Revisions to Test Methods and Testing Regulations, 1130-1179 [2011-31234]
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Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Parts 51, 60, 61, and 63
[EPA–HQ–OAR–2010–0114; FRL–9501–3]
RIN 2060–AQ01
Revisions to Test Methods and Testing
Regulations
Environmental Protection
Agency (EPA).
ACTION: Proposed rule.
AGENCY:
This action proposes editorial
and technical corrections necessary for
source testing of emissions and
operations. The revisions include the
addition of alternative equipment and
methods as well as corrections to
technical and typographical errors. We
also solicit public comment on potential
changes to the current procedures for
determining emission stratification.
DATES: Comments must be received on
or before March 9, 2012.
Public Hearing. If anyone contacts the
EPA by January 19, 2012 requesting to
speak at a public hearing, a hearing will
be held on February 8, 2012.
ADDRESSES: Submit your comments,
identified by Docket ID No. EPA–HQ–
OAR–2010–0114, by one of the
following methods:
• www.regulations.gov: Follow the
on-line instructions for submitting
comments.
• Email: a-and-r-docket@epa.gov.
• Fax: (202) 566–9744.
• Mail: Revisions to Test Methods
and Testing Regulations, Docket No.
EPA–HQ–OAR–2010–0114,
Environmental Protection Agency,
Mailcode: 2822T, 1200 Pennsylvania
Ave. NW., Washington, DC 20460.
Please include two copies.
• Hand Delivery: Docket No. EPA–
HQ–OAR–2010–0114, EPA Docket
Center, Public Reading Room, EPA
West, Room 3334, 1301 Constitution
Ave. NW., Washington, DC 20460. Such
deliveries are only accepted during the
Docket’s normal hours of operation, and
special arrangements should be made
for deliveries of boxed information.
Instructions: Direct your comments to
Docket ID No. EPA–HQ–OAR–2010–
0114. The EPA’s policy is that all
comments received will be included in
the public docket without change and
may be made available online at https://
www.regulations.gov, including any
personal information provided, unless
the comment includes information
claimed to be Confidential Business
Information (CBI) or other information
whose disclosure is restricted by statute.
Do not submit information that you
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SUMMARY:
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consider to be CBI or otherwise
protected through www.regulations.gov
or email. The www.regulations.gov Web
site is an ‘‘anonymous access’’ system,
which means the EPA will not know
your identity or contact information
unless you provide it in the body of
your comment. If you send an email
comment directly to the EPA without
going through www.regulations.gov,
your email address will be
automatically captured and included as
part of the comment that is placed in the
public docket and made available on the
Internet. If you submit an electronic
comment, the EPA recommends that
you include your name and other
contact information in the body of your
comment as well as with any disk or
CD–ROM you submit. If the EPA cannot
read your comment due to technical
difficulties and cannot contact you for
clarification, the EPA may not be able to
consider your comment. Electronic files
should avoid the use of special
characters, any form of encryption, and
be free of any defects or viruses.
Docket: All documents in the docket
are listed in the www.regulations.gov
index. Although listed in the index,
some information is not publicly
available, e.g., CBI or other information
whose disclosure is restricted by statute.
Certain other material, such as
copyrighted material, will be publicly
available only in hard copy. Publicly
available docket materials are available
either electronically in
www.regulations.gov or in hard copy at
the Revisions to Test Methods and
Testing Regulations Docket, EPA/DC,
EPA West, Room 3334, 1301
Constitution Ave. NW., Washington, DC
20460. The Public Reading Room is
open from 8:30 a.m. to 4:30 p.m.,
Monday through Friday, excluding legal
holidays. The telephone number for the
Public Reading Room is (202) 566–1744,
and the telephone number for the
Revisions to Test Methods and Testing
Regulations Docket is (202) 566–1742.
FOR FURTHER INFORMATION CONTACT: Mr.
Foston Curtis, Office of Air Quality
Planning and Standards, Air Quality
Assessment Division (E143–02),
Environmental Protection Agency,
Research Triangle Park, NC 27711;
telephone number: (919) 541–1063; fax
number: (919) 541–0516; email address:
curtis.foston@epa.gov.
SUPPLEMENTARY INFORMATION:
I. General Information
A. Does this action apply to me?
The proposed amendments apply to a
large number of industries that are
already subject to the current provisions
of Parts 51, 60, 61, and 63. Therefore,
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we have not listed specific affected
industries or their North American
Industry Classification System (NAICS)
codes here. If you have any questions
regarding the applicability of this action
to a particular entity, consult either the
air permitting authority for the entity or
your EPA regional representative as
listed in 40 CFR 63.13.
B. What should I consider as I prepare
my comments for the EPA?
1. Submitting CBI. Do not submit this
information to the EPA through https://
www.regulations.gov or email. Clearly
mark any of the information that you
claim to be CBI. For CBI information in
a disk or CD–ROM that you mail to the
EPA, mark the outside of the disk or
CD–ROM as CBI and then identify
electronically within the disk or CD–
ROM the specific information that is
claimed as CBI. In addition to one
complete version of the comment that
includes information claimed as CBI, a
copy of the comment that does not
contain the information claimed as CBI
must be submitted for inclusion in the
public docket. Information so marked
will not be disclosed except in
accordance with procedures set forth in
40 CFR part 2.
2. Tips for Preparing Your Comments.
When submitting comments, remember
to:
• Follow directions—The Agency
may ask you to respond to specific
questions or organize comments by
referencing a Code of Federal
Regulations (CFR) part or section
number.
• Explain why you agree or disagree,
suggest alternatives, and substitute
language for your requested changes.
• Describe any assumptions and
provide any technical information and/
or data that you used.
• If you estimate potential costs or
burdens, explain how you arrived at
your estimate in sufficient detail to
allow for it to be reproduced.
• Provide specific examples to
illustrate your concerns, and suggest
alternatives.
• Explain your views as clearly as
possible, avoiding the use of profanity
or personal threats.
• Make sure to submit your
comments by the comment period
deadline identified.
C. Where can I get a copy of this
document?
In addition to being available in the
docket, an electronic copy of this
proposed rule will also be available on
the Worldwide Web (WWW) through
the Technology Transfer Network
(TTN). Following signature, a copy of
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this proposed rule will be posted on the
TTN’s policy and guidance page for
newly proposed or promulgated rules at
the following address: https://
www.epa.gov/ttn/oarpg/. The TTN
provides information and technology
exchange in various areas of air
pollution control. A redline/strikeout
document comparing the proposed
revisions to the appropriate sections of
the current rules is located in the
docket.
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D. How is this document organized?
The supplementary information in
this preamble is organized as follows:
I. General Information
A. Does this action apply to me?
B. What should I consider as I prepare my
comments for the EPA?
C. Where can I get a copy of this
document?
D. How is this document organized?
II. Background
III. Summary of Amendments
A. Appendix M of Part 51
B. Method 201A of Appendix M of Part 51
C. Method 202 of Appendix M of Part 51
D. General Provisions (Subpart A) Part 60
E. Industrial-Commercial-Institutional
Steam Generating Units (Subpart Db)
Part 60
F. Hospital/Medical/Infectious Waste
Incinerators (Subpart Ec) Part 60
G. Sulfuric Acid Plants (Subpart H) Part 60
H. Sewage Treatments Plants (Subpart O)
Part 60
I. Kraft Pulp Mills (Subpart BB) Part 60
J. Stationary Gas Turbines (Subpart GG)
Part 60
K. Lead-Acid Battery Manufacturing Plants
(Subpart KK) Part 60
L. Metallic Mineral Processing Plants
(Subpart LL) Part 60
M. Asphalt Processing and Asphalt Roofing
Manufacture (Subpart UU) Part 60
N. Volatile Organic Chemical (VOC)
Emissions From Synthetic Organic
Compound Manufacturing Industry
(SOCMI) Distillation Operations (Subpart
NNN) Part 60
O. Stationary Compression Ignition
Internal Combustion Engines (Subpart
IIII) Part 60
P. Stationary Spark Ignition Internal
Combustion Engines (Subpart JJJJ) Part
60
Q. Method 1 of Appendix A–1 of Part 60
R. Method 2 of Appendix A–1 of Part 60
S. Method 2A of Appendix A–1 of Part 60
T. Method 2B of Appendix A–1 of Part 60
U. Method 2D of Appendix A–1 of Part 60
V. Method 3A of Appendix A–2 of Part 60
W. Method 4 of Appendix A–3 of Part 60
X. Method 5 of Appendix A–3 of Part 60
Y. Method 5A of Appendix A–3 of Part 60
Z. Method 5E of Appendix A–3 of Part 60
AA. Method 5H of Appendix A–3 of Part
60
BB. Method 6 of Appendix A–4 of Part 60
CC. Method 6C of Appendix A–4 of Part 60
DD. Method 7 of Appendix A–4 of Part 60
EE. Method 7A of Appendix A–4 of Part 60
FF. Method 7E of Appendix A–4 of Part 60
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GG. Method 8 of Appendix A–4 of Part 60
HH. Method 10 of Appendix A–4 of Part
60
II. Methods 10A and 10B of Appendix A–
4 of Part 60
JJ. Method 11 of Appendix A–5 of Part 60
KK. Method 12 of Appendix A–5 of Part 60
LL. Method 14A of Appendix A–5 of Part
60
MM. Method 16A of Appendix A–6 of Part
60
NN. Method 18 of Appendix A–6 of Part
60
OO. Method 23 of Appendix A–7 of Part
60
PP. Method 24 of Appendix A–7 of Part 60
QQ. Method 25 of Appendix A–7 of Part
60
RR. Method 25C of Appendix A–7 of Part
60
SS. Method 25D of Appendix A–7 of Part
60
TT. Method 26 of Appendix A–8 of Part 60
UU. Method 29 of Appendix A–8 of Part
60
VV. Method 30B of Appendix A–8 of Part
60
WW. Performance Specification 1 of
Appendix B of Part 60
XX. Performance Specification 3 of
Appendix B of Part 60
YY. Performance Specification 4 of
Appendix B of Part 60
ZZ. Performance Specification 4B of
Appendix B of Part 60
AAA. Performance Specification 7 of
Appendix B of Part 60
BBB. Performance Specification 11 of
Appendix B of Part 60
CCC. Performance Specification 15 of
Appendix B of Part 60
DDD. Performance Specification 16 of
Appendix B of Part 60
EEE. Procedure 1 of Appendix F of Part 60
FFF. Procedure 2 of Appendix F of Part 60
GGG. Procedure 5 of Appendix F of Part 60
HHH. General Provisions (Subpart A) Part
61
III. Beryllium (Subpart C) Part 61
JJJ. Beryllium Rocket Motor Firing (Subpart
D) Part 61
KKK. Mercury (Subpart E) Part 61
LLL. Inorganic Arsenic Emissions from
Glass Manufacturing Plants (Subpart N)
Part 61
MMM. Method 101 of Appendix B of Part
61
NNN. Method 101A of Appendix B of Part
61
OOO. Method 102 of Appendix B of Part
61
PPP. Method 104 of Appendix B of Part 61
QQQ. Methods 108 and 108A of Appendix
B of Part 61
RRR. General Provisions (Subpart A) Part
63
SSS. Synthetic Organic Chemical
Manufacturing Industry (Subpart G) Part
63
TTT. Chromium Emissions From Hard and
Decorative Chromium Electroplating and
Chromium Anodizing Tanks (Subpart N)
Part 63
UUU. Ethylene Oxide Emissions Standards
for Sterilization Facilities (Subpart O)
Part 63
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VVV. Marine Tank Vessel Loading
Operations (Subpart Y) Part 63
WWW. Aerospace Manufacturing and
Rework Facilities (Subpart GG) Part 63
XXX. Pharmaceuticals Production (Subpart
GGG) Part 63
YYY. Secondary Aluminum Production
(Subpart RRR) Part 63
ZZZ. Manufacturing of Nutritional Yeast
(Subpart CCCC) Part 63
AAAA. Petroleum Refineries: Catalytic
Cracking Units, Catalytic Reforming
Units, and Sulfur Recovery Units
(Subpart UUUU) Part 63
BBBB. Stationary Reciprocating Internal
Combustion Engines (Subpart ZZZZ)
Part 63
CCCC. Method 306 of Appendix A of Part
63
DDDD. Method 306A of Appendix A of
Part 63
EEEE. Methods 308, 315, and 316 of
Appendix A of Part 63
FFFF. Method 321 of Appendix A of Part
63
IV. Request for Comments
V. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory
Planning and Review and Executive
Order 13563: Improving Regulations and
Regulatory Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act
D. Unfunded Mandates Reform Act
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation
and Coordination With Indian Tribal
Governments
G. Executive Order 13045: Protection of
Children From Environmental Health
and Safety Risks
H. Executive Order 13211: Actions
Concerning Regulations That
Significantly Affect Energy Supply,
Distribution, or Use
I. National Technology Transfer and
Advancement Act
J. Executive Order 12898: Federal Actions
To Address Environmental Justice in
Minority Populations and Low-Income
Populations
II. Background
The EPA catalogs revisions and
updates that are needed for test
methods, performance specifications,
and associated regulations in 40 CFR
parts 51, 60, 61, and 63, and proposes
the revisions on a 5- to 10-year basis.
The last methods update was published
as a final rule on October 17, 2000 (65
FR 61744). Many of these needed
revisions were brought to our attention
by affected parties and end-users. The
revisions consist of allowable
alternatives that were not previously
available, changes that facilitate the use
of mercury-free equipment, and updates
needed to correct obsolete provisions or
add flexibility. Corrections to
typographical errors and technical
errors in equations and diagrams are
also proposed. It is important to note
that although numerous technical
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corrections are being proposed to
portions of the subparts in parts 51, 60,
61, and 63, changes are not made to any
compliance standard, reporting, or
recordkeeping requirement. For this
notice, the EPA is only proposing
revisions to sections of the subpart
pertaining to source testing or
monitoring of emissions and operations.
III. Summary of Amendments
A. Appendix M of Part 51
In the introduction of Appendix M of
part 51, Methods 3A and 19 would be
added to the list of methods not
requiring the use of audit samples.
Method 3A is a direct measurement
instrumental method which the audit
program does not evaluate, and Method
19 deals with calculation procedures
and not measurement procedures.
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B. Method 201A of Appendix M of Part
51
Revisions would be made to the
Method 201A published on December
21, 2010. Typographical errors in
references to isokinetic sampling rate,
source gas temperatures, stack blockage
dimensions by the sampling heads, and
PM10 in Sections 8.3.4(b), 8.3.4.1,
8.7.2.2, and 8.7.5.5(a), respectively,
would be corrected. An erroneous
reference to Methods 4A and 5 in
Section 10.1 when using a standard
pitot tube would be corrected to refer to
Methods 1 and 2. Section 10.5, which
addresses Class A volumetric glassware,
would be deleted because it is not
needed in the method. For those filters
whose weight cannot be weighed to a
constant weight in Section 11.2.1,
instruction would be added to flag and
report the data as a minimum value. It
would be noted that the nozzle, front
half, and in-stack filter samples need to
be speciated into organic and inorganic
fractions to be similar to the practice in
Method 17. The method would also note
that neither Method 17 nor 201A require
a separate analysis of the filter for
inorganic and organic particulate
matter. Method 201A is often used
together with Method 202 which
requires a separate analysis of inorganic
and organic PM. This note would
remind testers that a separate analysis is
not required for Method 201A. An
incorrect term in Equation 9 of Section
12.5 would be corrected. In the
nomenclature in Section 12.1, Vb, the
volume of aliquot taken for ion
chromatography (IC) analysis, would be
deleted since no IC analysis is
performed.
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C. Method 202 of Appendix M of Part
51
Revisions would be made to the
Method 202 published on December 21,
2010. In Section 8.5.3.1, the text
referring to empty impingers would be
deleted because empty impingers are
not used. Figures 2 and 3 would be
revised to correctly show the first
impinger with an extended stem instead
of a shortened one to be consistent with
the method text, and the condensed
moisture and sample portion of the
sampling train would be labeled to
make it easy to identify. Figures 4, 5,
and 6 would be republished because
they did not print clearly in the
December 21, 2010, publication.
D. General Provisions (Subpart A) Part
60
In the General Provisions of part 60,
Methods 3A and 19 would be added to
the list of methods not requiring the use
of audit samples in § 60.8(gd). Method
3A is a direct measurement
instrumental method which the audit
program does not evaluate, and Method
19 deals with calculation procedures in
lieu of measurement procedures.
A new § 60.8(h) would be added to
require that sampling sites be evaluated
for cyclonic flow and stratification
before testing. Cyclonic flow and gas
stratification has not been adequately
addressed in the past except for
particulate measurement methods. Our
experience has been that gaseous
pollutant measurements may also be
affected by these phenomena.
Procedures currently used in Methods 1
and 7E would be referenced for all tests
to evaluate the suitability of test
locations and give procedures for testing
under conditions of gas stratification
and cyclonic flow to preclude nonrepresentative sampling.
A new § 60.8(i) would be added to
allow the use of Method 205 of 40 CFR
part 51, Appendix M, ‘‘Verification of
Gas Dilution Systems for Field
Instrument Calibrations,’’ as an
alternative provision whenever the use
of multiple calibration gases is required
under Part 60. Method 205 has
previously been allowed for different
applications on a case-by-case basis.
Method 205 reduces the number of
cylinder gases needed for a test by
allowing lower-concentration gases to
be generated from a high-level gas.
Section 60.13(d)(1) would be revised to
remove the phrase ‘‘automatically,
intrinsic to the opacity monitor’’ which
was incorrectly inserted into the
paragraph in a past revision. The title of
an organization in a method that is
incorporated by reference would be
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updated in § 60.17(e), and the edition of
the method referred to in § 60.17(e)(1)
would be updated to reflect the
currently available version.
E. Industrial-Commercial-Institutional
Steam Generating Units (Subpart Db)
Part 60
In subpart Db, Method 320 would be
added as an alternative to the methods
for determining nitrogen oxides (NOX)
concentration in § 60.46b(f)(1)(ii), (h)(1)
and (2), and sulfur dioxide (SO2)
concentration in § 60.47b(b)(2). The EPA
has allowed the use of Method 320 in
the past on a case-by-case basis and now
believes it is appropriate for general use.
F. Hospital/Medical/Infectious Waste
Incinerators (Subpart Ec) Part 60
In subpart Ec, the definition of
medical/infectious wastes in § 60.51c
would be revised to correct the
misspelling of ‘‘cremation.’’
G. Sulfuric Acid Plants (Subpart H) Part
60
In Subpart H, an equation for
calculating the SO2 emission rate in
§ 60.84(d) would be corrected.
H. Sewage Treatment Plants (Subpart O)
Part 60
In subpart O, a reference to Method
209F in § 60.154(b)(5) would be revised
to reflect a newer available version of
the method (i.e., 2540G).
I. Kraft Pulp Mills (Subpart BB) Part 60
In subpart BB, a typographical error in
the equation in § 60.284(c)(3) would be
corrected.
J. Stationary Gas Turbines (Subpart GG)
Part 60
In subpart GG, the definitions of terms
for the equation in § 60.335(b)(l) would
be revised to allow the reference
combustor inlet absolute pressure to be
measured in millimeters of mercury
(mm Hg). Using the site barometric
pressure gives comparable results to the
observed combustor inlet absolute
pressure for calculating the mean NOX
emission concentration and would be
allowed as an alternative.
K. Lead-Acid Battery Manufacturing
Plants (Subpart KK) Part 60
In subpart KK, Method 29 would be
added as an alternative to Method 12 in
§ 60.374(b)(1)and (c)(2) for determining
the lead concentration and flow rate of
the effluent gas. Method 29 is an
accepted method for determining lead
under other rules and is appropriate for
this subpart as well. Also, an error in
the equation for calculating the lead
emission concentration in 60.374(b)(2)
would be corrected.
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L. Metallic Mineral Processing Plants
(Subpart LL) Part 60
In subpart LL, an error in the value of
the particulate matter standard in
§ 60.382(a)(1) would be corrected from
0.02 g/dscm to 0.05 g/dscm. An
alternative procedure, where a single
visible emission observer may conduct
visible emission observations for up to
three fugitive, stack, or vent emission
points within a 15-second interval,
would be added to § 60.386. This
alternative would allow the observer to
take readings in a more cost-effective
and timely manner than currently
allowed.
M. Asphalt Processing and Asphalt
Roofing Manufacture (Subpart UU) Part
60
In subpart UU, an error in the value
of the particulate matter standard for
saturated felt or smooth-surfaced roll
roofing in § 60.472(a)(1)(ii) would be
corrected from 0.04 kg/Mg to 0.4 kg/Mg.
N. Volatile Organic Compound (VOC)
Emissions From Synthetic Organic
Chemical Manufacturing Industry
(SOCMI) Distillation Operations
(Subpart NNN) Part 60
In subpart NNN, several paragraphs
were renumbered in a previous
amendment, but conforming changes in
sections that referenced these
paragraphs were not made. In
§ 60.660(c)(4) and § 60.665(h)(2) and (3),
these references would be corrected.
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O. Stationary Compression Ignition
Internal Combustion Engines (Subpart
IIII) Part 60
In Subpart IIII, the use of Method 1 or
1A for sampling point selection would
be dropped, and single-point sampling
at the centroid of the exhaust would be
added. The exhausts of most regulated
engines are too small and not equipped
with sampling ports. This makes it
difficult to divide the exhaust into
multiple sampling-point locations as
required by Methods 1 and 1A. Table 7
would be revised to delete the
requirement to use Method 1 or 1A.
P. Stationary Spark Ignition Internal
Combustion Engines (Subpart JJJJ) Part
60
In Subpart JJJJ, the exhausts of most
regulated engines do not contain
sampling ports and are too small to be
subdivided into multiple samplingpoint locations. Table 2 would be
revised to delete the requirement to use
Method 1 or 1A for determining
sampling site and sampling-point
location, and instruction would be
added to sample at the centroid of the
exhaust.
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Q. Method 1 of Appendix A–1 of Part 60
In Method 1, Section 11.2.2 would be
clarified to note that it specifically
applies to gaseous measurements. The
provisions in the section for
determining exhaust gas stratification
would be streamlined to make them
consistent with the new stratification
provisions in Method 7E. Figures 1–1
and 1–2 would be clarified to note that
the horizontal coordinates represent the
duct diameters from the sampling point
to the flow disturbance and not simply
the duct diameters from the flow
disturbance. Figure 1–2 would also be
corrected to show the proper
demarcation between the requirement
for 12 and 16 sampling points. The test
for the presence or absence of cyclonic
flow would be required for all tests
instead of recommended at sites
suspected of having cyclonic flow.
R. Method 2 of Appendix A–1 of Part 60
In Method 2, a pressure stability
specification that has been lacking for
the pitot tube leak-check would be
added to clearly note the desired
stability. An erroneous reference to a
Figure 2–6B would be corrected to
reference Figure 2–7B. An error in a
term in the denominator of Equation 2–
7 would be corrected to the average of
the square root of delta P rather than the
square root of the average delta P. The
velocity constant in English units used
in Equation 2–7 would be corrected by
changing m/sec to ft/sec. The term for
absolute temperature in Equations 2–7
and 2–8 would be corrected to represent
the average of the absolute
temperatures; an inadvertently omitted
term would be added to Section 12.1 for
the average absolute temperature; and
calibrating a barometer against a NISTtraceable barometer would be added as
an alternative to calibrating against a
mercury barometer to facilitate the use
of mercury-free products.
S. Method 2A of Appendix A–1 of Part
60
In Method 2A, calibrating a barometer
against a NIST-traceable barometer
would be added as an alternative to
calibrating against a mercury barometer
to facilitate the use of mercury-free
products.
T. Method 2B of Appendix A–1 of Part
60
In Method 2B, nomenclature errors
would be corrected and the assumed
ambient carbon dioxide concentration
used in the calculations would be
changed from 300 to 380 ppm to closer
approximate current ambient levels.
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U. Method 2D of Appendix A–1 of Part
60
In Method 2D, calibrating a barometer
against a NIST-traceable barometer
would be added as an alternative to
calibrating against a mercury barometer
to facilitate the use of mercury-free
products.
V. Method 3A of Appendix A–2 of Part
60
In Method 3A, a redundant sentence
noting that pre-cleaned air may be used
for the high-level calibration gas would
be deleted.
W. Method 4 of Appendix A–3 of Part
60
In Method 4, the English value for the
leak rate exceedance in Section 9.1
would be corrected from 0.20 cfm to
0.020 cfm. Method 6A, Method 320, and
a calculation using F-factors would be
added as alternatives to Method 4 for
the moisture determination. These are
logical alternatives in cases where
Methods 6A and 320 are already being
used, and the F-factors approach can
save both time and expenses in some
cases.
X. Method 5 of Appendix A–3 of Part 60
In Method 5, a clarification would be
added that the deionized water used in
the analysis of material caught in the
impingers must have ≤0.001 percent
residue; the factor K would be corrected
to K’ in Equation 5–13; calibrating a
barometer against a NIST-traceable
barometer would be added as an
alternative to calibrating against a
mercury barometer to facilitate the use
of mercury-free products; calibrating a
temperature sensor against a
thermometer equivalent to a mercury-inglass thermometer would be added as an
alternative to calibrating against a
mercury-in-glass thermometer to
facilitate the use of mercury-free
products; rechecking temperature
sensors for the filter holder and
metering system after each test has been
found to be sufficient and would replace
having sensors calibrated within 3 °F;
the option to check the probe heater
calibration after a test at a single point
using a reference thermometer would be
added; the use of weather station
barometric pressure corrected to testing
point elevation would be added as an
option to having an on-site barometer;
mention of stopcock grease for air-tight
impinger seals would be deleted since it
is outdated and not often used; a smaller
acetone cleanup blank is determined
sufficient and a single blank per
container would be allowed in place of
a blank from each wash bottle; Section
10.3.3 would be clarified as a post-test
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metering system calibration check rather
than a metering system calibration, and
an alternative metering check procedure
would be added; the Isostack metering
system would be noted as an acceptable
system for determining sample flow
rates; the use of a Teflon filter holder
would be allowed without having to
obtain the Administrator’s approval
first; and Reference 13 for post-test
calibration would be added to the
method.
Y. Method 5A of Appendix A–3 of Part
60
In Method 5A, mercury-free
thermometers would be added as an
alternative to mercury-in-glass
thermometers to facilitate the use of
mercury-free products.
Z. Method 5E of Appendix A–3 of Part
60
In Method 5E, the use of the
Rosemount Model 2100A total organic
content analyzer would be replaced
with the Tekmar-Dohrmann or
equivalent analyzer, as neither the
Rosemount analyzer nor any similar
dual-injection analyzer is currently
manufactured. Also, Section 12.5
inadvertently labels the equation for
total particulate concentration as Eq.
5E–4, which would be corrected to Eq.
5E–5.
AA. Method 5H of Appendix A–3 of Part
60
In Method 5H, Section 12.1 would be
revised to add missing terms Ci, Co, Qi,
and Qo; and procedures for the
determination of an alternative tracer
gas flow rate would be added.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
BB. Method 6 of Appendix A–4 of Part
60
In Method 6, calibrating a temperature
sensor against a thermometer equivalent
to a mercury-in-glass thermometer
would be added as an alternative to
using a mercury-in-glass thermometer,
and calibrating a barometer against a
NIST-traceable barometer would be
added as an alternative to calibrating
against a mercury barometer. These
revisions would facilitate the use of
mercury-free products.
CC. Method 6C of Appendix A–4 of Part
60
In Section 4.0 of Method 6C, an
incorrect reference to Section 4.1 of
Method 6 would be corrected to
reference Section 4.0 of Method 7E.
Provisions that were removed from the
original method that addressed potential
quenching effects in fluorescence
analyzers would be added again. It was
previously believed that current
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fluorescence analyzers are not affected
by quenching effects; however, we were
informed that the provisions are still
needed in many cases.
DD. Method 7 of Appendix A–4 of Part
60
In Method 7, procedures would be
added to avoid biased results when
sampling under conditions of high SO2
concentrations; calibrating a barometer
against a NIST-traceable barometer
would be added as an alternative to
calibrating against a mercury barometer;
and calibrating a temperature sensor
against a thermometer equivalent to a
mercury-in-glass thermometer would be
added as an alternative to using a
mercury-in-glass thermometer. These
revisions would facilitate the use of
mercury-free products.
EE. Method 7A of Appendix A–4 of Part
60
In Method 7A, new procedures would
be added to avoid biased results when
sampling under conditions of high SO2
concentrations, and calibrating a
temperature sensor against a
thermometer equivalent to a mercury-inglass thermometer would be added as an
alternative to using a mercury-in-glass
thermometer to facilitate the use of
mercury-free products.
FF. Method 7E of Appendix A–4 of Part
60
In Method 7E, the instructions for
choosing the high-level calibration gas
would be clarified. Instructions would
be added to minimize contact of the
sample with any condensate to reduce
the chance of sample loss, and an error
in the traverse point locations used to
determine stratification across large
stacks would be corrected. A statement
noting that the stratification test is not
required at sources with temporally
varying emissions or low-concentration
emissions would be added since a
stratification test under such conditions
would be meaningless or difficult to
pass. The basis of a stable response for
measurements in the system response
time determination would be revised in
Section 8.2.5 to conform with Section
8.2.6. The response time reading would
be recorded after the concentration
reading has reached 95 percent or
within 0.5 ppm of a stable response for
the gas instead of after reaching 95
percent of the certified gas
concentration. This change removes a
potential conflict between the response
time stable reading criterion and the
bias or system calibration error test
criterion. Alternative sampling bags
made of materials other than Tedlar
would be allowed if the materials are
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applicable for retaining the compounds
of interest. Tedlar bags are no longer
being produced.
GG. Method 8 of Appendix A–4 of Part
60
In Method 8, corrections would be
made to errors in the sample aliquot
volumes required for containers 1 and 2
and in the values for Va and Vsoln. Figure
8–1 would be clarified to identify which
impingers collect sulfuric acid/sulfur
trioxide and which collect sulfur
dioxide.
HH. Method 10 of Appendix A–4 of Part
60
Method 10 would be revised to allow
the use of sample tanks as an alternative
to flexible bags for sample collection.
Tanks are an acceptable collection
medium, are currently allowed for
carbon monoxide in other EPA methods,
and are appropriate for Method 10 as
well.
II. Methods 10A and 10B of Appendix
A–4 of Part 60
In Methods 10A and 10B, sampling
bags made of materials other than
Tedlar would be allowed if the materials
have the sample retaining qualities of
Tedlar. Tedlar bags are no longer
produced.
JJ. Method 11 of Appendix A–5 of Part
60
Method 11 would be revised to
address sample breakthrough at high
concentrations. An additional collection
impinger would be added to the train
whenever the final impinger solution
exhibits a yellow color. Calibrating a
temperature sensor against a
thermometer equivalent to a mercury-inglass thermometer would be added as an
alternative to using a mercury-in-glass
thermometer to facilitate the use of
mercury-free products.
KK. Method 12 of Appendix A–5 of Part
60
Method 12 would be revised to allow
an analysis by inductively coupled
plasma-atomic emission spectrometry
(ICP–AES) or cold vapor atomic
fluorescence spectrometry (CVAFS) as
alternatives to atomic absorption (AA)
analysis. The ICP–AES is currently an
approved technique for lead analysis in
Method 29, and CVAFS offers
comparable sensitivity and precision to
AA.
LL. Method 14A of Appendix A–5 of
Part 60
In Section 10.1.1 of Method 14A, we
inadvertently referenced Figure 5–6.
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SS. Method 25D of Appendix A–7 of
Part 60
In Method 25D, errors in crossreferences within the method would be
corrected.
This reference would be corrected to
Figure 5–5.
MM. Method 16A of Appendix A–6 of
Part 60
In Method 16A, the applicability
section would note that method results
may be biased low if used at sources
other than kraft pulp mills where stack
oxygen levels may be lower.
NN. Method 18 of Appendix A–6 of Part
60
In Method 18, sampling bags made of
materials other than Tedlar would be
allowed if the materials are applicable
for retaining the compounds of interest.
Tedlar bags are no longer produced.
OO. Method 23 of Appendix A–7 of Part
60
In Method 23, the requirement in
Section 2.2.7 that silica gel be stored in
metal containers is unnecessary and
would be deleted. Section 4.2.7 would
be clarified to note that the used silica
gel should be transferred to its original
container or other suitable vessel if
moisture is being determined. If
moisture is not being determined, the
spent silica gel may be discarded.
Mercury-free thermometers would be
added as an alternative to using
mercury-in-glass thermometers to
facilitate the use of mercury-free
products.
PP. Method 24 of Appendix A–7 of Part
60
Method 24 would be revised to cite
only ASTM Method D2369 and not the
specific sections of the method, since
the section numbers may change with
periodic updates.
QQ. Method 25 of Appendix A–7 of Part
60
In Method 25, more detailed
information would be added to describe
the filters used for sample collection.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
RR. Method 25C of Appendix A–7 of
Part 60
Method 25C would be revised to
allow sampling lines made of Teflon.
Probes that have closed points and are
driven below surface in a single step
and withdrawn at a distance to create a
gas gap would be allowed as acceptable
substitutes to using pilot probes and the
auger procedure. An equation for
correcting the sample nitrogen
concentration for tank dilution would
be added as a supplemental calculation
option.
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TT. Method 26 of Appendix A–8 of Part
60
Method 26 would be revised to allow
the use of heated Teflon probes in place
of glass-lined probes. Conflicting
temperature requirements for the
sampling system would be clarified. The
note to keep the probe and filter
temperature at least 20 °C above the
source temperature would be removed
because the specification is not needed
at higher temperature stacks. The
location of the thermocouple that
monitors the collected gas temperature
would be clarified as being in the gas
stream, not the filter box. Method 26A
would be an acceptable alternative to
Method 26 since the methods are
fundamentally similar and give
comparable results when determining
non-particulate hydrogen halides.
UU. Method 29 of Appendix A–8 of Part
60
Method 29 would be revised to allow
samples to be analyzed by CVAFS as an
alternative to AA analysis since CVAFS
is as sensitive and precise as AA.
VV. Method 30B of Appendix A–8 of
Part 60
In Method 30B, calibrating a
barometer against a NIST-traceable
barometer would be added as an
alternative to calibrating against a
mercury barometer to facilitate the use
of mercury-free products.
Table 9–1 and the method text would
be revised to amend the quality
assurance/quality control criteria for
sorbent trap section 2 breakthrough and
sample analysis. These revisions would
address compliance testing and relative
accuracy testing of mercury monitoring
systems currently being conducted at
much lower emission concentrations.
For compliance/emissions testing, the
specification in Table 9–1 for sample
analysis would be revised to require
analytical results be within the valid
calibration range down to a
concentration of 0.01 mg/dscm. This will
ensure that measurements at the low
levels being measured under recent
rulemakings are of known, acceptable,
and consistent quality. For relative
accuracy testing of mercury monitoring
systems, the sample analysis
specification in Table 9–1 would remain
the same, but the breakthrough criteria
for second section in the sorbent traps
would be revised to provide additional
flexibility where mercury
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concentrations are less than 0.5 mg/
dscm.
Finally, Method 30B would be revised
to include the most up to date citation
for determining the method detection
limit or MDL.
WW. Performance Specification 1 of
Appendix B of Part 60
In Performance Specification 1, the
terms ‘‘full scale’’ and ‘‘span’’ would be
noted as having the same meaning.
XX. Performance Specification 3 of
Appendix B of Part 60
In Performance Specification 3, a
statement that allows the relative
accuracy to be within 20 percent of the
reference method would be added to
establish the original intent of the rule.
This statement was inadvertently
deleted in a previous amendment.
YY. Performance Specification 4 of
Appendix B of Part 60
Performance Specification 4 would be
revised to remove the required use of
the interference trap specified in
Method 10 when evaluating nondispersive infrared continuous emission
monitoring systems against Method 10.
This is an old requirement, and the trap
is not needed with modern analyzers.
ZZ. Performance Specification 4B of
Appendix B of Part 60
Performance Specification 4B would
be clarified to note that Equation 1 in
Section 7.1.1 for calculating calibration
error only applies to the carbon
monoxide monitor and not the oxygen
monitor. It would be noted for the
oxygen monitor that the calibration
error should be expressed as the oxygen
concentration difference between the
mean monitor and reference value at
three levels.
AAA. Performance Specification 7 of
Appendix B of Part 60
Performance Specification 7 would be
revised to allow Methods 15 and 16 as
reference methods in addition to
Method 11. Methods 15 and 16 are
approved for determining hydrogen
sulfide and are appropriate for this
application. Methods 15 and 16 are
approved EPA reference methods for a
number of sources. A pertinent
reference would also be added to the
references section.
BBB. Performance Specification 11 of
Appendix B of Part 60
In Performance Specification 11,
errors in the denominators of Equations
11–1 and 11–2 would be corrected.
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CCC. Performance Specification 15 of
Appendix B of Part 60
methods were inadvertently omitted in
the original rule.
In Performance Specification 15, the
general references to 40 CFR part 60,
Appendix B for the relative accuracy
analysis procedure would specifically
cite Performance Specification 2 of 40
CFR part 60, Appendix B.
III. Beryllium (Subpart C) Part 61
DDD. Performance Specification 16 of
Appendix B of Part 60
Performance Specification 16 would
be clarified to answer questions that
have arisen since its publication.
Retesting a predictive emission
monitoring system (PEMS) after a sensor
is replaced would be explained more
clearly. Allowances would be made for
relative accuracy testing at three load or
production rate levels in cases where
the key operating parameter could not
be readily altered. Additional
instruction would be added for
performing the relative accuracy audit
(RAA). An error in the RAA acceptance
criterion would be corrected, and an
alternative acceptance criterion for low
concentration measurements would be
added. The yearly relative accuracy test
audit would clearly note that the
statistical tests in Section 8.3 are not
required. An incorrect reference to
Equation 16–4 in Section 12.4 would be
corrected.
EEE. Procedure 1 of Appendix F of Part
60
In Procedure 1, the relevant
performance specification would be
cited for the RAA calculation instead of
using the current Equation 1–1 which is
not appropriate for all pollutants.
FFF. Procedure 2 of Appendix F of Part
60
In Procedure 2, Equations 2–2 and 2–
3 would be revised to have the full-scale
value in the denominator, which is
more appropriate than the up-scale
check value. The denominator of
equation 2–4 would be revised to
include the volume of the reference
device rather than the full-scale value.
These revisions reflect the original
intent of the rule.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
GGG. Procedure 5 of Appendix F of Part
60
In Procedure 5, the second section
listed as Section 6.2.6 would be
correctly numbered as Section 6.2.7.
HHH. General Provisions (Subpart A)
Part 61
In the General Provisions of part 61,
Methods 3A and 19 would be added to
the list of methods not requiring the use
of audit samples in § 61.13(e). These
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In the beryllium National Emission
Standards for Hazardous Air Pollutants
(NESHAP), Method 29 of part 60 would
be added as an alternative to Method
104 in § 61.33(a) for emissions testing
since Method 29 is used to determine
beryllium under other rules and is
appropriate for this subpart as well.
JJJ. Beryllium Rocket Motor Firing
(Subpart D) Part 61
In the beryllium rocket motor firing
NESHAP, a conversion error in the
emission standard in § 61.42(a) would
be corrected.
KKK. Mercury (Subpart E) Part 61
In the mercury NESHAP, Method 29
of part 60 would be added as an
alternative to Method 101A in
§ 61.53(d)(2) for emissions testing since
Method 29 is used to determine mercury
under other rules and is appropriate for
this subpart as well.
LLL. Inorganic Arsenic Emissions From
Glass Manufacturing Plants (Subpart N)
Part 61
In the glass manufacturing plants
NESHAP, Method 29 in Appendix A of
part 60 would be added as an alternative
to Method 108 in § 61.164(d)(2)(i) for
determining the arsenic emissions rate
and in § 61.164(e)(1)(i) and (e)(2) for
determining the arsenic concentration
in a gas stream. Method 29 is used to
determine arsenic under other rules and
is appropriate for this subpart as well.
MMM. Method 101 of Appendix B of
Part 61
Method 101 would be revised to allow
analysis by ICP–AES or CVAFS as
alternatives to AA analysis. These
techniques are allowed for determining
mercury in other approved methods and
are appropriate for Method 101 as well.
They were not available when Method
101 was promulgated.
NNN. Method 101A of Appendix B of
Part 61
Method 101A would be revised to
allow analysis by ICP–AES or CVAFS as
alternatives to AA analysis. These
techniques are allowed for determining
mercury in other approved methods and
are appropriate for Method 101A as
well. They were not available when
Method 101A was promulgated.
OOO. Method 102 of Appendix B of Part
61
In Method 102, mercury-free
thermometers would be allowed in
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place of mercury-in-glass thermometers
to facilitate the use of mercury-free
products.
PPP. Method 104 of Appendix B of Part
61
Method 104 would be revised to allow
analysis by ICP–AES as an alternative to
AA analysis. This new technique is
acceptable for measuring beryllium and
was not available when Method 104 was
promulgated. A new alternative
procedures section would be added to
address ICP–AES.
QQQ. Methods 108 and 108A of
Appendix B of Part 61
Methods 108 and 108A would be
revised to allow analysis by ICP–AES as
an alternative to AA analysis. This new
technique is acceptable for measuring
arsenic and was not available when
Methods 108 and 108A were
promulgated. A new alternative
procedures section would be added to
address ICP–AES.
RRR. General Provisions (Subpart A)
Part 63
In the General Provisions of part 63,
Methods 3A and 19 would be added to
the list of methods not requiring the use
of audit samples in § 63.7(c). These were
inadvertent omissions of the original
rule. In § 63.8(f)(6)(iii), an incorrect
reference to a section of Performance
Specification 2 would be corrected.
SSS. Synthetic Organic Chemical
Manufacturing Industry (Subpart G)
Part 63
Subpart G would be revised to allow
the use of Method 8260B in the SW–846
Compendium of Methods or Method
316 to determine hazardous air
pollutant concentrations in wastewater
streams in § 63.144(b)(5)(i). Both
methods are appropriate for this
application but were not considered
during the original rule development.
TTT. Chromium Emissions From Hard
and Decorative Chromium
Electroplating and Chromium
Anodizing Tanks (Subpart N) Part 63
South Coast Air Quality Management
District Method 205.1 would be added
as a testing option for measuring total
chromium. Method 205.1 is appropriate
for this application, but its application
to this rule was not considered during
the original rule development.
UUU. Ethylene Oxide Emissions
Standards for Sterilization Facilities
(Subpart O) Part 63
The ethylene oxide emissions
standards for sterilization facilities
NESHAP would be revised to allow
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California Air Resources Board (CARB)
Method 431 as an alternative to the
procedures in § 63.365(b) for
determining efficiency at the
sterilization chamber vent. Method 431
is appropriate for this application but
was not considered during the original
rule development. An error in a
reference to a section in Performance
Specification 8 would also be corrected.
VVV. Marine Tank Vessel Loading
Operations (Subpart Y) Part 63
The marine tank vessel loading
operations NESHAP would be revised to
allow Method 25B as an alternative to
Method 25A in § 63.565(d)(5) for
determining the average volatile organic
compound (VOC) concentration
upstream and downstream of recovery
devices. Method 25B would be allowed
as an alternative to Methods 25 and 25A
for determining the percent reduction in
VOC in § 63.565(d)(8), and the
requirement that Method 25B be
validated according to Method 301 in
§ 63.565(d)(10) would be added. Method
25B would also be added as an
alternative to Method 25A in
determining the baseline outlet VOC
concentration in § 63.565(g). Method
25B uses a different detector than
Method 25A but gives comparable
results to Method 25A in these
applications.
WWW. Aerospace Manufacturing and
Rework Facilities (Subpart GG) Part 63
The aerospace manufacturing and
rework facilities NESHAP would be
revised to remove an incorrect reference
to the location of Method 319 in
§ 63.750(o).
XXX. Pharmaceuticals Production
(Subpart GGG) Part 63
The pharmaceuticals production
NESHAP would be revised to allow
Method 320 as an alternative to Method
18 for demonstrating that a vent is not
a process vent. Method 320 is a broadly
applicable method that is acceptable in
this application because it is selfvalidating.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
YYY. Secondary Aluminum Production
(Subpart RRR) Part 63
The secondary aluminum production
NESHAP would be revised to allow
Method 26 as an alternative to Method
26A in § 63.1511(c)(9) for determining
hydrochloric acid (HCl) concentration.
Method 26 is the non-isokinetic version
of Method 26A and is being allowed in
all cases where non-isokinetic sampling
for HCl is performed.
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ZZZ. Manufacturing of Nutritional
Yeast (Subpart CCCC) Part 63
EEEE. Methods 308, 315, and 316 of
Appendix A of Part 63
Table 2 in the manufacturing of
nutritional yeast NESHAP would be
revised to delete the requirements to use
Methods 1, 2, 3, and 4 when measuring
VOC by Method 25A. Methods 1, 2, 3,
and 4 are required for particulate matter
sampling and the VOC in this
application is normally not particulate
in nature.
In Methods 308, 315, and 316,
calibrating a temperature sensor against
a thermometer equivalent to a mercuryin-glass thermometer would be added as
an alternative to mercury-in-glass
thermometers to facilitate the use of
non-mercury products. Alternative
mercury-free thermometers would be
added as an alternative to using a
mercury-in-glass thermometers.
AAAA. Petroleum Refineries: Catalytic
Cracking Units, Catalytic Reforming
Units, and Sulfur Recovery Units
(Subpart UUUU) Part 63
Table 4 in the petroleum refineries:
catalytic cracking units, catalytic
reforming units, and sulfur recovery
units NESHAP would be revised to
allow Method 320 as an alternative to
Method 18 for determining control
device efficiency for organic
compounds. Method 320 is a broadly
applicable method that is acceptable in
this application because it is selfvalidating.
BBBB. Stationary Reciprocating Internal
Combustion Engines (Subpart ZZZZ)
Part 63
Table 4 in the stationary reciprocating
internal combustion engines NESHAP
would be revised to clarify that a heated
probe is not necessary when using
ASTM D6522 to measure oxygen or
carbon dioxide concentrations because
condensed moisture is normally not an
interferent to these compounds. The
requirement to use Method 1 or 1A for
sampling site and sampling point
location would be deleted because the
exhausts are small and have temporally
varying emissions. Instruction would be
added to sample at the centroid of the
stack.
CCCC. Method 306 of Appendix A of
Part 63
Method 306 would be revised to
remove references to two figures that do
not exist and to add clarifying
information about the conditions under
which ICP is appropriate for sample
analysis. Alternative mercury-free
thermometers also would be added as
alternatives to mercury-in-glass
thermometers to facilitate the use of
mercury-free products.
DDDD. Method 306A of Appendix A of
Part 63
In Method 306A, information would
be added to clarify the conditions under
which sample filtering is required.
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FFFF. Method 321 of Appendix A of
Part 63
In Method 321, the term for dilution
factor in the calculations would be
clarified.
IV. Request for Comments
The agency is reviewing the adequacy
of its current test methods in regard to
sampling site selection and sampling
point requirements. Emission gas flow
patterns affect representative testing,
and this is not addressed in many EPA
test methods. Method 1 contains
provisions for sampling point locations,
traversing, and determination of
cyclonic flow, and Method 7E was
revised to contain procedures for
determining gaseous stratification in
2006. However, there are no
requirements in most methods to follow
the Method 1 or 7E procedures.
Method 7E allows stratification to be
assessed through either a 3- or 12-point
traverse while measuring variations in
either a pollutant or diluent
concentration. The degree of
stratification determines whether a
single-point, 3-, or 12-point traverse is
used for the test. There are no
requirements to check for cyclonic flow
in Method 7E.
We have information that suggests
deficiencies exist in the 3-point test in
a number of cases and that at least a 5point, dual axis test should be required.
A summary of this information has been
included in the regulatory docket. We
are also reconsidering the
appropriateness of a diluent gas for the
test instead of the regulated pollutant.
In this proposed rule, we would
update the General Provisions of Parts
60, 61, and 63 to include evaluations of
gas stratification and cyclonic flow with
all compliance tests. The agency solicits
your comments and data to aid in
establishing better procedures.
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V. Statutory and Executive Order
Reviews
A. Executive Order 12866: Regulatory
Planning and Review and Executive
Order 13563: Improving Regulation and
Regulatory Review
This action is not a ‘‘significant
regulatory action’’ under the terms of
Executive Order (EO) 12866 (58 FR
51735, October 4, 1993) and is therefore
not subject to review under Executive
Orders 12866 and 13563 (76 FR 3821,
January 21, 2011).
tkelley on DSK3SPTVN1PROD with PROPOSALS2
B. Paperwork Reduction Act
This action does not impose an
information collection burden under the
provisions of the Paperwork Reduction
Act, 44 U.S.C. 3501 et seq. Burden is
defined at 5 CFR 1320.3(b). The
amendments being proposed in this
action to the test methods and testing
regulations do not add information
collection requirements but make
needed corrections and updates to
existing testing methodology.
C. Regulatory Flexibility Act
The Regulatory Flexibility Act (RFA)
generally requires an agency to prepare
a regulatory flexibility analysis of any
rule subject to notice and comment
rulemaking requirements under the
Administrative Procedure Act or any
other statute unless the agency certifies
that the rule will not have a significant
economic impact on a substantial
number of small entities. Small entities
include small businesses, small
organizations, and small governmental
jurisdictions.
For purposes of assessing the impacts
of this rule on small entities, small
entity is defined as (1) A small business
as defined by the Small Business
Administration’s (SBA) regulations at 13
CFR 121.201; (2) a small governmental
jurisdiction that is a government of a
city, county, town, school district or
special district with a population of less
than 50,000; and (3) a small
organization that is any not-for-profit
enterprise which is independently
owned and operated and is not
dominant in its field.
After considering the economic
impacts of this rule on small entities, I
certify that this action will not have a
significant economic impact on a
substantial number of small entities.
This proposed rule will neither impose
emission measurement requirements
beyond those specified in the current
regulations, nor will it change any
emission standard. This proposed action
will not impose any new requirements
on small entities. We continue to be
interested in the potential impacts of the
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proposed rule on small entities and
welcome comments on issues related to
such impacts.
D. Unfunded Mandates Reform Act
This action contains no Federal
mandates under the provisions of Title
II of the Unfunded Mandates Reform
Act of 1995 (UMRA), 2 U.S.C. 1531–
1538 for State, local, or tribal
governments or the private sector. The
action imposes no enforceable duty on
any State, local or tribal governments or
the private sector. Therefore, this action
is not subject to the requirements of
sections 202 or 205 of the UMRA. This
action is also not subject to the
requirements of section 203 of UMRA
because it contains no regulatory
requirements that might significantly or
uniquely affect small governments. This
action corrects and updates current
testing regulations and does not add any
new requirements.
E. Executive Order 13132: Federalism
This action does not have federalism
implications. It will not have substantial
direct effects on the States, on the
relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government, as specified in
Executive Order 13132. This action
simply corrects minor errors and makes
updates to current source testing
methods to maintain their original
intent. Thus, Executive Order 13132
does not apply to this action. In the
spirit of Executive Order 13132, and
consistent with the EPA policy to
promote communications between the
EPA and State and local governments,
the EPA specifically solicits comment
on this proposed rule from State and
local officials.
F. Executive Order 13175: Consultation
and Coordination With Indian Tribal
Governments
This action does not have tribal
implications, as specified in Executive
Order 13175 (65 FR 67249, November 9,
2000). This proposed rule imposes no
requirements on tribal governments.
This action simply corrects and updates
current testing regulations. Thus,
Executive Order 13175 does not apply
to this action. The EPA specifically
solicits additional comment on this
proposed action from tribal officials.
G. Executive Order 13045: Protection of
Children From Environmental Health
and Safety Risks
The EPA interprets EO 13045 (62 FR
19885, April 23, 1997) as applying only
to those regulatory actions that concern
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health or safety risks, such that the
analysis required under section 5–501 of
the EO has the potential to influence the
regulation. This action is not subject to
EO 13045 because it does not establish
an environmental standard intended to
mitigate health or safety risks.
H. Executive Order 13211: Actions
Concerning Regulations That
Significantly Affect Energy Supply,
Distribution, or Use
This action is not subject to Executive
Order 13211 (66 FR 28355 (May 22,
2001)), because it is not a significant
regulatory action under Executive Order
12866.
I. National Technology Transfer and
Advancement Act
Section 12(d) of the National
Technology Transfer and Advancement
Act of 1995 (‘‘NTTAA’’), Public Law
104–113 (15 U.S.C. 272 note) directs the
EPA to use voluntary consensus
standards in its regulatory activities
unless to do so would be inconsistent
with applicable law or otherwise
impractical. Voluntary consensus
standards are technical standards (e.g.,
materials specifications, test methods,
sampling procedures, and business
practices) that are developed or adopted
by voluntary consensus standards
bodies. NTTAA directs the EPA to
provide Congress, through OMB,
explanations when the Agency decides
not to use available and applicable
voluntary consensus standards.
This proposed rulemaking involves
technical standards. The EPA proposes
to use ASTM D975–076, developed and
adopted by the American Society for
Testing and Materials (ASTM). This
standard may be obtained from ASTM at
100 Barr Harbor Drive, P.O. Box C700,
West Conshohocken, PA 19428–2959.
ASTM D975–076 has been determined
to be at least as stringent as currently
required ASTM D396 for defining
‘‘distillate oil.’’ ASTM D975–076 is
required in some State permits for this
purpose and end users have asked that
it be allowed as an alternative to D396
under 40 CFR 60.41c.
J. Executive Order 12898: Federal
Actions To Address Environmental
Justice in Minority Populations and
Low-Income Populations
Executive Order (EO) 12898 (59 FR
7629 (Feb. 16, 1994)) establishes Federal
executive policy on environmental
justice. Its main provision directs
Federal agencies, to the greatest extent
practicable and permitted by law, to
make environmental justice part of their
mission by identifying and addressing,
as appropriate, disproportionately high
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and adverse human health or
environmental effects of their programs,
policies, and activities on minority
populations and low-income
populations in the United States.
The EPA has determined that this
proposed rule will not have
disproportionately high and adverse
human health or environmental effects
on minority or low-income populations
because it does not affect the level of
protection provided to human health or
the environment. This rule corrects and
updates current testing regulations and
does not cause emission increases from
regulated sources.
Revisions to Test Methods and Testing
Regulations
List of Subjects in 40 CFR Parts 51, 60,
61, and 63
Environmental protection, Air
pollution control, Test methods and
procedures, and Performance
specifications.
Dated: November 29, 2011.
Lisa P. Jackson,
Administrator.
For the reasons stated in the
preamble, the Environmental Protection
Agency proposes to amend title 40,
chapter I of the Code of Federal
Regulations as follows:
PART 51—REQUIREMENTS FOR
PREPARATION, ADOPTION, AND
SUBMITTAL OF IMPLEMENTATION
PLANS
1. The authority citation for part 51
continues to read as follows:
Authority: 23 U.S.C. 101; 42 U.S.C. 7401–
7671q.
2. Amend Appendix M by revising
section 4a. to read as follows:
Appendix M to Part 51—Recommended
Test Methods for State Implementation
Plans
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4. * * *
a. The source owner, operator, or
representative of the tested facility shall
obtain an audit sample, if commercially
available, from an AASP for each test method
used for regulatory compliance purposes. No
audit samples are required for the following
test methods: Methods 3A and 3C of
Appendix A–3 of Part 60, Methods 6C, 7E,
9, and 10 of Appendix A–4 of Part 60,
Methods 18 and 19 of Appendix A–6 of Part
60, Methods 20, 22, and 25A of Appendix A–
7 of Part 60, and Methods 303, 318, 320, and
321 of Appendix A of Part 63. If multiple
sources at a single facility are tested during
a compliance test event, only one audit
sample is required for each method used
during a compliance test. The compliance
authority responsible for the compliance test
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may waive the requirement to include an
audit sample if they believe that an audit
sample is not necessary. ‘‘Commercially
available’’ means that two or more
independent AASPs have blind audit
samples available for purchase. If the source
owner, operator, or representative cannot
find an audit sample for a specific method,
the owner, operator, or representative shall
consult the EPA Web site at the following
URL, https://www.epa.gov/ttn/emc, to confirm
whether there is a source that can supply an
audit sample for that method. If the EPA Web
site does not list an available audit sample
at least 60 days prior to the beginning of the
compliance test, the source owner, operator,
or representative shall not be required to
include an audit sample as part of the quality
assurance program for the compliance test.
When ordering an audit sample, the source
owner, operator, or representative shall give
the sample provider an estimate for the
concentration of each pollutant that is
emitted by the source or the estimated
concentration of each pollutant based on the
permitted level and the name, address, and
phone number of the compliance authority.
The source owner, operator, or representative
shall report the results for the audit sample
along with a summary of the emission test
results for the audited pollutant to the
compliance authority and shall report the
results of the audit sample to the AASP. The
source owner, operator, or representative
shall make both reports at the same time and
in the same manner or shall report to the
compliance authority first and report to the
AASP. If the method being audited is a
method that allows the samples to be
analyzed in the field and the tester plans to
analyze the samples in the field, the tester
may analyze the audit samples prior to
collecting the emission samples provided a
representative of the compliance authority is
present at the testing site. The tester may
request and the compliance authority may
grant a waiver to the requirement that a
representative of the compliance authority
must be present at the testing site during the
field analysis of an audit sample. The source
owner, operator, or representative may report
the results of the audit sample to the
compliance authority and then report the
results of the audit sample to the AASP prior
to collecting any emission samples. The test
protocol and final test report shall document
whether an audit sample was ordered and
utilized and the pass/fail results as
applicable.
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3. Amend Method 201A of Appendix
M as follows:
a. By revising sections 8.3.4(b) and
8.3.4.1.
b. By revising sections 8.7.2.2 and
8.7.5.5(a).
c. By revising the introductory text of
section 10.1.
d. By revising section 11.2.1.
e. By revising Equation 9 in section
12.5.
f. By removing section 10.5.
g. By removing the term ‘‘Vb’’ and its
definition from section 12.1.
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Method 201A—Determination of PM10
and PM2.5 Emissions From Stationary
Sources (Constant Sampling Rate
Procedure)
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8.3.4 * * *
(b) The appropriate nozzle to maintain the
required gas sampling rate for the velocity
pressure range and isokinetic range. If the
isokinetic range cannot be met (e.g., batch
processes, extreme process flow or
temperature variation), void the sample or
use methods subject to the approval of the
Administrator to correct the data. The
acceptable variation from isokinetic sampling
is 80 to 120 percent and no more than 100
± 21 percent (2 out of 12 or 5 out of 24)
sampling points outside of this criteria.
*
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8.3.4.1 Preliminary traverse. You must
use an S-type pitot tube with a conventional
thermocouple to conduct the traverse.
Conduct the preliminary traverse as close as
possible to the anticipated testing time on
sources that are subject to hour-by-hour gas
flow rate variations of approximately ± 20
percent and/or gas temperature variations of
approximately ± 10 °C (± 18; °F). (Note: You
should be aware that these variations can
cause errors in the cyclone cut diameters and
the isokinetic sampling velocities.)
*
*
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*
8.7.2.2 Probe blockage factor. You must
use Equation 26 to calculate an average probe
blockage correction factor (bf) if the diameter
of your stack or duct is between 25.7 and
36.4 inches for the combined PM2.5/PM10
sampling head and pitot and between 18.8
and 26.5 inches for the PM2.5 cyclone and
pitot. A probe blockage factor is calculated
because of the flow blockage caused by the
relatively large cross-sectional area of the
cyclone sampling head, as discussed in
Section 8.3.2.2 and illustrated in Figures 8
and 9 of Section 17. You must determine the
cross-sectional area of the cyclone head you
use and determine its stack blockage factor.
(Note: Commercially-available sampling
heads (including the PM10 cyclone, PM2.5
cyclone, pitot and filter holder) have a
projected area of approximately 31.2 square
inches when oriented into the gas stream. As
the probe is moved from the outermost to the
innermost point, the amount of blockage that
actually occurs ranges from approximately 13
square inches to the full 31.2 inches plus the
blockage caused by the probe extension. The
average cross-sectional area blocked is 22
square inches.
*
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8.7.5.5 * * *
(a) Container #1, Less than or equal to
PM2.5 micrometer filterable particulate. Use
tweezers and/or clean disposable surgical
gloves to remove the filter from the filter
holder. Place the filter in the Petri dish that
you labeled with the test identification and
Container #1. Using a dry brush and/or a
sharp-edged blade, carefully transfer any PM
and/or filter fibers that adhere to the filter
holder gasket or filter support screen to the
Petri dish. Seal the container. This container
holds particles less than or equal to 2.5
micrometers that are caught on the in-stack
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10.1 Gas Flow Velocities. You must use
an S-type pitot tube that meets the required
EPA specifications (EPA Publication 600/4–
77–0217b) during these velocity
measurements. (NOTE: If, as specified in
Section 8.7.2.3, testing is performed in stacks
less than 26.5 inches in diameter, testers may
use a standard pitot tube according to the
requirements in Method 1 or 2 of Appendix
*
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4. Amend Method 202 of Appendix M
as follows:
a. By revising the introductory text in
section 8.5.3.1.
b. By revising section 11.2.2.
c. By revising Figures 2, 3, 4, 5, and
6 in section 18.0.
Method 202—Dry Impinger Method for
Determining Condensable Particulate
Emissions from Stationary Sources
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8.5.3.1 If you choose to conduct a
pressurized nitrogen purge on the complete
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A–3 to Part 60.) You must also complete the
following:
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11.2.1 Container #1, Less than or Equal to
PM2.5 Micrometer Filterable Particulate.
Transfer the filter and any loose particulate
from the sample container to a tared
weighing dish or pan that is inert to solvent
or mineral acids. Desiccate for 24 hours in a
desiccator containing anhydrous calcium
sulfate. Weigh to a constant weight and
report the results to the nearest 0.1 mg. (See
Section 3.0 for a definition of constant
weight.) If constant weight requirements
cannot be met, data should be reported and
flagged as a minimum value. (Note:
CPM sampling train, you may quantitatively
transfer the water collected in the condenser
and the water dropout impinger to the
backup impinger as an alternative to
replacing the short stem impinger insert with
a long stem insert prior to purging the
sampling train. You must measure the water
combined in the backup impinger and record
the volume or weight as part of the moisture
collected during sampling as specified in
Section 8.5.3.4.
*
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11.2.2 CPM Container #1, Aqueous
Liquid Impinger Contents. Analyze the water
soluble CPM in Container #1 as described in
this section. Place the contents of Container
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Regardless of the stack temperature, you are
not required to speciate the Method 201A
nozzle, front half or in-stack filter sample
into organic and inorganic fractions. Neither
Method 17 nor 201A require separate
analysis of the filter for inorganic and organic
PM. Since the in-stack filter samples
collected at ≤30 °C (85 °F) may include both
filterable insoluble particulate and
condensable particulate, the filter should be
weighed after desiccation but not extracted
since insoluble particulate will not be
recovered from the extraction.)
*
*
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*
*
12.5 * * *
For Nre greater than or equal to 3,162:
#1 into a separatory funnel. Add
approximately 30 ml of hexane to the funnel,
mix well, and pour off the upper organic
phase. Repeat this procedure twice with 30
ml of hexane each time combining the
organic phase from each extraction. Each
time, leave a small amount of the organic/
hexane phase in the separatory funnel,
ensuring that no water is collected in the
organic phase. This extraction should yield
about 90 ml of organic extract. Combine the
organic extract from Container #1 with the
organic train rinse in Container #2.
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BILLING CODE 6560–50–P
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filter. (Note: If the test is conducted for PM10
only, then Container #1 would be for less
than or equal to PM10 micrometer filterable
particulate.)
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1144
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BILLING CODE 6560–50–C
PART 60—STANDARDS OF
PERFORMANCE FOR NEW
STATIONARY SOURCES
5. The authority citation for part 60
continues to read as follows:
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Authority: 42 U.S.C. 7401, et seq.
6. Amend § 60.8 by revising paragraph
(g)(1) and adding new paragraphs (h)
and (i) to read as follows:
§ 60.8
Performance tests.
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(g) * * *
(1) The source owner, operator, or
representative of the tested facility shall
obtain an audit sample, if commercially
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available, from an AASP for each test
method used for regulatory compliance
purposes. No audit samples are required
for the following test methods: Methods
3A and 3C of Appendix A–3 of Part 60,
Methods 6C, 7E, 9, and 10 of Appendix
A–4 of Part 60, Methods 18 and 19 of
Appendix A–6 of Part 60, Methods 20,
22, and 25A of Appendix A–7 of Part
60, and Methods 303, 318, 320, and 321
of Appendix A of Part 63. If multiple
sources at a single facility are tested
during a compliance test event, only one
audit sample is required for each
method used during a compliance test.
The compliance authority responsible
for the compliance test may waive the
requirement to include an audit sample
if they believe that an audit sample is
not necessary. ‘‘Commercially
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available’’ means that two or more
independent AASPs have blind audit
samples available for purchase. If the
source owner, operator, or
representative cannot find an audit
sample for a specific method, the owner,
operator, or representative shall consult
the EPA Web site at the following URL,
www.epa.gov/ttn/emc, to confirm
whether there is a source that can
supply an audit sample for that method.
If the EPA Web site does not list an
available audit sample at least 60 days
prior to the beginning of the compliance
test, the source owner, operator, or
representative shall not be required to
include an audit sample as part of the
quality assurance program for the
compliance test. When ordering an
audit sample, the source owner,
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operator, or representative shall give the
sample provider an estimate for the
concentration of each pollutant that is
emitted by the source or the estimated
concentration of each pollutant based
on the permitted level and the name,
address, and phone number of the
compliance authority. The source
owner, operator, or representative shall
report the results for the audit sample
along with a summary of the emission
test results for the audited pollutant to
the compliance authority and shall
report the results of the audit sample to
the AASP. The source owner, operator,
or representative shall make both
reports at the same time and in the same
manner or shall report to the
compliance authority first and then
report to the AASP. If the method being
audited is a method that allows the
samples to be analyzed in the field and
the tester plans to analyze the samples
in the field, the tester may analyze the
audit samples prior to collecting the
emission samples provided a
representative of the compliance
authority is present at the testing site.
The tester may request, and the
compliance authority may grant, a
waiver to the requirement that a
representative of the compliance
authority must be present at the testing
site during the field analysis of an audit
sample. The source owner, operator, or
representative may report the results of
the audit sample to the compliance
authority and report the results of the
audit sample to the AASP prior to
collecting any emission samples. The
test protocol and final test report shall
document whether an audit sample was
ordered and utilized and the pass/fail
results as applicable.
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(h) Unless otherwise specified in the
applicable subpart, each test location
must be verified to be free of cyclonic
flow and evaluated for the existence of
emission gas stratification and the
required number of sampling traverse
points. If other procedures are not
specified in the applicable subpart to
the regulations, use the appropriate
procedures in Method 1 to check for
cyclonic flow and Method 7E to
evaluate emission gas stratification and
selection of sampling points.
(i) Whenever the use of multiple
calibration gases is required by a test
method, performance specification, or
quality assurance procedure in a Part 60
standard or appendix, Method 205 of 40
CFR part 51, Appendix M, ‘‘Verification
of Gas Dilution Systems for Field
Instrument Calibrations,’’ may be used.
7. Amend § 60.13 by revising
paragraph (d)(1) to read as follows:
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§ 60.13
Monitoring requirements.
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(d)(1) Owners and operators of a
CEMS installed in accordance with the
provisions of this part, must check the
zero (or low level value between 0 and
20 percent of span value) and span (50
to 100 percent of span value) calibration
drifts at least once daily in accordance
with a written procedure. The zero and
span must, at a minimum, be adjusted
whenever either the 24-hour zero drift
or the 24-hour span drift exceeds two
times the limit of the applicable
performance specification in Appendix
B of this part. The system must allow
the amount of the excess zero and span
drift to be recorded and quantified
whenever specified. Owners and
operators of a COMS installed in
accordance with the provisions of this
part must check the zero and upscale
(span) calibration drifts at least once
daily. For a particular COMS, the
acceptable range of zero and upscale
calibration materials is defined in the
applicable version of PS–1 in Appendix
B of this part. For a COMS, the optical
surfaces, exposed to the effluent gases,
must be cleaned before performing the
zero and upscale drift adjustments,
except for systems using automatic zero
adjustments. The optical surfaces must
be cleaned when the cumulative
automatic zero compensation exceeds 4
percent opacity.
*
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*
8. Amend § 60.17 by revising
paragraphs (e) and (e)(1) to read as
follows:
§ 60.17
Incorporations by reference.
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(e) The following material is available
for purchase from the Water
Environment Federation, 2626
Pennsylvania Avenue NW., Washington,
DC 20037.
(1) Method 209A, Total Residue Dried
at 103–105 °C, in Standard Methods for
the Examination of Water and
Wastewater, 20th Edition, 1999, IBR
approved February 25, 1985, for
§ 60.683(b).
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9. Amend § 60.46b by revising
paragraphs (f)(1)(ii) and (h)(1) and (2) to
read as follows:
§ 60.46b Compliance and performance test
methods and procedures for particulate
matter and nitrogen oxides.
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*
(f) * * *
(1) * * *
(ii) Method 7E of Appendix A of this
part or Method 320 of Appendix A of
Part 63 shall be used to determine the
NOX concentrations. Method 3A or 3B
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1145
of Appendix A of this part shall be used
to determine O2 concentration.
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*
(h) * * *
(1) Conduct an initial performance
test as required under § 60.8 over a
minimum of 24 consecutive steam
generating unit operating hours at
maximum heat input capacity to
demonstrate compliance with the NOX
emission standards under § 60.44b using
Method 7, 7A, or 7E of Appendix A of
this part, Method 320 of Appendix A of
Part 63, or other approved reference
methods; and
(2) Conduct subsequent performance
tests once per calendar year or every 400
hours of operation (whichever comes
first) to demonstrate compliance with
the NOX emission standards under
§ 60.44b over a minimum of 3
consecutive steam generating unit
operating hours at maximum heat input
capacity using Method 7, 7A, or 7E of
Appendix A of this part, Method 320 of
Appendix A of Part 63, or other
approved reference methods.
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*
10. Amend § 60.47b by revising
paragraph (b)(2) to read as follows:
§ 60.47b
dioxide.
Emission monitoring for sulfur
*
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*
(b) * * *
(2) Measuring SO2 according to
Method 6B of Appendix A of this part
at the inlet or outlet to the SO2 control
system. An initial stratification test is
required to verify the adequacy of the
sampling location for Method 6B of
Appendix A of this part. The
stratification test shall consist of three
paired runs of a suitable SO2 and CO2
measurement train operated at the
candidate location and a second similar
train operated according to the
procedures in Section 3.2 and the
applicable procedures in Section 7 of
Performance Specification 2. Method 6B
of Appendix A of this part, Method 6A
of Appendix A of this part, or a
combination of Methods 6 and 3 or 3B
of Appendix A of this part or Methods
6C or Method 320 of Appendix A of Part
63 and 3A of Appendix A of this part
are suitable measurement techniques. If
Method 6B of Appendix A of this part
is used for the second train, sampling
time and timer operation may be
adjusted for the stratification test as long
as an adequate sample volume is
collected; however, both sampling trains
are to be operated similarly. For the
location to be adequate for Method 6B
of Appendix A of this part, 24-hour
tests, the mean of the absolute
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§ 60.51c
Definitions.
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Medical/infectious waste means any
waste generated in the diagnosis,
treatment, or immunization of human
beings or animals, in research pertaining
thereto, or in the production or testing
of biologicals that are listed in
paragraphs (1) through (7) of this
definition. The definition of medical/
infectious waste does not include
hazardous waste identified or listed
under the regulations in part 261 of this
chapter; household waste, as defined in
§ 261.4(b)(1) of this chapter; ash from
incineration of medical/infectious
waste, once the incineration process has
been completed; human corpses,
remains, and anatomical parts that are
intended for interment or cremation;
and domestic sewage materials
identified in § 261.4(a)(1) of this
chapter.
*
*
*
*
*
12. Amend § 60.84 by revising the
equation in paragraph (d) to read as
follows:
§ 60.84
Emission monitoring.
*
*
*
*
*
(d) * * *
Es = (Cs S)/[0.265 ¥ (0.0126 %O2) ¥ (A
%CO2)]
*
*
*
*
*
13. Amend § 60.154 by revising
paragraph (b)(5) to read as follows:
§ 60.154
(c) * * *
(3) * * *
Ccorr = Cmeas × (21 ¥ X)/(21 ¥ Y)
*
*
*
*
*
15. Amend § 60.335 by revising two
terms for the equation in paragraph
(b)(1)to read as follows:
§ 60.335
Test methods and procedures.
*
*
*
*
*
(b) * * *
(1) * * *
Pr = reference combustor inlet
absolute pressure at 101.3 kilopascals
ambient pressure. Alternatively, you
may use 760 mm Hg (29.92 in Hg),
Po = observed combustor inlet
absolute pressure at test, mm Hg.
Alternatively, you may use the
barometric pressure for the date of the
test,
*
*
*
*
*
16. Amend 60.374 by revising
paragraphs (b)(1), (b)(2), and (c)(2) to
read as follows:
§ 60.374
Test methods and procedures.
*
*
*
*
*
(b) * * *
(1) Method 12 or Method 29 shall be
used to determine the lead
concentration (CPb) and, if applicable,
the volumetric flow rate (Qsda) of the
effluent gas. The sampling time and
sample volume for each run shall be at
least 60 minutes and 0.85 dscm (30
dscf).
(2) When different operations in a
three-process operation facility are
ducted to separate control devices, the
lead emission concentration (C) from
the facility shall be determined as
follows:
Test methods and procedures.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
*
*
*
*
*
(b) * * *
(5) Samples of the sludge charged to
the incinerator shall be collected in
nonporous jars at the beginning of each
run and at approximately 1-hour
intervals thereafter until the test ends;
and ‘‘2540 G. Total, Fixed, and Volatile
Solids in Solid and Semisolid Samples,
in Standard Methods for the
Examination of Water and Wastewater,
20th Edition, 1998’’ (incorporated by
reference—see § 60.17) shall be used to
determine dry sludge content of each
sample (total solids residue), except
that:
*
*
*
*
*
14. Amend § 60.284 by revising the
equation in paragraph (c)(3) to read as
follows:
§ 60.284 Monitoring of emissions and
operations.
*
*
*
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*
*
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17. Amend § 60.382 by revising
paragraph (a)(1) to read as follows:
§ 60.382
Standard for particulate matter.
*
*
*
*
*
(a) * * *
(1) Contain particulate matter in
excess of 0.05 grams per dry standard
cubic meter (0.05 g/dscm).
*
*
*
*
*
18. Amend § 60.386 by revising
paragraph (b)(2) to read as follows:
§ 60.386
Test methods and procedures.
*
*
*
*
*
(b) * * *
(2) Method 9 and the procedures in
§ 60.11 shall be used to determine
opacity from stack emissions and
process fugitive emissions. The observer
shall read opacity only when emissions
are clearly identified as emanating
solely from the affected facility being
observed. A single visible emission
observer may conduct visible emission
observations for up to three fugitive,
stack, or vent emission points within a
15-second interval. This option is
subject to the following limitations:
(i) No more than three emission
points are read concurrently;
(ii) All three emission points must be
within a 70° viewing sector or angle in
front of the observer such that the
proper sun position can be maintained
for all three points; and
(iii) If an opacity reading for any one
of the three emission points is within 5
percent opacity of the application
standard, then the observer must stop
taking readings for the other two points
and continue reading just that single
point.
*
*
*
*
*
19. Amend § 60.472 by revising
paragraph (a)(1)(ii) to read as follows:
§ 60.472
Standards for particulate matter.
*
Where:
C = Concentration of lead emissions for the
entire facility, mg/dscm (gr/dscf).
Ca = Concentration of lead emissions from
facility ‘‘a’’, mg/dscm (gr/dscf).
Qsda = Volumetric flow rate of effluent gas
from facility ‘‘a’’, dscm/hr (dscf/hr).
N = Total number of control devices to which
separate operations in the facility are
ducted.
*
*
*
*
*
(c) * * *
(2) Method 12 or Method 29 shall be
used to determine the lead
concentration (CPb) and the volumetric
flow rate (Qsd) of the effluent gas. The
sampling time and sample volume for
each run shall be at least 60 minutes
and 0.85 dscm (30 dscf).
*
*
*
*
*
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*
*
*
*
(a) * * *
(1) * * *
(ii) 0.4 kg/Mg (0.8 lb/ton) of saturated
felt or smooth-surfaced roll roofing
produced;
*
*
*
*
*
20. Amend § 60.660 by revising
paragraph (c)(4) to read as follows:
§ 60.660 Applicability and designation of
affected facility.
*
*
*
*
*
(c) * * *
(4) Each affected facility that has a
total resource effectiveness (TRE) index
value greater than 8.0 is exempt from all
provisions of this subpart except for
§§ 60.662; 60.664 (e), (f), and (g); and
60.665 (h) and (l).
*
*
*
*
*
E:\FR\FM\09JAP2.SGM
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EP09JA12.024
difference between the three paired runs
must be less than 10 percent.
*
*
*
*
*
11. Amend § 60.51c by revising the
definition of ‘‘Medical/infectious waste’’
to read as follows:
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
21. Amend § 60.665 by revising
paragraphs (h)(2) and (3) to read as
follows:
§ 60.665 Reporting and recordkeeping
requirements.
*
*
*
*
(h) * * *
(2) Any recalculation of the TRE
index value performed pursuant to
§ 60.664(g); and
*
1147
(3) The results of any performance test
performed pursuant to the methods and
procedures required by § 60.664(e).
*
*
*
*
*
22. Amend Subpart IIII by revising
Table 7 to read as follows:
TABLE 7 TO SUBPART IIII OF PART 60—REQUIREMENTS FOR PERFORMANCE TESTS FOR STATIONARY CI ICE WITH A
DISPLACEMENT OF ≥ 30 LITERS PER CYLINDER
[As stated in § 60.4213, you must comply with the following requirements for performance tests for stationary CI ICE with a displacement of ≥ 30
liters per cylinder]
Each
Complying with the
requirement to
You must
Using
According to the following
requirements
1. Stationary CI internal
combustion engine with
a displacement of ≥ 30 liters per cylinder.
a. Reduce NOX emissions
by 90 percent or more.
i. Measure NOX at the
centroid of the exhaust
at the inlet and outlet of
the control device;
(1) Method 7E of 40 CFR
part 60, Appendix A,
Method 320 of 40 CFR
part 63, Appendix A, or
ASTM D 6348–03 (incorporated by reference,
see § 60.17).
(2) Method 3, 3A, or 3B of
40 CFR part 60, Appendix A.
(a) NOX concentration
must be at 15 percent
O2, dry basis. Results of
this test consist of the
average of the three 1hour or longer runs.
ii. Measure O2 at the inlet
and outlet of the control
device; and,
iii. If necessary, measure
moisture content at the
inlet and outlet of the
control device.
b. Limit the concentration
of NOX in the stationary
CI internal combustion
engine exhaust.
i. Measure NOX at the
centroid of the exhaust
of the stationary internal
combustion engine;
ii. Determine the O2 concentration of the stationary internal combustion engine exhaust at
the sampling port location; and,
iii. If necessary, measure
moisture content of the
stationary internal combustion engine exhaust
at the sampling port location.
(2) Method 3, 3A, or 3B of
40 CFR part 60, Appendix A.
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(2) Method 3, 3A, or 3B of
40 CFR part 60, Appendix A.
iii. If necessary, measure
moisture content at the
inlet and outlet of the
control device; and
VerDate Mar<15>2010
i. Select the sampling port
location and the number
of traverse points;
(3) Method 4 of 40 CFR
part 60, Appendix A,
Method 320 of 40 CFR
part 63, Appendix A, or
ASTM D 6348–03 (incorporated by reference,
see § 60.17).
(1) Method 1 or 1A of 40
CFR part 60, Appendix
A.
ii. Measure O2 at the inlet
and outlet of the control
device;
c. Reduce PM emissions
by 60 percent or more.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
(3) Method 4 of 40 CFR
part 60, Appendix A,
Method 320 of 40 CFR
part 63, Appendix A, or
ASTM D 6348–03 (incorporated by reference,
see § 60.17).
(1) Method 7E of 40 CFR
part 60, Appendix A,
Method 320 of 40 CFR
part 63, Appendix A, or
ASTM D 6348–03 (incorporated by reference,
see § 60.17).
(3) Method 4 of 40 CFR
part 60, Appendix A.
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(b) Measurements to determine O2 concentration
must be made at the
same time as the measurements for NOX concentration.
(c) Measurements to determine moisture content
must be made at the
same time as the measurements for NOX concentration.
(a) If using a control device, the sampling site
must be located at the
outlet of the control device. NOX concentration
must be at 15 percent
O2, dry basis. Results of
this test consist of the
average of the three 1hour or longer runs.
(b) Measurements to determine O2 concentration
must be made at the
same time as the measurement for NOX concentration.
(c) Measurements to determine moisture content
must be made at the
same time as the measurement for NOX concentration.
(a) Sampling sites must be
located at the inlet and
outlet of the control device.
(b) Measurements to determine O2 concentration
must be made at the
same time as the measurements for PM concentration.
(c) Measurements to determine and moisture
content must be made
at the same time as the
measurements for PM
concentration.
1148
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
TABLE 7 TO SUBPART IIII OF PART 60—REQUIREMENTS FOR PERFORMANCE TESTS FOR STATIONARY CI ICE WITH A
DISPLACEMENT OF ≥ 30 LITERS PER CYLINDER—Continued
[As stated in § 60.4213, you must comply with the following requirements for performance tests for stationary CI ICE with a displacement of ≥ 30
liters per cylinder]
Complying with the
requirement to
Each
You must
According to the following
requirements
Using
iv. Measure PM at the inlet
and outlet of the control
device.
i. Select the sampling port
location and the number
of traverse points;
(1) Method 1 or 1A of 40
CFR part 60, Appendix
A.
ii. Determine the O2 concentration of the stationary internal combustion engine exhaust at
the sampling port location; and
iii. If necessary, measure
moisture content of the
stationary internal combustion engine exhaust
at the sampling port location;
iv. Measure PM at the exhaust of the stationary
internal combustion engine.
d. Limit the concentration
of PM in the stationary
CI internal combustion
engine exhaust.
(4) Method 5 of 40 CFR
part 60, Appendix A.
(2) Method 3, 3A, or 3B of
40 CFR part 60, Appendix A.
(3) Method 4 of 40 CFR
part 60, Appendix A.
(4) Method 5 of 40 CFR
part 60, Appendix A.
(d) PM concentration must
be at 15 percent O2, dry
basis. Results of this
test consist of the average of the three 1-hour
or longer runs.
(a) If using a control device, the sampling site
must be located at the
outlet of the control device.
(b) Measurements to determine O2 concentration
must be made at the
same time as the measurements for PM concentration.
(c) Measurements to determine moisture content
must be made at the
same time as the measurements for PM concentration.
(d) PM concentration must
be at 15 percent O2, dry
basis. Results of this
test consist of the average of the three 1-hour
or longer runs.
23. Amend Subpart JJJJ by revising
Table 2 to read as follows:
TABLE 2 TO SUBPART JJJJ OF PART 60—REQUIREMENTS FOR PERFORMANCE TESTS
[As stated in § 60.4244, you must comply with the following requirements for performance tests within 10 percent of 100 percent peak (or the
highest achievable) load]
For each
Complying with the
requirement to
You must
Using
According to the following
requirements
1. Stationary SI internal
combustion engine demonstrating compliance
according to § 60.4244.
a. limit the concentration of
NOX in the stationary SI
internal combustion engine exhaust.
i. Measure NOX at the
centroid of the exhaust
of the stationary internal
combustion engine;
(1) Method 7E of 40 CFR
part 60, Appendix A,
Method D6522–
00(2005),a Method 320
of 40 CFR part 63, Appendix A, or ASTM
D6348–03 (incorporated
by reference, see
§ 60.17).
(2) Method 3, 3A, or 3B b
of 40 CFR part 60, Appendix A or ASTM Method D6522–00(2005).a
(a) If using a control device, the sampling site
must be located at the
outlet of the control device. Results of this test
consist of the average of
the three 1-hour or
longer runs.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
ii. Determine the O2 concentration of the stationary internal combustion engine exhaust;
iii. Determine the exhaust
flow rate of the stationary internal combustion engine exhaust; and
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(3) Method 2 or 19 of 40
CFR part 60.
E:\FR\FM\09JAP2.SGM
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(b) Measurements to determine O2 concentration
must be made at the
same time as the measurements for NOX concentration.
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
1149
TABLE 2 TO SUBPART JJJJ OF PART 60—REQUIREMENTS FOR PERFORMANCE TESTS—Continued
[As stated in § 60.4244, you must comply with the following requirements for performance tests within 10 percent of 100 percent peak (or the
highest achievable) load]
Complying with the
requirement to
You must
b. limit the concentration of
CO in the stationary SI
internal combustion engine exhaust.
Using
According to the following
requirements
iv. If necessary, measure
moisture content of the
stationary internal combustion engine exhaust
at the sampling port location.
For each
(4) Method 4 of 40 CFR
part 60, Appendix A,
Method 320 of 40 CFR
part 63, Appendix A, or
ASTM D6348–03 (incorporated by reference,
see § 60.17).
(1) Method 10 of 40 CFR
part 60, Appendix A,
ASTM Method D6522–
00(2005),a Method 320
of 40 CFR part 63, Appendix A, or ASTM D
6348–03 (incorporated
by reference, see
§ 60.17).
(2) Method 3, 3A, or 3B b
of 40 CFR part 60, Appendix A or ASTM Method D6522–00(2005).a
(c) Measurements to determine moisture must
be made at the same
time as the measurement for NOX concentration.
i. Sample for CO at the
centroid of the stack of
the stationary internal
combustion engine;
ii. Determine the O2 concentration of the stationary internal combustion engine exhaust at
the sampling port location;
iii. Determine the exhaust
flow rate of the stationary internal combustion engine exhaust; and
iv. If necessary, measure
moisture content of the
stationary internal combustion engine exhaust
at the sampling port location.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
c. limit the concentration of
VOC in the stationary SI
internal combustion engine exhaust.
i. Measure VOC at the
centroid of the exhaust
of the stationary internal
combustion engine;
ii. Determine the O2 concentration of the stationary internal combustion engine exhaust at
the sampling port location;
iii. Determine the exhaust
flow rate of the stationary internal combustion engine exhaust; and
iv. If necessary, measure
moisture content of the
stationary internal combustion engine exhaust
at the sampling port location.
(a) If using a control device, the sampling site
must be located at the
outlet of the control device. Results of this test
consist of the average of
the three 1-hour or
longer runs.
(b) Measurements to determine O2 concentration
must be made at the
same time as the measurements for CO concentration.
(3) Method 2 or 19 of 40
CFR part 60.
(4) Method 4 of 40 CFR
part 60, Appendix A,
Method 320 of 40 CFR
part 63, Appendix A, or
ASTM D6348–03 (incorporated by reference,
see § 60.17).
(1) Methods 25A and 18 of
40 CFR part 60, Appendix A, Method 25A with
the use of a methane
cutter as described in 40
CFR 1065.265, Method
18 or 40 CFR part 60,
Appendix A,c d Method
320 of 40 CFR part 63,
Appendix A, or ASTM
D6348–03 (incorporated
by reference, see
§ 60.17).
(2) Method 3, 3A, or 3B b
of 40 CFR part 60, Appendix A or ASTM Method D6522–00(2005).a
(c) Measurements to determine moisture must
be made at the same
time as the measurement for CO concentration.
(a) If using a control device, the sampling site
must be located at the
outlet of the control device. Results of this test
consist of the average of
the three 1-hour or
longer runs.
(b) Measurements to determine O2 concentration
must be made at the
same time as the measurements for VOC concentration.
(3) Method 2 or 19 of 40
CFR part 60.
(4) Method 4 of 40 CFR
part 60, Appendix A,
Method 320 of 40 CFR
part 63, Appendix A, or
ASTM D6348–03 (incorporated by reference,
see § 60.17).
(c) Measurements to determine moisture must
be made at the same
time as the measurement for VOC concentration.
a ASTM D6522–00 is incorporated by reference; see 40 CFR 60.17. Also, you may petition the Administrator for approval to use alternative
methods for portable analyzer.
b You may use ASME PTC 19.10–1981, Flue and Exhaust Gas Analyses, for measuring the O content of the exhaust gas as an alternative to
2
EPA Method 3B.
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Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
c You may use EPA Method 18 of 40 CFR part 60, appendix A, provided that you conduct an adequate pre-survey test prior to the emissions
test, such as the one described in OTM 11 on EPA’s Web site (https://www.epa.gov/ttn/emc/prelim/otm11.pdf).
d You may use ASTM D6420–99 (2004), Test Method for Determination of Gaseous Organic Compounds by Direct Interface Gas Chromatography/Mass Spectrometry as an alternative to EPA Method 18 for measuring total nonmethane organic.
Appendix A–1 to Part 60—Test
Methods 1 Through 2F
Method 1—Sample and Velocity Traverses
From Stationary Sources
*
*
*
*
*
tkelley on DSK3SPTVN1PROD with PROPOSALS2
11.2.2 Velocity and Gaseous (NonParticulate) Traverses. Perform a
stratification test to determine the
appropriate number of sample traverse
points. If testing for multiple pollutants or
diluents at the same site, a stratification test
using only one pollutant or diluent satisfies
this requirement. A stratification test is not
required for small stacks that are less than 4
inches in diameter. When the 8- and 2diameter criterion can be met, the minimum
number of traverse points for the
stratification test will be 12. Test for
stratification using a probe of appropriate
length to measure the gas concentration at
the required traverse points located
according to Table 1–2. Alternatively (if the
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8- and 2-diameter criterion is met), you may
measure the gas concentration at three points
on a line passing through the centroidal area.
Space the three points at 16.7, 50.0, and 83.3
percent of the measurement line. Sample for
a minimum of twice the system response
time at each traverse point. Calculate the
individual point and mean concentrations. If
the concentration at each traverse point
differs from the mean concentration for all
traverse points by no more than: (a) ± 5.0
percent of the mean concentration; or (b)
± 0.5 ppm (whichever is less restrictive), the
gas stream is considered unstratified and you
may collect samples from a single point that
most closely matches the mean. If the 5.0
percent or 0.5 ppm criterion is not met, but
the concentration at each traverse point
differs from the mean concentration for all
traverse points by no more than: (a) ± 10.0
percent of the mean; or (b) ± 1.0 ppm
(whichever is less restrictive), the gas stream
is considered to be minimally stratified, and
you may take samples from three points.
Space the three points at 16.7, 50.0, and 83.3
percent of the measurement line.
Alternatively, if a 12-point stratification test
was performed and the emissions were
shown to be minimally stratified (all points
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within ± 10.0 percent of their mean or within
± 1.0 ppm), and if the stack diameter (or
equivalent diameter, for a rectangular stack
or duct) is greater than 2.4 meters (7.8 ft),
then you may use 3-point sampling and
locate the three points along the
measurement line exhibiting the highest
average concentration during the
stratification test at 0.4, 1.0 and 2.0 meters
from the stack or duct wall. If the gas stream
is found to be stratified because the 10.0
percent or 1.0 ppm criterion for a 3-point test
is not met, locate 12 traverse points for the
test in accordance with Table 1–2.
*
*
*
*
*
11.4.1 In most stationary sources, the
direction of stack gas flow is essentially
parallel to the stack walls. However, cyclonic
flow may exist: (1) after such devices as
cyclones and inertial demisters following
venturi scrubbers, or (2) in stacks having
tangential inlets or other duct configurations
which tend to induce swirling. Determine the
presence or absence of cyclonic flow at each
sampling location. The following techniques
are acceptable for this determination.
*
E:\FR\FM\09JAP2.SGM
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*
09JAP2
*
*
EP09JA12.025
24. Amend Method 1 of Appendix A–
1 to Part 60 by revising Sections 11.2.2,
11.4.1, and Figures 1–1 and 1–2 to read
as follows:
1151
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
*
*
*
*
*
25. Amend Method 2 of Appendix A–
1 to Part 60 as follows:
a. By revising Section 8.1.
b. By revising the Note at the end of
10.1.1
c. By revising Section 10.4.
d. By adding a term to Section 12.1.
e. By revising Sections 12.6, and 12.7.
Method 2—Determination of Stack Gas
Velocity and Volumetric Flow Rate (Type S
Pitot Tube)
*
*
*
*
*
8.1 Set up the apparatus as shown in
Figure 2–1. Capillary tubing or surge tanks
installed between the manometer and pitot
tube may be used to dampen DP fluctuations.
It is recommended, but not required, that a
pretest leak-check be conducted as follows:
(1) blow through the pitot impact opening
until at least 7.6 cm (3.0 in.) H2O velocity
head registers on the manometer; then, close
off the impact opening. The pressure shall
remain stable (± 2.5 mm H2O, ± 0.10 in. H2O)
for at least 15 seconds; (2) do the same for
the static pressure side, except using suction
to obtain the minimum of 7.6 cm (3.0 in.)
H2O. Other leak-check procedures, subject to
the approval of the Administrator, may be
used.
12.1 Nomenclature
* * *
Ts(abavg)—Average absolute stack
temperature, °K (°R).
*
*
*
10.1.1
*
*
*
* * *
Note: Do not use a Type S pitot tube
assembly that is constructed such that the
impact pressure opening plane of the pitot
tube is below the entry plane of the nozzle
(see Figure 2–7B).
*
*
*
*
*
10.4 Barometer. Calibrate the barometer
used against a mercury barometer or NISTtraceable barometer prior to each field test.
*
*
*
12.6
*
*
*
*
*
*
Average Stack Gas Velocity.
EP09JA12.028
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tkelley on DSK3SPTVN1PROD with PROPOSALS2
Where:
1152
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
12.7 Average Stack Gas Dry Volumetric
Flow Rate.
*
*
*
*
26. Amend Method 2A of Appendix
A–1 to Part 60 by revising Sections 10.3
and 12.2 to read as follows:
Method 2A—Direct Measurement of Gas
Volume Through Pipes and Small Ducts
*
*
*
*
*
27. Amend Method 2B of Appendix
A–1 to Part 60 by revising Section 12.1
to read as follows:
Vis = Inlet gas volume, m3.
Qes = Exhaust gas volume flow rate, m3/min.
Qis = Inlet gas volume flow rate, m3/min.
Q = Sample run time, min.
S = Standard conditions: 20 °C, 760 mm Hg.
Method 2B—Determination of Exhaust Gas
Volume Flow Rate from Gasoline Vapor
Incinerators
*
*
*
*
*
*
*
12.1 Nomenclature.
COe = Mean carbon monoxide concentration
in system exhaust, ppm.
(CO2)a = Ambient carbon dioxide
concentration, ppm (if not measured
during the test period, may be assumed
to equal 380 ppm).
(CO2)e = Mean carbon dioxide concentration
in system exhaust, ppm.
HCe = Mean organic concentration in system
exhaust as defined by the calibration gas,
ppm.
Hci = Mean organic concentration in system
inlet as defined by the calibration gas,
ppm.
Ke = Hydrocarbon calibration gas factor for
the exhaust hydrocarbon analyzer,
unitless [equal to the number of carbon
atoms per molecule of the gas used to
calibrate the analyzer (2 for ethane, 3 for
propane, etc.)].
Ki = Hydrocarbon calibration gas factor for
the inlet hydrocarbon analyzer, unitless.
Ves = Exhaust gas volume, m3.
*
*
*
*
*
10.3 Barometer. Calibrate the barometer
used against a mercury barometer or NISTtraceable barometer prior to the field test.
*
*
12.2
*
*
*
*
28. Amend Method 2D of Appendix
A–1 to Part 60 by revising Section 10.4
to read as follows:
Method 2D—Measurement of Gas Volume
Flow Rates in Small Pipes and Ducts
*
*
*
*
*
10.4 Barometer. Calibrate the barometer
used against a mercury barometer or NISTtraceable barometer prior to the field test.
*
*
*
*
*
29. Amend Method 3A of Appendix
A–2 to Part 60 by revising Section 7.1
to read as follows:
Appendix A–2 to Part 60—Test
Methods 2G through 3C
*
*
*
*
*
*
*
*
30. Amend Method 4 of Appendix A–
3 to Part 60 by revising Sections 9.1 and
16 to read as follows:
Appendix A–3 to Part 60—Test
Methods 4 Through 5I
*
*
*
*
*
*
*
*
*
Method 7E for the calibration gas
requirements. Example calibration gas
mixtures are listed below. Pre-cleaned or
scrubbed air may be used for the O2 highcalibration gas provided it does not contain
other gases that interfere with the O2
measurement.
(a) CO2 in Nitrogen (N2).
(b) CO2 in air.
(c) CO2/SO2 gas mixture in N2.
(d) O2/SO2 gas mixture in N2.
(e) O2/CO2/SO2 gas mixture in N2.
(f) CO2/NOX gas mixture in N2.
(g) CO2/SO2/NOX gas mixture in N2.
The tests for analyzer calibration error and
system bias require high-, mid-, and lowlevel gases.
Method 3A—Determination of Oxygen and
Carbon Dioxide Concentrations in Emissions
From Stationary Sources (Instrumental
Analyzer Procedure)
*
*
Test Meter Calibration Coefficient.
*
7.1 Calibration Gas. What calibration
gases do I need? Refer to Section 7.1 of
*
*
*
*
Method 4—Determination of Moisture
Content in Stack Gases
*
*
*
*
9.1 Miscellaneous Quality Control
Measures.
Leak rate of the sampling system cannot exceed four
percent of the average sampling rate or 0.00057 m3/
min (0.020 cfm).
Leak rate of the sampling system cannot exceed two
percent of the average sampling rate.
Ensures the accuracy of the volume of gas sampled.
(Reference Method)
tkelley on DSK3SPTVN1PROD with PROPOSALS2
Section 8.2.1 ........................
*
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*
*
*
16.0
Alternative Procedures
16.1 The procedure described in Method
5 for determining moisture content is an
acceptable alternative to Method 4.
16.2 The procedures in Method 6A for
determining moisture is an acceptable
alternative to Method 4.
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Ensures the accuracy of the volume of gas sampled.
(Approximation Method)
16.3 Method 320 is an acceptable
alternative to Method 4 for determining
moisture.
16.4 Using F-factors to determine
moisture is an acceptable alternative to
Method 4. For a combustion stack not using
a scrubber, the moisture content may be
calculated as follows:
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Where:
BA = Mole fraction of moisture in the ambient
air.
BF = Mole fraction of moisture from free
water in the fuel.
E:\FR\FM\09JAP2.SGM
09JAP2
ep09ja12.031
Section 8.1.1.4 .....................
ep09ja12.032
Effect
EP09JA12.030
Quality control measure
EP09JA12.029
Section
1153
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
*
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31. Amend Method 5 of Appendix A–
3 to Part 60 as follows:
a. By revising Sections 6.1.1.5, 6.1.1.7,
and 6.1.1.9.
b. By revising Section 7.1.3.
c. By removing Section 7.1.5.
d. By revising Sections 8.1, 8.3.4,
8.7.3, and 8.7.5.
e. By revising Sections 10.3.3, 10.4,
10.5, and 10.6.
f. By revising Equation 5–13 in
Section 16.2.3.3.
g. By adding Section 16.3.
i. By adding reference 13 to Section
17.0.
Method 5—Determination of Particulate
Matter Emissions From Stationary Sources
*
*
*
*
*
6.1.1.5 Filter Holder. Borosilicate glass,
with a glass frit filter support and a silicone
rubber gasket. Alternatively, Teflon filter
holders may be used. Other materials of
construction (e.g., stainless steel or Viton)
may be used, subject to the approval of the
Administrator. The holder design shall
provide a positive seal against leakage from
the outside or around the filter. The holder
shall be attached immediately at the outlet of
the probe (or cyclone, if used).
tkelley on DSK3SPTVN1PROD with PROPOSALS2
*
*
*
*
*
6.1.1.7 Temperature Sensor. A calibrated
temperature sensor (rechecked at at least one
point after each test) shall be installed so that
the sensing tip of the temperature sensor is
in direct contact with the sample gas, and the
temperature around the filter holder can be
regulated and monitored during sampling.
*
*
*
*
*
6.1.1.9 Metering System. Vacuum gauge,
leak-free pump, calibrated temperature
sensors (rechecked at at least one point after
each test), dry gas meter (DGM) capable of
measuring volume to within 2 percent, and
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bottle prior to filling from the tested
container. Take 200 ml of this acetone
directly from the wash bottle being used, and
place it in a glass sample container labeled
‘‘acetone blank.’’
*
*
*
*
*
*
7.1.3 Water. When analysis of the
material caught in the impingers is required,
deionized distilled water (to conform to
ASTM D 1193–77 or 91 Type 3 (incorporated
by reference—see § 60.17)) with ≤ 0.001
percent residue shall be used. Run blanks
prior to field use to eliminate a high blank
on test samples, and use only water with low
blank values (≤ 0.001 percent).
*
*
*
*
*
8.1 Pretest Preparation. It is suggested
that sampling equipment be maintained
according to the procedures described in
APTD–0576. Alternative mercury-free
thermometers may be used if the
thermometers are at a minimum equivalent
in terms of performance or suitably effective
for the specific temperature measurement
application.
*
*
*
*
*
8.3.4 Set up the train as shown in Figure
5–1 ensuring that the connections are leaktight. Subject to the approval of the
Administrator, a glass cyclone may be used
between the probe and filter holder when the
total particulate catch is expected to exceed
100 mg or when water droplets are present
in the stack gas.
*
*
*
*
*
8.7.3 Before moving the sample train to
the cleanup site, remove the probe from the
sample train and cap the open outlet of the
probe. Be careful not to lose any condensate
that might be present. Cap the filter inlet
where the probe was fastened. Remove the
umbilical cord from the last impinger, and
cap the impinger. If a flexible line is used
between the first impinger or condenser and
the filter holder, disconnect the line at the
filter holder, and let any condensed water or
liquid drain into the impingers or condenser.
Cap off the filter holder outlet and impinger
inlet. Either ground-glass stoppers, plastic
caps, or serum caps may be used to close
these openings.
*
*
*
*
*
8.7.5 Save a portion of the acetone used
for cleanup as a blank. For each container of
acetone used for cleanup, save 200 ml and
place it in a glass sample container labeled
‘‘acetone blank.’’ To minimize any
particulate contamination, rinse the wash
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*
*
*
*
*
10.3.3 Acceptable Variation in
Calibration Check. If the DGM coefficient
values obtained before and after a test series
differ by more than 5 percent, the test series
shall either be voided, or calculations for the
test series shall be performed using
whichever meter coefficient value (i.e., before
or after) gives the lower value of total sample
volume.
*
*
*
*
10.4 Probe Heater Calibration. Use a heat
source to generate air heated to selected
temperatures that approximate those
expected to occur in the sources to be
sampled. Pass this air through the probe at
a typical sample flow rate while measuring
the probe inlet and outlet temperatures at
various probe heater settings. For each air
temperature generated, construct a graph of
probe heating system setting versus probe
outlet temperature. The procedure outlined
in APTD–0576 can also be used. Probes
constructed according to APTD–0581 need
not be calibrated if the calibration curves in
APTD–0576 are used. Also, probes with
outlet temperature monitoring capabilities do
not require calibration. As an alternative, the
following single-point calibration procedure
may be used. After each test run series, check
the accuracy (and, hence, the calibration) of
each thermocouple system at ambient
temperature, or any other temperature,
within the range specified by the
manufacturer, using a reference thermometer
(either ASTM reference thermometer or a
thermometer that has been calibrated against
an ASTM reference thermometer). The
temperatures of the thermocouple and
reference thermometers shall agree to within
±2 °F. Note: The probe heating system shall
be calibrated before its initial use in the field.
10.5 Temperature Sensors. Use the
procedure in Section 10.3 of Method 2 to
calibrate in-stack temperature sensors. Dial
thermometers, such as are used for the DGM
and condenser outlet, shall be calibrated
against mercury-in-glass thermometers. An
alternative mercury-free NIST-traceable
thermometer may be used if the thermometer
is, at a minimum, equivalent in terms of
performance or suitably effective for the
specific temperature measurement
application.
10.6 Barometer. Calibrate against a
mercury barometer or NIST-traceable
barometer prior to the field test.
Alternatively, barometric pressure may be
obtained from a weather report that has been
adjusted for the test point (on the stack)
elevation.
*
*
16.2.3.3
E:\FR\FM\09JAP2.SGM
*
* * *
09JAP2
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*
ep09ja12.034
Bws = Mole fraction of moisture in the stack
gas.
Fd = Volume of dry combustion components
per unit of heat content at 0 percent
oxygen, dscf/106 Btu (scm/J). See Table
19–2 in Method 19.
FW = Volume of wet combustion components
per unit of heat content at 0 percent
oxygen, wet scf/106 Btu (scm/J). See
Table 19–2 in Method 19.
%RH = Percent relative humidity (calibrated
hydrometer acceptable), percent.
PBar = Barometric pressure, in. Hg (mm Hg).
T = Ambient temperature, °F (°C).
W = Percent free water by weight, percent.
O2 = Percent oxygen in stack gas, dry basis,
percent.
related equipment, as shown in Figure 5–1.
Alternatively, an Isostack metering system
may be used if all Method 5 calibrations are
performed, with the exception of those
related to DH@ in Section 9.2.1, wherein the
sample flow rate system shall be calibrated
in lieu of DH@ and shall not deviate by more
than 5 percent. Other metering systems
capable of maintaining sampling rates within
10 percent of isokinetic and of determining
sample volumes to within 2 percent may be
used, subject to the approval of the
Administrator. When the metering system is
used in conjunction with a pitot tube, the
system shall allow periodic checks of
isokinetic rates.
ep09ja12.033
BH = Mole fraction of moisture from the
hydrogen in the fuel.
1154
*
*
Where:
Yqa = Dry gas meter calibration check value,
dimensionless.
0.0319 = (29.92/528)(0.75)2(in. Hg/°R) cfm2.
DH@ = Orifice meter calibration coefficient,
in. H2O.
Md = Dry molecular weight of stack gas, lb/
lb-mole.
29 = Dry molecular weight of air, lb/lb-mole.
16.3.2 After each test run series, do the
following:
16.3.2.1 Average the three or more Yqa’s
obtained from the test run series and
compare this average Yqa with the dry gas
meter calibration factor Y. The average Yqa
must be within 5 percent of Y.
16.3.2.2 If the average Yqa does not meet
the 5 percent criterion, recalibrate the meter
over the full range of orifice settings as
detailed in Section 10.3.1. Then follow the
procedure in Section 10.3.3.
*
*
*
*
*
17.0
*
*
References
*
*
*
13. Shigehara, Roger T., P.G. Royals, and
E.W. Steward. ‘‘Alternative Method 5 PostTest Calibration.’’ Entropy Incorporated,
Research Triangle Park, NC 27709.
*
*
*
*
*
32. Amend Method 5A of Appendix
A–3 to Part 60 by revising Section 8.1
to read as follows:
Method 5A—Determination of Particulate
Matter Emissions From the Asphalt
Processing and Asphalt Roofing Industry
tkelley on DSK3SPTVN1PROD with PROPOSALS2
*
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8.1 Pretest Preparation. Unless otherwise
specified, maintain and calibrate all
components according to the procedure
described in APTD–0576, ‘‘Maintenance,
Calibration, and Operation of Isokinetic
Source-Sampling Equipment’’ (Reference 3 in
Method 5, Section 17.0). Alternative
mercury-free thermometers may be used if
the thermometers are, at a minimum,
equivalent in terms of performance or
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system must pass the post-test leak-check
from either the inlet of the sampling train or
the inlet of the metering system. Therefore,
if the train fails the former leak-check,
another leak-check from the inlet of the
metering system must be conducted; (2) The
metering system must pass the leak-check of
that portion of the train from the pump to the
orifice meter as described in Section 10.3.1.1.
16.3.1 After each test run, do the
following:
16.3.1.1 Ensure that the metering system
has passed the post-test leak-check. If not,
conduct a leak-check of the metering system
from its inlet.
16.3.1.2 Conduct the leak-check of that
portion of the train from the pump to the
orifice meter as described in Section 10.3.1.1.
16.3.1.3 Calculate Yqa for each test run
using the following equation:
suitably effective for the specific temperature
measurement application.
La = Maximum acceptable leakage rate for
either a post-test leak-check or for a leakcheck following a component change;
equal to 0.00057 cmm (0.020 cfm) or 4
percent of the average sampling rate,
whichever is less.
L1 = Individual leakage rate observed during
the leak-check conducted before a
component change, cmm (cfm).
Lp = Leakage rate observed during the posttest leak-check, cmm (cfm).
mn = Total amount of particulate matter
collected, mg.
Ma = Mass of residue of solvent after
evaporation, mg.
NC = Grams of carbon/gram of dry fuel (lb/
lb), equal to 0.0425.
NT = Total dry moles of exhaust gas/kg of dry
wood burned, g-moles/kg (lb-moles/lb).
PR = Percent of proportional sampling rate.
Pbar = Barometric pressure at the sampling
site, mm Hg (in.Hg).
Pstd = Standard absolute pressure, 760 mm Hg
(29.92 in.Hg).
Qi = Gas volumetric flow rate at inlet, cfm (l/
min).
Qo = Gas volumetric flow rate at outlet, cfm
(l/min).
*
*
*
*
*
33. Amend Method 5E of Appendix
A–3 to Part 60 as follows:
a. By redesignating Sections 16 and 17
as Sections 17 and 18.
b. By adding a new Section 16.
Method 5E—Determination of Particulate
Matter Emissions From the Wool Fiberglass
Insulation Manufacturing Industry
*
*
*
*
*
16.0 Alternative Procedures
16.1 Total Organic Carbon Analyzer.
Tekmar-Dohrmann analyzers using the single
injection technique may be used as an
alternative to Rosemount Model 2100A
analyzers.
*
*
*
*
*
34. Amend Method 5H of Appendix
A–3 to Part 60 as follows:
a. By revising Section 12.1.
b. By adding Section 12.15.
c. By redesignating Sections 16 and 17
as Sections 17 and 18, respectively.
d. By adding a new Section 16.
Method 5H—Determination of Particulate
Matter Emissions From Wood Heaters From
a Stack Location
*
*
*
*
Frm 00026
Fmt 4701
*
*
*
*
12.15 Alternative Tracer Gas Flow Rate
Determination.
*
12.1 Nomenclature.
A = Sample flow rate adjustment factor.
BR = Dry wood burn rate, kg/hr (lb/hr), from
Method 28, Section 8.3.
Bws = Water vapor in the gas stream,
proportion by volume.
Ci = Tracer gas concentration at inlet, ppmv.
Co = Tracer gas concentration at outlet,
ppmv.
Cs = Concentration of particulate matter in
stack gas, dry basis, corrected to standard
conditions, g/dscm (g/dscf).
E = Particulate emission rate, g/hr (lb/hr).
DH = Average pressure differential across the
orifice meter (see Figure 5H–1), mm H2O
(in. H2O).
PO 00000
*
Sfmt 4702
Note: This gives Q for a single instance
only. Repeated multiple determinations are
needed to track temporal variations. Very
small variations in Qi, Ci, or Co may give very
large variations in Qo.
*
*
*
*
*
16.0 Alternative Procedures
16.1 Alternative Stack Gas Volumetric
Flow Rate Determination (Tracer Gas).
16.1.1 Apparatus.
16.1.1.1 Tracer Gas Injector System. This
is to inject a known concentration of tracer
gas into the stack. This system consists of a
cylinder of tracer gas, a gas cylinder
E:\FR\FM\09JAP2.SGM
09JAP2
EP09JA12.037
*
ep09ja12.036
*
16.3 Alternative Post-Test Metering
System Calibration. The following procedure
may be used as an alternative to the post-test
calibration described in Section 10.3.2. This
alternative procedure does not detect
leakages between the inlet of the metering
system and the dry gas meter. Therefore, two
steps must be included to make it an
equivalent alternative: (1) The metering
ep09ja12.035
*
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
1155
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
regulator, a stainless steel needle valve or a
flow controller, a nonreactive (stainless steel
or glass) rotameter, and an injection loop to
disperse the tracer gas evenly in the stack.
16.1.1.2 Tracer Gas Probe. A glass or
stainless steel sampling probe.
16.1.1.3 Gas Conditioning System. A gas
conditioning is a system suitable for
delivering a cleaned sample to the analyzer
consisting of a filter to remove particulate
and a condenser capable of lowering the dew
point of the sample gas to less than 5 °C (40
°F). A desiccant such as anhydrous calcium
sulfate may be used to dry the sample gas.
Desiccants which react or absorb tracer gas or
stack gas may not be used, e.g. silica gel
absorbs CO2.
16.1.1.4 Pump. An inert (i.e., stainless
steel or Teflon head) pump to deliver more
than the total sample required by the
manufacturer’s specifications for the analyzer
used to measure the downstream tracer gas
concentration.
16.1.1.5 Gas Analyzer. A gas analyzer is
any analyzer capable of measuring the tracer
gas concentration in the range necessary at
least every 10 minutes. A means of
controlling the analyzer flow rate and a
device for determining proper sample flow
rate shall be provided unless data is provided
to show that the analyzer is insensitive to
flow variations over the range encountered
during the test. The gas analyzer needs to
meet or exceed the flowing performance
specifications:
tkelley on DSK3SPTVN1PROD with PROPOSALS2
Linearity ..................
Calibration Error .....
Response Time ......
Zero Drift (24 hour)
Span Drift (24 hour)
Resolution ...............
± 1 percent of full scale.
≤ 2 percent of span.
≤ 10 seconds.
≤ 2 percent of full scale.
≤ 2 percent of full scale.
≤ 0.5 percent of span.
16.1.1.6 Recorder (optional). To provide a
permanent record of the analyzer output.
16.1.2 Reagents.
16.1.2.1 Tracer Gas. The tracer gas is
sulfur hexafluoride in an appropriate
concentration for accurate analyzer
measurement or pure sulfur dioxide. The gas
used must be nonreactive with the stack
effluent and give minimal (< 3 percent)
interference to measurement by the gas
analyzer.
16.1.3 Procedure. Select upstream and
downstream locations in the stack or duct for
introducing the tracer gas and delivering the
sampled gas to the analyzer. The inlet
location should be 8 or more duct diameters
beyond any upstream flow disturbance. The
outlet should be 8 or more undisturbed duct
diameters from the inlet and 2 or more duct
diameters from the duct exit. After installing
the apparatus, meter a known concentration
of the tracer gas into the stack at the inlet
location. Use the gas sample probe and
analyzer to show that no stratification of the
tracer gas is found in the stack at the
measurement locations. Monitor the tracer
gas concentration from the outlet location
and record the concentration at 10-minute
intervals or more often at the option of the
tester. A minimum of three measured
intervals is recommended to determine the
stack gas volumetric flow rate. Other
statistical procedures may be applied for
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complete flow characterization and
additional QA/QC.
*
*
*
*
*
35. Amend Method 6 of Appendix A–
4 to Part 60 by revising Sections 10.2
and 10.4 to read as follows:
Appendix A–4 to Part 60—Test
Methods 6 through 10B
*
*
*
*
*
Method 6—Determination of Sulfur Dioxide
Emissions From Stationary Sources
*
*
*
*
*
10.2 Temperature Sensors. Calibrate
against mercury-in-glass thermometers. An
alternative mercury-free thermometer may be
used if the thermometer is, at a minimum,
equivalent in terms of performance or
suitably effective for the specific temperature
measurement application.
*
*
*
*
*
10.4 Barometer. Calibrate against a
mercury barometer or NIST-traceable
barometer prior to the field test.
*
*
*
*
*
36. Amend Method 6C of Appendix
A–4 to Part 60 by revising Sections 4.0
and 8.3 to read as follows:
Method 6C—Determination of Sulfur
Dioxide Emissions From Stationary Sources
(Instrumental Analyzer Procedure)
*
*
*
*
*
4.0 Interferences
Refer to Section 4.0 of Method 7E.
*
*
*
*
*
8.3 Interference Check. You must follow
the procedures of Section 8.2.7 of Method 7E
to conduct an interference check, substituting
SO2 for NOX as the method pollutant. For
dilution-type measurement systems, you
must use the alternative interference check
procedure in Section 16 and a co-located,
unmodified Method 6 sampling train.
Quenching in fluorescence analyzers must be
evaluated and remedied unless a dilution
system and ambient-level analyzer is used.
This may be done by preparing the
calibration gas to contain within 1 percent of
the absolute oxygen and carbon dioxide
content of the measured gas, preparing the
calibration gas in air and using vendor
nomographs, or by other acceptable means.
*
*
*
*
*
37. Amend Method 7 of Appendix A–
4 to Part 60 by revising Sections 4.0,
10.2, and 10.3 to read as follows:
Method 7—Determination of Nitrogen Oxide
Emissions From Stationary Sources
*
*
*
*
*
4.0 Interferences
Biased results have been observed when
sampling under conditions of high sulfur
dioxide concentrations. At or above 2100
ppm SO2, use five times the H2O2
concentration of the Method 7 absorbing
solution. Laboratory tests have shown that
high concentrations of SO2 (about 2100 ppm)
cause low results in Method 7 and 7A.
Increasing the H2O2 concentration to five
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Sfmt 4702
times the original concentration eliminates
this bias. However, when no SO2 is present,
increasing the concentration by five times
results in a low bias.
*
*
*
*
*
10.2 Barometer. Calibrate against a
mercury barometer or NIST-traceable
barometer prior to the field test.
10.3 Temperature Gauge. Calibrate dial
thermometers against mercury-in-glass
thermometers. An alternative mercury-free
thermometer may be used if the thermometer
is, at a minimum, equivalent in terms of
performance or suitably effective for the
specific temperature measurement
application.
*
*
*
*
*
38. Amend Method 7A of Appendix
A–4 to Part 60 by revising Sections 4.0
and 10.4 to read as follows:
Method 7A—Determination of Nitrogen
Oxide Emissions From Stationary Sources
(Ion Chromatographic Method)
*
*
*
*
*
4.0 Interferences
Biased results have been observed when
sampling under conditions of high sulfur
dioxide concentrations. At or above 2100
ppm SO2, use five times the H2O2
concentration of the Method 7 absorbing
solution. Laboratory tests have shown that
high concentrations of SO2 (about 2100 ppm)
cause low results in Method 7 and 7A.
Increasing the H2O2 concentration to five
times the original concentration eliminates
this bias. However, when no SO2 is present,
increasing the concentration by five times
results in a low bias.
*
*
*
*
*
10.4 Temperature Gauge. Calibrate dial
thermometers against mercury-in-glass
thermometers. An alternative mercury-free
thermometer may be used if the thermometer
is, at a minimum, equivalent in terms of
performance or suitably effective for the
specific temperature measurement
application.
*
*
*
*
*
39. Amend Method 7E of Appendix
A–4 to Part 60 as follows:
a. By revising Section 6.1.
b. By revising Section 7.1.1.
c. By revising Sections 8.1.2 and 8.2.5.
d. By revising Section 16.2.2.
Method 7E—Determination of Nitrogen
Oxides Emissions From Stationary Sources
(Instrumental Analyzer Procedure)
*
*
*
*
*
6.1 What do I need for the measurement
system? You may use any equipment and
supplies meeting the following
specifications:
(1) Sampling system components that are
not evaluated in the system bias or system
calibration error test must be glass, Teflon, or
stainless steel. Other materials are potentially
acceptable, subject to approval by the
Administrator.
(2) The interference, calibration error, and
system bias criteria must be met.
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(3) Sample flow rate must be maintained
within 10 percent of the flow rate at which
the system response time was measured.
(4) All system components (excluding
sample conditioning components, if used)
must maintain the sample temperature above
the moisture dew point. Ensure minimal
contact between any condensate and the
sample gas. Section 6.2 provides example
equipment specifications for a NOX
measurement system. Figure 7E–1 is a
diagram of an example dry-basis
measurement system that is likely to meet the
method requirements and is provided as
guidance. For wet-basis systems, you may
use alternative equipment and supplies as
needed (some of which are described in
Section 6.2), provided that the measurement
system meets the applicable performance
specifications of this method.
*
*
*
*
*
7.1.1 High-Level Gas. This concentration
is chosen to set the calibration span as
defined in Section 3.4. Choose this high-level
concentration so that emission measurements
will be within 20 to 100 percent of this
concentration.
*
*
*
*
*
tkelley on DSK3SPTVN1PROD with PROPOSALS2
8.1.2 Determination of Stratification.
Perform a stratification test at each test site
to determine the appropriate number of
sample traverse points. If testing for multiple
pollutants or diluents at the same site, a
stratification test using only one pollutant or
diluent satisfies this requirement. A
stratification test is not required for small
stacks that are less than 4 inches in diameter.
To test for stratification, use a probe of
appropriate length to measure the NOX (or
pollutant of interest) concentration at 12
traverse points located according to Table 1–
1 or Table 1–2 of Method 1. Alternatively,
you may measure at three points on a line
passing through the centroidal area. Space
the three points at 16.7, 50.0, and 83.3
percent of the measurement line. Sample for
a minimum of twice the system response
time (see Section 8.2.6) at each traverse
point. Calculate the individual point and
mean NOX concentrations. If the
concentration at each traverse point differs
from the mean concentration for all traverse
points by no more than: (a) ± 5.0 percent of
the mean concentration; or (b) ± 0.5 ppm
(whichever is less restrictive), the gas stream
is considered unstratified and you may
collect samples from a single point that most
closely matches the mean. If the 5.0 percent
or 0.5 ppm criterion is not met, but the
concentration at each traverse point differs
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from the mean concentration for all traverse
points by no more than: (a) ± 10.0 percent of
the mean; or (b) ± 1.0 ppm (whichever is less
restrictive), the gas stream is considered to be
minimally stratified, and you may take
samples from three points. Space the three
points at 16.7, 50.0, and 83.3 percent of the
measurement line. Alternatively, if a 12-point
stratification test was performed and the
emissions shown to be minimally stratified
(all points within ± 10.0 percent of their
mean or within ± 1.0 ppm), and if the stack
diameter (or equivalent diameter for a
rectangular stack or duct) is greater than 2.4
meters (7.8 ft), then you may use 3-point
sampling and locate the three points along
the measurement line exhibiting the highest
average concentration during the
stratification test at 0.4, 1.2, and 2.0 meters
from the stack or duct wall. If the gas stream
is found to be stratified because the 10.0
percent or 1.0 ppm criterion for a 3-point test
is not met, locate 12 traverse points for the
test in accordance with Table 1–1 or Table
1–2 of Method 1. This stratification test may
not be meaningful at sources with temporally
varying emissions or where emission
concentrations are low. In these cases, the
stratification test is not required.
*
*
*
*
*
8.2.5 Initial System Bias and System
Calibration Error Checks. Before sampling
begins, determine whether the high-level or
mid-level calibration gas best approximates
the emissions and use it as the upscale gas.
Introduce the upscale gas at the probe
upstream of all sample conditioning
components in system calibration mode.
Record the time it takes for the measured
concentration to increase to a value that is
within 95 percent or 0.5 ppm (whichever is
less restrictive) of a stable response for both
the low-level and upscale gases. Continue to
observe the gas concentration reading until it
has reached a final, stable value. Record this
value on a form similar to Table 7E–2.
*
*
*
*
*
16.2.2 Bag Procedure. Perform the
analyzer calibration error test to document
the calibration (both NO and NOX modes, as
applicable). Fill a Tedlar or equivalent bag
approximately half full with either ambient
air, pure oxygen, or an oxygen standard gas
with at least 19.5 percent by volume oxygen
content. Fill the remainder of the bag with
mid- to high-level NO in N2 (or other
appropriate concentration) calibration gas.
(Note that the concentration of the NO
standard should be sufficiently high enough
for the diluted concentration to be easily and
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accurately measured on the scale used. The
size of the bag should be large enough to
accommodate the procedure and time
required. Contact the bag manufacturer for
guidance on the applicability of Tedlar
equivalent materials for NO.)
*
*
*
*
*
40. Amend Method 8 of Appendix A–
4 to Part 60 as follows:
a. By revising Sections 11.2.1 and
11.2.2.
b. By revising two definitions in
Section 12.1.
c. By revising Figure 8–1.
Method 8—Determination of Sulfuric Acid
Mist and Sulfur Dioxide Emissions From
Stationary Sources
*
*
*
*
*
11.2.1 Container No. 1. Shake the
container holding the isopropanol solution
and the filter. If the filter breaks up, allow the
fragments to settle for a few minutes before
removing a sample aliquot. For
determination of SO3/H2SO4 concentration,
pipette a 10-ml aliquot of this solution into
a 250-ml Erlenmeyer flask, add 2 to 4 drops
of thorin indicator, and titrate to a pink
endpoint using 0.0100 N barium standard
solution. Repeat the titration with a second
aliquot of sample, and average the titration
values. Replicate titrations must agree within
1 percent or 0.2 ml, whichever is greater.
11.2.2 Container No. 2. Thoroughly mix
the solution in the container holding the
contents of the second and third impingers.
For determination of SO2 concentration,
pipette a 100-ml aliquot of sample into a 250ml Erlenmeyer flask. Add 40 ml of
isopropanol, 2 to 4 drops of thorin indicator,
and titrate to a pink endpoint using 0.0100
N barium standard solution. Repeat the
titration with a second aliquot of sample, and
average the titration values. Replicate
titrations must agree within 1 percent or 0.2
ml, whichever is greater.
*
*
*
*
*
12.1 * * *
Va = Volume of sample aliquot titrated, 10 ml
for H2SO4 and 100 ml for SO2.
Vsoln = Total volume of solution in which the
sample is contained, 1000 ml for the SO2
sample and 250 ml for the H2SO4
sample.
*
*
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*
*
*
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*
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*
*
*
*
41. Amend Method 10 of Appendix
A–4 to Part 60 by revising Sections 6.2.5
and 8.4.2 to read as follows:
Method 10—Determination of Carbon
Monoxide Emissions From Stationary
Sources
*
*
*
*
*
tkelley on DSK3SPTVN1PROD with PROPOSALS2
6.2.5 Flexible Bag. Tedlar, or equivalent,
with a capacity of 60 to 90 liters (2 to 3 ft 3).
(Contact the bag manufacturer for guidance
on the applicability of Tedlar equivalent
materials for the compound of interest.) Leaktest the bag in the laboratory before using by
evacuating with a pump followed by a dry
gas meter. When the evacuation is complete,
there should be no flow through the meter.
Gas tanks may be used in place of bags if the
samples are analyzed within one week.
*
*
*
*
*
8.4.2 Integrated Sampling. Evacuate the
flexible bag. Set up the equipment as shown
in Figure 10–1 with the bag disconnected.
Place the probe in the stack and purge the
sampling line. Connect the bag, making sure
that all connections are leak-free. Sample at
a rate proportional to the stack velocity. If
needed, the CO2 content of the gas may be
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determined by using the Method 3 integrated
sample procedures, or by weighing an
ascarite CO2 removal tube used and
computing CO2 concentration from the gas
volume sampled and the weight gain of the
tube. Data may be recorded on a form similar
to Table 10–1. If a tank is used for sample
collection, follow procedures similar to those
in Sections 8.1.2, 8.2.3, 8.3, and 12.4 of
Method 25 as appropriate to prepare the tank,
conduct the sampling, and correct the
measured sample concentration.
2.0 Summary of Method
An integrated gas sample is extracted from
the stack, passed through an alkaline
permanganate solution to remove sulfur
oxides and nitrogen oxides, and collected in
a Tedlar or equivalent bag. (Contact the bag
manufacturer for guidance on the
applicability of Tedlar equivalent materials
for the compound of interest.) The CO
concentration in the sample is measured
spectrophotometrically using the reaction of
CO with p-sulfaminobenzoic acid.
*
*
*
*
*
42. Amend Method 10A of Appendix
A–4 to Part 60 as follows:
a. By revising Section 2.0.
b. By revising Sections 8.2.1 and
8.2.3.
c. By revising Sections 11.1 and 11.2.
d. By revising the narrative in Section
12.3.
e. By revising Section 13.5.
*
Method 10A—Determination of Carbon
Monoxide Emissions in Certifying
Continuous Emission Monitoring Systems at
Petroleum Refineries
8.2.3 Purge the system with sample gas
by inserting the probe into the stack and
drawing the sample gas through the system
at 300 ml/min ±10 percent for 5 minutes.
Connect the evacuated bag to the system,
*
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*
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*
*
*
*
8.2.1 Evacuate the bag completely using a
vacuum pump. Assemble the apparatus as
shown in Figure 10A–1. Loosely pack glass
wool in the tip of the probe. Place 400 ml of
alkaline permanganate solution in the first
two impingers and 250 ml in the third.
Connect the pump to the third impinger, and
follow this with the surge tank, rate meter,
and 3-way valve. Do not connect the bag to
the system at this time.
*
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record the starting time, and sample at a rate
of 300 ml/min for 30 minutes, or until the
bag is nearly full. Record the sampling time,
the barometric pressure, and the ambient
temperature. Purge the system as described
above immediately before each sample.
*
*
*
*
*
11.1 Assemble the system shown in
Figure 10A–3, and record the information
required in Table 10A–1 as it is obtained.
Pipet 10.0 ml of the colorimetric reagent into
each gas reaction bulb, and attach the bulbs
to the system. Open the stopcocks to the
reaction bulbs, but leave the valve to the bag
closed. Turn on the pump, fully open the
coarse-adjust flow valve, and slowly open the
fine-adjust valve until the pressure is
reduced to at least 40 mm Hg. Now close the
coarse adjust valve, and observe the
manometer to be certain that the system is
leak-free. Wait a minimum of 2 minutes. If
the pressure has increased less than 1 mm
Hg, proceed as described below. If a leak is
present, find and correct it before proceeding
further.
11.2 Record the vacuum pressure (Pv) to
the nearest 1 mm Hg, and close the reaction
bulb stopcocks. Open the bag valve, and
allow the system to come to atmospheric
pressure. Close the bag valve, open the pump
coarse adjust valve, and evacuate the system
again. Repeat this fill/evacuation procedure
at least twice to flush the manifold
completely. Close the pump coarse adjust
valve, open the bag valve, and let the system
fill to atmospheric pressure. Open the
stopcocks to the reaction bulbs, and let the
entire system come to atmospheric pressure.
Close the bulb stopcocks, remove the bulbs,
record the room temperature and barometric
pressure (Pbar, to nearest mm Hg), and place
the bulbs on the shaker table with their main
axis either parallel to or perpendicular to the
plane of the table top. Purge the bulb-filling
system with ambient air for several minutes
between samples. Shake the samples for
exactly 2 hours.
*
*
*
*
*
12.3 CO Concentration in the Bag.
Calculate Cb using Equations 10A–2 and
10A–3. If condensate is visible in the bag,
calculate Bw using Table 10A–2 and the
temperature and barometric pressure in the
analysis room. If condensate is not visible,
calculate Bw using the temperature and
barometric pressure at the sampling site.
* * *
tkelley on DSK3SPTVN1PROD with PROPOSALS2
*
*
*
*
*
13.5 Stability. The individual
components of the colorimetric reagent are
stable for at least one month. The
colorimetric reagent must be used within two
days after preparation to avoid excessive
blank correction. The samples in the bag
should be stable for at least one week if the
bags are leak-free.
*
*
*
*
*
43. Amend Method 10B of Appendix
A–4 to Part 60 by revising Sections 2.1
and 6.2.3, and by revising the narrative
in Section 12.2 to read as follows:
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Method 10B—Determination of Carbon
Monoxide Emissions From Stationary
Sources
*
*
*
*
*
2.1 An integrated gas sample is extracted
from the sampling point, passed through a
conditioning system to remove interferences,
and collected in a Tedlar or equivalent bag.
(Contact the bag manufacturer for guidance
on the applicability of Tedlar equivalent
materials for the compound of interest.) The
CO is separated from the sample by gas
chromatography (GC) and catalytically
reduced to methane (CH4) which is
determined by flame ionization detection
(FID). The analytical portion of this method
is identical to applicable sections in Method
25 detailing CO measurement.
*
*
*
*
*
6.2.3 Sample Injection System. Same as
in Method 25, Section 6.3.1.4, equipped to
accept a sample line from the bag.
*
*
*
*
*
12.2 CO Concentration in the Bag.
Calculate Cb using Equations 10B–1 and 10B–
2. If condensate is visible in the bag,
calculate Bw using Table 10A–2 of Method
10A and the temperature and barometric
pressure in the analysis room. If condensate
is not visible, calculate Bw using the
temperature and barometric pressure at the
sampling site. * * *
*
*
*
*
*
44. Amend Method 11 of Appendix
A–5 to Part 60 by revising Sections 8.5
and 10.1.2 to read as follows:
Appendix A–5 to Part 60—Test
Methods 11 Through 15A
*
*
*
*
*
Method 11—Determination of Hydrogen
Sulfide Content of Fuel Gas Streams in
Petroleum Refineries
*
*
*
*
*
8.5 Sample for at least 10 minutes. At the
end of the sampling time, close the sampling
valve, and record the final volume and
temperature readings. Conduct a leak-check
as described in Section 8.2. A yellow color
in the final cadmium sulfate impinger
indicates depletion of the absorbing solution.
An additional cadmium sulfate impinger
should be added for subsequent samples and
the sample with yellow color in the final
impinger should be voided.
*
*
*
*
*
10.1.2 Temperature Sensors. Calibrate
against mercury-in-glass thermometers. An
alternative mercury-free thermometer may be
used if the thermometer is at a minimum
equivalent in terms of performance or
suitably effective for the specific temperature
measurement application.
*
*
*
*
*
45. Amend Method 12 of Appendix
A–5 to Part 60 by revising Section 16.1
and adding Sections 16.4, 16.4.1, and
16.4.2 to read as follows:
Method 12—Determination of Inorganic
Lead Emissions From Stationary Sources
*
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*
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*
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*
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16.1 Simultaneous Determination of
Particulate Matter and Lead Emissions.
Method 12 may be used to simultaneously
determine Pb provided: (1) acetone is used to
remove particulate from the probe and inside
of the filter holder as specified by Method 5,
(2) 0.1 N HNO3 is used in the impingers, (3)
a glass fiber filter with a low Pb background
is used, and (4) the entire train contents,
including the impingers, are treated and
analyzed for Pb as described in Sections 8.0
and 11.0 of this method.
*
*
*
*
*
16.4 Alternative Analyzer. Inductively
coupled plasma-atomic emission
spectrometry (ICP–AES) may be used as an
alternative to atomic absorption analysis
provided the following conditions are met:
16.4.1 Sample collection, sample
preparation, and analytical preparation
procedures are as defined in the method
except as necessary for the ICP–AES
application.
16.4.2 The limit of quantitation for the
ICP–AES must be demonstrated, and the
sample concentrations reported should be no
less than two times the limit of quantitation.
The limit of quantitation is defined as ten
times the standard deviation of the blank
value. The standard deviation of the blank
value is determined from the analysis of
seven blanks. It has been reported that for
mercury and those elements that form
hydrides, a continuous-flow generator
coupled to an ICP–AES offers detection
limits comparable to cold vapor atomic
absorption.
*
*
*
*
*
46. Amend Method 14A of Appendix
A–5 to Part 60 by adding a sentence to
the end of Section 10.1.1 to read as
follows:
Method 14A — Determination of Total
Fluoride Emissions From Selected Sources at
Primary Aluminum Production Facilities
*
*
*
*
*
10.1.1 Metering system. * * * Allowable
tolerances for Y and DH@ are given in Figure
5–5 of Method 5 of this appendix.
*
*
*
*
*
47. Amend Method 16A of Appendix
A–6 to Part 60 by revising Section 1.2
to read as follows:
Appendix A–6 to Part 60—Test
Methods 16 Through 18
*
*
*
*
*
Method 16A—Determination of Total
Reduced Sulfur Emissions From Stationary
Sources (Impinger Technique)
*
*
*
*
*
1.2 Applicability. This method is
applicable for the determination of TRS
emissions from recovery boilers, lime kilns,
and smelt dissolving tanks at kraft pulp
mills, reduced sulfur compounds (H2S,
carbonyl sulfide, and carbon disulfide) from
sulfur recovery units at onshore natural gas
processing facilities, and from other sources
when specified in an applicable subpart of
the regulations. The flue gas must contain at
least 1 percent oxygen for complete oxidation
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of all TRS to SO2. Note: If sources other than
kraft pulp mills experience low oxygen levels
in the emissions, the method results may be
biased low.
positive displacement pump. Verify the
dilution factors before sampling each bag
through dilution and analysis of gases of
known concentration.
*
*
*
*
*
*
48. Amend Method 18 of Appendix
A–6 to Part 60 as follows:
a. By revising Sections 8.2.1.1.2,
8.2.1.4, 8.2.1.4.2.
b. By adding 8.2.1.5.2.2.
c. By revising Sections 16.1.1.12, and
16.1.3.2.
d. By revising the titles to Figures 18–
3 and 18–10.
Method 18—Measurement of Gaseous
Organic Compound Emissions by Gas
Chromatography
*
*
*
*
*
*
*
*
*
8.2.1.4 Other Modified Bag Sampling
Procedures. In the event that condensation is
observed in the bag while collecting the
sample and a direct interface system cannot
be used, heat the bag during collection and
maintain it at a suitably elevated temperature
during all subsequent operations. (Note: Take
care to leak-check the system prior to the
dilutions so as not to create a potentially
explosive atmosphere.) As an alternative,
collect the sample gas, and simultaneously
dilute it in the bag.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
*
*
*
*
*
8.2.1.4.2 Second Alternative Procedure.
Prefill the bag with a known quantity of inert
gas. Meter the inert gas into the bag according
to the procedure for the preparation of gas
concentration standards of volatile liquid
materials (Section 10.1.2.2), but eliminate the
midget impinger section. Take the partly
filled bag to the source, and meter the source
gas into the bag through heated sampling
lines and a heated flowmeter, or Teflon
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*
*
*
*
*
*
*
*
16.1.1.12 Flexible Bags. Tedlar or
equivalent, 10- and 50-liter capacity, for
preparation of standards. (Contact the bag
manufacturer for guidance on the
applicability of Tedlar equivalent materials
for the compound of interest.)
*
*
8.2.1.1.2 Sampling Procedure. To obtain a
sample, assemble the sample train as shown
in Figure 18–9. Leak-check both the bag and
the container. Connect the vacuum line from
the needle valve to the Teflon sample line
from the probe. Place the end of the probe
at the centroid of the stack or at a point no
closer to the walls than 1 m, and start the
pump. Set the flow rate so that the final
volume of the sample is approximately 80
percent of the bag capacity. After allowing
sufficient time to purge the line several
times, connect the vacuum line to the bag,
and evacuate until the rotameter indicates no
flow. Then position the sample and vacuum
lines for sampling, and begin the actual
sampling, keeping the rate proportional to
the stack velocity. As a precaution, direct the
gas exiting the rotameter away from sampling
personnel. At the end of the sample period,
shut off the pump, disconnect the sample
line from the bag, and disconnect the vacuum
line from the bag container. Record the
source temperature, barometric pressure,
ambient temperature, sampling flow rate, and
initial and final sampling time on the data
sheet shown in Figure 18–10. Protect the bag
and its container from sunlight. Record the
time lapsed between sample collection and
analysis, and then conduct the recovery
procedure in Section 8.4.2.
*
8.2.1.5.2.2 Analyze the two field audit
samples as described in Section 9.2 by
connecting each bag containing an audit gas
mixture to the sampling valve. Calculate the
results; record and report the data to the
audit supervisor.
*
*
*
*
16.1.3.2 Flexible Bag Procedure. Any
leak-free plastic (e.g., Tedlar, Mylar, Teflon)
or plastic-coated aluminum (e.g., aluminized
Mylar) bag, or equivalent, can be used to
obtain the pre-survey sample. Use new bags,
and leak-check them before field use. In
addition, check the bag before use for
contamination by filling it with nitrogen or
air and analyzing the gas by GC at high
sensitivity. Experience indicates that it is
desirable to allow the inert gas to remain in
the bag about 24 hours or longer to check for
desorption of organics from the bag. Follow
the leak-check and sample collection
procedures given in Section 8.2.1.
*
*
*
*
*
Figure 18–3. Preparation of Standards in
Tedlar or Tedlar-Equlivalent Bags and
Calibration Curve
*
*
*
*
*
Figure 18–10. Field Sample Data Sheet—
Tedlar or Tedlar-Equivalent Bag Collection
Method
*
*
*
*
*
49. Amend Method 23 of Appendix
A–7 to Part 60 by revising Sections
2.2.7, 4.1.1.3, and 4.2.7 to read as
follows:
Appendix A–7 to Part 60—Test
Methods 19 Through 25E
*
*
*
*
*
Method 23—Determination of
Polychlorinated Dibenzo-p-Dioxins and
Polychlorinated Dibenzofurans From
Stationary Sources
*
*
*
*
*
2.2.7 Storage Container. Air-tight
container to store silica gel.
*
*
*
*
*
4.1.1.3 Sample Train. It is suggested that
all components be maintained according to
the procedure described in APTD–0576.
Alternative mercury-free thermometers may
be used if the thermometers are, at a
minimum, equivalent in terms of
performance or suitably effective for the
specific temperature measurement
application.
*
*
*
*
*
4.2.7 Silica Gel. Note the color of the
indicating silica gel to determine if it has
been completely spent and make a mention
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of its condition. Transfer the silica gel from
the fifth impinger to its original container
and seal. If a moisture determination is made,
follow the applicable procedures in sections
8.7.6.3 and 11.2.3 of Method 5 to handle and
weigh the silica gel. If moisture is not
measured, the silica gel may be disposed.
*
*
*
*
*
50. Amend Method 24 of Appendix
A–7 to Part 60 by revising Section 11.2.2
to read as follows:
Method 24—Determination of Volatile
Matter Content, Water Content, Density,
Volume Solids, and Weight Solids of Surface
Coatings
*
*
*
*
*
11.2.2 Volatile Content. To determine
total volatile content, use the apparatus and
reagents described in ASTM D2369
(incorporated by reference; see § 60.17 for the
approved versions of the standard),
respectively, and use the following
procedures:
*
*
*
*
*
51. Amend Method 25 of Appendix
A–7 to Part 60 by revising Section 7.1.3
to read as follows:
Method 25—Determination of Total Gaseous
Nonmethane Organic Emissions as Carbon
*
*
*
*
*
7.1.3 Filters. Glass fiber filters, without
organic binder, exhibiting at least 99.95
percent efficiency (< 0.05 percent
penetration) on 0.3 micron dioctyl phthalate
smoke particles. The filter efficiency test
shall be conducted in accordance with ASTM
Method D2986–71, 78, or 95a (incorporated
by reference—see § 60.17). Test data from the
supplier’s quality control program are
sufficient for this purpose.
*
*
*
*
*
52. Amend Method 25C of Appendix
A–7 to Part 60 as follows:
a. By revising Sections 6.1.
b. By adding a new Section 8.2.3.
c. By revising Section 12.1.
d. By redesignating Equation 25C–2 in
Section 12.3 as Equation 25C–3.
c. By redesignating Section 12.3 as
Section 12.4.
d. By adding new Section 12.3.
Method 25C—Determination of Nonmethane
Organic Compounds (NMOC) in MSW
Landfill Gases
*
*
*
*
*
6.1 Sample Probe. Stainless steel, with
the bottom third perforated. Teflon probe
liners and sampling lines are also allowed.
Non-perforated probes are allowed as long as
they are withdrawn to create a gap equivalent
to having the bottom third perforated. The
sample probe must be capped at the bottom
and must have a threaded cap with a
sampling attachment at the top. The sample
probe must be long enough to go through and
extend no less than 0.9 m (3 ft) below the
landfill cover. If the sample probe is to be
driven into the landfill, the bottom cap
should be designed to facilitate driving the
probe into the landfill.
*
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09JAP2
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*
12.1 Nomenclature.
Bw = Moisture content in the sample,
fraction.
CN2 = Measured N2 concentration (by Method
3C), fraction.
*
*
*
*
*
53. Amend Method 25D of Appendix
A–7 to Part 60 by revising the first
sentence in Section 9.1 to read as
follows:
Method 25D—Determination of the Volatile
Organic Concentration of Waste Samples
*
*
*
*
*
9.1 Quality Control Samples. If audit
samples are not available, prepare and
analyze the two types of quality control
samples (QCS) listed in Sections 9.1.1 and
9.1.2. * * *
*
*
*
*
*
54. Amend Method 26 of Appendix
A–8 as follows:
a. By revising Sections 6.1.1 and 8.1.2.
b. By redesignating Sections 16 and
17 as Sections 17 and 18, respectively.
c. By adding a new Section 16.
*
*
*
*
Method 26—Determination of Hydrogen
Halide and Halogen Emissions From
Stationary Sources Non-Isokinetic Method
tkelley on DSK3SPTVN1PROD with PROPOSALS2
*
*
*
*
r = Total number of analyzer injections of
sample tank during analysis (where j =
injection number, 1 * * * r).
Tt = Sample tank temperature at completion
of sampling, °K.
Tti = Sample tank temperature before
sampling, °K.
Ttf = Sample tank temperature after
pressurizing, °K.
to remove particulate matter from the gas
stream (see Section 6.1.6).
56. Amend Method 30B of Appendix
A–8 to Part 60 as follows:
*
a. By revising the first paragraph in
Section 8.2.2.1.
*
6.1.1 Probe. Borosilicate glass,
approximately 3⁄8-in. (9-mm) I.D. with a
heating system capable of maintaining a
probe gas temperature during sampling of
120 ± 14 °C (248 ± 25 °F) to prevent moisture
condensation; or Teflon where stack probes
are below 210 °C. If HF is a target analyte,
then preconditioning of new teflon
components by heating should be considered
to prevent potential HF outgassing. A Teflonglass filter in a mat configuration should be
installed in the gas stream, not the filter box,
18:29 Jan 06, 2012
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*
*
*
*
*
Alternative Procedures
*
*
*
Method 26A. Method 26A, which uses
isokinetic sampling equipment, is an
acceptable alternative to Method 26.
*
*
*
*
*
55. Amend Method 29 of Appendix
A–8 as follows:
a. By redesignating Sections 16 and 17
as Sections 17 and 18, respectively.
b. By adding a new Section 16.
Method 29—Determination of Metals
Emissions From Stationary Sources
*
*
16.0
Alternative Procedures
*
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12.3 Measured N2 Concentration
Correction. Use the following equation to
correct the measured concentration of N2 as
determined by Method 3C for dilution.
b. By revising Table 9–1 in Section 9.
c. By revising Section 10.3.
d. By revising the first paragraph in
Section 11.3.
Method 30B—Determination of Total Vapor
Phase Mercury Emissions From Coal-Fired
Combustion Sources Using Carbon Sorbent
Traps
*
*
*
*
*
8.2.2.1 Determination of Minimum
Calibration Concentration or Mass. Based on
your instrument’s sensitivity and linearity,
determine the calibration concentrations or
masses that make up a representative low
level calibration range. Verify that you are
able to meet the multipoint calibration
performance criteria in section 11.0 of this
method. Select a calibration concentration or
mass that is no less than 2 times the lowest
concentration or mass in your calibration
curve. The lowest point in your calibration
curve must be at least 5, and preferably 10,
times the Method Detection Limit (MDL),
which is the minimum amount of the analyte
that can be detected and reported. The MDL
must be determined at least once for the
analytical system using an MDL study such
as that found in section 15.0 of the EPA
Method 301 (76 FR 28673, 5/18/2011). * * *
*
16.1 Alternative Analyzer. Samples may
also be analyzed by cold vapor atomic
fluorescence spectrometry.
*
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*
8.1.2 Adjust the probe temperature and
the temperature of the filter and the stopcock
(i.e., the heated area in Figure 26–1) to a
temperature sufficient to prevent water
condensation. This temperature should be
greater than 120 °C (248 °F). The temperature
should be monitored throughout a sampling
run to ensure that the desired temperature is
maintained. It is important to maintain a
temperature around the probe and filter of
greater than 120 °C (248 °F) since it is
extremely difficult to purge acid gases off
these components. (These components are
not quantitatively recovered and, hence, any
collection of acid gases on these components
would result in potential underreporting of
these emissions. The applicable subparts may
specify alternative higher temperatures.)
16.0
Appendix A–8 to Part 60—Test
Methods 26 Through 30B
*
CN2Corr = Measured N2 concentration
corrected for dilution, fraction.
Ct = Calculated NMOC concentration, ppmv
C equivalent.
Ctm = Measured NMOC concentration, ppmv
C equivalent.
Pb = Barometric pressure, mm Hg.
Pt = Gas sample tank pressure after sampling,
but before pressurizing, mm Hg absolute.
Ptf = Final gas sample tank pressure after
pressurizing, mm Hg absolute.
Pti = Gas sample tank pressure after
evacuation, mm Hg absolute.
Pw = Vapor pressure of H2O (from Table 25C–
1), mm Hg.
9.0
*
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Quality Assurance and Quality Control
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*
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8.2.3 Driven Probes. Closed-point probes
may be driven directly into the landfill in a
single step. This method may not require
backfilling if the probe is adequately sealed
by its insertion. Unperforated probes that are
inserted in this manner and withdrawn a
distance from a detachable tip to create an
open space are also acceptable.
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
1161
TABLE 9–1—QUALITY ASSURANCE/QUALITY CONTROL CRITERIA FOR METHOD 30B
QA/QC test or specification
Acceptance criteria
Frequency
Consequences if not met
Gas flow meter calibration (At 3
settings or points).
Calibration factor (Yi) at each flow
rate must be within ± 2% of the
average value (Y).
Calibration factor (Yi) must be
within ± 5% of the Y value from
the most recent 3-point calibration.
Prior to initial use and when posttest check is not within ± 5% of
Y.
After each field test. For mass
flow meters, must be done onsite, using stack gas.
Recalibrate at 3 points until the
acceptance criteria are met.
Absolute temperature measures
by sensor within ± 1.5% of a
reference sensor.
Absolute pressure measured by
instrument within ± 10 mm Hg
of reading with a mercury barometer or NIST traceable barometer.
≤ 4% of target sampling rate ........
Prior to initial use and before
each test thereafter.
Gas flow meter post-test calibration check (Single-point).
Temperature sensor calibration .....
Barometer calibration .....................
Pre-test leak check ........................
Post-test leak check ......................
Analytical matrix interference test
(wet chemical analysis, only).
Analytical bias test .........................
Multipoint analyzer calibration .......
Analysis of independent calibration
standard.
≤ 4% of average sampling rate .....
Establish minimum dilution (if any)
needed to eliminate sorbent
matrix interferences.
Average recovery between 90%
and 110% for Hg0 and HgCl2 at
each of the 2 spike concentration levels.
Each analyzer reading within
± 10% of true value and r2≥
0.99.
Within ± 10% of true value ...........
Recalibrate gas flow meter at 3
points to determine a new value
of Y. For mass flow meters,
must be done on-site, using
stack gas. Apply the new Y
value to the field test data.
Recalibrate; sensor may not be
used until specification is met.
Prior to initial use and before
each test thereafter.
Recalibrate; instrument may not
be used until specification is
met.
Prior to sampling ..........................
Sampling shall not commence
until the leak check is passed.
Sample invalidated.*
Field sample results not validated.
After sampling ...............................
Prior to analyzing any field samples; repeat for each type of
sorbent used.
Prior to analyzing field samples
and prior to use of new sorbent
media.
Field samples shall not be analyzed until the percent recovery
criteria has been met.
On the day of analysis, before
analyzing any samples.
Recalibrate until successful.
Following daily calibration, prior to
analyzing field samples.
Analysis of continuing calibration
verification standard (CCVS).
Within ±10% of true value ............
Following daily calibration, after
analyzing ≤ 10 field samples,
and at end of each set of analyses.
Test run total sample volume ........
Within ± 20% of total volume sampled during field recovery test.
For compliance/emissions testing:
Each individual sample .................
Recalibrate and repeat independent standard analysis until
successful.
Recalibrate and repeat independent standard analysis, reanalyze samples until successful, if possible; for destructive
techniques, samples invalidated.
Sample invalidated.
Every sample ................................
Sample invalidated.*
Every run ......................................
Run invalidated.*
All Section 1 samples where
stack Hg concentration is ≥ 0.5
μg/dscm.
Reanalyze at more concentrated
level if possible, samples invalidated if not within calibrated
range.
Expand bounds of Hg0 and HgCl2
Analytical Bias Test; if not successful, samples invalidated.
Sorbent trap
through.
section
2
break-
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Paired sorbent trap agreement ......
Sample analysis .............................
Sample analysis .............................
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≤ 10% of section 1 Hg mass for
Hg concentrations > 1 μg/dscm;
≤ 20% of section 1 Hg mass for
Hg concentrations ≤ 1 μg/dscm
For relative accuracy testing:
≤ 10% of section 1 Hg mass for
Hg concentrations > 1 μg/dscm;
≤ 20% of section 1 Hg mass for
Hg concentrations ≤ 1 μg/dscm
and > 0.5 μg/dscm;
≤ 50% of section 1 Hg mass for
Hg concentrations ≤ 0.5 μg/
dscm > 0.1 μg/dscm;
No criterion for Hg concentrations
≤ 0.1 μg/dscm (must meet all
other QA/QC specifications).
≤ 10% Relative Deviation (RD)
mass for Hg concentrations > 1
μg/dscm;
≤ 20% RD or ≤ 0.2 μg/dscm absolute difference for Hg concentrations ≤ 1 μg/dscm.
Within valid calibration range
(within calibration curve).
Within bounds of Hg0 and HgCl2
Analytical Bias Test.
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Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
TABLE 9–1—QUALITY ASSURANCE/QUALITY CONTROL CRITERIA FOR METHOD 30B—Continued
QA/QC test or specification
Acceptance criteria
Frequency
Consequences if not met
Field recovery test .........................
Average recovery between 85%
and 115% for Hg0.
Once per field test ........................
Field sample runs not validated
without successful field recovery test.
* And data from the pair of sorbent traps are also invalidated.
*
*
*
*
*
10.3 Thermocouples and Other
Temperature Sensors. Use the procedures
and criteria in Section 10.3 of Method 2 in
Appendix A–1 to this part to calibrate instack temperature sensors and
thermocouples. Dial thermometers shall be
calibrated against mercury-in-glass
thermometers or equivalent. * * *
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*
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11.3 Field Sample Analyses. Analyze the
sorbent trap samples following the same
procedures that were used for conducting the
Hg0 and HgCl2 analytical bias tests. The
individual sections of the sorbent trap and
their respective components must be
analyzed separately (i.e., section 1 and its
components, then section 2 and its
components). All sorbent trap section 1
sample analyses must be within the
calibrated range of the analytical system as
specified in Table 9–1. For wet analyses, the
sample can simply be diluted to fall within
the calibrated range. However, for the
destructive thermal analyses, samples that
are not within the calibrated range cannot be
re-analyzed. As a result, the sample cannot
be validated, and another sample must be
collected. It is strongly suggested that the
analytical system be calibrated over multiple
ranges so that thermally analyzed samples do
fall within the calibrated range. The total
mass of Hg measured in each sorbent trap
section 1 must also fall within the lower and
upper mass limits established during the
initial Hg0 and HgCl2 analytical bias test. If
a sample is analyzed and found to fall
outside of these limits, it is acceptable for an
additional Hg0 and HgCl2 analytical bias test
to be performed that now includes this level.
However, some samples (e.g., the mass
collected in trap section 2), may have Hg
levels so low that it may not be possible to
quantify them in the analytical system’s
calibrated range. Because a reliable estimate
of these low-level Hg measurements is
necessary to fully validate the emissions
data, the MDL (see section 8.2.2.1 of this
method) is used to establish the minimum
amount that can be detected and reported. If
the measured mass or concentration is below
the lowest point in the calibration curve and
above the MDL, the analyst must do the
following: Estimate the mass or concentration
of the sample based on the analytical
instrument response relative to an additional
calibration standard at a concentration or
mass between the MDL and the lowest point
in the calibration curve. This is
accomplished by establishing a response
factor (e.g., area counts per Hg mass or
concentration) and estimating the amount of
Hg present in the sample based on the
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analytical response and this response factor.
* * *
*
*
*
*
*
57. Amend Performance Specification
1 of Appendix B to Part 60 by revising
Section 3.5 to read as follows:
Appendix B to Part 60—Performance
Specifications
*
*
*
*
*
Performance Specification 1—Specifications
and Test Procedures for Continuous Opacity
Monitoring Systems in Stationary Sources
*
*
*
*
*
3.5 Full Scale. The maximum data
display output of the COMS. For purposes of
recordkeeping and reporting, full scale will
be greater than 80 percent opacity.
Note: ‘‘Full scale’’ means ‘‘span.’’
*
*
*
*
*
58. Amend Performance Specification
3 of Appendix B to Part 60 by revising
Section 13.2 to read as follows:
Performance Specification 3—Specifications
and Test Procedures for O2 and CO2
Continuous Emission Monitoring Systems in
Stationary Sources
*
*
*
*
*
13.2 CEMS Relative Accuracy
Performance Specification. The RA of the
CEMS must be no greater than 20 percent of
the mean value of the RM test data or 1.0
percent O2 or CO2, whichever is greater.
*
*
*
*
*
59. Amend Performance Specification
4 of Appendix B to Part 60 by revising
Section 8.2 to read as follows:
Performance Specification 4—Specifications
and Test Procedures for Carbon Monoxide
Continuous Emission Monitoring Systems in
Stationary Sources
*
*
*
*
*
8.2 Reference Methods. Unless otherwise
specified in an applicable subpart of the
regulation, Method 10, 10A, 10B, or other
approved alternative are the RM for this PS.
*
*
*
*
*
60. Amend Performance Specification
4B of Appendix B to Part 60 by revising
Section 7.1.1 to read as follows:
Performance Specification 4B—
Specifications and Test Procedures for
Carbon Monoxide and Oxygen Continuous
Monitoring Systems in Stationary Sources
*
*
*
*
*
7.1.1 Calculations. Summarize the results
on a data sheet. Average the differences
between the instrument response and the
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certified cylinder gas value for each gas.
Calculate the CE results for the CO monitor
according to:
CE = | d/FS | × 100 (1)
Where d is the mean difference between
the CEMS response and the known reference
concentration, and FS is the span value. The
CE for the O2 monitor is the average percent
O2 difference between the O2 monitor and the
certified cylinder gas value for each gas.
*
*
*
*
*
61. Amend Performance Specification
7 of Appendix B to Part 60 by revising
Section 8.4 and adding a reference to
the end of Section 16.0. to read as
follows:
Performance Specification 7—Specifications
and Test Procedures for Hydrogen Sulfide
Continuous Emission Monitoring Systems in
Stationary Sources
*
*
*
*
*
8.4 Relative Accuracy Test Procedure.
8.4.1 Sampling Strategy for RM Tests,
Number of RM Tests, Correlation of RM and
CEMS Data, and Calculations. These are the
same as that in PS–2, Sections 8.4.3 (except
as specified below), 8.4.4, 8.4.5, and 8.4.6,
respectively.
8.4.2 Reference Methods. Unless
otherwise specified in an applicable subpart
of the regulation, Methods 11, 15, and 16
may be used for the RM for this PS.
8.4.2.1 Sampling Time Per Run—Method
11. A sampling run, when Method 11
(integrated sampling) is used, shall consist of
a single measurement for at least 10 minutes
and 0.010 dscm (0.35 dscf). Each sample
shall be taken at approximately 30-minute
intervals.
8.4.2.2 Sampling Time Per Run—
Methods 15 and 16. The sampling run shall
consist of two injections equally spaced over
a 30-minute period following the procedures
described in the particular method.
Note: Caution! Heater or non-approved
electrical probes should not be used around
explosive or flammable sources.
*
*
16.0
References
*
*
*
*
*
*
*
*
5. Letter to RAMCON Environmental Corp.
from Robert Kellam, December 27, 1992.
*
*
*
*
*
62. Amend Performance Specification
11 of Appendix B to Part 60 by revising
Sections 12.1(1) and (2) to read as
follows:
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Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
Performance Specification 11—
Specifications and Test Procedures for
Particulate Matter Continuous Emission
Monitoring Systems at Stationary Sources
*
*
*
*
12.1 * * *
(1) Calculate the upscale drift (UD) using
Equation 11–1:
*
Where:
UD = The upscale (high-level) drift of your
PM CEMS in percent,
RCEM= The measured PM CEMS response to
the upscale reference standard, and
RU= The pre-established numerical value of
the upscale reference standard.
FS = Full-scale value.
(2) Calculate the zero drift (ZD) using
Equation 11–2:
Where:
ZD = The zero (low-level) drift of your PM
CEMS in percent,
RCEM= The measured PM CEMS response to
the zero reference standard,
RL = The pre-established numerical value of
the zero reference standard, and
FS = Full-scale value.
is not accessible, you may be required to shut
down the emissions unit to repair or replace
a sensor. Conduct a new RATA after
replacing a sensor that supplies a critical
PEMS parameter if the new sensor provides
a different output or scaling or changes the
historical training dataset of the PEMS.
Replacement of a non-critical sensor that
does not cause an impact in the accuracy of
the PEMS does not trigger a RATA. All
sensors must be calibrated as often as needed
but at least as often as recommended by the
manufacturers.
Performance Specification 15—Performance
Specification for Extractive FTIR Continuous
Emission Monitoring Systems in Stationary
Sources
11.1.1.4.3 Continuous Emission Monitors
as RMs. If the RM is a CEM, synchronize the
sampling flow rates of the RM and the FTIR
CEM. Each run is at least 1 hour long and
consists of at least 10 FTIR CEM
measurements and the corresponding 10 RM
measurements (or averages). For the
statistical comparison, use the relative
accuracy analysis procedure in Performance
Specification 2 of Appendix B of 40 CFR part
60. If the RM time constant is < 1⁄2 the FTIR
CEM time constant, brief fluctuations in
analyte concentrations that are not
adequately measured with the slower FTIR
CEM time constant can be excluded from the
run average along with the corresponding RM
measurements. However, the FTIR CEM run
average must still include at least 10
measurements over a 1-hour period.
*
*
*
*
*
*
*
63. Amend Performance Specification
15 of Appendix B to Part 60 by revising
Sections 11.1.1.4.2 and 11.1.1.4.3 to
read as follows:
*
*
*
*
11.1.1.4.2 RMs Using a Grab Sampling
Technique. Synchronize the RM and FTIR
CEM measurements as closely as possible.
For a grab sampling RM, record the volume
collected and the exact sampling period for
each sample. Synchronize the FTIR CEM so
that the FTIR measures a spectrum of a
similar cell volume at the same time as the
RM grab sample was collected. Measure at
least five independent samples with both the
FTIR CEM and the RM for each of the
minimum nine runs. Compare the run
concentration averages by using the relative
accuracy analysis procedure in Performance
Specification 2 of Appendix B of 40 CFR part
60.
*
*
*
*
64. Amend Performance Specification
16 of Appendix B to Part 60 by revising
Sections 6.1.7, 8.2.1, 9.1, 9.3, 9.4, 12.4,
and 13.5 to read as follows:
Performance Specification 16—
Specifications and Test Procedures for
Predictive Emission Monitoring Systems in
Stationary Sources
*
*
*
*
*
6.1.7 Sensor Location and Repair. We
recommend you install sensors in an
accessible location in order to perform
repairs and replacements. Permanentlyinstalled platforms or ladders may not be
needed. If you install sensors in an area that
*
*
*
*
*
8.2.1 Reference Methods. Unless
otherwise specified in the applicable
regulations, you must use the test methods in
Appendix A of this part for the RM test.
Conduct the RM tests at three operating
levels. The RM tests shall be performed at a
low-load (or production) level between the
minimum safe, stable load and 50 percent of
the maximum level load, at the mid-load
level (an intermediary level between the low
and high levels), and at a high-load level
between 80 percent and the maximum load.
Alternatively, if practicable, you may test at
three levels of the key operating parameter
(e.g. selected based on a covariance analysis
between each parameter and the PEMS
output) equally spaced within the normal
range of the parameter.
*
*
*
*
*
9.1 QA/QC Summary. Conduct the
applicable ongoing tests listed below.
ONGOING QUALITY ASSURANCE TESTS
Acceptability
Frequency
Sensor Evaluation ..........................
RAA ................................................
All ..................................................
Compliance ...................................
RATA .............................................
All ..................................................
.......................................................
3-test avg ≤ 10% of simultaneous
analyzer or RM average.
Same as for RA in Sec. 13.1 .......
Bias Correction ..............................
All ..................................................
If davg ≤ |cc| ...................................
PEMS Training ...............................
All ..................................................
If Fcritical ≥ Fr ≥ 0.8 ........................
Daily.
Each quarter except quarter when
RATA performed.
Yearly in quarter when RAA not
performed.
Bias test passed (no correction
factor needed).
Optional after initial and subsequent RATAs.
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Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
ONGOING QUALITY ASSURANCE TESTS—Continued
Test
PEMS regulatory purpose
Acceptability
Sensor Evaluation Alert Test (optional).
All ..................................................
See Section 6.1.8 .........................
*
*
*
*
*
9.3 Quarterly Relative Accuracy Audits.
In the first year of operation after the initial
certification, perform a RAA consisting of at
least three 30-minute portable analyzer or
RM determinations each quarter a RATA is
not performed. To conduct a RAA, follow the
procedures in Section 8.2 for the relative
accuracy test, except that only three sets of
measurement data are required, and the
statistical tests are not required. The average
of the three or more portable analyzer or RM
*
*
*
*
*
13.5 Relative Accuracy Audits. The
average of the three portable analyzer or RM
determinations must not differ from the
simultaneous PEMS average value by more
than 10 percent of the analyzer or RM for
concentrations greater than 100 ppm or 20
percent for concentrations between 100 and
20 ppm, or the test is failed. For
measurements at 20 ppm or less, this
difference must not exceed 2 ppm for a
pollutant PEMS and 1 percent absolute for a
diluents PEMS.
Frequency
After each PEMS training.
determinations must not exceed the limits
given in Section 13.5. Report the data from
all sets of measurement data. If a PEMS
passes all quarterly RAAs in the first year
and also passes the subsequent yearly RATA
in the second year, you may elect to perform
a single mid-year RAA in the second year in
place of the quarterly RAAs. This option may
be repeated, but only until the PEMS fails
either a mid-year RAA or a yearly RATA.
When such a failure occurs, you must resume
quarterly RAAs in the quarter following the
failure and continue conducting quarterly
RAAs until the PEMS successfully passes
both a year of quarterly RAAs and a
subsequent RATA.
9.4 Yearly Relative Accuracy Test.
Perform a minimum 9-run RATA at the
normal operating level on a yearly basis in
the quarter that the RAA is not performed.
The statistical tests in Section 8.3 are not
required for the yearly RATA.
65. Amend Procedure 1 of Appendix
F to Part 60 by revising Section 6.2 to
read as follows:
calculated in the units of the applicable
emission standard.
*
*
*
*
*
12.4 Relative Accuracy Audit. Calculate
the quarterly RAA using Equation 16–9.
*
*
*
*
*
Appendix F to Part 60—Quality
Assurance Procedures
66. Amend Procedure 2 of Appendix F to
Part 60 by revising paragraphs (3) and (4) in
Section 12.0 to read as follows:
Procedure 1—Quality Assurance
Requirements for Gas Continuous Emission
Monitoring Systems Used for Compliance
Determination
Procedure 2—Quality Assurance
Requirements for Particulate Matter
Continuous Emission Monitoring Systems at
Stationary Sources
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Where:
UD = The upscale drift of your PM CEMS,
in percent,
RCEM = Your PM CEMS response to the
upscale check value, and
RU = The upscale check value.
FS = Full-scale value.
Where:
ZD = The zero (low-level) drift of your PM
CEMS, in percent,
RCEM = Your PM CEMS response of the zero
check value,
RL = The zero check value, and
(4) How do I calculate SVA accuracy? You
must use Equation 2–4 to calculate the
accuracy, in percent, for each of the three
SVA tests or the daily sample volume check:
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12.0 * * *
(3) How do I calculate daily upscale and
zero drift? You must calculate the upscale
drift using Equation 2–2 and the zero drift
using Equation 2–3:
EP09JA12.044
6.2 RAA Accuracy Calculation. Use the
calculation procedure in the relevant
performance specification to calculate the
accuracy for the RAA. The RAA must be
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
Where:
VM = Sample gas volume determined/
reported by your PM CEMS (e.g., dscm),
VR = Sample gas volume measured by the
independent calibrated reference device
(e.g., dscm) for the SVA or the reference
value for the daily sample volume check.
Note: Before calculating SVA accuracy, you
must correct the sample gas volumes
measured by your PM CEMS and the
independent calibrated reference device to
the same basis of temperature, pressure, and
moisture content. You must document all
data and calculations.
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67. Amend Procedure 5 of Appendix
F to Part 60 by redesignating the second
listing of Section 6.2.6 as Section 6.2.7.
PART 61—NATIONAL EMISSION
STANDARDS FOR HAZARDOUS AIR
POLLUTANTS
68. The authority citation for Part 61
continues to read as follows:
Authority: 42 U.S.C. 7401, et seq.
69. Amend § 61.13 by revising
paragraph (e)(1)(i) to read as follows:
§ 61.13 Emission tests and waiver of
emission tests.
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(e) * * *
(1) * * *
(i) The source owner, operator, or
representative of the tested facility shall
obtain an audit sample, if commercially
available, from an AASP for each test
method used for regulatory compliance
purposes. No audit samples are required
for the following test methods: Methods
3A and 3C of Appendix A–3 of Part 60;
Methods 6C, 7E, 9, and 10 of Appendix
A–4 of Part 60; Method 18 and 19 of
Appendix A–6 of Part 60; Methods 20,
22, and 25A of Appendix A–7 of Part
60; and Methods 303, 318, 320, and 321
of Appendix A of Part 63. If multiple
sources at a single facility are tested
during a compliance test event, only one
audit sample is required for each
method used during a compliance test.
The compliance authority responsible
for the compliance test may waive the
requirement to include an audit sample
if they believe that an audit sample is
not necessary. ‘‘Commercially
available’’ means that two or more
independent AASPs have blind audit
samples available for purchase. If the
source owner, operator, or
representative cannot find an audit
sample for a specific method, the owner,
operator, or representative shall consult
the EPA Web site at the following URL,
www.epa.gov/ttn/emc, to confirm
whether there is a source that can
supply an audit sample for that method.
If the EPA Web site does not list an
available audit sample at least 60 days
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prior to the beginning of the compliance
test, the source owner, operator, or
representative shall not be required to
include an audit sample as part of the
quality assurance program for the
compliance test. When ordering an
audit sample, the source owner,
operator, or representative shall give the
sample provider an estimate for the
concentration of each pollutant that is
emitted by the source or the estimated
concentration of each pollutant based
on the permitted level and the name,
address, and phone number of the
compliance authority. The source
owner, operator, or representative shall
report the results for the audit sample
along with a summary of the emission
test results for the audited pollutant to
the compliance authority and shall
report the results of the audit sample to
the AASP. The source owner, operator,
or representative shall make both
reports at the same time and in the same
manner or shall report to the
compliance authority first and report to
the AASP. If the method being audited
is a method that allows the samples to
be analyzed in the field and the tester
plans to analyze the samples in the
field, the tester may analyze the audit
samples prior to collecting the emission
samples provided a representative of the
compliance authority is present at the
testing site. The tester may request, and
the compliance authority may grant, a
waiver to the requirement that a
representative of the compliance
authority must be present at the testing
site during the field analysis of an audit
sample. The source owner, operator, or
representative may report the results of
the audit sample to the compliance
authority and then report the results of
the audit sample to the AASP prior to
collecting any emission samples. The
test protocol and final test report shall
document whether an audit sample was
ordered and utilized and the pass/fail
results as applicable.
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70. Amend § 61.33 by revising
paragraph (a) to read as follows:
§ 61.33
Stack sampling.
(a) Unless a waiver of emission testing
is obtained under § 61.13, each owner or
operator required to comply with
§ 61.32(a) shall test emissions from the
source according to Method 104 of
Appendix B to this part or according to
Method 29 of Appendix A to Part 60.
Method 103 of Appendix B to this part
is approved by the Administrator as an
alternative method for sources subject to
§ 61.32(a). The emission test shall be
performed:
(1) Within 90 days of the effective
date in the case of an existing source or
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1165
a new source which has an initial
startup date preceding the effective date;
or
(2) Within 90 days of startup in the
case of a new source which did not have
an initial startup date preceding the
effective date.
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71. Amend § 61.42 by revising
paragraph (a) to read as follows:
§ 61.42
Emission standard.
(a) Emissions to the atmosphere from
rocket-motor test sites shall not cause
time-weighted atmospheric
concentrations of beryllium to exceed
75 microgram minutes per cubic meter
(mg-min/m 3) (4.68 × 10¥9 pound
minutes per cubic foot (lb-min/ft 3)) of
air within the limits of 10 to 60 minutes,
accumulated during any 2 consecutive
weeks, in any area in which an adverse
effect to public health could occur.
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72. Amend § 61.53 by revising
paragraph (d)(2) to read as follows:
§ 61.53
Stack sampling.
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(d) * * *
(2) Method 101A in Appendix B or
Method 29 in Appendix A to part 60
shall be used to test emissions as
follows:
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73. Amend § 61.164 by revising
paragraphs (d)(2)(i), (e)(1)(i), and (e)(2)
to read as follows:
§ 61.164
Test methods and procedures.
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(d) * * *
(2) * * *
(i) Use Method 108 in Appendix B to
this part or Method 29 in Appendix A
to part 60 for determining the arsenic
emission rate, g/hr (lb/hr). The emission
rate shall equal the arithmetic mean of
the results of three 60-minute test runs.
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(e) * * *
(1) * * *
(i) Use Method 108 in Appendix B to
this part or Method 29 in Appendix A
to part 60 to determine the
concentration of arsenic in the gas
streams entering and exiting the control
device. Conduct three 60-minute test
runs, each consisting of simultaneous
testing of the inlet and outlet gas
streams. The gas streams shall contain
all the gas exhausted from the glass
melting furnace.
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(2) Calculate the percent emission
reduction for each run as follows:
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Where:
D = the percent emission reduction.
Cb = the arsenic concentration of the stack
gas entering the control device, as
measured by Method 108 or Method 29.
Ca = the arsenic concentration of the stack gas
exiting the control device, as measured
by Method 108 or Method 29.
Method 102—Determination of Particulate
and Gaseous Mercury Emissions From
Chlor-Alkali Plants (Hydrogen Streams)
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Method 101—Determination of Particulate
and Gaseous Mercury Emissions From
Chlor-Alkali Plants (Air Streams)
8.1.1.1 Calibrate the meter box orifice.
Use the techniques described in APTD–0576
(see Reference 9 in Section 17.0 of Method
5 of Appendix A to Part 60). Calibration of
the orifice meter at flow conditions that
simulate the conditions at the source is
suggested. Calibration should either be done
with hydrogen or with some other gas having
a similar Reynolds Number so that there is
similarity between the Reynolds Numbers
during calibration and during sampling.
Alternative mercury-free thermometers may
be used if the thermometers are, at a
minimum, equivalent in terms of
performance or suitably effective for the
specific temperature measurement
application.
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74. Amend Method 101 of Appendix
B to Part 61 by redesignating Sections
16 and 17 as Sections 17 and 18,
respectively; and by adding a new
Section 16 to read as follows:
Appendix B to Part 61—Test Methods
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16.0 Alternative Procedures
16.1 Alternative Analyzer. Samples may
also be analyzed by cold vapor atomic
fluorescence spectrometry.
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75. Amend Method 101A of Appendix
B to Part 61 by redesignating Sections
16 and 17 as Sections 17 and 18,
respectively; and by adding a new
Section 16 to read as follows:
Method 101A—Determination of Particulate
and Gaseous Mercury Emissions From
Sewage Sludge Incinerators
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16.0 Alternative Procedures
16.1 Alternative Analyzers.
16.1.1 Inductively coupled plasmaatomic emission spectrometry (ICP–AES)
may be used as an alternative to atomic
absorption analysis provided the following
conditions are met:
16.1.1.1 Sample collection, sample
preparation, and analytical preparation
procedures are as defined in the method
except as necessary for the ICP–AES
application.
16.1.1.2 The quality control procedures
are conducted as prescribed.
16.1.1.3 The limit of quantitation for the
ICP–AES must be demonstrated and the
sample concentrations reported should be no
less than two times the limit of quantitation.
The limit of quantitation is defined as ten
times the standard deviation of the blank
value. The standard deviation of the blank
value is determined from the analysis of
seven blanks. It has been reported that for
mercury and those elements that form
hydrides, a continuous-flow generator
coupled to an ICP–AES offers detection
limits comparable to cold vapor atomic
absorption.
6.1.2 Samples may also be analyzed by
cold vapor atomic fluorescence spectrometry.
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77. Amend Method 104 in Appendix
B to Part 61 as follows:
a. By revising Section 4.1.
b. By revising Section 11.5.3.
c. By redesignating Sections 16 and 17
as Sections 17 and 18 respectively.
d. By adding a new Section 16.
Method 104—Determination of Beryllium
Emissions From Stationary Sources
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4.1 Matrix Effects. Analysis for Be by
flame atomic absorption spectrophotometry
is sensitive to the chemical composition and
to the physical properties (e.g., viscosity, pH)
of the sample. Aluminum and silicon, in
particular, are known to interfere when
present in appreciable quantities. The
analytical procedure includes (optionally)
the use of the Method of Standard Additions
to check for these matrix effects, and sample
analysis using the Method of Standard
Additions if significant matrix effects are
found to be present (see Reference 2 in
Section 17.0).
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*
11.5.3 Check for Matrix Effects (optional).
Use the Method of Standard Additions (see
Reference 2 in Section 17.0) to check at least
one sample from each source for matrix
effects on the Be results. If the results of the
Method of Standard Additions procedure
used on the single source sample do not
agree to within 5 percent of the value
obtained by the routine atomic absorption
analysis, then reanalyze all samples from the
source using the Method of Standard
Additions procedure.
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*
16.0 Alternative Procedures
16.1 Alternative Analyzer. Inductively
coupled plasma-atomic emission
spectrometry (ICP–AES) may be used as an
alternative to atomic absorption analysis
provided the following conditions are met:
16.1.1 Sample collection, sample
preparation, and analytical preparation
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procedures are as defined in the method
except as necessary for the ICP–AES
application.
16.1.2 Quality Assurance/Quality Control
procedures, including audit material
analysis, are conducted as prescribed in the
method. The QA acceptance conditions must
be met.
16.1.3 The limit of quantitation for the
ICP–AES must be demonstrated and the
sample concentrations reported should be no
less than two times the limit of quantitation.
The limit of quantitation is defined as ten
times the standard deviation of the blank
value. The standard deviation of the blank
value is determined from the analysis of
seven blanks. It has been reported that for
mercury and those elements that form
hydrides, a continuous-flow generator
coupled to an ICP–AES offers detection
limits comparable to cold vapor atomic
absorption.
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*
78. Amend Method 108 of Appendix
B to Part 61 by redesignating Sections
16 and 17 as Sections 17 and 18
respectively, and by adding a new
Section 16 to read as follows:
Method 108—Determination of Particulate
and Gaseous Arsenic Emissions
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*
16.0 Alternative Procedures
16.1 Alternative Analyzer. Inductively
coupled plasma-atomic emission
spectrometry (ICP–AES) may be used as an
alternative to atomic absorption analysis
provided the following conditions are met:
16.1.1 Sample collection, sample
preparation, and analytical preparation
procedures are as defined in the method
except as necessary for the ICP–AES
application.
16.1.2 Quality Assurance/Quality Control
procedures, including audit material
analysis, are conducted as prescribed in the
method. The QA acceptance conditions must
be met.
16.1.3 The limit of quantitation for the
ICP–AES must be demonstrated and the
sample concentrations reported should be no
less than two times the limit of quantitation.
The limit of quantitation is defined as ten
times the standard deviation of the blank
value. The standard deviation of the blank
value is determined from the analysis of
seven blanks. It has been reported that for
mercury and those elements that form
hydrides, a continuous-flow generator
coupled to an ICP–AES offers detection
limits comparable to cold vapor atomic
absorption.
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79. Amend Method 108A of Appendix
B to Part 61 by redesignating Sections
16 and 17 as Sections 17 and 18
respectively, and by adding a new
Section 16 to read as follows:
Method 108A—Determination of Arsenic
Content in Ore Samples From Nonferrous
Smelters
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EP09JA12.046
76. Amend Method 102 in Appendix
B to Part 61 by revising Section 8.1.1.1
to read as follows:
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
16.0 Alternative Procedures
16.1 Alternative Analyzer. Inductively
coupled plasma-atomic emission
spectrometry (ICP–AES) may be used as an
alternative to atomic absorption analysis
provided the following conditions are met:
16.1.1 Sample collection, sample
preparation, and analytical preparation
procedures are as defined in the method
except as necessary for the ICP–AES
application.
16.1.2 Quality Assurance/Quality Control
procedures, including audit material
analysis, are conducted as prescribed in the
method. The QA acceptance conditions must
be met.
16.1.3 The limit of quantitation for the
ICP–AES must be demonstrated and the
sample concentrations reported should be no
less than two times the limit of quantitation.
The limit of quantitation is defined as ten
times the standard deviation of the blank
value. The standard deviation of the blank
value is determined from the analysis of
seven blanks. It has been reported that for
mercury and those elements that form
hydrides, a continuous-flow generator
coupled to an ICP–AES offers detection
limits comparable to cold vapor atomic
absorption.
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PART 63—NATIONAL EMISSION
STANDARDS FOR HAZARDOUS AIR
POLLUTANTS FOR SOURCE
CATEGORIES
80. The authority citation for part 63
continues to read as follows:
Authority: 42 U.S.C. 7401 et seq.
81. Amend § 63.7 by revising
paragraph (c)(2)(iii)(A) to read as
follows:
§ 63.7
Performance testing requirements.
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(c) * * *
(2) * * *
(iii) * * *
(A) The source owner, operator, or
representative of the tested facility shall
obtain an audit sample, if commercially
available, from an AASP for each test
method used for regulatory compliance
purposes. No audit samples are required
for the following test methods: Methods
3A and 3C of Appendix A–3 of Part 60;
Methods 6C, 7E, 9, and 10 of Appendix
A–4 of Part 60; Methods 18 and 19 of
Appendix A–6 of Part 60; Methods 20,
22, and 25A of Appendix A–7 of Part
60; and Methods 303, 318, 320, and 321
of Appendix A of Part 63. If multiple
sources at a single facility are tested
during a compliance test event, only one
audit sample is required for each
method used during a compliance test.
The compliance authority responsible
for the compliance test may waive the
requirement to include an audit sample
if they believe that an audit sample is
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not necessary. ‘‘Commercially
available’’ means that two or more
independent AASPs have blind audit
samples available for purchase. If the
source owner, operator, or
representative cannot find an audit
sample for a specific method, the owner,
operator, or representative shall consult
the EPA web site at the following URL,
www.epa.gov/ttn/emc, to confirm
whether there is a source that can
supply an audit sample for that method.
If the EPA web site does not list an
available audit sample at least 60 days
prior to the beginning of the compliance
test, the source owner, operator, or
representative shall not be required to
include an audit sample as part of the
quality assurance program for the
compliance test. When ordering an
audit sample, the source owner,
operator, or representative shall give the
sample provider an estimate for the
concentration of each pollutant that is
emitted by the source or the estimated
concentration of each pollutant based
on the permitted level and the name,
address, and phone number of the
compliance authority. The source
owner, operator, or representative shall
report the results for the audit sample
along with a summary of the emission
test results for the audited pollutant to
the compliance authority and shall
report the results of the audit sample to
the AASP. The source owner, operator,
or representative shall make both
reports at the same time and in the same
manner or shall report to the
compliance authority first and report to
the AASP. If the method being audited
is a method that allows the samples to
be analyzed in the field and the tester
plans to analyze the samples in the
field, the tester may analyze the audit
samples prior to collecting the emission
samples provided a representative of the
compliance authority is present at the
testing site. The tester may request, and
the compliance authority may grant, a
waiver to the requirement that a
representative of the compliance
authority must be present at the testing
site during the field analysis of an audit
sample. The source owner, operator, or
representative may report the results of
the audit sample to the compliance
authority and then report the results of
the audit sample to the AASP prior to
collecting any emission samples. The
test protocol and final test report shall
document whether an audit sample was
ordered and utilized and the pass/fail
results as applicable.
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82. Amend § 63.8 by adding a
sentence to the end of paragraph
(f)(6)(iii) to read as follows:
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§ 63.8
1167
Monitoring requirements.
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(f) * * *
(6) * * *
(iii) * * * The Administrator will
review the notification and may rescind
permission to use an alternative and
require the owner or operator to conduct
a relative accuracy test of the CEMS as
specified in section 8.4 of Performance
Specification 2.
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83. Amend § 63.144 by adding
paragraphs (b)(5)(i)(G) and (b)(5)(i)(H) to
read as follows:
§ 63.144 Process wastewater provisions—
test methods and procedures for
determining applicability and Group 1/
Group 2 determinations (determining which
wastewater streams require control).
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(b) * * *
(5) * * *
(i) * * *
(G) Method 8260B. Use procedures
specified in Method 8260B in the SW–
846 Compendium of Methods.
(H) Method 316. Use Method 316 to
determine formaldehyde concentration.
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84. Amend § 63.344 by adding
paragraph (c)(5) to read as follows:
§ 63.344 Performance test requirements
and test methods.
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(c) * * *
(5) The South Coast Air Quality
Management District (SCAQMD)
Method 205.1 (which is available by
contacting the South Coast AQMD,
21865 Copley Dr., Diamond Bar, CA
91765) may be used to determine the
total chromium concentration from hard
and decorative chromium electroplating
tanks and chromium anodizing tanks.
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85. Amend § 63.364 by revising
paragraph (e) to read as follows:
§ 63.364
Monitoring requirements.
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(e) Measure and record once per hour
the ethylene oxide concentration at the
outlet to the atmosphere after any
control device according to the
procedures specified in § 63.365(c)(1).
The owner or operator shall compute
and record a 24-hour average daily. The
owner or operator will install, calibrate,
operate, and maintain a monitor
consistent with the requirements of
performance specification (PS) 8 or 9 in
40 CFR part 60, Appendix B, to measure
ethylene oxide. The daily calibration
requirements of section 7.2 of PS–9 or
Section 13.1 of PS–8 are required only
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§ 63.365
Test methods and procedures.
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(b) Efficiency at the sterilization
chamber vent. California Air Resources
Board (CARB) Method 431 or the
following procedures shall be used to
determine the efficiency of all types of
control devices used to comply with
§ 63.362(c), sterilization chamber vent
standard.
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87. Amend § 63.565 by revising
paragraphs (d)(5), (8), and (10) and (g)
to read as follows:
§ 63.565
Test methods and procedures.
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(d) * * *
(5) Recovery devices. The average
VOC concentration in the vent upstream
and downstream of the control device
shall be determined using Method 25A
or 25B of Appendix A to part 60 of this
chapter for recovery devices. The
average VOC concentration shall
correspond to the volume measurement
by taking into account the sampling
system response time.
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(8) Where Method 25, 25A, or 25B is
used to measure the percent reduction
in VOC, the percent reduction across the
combustion or recovery device shall be
calculated as follows:
Where:
R = control efficiency of control device,
percent.
Ei = mass flow rate of VOC at the inlet to the
combustion or recovery device as
calculated under paragraph (c)(7) of this
section, kg/hr.
Eo = mass flow rate of VOC at the outlet of
the combustion or recovery device, as
calculated under paragraph (c)(7) of this
section, kg/hr.
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(10) Use of methods other than
Method 25, 25A, or 25B shall be
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validated pursuant to Method 301 of
Appendix A to part 63 of this chapter.
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(g) Baseline outlet VOC concentration.
The procedures in this paragraph shall
be used to determine the outlet VOC
concentration required in § 63.563(b)(4),
(6), (7), and (8) for combustion devices
except flare, carbon adsorbers,
condenser/refrigeration units, and
absorbers, respectively, and to monitor
the VOC concentration as required in
§ 63.564(e), (g), (h), and (i). The owner
or operator shall use the procedures
outlined in Method 25A or 25B. For the
baseline VOC concentration, the
arithmetic average of the outlet VOC
concentration from three test runs from
paragraph (d) of this section shall be
calculated for the control device. The
VOC concentration shall be measured at
least every 15 minutes. Compliance
testing of VOC CEMS shall be performed
using PS 8.
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88. Amend § 63.750 by revising
paragraph (o) to read as follows:
§ 63.750
Test methods and procedures.
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(o) Inorganic HAP emissions—dry
particulate filter certification
requirements. Dry particulate filters
used to comply with § 63.745(g)(2) or
§ 63.746(b)(4) must be certified by the
filter manufacturer or distributor, paint/
depainting booth supplier, and/or the
facility owner or operator using method
319 in Appendix A of this part, to meet
or exceed the efficiency data points
found in Tables 1 and 2, or 3 and 4 of
§ 63.745 for existing or new sources
respectively.
89. Amend § 63.1251 by revising the
definition of ‘‘Process vent’’ to read as
follows:
§ 63.1251
Definitions.
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Process vent means a vent from a unit
operation or vents from multiple unit
operations within a process that are
manifolded together into a common
header, through which a HAPcontaining gas stream is, or has the
potential to be, released to the
atmosphere. Examples of process vents
include, but are not limited to, vents on
condensers used for product recovery,
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bottom receivers, surge control vessels,
reactors, filters, centrifuges, and process
tanks. Emission streams that are
undiluted and uncontrolled containing
less than 50 ppmv HAP, as determined
through process knowledge that no HAP
are present in the emission stream or
using an engineering assessment as
discussed in § 63.1257(d)(2)(ii); test data
using Method 18 of 40 CFR part 60,
Appendix A; Method 320 of 40 CFR part
63; or any other test method that has
been validated according to the
procedures in Method 301 of Appendix
A of this part, are not considered
process vents. Process vents do not
include vents on storage tanks regulated
under § 63.1253, vents on wastewater
emission sources regulated under
§ 63.1256, or pieces of equipment
regulated under § 63.1255.
*
*
*
*
*
90. Amend § 63.1511 by revising
paragraph (c)(9) as to read follows:
§ 63.1511 Performance test/compliance
demonstration general requirements.
*
*
*
*
*
(c) * * *
(9) Method 26A for the concentration
of HCl. Where a lime-injected fabric
filter is used as the control device to
comply with the 90 percent reduction
standard, the owner or operator must
measure the fabric filter inlet
concentration of HCl at a point before
lime is introduced to the system.
Method 26 may be used in place of
Method 26A where it can be
demonstrated that there are no water
droplets in the emission stream. This
can be demonstrated by showing that
the vapor pressure of water in the
emission stream that you are testing is
less than the equilibrium vapor pressure
of water at the emission stream
temperature, and by certifying that the
emission stream is not controlled by a
wet scrubber.
*
*
*
*
*
Subpart CCCC—National Emission
Standards for Hazardous Air
Pollutants: Manufacturing of
Nutritional Yeast
91. Subpart CCCC of Part 63 is
amended by revising Table 2 to read as
follows:
E:\FR\FM\09JAP2.SGM
09JAP2
EP09JA12.047
on days when ethylene oxide emissions
are vented to the control device.
*
*
*
*
*
86. Amend § 63.365 by revising
paragraph (b) introductory text to read
as follows:
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
1169
TABLE 2 TO SUBPART CCCC OF PART 63—REQUIREMENTS FOR PERFORMANCE TESTS
[As stated in § 63.2161, if you demonstrate compliance by monitoring brew ethanol, you must comply with the requirements for performance tests
in the following table (brew ethanol monitoring only)]
For each fed-batch fermenter for which compliance is determined by monitoring brew ethanol
concentration and calculating VOC concentration in the fermenter exhaust according to the
procedures in § 63.2161, you must . . .
1. Measure VOC as propane .............................
Using . . .
According to the following requirements . . .
Method 25A *, or an alternative validated by
EPA Method 301 * and approved by the Administrator.
You must measure the VOC concentration in
the fermenter exhaust at any point prior to
the dilution of the exhaust stream.
* EPA Test Methods found in Appendix A of 40 CFR part 60.
Subpart UUUU—National Emission
Standards for Hazardous Air Pollutants
for Cellulose Products Manufacturing
92. Amend Subpart UUUU by revising
Table 4 to read as follows:
Table 4 to Subpart UUUU of Part 63—
Requirements for Performance Tests
As required in §§ 63.5530(b) and
63.5535(a), (b), (g)(1), and (h)(1), you
must conduct performance tests, other
initial compliance demonstrations, and
CEMS performance evaluations and
establish operating limits according to
the requirements in the following table:
For . . .
At . . .
You must . . .
Using . . .
According to the following
requirements . . .
1. the sum of all process vents
a. each existing or new affected source.
i. select sampling port’s location and the number of traverse points;
ii. determine velocity and volumetric flow rate;
EPA Method 1 or 1A in Appendix
A
to
40
CFR
§ 63.7(d)(1)(i);
EPA Method 2, 2A, 2C, 2D,
2F, or 2G in Appendix A to
part 60 of this chapter;
iii. conduct gas analysis; and,
(1) EPA Method 3, 3A, or 3B
in Appendix A to part 60 of
this chapter; or,
(2) ASME PTC 19.101981—
Part 10; and,
sampling sites must be located
at the inlet and outlet to
each control device;
you may use EPA Method 2A,
2C, 2D, 2F, or 2G as an alternative to using EPA Method 2, as appropriate;
you may use EPA Method 3A
or 3B as an alternative to
using EPA Method 3; or,
you may use ASME PTC
19.10–1981—Part 10 (available for purchase from
Three Park Avenue, New
York, NY 10016–5990) as
an alternative to using EPA
Method 3B.
iv. measure moisture content
of the stack gas.
EPA Method 4 in Appendix A
to part 60 of this chapter.
i. measure total sulfide emissions.
(1) EPA Method 15 in Appendix A to part 60 of this chapter; or
tkelley on DSK3SPTVN1PROD with PROPOSALS2
2. the sum of all viscose process vents.
a. each existing or new viscose process source.
(2) carbon disulfide and/or hydrogen sulfide CEMS, as applicable;
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(a) you must conduct testing of
emissions at the inlet and
outlet of each control device;
(b) you must conduct testing of
emissions from continuous
viscose process vents and
combinations of batch and
continuous viscose process
vents at normal operating
conditions, as specified in
§§ 63.7(e)(1) and 63.5535;
(c) you must conduct testing of
emissions from batch viscose process vents as specified in § 63.490(c), except
that the emission reductions
required for process vents
under this subpart supersede the emission reductions required for process
vents under subpart U of this
part; and
(d) you must collect CPMS
data during the period of the
initial compliance demonstration and determine the
CPMS operating limit during
the period of the initial compliance demonstration; or
(a) you must measure emissions at the inlet and outlet
of each control device using
CEMS;
1170
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
For . . .
At . . .
You must . . .
According to the following
requirements . . .
Using . . .
(b) you must install, operate,
and maintain the CEMS according to the applicable
performance specification
(PS–7, PS–8, PS–9, or PS–
15) of 40 CFR part 60, Appendix B; and
(c) you must collect CEMS
emissions data at the inlet
and outlet of each control
device during the period of
the initial compliance demonstration and determine the
CEMS operating limit during
the period of the initial compliance demonstration.
3. the sum of all solvent coating process vents.
a. each existing or new cellophane operation.
i. measure toluene emissions ..
(1) EPA Method 18 in Appendix A to part 60 of this chapter, or Method 320 in appendix A to part 63, or
tkelley on DSK3SPTVN1PROD with PROPOSALS2
(2) ASTM D6420–99 ................
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(a) you must conduct testing of
emissions at the inlet and
outlet of each control device;
(b) you may use EPA Method
18 or 320 to determine the
control efficiency of any control device for organic compounds; for a combustion
device, you must use only
HAP that are present in the
inlet to the control device to
characterize the percent reduction across the combustion device;
(c) you must conduct testing of
emissions from continuous
solvent coating process
vents and combinations of
batch and continuous solvent coating process vents
at normal operating conditions, as specified in
§§ 63.7(e)(1) and 63.5535;
(d) you must conduct testing of
emissions from batch solvent
coating process vents as
specified in § 63.490(c), except that the emission reductions required for process
vents under this subpart supersede the emission reductions required for process
vents under subpart U of this
part; and
(e) you must collect CPMS
data during the period of the
initial compliance demonstration and determine the
CPMS operating limit during
the initial compliance demonstration; or
(a) you must conduct testing of
emissions at the inlet and
outlet of each control device;
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
For . . .
At . . .
You must . . .
1171
According to the following
requirements . . .
Using . . .
(b) you may use ASTM
D6420–99 (available for purchase from at least one of
the following addresses: 100
Barr Harbor Drive, West
Conshohocken, PA 19428–
2959; or University Microfilms International, 300 North
Zeeb Road, Ann Arbor, MI
48106) as an alternative to
EPA Method 18 only where:
The target compound(s) are
those listed in Section 1.1 of
ASTM D6420–99; and the
target concentration is between 150 parts per billion
by volume (ppbv) and 100
ppmv; for target compound(s) not listed in Section 1.1 of ASTM D6420–99,
but potentially detected by
mass spectrometry, the additional system continuing calibration check after each run,
as detailed in Section 10.5.3
of the ASTM method, must
be followed, met, documented, and submitted with
the data report even if there
is no moisture condenser
used or the compound is not
considered water soluble;
and for target compound(s)
not listed in Section 1.1 of
ASTM D6420–99 and not
amenable to detection by
mass spectrometry, ASTM
D6420–99 does not apply;
(c) you must conduct testing of
emissions from continuous
solvent coating process
vents and combinations of
batch and continuous solvent coating process vents
at normal operating conditions, as specified in
§§ 63.7(e)(1) and 63.5535;
(d) you must conduct testing of
emissions from batch solvent
coating process vents as
specified in § 63.490(c), except that the emission reductions required for process
vents under this subpart supersede the emission reductions required for process
vents under subpart U of this
part; and,
(e) you must collect CPMS
data during the period of the
initial compliance demonstration and determine the
CPMS operating limit during
the period of the initial compliance demonstration.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
4. the sum of all cellulose
ether process vents.
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a. each existing or new cellulose ether operation.
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i. measure total organic HAP
emissions.
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(1) EPA Method 18 in Appendix A to Part 60 of this chapter or Method 320 in Appendix A to Part 63, or
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(a) you must conduct testing of
emissions at the inlet and
outlet of each control device;
(b) you may use EPA Method
18 or 320 to determine the
control efficiency of any control device for organic compounds; for a combustion
device, you must use only
HAP that are present in the
inlet to the control device to
characterize the percent reduction across the combustion device;
1172
For . . .
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
At . . .
You must . . .
According to the following
requirements . . .
Using . . .
tkelley on DSK3SPTVN1PROD with PROPOSALS2
(2) ASTM D6420–99 ................
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(c) you must conduct testing of
emissions from continuous
cellulose ether process vents
and combinations of batch
and continuous cellulose
ether process vents at normal operating conditions, as
specified in §§ 63.7(e)(1) and
63.5535;
(d) you must conduct testing of
emissions from batch cellulose ether process vents
as specified in § 63.490(c),
except that the emission reductions required for process
vents under this subpart supersede the emission reductions required for process
vents under subpart U of this
part; and
(e) you must collect CPMS
data during the period of the
initial performance test and
determine the CPMS operating limit during the period
of the initial performance
test;
(a) you must conduct testing of
emissions at the inlet and
outlet of each control device;
(b) you may use ASTM
D6420–99 (available for purchase from at least one of
the following addresses: 100
Barr Harbor Drive, West
Conshohocken, PA 19428–
2959; or University Microfilms International, 300 North
Zeeb Road, Ann Arbor, MI
48106) as an alternative to
EPA Method 18 only where:
The target compound(s) are
those listed in Section 1.1 of
ASTM D6420–99; and the
target concentration is between 150 ppbv and 100
ppmv; for target compound(s) not listed in Section 1.1 of ASTM D6420–99,
but potentially detected by
mass spectrometry, the additional system continuing calibration check after each run,
as detailed in Section 10.5.3
of the ASTM method, must
be followed, met, documented, and submitted with
the data report even if there
is no moisture condenser
used or the compound is not
considered water soluble;
and for target compound(s)
not listed in Section 1.1 of
ASTM D6420–99 and not
amenable to detection by
mass spectrometry, ASTM
D6420–99 does not apply;
target concentration is between 150 ppbv and 100
ppmv for target compound(s).
(c) you must conduct testing of
emissions from continuous
cellulose ether process vents
and combinations of batch
and continuous cellulose
ether process vents at normal operating conditions, as
specified in §§ 63.7(e)(1) and
63.5535;
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
For . . .
At . . .
You must . . .
According to the following
requirements . . .
Using . . .
(3) EPA Method 25 in Appendix A to Part 60 of this chapter; or
tkelley on DSK3SPTVN1PROD with PROPOSALS2
(4) EPA Method 25A in Appendix A to Part 60 of this chapter.
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1173
09JAP2
(d) you must conduct testing of
emissions from batch cellulose ether process vents
as specified in § 63.490(c),
except that the emission reductions required for process
vents under this subpart supersede the emission reductions required for process
vents under subpart U of this
part; and
(e) you must collect CPMS
data during the period of the
initial performance test and
determine the CPMS operating limit during the period
of the initial performance
test.
(a) you must conduct testing of
emissions at the inlet and
outlet of each control device;
(b) you may use EPA Method
25 to determine the control
efficiency of combustion devices for organic compounds; you may not use
EPA Method 25 to determine
the control efficiency of noncombustion control devices;
(c) you must conduct testing of
emissions from continuous
cellulose ether process vents
and combinations of batch
and continuous cellulose
ether process vents at normal operating conditions, as
specified in §§ 63.7(e)(1) and
63.5535;
(d) you must conduct testing of
emissions from batch cellulose ether process vents
as specified in § 63.490(c),
except that the emission reductions required for process
vents under this subpart supersede the emission reductions required for process
vents under subpart U of this
part; and
(e) you must collect CPMS
data during the period of the
initial performance test and
determine the CPMS operating limit during the period
of the initial performance
test; or
(a) you must conduct testing of
emissions at the inlet and
outlet of each control device;
(b) you may use EPA Method
25A if: An exhaust gas volatile organic matter concentration of 50 ppmv or
less is required in order to
comply with the emission
limit; the volatile organic
matter concentration at the
inlet to the control device
and the required level of
control are such as to result
in exhaust volatile organic
matter concentrations of 50
ppmv or less; or because of
the high control efficiency of
the control device, the anticipated volatile organic matter
concentration at the control
device exhaust is 50 ppmv
or less, regardless of the
inlet concentration;
1174
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
For . . .
At . . .
You must . . .
According to the following
requirements . . .
Using . . .
(c) you must conduct testing of
emissions from continuous
cellulose ether process vents
and combinations of batch
and continuous cellulose
ether process vents at normal operating conditions, as
specified in §§ 63.7(e)(1) and
63.5535;
(d) you must conduct testing of
emissions from batch cellulose ether process vents
as specified in § 63.490(c),
except that the emission reductions required for process
vents under this subpart supersede the emission reductions required for process
vents under subpart U of this
part; and,
(e) you must collect CPMS
data during the period of the
initial performance test and
determine the CPMS operating limit during the period
of the initial performance
test.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
5. each toluene storage vessel
a. each existing or new cellophane operation.
i. measure toluene emissions ..
(1) EPA Method 18 in Appendix A to Part 60 of this chapter or Method 320 in Appendix A to Part 63; or
(2) ASTM D6420–99 ................
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(a) if venting to a control device to reduce emissions,
you must conduct testing of
emissions at the inlet and
outlet of each control device;
(b) you may use EPA Method
18 or 320 to determine the
control efficiency of any control device for organic compounds; for a combustion
device, you must use only
HAP that are present in the
inlet to the control device to
characterize the percent reduction across the combustion device;
(c) you must conduct testing of
emissions from continuous
storage vessel vents and
combinations of batch and
continuous storage vessel
vents at normal operating
conditions, as specified in
§§ 63.7(e)(1) and 63.5535
for continuous process
vents;
(d) you must conduct testing of
emissions from batch storage vessel vents as specified in § 63.490(c) for batch
process vents, except that
the emission reductions required for process vents
under this subpart supersede the emission reductions required for process
vents under subpart U of this
part; and,
(e) you must collect CPMS
data during the period of the
initial compliance demonstration and determine the
CPMS operating limit during
the period of the initial compliance demonstration; or
(a) if venting to a control device to reduce emissions,
you must conduct testing of
emissions at the inlet and
outlet of each control device;
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
For . . .
At . . .
You must . . .
1175
According to the following
requirements . . .
Using . . .
(b) you may use ASTM
D6420–99 (available for purchase from at least one of
the following addresses: 100
Barr Harbor Drive, West
Conshohocken, PA 19428–
2959; or University Microfilms International, 300 North
Zeeb Road, Ann Arbor, MI
48106) as an alternative to
EPA Method 18 only where:
the target compound(s) are
those listed in Section 1.1 of
ASTM D6420–99, and the
target concentration is between 150 ppbv and 100
ppmv; for target compound(s) not listed in Section 1.1 of ASTM D6420–99,
but potentially detected by
mass spectrometry, the additional system continuing calibration check after each run,
as detailed in Section 10.5.3
of the ASTM method, must
be followed, met, documented, and submitted with
the data report even if there
is no moisture condenser
used or the compound is not
considered water soluble;
and for target compound(s)
not listed in Section 1.1 of
ASTM D6420–99 and not
amenable to detection by
mass spectrometry, ASTM
D6420–99 does not apply;
(c) you must conduct testing of
emissions from continuous
storage vessel vents and
combinations of batch and
continuous storage vessel
vents at normal operating
conditions, as specified in
§§ 63.7(e)(1) and 63.5535
for continuous process
vents;
(d) you must conduct testing of
emissions from batch storage vessel vents as specified in § 63.490(c) for batch
process vents, except that
the emission reductions required for process vents
under this subpart supersede the emission reductions required for process
vents under subpart U of this
part; and,
(e) you must collect CPMS
data during the period of the
initial compliance demonstration and determine the
CPMS operating limit during
the period of the initial compliance demonstration.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
6. the sum of all process vents
controlled using a flare.
a. each existing or new affected source.
i. measure visible emissions ....
(1) EPA Method 22 in Appendix A to Part 60 of this chapter.
(a) you must conduct the flare
visible emissions test according to § 63.11(b).
7. equipment leaks ..................
a. each existing or new cellulose ether operation.
i. measure leak rate .................
(1) applicable equipment leak
test methods in § 63.180; or
(a) you must follow all requirements for the applicable
equipment leak test methods
in § 63.180; or
(a) you must follow all requirements for the applicable
equipment leak test methods
in § 63.1023.
(2) applicable equipment leak
test methods in § 63.1023.
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1176
Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
For . . .
At . . .
You must . . .
Using . . .
According to the following
requirements . . .
8. all sources of wastewater
emissions.
a. each existing or new cellulose ether operation.
i. measure wastewater HAP
emissions.
(1) applicable wastewater test
methods and procedures in
§§ 63.144 and 63.145; or
(a) You must follow all requirements for the applicable
wastewater test methods
and procedures in §§ 63.144
and 63.145; or
(a) you must follow all requirements for the applicable
waste water test methods
and procedures in §§ 63.144
and 63.145, except that you
may use ASTM D5790–95
(available for purchase from
at least one of the following
addresses: 100 Barr Harbor
Drive, West Conshohocken,
PA 19428–2959; or University Microfilms International,
300 North Zeeb Road, Ann
Arbor, MI 48106) as an alternative to EPA Method 624,
under the condition that this
ASTM method be used with
the sampling procedures of
EPA Method 25D or an
equivalent method.
(2) applicable wastewater test
methods and procedures in
§§ 63.144 and 63.145, using
ASTM D5790–95 as an alternative to EPA Method 624
in Appendix A to Part 163 of
this chapter.
9. any emission point ...............
a. each existing or new affected source using a CEMS
to demonstrate compliance.
i. conduct a CEMS performance evaluation.
(1) applicable requirements in
§ 63.8 and applicable performance specification (PS–
7, PS–8, PS–9, or PS–15) in
Appendix B to part 60 of this
chapter.
(a) you must conduct the
CEMS performance evaluation during the period of the
initial compliance demonstration according to the applicable requirements in § 63.8
and the applicable performance specification (PS–7,
PS–8, PS–9, or PS–15) of
40 CFR part 60, Appendix B;
(b) you must install, operate,
and maintain the CEMS according to the applicable
performance specification
(PS–7, PS–8, PS–9, or PS–
15) of 40 CFR part 60, Appendix B; and
(c) you must collect CEMS
emissions data at the inlet
and outlet of each control
device during the period of
the initial compliance demonstration and determine the
CEMS operating limit during
the period of the initial compliance demonstration.
Subpart ZZZZ—National Emission
Standards for Hazardous Air Pollutants
for Stationary Reciprocating Internal
Combustion Engines
93. Amend Subpart ZZZZ by revising
Table 4 to read as follows:
TABLE 4 TO SUBPART ZZZZ OF PART 63—REQUIREMENTS FOR PERFORMANCE TESTS
[As stated in §§ 63.6610, 63.6611, 63.6620, and 63.6640, you must comply with the following requirements for performance tests for stationary
RICE]
tkelley on DSK3SPTVN1PROD with PROPOSALS2
For each . . .
Complying with the
requirement to . . .
You must . . .
Using . . .
According to the following requirements . . .
1. 2SLB, 4SLB, and
CI stationary RICE.
a. Reduce CO emissions.
i. Measure the O2 at
the inlet and outlet
of the control device; and
(1) Portable CO and
O2 analyzer.
(a) Using ASTM D6522–00 (2005) a (heated
probe not necessary; single-point sampling) (incorporated by reference, see
§ 63.14). Measurements to determine O2
must be made at the same time as the
measurements for CO concentration.
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Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
1177
TABLE 4 TO SUBPART ZZZZ OF PART 63—REQUIREMENTS FOR PERFORMANCE TESTS—Continued
[As stated in §§ 63.6610, 63.6611, 63.6620, and 63.6640, you must comply with the following requirements for performance tests for stationary
RICE]
Complying with the
requirement to . . .
For each . . .
a. Reduce formaldehyde emissions.
Using . . .
According to the following requirements . . .
ii. Measure the CO at
the inlet and the
outlet of the control
device.
2. 4SRB stationary
RICE.
You must . . .
(1) Portable CO and
O2 analyzer.
i. Sample at the centroid of the exhaust;
ii. Measure O2 at the
inlet and outlet of
the control device.
....................................
(a) Using ASTM D6522–00 (2005) a (heated
probe not necessary; single-point sampling) (incorporated by reference, see
§ 63.14) or Method 10 of 40 CFR part 60,
Appendix A. The CO concentration must
be at 15 percent O2, dry basis.
(a) Sampling sites must be located at the
inlet and outlet of the control device.
(a) Measurements to determine O2 concentration must be made at the same time
as the measurements for formaldehyde
concentration.
iii. Measure moisture
content at the inlet
and outlet of the
control device; and
iv. Measure formaldehyde at the inlet
and the outlet of the
control device.
3. Stationary RICE .....
a. Limit the concentration of formaldehyde
in the stationary
RICE exhaust.
i. Sample at the centroid of the exhaust;
ii. Determine the O2
concentration of the
stationary RICE exhaust at the sampling port location;
tkelley on DSK3SPTVN1PROD with PROPOSALS2
iii. Measure moisture
content of the stationary RICE exhaust at the sampling port location;
and,
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(1) Method 3 or 3A or
3B of 40 CFR part
60, Appendix A, or
ASTM Method
D6522–00 (2005)
(heated probe not
necessary; singlepoint sampling).
(1) Method 4 of 40
(a) Measurements to determine moisture
CFR part 60, Apcontent must be made at the same time
pendix A, or Test
and location as the measurements for
Method 320 of 40
formaldehyde concentration.
CFR part 63, Appendix A, or ASTM
D 6348–03.
(1) Method 320 or 323 (a) Formaldehyde concentration must be at
of 40 CFR part 63,
15 percent O2, dry basis. Results of this
Appendix A; or
test consist of the average of the three 1ASTM D6348–03,b
hour or longer runs.
provided in ASTM
D6348–03 Annex
A5 (Analyte Spiking
Technique), the percent R must be
greater than or
equal to 70 and less
than or equal to 130.
(a) If using a control device, the sampling
site must be located at the outlet of the
control device.
(1) Method 3 or 3A or
3B of 40 CFR part
60, Appendix A, or
ASTM Method
D6522–00 (2005)
(heated probe not
necessary; singlepoint sampling).
(1) Method 4 of 40
CFR part 60, Appendix A, or Test
Method 320 of 40
CFR part 63, Appendix A, or ASTM
D 6348–03.
Sfmt 4702
(a) Measurements to determine O2 concentration must be made at the same time
and location as the measurements for
formaldehyde concentration.
(a) Measurements to determine moisture
content must be made at the same time
and location as the measurements for
formaldehyde concentration.
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TABLE 4 TO SUBPART ZZZZ OF PART 63—REQUIREMENTS FOR PERFORMANCE TESTS—Continued
[As stated in §§ 63.6610, 63.6611, 63.6620, and 63.6640, you must comply with the following requirements for performance tests for stationary
RICE]
Complying with the
requirement to . . .
For each . . .
You must . . .
Using . . .
According to the following requirements . . .
iv. Measure formaldehyde at the exhaust
of the stationary
RICE.
(1) Method 320 or 323 (a) Formaldehyde concentration must be at
of 40 CFR part 63,
15 percent O2, dry basis. Results of this
test consist of the average of the three 1Appendix A; or
hour or longer runs.
ASTM D6348–03,b
provided in ASTM
D6348–03 Annex
A5 (Analyte Spiking
Technique), the percent R must be
greater than or
equal to 70 and less
than or equal to 130.
a You may also use Methods 3A and 10 as options to ASTM–D6522–00 (2005). You may obtain a copy of ASTM–D6522–00 (2005) from at
least one of the following addresses: American Society for Testing and Materials, 100 Barr Harbor Drive, West Conshohocken, PA 19428–2959,
or University Microfilms International, 300 North Zeeb Road, Ann Arbor, MI 48106.
b You may obtain a copy of ASTM–D6348–03 from at least one of the following addresses: American Society for Testing and Materials, 100
Barr Harbor Drive, West Conshohocken, PA 19428–2959, or University Microfilms International, 300 North Zeeb Road, Ann Arbor, MI 48106.
94. Amend Method 306 of Appendix
A to Part 63 by revising Sections 2.2.1,
6.1.4, and 8.0 to read as follows:
performed. Which analysis option(s) will be
performed will determine which sample
recovery and storage procedures will be
required to process the sample.
Appendix A to Part 63—Test Methods
Pollutant Measurement Methods From
Various Waste Media
*
*
*
*
*
*
*
*
*
*
95. Amend Method 306A of Appendix
A to Part 63 by revising Section 8.2 to
read as follows:
Method 306—Determination of Chromium
Emissions From Decorative and Hard
Chromium Electroplating and Chromium
Anodizing Operations—Isokinetic Method
Method 306A—Determination of Chromium
Emissions From Decorative and Hard
Chromium Electroplating and Chromium
Anodizing Operations
*
*
*
*
*
*
2.2.1 Total chromium samples with high
chromium concentrations (≥35 mg/L) may be
analyzed using inductively coupled plasma
emission spectrometry (ICP) at 267.72 nm.
Note: The ICP analysis is applicable for this
method only when the solution analyzed has
a Cr concentration greater than or equal to 35
mg/L or five times the method detection limit
as determined according to Appendix B in 40
CFR part 136. Similarly, inductively coupled
plasma-mass spectroscopy (ICP–MS) may be
used for total chromium analysis provided
the procedures for ICP–MS analysis
described in Method 6020 or 6020A (EPA
Office of Solid Waste, publication SW–846)
are followed.
tkelley on DSK3SPTVN1PROD with PROPOSALS2
*
*
*
*
*
6.1.4 Operating and maintenance
procedures for the sampling train are
described in APTD–0576 of Method 5. Users
should read the APTD–0576 document and
adopt the outlined procedures. Alternative
mercury-free thermometers may be used if
the thermometers are, at a minimum,
equivalent in terms of performance or
suitably effective for the specific temperature
measurement application.
*
*
*
*
*
Note: Prior to sample collection,
consideration should be given to the type of
analysis (Cr +6 or total Cr) that will be
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*
*
*
*
*
*
*
*
96. Amend Method 308 of Appendix
A to Part 63 by revising Section 10.1.3
to read as follows:
Method 308—Procedure for Determination
of Methanol Emission From Stationary
Sources
8.0 Sample Collection, Preservation,
Holding Times, Storage, and Transport
VerDate Mar<15>2010
*
8.2 Sample Recovery. After the train has
been transferred to the sample recovery area,
disconnect the tubing that connects the jar/
impingers. The tester shall select either the
total Cr or Cr +6 sample recovery option.
Samples to be analyzed for both total Cr and
Cr +6 shall be recovered using the Cr +6
sample option (Section 8.2.2). Note: Collect
a reagent blank sample for each of the total
Cr or the Cr +6 analytical options. If both
analyses (Cr and Cr +6) are to be conducted
on the samples, collect separate reagent
blanks for each analysis. Also, since
particulate matter is not usually present at
chromium electroplating and/or chromium
anodizing operations, it is not necessary to
filter the Cr +6 samples unless there is
observed sediment in the collected solutions.
If it is necessary to filter the Cr +6 solutions,
please refer to Method 0061, Determination
of Hexavalent Chromium Emissions from
Stationary Sources, Section 7.4, Sample
Preparation in SW–846 (see Reference 1).
*
*
*
*
*
10.1.3 Temperature Sensors. Calibrate
against mercury-in-glass thermometers. An
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Sfmt 4702
alternative mercury-free thermometer may be
used if the thermometer is, at a minimum,
equivalent in terms of performance or
suitably effective for the specific temperature
measurement application.
*
*
*
*
*
97. Amend Method 315 of Appendix
A to Part 63 by revising Sections 6.1.1
and 10.5 and by redesignating Section
8.11 as 8.1 and revising newly
designated section 8.1 to read as
follows:
Method 315—Determination of Particulate
and Methylene Chloride Extractable Matter
(MCEM) From Selected Sources at Primary
Aluminum Production Facilities
*
*
*
*
*
6.1.1 Sampling train. A schematic of the
sampling train used in this method is shown
in Figure 5–1, Method 5, 40 CFR part 60,
Appendix A. Complete construction details
are given in APTD–0581 (Reference 2 in
section 17.0 of this method); commercial
models of this train are also available. For
changes from APTD–0581 and for allowable
modifications of the train shown in Figure
5–1, Method 5, 40 CFR part 60, Appendix A,
see the following subsections. Note: The
operating and maintenance procedures for
the sampling train are described in APTD–
0576 (Reference 3 in section 17.0 of this
method). Since correct usage is important in
obtaining valid results, all users should read
APTD–0576 and adopt the operating and
maintenance procedures outlined in it,
unless otherwise specified herein.
Alternative mercury-free thermometers may
be used if the thermometers are, at a
minimum, equivalent in terms of
performance or suitably effective for the
specific temperature measurement
application. The use of grease for sealing
sampling train components is not
recommended because many greases are
soluble in methylene chloride. The sampling
train consists of the following components:
*
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*
*
09JAP2
*
*
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Federal Register / Vol. 77, No. 5 / Monday, January 9, 2012 / Proposed Rules
8.1 Pretest preparation. It is suggested
that sampling equipment be maintained
according to the procedures described in
APTD–0576. Alternative mercury-free
thermometers may be used if the
thermometers are at a minimum equivalent
in terms of performance or suitably effective
for the specific temperature measurement
application.
*
*
*
*
*
tkelley on DSK3SPTVN1PROD with PROPOSALS2
10.5 Temperature sensors. Use the
procedure in Section 10.3 of Method 2, 40
CFR part 60, Appendix A to calibrate in-stack
temperature sensors. Dial thermometers, such
as are used for the DGM and condenser
outlet, shall be calibrated against mercury-inglass thermometers. An alternative mercuryfree thermometer may be used if the
thermometer is, at a minimum, equivalent in
terms of performance or suitably effective for
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the specific temperature measurement
application.
specific temperature measurement
application.
*
*
*
*
*
*
98. Amend Method 316 of Appendix
A to Part 63 by revising Section 10.5 to
read as follows:
Method 316—Sampling and Analysis for
Formaldehyde Emissions From Stationary
Sources in the Mineral Wool and Wool
Fiberglass Industries
*
*
*
*
*
10.5 Temperature gauges: Use the
procedure in Section 4.3 of EPA Method 2 to
calibrate in-stack temperature gauges. Dial
thermometers, such as are used for the dry
gas meter and condenser outlet, shall be
calibrated against mercury-in-glass
thermometers. An alternative mercury-free
thermometer may be used if the thermometer
is, at a minimum, equivalent in terms of
performance or suitably effective for the
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Sfmt 9990
*
*
*
*
99. Amend Method 321 of Appendix
A to Part 63 by revising the definition
for the term ‘‘Df’’ after equation (2) in
Section 9.3.1 to read as follows:
Test Method 321—Measurement of Gaseous
Hydrogen Chloride Emissions at Portland
Cement Kilns by Fourier Transform Infrared
(FTIR) Spectroscopy
*
*
*
*
*
9.3 * * *
DF = Dilution Factor (Total flow/Spike flow).
Total flow = spike flow plus effluent
flow.
*
*
*
*
*
[FR Doc. 2011–31234 Filed 1–6–12; 8:45 am]
BILLING CODE 6560–50–P
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Agencies
[Federal Register Volume 77, Number 5 (Monday, January 9, 2012)]
[Proposed Rules]
[Pages 1130-1179]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: 2011-31234]
[[Page 1129]]
Vol. 77
Monday,
No. 5
January 9, 2012
Part II
Environmental Protection Agency
-----------------------------------------------------------------------
40 CFR Parts 51, 60, 61, et al.
Revisions to Test Methods and Testing Regulations; Proposed Rule
Federal Register / Vol. 77 , No. 5 / Monday, January 9, 2012 /
Proposed Rules
[[Page 1130]]
-----------------------------------------------------------------------
ENVIRONMENTAL PROTECTION AGENCY
40 CFR Parts 51, 60, 61, and 63
[EPA-HQ-OAR-2010-0114; FRL-9501-3]
RIN 2060-AQ01
Revisions to Test Methods and Testing Regulations
AGENCY: Environmental Protection Agency (EPA).
ACTION: Proposed rule.
-----------------------------------------------------------------------
SUMMARY: This action proposes editorial and technical corrections
necessary for source testing of emissions and operations. The revisions
include the addition of alternative equipment and methods as well as
corrections to technical and typographical errors. We also solicit
public comment on potential changes to the current procedures for
determining emission stratification.
DATES: Comments must be received on or before March 9, 2012.
Public Hearing. If anyone contacts the EPA by January 19, 2012
requesting to speak at a public hearing, a hearing will be held on
February 8, 2012.
ADDRESSES: Submit your comments, identified by Docket ID No. EPA-HQ-
OAR-2010-0114, by one of the following methods:
www.regulations.gov: Follow the on-line instructions for
submitting comments.
Email: a-and-r-docket@epa.gov.
Fax: (202) 566-9744.
Mail: Revisions to Test Methods and Testing Regulations,
Docket No. EPA-HQ-OAR-2010-0114, Environmental Protection Agency,
Mailcode: 2822T, 1200 Pennsylvania Ave. NW., Washington, DC 20460.
Please include two copies.
Hand Delivery: Docket No. EPA-HQ-OAR-2010-0114, EPA Docket
Center, Public Reading Room, EPA West, Room 3334, 1301 Constitution
Ave. NW., Washington, DC 20460. Such deliveries are only accepted
during the Docket's normal hours of operation, and special arrangements
should be made for deliveries of boxed information.
Instructions: Direct your comments to Docket ID No. EPA-HQ-OAR-
2010-0114. The EPA's policy is that all comments received will be
included in the public docket without change and may be made available
online at https://www.regulations.gov, including any personal
information provided, unless the comment includes information claimed
to be Confidential Business Information (CBI) or other information
whose disclosure is restricted by statute. Do not submit information
that you consider to be CBI or otherwise protected through
www.regulations.gov or email. The www.regulations.gov Web site is an
``anonymous access'' system, which means the EPA will not know your
identity or contact information unless you provide it in the body of
your comment. If you send an email comment directly to the EPA without
going through www.regulations.gov, your email address will be
automatically captured and included as part of the comment that is
placed in the public docket and made available on the Internet. If you
submit an electronic comment, the EPA recommends that you include your
name and other contact information in the body of your comment as well
as with any disk or CD-ROM you submit. If the EPA cannot read your
comment due to technical difficulties and cannot contact you for
clarification, the EPA may not be able to consider your comment.
Electronic files should avoid the use of special characters, any form
of encryption, and be free of any defects or viruses.
Docket: All documents in the docket are listed in the
www.regulations.gov index. Although listed in the index, some
information is not publicly available, e.g., CBI or other information
whose disclosure is restricted by statute. Certain other material, such
as copyrighted material, will be publicly available only in hard copy.
Publicly available docket materials are available either electronically
in www.regulations.gov or in hard copy at the Revisions to Test Methods
and Testing Regulations Docket, EPA/DC, EPA West, Room 3334, 1301
Constitution Ave. NW., Washington, DC 20460. The Public Reading Room is
open from 8:30 a.m. to 4:30 p.m., Monday through Friday, excluding
legal holidays. The telephone number for the Public Reading Room is
(202) 566-1744, and the telephone number for the Revisions to Test
Methods and Testing Regulations Docket is (202) 566-1742.
FOR FURTHER INFORMATION CONTACT: Mr. Foston Curtis, Office of Air
Quality Planning and Standards, Air Quality Assessment Division (E143-
02), Environmental Protection Agency, Research Triangle Park, NC 27711;
telephone number: (919) 541-1063; fax number: (919) 541-0516; email
address: curtis.foston@epa.gov.
SUPPLEMENTARY INFORMATION:
I. General Information
A. Does this action apply to me?
The proposed amendments apply to a large number of industries that
are already subject to the current provisions of Parts 51, 60, 61, and
63. Therefore, we have not listed specific affected industries or their
North American Industry Classification System (NAICS) codes here. If
you have any questions regarding the applicability of this action to a
particular entity, consult either the air permitting authority for the
entity or your EPA regional representative as listed in 40 CFR 63.13.
B. What should I consider as I prepare my comments for the EPA?
1. Submitting CBI. Do not submit this information to the EPA
through https://www.regulations.gov or email. Clearly mark any of the
information that you claim to be CBI. For CBI information in a disk or
CD-ROM that you mail to the EPA, mark the outside of the disk or CD-ROM
as CBI and then identify electronically within the disk or CD-ROM the
specific information that is claimed as CBI. In addition to one
complete version of the comment that includes information claimed as
CBI, a copy of the comment that does not contain the information
claimed as CBI must be submitted for inclusion in the public docket.
Information so marked will not be disclosed except in accordance with
procedures set forth in 40 CFR part 2.
2. Tips for Preparing Your Comments. When submitting comments,
remember to:
Follow directions--The Agency may ask you to respond to
specific questions or organize comments by referencing a Code of
Federal Regulations (CFR) part or section number.
Explain why you agree or disagree, suggest alternatives,
and substitute language for your requested changes.
Describe any assumptions and provide any technical
information and/or data that you used.
If you estimate potential costs or burdens, explain how
you arrived at your estimate in sufficient detail to allow for it to be
reproduced.
Provide specific examples to illustrate your concerns, and
suggest alternatives.
Explain your views as clearly as possible, avoiding the
use of profanity or personal threats.
Make sure to submit your comments by the comment period
deadline identified.
C. Where can I get a copy of this document?
In addition to being available in the docket, an electronic copy of
this proposed rule will also be available on the Worldwide Web (WWW)
through the Technology Transfer Network (TTN). Following signature, a
copy of
[[Page 1131]]
this proposed rule will be posted on the TTN's policy and guidance page
for newly proposed or promulgated rules at the following address:
https://www.epa.gov/ttn/oarpg/. The TTN provides information and
technology exchange in various areas of air pollution control. A
redline/strikeout document comparing the proposed revisions to the
appropriate sections of the current rules is located in the docket.
D. How is this document organized?
The supplementary information in this preamble is organized as
follows:
I. General Information
A. Does this action apply to me?
B. What should I consider as I prepare my comments for the EPA?
C. Where can I get a copy of this document?
D. How is this document organized?
II. Background
III. Summary of Amendments
A. Appendix M of Part 51
B. Method 201A of Appendix M of Part 51
C. Method 202 of Appendix M of Part 51
D. General Provisions (Subpart A) Part 60
E. Industrial-Commercial-Institutional Steam Generating Units
(Subpart Db) Part 60
F. Hospital/Medical/Infectious Waste Incinerators (Subpart Ec)
Part 60
G. Sulfuric Acid Plants (Subpart H) Part 60
H. Sewage Treatments Plants (Subpart O) Part 60
I. Kraft Pulp Mills (Subpart BB) Part 60
J. Stationary Gas Turbines (Subpart GG) Part 60
K. Lead-Acid Battery Manufacturing Plants (Subpart KK) Part 60
L. Metallic Mineral Processing Plants (Subpart LL) Part 60
M. Asphalt Processing and Asphalt Roofing Manufacture (Subpart
UU) Part 60
N. Volatile Organic Chemical (VOC) Emissions From Synthetic
Organic Compound Manufacturing Industry (SOCMI) Distillation
Operations (Subpart NNN) Part 60
O. Stationary Compression Ignition Internal Combustion Engines
(Subpart IIII) Part 60
P. Stationary Spark Ignition Internal Combustion Engines
(Subpart JJJJ) Part 60
Q. Method 1 of Appendix A-1 of Part 60
R. Method 2 of Appendix A-1 of Part 60
S. Method 2A of Appendix A-1 of Part 60
T. Method 2B of Appendix A-1 of Part 60
U. Method 2D of Appendix A-1 of Part 60
V. Method 3A of Appendix A-2 of Part 60
W. Method 4 of Appendix A-3 of Part 60
X. Method 5 of Appendix A-3 of Part 60
Y. Method 5A of Appendix A-3 of Part 60
Z. Method 5E of Appendix A-3 of Part 60
AA. Method 5H of Appendix A-3 of Part 60
BB. Method 6 of Appendix A-4 of Part 60
CC. Method 6C of Appendix A-4 of Part 60
DD. Method 7 of Appendix A-4 of Part 60
EE. Method 7A of Appendix A-4 of Part 60
FF. Method 7E of Appendix A-4 of Part 60
GG. Method 8 of Appendix A-4 of Part 60
HH. Method 10 of Appendix A-4 of Part 60
II. Methods 10A and 10B of Appendix A-4 of Part 60
JJ. Method 11 of Appendix A-5 of Part 60
KK. Method 12 of Appendix A-5 of Part 60
LL. Method 14A of Appendix A-5 of Part 60
MM. Method 16A of Appendix A-6 of Part 60
NN. Method 18 of Appendix A-6 of Part 60
OO. Method 23 of Appendix A-7 of Part 60
PP. Method 24 of Appendix A-7 of Part 60
QQ. Method 25 of Appendix A-7 of Part 60
RR. Method 25C of Appendix A-7 of Part 60
SS. Method 25D of Appendix A-7 of Part 60
TT. Method 26 of Appendix A-8 of Part 60
UU. Method 29 of Appendix A-8 of Part 60
VV. Method 30B of Appendix A-8 of Part 60
WW. Performance Specification 1 of Appendix B of Part 60
XX. Performance Specification 3 of Appendix B of Part 60
YY. Performance Specification 4 of Appendix B of Part 60
ZZ. Performance Specification 4B of Appendix B of Part 60
AAA. Performance Specification 7 of Appendix B of Part 60
BBB. Performance Specification 11 of Appendix B of Part 60
CCC. Performance Specification 15 of Appendix B of Part 60
DDD. Performance Specification 16 of Appendix B of Part 60
EEE. Procedure 1 of Appendix F of Part 60
FFF. Procedure 2 of Appendix F of Part 60
GGG. Procedure 5 of Appendix F of Part 60
HHH. General Provisions (Subpart A) Part 61
III. Beryllium (Subpart C) Part 61
JJJ. Beryllium Rocket Motor Firing (Subpart D) Part 61
KKK. Mercury (Subpart E) Part 61
LLL. Inorganic Arsenic Emissions from Glass Manufacturing Plants
(Subpart N) Part 61
MMM. Method 101 of Appendix B of Part 61
NNN. Method 101A of Appendix B of Part 61
OOO. Method 102 of Appendix B of Part 61
PPP. Method 104 of Appendix B of Part 61
QQQ. Methods 108 and 108A of Appendix B of Part 61
RRR. General Provisions (Subpart A) Part 63
SSS. Synthetic Organic Chemical Manufacturing Industry (Subpart
G) Part 63
TTT. Chromium Emissions From Hard and Decorative Chromium
Electroplating and Chromium Anodizing Tanks (Subpart N) Part 63
UUU. Ethylene Oxide Emissions Standards for Sterilization
Facilities (Subpart O) Part 63
VVV. Marine Tank Vessel Loading Operations (Subpart Y) Part 63
WWW. Aerospace Manufacturing and Rework Facilities (Subpart GG)
Part 63
XXX. Pharmaceuticals Production (Subpart GGG) Part 63
YYY. Secondary Aluminum Production (Subpart RRR) Part 63
ZZZ. Manufacturing of Nutritional Yeast (Subpart CCCC) Part 63
AAAA. Petroleum Refineries: Catalytic Cracking Units, Catalytic
Reforming Units, and Sulfur Recovery Units (Subpart UUUU) Part 63
BBBB. Stationary Reciprocating Internal Combustion Engines
(Subpart ZZZZ) Part 63
CCCC. Method 306 of Appendix A of Part 63
DDDD. Method 306A of Appendix A of Part 63
EEEE. Methods 308, 315, and 316 of Appendix A of Part 63
FFFF. Method 321 of Appendix A of Part 63
IV. Request for Comments
V. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory Planning and Review and
Executive Order 13563: Improving Regulations and Regulatory Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act
D. Unfunded Mandates Reform Act
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation and Coordination With
Indian Tribal Governments
G. Executive Order 13045: Protection of Children From
Environmental Health and Safety Risks
H. Executive Order 13211: Actions Concerning Regulations That
Significantly Affect Energy Supply, Distribution, or Use
I. National Technology Transfer and Advancement Act
J. Executive Order 12898: Federal Actions To Address
Environmental Justice in Minority Populations and Low-Income
Populations
II. Background
The EPA catalogs revisions and updates that are needed for test
methods, performance specifications, and associated regulations in 40
CFR parts 51, 60, 61, and 63, and proposes the revisions on a 5- to 10-
year basis. The last methods update was published as a final rule on
October 17, 2000 (65 FR 61744). Many of these needed revisions were
brought to our attention by affected parties and end-users. The
revisions consist of allowable alternatives that were not previously
available, changes that facilitate the use of mercury-free equipment,
and updates needed to correct obsolete provisions or add flexibility.
Corrections to typographical errors and technical errors in equations
and diagrams are also proposed. It is important to note that although
numerous technical
[[Page 1132]]
corrections are being proposed to portions of the subparts in parts 51,
60, 61, and 63, changes are not made to any compliance standard,
reporting, or recordkeeping requirement. For this notice, the EPA is
only proposing revisions to sections of the subpart pertaining to
source testing or monitoring of emissions and operations.
III. Summary of Amendments
A. Appendix M of Part 51
In the introduction of Appendix M of part 51, Methods 3A and 19
would be added to the list of methods not requiring the use of audit
samples. Method 3A is a direct measurement instrumental method which
the audit program does not evaluate, and Method 19 deals with
calculation procedures and not measurement procedures.
B. Method 201A of Appendix M of Part 51
Revisions would be made to the Method 201A published on December
21, 2010. Typographical errors in references to isokinetic sampling
rate, source gas temperatures, stack blockage dimensions by the
sampling heads, and PM10 in Sections 8.3.4(b), 8.3.4.1,
8.7.2.2, and 8.7.5.5(a), respectively, would be corrected. An erroneous
reference to Methods 4A and 5 in Section 10.1 when using a standard
pitot tube would be corrected to refer to Methods 1 and 2. Section
10.5, which addresses Class A volumetric glassware, would be deleted
because it is not needed in the method. For those filters whose weight
cannot be weighed to a constant weight in Section 11.2.1, instruction
would be added to flag and report the data as a minimum value. It would
be noted that the nozzle, front half, and in-stack filter samples need
to be speciated into organic and inorganic fractions to be similar to
the practice in Method 17. The method would also note that neither
Method 17 nor 201A require a separate analysis of the filter for
inorganic and organic particulate matter. Method 201A is often used
together with Method 202 which requires a separate analysis of
inorganic and organic PM. This note would remind testers that a
separate analysis is not required for Method 201A. An incorrect term in
Equation 9 of Section 12.5 would be corrected. In the nomenclature in
Section 12.1, Vb, the volume of aliquot taken for ion
chromatography (IC) analysis, would be deleted since no IC analysis is
performed.
C. Method 202 of Appendix M of Part 51
Revisions would be made to the Method 202 published on December 21,
2010. In Section 8.5.3.1, the text referring to empty impingers would
be deleted because empty impingers are not used. Figures 2 and 3 would
be revised to correctly show the first impinger with an extended stem
instead of a shortened one to be consistent with the method text, and
the condensed moisture and sample portion of the sampling train would
be labeled to make it easy to identify. Figures 4, 5, and 6 would be
republished because they did not print clearly in the December 21,
2010, publication.
D. General Provisions (Subpart A) Part 60
In the General Provisions of part 60, Methods 3A and 19 would be
added to the list of methods not requiring the use of audit samples in
Sec. 60.8(gd). Method 3A is a direct measurement instrumental method
which the audit program does not evaluate, and Method 19 deals with
calculation procedures in lieu of measurement procedures.
A new Sec. 60.8(h) would be added to require that sampling sites
be evaluated for cyclonic flow and stratification before testing.
Cyclonic flow and gas stratification has not been adequately addressed
in the past except for particulate measurement methods. Our experience
has been that gaseous pollutant measurements may also be affected by
these phenomena. Procedures currently used in Methods 1 and 7E would be
referenced for all tests to evaluate the suitability of test locations
and give procedures for testing under conditions of gas stratification
and cyclonic flow to preclude non-representative sampling.
A new Sec. 60.8(i) would be added to allow the use of Method 205
of 40 CFR part 51, Appendix M, ``Verification of Gas Dilution Systems
for Field Instrument Calibrations,'' as an alternative provision
whenever the use of multiple calibration gases is required under Part
60. Method 205 has previously been allowed for different applications
on a case-by-case basis. Method 205 reduces the number of cylinder
gases needed for a test by allowing lower-concentration gases to be
generated from a high-level gas. Section 60.13(d)(1) would be revised
to remove the phrase ``automatically, intrinsic to the opacity
monitor'' which was incorrectly inserted into the paragraph in a past
revision. The title of an organization in a method that is incorporated
by reference would be updated in Sec. 60.17(e), and the edition of the
method referred to in Sec. 60.17(e)(1) would be updated to reflect the
currently available version.
E. Industrial-Commercial-Institutional Steam Generating Units (Subpart
Db) Part 60
In subpart Db, Method 320 would be added as an alternative to the
methods for determining nitrogen oxides (NOX) concentration
in Sec. 60.46b(f)(1)(ii), (h)(1) and (2), and sulfur dioxide
(SO2) concentration in Sec. 60.47b(b)(2). The EPA has
allowed the use of Method 320 in the past on a case-by-case basis and
now believes it is appropriate for general use.
F. Hospital/Medical/Infectious Waste Incinerators (Subpart Ec) Part 60
In subpart Ec, the definition of medical/infectious wastes in Sec.
60.51c would be revised to correct the misspelling of ``cremation.''
G. Sulfuric Acid Plants (Subpart H) Part 60
In Subpart H, an equation for calculating the SO2
emission rate in Sec. 60.84(d) would be corrected.
H. Sewage Treatment Plants (Subpart O) Part 60
In subpart O, a reference to Method 209F in Sec. 60.154(b)(5)
would be revised to reflect a newer available version of the method
(i.e., 2540G).
I. Kraft Pulp Mills (Subpart BB) Part 60
In subpart BB, a typographical error in the equation in Sec.
60.284(c)(3) would be corrected.
J. Stationary Gas Turbines (Subpart GG) Part 60
In subpart GG, the definitions of terms for the equation in Sec.
60.335(b)(l) would be revised to allow the reference combustor inlet
absolute pressure to be measured in millimeters of mercury (mm Hg).
Using the site barometric pressure gives comparable results to the
observed combustor inlet absolute pressure for calculating the mean
NOX emission concentration and would be allowed as an
alternative.
K. Lead-Acid Battery Manufacturing Plants (Subpart KK) Part 60
In subpart KK, Method 29 would be added as an alternative to Method
12 in Sec. 60.374(b)(1)and (c)(2) for determining the lead
concentration and flow rate of the effluent gas. Method 29 is an
accepted method for determining lead under other rules and is
appropriate for this subpart as well. Also, an error in the equation
for calculating the lead emission concentration in 60.374(b)(2) would
be corrected.
[[Page 1133]]
L. Metallic Mineral Processing Plants (Subpart LL) Part 60
In subpart LL, an error in the value of the particulate matter
standard in Sec. 60.382(a)(1) would be corrected from 0.02 g/dscm to
0.05 g/dscm. An alternative procedure, where a single visible emission
observer may conduct visible emission observations for up to three
fugitive, stack, or vent emission points within a 15-second interval,
would be added to Sec. 60.386. This alternative would allow the
observer to take readings in a more cost-effective and timely manner
than currently allowed.
M. Asphalt Processing and Asphalt Roofing Manufacture (Subpart UU) Part
60
In subpart UU, an error in the value of the particulate matter
standard for saturated felt or smooth-surfaced roll roofing in Sec.
60.472(a)(1)(ii) would be corrected from 0.04 kg/Mg to 0.4 kg/Mg.
N. Volatile Organic Compound (VOC) Emissions From Synthetic Organic
Chemical Manufacturing Industry (SOCMI) Distillation Operations
(Subpart NNN) Part 60
In subpart NNN, several paragraphs were renumbered in a previous
amendment, but conforming changes in sections that referenced these
paragraphs were not made. In Sec. 60.660(c)(4) and Sec. 60.665(h)(2)
and (3), these references would be corrected.
O. Stationary Compression Ignition Internal Combustion Engines (Subpart
IIII) Part 60
In Subpart IIII, the use of Method 1 or 1A for sampling point
selection would be dropped, and single-point sampling at the centroid
of the exhaust would be added. The exhausts of most regulated engines
are too small and not equipped with sampling ports. This makes it
difficult to divide the exhaust into multiple sampling-point locations
as required by Methods 1 and 1A. Table 7 would be revised to delete the
requirement to use Method 1 or 1A.
P. Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ)
Part 60
In Subpart JJJJ, the exhausts of most regulated engines do not
contain sampling ports and are too small to be subdivided into multiple
sampling-point locations. Table 2 would be revised to delete the
requirement to use Method 1 or 1A for determining sampling site and
sampling-point location, and instruction would be added to sample at
the centroid of the exhaust.
Q. Method 1 of Appendix A-1 of Part 60
In Method 1, Section 11.2.2 would be clarified to note that it
specifically applies to gaseous measurements. The provisions in the
section for determining exhaust gas stratification would be streamlined
to make them consistent with the new stratification provisions in
Method 7E. Figures 1-1 and 1-2 would be clarified to note that the
horizontal coordinates represent the duct diameters from the sampling
point to the flow disturbance and not simply the duct diameters from
the flow disturbance. Figure 1-2 would also be corrected to show the
proper demarcation between the requirement for 12 and 16 sampling
points. The test for the presence or absence of cyclonic flow would be
required for all tests instead of recommended at sites suspected of
having cyclonic flow.
R. Method 2 of Appendix A-1 of Part 60
In Method 2, a pressure stability specification that has been
lacking for the pitot tube leak-check would be added to clearly note
the desired stability. An erroneous reference to a Figure 2-6B would be
corrected to reference Figure 2-7B. An error in a term in the
denominator of Equation 2-7 would be corrected to the average of the
square root of delta P rather than the square root of the average delta
P. The velocity constant in English units used in Equation 2-7 would be
corrected by changing m/sec to ft/sec. The term for absolute
temperature in Equations 2-7 and 2-8 would be corrected to represent
the average of the absolute temperatures; an inadvertently omitted term
would be added to Section 12.1 for the average absolute temperature;
and calibrating a barometer against a NIST-traceable barometer would be
added as an alternative to calibrating against a mercury barometer to
facilitate the use of mercury-free products.
S. Method 2A of Appendix A-1 of Part 60
In Method 2A, calibrating a barometer against a NIST-traceable
barometer would be added as an alternative to calibrating against a
mercury barometer to facilitate the use of mercury-free products.
T. Method 2B of Appendix A-1 of Part 60
In Method 2B, nomenclature errors would be corrected and the
assumed ambient carbon dioxide concentration used in the calculations
would be changed from 300 to 380 ppm to closer approximate current
ambient levels.
U. Method 2D of Appendix A-1 of Part 60
In Method 2D, calibrating a barometer against a NIST-traceable
barometer would be added as an alternative to calibrating against a
mercury barometer to facilitate the use of mercury-free products.
V. Method 3A of Appendix A-2 of Part 60
In Method 3A, a redundant sentence noting that pre-cleaned air may
be used for the high-level calibration gas would be deleted.
W. Method 4 of Appendix A-3 of Part 60
In Method 4, the English value for the leak rate exceedance in
Section 9.1 would be corrected from 0.20 cfm to 0.020 cfm. Method 6A,
Method 320, and a calculation using F-factors would be added as
alternatives to Method 4 for the moisture determination. These are
logical alternatives in cases where Methods 6A and 320 are already
being used, and the F-factors approach can save both time and expenses
in some cases.
X. Method 5 of Appendix A-3 of Part 60
In Method 5, a clarification would be added that the deionized
water used in the analysis of material caught in the impingers must
have <=0.001 percent residue; the factor K would be corrected to K' in
Equation 5-13; calibrating a barometer against a NIST-traceable
barometer would be added as an alternative to calibrating against a
mercury barometer to facilitate the use of mercury-free products;
calibrating a temperature sensor against a thermometer equivalent to a
mercury-in-glass thermometer would be added as an alternative to
calibrating against a mercury-in-glass thermometer to facilitate the
use of mercury-free products; rechecking temperature sensors for the
filter holder and metering system after each test has been found to be
sufficient and would replace having sensors calibrated within 3 [deg]F;
the option to check the probe heater calibration after a test at a
single point using a reference thermometer would be added; the use of
weather station barometric pressure corrected to testing point
elevation would be added as an option to having an on-site barometer;
mention of stopcock grease for air-tight impinger seals would be
deleted since it is outdated and not often used; a smaller acetone
cleanup blank is determined sufficient and a single blank per container
would be allowed in place of a blank from each wash bottle; Section
10.3.3 would be clarified as a post-test
[[Page 1134]]
metering system calibration check rather than a metering system
calibration, and an alternative metering check procedure would be
added; the Isostack metering system would be noted as an acceptable
system for determining sample flow rates; the use of a Teflon filter
holder would be allowed without having to obtain the Administrator's
approval first; and Reference 13 for post-test calibration would be
added to the method.
Y. Method 5A of Appendix A-3 of Part 60
In Method 5A, mercury-free thermometers would be added as an
alternative to mercury-in-glass thermometers to facilitate the use of
mercury-free products.
Z. Method 5E of Appendix A-3 of Part 60
In Method 5E, the use of the Rosemount Model 2100A total organic
content analyzer would be replaced with the Tekmar-Dohrmann or
equivalent analyzer, as neither the Rosemount analyzer nor any similar
dual-injection analyzer is currently manufactured. Also, Section 12.5
inadvertently labels the equation for total particulate concentration
as Eq. 5E-4, which would be corrected to Eq. 5E-5.
AA. Method 5H of Appendix A-3 of Part 60
In Method 5H, Section 12.1 would be revised to add missing terms
Ci, Co, Qi, and Qo; and
procedures for the determination of an alternative tracer gas flow rate
would be added.
BB. Method 6 of Appendix A-4 of Part 60
In Method 6, calibrating a temperature sensor against a thermometer
equivalent to a mercury-in-glass thermometer would be added as an
alternative to using a mercury-in-glass thermometer, and calibrating a
barometer against a NIST-traceable barometer would be added as an
alternative to calibrating against a mercury barometer. These revisions
would facilitate the use of mercury-free products.
CC. Method 6C of Appendix A-4 of Part 60
In Section 4.0 of Method 6C, an incorrect reference to Section 4.1
of Method 6 would be corrected to reference Section 4.0 of Method 7E.
Provisions that were removed from the original method that addressed
potential quenching effects in fluorescence analyzers would be added
again. It was previously believed that current fluorescence analyzers
are not affected by quenching effects; however, we were informed that
the provisions are still needed in many cases.
DD. Method 7 of Appendix A-4 of Part 60
In Method 7, procedures would be added to avoid biased results when
sampling under conditions of high SO2 concentrations;
calibrating a barometer against a NIST-traceable barometer would be
added as an alternative to calibrating against a mercury barometer; and
calibrating a temperature sensor against a thermometer equivalent to a
mercury-in-glass thermometer would be added as an alternative to using
a mercury-in-glass thermometer. These revisions would facilitate the
use of mercury-free products.
EE. Method 7A of Appendix A-4 of Part 60
In Method 7A, new procedures would be added to avoid biased results
when sampling under conditions of high SO2 concentrations,
and calibrating a temperature sensor against a thermometer equivalent
to a mercury-in-glass thermometer would be added as an alternative to
using a mercury-in-glass thermometer to facilitate the use of mercury-
free products.
FF. Method 7E of Appendix A-4 of Part 60
In Method 7E, the instructions for choosing the high-level
calibration gas would be clarified. Instructions would be added to
minimize contact of the sample with any condensate to reduce the chance
of sample loss, and an error in the traverse point locations used to
determine stratification across large stacks would be corrected. A
statement noting that the stratification test is not required at
sources with temporally varying emissions or low-concentration
emissions would be added since a stratification test under such
conditions would be meaningless or difficult to pass. The basis of a
stable response for measurements in the system response time
determination would be revised in Section 8.2.5 to conform with Section
8.2.6. The response time reading would be recorded after the
concentration reading has reached 95 percent or within 0.5 ppm of a
stable response for the gas instead of after reaching 95 percent of the
certified gas concentration. This change removes a potential conflict
between the response time stable reading criterion and the bias or
system calibration error test criterion. Alternative sampling bags made
of materials other than Tedlar would be allowed if the materials are
applicable for retaining the compounds of interest. Tedlar bags are no
longer being produced.
GG. Method 8 of Appendix A-4 of Part 60
In Method 8, corrections would be made to errors in the sample
aliquot volumes required for containers 1 and 2 and in the values for
Va and Vsoln. Figure 8-1 would be clarified to
identify which impingers collect sulfuric acid/sulfur trioxide and
which collect sulfur dioxide.
HH. Method 10 of Appendix A-4 of Part 60
Method 10 would be revised to allow the use of sample tanks as an
alternative to flexible bags for sample collection. Tanks are an
acceptable collection medium, are currently allowed for carbon monoxide
in other EPA methods, and are appropriate for Method 10 as well.
II. Methods 10A and 10B of Appendix A-4 of Part 60
In Methods 10A and 10B, sampling bags made of materials other than
Tedlar would be allowed if the materials have the sample retaining
qualities of Tedlar. Tedlar bags are no longer produced.
JJ. Method 11 of Appendix A-5 of Part 60
Method 11 would be revised to address sample breakthrough at high
concentrations. An additional collection impinger would be added to the
train whenever the final impinger solution exhibits a yellow color.
Calibrating a temperature sensor against a thermometer equivalent to a
mercury-in-glass thermometer would be added as an alternative to using
a mercury-in-glass thermometer to facilitate the use of mercury-free
products.
KK. Method 12 of Appendix A-5 of Part 60
Method 12 would be revised to allow an analysis by inductively
coupled plasma-atomic emission spectrometry (ICP-AES) or cold vapor
atomic fluorescence spectrometry (CVAFS) as alternatives to atomic
absorption (AA) analysis. The ICP-AES is currently an approved
technique for lead analysis in Method 29, and CVAFS offers comparable
sensitivity and precision to AA.
LL. Method 14A of Appendix A-5 of Part 60
In Section 10.1.1 of Method 14A, we inadvertently referenced Figure
5-6.
[[Page 1135]]
This reference would be corrected to Figure 5-5.
MM. Method 16A of Appendix A-6 of Part 60
In Method 16A, the applicability section would note that method
results may be biased low if used at sources other than kraft pulp
mills where stack oxygen levels may be lower.
NN. Method 18 of Appendix A-6 of Part 60
In Method 18, sampling bags made of materials other than Tedlar
would be allowed if the materials are applicable for retaining the
compounds of interest. Tedlar bags are no longer produced.
OO. Method 23 of Appendix A-7 of Part 60
In Method 23, the requirement in Section 2.2.7 that silica gel be
stored in metal containers is unnecessary and would be deleted. Section
4.2.7 would be clarified to note that the used silica gel should be
transferred to its original container or other suitable vessel if
moisture is being determined. If moisture is not being determined, the
spent silica gel may be discarded. Mercury-free thermometers would be
added as an alternative to using mercury-in-glass thermometers to
facilitate the use of mercury-free products.
PP. Method 24 of Appendix A-7 of Part 60
Method 24 would be revised to cite only ASTM Method D2369 and not
the specific sections of the method, since the section numbers may
change with periodic updates.
QQ. Method 25 of Appendix A-7 of Part 60
In Method 25, more detailed information would be added to describe
the filters used for sample collection.
RR. Method 25C of Appendix A-7 of Part 60
Method 25C would be revised to allow sampling lines made of Teflon.
Probes that have closed points and are driven below surface in a single
step and withdrawn at a distance to create a gas gap would be allowed
as acceptable substitutes to using pilot probes and the auger
procedure. An equation for correcting the sample nitrogen concentration
for tank dilution would be added as a supplemental calculation option.
SS. Method 25D of Appendix A-7 of Part 60
In Method 25D, errors in cross-references within the method would
be corrected.
TT. Method 26 of Appendix A-8 of Part 60
Method 26 would be revised to allow the use of heated Teflon probes
in place of glass-lined probes. Conflicting temperature requirements
for the sampling system would be clarified. The note to keep the probe
and filter temperature at least 20 [deg]C above the source temperature
would be removed because the specification is not needed at higher
temperature stacks. The location of the thermocouple that monitors the
collected gas temperature would be clarified as being in the gas
stream, not the filter box. Method 26A would be an acceptable
alternative to Method 26 since the methods are fundamentally similar
and give comparable results when determining non-particulate hydrogen
halides.
UU. Method 29 of Appendix A-8 of Part 60
Method 29 would be revised to allow samples to be analyzed by CVAFS
as an alternative to AA analysis since CVAFS is as sensitive and
precise as AA.
VV. Method 30B of Appendix A-8 of Part 60
In Method 30B, calibrating a barometer against a NIST-traceable
barometer would be added as an alternative to calibrating against a
mercury barometer to facilitate the use of mercury-free products.
Table 9-1 and the method text would be revised to amend the quality
assurance/quality control criteria for sorbent trap section 2
breakthrough and sample analysis. These revisions would address
compliance testing and relative accuracy testing of mercury monitoring
systems currently being conducted at much lower emission
concentrations.
For compliance/emissions testing, the specification in Table 9-1
for sample analysis would be revised to require analytical results be
within the valid calibration range down to a concentration of 0.01
[micro]g/dscm. This will ensure that measurements at the low levels
being measured under recent rulemakings are of known, acceptable, and
consistent quality. For relative accuracy testing of mercury monitoring
systems, the sample analysis specification in Table 9-1 would remain
the same, but the breakthrough criteria for second section in the
sorbent traps would be revised to provide additional flexibility where
mercury concentrations are less than 0.5 [micro]g/dscm.
Finally, Method 30B would be revised to include the most up to date
citation for determining the method detection limit or MDL.
WW. Performance Specification 1 of Appendix B of Part 60
In Performance Specification 1, the terms ``full scale'' and
``span'' would be noted as having the same meaning.
XX. Performance Specification 3 of Appendix B of Part 60
In Performance Specification 3, a statement that allows the
relative accuracy to be within 20 percent of the reference method would
be added to establish the original intent of the rule. This statement
was inadvertently deleted in a previous amendment.
YY. Performance Specification 4 of Appendix B of Part 60
Performance Specification 4 would be revised to remove the required
use of the interference trap specified in Method 10 when evaluating
non-dispersive infrared continuous emission monitoring systems against
Method 10. This is an old requirement, and the trap is not needed with
modern analyzers.
ZZ. Performance Specification 4B of Appendix B of Part 60
Performance Specification 4B would be clarified to note that
Equation 1 in Section 7.1.1 for calculating calibration error only
applies to the carbon monoxide monitor and not the oxygen monitor. It
would be noted for the oxygen monitor that the calibration error should
be expressed as the oxygen concentration difference between the mean
monitor and reference value at three levels.
AAA. Performance Specification 7 of Appendix B of Part 60
Performance Specification 7 would be revised to allow Methods 15
and 16 as reference methods in addition to Method 11. Methods 15 and 16
are approved for determining hydrogen sulfide and are appropriate for
this application. Methods 15 and 16 are approved EPA reference methods
for a number of sources. A pertinent reference would also be added to
the references section.
BBB. Performance Specification 11 of Appendix B of Part 60
In Performance Specification 11, errors in the denominators of
Equations 11-1 and 11-2 would be corrected.
[[Page 1136]]
CCC. Performance Specification 15 of Appendix B of Part 60
In Performance Specification 15, the general references to 40 CFR
part 60, Appendix B for the relative accuracy analysis procedure would
specifically cite Performance Specification 2 of 40 CFR part 60,
Appendix B.
DDD. Performance Specification 16 of Appendix B of Part 60
Performance Specification 16 would be clarified to answer questions
that have arisen since its publication. Retesting a predictive emission
monitoring system (PEMS) after a sensor is replaced would be explained
more clearly. Allowances would be made for relative accuracy testing at
three load or production rate levels in cases where the key operating
parameter could not be readily altered. Additional instruction would be
added for performing the relative accuracy audit (RAA). An error in the
RAA acceptance criterion would be corrected, and an alternative
acceptance criterion for low concentration measurements would be added.
The yearly relative accuracy test audit would clearly note that the
statistical tests in Section 8.3 are not required. An incorrect
reference to Equation 16-4 in Section 12.4 would be corrected.
EEE. Procedure 1 of Appendix F of Part 60
In Procedure 1, the relevant performance specification would be
cited for the RAA calculation instead of using the current Equation 1-1
which is not appropriate for all pollutants.
FFF. Procedure 2 of Appendix F of Part 60
In Procedure 2, Equations 2-2 and 2-3 would be revised to have the
full-scale value in the denominator, which is more appropriate than the
up-scale check value. The denominator of equation 2-4 would be revised
to include the volume of the reference device rather than the full-
scale value. These revisions reflect the original intent of the rule.
GGG. Procedure 5 of Appendix F of Part 60
In Procedure 5, the second section listed as Section 6.2.6 would be
correctly numbered as Section 6.2.7.
HHH. General Provisions (Subpart A) Part 61
In the General Provisions of part 61, Methods 3A and 19 would be
added to the list of methods not requiring the use of audit samples in
Sec. 61.13(e). These methods were inadvertently omitted in the
original rule.
III. Beryllium (Subpart C) Part 61
In the beryllium National Emission Standards for Hazardous Air
Pollutants (NESHAP), Method 29 of part 60 would be added as an
alternative to Method 104 in Sec. 61.33(a) for emissions testing since
Method 29 is used to determine beryllium under other rules and is
appropriate for this subpart as well.
JJJ. Beryllium Rocket Motor Firing (Subpart D) Part 61
In the beryllium rocket motor firing NESHAP, a conversion error in
the emission standard in Sec. 61.42(a) would be corrected.
KKK. Mercury (Subpart E) Part 61
In the mercury NESHAP, Method 29 of part 60 would be added as an
alternative to Method 101A in Sec. 61.53(d)(2) for emissions testing
since Method 29 is used to determine mercury under other rules and is
appropriate for this subpart as well.
LLL. Inorganic Arsenic Emissions From Glass Manufacturing Plants
(Subpart N) Part 61
In the glass manufacturing plants NESHAP, Method 29 in Appendix A
of part 60 would be added as an alternative to Method 108 in Sec.
61.164(d)(2)(i) for determining the arsenic emissions rate and in Sec.
61.164(e)(1)(i) and (e)(2) for determining the arsenic concentration in
a gas stream. Method 29 is used to determine arsenic under other rules
and is appropriate for this subpart as well.
MMM. Method 101 of Appendix B of Part 61
Method 101 would be revised to allow analysis by ICP-AES or CVAFS
as alternatives to AA analysis. These techniques are allowed for
determining mercury in other approved methods and are appropriate for
Method 101 as well. They were not available when Method 101 was
promulgated.
NNN. Method 101A of Appendix B of Part 61
Method 101A would be revised to allow analysis by ICP-AES or CVAFS
as alternatives to AA analysis. These techniques are allowed for
determining mercury in other approved methods and are appropriate for
Method 101A as well. They were not available when Method 101A was
promulgated.
OOO. Method 102 of Appendix B of Part 61
In Method 102, mercury-free thermometers would be allowed in place
of mercury-in-glass thermometers to facilitate the use of mercury-free
products.
PPP. Method 104 of Appendix B of Part 61
Method 104 would be revised to allow analysis by ICP-AES as an
alternative to AA analysis. This new technique is acceptable for
measuring beryllium and was not available when Method 104 was
promulgated. A new alternative procedures section would be added to
address ICP-AES.
QQQ. Methods 108 and 108A of Appendix B of Part 61
Methods 108 and 108A would be revised to allow analysis by ICP-AES
as an alternative to AA analysis. This new technique is acceptable for
measuring arsenic and was not available when Methods 108 and 108A were
promulgated. A new alternative procedures section would be added to
address ICP-AES.
RRR. General Provisions (Subpart A) Part 63
In the General Provisions of part 63, Methods 3A and 19 would be
added to the list of methods not requiring the use of audit samples in
Sec. 63.7(c). These were inadvertent omissions of the original rule.
In Sec. 63.8(f)(6)(iii), an incorrect reference to a section of
Performance Specification 2 would be corrected.
SSS. Synthetic Organic Chemical Manufacturing Industry (Subpart G) Part
63
Subpart G would be revised to allow the use of Method 8260B in the
SW-846 Compendium of Methods or Method 316 to determine hazardous air
pollutant concentrations in wastewater streams in Sec.
63.144(b)(5)(i). Both methods are appropriate for this application but
were not considered during the original rule development.
TTT. Chromium Emissions From Hard and Decorative Chromium
Electroplating and Chromium Anodizing Tanks (Subpart N) Part 63
South Coast Air Quality Management District Method 205.1 would be
added as a testing option for measuring total chromium. Method 205.1 is
appropriate for this application, but its application to this rule was
not considered during the original rule development.
UUU. Ethylene Oxide Emissions Standards for Sterilization Facilities
(Subpart O) Part 63
The ethylene oxide emissions standards for sterilization facilities
NESHAP would be revised to allow
[[Page 1137]]
California Air Resources Board (CARB) Method 431 as an alternative to
the procedures in Sec. 63.365(b) for determining efficiency at the
sterilization chamber vent. Method 431 is appropriate for this
application but was not considered during the original rule
development. An error in a reference to a section in Performance
Specification 8 would also be corrected.
VVV. Marine Tank Vessel Loading Operations (Subpart Y) Part 63
The marine tank vessel loading operations NESHAP would be revised
to allow Method 25B as an alternative to Method 25A in Sec.
63.565(d)(5) for determining the average volatile organic compound
(VOC) concentration upstream and downstream of recovery devices. Method
25B would be allowed as an alternative to Methods 25 and 25A for
determining the percent reduction in VOC in Sec. 63.565(d)(8), and the
requirement that Method 25B be validated according to Method 301 in
Sec. 63.565(d)(10) would be added. Method 25B would also be added as
an alternative to Method 25A in determining the baseline outlet VOC
concentration in Sec. 63.565(g). Method 25B uses a different detector
than Method 25A but gives comparable results to Method 25A in these
applications.
WWW. Aerospace Manufacturing and Rework Facilities (Subpart GG) Part 63
The aerospace manufacturing and rework facilities NESHAP would be
revised to remove an incorrect reference to the location of Method 319
in Sec. 63.750(o).
XXX. Pharmaceuticals Production (Subpart GGG) Part 63
The pharmaceuticals production NESHAP would be revised to allow
Method 320 as an alternative to Method 18 for demonstrating that a vent
is not a process vent. Method 320 is a broadly applicable method that
is acceptable in this application because it is self-validating.
YYY. Secondary Aluminum Production (Subpart RRR) Part 63
The secondary aluminum production NESHAP would be revised to allow
Method 26 as an alternative to Method 26A in Sec. 63.1511(c)(9) for
determining hydrochloric acid (HCl) concentration. Method 26 is the
non-isokinetic version of Method 26A and is being allowed in all cases
where non-isokinetic sampling for HCl is performed.
ZZZ. Manufacturing of Nutritional Yeast (Subpart CCCC) Part 63
Table 2 in the manufacturing of nutritional yeast NESHAP would be
revised to delete the requirements to use Methods 1, 2, 3, and 4 when
measuring VOC by Method 25A. Methods 1, 2, 3, and 4 are required for
particulate matter sampling and the VOC in this application is normally
not particulate in nature.
AAAA. Petroleum Refineries: Catalytic Cracking Units, Catalytic
Reforming Units, and Sulfur Recovery Units (Subpart UUUU) Part 63
Table 4 in the petroleum refineries: catalytic cracking units,
catalytic reforming units, and sulfur recovery units NESHAP would be
revised to allow Method 320 as an alternative to Method 18 for
determining control device efficiency for organic compounds. Method 320
is a broadly applicable method that is acceptable in this application
because it is self-validating.
BBBB. Stationary Reciprocating Internal Combustion Engines (Subpart
ZZZZ) Part 63
Table 4 in the stationary reciprocating internal combustion engines
NESHAP would be revised to clarify that a heated probe is not necessary
when using ASTM D6522 to measure oxygen or carbon dioxide
concentrations because condensed moisture is normally not an
interferent to these compounds. The requirement to use Method 1 or 1A
for sampling site and sampling point location would be deleted because
the exhausts are small and have temporally varying emissions.
Instruction would be added to sample at the centroid of the stack.
CCCC. Method 306 of Appendix A of Part 63
Method 306 would be revised to remove references to two figures
that do not exist and to add clarifying information about the
conditions under which ICP is appropriate for sample analysis.
Alternative mercury-free thermometers also would be added as
alternatives to mercury-in-glass thermometers to facilitate the use of
mercury-free products.
DDDD. Method 306A of Appendix A of Part 63
In Method 306A, information would be added to clarify the
conditions under which sample filtering is required.
EEEE. Methods 308, 315, and 316 of Appendix A of Part 63
In Methods 308, 315, and 316, calibrating a temperature sensor
against a thermometer equivalent to a mercury-in-glass thermometer
would be added as an alternative to mercury-in-glass thermometers to
facilitate the use of non-mercury products. Alternative mercury-free
thermometers would be added as an alternative to using a mercury-in-
glass thermometers.
FFFF. Method 321 of Appendix A of Part 63
In Method 321, the term for dilution factor in the calculations
would be clarified.
IV. Request for Comments
The agency is reviewing the adequacy of its current test methods in
regard to sampling site selection and sampling point requirements.
Emission gas flow patterns affect representative testing, and this is
not addressed in many EPA test methods. Method 1 contains provisions
for sampling point locations, traversing, and determination of cyclonic
flow, and Method 7E was revised to contain procedures for determining
gaseous stratification in 2006. However, there are no requirements in
most methods to follow the Method 1 or 7E procedures.
Method 7E allows stratification to be assessed through either a 3-
or 12-point traverse while measuring variations in either a pollutant
or diluent concentration. The degree of stratification determines
whether a single-point, 3-, or 12-point traverse is used for the test.
There are no requirements to check for cyclonic flow in Method 7E.
We have information that suggests deficiencies exist in the 3-point
test in a number of cases and that at least a 5-point, dual axis test
should be required. A summary of this information has been included in
the regulatory docket. We are also reconsidering the appropriateness of
a diluent gas for the test instead of the regulated pollutant.
In this proposed rule, we would update the General Provisions of
Parts 60, 61, and 63 to include evaluations of gas stratification and
cyclonic flow with all compliance tests. The agency solicits your
comments and data to aid in establishing better procedures.
[[Page 1138]]
V. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory Planning and Review and Executive
Order 13563: Improving Regulation and Regulatory Review
This action is not a ``significant regulatory action'' under the
terms of Executive Order (EO) 12866 (58 FR 51735, October 4, 1993) and
is therefore not subject to review under Executive Orders 12866 and
13563 (76 FR 3821, January 21, 2011).
B. Paperwork Reduction Act
This action does not impose an information collection burden under
the provisions of the Paperwork Reduction Act, 44 U.S.C. 3501 et seq.
Burden is defined at 5 CFR 1320.3(b). The amendments being proposed in
this action to the test methods and testing regulations do not add
information collection requirements but make needed corrections and
updates to existing testing methodology.
C. Regulatory Flexibility Act
The Regulatory Flexibility Act (RFA) generally requires an agency
to prepare a regulatory flexibility analysis of any rule subject to
notice and comment rulemaking requirements under the Administrative
Procedure Act or any other statute unless the agency certifies that the
rule will not have a significant economic impact on a substantial
number of small entities. Small entities include small businesses,
small organizations, and small governmental jurisdictions.
For purposes of assessing the impacts of this rule on small
entities, small entity is defined as (1) A small business as defined by
the Small Business Administration's (SBA) regulations at 13 CFR
121.201; (2) a small governmental jurisdiction that is a government of
a city, county, town, school district or special district with a
population of less than 50,000; and (3) a small organization that is
any not-for-profit enterprise which is independently owned and operated
and is not dominant in its field.
After considering the economic impacts of this rule on small
entities, I certify that this action will not have a significant
economic impact on a substantial number of small entities. This
proposed rule will neither impose emission measurement requirements
beyond those specified in the current regulations, nor will it change
any emission standard. This proposed action will not impose any new
requirements on small entities. We continue to be interested in the
potential impacts of the proposed rule on small entities and welcome
comments on issues related to such impacts.
D. Unfunded Mandates Reform Act
This action contains no Federal mandates under the provisions of
Title II of the Unfunded Mandates Reform Act of 1995 (UMRA), 2 U.S.C.
1531-1538 for State, local, or tribal governments or the private
sector. The action imposes no enforceable duty on any State, local or
tribal governments or the private sector. Therefore, this action is not
subject to the requirements of sections 202 or 205 of the UMRA. This
action is also not subject to the requirements of section 203 of UMRA
because it contains no regulatory requirements that might significantly
or uniquely affect small governments. This action corrects and updates
current testing regulations and does not add any new requirements.
E. Executive Order 13132: Federalism
This action does not have federalism implications. It will not have
substantial direct effects on the States, on the relationship between
the national government and the States, or on the distribution of power
and responsibilities among the various levels of government, as
specified in Executive Order 13132. This action simply corrects minor
errors and makes updates to current source testing methods to maintain
their original intent. Thus, Executive Order 13132 does not apply to
this action. In the spirit of Executive Order 13132, and consistent
with the EPA policy to promote communications between the EPA and State
and local governments, the EPA specifically solicits comment on this
proposed rule from State and local officials.
F. Executive Order 13175: Consultation and Coordination With Indian
Tribal Governments
This action does not have tribal implications, as specified in
Executive Order 13175 (65 FR 67249, November 9, 2000). This proposed
rule imposes no requirements on tribal governments. This action simply
corrects and updates current testing regulations. Thus, Executive Order
13175 does not apply to this action. The EPA specifically solicits
additional comment on this proposed action from tribal officials.
G. Executive Order 13045: Protection of Children From Environmental
Health and Safety Risks
The EPA interprets EO 13045 (62 FR 19885, April 23, 1997) as
applying only to those regulatory actions that concern health or safety
risks, such that the analysis required under section 5-501 of the EO
has the potential to influence the regulation. This action is not
subject to EO 13045 because it does not establish an environmental
standard intended to mitigate health or safety risks.
H. Executive Order 13211: Actions Concerning Regulations That
Significantly Affect Energy Supply, Distribution, or Use
This action is not subject to Executive Order 13211 (66 FR 28355
(May 22, 2001)), because it is not a significant regulatory action
under Executive Order 12866.
I. National Technology Transfer and Advancement Act
Section 12(d) of the National Technology Transfer and Advancement
Act of 1995 (``NTTAA''), Public Law 104-113 (15 U.S.C. 272 note)
directs the EPA to use voluntary consensus standards in its regulatory
activities unless to do so would be inconsistent with applicable law or
otherwise impractical. Voluntary consensus standards are technical
standards (e.g., materials specifications, test methods, sampling
procedures, and business practices) that are developed or adopted by
voluntary consensus standards bodies. NTTAA directs the EPA to provide
Congress, through OMB, explanations when the Agency decides not to use
available and applicable voluntary consensus standards.
This proposed rulemaking involves technical standards. The EPA
proposes to use ASTM D975-076, developed and adopted by the American
Society for Testing and Materials (ASTM). This standard may be obtained
from ASTM at 100 Barr Harbor Drive, P.O. Box C700, West Conshohocken,
PA 19428-2959. ASTM D975-076 has been determined to be at least as
stringent as currently required ASTM D396 for defining ``distillate
oil.'' ASTM D975-076 is required in some State permits for this purpose
and end users have asked that it be allowed as an alternative to D396
under 40 CFR 60.41c.
J. Executive Order 12898: Federal Actions To Address Environmental
Justice in Minority Populations and Low-Income Populations
Executive Order (EO) 12898 (59 FR 7629 (Feb. 16, 1994)) establishes
Federal executive policy on environmental justice. Its main provision
directs Federal agencies, to the greatest extent practicable and
permitted by law, to make environmental justice part of their mission
by identifying and addressing, as appropriate, disproportionately high
[[Page 1139]]
and adverse human health or environmental effects of their programs,
policies, and activities on minority populations and low-income
populations in the United States.
The EPA has determined that this proposed rule will not have
disproportionately high and adverse human health or environmental
effects on minority or low-income populations because it does not
affect the level of protection provided to human health or the
environment. This rule corrects and updates current testing regulations
and does not cause emission increases from regulated sources.
Revisions to Test Methods and Testing Regulations
List of Subjects in 40 CFR Parts 51, 60, 61, and 63
Environmental protection, Air pollution control, Test methods and
procedures, and Performance specifications.
Dated: November 29, 2011.
Lisa P. Jackson,
Administrator.
For the reasons stated in the preamble, the Environmental
Protection Agency proposes to amend title 40, chapter I of the Code of
Federal Regulations as follows:
PART 51--REQUIREMENTS FOR PREPARATION, ADOPTION, AND SUBMITTAL OF
IMPLEMENTATION PLANS
1. The authority citation for part 51 continues to read as follows:
Authority: 23 U.S.C. 101; 42 U.S.C. 7401-7671q.
2. Amend Appendix M by revising section 4a. to read as follows:
Appendix M to Part 51--Recommended Test Methods for State
Implementation Plans
* * * * *
4. * * *
a. The source owner, operator, or representative of the tested
facility shall obtain an audit sample, if commercially available,
from an AASP for each test method used for regulatory compliance
purposes. No audit samples are required for the following test
methods: Methods 3A and 3C of Appendix A-3 of Part 60, Methods 6C,
7E, 9, and 10 of Appendix A-4 of Part 60, Methods 18 and 19 of
Appendix A-6 of Part 60, Methods 20, 22, and 25A of Appendix A-7 of
Part 60, and Methods 303, 318, 320, and 321 of Appendix A of Part
63. If multiple sources at a single facility are tested during a
compliance test event, only one audit sample is required for each
method used during a compliance test. The compliance authority
responsible for the compliance test may waive the requirement to
include an audit sample if they believe that an audit sample is not
necessary. ``Commercially available'' means that two or more
independent AASPs have blind audit samples available for purchase.
If the source owner, operator, or representative cannot find an
audit sample for a specific method, the owner, operator, or
representative shall consult the EPA Web site at the following URL,
https://www.epa.gov/ttn/emc, to confirm whether there is a source
that can supply an audit sample for that method. If the EPA Web site
does not list an available audit sample at least 60 days prior to
the beginning of the compliance test, the source owner, operator, or
representative shall not be required to include an audit sample as
part of the quality assurance program for the compliance test. When
ordering an audit s