New Source Performance Standards Review for Nitric Acid Plants, 63878-63891 [2011-26089]
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Federal Register / Vol. 76, No. 199 / Friday, October 14, 2011 / Proposed Rules
SO2 Group 2 trading
budget (tons) * for 2014
and thereafter
State
Texas ...........................................................................................
New unit set-aside
(tons) for 2014 and
thereafter
314,021
15,387
Indian country new unit
set-aside (tons) for 2014
and thereafter
314
* Each trading budget includes the new unit set-aside and, where applicable, the Indian country new unit set-aside and does not include the
variability limit.
(b) The States’ variability limits for
the State SO2 Group 2 trading budgets
for the control periods in 2014 and
thereafter are as follows:
State
Variability limits
for 2014 and
thereafter
Alabama ............................
Georgia .............................
Kansas ..............................
Minnesota .........................
Nebraska ..........................
South Carolina ..................
Texas ................................
38,386
17,142
7,475
7,557
11,709
15,952
56,524
15. Section 97.725 is amended by, in
paragraph (b)(1), removing the word
‘‘2013’’ and adding, in its place, the
word ‘‘2015’’.
[FR Doc. 2011–26521 Filed 10–13–11; 8:45 am]
BILLING CODE 6560–50–P
ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Part 60
[EPA–HQ–OAR–2010–0750; FRL–9477–1]
RIN 2060–AQ10
New Source Performance Standards
Review for Nitric Acid Plants
Environmental Protection
Agency (EPA).
ACTION: Proposed rule.
AGENCY:
The EPA is proposing
revisions to the new source performance
standards (NSPS) for nitric acid plants.
Nitric acid plants include one or more
nitric acid production units. These
proposed revisions include a change to
the nitrogen oxides (NOX) emission
limit, which applies to each nitric acid
production unit commencing
construction, modification, or
reconstruction after October 14, 2011.
These proposed revisions will also
include additional testing and
monitoring requirements.
DATES: Comments must be received on
or before November 28, 2011. Under the
Paperwork Reduction Act, comments on
the information collection provisions
are best assured of having full effect if
the Office of Management and Budget
(OMB) receives a copy of your
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SUMMARY:
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comments on or before November 14,
2011.
ADDRESSES: Submit your comments,
identified by Docket ID No. EPA–HQ–
OAR–2010–0750, by one of the
following methods:
• Federal eRulemaking Portal: https://
www.regulations.gov. Follow the
instructions for submitting comments.
• Agency Web site: https://
www.epa.gov/oar/docket.html. Follow
the instructions for submitting
comments on the EPA Air and Radiation
Docket Web site.
• E-mail: a-and-r-Docket@epa.gov.
Include EPA–HQ–OAR–2010–0750 in
the subject line of the message.
• Fax: Fax your comments to: (202)
566–9744, Attention Docket ID No.
EPA–HQ–OAR–2010–0750.
• Mail: Send your comments to: EPA
Docket Center (EPA/DC), Environmental
Protection Agency, Mailcode: 2822T,
1200 Pennsylvania Ave., NW.,
Washington, DC 20460, Attention:
Docket ID No. EPA–HQ–OAR–2010–
0750. Please include a total of two
copies. In addition, please mail a copy
of your comments on the information
collection provisions to the Office of
Information and Regulatory Affairs,
Office of Management and Budget
(OMB), Attn: Desk Officer for EPA, 725
17th St., NW., Washington, DC 20503.
• Hand Delivery or Courier: In person
or by courier, deliver comments to EPA
Docket Center, EPA West, Room 3334,
1301 Constitution Ave., NW.,
Washington, DC 20460. Such deliveries
are only accepted during the Docket
Center’s normal hours of operation,
(8:30 a.m. to 4:30 p.m., Monday through
Friday, excluding legal holidays), and
special arrangements should be made
for deliveries of boxed information.
Please include a total of two copies.
Instructions: All submissions received
must include the agency name and
docket number or Regulatory
Information Number (RIN) for this
rulemaking. All comments received will
be posted without change to https://
www.regulations.gov, including any
personal information provided, unless
the comment includes information
claimed to be confidential business
information (CBI) or other information
whose disclosure is restricted by statute.
Do not submit information that you
consider to be CBI or otherwise
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protected through https://
www.regulations.gov or e-mail. The
https://www.regulations.gov Web site is
an ‘‘anonymous access’’ system, which
means that the EPA will not know your
identity or contact information unless
you provide it in the body of your
comment. If you send an e-mail
comment directly to the EPA without
going through https://
www.regulations.gov, your e-mail
address will be automatically captured
and included as part of the comment
that is placed in the public docket and
will be made available on the Internet.
If you submit an electronic comment,
the EPA recommends that you include
your name and other contact
information in the body of your
comment and with any disk or CD–ROM
you submit. If EPA cannot read your
comment due to technical difficulties
and cannot contact you for clarification,
EPA may not be able to consider your
comment. Electronic files should avoid
the use of special characters, any form
of encryption, and be free of any defects
or viruses. For detailed instructions on
submitting comments and additional
information on the rulemaking process,
see the ‘‘General Information’’ heading
of the SUPPLEMENTARY INFORMATION
section of this document.
Docket: All documents in the docket
are listed in the https://
www.regulations.gov index. Although
listed in the index, some information is
not publicly available (e.g., CBI or other
information whose disclosure is
restricted by statute). Certain other
material, such as copyrighted material,
will be publicly available only in hard
copy form. Publicly available docket
materials are available either
electronically in https://
www.regulations.gov or in hard copy at
the EPA Docket Center, Public Reading
Room, EPA West, Room 3334, 1301
Constitution Ave., NW., Washington,
DC. The Public Reading Room is open
from 8:30 a.m. to 4:30 p.m., Monday
through Friday, excluding legal
holidays. The telephone number for the
Public Reading Room is (202) 566–1744,
and the telephone number for the Air
Docket is (202) 566–1742.
FOR FURTHER INFORMATION CONTACT: For
questions about these proposed
standards for nitric acid production
units, contact Mr. Chuck French, Sector
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Policies and Program Division, Office of
Air Quality Planning and Standards
(D243–02), Environmental Protection
Agency, Research Triangle Park, North
Carolina 27711, telephone number (919)
541–7912; fax number (919) 541–3207,
e-mail address: French.chuck@epa.gov.
SUPPLEMENTARY INFORMATION:
The information presented in this
preamble is organized as follows:
I. General Information
A. Does this action apply to me?
B. What should I consider as I prepare my
comments to EPA?
C. Where can I get a copy of this
document?
D. When would a public hearing occur?
II. Background Information
A. What is the statutory authority for these
proposed revisions?
B. What are the current NSPS for Nitric
Acid Plants?
III. Summary of Proposed Standards
A. What source category is being regulated?
B. What pollutants are emitted from these
sources?
C. What are the proposed standards?
IV. Rationale for the Proposed Standards
A. How is EPA proposing to revise the
emissions limit for affected sources?
B. How is EPA proposing to revise the
testing and monitoring requirements?
C. How is EPA proposing to revise the
notification, reporting, and
recordkeeping requirements?
V. Summary of Cost, Environmental, Energy,
and Economic Impacts of These
Proposed Standards
A. What are the impacts for new nitric acid
production units?
B. What are the secondary impacts for new
nitric acid production units?
C. What are the economic impacts for new
nitric acid production units?
VI. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory
Planning and Review and Executive
Order 13563: Improving Regulation and
Regulatory Review
B. Paper Reduction Act
Category
325311
............................
............................
1 North
I. General Information
A. Does this action apply to me?
Categories and entities potentially
regulated by these proposed revisions
include:
Examples of regulated entities
Nitrogenous Fertilizer Manufacturing.
Not affected.
Not affected.
American Industrial Classification System.
This table is not intended to be
exhaustive, but rather provides a guide
for readers regarding entities likely to be
regulated by this action. To determine
whether your facility would be
regulated by this action, you should
examine the applicability criteria in 40
CFR 60.70a. If you have any questions
regarding the applicability of this
proposed action to a particular entity,
contact the person in the preceding FOR
FURTHER INFORMATION CONTACT section.
B. What should I consider as I prepare
my comments to the EPA?
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C. Regulatory Flexibility Act
D. Unfunded Mandates Reform Act
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation
and Coordination With Indian Tribal
Governments
G. Executive Order 13045: Protection of
Children From Environmental Health
and Safety Risks
H. Executive Order 13211: Actions
Concerning Regulations That
Significantly Affect Energy Supply,
Distribution, or Use
I. National Technology Transfer and
Advancement Act
J. Executive Order 12898: Federal Actions
To Address Environmental Justice in
Minority Populations and Low-Income
Populations
NAICS code 1
Industry .......................................................................................................
Federal government ....................................................................................
State/local/tribal government ......................................................................
63879
Do not submit information that you
consider to be CBI electronically
through https://www.regulations.gov or
e-mail. Send or deliver information
identified as CBI only to the following
address: Roberto Morales, OAQPS
Document Control Officer (C404–02),
Office of Air Quality Planning and
Standards, Environmental Protection
Agency, Research Triangle Park, NC
27711, Attention Docket ID No. EPA–
HQ–OAR–2010–0750. Clearly mark the
part or all of the information that you
claim to be CBI. For CBI information in
a disk or CD–ROM that you mail to EPA,
mark the outside of the disk or CD–ROM
as CBI and then identify electronically
within the disk or CD–ROM the specific
information that is claimed as CBI. In
addition to one complete version of the
comment that includes information
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claimed as CBI, a copy of the comment
that does not contain the information
claimed as CBI must be submitted for
inclusion in the public docket.
Information marked as CBI will not be
disclosed except in accordance with
procedures set forth in 40 CFR part 2.
C. Where can I get a copy of this
document?
In addition to being available in the
docket, an electronic copy of the
proposed action is available on the
Worldwide Web (WWW) through the
Technology Transfer Network (TTN)
Web site. Following signature, EPA
posted a copy of the proposed action on
the TTN Web site’s policy and guidance
page for newly proposed or promulgated
rules at https://www.epa.gov/ttn/oarpg.
The TTN Web site provides information
and technology exchange in various
areas of air pollution control.
D. When would a public hearing occur?
If anyone contacts EPA requesting to
speak at a public hearing by October 24,
2011, a public hearing will be held on
October 28, 2011. Persons interested in
presenting oral testimony or inquiring
as to whether a public hearing is to be
held should contact Mr. Chuck French,
listed in the FOR FURTHER INFORMATION
CONTACT section.
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II. Background Information
A. What is the statutory authority for
these proposed revisions?
New source performance standards
(NSPS) implement Clean Air Act (CAA)
section 111. Section 111 of the CAA
requires that NSPS reflect the
application of the best system of
emission reductions which (taking into
consideration the cost of achieving such
emission reductions, any nonair quality
health and environmental impact and
energy requirements) the Administrator
determines has been adequately
demonstrated. This level of control has
sometimes been referred to as ‘‘best
demonstrated technology’’ or BDT, and
will be referred to in this preamble as
best system of emissions reduction
(BSER). In assessing whether a standard
is achievable, EPA must account for
routine operating variability associated
with performance of the system on
whose performance the standard is
based. See National Lime Ass’n v. EPA,
627 F. 2d 416, 431–33 (DC Cir. 1980).
Common sources of information as to
what constitutes a BSER, and for
assessing that technology’s level of
performance, include best available
control technology (BACT)
determinations made as part of new
source review (NSR). Also, emissions
limits that exist in state and federal
permits for recently permitted sources,
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and emissions test data for
demonstrated control technologies
collected for compliance demonstration
or other purposes are evaluated during
these assessments. EPA compares
permit limitations and BACT
determination data with actual
performance test data to identify any
site-specific factors that could influence
general applicability of this information.
Also, as part of this review we evaluate
if NOX emissions limits more stringent
than those in Subpart G have been
established, or if emissions limits have
been developed for additional air
pollutants.
The use of State permit data and
BACT determination developed as part
of NSR is appropriate because a BACT
determination evaluates information
that is similar to BSER, such as available
controls, their performance, cost, and
non-air environmental impacts. One
important difference between BACT
determinations and a BSER
determination for purposes of NSPS is
that BACT determinations are made on
a site-specific basis. Therefore, in
evaluating BACT determinations, we
have to account for any site-specific
factors that may not be applicable to the
source category as a whole.
Section 111(b)(1)(B) of the CAA
requires EPA to periodically review and
revise the standards of performance, as
necessary, to reflect improvements in
methods for reducing emissions.
Existing affected facilities that are
modified or reconstructed would also be
subject to these proposed revisions for
affected sources. Under CAA section
111(a)(4), ‘‘modification’’ means any
physical change in, or change in the
method of operation of, a stationary
source which increases the amount of
any air pollutant emitted by such source
or which results in the emission of any
air pollutant not previously emitted.
Changes to an existing facility that do
not result in an increase in emissions
are not considered modifications.
Rebuilt affected facilities would become
subject to the proposed standards under
the reconstruction provisions, regardless
of changes in emission rate.
Reconstruction means the replacement
of components of an existing facility
such that (1) The fixed capital cost of
the new components exceeds 50 percent
of the fixed capital cost that would be
required to construct a comparable
entirely new facility; and (2) it is
technologically and economically
feasible to meet the applicable standards
(40 CFR 60.15).
The NSPS are directly enforceable
federal regulations issued for categories
of sources which cause, or contribute
significantly to, air pollution which may
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reasonably be anticipated to endanger
public health or welfare. The primary
purpose of the NSPS is to attain and
maintain ambient air quality by
ensuring that the best demonstrated
emission control technologies are
installed as the industrial infrastructure
is modernized, when it is most cost
effective to build in controls. Since
1970, the NSPS have been successful in
achieving long-term emissions
reductions in numerous industries by
assuring that cost-effective controls are
installed on new, reconstructed, or
modified sources.
B. What are the current NSPS for Nitric
Acid Plants NSPS?
The current NSPS for Nitric Acid
Plants (40 CFR part 60, Subpart G) were
promulgated in the Federal Register on
December 23, 1971 (36 FR 24881). The
first review of the Nitric Acid Plants
NSPS was completed on June 19, 1979
(44 FR 35265). An additional review
was completed on April 5, 1984 (49 FR
13654). No changes were made to the
NSPS as a result of those reviews. Minor
testing and monitoring changes were
made during three reviews since the
original promulgation in 1971 (October
6, 1975 (40 FR 46258), April 22, 1985
(50 FR 15894), and February 14, 1989
(54 FR 6666)). The current Nitric Acid
Plants NSPS (Subpart G) applies to each
nitric acid production unit constructed
or modified after August 17, 1971. The
present NSPS has an emissions limit of
3.0 lb of NOX per ton of 100% nitric
acid produced and a 10% opacity
standard as an additional method of
demonstrating compliance with the
NOX emission limit. Continuous NOX
monitors are required as well as
recording daily production rates.
III. Summary of Proposed Standards
A. What source category is being
regulated?
Today’s proposed standards would
apply to new nitric acid production
units. Nitric acid plants may include
one or more nitric acid production
units. For purposes of these proposed
regulations, a nitric acid production
unit is defined as any facility producing
weak nitric acid by either the pressure
or atmospheric pressure process. This
definition has not changed from
Subpart G.
A new nitric acid production unit is
defined as a nitric acid production unit
for which construction, modification, or
reconstruction commences on or after
October 14, 2011. The affected facility
under the proposed NSPS is each nitric
acid production unit.
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B. What pollutants are emitted from
these sources?
The pollutant to be regulated under
section 111(b), for new nitric acid
production units, is NOX which undergo
reactions in the atmosphere to form
particulate matter and ozone. Nitrogen
oxides, particulate matter, and ozone are
all subject to national ambient air
quality standards under section 109 of
the Clean Air Act, based on their
adverse effects to human health and
welfare. NOX is a criteria pollutant.
These nitric acid production units
also emit another nitrogen compound
known as nitrous oxide (N2O), which is
considered a greenhouse gas (GHG). We
are not proposing an N2O emission
standard in this action. Although we
have limited data from facilities in the
U.S, we believe that owners/operators of
nitric acid production units should
consider technologies and technology
combinations that would be appropriate
for controlling both NOX and N2O. Some
technologies such as selective catalytic
reduction (SCR) and hydrogen peroxide
injection (HPI) are effective only in
controlling NOX. However, other
technologies such as nonselective
catalytic reduction (NSCR) are effective
in controlling both NOX and N2O.
The technology combinations that
control both NOX and N2O include SCR
plus secondary catalysts (located in the
ammonia reactor), and SCR plus other
non-NSCR types of tertiary catalysts
(located after the absorption tower). We
expect any controls applied to control
NOX emissions would not preclude
installing cost effective N2O control
technologies in the future. We solicit
relevant comments and additional
information on these technologies.
Nitric acid production is also one of the
industrial sectors for which ‘‘white
papers’’ were written to provide basic
information on GHG control options to
assist state and local air pollution
control agencies, tribal authorities, and
regulated entities in implementing
measures to reduce GHGs, particularly
in the assessment of BACT under the
PSD permitting program. These papers
provide basic technical information that
may be useful in a BACT analysis but
they do not define BACT for each sector.
For more information regarding the
‘‘white papers,’’ see https://
www.epa.gov/nsr/ghgpermitting.html.
C. What are the proposed standards?
We are proposing to reduce the NOX
emissions limit from 3.0 pounds of NOX
per ton of nitric acid produced (lb NOX/
ton acid), expressed as NO2, with the
production being expressed as 100
percent nitric acid, to 0.50 lb NOX/ton
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acid as a 30-day emission rate
calculated each operating day based on
the previous 30 consecutive operating
days.
The general provisions in 40 CFR part
60 provide that emissions in excess of
the level of the applicable emissions
limit during periods of startup,
shutdown, and malfunction shall not be
considered a violation of the applicable
emission limit unless otherwise
specified in the applicable standard. See
40 CFR 60.8(c). The general provisions,
however, may be amended for
individual subparts. See 40 CFR 60.8(h).
Here, the EPA is proposing standards in
Subpart Ga that apply at all times,
including periods of startup or
shutdown, and periods of malfunction.
IV. Rationale for the Proposed
Standards
Section 111(a)(1) requires that
standards of performance for new
sources reflect the—
* * * degree of emission limitation
achievable through the application of the best
system of emission reduction which (taking
into account the cost of achieving such
reduction, and any nonair quality health and
environmental impact and energy
requirements) the Administrator determines
has been adequately demonstrated.
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A. How is EPA proposing to revise the
emissions limit for affected sources?
For affected sources constructed,
modified, or reconstructed after October
14, 2011, we are proposing to reduce the
NOX emissions limit from 3.0 lb NOX/
ton acid to 0.50 lb NOX/ton acid as a 30day emission rate calculated each
operating day based on the previous 30
consecutive operating days.
The NOX emissions limit for affected
facilities constructed, modified, or
reconstructed after August 17, 1971, and
before October 14, 2011 remains
unchanged at 3.0 lb NOX/ton acid.
The 1971 promulgated Nitric Acid
Plants NSPS were based on emission
levels achieved using catalytic
reduction (see 36 FR 2881, December
23, 1971). Additional reviews of the
NSPS were conducted in 1979 and
1984, where EPA again concluded that
catalytic reduction was the BSER
considering economic, energy, and
nonair environmental impacts. No
changes were made to the NSPS during
these reviews.
There are currently 40 nitric acid
production facilities in the U.S. with a
total of 67 nitric acid production units.
For this review, information was
collected from responses to a section
114 information collection request
(ICR), through site visits and from trade
associations. The information and
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comments from stakeholders are
contained in the docket.
The review of permits and other
available information in the record
revealed that SCR, NSCR, and HPI are
all air pollution control technologies
that are used for NOX control in the
nitric acid production source category
and EPA considered all of these as
candidates for BSER as we developed
this proposed rule. We are not aware of
any other established or emerging
technologies that should be considered
as candidates for BSER for this source
category. SCR is used in 25 nitric acid
production units in the U.S. NSCR is
used in 14 nitric acid process units in
the U.S. HPI is used by one facility. All
of these air pollution control
technologies are effective in controlling
NOX emissions. The average NOX
emission reductions for these controls
are: SCR—98%; NSCR—99%, HPI—
95% (for more information see Table 3.3
in the Economic Impact Analysis, which
is available in the docket for this
action).
The approach used for determining
BSER for nitric acid production units
involved reviewing the emission test
data submitted in response to the
section 114 ICR, recently issued state
permit data, and BACT determinations
developed as part of NSR. In response
to clarifications of the section 114 ICRs,
industry provided additional data. In
determining BSER we generally look at
the controls and control performance of
new sources. All recent nitric acid units
have installed SCR as NOX controls.
Recent BACT determinations have also
identified SCR as BACT.
A 2009 BACT determination has been
incorporated into the facility permit
limit for a nitric acid plant in American
Falls, Idaho (Southeast Idaho Energy,
LLC). For this analysis, SCR was
determined as BACT, and 0.60 lb NOX/
ton acid was determined as the BACT
level of control. The Southeast Idaho
Energy, LLC emission limit of 0.60 lb
NOX/ton acid will apply at all times
during steady-state operations (no
standard applies during periods of
startup or shutdown, and periods of
malfunction). The compliance period
was not specified.
There are other recent BACT analyses
at two other nitric acid production
units. At Agrium in North Bend, Ohio,
the BACT limit set in 2009 is 0.61 lb
NOX/ton acid on a 365-day rolling basis.
At Agrium in Kennewick, Washington,
the BACT limit set in 2008 is 0.60 lb
NOX/ton acid in any continuous 12month period (including startup,
shutdown and malfunction).
As part of our BSER analysis, we are
proposing that the standard be stated as
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63881
a rolling 30-day limit based on 30
consecutive operating days and that the
limit be met at all times. We believe that
the 0.50 lb NOX/ton acid standard,
supported by existing source data and
BACT determinations, is more stringent
than any state BACT determination
because 0.50 lb NOX/ton acid is lower
than both 0.61 lb NOX/ton acid and 0.60
lb NOX/ton acid.
Emissions test data were obtained
from a number of sources including a
section 114 ICR, trade associations, and
the EPA Region 5. We received nine
relative accuracy test audit (RATA)
reports for 5 nitric acid production units
controlled with SCR, 6 RATA reports for
6 nitric acid production units controlled
with NSCR, and 1 RATA report for 1
nitric acid production unit controlled
with HPI. These emissions tests are
short term and are presented in the
memorandum Summary of Test Data
Received from Section 114 ICR, dated
August 25, 2010 (updated December 17,
2010).
In response to the section 114 request,
nitric acid plants submitted NOX
Continuous Emission Monitoring
Systems (CEMS) data. These included 3
facilities using SCR and 2 facilities
using NSCR.
All emission test data (short term and
CEMS data) indicate that lower
emissions than the current Subpart G
emission limit of 3.0 lb NOX/ton acid
are being achieved, regardless of the
type of NOX control being used. We
decided to further analyze the long-term
CEMS data because: (1) Long term data
include periods of startup and
shutdown, where emissions are shown
to be larger than during steady state
operating conditions, (2) long term data
allow the seasonal impacts of
temperature and humidity on NOX
controls to be evenly distributed, as
these factors often vary by the time of
year and location, and (3) long term data
include seasonal supply and demand
cycles so that all factors that influence
production are equally considered.
We have concluded that SCR is BSER
based on data showing lower emissions
rates from SCR-controlled units. For
more information, see Table 1 of this
preamble and the related discussion.
The fact that SCR is the only known
NOX control technology being installed
in new nitric acid production units, and
that SCR has been determined to be
BACT supports this conclusion. Further,
SCR does not produce any secondary
environmental impacts.
The next step in the NSPS process is
to establish an achievable standard
using BSER. In assessing whether a
standard is achievable, the EPA must
account for routine operating variability
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associated with performance of the
system on which the standard is based.
For each plant that submitted long-term
CEMS data, these data cover the entire
operating period including startups,
shutdowns and malfunctions. To ensure
that the new NOX standard is achievable
by all properly designed and operated
SCR units and covers all operating
periods including startup and
shutdowns, we analyzed the statistical
variation by calculating the 99th
percentile. When establishing an
emissions limit (which is considered a
never to exceed level of emissions), we
use a 99th percentile based on statistical
analyses. This approach accounts for
short and long-term variability in
emissions associated with all normal
operating conditions, including startup
and shutdown (see 72 FR 54878–79,
September 27, 2007). This analysis is
contained in the memorandum
Statistical Evaluation of CEMS Data to
Determine the NOX Emission Standard,
dated July 18, 2011.
Using the long term CEMS data
received through the ICR, the EPA
determined that there were sufficient
data to directly calculate the 99th
percentile for the best performing
sources. The EPA determined that the
CEMS represents long-term performance
and accounts for long-term and day-today variability.
Long term CEMS data were obtained
from 3 plants using SCR and 2 plants
using NSCR. The plant with HPI did not
submit long term CEMS data. Following
is a discussion of these data—the 3
plants with SCR are discussed first
followed by the 2 plants with NSCR.
The 99th percentile was directly
calculated for these 5 best performing
sources. A summary of the values is
shown in Table 1.
TABLE 1—CEMS DATA—99TH PERCENTILE BY COMPLIANCE PERIOD
[lb of NOX/T of 100% nitric acid]
Control
PCS Geismar (Train 5) .............................................
Agrium North Bend ...................................................
El Dorado Nitrogen ...................................................
PCS Geismar (Train 4) .............................................
Agrium Sacramento ..................................................
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Compliance period
SCR ..................
SCR ..................
SCR ..................
NSCR ...............
NSCR ...............
The Agrium-North Bend plant
submitted data spanning from January
2010 through December 2010. The
continuous data over the 12-month
period show 0.50 lb NOX/ton acid as the
99th percentile for each 30-day rolling
time period. The 30-day periods with
high NOX emissions occurred during
periods of startup and shutdown.
The PCS Geismar plant submitted 15minute average data for Train 5 for
2007–2009. Train 5 is controlled with
SCR. The period spanning January 2009
through December 2009 was analyzed.
The continuous data from a 12-month
period show 0.38 lb NOX/ton acid as the
99th percentile for each 30-day rolling
time period.
The El Dorado plant submitted hourly
averages data for the period of July
2010–June 2011. The continuous data
from a 12-month period show 0.37 lb
NOX/ton acid as the 99th percentile for
each 30-day rolling time period.
We also received 15-minute average
data on NOX emissions for 2007–2009
from the PCS Geismar plant for Train 4,
which is controlled with NSCR. The
period spanning January 2009 through
December 2009 was analyzed to be
consistent with Train 5 (controlled with
SCR). The continuous data from a 12month period show 2.41 lb NOX/ton
acid as the 99th percentile emissions
level for a 30-day time period for train
4. The result of this analysis is limited
due to the fact that the nitric acid train
was operational for approximately 65
days during the 12-month period. It is
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15 minute
0.84
NA
NA
0.97
NA
hourly
0.89
0.69
0.47
1.25
2.13
unlikely that this short time period is
representative of the NSCR performance
over time.
The Agrium-Sacramento plant
submitted data spanning from January
2010 through December 2010. The
continuous data over the 12-month
period show 1.29 lb NOX/ton acid as the
99th percentile for a 30-day time period.
The 30-day periods with high NOX
emissions occurred during periods of
startup and shutdown.
As shown by Table 1, all units are
meeting the current Subpart G NOX
emission standard of 3.0 lb NOX/ton
acid, regardless of the compliance
period. We did not receive any long
term data from the nitric acid train
using HPI but the table shows that the
NOX emissions from nitric acid trains
using SCR are lower than nitric acid
trains using NSCR. For example,
reviewing the 99th percentile on a 30day rolling basis, SCR data range from
0.38 to 0.50 lb NOX/ton acid and NSCR
data range from 1.29 to 2.41 lb NOX/ton
acid. The lower emissions from SCR
when compared to emissions from
NSCR are the main reason that SCR has
been determined as BSER.
Whether NSCR can meet the levels
achievable by SCR over a long term, is
uncertain. The long term CEMS data
from 2 NSCR plants indicate difficulty
in meeting the 0.50 lb NOX/ton limit.
However, we have monthly average data
from 2 other facilities using NSCR.
These plants with NSCR (Dyno NobelDeer Island and JR Simplot–Helm)
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3-hour
rolling
1.00
0.80
0.47
1.74
NA
daily
block
1.02
1.67
0.44
5.58
1.60
7-day
rolling
0.72
0.92
0.40
2.41
1.31
30-day
rolling
0.38
0.50
0.37
2.41
1.29
submitted monthly block averages for a
three year period. For 2009, the monthly
block averages for both plants were very
close and range from 7 to 17 ppm or
approximately 0.15–0.36 lb NOX/ton
acid. As these data are not continuous
but rather block monthly averages,
comparison of these with the CEMS data
discussed above is not possible. These
data are presented to show that NSCR
may be able to achieve the proposed
emission limit. Also, the data presented
in the memorandum Summary of Test
Data Received from Section 114 ICR,
dated August 25, 2010 (updated
December 17, 2010) show that low
short-term NOX emissions rates are
possible when using NSCR and HPI.
For the units controlled by SCR, we
have not been able to identify any
specific factors associated with the El
Dorado Nitrogen and PCS Nitrogen
Train 5 units that account for the lower
emission levels compared to the
Agrium-North Bend unit. Thus, based
on the information currently in the
record, we believe that emission levels
of NOX are not only dependent on the
use of SCR but also on process factors
that result in variability that cannot be
avoided through better or different
design or through changes in operating
practices.
By selecting an emission limit based
on the 99th percentile of emissions data
from unit with BSER (which is SCR), we
ensure that this limit reflects BSER but
is also achievable during all periods by
facilities that have BSER equivalent
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controls. The available data for units
with BSER, which were used to derive
the proposed NOX emissions limit for
new, modified and reconstructed units,
are from existing nitric acid units that
have been in operation for at least 10
years. Therefore, we believe that
reconstructed, modified and new
sources will be able to meet the
proposed limit. We have no reason to
believe that modified or reconstructed
sources would not be able to meet this
limit. Thus, we do not believe different
standards are needed for modified or
reconstructed sources.
Moreover, in the past when
companies chose to increase production
or replace units, it is our understanding
that they would build new production
units rather than modify or reconstruct
existing units. In fact, to our knowledge,
no existing nitric acid production unit
has been reconstructed or modified
since Subpart G was promulgated.
Therefore, we expect no reconstructions
or modifications to occur for the nitric
acid industry in the foreseeable future.
Nevertheless, we request comment on
any reconstructions or modifications to
nitric acid production units that have
taken place or information about any
future plans to do such modifications or
reconstructions. Also, we request data
on the level of NOX emissions that these
nitric acid units are able to achieve. If
these emission levels are different than
0.50 lb NOX/ton acid on a 30 day rolling
basis, the commenter should include
data to support the suggested emission
level.
Nevertheless, we expect that growth
within the industry will be limited to
newly constructed nitric acid
production units. We believe that new
nitric acid production units will be able
to meet the proposed limit which takes
into consideration routine operating
variability as well as variation due to
weather and periods of startups and
shutdowns. The proposed emission
limit of 0.50 lb NOX/ton acid is a never
to exceed limit. We have not identified
any specific process or technology that
new nitric acid production units could
employ to consistently meet an
emission limit lower than 0.50 lb NOX/
ton acid. Therefore, we are proposing a
limit of 0.50 lb NOX/ton acid for
Subpart Ga.
As part of our BSER analysis, we are
proposing that the standard be stated as
a rolling 30-day limit based on 30
consecutive operating days and that the
limit be met at all times including
periods of startup and shutdown. We
believe that the 0.50 lb NOX/ton acid
standard is supported by existing source
data. The use of a 30-day period
accounts for peaks in the data that occur
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during startup and shutdown. These
periods occur on average about 3 to 4
hours per month and emissions during
those periods are much higher than
normal. Therefore, the 3 to 4 hour
periods can affect average emissions
beyond that 3 to 4 hour period. Setting
the standard with a 30-day compliance
period meets the statutory requirement
that the standard reflect the degree of
emission limitation that is achievable
through BSER, including during periods
that include startup and shutdown.
Although the proposed limit of 0.50 lb
NOX/ton acid is based on the data for
SCR, NSPS do not require the use and
installation of a specific control device.
We request additional long-term data (in
units of the standard) to determine
whether NSCR and HPI can achieve the
proposed limit.
For all of the reasons discussed above,
we are proposing 0.50 lb NOX/ton acid
as the revised standard for Nitric Acid
Plants to be established in Subpart Ga.
Periods of Startup or Shutdown. In
proposing the standards in this rule, the
EPA has taken into account startup and
shutdown periods and, for the reasons
explained below, has not proposed
different standards for those periods.
According to information received
from industry in the section 114 ICR,
NOX emissions during startup and
shutdown are higher than during
normal operations. Due to the relatively
short duration of startup and shutdown
events (generally a few hours) compared
to normal steady-state operations, we
believe that a 30-day emission rate
calculated based on 30 consecutive
operating days will allow affected
sources to meet the 0.50 lb NOX/ton
acid at all times, including periods of
startup and shutdown. We request
comment on the use of a 30-day
emission rate calculated based on 30
consecutive operating days. Further, we
request comment on whether the
standard should be set with a
compliance period that is shorter (such
as 24 hours). For any comment
suggesting a shorter time period, the
comment should explain why that
different period is appropriate and
include data supporting the different
compliance period and how startup and
shutdown would be factored into a
shorter term limit.
If you believe that the EPA’s
conclusion is incorrect, or that the EPA
has failed to consider any relevant
information on this point, we encourage
you to submit comments. In particular,
we note that the general provisions in
Part 60 require facilities to keep records
of the occurrence and duration of any
startup, shutdown or malfunction (40
CFR 60.7(b)) and either report to the
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63883
EPA any period of excess emissions that
occurs during periods of startup,
shutdown or malfunction (40 CFR
60.7(c)(2)) or report that no excess
emissions occurred (40 CFR 60.7(c)(4)).
Thus, any comments that contend that
sources cannot meet the proposed
standard during startup and shutdown
periods should provide data and other
specifics supporting their claim.
Periods of Malfunction. Periods of
startup, normal operations, and
shutdown are all predictable and
routine aspects of a source’s operations.
However, by contrast, malfunction is
defined as a ‘‘sudden, infrequent, and
not reasonably preventable failure of air
pollution control and monitoring
equipment, process equipment or a
process to operate in a normal or usual
manner * * *’’ (40 CFR 60.2). The EPA
has determined that malfunctions
should not be viewed as a distinct
operating mode. Further, nothing in
section 111 or in case law requires that
the EPA anticipate and account for the
innumerable types of potential
malfunction events in setting emission
standards. See, Weyerhaeuser v. Costle,
590 F.2d 1011, 1058 (DC Cir. 1978) (‘‘In
the nature of things, no general limit,
individual permit, or even any upset
provision can anticipate all upset
situations. After a certain point, the
transgression of regulatory limits caused
by ‘uncontrollable acts of third parties,’
such as strikes, sabotage, operator
intoxication or insanity, and a variety of
other eventualities, must be a matter for
the administrative exercise of case-bycase enforcement discretion, not for
specification in advance by regulation.’’)
Further, it is reasonable to interpret
section 111 as not requiring the EPA to
account for malfunctions in setting
emissions standards. For example, we
note that section 111 provides that the
EPA will set standards of performance
which reflect the degree of emission
limitation achievable through ‘‘the
application of the best system of
emission reduction’’ that the EPA
determines is adequately demonstrated.
Applying the concept of ‘‘the
application of the best system of
emission reduction’’ to periods during
which a source is malfunctioning
presents significant difficulties. The
‘‘application of the best system of
emission reduction’’ is more
appropriately understood to include
operating in such a way as to avoid
malfunctions of their units.
Moreover, even if malfunctions were
considered a distinct operating mode,
we believe it would be impracticable to
take malfunctions into account in
setting CAA section 111 standards for
the nitric acid production units that will
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be covered in the proposed Subpart Ga.
As noted above, by definition,
malfunctions are sudden and
unexpected events and it would be
difficult to set a standard that takes into
account the myriad different types of
malfunctions that can occur across all
sources in the category. Moreover,
malfunctions can vary in frequency,
degree, and duration, further
complicating standard setting.
If the standard is stated as a 30-day
emission rate calculated based on 30
consecutive operating days, or some
other time period, we believe that
sources will be able to operate their
plants in compliance with the standard
even if they experience malfunctions.
Also, excess emissions from a nitric acid
production unit during a malfunction
can frequently be mitigated or avoided
by shutting the plant down if a key
component fails.
In the event that a source fails to
comply with the applicable CAA section
111 standards as a result of a
malfunction event, the EPA would
determine an appropriate response
based on, among other things, the good
faith efforts of the source to avoid
malfunctions and to minimize
emissions during malfunction periods,
including preventative and corrective
actions, as well as root cause analyses
to ascertain and rectify excess
emissions. The EPA would also
consider whether the source’s failure to
comply with the CAA section 111
standard was, in fact, ‘‘sudden,
infrequent, not reasonably preventable’’
and was not instead ‘‘caused in part by
poor maintenance or careless
operation.’’ 40 CFR 60.2 (definition of
malfunction).
Finally, the EPA recognizes that even
equipment that is properly designed and
maintained can sometimes fail and that
such failure can sometimes cause an
exceedance of the relevant emission
standard. (See, e.g., State
Implementation Plans: Policy Regarding
Excessive Emissions During
Malfunctions, Startup, and Shutdown
(Sept. 20, 1999); Policy on Excess
Emissions During Startup, Shutdown,
Maintenance, and Malfunctions (Feb.
15, 1983)). The EPA is therefore
proposing to add an affirmative defense
to civil penalties for exceedances of
emission limits that are caused by
malfunctions. See 40 CFR 60.71a
(defining ‘‘affirmative defense’’ to mean,
in the context of an enforcement
proceeding, a response or defense put
forward by a defendant, regarding
which the defendant has the burden of
proof, and the merits of which are
independently and objectively
evaluated in a judicial or administrative
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proceeding). We also are proposing
other regulatory provisions to specify
the elements that are necessary to
establish this affirmative defense; the
source must prove by a preponderance
of the evidence that it has met all of the
elements set forth in 60.74a. (See 40
CFR 22.24). The criteria ensure that the
affirmative defense is available only
where the event that causes an
exceedance of the emission limit meets
the narrow definition of malfunction in
40 CFR 60.2 (sudden, infrequent, not
reasonably preventable and not caused
by poor maintenance and/or careless
operation). For example, to successfully
assert the affirmative defense, the source
must prove by a preponderance of the
evidence that excess emissions ‘‘[w]ere
caused by a sudden, infrequent, and
unavoidable failure of air pollution
control and monitoring equipment,
process equipment, or a process to
operate in a normal or usual manner
* * *.’’ The criteria also are designed to
ensure that steps are taken to correct the
malfunction, to minimize emissions in
accordance with section 60.72a(b) and
to prevent future malfunctions. For
example, the source must prove by a
preponderance of the evidence that
‘‘[r]epairs were made as expeditiously as
possible when the applicable emission
limitations were being exceeded * * *’’
and that ‘‘[a]ll possible steps were taken
to minimize the impact of the excess
emissions on ambient air quality, the
environment and human health * * *.’’
In any judicial or administrative
proceeding, the Administrator may
challenge the assertion of the affirmative
defense and, if the respondent has not
met its burden of proving all of the
requirements in the affirmative defense,
appropriate penalties may be assessed
in accordance with section 113 of the
Clean Air Act (see also 40 CFR part
22.77).
B. How is the EPA proposing to revise
the testing and monitoring
requirements?
The current NSPS requires an initial
performance test, the installation of a
continuous NOX monitor and the
recording of the daily production rate
and hours of operations. We are
proposing that the new Subpart Ga also
require the installation, operation, and
maintenance of an exhaust gas flow rate
monitor. The capital cost of this monitor
is $39,000 and the total annualized cost
for this monitor for a new nitric acid
production unit is estimated to be
$15,000. The gas flow rate monitor
provides data on the volume of gas
emitted per unit of time, and this
information combined with the data
from the NOx monitor will result in
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more accurate measurements of the total
NOX being emitted.
Subpart G currently requires that
owners/operators of nitric acid
production units conduct an initial
performance test to demonstrate initial
compliance with the NOX emission
limit. The initial performance test is
based on three one-hour test runs for
NOX using manual testing methods;
specifically, Method 7 (or, alternatively,
Method 7A, 7B, 7C, or 7D) for NOX
concentration, and Method 2 for
volumetric flow rate (40 CFR 60,
appendix A–4). The nitric acid
production rate also must be determined
during the initial performance test so
that the emissions can be calculated in
terms of the emissions limit, lb NOX per
ton of acid produced (100 percent acid
basis). The current rule does not provide
specific procedures or criteria for
determining the production rate or
concentration.
The current NSPS also requires the
owner/operator to install, calibrate,
maintain and operate a CEMS for
measuring NOX concentration (40 CFR
60, appendix B, Performance
Specification 2) to demonstrate
continuing compliance. The owner/
operator is required to establish a
conversion factor expressed as lb NOX
per ton acid produced per ppm NOX by
comparing the CEMS data (ppm NOX)
obtained during the performance test to
the performance test results (lb NOX per
ton of acid). The conversion factor is
used to convert the CEMS concentration
data into units of the emissions standard
on an on-going basis. Subsequently, the
owner/operator must report periods of
excess emissions defined as any 3-hour
period during which the average nitric
acid emissions (arithmetic average of
three contiguous 1-hour periods) as
measured by the CEMS exceed the
emissions standard. The owner/operator
must reestablish the conversion factor
during any subsequent performance test.
As part of an ongoing effort to
improve compliance with various
federal air emission regulations, we are
proposing to require use of a continuous
compliance determination method
(CCDM) for NOX for nitric acid
production units subject to Subpart Ga.
The proposed CCDM is a continuous
emissions rate monitoring system
(CERMS) comprised of the NOX CEMS
and a continuous exhaust gas flow rate
monitoring system. The CERMS would
be required to meet the requirements of
performance specification 6 (40 CFR 60,
appendix B).
Performance Specification 6 (PS6)
provides performance criteria for the
flow rate monitoring system and
stipulates the overall performance
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criteria for the monitoring system in
terms of pollutant emissions rate (i.e., lb
NOX/hour). PS6 refers to the criteria of
performance specification 2 (PS2) for
the NOX CEMS. Extractive Fourier
Transform Infrared Spectroscopy (FTIR)
is capable of measuring NOX through
the requirements in Performance
Specification 15 (PS15). The proposed
regulation allows use of the FTIR CEMS
for determining compliance with the
NOX emissions limit, in lieu of a
monitor meeting the requirements of
PS2, at the discretion of the owner/
operator.
This proposed rule would require the
acid production rate to be determined
on a daily basis. The daily NOX
emissions rate measured by the CERMS
(lb) and the daily production rate (tons
of acid per day) are used to calculate the
emissions rates in units of the standard,
lbs NOX per ton of acid. This proposed
rule would provide options for
measuring the production rate and
stipulates a minimum accuracy
requirement for the measurement
equipment. This proposed rule also
requires that the concentration of the
produced nitric acid be tested daily.
We are proposing that nitric acid
production units subject to Subpart Ga
will not be subject to an opacity
standard; consequently no test or
monitoring method for opacity is
included in this proposed rule. Using
the nitric acid production rate and
concentration of the nitric acid, the NOX
concentration from the NOX CEMS, and
the flow rate from the proposed flow
monitor, the NOX emission rate in units
of the standard (lb NOX/ton acid) can be
determined at any point in time.
Therefore, an opacity standard is not
required as an additional method of
demonstrating compliance with a NOX
emission limit.
C. How is the EPA proposing to revise
the notification, reporting, and
recordkeeping requirements?
The only recordkeeping requirements
in the existing Subpart G are of daily
production rate and hours of operation.
The reporting requirements in the
existing subpart G include reports of
excess emissions and production rate.
The frequency of reporting is
semiannually as specified in 60.7(c).
Reporting and recordkeeping
requirements are being proposed as
separate sections for Subpart Ga.
Owners/operators subject to Subpart Ga
must keep records of all performance
tests and results; and dated daily
records of hours of operation, nitric acid
production rate, and nitric acid
concentration; explanations for periods
of noncompliance and corrective actions
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taken; span exceedances; and any
modifications to CERMS which could
affect the ability of the CERMS to
comply with applicable performance
specifications.
Owners/operators must report all
performance tests and results; dated
daily records of NOX emission rates that
exceed the standard, explanations for
periods of noncompliance and
corrective actions taken, span
exceedances, and any modifications to
CERMS which could affect the ability of
the CERMS to comply with applicable
performance specifications; and RATA
(i.e., from the initial certification) and
performance test data. The frequency of
reporting for Subpart Ga is the same as
for Subpart G.
V. Summary of Cost, Environmental,
Energy, and Economic Impacts of These
Proposed Standards
In setting standards, the CAA requires
us to consider alternative emission
control approaches, taking into account
the estimated costs as well as impacts
on energy, solid waste, and other effects.
A. What are the impacts for new nitric
acid production units?
We are presenting estimates of the
impacts for the proposed 40 CFR part
60, Subpart Ga that change the
performance standards for new nitric
acid production units. The cost,
environmental, and economic impacts
presented in this section are expressed
as incremental differences between the
impacts of nitric acid production units
complying with the proposed Subpart
Ga and the current NSPS requirements
of Subpart G (i.e., baseline). The impacts
are presented for future nitric acid
production units that commence
construction, reconstruction, or
modification over the 5 years following
promulgation of the revised NSPS. Costs
are based on 2nd quarter of 2010. The
analyses and the documents referenced
below can be found in Docket ID No.
EPA–HQ–OAR–2010–0750.
In order to determine the incremental
impacts of this proposed rule, we first
estimated the number of new nitric acid
production units that would become
subject to regulation during the five year
period after promulgation of subpart Ga.
Based on existing nitric acid production
units and estimated future growth rates,
6 new nitric acid production units are
expected to be required to meet the
nitric acid production demand in that
five year period. For further detail on
the methodology of these calculations,
see memorandum Impacts of Nitric Acid
NSPS Review—NOX, dated December
15, 2010, in Docket ID No. EPA–HQ–
OAR–2010–0750.
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The proposed Subpart Ga NOX
emission limit reflects the use of control
technologies currently in use by the
industry and reflects an adjustment of
the limit to more accurately reflect the
performance of these control
technologies. The current Subpart G
NSPS NOX emissions limit can be
achieved using a number of control
techniques including NSCR, SCR and
HPI. In many cases, the air pollution
control systems used to meet the current
NSPS could be used to meet the
proposed revised NOX emission limit
for future affected facilities. The
potential nationwide emission
reduction associated with lowering the
NOX limit from 3.0 to 0.50 lb NOX/ton
acid (100 percent acid basis) is
estimated to be 2,000 tons per year (tpy)
NOX. This potential emission reduction
may be overestimated because the
majority of control systems installed on
future affected facilities would likely
result in emissions at or below the
proposed emissions limit even in the
absence of these proposed revisions.
There are many existing nitric acid
production units currently meeting 0.50
lb NOX/ton acid. Therefore, there is no
increase in control costs of meeting the
proposed emission limit of 0.50 lb NOX/
ton acid for new nitric acid production
units compared to the control costs to
comply with subpart Ga. The only costs
incurred would be the installation of an
air flow monitor, which is discussed
below.
There are differences in notification,
testing, monitoring, reporting, and
recordkeeping (MRR) between Subpart
G and the new Subpart Ga that result in
increased costs. We are proposing the
use of a CERMS for monitoring
compliance with Subpart Ga. The
CERMS requires the installation of both
a continuous NOX monitor and
continuous exhaust gas flow rate
monitor. The current NSPS (subpart G)
requires only the installation of a
continuous NOX monitor. The
installation, operation, and maintenance
of an exhaust gas flow rate monitor will
increase the cost to nitric acid
production units over what would be
incurred to comply with subpart G. We
estimate that the total increase in
nationwide annual cost associated with
this proposed monitoring revision is
$90,110 for all six of the new
production units projected to be built
from 2011 to 2016.
The estimated nationwide
incremental 5-year NOX emissions
reductions and cost impacts for these
proposed revisions are summarized in
Table 2 of this preamble. The
methodology is detailed in the
memorandum Impacts of Nitric Acid
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NSPS Review—NOX, dated December
13, 2010 (updated July 27, 2011). The
overall cost effectiveness is about $45
per ton of NOX removed.
TABLE 2—NATIONAL INCREMENTAL NOX EMISSION REDUCTIONS AND COST IMPACTS FOR NEW NITRIC ACID PRODUCTION
UNITS SUBJECT TO PROPOSED STANDARDS UNDER 40 CFR PART 60, SUBPART GA (FIFTH YEAR AFTER PROMULGATION)
Total annualized
cost
[$1,000/yr]
Potential annual
NOX emission
reductions
[tons NOX/yr]
Revisions to NOX emission limit ......................................................................................
$0
2,000
$0.00
Revisions to MRR requirements ......................................................................................
90
Total ..........................................................................................................................
90
2,000
45
Proposed revisions for future affected facilities
B. What are the secondary impacts for
new nitric acid production units?
VI. Statutory and Executive Order
Reviews
Indirect or secondary air quality
impacts are impacts that would result
from the increased electricity usage
associated with the operation of control
devices (i.e., increased secondary
emissions of criteria pollutants from
power plants). Energy impacts consist of
the electricity and steam needed to
operate control devices and other
equipment that would be required
under this proposed rule. In most cases,
to comply with the current Subpart G
NOX emission limit or this Subpart Ga
NOX emission limit, the same control
system (SCR, NSCR, or HPI) would have
been installed. These proposed
revisions only require the addition of
exhaust gas flow monitors, which would
result in minimal secondary air impacts
or increase in overall energy demand.
A. Executive Order 12866: Regulatory
Planning and Review and Executive
Order 13563: Improving Regulation and
Regulatory Review
Under Executive Order 12866 (58 FR
51735, October 4, 1993), this action is a
significant regulatory action because it
could raise novel legal or policy issues.
Accordingly, the EPA submitted this
action to the Office of Management and
Budget for review under Executive
Order 12866 and any changes made in
response to OMB recommendations
have been documented in the docket for
this action.
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C. What are the economic impacts for
new nitric acid production units?
We performed an economic impact
analysis that estimates changes in prices
and output for nitric acid production
units nationally using the annual
compliance costs estimated for this
proposed rule. All estimates are for the
fifth year after promulgation since this
is the year for which the compliance
cost impacts are estimated. The impacts
to producers and consumers affected by
this proposed rule are slightly higher
product prices and slightly lower
outputs. Prices for products (nitric acid)
from affected plants should increase by
less than 0.07 percent for the fifth year.
The output of nitric acid should
decrease by less than 0.50 percent for
the fifth year. Hence, the overall
economic impact of this proposed NSPS
should be low on the affected industries
and their consumers. For more
information, please refer to the
Economic Impact Analysis for this
proposed rulemaking in the public
docket.
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B. Paperwork Reduction Act
The information collection
requirements in this proposed rule have
been submitted for approval to the
Office of Management and Budget
(OMB) under the Paperwork Reduction
Act, 44 U.S.C. 3501 et seq. The
Information Collection Request (ICR)
document prepared by the EPA has been
assigned the EPA ICR number [2445.01].
These proposed revisions to the
existing new source performance
standards for nitric acid production
units would add monitoring
requirements for future affected
facilities. We have revised the ICR for
the existing rule.
These proposed revisions to the new
source performance standards for nitric
acid production units for future affected
facilities include a change to the
emission limit and additional
continuous monitoring requirements.
The monitoring requirements include
installing a continuous flow monitor
and monitoring the nitric acid
concentration. These monitoring
requirements are in addition to a CEMS
for NOX concentration which is required
under the current subpart G. These
requirements are based on specific
requirements in Subpart Ga which are
mandatory for all operators subject to
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Potential cost
effectiveness
[$/ton NOX]
NSPS. These recordkeeping and
reporting requirements are specifically
authorized by section 114 of the CAA
(42 U.S.C. 7414). All information
submitted to the EPA pursuant to the
recordkeeping and reporting
requirements for which a claim of
confidentiality is made is safeguarded
according to the EPA policies set forth
in 40 CFR part 2, subpart B.
The annual burden for this
information collection averaged over the
first 3 years of this ICR is estimated to
total 968 labor-hours per year at a cost
of $91,808 per year. The annualized
capital costs are estimated at $19,288
per year. The annualized operation and
maintenance (O&M) costs are $23,488.
The total annualized capital and O&M
costs are $42,776 per year. Burden is
defined at 5 CFR 1320.3(b).
An agency may not conduct or
sponsor, and a person is not required to
respond to, a collection of information
unless it displays a currently valid OMB
control number. The OMB control
numbers for the EPA’s regulations in 40
CFR are listed in 40 CFR part 9.
To comment on the agency’s need for
this information, the accuracy of the
provided burden estimates, and any
suggested methods for minimizing
respondent burden, the EPA has
established a public docket for this rule,
which includes this ICR, under Docket
ID number EPA–HQ–OAR–2010–0750.
Submit any comments related to the ICR
to the EPA and OMB. See ADDRESSES
section at the beginning of this notice
for where to submit comments to the
EPA. Send comments to OMB at the
Office of Information and Regulatory
Affairs, Office of Management and
Budget, 725 17th Street, NW.,
Washington, DC 20503, Attention: Desk
Office for the EPA. Since OMB is
required to make a decision concerning
the ICR between 30 and 60 days after
October 14, 2011, a comment to OMB is
best assured of having its full effect if
OMB receives it by November 14, 2011.
The final rule will respond to any OMB
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or public comments on the information
collection requirements contained in
this proposal.
on small entities and welcome
comments on issues related to such
impacts.
C. Regulatory Flexibility Act
The Regulatory Flexibility Act (RFA)
generally requires an agency to prepare
a regulatory flexibility analysis of any
rule subject to notice and comment
rulemaking requirements under the
Administrative Procedure Act or any
other statute unless the agency certifies
that this rule will not have a significant
economic impact on a substantial
number of small entities. Small entities
include small businesses, small
organizations, and small governmental
jurisdictions.
For purposes of assessing the impacts
of this rule on small entities, small
entity is defined as: (1) A small business
as defined by the Small Business
Administration’s regulations at 13 CFR
121.201; (2) a small governmental
jurisdiction that is a government of a
city, county, town, school district or
special district with a population of less
than 50,000; and (3) a small
organization that is any not-for-profit
enterprise which is independently
owned and operated and is not
dominant in its field.
After considering the economic
impacts of this proposed rule on small
entities, I certify that this action will not
have a significant economic impact on
a substantial number of small entities.
This certification is based on the
economic impact of this action to all
affected small entities. Only four small
entities may be impacted by this
proposed rule. We estimate that all
affected small entities will have
annualized costs of less than 0.3 percent
of their sales. We conclude that there is
no significant economic impact on a
substantial number of small entities
(SISNOSE) for this rule.
For more information on the small
entity impacts associated with this
proposed rule, please refer to the
Economic Impact and Small Business
Analyses in the public docket. Although
this proposed rule would not have a
significant economic impact on a
substantial number of small entities, the
EPA nonetheless tried to reduce the
impact of this proposed rule on small
entities. When developing the revised
standards, the EPA took special steps to
ensure that the burdens imposed on
small entities were minimal. The EPA
conducted several meetings with
industry trade associations to discuss
regulatory options and the
corresponding burden on industry, such
as recordkeeping and reporting. We
continue to be interested in the
potential impacts of the proposed rule
D. Unfunded Mandates Reform Act
This rule does not contain a federal
mandate that may result in expenditures
of $100 million or more for state, local,
and tribal governments, in the aggregate,
or to the private sector in any one year.
This rule is not expected to impact state,
local, or tribal governments. The
nationwide annualized cost of this
proposed rule for affected industrial
sources is $90,010/yr. Thus, this rule is
not subject to the requirements of
sections 202 and 205 of the Unfunded
Mandates Reform Act (UMRA).
This rule is also not subject to the
requirements of section 203 of UMRA
because it contains no regulatory
requirements that might significantly or
uniquely affect small governments. This
rule will not apply to such governments
and will not impose any obligations
upon them.
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E. Executive Order 13132, Federalism
This action does not have federalism
implications. It will not have substantial
direct effects on the states, on the
relationship between the national
government and the states, or on the
distribution of power and
responsibilities among the various
levels of government, as specified in
Executive Order 13132. Nitric acid
plants are privately owned companies
and there will be no direct impact on
states and other federal offices. Thus,
Executive Order 13132 does not apply
to this proposed rule. In the spirit of
Executive Order 13132, and consistent
with the EPA policy to promote
communications between the EPA and
state and local governments, the EPA
specifically solicited comment on this
proposed rule from state and local
officials.
F. Executive Order 13175, Consultation
and Coordination With Indian Tribal
Governments
This action does not have tribal
implications, as specified in Executive
Order 13175 (65 FR 67249, November 9,
2000). It will not have substantial direct
effects on tribal governments, on the
relationship between the federal
government and Indian tribes, or on the
distribution of power and
responsibilities between the federal
government and Indian tribes, as
specified in Executive Order 13175.
This proposed rule imposes
requirements on owners and operators
of nitric acid production units and not
tribal governments. We do not know of
any nitric acid production units owned
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63887
or operated by Indian tribal
governments. However, if there are any,
the effect of this proposed rule on
communities of tribal governments
would not be unique or
disproportionate to the effect on other
communities. Thus, Executive Order
13175 does not apply to this action. The
EPA specifically solicits additional
comment on this proposed rule from
tribal officials.
G. Executive Order 13045: Protection of
Children From Environmental Health
and Safety Risks
The EPA interprets Executive Order
13045 (62 FR 19885, April 22, 1997) as
applying to those regulatory actions that
concern health or safety risks, such that
the analysis required under section 5–
501 of the Executive Order has the
potential to influence the regulation.
This action is not subject to Executive
Order 13045 because it is based solely
on technology performance.
H. Executive Order 13211: Actions
Concerning Regulations That
Significantly Affect Energy Supply,
Distribution, or Use
This action is not subject to Executive
Order 13211 (66 FR 28355 (May 22,
2001)), because it is not a significant
regulatory action under Executive Order
12866.
I. National Technology Transfer and
Advancement Act
Section 12(d) of the National
Technology Transfer and Advancement
Act of 1995 (‘‘NTTAA’’), Public Law No.
104–113 (15 U.S.C. 272 note), directs
the EPA to use voluntary consensus
standards (VCS) in its regulatory
activities unless to do so would be
inconsistent with applicable law or
otherwise impractical. VCS are
technical standards (e.g., materials
specifications, test methods, sampling
procedures, business practices) that are
developed or adopted by voluntary
consensus standards bodies. NTTAA
directs the EPA to provide Congress,
through OMB, explanations when the
Agency decides not to use available and
applicable VCS.
This proposed rulemaking involves
technical standards. The EPA proposes
to use: ASTM D6348–03, Standard Test
Method for Determination of Gaseous
Compounds by Extractive Direct
Interface Fourier Transform Infrared
(FTIR) Spectroscopy, and ASTM E1584,
Standard Test Method for Assay of
Nitric Acid, which have been
incorporated by reference.
The EPA welcomes comments on this
aspect of the proposed rulemaking and
specifically invites the public to identify
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potentially applicable voluntary
consensus standards and to explain why
such standards should be used in this
regulation.
J. Executive Order 12898: Federal
Actions To Address Environmental
Justice in Minority Populations and
Low-Income Populations
Executive Order 12898 (59 FR 7629,
February 16, 1994) establishes federal
executive policy on environmental
justice. Its main provision directs
federal agencies, to the greatest extent
practicable and permitted by law, to
make environmental justice part of their
mission by identifying and addressing,
as appropriate, disproportionately high
and adverse human health or
environmental effects of their programs,
policies, and activities on minority
populations and low-income
populations in the United States.
The EPA has determined that this
proposed rule will not have
disproportionately high and adverse
human health or environmental effects
on minority or low-income populations
because it increases the level of
environmental protection for all affected
populations without having any
disproportionately high and adverse
human health or environmental effects
on any population, including any
minority or low-income population. The
EPA has also determined that a
proximity-based demographic study
comparing populations in closest
proximity to the regulated sources to the
general population is not appropriate for
this rulemaking due to lack of pollutants
with localized effects.
List of Subjects in 40 CFR Part 60
Environmental protection,
Administrative practice and procedure,
Air pollution control, Intergovernmental
relations, Reporting and recordkeeping
requirements, Incorporation by
reference.
Dated: September 30, 2011.
Lisa P. Jackson,
Administrator.
§ 60.17
Incorporations by reference.
*
*
*
*
*
(a) * * *
(82) ASTM D6348–03, Standard Test
Method for Determination of Gaseous
Compounds by Extractive Direct
Interface Fourier Transform Infrared
(FTIR) Spectroscopy, IBR approved for
§ 60.73a(f)(2) of subpart Ga, table 7 of
subpart IIII of this part, and table 2 of
subpart JJJJ of this part.
*
*
*
*
*
(93) ASTM E1584–00(2005)e1,
Standard Test Method for Assay of
Nitric Acid, IBR approved for
§ 60.73a(b)(2) of subpart Ga.
*
*
*
*
*
3. Section 60.70 is amended by
revising paragraph (b) to read as follows:
§ 60.70 Applicability and designation of
affected facility.
*
*
*
*
*
(b) Any facility under paragraph (a) of
this section that commences
construction or modification after
August 17, 1971, and on or before
October 14, 2011 is subject to the
requirements of Subpart G. Any facility
that commences construction or
modification after October 14, 2011 is
subject to Subpart Ga.
*
*
*
*
*
4. Add Subpart Ga to read as follows:
Subpart Ga—Standards of
Performance for Nitric Acid Plants for
Which Construction, Reconstruction,
or Modification Commenced After
October 14, 2011
Sec.
60.70a Applicability and designation of
affected facility.
60.71a Definitions.
60.72a Standards.
60.73a Emissions testing and monitoring.
60.74a Affirmative Defense for Exceedance
of Emission Limit During Malfunction.
60.75a Calculations.
60.76a Recordkeeping.
60.77a Reporting.
Subpart Ga—Standards of
Performance for Nitric Acid Plants for
Which Construction, Reconstruction,
or Modification Commenced After
October 14, 2011
PART 60—[AMENDED]
tkelley on DSK3SPTVN1PROD with PROPOSALS
For the reasons stated in the
preamble, title 40, chapter I, of the Code
of Federal Regulations is amended as
follows:
§ 60.70a Applicability and designation of
affected facility.
1. The authority citation for part 60
continues to read as follows:
Authority: 42 U.S.C. 7401.
Subpart A—[Amended]
2. Section 60.17 is amended by
revising paragraph (a)(82) and adding
paragraph (a)(93) to read as follows:
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(a) The provisions of this subpart are
applicable to each nitric acid
production unit, which is the affected
facility.
(b) This subpart applies to any nitric
acid production unit that commences
construction or modification on or after
October 14, 2011.
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§ 60.71a
Definitions.
As used in this subpart, all terms not
defined herein shall have the meaning
given them in the Act and in subpart A
of this part.
(a) Affirmative defense means, in the
context of an enforcement proceeding, a
response or defense put forward by a
defendant, regarding which the
defendant has the burden of proof, and
the merits of which are independently
and objectively evaluated in a judicial
or administrative proceeding.
(b) Nitric acid production unit means
any facility producing weak nitric acid
by either the pressure or atmospheric
pressure process.
(c) Operating day means a 24-hour
period beginning at 12:00 a.m. during
which the nitric acid production unit at
any time during this period.
(d) Weak nitric acid means acid
which is 30 to 70 percent in strength.
§ 60.72a
Standards.
(a) Nitrogen oxides. On and after the
date on which the performance test
required to be conducted by § 60.73a(a)
is completed, you may not discharge
into the atmosphere from any affected
facility any gases which contain NOX,
expressed as NO2, in excess of 0.50
pounds (lb) per ton of nitric acid
produced, as a 30-day emission rate
calculated based on 30 consecutive
operating days, the production being
expressed as 100 percent nitric acid.
The emission standard applies at all
times.
(b) General Duty to minimize
emissions. At all times, the owner or
operator must operate and maintain any
affected source, including associated air
pollution control equipment and
monitoring equipment, in a manner
consistent with safety and good air
pollution control practices for
minimizing emissions. Determination of
whether such operation and
maintenance procedures are being used
will be based on information available
to the Administrator which may
include, but is not limited to,
monitoring results, review of operation
and maintenance procedures, review of
operation and maintenance records, and
inspection of the source.
§ 60.73a Emissions testing and
monitoring.
(a) Nitric acid production monitoring.
(1) For any affected facility, you must
determine the daily nitric acid
production parameters (production rate
and concentration) by installing,
calibrating, maintaining, and operating a
permanent monitoring system (e.g.,
weigh scale, volume flow meter, mass
flow meter, tank volume) to measure
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and record the weight rates of nitric acid
produced in tons per day. You must
verify that each component of the
monitoring system has an accuracy and
precision of no more than ±5 percent of
full scale.
(2) You may analyze product
concentration via titration or by
determining the temperature and
specific gravity of the nitric acid. You
may also use ASTM E1584–00(2005)e1
(incorporated by reference, see § 60.17),
for determining the concentration of
nitric acid in percent. You must
determine product concentration daily.
(3) For any affected facility, you must
use the acid concentration to express
the daily nitric acid production as 100
percent nitric acid.
(4) For any affected facility, you must
record the daily nitric acid production,
expressed as 100 percent nitric acid,
and the hours of operation.
(b) Nitrogen oxides continuous
emissions monitoring system. (1) You
must install, calibrate, maintain, and
operate a continuous emission rate
monitoring system (CERMS) for
measuring and recording the mass
emissions of NOX in accordance with
the provisions of 60.13 and Performance
Specifications 2 and 6 of appendix B of
this part. The CERMS must consist of
equipment for measuring NOX
concentration and stack gas volumetric
flow rate monitoring equipment for
measuring the volumetric flow rate and
for calculating and reporting hourly and
daily NOX mass emissions rates in units
of lb/hour and lb NOX/ton of 100%
nitric acid.
(2) As applicable, use a span value, as
defined in Performance Specification 2
§ 3.11, for all NOX concentration
monitoring equipment equal to 125
percent of the maximum estimated NOX
emission concentration.
(3) You must conduct performance
evaluations of the NOX CERMS
according to the requirements in
§ 60.13(c) and Performance
Specifications 2 and 6 of appendix B of
this part. For conducting the relative
accuracy evaluations, per § 8.4 of the
Performance Specification 2, use either
EPA Reference Method 7, 7A, 7C, 7D, or
7E of appendix A–4 of this part; EPA
Reference Method 320 of appendix A of
part 63 of this chapter; or ASTM D6348–
03 (incorporated by reference, see
§ 60.17).
(4) If you use EPA Reference Method
7E of Appendix A–4 of this part, you
must mitigate loss of NO2 in water
according to the requirements in
paragraphs (a)(4)(i), (ii), or (iii) of this
section and verify performance by
conducting the system bias checks
required in § 8 of EPA Reference
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Method 7E of appendix A–4 of this part
according to (b)(4)(iv) of this section, or
follow the dynamic spike procedure
according to paragraph (b)(4)(v) of this
section.
(i) For a wet-basis measurement
system, you must measure and report
temperature of sample line and
components (up to analyzer inlet) to
demonstrate that the temperatures
remain above the sample gas dew point
at all times during the sampling.
(ii) You may use a dilution probe to
reduce the dew point of the sample gas.
(iii) You may use a refrigerated-type
condenser or similar device (e.g.,
permeation dryer) to remove condensate
continuously from sample gas while
maintaining minimal contact between
condensate and sample gas.
(iv) If your analyzer measures nitric
oxide (NO) and nitrogen dioxide (NO2)
separately, you must use both NO and
NO2 calibration gases. Otherwise, you
must substitute NO2 calibration gas for
NO calibration gas in the performance of
system bias checks.
(v) You must conduct dynamic
spiking according to § 16.1 in EPA
Reference Method 7E of appendix A–4
of this part using NO2 as the spike gas.
(5) You must use stack gas flow rate
measurement equipment with a full
scale output of at least 125 percent of
the maximum expected exhaust
volumetric flow rate (see § 8 of
Performance Specification 6, Appendix
B, of this part).
(d) CERMS Quality Assurance and
Quality Control.
(1) The CERMS must comply with the
quality assurance requirements in
Procedure 1 of Appendix F of this part.
You must use cylinder gas audits to
fulfill the quarterly auditing
requirement at Appendix F, Procedure
1, § 5.1 of this part only on the NOX
concentration measurement equipment.
You must conduct relative accuracy
testing to provide for calculating the
relative accuracy for RATA and RAA
determinations in units of lb/hour and
lb NOX/ton nitric acid.
(2) You must determine daily
calibration drift assessments separately
for each analyzer in terms of its specific
measurement. You must perform the
daily assessments in accordance with
the procedures specified in §§ 8.1 and
13.1 of Performance Specification 6 of
appendix B of this part.
(3) Should you apply an FTIR CEMS
meeting the requirements of
Performance Specification 15, Appendix
B of this part, you must replace the
Relative Accuracy Test Audit
requirements of Procedure 1 of
appendix F of this part with the
validation requirements and criteria of
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§§ 11.1.1 and 12.0 of Performance
Specification 15 of appendix B of this
part.
(e) For each CERMS, including NOX
concentration measurement, volumetric
flow rate measurement, and nitric acid
production measurement equipment,
you must meet the requirements in
paragraphs (e)(1) through (3) of this
section.
(1) You must operate the CERMS and
collect data at all required intervals at
all times the affected source is operating
except for periods of monitoring system
malfunctions or out-of-control periods
as defined in Appendix F, §§ 4 and 5,
repairs associated with monitoring
system malfunctions or out-of-control
periods, and required monitoring
system quality assurance or quality
control activities including, as
applicable, calibration checks and
required zero and span adjustments. A
monitoring system malfunction is any
sudden, infrequent, not reasonably
preventable failure of the monitoring
system to provide valid data.
Monitoring system failures that are
caused in part by poor maintenance or
careless operation are not malfunctions.
You are required to affect monitoring
system repairs in response to
monitoring system malfunctions or outof-control periods, and to return the
monitoring system to operation as
expeditiously as practicable.
(2) You may not use data recorded
during monitoring system malfunctions
or out-of-control periods, repairs
associated with monitoring system
malfunctions or out-of-control periods,
or required monitoring system quality
assurance or control activities in
calculations used to report emissions or
operating levels. You must use all the
data collected during all other periods
in calculating emissions and the status
of compliance with the applicable
emissions limit in accordance with
§ 60.72a(a).
(3) Except for periods of monitoring
system malfunctions or out-of-control
periods, repairs associated with
monitoring system malfunctions or outof-control periods, and required
monitoring system quality assurance or
quality control activities including, as
applicable, calibration checks and
required zero and span adjustments,
failure to collect required data is a
violation of the monitoring
requirements.
(f) Initial Performance Testing. You,
as the owner or operator of a new unit,
must conduct an initial performance test
to demonstrate compliance with the
NOX emissions limit under § 60.72a(a)
beginning in the calendar month
following initial certification of the NOX
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§ 60.74a Affirmative Defense for
Exceedance of Emission Limit During
Malfunction.
In response to an action to enforce the
standards set forth in paragraph
§ 60.72a, you may assert an affirmative
defense to a claim for civil penalties for
exceedances of such standards that are
caused by malfunction, as defined at 40
CFR 60.2. Appropriate penalties may be
assessed, however, if you fail to meet
your burden of proving all of the
requirements in the affirmative defense.
The affirmative defense shall not be
available for claims for injunctive relief.
(a) To establish the affirmative
defense in any action to enforce such a
limit, you must timely meet the
notification requirements in paragraph
(b) of this section, and must prove by a
preponderance of evidence that:
(1) The excess emissions:
(i) Were caused by a sudden,
infrequent, and unavoidable failure of
air pollution control and monitoring
equipment, process equipment, or a
process to operate in a normal or usual
manner, and
(ii) Could not have been prevented
through careful planning, proper design
or better operation and maintenance
practices; and
(iii) Did not stem from any activity or
event that could have been foreseen and
avoided, or planned for; and
(iv) Were not part of a recurring
pattern indicative of inadequate design,
operation, or maintenance; and
(2) Repairs were made as
expeditiously as possible when the
applicable emission limitations were
being exceeded. Off-shift and overtime
labor were used, to the extent
practicable to make these repairs; and
(3) The frequency, amount and
duration of the excess emissions
(including any bypass) were minimized
to the maximum extent practicable
during periods of such emissions; and
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(4) If the excess emissions resulted
from a bypass of control equipment or
a process, then the bypass was
unavoidable to prevent loss of life,
personal injury, or severe property
damage; and
(5) All possible steps were taken to
minimize the impact of the excess
emissions on ambient air quality, the
environment and human health; and
(6) All emissions monitoring and
control systems were kept in operation
if at all possible consistent with safety
and good air pollution control practices;
and
(7) All of the actions in response to
the excess emissions were documented
by properly signed, contemporaneous
operating logs; and
(8) At all times, the facility was
operated in a manner consistent with
good practices for minimizing
emissions; and
(9) A written root cause analysis has
been prepared, the purpose of which is
to determine, correct, and eliminate the
primary causes of the malfunction and
the excess emissions resulting from the
malfunction event at issue. The analysis
shall also specify, using best monitoring
methods and engineering judgment, the
amount of excess emissions that were
the result of the malfunction.
(b) Notification. The owner or
operator of the facility experiencing an
exceedance of its emission limit(s)
during a malfunction shall notify the
Administrator by telephone or facsimile
(FAX) transmission as soon as possible,
but no later than two business days after
the initial occurrence of the
malfunction, if it wishes to avail itself
of an affirmative defense to civil
penalties for that malfunction. The
owner or operator seeking to assert an
affirmative defense shall also submit a
written report to the Administrator
within 45 days of the initial occurrence
of the exceedance of the standard in
§ 60.72a to demonstrate, with all
necessary supporting documentation,
that it has met the requirements set forth
in paragraph (a) of this section. The
owner or operator may seek an
extension of this deadline for up to 30
additional days by submitting a written
request to the Administrator before the
expiration of the 45 day period. Until a
request for an extension has been
approved by the Administrator, the
owner or operator is subject to the
requirement to submit such report
within 45 days of the initial occurrence
of the exceedance.
§ 60.75a
Calculations.
(a) The 30-day rolling NOX emission
rate is calculated as the sum of all daily
NOX mass emissions recorded by the
PO 00000
Frm 00045
Fmt 4702
Sfmt 4702
CERMS for 30 consecutive operating
days divided by the sum of nitric acid
production for these 30 consecutive
operating days. Calculate and record the
daily mass emissions of NOX according
to the procedures in paragraphs (a)(1)
through (4) of this section.
(1) You must calculate the daily mass
emissions according to Equation 1:
Where:
Md = daily mass emissions of NOX as NO2,
lb NOX.
Ci = concentration of NOX for hour i, lb/
standard cubic foot (scf).
Qi = volumetric flow rate of effluent gas for
hour i, scf/hour.
n = number of operating hours in the
operating day.
(2) For any operating day where
monitoring data are only available for
part of the hours where nitric acid is
produced during that day due to CERMS
malfunctions, out-of-control periods, or
repairs associated with monitoring
system malfunctions or out-of-control
periods, you must calculate Md for the
periods where monitoring data are
available using Equation 1 in (a)(1)
above, and then adjust upwards overall
operating hours on a pro rata basis.
(3) You must ensure appropriate
corrections for moisture are made when
measuring flow rates.
(4) Following each calendar day on
which the affected facility was operated,
you must calculate the 30-day NOX
emission rate according to Equation 2:
Where:
E30-day = emission rate of NOX as NO2
calculated based on 30 consecutive
operating days, lb NOX/ton of 100
percent nitric acid.
Md = daily mass emissions of NOX as NO2 for
operating day d, lb NOX
Pd = daily nitric acid production for
operating day d, tons of 100 percent
nitric acid.
m = number of days in the 30-day
compliance period for which CERMS
data is available.
§ 60.76a
Recordkeeping.
(a) For the NOX emissions rate, you
must keep records of the performance
test data from the initial and subsequent
performance tests and from the
performance evaluation of the
continuous monitors.
E:\FR\FM\14OCP1.SGM
14OCP1
EP14OC11.001
and flow rate monitoring CEMS. The
initial performance test consists of
collection of hourly NOX average
concentration, mass flow rate (SCFH)
recorded with the certified NOX
concentration and flow rate CEMS and
the corresponding acid generation (tons)
data for all of the hours of operation for
the first 30 days beginning on the first
day of the first month following
completion of the CEMS installation
and certification as described above.
You must assure that the CERMS meets
all of the data quality assurance
requirements as per § 60.13 and
appendix F, procedure 1 of this part and
you must use the data from the CERMS
for this compliance determination.
EP14OC11.000
63890
Federal Register / Vol. 76, No. 199 / Friday, October 14, 2011 / Proposed Rules
(b) You must maintain records of the
following information for each 30 day
period:
(1) Hours of operation.
(2) Production rate of nitric acid,
expressed as 100 percent nitric acid.
(3) NOX mass emissions.
(c) You must maintain records of the
following time periods:
(1) Times when you were not in
compliance with the emissions
standards.
(2) Times when the pollutant
concentration exceeded full span of the
NOX pollutant monitoring equipment.
(3) Times when the volumetric flow
rate exceeded the high value of the
volumetric flow rate monitoring
equipment.
(d) You must maintain records of the
reasons for any periods of
noncompliance and description of
corrective actions taken.
(e) You must maintain records of any
modifications to CERMS which could
affect the ability of the CERMS to
comply with applicable performance
specifications.
(f) For each malfunction, you must
maintain records of the following
information:
(1) Records of the occurrence and
duration of each malfunction of
operation (i.e., process equipment) or
the air pollution control and monitoring
equipment.
(2) Records of actions taken during
periods of malfunction to minimize
emissions in accordance with section
60.72a(b), including corrective actions
to restore malfunctioning process and
air pollution control and monitoring
equipment to its normal or usual
manner of operation.
tkelley on DSK3SPTVN1PROD with PROPOSALS
§ 60.77a
(a) The performance test data from the
initial and subsequent performance tests
and from the performance evaluations of
the continuous monitors must be
submitted to the Administrator at the
appropriate address as shown in 40 CFR
60.4.
(b) The following information must be
reported to the Administrator for each
30 day period where you were not in
compliance with the emissions
standard:
(1) Time period.
(2) NOX emission rates (lb/ton of acid
produced).
(3) Reasons for noncompliance with
the emissions standard; and description
of corrective actions taken.
(c) You must also report the following
whenever they occur:
(1) Times when the pollutant
concentration exceeded full span of the
NOX pollutant monitoring equipment.
16:49 Oct 13, 2011
[FR Doc. 2011–26089 Filed 10–13–11; 8:45 am]
BILLING CODE 6560–50–P
DEPARTMENT OF HEALTH AND
HUMAN SERVICES
42 CFR Part 71
[Docket No. CDC–2011–0007]
RIN 0920–AA37
Reporting.
VerDate Mar<15>2010
(2) Times when the volumetric flow
rate exceeded the high value of the
volumetric flow rate monitoring
equipment.
(d) You must report any modifications
to CERMS which could affect the ability
of the CERMS to comply with
applicable performance specifications.
(e) As of December 31, 2011 and
within 60 days after the date of
completing each performance
evaluation or test required under this
subpart, you must submit the relative
accuracy test audit data and
performance test data by successfully
submitting the data electronically to
EPA’s Central Data Exchange (CDX) by
using the Electronic Reporting Tool
(ERT) (see https://www.epa.gov/ttn/chief/
ert/ert_tool.html/).
(f) If a malfunction occurred during
the reporting period, you must submit a
report that contains the following:
(1) The number, duration, and a brief
description for each type of malfunction
which occurred during the reporting
period and which caused or may have
caused any applicable emission
limitation to be exceeded.
(2) A description of actions taken by
an owner or operator during a
malfunction of an affected source to
minimize emissions in accordance with
60.72a(b), including actions taken to
correct a malfunction.
Jkt 226001
Foreign Quarantine; Etiological
Agents, Hosts, and Vectors
Centers for Disease Control and
Prevention (CDC), Department of Health
and Human Services (HHS).
ACTION: Notice of proposed rulemaking.
AGENCY:
The Centers for Disease
Control and Prevention (CDC) within
the U.S. Department of Health and
Human Services (HHS) is issuing this
Notice of Proposed Rulemaking (NPRM)
to revise the regulations that cover the
importation of etiological agents and the
hosts and vectors of human disease. The
changes are proposed to improve CDC’s
ability to prevent the introduction,
transmission, or spread of
communicable diseases into the United
States.
DATES: To be assured consideration,
comments must be received on or before
SUMMARY:
PO 00000
Frm 00046
Fmt 4702
Sfmt 4702
63891
December 13, 2011. Comments received
after the close of the comment period
will be considered to the fullest extent
possible.
You may submit comments,
identified by Regulatory Information
Number (RIN) 0920–AA37 in the
heading of this document, by any of the
following methods:
• Federal eRulemaking Portal: https://
www.regulations.gov. Follow the
instructions for submitting comments.
• E-mail: SAPcomments@cdc.gov.
Please include the RIN number in the
subject line of the message.
• Fax: 404–718–2093.
• Mail: Division of Select Agents and
Toxins, Centers for Disease Control and
Prevention, ATTN: Importation
Regulations, 1600 Clifton Road, NE., MS
A–46, Atlanta, Georgia 30333.
• Hand Delivery/Courier: Division of
Select Agents and Toxins, Centers for
Disease Control and Prevention, ATTN:
Importation Regulations, 1600 Clifton
Road, NE., MS A–46, Atlanta, Georgia
30333.
Instructions: All submissions received
must include the agency name and RIN
for this rulemaking. All relevant
comments received will be posted
without change to https://
www.regulations.gov, including any
personal information provided.
Docket: For access to the docket to
read background documents or
comments received or to download an
electronic version of the NPRM, go to
https://www.regulations.gov. Comments
will be available for public inspection
Monday through Friday, except for legal
holidays, from 9 a.m. until 5 p.m. at
1600 Clifton Road, NE., Atlanta, GA
30333. Please call ahead to 1–866–694–
4867 and ask for a representative in the
Division of Select Agents and Toxins to
schedule your visit. Our general policy
for comments and other submissions
from members of the public is to make
these submissions available for public
viewing on the Internet as they are
received and without change.
ADDRESSES:
FOR FURTHER INFORMATION CONTACT:
Robbin Weyant, PhD, Director, Division
of Select Agents and Toxins, Centers for
Disease Control and Prevention, 1600
Clifton Road, NE., MS A–46, Atlanta,
GA 30333. Telephone: 404–718–2000.
The
Preamble to this notice of proposed
rulemaking is organized as follows:
SUPPLEMENTARY INFORMATION:
I. Background
A. HHS/CDC Authority
II. Proposed Changes to 42 CFR 71.54
A. Section Heading & Definitions
B. Biosafety and Inspection Provisions
E:\FR\FM\14OCP1.SGM
14OCP1
Agencies
[Federal Register Volume 76, Number 199 (Friday, October 14, 2011)]
[Proposed Rules]
[Pages 63878-63891]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: 2011-26089]
-----------------------------------------------------------------------
ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 60
[EPA-HQ-OAR-2010-0750; FRL-9477-1]
RIN 2060-AQ10
New Source Performance Standards Review for Nitric Acid Plants
AGENCY: Environmental Protection Agency (EPA).
ACTION: Proposed rule.
-----------------------------------------------------------------------
SUMMARY: The EPA is proposing revisions to the new source performance
standards (NSPS) for nitric acid plants. Nitric acid plants include one
or more nitric acid production units. These proposed revisions include
a change to the nitrogen oxides (NOX) emission limit, which
applies to each nitric acid production unit commencing construction,
modification, or reconstruction after October 14, 2011. These proposed
revisions will also include additional testing and monitoring
requirements.
DATES: Comments must be received on or before November 28, 2011. Under
the Paperwork Reduction Act, comments on the information collection
provisions are best assured of having full effect if the Office of
Management and Budget (OMB) receives a copy of your comments on or
before November 14, 2011.
ADDRESSES: Submit your comments, identified by Docket ID No. EPA-HQ-
OAR-2010-0750, by one of the following methods:
Federal eRulemaking Portal: https://www.regulations.gov.
Follow the instructions for submitting comments.
Agency Web site: https://www.epa.gov/oar/docket.html.
Follow the instructions for submitting comments on the EPA Air and
Radiation Docket Web site.
E-mail: a-and-r-Docket@epa.gov. Include EPA-HQ-OAR-2010-
0750 in the subject line of the message.
Fax: Fax your comments to: (202) 566-9744, Attention
Docket ID No. EPA-HQ-OAR-2010-0750.
Mail: Send your comments to: EPA Docket Center (EPA/DC),
Environmental Protection Agency, Mailcode: 2822T, 1200 Pennsylvania
Ave., NW., Washington, DC 20460, Attention: Docket ID No. EPA-HQ-OAR-
2010-0750. Please include a total of two copies. In addition, please
mail a copy of your comments on the information collection provisions
to the Office of Information and Regulatory Affairs, Office of
Management and Budget (OMB), Attn: Desk Officer for EPA, 725 17th St.,
NW., Washington, DC 20503.
Hand Delivery or Courier: In person or by courier, deliver
comments to EPA Docket Center, EPA West, Room 3334, 1301 Constitution
Ave., NW., Washington, DC 20460. Such deliveries are only accepted
during the Docket Center's normal hours of operation, (8:30 a.m. to
4:30 p.m., Monday through Friday, excluding legal holidays), and
special arrangements should be made for deliveries of boxed
information. Please include a total of two copies.
Instructions: All submissions received must include the agency name
and docket number or Regulatory Information Number (RIN) for this
rulemaking. All comments received will be posted without change to
https://www.regulations.gov, including any personal information
provided, unless the comment includes information claimed to be
confidential business information (CBI) or other information whose
disclosure is restricted by statute. Do not submit information that you
consider to be CBI or otherwise protected through https://www.regulations.gov or e-mail. The https://www.regulations.gov Web site
is an ``anonymous access'' system, which means that the EPA will not
know your identity or contact information unless you provide it in the
body of your comment. If you send an e-mail comment directly to the EPA
without going through https://www.regulations.gov, your e-mail address
will be automatically captured and included as part of the comment that
is placed in the public docket and will be made available on the
Internet. If you submit an electronic comment, the EPA recommends that
you include your name and other contact information in the body of your
comment and with any disk or CD-ROM you submit. If EPA cannot read your
comment due to technical difficulties and cannot contact you for
clarification, EPA may not be able to consider your comment. Electronic
files should avoid the use of special characters, any form of
encryption, and be free of any defects or viruses. For detailed
instructions on submitting comments and additional information on the
rulemaking process, see the ``General Information'' heading of the
SUPPLEMENTARY INFORMATION section of this document.
Docket: All documents in the docket are listed in the https://www.regulations.gov index. Although listed in the index, some
information is not publicly available (e.g., CBI or other information
whose disclosure is restricted by statute). Certain other material,
such as copyrighted material, will be publicly available only in hard
copy form. Publicly available docket materials are available either
electronically in https://www.regulations.gov or in hard copy at the EPA
Docket Center, Public Reading Room, EPA West, Room 3334, 1301
Constitution Ave., NW., Washington, DC. The Public Reading Room is open
from 8:30 a.m. to 4:30 p.m., Monday through Friday, excluding legal
holidays. The telephone number for the Public Reading Room is (202)
566-1744, and the telephone number for the Air Docket is (202) 566-
1742.
FOR FURTHER INFORMATION CONTACT: For questions about these proposed
standards for nitric acid production units, contact Mr. Chuck French,
Sector
[[Page 63879]]
Policies and Program Division, Office of Air Quality Planning and
Standards (D243-02), Environmental Protection Agency, Research Triangle
Park, North Carolina 27711, telephone number (919) 541-7912; fax number
(919) 541-3207, e-mail address: French.chuck@epa.gov.
SUPPLEMENTARY INFORMATION:
The information presented in this preamble is organized as follows:
I. General Information
A. Does this action apply to me?
B. What should I consider as I prepare my comments to EPA?
C. Where can I get a copy of this document?
D. When would a public hearing occur?
II. Background Information
A. What is the statutory authority for these proposed revisions?
B. What are the current NSPS for Nitric Acid Plants?
III. Summary of Proposed Standards
A. What source category is being regulated?
B. What pollutants are emitted from these sources?
C. What are the proposed standards?
IV. Rationale for the Proposed Standards
A. How is EPA proposing to revise the emissions limit for
affected sources?
B. How is EPA proposing to revise the testing and monitoring
requirements?
C. How is EPA proposing to revise the notification, reporting,
and recordkeeping requirements?
V. Summary of Cost, Environmental, Energy, and Economic Impacts of
These Proposed Standards
A. What are the impacts for new nitric acid production units?
B. What are the secondary impacts for new nitric acid production
units?
C. What are the economic impacts for new nitric acid production
units?
VI. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory Planning and Review and
Executive Order 13563: Improving Regulation and Regulatory Review
B. Paper Reduction Act
C. Regulatory Flexibility Act
D. Unfunded Mandates Reform Act
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation and Coordination With
Indian Tribal Governments
G. Executive Order 13045: Protection of Children From
Environmental Health and Safety Risks
H. Executive Order 13211: Actions Concerning Regulations That
Significantly Affect Energy Supply, Distribution, or Use
I. National Technology Transfer and Advancement Act
J. Executive Order 12898: Federal Actions To Address
Environmental Justice in Minority Populations and Low-Income
Populations
I. General Information
A. Does this action apply to me?
Categories and entities potentially regulated by these proposed
revisions include:
----------------------------------------------------------------------------------------------------------------
Category NAICS code \1\ Examples of regulated entities
----------------------------------------------------------------------------------------------------------------
Industry...................... 325311 Nitrogenous Fertilizer Manufacturing.
Federal government............ ................ Not affected.
State/local/tribal government. ................ Not affected.
----------------------------------------------------------------------------------------------------------------
\1\ North American Industrial Classification System.
This table is not intended to be exhaustive, but rather provides a
guide for readers regarding entities likely to be regulated by this
action. To determine whether your facility would be regulated by this
action, you should examine the applicability criteria in 40 CFR 60.70a.
If you have any questions regarding the applicability of this proposed
action to a particular entity, contact the person in the preceding FOR
FURTHER INFORMATION CONTACT section.
B. What should I consider as I prepare my comments to the EPA?
Do not submit information that you consider to be CBI
electronically through https://www.regulations.gov or e-mail. Send or
deliver information identified as CBI only to the following address:
Roberto Morales, OAQPS Document Control Officer (C404-02), Office of
Air Quality Planning and Standards, Environmental Protection Agency,
Research Triangle Park, NC 27711, Attention Docket ID No. EPA-HQ-OAR-
2010-0750. Clearly mark the part or all of the information that you
claim to be CBI. For CBI information in a disk or CD-ROM that you mail
to EPA, mark the outside of the disk or CD-ROM as CBI and then identify
electronically within the disk or CD-ROM the specific information that
is claimed as CBI. In addition to one complete version of the comment
that includes information claimed as CBI, a copy of the comment that
does not contain the information claimed as CBI must be submitted for
inclusion in the public docket. Information marked as CBI will not be
disclosed except in accordance with procedures set forth in 40 CFR part
2.
C. Where can I get a copy of this document?
In addition to being available in the docket, an electronic copy of
the proposed action is available on the Worldwide Web (WWW) through the
Technology Transfer Network (TTN) Web site. Following signature, EPA
posted a copy of the proposed action on the TTN Web site's policy and
guidance page for newly proposed or promulgated rules at https://www.epa.gov/ttn/oarpg. The TTN Web site provides information and
technology exchange in various areas of air pollution control.
D. When would a public hearing occur?
If anyone contacts EPA requesting to speak at a public hearing by
October 24, 2011, a public hearing will be held on October 28, 2011.
Persons interested in presenting oral testimony or inquiring as to
whether a public hearing is to be held should contact Mr. Chuck French,
listed in the FOR FURTHER INFORMATION CONTACT section.
II. Background Information
A. What is the statutory authority for these proposed revisions?
New source performance standards (NSPS) implement Clean Air Act
(CAA) section 111. Section 111 of the CAA requires that NSPS reflect
the application of the best system of emission reductions which (taking
into consideration the cost of achieving such emission reductions, any
nonair quality health and environmental impact and energy requirements)
the Administrator determines has been adequately demonstrated. This
level of control has sometimes been referred to as ``best demonstrated
technology'' or BDT, and will be referred to in this preamble as best
system of emissions reduction (BSER). In assessing whether a standard
is achievable, EPA must account for routine operating variability
associated with performance of the system on whose performance the
standard is based. See National Lime Ass'n v. EPA, 627 F. 2d 416, 431-
33 (DC Cir. 1980).
Common sources of information as to what constitutes a BSER, and
for assessing that technology's level of performance, include best
available control technology (BACT) determinations made as part of new
source review (NSR). Also, emissions limits that exist in state and
federal permits for recently permitted sources,
[[Page 63880]]
and emissions test data for demonstrated control technologies collected
for compliance demonstration or other purposes are evaluated during
these assessments. EPA compares permit limitations and BACT
determination data with actual performance test data to identify any
site-specific factors that could influence general applicability of
this information. Also, as part of this review we evaluate if
NOX emissions limits more stringent than those in Subpart G
have been established, or if emissions limits have been developed for
additional air pollutants.
The use of State permit data and BACT determination developed as
part of NSR is appropriate because a BACT determination evaluates
information that is similar to BSER, such as available controls, their
performance, cost, and non-air environmental impacts. One important
difference between BACT determinations and a BSER determination for
purposes of NSPS is that BACT determinations are made on a site-
specific basis. Therefore, in evaluating BACT determinations, we have
to account for any site-specific factors that may not be applicable to
the source category as a whole.
Section 111(b)(1)(B) of the CAA requires EPA to periodically review
and revise the standards of performance, as necessary, to reflect
improvements in methods for reducing emissions.
Existing affected facilities that are modified or reconstructed
would also be subject to these proposed revisions for affected sources.
Under CAA section 111(a)(4), ``modification'' means any physical change
in, or change in the method of operation of, a stationary source which
increases the amount of any air pollutant emitted by such source or
which results in the emission of any air pollutant not previously
emitted. Changes to an existing facility that do not result in an
increase in emissions are not considered modifications. Rebuilt
affected facilities would become subject to the proposed standards
under the reconstruction provisions, regardless of changes in emission
rate. Reconstruction means the replacement of components of an existing
facility such that (1) The fixed capital cost of the new components
exceeds 50 percent of the fixed capital cost that would be required to
construct a comparable entirely new facility; and (2) it is
technologically and economically feasible to meet the applicable
standards (40 CFR 60.15).
The NSPS are directly enforceable federal regulations issued for
categories of sources which cause, or contribute significantly to, air
pollution which may reasonably be anticipated to endanger public health
or welfare. The primary purpose of the NSPS is to attain and maintain
ambient air quality by ensuring that the best demonstrated emission
control technologies are installed as the industrial infrastructure is
modernized, when it is most cost effective to build in controls. Since
1970, the NSPS have been successful in achieving long-term emissions
reductions in numerous industries by assuring that cost-effective
controls are installed on new, reconstructed, or modified sources.
B. What are the current NSPS for Nitric Acid Plants NSPS?
The current NSPS for Nitric Acid Plants (40 CFR part 60, Subpart G)
were promulgated in the Federal Register on December 23, 1971 (36 FR
24881). The first review of the Nitric Acid Plants NSPS was completed
on June 19, 1979 (44 FR 35265). An additional review was completed on
April 5, 1984 (49 FR 13654). No changes were made to the NSPS as a
result of those reviews. Minor testing and monitoring changes were made
during three reviews since the original promulgation in 1971 (October
6, 1975 (40 FR 46258), April 22, 1985 (50 FR 15894), and February 14,
1989 (54 FR 6666)). The current Nitric Acid Plants NSPS (Subpart G)
applies to each nitric acid production unit constructed or modified
after August 17, 1971. The present NSPS has an emissions limit of 3.0
lb of NOX per ton of 100% nitric acid produced and a 10%
opacity standard as an additional method of demonstrating compliance
with the NOX emission limit. Continuous NOX
monitors are required as well as recording daily production rates.
III. Summary of Proposed Standards
A. What source category is being regulated?
Today's proposed standards would apply to new nitric acid
production units. Nitric acid plants may include one or more nitric
acid production units. For purposes of these proposed regulations, a
nitric acid production unit is defined as any facility producing weak
nitric acid by either the pressure or atmospheric pressure process.
This definition has not changed from Subpart G.
A new nitric acid production unit is defined as a nitric acid
production unit for which construction, modification, or reconstruction
commences on or after October 14, 2011. The affected facility under the
proposed NSPS is each nitric acid production unit.
B. What pollutants are emitted from these sources?
The pollutant to be regulated under section 111(b), for new nitric
acid production units, is NOX which undergo reactions in the
atmosphere to form particulate matter and ozone. Nitrogen oxides,
particulate matter, and ozone are all subject to national ambient air
quality standards under section 109 of the Clean Air Act, based on
their adverse effects to human health and welfare. NOX is a
criteria pollutant.
These nitric acid production units also emit another nitrogen
compound known as nitrous oxide (N2O), which is considered a
greenhouse gas (GHG). We are not proposing an N2O emission
standard in this action. Although we have limited data from facilities
in the U.S, we believe that owners/operators of nitric acid production
units should consider technologies and technology combinations that
would be appropriate for controlling both NOX and
N2O. Some technologies such as selective catalytic reduction
(SCR) and hydrogen peroxide injection (HPI) are effective only in
controlling NOX. However, other technologies such as
nonselective catalytic reduction (NSCR) are effective in controlling
both NOX and N2O.
The technology combinations that control both NOX and
N2O include SCR plus secondary catalysts (located in the
ammonia reactor), and SCR plus other non-NSCR types of tertiary
catalysts (located after the absorption tower). We expect any controls
applied to control NOX emissions would not preclude
installing cost effective N2O control technologies in the
future. We solicit relevant comments and additional information on
these technologies. Nitric acid production is also one of the
industrial sectors for which ``white papers'' were written to provide
basic information on GHG control options to assist state and local air
pollution control agencies, tribal authorities, and regulated entities
in implementing measures to reduce GHGs, particularly in the assessment
of BACT under the PSD permitting program. These papers provide basic
technical information that may be useful in a BACT analysis but they do
not define BACT for each sector. For more information regarding the
``white papers,'' see https://www.epa.gov/nsr/ghgpermitting.html.
C. What are the proposed standards?
We are proposing to reduce the NOX emissions limit from
3.0 pounds of NOX per ton of nitric acid produced (lb
NOX/ton acid), expressed as NO2, with the
production being expressed as 100 percent nitric acid, to 0.50 lb
NOX/ton
[[Page 63881]]
acid as a 30-day emission rate calculated each operating day based on
the previous 30 consecutive operating days.
The general provisions in 40 CFR part 60 provide that emissions in
excess of the level of the applicable emissions limit during periods of
startup, shutdown, and malfunction shall not be considered a violation
of the applicable emission limit unless otherwise specified in the
applicable standard. See 40 CFR 60.8(c). The general provisions,
however, may be amended for individual subparts. See 40 CFR 60.8(h).
Here, the EPA is proposing standards in Subpart Ga that apply at all
times, including periods of startup or shutdown, and periods of
malfunction.
IV. Rationale for the Proposed Standards
Section 111(a)(1) requires that standards of performance for new
sources reflect the--
* * * degree of emission limitation achievable through the
application of the best system of emission reduction which (taking
into account the cost of achieving such reduction, and any nonair
quality health and environmental impact and energy requirements) the
Administrator determines has been adequately demonstrated.
A. How is EPA proposing to revise the emissions limit for affected
sources?
For affected sources constructed, modified, or reconstructed after
October 14, 2011, we are proposing to reduce the NOX
emissions limit from 3.0 lb NOX/ton acid to 0.50 lb
NOX/ton acid as a 30-day emission rate calculated each
operating day based on the previous 30 consecutive operating days.
The NOX emissions limit for affected facilities
constructed, modified, or reconstructed after August 17, 1971, and
before October 14, 2011 remains unchanged at 3.0 lb NOX/ton
acid.
The 1971 promulgated Nitric Acid Plants NSPS were based on emission
levels achieved using catalytic reduction (see 36 FR 2881, December 23,
1971). Additional reviews of the NSPS were conducted in 1979 and 1984,
where EPA again concluded that catalytic reduction was the BSER
considering economic, energy, and nonair environmental impacts. No
changes were made to the NSPS during these reviews.
There are currently 40 nitric acid production facilities in the
U.S. with a total of 67 nitric acid production units. For this review,
information was collected from responses to a section 114 information
collection request (ICR), through site visits and from trade
associations. The information and comments from stakeholders are
contained in the docket.
The review of permits and other available information in the record
revealed that SCR, NSCR, and HPI are all air pollution control
technologies that are used for NOX control in the nitric
acid production source category and EPA considered all of these as
candidates for BSER as we developed this proposed rule. We are not
aware of any other established or emerging technologies that should be
considered as candidates for BSER for this source category. SCR is used
in 25 nitric acid production units in the U.S. NSCR is used in 14
nitric acid process units in the U.S. HPI is used by one facility. All
of these air pollution control technologies are effective in
controlling NOX emissions. The average NOX
emission reductions for these controls are: SCR--98%; NSCR--99%, HPI--
95% (for more information see Table 3.3 in the Economic Impact
Analysis, which is available in the docket for this action).
The approach used for determining BSER for nitric acid production
units involved reviewing the emission test data submitted in response
to the section 114 ICR, recently issued state permit data, and BACT
determinations developed as part of NSR. In response to clarifications
of the section 114 ICRs, industry provided additional data. In
determining BSER we generally look at the controls and control
performance of new sources. All recent nitric acid units have installed
SCR as NOX controls. Recent BACT determinations have also
identified SCR as BACT.
A 2009 BACT determination has been incorporated into the facility
permit limit for a nitric acid plant in American Falls, Idaho
(Southeast Idaho Energy, LLC). For this analysis, SCR was determined as
BACT, and 0.60 lb NOX/ton acid was determined as the BACT
level of control. The Southeast Idaho Energy, LLC emission limit of
0.60 lb NOX/ton acid will apply at all times during steady-
state operations (no standard applies during periods of startup or
shutdown, and periods of malfunction). The compliance period was not
specified.
There are other recent BACT analyses at two other nitric acid
production units. At Agrium in North Bend, Ohio, the BACT limit set in
2009 is 0.61 lb NOX/ton acid on a 365-day rolling basis. At
Agrium in Kennewick, Washington, the BACT limit set in 2008 is 0.60 lb
NOX/ton acid in any continuous 12-month period (including
startup, shutdown and malfunction).
As part of our BSER analysis, we are proposing that the standard be
stated as a rolling 30-day limit based on 30 consecutive operating days
and that the limit be met at all times. We believe that the 0.50 lb
NOX/ton acid standard, supported by existing source data and
BACT determinations, is more stringent than any state BACT
determination because 0.50 lb NOX/ton acid is lower than
both 0.61 lb NOX/ton acid and 0.60 lb NOX/ton
acid.
Emissions test data were obtained from a number of sources
including a section 114 ICR, trade associations, and the EPA Region 5.
We received nine relative accuracy test audit (RATA) reports for 5
nitric acid production units controlled with SCR, 6 RATA reports for 6
nitric acid production units controlled with NSCR, and 1 RATA report
for 1 nitric acid production unit controlled with HPI. These emissions
tests are short term and are presented in the memorandum Summary of
Test Data Received from Section 114 ICR, dated August 25, 2010 (updated
December 17, 2010).
In response to the section 114 request, nitric acid plants
submitted NOX Continuous Emission Monitoring Systems (CEMS)
data. These included 3 facilities using SCR and 2 facilities using
NSCR.
All emission test data (short term and CEMS data) indicate that
lower emissions than the current Subpart G emission limit of 3.0 lb
NOX/ton acid are being achieved, regardless of the type of
NOX control being used. We decided to further analyze the
long-term CEMS data because: (1) Long term data include periods of
startup and shutdown, where emissions are shown to be larger than
during steady state operating conditions, (2) long term data allow the
seasonal impacts of temperature and humidity on NOX controls
to be evenly distributed, as these factors often vary by the time of
year and location, and (3) long term data include seasonal supply and
demand cycles so that all factors that influence production are equally
considered.
We have concluded that SCR is BSER based on data showing lower
emissions rates from SCR-controlled units. For more information, see
Table 1 of this preamble and the related discussion. The fact that SCR
is the only known NOX control technology being installed in
new nitric acid production units, and that SCR has been determined to
be BACT supports this conclusion. Further, SCR does not produce any
secondary environmental impacts.
The next step in the NSPS process is to establish an achievable
standard using BSER. In assessing whether a standard is achievable, the
EPA must account for routine operating variability
[[Page 63882]]
associated with performance of the system on which the standard is
based. For each plant that submitted long-term CEMS data, these data
cover the entire operating period including startups, shutdowns and
malfunctions. To ensure that the new NOX standard is
achievable by all properly designed and operated SCR units and covers
all operating periods including startup and shutdowns, we analyzed the
statistical variation by calculating the 99th percentile. When
establishing an emissions limit (which is considered a never to exceed
level of emissions), we use a 99th percentile based on statistical
analyses. This approach accounts for short and long-term variability in
emissions associated with all normal operating conditions, including
startup and shutdown (see 72 FR 54878-79, September 27, 2007). This
analysis is contained in the memorandum Statistical Evaluation of CEMS
Data to Determine the NOX Emission Standard, dated July 18,
2011.
Using the long term CEMS data received through the ICR, the EPA
determined that there were sufficient data to directly calculate the
99th percentile for the best performing sources. The EPA determined
that the CEMS represents long-term performance and accounts for long-
term and day-to-day variability.
Long term CEMS data were obtained from 3 plants using SCR and 2
plants using NSCR. The plant with HPI did not submit long term CEMS
data. Following is a discussion of these data--the 3 plants with SCR
are discussed first followed by the 2 plants with NSCR.
The 99th percentile was directly calculated for these 5 best
performing sources. A summary of the values is shown in Table 1.
Table 1--CEMS Data--99th Percentile by Compliance Period
[lb of NOX/T of 100% nitric acid]
--------------------------------------------------------------------------------------------------------------------------------------------------------
3-hour daily 7-day 30-day
Compliance period Control 15 minute hourly rolling block rolling rolling
--------------------------------------------------------------------------------------------------------------------------------------------------------
PCS Geismar (Train 5)......................... SCR................................... 0.84 0.89 1.00 1.02 0.72 0.38
Agrium North Bend............................. SCR................................... NA 0.69 0.80 1.67 0.92 0.50
El Dorado Nitrogen............................ SCR................................... NA 0.47 0.47 0.44 0.40 0.37
PCS Geismar (Train 4)......................... NSCR.................................. 0.97 1.25 1.74 5.58 2.41 2.41
Agrium Sacramento............................. NSCR.................................. NA 2.13 NA 1.60 1.31 1.29
--------------------------------------------------------------------------------------------------------------------------------------------------------
The Agrium-North Bend plant submitted data spanning from January
2010 through December 2010. The continuous data over the 12-month
period show 0.50 lb NOX/ton acid as the 99th percentile for
each 30-day rolling time period. The 30-day periods with high
NOX emissions occurred during periods of startup and
shutdown.
The PCS Geismar plant submitted 15-minute average data for Train 5
for 2007-2009. Train 5 is controlled with SCR. The period spanning
January 2009 through December 2009 was analyzed. The continuous data
from a 12-month period show 0.38 lb NOX/ton acid as the 99th
percentile for each 30-day rolling time period.
The El Dorado plant submitted hourly averages data for the period
of July 2010-June 2011. The continuous data from a 12-month period show
0.37 lb NOX/ton acid as the 99th percentile for each 30-day
rolling time period.
We also received 15-minute average data on NOX emissions
for 2007-2009 from the PCS Geismar plant for Train 4, which is
controlled with NSCR. The period spanning January 2009 through December
2009 was analyzed to be consistent with Train 5 (controlled with SCR).
The continuous data from a 12-month period show 2.41 lb NOX/
ton acid as the 99th percentile emissions level for a 30-day time
period for train 4. The result of this analysis is limited due to the
fact that the nitric acid train was operational for approximately 65
days during the 12-month period. It is unlikely that this short time
period is representative of the NSCR performance over time.
The Agrium-Sacramento plant submitted data spanning from January
2010 through December 2010. The continuous data over the 12-month
period show 1.29 lb NOX/ton acid as the 99th percentile for
a 30-day time period. The 30-day periods with high NOX
emissions occurred during periods of startup and shutdown.
As shown by Table 1, all units are meeting the current Subpart G
NOX emission standard of 3.0 lb NOX/ton acid,
regardless of the compliance period. We did not receive any long term
data from the nitric acid train using HPI but the table shows that the
NOX emissions from nitric acid trains using SCR are lower
than nitric acid trains using NSCR. For example, reviewing the 99th
percentile on a 30-day rolling basis, SCR data range from 0.38 to 0.50
lb NOX/ton acid and NSCR data range from 1.29 to 2.41 lb
NOX/ton acid. The lower emissions from SCR when compared to
emissions from NSCR are the main reason that SCR has been determined as
BSER.
Whether NSCR can meet the levels achievable by SCR over a long
term, is uncertain. The long term CEMS data from 2 NSCR plants indicate
difficulty in meeting the 0.50 lb NOX/ton limit. However, we
have monthly average data from 2 other facilities using NSCR. These
plants with NSCR (Dyno Nobel-Deer Island and JR Simplot-Helm) submitted
monthly block averages for a three year period. For 2009, the monthly
block averages for both plants were very close and range from 7 to 17
ppm or approximately 0.15-0.36 lb NOX/ton acid. As these
data are not continuous but rather block monthly averages, comparison
of these with the CEMS data discussed above is not possible. These data
are presented to show that NSCR may be able to achieve the proposed
emission limit. Also, the data presented in the memorandum Summary of
Test Data Received from Section 114 ICR, dated August 25, 2010 (updated
December 17, 2010) show that low short-term NOX emissions
rates are possible when using NSCR and HPI.
For the units controlled by SCR, we have not been able to identify
any specific factors associated with the El Dorado Nitrogen and PCS
Nitrogen Train 5 units that account for the lower emission levels
compared to the Agrium-North Bend unit. Thus, based on the information
currently in the record, we believe that emission levels of
NOX are not only dependent on the use of SCR but also on
process factors that result in variability that cannot be avoided
through better or different design or through changes in operating
practices.
By selecting an emission limit based on the 99th percentile of
emissions data from unit with BSER (which is SCR), we ensure that this
limit reflects BSER but is also achievable during all periods by
facilities that have BSER equivalent
[[Page 63883]]
controls. The available data for units with BSER, which were used to
derive the proposed NOX emissions limit for new, modified
and reconstructed units, are from existing nitric acid units that have
been in operation for at least 10 years. Therefore, we believe that
reconstructed, modified and new sources will be able to meet the
proposed limit. We have no reason to believe that modified or
reconstructed sources would not be able to meet this limit. Thus, we do
not believe different standards are needed for modified or
reconstructed sources.
Moreover, in the past when companies chose to increase production
or replace units, it is our understanding that they would build new
production units rather than modify or reconstruct existing units. In
fact, to our knowledge, no existing nitric acid production unit has
been reconstructed or modified since Subpart G was promulgated.
Therefore, we expect no reconstructions or modifications to occur for
the nitric acid industry in the foreseeable future. Nevertheless, we
request comment on any reconstructions or modifications to nitric acid
production units that have taken place or information about any future
plans to do such modifications or reconstructions. Also, we request
data on the level of NOX emissions that these nitric acid
units are able to achieve. If these emission levels are different than
0.50 lb NOX/ton acid on a 30 day rolling basis, the
commenter should include data to support the suggested emission level.
Nevertheless, we expect that growth within the industry will be
limited to newly constructed nitric acid production units. We believe
that new nitric acid production units will be able to meet the proposed
limit which takes into consideration routine operating variability as
well as variation due to weather and periods of startups and shutdowns.
The proposed emission limit of 0.50 lb NOX/ton acid is a
never to exceed limit. We have not identified any specific process or
technology that new nitric acid production units could employ to
consistently meet an emission limit lower than 0.50 lb NOX/
ton acid. Therefore, we are proposing a limit of 0.50 lb
NOX/ton acid for Subpart Ga.
As part of our BSER analysis, we are proposing that the standard be
stated as a rolling 30-day limit based on 30 consecutive operating days
and that the limit be met at all times including periods of startup and
shutdown. We believe that the 0.50 lb NOX/ton acid standard
is supported by existing source data. The use of a 30-day period
accounts for peaks in the data that occur during startup and shutdown.
These periods occur on average about 3 to 4 hours per month and
emissions during those periods are much higher than normal. Therefore,
the 3 to 4 hour periods can affect average emissions beyond that 3 to 4
hour period. Setting the standard with a 30-day compliance period meets
the statutory requirement that the standard reflect the degree of
emission limitation that is achievable through BSER, including during
periods that include startup and shutdown.
Although the proposed limit of 0.50 lb NOX/ton acid is
based on the data for SCR, NSPS do not require the use and installation
of a specific control device. We request additional long-term data (in
units of the standard) to determine whether NSCR and HPI can achieve
the proposed limit.
For all of the reasons discussed above, we are proposing 0.50 lb
NOX/ton acid as the revised standard for Nitric Acid Plants
to be established in Subpart Ga.
Periods of Startup or Shutdown. In proposing the standards in this
rule, the EPA has taken into account startup and shutdown periods and,
for the reasons explained below, has not proposed different standards
for those periods.
According to information received from industry in the section 114
ICR, NOX emissions during startup and shutdown are higher
than during normal operations. Due to the relatively short duration of
startup and shutdown events (generally a few hours) compared to normal
steady-state operations, we believe that a 30-day emission rate
calculated based on 30 consecutive operating days will allow affected
sources to meet the 0.50 lb NOX/ton acid at all times,
including periods of startup and shutdown. We request comment on the
use of a 30-day emission rate calculated based on 30 consecutive
operating days. Further, we request comment on whether the standard
should be set with a compliance period that is shorter (such as 24
hours). For any comment suggesting a shorter time period, the comment
should explain why that different period is appropriate and include
data supporting the different compliance period and how startup and
shutdown would be factored into a shorter term limit.
If you believe that the EPA's conclusion is incorrect, or that the
EPA has failed to consider any relevant information on this point, we
encourage you to submit comments. In particular, we note that the
general provisions in Part 60 require facilities to keep records of the
occurrence and duration of any startup, shutdown or malfunction (40 CFR
60.7(b)) and either report to the EPA any period of excess emissions
that occurs during periods of startup, shutdown or malfunction (40 CFR
60.7(c)(2)) or report that no excess emissions occurred (40 CFR
60.7(c)(4)). Thus, any comments that contend that sources cannot meet
the proposed standard during startup and shutdown periods should
provide data and other specifics supporting their claim.
Periods of Malfunction. Periods of startup, normal operations, and
shutdown are all predictable and routine aspects of a source's
operations. However, by contrast, malfunction is defined as a ``sudden,
infrequent, and not reasonably preventable failure of air pollution
control and monitoring equipment, process equipment or a process to
operate in a normal or usual manner * * *'' (40 CFR 60.2). The EPA has
determined that malfunctions should not be viewed as a distinct
operating mode. Further, nothing in section 111 or in case law requires
that the EPA anticipate and account for the innumerable types of
potential malfunction events in setting emission standards. See,
Weyerhaeuser v. Costle, 590 F.2d 1011, 1058 (DC Cir. 1978) (``In the
nature of things, no general limit, individual permit, or even any
upset provision can anticipate all upset situations. After a certain
point, the transgression of regulatory limits caused by `uncontrollable
acts of third parties,' such as strikes, sabotage, operator
intoxication or insanity, and a variety of other eventualities, must be
a matter for the administrative exercise of case-by-case enforcement
discretion, not for specification in advance by regulation.'')
Further, it is reasonable to interpret section 111 as not requiring
the EPA to account for malfunctions in setting emissions standards. For
example, we note that section 111 provides that the EPA will set
standards of performance which reflect the degree of emission
limitation achievable through ``the application of the best system of
emission reduction'' that the EPA determines is adequately
demonstrated. Applying the concept of ``the application of the best
system of emission reduction'' to periods during which a source is
malfunctioning presents significant difficulties. The ``application of
the best system of emission reduction'' is more appropriately
understood to include operating in such a way as to avoid malfunctions
of their units.
Moreover, even if malfunctions were considered a distinct operating
mode, we believe it would be impracticable to take malfunctions into
account in setting CAA section 111 standards for the nitric acid
production units that will
[[Page 63884]]
be covered in the proposed Subpart Ga. As noted above, by definition,
malfunctions are sudden and unexpected events and it would be difficult
to set a standard that takes into account the myriad different types of
malfunctions that can occur across all sources in the category.
Moreover, malfunctions can vary in frequency, degree, and duration,
further complicating standard setting.
If the standard is stated as a 30-day emission rate calculated
based on 30 consecutive operating days, or some other time period, we
believe that sources will be able to operate their plants in compliance
with the standard even if they experience malfunctions. Also, excess
emissions from a nitric acid production unit during a malfunction can
frequently be mitigated or avoided by shutting the plant down if a key
component fails.
In the event that a source fails to comply with the applicable CAA
section 111 standards as a result of a malfunction event, the EPA would
determine an appropriate response based on, among other things, the
good faith efforts of the source to avoid malfunctions and to minimize
emissions during malfunction periods, including preventative and
corrective actions, as well as root cause analyses to ascertain and
rectify excess emissions. The EPA would also consider whether the
source's failure to comply with the CAA section 111 standard was, in
fact, ``sudden, infrequent, not reasonably preventable'' and was not
instead ``caused in part by poor maintenance or careless operation.''
40 CFR 60.2 (definition of malfunction).
Finally, the EPA recognizes that even equipment that is properly
designed and maintained can sometimes fail and that such failure can
sometimes cause an exceedance of the relevant emission standard. (See,
e.g., State Implementation Plans: Policy Regarding Excessive Emissions
During Malfunctions, Startup, and Shutdown (Sept. 20, 1999); Policy on
Excess Emissions During Startup, Shutdown, Maintenance, and
Malfunctions (Feb. 15, 1983)). The EPA is therefore proposing to add an
affirmative defense to civil penalties for exceedances of emission
limits that are caused by malfunctions. See 40 CFR 60.71a (defining
``affirmative defense'' to mean, in the context of an enforcement
proceeding, a response or defense put forward by a defendant, regarding
which the defendant has the burden of proof, and the merits of which
are independently and objectively evaluated in a judicial or
administrative proceeding). We also are proposing other regulatory
provisions to specify the elements that are necessary to establish this
affirmative defense; the source must prove by a preponderance of the
evidence that it has met all of the elements set forth in 60.74a. (See
40 CFR 22.24). The criteria ensure that the affirmative defense is
available only where the event that causes an exceedance of the
emission limit meets the narrow definition of malfunction in 40 CFR
60.2 (sudden, infrequent, not reasonably preventable and not caused by
poor maintenance and/or careless operation). For example, to
successfully assert the affirmative defense, the source must prove by a
preponderance of the evidence that excess emissions ``[w]ere caused by
a sudden, infrequent, and unavoidable failure of air pollution control
and monitoring equipment, process equipment, or a process to operate in
a normal or usual manner * * *.'' The criteria also are designed to
ensure that steps are taken to correct the malfunction, to minimize
emissions in accordance with section 60.72a(b) and to prevent future
malfunctions. For example, the source must prove by a preponderance of
the evidence that ``[r]epairs were made as expeditiously as possible
when the applicable emission limitations were being exceeded * * *''
and that ``[a]ll possible steps were taken to minimize the impact of
the excess emissions on ambient air quality, the environment and human
health * * *.'' In any judicial or administrative proceeding, the
Administrator may challenge the assertion of the affirmative defense
and, if the respondent has not met its burden of proving all of the
requirements in the affirmative defense, appropriate penalties may be
assessed in accordance with section 113 of the Clean Air Act (see also
40 CFR part 22.77).
B. How is the EPA proposing to revise the testing and monitoring
requirements?
The current NSPS requires an initial performance test, the
installation of a continuous NOX monitor and the recording
of the daily production rate and hours of operations. We are proposing
that the new Subpart Ga also require the installation, operation, and
maintenance of an exhaust gas flow rate monitor. The capital cost of
this monitor is $39,000 and the total annualized cost for this monitor
for a new nitric acid production unit is estimated to be $15,000. The
gas flow rate monitor provides data on the volume of gas emitted per
unit of time, and this information combined with the data from the NOx
monitor will result in more accurate measurements of the total
NOX being emitted.
Subpart G currently requires that owners/operators of nitric acid
production units conduct an initial performance test to demonstrate
initial compliance with the NOX emission limit. The initial
performance test is based on three one-hour test runs for
NOX using manual testing methods; specifically, Method 7
(or, alternatively, Method 7A, 7B, 7C, or 7D) for NOX
concentration, and Method 2 for volumetric flow rate (40 CFR 60,
appendix A-4). The nitric acid production rate also must be determined
during the initial performance test so that the emissions can be
calculated in terms of the emissions limit, lb NOX per ton
of acid produced (100 percent acid basis). The current rule does not
provide specific procedures or criteria for determining the production
rate or concentration.
The current NSPS also requires the owner/operator to install,
calibrate, maintain and operate a CEMS for measuring NOX
concentration (40 CFR 60, appendix B, Performance Specification 2) to
demonstrate continuing compliance. The owner/operator is required to
establish a conversion factor expressed as lb NOX per ton
acid produced per ppm NOX by comparing the CEMS data (ppm
NOX) obtained during the performance test to the performance
test results (lb NOX per ton of acid). The conversion factor
is used to convert the CEMS concentration data into units of the
emissions standard on an on-going basis. Subsequently, the owner/
operator must report periods of excess emissions defined as any 3-hour
period during which the average nitric acid emissions (arithmetic
average of three contiguous 1-hour periods) as measured by the CEMS
exceed the emissions standard. The owner/operator must reestablish the
conversion factor during any subsequent performance test.
As part of an ongoing effort to improve compliance with various
federal air emission regulations, we are proposing to require use of a
continuous compliance determination method (CCDM) for NOX
for nitric acid production units subject to Subpart Ga. The proposed
CCDM is a continuous emissions rate monitoring system (CERMS) comprised
of the NOX CEMS and a continuous exhaust gas flow rate
monitoring system. The CERMS would be required to meet the requirements
of performance specification 6 (40 CFR 60, appendix B).
Performance Specification 6 (PS6) provides performance criteria for
the flow rate monitoring system and stipulates the overall performance
[[Page 63885]]
criteria for the monitoring system in terms of pollutant emissions rate
(i.e., lb NOX/hour). PS6 refers to the criteria of
performance specification 2 (PS2) for the NOX CEMS.
Extractive Fourier Transform Infrared Spectroscopy (FTIR) is capable of
measuring NOX through the requirements in Performance
Specification 15 (PS15). The proposed regulation allows use of the FTIR
CEMS for determining compliance with the NOX emissions
limit, in lieu of a monitor meeting the requirements of PS2, at the
discretion of the owner/operator.
This proposed rule would require the acid production rate to be
determined on a daily basis. The daily NOX emissions rate
measured by the CERMS (lb) and the daily production rate (tons of acid
per day) are used to calculate the emissions rates in units of the
standard, lbs NOX per ton of acid. This proposed rule would
provide options for measuring the production rate and stipulates a
minimum accuracy requirement for the measurement equipment. This
proposed rule also requires that the concentration of the produced
nitric acid be tested daily.
We are proposing that nitric acid production units subject to
Subpart Ga will not be subject to an opacity standard; consequently no
test or monitoring method for opacity is included in this proposed
rule. Using the nitric acid production rate and concentration of the
nitric acid, the NOX concentration from the NOX
CEMS, and the flow rate from the proposed flow monitor, the
NOX emission rate in units of the standard (lb
NOX/ton acid) can be determined at any point in time.
Therefore, an opacity standard is not required as an additional method
of demonstrating compliance with a NOX emission limit.
C. How is the EPA proposing to revise the notification, reporting, and
recordkeeping requirements?
The only recordkeeping requirements in the existing Subpart G are
of daily production rate and hours of operation. The reporting
requirements in the existing subpart G include reports of excess
emissions and production rate. The frequency of reporting is
semiannually as specified in 60.7(c).
Reporting and recordkeeping requirements are being proposed as
separate sections for Subpart Ga. Owners/operators subject to Subpart
Ga must keep records of all performance tests and results; and dated
daily records of hours of operation, nitric acid production rate, and
nitric acid concentration; explanations for periods of noncompliance
and corrective actions taken; span exceedances; and any modifications
to CERMS which could affect the ability of the CERMS to comply with
applicable performance specifications.
Owners/operators must report all performance tests and results;
dated daily records of NOX emission rates that exceed the
standard, explanations for periods of noncompliance and corrective
actions taken, span exceedances, and any modifications to CERMS which
could affect the ability of the CERMS to comply with applicable
performance specifications; and RATA (i.e., from the initial
certification) and performance test data. The frequency of reporting
for Subpart Ga is the same as for Subpart G.
V. Summary of Cost, Environmental, Energy, and Economic Impacts of
These Proposed Standards
In setting standards, the CAA requires us to consider alternative
emission control approaches, taking into account the estimated costs as
well as impacts on energy, solid waste, and other effects.
A. What are the impacts for new nitric acid production units?
We are presenting estimates of the impacts for the proposed 40 CFR
part 60, Subpart Ga that change the performance standards for new
nitric acid production units. The cost, environmental, and economic
impacts presented in this section are expressed as incremental
differences between the impacts of nitric acid production units
complying with the proposed Subpart Ga and the current NSPS
requirements of Subpart G (i.e., baseline). The impacts are presented
for future nitric acid production units that commence construction,
reconstruction, or modification over the 5 years following promulgation
of the revised NSPS. Costs are based on 2nd quarter of 2010. The
analyses and the documents referenced below can be found in Docket ID
No. EPA-HQ-OAR-2010-0750.
In order to determine the incremental impacts of this proposed
rule, we first estimated the number of new nitric acid production units
that would become subject to regulation during the five year period
after promulgation of subpart Ga. Based on existing nitric acid
production units and estimated future growth rates, 6 new nitric acid
production units are expected to be required to meet the nitric acid
production demand in that five year period. For further detail on the
methodology of these calculations, see memorandum Impacts of Nitric
Acid NSPS Review--NOX, dated December 15, 2010, in Docket ID No. EPA-
HQ-OAR-2010-0750.
The proposed Subpart Ga NOX emission limit reflects the
use of control technologies currently in use by the industry and
reflects an adjustment of the limit to more accurately reflect the
performance of these control technologies. The current Subpart G NSPS
NOX emissions limit can be achieved using a number of
control techniques including NSCR, SCR and HPI. In many cases, the air
pollution control systems used to meet the current NSPS could be used
to meet the proposed revised NOX emission limit for future
affected facilities. The potential nationwide emission reduction
associated with lowering the NOX limit from 3.0 to 0.50 lb
NOX/ton acid (100 percent acid basis) is estimated to be
2,000 tons per year (tpy) NOX. This potential emission
reduction may be overestimated because the majority of control systems
installed on future affected facilities would likely result in
emissions at or below the proposed emissions limit even in the absence
of these proposed revisions.
There are many existing nitric acid production units currently
meeting 0.50 lb NOX/ton acid. Therefore, there is no
increase in control costs of meeting the proposed emission limit of
0.50 lb NOX/ton acid for new nitric acid production units
compared to the control costs to comply with subpart Ga. The only costs
incurred would be the installation of an air flow monitor, which is
discussed below.
There are differences in notification, testing, monitoring,
reporting, and recordkeeping (MRR) between Subpart G and the new
Subpart Ga that result in increased costs. We are proposing the use of
a CERMS for monitoring compliance with Subpart Ga. The CERMS requires
the installation of both a continuous NOX monitor and
continuous exhaust gas flow rate monitor. The current NSPS (subpart G)
requires only the installation of a continuous NOX monitor.
The installation, operation, and maintenance of an exhaust gas flow
rate monitor will increase the cost to nitric acid production units
over what would be incurred to comply with subpart G. We estimate that
the total increase in nationwide annual cost associated with this
proposed monitoring revision is $90,110 for all six of the new
production units projected to be built from 2011 to 2016.
The estimated nationwide incremental 5-year NOX
emissions reductions and cost impacts for these proposed revisions are
summarized in Table 2 of this preamble. The methodology is detailed in
the memorandum Impacts of Nitric Acid
[[Page 63886]]
NSPS Review--NOX, dated December 13, 2010 (updated July 27, 2011). The
overall cost effectiveness is about $45 per ton of NOX
removed.
Table 2--National Incremental NOX Emission Reductions and Cost Impacts for New Nitric Acid Production Units
Subject to Proposed Standards Under 40 CFR Part 60, Subpart Ga (Fifth Year After Promulgation)
----------------------------------------------------------------------------------------------------------------
Potential annual
Total annualized NOX emission Potential cost
Proposed revisions for future affected facilities cost [$1,000/yr] reductions effectiveness
[tons NOX/yr] [$/ton NOX]
----------------------------------------------------------------------------------------------------------------
Revisions to NOX emission limit........................... $0 2,000 $0.00
-----------------------------------------------------
Revisions to MRR requirements............................. 90 ................ ................
-----------------------------------------------------
Total................................................. 90 2,000 45
----------------------------------------------------------------------------------------------------------------
B. What are the secondary impacts for new nitric acid production units?
Indirect or secondary air quality impacts are impacts that would
result from the increased electricity usage associated with the
operation of control devices (i.e., increased secondary emissions of
criteria pollutants from power plants). Energy impacts consist of the
electricity and steam needed to operate control devices and other
equipment that would be required under this proposed rule. In most
cases, to comply with the current Subpart G NOX emission
limit or this Subpart Ga NOX emission limit, the same
control system (SCR, NSCR, or HPI) would have been installed. These
proposed revisions only require the addition of exhaust gas flow
monitors, which would result in minimal secondary air impacts or
increase in overall energy demand.
C. What are the economic impacts for new nitric acid production units?
We performed an economic impact analysis that estimates changes in
prices and output for nitric acid production units nationally using the
annual compliance costs estimated for this proposed rule. All estimates
are for the fifth year after promulgation since this is the year for
which the compliance cost impacts are estimated. The impacts to
producers and consumers affected by this proposed rule are slightly
higher product prices and slightly lower outputs. Prices for products
(nitric acid) from affected plants should increase by less than 0.07
percent for the fifth year. The output of nitric acid should decrease
by less than 0.50 percent for the fifth year. Hence, the overall
economic impact of this proposed NSPS should be low on the affected
industries and their consumers. For more information, please refer to
the Economic Impact Analysis for this proposed rulemaking in the public
docket.
VI. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory Planning and Review and Executive
Order 13563: Improving Regulation and Regulatory Review
Under Executive Order 12866 (58 FR 51735, October 4, 1993), this
action is a significant regulatory action because it could raise novel
legal or policy issues. Accordingly, the EPA submitted this action to
the Office of Management and Budget for review under Executive Order
12866 and any changes made in response to OMB recommendations have been
documented in the docket for this action.
B. Paperwork Reduction Act
The information collection requirements in this proposed rule have
been submitted for approval to the Office of Management and Budget
(OMB) under the Paperwork Reduction Act, 44 U.S.C. 3501 et seq. The
Information Collection Request (ICR) document prepared by the EPA has
been assigned the EPA ICR number [2445.01].
These proposed revisions to the existing new source performance
standards for nitric acid production units would add monitoring
requirements for future affected facilities. We have revised the ICR
for the existing rule.
These proposed revisions to the new source performance standards
for nitric acid production units for future affected facilities include
a change to the emission limit and additional continuous monitoring
requirements. The monitoring requirements include installing a
continuous flow monitor and monitoring the nitric acid concentration.
These monitoring requirements are in addition to a CEMS for
NOX concentration which is required under the current
subpart G. These requirements are based on specific requirements in
Subpart Ga which are mandatory for all operators subject to NSPS. These
recordkeeping and reporting requirements are specifically authorized by
section 114 of the CAA (42 U