EPA–HQ–OPP–2015–0338 or
EPA–HQ–OPP–2015–0339.
B. Toxicological Points of Departure/
Levels of Concern
Once a pesticide’s toxicological
profile is determined, EPA identifies
toxicological points of departure (POD)
and levels of concern to use in
evaluating the risk posed by human
exposure to the pesticide. For hazards
that have a threshold below which there
is no appreciable risk, the toxicological
POD is used as the basis for derivation
of reference values for risk assessment.
PODs are developed based on a careful
analysis of the doses in each
toxicological study to determine the
dose at which no adverse effects are
observed (the NOAEL) and the lowest
dose at which adverse effects of concern
are identified (the LOAEL). Uncertainty/
safety factors are used in conjunction
with the POD to calculate a safe
exposure level—generally referred to as
a population-adjusted dose (PAD) or a
reference dose (RfD)—and a safe margin
of exposure (MOE). For non-threshold
risks, the Agency assumes that any
amount of exposure will lead to some
degree of risk. Thus, the Agency
estimates risk in terms of the probability
of an occurrence of the adverse effect
expected in a lifetime. For more
information on the general principles
EPA uses in risk characterization and a
complete description of the risk
assessment process, see https://
www.epa.gov/pesticides/factsheets/
riskassess.htm. A summary of the
toxicological endpoints for hexythiazox
used for human risk assessment is
shown in Table 1 of this unit.
TABLE 1—SUMMARY OF TOXICOLOGICAL DOSES AND ENDPOINTS FOR HEXYTHIAZOX FOR USE IN HUMAN HEALTH RISK
ASSESSMENT
Exposure/scenario
Point of departure
and
uncertainty/safety
factors
RfD, PAD, LOC for
risk
assessment
Study and toxicological effects
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Acute dietary (All populations) ..
No risk is expected from this exposure scenario as no hazard was identified in any toxicity study for this duration of exposure.
Chronic dietary (All populations)
NOAEL = 2.5 mg/kg/
day UFA = 10x.
UFH = 10x
FQPA SF = 1x
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Chronic RfD = 0.025
mg/kg/day.
cPAD = 0.025 mg/
kg/day
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1-year toxicity feeding study—Dog
LOAEL = 12.5 mg/kg/day based on increased absolute and relative adrenal weights and associated adrenal histopathology.
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TABLE 1—SUMMARY OF TOXICOLOGICAL DOSES AND ENDPOINTS FOR HEXYTHIAZOX FOR USE IN HUMAN HEALTH RISK
ASSESSMENT—Continued
Point of departure
and
uncertainty/safety
factors
RfD, PAD, LOC for
risk
assessment
Incidental oral short-term (1 to
30 days) and intermediateterm (1 to 6 months).
NOAEL = 30 mg/kg/
day UFA = 10x.
UFH = 10x
FQPA SF = 1x
LOC for MOE = 100
2-generation reproduction study—Rat.
LOAEL = 180 mg/kg/day based on decreased pup body weight
during lactation and delayed hair growth and/or eye opening,
and decreased parental body-weight gain and increased absolute and relative liver, kidney, and adrenal weights.
Co-critical
13-Week Oral Toxicity Study—Rat.
NOAEL = 5.5 mg/kg/day
LOAEL = 38 mg/kg/day, based on increased absolute and relative liver weights in both sexes, increased relative ovarian
and kidney weights, and fatty degeneration of the adrenal
zona fasciculata.
@397.5/257.6 mg/kg/day, decreased body-weight gain in females, slight swelling of hepatocytes in central zone (both
sexes), increased incidence of glomerulonephrosis in males,
increased adrenal weights.
Inhalation short-term (1 to 30
days) and
intermediate-term (1 to 6
months).
Oral study NOAEL =
30 mg/kg/day (inhalation absorption
rate = 100%).
UFA = 10x
UFH = 10x
LOC for MOE = 100
2-generation reproduction study—Rat.
LOAEL = 180 mg/kg/day based on decreased pup body weight
during lactation and delayed hair growth and/or eye opening,
and decreased parental body-weight gain and increased absolute and relative liver, kidney, and adrenal weights.
Co-Critical
13-Week Feeding Study—Rat.
LOAEL = 38.1 mg/kg/day, based on increased absolute and
relative liver weights in both sexes, increased relative ovarian
and kidney weights, and fatty degeneration of the adrenal
zona fasciculata.
Cancer (Oral, dermal, inhalation).
Classification: ‘‘Likely to be Carcinogenic to Humans’’. Insufficient evidence to warrant a quantitative estimation
of human risk using a cancer slope factor based on the common liver tumors (benign and malignant) observed
only in high dose female mice, and benign mammary gland tumors of no biological significance, observed only
in high dose male rats in the absence of mutagenic concerns. The chronic RfD is protective of all chronic effects including potential carcinogenicity of hexythiazox.
Exposure/scenario
Study and toxicological effects
FQPA SF = Food Quality Protection Act Safety Factor. LOAEL = lowest-observed-adverse-effect-level. LOC = level of concern. mg/kg/day =
milligram/kilogram/day. MOE = margin of exposure. NOAEL = no-observed-adverse-effect-level. PAD = population adjusted dose (a = acute, c =
chronic). RfD = reference dose. UF = uncertainty factor. UFA = extrapolation from animal to human (interspecies). UFH = potential variation in
sensitivity among members of the human population (intraspecies).
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C. Exposure Assessment
1. Dietary exposure from food and
feed uses. In evaluating dietary
exposure to hexythiazox, EPA
considered exposure under the
petitioned-for tolerances as well as all
existing hexythiazox tolerances in 40
CFR 180.448. EPA assessed dietary
exposures from hexythiazox in food as
follows:
i. Acute exposure. Quantitative acute
dietary exposure and risk assessments
are performed for a food-use pesticide,
if a toxicological study has indicated the
possibility of an effect of concern
occurring as a result of a 1-day or single
exposure. No such effects were
identified in the toxicological studies
for hexythiazox; therefore, a quantitative
acute dietary exposure assessment is
unnecessary.
ii. Chronic exposure. In conducting
the chronic dietary exposure assessment
EPA used the food consumption data
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from the U.S. Department of
Agriculture’s 2003–2008 National
Health and Nutrition Examination
Survey, What We Eat in America
(NHANES/WWEIA). As to residue levels
in food, EPA used tolerance-level
residues, assumed 100 percent crop
treated (PCT), and incorporated DEEM
default processing factors when
processing data were not available.
iii. Cancer. Based on the data
summarized in Unit III.A., EPA has
concluded that a nonlinear RfD
approach is appropriate for assessing
cancer risk to hexythiazox. Cancer risk
was assessed using the same exposure
estimates as discussed in Unit III.C.1.ii.
iv. Anticipated residue and percent
crop treated (PCT) information. EPA did
not use anticipated residue and/or PCT
information in the dietary assessment
for hexythiazox. Tolerance-level
residues and/or 100% CT were assumed
for all food commodities.
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2. Dietary exposure from drinking
water. The Agency used screening-level
water exposure models in the dietary
exposure analysis and risk assessment
for hexythiazox in drinking water.
These simulation models take into
account data on the physical, chemical,
and fate/transport characteristics of
hexythiazox. Further information
regarding EPA drinking water models
used in pesticide exposure assessment
can be found at https://www.epa.gov/
oppefed1/models/water/index.htm.
Based on the Surface Water
Concentration Calculator, the estimated
drinking water concentrations (EDWCs)
of hexythiazox for chronic exposures for
non-cancer assessments are estimated to
be 4.3 parts per billion (ppb) for surface
water. Since groundwater residues are
not expected to exceed surface water
residues, surface water residues were
used in the dietary risk assessment.
Modeled estimates of drinking water
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concentrations were directly entered
into the dietary exposure model.
3. From non-dietary exposure. The
term ‘‘residential exposure’’ is used in
this document to refer to nonoccupational, non-dietary exposure
(e.g., for lawn and garden pest control,
indoor pest control, termiticides, and
flea and tick control on pets).
Hexythiazox is currently registered for
the following uses that could result in
residential exposures: Ornamental
plantings, lawns, recreational sites such
as campgrounds and golf courses, turf,
and fruit and nut trees in residential
settings. EPA assessed residential
exposure using the following
assumptions:
Residential handler exposures are
expected to be short-term (1 to 30 days)
via either the dermal or inhalation
routes of exposures. Intermediate-term
exposures are not likely because of the
intermittent nature of applications by
residential applicators. Since
hexythiazox does not pose a significant
dermal risk, a quantitative dermal risk
assessment was not performed and
handler margins of exposure (MOE)
were calculated for the inhalation route
of exposure only.
Both adults and children may be
exposed to hexythiazox residues from
contact with treated lawns or treated
residential plants. Post-application
exposures are expected to be short-term
(1 to 30 days) in duration for most
exposure scenarios, and intermediateterm (1 to 6 months) in duration for soil
ingestion only due to the aerobic soil
metabolism half-life for hexythiazox.
Adult post-application exposures were
not assessed since no quantitative
dermal risk assessment is needed for
hexythiazox and inhalation exposures
are typically negligible in outdoor
settings. The exposure assessment for
children included incidental oral
exposure resulting from transfer of
residues from the hands or objects to the
mouth, and from incidental ingestion of
soil.
Further information regarding EPA
standard assumptions and generic
inputs for residential exposures may be
found at https://www.epa.gov/pesticides/
trac/science/trac6a05.pdf.
4. Cumulative effects from substances
with a common mechanism of toxicity.
Section 408(b)(2)(D)(v) of FFDCA
requires that, when considering whether
to establish, modify, or revoke a
tolerance, the Agency consider
‘‘available information’’ concerning the
cumulative effects of a particular
pesticide’s residues and ‘‘other
substances that have a common
mechanism of toxicity.’’ EPA has not
found hexythiazox to share a common
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mechanism of toxicity with any other
substances, and hexythiazox does not
appear to produce a toxic metabolite.
For the purposes of this tolerance
action, therefore, EPA has assumed that
hexythiazox does not have a common
mechanism of toxicity with other
substances. For information regarding
EPA’s efforts to determine which
chemicals have a common mechanism
of toxicity and to evaluate the
cumulative effects of such chemicals,
see EPA’s Web site at https://
www.epa.gov/pesticides/cumulative.
D. Safety Factor for Infants and
Children
1. In general. Section 408(b)(2)(C) of
FFDCA provides that EPA shall apply
an additional tenfold (10X) margin of
safety for infants and children in the
case of threshold effects to account for
prenatal and postnatal toxicity and the
completeness of the database on toxicity
and exposure unless EPA determines
based on reliable data that a different
margin of safety will be safe for infants
and children. This additional margin of
safety is commonly referred to as the
FQPA Safety Factor (SF). In applying
this provision, EPA either retains the
default value of 10X, or uses a different
additional safety factor when reliable
data available to EPA support the choice
of a different factor.
2. Prenatal and postnatal sensitivity.
The prenatal development studies in
rabbits and rats and the two-generation
reproduction study in rats showed no
indication of increased susceptibility to
in utero and/or postnatal exposure to
hexythiazox.
3. Conclusion. EPA has determined
that reliable data show the safety of
infants and children would be
adequately protected if the FQPA SF
were reduced to 1X. That decision is
based on the following findings:
i. The toxicity database for
hexythiazox is complete.
ii. There is no indication that
hexythiazox is a neurotoxic chemical
and there is no need for a
developmental neurotoxicity study or
additional UFs to account for
neurotoxicity.
iii. There is no evidence that
hexythiazox results in increased
susceptibility in in utero rats or rabbits
in the prenatal developmental studies or
in young rats in the 2-generation
reproduction study.
iv. There are no residual uncertainties
identified in the exposure databases.
EPA made conservative (protective)
assumptions in the ground and surface
water modeling used to assess exposure
to hexythiazox in drinking water. EPA
used similarly conservative assumptions
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to assess post-application exposure of
children as well as incidental oral
exposure of toddlers. These assessments
will not underestimate the exposure and
risks posed by hexythiazox.
E. Aggregate Risks and Determination of
Safety
EPA determines whether acute and
chronic dietary pesticide exposures are
safe by comparing aggregate exposure
estimates to the acute PAD (aPAD) and
chronic PAD (cPAD). For linear cancer
risks, EPA calculates the lifetime
probability of acquiring cancer given the
estimated aggregate exposure. Short-,
intermediate- and chronic-term risks are
evaluated by comparing the estimated
aggregate food, water, and residential
exposure to the appropriate PODs to
ensure that an adequate MOE exists.
1. Acute risk. An acute aggregate risk
assessment takes into account acute
exposure estimates from dietary
consumption of food and drinking
water. No adverse effect, resulting from
a single oral exposure, was identified
and no acute dietary endpoint was
selected. Therefore, hexythiazox is not
expected to pose an acute risk.
2. Chronic risk. Using the exposure
assumptions described in this unit for
chronic exposure, EPA has concluded
that chronic exposure to hexythiazox
from food and water will utilize 81% of
the cPAD for children 1 to 2 years of
age, the population group receiving the
greatest exposure. Based on the
explanation in Unit III.C.3., regarding
residential use patterns, chronic
residential exposure to residues of
hexythiazox is not expected.
3. Short-term risk. Short-term
aggregate exposure takes into account
short-term residential exposure plus
chronic exposure to food and water
(considered to be a background
exposure level).
Hexythiazox is currently registered for
uses that could result in short-term
residential exposure, and the Agency
has determined that it is appropriate to
aggregate chronic exposure through food
and water with short-term residential
exposures to hexythiazox.
Using the exposure assumptions
described in this unit for short-term
exposures, EPA has concluded the
combined short-term food, water, and
residential exposures result in aggregate
MOEs of 1,300 for children and 9,900
for adults. Because EPA’s level of
concern for hexythiazox is a MOE of 100
or below, these MOEs are not of
concern.
4. Intermediate-term risk.
Intermediate-term aggregate exposure
takes into account intermediate-term
residential exposure plus chronic
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exposure to food and water (considered
to be a background exposure level).
Hexythiazox is currently registered for
uses that could result in intermediateterm residential exposure, and the
Agency has determined that it is
appropriate to aggregate chronic
exposure through food and water with
intermediate-term residential exposures
to hexythiazox.
Using the exposure assumptions
described in this unit for intermediateterm exposures, EPA has concluded that
the combined intermediate-term food,
water, and residential exposures result
in aggregate MOEs of 1,500 for children
and 9,900 for adults. Because EPA’s
level of concern for hexythiazox is a
MOE of 100 or below, these MOEs are
not of concern.
5. Aggregate cancer risk for U.S.
population. As discussed in Unit
III.C.1.iii., EPA concluded that
regulation based on the chronic
reference dose will be protective for
both chronic and carcinogenic risks. As
noted in this unit, there are no chronic
risks of concern.
6. Determination of safety. Based on
these risk assessments, EPA concludes
that there is a reasonable certainty that
no harm will result to the general
population, or to infants and children
from aggregate exposure to hexythiazox
residues.
IV. Other Considerations
A. Analytical Enforcement Methodology
Adequate enforcement methodology
(high performance liquid
chromatography method with
ultraviolet detection (HPLC/UV)) is
available to enforce the tolerance
expression. This method is listed in the
U.S. EPA Index of Residue Analytical
methods under hexythiazox as method
AMR–985–87.
asabaliauskas on DSK3SPTVN1PROD with RULES
B. International Residue Limits
In making its tolerance decisions, EPA
seeks to harmonize U.S. tolerances with
international standards whenever
possible, consistent with U.S. food
safety standards and agricultural
practices. EPA considers the
international maximum residue limits
(MRLs) established by the Codex
Alimentarius Commission (Codex), as
required by FFDCA section 408(b)(4).
The Codex Alimentarius is a joint
United Nations Food and Agriculture
Organization/World Health
Organization food standards program,
and it is recognized as an international
food safety standards-setting
organization in trade agreements to
which the United States is a party. EPA
may establish a tolerance that is
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different from a Codex MRL; however,
FFDCA section 408(b)(4) requires that
EPA explain the reasons for departing
from the Codex level.
The Codex has established MRLs for
residues of hexythiazox on citrus, fruits
but not for cotton. The Codex plant
residue definition is for hexythiazox as
opposed to the U.S. definition which
includes hexythiazox plus metabolites
containing the (4-chlorophenyl)-4methyl-2-oxo-3-thiazolidine moiety. The
differences in U.S. and Codex residue
definitions prohibits harmonization.
C. Revisions to Petitioned-for Tolerances
Although the petitioner requested an
amended tolerance for citrus, dried pulp
at 0.6, the Agency has determined that
no such tolerance is necessary because
that commodity is covered by the
established citrus group 10–10
tolerance. The Agency is revising the
tolerance for citrus oil to 25 ppm based
on the following: By multiplying the
citrus oil processing factor (104X) from
the 2006 processing study (D334889, 07/
03/2006, T. Bloem) by the highest
average field trial (HAFT) residue for
lemons (0.243 ppm) from the submitted
citrus study since lemons are the citrus
crop that produced the highest residues.
As noted in its most recent crop group
rulemaking in the Federal Register of
August 22, 2012 (77 FR 50617) (FRL–
9354–3), EPA generally does not
establish new tolerances under preexisting crop groups that have been
updated. EPA updated crop group 10 in
2010, making the new group 10–10.
Therefore, EPA is establishing citrus
fruit group tolerances for group 10–10,
rather than crop group 10 as requested.
The Agency is amending the tolerance
for cotton, undelinted seed at 0.4 ppm
based on the available cotton data that
reflect a national use at the label
specified 35 day pre-harvest internal
(PHI) to calculate the 0.4 ppm tolerance.
V. Conclusion
Therefore, tolerances are amended for
residues of hexythiazox and its
metabolites containing the (4chlorophenyl)-4-methyl-2-oxo-3thiazolidine moiety, in or on citrus, oil
at 25 ppm; fruit, citrus, group 10–10 at
0.6 ppm; cotton, gin byproducts at 15
ppm; cotton, undelinted seed at 0.4
ppm. The current citrus, dried pulp
tolerance is revoked because it is
unnecessary due to the establishment of
the fruit, citrus, group 10–10 tolerance.
VI. Statutory and Executive Order
Reviews
This action amends tolerances under
FFDCA section 408(d) in response to a
petition submitted to the Agency. The
PO 00000
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Fmt 4700
Sfmt 4700
19895
Office of Management and Budget
(OMB) has exempted these types of
actions from review under Executive
Order 12866, entitled ‘‘Regulatory
Planning and Review’’ (58 FR 51735,
October 4, 1993). Because this action
has been exempted from review under
Executive Order 12866, this action is
not subject to Executive Order 13211,
entitled ‘‘Actions Concerning
Regulations That Significantly Affect
Energy Supply, Distribution, or Use’’ (66
FR 28355, May 22, 2001) or Executive
Order 13045, entitled ‘‘Protection of
Children from Environmental Health
Risks and Safety Risks’’ (62 FR 19885,
April 23, 1997). This action does not
contain any information collections
subject to OMB approval under the
Paperwork Reduction Act (PRA) (44
U.S.C. 3501 et seq.), nor does it require
any special considerations under
Executive Order 12898, entitled
‘‘Federal Actions to Address
Environmental Justice in Minority
Populations and Low-Income
Populations’’ (59 FR 7629, February 16,
1994).
Since tolerances and exemptions that
are established on the basis of a petition
under FFDCA section 408(d), such as
the tolerance in this final rule, do not
require the issuance of a proposed rule,
the requirements of the Regulatory
Flexibility Act (RFA) (5 U.S.C. 601 et
seq.), do not apply.
This action directly regulates growers,
food processors, food handlers, and food
retailers, not States or tribes, nor does
this action alter the relationships or
distribution of power and
responsibilities established by Congress
in the preemption provisions of FFDCA
section 408(n)(4). As such, the Agency
has determined that this action will not
have a substantial direct effect on States
or tribal governments, on the
relationship between the national
government and the States or tribal
governments, or on the distribution of
power and responsibilities among the
various levels of government or between
the Federal Government and Indian
tribes. Thus, the Agency has determined
that Executive Order 13132, entitled
‘‘Federalism’’ (64 FR 43255, August 10,
1999) and Executive Order 13175,
entitled ‘‘Consultation and Coordination
with Indian Tribal Governments’’ (65 FR
67249, November 9, 2000) do not apply
to this action. In addition, this action
does not impose any enforceable duty or
contain any unfunded mandate as
described under Title II of the Unfunded
Mandates Reform Act (UMRA) (2 U.S.C.
1501 et seq.).
This action does not involve any
technical standards that would require
Agency consideration of voluntary
E:\FR\FM\06APR1.SGM
06APR1
19896
Federal Register / Vol. 81, No. 66 / Wednesday, April 6, 2016 / Rules and Regulations
consensus standards pursuant to section
12(d) of the National Technology
Transfer and Advancement Act
(NTTAA) (15 U.S.C. 272 note).
Cotton, undelinted seed .............
VII. Congressional Review Act
*
Pursuant to the Congressional Review
Act (5 U.S.C. 801 et seq.), EPA will
submit a report containing this rule and
other required information to the U.S.
Senate, the U.S. House of
Representatives, and the Comptroller
General of the United States prior to
publication of the rule in the Federal
Register. This action is not a ‘‘major
rule’’ as defined by 5 U.S.C. 804(2).
List of Subjects in 40 CFR Part 180
Environmental protection,
Administrative practice and procedure,
Agricultural commodities, Pesticides
and pests, Reporting and recordkeeping
requirements.
Dated: March 22, 2016.
Susan Lewis,
Director, Registration Division, Office of
Pesticide Programs.
Parts per
million
Commodity
*
*
0.4
*
*
(c) Tolerances with regional
registrations. * * *
Parts per
million
Commodity
*
*
*
*
*
Fruit, citrus group 10–10 (CA,
AZ, TX only) ............................
*
*
*
*
*
*
*
0.6
*
*
*
[FR Doc. 2016–07661 Filed 4–5–16; 8:45 am]
BILLING CODE 6560–50–P
FEDERAL COMMUNICATIONS
COMMISSION
Therefore, 40 CFR chapter I is
amended as follows:
47 CFR Part 15
PART 180—[AMENDED]
[ET Docket No. 13–49; FCC 16–24]
1. The authority citation for part 180
continues to read as follows:
Unlicensed—National Information
Infrastructure, Order on
Reconsideration
■
Authority: 21 U.S.C. 321(q), 346a and 371.
2. In § 180.448:
i. Add alphabetically the entries for
‘‘Cotton, gin byproducts’’ and ‘‘Cotton,
undelinted seed’’ to the table in
paragraph (a).
■ ii. Remove the entry for ‘‘Citrus, dried
pulp’’ from the table in paragraph (a).
■ iii. Revise the entry for ‘‘Citrus, oil’’ in
the table in paragraph (a).
■ iv. Remove the entries for ‘‘Cotton, gin
byproducts, CA and AZ only’’, and
‘‘Cotton, undelinted seed, CA and AZ
only’’ from the table in paragraph (c).
■ v. Revise the entry for ‘‘Fruit, citrus
group 10 (CA, AZ, TX only)’’ in the
table in paragraph (c).
The additions and revisions read as
follows:
asabaliauskas on DSK3SPTVN1PROD with RULES
■
■
Federal Communications
Commission.
ACTION: Final rule.
AGENCY:
This document responds to
seven petitions for reconsideration of
certain rules adopted in the First Report
and Order (First R&O) in this
proceeding, the Commission amends its
Part 15 rules governing the operation of
unlicensed National Information
Infrastructure (U–NII) devices in the 5
GHz band. These rule changes are
intended to make broadband
technologies more widely available for
consumers and businesses by
temporarily increasing the in-band
power limits and permanently
increasing the out-of- band power limits
§ 180.448 Hexythiazox; tolerances for
for certain U–NII–3 band devices. The
residues.
Commission also takes steps to maintain
(a) General. * * *
certain levels of interference protection
for other authorized operations within
Parts per
the 5 GHz band.
Commodity
million
DATES: Effective May 6, 2016.
FOR FURTHER INFORMATION CONTACT: Aole
*
*
*
*
*
Wilkins, Office of Engineering and
Technology, (202) 418–2406, email:
Citrus, oil .....................................
25 Aole.Wilkins@fcc.gov, TTY (202) 418–
2989.
*
*
*
*
*
SUPPLEMENTARY INFORMATION: This is a
Cotton, gin byproducts ...............
15 summary of the Commission’s
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16:28 Apr 05, 2016
Jkt 238001
SUMMARY:
PO 00000
Frm 00040
Fmt 4700
Sfmt 4700
Memorandum Opinion & Order
(MO&O), ET Docket No. 13–49, FCC 16–
24, adopted March 1, 2015, and released
March 2, 2016. The full text of this
document is available for inspection
and copying during normal business
hours in the FCC Reference Center
(Room CY–A257), 445 12th Street SW.,
Washington, DC 20554. The full text
may also be downloaded at:
www.fcc.gov. People with Disabilities:
To request materials in accessible
formats for people with disabilities
(braille, large print, electronic files,
audio format), send an email to fcc504@
fcc.gov or call the Consumer &
Governmental Affairs Bureau at 202–
418–0530 (voice), 202–418–0432 (tty).
Summary of Memorandum Opinion
and Order
A. U–NII–3 Band Proposals for Changes
to the First R&O
1. Prior to adoption of the First R&O,
the FCC’s rules permitted the
certification of devices that operate in
the 5.725–5.85 GHz (U–NII–3) band
under two different rule sections (i.e.
Sections 15.247 and 15.407). In some
instances, and especially for devices
that operate in point-to-point
configurations with high gain antennas,
the old Section 15.247 out-of-band
emission (OOBE) limits were as much as
47 dB more permissive than the Section
15.407 OOBE limits and, therefore
devices certified under the old limits
were significantly more likely to create
harmful interference to other operations.
In the First R&O, the Commission
adopted a consolidated set of rules for
the 5.725–5.85 GHz band devices under
the Section 15.407 U–NII rules to
resolve interference issues to Terminal
Doppler Weather Radar (TDWR) and
other radar facilities in the adjacent
band. In the First R&O, the Commission
recognized that point-to-point systems
utilizing high gain transmit antennas
certified under the old Section 15.247
requirement may have to be modified to
comply with the lower OOBE limit
required for operation under Section
15.407. The Commission stated that
manufacturers had the flexibility to
determine how they should meet the
lower OOBE limits, whether by
reducing output power, decreasing the
transmit antenna gain, or utilizing
improved bandpass filters.
2. In response to the First R&O, the
Commission received several petitions
for reconsideration of its decision.
Petitioners, mainly manufacturers and
operators of high gain point-to-point
communication systems, ask that the
Commission’s decision to impose more
restrictive OOBE limits for devices in
E:\FR\FM\06APR1.SGM
06APR1
Agencies
[Federal Register Volume 81, Number 66 (Wednesday, April 6, 2016)]
[Rules and Regulations]
[Pages 19891-19896]
From the Federal Register Online via the Government Publishing Office [www.gpo.gov]
[FR Doc No: 2016-07661]
=======================================================================
-----------------------------------------------------------------------
ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 180
[EPA-HQ-OPP-2015-0338 and EPA-HQ-OPP-2015-0339; FRL-9942-32]
Hexythiazox; Pesticide Tolerances
AGENCY: Environmental Protection Agency (EPA).
ACTION: Final rule.
-----------------------------------------------------------------------
SUMMARY: This regulation amends tolerances for residues of hexythiazox
in or on citrus and cotton. Gowan Company requested these tolerances
under the Federal Food, Drug, and Cosmetic Act (FFDCA).
DATES: This regulation is effective April 6, 2016. Objections and
requests for hearings must be received on or before June 6, 2016, and
must be filed in accordance with the instructions provided in 40 CFR
part 178 (see also Unit I.C. of the SUPPLEMENTARY INFORMATION).
ADDRESSES: The dockets for this action, identified by docket
identification (ID) number EPA-HQ-OPP-2015-0338 and EPA-HQ-OPP-2015-
0339, are available at https://www.regulations.gov or at the Office of
Pesticide Programs Regulatory Public Docket (OPP Docket) in the
Environmental Protection Agency Docket Center (EPA/DC), West William
Jefferson Clinton Bldg., Rm. 3334, 1301 Constitution Ave. NW.,
Washington, DC 20460-0001. The Public Reading Room is open from 8:30
a.m. to 4:30 p.m., Monday through Friday, excluding legal holidays. The
telephone number for the Public Reading Room is (202) 566-1744, and the
telephone number for the OPP Docket is (703) 305-5805. Please review
the visitor instructions and additional information about the docket
available at https://www.epa.gov/dockets.
FOR FURTHER INFORMATION CONTACT: Susan Lewis, Registration Division
(7505P), Office of Pesticide Programs, Environmental Protection Agency,
1200 Pennsylvania Ave. NW., Washington, DC 20460-0001; main telephone
number: (703) 305-7090; email address: RDFRNotices@epa.gov.
SUPPLEMENTARY INFORMATION:
I. General Information
A. Does this action apply to me?
You may be potentially affected by this action if you are an
agricultural producer, food manufacturer, or pesticide manufacturer.
The following list of North American Industrial Classification System
(NAICS) codes is not intended to be exhaustive, but rather provides a
guide to help readers determine whether this document applies to them.
Potentially affected entities may include:
Crop production (NAICS code 111).
Animal production (NAICS code 112).
Food manufacturing (NAICS code 311).
Pesticide manufacturing (NAICS code 32532).
B. How can I get electronic access to other related information?
You may access a frequently updated electronic version of EPA's
tolerance regulations at 40 CFR part 180 through the Government
Printing Office's e-CFR site at https://www.ecfr.gov/cgi-bin/text-idx?&c=ecfr&tpl=/ecfrbrowse/Title40/40tab_02.tpl.
C. How can I file an objection or hearing request?
Under FFDCA section 408(g), 21 U.S.C. 346a, any person may file an
objection to any aspect of this regulation and may also request a
hearing on those objections. You must file your objection or request a
hearing on this regulation in accordance with the instructions provided
in 40 CFR part 178. To ensure proper receipt by EPA, you must identify
docket ID number EPA-HQ-OPP-2015-0338 and EPA-HQ-OPP-2015-0339 in the
subject line on the first page of your submission. All objections and
requests for a hearing must be in writing, and must be received by the
Hearing Clerk on or before June 6, 2016. Addresses for mail and hand
delivery of objections and hearing requests are provided in 40 CFR
178.25(b).
In addition to filing an objection or hearing request with the
Hearing Clerk as described in 40 CFR part 178, please submit a copy of
the filing (excluding any Confidential Business Information (CBI)) for
inclusion in the public docket. Information not marked confidential
pursuant to 40 CFR part 2 may be disclosed publicly by EPA without
prior notice. Submit the non-CBI copy of your objection or hearing
request, identified by docket ID number EPA-HQ-OPP-2015-0338 and EPA-
HQ-OPP-2015-0339, by one of the following methods:
Federal eRulemaking Portal: https://www.regulations.gov.
Follow the online instructions for submitting comments. Do not submit
electronically any information you consider to be CBI or other
information whose disclosure is restricted by statute.
Mail: OPP Docket, Environmental Protection Agency Docket
Center (EPA/DC), (28221T), 1200 Pennsylvania Ave. NW., Washington, DC
20460-0001.
Hand Delivery: To make special arrangements for hand
delivery or delivery of boxed information, please follow the
instructions at https://www.epa.gov/dockets/contacts.html. Additional
instructions on commenting or visiting the docket, along with more
information about dockets generally, is available at https://www.epa.gov/dockets.
II. Summary of Petitioned-for Tolerance
In the Federal Register of July 17, 2015 (80 FR 42462) (FRL-9929-
13), EPA issued a document pursuant to FFDCA section 408(d)(3), 21
U.S.C. 346a(d)(3), announcing the filing of pesticide petitions (PP
5F8346 and PP 5F8356) by Gowan Company, P.O. Box 5569, Yuma, AZ 85366-
5569. The petitions requested that tolerances currently listed in 40
CFR 180.448 be amended for residues of the insecticide hexythiazox and
its metabolites containing the (4-chlorophenyl)-4-methyl-2-oxo-3-
thiazolidine moiety, in or on citrus, dried pulp at 0.6 parts per
million (ppm); citrus, oil at 26 ppm; fruit, citrus, group 10 at 0.6
ppm; cotton gin byproducts at 15 ppm; and cotton, undelinted seed at
0.5 ppm. That document referenced a summary of the petitions prepared
by Gowan Company, the registrant, which is available in the docket,
https://www.regulations.gov. There were no comments received in response
to the notice of filing.
Based upon review of the data supporting the petition, EPA has
revoked citrus, dried pulp tolerance as it is covered by the
recommended fruit, citrus, group 10-10 tolerance. For citrus oil, EPA
revised the tolerance to 25 ppm and for cotton undelinted seed to 0.4
[[Page 19892]]
ppm. The reasons for these changes are explained in Unit IV.C.
III. Aggregate Risk Assessment and Determination of Safety
Section 408(b)(2)(A)(i) of FFDCA allows EPA to establish a
tolerance (the legal limit for a pesticide chemical residue in or on a
food) only if EPA determines that the tolerance is ``safe.'' Section
408(b)(2)(A)(ii) of FFDCA defines ``safe'' to mean that ``there is a
reasonable certainty that no harm will result from aggregate exposure
to the pesticide chemical residue, including all anticipated dietary
exposures and all other exposures for which there is reliable
information.'' This includes exposure through drinking water and in
residential settings, but does not include occupational exposure.
Section 408(b)(2)(C) of FFDCA requires EPA to give special
consideration to exposure of infants and children to the pesticide
chemical residue in establishing a tolerance and to ``ensure that there
is a reasonable certainty that no harm will result to infants and
children from aggregate exposure to the pesticide chemical residue. . .
.''
Consistent with FFDCA section 408(b)(2)(D), and the factors
specified in FFDCA section 408(b)(2)(D), EPA has reviewed the available
scientific data and other relevant information in support of this
action. EPA has sufficient data to assess the hazards of and to make a
determination on aggregate exposure for hexythiazox including exposure
resulting from the tolerances established by this action. EPA's
assessment of exposures and risks associated with hexythiazox follows.
A. Toxicological Profile
EPA has evaluated the available toxicity data and considered its
validity, completeness, and reliability as well as the relationship of
the results of the studies to human risk. EPA has also considered
available information concerning the variability of the sensitivities
of major identifiable subgroups of consumers, including infants and
children. Hexythiazox has low acute toxicity by oral, dermal and
inhalation routes of exposure. It is not a dermal irritant, is negative
for dermal sensitization and produces only mild eye irritation.
Hexythiazox is associated with toxicity of the liver and adrenals
following subchronic and chronic exposure to dogs, rats and mice, with
the dog being the most sensitive species. The prenatal developmental
studies in rabbits and rats and the two-generation reproduction study
in rats showed no indication of increased susceptibility to in utero or
postnatal exposure to hexythiazox. Reproductive toxicity was not
observed. There is no concern for immunotoxicity or neurotoxicity
following exposure to hexythiazox. The toxicology database for
hexythiazox does not show any evidence of treatment-related effects on
the immune system. Hexythiazox is classified as ``likely to be
carcinogenic to humans;'' however, the weight of evidence indicates
that assessing chronic risk using the chronic population adjusted dose
will be protective for any potential carcinogenic effects. Since the
effects seen in the study that serves as the basis for the chronic PAD
occurred at doses substantially below the lowest dose that induced
tumors, the chronic PAD is considered protective of all chronic effects
including potential carcinogenicity.
Specific information on the studies received and the nature of the
adverse effects caused by hexythiazox as well as the no-observed-
adverse-effect-level (NOAEL) and the lowest-observed-adverse-effect-
level (LOAEL) from the toxicity studies can be found at https://www.regulations.gov in the document: Hexythiazox. Human Health Risk
Assessment to Support Amended Uses on Cotton and Citrus in docket ID
number EPA-HQ-OPP-2015-0338 or EPA-HQ-OPP-2015-0339.
B. Toxicological Points of Departure/Levels of Concern
Once a pesticide's toxicological profile is determined, EPA
identifies toxicological points of departure (POD) and levels of
concern to use in evaluating the risk posed by human exposure to the
pesticide. For hazards that have a threshold below which there is no
appreciable risk, the toxicological POD is used as the basis for
derivation of reference values for risk assessment. PODs are developed
based on a careful analysis of the doses in each toxicological study to
determine the dose at which no adverse effects are observed (the NOAEL)
and the lowest dose at which adverse effects of concern are identified
(the LOAEL). Uncertainty/safety factors are used in conjunction with
the POD to calculate a safe exposure level--generally referred to as a
population-adjusted dose (PAD) or a reference dose (RfD)--and a safe
margin of exposure (MOE). For non-threshold risks, the Agency assumes
that any amount of exposure will lead to some degree of risk. Thus, the
Agency estimates risk in terms of the probability of an occurrence of
the adverse effect expected in a lifetime. For more information on the
general principles EPA uses in risk characterization and a complete
description of the risk assessment process, see https://www.epa.gov/pesticides/factsheets/riskassess.htm. A summary of the toxicological
endpoints for hexythiazox used for human risk assessment is shown in
Table 1 of this unit.
Table 1--Summary of Toxicological Doses and Endpoints for Hexythiazox for Use in Human Health Risk Assessment
----------------------------------------------------------------------------------------------------------------
Point of departure
Exposure/scenario and uncertainty/ RfD, PAD, LOC for Study and toxicological effects
safety factors risk assessment
----------------------------------------------------------------------------------------------------------------
Acute dietary (All populations).. No risk is expected from this exposure scenario as no hazard was identified
in any toxicity study for this duration of exposure.
----------------------------------------------------------------------------------------------------------------
Chronic dietary (All populations) NOAEL = 2.5 mg/kg/ Chronic RfD = 0.025 1-year toxicity feeding study--Dog
day UFA = 10x. mg/kg/day. LOAEL = 12.5 mg/kg/day based on
UFH = 10x........... cPAD = 0.025 mg/kg/ increased absolute and relative
FQPA SF = 1x........ day. adrenal weights and associated
adrenal histopathology.
----------------------------------------------------------------------------------------------------------------
[[Page 19893]]
Incidental oral short-term (1 to NOAEL = 30 mg/kg/day LOC for MOE = 100.. 2-generation reproduction study--
30 days) and intermediate-term UFA = 10x. Rat.
(1 to 6 months). UFH = 10x........... LOAEL = 180 mg/kg/day based on
FQPA SF = 1x........ decreased pup body weight during
lactation and delayed hair growth
and/or eye opening, and decreased
parental body-weight gain and
increased absolute and relative
liver, kidney, and adrenal
weights.
Co-critical
13-Week Oral Toxicity Study--Rat.
NOAEL = 5.5 mg/kg/day
LOAEL = 38 mg/kg/day, based on
increased absolute and relative
liver weights in both sexes,
increased relative ovarian and
kidney weights, and fatty
degeneration of the adrenal zona
fasciculata.
@397.5/257.6 mg/kg/day, decreased
body-weight gain in females,
slight swelling of hepatocytes in
central zone (both sexes),
increased incidence of
glomerulonephrosis in males,
increased adrenal weights.
----------------------------------------------------------------------------------------------------------------
Inhalation short-term (1 to 30 Oral study NOAEL = LOC for MOE = 100.. 2-generation reproduction study--
days) and 30 mg/kg/day Rat.
intermediate-term (1 to 6 months) (inhalation LOAEL = 180 mg/kg/day based on
absorption rate = decreased pup body weight during
100%). lactation and delayed hair growth
UFA = 10x........... and/or eye opening, and decreased
UFH = 10x........... parental body-weight gain and
increased absolute and relative
liver, kidney, and adrenal
weights.
Co-Critical
13-Week Feeding Study--Rat.
LOAEL = 38.1 mg/kg/day, based on
increased absolute and relative
liver weights in both sexes,
increased relative ovarian and
kidney weights, and fatty
degeneration of the adrenal zona
fasciculata.
----------------------------------------------------------------------------------------------------------------
Cancer (Oral, dermal, inhalation) Classification: ``Likely to be Carcinogenic to Humans''. Insufficient
evidence to warrant a quantitative estimation of human risk using a cancer
slope factor based on the common liver tumors (benign and malignant)
observed only in high dose female mice, and benign mammary gland tumors of
no biological significance, observed only in high dose male rats in the
absence of mutagenic concerns. The chronic RfD is protective of all chronic
effects including potential carcinogenicity of hexythiazox.
----------------------------------------------------------------------------------------------------------------
FQPA SF = Food Quality Protection Act Safety Factor. LOAEL = lowest-observed-adverse-effect-level. LOC = level
of concern. mg/kg/day = milligram/kilogram/day. MOE = margin of exposure. NOAEL = no-observed-adverse-effect-
level. PAD = population adjusted dose (a = acute, c = chronic). RfD = reference dose. UF = uncertainty factor.
UFA = extrapolation from animal to human (interspecies). UFH = potential variation in sensitivity among
members of the human population (intraspecies).
C. Exposure Assessment
1. Dietary exposure from food and feed uses. In evaluating dietary
exposure to hexythiazox, EPA considered exposure under the petitioned-
for tolerances as well as all existing hexythiazox tolerances in 40 CFR
180.448. EPA assessed dietary exposures from hexythiazox in food as
follows:
i. Acute exposure. Quantitative acute dietary exposure and risk
assessments are performed for a food-use pesticide, if a toxicological
study has indicated the possibility of an effect of concern occurring
as a result of a 1-day or single exposure. No such effects were
identified in the toxicological studies for hexythiazox; therefore, a
quantitative acute dietary exposure assessment is unnecessary.
ii. Chronic exposure. In conducting the chronic dietary exposure
assessment EPA used the food consumption data from the U.S. Department
of Agriculture's 2003-2008 National Health and Nutrition Examination
Survey, What We Eat in America (NHANES/WWEIA). As to residue levels in
food, EPA used tolerance-level residues, assumed 100 percent crop
treated (PCT), and incorporated DEEM default processing factors when
processing data were not available.
iii. Cancer. Based on the data summarized in Unit III.A., EPA has
concluded that a nonlinear RfD approach is appropriate for assessing
cancer risk to hexythiazox. Cancer risk was assessed using the same
exposure estimates as discussed in Unit III.C.1.ii.
iv. Anticipated residue and percent crop treated (PCT) information.
EPA did not use anticipated residue and/or PCT information in the
dietary assessment for hexythiazox. Tolerance-level residues and/or
100% CT were assumed for all food commodities.
2. Dietary exposure from drinking water. The Agency used screening-
level water exposure models in the dietary exposure analysis and risk
assessment for hexythiazox in drinking water. These simulation models
take into account data on the physical, chemical, and fate/transport
characteristics of hexythiazox. Further information regarding EPA
drinking water models used in pesticide exposure assessment can be
found at https://www.epa.gov/oppefed1/models/water/index.htm.
Based on the Surface Water Concentration Calculator, the estimated
drinking water concentrations (EDWCs) of hexythiazox for chronic
exposures for non-cancer assessments are estimated to be 4.3 parts per
billion (ppb) for surface water. Since groundwater residues are not
expected to exceed surface water residues, surface water residues were
used in the dietary risk assessment. Modeled estimates of drinking
water
[[Page 19894]]
concentrations were directly entered into the dietary exposure model.
3. From non-dietary exposure. The term ``residential exposure'' is
used in this document to refer to non-occupational, non-dietary
exposure (e.g., for lawn and garden pest control, indoor pest control,
termiticides, and flea and tick control on pets).
Hexythiazox is currently registered for the following uses that
could result in residential exposures: Ornamental plantings, lawns,
recreational sites such as campgrounds and golf courses, turf, and
fruit and nut trees in residential settings. EPA assessed residential
exposure using the following assumptions:
Residential handler exposures are expected to be short-term (1 to
30 days) via either the dermal or inhalation routes of exposures.
Intermediate-term exposures are not likely because of the intermittent
nature of applications by residential applicators. Since hexythiazox
does not pose a significant dermal risk, a quantitative dermal risk
assessment was not performed and handler margins of exposure (MOE) were
calculated for the inhalation route of exposure only.
Both adults and children may be exposed to hexythiazox residues
from contact with treated lawns or treated residential plants. Post-
application exposures are expected to be short-term (1 to 30 days) in
duration for most exposure scenarios, and intermediate-term (1 to 6
months) in duration for soil ingestion only due to the aerobic soil
metabolism half-life for hexythiazox. Adult post-application exposures
were not assessed since no quantitative dermal risk assessment is
needed for hexythiazox and inhalation exposures are typically
negligible in outdoor settings. The exposure assessment for children
included incidental oral exposure resulting from transfer of residues
from the hands or objects to the mouth, and from incidental ingestion
of soil.
Further information regarding EPA standard assumptions and generic
inputs for residential exposures may be found at https://www.epa.gov/pesticides/trac/science/trac6a05.pdf.
4. Cumulative effects from substances with a common mechanism of
toxicity. Section 408(b)(2)(D)(v) of FFDCA requires that, when
considering whether to establish, modify, or revoke a tolerance, the
Agency consider ``available information'' concerning the cumulative
effects of a particular pesticide's residues and ``other substances
that have a common mechanism of toxicity.'' EPA has not found
hexythiazox to share a common mechanism of toxicity with any other
substances, and hexythiazox does not appear to produce a toxic
metabolite. For the purposes of this tolerance action, therefore, EPA
has assumed that hexythiazox does not have a common mechanism of
toxicity with other substances. For information regarding EPA's efforts
to determine which chemicals have a common mechanism of toxicity and to
evaluate the cumulative effects of such chemicals, see EPA's Web site
at https://www.epa.gov/pesticides/cumulative.
D. Safety Factor for Infants and Children
1. In general. Section 408(b)(2)(C) of FFDCA provides that EPA
shall apply an additional tenfold (10X) margin of safety for infants
and children in the case of threshold effects to account for prenatal
and postnatal toxicity and the completeness of the database on toxicity
and exposure unless EPA determines based on reliable data that a
different margin of safety will be safe for infants and children. This
additional margin of safety is commonly referred to as the FQPA Safety
Factor (SF). In applying this provision, EPA either retains the default
value of 10X, or uses a different additional safety factor when
reliable data available to EPA support the choice of a different
factor.
2. Prenatal and postnatal sensitivity. The prenatal development
studies in rabbits and rats and the two-generation reproduction study
in rats showed no indication of increased susceptibility to in utero
and/or postnatal exposure to hexythiazox.
3. Conclusion. EPA has determined that reliable data show the
safety of infants and children would be adequately protected if the
FQPA SF were reduced to 1X. That decision is based on the following
findings:
i. The toxicity database for hexythiazox is complete.
ii. There is no indication that hexythiazox is a neurotoxic
chemical and there is no need for a developmental neurotoxicity study
or additional UFs to account for neurotoxicity.
iii. There is no evidence that hexythiazox results in increased
susceptibility in in utero rats or rabbits in the prenatal
developmental studies or in young rats in the 2-generation reproduction
study.
iv. There are no residual uncertainties identified in the exposure
databases. EPA made conservative (protective) assumptions in the ground
and surface water modeling used to assess exposure to hexythiazox in
drinking water. EPA used similarly conservative assumptions to assess
post-application exposure of children as well as incidental oral
exposure of toddlers. These assessments will not underestimate the
exposure and risks posed by hexythiazox.
E. Aggregate Risks and Determination of Safety
EPA determines whether acute and chronic dietary pesticide
exposures are safe by comparing aggregate exposure estimates to the
acute PAD (aPAD) and chronic PAD (cPAD). For linear cancer risks, EPA
calculates the lifetime probability of acquiring cancer given the
estimated aggregate exposure. Short-, intermediate- and chronic-term
risks are evaluated by comparing the estimated aggregate food, water,
and residential exposure to the appropriate PODs to ensure that an
adequate MOE exists.
1. Acute risk. An acute aggregate risk assessment takes into
account acute exposure estimates from dietary consumption of food and
drinking water. No adverse effect, resulting from a single oral
exposure, was identified and no acute dietary endpoint was selected.
Therefore, hexythiazox is not expected to pose an acute risk.
2. Chronic risk. Using the exposure assumptions described in this
unit for chronic exposure, EPA has concluded that chronic exposure to
hexythiazox from food and water will utilize 81% of the cPAD for
children 1 to 2 years of age, the population group receiving the
greatest exposure. Based on the explanation in Unit III.C.3., regarding
residential use patterns, chronic residential exposure to residues of
hexythiazox is not expected.
3. Short-term risk. Short-term aggregate exposure takes into
account short-term residential exposure plus chronic exposure to food
and water (considered to be a background exposure level).
Hexythiazox is currently registered for uses that could result in
short-term residential exposure, and the Agency has determined that it
is appropriate to aggregate chronic exposure through food and water
with short-term residential exposures to hexythiazox.
Using the exposure assumptions described in this unit for short-
term exposures, EPA has concluded the combined short-term food, water,
and residential exposures result in aggregate MOEs of 1,300 for
children and 9,900 for adults. Because EPA's level of concern for
hexythiazox is a MOE of 100 or below, these MOEs are not of concern.
4. Intermediate-term risk. Intermediate-term aggregate exposure
takes into account intermediate-term residential exposure plus chronic
[[Page 19895]]
exposure to food and water (considered to be a background exposure
level).
Hexythiazox is currently registered for uses that could result in
intermediate-term residential exposure, and the Agency has determined
that it is appropriate to aggregate chronic exposure through food and
water with intermediate-term residential exposures to hexythiazox.
Using the exposure assumptions described in this unit for
intermediate-term exposures, EPA has concluded that the combined
intermediate-term food, water, and residential exposures result in
aggregate MOEs of 1,500 for children and 9,900 for adults. Because
EPA's level of concern for hexythiazox is a MOE of 100 or below, these
MOEs are not of concern.
5. Aggregate cancer risk for U.S. population. As discussed in Unit
III.C.1.iii., EPA concluded that regulation based on the chronic
reference dose will be protective for both chronic and carcinogenic
risks. As noted in this unit, there are no chronic risks of concern.
6. Determination of safety. Based on these risk assessments, EPA
concludes that there is a reasonable certainty that no harm will result
to the general population, or to infants and children from aggregate
exposure to hexythiazox residues.
IV. Other Considerations
A. Analytical Enforcement Methodology
Adequate enforcement methodology (high performance liquid
chromatography method with ultraviolet detection (HPLC/UV)) is
available to enforce the tolerance expression. This method is listed in
the U.S. EPA Index of Residue Analytical methods under hexythiazox as
method AMR-985-87.
B. International Residue Limits
In making its tolerance decisions, EPA seeks to harmonize U.S.
tolerances with international standards whenever possible, consistent
with U.S. food safety standards and agricultural practices. EPA
considers the international maximum residue limits (MRLs) established
by the Codex Alimentarius Commission (Codex), as required by FFDCA
section 408(b)(4). The Codex Alimentarius is a joint United Nations
Food and Agriculture Organization/World Health Organization food
standards program, and it is recognized as an international food safety
standards-setting organization in trade agreements to which the United
States is a party. EPA may establish a tolerance that is different from
a Codex MRL; however, FFDCA section 408(b)(4) requires that EPA explain
the reasons for departing from the Codex level.
The Codex has established MRLs for residues of hexythiazox on
citrus, fruits but not for cotton. The Codex plant residue definition
is for hexythiazox as opposed to the U.S. definition which includes
hexythiazox plus metabolites containing the (4-chlorophenyl)-4-methyl-
2-oxo-3-thiazolidine moiety. The differences in U.S. and Codex residue
definitions prohibits harmonization.
C. Revisions to Petitioned-for Tolerances
Although the petitioner requested an amended tolerance for citrus,
dried pulp at 0.6, the Agency has determined that no such tolerance is
necessary because that commodity is covered by the established citrus
group 10-10 tolerance. The Agency is revising the tolerance for citrus
oil to 25 ppm based on the following: By multiplying the citrus oil
processing factor (104X) from the 2006 processing study (D334889, 07/
03/2006, T. Bloem) by the highest average field trial (HAFT) residue
for lemons (0.243 ppm) from the submitted citrus study since lemons are
the citrus crop that produced the highest residues.
As noted in its most recent crop group rulemaking in the Federal
Register of August 22, 2012 (77 FR 50617) (FRL-9354-3), EPA generally
does not establish new tolerances under pre-existing crop groups that
have been updated. EPA updated crop group 10 in 2010, making the new
group 10-10. Therefore, EPA is establishing citrus fruit group
tolerances for group 10-10, rather than crop group 10 as requested.
The Agency is amending the tolerance for cotton, undelinted seed at
0.4 ppm based on the available cotton data that reflect a national use
at the label specified 35 day pre-harvest internal (PHI) to calculate
the 0.4 ppm tolerance.
V. Conclusion
Therefore, tolerances are amended for residues of hexythiazox and
its metabolites containing the (4-chlorophenyl)-4-methyl-2-oxo-3-
thiazolidine moiety, in or on citrus, oil at 25 ppm; fruit, citrus,
group 10-10 at 0.6 ppm; cotton, gin byproducts at 15 ppm; cotton,
undelinted seed at 0.4 ppm. The current citrus, dried pulp tolerance is
revoked because it is unnecessary due to the establishment of the
fruit, citrus, group 10-10 tolerance.
VI. Statutory and Executive Order Reviews
This action amends tolerances under FFDCA section 408(d) in
response to a petition submitted to the Agency. The Office of
Management and Budget (OMB) has exempted these types of actions from
review under Executive Order 12866, entitled ``Regulatory Planning and
Review'' (58 FR 51735, October 4, 1993). Because this action has been
exempted from review under Executive Order 12866, this action is not
subject to Executive Order 13211, entitled ``Actions Concerning
Regulations That Significantly Affect Energy Supply, Distribution, or
Use'' (66 FR 28355, May 22, 2001) or Executive Order 13045, entitled
``Protection of Children from Environmental Health Risks and Safety
Risks'' (62 FR 19885, April 23, 1997). This action does not contain any
information collections subject to OMB approval under the Paperwork
Reduction Act (PRA) (44 U.S.C. 3501 et seq.), nor does it require any
special considerations under Executive Order 12898, entitled ``Federal
Actions to Address Environmental Justice in Minority Populations and
Low-Income Populations'' (59 FR 7629, February 16, 1994).
Since tolerances and exemptions that are established on the basis
of a petition under FFDCA section 408(d), such as the tolerance in this
final rule, do not require the issuance of a proposed rule, the
requirements of the Regulatory Flexibility Act (RFA) (5 U.S.C. 601 et
seq.), do not apply.
This action directly regulates growers, food processors, food
handlers, and food retailers, not States or tribes, nor does this
action alter the relationships or distribution of power and
responsibilities established by Congress in the preemption provisions
of FFDCA section 408(n)(4). As such, the Agency has determined that
this action will not have a substantial direct effect on States or
tribal governments, on the relationship between the national government
and the States or tribal governments, or on the distribution of power
and responsibilities among the various levels of government or between
the Federal Government and Indian tribes. Thus, the Agency has
determined that Executive Order 13132, entitled ``Federalism'' (64 FR
43255, August 10, 1999) and Executive Order 13175, entitled
``Consultation and Coordination with Indian Tribal Governments'' (65 FR
67249, November 9, 2000) do not apply to this action. In addition, this
action does not impose any enforceable duty or contain any unfunded
mandate as described under Title II of the Unfunded Mandates Reform Act
(UMRA) (2 U.S.C. 1501 et seq.).
This action does not involve any technical standards that would
require Agency consideration of voluntary
[[Page 19896]]
consensus standards pursuant to section 12(d) of the National
Technology Transfer and Advancement Act (NTTAA) (15 U.S.C. 272 note).
VII. Congressional Review Act
Pursuant to the Congressional Review Act (5 U.S.C. 801 et seq.),
EPA will submit a report containing this rule and other required
information to the U.S. Senate, the U.S. House of Representatives, and
the Comptroller General of the United States prior to publication of
the rule in the Federal Register. This action is not a ``major rule''
as defined by 5 U.S.C. 804(2).
List of Subjects in 40 CFR Part 180
Environmental protection, Administrative practice and procedure,
Agricultural commodities, Pesticides and pests, Reporting and
recordkeeping requirements.
Dated: March 22, 2016.
Susan Lewis,
Director, Registration Division, Office of Pesticide Programs.
Therefore, 40 CFR chapter I is amended as follows:
PART 180--[AMENDED]
0
1. The authority citation for part 180 continues to read as follows:
Authority: 21 U.S.C. 321(q), 346a and 371.
0
2. In Sec. 180.448:
0
i. Add alphabetically the entries for ``Cotton, gin byproducts'' and
``Cotton, undelinted seed'' to the table in paragraph (a).
0
ii. Remove the entry for ``Citrus, dried pulp'' from the table in
paragraph (a).
0
iii. Revise the entry for ``Citrus, oil'' in the table in paragraph
(a).
0
iv. Remove the entries for ``Cotton, gin byproducts, CA and AZ only'',
and ``Cotton, undelinted seed, CA and AZ only'' from the table in
paragraph (c).
0
v. Revise the entry for ``Fruit, citrus group 10 (CA, AZ, TX only)'' in
the table in paragraph (c).
The additions and revisions read as follows:
Sec. 180.448 Hexythiazox; tolerances for residues.
(a) General. * * *
------------------------------------------------------------------------
Parts per
Commodity million
------------------------------------------------------------------------
* * * * *
Citrus, oil................................................. 25
* * * * *
Cotton, gin byproducts...................................... 15
Cotton, undelinted seed..................................... 0.4
* * * * *
------------------------------------------------------------------------
(c) Tolerances with regional registrations. * * *
------------------------------------------------------------------------
Parts per
Commodity million
------------------------------------------------------------------------
* * * * *
Fruit, citrus group 10-10 (CA, AZ, TX only)................. 0.6
* * * * *
------------------------------------------------------------------------
* * * * *
[FR Doc. 2016-07661 Filed 4-5-16; 8:45 am]
BILLING CODE 6560-50-P