Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Final Exclusion, 72311-72325 [2011-30147]
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[FR Doc. 2011–30188 Filed 11–22–11; 8:45 am]
BILLING CODE 9110–04–P
ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Part 261
[EPA–R06–RCRA–2009–0312; SW FRL–
9490–9]
Hazardous Waste Management
System; Identification and Listing of
Hazardous Waste; Final Exclusion
Environmental Protection
Agency.
ACTION: Final rule.
AGENCY:
The Environmental Protection
Agency (EPA) is granting a petition
submitted by Eastman Chemical
Corporation—Texas Operations
(Eastman Chemical) to exclude from
hazardous waste control (or delist) a
certain solid waste. This final rule
responds to the petition submitted by
Eastman Chemical to delist three waste
streams generated from its rotary kiln
incinerator (RKI). These waste streams
are the rotary kiln incinerator (RKI)
bottom ash, RKI fly ash, and RKI
scrubber water blowdown. The RKI
bottom ash and the RKI fly ash are
derived from the management of several
F-, K-, and U-waste codes. These waste
codes are F001, F002, F003, F005, F039,
K009, K010, U001, U002, U031, U069,
U107, U112, U117, U140, U147, U161,
U213, and U359. The Scrubber water
blowdown produced by the RKI’s air
pollution control equipment is also
derived from the management of several
F-, K-, and U-waste codes as well as
certain characteristic hazardous wastes.
These waste codes are D001, D002,
D003, D007, D008, D018, D022, F001,
F002, F003, F005, F039, K009, K010,
U001, U002, U031, U069, U107, U112,
U117, U140, U147, U161, U213, and
U359. The RKI is authorized to manage
a list of additional F-, K-, U-, and Pcodes to cover off-site sources not
attributed to the above waste codes. If
these waste codes are not specifically
listed in the delisting exclusion, they
are not covered by the exclusion and
can not be managed as non-hazardous,
unless and until, the exclusion is
modified to include them.
After careful analysis and evaluation
of comments submitted by the public,
SUMMARY:
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72311
the EPA has concluded that the
petitioned wastes are not hazardous
waste when disposed of in Subtitle D
landfills or in the case of the scrubber
water blowdown, discharged in
conjunction with its TPDES discharge
permit. This exclusion applies to the
RKI bottom ash, RKI fly ash and RKI
scrubber water blowdown generated at
Eastman Chemical’s Longview, Texas
facility. Accordingly, this final rule
excludes the petitioned waste from the
requirements of hazardous waste
regulations under the Resource
Conservation and Recovery Act (RCRA)
when disposed of in Subtitle D landfills
or discharged in accordance with a
TPDES permit but imposes testing
conditions to ensure that the futuregenerated wastes remain qualified for
delisting.
DATES:
Effective Date: November 23,
2011.
The public docket for this
final rule is located at the U.S.
Environmental Protection Agency
Region 6, 1445 Ross Avenue, Dallas,
Texas 75202, and is available for
viewing in the EPA Freedom of
Information Act review room on the 7th
floor from 9 a.m. to 4 p.m., Monday
through Friday, excluding Federal
holidays. Call (214) 665–6444 for
appointments. The reference number for
this docket is ‘‘EPA–R06–RCRA–2009–
0312’’. The public may copy material
from any regulatory docket at no cost for
the first 100 pages and at a cost of $0.15
per page for additional copies.
FOR FURTHER INFORMATION CONTACT: For
general information, contact Ben
Banipal, at (214) 665–7324. For
technical information concerning this
notice, contact Michelle Peace, U.S.
Environmental Protection Agency, 1445
Ross Avenue, Dallas, Texas, (214) 665–
7430.
SUPPLEMENTARY INFORMATION: The
information in this section is organized
as follows:
ADDRESSES:
I. Overview Information
A. What action is EPA finalizing?
B. Why is EPA approving this delisting?
C. What are the limits of this exclusion?
D. How will Eastman Chemical manage the
waste if it is delisted?
E. When is the final delisting exclusion
effective?
F. How does this final rule affect states?
II. Background
A. What is a ‘‘delisting’’?
B. What regulations allow facilities to
delist a waste?
C. What information must the generator
supply?
III. EPA’s Evaluation of the Waste Data
A. What wastes did Eastman Chemical
petition EPA to delist?
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B. How much waste did Eastman Chemical
propose to delist?
C. How did Eastman Chemical sample and
analyze the waste data in this petition?
IV. Public Comments Received on the
Proposed Exclusion
A. Who submitted comments on the
proposed rule?
B. Comments and Responses
V. Statutory and Executive Order Reviews
I. Overview Information
A. What action is EPA finalizing?
The EPA is finalizing:
(1) The decision to grant Eastman’s
petition to have its RKI Fly ash, bottom
ash and scrubber blowdown water
excluded, or delisted, from the
definition of a hazardous waste, subject
to certain continued verification and
monitoring conditions; and
(2) to use the Delisting Risk
Assessment Software to evaluate the
potential impact of the petitioned waste
on human health and the environment.
The Agency used this model to predict
the concentration of hazardous
constituents released from the
petitioned waste, once it is disposed.
After evaluating the petition, EPA
proposed and issued a direct final rule,
on September 24, 2010 to exclude the
Eastman Chemical waste from the lists
of hazardous wastes under §§ 261.31
and 261.32. The direct final rule
received adverse comments and was
subsequently withdrawn on November
1, 2010. This decision is based on the
proposed rule issued on September 24,
2010. The comments received on this
rulemaking will be addressed as part of
this decision.
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B. Why is EPA approving this delisting?
Eastman’s petition requests a delisting
for the listed hazardous wastes
associated with three waste streams.
Eastman does not believe that the
petitioned wastes meet the criteria for
which EPA listed it. Eastman also
believes no additional constituents or
factors could cause the waste to be
hazardous. EPA’s review of this petition
included consideration of the original
listing criteria, and the additional
factors required by the Hazardous and
Solid Waste Amendments of 1984
(HSWA). See section 3001(f) of RCRA,
42 U.S.C. 6921(f), and 40 CFR
260.22(d)(1)–(4). In making the final
delisting determination, EPA evaluated
the petitioned waste against the listing
criteria and factors cited in
§§ 261.11(a)(2) and (a)(3). Based on this
review, the EPA agrees with the
petitioner that the waste is
nonhazardous with respect to the
original listing criteria. (If the EPA had
found, based on this review, that the
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waste remained hazardous based on the
factors for which the waste were
originally listed, EPA would have
proposed to deny the petition.) The EPA
evaluated the waste with respect to
other factors or criteria to assess
whether there is a reasonable basis to
believe that such additional factors
could cause the waste to be hazardous.
The EPA considered whether the waste
is acutely toxic, the concentration of the
constituents in the waste, their tendency
to migrate and to bioaccumulate, their
persistence in the environment once
released from the waste, plausible and
specific types of management of the
petitioned waste, the quantities of waste
generated, and waste variability. The
EPA believes that the petitioned waste
does not meet these criteria. EPA’s final
decision to delist waste from Eastman’s
facility is based on the information
submitted in support of this rule, i.e.,
descriptions of the Rotary Kiln
Incinerator, and analytical data from the
Longview facility.
C. What are the limits of this exclusion?
This exclusion applies to the waste
described in the petition only if the
requirements described in Table 1, 2,
and 3 of part 261, Appendix IX and the
conditions contained herein are
satisfied. The exclusion applies to 1,000
cubic yards per calendar year of RKI fly
ash; 750 cubic yards per calendar year
of RKI bottom ash; and 643,000 cubic
yards (500,000 million gallons) of RKI
scrubber water blowdown waste
resulting from the operations of the
rotary kiln incinerator at its facility.
D. How will Eastman Chemical manage
the waste if it is delisted?
Eastman will dispose of the fly ash
and bottom ash in an onsite Subtitle D
landfill. The scrubber water blowdown
will be managed in the waste water
treatment plant (WWTP). The sludge
from the WWTP was delisted in 2000,
and there are new waste codes being
managed as part of this petition. See
Appendix IX to Part 261, Table 1. All
management occurs on-site and will
remain the same after the delisting is
granted.
E. When is the final delisting exclusion
effective?
This rule is effective November 23,
2011. The Hazardous and Solid Waste
Amendments of 1984 amended Section
3010 of RCRA to allow rules to become
effective in less than six months when
the regulated community does not need
the six-month period to come into
compliance. That is the case here
because this rule reduces, rather than
increases, the existing requirements for
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persons generating hazardous wastes.
These reasons also provide a basis for
making this rule effective immediately,
upon publication, under the
Administrative Procedure Act, pursuant
to 5 U.S.C. 553(d).
F. How does this final rule affect states?
Because EPA is issuing this exclusion
under the Federal RCRA delisting
program, only states subject to Federal
RCRA delisting provisions would be
affected. This would exclude two
categories of States: States having a dual
system that includes Federal RCRA
requirements and their own
requirements, and States who have
received our authorization to make their
own delisting decisions.
Here are the details: We allow states
to impose their own non-RCRA
regulatory requirements that are more
stringent than EPA’s, under section
3009 of RCRA. These more stringent
requirements may include a provision
that prohibits a Federally issued
exclusion from taking effect in the State.
Because a dual system (that is, both
Federal (RCRA) and State (non-RCRA)
programs) may regulate a petitioner’s
waste, we urge petitioners to contact the
State regulatory authority to establish
the status of their wastes under the State
law.
EPA has also authorized some States
(for example, Louisiana, Georgia,
Illinois) to administer a delisting
program in place of the Federal
program, that is, to make State delisting
decisions. Therefore, this exclusion
does not apply in those authorized
States. If Eastman Chemical transports
the petitioned waste to or manages the
waste in any State with delisting
authorization, Eastman Chemical must
obtain delisting authorization from that
State before they can manage the waste
as nonhazardous in the State.
II. Background
A. What is a delisting petition?
A delisting petition is a request from
a generator to EPA or another agency
with jurisdiction to exclude from the list
of hazardous wastes, wastes the
generator does not consider hazardous
under RCRA.
B. What regulations allow facilities to
delist a waste?
Under 40 CFR 260.20 and 260.22,
facilities may petition the EPA to
remove their wastes from hazardous
waste control by excluding them from
the lists of hazardous wastes contained
in §§ 261.31 and 261.32. Specifically,
§ 260.20 allows any person to petition
the Administrator to modify or revoke
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any provision of Parts 260 through 266,
268 and 273 of Title 40 of the Code of
Federal Regulations. Section 260.22
provides generators the opportunity to
petition the Administrator to exclude a
waste on a ‘‘generator-specific’’ basis
from the hazardous waste lists.
C. What information must the generator
supply?
Petitioners must provide sufficient
information to EPA to allow the EPA to
determine that the waste to be excluded
does not meet any of the criteria under
which the waste was listed as a
hazardous waste. In addition, the
Administrator must determine, where
he/she has a reasonable basis to believe
that factors (including additional
constituents) other than those for which
the waste was listed could cause the
waste to be a hazardous waste, that such
factors do not warrant retaining the
waste as a hazardous waste.
III. EPA’s Evaluation of the Waste Data
A. What waste did Eastman Chemical
petition EPA to delist?
Eastman petitioned EPA on December
1, 2008, to exclude from the lists of
hazardous wastes contained in
§§ 261.24, 261.31, and 261.32, certain
wastes from its rotary kiln incineration
system. The three waste streams
included in the petition were: The RKI
fly ash, RKI bottom ash and RKI
scrubber water blowdown.
The waste streams are generated from
the Eastman facility located in
Longview, Texas. The RKI fly ash and
RKI bottom ash are listed under EPA
Hazardous Waste No. F001, F002, F003,
F005, F039, K009, K010, U001, U002,
U031, U069, U107, U112, U117, U140,
U147, U161, U213, and U359. The
Scrubber water blowdown produced by
the RKI’s air pollution control
equipment is also derived from the
management of several F-, K-, and Uwaste codes as well as certain
characteristic hazardous wastes. These
waste codes are D001, D002, D003,
D007, D008, D018, D022, F001, F002,
F003, F005, F039, K009, K010, U001,
U002, U031, U069, U107, U112, U117,
U140, U147, U161, U213, and U359.
Specifically, in its petition, Eastman
requested that EPA grant exclusions for
1,000 cubic yards per calendar year of
RKI fly ash; 750 cubic yards per
72313
calendar year of RKI bottom ash; and
643,000 cubic yards (500,000 million
gallons) of RKI scrubber water
blowdown waste resulting from the
operations of the rotary kiln incinerator
at its facility.
Eastman intends to dispose of the
delisted RKI bottom ash and RKI fly ash
at a on-site Subtitle D Landfill, and the
RKI scrubber water blowdown will be
treated in the Wastewater Treatment
Plant. Treatment of process wastes and
wastes from captured facilities generate
the RKI bottom ash, RKI fly ash, and RKI
scrubber water blowdown that is
classified as F001, F002, F003, F005,
F039, K009, K010, U001, U002, U031,
U069, U107, U112, U117, U140, U147,
U161, U213, and U359 listed hazardous
wastes pursuant to 40 CFR 261.31 and
261.32. The 40 CFR part 261 appendix
VII hazardous constituents which are
the basis for listing can be found in
Table 1 and Table 2.
TABLE 1—EPA WASTE CODES FOR RKI FLY AND BOTTOM ASHES AND THE BASIS FOR LISTING
Waste code
Basis for listing
F001 ..........
F002 ..........
Tetrachloroethylene, methylene chloride trichloroethylene, 1,1,1-trichloroethane, carbon tetrachloride, chlorinated fluorocarbons.
Tetrachloroethylene, methylene chloride, trichloroethylene, 1,1,1-trichloroethane, 1,1,2-trichloroethane, chlorobenzene, 1,1,2trichloro-1,2,2-trifluoroethane, ortho-dichlorobenzene, trichlorofluoromethane.
N.A., xylene, acetone, ethyl acetate, ethyl benzene, ethyl ether, methyl isobutyl ketone, n-butyl alcohol, cyclohexane, methanol.
Toluene, methyl ethyl ketone, carbon disulfide, isobutanol, pyridine, 2-ethoxyethanol, benzene, 2-nitropropane..
All constituents for which treatment standards are specified for multi-source leachate (wastewaters and nonwastewaters) under 40
CFR 268.43, Table CCW.
Chloroform, formaldehyde, methylene chloride, methyl chloride, paraldehyde, formic acid.
Chloroform, formaldehyde, methylene chloride, methyl chloride, paraldehyde, formic acid, chloroacetaldehyde.
Acetaldehyde.
Acetone.
Bis (2-ethyl hexyl) phthalate.
n-Butyl alcohol.
Dibutyl phthalate.
Di-ethyl phthalate.
Di-n-octyl phthalate.
Ethyl acetate.
Ethylene oxide.
Ethane, 1,1′-oxybis-(I).
Formaldehyde.
Isobutyl alcohol.
Maleic anhydride.
Methanol.
Methyl ethyl ketone.
Methyl isobutyl ketone.
Tetrahydrofuran.
Toluene.
1,1,1-Trichloroethane (methyl chloroform).
Xylene.
Ethylene glycol monoethyl ether.
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F003 ..........
F005 ..........
F039 ..........
K009
K010
U001
U002
U028
U031
U069
U088
U107
U112
U115
U117
U122
U140
U147
U154
U159
U161
U213
U220
U226
U239
U359
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TABLE 2—EPA WASTE CODES FOR RKI SCRUBBER WATER BLOWDOWN AND THE BASIS FOR LISTING
Waste code
F001 ..........
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Basis for listing
Tetrachloroethylene, methylene chloride trichloroethylene, 1,1,1-trichloroethane, carbon tetrachloride, chlorinated fluorocarbons.
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TABLE 2—EPA WASTE CODES FOR RKI SCRUBBER WATER BLOWDOWN AND THE BASIS FOR LISTING—Continued
Waste code
Basis for listing
F002 ..........
Tetrachloroethylene, methylene chloride, trichloroethylene, 1,1,1-trichloroethane, 1,1,2-trichloroethane, chlorobenzene, 1,1,2trichloro-1,2,2-trifluoroethane, ortho-dichlorobenzene, trichlorofluoromethane.
N.A., xylene, acetone, ethyl acetate, ethyl benzene, ethyl ether, methyl isobutyl ketone, n-butyl alcohol, cyclohexane, methanol.
Toluene, methyl ethyl ketone, carbon disulfide, isobutanol, pyridine, 2-ethoxyethanol, benzene, 2-nitropropane.
All constituents for which treatment standards are specified for multi-source leachate (wastewaters and nonwastewaters) under 40
CFR 268.43, Table CCW.
Chloroform, formaldehyde, methylene chloride, methyl chloride, paraldehyde, formic acid.
Chloroform, formaldehyde, methylene chloride, methyl chloride, paraldehyde, formic acid, chloroacetaldehyde.
Acetaldehyde.
Acetone.
Bis (2-ethyl hexyl) phthalate.
n-Butyl alcohol.
Dibutyl phthalate.
Di-ethyl phthalate.
Di-n-octyl phthalate.
Ethyl acetate.
Ethylene oxide.
Ethane, 1,1′-oxybis-(I).
Formaldehyde.
Isobutyl alcohol.
Maleic anhydride.
Methanol.
Methyl ethyl ketone.
Methyl isobutyl ketone.
Tetrahydrofuran.
Toluene.
1,1,1-Trichloroethane (methyl chloroform).
Xylene.
Ethylene glycol monoethyl ether.
Ignitability.
Corrosivity.
Reactivity.
Chromium.
Lead.
Benzene.
Chloroform.
F003 ..........
F005 ..........
F039 ..........
K009
K010
U001
U002
U028
U031
U069
U088
U107
U112
U115
U117
U122
U140
U147
U154
U159
U161
U213
U220
U226
U239
U359
D001
D002
D003
D007
D008
D018
D022
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B. How much waste did Eastman
Chemical propose to delist?
Specifically, in its petition, Eastman
requested that EPA grant exclusions for
1,000 cubic yards per calendar year of
RKI fly ash; 750 cubic yards per
calendar year of RKI bottom ash; and
643,000 cubic yards (500,000 million
gallons) of RKI scrubber water
blowdown waste resulting from the
operations of the rotary kiln incinerator
at its facility.
C. How did Eastman Chemical sample
and analyze the waste data in this
petition?
To support its petition, Eastman
submitted:
1. Analytical results of the toxicity
characteristic leaching procedure and
total constituent analysis for volatile
and semivolatile organics, pesticides,
herbicides, dioxins/furans, PCBs and
metals for eight samples for the RKI fly
ash and RKI bottom ash, and RKI
scrubber water blowdown;
2. Analytical results of the total
constituent analysis for volatile and
semivolatile organics, pesticides,
herbicides, dioxins/furans, PCBs and
metals for eight samples for the RKI
scrubber water blowdown;
3. Analytical results from multiple pH
leaching of metals and;
4. The comparison of the results to the
maximum allowable TCLP delisting
levels found in Tables 4, 5, and 6.
5. Description of the operations and
waste received of the RKI.
TABLE 4—ANALYTICAL RESULTS AND MAXIMUM ALLOWABLE DELISTING CONCENTRATIONS OF THE RKI BOTTOM ASH 1
Maximum total
(mg/kg)
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Constituent
Antimony ............................................................................................................................
Acetone ..............................................................................................................................
Arsenic ...............................................................................................................................
Acetaldehyde .....................................................................................................................
Acenaphthylene .................................................................................................................
Anthracene .........................................................................................................................
Acenaphthene ....................................................................................................................
Barium ................................................................................................................................
Benzene .............................................................................................................................
Bis(2-ethylhexyl)phthalate ..................................................................................................
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Maximum TCLP
(mg/l)
16
0.194
8.8
1.37
3.5
1.6
0.721
370
< 0.170
0.23
0.062
0.772
0.029
< 0.0100
0.014
<0.0100
0.014
0.7
0.0048
0.017
E:\FR\FM\23NOR1.SGM
23NOR1
Maximum
allowable TCLP
delisting level
(mg/L)
0.801
33.8
0.126
5.35
31.9
77.9
31.9
100
0.231
103.0
Federal Register / Vol. 76, No. 226 / Wednesday, November 23, 2011 / Rules and Regulations
72315
TABLE 4—ANALYTICAL RESULTS AND MAXIMUM ALLOWABLE DELISTING CONCENTRATIONS OF THE RKI BOTTOM ASH 1—
Continued
Maximum total
(mg/kg)
Constituent
Maximum TCLP
(mg/l)
Maximum
allowable TCLP
delisting level
(mg/L)
Benzo(a) anthracene .........................................................................................................
Benzo(a) pyrene ................................................................................................................
Benzo(b) flouranthene .......................................................................................................
Bromomethane ..................................................................................................................
n-Butyl alcohol ...................................................................................................................
Cadmium ............................................................................................................................
Chromium ..........................................................................................................................
Cobalt .................................................................................................................................
Copper ...............................................................................................................................
Chloroform .........................................................................................................................
Chrysene ............................................................................................................................
Chloromethane ..................................................................................................................
Cyanide ..............................................................................................................................
4,4-DDT .............................................................................................................................
Di-n-butyl phthalate ............................................................................................................
Dieldrin ...............................................................................................................................
Ethylbenzene .....................................................................................................................
Fluorene .............................................................................................................................
Formaldehyde ....................................................................................................................
Fluoranthrene .....................................................................................................................
Isobutanol ..........................................................................................................................
Lead ...................................................................................................................................
Mercury ..............................................................................................................................
Methyl Isobutyl ketone .......................................................................................................
2-Methylnaphathalene .......................................................................................................
Methylene Chloride ............................................................................................................
Naphthalene .......................................................................................................................
Nickel .................................................................................................................................
Phenanthrene ....................................................................................................................
Pyrene ................................................................................................................................
Selenium ............................................................................................................................
Silver ..................................................................................................................................
Tetrachlorodibenzo-p-dioxin ..............................................................................................
(TCDD) 2,3,7,8- .................................................................................................................
0.763
0.519
0.343
0.057
4.5
1.5
14
31
29
0.0024
0.545
0.034
0.195
0.0032
< 0.010
0.0013
0.0086
2.24
4.6
1.22
1.9
7.1
< 0.017
0.0035
0.501
0.072
< 0.022
44,000
6.48
2.67
15
0.027
< 0.0100
< 0.0100
< 0.0100
< 0.0100
< 0.0100
0.002
0.02
0.023
0.048
0.0047
< 0.0100
< 0.0100
0.125
< 0.0100
0.005
< 0.0100
0.00855
0.031
0.23
< 0.0100
1.88
0.016
< 0.0002
0.0048
0.012
0.131
< 0.0100
52
0.039
< 0.0100
0.074
< 0.0020
0.211
79.1
673
0.0526
174
0.274
5.0
0.643
73.8
0.241
211
18.2
9.25
0.0103
73.9
2.78
32.6
14.7
347
7.39
521
1.95
0.2
139
2.18
0.237
0.0983
54.1
14.7
13.4
1.0
5.0
0.31E–06
< 5.92E–08
Thallium .............................................................................................................................
Tin ......................................................................................................................................
Toluene ..............................................................................................................................
Vanadium ...........................................................................................................................
Xylenes ..............................................................................................................................
Zinc ....................................................................................................................................
3.7
3.9
0.015
7.1
0.049
550
0.017
< 0.0100
0.0066
0.11
0.0486
8.5
7.46 E–06
mg/kg total
0.110
22.5
45.4
10.4
28.7
600
1 These levels represent the highest concentration of each constituent found in any one sample. These levels do not necessarily represent the
specific levels found in one sample.
< # Denotes that the constituent was below the detection limit.
TABLE 5—ANALYTICAL RESULTS AND MAXIMUM ALLOWABLE DELISTING CONCENTRATIONS OF THE RKI FLY ASH 1
Maximum total
(mg/kg)
pmangrum on DSK3VPTVN1PROD with RULES
Constituent
Antimony ............................................................................................................................
Acetone ..............................................................................................................................
Arsenic ...............................................................................................................................
Acetaldehyde .....................................................................................................................
Barium ................................................................................................................................
Bis(2-ethylhexyl)phthalate ..................................................................................................
Cadmium ............................................................................................................................
Chromium ..........................................................................................................................
Cobalt .................................................................................................................................
Copper ...............................................................................................................................
Chloroform .........................................................................................................................
Chloromethane ..................................................................................................................
Cyanide ..............................................................................................................................
Delta BHC ..........................................................................................................................
1,2-Dichlorobenzene ..........................................................................................................
1,3-Dichlorobenzene ..........................................................................................................
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Maximum TCLP
(mg/l)
25
0.177
18
255
110
0.157
2.9
5.9
86
100
0.002
0.0285
0.17
0.0031
< 0.5
< 0.5
0.18
0.959
0.045
< 0.001
1.4
0.006
0.011
0.015
0.1
0.52
0.0044
0.0018
< 0.001
< 0.001
0.0027
0.0023
E:\FR\FM\23NOR1.SGM
23NOR1
Maximum
allowable TCLP
delisting level
(mg/L)
0.433
2070
0.418
0.6264
100
0.0522
0.362
5.0
0.852
97.1
0.319
24.1
0.0154
3
37
37
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Federal Register / Vol. 76, No. 226 / Wednesday, November 23, 2011 / Rules and Regulations
TABLE 5—ANALYTICAL RESULTS AND MAXIMUM ALLOWABLE DELISTING CONCENTRATIONS OF THE RKI FLY ASH 1—
Continued
Maximum
allowable TCLP
delisting level
(mg/L)
Maximum total
(mg/kg)
Constituent
Formaldehyde ....................................................................................................................
Lead ...................................................................................................................................
Methanol ............................................................................................................................
Methyl isobutanol ketone ...................................................................................................
Methylene Chloride ............................................................................................................
Nickel .................................................................................................................................
Nitrobenzene ......................................................................................................................
Selenium ............................................................................................................................
Silver ..................................................................................................................................
Thallium .............................................................................................................................
Tin ......................................................................................................................................
Toluene ..............................................................................................................................
Vanadium ...........................................................................................................................
Zinc ....................................................................................................................................
Tetrachlorodibenzo-p-dioxin ..............................................................................................
(TCDD) 2,3,7,8- .................................................................................................................
Maximum TCLP
(mg/l)
5.44
12
12.2
0.004
0.047
110,000
< 0.5
25
2.4
6.7
7.8
0.002
6.2
4200
0.272
0.021
< 0.001
0.0048
0.137
47
0.011
0.082
< 0.001
0.019
< 0.001
0.037
< 0.001
< 0.001
461
2.45
0.6743
184
0.315
53.8
1.15
1.0
5.0
0.146
22.5
60.1
14.36
11.3
..........................
2.8 E–06mg/kg
8.39 E–05
mg/kg total
1 These levels represent the highest concentration of each constituent found in any one sample. These levels do not necessarily represent the
specific levels found in one sample.
< # Denotes that the constituent was below the detection limit.
TABLE 6—ANALYTICAL RESULTS AND MAXIMUM ALLOWABLE DELISTING CONCENTRATIONS OF THE RKI SCRUBBER WATER
BLOWDOWN 1
Maximum TCLP
(mg/l)
Constituent
Antimony ..........................................................................................................................................................
Arsenic .............................................................................................................................................................
Barium ..............................................................................................................................................................
Bis (2-ethylhexyl)phthalate ..............................................................................................................................
Chromium ........................................................................................................................................................
Cobalt ...............................................................................................................................................................
Copper .............................................................................................................................................................
Chloroform .......................................................................................................................................................
Chloromethane ................................................................................................................................................
Cyanide ............................................................................................................................................................
Di-n-butylphthalate ...........................................................................................................................................
Lead .................................................................................................................................................................
Methanol ..........................................................................................................................................................
Nickel ...............................................................................................................................................................
Silver ................................................................................................................................................................
Thallium ...........................................................................................................................................................
Tin ....................................................................................................................................................................
Vanadium .........................................................................................................................................................
Zinc ..................................................................................................................................................................
0.041
0.013
0.61
0.009
0.019
0.012
0.052
0.001
0.0021
0.0048
0.001
0.019
0.42
0.50
0.002
0.011
0.022
0.006
16
Maximum
allowable TCLP
delisting level
(mg/l)
0.0568
0.112
11.6
0.0522
10.3
0.318
22.1
0.0163
1.48
0.752
25.6
2.57
70.6
5.74
1.71
0.0179
22.5
4.88
77.7
1 These levels represent the highest concentration of each constituent found in any one sample. These levels do not necessarily represent the
specific levels found in one sample.
< # Denotes that the constituent was below the detection limit.
IV. Public Comments Received on the
Proposed Exclusion
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A. Who submitted comments on the
proposed rule?
The EPA received public comments
on the September 24, 2010, proposed
rule from two interested parties, the
Environmental Technology Council
(ETC), and Heritage Environmental.
Heritage Environmental submitted
comments objecting to the absence of
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the full administrative record not
appearing electronically on the
regulations.gov site on October 28, 2010.
ETC submitted three rounds of
comments dated October 28, 2010,
February 7, 2011, and March 7, 2011.
The comments and responses are
addressed below. Some of the ETC
October 28, 2010 comments requested
documents that were not contained in
the electronic docket. The actual records
were sent to the commenter for
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verification purposes and no further
comment is warranted.
B. What comments were submitted on
the Eastman Delisting Petition?
Comment 1. The administrative
record does not contain the company’s
waste sampling plan, waste analysis
plan or analytical test results. The
commenter cannot determine such basic
information as the number and
representative nature of the waste
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samples. The Federal Register notice
ambiguously states that Eastman
submitted analytical results ‘‘for eight
samples for the RKI fly ash and RKI
bottom ash, and RKI scrubber water
blowdown.’’ 75 FR at 58319.
Response 1. The electronic docket for
this rule only contained the proposed
rule and associated materials. The
administrative record for this rule
contains the petition including the
sampling and analysis plan and results.
Requests for items not found online in
the electronic docket can be requested
from the Regional office as described in
the notice. These documents were
provided to the commenter in an
electronic format on January 7, 2011,
after a request for information was
made.
Comment 2. A commenter cannot
determine from this general description
whether the petition is supported by a
total of only eight sample results, or
whether EPA Region 6 meant eight
samples for each type of waste material,
or how many samples of each type of
waste were collected. In other words,
commenters cannot even determine
whether the minimum number of four
samples of each type of waste was
collected as provided in EPA’s Delisting
Guidance. There is no information on
how the samples were collected, what
wastes were incinerated prior to
sampling, whether the samples were
representative of wastes processed in
the unit, and why EPA Region 6
believes the analytical results submitted
with the petition adequately support the
delisting. In addition, commenters
cannot ascertain basic information on
the analytical testing that was
conducted, such as detection limits and
the quality assurance/quality control
procedures followed by the testing
laboratory. We cannot even determine
whether the analysis was conducted by
Eastman or a certified third-party
laboratory. The commenter cannot
effectively comment on the delisting
without this necessary information and
an adequate explanation by EPA of the
basis for this administrative action.
Response 2. The administrative record
for this petition does include the
information the commenter wanted to
verify. Those documents were not
included in the electronic docket
because electronic copies were not
available at the time of proposal.
Requests for items not found online in
the electronic docket could have been
requested from the Regional office as
described in the notice.
Comment 3. Surprisingly, the record
also does not contain the DRAS
modeling results or any report on the
model inputs, analysis, or conclusions,
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other than the summaries for
constituents in the Federal Register
tables. Most of the description of the
DRAS analysis in the Federal Register
notice is boilerplate that EPA includes
in every delisting notice, and very little
information or analysis is presented
regarding the subject wastes.
Response 3. The DRAS results are not
available electronically for this docket.
The administrative record for the rule
contains hard copies of each DRAS run
and the results. Requests for items not
found online in the electronic docket
can be requested from the Regional
office as described in the notice.
Comment 4. From the limited
information gleaned from the Federal
Register notices, the commenter must
also raise a number of substantive
concerns about the delisting petition. It
appears that only total and TCLP
analyses were conducted on the subject
wastes. As EPA is aware, the TCLP was
intended to simulate the highly acidic
conditions in an active municipal
landfill with decomposing organic
wastes, and yet it appears that the
subject wastes would be disposed in an
on-site industrial landfill. No
information is provided on the pH
conditions of the industrial landfill. The
leachability of hazardous constituents
can be highly dependent on pH. If the
pH in the landfill receiving the waste is
not acidic, the leaching of the delisted
waste may not perform as predicted by
the TCLP. For this reason, EPA’s
Delisting Guidance provides for testing
of the waste under a range of pH
conditions. It does not appear that this
guidance was followed, and EPA has
provided no explanation for public
comment on why the subject waste was
not tested under multiple pH
conditions. In most of the delisting
actions by other EPA regions of which
the commenter is aware, multiple pH
testing was required and we cannot
determine, and therefore cannot
comment on, whether and why such
testing was not required for this
delisting petition.
Response 4. Multiple pH testing was
conducted on the materials, since the
multiple pH test is not a recognized test
method or test protocol, while
mentioned in guidance and performed
by most petitioners, EPA Region 6 has
never published the data gathered from
these results. In all delistings, only
TCLP and totals data are reported.
Requests for items not found online in
the electronic docket can be requested
from the Regional office as described in
the notice.
Comment 5. In addition, Eastman
apparently petitioned to exclude waste
streams that bear a limited subset of
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72317
RCRA Hazardous Waste Codes (5 Fcodes, 2 K-codes, and 12 U-codes). The
correct identification of these waste
codes is critical because EPA then used
the basis for listing these waste codes to
select a relatively short list of hazardous
constituents for analysis and delisting
levels. 75 FR at 58318. In our
experience, it seems highly improbable
that these are the only codes associated
with incinerator operations at a large,
complex chemical facility. Indeed, the
Federal Register notice does disclose
that the incinerator is RCRA-permitted
for ‘‘a variety of D-, F-, U-, K-, and Pcodes.’’ 75 FR at 58317. Apparently
many of these coded wastes were not
considered for purposes of the petition.
Given the nature of incinerator
operations, there is no explanation for
how ash and scrubber water covered by
the petition would not also contain
these additional waste codes. Indeed,
there is literally no information in the
administrative record for public
comment on why the limited set of
waste codes was selected for the
petition, and how EPA will assure that
only incinerator ash and scrubber water
bearing only the 19 selected codes will
be managed as delisted wastes.
Response 5. The Eastman Permit
limits the types of wastes that are
treated in its rotary kiln incinerator to
those addressed in the delisting
petition. The operating permit for the
rotary kiln incinerator restricts and
limits the acceptance of wastes which
carry only these 19 codes. Those 19
waste codes were considered the focus
of the delisting. Wastes with codes not
listed in the Delisting Petition are still
subject to hazardous waste regulation
and are not covered by the delisting
exclusion.
Comment 6. Moreover, the Federal
Register notice states that ‘‘there are
some production plants that are not
owned by Eastman but are located on
the facility,’’ and these unidentified
plants also send hazardous wastes to the
incinerator. 75 FR at 58317. There is no
information in the record that identifies
these facilities, including the nature of
their production activities, raw
materials used, and wastes generated.
Hazardous wastes are also accepted for
processing in the incinerator ‘‘from
other off-site Eastman facilities.’’ Id.
Again, no information is provided in the
administrative record that identifies
these facilities or describes their
processes, raw materials, or generated
wastes, other than the broad assertion in
the Federal Register that the wastes are
‘‘similar’’ to those generated by
Eastman. Id. Since the full and accurate
description of the hazardous wastes
processed in the incinerator is critical to
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Federal Register / Vol. 76, No. 226 / Wednesday, November 23, 2011 / Rules and Regulations
the proper selection of hazardous
constituents for testing and delisting
analysis, this bare-bones description
and lack of supporting data and
information in the administrative record
cannot sustain a delisting action.
Response 6. The Eastman RCRA
Permit allows the facility to accept
wastes from other Eastman facilities and
treat in the rotary kiln incinerator. The
Permit limits the types of wastes that are
treated in its rotary kiln incinerator to
those addressed in the delisting
petition. The operating permit for the
rotary kiln incinerator restricts and
limits the acceptance of wastes which
carry only these 19 codes. Those 19
waste codes were considered the focus
of the delisting. Wastes with codes not
listed in the Delisting Petition are still
subject to hazardous waste regulation
and are not covered by the delisting
exclusion.
Comment 7. The DRAS model was
apparently run for only 49 hazardous
constituents, a surprisingly small
number. Under RCRA section 3001(f),
EPA must consider not only the
constituents for which the subject
wastes were listed, but also additional
constituents that may cause the waste to
be hazardous. Under EPA’s Delisting
Guidance, the Agency usually requires
that a delisting petitioner submit
analytical results and undertake DRAS
modeling for literally hundreds more
hazardous constituents. Again, it
somewhat defies credulity that
incinerator ash and scrubber water from
a major, complex chemical plant would
contain such a small list of only 49
hazardous constituents. Lacking any
analytical data or other information in
the administrative record, however, ETC
cannot effectively comment on this
critical issue. In fact, ETC cannot
comment on the DRAS modeling in any
substantive respect because the record
contains inadequate information.
Response 7. The EPA provided the
administrative record and its supporting
documents to the commenter. No
additional comments were received
regarding the DRAS analysis of the
waste streams. Generally, in all
delistings, the DRAS model is run for
chemicals which are the basis for the
waste codes petitioned for in the
delisting and any additional waste
codes detected in the waste. For
Eastman specifically, there were 19
waste codes evaluated. These waste
codes represented more than 200
chemical constituents. In its analysis of
the data, EPA only found that 49 of the
chemical constituents were detected in
the analysis of the three Eastman waste
streams. These 49 waste codes were
evaluated in the DRAS model.
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Comment 8. We also must question
why this delisting is being considered
for incinerator ash and scrubber water
that would effectively override the
RCRA land disposal treatment standards
for the subject wastes. Eastman has not
petitioned to delist hazardous wastes
which do not meet the listing criteria as
generated. There is apparently no
dispute that the waste materials
processed in the incinerator are
hazardous wastes.
With respect to those wastes, EPA has
already made the determination based
on lengthy and thorough LDR
rulemakings that combustion or
comparable treatment to the specified
treatment levels is required to minimize
short-term and long-term threats to
human health and the environment. In
addition, EPA has already determined
that disposal of the treated wastes in a
RCRA-permitted landfill that meets
minimum technology requirements
(double synthetic liner, groundwater
monitoring, etc.) is necessary for
adequate public health and
environmental protection. EPA Region 6
has provided no justification in the
record for overriding these national
determinations, other than the
conclusory and unsupported assertion
in the Federal Register notice that the
delisting levels will be adequate for
such protections. Since the petitioner
already processes the hazardous wastes
in a RCRA-permitted incinerator and
disposes of the residuals in an on-site
RCRA-permitted landfill, we can see no
justification for the potential lessening
of public health and environmental
protection from the proposed delisting
action. The ETC is also concerned that
EPA Region 6’s approval of this
delisting would contravene Congress’s
land disposal restrictions and treatment
requirements in the RCRA statute.
Likewise, after careful review of the
administrative record for the Eastman
Chemical delisting petition, it is clear
that the incinerator ash and scrubber
water blowdown derived from the
incineration of numerous F-, K- and Ulisted hazardous wastes are not eligible
for delisting, and that such an action
would also violate the RCRA treatment
requirements and land disposal
prohibitions.
We begin with basic principles—all
seemingly ignored in the proposed
delistings. A waste is eligible for
delisting only if that waste as generated
at a particular facility does not meet any
of the criteria under which the waste
was listed as a hazardous waste. In
addition, the waste may not contain any
other Appendix VIII constituents that
would cause the waste to be hazardous.
RCRA § 3001(f) and 40 CFR 260.22.
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Likewise, the incinerator residues
from the Eastman facility are derived
from the incineration of numerous
waste streams that are F001, F002, F003,
F005, F039, K009, K010, U001, U002,
U031, U069, U107, U112, U117, U140,
U147, U161, U213 and U359 hazardous
wastes. By operation of the derived-from
rule, the Eastman incinerator residues
are these same F-, K- and U-listed
hazardous wastes. The legal issue raised
by the Eastman Chemical delisting is
whether the original F-, K- and U-listed
hazardous wastes would meet the
applicable treatment requirements prior
to land disposal if the proposed
delisting of the incineration residuals
were granted.
However, EPA Region 6 has proposed
to delist the incinerator residues and
allow land disposal at constituent levels
that are significantly higher than the
required treatment standards. There is
no exception from the land disposal
prohibitions for inadequately treated
residues; in fact, allowing such an
exception would obviously eviscerate
the treatment requirements. The original
F-, K- and U-listed hazardous wastes
cannot be land disposed if the
incinerator ash does not meet the
applicable treatment standards, and a
delisting petition cannot be used to
evade this statutory requirement. For
this reason, the concentration levels in
the incineration residues would have to
be lower than applicable treatment
standards for a delisting to be possible.
The following are examples of F039
treatment levels compared to Eastman
delisting levels (all concentrations in
mg/l TCLP): Barium 21.0 vs. 100
delisted fly ash; Cadmium 0.11 vs. 0.362
delisted fly ash; Chromium 0.60 vs. 5.0
delisted bottom ash and fly ash; Lead
0.75 vs. 2.45 delisted fly ash; Nickel
11.0 vs. 54.1 delisted bottom ash; Silver
0.14 vs. 5.0 delisted fly ash and bottom
ash.
Response 8. The Delisting Program
and the LDR program serve different
purposes and because they serve
different purposes, different standards
of compliance apply. As the commenter
states ‘‘A waste is eligible for delisting
only if that waste as generated at a
particular facility does not meet any of
the criteria under which the waste was
listed as a hazardous waste. In addition,
the waste may not contain any other
Appendix VIII constituents that would
cause the waste to be hazardous. RCRA
§ 3001(f) and 40 CFR 260.22.’’
The derived-from rule states that any
solid waste generated from the
treatment, storage, or disposal of a listed
hazardous waste, including any sludge,
spill residue, ash, emission control dust,
or leachate, remains a hazardous waste
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Federal Register / Vol. 76, No. 226 / Wednesday, November 23, 2011 / Rules and Regulations
unless and until delisted.
(§ 261.3(c)(2)(i)).
EPA’s regulations establish two ways
of identifying solid wastes as hazardous
under RCRA. A waste may be
considered hazardous if it exhibits
certain hazardous properties
(‘‘characteristics’’) or if it is included on
a specific list of wastes EPA has
determined are hazardous (‘‘listing’’ a
waste as hazardous) because we found
them to pose substantial present or
potential hazards to human health or
the environment. EPA’s regulations in
the Code of Federal Regulations (40
CFR) define four hazardous waste
characteristic properties: ignitability,
corrosivity, reactivity, or toxicity (see 40
CFR 261.21–261.24).
In order to list wastes EPA conducts
a more specific assessment of a
particular waste or category of wastes.
The Agency will ‘‘list’’ them if they
meet criteria set out in 40 CFR 261.11.
As described in § 261.11, EPA may list
a waste as hazardous if the waste:
Exhibits any of the characteristics, i.e.,
ignitability, corrosivity, reactivity, or
toxicity (§ 261.11(a)(1)); is ‘‘acutely’’
hazardous (e.g., if it is fatal to humans
or animals at low doses, § 261.11(a)(2));
or it contains any of the toxic
constituents listed in 40 CFR part 261,
Appendix VIII and, after consideration
of various factors described in the
regulation, is capable of posing a
‘‘substantial present or potential hazard
to human health or the environment
when improperly treated, stored,
transported, or disposed of, or otherwise
managed’’ (§ 261.11(a)(3)).
EPA placed a substance on the list of
hazardous constituents in Appendix
VIII if scientific studies have shown the
substance has toxic effects on humans
or other life forms.
Generally, listing of wastes are not
driven by threshold limits except in the
case of the toxicity characteristic (TC)
determination. Several of the limits
cited by the commenter are the TC limit
for the constituents stated. If the waste
is characteristic, then it can’t be
delisted. The delisting limit is bound by
the TC limit.
In 1984, Congress created EPA’s Land
Disposal Restrictions (LDR) program.
The LDR program ensures that toxic
constituents present in hazardous waste
are properly treated before hazardous
waste is land disposed. Since then, the
LDR team has developed mandatory
technology-based treatment standards
that must be met before hazardous waste
is placed in a landfill. These standards
help minimize short and long-term
threats to human health and the
environment, which directly benefits
local communities where hazardous
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waste landfills are located. The LDR
Program does not determine if a waste
is hazardous. It regulates how hazardous
wastes are to be managed at the time of
disposal.
We do believe that the concentrations
specified as delisting levels do
minimize short term and long term
threats to human health and the
environment. Whereas, some LDR
treatment standards are based on the
best demonstrated technology, the
delisting exit levels are risk based
standards. We have not stated that
Eastman is not subject to the LDR
standards because the waste was not
delisted at the point of generation,
Eastman may submit a variance to the
treatment standards as described in
§ 268.42(b) or 268.44 in order to ensure
compliance with the LDR standards, but
the Delisting decision may still be made.
However, wastes destined for disposal
in Subtitle C landfills are subject to the
LDR limits. Therefore, wastes when
delisted must comply with all
applicable Subtitle D landfill
requirements.
Comment 9. The ETC also notes that
the DRAS software used by EPA for
these delistings was apparently a new
Version 3, and that the changes from
Version 2 may not previously have been
subject to public notice and opportunity
for comment. We are in the process of
determining all the changes
incorporated into Version 3 and the
effect of those changes on delisting
levels and the protection of human
health and the environment. The ETC
requests that EPA Region 6 clarify the
changes made in Version 3, the effect of
those changes on the pending delistings,
and the agency’s rationales for those
changes to allow for effective public
comment.
Response 9. As discussed in the
Eastman Direct Final Rule and Proposal,
the changes made between version 2 of
DRAS and Version 3 of DRAS are
described in 73 FR 28777. In July 2007,
U.S. EPA prepared an update of the
DRAS by releasing version 3.0. The
update addressed a number of issues
with version 2 and improved the fate
and transport modeling. To estimate the
downgradient concentrations of waste
leachate constituents released into
groundwater, the DRAS utilizes
conservative dilution attenuation factors
(DAFs) taken from Monte-Carlo
applications of U.S. EPA’s Composite
Model for Leachate Migration with
Transformation Products (CMTP). DRAS
3.0 includes all new DAFs from new
CMTP modeling runs. The new
modeling takes advantage of: Updated
saturated flow and transport modules; a
new surface impoundment module and
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database; model corrections for
unrealistic scenarios (like water tables
modeled above the ground surface); new
isotherms for metals; and a revised
recharge and infiltration database. As a
result, many of the DAFs used in
previous versions of DRAS have
changed. Further affecting the
groundwater calculation, the
relationships for determining scaling
factors used to scale the DAFs to
account for very small waste streams
have been updated to reflect the new
database information on landfills and
surface impoundments and were also
corrected for a metric conversion of
cubic meters to cubic yards. The new
scaling factors are generally higher than
those of previous versions of DRAS,
resulting in higher estimated dilution
and attenuation at lower waste volumes
for both landfills and surface
impoundments. The new metals DAFs,
based on MINTEQA2 isotherms, can
vary as a function of the landfill
leachate concentration. This means that
the effective DAF (including a scaling
factor adjustment, if necessary) for an
input concentration may differ
significantly with the effective DAF that
corresponds to the allowable leachate
concentration. DRAS 3.0 now displays
the DAFs in both the forward calculated
risk tables and the tables of maximum
allowable concentrations so that the
difference is evident to the user. The
isotherms that vary by leachate
concentration are represented in DRAS
by a look-up table with leachate
concentrations paired with DAFs. In the
event that an actual concentration input
to DRAS lies between two values in the
table, or an allowable receptor
concentration lies between two
calculated receptor concentrations from
the table, DRAS 3.0 will linearly and
proportionally extrapolate between the
two values to determine the
corresponding exposure or allowable
leachate concentration. EPA changed
the calculation for particle emissions
caused by vehicles driving over the
waste at the landfill to provide a more
realistic estimate. The estimate depends
upon the number of trips per day
landfill vehicles make back and forth
over the waste. In previous versions of
DRAS, this value was conservatively set
at a 100 trips per day, corresponding
with an extremely high annual waste
volume. In DRAS 3.0, a minimum
number of trips per day was
conservatively assumed from the
Subtitle D landfill survey (7.4 trips per
day at the 95th percentile of values
reported). The number of trips per day
specific to the actual waste volume is
then added to the minimum to reflect
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the impact of very large waste streams.
This will considerably reduce the
particle emission estimate for wastes
generated at all but the largest annual
volumes. EPA added a conversion from
English to metric tons to the calculation
of particle emissions from waste
unloading, resulting in a decrease of
roughly 10% over previous versions of
DRAS. We also made a unit-conversion
factor correction to part of the air
volatile pathway which will reduce the
impact to the receptor. An error in the
back-calculation for fish ingestion
pathway was corrected to reflect the
difference between freely dissolved and
total water column waste constituent
concentrations. For the estimation of
risk and hazard, we made a number of
updates to the forward and back
calculations. Previous versions of DRAS
assumed that only 12.5% of particles are
absorbed by the receptor’s respiratory
system. This is no longer necessary as
toxicity reference values for inhalation
currently recommended by U.S. EPA
relate risk or hazard directly to exposure
concentration. DRAS 3.0 does not
include the 12.5% reduction. This
change significantly increases estimated
risks due to particle inhalation and
lowers corresponding allowable
concentrations. DRAS Version 3.0.47
has a reformulated back calculation of
the allowable leachate concentrations
from exposure due to contaminants
volatilized during household water use
to match the forward calculation of risk.
In previous versions of DRAS, the
forward calculation summed the risks
from exposure to all three evaluated
household compartments (the shower,
the bathroom, and the whole house)
while the back calculation based the
maximum allowable level on the single
most conservative compartment. The
DRAS 3.0 maximum allowable leachate
concentrations are now based on the
combined impact of all three
compartments. The house exposure was
also expanded to a 900 minute (15 hour)
daily exposure to reflect non-working
residents who have an overall 16 hour
in-house exposure (the other 1 hour is
spent in the shower and bathroom). EPA
resolved the inconsistencies with the
way DRAS chooses limiting pathways
for specific waste constituents in DRAS
3.0. EPA checked all toxicity reference
values in DRAS and updated where
necessary. Approximately 180 changes
were made to the toxicity reference
values in DRAS based on data in IRIS,
PPRTV, HEAST, NCEA, CalEPA and
other sources. Some route-to-route
extrapolations of oral toxicity data to
inhalation exposure have been returned
to DRAS 3.0 if consistent with Agency
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policy. See U.S. EPA 2006 for full
accounting of this methodology. The
same reference also includes
discussions of toxicity reference choices
where the multiple values were
available or where the toxicity reference
values were specific to particular
species of constituents.
Comment 10. On January 18, 2011,
President Barack Obama signed
Executive Order 13563 to ‘‘improve
regulation and regulatory review’’ in his
Administration. In the section on public
participation in the regulatory process,
President Obama stated that ‘‘each
agency shall afford the public a
meaningful opportunity to comment
through the internet on any proposed
regulation, with a comment period that
should generally be at least 60 days.’’
Response 10. The Eastman Direct
Final Rule published in the Federal
Register on September 24, 2010, several
months before President Obama’s
Executive Order was issued. The EPA
Region 6 will abide by the order issued
on January 18, 2011 in future delisting
actions.
Comment 11. Obviously, our concern
is that these supporting materials may
have been generated subsequent to the
proposed delisting, and therefore could
not have been relied on by EPA in
developing the proposed rule. We
request that EPA Region 6 clarify
whether the DRAS output files included
in the administrative record were the
output files relied on for the proposed
rule, how this could be possible given
the dates of the output files, and
whether other output files existed prior
to proposal of the delisting that were not
included in the administrative record.
Response 11. The DRAS outputs for
the Eastman petition were generated
December 10, 2009 and January 6, 2010
both prior to the issuance of the direct
final rules.
Comment 12. An initial review of the
Eastman Chemical delisting petition
raises numerous questions. The petition
reveals that several dioxin/furan
congeners were present in the samples
of incinerator ash, with analytical
results for selected hexa-, hepta-, and
octa- dioxins and -furans in the fly and
bottom ashes listed in Tables 1–5 of the
Petition. However, only one delisting
value was provided in the tables for
octachlorodibenzofuran (OCDF) in the
bottom ash and fly ash at a level of
10,000,000 mg/kg. This value is equal to
1000 percent OCDF, which of course is
impossible. This approach to dioxins/
furans is totally inadequate for a
hazardous waste incinerator, where
products of incomplete combustion are
a concern that must be addressed.
Similarly, the delisting petition ignores
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PCBs, even though PCBs can form as
PICs in the combustion process.
In addition, the delisting levels for
numerous metals, volatiles, semivolatiles and pesticides listed in the
tables are very high, some on the order
of 1,000,000,000 mg/kg (e.g., tin and
xylenes for the bottom ash and
methanol for the fly ash). Again, these
levels are impossible, and indicate
serious errors that undermine the
technical veracity of the delisting
petition.
Response 12. The DRAS is a
mathematical model which calculates
the delisting level based on health based
numbers and a delisting attenuation
factor. The delisting attenuation factor is
not bound, so it can sometimes produce
impractical values for the delisting
level, because of a chemicals affinity not
to leach or degrade. Those values are
not proposed as exit values because the
technical review of the petition
highlighted the infeasibility of these
situations.
Comment 13. Some metals are present
in the incinerator ash at very close to
the delisting levels. For example,
antimony was present in the fly ash at
a level of 0.18 mg/l TCLP versus the
delisting level of 1.08 mg/l TCLP;
arsenic at a level of 0.045 versus 0.049;
and nickel at 47 versus 148. For this
reason, sampling and analysis to
demonstrate compliance with the
delisting levels should be fairly
stringent, yet we do not see any
information in the administrative record
on EPA’s sampling requirements.
Response 13. The sampling plan is
part of the administrative record and the
requirements for sampling frequency are
explained in the verification
requirements of the exclusion language.
A waste is eligible for delisting only if
that waste as generated at a particular
facility does not meet any of the criteria
under which the waste was listed as a
hazardous waste. In addition, the waste
may not contain any other Appendix
VIII constituents that would cause the
waste to be hazardous. RCRA § 3001(f)
and 40 CFR 260.22. Concentrations
below a delisting level are eligible for
the exclusion. We do monitor and
require sampling to ensure that the
concentrations of the waste to be
delisted are measured and below the
delisting level.
Comment 14. As a further concern,
most of the analysis for the Eastman
delisting petition was apparently
performed by a laboratory owned and
operated by Eastman. There is no
explanation for why in this case EPA
Region 6 did not require use of an
independent certified analytical
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laboratory, as must be done in most
other delisting cases.
Response 14. The petitioner must use
a certified analytical laboratory to
supply data for the delisting petition.
The laboratory used by Eastman is a
certified laboratory and the data
validation package was reviewed and
accepted.
Comment 15. The Eastman incinerator
should be considered a commercial
incineration facility because Huntsman
Chemical and Air Liquide ship
significant quantities of hazardous
waste to the Eastman incinerator. Yet
very little data is presented to describe
the Huntsman and Air Liquide waste
and no information is provided on
waste codes. Because of the wider range
and variability of waste streams
processed, the sampling and analytical
concerns described above are magnified
and require a reasonable response from
EPA.
Response 15. The wastes generated
from Huntsman Chemical and Air
Liquide are covered by the Texas
Eastman Operating Permit and are
acceptable waste streams for
incineration in the rotary kiln
incinerator. Both facilities are on-site at
Eastman Chemical and are processes
which were previously part of the
Eastman Chemical Process Train but for
business reasons were sold to the
aforementioned companies. There is no
additional variability of the waste
stream created because the wastes are
generated by processes owned by
Huntsman and Air Liquide are present
in the waste stream.
pmangrum on DSK3VPTVN1PROD with RULES
V. Statutory and Executive Order
Reviews
Under Executive Order 12866,
‘‘Regulatory Planning and Review’’ (58
FR 51735, October 4, 1993), this rule is
not of general applicability and
therefore is not a regulatory action
subject to review by the Office of
Management and Budget (OMB). This
rule does not impose an information
collection burden under the provisions
of the Paperwork Reduction Act of 1995
(44 U.S.C. 3501 et seq.) because it
applies to a particular facility only.
Because this rule is of particular
applicability relating to a particular
facility, it is not subject to the regulatory
flexibility provisions of the Regulatory
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Flexibility Act (5 U.S.C. 601 et seq.), or
to sections 202, 204, and 205 of the
Unfunded Mandates Reform Act of 1995
(UMRA) (Pub. L. 104–4). Because this
rule will affect only a particular facility,
it will not significantly or uniquely
affect small governments, as specified in
section 203 of UMRA. Because this rule
will affect only a particular facility, this
proposed rule does not have federalism
implications. It will not have substantial
direct effects on the States, on the
relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government, as specified in
Executive Order 13132, ‘‘Federalism,’’
(64 FR 43255, August 10, 1999). Thus,
Executive Order 13132 does not apply
to this rule. Similarly, because this rule
will affect only a particular facility, this
proposed rule does not have tribal
implications, as specified in Executive
Order 13175, ‘‘Consultation and
Coordination with Indian Tribal
Governments’’ (65 FR 67249, November
9, 2000). Thus, Executive Order 13175
does not apply to this rule. This rule
also is not subject to Executive Order
13045, ‘‘Protection of Children from
Environmental Health Risks and Safety
Risks’’ (62 FR 19885, April 23, 1997),
because it is not economically
significant as defined in Executive
Order 12866, and because the Agency
does not have reason to believe the
environmental health or safety risks
addressed by this action present a
disproportionate risk to children. The
basis for this belief is that the Agency
used the DRAS program, which
considers health and safety risks to
infants and children, to calculate the
maximum allowable concentrations for
this rule. This rule is not subject to
Executive Order 13211, ‘‘Actions
Concerning Regulations That
Significantly Affect Energy Supply,
Distribution, or Use’’ (66 FR 28355 (May
22, 2001)), because it is not a significant
regulatory action under Executive Order
12866. This rule does not involve
technical standards; thus, the
requirements of section 12(d) of the
National Technology Transfer and
Advancement Act of 1995 (15 U.S.C.
272 note) do not apply. As required by
section 3 of Executive Order 12988,
‘‘Civil Justice Reform,’’ (61 FR 4729,
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72321
February 7, 1996), in issuing this rule,
EPA has taken the necessary steps to
eliminate drafting errors and ambiguity,
minimize potential litigation, and
provide a clear legal standard for
affected conduct. The Congressional
Review Act, 5 U.S.C. 801 et seq., as
added by the Small Business Regulatory
Enforcement Fairness Act of 1996,
generally provides that before a rule
may take effect, the agency
promulgating the rule must submit a
rule report which includes a copy of the
rule to each House of the Congress and
to the Comptroller General of the United
States. Section 804 exempts from
section 801 the following types of rules
(1) Rules of particular applicability; (2)
rules relating to agency management or
personnel; and (3) rules of agency
organization, procedure, or practice that
do not substantially affect the rights or
obligations of non-agency parties, 5
U.S.C. 804(3). EPA is not required to
submit a rule report regarding this
action under section 801 because this is
a rule of particular applicability.
Lists of Subjects in 40 CFR Part 261
Environmental protection, Hazardous
waste, Recycling, Reporting and
recordkeeping requirements.
Authority: Sec. 3001(f) RCRA, 42 U.S.C.
6921(f).
Dated: November 9, 2011.
Carl E. Edlund,
Director, Multimedia Planning and Permitting
Division.
For the reasons set out in the
preamble, 40 CFR part 261 is amended
as follows:
PART 261—IDENTIFICATION AND
LISTING OF HAZARDOUS WASTE
1. The authority citation for part 261
continues to read as follows:
■
Authority: 42 U.S.C. 6905, 6912(a), 6921,
6922, and 6938.
PART 261—[AMENDED]
2. In Tables 1, 2 and 3 of Appendix
IX to Part 261 add the following waste
stream in alphabetical order by facility
to read as follows:
■
Appendix IX to Part 261—Waste
Excluded Under §§ 260.20 and 260.22
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TABLE 1—WASTE EXCLUDED FROM NON-SPECIFIC SOURCES
Facility
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*
Eastman Chemical
Company-Texas Operations.
VerDate Mar<15>2010
Address
Waste description
*
*
*
*
*
*
Longview, TX .............. RKI bottom ash (EPA Hazardous Waste Numbers F001, F002, F003, F005, F039, K009,
K010, U001, U002, U031, U069, U107, U112, U117, U140, U147, U161, U213, and U359.)
generated at a maximum rate of 1,000 cubic yards per calendar year after November 23,
2011 and disposed in Subtitle D Landfill.
RKI fly ash EPA Hazardous Waste Number F001, F002, F003, F005, F039, K009, K010,
U001, U002, U031, U069, U107, U112, U117, U140, U147, U161, U213, and U359 generated at a maximum rate of 750 cubic yards per calendar year after November 23, 2011
and disposed in Subtitle D Landfill.
RKI scrubber water blowdown (EPA Hazardous Waste Numbers D001, D002, D003, D007,
D008, D018, D022, F001, F002, F003, F005, F039, K009, K010, U001, U002, U031, U069,
U107, U112, U117, U140, U147, U161, U213, and U359 generated at a maximum rate of
643,000 cubic yards (500,000 million gallons) per calendar year after November 23, 2011
and treated and discharged from a Wastewater Treatment Plant.
For the exclusion to be valid, Eastman must implement a verification testing program for
each of the waste streams that meets the following Paragraphs:
(1) Delisting Levels: All concentrations for those constituents must not exceed the maximum
allowable concentrations in mg/l specified in this paragraph.
(A) RKI Bottom Ash. Leachable Concentrations (mg/l): Antimony—0.801; Acetone—33.8; Arsenic—0.126; Acetaldehyde—5.35; Acenaphthylene—31.9; Anthracene—77.9; Acenaphthene—31.9; Barium—100; Benzene—0.231; Bis(2-ethylhexyl)phthalate—103; Benzo(a)
anthracene—0.211;
Benzo(a)
pyrene—79.1;
Benzo(b)
flouranthene—673;
Bromomethane—0.0526; n-Butyl Alcohol—174; Cadmium—0.274; Chromium—5.0; Cobalt—0.643; Copper—73.8; Chloroform—0.241; Chrysene—211; chloromethane—18.2; Cyanide—9.25; 4,4- DDT—0.0103; Di-n-butyl phthalate- 73.9; Dieldrin—2.78; Ethylbenzene—
32.6; Fluorene—14.7; Formaldehyde—347; Fluoranthrene—7.39; Isobutanol—521; Lead—
1.95; Mercury—0.2; Methy Isobutyl ketone—139; 2-Methylnaphathalene—2.18; Methylene
Chloride—0.237; Naphthalene—0.0983; Nickel—54.1; Phenanthrene—14.7; Pyrene—13.4;
Selenium—1.0; Silver—5.0; Thallium—0.110; Tin—22.5; Toluene—45.4; Vanadium—10.4;
Xylene—28.7; Zinc—600.
Total Concentrations (mg/kg) Tetrachlorodibenzo-p-dioxin (TCDD) 2,3,7,8–7.46 E–06 mg/kg.
(B) RKI Fly Ash. Leachable Concentrations (mg/l): Antimony—0.111; Acetone—533; Arsenic—0.178; Barium—36.9; Bis(2-ethylhexyl)phthalate—6.15; Chromium—2.32; Copper—
26.5; Ehtylbenzene—11.1; Methylene Chloride—0.0809; Naphthalene—0.0355; Nickel—
13.8; Phenanthrene—2.72; Toluene—15.5; Trichloroethane—11900; Trichloroethylene—
0.0794; Vanadium—1.00; Zinc—202.
Total Concentrations (mg/kg) Tetrachlorodibenzo-p-dioxin (TCDD) 2,3,7,8-4.30 E–05 mg/kg.
(C) RKI Scrubber Water Blowdown. TCLP Concentrations (mg/l): Antimony—0.0568; Arsenic—0.112; Barium—11.6; Bis(2-ethylhexyl)phthalate—0.0522; Chromium—5.0; Cobalt—
0.318, Copper—22.1; Chloroform—0.0163, Chloromethane—1.48; Cyanide—0.752; Di-nbutylphthalate—25.6; Lead—2.57; Methanol—70.6; Nickel—5.74; Silver—1.71; Thallium—
0.0179; Tin—22.5; Vanadium—4.88; Zinc—77.7.
(2) Waste Holding and Handling:
(A) Waste classification as non-hazardous can not begin until compliance with the limits set
in paragraph (1) for RKI bottom ash, RKI fly ash, and RKI scrubber water blowdown has
occurred for four consecutive quarterly sampling events.
(B) If constituent levels in any annual sample and retest sample taken by Eastman exceed
any of the delisting levels set in paragraph (1) for the RKI bottom ash, RKI fly ash, and RKI
scrubber water blowdown, Eastman must do the following:
(i) Notify EPA in accordance with paragraph (6) and
(ii) Manage and dispose the RKI bottom ash, RKI fly ash, and RKI scrubber water blowdown
as hazardous waste generated under Subtitle C of RCRA.
(3) Testing Requirements:
Upon this exclusion becoming final, Eastman must perform analytical testing by sampling and
analyzing the RKI bottom ash, RKI fly ash, and RKI scrubber water blowdown as follows:
(A) Initial Verification Testing:
(i) Collect four representative composite samples of each of the RKI bottom ash, RKI fly ash,
and RKI scrubber water blowdown at quarterly intervals after EPA grants the final exclusion. The first round of composite samples of each waste stream may be taken at any time
after EPA grants the final approval. Sampling must be performed in accordance with the
sampling plan approved by EPA in support of the exclusion.
(ii) Analyze the samples for all constituents listed in paragraph (1). Any composite sample
taken that exceeds the delisting levels listed in paragraph (1) indicates that the RKI bottom
ash, RKI fly ash, and RKI scrubber water blowdown must continue to be disposed as hazardous waste in accordance with the applicable hazardous waste requirements until such
time that four consecutive quarterly samples indicate compliance with delisting levels listed
in paragraph (1).
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TABLE 1—WASTE EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
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Facility
Address
Waste description
(iii) Within sixty (60) days after taking its last quarterly sample, Eastman will report its analytical test data to EPA. If levels of constituents measured in the samples of the RKI bottom
ash, RKI fly ash, and RKI scrubber water blowdown do not exceed the levels set forth in
paragraph (1) of this exclusion for four consecutive quarters, Eastman can manage and
dispose the non-hazardous RKI bottom ash, RKI fly ash, and RKI scrubber water blowdown according to all applicable solid waste regulations.
(B) Annual Testing:
(i) If Eastman completes the quarterly testing specified in paragraph (3) above and no sample contains a constituent at a level which exceeds the limits set forth in paragraph (1),
Eastman must begin annual testing as follows: Eastman must test a representative composite sample of the RKI bottom ash, RKI fly ash, and RKI scrubber water blowdown for all
constituents listed in paragraph (1) at least once per calendar year. If any measured constituent concentration exceeds the delisting levels set forth in paragraph (1), Eastman must
collect an additional representative composite sample within 10 days of being made aware
of the exceedence and test it expeditiously for the constituent(s) which exceeded delisting
levels in the original annual sample.
(ii) The samples for the annual testing shall be a representative composite sample according
to appropriate methods. As applicable to the method-defined parameters of concern, analyses requiring the use of SW–846 methods incorporated by reference in 40 CFR 260.11
must be used without substitution. As applicable, the SW–846 methods might include
Methods 0010, 0011, 0020, 0023A, 0030, 0031, 0040, 0050, 0051, 0060, 0061, 1010A,
1020B,1110A, 1310B, 1311, 1312, 1320, 1330A, 9010C, 9012B, 9040C, 9045D, 9060A,
9070A (uses EPA Method 1664, Rev. A), 9071B, and 9095B. Methods must meet Performance Based Measurement System Criteria in which the Data Quality Objectives are to
demonstrate that samples of the Eastman RKI bottom ash, RKI fly ash, and RKI scrubber
water blowdown are representative for all constituents listed in paragraph (1).
(iii) The samples for the annual testing taken for the second and subsequent annual testing
events shall be taken within the same calendar month as the first annual sample taken.
(iv) The annual testing report shall include the total amount of delisted waste in cubic yards
disposed during the calendar year.
(4) Changes in Operating Conditions: If Eastman significantly changes the process described
in its petition or starts any processes that generate(s) the waste that may or could affect
the composition or type of waste generated (by illustration, but not limitation, changes in
equipment or operating conditions of the treatment process), it must notify EPA in writing
and it may no longer handle the wastes generated from the new process as non-hazardous until the wastes meet the delisting levels set in paragraph (1) and it has received
written approval to do so from EPA.
Eastman must submit a modification to the petition complete with full sampling and analysis
for circumstances where the waste volume changes and/or additional waste codes are
added to the waste stream.
(5) Data Submittals:
Eastman must submit the information described below. If Eastman fails to submit the required data within the specified time or maintain the required records on-site for the specified time, EPA, at its discretion, will consider this sufficient basis to reopen the exclusion as
described in paragraph(6). Eastman must:
(A) Submit the data obtained through paragraph 3 to the Chief, Corrective Action and Waste
Minimization Section, Multimedia Planning and Permitting Division, U.S. Environmental
Protection Agency Region 6, 1445 Ross Ave., Dallas, Texas 75202, within the time specified. All supporting data can be submitted on CD–ROM or comparable electronic media.
(B) Compile records of analytical data from paragraph (3), summarized, and maintained onsite for a minimum of five years.
(C) Furnish these records and data when either EPA or the State of Texas requests them for
inspection.
(D) Send along with all data a signed copy of the following certification statement, to attest to
the truth and accuracy of the data submitted:
‘‘Under civil and criminal penalty of law for the making or submission of false or fraudulent
statements or representations (pursuant to the applicable provisions of the Federal Code,
which include, but may not be limited to, 18 U.S.C. 1001 and 42 U.S.C. 6928), I certify that
the information contained in or accompanying this document is true, accurate and complete.
As to the (those) identified section(s) of this document for which I cannot personally verify its
(their) truth and accuracy, I certify as the company official having supervisory responsibility
for the persons who, acting under my direct instructions, made the verification that this information is true, accurate and complete.
If any of this information is determined by EPA in its sole discretion to be false, inaccurate or
incomplete, and upon conveyance of this fact to the company, I recognize and agree that
this exclusion of waste will be void as if it never had effect or to the extent directed by EPA
and that the company will be liable for any actions taken in contravention of the company’s
RCRA and CERCLA obligations premised upon the company’s reliance on the void exclusion.’’
(6) Reopener.
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Federal Register / Vol. 76, No. 226 / Wednesday, November 23, 2011 / Rules and Regulations
TABLE 1—WASTE EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
(A) If, anytime after disposal of the delisted waste Eastman possesses or is otherwise made
aware of any environmental data (including but not limited to leachate data or ground water
monitoring data) or any other data relevant to the delisted waste indicating that any constituent identified for the delisting verification testing is at level higher than the delisting
level allowed by the Division Director in granting the petition, then the facility must report
the data, in writing, to the Division Director within 10 days of first possessing or being
made aware of that data.
(B) If either the annual testing (and retest, if applicable) of the waste does not meet the
delisting requirements in paragraph 1, Eastman must report the data, in writing, to the Division Director within 10 days of first possessing or being made aware of that data.
(C) If Eastman fails to submit the information described in paragraphs (5), (6)(A) or (6)(B) or
if any other information is received from any source, the Division Director will make a preliminary determination as to whether the reported information requires EPA action to protect human health and/or the environment. Further action may include suspending, or revoking the exclusion, or other appropriate response necessary to protect human health and
the environment.
(D) If the Division Director determines that the reported information requires action by EPA,
the Division Director will notify the facility in writing of the actions the Division Director believes are necessary to protect human health and the environment. The notice shall include
a statement of the proposed action and a statement providing the facility with an opportunity to present information as to why the proposed EPA action is not necessary. The facility shall have 10 days from receipt of the Division Director’s notice to present such information.
(E) Following the receipt of information from the facility described in paragraph (6)(D) or (if no
information is presented under paragraph (6)(D)) the initial receipt of information described
in paragraphs (5), (6)(A) or (6)(B), the Division Director will issue a final written determination describing EPA actions that are necessary to protect human health and/or the environment. Any required action described in the Division Director’s determination shall become
effective immediately, unless the Division Director provides otherwise.
(7) Notification Requirements: Eastman must do the following before transporting the delisted
waste. Failure to provide this notification will result in a violation of the delisting petition and
a possible revocation of the decision.
(A) Provide a one-time written notification to any state Regulatory Agency to which or through
which it will transport the delisted waste described above for disposal, 60 days before beginning such activities.
(B) For onsite disposal a notice should be submitted to the State to notify the State that disposal of the delisted materials have begun.
(C) Update one-time written notification, if it ships the delisted waste into a different disposal
facility.
(D) Failure to provide this notification will result in a violation of the delisting variance and a
possible revocation of the decision.
*
*
*
*
*
*
*
TABLE 2—WASTE EXCLUDED FROM SPECIFIC SOURCES
Facility
pmangrum on DSK3VPTVN1PROD with RULES
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Eastman Chemical
Company—Texas
Operations.
*
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Address
Waste description
*
*
*
*
*
*
Longview, TX .............. RKI Bottom Ash. (EPA Hazardous Waste Number F001, F002, F003, F005, F039, K009,
K010, U001, U002, U031, U069, U107, U112, U117, U140, U147, U161, U213, and U359)
generated at a maximum rate of 1,000 cubic yards per calendar year after November 23,
2011 and disposed in Subtitle D Landfill.
RKI Fly Ash. (EPA Hazardous Waste Number F001, F002, F003, F005, F039, K009, K010,
U001, U002, U031, U069, U107, U112, U117, U140, U147, U161, U213, and U359) generated at a maximum rate of 2,000 cubic yards per calendar year after November 23, 2011
and disposed in Subtitle D Landfill.
RKI Scrubber Water Blowdown. (EPA Hazardous Numbers D001, D002, D003, D007, D008,
D018, D022, F001, F002, F003, F005, F039, K009, K010, U001, U002, U031, U069, U107,
U112, U117, U140, U147, U161, U213, and U359) generated at a maximum rate of
643,000 cubic yards (500,000 million gallons) per calendar year after November 23, 2011
and treated and discharged from a Wastewater Treatment Plant.
Eastman must implement the testing program in Table 1. Wastes Excluded from Non-Specific
Sources for the petition to be valid.
*
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TABLE 3—WASTE EXCLUDED FROM COMMERCIAL CHEMICAL PRODUCTS, OFF-SPECIFICATION SPECIES, CONTAINER
RESIDUES, AND SOIL RESIDUES THEREOF
Facility
*
Eastman Chemical
Company-Texas Operations.
*
Address
Waste description
*
*
*
*
*
*
Longview, TX .............. RKI Bottom Ash. (EPA Hazardous Waste Number F001, F002, F003, F005, F039, K009,
K010, U001, U002, U031, U069, U107, U112, U117, U140, U147, U161, U213, and U359)
generated at a maximum rate of 1,000 cubic yards per calendar year after November 23,
2011 and disposed in Subtitle D Landfill.
RKI Fly Ash. (EPA Hazardous Waste Number F001, F002, F003, F005, F039, K009, K010,
U001, U002, U031, U069, U107, U112, U117, U140, U147, U161, U213, and U359) generated at a maximum rate of 2,000 cubic yards per calendar year after November 23, 2011
and disposed in Subtitle D Landfill.
RKI Scrubber Water Blowdown. (EPA Hazardous Numbers D001, D002, D003, D007, D008,
D018, D022, F001, F002, F003, F005, F039, K009, K010, U001, U002, U031, U069, U107,
U112, U117, U140, U147, U161, U213, and U359) generated at a maximum rate of
643,000 cubic yards (500,000 million gallons) per calendar year after November 23, 2011
and treated and discharged from a Wastewater Treatment Plant.
Eastman must implement the testing program in Table 1. Wastes Excluded from Non-Specific
Wastes for the petition to be valid.
*
*
BILLING CODE 6560–50–P
DEPARTMENT OF HEALTH AND
HUMAN SERVICES
45 CFR Part 5b
RIN 0906–AA91
Privacy Act; Exempt Record System
Health Resources and Services
Administration (HRSA), HHS.
ACTION: Final rule.
AGENCY:
This final rule exempts the
system of records (09–15–0054, the
National Practitioner Data Bank for
Adverse Information on Physicians and
Other Health Care Practitioners, HHS/
HRSA/BHPr) for the National
Practitioner Data Bank (NPDB) from
certain provisions of the Privacy Act
(5 U.S.C. 552a). The exemption is
necessary due to the recent expansion of
the NPDB under section 1921 of the
Social Security Act to include the
investigative materials compiled for law
enforcement purposes reported to the
Healthcare Integrity and Protection Data
Bank (HIPDB). The system of records for
the HIPDB is exempt from certain
provisions of the Privacy Act (see 45
CFR 5b.11(b)(2)(ii)(F)). In order to
maintain the exemption for the HIPDB
investigative materials, which will now
also be available through the NPDB, it
is necessary to extend the same
exemption to the NPDB.
DATES: The effective date of this rule is
December 23, 2011.
FOR FURTHER INFORMATION CONTACT:
Cynthia Grubbs, Director, Division of
pmangrum on DSK3VPTVN1PROD with RULES
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Practitioner Data Banks, Bureau of
Health Professions, Health Resources
and Services Administration, Parklawn
Building, 5600 Fishers Lane, Room 8–
103, Rockville, MD 20857; telephone
number: (301) 443–2300.
SUPPLEMENTARY INFORMATION:
[FR Doc. 2011–30147 Filed 11–22–11; 8:45 am]
SUMMARY:
*
I. Background
The NPDB was established by Title IV
of Public Law 99–660, the Health Care
Quality Improvement Act of 1986, as
amended. The NPDB is primarily an
alert or flagging system intended to
facilitate a comprehensive review of
health care practitioners’ professional
credentials. On January 28, 2010, HRSA
published a final rule in the Federal
Register (75 FR 4656) designed to
implement section 1921 of the Social
Security Act (herein referred to as
section 1921). Section 1921 expands the
scope of the NPDB. Section 1921
requires each State to adopt a system of
reporting to the Secretary certain
adverse licensure actions taken against
health care practitioners and health care
entities by any authority of the State
responsible for the licensing of such
practitioners or entities. It also requires
each State to report any negative action
or finding that a State licensing
authority, a peer review organization, or
a private accreditation entity has
finalized against a health care
practitioner or entity. Practically
speaking, section 1921 resulted in,
among other consequences, the transfer
of the vast majority of information
contained in the HIPDB, a companion
data bank, to the NPDB.
The HIPDB was created by the Health
Insurance Portability and
Accountability Act (HIPAA) of 1996,
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Public Law (Pub. L. 104–191), which
required the Secretary, acting through
the Office of Inspector General (OIG)
and the United States Attorney General,
to establish a new health care fraud and
abuse control program, to combat health
care fraud and abuse. Together, the
HIPDB and NPDB serve to facilitate
review of health care practitioners’ and
entities’ backgrounds.
II. Summary of the Proposed Rule
In the February 17, 2011 Federal
Register (76 FR 9295), HRSA published
a proposed rule that would exempt the
NPDB system of records from subsection
(c)(3), (d)(1) through (d)(4), (e)(4)(G) and
(H), and (f) of the Privacy Act pursuant
to 5 U.S.C. 552a(k)(2). These exemptions
are necessary to deal with the expansion
of NPDB information after
implementation of section 1921 on
March 1, 2010. Groups that have access
to the section 1921 information in the
NPDB include all organizations eligible
to query the NPDB under the Health
Care Quality Improvement Act of 1986
(hospitals, other health care entities that
conduct peer review and provide health
care services, State medical or dental
boards, and other health care
practitioner State boards), other State
licensing authorities, agencies
administering Federal health care
programs (including private entities
administering such programs under
contract), State agencies administering
or supervising the administration of
State health care programs, State
Medicaid Fraud Control Units, certain
law enforcement agencies, utilization
and quality control peer review
organizations (referred to as QIOs), as
defined in Part B of title XI of the Social
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Agencies
[Federal Register Volume 76, Number 226 (Wednesday, November 23, 2011)]
[Rules and Regulations]
[Pages 72311-72325]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: 2011-30147]
=======================================================================
-----------------------------------------------------------------------
ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 261
[EPA-R06-RCRA-2009-0312; SW FRL-9490-9]
Hazardous Waste Management System; Identification and Listing of
Hazardous Waste; Final Exclusion
AGENCY: Environmental Protection Agency.
ACTION: Final rule.
-----------------------------------------------------------------------
SUMMARY: The Environmental Protection Agency (EPA) is granting a
petition submitted by Eastman Chemical Corporation--Texas Operations
(Eastman Chemical) to exclude from hazardous waste control (or delist)
a certain solid waste. This final rule responds to the petition
submitted by Eastman Chemical to delist three waste streams generated
from its rotary kiln incinerator (RKI). These waste streams are the
rotary kiln incinerator (RKI) bottom ash, RKI fly ash, and RKI scrubber
water blowdown. The RKI bottom ash and the RKI fly ash are derived from
the management of several F-, K-, and U-waste codes. These waste codes
are F001, F002, F003, F005, F039, K009, K010, U001, U002, U031, U069,
U107, U112, U117, U140, U147, U161, U213, and U359. The Scrubber water
blowdown produced by the RKI's air pollution control equipment is also
derived from the management of several F-, K-, and U-waste codes as
well as certain characteristic hazardous wastes. These waste codes are
D001, D002, D003, D007, D008, D018, D022, F001, F002, F003, F005, F039,
K009, K010, U001, U002, U031, U069, U107, U112, U117, U140, U147, U161,
U213, and U359. The RKI is authorized to manage a list of additional F-
, K-, U-, and P- codes to cover off-site sources not attributed to the
above waste codes. If these waste codes are not specifically listed in
the delisting exclusion, they are not covered by the exclusion and can
not be managed as non-hazardous, unless and until, the exclusion is
modified to include them.
After careful analysis and evaluation of comments submitted by the
public, the EPA has concluded that the petitioned wastes are not
hazardous waste when disposed of in Subtitle D landfills or in the case
of the scrubber water blowdown, discharged in conjunction with its
TPDES discharge permit. This exclusion applies to the RKI bottom ash,
RKI fly ash and RKI scrubber water blowdown generated at Eastman
Chemical's Longview, Texas facility. Accordingly, this final rule
excludes the petitioned waste from the requirements of hazardous waste
regulations under the Resource Conservation and Recovery Act (RCRA)
when disposed of in Subtitle D landfills or discharged in accordance
with a TPDES permit but imposes testing conditions to ensure that the
future-generated wastes remain qualified for delisting.
DATES: Effective Date: November 23, 2011.
ADDRESSES: The public docket for this final rule is located at the U.S.
Environmental Protection Agency Region 6, 1445 Ross Avenue, Dallas,
Texas 75202, and is available for viewing in the EPA Freedom of
Information Act review room on the 7th floor from 9 a.m. to 4 p.m.,
Monday through Friday, excluding Federal holidays. Call (214) 665-6444
for appointments. The reference number for this docket is ``EPA-R06-
RCRA-2009-0312''. The public may copy material from any regulatory
docket at no cost for the first 100 pages and at a cost of $0.15 per
page for additional copies.
FOR FURTHER INFORMATION CONTACT: For general information, contact Ben
Banipal, at (214) 665-7324. For technical information concerning this
notice, contact Michelle Peace, U.S. Environmental Protection Agency,
1445 Ross Avenue, Dallas, Texas, (214) 665-7430.
SUPPLEMENTARY INFORMATION: The information in this section is organized
as follows:
I. Overview Information
A. What action is EPA finalizing?
B. Why is EPA approving this delisting?
C. What are the limits of this exclusion?
D. How will Eastman Chemical manage the waste if it is delisted?
E. When is the final delisting exclusion effective?
F. How does this final rule affect states?
II. Background
A. What is a ``delisting''?
B. What regulations allow facilities to delist a waste?
C. What information must the generator supply?
III. EPA's Evaluation of the Waste Data
A. What wastes did Eastman Chemical petition EPA to delist?
[[Page 72312]]
B. How much waste did Eastman Chemical propose to delist?
C. How did Eastman Chemical sample and analyze the waste data in
this petition?
IV. Public Comments Received on the Proposed Exclusion
A. Who submitted comments on the proposed rule?
B. Comments and Responses
V. Statutory and Executive Order Reviews
I. Overview Information
A. What action is EPA finalizing?
The EPA is finalizing:
(1) The decision to grant Eastman's petition to have its RKI Fly
ash, bottom ash and scrubber blowdown water excluded, or delisted, from
the definition of a hazardous waste, subject to certain continued
verification and monitoring conditions; and
(2) to use the Delisting Risk Assessment Software to evaluate the
potential impact of the petitioned waste on human health and the
environment. The Agency used this model to predict the concentration of
hazardous constituents released from the petitioned waste, once it is
disposed.
After evaluating the petition, EPA proposed and issued a direct
final rule, on September 24, 2010 to exclude the Eastman Chemical waste
from the lists of hazardous wastes under Sec. Sec. 261.31 and 261.32.
The direct final rule received adverse comments and was subsequently
withdrawn on November 1, 2010. This decision is based on the proposed
rule issued on September 24, 2010. The comments received on this
rulemaking will be addressed as part of this decision.
B. Why is EPA approving this delisting?
Eastman's petition requests a delisting for the listed hazardous
wastes associated with three waste streams. Eastman does not believe
that the petitioned wastes meet the criteria for which EPA listed it.
Eastman also believes no additional constituents or factors could cause
the waste to be hazardous. EPA's review of this petition included
consideration of the original listing criteria, and the additional
factors required by the Hazardous and Solid Waste Amendments of 1984
(HSWA). See section 3001(f) of RCRA, 42 U.S.C. 6921(f), and 40 CFR
260.22(d)(1)-(4). In making the final delisting determination, EPA
evaluated the petitioned waste against the listing criteria and factors
cited in Sec. Sec. 261.11(a)(2) and (a)(3). Based on this review, the
EPA agrees with the petitioner that the waste is nonhazardous with
respect to the original listing criteria. (If the EPA had found, based
on this review, that the waste remained hazardous based on the factors
for which the waste were originally listed, EPA would have proposed to
deny the petition.) The EPA evaluated the waste with respect to other
factors or criteria to assess whether there is a reasonable basis to
believe that such additional factors could cause the waste to be
hazardous. The EPA considered whether the waste is acutely toxic, the
concentration of the constituents in the waste, their tendency to
migrate and to bioaccumulate, their persistence in the environment once
released from the waste, plausible and specific types of management of
the petitioned waste, the quantities of waste generated, and waste
variability. The EPA believes that the petitioned waste does not meet
these criteria. EPA's final decision to delist waste from Eastman's
facility is based on the information submitted in support of this rule,
i.e., descriptions of the Rotary Kiln Incinerator, and analytical data
from the Longview facility.
C. What are the limits of this exclusion?
This exclusion applies to the waste described in the petition only
if the requirements described in Table 1, 2, and 3 of part 261,
Appendix IX and the conditions contained herein are satisfied. The
exclusion applies to 1,000 cubic yards per calendar year of RKI fly
ash; 750 cubic yards per calendar year of RKI bottom ash; and 643,000
cubic yards (500,000 million gallons) of RKI scrubber water blowdown
waste resulting from the operations of the rotary kiln incinerator at
its facility.
D. How will Eastman Chemical manage the waste if it is delisted?
Eastman will dispose of the fly ash and bottom ash in an onsite
Subtitle D landfill. The scrubber water blowdown will be managed in the
waste water treatment plant (WWTP). The sludge from the WWTP was
delisted in 2000, and there are new waste codes being managed as part
of this petition. See Appendix IX to Part 261, Table 1. All management
occurs on-site and will remain the same after the delisting is granted.
E. When is the final delisting exclusion effective?
This rule is effective November 23, 2011. The Hazardous and Solid
Waste Amendments of 1984 amended Section 3010 of RCRA to allow rules to
become effective in less than six months when the regulated community
does not need the six-month period to come into compliance. That is the
case here because this rule reduces, rather than increases, the
existing requirements for persons generating hazardous wastes. These
reasons also provide a basis for making this rule effective
immediately, upon publication, under the Administrative Procedure Act,
pursuant to 5 U.S.C. 553(d).
F. How does this final rule affect states?
Because EPA is issuing this exclusion under the Federal RCRA
delisting program, only states subject to Federal RCRA delisting
provisions would be affected. This would exclude two categories of
States: States having a dual system that includes Federal RCRA
requirements and their own requirements, and States who have received
our authorization to make their own delisting decisions.
Here are the details: We allow states to impose their own non-RCRA
regulatory requirements that are more stringent than EPA's, under
section 3009 of RCRA. These more stringent requirements may include a
provision that prohibits a Federally issued exclusion from taking
effect in the State. Because a dual system (that is, both Federal
(RCRA) and State (non-RCRA) programs) may regulate a petitioner's
waste, we urge petitioners to contact the State regulatory authority to
establish the status of their wastes under the State law.
EPA has also authorized some States (for example, Louisiana,
Georgia, Illinois) to administer a delisting program in place of the
Federal program, that is, to make State delisting decisions. Therefore,
this exclusion does not apply in those authorized States. If Eastman
Chemical transports the petitioned waste to or manages the waste in any
State with delisting authorization, Eastman Chemical must obtain
delisting authorization from that State before they can manage the
waste as nonhazardous in the State.
II. Background
A. What is a delisting petition?
A delisting petition is a request from a generator to EPA or
another agency with jurisdiction to exclude from the list of hazardous
wastes, wastes the generator does not consider hazardous under RCRA.
B. What regulations allow facilities to delist a waste?
Under 40 CFR 260.20 and 260.22, facilities may petition the EPA to
remove their wastes from hazardous waste control by excluding them from
the lists of hazardous wastes contained in Sec. Sec. 261.31 and
261.32. Specifically, Sec. 260.20 allows any person to petition the
Administrator to modify or revoke
[[Page 72313]]
any provision of Parts 260 through 266, 268 and 273 of Title 40 of the
Code of Federal Regulations. Section 260.22 provides generators the
opportunity to petition the Administrator to exclude a waste on a
``generator-specific'' basis from the hazardous waste lists.
C. What information must the generator supply?
Petitioners must provide sufficient information to EPA to allow the
EPA to determine that the waste to be excluded does not meet any of the
criteria under which the waste was listed as a hazardous waste. In
addition, the Administrator must determine, where he/she has a
reasonable basis to believe that factors (including additional
constituents) other than those for which the waste was listed could
cause the waste to be a hazardous waste, that such factors do not
warrant retaining the waste as a hazardous waste.
III. EPA's Evaluation of the Waste Data
A. What waste did Eastman Chemical petition EPA to delist?
Eastman petitioned EPA on December 1, 2008, to exclude from the
lists of hazardous wastes contained in Sec. Sec. 261.24, 261.31, and
261.32, certain wastes from its rotary kiln incineration system. The
three waste streams included in the petition were: The RKI fly ash, RKI
bottom ash and RKI scrubber water blowdown.
The waste streams are generated from the Eastman facility located
in Longview, Texas. The RKI fly ash and RKI bottom ash are listed under
EPA Hazardous Waste No. F001, F002, F003, F005, F039, K009, K010, U001,
U002, U031, U069, U107, U112, U117, U140, U147, U161, U213, and U359.
The Scrubber water blowdown produced by the RKI's air pollution control
equipment is also derived from the management of several F-, K-, and U-
waste codes as well as certain characteristic hazardous wastes. These
waste codes are D001, D002, D003, D007, D008, D018, D022, F001, F002,
F003, F005, F039, K009, K010, U001, U002, U031, U069, U107, U112, U117,
U140, U147, U161, U213, and U359. Specifically, in its petition,
Eastman requested that EPA grant exclusions for 1,000 cubic yards per
calendar year of RKI fly ash; 750 cubic yards per calendar year of RKI
bottom ash; and 643,000 cubic yards (500,000 million gallons) of RKI
scrubber water blowdown waste resulting from the operations of the
rotary kiln incinerator at its facility.
Eastman intends to dispose of the delisted RKI bottom ash and RKI
fly ash at a on-site Subtitle D Landfill, and the RKI scrubber water
blowdown will be treated in the Wastewater Treatment Plant. Treatment
of process wastes and wastes from captured facilities generate the RKI
bottom ash, RKI fly ash, and RKI scrubber water blowdown that is
classified as F001, F002, F003, F005, F039, K009, K010, U001, U002,
U031, U069, U107, U112, U117, U140, U147, U161, U213, and U359 listed
hazardous wastes pursuant to 40 CFR 261.31 and 261.32. The 40 CFR part
261 appendix VII hazardous constituents which are the basis for listing
can be found in Table 1 and Table 2.
Table 1--EPA Waste Codes for RKI Fly and Bottom Ashes and the Basis for
Listing
------------------------------------------------------------------------
Waste code Basis for listing
------------------------------------------------------------------------
F001......................... Tetrachloroethylene, methylene chloride
trichloroethylene, 1,1,1-
trichloroethane, carbon tetrachloride,
chlorinated fluorocarbons.
F002......................... Tetrachloroethylene, methylene chloride,
trichloroethylene, 1,1,1-
trichloroethane, 1,1,2-trichloroethane,
chlorobenzene, 1,1,2-trichloro-1,2,2-
trifluoroethane, ortho-dichlorobenzene,
trichlorofluoromethane.
F003......................... N.A., xylene, acetone, ethyl acetate,
ethyl benzene, ethyl ether, methyl
isobutyl ketone, n-butyl alcohol,
cyclohexane, methanol.
F005......................... Toluene, methyl ethyl ketone, carbon
disulfide, isobutanol, pyridine, 2-
ethoxyethanol, benzene, 2-nitropropane..
F039......................... All constituents for which treatment
standards are specified for multi-source
leachate (wastewaters and
nonwastewaters) under 40 CFR 268.43,
Table CCW.
K009......................... Chloroform, formaldehyde, methylene
chloride, methyl chloride, paraldehyde,
formic acid.
K010......................... Chloroform, formaldehyde, methylene
chloride, methyl chloride, paraldehyde,
formic acid, chloroacetaldehyde.
U001......................... Acetaldehyde.
U002......................... Acetone.
U028......................... Bis (2-ethyl hexyl) phthalate.
U031......................... n-Butyl alcohol.
U069......................... Dibutyl phthalate.
U088......................... Di-ethyl phthalate.
U107......................... Di-n-octyl phthalate.
U112......................... Ethyl acetate.
U115......................... Ethylene oxide.
U117......................... Ethane, 1,1'-oxybis-(I).
U122......................... Formaldehyde.
U140......................... Isobutyl alcohol.
U147......................... Maleic anhydride.
U154......................... Methanol.
U159......................... Methyl ethyl ketone.
U161......................... Methyl isobutyl ketone.
U213......................... Tetrahydrofuran.
U220......................... Toluene.
U226......................... 1,1,1-Trichloroethane (methyl
chloroform).
U239......................... Xylene.
U359......................... Ethylene glycol monoethyl ether.
------------------------------------------------------------------------
Table 2--EPA Waste Codes for RKI Scrubber Water Blowdown and the Basis
for Listing
------------------------------------------------------------------------
Waste code Basis for listing
------------------------------------------------------------------------
F001......................... Tetrachloroethylene, methylene chloride
trichloroethylene, 1,1,1-
trichloroethane, carbon tetrachloride,
chlorinated fluorocarbons.
[[Page 72314]]
F002......................... Tetrachloroethylene, methylene chloride,
trichloroethylene, 1,1,1-
trichloroethane, 1,1,2-trichloroethane,
chlorobenzene, 1,1,2-trichloro-1,2,2-
trifluoroethane, ortho-dichlorobenzene,
trichlorofluoromethane.
F003......................... N.A., xylene, acetone, ethyl acetate,
ethyl benzene, ethyl ether, methyl
isobutyl ketone, n-butyl alcohol,
cyclohexane, methanol.
F005......................... Toluene, methyl ethyl ketone, carbon
disulfide, isobutanol, pyridine, 2-
ethoxyethanol, benzene, 2-nitropropane.
F039......................... All constituents for which treatment
standards are specified for multi-source
leachate (wastewaters and
nonwastewaters) under 40 CFR 268.43,
Table CCW.
K009......................... Chloroform, formaldehyde, methylene
chloride, methyl chloride, paraldehyde,
formic acid.
K010......................... Chloroform, formaldehyde, methylene
chloride, methyl chloride, paraldehyde,
formic acid, chloroacetaldehyde.
U001......................... Acetaldehyde.
U002......................... Acetone.
U028......................... Bis (2-ethyl hexyl) phthalate.
U031......................... n-Butyl alcohol.
U069......................... Dibutyl phthalate.
U088......................... Di-ethyl phthalate.
U107......................... Di-n-octyl phthalate.
U112......................... Ethyl acetate.
U115......................... Ethylene oxide.
U117......................... Ethane, 1,1'-oxybis-(I).
U122......................... Formaldehyde.
U140......................... Isobutyl alcohol.
U147......................... Maleic anhydride.
U154......................... Methanol.
U159......................... Methyl ethyl ketone.
U161......................... Methyl isobutyl ketone.
U213......................... Tetrahydrofuran.
U220......................... Toluene.
U226......................... 1,1,1-Trichloroethane (methyl
chloroform).
U239......................... Xylene.
U359......................... Ethylene glycol monoethyl ether.
D001......................... Ignitability.
D002......................... Corrosivity.
D003......................... Reactivity.
D007......................... Chromium.
D008......................... Lead.
D018......................... Benzene.
D022......................... Chloroform.
------------------------------------------------------------------------
B. How much waste did Eastman Chemical propose to delist?
Specifically, in its petition, Eastman requested that EPA grant
exclusions for 1,000 cubic yards per calendar year of RKI fly ash; 750
cubic yards per calendar year of RKI bottom ash; and 643,000 cubic
yards (500,000 million gallons) of RKI scrubber water blowdown waste
resulting from the operations of the rotary kiln incinerator at its
facility.
C. How did Eastman Chemical sample and analyze the waste data in this
petition?
To support its petition, Eastman submitted:
1. Analytical results of the toxicity characteristic leaching
procedure and total constituent analysis for volatile and semivolatile
organics, pesticides, herbicides, dioxins/furans, PCBs and metals for
eight samples for the RKI fly ash and RKI bottom ash, and RKI scrubber
water blowdown;
2. Analytical results of the total constituent analysis for
volatile and semivolatile organics, pesticides, herbicides, dioxins/
furans, PCBs and metals for eight samples for the RKI scrubber water
blowdown;
3. Analytical results from multiple pH leaching of metals and;
4. The comparison of the results to the maximum allowable TCLP
delisting levels found in Tables 4, 5, and 6.
5. Description of the operations and waste received of the RKI.
Table 4--Analytical Results and Maximum Allowable Delisting Concentrations of the RKI Bottom Ash \1\
----------------------------------------------------------------------------------------------------------------
Maximum
Maximum total Maximum TCLP allowable TCLP
Constituent (mg/kg) (mg/l) delisting level
(mg/L)
----------------------------------------------------------------------------------------------------------------
Antimony................................................... 16 0.062 0.801
Acetone.................................................... 0.194 0.772 33.8
Arsenic.................................................... 8.8 0.029 0.126
Acetaldehyde............................................... 1.37 < 0.0100 5.35
Acenaphthylene............................................. 3.5 0.014 31.9
Anthracene................................................. 1.6 <0.0100 77.9
Acenaphthene............................................... 0.721 0.014 31.9
Barium..................................................... 370 0.7 100
Benzene.................................................... < 0.170 0.0048 0.231
Bis(2-ethylhexyl)phthalate................................. 0.23 0.017 103.0
[[Page 72315]]
Benzo(a) anthracene........................................ 0.763 < 0.0100 0.211
Benzo(a) pyrene............................................ 0.519 < 0.0100 79.1
Benzo(b) flouranthene...................................... 0.343 < 0.0100 673
Bromomethane............................................... 0.057 < 0.0100 0.0526
n-Butyl alcohol............................................ 4.5 < 0.0100 174
Cadmium.................................................... 1.5 0.002 0.274
Chromium................................................... 14 0.02 5.0
Cobalt..................................................... 31 0.023 0.643
Copper..................................................... 29 0.048 73.8
Chloroform................................................. 0.0024 0.0047 0.241
Chrysene................................................... 0.545 < 0.0100 211
Chloromethane.............................................. 0.034 < 0.0100 18.2
Cyanide.................................................... 0.195 0.125 9.25
4,4-DDT.................................................... 0.0032 < 0.0100 0.0103
Di-n-butyl phthalate....................................... < 0.010 0.005 73.9
Dieldrin................................................... 0.0013 < 0.0100 2.78
Ethylbenzene............................................... 0.0086 0.00855 32.6
Fluorene................................................... 2.24 0.031 14.7
Formaldehyde............................................... 4.6 0.23 347
Fluoranthrene.............................................. 1.22 < 0.0100 7.39
Isobutanol................................................. 1.9 1.88 521
Lead....................................................... 7.1 0.016 1.95
Mercury.................................................... < 0.017 < 0.0002 0.2
Methyl Isobutyl ketone..................................... 0.0035 0.0048 139
2-Methylnaphathalene....................................... 0.501 0.012 2.18
Methylene Chloride......................................... 0.072 0.131 0.237
Naphthalene................................................ < 0.022 < 0.0100 0.0983
Nickel..................................................... 44,000 52 54.1
Phenanthrene............................................... 6.48 0.039 14.7
Pyrene..................................................... 2.67 < 0.0100 13.4
Selenium................................................... 15 0.074 1.0
Silver..................................................... 0.027 < 0.0020 5.0
Tetrachlorodibenzo-p-dioxin................................ 0.31E-06 < 5.92E-08 7.46 E-06
(TCDD) 2,3,7,8-............................................ mg/kg total
Thallium................................................... 3.7 0.017 0.110
Tin........................................................ 3.9 < 0.0100 22.5
Toluene.................................................... 0.015 0.0066 45.4
Vanadium................................................... 7.1 0.11 10.4
Xylenes.................................................... 0.049 0.0486 28.7
Zinc....................................................... 550 8.5 600
----------------------------------------------------------------------------------------------------------------
\1\ These levels represent the highest concentration of each constituent found in any one sample. These levels
do not necessarily represent the specific levels found in one sample.
< Denotes that the constituent was below the detection limit.
Table 5--Analytical Results and Maximum Allowable Delisting Concentrations of the RKI Fly Ash \1\
----------------------------------------------------------------------------------------------------------------
Maximum
Maximum total Maximum TCLP allowable TCLP
Constituent (mg/kg) (mg/l) delisting level
(mg/L)
----------------------------------------------------------------------------------------------------------------
Antimony................................................... 25 0.18 0.433
Acetone.................................................... 0.177 0.959 2070
Arsenic.................................................... 18 0.045 0.418
Acetaldehyde............................................... 255 < 0.001 0.6264
Barium..................................................... 110 1.4 100
Bis(2-ethylhexyl)phthalate................................. 0.157 0.006 0.0522
Cadmium.................................................... 2.9 0.011 0.362
Chromium................................................... 5.9 0.015 5.0
Cobalt..................................................... 86 0.1 0.852
Copper..................................................... 100 0.52 97.1
Chloroform................................................. 0.002 0.0044 0.319
Chloromethane.............................................. 0.0285 0.0018 24.1
Cyanide.................................................... 0.17 < 0.001 0.0154
Delta BHC.................................................. 0.0031 < 0.001 3
1,2-Dichlorobenzene........................................ < 0.5 0.0027 37
1,3-Dichlorobenzene........................................ < 0.5 0.0023 37
[[Page 72316]]
Formaldehyde............................................... 5.44 0.272 461
Lead....................................................... 12 0.021 2.45
Methanol................................................... 12.2 < 0.001 0.6743
Methyl isobutanol ketone................................... 0.004 0.0048 184
Methylene Chloride......................................... 0.047 0.137 0.315
Nickel..................................................... 110,000 47 53.8
Nitrobenzene............................................... < 0.5 0.011 1.15
Selenium................................................... 25 0.082 1.0
Silver..................................................... 2.4 < 0.001 5.0
Thallium................................................... 6.7 0.019 0.146
Tin........................................................ 7.8 < 0.001 22.5
Toluene.................................................... 0.002 0.037 60.1
Vanadium................................................... 6.2 < 0.001 14.36
Zinc....................................................... 4200 < 0.001 11.3
Tetrachlorodibenzo-p-dioxin................................ ............... 2.8 E-06mg/kg 8.39 E-05
(TCDD) 2,3,7,8-............................................ mg/kg total
----------------------------------------------------------------------------------------------------------------
\1\ These levels represent the highest concentration of each constituent found in any one sample. These levels
do not necessarily represent the specific levels found in one sample.
< Denotes that the constituent was below the detection limit.
Table 6--Analytical Results and Maximum Allowable Delisting
Concentrations of the RKI Scrubber Water Blowdown \1\
------------------------------------------------------------------------
Maximum
Maximum TCLP allowable TCLP
Constituent (mg/l) delisting level
(mg/l)
------------------------------------------------------------------------
Antimony............................ 0.041 0.0568
Arsenic............................. 0.013 0.112
Barium.............................. 0.61 11.6
Bis (2-ethylhexyl)phthalate......... 0.009 0.0522
Chromium............................ 0.019 10.3
Cobalt.............................. 0.012 0.318
Copper.............................. 0.052 22.1
Chloroform.......................... 0.001 0.0163
Chloromethane....................... 0.0021 1.48
Cyanide............................. 0.0048 0.752
Di-n-butylphthalate................. 0.001 25.6
Lead................................ 0.019 2.57
Methanol............................ 0.42 70.6
Nickel.............................. 0.50 5.74
Silver.............................. 0.002 1.71
Thallium............................ 0.011 0.0179
Tin................................. 0.022 22.5
Vanadium............................ 0.006 4.88
Zinc................................ 16 77.7
------------------------------------------------------------------------
\1\ These levels represent the highest concentration of each constituent
found in any one sample. These levels do not necessarily represent the
specific levels found in one sample.
< Denotes that the constituent was below the detection limit.
IV. Public Comments Received on the Proposed Exclusion
A. Who submitted comments on the proposed rule?
The EPA received public comments on the September 24, 2010,
proposed rule from two interested parties, the Environmental Technology
Council (ETC), and Heritage Environmental. Heritage Environmental
submitted comments objecting to the absence of the full administrative
record not appearing electronically on the regulations.gov site on
October 28, 2010. ETC submitted three rounds of comments dated October
28, 2010, February 7, 2011, and March 7, 2011. The comments and
responses are addressed below. Some of the ETC October 28, 2010
comments requested documents that were not contained in the electronic
docket. The actual records were sent to the commenter for verification
purposes and no further comment is warranted.
B. What comments were submitted on the Eastman Delisting Petition?
Comment 1. The administrative record does not contain the company's
waste sampling plan, waste analysis plan or analytical test results.
The commenter cannot determine such basic information as the number and
representative nature of the waste
[[Page 72317]]
samples. The Federal Register notice ambiguously states that Eastman
submitted analytical results ``for eight samples for the RKI fly ash
and RKI bottom ash, and RKI scrubber water blowdown.'' 75 FR at 58319.
Response 1. The electronic docket for this rule only contained the
proposed rule and associated materials. The administrative record for
this rule contains the petition including the sampling and analysis
plan and results. Requests for items not found online in the electronic
docket can be requested from the Regional office as described in the
notice. These documents were provided to the commenter in an electronic
format on January 7, 2011, after a request for information was made.
Comment 2. A commenter cannot determine from this general
description whether the petition is supported by a total of only eight
sample results, or whether EPA Region 6 meant eight samples for each
type of waste material, or how many samples of each type of waste were
collected. In other words, commenters cannot even determine whether the
minimum number of four samples of each type of waste was collected as
provided in EPA's Delisting Guidance. There is no information on how
the samples were collected, what wastes were incinerated prior to
sampling, whether the samples were representative of wastes processed
in the unit, and why EPA Region 6 believes the analytical results
submitted with the petition adequately support the delisting. In
addition, commenters cannot ascertain basic information on the
analytical testing that was conducted, such as detection limits and the
quality assurance/quality control procedures followed by the testing
laboratory. We cannot even determine whether the analysis was conducted
by Eastman or a certified third-party laboratory. The commenter cannot
effectively comment on the delisting without this necessary information
and an adequate explanation by EPA of the basis for this administrative
action.
Response 2. The administrative record for this petition does
include the information the commenter wanted to verify. Those documents
were not included in the electronic docket because electronic copies
were not available at the time of proposal. Requests for items not
found online in the electronic docket could have been requested from
the Regional office as described in the notice.
Comment 3. Surprisingly, the record also does not contain the DRAS
modeling results or any report on the model inputs, analysis, or
conclusions, other than the summaries for constituents in the Federal
Register tables. Most of the description of the DRAS analysis in the
Federal Register notice is boilerplate that EPA includes in every
delisting notice, and very little information or analysis is presented
regarding the subject wastes.
Response 3. The DRAS results are not available electronically for
this docket. The administrative record for the rule contains hard
copies of each DRAS run and the results. Requests for items not found
online in the electronic docket can be requested from the Regional
office as described in the notice.
Comment 4. From the limited information gleaned from the Federal
Register notices, the commenter must also raise a number of substantive
concerns about the delisting petition. It appears that only total and
TCLP analyses were conducted on the subject wastes. As EPA is aware,
the TCLP was intended to simulate the highly acidic conditions in an
active municipal landfill with decomposing organic wastes, and yet it
appears that the subject wastes would be disposed in an on-site
industrial landfill. No information is provided on the pH conditions of
the industrial landfill. The leachability of hazardous constituents can
be highly dependent on pH. If the pH in the landfill receiving the
waste is not acidic, the leaching of the delisted waste may not perform
as predicted by the TCLP. For this reason, EPA's Delisting Guidance
provides for testing of the waste under a range of pH conditions. It
does not appear that this guidance was followed, and EPA has provided
no explanation for public comment on why the subject waste was not
tested under multiple pH conditions. In most of the delisting actions
by other EPA regions of which the commenter is aware, multiple pH
testing was required and we cannot determine, and therefore cannot
comment on, whether and why such testing was not required for this
delisting petition.
Response 4. Multiple pH testing was conducted on the materials,
since the multiple pH test is not a recognized test method or test
protocol, while mentioned in guidance and performed by most
petitioners, EPA Region 6 has never published the data gathered from
these results. In all delistings, only TCLP and totals data are
reported. Requests for items not found online in the electronic docket
can be requested from the Regional office as described in the notice.
Comment 5. In addition, Eastman apparently petitioned to exclude
waste streams that bear a limited subset of RCRA Hazardous Waste Codes
(5 F-codes, 2 K-codes, and 12 U-codes). The correct identification of
these waste codes is critical because EPA then used the basis for
listing these waste codes to select a relatively short list of
hazardous constituents for analysis and delisting levels. 75 FR at
58318. In our experience, it seems highly improbable that these are the
only codes associated with incinerator operations at a large, complex
chemical facility. Indeed, the Federal Register notice does disclose
that the incinerator is RCRA-permitted for ``a variety of D-, F-, U-,
K-, and P-codes.'' 75 FR at 58317. Apparently many of these coded
wastes were not considered for purposes of the petition. Given the
nature of incinerator operations, there is no explanation for how ash
and scrubber water covered by the petition would not also contain these
additional waste codes. Indeed, there is literally no information in
the administrative record for public comment on why the limited set of
waste codes was selected for the petition, and how EPA will assure that
only incinerator ash and scrubber water bearing only the 19 selected
codes will be managed as delisted wastes.
Response 5. The Eastman Permit limits the types of wastes that are
treated in its rotary kiln incinerator to those addressed in the
delisting petition. The operating permit for the rotary kiln
incinerator restricts and limits the acceptance of wastes which carry
only these 19 codes. Those 19 waste codes were considered the focus of
the delisting. Wastes with codes not listed in the Delisting Petition
are still subject to hazardous waste regulation and are not covered by
the delisting exclusion.
Comment 6. Moreover, the Federal Register notice states that
``there are some production plants that are not owned by Eastman but
are located on the facility,'' and these unidentified plants also send
hazardous wastes to the incinerator. 75 FR at 58317. There is no
information in the record that identifies these facilities, including
the nature of their production activities, raw materials used, and
wastes generated. Hazardous wastes are also accepted for processing in
the incinerator ``from other off-site Eastman facilities.'' Id. Again,
no information is provided in the administrative record that identifies
these facilities or describes their processes, raw materials, or
generated wastes, other than the broad assertion in the Federal
Register that the wastes are ``similar'' to those generated by Eastman.
Id. Since the full and accurate description of the hazardous wastes
processed in the incinerator is critical to
[[Page 72318]]
the proper selection of hazardous constituents for testing and
delisting analysis, this bare-bones description and lack of supporting
data and information in the administrative record cannot sustain a
delisting action.
Response 6. The Eastman RCRA Permit allows the facility to accept
wastes from other Eastman facilities and treat in the rotary kiln
incinerator. The Permit limits the types of wastes that are treated in
its rotary kiln incinerator to those addressed in the delisting
petition. The operating permit for the rotary kiln incinerator
restricts and limits the acceptance of wastes which carry only these 19
codes. Those 19 waste codes were considered the focus of the delisting.
Wastes with codes not listed in the Delisting Petition are still
subject to hazardous waste regulation and are not covered by the
delisting exclusion.
Comment 7. The DRAS model was apparently run for only 49 hazardous
constituents, a surprisingly small number. Under RCRA section 3001(f),
EPA must consider not only the constituents for which the subject
wastes were listed, but also additional constituents that may cause the
waste to be hazardous. Under EPA's Delisting Guidance, the Agency
usually requires that a delisting petitioner submit analytical results
and undertake DRAS modeling for literally hundreds more hazardous
constituents. Again, it somewhat defies credulity that incinerator ash
and scrubber water from a major, complex chemical plant would contain
such a small list of only 49 hazardous constituents. Lacking any
analytical data or other information in the administrative record,
however, ETC cannot effectively comment on this critical issue. In
fact, ETC cannot comment on the DRAS modeling in any substantive
respect because the record contains inadequate information.
Response 7. The EPA provided the administrative record and its
supporting documents to the commenter. No additional comments were
received regarding the DRAS analysis of the waste streams. Generally,
in all delistings, the DRAS model is run for chemicals which are the
basis for the waste codes petitioned for in the delisting and any
additional waste codes detected in the waste. For Eastman specifically,
there were 19 waste codes evaluated. These waste codes represented more
than 200 chemical constituents. In its analysis of the data, EPA only
found that 49 of the chemical constituents were detected in the
analysis of the three Eastman waste streams. These 49 waste codes were
evaluated in the DRAS model.
Comment 8. We also must question why this delisting is being
considered for incinerator ash and scrubber water that would
effectively override the RCRA land disposal treatment standards for the
subject wastes. Eastman has not petitioned to delist hazardous wastes
which do not meet the listing criteria as generated. There is
apparently no dispute that the waste materials processed in the
incinerator are hazardous wastes.
With respect to those wastes, EPA has already made the
determination based on lengthy and thorough LDR rulemakings that
combustion or comparable treatment to the specified treatment levels is
required to minimize short-term and long-term threats to human health
and the environment. In addition, EPA has already determined that
disposal of the treated wastes in a RCRA-permitted landfill that meets
minimum technology requirements (double synthetic liner, groundwater
monitoring, etc.) is necessary for adequate public health and
environmental protection. EPA Region 6 has provided no justification in
the record for overriding these national determinations, other than the
conclusory and unsupported assertion in the Federal Register notice
that the delisting levels will be adequate for such protections. Since
the petitioner already processes the hazardous wastes in a RCRA-
permitted incinerator and disposes of the residuals in an on-site RCRA-
permitted landfill, we can see no justification for the potential
lessening of public health and environmental protection from the
proposed delisting action. The ETC is also concerned that EPA Region
6's approval of this delisting would contravene Congress's land
disposal restrictions and treatment requirements in the RCRA statute.
Likewise, after careful review of the administrative record for the
Eastman Chemical delisting petition, it is clear that the incinerator
ash and scrubber water blowdown derived from the incineration of
numerous F-, K- and U-listed hazardous wastes are not eligible for
delisting, and that such an action would also violate the RCRA
treatment requirements and land disposal prohibitions.
We begin with basic principles--all seemingly ignored in the
proposed delistings. A waste is eligible for delisting only if that
waste as generated at a particular facility does not meet any of the
criteria under which the waste was listed as a hazardous waste. In
addition, the waste may not contain any other Appendix VIII
constituents that would cause the waste to be hazardous. RCRA Sec.
3001(f) and 40 CFR 260.22.
Likewise, the incinerator residues from the Eastman facility are
derived from the incineration of numerous waste streams that are F001,
F002, F003, F005, F039, K009, K010, U001, U002, U031, U069, U107, U112,
U117, U140, U147, U161, U213 and U359 hazardous wastes. By operation of
the derived-from rule, the Eastman incinerator residues are these same
F-, K- and U-listed hazardous wastes. The legal issue raised by the
Eastman Chemical delisting is whether the original F-, K- and U-listed
hazardous wastes would meet the applicable treatment requirements prior
to land disposal if the proposed delisting of the incineration
residuals were granted.
However, EPA Region 6 has proposed to delist the incinerator
residues and allow land disposal at constituent levels that are
significantly higher than the required treatment standards. There is no
exception from the land disposal prohibitions for inadequately treated
residues; in fact, allowing such an exception would obviously
eviscerate the treatment requirements. The original F-, K- and U-listed
hazardous wastes cannot be land disposed if the incinerator ash does
not meet the applicable treatment standards, and a delisting petition
cannot be used to evade this statutory requirement. For this reason,
the concentration levels in the incineration residues would have to be
lower than applicable treatment standards for a delisting to be
possible.
The following are examples of F039 treatment levels compared to
Eastman delisting levels (all concentrations in mg/l TCLP): Barium 21.0
vs. 100 delisted fly ash; Cadmium 0.11 vs. 0.362 delisted fly ash;
Chromium 0.60 vs. 5.0 delisted bottom ash and fly ash; Lead 0.75 vs.
2.45 delisted fly ash; Nickel 11.0 vs. 54.1 delisted bottom ash; Silver
0.14 vs. 5.0 delisted fly ash and bottom ash.
Response 8. The Delisting Program and the LDR program serve
different purposes and because they serve different purposes, different
standards of compliance apply. As the commenter states ``A waste is
eligible for delisting only if that waste as generated at a particular
facility does not meet any of the criteria under which the waste was
listed as a hazardous waste. In addition, the waste may not contain any
other Appendix VIII constituents that would cause the waste to be
hazardous. RCRA Sec. 3001(f) and 40 CFR 260.22.''
The derived-from rule states that any solid waste generated from
the treatment, storage, or disposal of a listed hazardous waste,
including any sludge, spill residue, ash, emission control dust, or
leachate, remains a hazardous waste
[[Page 72319]]
unless and until delisted. (Sec. 261.3(c)(2)(i)).
EPA's regulations establish two ways of identifying solid wastes as
hazardous under RCRA. A waste may be considered hazardous if it
exhibits certain hazardous properties (``characteristics'') or if it is
included on a specific list of wastes EPA has determined are hazardous
(``listing'' a waste as hazardous) because we found them to pose
substantial present or potential hazards to human health or the
environment. EPA's regulations in the Code of Federal Regulations (40
CFR) define four hazardous waste characteristic properties:
ignitability, corrosivity, reactivity, or toxicity (see 40 CFR 261.21-
261.24).
In order to list wastes EPA conducts a more specific assessment of
a particular waste or category of wastes. The Agency will ``list'' them
if they meet criteria set out in 40 CFR 261.11. As described in Sec.
261.11, EPA may list a waste as hazardous if the waste: Exhibits any of
the characteristics, i.e., ignitability, corrosivity, reactivity, or
toxicity (Sec. 261.11(a)(1)); is ``acutely'' hazardous (e.g., if it is
fatal to humans or animals at low doses, Sec. 261.11(a)(2)); or it
contains any of the toxic constituents listed in 40 CFR part 261,
Appendix VIII and, after consideration of various factors described in
the regulation, is capable of posing a ``substantial present or
potential hazard to human health or the environment when improperly
treated, stored, transported, or disposed of, or otherwise managed''
(Sec. 261.11(a)(3)).
EPA placed a substance on the list of hazardous constituents in
Appendix VIII if scientific studies have shown the substance has toxic
effects on humans or other life forms.
Generally, listing of wastes are not driven by threshold limits
except in the case of the toxicity characteristic (TC) determination.
Several of the limits cited by the commenter are the TC limit for the
constituents stated. If the waste is characteristic, then it can't be
delisted. The delisting limit is bound by the TC limit.
In 1984, Congress created EPA's Land Disposal Restrictions (LDR)
program. The LDR program ensures that toxic constituents present in
hazardous waste are properly treated before hazardous waste is land
disposed. Since then, the LDR team has developed mandatory technology-
based treatment standards that must be met before hazardous waste is
placed in a landfill. These standards help minimize short and long-term
threats to human health and the environment, which directly benefits
local communities where hazardous waste landfills are located. The LDR
Program does not determine if a waste is hazardous. It regulates how
hazardous wastes are to be managed at the time of disposal.
We do believe that the concentrations specified as delisting levels
do minimize short term and long term threats to human health and the
environment. Whereas, some LDR treatment standards are based on the
best demonstrated technology, the delisting exit levels are risk based
standards. We have not stated that Eastman is not subject to the LDR
standards because the waste was not delisted at the point of
generation, Eastman may submit a variance to the treatment standards as
described in Sec. 268.42(b) or 268.44 in order to ensure compliance
with the LDR standards, but the Delisting decision may still be made.
However, wastes destined for disposal in Subtitle C landfills are
subject to the LDR limits. Therefore, wastes when delisted must comply
with all applicable Subtitle D landfill requirements.
Comment 9. The ETC also notes that the DRAS software used by EPA
for these delistings was apparently a new Version 3, and that the
changes from Version 2 may not previously have been subject to public
notice and opportunity for comment. We are in the process of
determining all the changes incorporated into Version 3 and the effect
of those changes on delisting levels and the protection of human health
and the environment. The ETC requests that EPA Region 6 clarify the
changes made in Version 3, the effect of those changes on the pending
delistings, and the agency's rationales for those changes to allow for
effective public comment.
Response 9. As discussed in the Eastman Direct Final Rule and
Proposal, the changes made between version 2 of DRAS and Version 3 of
DRAS are described in 73 FR 28777. In July 2007, U.S. EPA prepared an
update of the DRAS by releasing version 3.0. The update addressed a
number of issues with version 2 and improved the fate and transport
modeling. To estimate the downgradient concentrations of waste leachate
constituents released into groundwater, the DRAS utilizes conservative
dilution attenuation factors (DAFs) taken from Monte-Carlo applications
of U.S. EPA's Composite Model for Leachate Migration with
Transformation Products (CMTP). DRAS 3.0 includes all new DAFs from new
CMTP modeling runs. The new modeling takes advantage of: Updated
saturated flow and transport modules; a new surface impoundment module
and database; model corrections for unrealistic scenarios (like water
tables modeled above the ground surface); new isotherms for metals; and
a revised recharge and infiltration database. As a result, many of the
DAFs used in previous versions of DRAS have changed. Further affecting
the groundwater calculation, the relationships for determining scaling
factors used to scale the DAFs to account for very small waste streams
have been updated to reflect the new database information on landfills
and surface impoundments and were also corrected for a metric
conversion of cubic meters to cubic yards. The new scaling factors are
generally higher than those of previous versions of DRAS, resulting in
higher estimated dilution and attenuation at lower waste volumes for
both landfills and surface impoundments. The new metals DAFs, based on
MINTEQA2 isotherms, can vary as a function of the landfill leachate
concentration. This means that the effective DAF (including a scaling
factor adjustment, if necessary) for an input concentration may differ
significantly with the effective DAF that corresponds to the allowable
leachate concentration. DRAS 3.0 now displays the DAFs in both the
forward calculated risk tables and the tables of maximum allowable
concentrations so that the difference is evident to the user. The
isotherms that vary by leachate concentration are represented in DRAS
by a look-up table with leachate concentrations paired with DAFs. In
the event that an actual concentration input to DRAS lies between two
values in the table, or an allowable receptor concentration lies
between two calculated receptor concentrations from the table, DRAS 3.0
will linearly and proportionally extrapolate between the two values to
determine the corresponding exposure or allowable leachate
concentration. EPA changed the calculation for particle emissions
caused by vehicles driving over the waste at the landfill to provide a
more realistic estimate. The estimate depends upon the number of trips
per day landfill vehicles make back and forth over the waste. In
previous versions of DRAS, this value was conservatively set at a 100
trips per day, corresponding with an extremely high annual waste
volume. In DRAS 3.0, a minimum number of trips per day was
conservatively assumed from the Subtitle D landfill survey (7.4 trips
per day at the 95th percentile of values reported). The number of trips
per day specific to the actual waste volume is then added to the
minimum to reflect
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the impact of very large waste streams. This will considerably reduce
the particle emission estimate for wastes generated at all but the
largest annual volumes. EPA added a conversion from English to metric
tons to the calculation of particle emissions from waste unloading,
resulting in a decrease of roughly 10% over previous versions of DRAS.
We also made a unit-conversion factor correction to part of the air
volatile pathway which will reduce the impact to the receptor. An error
in the back-calculation for fish ingestion pathway was corrected to
reflect the difference between freely dissolved and total water column
waste constituent concentrations. For the estimation of risk and
hazard, we made a number of updates to the forward and back
calculations. Previous versions of DRAS assumed that only 12.5% of
particles are absorbed by the receptor's respiratory system. This is no
longer necessary as toxicity reference values for inhalation currently
recommended by U.S. EPA relate risk or hazard directly to exposure
concentration. DRAS 3.0 does not include the 12.5% reduction. This
change significantly increases estimated risks due to particle
inhalation and lowers corresponding allowable concentrations. DRAS
Version 3.0.47 has a reformulated back calculation of the allowable
leachate concentrations from exposure due to contaminants volatilized
during household water use to match the forward calculation of risk. In
previous versions of DRAS, the forward calculation summed the risks
from exposure to all three evaluated household compartments (the
shower, the bathroom, and the whole house) while the back calculation
based the maximum allowable level on the single most conservative
compartment. The DRAS 3.0 maximum allowable leachate concentrations are
now based on the combined impact of all three compartments. The house
exposure was also expanded to a 900 minute (15 hour) daily exposure to
reflect non-working residents who have an overall 16 hour in-house
exposure (the other 1 hour is spent in the shower and bathroom). EPA
resolved the inconsistencies with the way DRAS chooses limiting
pathways for specific waste constituents in DRAS 3.0. EPA checked all
toxicity reference values in DRAS and updated where necessary.
Approximately 180 changes were made to the toxicity reference values in
DRAS based on data in IRIS, PPRTV, HEAST, NCEA, CalEPA and other
sources. Some route-to-route extrapolations of oral toxicity data to
inhalation exposure have been returned to DRAS 3.0 if consistent with
Agency policy. See U.S. EPA 2006 for full accounting of this
methodology. The same reference also includes discussions of toxicity
reference choices where the multiple values were available or where the
toxicity reference values were specific to particular species of
constituents.
Comment 10. On January 18, 2011, President Barack Obama signed
Executive Order 13563 to ``improve regulation and regulatory review''
in his Administration. In the section on public participation in the
regulatory process, President Obama stated that ``each agency shall
afford the public a meaningful opportunity to comment through the
internet on any proposed regulation, with a comment period that should
generally be at least 60 days.''
Response 10. The Eastman Direct Final Rule published in the Federal
Register on September 24, 2010, several months before President Obama's
Executive Order was issued. The EPA Region 6 will abide by the order
issued on January 18, 2011 in future delisting actions.
Comment 11. Obviously, our concern is that these supporting
materials may have been generated subsequent to the proposed delisting,
and therefore could not have been relied on by EPA in developing the
proposed rule. We request that EPA Region 6 clarify whether the DRAS
output files included in the administrative record were the output
files relied on for the proposed rule, how this could be possible given
the dates of the output files, and whether other output files existed
prior to proposal of the delisting that were not included in the
administrative record.
Response 11. The DR