Performance Specification 18-Specifications and Test Procedures for Gaseous HCl Continuous Emission Monitoring Systems at Stationary Sources, 27689-27716 [2014-10824]

Agencies

[Federal Register Volume 79, Number 93 (Wednesday, May 14, 2014)]
[Proposed Rules]
[Pages 27689-27716]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: 2014-10824]



[[Page 27689]]

Vol. 79

Wednesday,

No. 93

May 14, 2014

Part II





Environmental Protection Agency





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40 CFR Part 60





Performance Specification 18--Specifications and Test Procedures for 
Gaseous HCl Continuous Emission Monitoring Systems at Stationary 
Sources; Proposed Rule

Federal Register / Vol. 79 , No. 93 / Wednesday, May 14, 2014 / 
Proposed Rules

[[Page 27690]]


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ENVIRONMENTAL PROTECTION AGENCY

40 CFR Part 60

[EPA-HQ-OAR-2013-0696; FRL-9909-79-OAR]
RIN 2060-5689


Performance Specification 18--Specifications and Test Procedures 
for Gaseous HCl Continuous Emission Monitoring Systems at Stationary 
Sources

AGENCY: Environmental Protection Agency (EPA).

ACTION: Proposed rule.

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SUMMARY: The Environmental Protection Agency (EPA) is proposing 
performance specifications and test procedures for hydrogen chloride 
continuous emission monitoring systems to provide sources and 
regulatory agencies with criteria and test procedures for evaluating 
the acceptability of hydrogen chloride continuous emission monitoring 
systems. The proposed specification (Performance Specification 18) 
includes requirements for initial acceptance including instrument 
accuracy and stability assessments. This action also proposes quality 
assurance procedures for hydrogen chloride continuous emission 
monitoring systems used for compliance determination at stationary 
sources. The quality assurance procedures (Procedure 6) specify the 
minimum quality assurance requirements necessary for the control and 
assessment of the quality of continuous emission monitoring systems 
data submitted to the EPA.
    This action would establish consistent requirements for ensuring 
and assessing the quality of data measured by hydrogen chloride 
continuous emission monitoring systems. The affected systems are those 
used for determining compliance with emission standards for hydrogen 
chloride on a continuous basis as specified in an applicable permit or 
regulation. The affected industries and their North American Industry 
Classification System codes are listed in the SUPPLEMENTARY INFORMATION 
section of this preamble.

DATES: Comments. Comments must be received on or before June 13, 2014.
    Public Hearing. The EPA will hold a public hearing on this rule if 
requested. Requests for a hearing must be made by May 27, 2014. 
Requests for a hearing should be made to Ms. Candace Sorrell via email 
at sorrell.candace@epa.gov or by phone at (919) 541-1064. If a hearing 
is requested, it will be held on May 28, 2014 at the EPA facility in 
Research Triangle Park, NC.

ADDRESSES: Comments. Submit your comments, identified by Docket ID No. 
EPA-HQ-OAR-2013-0696, by one of the following methods:
     https://www.regulations.gov: Follow the online instructions 
for submitting comments.
     Email: a-and-r-docket@epa.gov, Attention Docket ID Number 
EPA-HQ-OAR-2013-0696.
     Fax: (202) 566-9744, Attention Docket ID No. EPA-HQ-OAR-
2013-0696.
     Mail: U.S. Postal Service, send comments to: EPA Docket 
Center, William J. Clinton (WJC) West Building, Attention Docket ID 
Number EPA-HQ-OAR-2013-0696, U.S. Environmental Protection Agency, Mail 
code: 28221T, 1200 Pennsylvania Ave. NW., Washington, DC 20460. Please 
include a total of two copies.
     Hand Delivery: U.S. Environmental Protection Agency, WJC 
West Building (Air Docket), Room 3334, 1301 Constitution Ave. NW., 
Washington, DC, 20004, Attention Docket ID Number EPA-HQ-OAR-2013-0696. 
Such deliveries are only accepted during the Docket's normal hours of 
operation, and special arrangements should be made for deliveries of 
boxed information.
    Instructions. Direct your comments to Docket ID Number EPA-HQ-OAR-
2013-0696. The EPA's policy is that all comments received will be 
included in the public docket without change and may be made available 
online at https://www.regulations.gov, including any personal 
information provided, unless the comment includes information claimed 
to be Confidential Business Information (CBI) or other information 
whose disclosure is restricted by statute. Do not submit information 
that you consider to be CBI or otherwise protected through https://www.regulations.gov or email. The https://www.regulations.gov Web site 
is an ``anonymous access'' system, which means the EPA will not know 
your identity or contact information unless you provide it in the body 
of your comment. If you send an email comment directly to the EPA 
without going through https://www.regulations.gov, your email address 
will be automatically captured and included as part of the comment that 
is placed in the public docket and made available on the Internet. If 
you submit an electronic comment, the EPA recommends that you include 
your name and other contact information in the body of your comment and 
with any disk or CD-ROM you submit. If the EPA cannot read your comment 
due to technical difficulties and cannot contact you for clarification, 
the EPA may not be able to consider your comment. Electronic files 
should not include special characters or any form of encryption and be 
free of any defects or viruses. For additional information about the 
EPA's public docket, visit the EPA Docket Center homepage at: https://www.epa.gov/epahome/dockets.
    Docket: The EPA has established a docket for this rulemaking under 
Docket ID Number EPA-HQ-OAR-2013-0696. All documents in the docket are 
listed in the regulations.gov index. Although listed in the index, some 
information is not publicly available, e.g., CBI or other information 
whose disclosure is restricted by statute. Certain other material, such 
as copyrighted material, is not placed on the Internet and will be 
publicly available only in hard copy. Publicly available docket 
materials are available either electronically in regulations.gov or in 
hard copy at the EPA Docket Center, WJC West Building, Room 3334, 1301 
Constitution Ave. NW., Washington, DC 20004. The Public Reading Room is 
open from 8:30 a.m. to 4:30 p.m., Monday through Friday, excluding 
legal holidays. The telephone number for the Public Reading Room is 
(202) 566-1744, and the telephone number for the EPA Docket Center is 
(202) 566-1742.

FOR FURTHER INFORMATION CONTACT: For questions about this proposed 
action, contact Ms. Candace Sorrell, Office of Air Quality Planning and 
Standards, Air Quality Assessment Division (AQAD), Measurement 
Technology Group, U.S. Environmental Protection Agency, Research 
Triangle Park, North Carolina 27709; telephone number: (919) 541-1064; 
fax number: (919) 541-0516; email address: sorrell.candace@epa.gov.

SUPPLEMENTARY INFORMATION: Organization of this Document. The 
information in this preamble is organized as follows:

I. General Information
    A. Does this action apply to me?
    B. Where can I get a copy of this document and other related 
information?
    C. What should I consider as I prepare my comments for the EPA?
II. Background
III. Summary of Proposed Performance Specification 18
    A. What is the purpose of PS-18?
    B. Who must comply with PS-18?
    C. When must I comply with PS-18?
    D. What are the basic requirements of PS-18?
    E. What are the reporting and recordkeeping requirements for PS-
18?
IV. Summary of Proposed Procedure 6
    A. What is the purpose of Procedure 6?
    B. Who must comply with Procedure 6?
    C. When must I comply with Procedure 6?
    D. What are the basic requirements of Procedure 6?

[[Page 27691]]

    E. What are the reporting and recordkeeping requirements for 
Procedure 6?
V. Rationale for Selecting the Proposed Requirements of Performance 
Specification 18 and Procedure 6
    A. What information did we use to develop PS-18 and Procedure 6?
    B. How did we select the requirements for PS-18 and Procedure 6?
    C. Solicitation for Comment
VI. Statutory and Executive Order Reviews
    A. Executive Order 12866: Regulatory Planning and Review and 
Executive Order 13563: Improving Regulation and Regulatory Review
    B. Paperwork Reduction Act
    C. Regulatory Flexibility Act
    D. Unfunded Mandates Reform Act
    E. Executive Order 13132: Federalism
    F. Executive Order 13175: Consultation and Coordination With 
Indian Tribal Governments
    G. Executive Order 13045: Protection of Children From 
Environmental Health Risks and Safety Risks
    H. Executive Order 13211: Actions Concerning Regulations That 
Significantly Affect Energy Supply, Distribution, or Use
    I. National Technology Transfer and Advancement Act
    J. Executive Order 12898: Federal Actions To Address 
Environmental Justice in Minority Populations and Low-Income 
Populations

I. General Information

A. Does this action apply to me?

    The major entities that would potentially be affected by the 
proposed performance specification 18 (PS-18) and the quality assurance 
(QA) requirements of Procedure 6 for gaseous hydrogen chloride (HCl) 
continuous emission monitoring systems (CEMS) are those entities that 
are required to install a new CEMS, relocate an existing CEMS, or 
replace an existing CEMS under any applicable subpart of 40 CFR parts 
60, 61 or 63. Table 1 of this preamble lists the current federal rules 
by subpart and the corresponding source categories to which the 
proposed PS-18 and Procedure 6 potentially would apply.

 Table 1--Source Categories That Would Be Subject to PS-18 and Procedure
                                    6
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            Subpart(s)                         Source category
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                             40 CFR part 60
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Subpart F.........................  Portland Cement Plants.
Subpart Da........................  Fossil Fuel-Fired Electric Utility,
                                     Industrial-Commercial-
                                     Institutional, and Small Industrial-
                                     Commercial-Institutional Steam
                                     Generating Units.
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                             40 CFR part 63
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Subpart LLL.......................  Portland Cement Manufacturing
                                     Industry.
Subpart UUUUU.....................  Coal- and Oil-fired Electric Utility
                                     Steam Generating Units.
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    The requirements of the proposed PS-18 and Procedure 6 may also 
apply to stationary sources located in a state, district, reservation 
or territory that adopts PS-18 or Procedure 6 in its implementation 
plan.
    Should PS-18 and Procedure 6 ultimately be finalized, we plan to 
amend 40 CFR part 63 subpart UUUUU, National Emission Standards for 
Hazardous Air Pollutants: Coal- and Oil-fired Electric Utility Steam 
Generating Units to offer PS-18 and Procedure 6 as an alternative to 
PS-15 for continuous monitoring of HCl. Note, however, that the 
alternative test method approval process of 63.7(f) is already 
available, even without any regulatory amendment, as a way for affected 
facilities to request approval to use PS-18/Procedure 6 in lieu of PS-
15.
    With regard to 40 CFR part 63, Subpart LLL which affects Portland 
cement manufacturing facilities and includes HCl monitoring 
requirements, should PS-18 and Procedure 6 be finalized, no amendments 
will be needed as Subpart LLL already allows for use of any promulgated 
performance specification for HCl CEMS in 40 CFR part 60, Appendix B.
    Table 2 lists the corresponding North American Industry 
Classification System (NAICS) codes for the source categories listed in 
Table 1 of this preamble.

            Table 2--NAICS for Potentially Regulated Entities
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                       Industry                           NAICS Codes
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Fossil Fuel-Fired Electric Utility Steam Generating               327310
 Units...............................................         \a\ 921150
Portland Cement Manufacturing Plants.................             327310
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\a\ Industry in Indian Country.

    Tables 1 and 2 are not intended to be exhaustive, but rather they 
provide a guide for readers regarding entities potentially affected by 
this action. If you have any questions regarding the potential 
applicability of the proposed PS-18 and test procedures (Procedure 6) 
to a particular entity, consult the person listed in the FOR FURTHER 
INFORMATION CONTACT section.

B. Where can I get a copy of this document and other related 
information?

    In addition to being available in the docket, an electronic copy of 
this action is available on the Internet through the EPA's Technology 
Transfer Network (TTN) Web site, a forum for information and technology 
exchange in various areas of air pollution control. Following signature 
by the EPA Administrator, the EPA will post a copy of this proposed 
action on the TTN's policy and guidance page for newly proposed or 
promulgated rules at: https://www.epa.gov/ttn/oarpg/t3pfpr.html. 
Following publication in the Federal Register, the EPA will post the 
signed proposal and key technical documents

[[Page 27692]]

on the project Web site: https://www.epa.gov/ttn/emc/proposed.html.

C. What should I consider as I prepare my comments for the EPA?

1. Submitting CBI
    Do not submit information containing CBI to the EPA through https://www.regulations.gov or email. Clearly mark the part or all of the 
information that you claim to be CBI. For CBI information on a disk or 
CD-ROM that you will mail to the EPA, mark the outside of the disk or 
CD-ROM as CBI and then identify electronically within the disk or CD-
ROM the specific information that is claimed as CBI. In addition to one 
complete version of the comments that includes information claimed as 
CBI, you must submit a copy of the comments that does not contain the 
information claimed as CBI for inclusion in the public docket. If you 
submit a CD-ROM or disk that does not contain CBI, mark the outside of 
the disk or CD-ROM clearly that it does not contain CBI. Information 
not marked as CBI will be included in the public docket and the EPA's 
electronic public docket without prior notice. Information marked as 
CBI will not be disclosed except in accordance with procedures set 
forth in 40 Code of Federal Regulations (CFR) part 2. Send or deliver 
information identified as CBI only to the following address: Roberto 
Morales, OAQPS Document Control Officer (C404-02), OAQPS, U.S. 
Environmental Protection Agency, Research Triangle Park, North Carolina 
27711, Attention Docket ID Number EPA-HQ-OAR-2013-0696.
2. Tips for Preparing Your Comments
    When submitting comments, remember to:
     Identify the rulemaking by docket number and other 
identifying information (subject heading, Federal Register date and 
page number).
     Follow directions. Respond to specific questions and 
organize comments by a section number.
     Explain why you agree or disagree; suggest alternatives 
and substitute language for your requested changes.
     Describe any assumptions and provide any technical 
information and/or data that you used.
     If you estimate potential costs or burdens, explain how 
you arrived at your estimate in sufficient detail to allow for it to be 
reproduced.
     Provide specific examples to illustrate your concerns and 
suggest alternatives.
     Explain your views as clearly as possible, avoiding the 
use of profanity or personal threats or character assassination.
     Make sure to submit your comments by the comment period 
deadline.

II. Background

    The EPA recently promulgated the Portland Cement Maximum Achievable 
Control Technology (MACT) rule (75 FR 54970, September 9, 2010; 78 FR 
10006, February 12, 2013) and the Mercury and Air Toxics Standards 
(MATS) rule (77 FR 9303, February 16, 2012; 78 FR 24075, April 24, 
2013). Both rules specify the use of extractive Fourier Transform 
Infrared Spectroscopy (FTIR) and PS-15 when affected facilities opt or 
are required to continuously measure HCl emissions. To facilitate use 
of alternative technologies to FTIR and aid in measuring the low levels 
of HCl specified in those rules the EPA has developed and is proposing 
these new specifications and quality control (QC) procedures (PS-18 and 
Procedure 6) for HCl CEMS as an alternative to the use of PS-15.
    Multiple technologies are available for HCl emissions monitoring. 
The goals of the proposed PS-18 and Procedure 6 are (1) to allow for 
the use of different HCl CEMS sampling and analytical technologies as 
long as the required performance criteria set out in the performance 
specification (PS) are met; and (2) to establish consistent 
requirements for ensuring and assessing the quality of data measured by 
HCl CEMS.

III. Summary of Proposed Performance Specification 18

A. What is the purpose of PS-18?

    Proposed PS-18 establishes the criteria to evaluate acceptable 
performance of HCl CEMS at the time of installation or soon after and 
when regulations require reevaluation of HCl CEMS performance.

B. Who must comply with PS-18?

    You may comply with PS-18 as an alternative to other HCl CEMS 
performance specifications (e.g., PS-15) allowed under an applicable 
subpart if you use CEMS to monitor HCl emissions from controlled and 
uncontrolled emission sources subject to HCl CEMS requirements under a 
part 60, 61 or 63 regulation.

C. When must I comply with PS-18?

    If you are the owner or operator of existing facilities required to 
install HCl CEMS in compliance with an associated rule, regulation or 
permit, you must comply with PS-18 if you choose and have these 
specifications approved as an alternative to other PS required under an 
applicable subpart [e.g., PS-15]. Equipment and supplies for HCl CEMS 
will vary depending on the measurement technology and equipment 
vendors. If you are the owner or operator of affected HCl CEMS at new 
stationary sources, you must comply with either the HCl CEMS PS [e.g., 
PS-15] required by the associated rule or permit or PS-18 as an 
approved alternative when you install and place into operation the 
affected HCl CEMS.

D. What are the basic requirements of PS-18?

    The proposed PS-18 would require owners and operators subject to 
HCl CEMS requirements to: (1) Select an HCl CEMS that satisfies basic 
equipment control criteria; (2) install your HCl CEMS according to the 
manufacturer's specifications and the requirements set out in PS-18; 
(3) verify that the instrument is functioning properly; (4) calibrate 
and standardize your equipment; and (5) perform PS-18 procedures that 
demonstrate initial performance requirements for the HCl CEMS. A 
summary of the basic requirements is presented below.
1. HCl CEMS Equipment Selection
    As noted in section III.C, PS-18 equipment and supplies for HCl 
CEMS can and will vary depending on the measurement technology and 
equipment vendors you select. The proposed PS-18 describes the typical 
key equipment and supply components found in one or more types of HCl 
CEMS. Extractive HCl CEMS typically include a sample extraction system, 
sample conditioning module, HCl analyzer, diluent analyzer, system 
controller, data recorder, reference gas system and moisture 
measurement system. Hydrogen chloride integrated path-CEMS (HCl IP-
CEMS) typically include source temperature and pressure monitors and an 
optical transmitter and receiver with or without optics to generate 
longer measurement paths in the emission stream.
    The proposed PS-18 defines the differing HCl CEMS equipment 
components and specifies design/operation basic criteria for the 
differing equipment components. For example, (1) for reference gas 
systems, PS-18 specifies that, for extractive CEMS, the system must be 
designed to be able to introduce reference gas flow sufficient to flood 
the sampling probe and prevent entry of gas from the effluent stream; 
and (2) for sample conditioning that, you must operate the module in 
such a way as to keep the particle-free gas sample above the modules, 
PS-18

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specifies dew point temperature of its components. For HCl IP-CEMS, you 
must operate and qualify equipment to measure source gas temperature 
and pressure.
2. CEMS Measurement Location Specifications and Pretest Preparation
    After you have selected the appropriate HCl CEMS for your 
operations, the proposed PS-18 requires that you install the system 
according to the manufacturer's specifications and as specified under 
section 8.0 of PS-18. The proposed PS-18 requires that you install the 
CEMS at an accessible location where the pollutant concentration or 
emission rate measurements are directly representative of the HCl 
emissions or can be corrected to be representative of the emissions 
from the affected facility.
    With regards to HCl CEMS emissions measurement location, the 
proposed PS-18 specifies that it should be (1) at least two equivalent 
diameters downstream of the nearest control device, point of pollution 
generation or other point at which a change of pollutant concentration 
may occur; and (2) at least half an equivalent diameter (calculated 
according to Method 1 in Appendix A-1 to part 60) upstream from the 
effluent exhaust. We are soliciting comment on alternative measurement 
location requirements in this preamble (see section V.C of this 
preamble).
3. HCl CEMS Measurement Range
    After installation, the proposed PS-18 recommends that you check, 
record and document the continuous emissions measurement range of the 
HCl CEMS to verify that the instrument is functioning correctly. 
Performance Specification 18 requires that the data collection device 
output range include zero and the upper limit of the measurement range.
4. HCl CEMS Performance Requirements and Procedures
    After you have installed, set up, verified, and calibrated your HCl 
CEMS, the proposed PS-18 requires that you follow specified performance 
tests and procedures for the initial demonstration of your HCl CEMS and 
subsequent performance evaluations of your HCl CEMS. In general, the 
proposed PS-18 requires that: (1) Technology used to measure gaseous 
HCl provides a distinct response (DR) and addresses any appropriate 
interference correction(s); (2) the relative accuracy (RA) be 
established against a reference method (RM); and (3) dynamic spiking 
(DS) into the CEMS using a National Institute of Standards and 
Technology (NIST) traceable standard may be required to demonstrate 
initial performance at sources with emissions near the detection level 
of the CEMS and for ongoing QA tests. Specific proposed PS-18 test 
procedures are outlined below.
     Interference Test. You must test to detect analyzer 
responses to interferences not adequately accounted for in the 
calibration procedure that may cause measurement bias. The combined 
interference response for the analyzer used for the test must not be 
greater than  3.0 percent of the equivalent HCl 
concentration used for the interference test.
     Beam Intensity Test for Integrated Patch CEMS (IP-CEMS). 
For IP-CEMS, you must establish the light attenuation tolerance of your 
system and demonstrate that the HCl response is independent of the beam 
intensity. The percent difference during the attenuated light 
calibration check must not be more than  3.0 percent of the 
measured concentration with no attenuation used for the test.
     Temperature Measurement Verification Procedure for IP-
CEMS. You must perform a temperature verification test as part of 
initial installation and verification procedures for an IP-CEMS. 
Temperature measurement must agree with a NIST traceable calibrated 
temperature measuring device within 2.8 [deg]C (5.0 [deg]F).
     Pressure Measurement Verification Test for IP-CEMS. You 
must conduct a pressure measurement verification test if you have an 
IP-CEMS. Your pressure monitor must agree with a NIST traceable 
calibrated measurement device within  5 percent or <= 0.12 
kilopascals (0.5 inches of water column), whichever is greater. For 
stack pressure verification, you should select a gauge or monitor that 
conforms to the design requirements of American Society of Mechanical 
Engineers (ASME) standard B40.100-2010, ``Pressure Gauges and Gauge 
Attachments'' (incorporated by reference, see Sec.  60.17).
     Level of Detection (LOD) Determination. You must determine 
the minimum amount of HCl that can be detected above the background in 
an HCl-free representative gas matrix (the LOD). If you choose to 
perform the LOD determination test in a controlled environment, you 
must verify the LOD during the initial field certification test using 
the DS test procedure (included in Appendix A of the PS). You must make 
three independent DS measurements at no more than five times the LOD 
for the detection level verification. If you cannot detect the DS HCl 
at the estimated LOD, you must increase the spike concentration 
incrementally until you establish a field verified detection level 
where the HCl measurement is a minimum of three times the noise for 
zero HCL concentration. The field verified detection level would 
replace the controlled environment LOD and would become the site- or 
installation-specific LOD.
     Response Time (RT) Determination. You must determine the 
average upscale and downscale response time as the response time for 
the system (the RT). This is the time it takes for the measurement 
system, while operating normally, to respond to a known step change in 
gas concentration (from a low- or zero-level to high-level gas 
concentration or vice versa). Stable RT measurements are made when 
measured HCl concentration is within five percent of the spike gas 
concentration (i.e., the measurements must meet the  5 
percent calibration error requirement; see below).
     Calibration Error (CE) Test. The CE test is the mean 
difference between the HCl calibration gas value and the CEMS response 
at each calibration point expressed as a percentage of the span. The CE 
of your HCl CEMS must be less than five percent.
     Seven-Day Calibration Drift (CD) Test. Prior to conducting 
an RA test on your HCl CEMS, you must perform a 7-day CD test. The 
purpose of the 7-day CD test is to verify the ability of the CEMS to 
maintain calibration for each of seven, 24-hour periods. The zero-level 
and high-level drift for each day must be less than five percent of the 
span value. You must pass each day's drift checks for seven days to 
meet this requirement and each drift check must be recorded and 
reported for the 7-day drift check test.
     RA Test. You must determine the RA for your HCl CEMS. As 
noted above, the RA must be established against an RM. The RA is the 
absolute mean difference between the gas concentration determined by 
the CEMS and the value determined by the RM, plus the 2.5 percent error 
confidence coefficient of a series of tests divided by the average of 
the RM or the applicable emission standard.

E. What are the reporting and recordkeeping requirements for PS-18?

    The proposed PS-18 specifies requirements to record and report 
supporting data for test procedures and calculations set out in PS-18. 
For example, for systems that use a gas blender and/or liquid 
evaporative calibrator to deliver HCl gas standards, PS-18 requires 
that you record and report supporting data for these devices,

[[Page 27694]]

including liquid feed calibrations, liquid standard(s) concentration, 
feed rate and gas flow calibrations for all diluent and HCl gas flows. 
The proposed PS-18 also requires that you record and report summaries 
(in tabular form) of the results of CD tests, linearity tests, RT 
tests, CE tests, RA tests and optional spike recovery procedures. 
Additionally, the proposed PS-18 requires that you record and report 
supporting dilution system data and LOD and system limitation 
verification data for installed HCl CEMS.

IV. Summary of Proposed Procedure 6

A. What is the purpose of Procedure 6?

    This proposed procedure specifies the minimum QA requirements 
necessary for the control and assessment of the quality of CEMS data 
submitted to the EPA. The proposed Procedure 6 would have two distinct 
and important purposes. First, the procedure would assess the quality 
of the HCl CEMS data produced by estimating accuracy. Second, the 
procedure would assist in the control and improvement of the quality of 
the CEMS data by implementing QC policies and corrective actions. Both 
of these purposes work together to ensure that data quality is 
acceptable.

B. Who must comply with Procedure 6?

    Under the proposed Procedure 6, if you are responsible for one or 
more CEMS used for HCl compliance monitoring, you would be required to 
meet the minimum requirements of Procedure 6 and are encouraged to 
develop and implement a more extensive QA program or to continue such 
programs where they already exist. The proposed Procedure 6 would apply 
to any HCl CEMS that is subject to PS-18. That is, if you are required 
under an applicable subpart to parts 60, 61, or 63 to install and 
operate an HCl CEMS and you choose to comply with PS-18, you would be 
subject to both PS-18 and Procedure 6.

C. When must I comply with Procedure 6?

    If you are the owner or operator of an affected HCl CEMS, you must 
comply with Procedure 6 when you install and place into operation an 
HCl CEMS that is subject to PS-18 or when an existing HCl CEMS becomes 
subject to PS-18.

D. What are the basic requirements of Procedure 6?

    Requirements are based on proposed PS-18. Procedure 6 includes 
requirements for: (1) QC plan; (2) daily quality, calibration and 
measurement standardization procedures; and (3) data accuracy 
assessment. A summary of the proposed basic requirements is presented 
below.
1. Quality Control Plan
    The proposed Procedure 6 requires that you develop and implement a 
QC plan that includes written procedures and manufacturer's information 
describing in detail complete, step-by-step measures that ensure 
quality data. The QC plan must cover procedures and operations for 
specified activities (e.g., CD checks of HCl CEMS, HCl IP-CEMS emission 
source temperature and pressure accuracy). Records of these written 
procedures must be maintained and available for inspection by 
enforcement agencies. The proposed Procedure 6 requires either revising 
the QC plan or modifying or replacing the CEMS when quality control 
failures occur for two consecutive quarters.
2. Daily Quality Requirements, Calibration and Measurement Procedures
     CD Assessment. You are required to check, record and 
quantify the CD at two concentration values at least once daily in 
accordance with the method prescribed by the manufacturer. The HCl CEMS 
calibration must, at a minimum, be adjusted whenever the daily zero (or 
low-level) CD or daily high-level CD exceeds two times the drift limits 
of the applicable performance specification (e.g., PS-18).
     Beam Intensity Requirement for HCl IP-CEMS. You must 
check, record and quantify the beam intensity of your IP-CEMS at least 
once daily according to manufacturer's specifications and procedures. 
If the HCl CEMS is out-of-control (the beam intensity falls outside of 
the operation range determined by section 11.2 of the proposed PS-18 of 
part 60), you must take the necessary corrective action and verify that 
the issue has been corrected (i.e., by documenting and reporting the 
results of the quality control check procedure following corrective 
action showing the CEMS to be operating within specifications).
     CEMS Data Status During Out-of-Control Period. Procedure 6 
requires that CEMS data obtained during out-of-control periods not be 
used when calculating compliance with an emissions limit or counted 
toward meeting minimum data availability requirements under an 
applicable regulation or permit.
3. Data Accuracy Assessment
    Procedure 6 requires a weekly ``above span linearity'' challenge of 
the monitoring system with a certified calibration value greater than 
your highest expected hourly concentration. The ``above span'' 
reference gas must be introduced to the measurement system at the 
probe. You must record and report the results of this procedure as you 
would for a daily calibration. The ``above span linearity'' challenge 
must fall within 10 percent of the certified value of the reference 
gas.
     Temperature and Pressure Accuracy Assessment. Procedure 6 
requires temperature and pressure accuracy verification for HCl IP-
CEMS. The accuracy of the temperature and pressure measurement systems 
in each HCl IP-CEMS and stack pressure readings used with IP-CEMS data 
need to be verified and recorded at least once each calendar quarter 
(according to procedures in section 11.3 of the proposed PS-18). 
Procedure 6 also requires that measurement instruments or devices used 
to conduct verification of temperature or pressure measurement have an 
accuracy that is traceable to NIST. If the temperature and pressure 
verification exceeds criteria specified in the procedure that indicates 
that the HCl IP-CEMS is out-of-control, you need to take the necessary 
corrective action to eliminate the problem and verify that it has been 
corrected by repeating the failed verification (i.e., by documenting 
and reporting the results of the audit following corrective action 
showing the CEMS to be operating within specifications).
     Concentration Accuracy Auditing Requirements. Procedure 6 
requires that the accuracy of each HCl CEMS be audited at least once 
each calendar quarter by a relative accuracy test audit (RATA), DS 
audit (DSA), a cylinder gas audit (CGA) or other acceptable alternative 
approved by the Administrator. Hydrogen chloride audit gases are 
required to be NIST certified or NIST-traceable. Procedure 6 also 
requires a RATA to be conducted at least once every four calendar 
quarters unless the affected facility is off-line. Procedure 6 would 
require the analysis of RM audit samples, if they are available, 
concurrently with RM tests as specified in the general provisions of 
the applicable part (i.e., based on the part [i.e., part 60, 61, or 63] 
that contains the subpart that requires the owner or operator to 
install and operate an HCl CEMS).
     Excessive Audit Inaccuracy. Procedure 6 requires 
corrective actions to eliminate problem(s) when the CEMS is out-of-
control. The procedure also requires that you verify that you have 
eliminated the problem(s) by documenting and reporting the results of 
the audit following corrective action

[[Page 27695]]

showing the CEMS to be operating within specifications. For purposes of 
excessive audit inaccuracy, a CEMS is considered out-of-control when 
(1) RA is greater than 20 percent of the RM when RMavg is used in the 
denominator to determine RA or greater than 15 percent when the 
equivalent emission standard value in parts per million by volume wet 
(ppmvw) is used in the denominator to determine RA; (2) the RA of the 
DSA is greater than 15 percent if the average spike value is used to 
determine RA or greater than 20 percent of the applicable emission 
standard if the emission standard is used to determine RA; or (3) the 
error determined by the CGA is greater than five percent of span. 
Procedure 6 proposes that CEMS data collected during out-of-control 
periods not be used in calculating compliance with emission limits nor 
be counted towards meeting minimum data availability requirements under 
an applicable regulation or permit.
     Criteria for Acceptable QC Procedures. In situations where 
a CEMS experiences excessive audit inaccuracies for two consecutive 
quarters, the proposed procedure requires that you revise your QC 
procedures, or modify or replace your CEMS.
     Criteria for Optional QA Test Frequency. The proposed 
Procedure 6 specifies that, if a CEMS is determined to be in-control 
for eight consecutive quarters that include a minimum of two RATA, you 
may revise your auditing procedures to use CGA or DSA each quarter for 
eight subsequent quarters. Under this scenario, you would only be 
required to perform a RATA that meets the acceptance criteria once 
every two years. If a CEMS fails a RATA, CGA, or DSA, you would need to 
revert to the original auditing schedule until the audit results meet 
in-control criteria to start re-qualifying for the optional QA test 
frequency again.
     Calculations for CEMS Data Accuracy. The proposed 
Procedure 6 specifies RA, CGA accuracy and DSA accuracy calculation 
requirements.

E. What are the reporting and recordkeeping requirements for Procedure 
6?

    The proposed Procedure 6 would require that if you own or operate 
an affected HCl CEMS, you must report for each CEMS the accuracy and CD 
assessment results as a Data Assessment Report (DAR) (an example of a 
DAR format is provided in Procedure 6; section 9.0, Figure 1). At a 
minimum, the DAR must contain source owner and operator information; 
identification and location of monitors in the CEMS; manufacturer and 
model number of each monitor in the CEMS; assessment of CEMS data 
accuracy; and date of assessment. The DAR is required to be submitted 
with the report of emissions required under the applicable regulation 
or permit that requires continuous emission monitoring.

V. Rationale for Selecting the Proposed Requirements of Performance 
Specification 18 and Procedure 6

A. What information did we use to develop PS-18 and Procedure 6?

    To develop proposed PS-18 and Procedure 6, we considered the 
requirements of emission standards promulgated under 40 CFR parts 60, 
61 and 63; state agency requirements for CEMS; manufacturer and vendor 
recommendations; and current operational and design practices in the 
industry. As part of this consideration, the EPA's Office of Air 
Quality Planning and Standards (OAQPS) gathered information from 
instrument and gas vendors, affected facilities, testers and regulatory 
bodies with experience performing continuous measurements of HCl from 
stationary sources.
    Concurrent with the EPA's OAQPS' information gathering efforts, the 
EPA's Office of Research and Development (ORD) conducted research to 
establish additional data to support the new performance specification 
and QA test procedures. As part of the EPA's ORD's research efforts, 
they evaluated commercial HCl CEMS under controlled and representative 
emission environments, the suitability of candidate RMs and the status 
and quality of available gas standards. The ORD focused their testing 
research on interference tests, LOD tests, 7-day drift, linearity, 
RATAs and DS.

B. How did we select the requirements for PS-18 and Procedure 6?

    Generally, the basic requirements proposed under PS-18 and 
Procedure 6 for calibration error, calibration drift, RATA, and 
cylinder gas audit agreement are consistent with other CEMS performance 
specifications. The proposed LOD requirements are based on an adequate 
safety margin so that equipment can measure quantitatively at the 
compliance limit. The proposed DS requirements are consistent with 
other RM recovery requirements (e.g., EPA Method 320, EPA Method 18). 
The above-span calibration and linearity requirements proposed are 
based on the PS-12 precedent used for mercury CEMS.
    During the development of the proposed PS-18 and Procedure 6, we 
evaluated all options and attempted to develop the most appropriate 
performance specifications and procedures based on available 
information, testing and feedback from vendors and industry regarding 
the use of HCl CEMS. Although we believe this proposal includes the 
most appropriate HCl CEMS performance specifications and procedures 
(for use as an alternative to PS-15 for HCl CEMS), we are soliciting 
comment on several issues provided in paragraph V.C of this preamble.

C. Solicitation for Comment

1. Performance Specification 18 Topics
a. Integrated Path (IP-CEMS) Line Strength Factor
    Calibration error procedures proposed for IP-CEMS in PS-18 require 
correcting for calibration cell path length, temperature, pressure, 
line strength factor (LSM) and, if necessary, the native source gas HCl 
concentration when you calculate the stack equivalent concentration of 
the HCl gas measured in your calibration cell. The proposed 
specification allows the use of the line LSM provided by the instrument 
manufacturer or an instrument-specific LSM experimentally determined 
using a heated gas cell at effective gas concentrations equivalent to 
between 50 and 150 percent of the emission limit. We are soliciting 
comment on approaches used by IP instrument vendors to determine LSM 
and data showing the effect of LSM on the accuracy of the stack 
equivalent concentration calculation.
b. Optical Measurement Path Length Determination
    An IP-CEMS measures the gas concentration along an open optical 
path across the stack or duct cross section. Specifically, for IP-CEMS, 
measurement path is the distance of the optical path that passes 
through the source gas in the stack or duct correcting for ports, 
standoffs, and extensions or CEM-specific optical path length 
alterations. The optical measurement path length must be measured and 
not based on engineering diagrams. We are requesting information on 
procedures currently available to measure the optical path length for 
IP monitors that will result in an accuracy of at least  1 
percent. (See PS-1 of Appendix B to Part 60 (Specifications and Test 
Procedures for Continuous Opacity Monitoring Systems in Stationary 
Sources); section 8.1.)

[[Page 27696]]

c. Alternative CEMS Probe Placement Locations
    Section 8.3 of the proposed PS-18 specifies HCl measurement 
location requirements downstream of the control device, point of 
pollution generation or other point at which a change of pollutant 
concentration may occur and upstream of the exhaust. We are seeking 
comment and supporting data on alternative probe placement locations 
such as in the breeching of the stack (i.e., in the exhaust duct or 
pipe that leads from the stack) that pass the RATA requirements.
2. Appendix F Procedure 6 Topics
a. Effect of Temperature and Pressure on HCl Concentration 
Determination During DS Measurements
    We provided options in Appendix F Procedure 6 for initial and 
ongoing quality control using DS for IP-CEMS. The procedure to perform 
DS is described in Appendix A of PS-18. For IP-CEMS, dynamic spiking is 
a standard addition procedure where you spike a known concentration of 
HCl gas into a calibration cell. You are required to assess the 
accurate recovery of HCl introduced into the measurement system in the 
presence of potential interference from the flue gas sample matrix. The 
measurement involves recording the combined optical signal from HCl in 
the calibration cell at ambient temperature and HCl in the stack at 
elevated temperature. The combination of HCl absorbance at two 
different temperatures would create hybrid spectra features of both 
temperatures. Based on our evaluation, we understand there can be as 
much as a 10 percent difference line shape/area used for IP 
measurements between instrument operating temperature near 20[deg]C and 
typical stack temperatures up to 250[deg]C. We are requesting comment 
on procedures that can be used to determine the concentration when IP 
calibration cells contain HCl at ambient temperature (approximately 
20[deg]C) or the need to heat the calibration cell to a specific 
temperature during DS measurements that include absorbance for both 
stack gas (HCl) at elevated temperature and ambient temperature 
calibration cell HCl.
b. Use of Dynamic Spiking
    The proposed PS-18 and Procedure 6 require that you audit the 
accuracy of each HCl CEMS at least once each calendar quarter (except 
the quarter the RATA is conducted) by a DSA, a CGA or other acceptable 
alternative. Appendix A to the proposed PS-18 describes the procedure 
and performance requirements for DS as a quality check for HCl CEMS. We 
are proposing this option as one of three alternatives to a RATA in 
three of the four quarterly QA checks required in Procedure 6. We are 
soliciting comment on our proposal and data on the use of periodic DS 
as an alternative to the use of a CGA.
c. Alternative QA for Low Level RM RATA Measurements
    We are proposing a mandatory RATA with the appropriate RM during 
initial demonstration and periodically thereafter. We are also 
soliciting comment and data on alternative or additional QA that should 
be performed when the stack HCl concentration is below the RM 
quantitation limit.
d. Long-Term Quality Control Under Procedure 6
    The proposed Appendix F to part 60 (Quality Assurance Procedure 6) 
requires a RATA at least once every four calendar quarters, except in 
the case where the affected facility is off-line (does not operate in 
the fourth calendar quarter since the quarter of the previous RATA). 
Section 5.5 of the procedure specifies that if the CEMS is in-control 
for eight consecutive quarters that include a minimum of two RATA, you 
may revise your auditing procedures to use CGA or DSA each quarter for 
eight subsequent quarters, but you must perform at least one RATA and 
demonstrate that the source meets the acceptance criteria every 2 
years. We are requesting comments and data on alternative grace periods 
allowed between required RATAs when your audits demonstrate that the 
source has been in-control long-term under Procedure 6.
e. Method 205 to Generate Cylinder Gas Audit Concentrations for 
Quarterly Audits
    Section 7.3 (Reagents and Standards) of the proposed PS-18 allows 
the use of diluted high concentration HCl standards to achieve the HCl 
gas concentrations required in PS-18 as long as you follow Method 205 
or other procedures approved by the Administrator. We are soliciting 
comment and data comparing the uncertainty of gases generated by 
dilution using Method 205 to the tolerance allowed for cylinder gas 
audits in section 5.2.2.3 of Procedure 6 proposed for 40 CFR part 60, 
Appendix F.
f. Direct Instrument Cell Calibration Checks
    As noted previously, for extractive CEMS, DS involves adding a 
known concentration of HCl gas at a known flow rate into the probe 
sample gas stream to assess the ability of the measurement system to 
recover and accurately measure HCl in the presence of potential 
interference from the flue gas matrix. We are considering an 
alternative that includes instrument calibration checks for extractive 
CEMS and request comment and supporting data on two topics related to 
calibration check procedures: (1) What is the feasibility of achieving 
DS accuracy to 95 percent of the theoretical spike at the span 
concentration? and (2) If calibration checks are performed at the 
instrument for extractive CEMS, what is the accuracy of dynamic spike 
recovery?
g. Using DS and Associated Acceptance Criteria as an Alternative to 
Daily Calibration Check for Quality Assurance Procedure 6
    Calibration drift is a quantitative assessment of whether your HCl 
CEMS measurements are in control. Checking calibration also allows the 
facility to reset the calibration and improve the consistency and 
quality of HCl CEMS data. We are considering using dynamic spiking as 
an alternative to direct cylinder gas assessment of calibration drift 
as a measure of QC for HCl CEMS. We are taking comment and data on the 
quantitative comparison of dynamic spike recovery results compared to 
CD results to determine if there are comparable criteria for DS to 
qualify as an alternative for CD tests.
h. Moisture Measurements To Correct HCl Results
    Section 6.8 (Moisture Measurement System) of the proposed PS-18 
stipulates that, if correction of the measured HCl emissions for 
moisture is required, either Method 4 in Appendix A-3 of part 60 or 
other moisture measurement methods approved by the Administrator will 
be needed to measure stack gas moisture content. We are requesting 
comment/data on conditions or situations where continuous moisture 
measurements should be required to correct HCl results to the units of 
the standard, and where periodic Method 4 tests or equivalent is good 
enough on a periodic basis to define moisture for the entire duration 
between Method 4 tests.
i. Other Initial or On-Going Procedures for IP-CEMS
    We are soliciting comment/data on other initial or on-going 
procedures for

[[Page 27697]]

IP-CEMS not included in the proposal that are commonly performed and 
necessary to ensure data are of known and acceptable quality to 
demonstrate compliance.

VI. Statutory and Executive Order Reviews

A. Executive Order 12866: Regulatory Planning and Review and Executive 
Order 13563: Improving Regulation and Regulatory Review

    This action is not a ``significant regulatory action'' under the 
terms of Executive Order 12866 (58 FR 51735, October 4, 1993) and is 
therefore not subject to review under Executive Orders 12866 and 13563 
(76 FR 3821, January 21, 2011).

B. Paperwork Reduction Act

    This action does not impose an information collection burden under 
the provisions of the Paperwork Reduction Act, 44 U.S.C. 3501 et seq. 
Burden is defined at 5 CFR 1320.3(b). This action provides performance 
criteria and QA test procedures for assessing the acceptability of HCl 
CEMS performance and data quality. These criteria and QA test 
procedures do not add information collection requirements beyond those 
currently required under the applicable regulation.

C. Regulatory Flexibility Act

    The Regulatory Flexibility Act (RFA) generally requires an agency 
to prepare a regulatory flexibility analysis of any rule subject to 
notice and comment rulemaking requirements under the Administrative 
Procedure Act or any other statute unless the agency certifies that the 
rule will not have a significant economic impact on a substantial 
number of small entities. Small entities include small businesses, 
small organizations, and small governmental jurisdictions.
    For purposes of assessing the impacts of this rule on small 
entities, small entity is defined as: (1) A small business as defined 
by the Small Business Administration's regulations at 13 CFR 121.201; 
(2) a small governmental jurisdiction that is a government of a city, 
county, town, school district or special district with a population of 
less than 50,000; and (3) a small organization that is any not-for-
profit enterprise which is independently owned and operated and is not 
dominant in its field.
    After considering the economic impacts of this rule on small 
entities, I certify that this action will not have a significant 
economic impact on a substantial number of small entities. This 
proposed rule will not impose any requirements on small entities. We 
continue to be interested in the potential impacts of the proposed rule 
on small entities and welcome comments on issues related to such 
impacts.

D. Unfunded Mandates Reform Act

    This action contains no federal mandates under the provisions of 
Title II of the Unfunded Mandates Reform Act of 1995 (UMRA), 2 U.S.C. 
1531-1538, for state, local or tribal governments or the public sector. 
This action imposes no enforceable duty on any state, local or tribal 
governments or the private sector. Therefore, this action is not 
subject to the requirements of sections 202 or 205 of UMRA.
    This action is also not subject to the requirements of section 203 
of the UMRA because it contains no regulatory requirements that might 
significantly or uniquely affect small governments. This rule will not 
apply to such governments and will not impose any obligations upon 
them.

E. Executive Order 13132: Federalism

    This action does not have federalism implications. It will not have 
substantial direct effects on the states, on the relationship between 
the national government and the states or on the distribution of power 
and responsibilities among the various levels of government, as 
specified in Executive Order 13132. Thus, Executive Order 13132 does 
not apply to this action.
    In the spirit of Executive Order 13132 and consistent with EPA 
policy to promote communications between the EPA and state and local 
governments, the EPA specifically solicits comment on this proposed 
rule from state and local officials.

F. Executive Order 13175: Consultation and Coordination With Indian 
Tribal Governments

    This action does not have tribal implications, as specified in 
Executive Order 13175 (65 FR 67249, November 9, 2000). This action 
proposes performance specifications that can be used as an additional 
option to PS-15 for HCl continuous emissions monitoring. Thus, 
Executive Order 13175 does not apply to this action. The EPA solicits 
additional comment on this proposed action from tribal officials.

G. Executive Order 13045: Protection of Children From Environmental 
Health Risks and Safety Risks

    The EPA interprets Executive Order 13045 (62 FR 19885, April 23, 
1997) as applying only to regulatory actions that are based on health 
or safety risks, such that the analysis required under section 5-501 of 
the Executive Order has the potential to influence the regulation. This 
action is not subject to Executive Order 13045 because it does not 
establish an environmental standard intended to mitigate health or 
safety risks.

H. Executive Order 13211: Actions Concerning Regulations That 
Significantly Affect Energy Supply, Distribution, or Use

    This action is not subject to Executive Order 13211 (66 FR 28355 
(May 22, 2001)), because it is not a significant regulatory action 
under Executive Order 12866.

I. National Technology Transfer and Advancement Act

    Section 12(d) of the National Technology Transfer and Advancement 
Act of 1995 (NTTAA), Public Law 104-113, 12(d) (15 U.S.C. 272 note) 
directs the EPA to use voluntary consensus standards (VCS) in its 
regulatory activities unless to do so would be inconsistent with 
applicable law or otherwise impractical. Voluntary consensus standards 
are technical standards (e.g., materials specifications, test methods, 
sampling procedures, and business practices) that are developed or 
adopted by VCS bodies. The NTTAA directs the EPA to provide Congress, 
through OMB, explanations when the agency decides not to use available 
and applicable VCS. This proposed rule does not involve technical 
standards. Therefore, the EPA is not considering the use of any 
voluntary consensus standards.

J. Executive Order 12898: Federal Actions To Address Environmental 
Justice in Minority Populations and Low-Income Populations

    Executive Order 12898 (59 FR 7629, February 16, 1994) establishes 
federal executive policy on environmental justice. Its main provision 
directs federal agencies, to the greatest extent practicable and 
permitted by law, to make environmental justice part of their mission 
by identifying and addressing, as appropriate, disproportionately high 
and adverse human health or environmental effects of their programs, 
policies, and activities on minority populations and low-income 
populations in the United States.
    The EPA has determined that this proposed rule will not have 
disproportionately high and adverse human health or environmental 
effects on minority or low-income populations

[[Page 27698]]

because it does not affect the level of protection provided to human 
health or the environment. This proposed rule will help to ensure that 
emission control devices are operated properly and maintained as 
needed, thereby helping to ensure compliance with emission standards, 
which would benefit all affected populations.

Performance Specification 18--Specifications and Test Procedures for 
Gaseous HCl Continuous Emission Monitoring Systems at Stationary 
Sources

List of Subjects in 40 CFR Part 60

    Environmental protection, Administrative practice and procedure, 
Air pollution control, Continuous emission monitoring systems, Hydrogen 
chloride, Performance specifications, Test methods and procedures.

    Dated: April 30, 2014.
Gina McCarthy,
Administrator.

    For the reasons stated in the preamble, the Environmental 
Protection Agency proposes to amend title 40, chapter 1 of the Code of 
Federal Regulations as follows:

0
1. The authority citation for part 60 continues to read as follows:

    Authority: 42 U.S.C., 7401-7671q.

0
2. Appendix B is amended by adding Performance Specification 18 and 
Appendix A to Performance Specification 18 to read as follows:

Appendix B to Part 60--Performance Specifications

* * * * *

PERFORMANCE SPECIFICATION 18--PERFORMANCE SPECIFICATIONS AND TEST 
PROCEDURES FOR GASEOUS HYDROGEN CHLORIDE (HCl) CONTINUOUS EMISSION 
MONITORING SYSTEMS AT STATIONARY SOURCES

    1.0 Scope and Application.
    1.1 Analyte. This performance specification (PS) is applicable 
for measuring gaseous concentrations of hydrogen chloride (HCl), 
CAS: 7647-01-0, on a continuous basis in the units of the applicable 
standard or in units that can be converted to units of the 
applicable standard(s).
    1.2 Applicability.
    1.2.1 This specification is used to evaluate the acceptability 
of HCl continuous emission monitoring systems (CEMS) at the time of 
installation or soon after and when regulations require reevaluation 
of HCl CEMS performance. The specification includes requirements for 
initial acceptance including instrument accuracy and stability 
assessments.
    1.2.2 The Administrator may require the operator under section 
114 of the Clean Air Act (CAA), to conduct CEMS performance 
evaluations at other times besides the initial test to evaluate the 
CEMS performance. See 40 CFR part 60, Sec.  60.13(c) and Sec.  
63.8(e)(1).
    1.2.3 A source that demonstrates their CEMS meets the criteria 
of this PS may use the system to continuously monitor gaseous HCl. 
If your HCl CEMS is capable of reporting the HCl concentration in 
the units of the existing standard, no additional CEMS components 
are necessary. If your HCl CEMS does not report concentrations in 
the units of the existing standard, then other CEMS components 
(e.g., oxygen (O2), temperature, stack gas flow, moisture 
and pressure) are necessary to convert the units reported by your 
HCl CEMS to the units of the standard.
    1.2.4 These specification test results are intended to be valid 
for the life of the system. As a result, the HCl measurement system 
must be tested and operated in a configuration consistent with the 
configuration that will be used for ongoing continuous emissions 
monitoring.
    1.2.5 Substantive changes to the system configuration require 
retesting according to this PS. Examples of such conditions include, 
but are not limited to: major changes in dilution ratio (for 
dilution based systems); changes in catalyst materials, if used; 
changes in sample conditioning, if used, such as filtering device 
design or materials; changes in probe design or configuration; light 
source or detector substitution; and changes in materials of 
construction.
    1.2.6 This specification is not designed to evaluate the ongoing 
CEMS performance nor does it identify specific calibration 
techniques and auxiliary procedures to assess CEMS performance over 
an extended period of time. The source owner or operator is 
responsible to calibrate, maintain, and operate the CEMS properly.
    2.0 Summary of Performance Specification.
    2.1 This specification covers the procedures that each HCl CEMS 
must meet during the performance evaluation test. Installation and 
measurement location specifications, data reduction procedures and 
performance criteria are included.
    2.2 The technology used to measure gaseous HCl must provide a 
distinct response and address any appropriate interference 
correction(s). It must accurately measure gaseous HCl in a 
representative sample (path or point sampling) of stack effluent.
    2.3 The relative accuracy (RA) must be established against a 
reference method (RM) (e.g., Method 26A, Method 320, ASTM 
International (ASTM) D6348-12, including mandatory annexes, or 
Method 321, as appropriate for the source concentration and 
category).
    2.4 Dynamic spiking (DS) into the CEMS using a National 
Institute of Standards and Technology (NIST) traceable standard may 
be required to demonstrate performance at sources with emissions 
near the detection level of the CEMS and for ongoing quality 
assurance tests.
    3.0 Definitions.
    3.1 Calibration Cell means a gas containment cell used with 
cross stack or integrated path (IP) monitors to perform precision 
and calibration checks. The cell may be a removable sealed cell or 
an evacuated and/or purged cell capable of exchanging calibration 
and zero gases. When charged, it contains a known concentration of 
HCl calibration gas. The calibration cell is filled with zero gas or 
removed from the optical path during stack gas measurement.
    3.2 Calibration Drift (CD) means the absolute value of the 
difference between the CEMS output response and an upscale reference 
or a zero-level reference, expressed as a percentage of the span 
value, when the CEMS is challenged after a stated period of 
operation during which no unscheduled maintenance or repair took 
place. A separate CD determination must be performed for pollutant 
and diluent analyzers.
    3.3 Calibration Error (CE) means the mean difference between the 
concentration measured by the CEMS and the known concentration from 
a calibration standard, divided by the span, when the entire CEMS, 
including the sampling interface, is challenged.
    3.4 Calibration Range Above Span (CRAS) means the upper limit of 
the measurement range. The calibration range must accommodate the DS 
procedure if that option is selected. The CRAS should be a 
conservatively high estimate of the range of HCl measurements 
expected from the source category. The CRAS value defines the 
calibration and quality assurance at the upper limit of HCl 
concentration measurement. The CRAS may require a calibration 
standard above span.
    3.5 Centroidal Area means a central area that is geometrically 
identical to the stack or duct cross section and is no greater than 
ten percent of the stack or duct cross-sectional area.
    3.6 Continuous Emission Monitoring System (CEMS) means the total 
equipment required to measure the pollutant concentration or 
emission rate continuously.
    3.7 Continuous Operation means the time between periodic 
maintenance when an instrument and sampling system operates without 
user intervention, continuously samples flue gas, analyzes the 
sample gas for HCl and related parameters (e.g., gas flow, diluent), 
records measurement data, and saves the results to a computer file. 
User intervention is permitted for initial set-up of sampling 
system, initial calibrations, periodic calibration corrections, 
periodic maintenance and periodic quality assurance audits.
    3.8 Data Recorder means the portion of the CEMS that provides a 
permanent record of analyzer output. The data recorder may record 
other pertinent data such as effluent flow rates, various instrument 
temperatures or abnormal CEMS operation. The data recorder may also 
include automatic data reduction capabilities and CEMS control 
ca
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