Acephate, Cacodylic acid, Dicamba, Dicloran et al.; Proposed Tolerance Actions, 28156-28179 [2010-11845]
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Federal Register / Vol. 75, No. 96 / Wednesday, May 19, 2010 / Proposed Rules
ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Part 180
[EPA–HQ–OPP–2010–0262; FRL–8821–3]
Acephate, Cacodylic acid, Dicamba,
Dicloran et al.; Proposed Tolerance
Actions
AGENCY: Environmental Protection
Agency (EPA).
ACTION: Proposed rule.
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SUMMARY: EPA is proposing to revoke
certain tolerances for the fungicides
dicloran and thiophanate-methyl; the
herbicides EPTC, hexazinone, picloram,
and propazine; the defoliant and
herbicide cacodylic acid; the plant
growth regulator and herbicide diquat,
the insecticides disulfoton, malathion,
methamidophos, methomyl, phosmet,
piperonyl butoxide, pyrethrins, and
thiodicarb; the fumigant antimicrobial
and insecticide methyl bromide, the
nematicides/insecticides ethoprop and
fenamiphos, the insecticide synergist Noctyl bicycloheptene dicarboximide,
and the tolerance exemptions for the
insecticide/miticide pyrethrum and
insecticide synergist N-octyl
bicycloheptene dicarboximide. In
addition, EPA is proposing to remove
certain expired tolerances for
disulfoton, fenamiphos, and
thiophanate-methyl. Also, EPA is
proposing to modify certain tolerances
for the fungicide thiophanate-methyl,
herbicides dicamba, EPTC, hexazinone
and picloram, and insecticide synergist
N-octyl bicycloheptene dicarboximide.
In addition, EPA is proposing to
establish new tolerances for the
fungicide thiophanate-methyl and the
herbicides EPTC, hexazinone, and
picloram. Also, EPA is proposing to
reinstate specific tolerances for
methamidophos residues as a result of
the application of the insecticide
acephate. The regulatory actions
proposed in this document are in
follow-up to the Agency’s reregistration
program under the Federal Insecticide,
Fungicide, and Rodenticide Act
(FIFRA), and tolerance reassessment
program under the Federal Food, Drug,
and Cosmetic Act (FFDCA), section
408(q).
DATES: Comments must be received on
or before July 19, 2010.
ADDRESSES: Submit your comments,
identified by docket identification (ID)
number EPA–HQ–OPP–2010–0262, by
one of the following methods:
• Federal eRulemaking Portal: https://
www.regulations.gov. Follow the on-line
instructions for submitting comments.
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• Mail: Office of Pesticide Programs
(OPP) Regulatory Public Docket (7502P),
Environmental Protection Agency, 1200
Pennsylvania Ave., NW., Washington,
DC 20460–0001.
• Delivery: OPP Regulatory Public
Docket (7502P), Environmental
Protection Agency, Rm. S–4400, One
Potomac Yard (South Bldg.), 2777 S.
Crystal Dr., Arlington, VA. Deliveries
are only accepted during the Docket
Facility’s normal hours of operation
(8:30 a.m. to 4 p.m., Monday through
Friday, excluding legal holidays).
Special arrangements should be made
for deliveries of boxed information. The
Docket Facility telephone number is
(703) 305–5805.
Instructions: Direct your comments to
docket ID number EPA–HQ–OPP–2010–
0262. EPA’s policy is that all comments
received will be included in the docket
without change and may be made
available on-line at https://
www.regulations.gov, including any
personal information provided, unless
the comment includes information
claimed to be Confidential Business
Information (CBI) or other information
whose disclosure is restricted by statute.
Do not submit information that you
consider to be CBI or otherwise
protected through regulations.gov or email. The regulations.gov website is an
‘‘anonymous access’’ system, which
means EPA will not know your identity
or contact information unless you
provide it in the body of your comment.
If you send an e-mail comment directly
to EPA without going through
regulations.gov, your e-mail address
will be automatically captured and
included as part of the comment that is
placed in the docket and made available
on the Internet. If you submit an
electronic comment, EPA recommends
that you include your name and other
contact information in the body of your
comment and with any disk or CD-ROM
you submit. If EPA cannot read your
comment due to technical difficulties
and cannot contact you for clarification,
EPA may not be able to consider your
comment. Electronic files should avoid
the use of special characters, any form
of encryption, and be free of any defects
or viruses.
Docket: All documents in the docket
are listed in the docket index available
at https://www.regulations.gov. Although
listed in the index, some information is
not publicly available, e.g., CBI or other
information whose disclosure is
restricted by statute. Certain other
material, such as copyrighted material,
is not placed on the Internet and will be
publicly available only in hard copy
form. Publicly available docket
materials are available either in the
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electronic docket at https://
www.regulations.gov, or, if only
available in hard copy, at the OPP
Regulatory Public Docket in Rm. S–
4400, One Potomac Yard (South Bldg.),
2777 S. Crystal Dr., Arlington, VA. The
hours of operation of this Docket
Facility are from 8:30 a.m. to 4 p.m.,
Monday through Friday, excluding legal
holidays. The Docket Facility telephone
number is (703) 305–5805.
FOR FURTHER INFORMATION CONTACT:
Joseph Nevola, Pesticide Re-evaluation
Division (7508P), Office of Pesticide
Programs, Environmental Protection
Agency, 1200 Pennsylvania Ave, NW.,
Washington, DC 20460–0001; telephone
number: (703) 308-8037; e-mail address:
nevola.joseph@epa.gov.
SUPPLEMENTARY INFORMATION:
I. General Information
A. Does this Action Apply to Me?
You may be potentially affected by
this action if you are an agricultural
producer, food manufacturer, or
pesticide manufacturer. Potentially
affected entities may include, but are
not limited to:
• Crop production (NAICS code 111).
• Animal production (NAICS code
112).
• Food manufacturing (NAICS code
311).
• Pesticide manufacturing (NAICS
code 32532).
This listing is not intended to be
exhaustive, but rather provides a guide
for readers regarding entities likely to be
affected by this action. Other types of
entities not listed in this unit could also
be affected. The North American
Industrial Classification System
(NAICS) codes have been provided to
assist you and others in determining
whether this action might apply to
certain entities. To determine whether
you or your business may be affected by
this action, you should carefully
examine the applicability provisions in
Unit II.A. If you have any questions
regarding the applicability of this action
to a particular entity, consult the person
listed under FOR FURTHER INFORMATION
CONTACT.
B. What Should I Consider as I Prepare
My Comments for EPA?
1. Submitting CBI. Do not submit this
information to EPA through
regulations.gov or e-mail. Clearly mark
the part or all of the information that
you claim to be CBI. For CBI
information in a disk or CD-ROM that
you mail to EPA, mark the outside of the
disk or CD-ROM as CBI and then
identify electronically within the disk or
CD-ROM the specific information that is
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claimed as CBI. In addition to one
complete version of the comment that
includes information claimed as CBI, a
copy of the comment that does not
contain the information claimed as CBI
must be submitted for inclusion in the
public docket. Information so marked
will not be disclosed except in
accordance with procedures set forth in
40 CFR part 2.
2. Tips for preparing your comments.
When submitting comments, remember
to:
i. Identify the document by docket ID
number and other identifying
information (subject heading, Federal
Register date and page number).
ii. Follow directions. The Agency may
ask you to respond to specific questions
or organize comments by referencing a
Code of Federal Regulations (CFR) part
or section number.
iii. Explain why you agree or disagree;
suggest alternatives and substitute
language for your requested changes.
iv. Describe any assumptions and
provide any technical information and/
or data that you used.
v. If you estimate potential costs or
burdens, explain how you arrived at
your estimate in sufficient detail to
allow for it to be reproduced.
vi. Provide specific examples to
illustrate your concerns and suggest
alternatives.
vii. Explain your views as clearly as
possible, avoiding the use of profanity
or personal threats.
viii. Make sure to submit your
comments by the comment period
deadline identified.
C. What Can I do if I Wish the Agency
to Maintain a Tolerance that the Agency
Proposes to Revoke?
This proposed rule provides a
comment period of 60 days for any
person to state an interest in retaining
a tolerance proposed for revocation. If
EPA receives a comment within the 60–
day period to that effect, EPA will not
proceed to revoke the tolerance
immediately. However, EPA will take
steps to ensure the submission of any
needed supporting data and will issue
an order in the Federal Register under
FFDCA section 408(f), if needed. The
order would specify data needed and
the timeframes for its submission, and
would require that within 90 days some
person or persons notify EPA that they
will submit the data. If the data are not
submitted as required in the order, EPA
will take appropriate action under
FFDCA.
EPA issues a final rule after
considering comments that are
submitted in response to this proposed
rule. In addition to submitting
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comments in response to this proposal,
you may also submit an objection at the
time of the final rule. If you fail to file
an objection to the final rule within the
time period specified, you will have
waived the right to raise any issues
resolved in the final rule. After the
specified time, issues resolved in the
final rule cannot be raised again in any
subsequent proceedings.
II. Background
A. What Action is the Agency Taking?
EPA is proposing to revoke, modify,
and establish specific tolerances for
residues of the fungicides dicloran and
thiophanate-methyl; the herbicides
dicamba, EPTC, hexazinone, picloram,
and propazine; the defoliant and
herbicide cacodylic acid; the plant
growth regulator and herbicide diquat,
the insecticides disulfoton, malathion,
methamidophos, methomyl, phosmet,
piperonyl butoxide, pyrethrins, and
thiodicarb; the fumigant antimicrobial
and insecticide methyl bromide, the
nematicides/insecticides ethoprop and
fenamiphos; and the insecticide
synergist N-octyl bicycloheptene
dicarboximide; revoke the tolerance
exemptions for the insecticide/miticide
pyrethrum and insecticide synergist Noctyl bicycloheptene dicarboximide;
remove certain expired tolerances for
disulfoton, fenamiphos, and
thiophanate-methyl; and reinstate
specific tolerances for methamidophos
residues as a result of the application of
the insecticide acephate in or on
commodities listed in the regulatory
text.
EPA is proposing these tolerance/
tolerance exemption actions to
implement the tolerance
recommendations made during the
reregistration and tolerance
reassessment processes (including
follow-up on canceled or additional
uses of pesticides). As part of these
processes, EPA is required to determine
whether each of the amended tolerances
meets the safety standard of FFDCA.
The safety finding determination of
‘‘reasonable certainty of no harm’’ is
discussed in detail in each
Reregistration Eligibility Decision (RED)
and Report of the Food Quality
Protection Act (FQPA) Tolerance
Reassessment Progress and Risk
Management Decision (TRED) for the
active ingredient. REDs and TREDs
recommend the implementation of
certain tolerance actions, including
modifications to reflect current use
patterns, meet safety findings, and
change commodity names and
groupings in accordance with new EPA
policy. Printed copies of many REDs
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and TREDs may be obtained from EPA’s
National Service Center for
Environmental Publications (EPA/
NSCEP), P.O. Box 42419, Cincinnati,
OH 45242–2419; telephone number: 1–
800–490–9198; fax number: 1–513–489–
8695; Internet at https://www.epa.gov/
ncepihom and from the National
Technical Information Service (NTIS),
5285 Port Royal Rd., Springfield, VA
22161; telephone number: 1–800–553–
6847 or (703) 605–6000; Internet at
https://www.ntis.gov. Electronic copies of
REDs and TREDs are available on the
Internet in public dockets; REDs for
cacodylic acid (EPA–HQ–OPP–2006–
0201), dicamba (EPA–HQ–OPP–2005–
0479), ethoprop (EPA–HQ–OPP–2002–
0269), malathion (EPA–HQ–OPP–2004–
0348), N-octyl bicycloheptene
dicarboximide (EPA–HQ–OPP–2005–
0040), pyrethrum (see pyrethrins RED in
EPA–HQ–OPP–2005–0043), and
thiophanate-methyl (EPA–HQ–OPP–
2004–0265), and TREDs for hexazinone
(EPA–HQ–OPP–2002–0188) and
propazine (EPA–HQ–OPP–2005-0496) at
https://www.regulations.gov and REDs
for acephate, EPTC, methamidophos,
phosmet, and picloram at https://
www.epa.gov/pesticides/reregistration/
status.htm.
The selection of an individual
tolerance level is based on crop field
residue studies designed to produce the
maximum residues under the existing or
proposed product label. Generally, the
level selected for a tolerance is a value
slightly above the maximum residue
found in such studies, provided that the
tolerance is safe. The evaluation of
whether a tolerance is safe is a separate
inquiry. EPA recommends the raising of
a tolerance when data show that:
• Lawful use (sometimes through a
label change) may result in a higher
residue level on the commodity.
• The tolerance remains safe,
notwithstanding increased residue level
allowed under the tolerance.
In REDs, Chapter IV on ‘‘Risk
management, Reregistration, and
Tolerance reassessment’’ typically
describes the regulatory position, FQPA
assessment, cumulative safety
determination, determination of safety
for U.S. general population, and safety
for infants and children. In particular,
the human health risk assessment
document which supports the RED
describes risk exposure estimates and
whether the Agency has concerns. In
TREDs, the Agency discusses its
evaluation of the dietary risk associated
with the active ingredient and whether
it can determine that there is a
reasonable certainty (with appropriate
mitigation) that no harm to any
population subgroup will result from
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aggregate exposure. EPA also seeks to
harmonize tolerances with international
standards set by the Codex Alimentarius
Commission, as described in Unit III.
Explanations for proposed
modifications in tolerances can be
found in the RED and TRED document
and in more detail in the Residue
Chemistry Chapter document which
supports the RED and TRED. Copies of
the Residue Chemistry Chapter
documents are found in the
Administrative Record and electronic
copies for dicamba, ethoprop (Data
Requirements and Tolerance
Reassessment), hexazinone, malathion,
N-octyl bicycloheptene dicarboximide,
propazine, pyrethrum (see pyrethrins),
and thiophanate-methyl can be found
under their respective public docket ID
numbers, identified in Unit II.A.
Electronic copies are also available in
public dockets for acephate (EPA–HQ–
OPP–2007–0445), cacodylic acid (EPA–
HQ–OPP–2006–0201), methamidophos
(EPA–HQ–OPP–2007–0261), and
phosmet (EPA–HQ–OPP–2008–0834),
and for EPTC in the public docket for
this proposed rule. Electronic copies are
available through EPA’s electronic
public docket and comment system,
regulations.gov at https://
www.regulations.gov. You may search
for this proposed rule under docket ID
number EPA–HQ–OPP–2010-0262, then
click on that docket ID number to view
its contents.
EPA has determined that the aggregate
exposures and risks are not of concern
for the above mentioned pesticide active
ingredients based upon the data
identified in the RED or TRED which
lists the submitted studies that the
Agency found acceptable.
EPA has found that the tolerances/
tolerance exemptions that are proposed
in this document to be modified, are
safe; i.e., that there is a reasonable
certainty that no harm will result to
infants and children from aggregate
exposure to the pesticide chemical
residues, in accordance with FFDCA
section 408(b)(2)(C). (Note that changes
to tolerance nomenclature do not
constitute modifications of tolerances).
These findings are discussed in detail in
each RED or TRED. The references are
available for inspection as described in
this document under SUPPLEMENTARY
INFORMATION.
In addition, EPA is proposing to
revoke certain specific tolerances/
tolerance exemptions because either
they are no longer needed or are
associated with food uses that are no
longer registered under FIFRA. Those
instances where registrations were
canceled were because the registrant
failed to pay the required maintenance
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fee and/or the registrant voluntarily
requested cancellation of one or more
registered uses of the pesticide. It is
EPA’s general practice to propose
revocation of those tolerances/tolerance
exemptions for residues of pesticide
active ingredients on crop uses for
which there are no active registrations
under FIFRA, unless any person in
comments on the proposal indicates a
need for the tolerance to cover residues
in or on imported commodities or
legally treated domestic commodities.
1. Acephate. In order to describe more
clearly the measurement and scope or
coverage of the tolerances, EPA is
proposing to revise the introductory text
containing the tolerance expression in
40 CFR 180.108(a)(1) to read as follows:
Tolerances are established for residues of
acephate, O,S-dimethyl acetyl
phosphoramidothioate, including its
metabolites and degradates other than
methamidophos, in or on the commodities in
the table in this paragraph. Compliance with
the tolerance levels specified in this
paragraph is to be determined by measuring
only acephate, O,S-dimethyl acetyl
phosphoramidothioate, in or on the
commodity.
In the Federal Register of January 29,
2008 (73 FR 5104) (FRL–8348–8), EPA
revised the tolerance expression for
acephate in 40 CFR 180.108 from the
combined residues of acephate, O,Sdimethyl acetyl phosphoramidothioate,
and methamidophos, O,S-dimethyl
phosphoramidothioate, to residues of
acephate per se, removed the
terminology ‘‘of which no more than 1
ppm, 0.5 ppm, or 0.1 ppm is O,Sdimethyl phosphoramidothioate’’ from
tolerances on bean (succulent and dry);
Brussels sprouts; cauliflower; celery;
cranberry; lettuce, head; mint hay, and
pepper; and footnoted that residues of
the acephate metabolite,
methamidophos, are regulated under 40
CFR 180.315. However, the basis for this
action was in error, as methamidophos
tolerances for bean, dry, seed; bean,
succulent; cranberry; peppermint, tops;
and spearmint, tops had not in fact been
established in 40 CFR 180.315. To
remedy this inadvertent error, the
Agency proposes to reinstate the 40 CFR
180.108 tolerances. Consequently, EPA
is proposing to separate tolerances for
residues of methamidophos from the
application of acephate in newly
designated 40 CFR 180.108(a)(3), with
the introductory text to read as follows:
Tolerances are established for residues of
methamidophos, O,S-dimethyl
phosphoramidothioate, including its
metabolites and degradates, in or on the
commodities in the table in this paragraph as
a result of the application of acephate.
Compliance with the tolerance levels
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specified in this paragraph is to be
determined by measuring only
methamidophos, O,S-dimethyl
phosphoramidothioate, in or on the
commodity.
In addition, EPA is proposing to
reinstate the tolerances in 40 CFR
180.108(a)(3) on bean, dry, seed at 1
ppm; bean, succulent at 1 ppm; Brussels
sprouts at 0.5 ppm; cauliflower at 0.5
ppm (which is in harmony with the
Codex maximumn residue limits (MRL)
of 0.5 milligrams/kilogram (mg/kg) on
cauliflower); celery 1 ppm; cranberry at
0.1 ppm; lettuce, head at 1 ppm; pepper
at 1 ppm; and reinstate mint hay,
revising the tolerance terminology to
peppermint, tops at 1 ppm and
spearmint, tops at 1 ppm. On January
29, 2008, EPA published a final rule in
the Federal Register (73 FR 5104) (FRL–
8348–8), which finalized tolerance
actions for several active ingredients,
including acephate, and which
increased the tolerances in 40 CFR
180.108(a)(1) for acephate residues in or
on mint hay (peppermint, tops and
spearmint, tops) from 15.0 to 27.0 ppm.
Consequently, methamidophos residues
resulting from acephate application are
expected by the Agency to be increased
from 1.0 to 2.0 ppm in or on
peppermint, tops and spearmint, tops.
However, the Agency is not proposing
an increase on the peppermint, tops and
spearmint, tops tolerances for
methamidophos residues at this time.
Based on available data that showed
residues of acephate were as high as
0.02 ppm for only one of seven exposed
food items following both a spot
treatment and crack/crevice treatment
for rooms treated with acephate at the
1x rate and residues of methamidophos
were undetectable from these acephate
treatments, the Agency determined that
a tolerance level of 0.02 ppm for
acephate residues was appropriate and
that there was no expectation of
methamidophos residues and therefore
no methamidophos tolerance was
needed concerning food handling
establishments. Consequently,
compliance with the tolerance at 0.02
ppm in 40 CFR 180.108(a)(2) should
continue to be determined by measuring
only acephate residues. However, in
order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.108(a)(2), to read as follows:
A tolerance of 0.02 ppm is established for
residues of acephate, O,S-dimethyl acetyl
phosphoramidothioate, including its
metabolites and degradates other than
methamidophos, in or on all food items
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(other than those already covered by a higher
tolerance as a result of use on growing crops)
in food handling establishments where food
and food products are held, processed,
prepared and served, including food service,
manufacturing and processing
establishments, such as restaurants,
cafeterias, supermarkets, bakeries, breweries,
dairies, meat slaughtering and packing
plants, and canneries, where application of
acephate shall be limited solely to spot and/
or crack and crevice treatment (a coarse, lowpressure spray shall be used to avoid
atomization or splashing of the spray for spot
treatments; equipment capable of delivering
a pin-stream of insecticide shall be used for
crack and crevice treatments). Spray
concentration shall be limited to a maximum
of 1.0 percent active ingredient.
Contamination of food or food-contact
surfaces shall be avoided. Compliance with
the tolerance levels specified in this
paragraph is to be determined by measuring
only acephate, O,S-dimethyl acetyl
phosphoramidothioate, in or on the
commodity.
Because EPA is proposing to revise 40
CFR 180.108(a)(2) and include text from
40 CFR 180.108(a)(2)(i) and (a)(2)(ii),
existing paragraphs (a)(2)(i) and (a)(2)(ii)
are no longer needed. Therefore, EPA is
proposing to remove 40 CFR
180.108(a)(2)(i) and (a)(2)(ii).
In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the regional tolerance expression in 40
CFR 180.108(c) to read as follows:
A tolerance with a regional registration is
established for residues of acephate, O,Sdimethyl acetyl phosphoramidothioate,
including its metabolites and degradates
other than methamidophos, in or on the
commodity in the table in this paragraph.
Compliance with the tolerance level
specified in this paragraph is to be
determined by measuring only acephate, O,Sdimethyl acetyl phosphoramidothioate, in or
on the commodity.
Also, EPA is proposing to revise the
table footnote in 40 CFR 180.108(a)(1)
and add a table footnote in 40 CFR
180.108(c) to read as follows:
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Where there is a direct use of
methamidophos on the commodity, residues
of methamidophos resulting from
methamidophos application are regulated
under 40 CFR 180.315.
There are Codex MRLs for acephate,
including those on beans, except broad
bean and soya bean at 5 mg/kg,
cauliflower at 2 mg/kg, cranberry at 0.5
mg/kg, peppers, chili (dry) at 50 mg/kg,
and other commodities.
2. Cacodylic acid. In the Federal
Register notice of July 8, 2009 (74 FR
32596) (FRL–8422–6), EPA issued a
notice regarding EPA’s announcement
of the receipt of requests from
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registrants to voluntarily cancel certain
registrations, including ones for
cacodylic acid (and sodium salt) and
therefore terminate the last cacodylic
acid (and sodium salt) uses in or on
cotton. After the close of the 30–day
comment period, EPA approved
cancellation of certain registrations,
including the cacodylic acid (and
sodium salt) registrations for uses in or
on cotton and issued a cancellation
order in the Federal Register notice of
September 30, 2009 (74 FR 50187)(FRL–
8437–7), made them effective on
September 30, 2009, and prohibited the
registrants for the canceled cacodylic
acid (and sodium salt) registrations to
sell and distribute existing stocks after
December 31, 2009. Also, EPA
prohibited persons other than the
registrant to sell and distribute the
canceled cacodylic acid (and sodium
salt) existing stocks after December 31,
2010. The Agency believes that end
users will have had sufficient time to
exhaust those existing stocks and for
treated cotton commodities to have
cleared the channels of trade by January
1, 2012. The termination of the last
cacodylic acid (and sodium salt) uses in
or on cotton means that the tolerance
will no longer be needed and should be
revoked with an expiration/revocation
date. Therefore, EPA is proposing to
revoke the tolerance in 40 CFR
180.311(a) on cotton, undelinted seed
with an expiration/revocation date of
January 1, 2012.
Currently, tolerances are expressed for
the defoliant cacodylic acid in 40 CFR
180.311(a) for residues of cacodylic acid
(dimethylarsinic acid), expressed as
As2O3. In order to describe more clearly
the measurement and scope or coverage
of the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.311(a) to read as follows:
A tolerance is established for residues of
the defoliant cacodylic acid, dimethylarsinic
acid, including its metabolites and
degradates, in or on the commodity in the
table in this paragraph. Compliance with the
tolerance level specified in this paragraph is
to be determined by measuring only those
cacodylic acid residues convertible to As2O3,
expressed as the stoichiometric equivalent of
cacodylic acid, in or on the commodity.
There are no Codex MRLs for
cacodylic acid.
3. Dicamba. Based on available
processing data that showed an average
concentration factor of 24.4X for
molasses and the Highest Average Field
Trial (HAFT) residue of 0.183 ppm for
sugarcane, EPA determined that the
expected combined dicamba residues of
concern in sugarcane molasses are 4.465
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ppm, and that the currently established
tolerance of 2.0 ppm for sugarcane
molasses should be increased from 2.0
to 5.0 ppm. Therefore, the Agency is
proposing to increase the tolerance in 40
CFR 180.227(a)(1) on sugarcane,
molasses to 5.0 ppm. The Agency
determined that the increased tolerance
is safe; i.e., there is a reasonable
certainty that no harm will result from
aggregate exposure to the pesticide
chemical residue.
Based on available sugarcane field
trial data that showed combined
dicamba residues of concern as high as
0.2 ppm in or on sugarcane harvested
87-173 days following a single layby
application at 2.0 lb dicamba acid
equivalents per acre (ae/A), EPA
determined that the tolerance should be
increased from 0.1 to 0.3 ppm. While
the available data, conducted at an
application rate of 2.0 lb dicamba ae/A,
do not support the maximum seasonal
single/yearly rate of 2.8 lb dicamba ae/
A that was listed in the Dicamba Master
Use Profile, the Agency determined that
the available data was adequate
provided the registrants revise their
product labels to specify a maximum
seasonal rate of 2.0 lb dicamba ae/A and
an 87–day preharvest interval (PHI) for
sugarcane or submit additional data on
sugarcane reflecting a maximum single/
yearly rate of 2.8 lb dicamba ae/A. In
response to the Data Call-In (DCI) of
June 27, 2008 that was issued to
registrants, including the basic
manufacturer BASF, BASF requested a
waiver of the sugarcane study at 2.8 lb
dicamba ae/A and cited MRID
44089302, and accepted rate limitations
of 1 lb dicamba ae/A for single
application, and an annual rate
limitation of 2 lb dicamba ae/A. The
Agency considers that available data to
be sufficient provided product labels
specify a maximum seasonal rate of 2.0
lb dicamba ae/A and an 87–day PHI for
sugarcane. Therefore, because the
current tolerance on sugarcane, cane at
0.1 ppm is too low, based on the
available data, EPA is proposing to
increase the tolerance in 40 CFR
180.227(a)(1) on sugarcane, cane to 0.3
ppm. The Agency determined that the
increased tolerance is safe; i.e., there is
a reasonable certainty that no harm will
result from aggregate exposure to the
pesticide chemical residue.
In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.227(a)(1) to read as follows:
Tolerances are established for residues of
the herbicide dicamba, 3,6-dichloro-o-anisic
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acid, including its metabolites and
degradates, in or on the commodities in the
table in this paragraph. Compliance with the
tolerance levels specified in this paragraph is
to be determined by measuring only the sum
of dicamba, 3,6-dichloro-o-anisic acid, and
its metabolite, 3,6-dichloro-5-hydroxy-oanisic acid, calculated as the stoichiometric
equivalent of dicamba, in or on the
commodity.
In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.227(a)(2) to read as follows:
Tolerances are established for residues of
the herbicide dicamba, 3,6-dichloro-o-anisic
acid, including its metabolites and
degradates, in or on the commodities in the
table in this paragraph. Compliance with the
tolerance levels specified in this paragraph is
to be determined by measuring only the sum
of dicamba, 3,6-dichloro-o-anisic acid, and
its metabolite, 3,6-dichloro-2-hydroxybenzoic
acid, calculated as the stoichiometric
equivalent of dicamba, in or on the
commodity.
In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.227(a)(3) to read as follows:
jlentini on DSKJ8SOYB1PROD with PROPOSALS2
Tolerances are established for residues of
the herbicide dicamba, 3,6-dichloro-o-anisic
acid, including its metabolites and
degradates, in or on the commodities in the
table in this paragraph. Compliance with the
tolerance levels specified in this paragraph is
to be determined by measuring only the sum
of dicamba, 3,6-dichloro-o-anisic acid, and
its metabolites, 3,6-dichloro-5-hydroxy-oanisic acid, and 3,6-dichloro-2hydroxybenzoic acid, calculated as the
stoichiometric equivalent of dicamba, in or
on the commodity.
There are no Codex MRLs for
dicamba.
4. Dicloran (DCNA). On December 2,
2009, EPA published a notice in the
Federal Register (74 FR 63151) (FRL–
8800–4) that announced the Agency’s
receipt of requests from the registrants
to voluntarily amend certain dicloran
registrations and therefore terminate the
last dicloran uses on carrots. EPA
approved amendment of the affected
DCNA registrations by publishing a
cancellation order on March 31, 2010 in
the Federal Register (75 FR 16105)
(FRL–8815–8) and made them effective
on November 2, 2010, and permitted the
dicloran registrant to sell and distribute
existing dicloran stocks (concerning the
last uses for carrots) until November 2,
2010. For all affected dicloran products,
the Agency permitted persons other
than the registrant to sell and distribute
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existing stocks and use of those
cancelled products until exhaustion.
However, the Agency believes that end
users will have had sufficient time to
exhaust those existing stocks and for
treated carrot commodities to have
cleared the channels of trade by
November 2, 2011. Therefore, EPA is
proposing to revoke the tolerance in 40
CFR 180.200(a)(1) for carrot, roots,
postharvest with an expiration/
revocation date of November 2, 2011.
In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.200(a)(1) to read as follows:
Tolerances are established for residues of
the fungicide dicloran, 2,6-dichloro-4nitroaniline, including its metabolites and
degradates, in or on the commodities in the
table in this paragraph. Compliance with the
tolerance levels specified in this paragraph is
to be determined by measuring only dicloran,
2,6-dichloro-4-nitroaniline, in or on the
commodity. Unless otherwise specified,
these tolerances prescribed in this paragraph
provide for residues from preharvest
application only.
There are Codex MRLs for dicloran,
including an MRL on carrot at 15 mg/
kg, and MRLs on other plant
commodities.
5. Diquat. Currently, the only active
registrations for diquat use on both
sorghum grain and soybeans are for seed
crops, and both uses have restrictions to
not graze or feed treated forage to
livestock and not use seed from treated
plants for food, feed, or oil purposes.
Given the restrictions, such uses are
considered by the Agency to be nonfood, and therefore the tolerances are no
longer needed and should be revoked.
Consequently, EPA is proposing to
revoke the tolerances in 40 CFR
180.226(a)(1) on sorghum, grain, grain
and soybean, seed.
There are Codex MRLs for diquat on
sorghum at 2 mg/kg and on soybean
(dry) at 0.2 mg/kg.
6. Disulfoton. On July 22, 2009, EPA
published a notice in the Federal
Register (74 FR 36204) (FRL–8427–2)
that announced the Agency’s receipt of
requests from the registrants to
voluntarily cancel all disulfoton and
methamidophos registrations and
therefore terminate the last disulfoton
and methamidophos products registered
for use in the United States, including
the last disulfoton uses on asparagus,
lima and snap beans, broccoli, Brussels
sprouts, cabbage, cauliflower, coffee,
cotton, and lettuce. EPA approved
cancellation of the registrations by
publishing a cancellation order on
September 23, 2009 in the Federal
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Register (74 FR 48551) (FRL–8437–1)
and made them effective on September
23, 2009, and permitted the disulfoton
registrants to sell and distribute existing
disulfoton stocks (concerning the last
uses for asparagus, lima and snap beans,
broccoli, Brussels sprouts, cabbage,
cauliflower, cotton, and lettuce) until
December 31, 2010 and stocks of a
single registration (264-723) with the
last coffee use until June 30, 2011. For
all affected disulfoton products, the
Agency permitted persons other than
the registrant to sell and distribute
existing stocks and use of those
cancelled products until exhaustion.
However, the Agency believes that end
users will have had sufficient time to
exhaust those existing stocks and for
treated asparagus, lima and snap beans,
broccoli, Brussels sprouts, cabbage,
cauliflower, cotton, and lettuce
commodities to have cleared the
channels of trade by December 31, 2012
and treated coffee commodities to have
cleared the channels of trade by June 30,
2013. Therefore, EPA is proposing to
revoke the tolerances in 40 CFR
180.183(a) for bean, lima; bean, snap,
succulent; broccoli; Brussels sprouts;
cabbage; cauliflower; cotton, undelinted
seed; lettuce, head; and lettuce, leaf
with expiration/revocation dates of
December 31, 2012. Also, because there
had been only active FIFRA section
24(c) registrations for use of disulfoton
on asparagus, EPA is proposing to
revoke the regional tolerance in 40 CFR
180.183(c) on asparagus with an
expiration/revocation date of December
31, 2012. In addition, EPA is proposing
to revoke the tolerance in 40 CFR
180.183(a) for coffee, green bean with an
expiration/revocation date of June 30,
2013.
Because the tolerances for combined
disulfoton residues of concern expired
on October 14, 2009, EPA is proposing
to remove the tolerances in 40 CFR
180.183(a) on spinach and tomato. Also,
because the tolerances for combined
disulfoton residues of concern expired
on January 30, 2010, EPA is proposing
to remove the tolerances in 40 CFR
180.183(a) on barley, grain; barley,
straw; cattle, fat; cattle, meat; cattle,
meat byproducts; goat, fat; goat, meat;
goat, meat byproducts; grain, aspirated
fractions; hog, fat; hog, meat; hog, meat
byproducts; horse, fat; horse, meat;
horse, meat byproducts; milk; peanut;
pepper; potato; sheep, fat; sheep, meat;
sheep, meat byproducts; wheat, grain;
wheat, hay; and wheat, straw.
In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the section heading in 40 CFR
180.183 from O,O-diethyl S-(2-
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(ethylthio)ethyl) phosphorodithioate to
disulfoton and revise the introductory
text containing the tolerance expression
in 40 CFR 180.183(a) to read as follows:
Tolerances are established for residues of
the insecticide disulfoton, O,O-diethyl S-(2(ethylthio)ethyl) phosphorodithioate,
including its metabolites and degradates, in
or on the commodities in the table in this
paragraph. Compliance with the tolerance
levels specified in this paragraph is to be
determined by measuring only the sum of
disulfoton, O,O-diethyl S-(2-(ethylthio)ethyl)
phosphorodithioate, and its metabolites
demeton-S,O,O-diethyl S-(2-(ethylthio)ethyl)
phosphorothioate; disulfoton sulfoxide, O,Odiethyl S-(2-(ethylsulfinyl)ethyl)
phosphorodithioate; disulfoton oxygen
analog sulfoxide, O,O-diethyl S-(2(ethylsulfinyl)ethyl) phosphorothioate,
disulfoton sulfone, O,O-diethyl S-(2(ethylsulfonyl)ethyl) phosphorodithioate;
and disulfoton oxygen analog sulfone, O,Odiethyl S-(2-(ethylsulfonyl)ethyl)
phosphorothioate; calculated as the
stoichiometric equivalent of disulfoton, in or
on the commodity.
In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the regional tolerance expression in 40
CFR 180.183(c) to read as follows:
jlentini on DSKJ8SOYB1PROD with PROPOSALS2
A tolerance with regional registration is
established for residues of the insecticide
disulfoton, O,O-diethyl S-(2-(ethylthio)ethyl)
phosphorodithioate, including its metabolites
and degradates, in or on the commodity in
the table in this paragraph. Compliance with
the tolerance levels specified in this
paragraph is to be determined by measuring
only the sum of disulfoton, O,O-diethyl S-(2(ethylthio)ethyl) phosphorodithioate, and its
metabolites demeton-S, O,O-diethyl S-(2(ethylthio)ethyl) phosphorothioate;
disulfoton sulfoxide, O,O-diethyl S-(2(ethylsulfinyl)ethyl) phosphorodithioate;
disulfoton oxygen analog sulfoxide, O,Odiethyl S-(2-(ethylsulfinyl)ethyl)
phosphorothioate, disulfoton sulfone, O,Odiethyl S-(2-(ethylsulfonyl)ethyl)
phosphorodithioate; and disulfoton oxygen
analog sulfone, O,O-diethyl S-(2(ethylsulfonyl)ethyl) phosphorothioate;
calculated as the stoichiometric equivalent of
disulfoton, in or on the commodity.
There are Codex MRLs for disulfoton,
including those on asparagus at 0.02
mg/kg, coffee beans at 0.2 mg/kg,
common bean (pods and/or immature
seeds) at 0.2 mg/kg, cotton, seed at 0.1
mg/kg, and other commodities.
7. EPTC. Because cotton forage is no
longer considered by the Agency to be
a significant livestock feed commodity
as delineated in ‘‘Table 1.—Raw
Agricultural and Processed
Commodities and Feedstuffs Derived
from Crops,’’ which is found in Residue
Chemistry Test Guidelines OPPTS
860.1000, dated August 1996 (available
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at https://www.epa.gov/opptsfrs/
publications/OPPTS_Harmonized/860_
Residue_Chemistry_Test_Guidelines/
Series/), EPA determined that the
tolerance is no longer needed, and
therefore should be revoked.
Consequently, the Agency is proposing
to revoke the tolerance in 40 CFR
180.117 for residues of S-ethyl
dipropylthiocarbamate (EPTC) in or on
cotton, forage.
Because there have been no active Sethyl dipropylthiocarbamate
registrations in the United States for use
on asparagus, small fruits (including
strawberries), flax seeds, and pineapples
for more than 10 years, the tolerances
are no longer needed and therefore
should be revoked. Consequently, EPA
is proposing to revoke the tolerances in
40 CFR 180.117 on asparagus; fruit,
small; strawberry; flax, seed; and
pineapple.
Because castor beans and oil products
are not consumed by humans or
livestock, EPA determined that the
tolerance is no longer needed and
therefore should be revoked.
Consequently, EPA is proposing to
revoke the tolerance in 40 CFR 180.117
on castorbean, seed.
EPA is proposing, in 40 CFR 180.117,
to remove the ‘‘(N)’’ designation from all
entries to conform to current Agency
administrative practice (‘‘N’’ designation
means negligible residues). Also,
tolerances are currently established in
40 CFR 180.117 for negligible residues
of the herbicide S-ethyl
dipropylthiocarbamate, also called
EPTC. EPA determined that EPTC plant
residues of toxicological concern are
EPTC, EPTC sulfoxide, EPTC sulfone,
and the EPTC conjugates (glutathione,
cysteine, N-malonyl cysteine, S-lactic
acid, and O-malonyl S-lactic acid
conjugates). However, the Agency
concurred with the registrant’s position
that development of a single
enforcement analytical method that can
detect each of these residues was not
feasible. Because development of an
enforcement analytical method for the
hydroxylated metabolites (S-ethyl (2hydroxypropyl)propylcarbamothioate,
S-(2-hydroxyethyl)dipropyl
carbamothioate, and S-ethyl (3hydroxypropyl)propylcarbamothioate)
was feasible, the Agency concurred with
the registrant’s recommendation that
EPTC and its hydroxylated metabolites
be used as marker residues of EPTC
residues of toxicological concern.
Therefore, in order to describe more
clearly the measurement and scope or
coverage of the tolerances, EPA is
proposing to redesignate the existing
paragraph from 40 CFR 180.117 to
180.117(a) and revise the introductory
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28161
text containing the tolerance expression
in newly designated 40 CFR 180.117(a)
to include its hydroxylated metabolites
as marker residues of S-ethyl
dipropylthiocarbamate residues of
toxicological concern (i.e., markers of
EPTC, EPTC sulfoxide, EPTC sulfone,
and the EPTC conjugates resulting from
the glutathione-S-transferase pathway),
to read as follows:
Tolerances are established for residues of
the herbicide S-ethyl dipropylthiocarbamate,
including its metabolites and degradates, in
or on the commodities in the table in this
paragraph. Compliance with the tolerance
levels specified in this paragraph is to be
determined by measuring only the sum of Sethyl dipropylthiocarbamate, S-ethyl (2hydroxypropyl)propylcarbamothioate, S-(2hydroxyethyl)dipropylcarbamothioate, and
S-ethyl (3hydroxypropyl)propylcarbamothioate,
calculated as the stoichiometric equivalent of
S-ethyl dipropylthiocarbamate, in or on the
commodity.
The majority of the current crop
groupings for residues of EPTC are
based on obsolete crop groupings and,
for many, the minimum data
requirements for the establishment of
crop group tolerances were not satisfied.
Therefore, in the EPTC RED, the Agency
recommended revocation of crop group
tolerances, concomitant with the
establishment of individual tolerances
for the affected commodities.
Based on available field trial data that
showed residues of S-ethyl
dipropylthiocarbamate and its
hydroxylated metabolites were <0.09
ppm in or on potatoes and <0.11 ppm
in on sugar beet roots, the Agency
determined that the tolerance for the
obsolete group, vegetable, root, should
be revoked and individual tolerances
should be established for beet, garden,
roots; beet, sugar, roots; potato; and
sweet potato (based on translation of
available data from potatoes). Therefore,
EPA is proposing in newly designated
and revised 40 CFR 180.117(a) to revoke
the tolerance on vegetable, root at 0.1
ppm and establish tolerances on beet,
garden, roots at 0.1 ppm; beet, sugar,
roots at 0.1 ppm; potato at 0.1 ppm; and
sweet potato, roots at 0.1 ppm. Also,
based on processing data that showed
combined residues of EPTC and its
hydroxylated metabolites were as high
as <0.80 ppm in molasses that was
processed from the raw agricultural
commodity (sugar beet roots) with
residues as high as <0.2 ppm (after
application at 2X the maximum
exposure rate), the Agency determined
that combined residues had
concentrated in molasses by a factor of
4X and that after a 1X application on
sugar beet roots, residues in molasses
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would be expected at <0.1 ppm.
Therefore, EPA is proposing to establish
a tolerance in newly designated and
revised 40 CFR 180.117(a) on beet,
sugar, molasses at 0.4 ppm.
Based on available field trial data that
showed residues of S-ethyl
dipropylthiocarbamate and its
hydroxylated metabolites were nondetectable (<0.05 ppm and <0.01 ppm
for each of the three hydroxylated
metabolites; i.e., the Limit of
Quantitation (LOQ) of the enforcement
method for EPTC and its hydroxylated
metabolites, respectively) in or on
almond nutmeats and hulls, and walnut
nutmeats, the Agency determined that
the tolerance for the obsolete group, nut,
should be revoked and individual
tolerances should be established for
almond, nutmeat and walnut, nutmeat;
each at 0.08 ppm (0.05 ppm for EPTC
and 0.03 ppm for the combined
hydroxylated metabolites), and decrease
almond, hulls from 0.1 ppm to 0.08
ppm. Therefore, EPA is proposing in
newly designated and revised 40 CFR
180.117(a) to revoke the tolerance on
nut at 0.1 ppm and establish tolerances
on almond at 0.08 ppm and walnut at
0.08 ppm, and decrease the tolerance on
almond, hulls to 0.08 ppm.
Based on available field trial data that
showed residues of S-ethyl
dipropylthiocarbamate and its
hydroxylated metabolites were nondetectable (<0.05 ppm and <0.01 ppm
for each of the three hydroxylated
metabolites; i.e., the LOQ of the
enforcement method for EPTC and its
hydroxylated metabolites, respectively)
in or on tomatoes, the Agency
determined that the tolerance for the
obsolete group, vegetable, fruiting,
should be revoked and an individual
tolerance should be established for
tomato at 0.08 ppm (0.05 ppm for EPTC
and 0.03 ppm for the combined
hydroxylated metabolites). Therefore,
EPA is proposing in newly designated
and revised 40 CFR 180.117(a) to revoke
the tolerance on vegetable, fruiting at
0.1 ppm and establish a tolerance on
tomato at 0.08 ppm.
Based on available field trial data that
showed residues of S-ethyl dipropyl
thiocarbamate were non-detectable
(<0.05 ppm) in or on alfalfa forage and
hay, and clover forage and hay, and
maximum total residues of EPTC
hydroxylated metabolites were 0.18
ppm in or on alfalfa forage, 0.61 ppm in
or on alfalfa hay, 0.01 ppm in or on
clover forage, and 0.05 ppm in or on
clover hay, the Agency determined that
the tolerance for the obsolete group,
legume, forage, should be revoked and
individual tolerances should be
established for alfalfa, forage at 0.2 ppm
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and alfalfa, hay at 0.6 ppm, clover,
forage at 0.1 ppm, and clover, hay at 0.1
ppm. Also, the Agency determined that
the data for clover forage and hay can
be translated to the forage and hay of
trefoil and lespedeza, and therefore
individual tolerances for each of them
should be established at 0.1 ppm.
Consequently, EPA is proposing in
newly designated and revised 40 CFR
180.117(a) to revoke the tolerance on
legume, forage at 0.1 ppm and establish
tolerances on alfalfa, forage at 0.2 ppm,
alfalfa, hay at 0.6 ppm, clover, forage at
0.1 ppm, clover, hay at 0.1 ppm,
lespedeza, forage at 0.1 ppm, lespedeza,
hay at 0.1 ppm, trefoil, forage at 0.1
ppm, and trefoil, hay at 0.1 ppm.
Based on available field trial data that
showed residues of S-ethyl
dipropylthiocarbamate were nondetectable (<0.05 ppm) in or on sugar
beet tops, and maximum total residues
of EPTC and its hydroxylated
metabolites were <0.47 ppm in or on
sugar beet tops, the Agency determined
that the tolerance for the obsolete group,
vegetable, leafy, should be revoked and
individual tolerances should be
established for beet, garden, tops at 0.5
ppm and beet, sugar, tops at 0.5 ppm.
Therefore, EPA is proposing in newly
designated and revised 40 CFR
180.117(a) to revoke the tolerance on
vegetable, leafy at 0.1 ppm and establish
tolerances on beet, garden, tops at 0.5
ppm and beet, sugar, tops at 0.5 ppm.
Based on available field trial data that
showed residues of S-ethyl
dipropylthiocarbamate and its
hydroxylated metabolites were nondetectable (<0.05 ppm and <0.01 ppm
for each of the three hydroxylated
metabolites; i.e., the LOQ of the
enforcement method for EPTC and its
hydroxylated metabolites, respectively)
in or on beans (succulent and dry), the
Agency determined that the tolerance
for the obsolete group, vegetable, seed
and pod, should be revoked and
individual tolerances should be
established for bean, dry, seed; bean,
succulent; and pea, succulent (based on
translation of available data from
succulent beans); each at 0.08 ppm (0.05
ppm for EPTC and 0.03 ppm for the
combined hydroxylated metabolites).
Therefore, EPA is proposing in newly
designated and revised 40 CFR
180.117(a) to revoke the tolerance on
vegetable, seed and pod at 0.1 ppm and
establish tolerances on bean, dry, seed
at 0.08 ppm, bean, succulent at 0.08
ppm, and pea, succulent at 0.08 ppm.
Based on available field trial data that
showed residues of S-ethyl
dipropylthiocarbamate and its
hydroxylated metabolites were nondetectable (<0.05 ppm and <0.01 ppm
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for each of the three hydroxylated
metabolites; i.e., the LOQ of the
enforcement method for EPTC and its
hydroxylated metabolites, respectively)
in or on field corn grain or sweet corn
ear, the Agency determined that the
tolerance for the obsolete group, grain,
crop, should be revoked, data could be
translated from field corn grain to
popcorn grain, and individual
tolerances should be established for
corn, field, grain; corn, pop, grain; and
corn, sweet, kernel plus cob with husks
removed; each at 0.08 ppm (0.05 ppm
for EPTC and 0.03 ppm for the
combined hydroxylated metabolites).
Therefore, EPA is proposing in newly
designated and revised 40 CFR
180.117(a) to revoke the tolerance on
grain, crop at 0.1 ppm and establish
tolerances on corn, field, grain at 0.08
ppm, corn, pop, grain at 0.08 ppm, and
corn, sweet, kernel plus cob with husks
removed at 0.08 ppm.
Based on available field trial data that
showed residues of S-ethyl
dipropylthiocarbamate and its
hydroxylated metabolites were nondetectable (<0.05 ppm and <0.01 ppm
for each of the three hydroxylated
metabolites; i.e., the LOQ of the
enforcement method for EPTC and its
hydroxylated metabolites, respectively)
in or on field corn forage and stover,
and sweet corn forage and ears, the
Agency determined that the tolerance
for the obsolete group, grass, forage,
should be revoked, data could be
translated from field corn stover to
popcorn stover, and individual
tolerances should be established for
corn, field, forage; corn, field, stover;
corn, pop, stover; corn, sweet, forage;
and corn, sweet, stover; each at 0.08
ppm (0.05 ppm for EPTC and 0.03 ppm
for the combined hydroxylated
metabolites). Therefore, EPA is
proposing in newly designated and
revised 40 CFR 180.117(a) to revoke the
tolerance on grass, forage at 0.1 ppm
and establish tolerances on corn, field,
forage at 0.08 ppm, corn, field, stover at
0.08 ppm, corn, pop, stover at 0.08 ppm,
corn, sweet, forage at 0.08 ppm, and
corn, sweet, stover at 0.08 ppm.
Based on available field trial data that
showed residues of S-ethyl
dipropylthiocarbamate and its
hydroxylated metabolites were nondetectable (<0.05 ppm and <0.01 ppm
for each of the three hydroxylated
metabolites; i.e., the LOQ of the
enforcement method for EPTC and its
hydroxylated metabolites, respectively)
in or on cottonseed, safflower seeds, and
sunflower seeds, the Agency determined
that the tolerances on cottonseed,
safflower seed, and sunflower seed
should be decreased from 0.1 to 0.08
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ppm (0.05 ppm for EPTC and 0.03 ppm
for the combined hydroxylated
metabolites). Therefore, EPA is
proposing in newly designated and
revised 40 CFR 180.117(a) to decrease
the tolerances on cotton, undelinted
seed to 0.08 ppm; safflower, seed to 0.08
ppm; and sunflower, seed to 0.08 ppm.
Based on available field trial data that
showed residues of S-ethyl
dipropylthiocarbamate and its
hydroxylated metabolites were <0.05
ppm for EPTC and each of the three
hydroxylated metabolites (total
combined residues were <0.20 ppm) in
or on cotton gin byproducts, the Agency
determined that a tolerance should be
established at 0.20 ppm. Therefore, EPA
is proposing in newly designated and
revised 40 CFR 180.117(a) to establish a
tolerance on cotton, gin byproducts at
0.20 ppm.
In accordance with current Agency
practice, EPA is proposing to revise 40
CFR 180.117 by adding separate
paragraphs (b), (c), and (d), and
reserving those paragraphs with
tolerance exemptions for section 18
emergency exemptions, tolerances with
regional registrations, and tolerances
with indirect or inadvertent residues,
respectively. Also EPA is proposing to
revise the nomenclature and tolerance
in newly designated and revised 40 CFR
180.117(a) from ‘‘fruit, citrus’’ to ‘‘fruit,
citrus, group 10.’’
There are no Codex MRLs for EPTC.
8. Ethoprop. On May 27, 2009, EPA
published a notice in the Federal
Register (74 FR 25237) (FRL–8418–2)
that announced the Agency’s receipt of
request from the registrant to voluntarily
amend a registration and therefore
terminate the last ethoprop use in the
United States on pineapple. EPA
approved amendment of the registration
by issuing a cancellation order on July
9, 2009 to the registrant, made it
effective on July 23, 2009, and permitted
the registrant to sell and distribute
existing ethoprop stocks of the amended
registration (concerning pineapple use
deletion) for 18 months after July 9,
2009; i.e., until January 9, 2011. The
Agency permitted persons other than
the registrant to sell and distribute
existing stocks and use of the affected
ethoprop product until exhaustion.
However, the Agency believes that end
users will have had sufficient time to
exhaust those existing stocks and for
ethoprop treated pineapple
commodities to have cleared the
channels of trade by January 9, 2012.
Therefore, EPA is proposing to revoke
the tolerance in 40 CFR 180.262(a) for
pineapple with an expiration/revocation
date of January 9, 2012.
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Because there have been no active
registrations in the United States for
ethoprop use on popcorn for more than
10 years, and therefore, tolerances
covering popcorn use are no longer
needed, EPA is proposing to revoke the
tolerances in 40 CFR 180.262(a) on corn,
pop, grain and corn, pop, stover.
In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.262(a) to read as follows:
Tolerances are established for residues of
the nematocide and insecticide ethoprop, Oethyl S,S-dipropyl phosphorodithioate,
including its metabolites and degradates, in
or on the commodities in the table in this
paragraph. Compliance with the tolerance
levels specified in this paragraph is to be
determined by measuring only ethoprop, Oethyl S,S-dipropyl phosphorodithioate, in or
on the commodity.
There are no Codex MRLs for
ethoprophos on pineapple or corn, but
there are MRLs for ethoprophos on other
commodities.
9. Fenamiphos. There have been no
active food use registrations for
fenamiphos in the United States since
2007. In a proposed rule that EPA
published in the Federal Register on
February 6, 2008 (73 FR 6867) (FRL–
8345–2), the Agency proposed specific
tolerances for multiple pesticide active
ingredients, including fenamiphos, and
stated that Bayer CropScience informed
the Agency that it would support
fenamiphos tolerances on citrus and
garlic, among others, for import
purposes since there were no active
domestic registrations for those uses. In
January 2010, Bayer CropScience
informed EPA that it no longer was
interested in supporting import
tolerances for residues of fenamiphos in
or on citrus and garlic, but would
continue to support import tolerances
for residues of fenamiphos in or on
banana, grape, and pineapple. Because
no one other than Bayer CropScience
expressed an interest in retaining the
fenamiphos tolerances on citrus and
garlic, there is no longer a need for
them. Therefore, EPA is proposing to
revoke the tolerances in 40 CFR
180.349(a) on citrus, dried pulp; citrus,
oil; fruit, citrus, group 10; and garlic;
add a missing footnote to the tolerance
for grape, raisin to reflect that it has no
U.S. registrations, and revise the
footnoted information for all remaining
tolerances to reflect the effective
cancellation date of the last fenamiphos
registrations in the United States to be
as of May 31, 2007.
Because the tolerances expired on
December 31, 2009, EPA is proposing to
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remove the tolerances in 40 CFR
180.349(a) on apple; Brussels sprouts;
cabbage; cherry, sweet; cherry, tart;
eggplant; okra; peach; peanut; raspberry;
and strawberry; in 180.349(c) on
asparagus; beet, garden, roots; beet,
garden, tops; cabbage, Chinese, bok
choy; kiwifruit; and pepper, nonbell;
and reserve paragraph (c).
Also, in order to describe more clearly
the measurement and scope or coverage
of the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.349(a) to read as follows:
Tolerances are established for residues of
the nematicide/insecticide fenamiphos, ethyl
3-methyl-4-(methylthio)phenyl 1(methylethyl)phosphoramidate, including its
metabolites and degradates, in or on the
commodities in the table in this paragraph.
Compliance with the tolerance levels
specified in this paragraph is to be
determined by measuring only the sum of
fenamiphos, ethyl 3-methyl-4(methylthio)phenyl 1(methylethyl)phosphoramidate, and its
cholinesterase inhibiting metabolites ethyl 3methyl-4-(methylsulfinyl)phenyl 1(methylethyl)phosphoramidate and ethyl 3methyl-4-(methylsulfonyl)phenyl 1(methylethyl)phosphoramidate, calculated as
the stoichiometric equivalent of fenamiphos,
in or on the commodity.
There are Codex MRLs for
fenamiphos, including those on apple;
banana; Brussels sprouts; cabbages,
head; and peanut at 0.05 mg/kg, and
other commodities.
10. Hexazinone. Currently, tolerances
are expressed for the herbicide
hexazinone in 40 CFR 180.396(a)(1) for
the combined residues of hexazinone (3cyclohexyl-6-(dimethylamino)-1methyl-1,3,5-triazine-2,4-(1H, 3H)dione) and its plant metabolites; A (3(4-hydroxycyclohexyl)-6(dimethylamino)-1-methyl-1,3,5triazine-2,4-(1H, 3H)-dione, B (3cyclohexyl-6-(methylamino)-1-methyl1,3,5-triazine-2,4-(1H, 3H)-dione), C (3(4-hydroxycyclohexyl)-6(methylamino)-1-methyl-1,3,5-triazine2,4-(1H, 3H)-dione), D (3-cyclohexyl)-1methyl-1,3,5-triazine-2,4,6-(1H, 3H, 5H)trione), and E (3-(4-hydroxycyclohexyl)1-methyl-1,3,5-triazine-2,4,6-(1H, 3H,
5H)-trione) (calculated as hexazinone).
In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.396(a)(1) to read as follows:
Tolerances are established for residues of
the herbicide hexazinone, 3-cyclohexyl-6(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H, 3H)-dione, including its metabolites and
degradates, in or on the commodities in the
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table in this paragraph. Compliance with the
tolerance levels specified in this paragraph is
to be determined by measuring only the sum
of hexazinone, 3-cyclohexyl-6(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H, 3H)-dione, and its plant metabolites:
metabolite A, 3-(4-hydroxycyclohexyl)-6(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H, 3H)-dione, metabolite B, 3-cyclohexyl-6(methylamino)-1-methyl-1,3,5-triazine-2,4(1H, 3H)-dione, metabolite C, 3-(4hydroxycyclohexyl)-6-(methylamino)-1methyl-1,3,5-triazine-2,4-(1H, 3H)-dione,
metabolite D, 3-cyclohexyl-1-methyl-1,3,5triazine-2,4,6-(1H, 3H, 5H)-trione, and
metabolite E, 3-(4-hydroxycyclohexyl)-1methyl-1,3,5-triazine-2,4,6-(1H, 3H, 5H)trione, calculated as the stoichiometric
equivalent of hexazinone, in or on the
commodity.
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Based on available field trial data that
showed combined hexazinone residues
of concern as high as 183 ppm in or on
grass forage at a 0–day PHI and 133 ppm
in or on grass, hay at a 14 to 38–day
PHI, EPA determined that the tolerance
for grass forage should be increased
from 10 to 250 ppm, and a tolerance for
grass hay should be established at 230
ppm. Therefore, EPA is proposing to
increase the tolerance in 40 CFR
180.396(a)(1) on grass, forage to 250
ppm and establish a tolerance in 40 CFR
180.396(a)(1) on grass, hay at 230 ppm.
The Agency determined that the
increased tolerance is safe; i.e., there is
a reasonable certainty that no harm will
result from aggregate exposure to the
pesticide chemical residue.
Based on available field trial data that
showed combined hexazinone residues
of concern as high as <3.33 ppm in or
on alfalfa hay, EPA determined that the
tolerance on alfalfa hay should be
decreased from 8.0 to 4.0 ppm.
Therefore, the Agency is proposing in
40 CFR 180.396(a)(1) to decrease the
tolerance on alfalfa, hay to 4.0 ppm.
In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.396(a)(2) to read as follows:
Tolerances are established for residues of
the herbicide hexazinone, 3-cyclohexyl-6(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H, 3H)-dione, including its metabolites and
degradates, in or on the commodities in the
table in this paragraph. Compliance with the
tolerance levels specified in this paragraph is
to be determined by measuring only the sum
of hexazinone, 3-cyclohexyl-6(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H, 3H)-dione, and its animal tissue
metabolites: metabolite B, 3-cyclohexyl-6(methylamino)-1-methyl-1,3,5-triazine-2,4(1H, 3H)-dione, and metabolite F, 3cyclohexyl-6-amino-1-methyl-1,3,5-triazine2,4-(1H, 3H)-dione, calculated as the
stoichiometric equivalent of hexazinone, in
or on the commodity.
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In order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.396(a)(3) to read as follows:
A tolerance is established for residues of
the herbicide hexazinone, 3-cyclohexyl-6(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H, 3H)-dione, including its metabolites and
degradates, in or on the commodity in the
table in this paragraph. Compliance with the
tolerance level specified in this paragraph is
to be determined by measuring only the sum
of hexazinone, 3-cyclohexyl-6(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H, 3H)-dione, and its metabolites:
metabolite B, 3-cyclohexyl-6-(methylamino)1-methyl-1,3,5-triazine-2,4-(1H, 3H)-dione,
metabolite C, 3-(4-hydroxycyclohexyl)-6(methylamino)-1-methyl-1,3,5-triazine-2,4(1H, 3H)-dione, metabolite C-2, 3-(3hydroxycyclohexyl)-6-(methylamino)-1methyl-1,3,5-triazine-2,4-(1H, 3H)-dione, and
metabolite F, 3-cyclohexyl-6-amino-1methyl-1,3,5-triazine-2,4-(1H, 3H)-dione,
calculated as the stoichiometric equivalent of
hexazinone, in or on the commodity.
In the Federal Register of September
27, 2006 (71 FR 56392) (FRL–8089–6),
EPA published a final tolerance rule for
several active pesticide ingredients,
including hexazinone. Because the
Agency received a comment from
DuPont Crop Protection which stated
that it would be submitting grass
residue data and expected increased
residues that would warrant revision of
existing tolerances for both grass and
hay as livestock feed commodities, EPA
did not finalize revocation of certain
livestock tolerances for hexazinone, in
40 CFR 180.396, at that time. Upon
review of the submitted data, EPA has
determined that tolerances on the fat of
cattle, goats, hogs, horses, and sheep
should be maintained at 0.1 ppm.
However, based on available field trial
data for grass and hay, and a
recalculation of dietary burden that
show the maximum total hexazinone
residues were 3.85 ppm in liver, 2.19
ppm in kidney, 0.32 ppm in muscle,
<0.1 ppm in fat, and 11.09 ppm in milk,
the Agency determined that meat
byproduct tolerances of cattle, goats,
hogs, horses, and sheep should be
increased from 0.1 to 4.0 ppm; meat
tolerances of cattle, goats, hogs, horses,
and sheep should be increased from 0.1
to 0.5 ppm, and the milk tolerance
should be increased from 0.2 to 11 ppm.
Therefore, EPA is proposing to increase
the tolerances in 40 CFR 180.396(a)(2)
on cattle, meat byproducts; goat, meat
byproducts; hog, meat byproducts;
horse, meat byproducts; and sheep,
meat byproducts; each to 4.0 ppm; and
on cattle, meat; goat, meat; hog, meat;
horse, meat; and sheep, meat; each to
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0.5 ppm. Also, EPA is proposing to
increase the tolerance in 40 CFR
180.396(a)(3) on milk to 11 ppm. The
Agency determined that the increased
tolerances are safe; i.e., there is a
reasonable certainty that no harm will
result from aggregate exposure to the
pesticide chemical residue.
Also, in the Federal Register of
September 27, 2006 (71 FR 56392), EPA
agreed with a comment from DuPont
Crop Protection which stated that
registrations for use of hexazinone on
sugarcane in Florida are active and that
the current regional tolerances for
sugarcane be designated as general
tolerances. Therefore, EPA is proposing
to revoke the regional tolerances in 40
CFR 180.396(c) on sugarcane, cane at
0.6 ppm and sugarcane, molasses at 4.0
ppm, reserve paragraph (c) for
tolerances with regional registrations,
and establish tolerances in 40 CFR
180.396(a)(1) on sugarcane, cane at 0.6
ppm and sugarcane, molasses at 4.0
ppm.
There are no Codex MRLs for
hexazinone.
11. Malathion. Based on available
ruminant and poultry metabolism data
at exaggerated feeding rates of
malathion–treated livestock feeds and
that no active registrations for direct
animal treatment with malathion have
existed since March 2005, EPA
determined that there is no reasonable
expectation of finite residues of
malathion in fat, meat, and meat
byproducts of cattle, goats, hogs, horses,
poultry, and sheep; milk fat; and eggs.
These tolerances are no longer needed
under 40 CFR 180.6(a)(3). Therefore,
EPA is proposing to revoke the
tolerances in 40 CFR 180.111(a)(3) for
residues of malathion in or on egg; milk,
fat; cattle, fat; cattle, meat; cattle, meat
byproducts; goat, fat; goat, meat; goat,
meat byproducts; hog, fat; hog, meat;
hog, meat byproducts; horse, fat; horse,
meat; horse, meat byproducts; poultry,
fat; poultry, meat; poultry, meat
byproducts; sheep, fat; sheep, meat; and
sheep, meat byproducts; and therefore,
remove paragraph (a)(3) in its entirety,
including its footnote.
On May 20, 2009, EPA published a
notice in the Federal Register (74 FR
23708) (FRL–8414–2) that announced
the Agency’s receipt of requests from
the registrants to voluntarily cancel or
amend specific malathion registrations
and therefore terminate specific uses,
including the last use on cranberries for
malathion products registered for use in
the United States. EPA approved
cancellation of these registrations and
uses by publishing a cancellation order
on July 15, 2009 in the Federal Register
(74 FR 34345) (FRL–8425–3) and made
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them effective on July 15, 2009, and
permitted the malathion registrants,
including the registrant who requested
to amend to terminate the use on
cranberry, to sell and distribute existing
malathion stocks (concerning the last
use for cranberry) for 1 year from the
effective date of July 15, 2009; i.e., until
July 15, 2010. The Agency permitted
persons other than the registrant to sell
and distribute existing stocks and use of
those cancelled products until
exhaustion. However, the Agency
believes that end users will have had
sufficient time to exhaust those existing
stocks and for treated cranberry
commodities to have cleared the
channels of trade by July 15, 2011.
Therefore, EPA is proposing to revoke
the tolerance in 40 CFR 180.111(a)(1) on
cranberry with an expiration/revocation
date of July 15, 2011.
Based on available processing data
that showed combined residues of
malathion and malaoxon on whole
grapes were higher than those on raisins
from pre-harvest grapes treated at 5X the
maximum single application rate, the
Agency determined that malathion
residues of concern did not concentrate
in raisins. Also, while there are active
registrations for the pre-harvest use of
malathion on grapes, covered by the
tolerance on grapes at 8 ppm in 40 CFR
180.111(a)(1), there have been no active
malathion registrations in the United
States for malathion use on raisins or
paper trays for drying grapes to raisins
for more than 10 years. Therefore, the
tolerance in currently existing 40 CFR
180.111(a)(4) on raisin at 12 ppm is no
longer needed and should be revoked.
Consequently, EPA is proposing to
revoke the tolerance in currently
existing 40 CFR 180.111(a)(4) on raisins
at 12 ppm resulting from drying of grape
on treated trays and from application to
grape before harvest, and remove
paragraphs (a)(4) and (a)(6) in their
entireties.
Because there have been no active
malathion registrations in the United
States for use on paper used in
packaging non-medicated cattle feed
concentrate blocks since 1997, use on
bagged citrus pulp since 1997, use on
sunflower commodities since 2002,
safflower commodities since 2003, and
peanut commodities since early 2007,
the tolerances are no longer needed and
therefore should be revoked.
Consequently, EPA is proposing to
revoke the tolerances in 40 CFR
180.111(a)(1) on sunflower, seed,
postharvest; safflower, seed; peanut,
hay; peanut, postharvest; the tolerance
in currently existing 40 CFR
180.111(a)(5) on safflower, refined oil,
and remove paragraph (a)(5) in its
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entirety; and the tolerances in currently
existing 40 CFR 180.111(a)(7)(i) on
citrus, dried pulp as the result of the
application to bagged citrus pulp during
storage, and in currently existing 40
CFR 180.111(a)(7)(ii) on non-medicated
cattle feed concentrate blocks as the
result of application to paper used in its
packaging, and remove paragraph (a)(7)
in its entirety.
In order to conform to current Agency
practice in 40 CFR 180.111(a)(1), EPA is
proposing to revise the commodity
terminology from ‘‘bean, dry seed’’ to
‘‘bean, dry, seed.’’
There are no Codex MRLs for
malathion on egg, milk, or animal
commodities; however, there are Codex
MRLs for malathion on citrus fruits and
other specific plant commodities.
12. Methamidophos. On July 22, 2009,
EPA published a notice in the Federal
Register (74 FR 36204) (FRL–8427–2)
that announced the Agency’s receipt of
requests from the registrants to
voluntarily cancel all disulfoton and
methamidophos registrations and
therefore terminate the last disulfoton
and methamidophos products registered
for use in the United States, including
the last methamidophos uses on cotton,
potato, and tomato. EPA approved
cancellation of the registrations by
publishing a cancellation order on
September 23, 2009 in the Federal
Register (74 FR 48551) (FRL–8437–1)
and made them effective on September
23, 2009, and permitted the
methamidophos registrant to sell and
distribute existing methamidophos
stocks (concerning cotton, potato, and
tomato use) until December 31, 2010.
For all affected methamidophos
products, the Agency permitted persons
other than the registrant to sell and
distribute existing stocks and use of
those cancelled products until
exhaustion. However, the Agency
believes that end users will have had
sufficient time to exhaust those existing
stocks and for treated cotton, potato,
and tomato commodities to have cleared
the channels of trade by December 31,
2012. Therefore, EPA is proposing to
revoke the tolerances in 40 CFR
180.315(a) on cotton, undelinted seed,
potato, and tomato with expiration/
revocation dates of December 31, 2012.
Also, because the last registrations for
use of methamidophos on tomatoes
were FIFRA section 24(c) registrations
and there are no active registrations for
use of acephate on tomatoes, the Agency
has determined that the tomato
tolerance should be redesignated as a
regional tolerance. In addition, on May
23, 2007 (72 FR 28912) (FRL–8130–8),
EPA published a proposed rule in the
Federal Register concerning a number
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of pesticide active ingredients and
proposed tolerance actions, including
the proposed recodification of the
methamidophos tolerance in 40 CFR
180.315 on tomato as a regional
tolerance and an increase from 1.0 to 2.0
ppm based on data that showed residues
as high as 1.4 ppm. During the public
comment period, the Agency received
comment from the California
Department of Pesticide Regulation
(CDPR), who asked that the tolerance in
40 CFR 180.315 on tomato be decreased
to 0.3 ppm in order to be health
protective. The suggested decrease was
based on CDPR’s dietary risk
assessments for methamidophos at the
95th percentile for exposure and a
tolerance level of 1 ppm, and not using
a percent crop treated (PCT) adjustment
for tomato. On September 26, 2007 (72
FR 54574) (FRL–8147–6), EPA
published a final rule in the Federal
Register in follow-up to the proposed
rule of May 23, 2007 (72 FR 28912) and
announced that it would not take action
on methamidophos tolerances at that
time based upon comments and issues
concerning several commodities.
However, EPA estimates dietary risks
based on tolerance levels only as a
screening tool. If risks are unacceptable
using tolerance levels, a number of
refinements can be made including the
use of the entire distribution of field
trial data, monitoring data, average
residue levels for blended commodities,
and PCT data. When using PCT data in
dietary risk assessment, it is the
Agency’s policy to regulate at a higher
percentile of exposure, typically the
99.9th percentile, to assure protection of
public health. Using these refinements
provides more accurate estimates of the
level of pesticide residues present at the
time of consumption and therefore more
realistic dietary risk estimates. Since
tolerances are established based solely
on the available field trial residue data,
and dietary risks can be refined in the
ways described, which are not
necessarily directly correlated with the
tolerance level, the Agency does not
agree that decreasing the current
tolerance for tomato will provide any
additional health protection. The
Agency believes that the recommended
tolerance of 2.0 ppm on tomato and the
dietary risk assessment performed for
methamidophos are protective of public
health. Therefore, the Agency is
proposing to redesignate 40 CFR
180.315(b) as 40 CFR 180.315(c), remove
the tolerance on tomato from 40 CFR
180.315(a) and transfer it to newly
designated and revised 40 CFR
180.315(c), revoke the tolerance on
tomato with an expiration/revocation
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date of December 31, 2012, and increase
the tolerance from 1.0 to 2.0 ppm. The
Agency determined that the increased
tolerance is safe; i.e., there is a
reasonable certainty that no harm will
result from aggregate exposure to the
pesticide chemical residue.
Also, currently, tolerances for the
insecticide methamidophos are
expressed in 40 CFR 180.315(a) and
newly designated and revised
180.315(c) for residues of
methamidophos, O,S-dimethyl
phosphoramidothioate. In order to
describe more clearly the measurement
and scope or coverage of the tolerances,
EPA is proposing to revise the
introductory text containing the
tolerance expression in 40 CFR
180.315(a) to read as follows:
Tolerances are established for residues of
methamidophos, O,S-dimethyl
phosphoramidothioate, including its
metabolites and degradates, in or on the
commodities in the table in this paragraph as
a result of the application of methamidophos.
Compliance with the tolerance levels
specified in this paragraph is to be
determined by measuring only
methamidophos, O,S-dimethyl
phosphoramidothioate, in or on the
commodity.
In addition, EPA is proposing to
revise the introductory text containing
the tolerance expression in newly
designated and revised 40 CFR
180.315(c) to read as follows:
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A tolerance with a regional registration is
established for residues of methamidophos,
O,S-dimethyl phosphoramidothioate,
including its metabolites and degradates, in
or on the commodity in the table in this
paragraph as a result of the application of
methamidophos. Compliance with the
tolerance level specified in this paragraph is
to be determined by measuring only
methamidophos, O,S-dimethyl
phosphoramidothioate, in or on the
commodity.
Because there are no active
registrations in the United States for
methamidophos on Brussels sprouts and
cauliflower since 1989; celery since
1998; and lettuce and peppers since
2001; the tolerances are no longer
needed and therefore should be
revoked. Consequently, EPA is
proposing to revoke the tolerances in 40
CFR 180.315(a) on Brussels sprouts;
cauliflower; lettuce; and pepper; and the
regional tolerance in newly designated
and revised 40 CFR 180.315(c) on
celery.
On May 23, 2007 (72 FR 28912), EPA
published a proposed rule in the
Federal Register concerning a number
of pesticide active ingredients and
proposed tolerance actions, including
the proposed revocation of
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methamidophos tolerances in 40 CFR
180.315 on broccoli and cabbage
because there are no active registrations
for uses of either methamidophos or
acephate on broccoli and cabbage in the
United States and therefore, the
tolerances were no longer needed.
However, during the public comment
period, the Agency received comment
from Bayer CropScience Inc. and the
Canadian Horticultural Council, who
each asked that the tolerances in 40 CFR
180.315 on broccoli and cabbage not be
revoked to allow continuation of the
importation of methamidophos-treated
broccoli and cabbage commodities from
Canada into the United States. On
September 26, 2007 (72 FR 54574), EPA
published a final rule in the Federal
Register in follow-up to the proposed
rule of May 23, 2007 and announced
that it would not take action on
methamidophos tolerances at that time.
Since then, Bayer CropScience Inc. has
notified the Agency of a phase-out
schedule they negotiated with the Pest
Management Regulatory Agency
(PMRA) in Canada where the last date
of methamidophos product sale
(Monitor 480) by Bayer CropScience Inc.
is December 31, 2010, last date of
methamidophos product sale (Monitor
480) by retailers is December 31, 2011,
and last date of permitted use and
expiration of Monitor 480 registration in
Canada is December 31, 2012. In
addition, Bayer CropScience Inc. has
requested that EPA maintain U.S.
tolerances on broccoli and cabbage until
December 31, 2012 in order to allow
imports into the U.S. of broccoli and
cabbage treated with methamidophos
product. Therefore, EPA is proposing to
revoke the tolerances in 40 CFR
180.315(a) on broccoli and cabbage with
expiration/revocation dates of December
31, 2012.
In accordance with current Agency
practice, EPA is proposing to revise 40
CFR 180.315 by adding paragraphs (b)
and (d), and reserving those paragraphs
for tolerances with section 18
emergency exemptions and indirect or
inadvertent residues, respectively.
There are Codex MRLs for
methamidophos, including those on
cottonseed at 0.2 mg/kg and potato at
0.05 mg/kg, and other commodities.
13. Methomyl. On April 25, 2007, EPA
published a notice in the Federal
Register (72 FR 20541) (FRL–8125–6)
that announced the Agency’s receipt of
requests from the registrants for
amendments to delete uses, including
the last methomyl uses on strawberry.
After a 180–day public comment period,
EPA approved the use deletions and
made them effective on March 10, 2008,
and permitted the methomyl registrant
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to sell and distribute existing methomyl
stocks (concerning strawberry use) for a
period of 18 months after approval of
the revision; i.e., until September 10,
2009. For all affected methomyl
products, the Agency permitted persons
other than the registrant to sell and
distribute existing stocks and use of
those cancelled products until
exhaustion. However, the Agency
believes that end users will have had
sufficient time to exhaust those existing
stocks and for treated strawberry
commodities to have cleared the
channels of trade by September 10,
2010. Therefore, EPA is proposing to
revoke the tolerance in 40 CFR
180.253(a) on strawberry on the date a
final rule, in follow-up to this proposed
rule, publishes in the Federal Register
(which the Agency expects to occur
after September 10, 2010). In addition,
there have been no active food-use
registrations for use of methomyl on
leeks for more than 10 years and
watercress since 1991, and therefore the
tolerances are no longer needed and
should be revoked. Consequently, EPA
is proposing to revoke the tolerances in
40 CFR 180.253(a) on leek and
watercress.
There are no Codex MRLs on leek,
strawberry, or watercress for methomyl.
14. Methyl bromide. On September
30, 2009, EPA published a notice in the
Federal Register (74 FR 50199) (FRL–
8792–8) that announced the Agency’s
receipt of requests from the registrants
for amendments to delete uses,
including the last methyl bromide
postharvest uses on alfalfa hay and
cottonseed. On February 3, 2010 (75 FR
5582) (FRL–8805–9), EPA approved the
use deletions and made them effective
on February 3, 2010, and permitted the
methyl bromide registrant to sell and
distribute existing methyl bromide
stocks (concerning alfalfa hay and
cottonseed postharvest uses) until
October 31, 2009. For all affected
methyl bromide products, the Agency
permitted persons other than the
registrant to sell and distribute existing
stocks until October 31, 2010, and use
of those cancelled products until
exhaustion. However, the Agency
believes that end users will have had
sufficient time to exhaust those existing
stocks and for treated alfalfa hay and
cottonseed commodities to have cleared
the channels of trade by October 31,
2011. Therefore, EPA is proposing to
revoke the tolerances in 40 CFR
180.123(a)(1) on alfalfa, hay, postharvest
and cotton, undelinted seed, postharvest
with expiration/revocation dates of
October 31, 2011.
Because there have been no active
methyl bromide registrations in the
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United States for postharvest use on
mangos and papayas for more than 10
years, the tolerances are no longer
needed and therefore should be
revoked. Consequently, EPA is
proposing to revoke the tolerances in 40
CFR 180.123(a)(1) on mango,
postharvest and papaya, postharvest.
Also, because there have been no active
methyl bromide registrations in the
United States for postharvest use on
timothy hay since October 19, 2009,
when one FIFRA section 24(c), special
local need registration in California was
amended to delete use on timothy hay,
the tolerance is no longer needed and
therefore should be revoked. The
Agency believes that there will be
sufficient time for product in channels
of trade to be distributed and sold to
users and for end users to exhaust those
existing stocks and for treated timothy
hay commodities to have cleared the
channels of trade by October 19, 2010.
Consequently, EPA is proposing to
revoke the tolerance in 40 CFR
180.123(a)(1) on timothy, hay,
postharvest with an expiration/
revocation date of October 19, 2010.
While there are no Codex MRLs for
methyl bromide, there are MRLs for the
bromide ion on specific commodities,
but none on alfalfa, cottonseed, mango,
papaya, or timothy hay.
15. N-octyl bicycloheptene
dicarboximide (MGK-264). Currently,
there are tolerances in 40 CFR
180.367(a)(2) for residues of MGK-264,
piperonyl butoxide, and pyrethrins at 10
ppm, 10 ppm, and 1 ppm, respectively,
when these pesticides are used in
combination in or on food resulting
from applications in food-processing
and food-storage areas, provided that
the food is removed or covered prior to
such use. Based on available residue
data for uncovered bagged foods that
showed levels of MGK-264 at <5.0 ppm,
the Agency determined that the
tolerance for residues of MGK-264 in or
on food in food-processing and foodstorage areas (where food is removed or
covered prior to MGK-264 treatment)
should be decreased from 10 ppm to 5
ppm, that bagged foods in warehouse
storage need not be removed or covered
prior to applications of formulations
containing MGK-264, and that while
covered or removed foods in food
processing/handling establishments are
not likely to have detectable residues of
MGK-264, uncovered foods showed
residues at >5 ppm. Also, given that a
proposed food handling establishment
tolerance of 5 ppm in 40 CFR
180.367(a)(2) would cover the
individual fat tolerances for residues
resulting from dermal application at 0.3
ppm in § 180.367(a)(1), the Agency
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determined that there is no longer a
need for the fat tolerances at 0.3 ppm
and they should be revoked. In addition,
because tolerances for residues in or on
food from applications in foodprocessing and food-storage areas
currently exist in 40 CFR
180.127(a)(2)(iii) for piperonyl butoxide
at 10 ppm and in 40 CFR 180.128(a)(3)
for pyrethrins at 1.0 ppm, the Agency
determined that the tolerances for
piperonyl butoxide and pyrethrins in 40
CFR 180.367(a)(2) are duplicates which
are no longer needed and should be
revoked since the use would be covered
by the other tolerances. Therefore, EPA
is proposing to revoke the tolerances at
0.3 ppm in 40 CFR 180.367(a)(1) for Noctyl bicycloheptene dicarboximide
residues resulting from dermal
application in or on cattle, fat; goat, fat;
hog, fat; horse, fat; milk, fat; and sheep,
fat; and remove existing paragraph (a)(1)
in its entirety, revoke the tolerances for
piperonyl butoxide at 10 ppm and
pyrethrins at 1 ppm in 40 CFR
180.367(a)(2)(ii), remove existing
introductory text in 40 CFR
180.367(a)(2), (a)(2)(i), and (a)(2)(iii);
decrease the tolerance in 40 CFR
180.367(a)(2)(ii) to 5 ppm and
redesignate it as 40 CFR 180.367(a), and
revise newly designated paragraph (a),
as follows:
A tolerance of 5 parts per million is
established for residues of the insecticide
synergist N-octyl bicycloheptene
dicarboximide, including its metabolites and
degradates, in or on all food items in food
handling establishments where food and food
products are held, processed, prepared and/
or served, provided that the food is removed
or covered prior to such use, except for
bagged food in warehouse storage which
need not be removed or covered prior to
applications of formulations containing Noctyl bicycloheptene dicarboximide.
Compliance with the tolerance level
specified in this paragraph is to be
determined by measuring only N-octyl
bicycloheptene dicarboximide, in or on the
commodity.
Because there have been no uses of Noctyl bicycloheptenedicarboximide,
MGK-264, in or on growing agricultural
crops for more than 10 years, the
tolerance exemption is no longer needed
and therefore should be revoked.
Consequently, EPA is proposing to
revoke the tolerance exemption in 40
CFR 180.905(a)(2) for N-octyl
bicyclo(2,2,1)-5-heptene-2,3dicarboximide, when applied to
growing crops. In addition, EPA is
proposing to revise 40 CFR 180.905(a) as
described herein under proposals for
pyrethrum.
There are no Codex MRLs for N-octyl
bicycloheptene dicarboximide.
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28167
16. Phosmet. On November 4, 2005,
EPA published a notice in the Federal
Register (70 FR 67167) (FRL–7744–7)
that announced the Agency’s receipt of
requests from the registrants for
amendments to delete uses in certain
pesticide registrations, including the
last phosmet uses on cotton. No
comments were received by EPA and
the Agency approved the use deletions
on December 5, 2005, and permitted the
registrants to sell and distribute existing
stocks for a period of 18 months after
approval; i.e., until June 5, 2007. The
Agency believes that end users have had
sufficient time to exhaust those existing
stocks and for treated cotton to have
cleared the channels of trade. Therefore,
EPA is proposing to revoke the
tolerances in 40 CFR 180.261(a) on
cotton, refined oil and cotton,
undelinted seed.
Also, in order to describe more clearly
the measurement and scope or coverage
of the tolerances, EPA is proposing to
revise the section heading in 40 CFR
180.261 from N-(mercaptomethyl)
phthalimide S-(O,O-dimethyl
phosphorodithioate) and its oxygen
analog to phosmet and revise the
introductory text containing the
tolerance expression in 40 CFR
180.261(a) to read as follows:
Tolerances are established for residues of
the insecticide phosmet, N-(mercaptomethyl)
phthalimide S-(O,O-dimethyl
phosphorodithioate), including its
metabolites and degradates, in or on the
commodities in the table in this paragraph.
Compliance with the tolerance levels
specified in this paragraph is to be
determined by measuring only the sum of
phosmet, N-(mercaptomethyl) phthalimide S(O,O-dimethyl phosphorodithioate), and its
oxygen analog, N-(mercaptomethyl)
phthalimide S-(O,O-dimethyl
phosphorothioate, calculated as the
stoichiometric equivalent of phosmet, in or
on the commodity.
In addition, EPA is proposing to
revise the introductory text containing
the tolerance expression for regional
tolerances in 40 CFR 180.261(c) to read
as follows:
Tolerances with regional registration are
established for residues of the insecticide
phosmet, N-(mercaptomethyl) phthalimide S(O,O-dimethylp phosphorodithioate),
including its metabolites and degradates, in
or on the commodities in the table in this
paragraph. Compliance with the tolerance
levels specified in this paragraph is to be
determined by measuring only the sum of
phosmet, N-(mercaptomethyl) phthalimide S(O,O-dimethyl phosphorodithioate), and its
oxygen analog, N-(mercaptomethyl)
phthalimide S-(O,O-dimethyl
phosphorothioate, calculated as the
stoichiometric equivalent of phosmet, in or
on the commodity.
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There are Codex MRLs on certain
commodities for phosmet, including an
MRL on cottonseed.
17. Picloram. As a post-RED action,
EPA made certain tolerance
determinations for picloram on
November 19, 2009 in a document made
available in the public docket of this
proposed rule. Because there is no need
for a different tolerance expression for
the existing tolerances for picloram
residues in processed grain
commodities in 40 CFR 180.292(a)(2),
EPA determined that paragraph (a)(2)
should be removed and the tolerances
there should be moved into the table in
§ 180.292(a)(1), which therefore should
be redesignated as paragraph (a).
Also, in order to describe more clearly
the measurement and scope or coverage
of the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in newly
designated 40 CFR 180.292(a) to read as
follows:
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Tolerances are established for residues of
the herbicide picloram, 4-amino-3,5,6trichloropicolinic acid, including its
metabolites and degradates, in or on the
commodities in the table in this paragraph
from its application in the acid form or in the
form of its salts. Compliance with the
tolerance levels specified in this paragraph is
to be determined by measuring only
picloram, 4-amino-3,5,6-trichloropicolinic
acid, in or on the commodity.
Based on available field trial data that
showed picloram residues of 195 ppm
in or on grass forage at an application
rate of 0.5 lb ae/A with a 0–day PHI,
EPA determined that the existing
tolerance should be increased from 80.0
to 400 ppm, which is an appropriate
tolerance level for grass forage for the
existing maximum approved rate of 1.0
lb ae/A. Also, based on available data
that showed picloram residues as high
as 170 ppm in or on grass hay at an
application rate of 2.0 lb ae/A with a
14–day PHI and 213 ppm in or on grass
hay at an application rate of 0.5 lb ae/
A with a 0–day PHI, EPA determined
that a tolerance should be established
on grass hay at 225 ppm. Therefore, EPA
is proposing to increase the tolerance in
40 CFR 180.292(a) on grass, forage to
400 ppm and establish a tolerance in 40
CFR 180.292(a) on grass, hay at 225
ppm. The Agency determined that the
increased tolerance is safe; i.e., there is
a reasonable certainty that no harm will
result from aggregate exposure to the
pesticide chemical residue.
Based on available cattle exaggerated
feeding data at 1.39X the Maximum
Theoretical Dietary Burden (MTDB) that
showed picloram residues at 0.5 ppm in
fat, 0.5 ppm in muscle, 18 ppm in
kidney, 2.0 ppm in liver, and 0.29 ppm
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in milk, EPA calculated that the
maximum expected residues in fat,
muscle, meat byproducts, and milk at
1X MTDB to be 0.36 ppm, 0.36 ppm,
12.95 ppm, and 0.21 pm, respectively.
Therefore, the Agency determined that
the tolerances for the fat and meat of
cattle, goats, horses, and sheep should
be increased from 0.2 to 0.4 ppm, the
tolerance for milk should be increased
from 0.05 to 0.25 ppm; the separate
tolerances for the kidney of cattle, goats,
horses, and sheep, and liver of cattle,
goats, horses, and sheep should be
revoked because they will be covered by
redefined meat byproduct tolerances for
cattle, goats, horses, and sheep, and the
redefined meat byproduct tolerances
should be increased to 15 ppm.
Consequently, EPA is proposing to
increase the tolerances in 40 CFR
180.292(a) on cattle, fat; cattle, meat;
goat, fat; goat, meat; horse, fat; horse,
meat; sheep, fat; and sheep, meat to 0.4
ppm, and milk to 0.25 ppm. Also, EPA
is proposing to revoke the individual
tolerances in 40 CFR 180.292(a) on
cattle, kidney; cattle, liver; goat, kidney;
goat, liver; horse, kidney, horse, liver;
sheep kidney; and sheep, liver. In
addition, EPA is proposing to revise the
tolerances in 40 CFR 180.292(a) on
‘‘cattle, meat byproducts, except kidney
and liver’’ to ‘‘cattle, meat byproducts;’’
‘‘goat, meat byproducts, except kidney
and liver’’ to ‘‘goat, meat byproducts;’’
‘‘horse, meat byproducts, except kidney
and liver’’ to ‘‘horse, meat byproducts;’’
and ‘‘sheep, meat byproducts, except
kidney and liver’’ to ‘‘sheep, meat
byproducts;’’ and increase them to 15
ppm. The Agency determined that the
increased tolerances are safe; i.e., there
is a reasonable certainty that no harm
will result from aggregate exposure to
the pesticide chemical residue.
Although grass commodities are not
significant feed items for swine, wheat
milled byproduct feed items which have
picloram tolerances show that the
MTDB for swine is low (1.5 ppm). The
lowest levels of picloram fed to cattle
and sheep (200 and 30 ppm) were well
above the anticipated exposure for hogs
and the 30 ppm dose showed picloram
residues in kidney, liver, fat, and
muscle of sheep were 0.38 ppm, <0.05
ppm, <0.05 ppm, and <0.05 ppm,
respectively. Based on the available
data, the Agency determined that the
tolerances for hog, fat; hog, meat; and
hog, meat byproducts should be
decreased from 0.2 to 0.05 ppm, and
hog, kidney and hog, liver should be
decreased to 0.05 ppm. However, these
separate kidney and liver tolerances are
no longer needed since they will be
covered by redefined meat byproduct
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tolerances. Therefore, EPA is proposing
to decrease the tolerances in 40 CFR
180.292(a) on hog, fat and hog, meat,
each to 0.05 ppm. Also EPA is
proposing to revoke the individual
tolerances in 40 CFR 180.292(a) on hog,
kidney and hog, liver. In addition, EPA
is proposing to revise the tolerance in 40
CFR 180.292(a) on ‘‘hog, meat
byproducts, except kidney and liver’’ to
‘‘hog, meat byproducts’’ and decrease it
to 0.05 ppm.
There are no Codex MRLs for
picloram.
18. Propazine. Because there have
been no active registrations for
propazine use on sweet sorghum for
more than 4 years, EPA is proposing to
revoke the tolerance in 40 CFR 180.243
on sorghum, sweet.
Tolerances established in 40 CFR
180.243 are currently defined for
residues of propazine (the parent
compound) only. Based on the results of
sorghum metabolism data, the Agency
determined that two chlorinated
degradates should be included in the
residue definition. Therefore, in order to
describe more clearly the measurement
and scope or coverage of the tolerances,
EPA is proposing to revise the
introductory text containing the
tolerance expression in 40 CFR 180.243,
and designate it as paragraph (a), to read
as follows:
Tolerances are established for residues of
the herbicide propazine, 2-chloro-4,6bis(isopropylamino)-s-triazine, including its
metabolites and degradates, in or on the
commodities in the table in this paragraph.
Compliance with the tolerance levels
specified in this paragraph is to be
determined by measuring only the sum of
propazine, 2-chloro-4,6-bis(isopropylamino)s-triazine, and its two chlorinated degradates,
2-amino-4-chloro-6-isopropylamino-striazine and 2,4-diamino-6-chloro-s-triazine,
calculated as the stoichiometric equivalent of
propazine, in or on the commodity.
Also, in newly designated 40 CFR
180.243(a), EPA is removing the ‘‘(N)’’
designation from all entries to conform
to current Agency administrative
practice, where the ‘‘N’’ designation
means negligible residues, and revising
commodity terminology to conform to
current Agency practice as follows:
‘‘sorghum, forage’’ to ‘‘sorghum, grain,
forage.’’
In accordance with current Agency
practice, EPA is proposing to revise 40
CFR 180.243 by adding separate
paragraphs (b), (c), and (d), and
reserving those sections for tolerances
with section 18 emergency exemptions,
regional registrations, and indirect or
inadvertent residues, respectively.
There are no Codex MRLs for
propazine.
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19. Pyrethrum. Currently, there are
tolerance exemptions in 40 CFR
180.905(a)(6) for pyrethrum and
pyrethrins when applied to growing
crops in accordance with good
agricultural practice. Because there have
been no active registrations in the
United States for pyrethrum since 1991,
there is no longer a need for a tolerance
exemption on pyrethrum and the
tolerance exemption for it should be
revoked. Consequently, EPA is
proposing to revoke the tolerance
exemption for pyrethrum in 40 CFR
180.905(a)(6). While the tolerance
exemption for pyrethrins will be
maintained, EPA is proposing to revise
40 CFR 180.905(a) in accordance with
the proposed revocation of the tolerance
exemption for N-octylbicyclo(2,2,1)-5heptene-2,3-dicarboximide in 40 CFR
180.905(a)(2) as described elsewhere in
this rule and transfer the entry for
petroleum oils from 40 CFR
180.905(a)(3) to 40 CFR 180.905(a)(1),
which had been reserved, transfer the
entry for piperonyl butoxide from 40
CFR 180.905(a)(4) to 40 CFR
180.905(a)(2), transfer the entry for
pyrethrins from 40 CFR 180.905(a)(6) to
40 CFR 180.905(a)(3), transfer the entry
for rotenone or derris or cube roots from
40 CFR 180.905(a)(7) to 40 CFR
180.905(a)(4), transfer the entry for
Sabadilla from 40 CFR 180.905(a)(8) to
40 CFR 180.905(a)(5), which had been
reserved, and remove paragraphs (a)(6),
(a)(7), and (a)(8).
There are no Codex MRLs for
pyrethrum. However, there are Codex
MRLs for pyrethrins concerning specific
commodities.
20. Thiodicarb. Based on available
field trial at 5X the maximum label rate
and processing data that showed
combined thiodicarb residues of
concern as high as 0.215 ppm on
cottonseed and 0.228 in cottonseed
hulls, EPA calculated that the residues
in cottonseed hulls are unlikely to
exceed both the current tolerance of 0.4
ppm on the raw agricultural commodity
(cotton, undelinted seed) and a
tolerance of 0.2 ppm recommended for
cottonseed in the 1998 RED for
thiodicarb. Because thiodicarb residues
of concern concentrated by only 1.1X in
cottonseed hulls (based on average
residues of 0.200 ppm in cottonseed and
0.223 ppm in cottonseed hulls), the
Agency determined that residues in
cottonseed hulls will be covered by the
tolerance on the raw agricultural
commodity and that the existing
tolerance of 0.8 ppm on cottonseed
hulls is no longer needed and should be
revoked. Therefore, EPA is proposing to
revoke the tolerance in 40 CFR
180.407(a) on cotton, hulls.
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There are no Codex MRLs for
thiodicarb.
21. Thiophanate-methyl. Currently,
tolerances for the fungicide thiophanatemethyl are expressed in 40 CFR
180.371(a) and 180.371(c) for the
combined residues of thiophanatemethyl, dimethyl ((1,2-phenylene) bis
(iminocarbonothioyl)) bis(carbamate),
and its metabolite methyl 2benzimidazoyl carbamate (MBC),
calculated as thiophanate-methyl. In
order to describe more clearly the
measurement and scope or coverage of
the tolerances, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.371(a) to read as follows:
Tolerances are established for residues of
thiophanate-methyl, dimethyl ((1,2phenylene) bis (iminocarbonothioyl))
bis(carbamate), including its metabolites and
degradates, in or on the commodities in the
table in this paragraph. Compliance with the
tolerance levels specified in this paragraph is
to be determined by measuring only the sum
of thiophanate-methyl, dimethyl ((1,2phenylene) bis (iminocarbonothioyl))
bis(carbamate), and its metabolite, methyl 2benzimidazoyl carbamate (MBC), calculated
as the stoichiometric equivalent of
thiophanate-methyl, in or on the commodity.
In addition, EPA is proposing to
revise the introductory text containing
the tolerance expression in 40 CFR
180.371(c) to read as follows:
A tolerance with a regional registration is
established for residues of thiophanatemethyl, dimethyl ((1,2-phenylene) bis
(iminocarbonothioyl)) bis(carbamate),
including its metabolites and degradates, in
or on the commodity in the table in this
paragraph. Compliance with the tolerance
level specified in this paragraph is to be
determined by measuring only the sum of
thiophanate-methyl, dimethyl ((1,2phenylene) bis (iminocarbonothioyl))
bis(carbamate), and its metabolite, methyl 2benzimidazoyl carbamate (MBC), calculated
as the stoichiometric equivalent of
thiophanate-methyl, in or on the commodity.
Because tolerances for FIFRA section
18 emergency exemptions in 40 CFR
180.371(b) for cotton, gin byproducts
and cotton, undelinted seed expired on
December 31, 2008, blueberry expired
on June 30, 2009, and citrus, mushroom,
and vegetable, fruiting, group 8 expired
on December 31, 2009, they should be
removed. Therefore, EPA is proposing to
remove the expired tolerances in 40 CFR
180.371(b) for blueberry; citrus; cotton,
gin byproducts; cotton, undelinted seed;
mushroom; and vegetable, fruiting,
group 8. Consequently, because no
tolerances will remain there, EPA is also
proposing to reserve 40 CFR 180.371(b).
Because sugar beet tops are no longer
considered by the Agency to be a
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28169
significant feed item that will contribute
to the overall dietary burden of
livestock, the tolerance is no longer
needed and should be revoked.
Therefore, EPA is proposing to revoke
the tolerance in 40 CFR 180.371(a) on
beet, sugar, tops.
Because there have been no active
registrations in the United States for
thiophanate-methyl use on sugarcane
for more than 9 years, the tolerance
should be revoked. Therefore, EPA is
proposing to revoke the tolerance in 40
CFR 180.371(a) on sugarcane, cane.
Based on available cattle feeding data
at exaggerated pesticide dose levels and
MTDB for cattle, the Agency determined
that there is no reasonable expectation
of detecting finite residues of
thiophanate-methyl residues of concern
in the milk and fat, meat, and meat
byproducts of cattle, goats, horses and
sheep. Therefore, these tolerances are no
longer needed under 40 CFR 180.6(a)(3).
Consequently, EPA is proposing to
revoke the tolerances in 40 CFR
180.371(a) on cattle, fat; cattle, meat;
cattle, meat byproducts; goat, fat; goat,
meat; goat, meat byproducts; horse, fat;
horse, meat; horse, meat byproducts;
sheep, fat; sheep, meat; and sheep, meat
byproducts; and milk.
Based on available data provided to
support reregistration that showed
thiophanate-methyl residues of concern,
the Agency determined that tolerances
should be established on aspirated grain
fractions (based on soybean) at 12 ppm
and wheat forage at 1.1 ppm. Therefore,
EPA is proposing to establish tolerances
in 40 CFR 180.371(a) on grain, aspirated
fractions at 12 ppm and wheat, forage at
1.1 ppm.
In the Federal Register of July 11,
2007 (72 FR 37646)(FRL–8131–6), EPA
issued a final rule which revoked,
modified, and established certain
tolerances for specific pesticide active
ingredients, including thiophanatemethyl, for which the Agency revised
the commodity terminology in 40 CFR
180.371(a) for bean (snap and dry) into
bean, dry, seed and bean, snap,
succulent, and inadvertently decreased
the tolerance for bean, snap, succulent
from 2.0 to 0.2 ppm. However, in the
Federal Register of September 20, 2006
(71 FR 54953)(FRL–8078–2), EPA issued
a proposed rule which proposed to
revise the tolerance in 40 CFR
180.371(a) for bean (snap and dry) into
bean, dry, seed and bean, snap,
succulent, and stated that the tolerance
for bean, snap, succulent would be
maintained at 2.0 ppm. Consequently,
the Agency is proposing to reinstate the
correct tolerance level for the tolerance
in 40 CFR 180.371(a) on bean, snap,
succulent to 2.0 ppm.
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There are no Codex MRLs for
thiophanate-methyl.
B. What is the Agency’s Authority for
Taking this Action?
A ‘‘tolerance’’ represents the
maximum level for residues of pesticide
chemicals legally allowed in or on raw
agricultural commodities and processed
foods. Section 408 of FFDCA, 21 U.S.C.
346a, as amended by FQPA of 1996,
Public Law 104–170, authorizes the
establishment of tolerances, exemptions
from tolerance requirements,
modifications in tolerances, and
revocation of tolerances for residues of
pesticide chemicals in or on raw
agricultural commodities and processed
foods. Without a tolerance or
exemption, food containing pesticide
residues is considered to be unsafe and
therefore ‘‘adulterated’’ under section
402(a) of FFDCA, 21 U.S.C. 342(a). Such
food may not be distributed in interstate
commerce (21 U.S.C. 331(a)). For a fooduse pesticide to be sold and distributed,
the pesticide must not only have
appropriate tolerances under the
FFDCA, but also must be registered
under FIFRA (7 U.S.C. 136 et seq.).
Food-use pesticides not registered in the
United States must have tolerances in
order for commodities treated with
those pesticides to be imported into the
United States.
EPA is proposing these tolerance/
tolerance exemption actions to
implement the tolerance
recommendations made during the
reregistration and tolerance
reassessment processes (including
follow-up on canceled or additional
uses of pesticides). As part of these
processes, EPA is required to determine
whether each of the amended
tolerances/tolerance exemptions meets
the safety standard of FQPA. The safety
finding determination is discussed in
detail in each post-FQPA RED and
TRED for the active ingredient. REDs
and TREDs recommend the
implementation of certain tolerance/
tolerance exemption actions, including
modifications to reflect current use
patterns, to meet safety findings, and
change commodity names and
groupings in accordance with new EPA
policy. Printed and electronic copies of
the REDs and TREDs are available as
provided in Unit II.A.
EPA has issued REDs for acephate,
cacodylic acid, ethoprop, hexazinone,
methamidophos, N-octyl bicycloheptene
dicarboximide, phosmet, picloram,
pyrethrum (see pyrethrins RED), and
thiophanate-methyl, and TREDs for
hexazinone and propazine, as noted in
Unit II.A., and made a safety finding
which reassessed picloram tolerances
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according to the FFDCA standard,
maintaining them when new picloram
tolerances were established on January
5, 1999 (64 FR 418) (FRL–6039–4), and
since then made certain tolerance
determinations for picloram on
November 19, 2009 in a document made
available in the public docket of this
proposed rule, as noted in Unit II.A.
REDs and TREDs contain the Agency’s
evaluation of the database for these
pesticides, including requirements for
additional data on the active ingredients
to confirm the potential human health
and environmental risk assessments
associated with current product uses,
and in REDs state conditions under
which these uses and products will be
eligible for reregistration. The REDs and
TREDs recommended the establishment,
modification, and/or revocation of
specific tolerances/tolerance
exemptions. RED and TRED
recommendations such as establishing
or modifying tolerances, and in some
cases revoking tolerances, are the result
of assessment under the FFDCA
standard of ‘‘reasonable certainty of no
harm.’’ However, tolerance revocations
recommended in REDs and TREDs that
are proposed in this document do not
need such assessment when the
tolerances are no longer necessary.
EPA’s general practice is to propose
revocation of tolerances/tolerance
exemptions for residues of pesticide
active ingredients on crops for which
FIFRA registrations no longer exist and
on which the pesticide may therefore no
longer be used in the United States. EPA
has historically been concerned that
retention of tolerances that are not
necessary to cover residues in or on
legally treated foods may encourage
misuse of pesticides within the United
States. Nonetheless, EPA will establish
and maintain tolerances even when
corresponding domestic uses are
canceled if the tolerances, which EPA
refers to as ‘‘import tolerances,’’ are
necessary to allow importation into the
United States of food containing such
pesticide residues. However, where
there are no imported commodities that
require these import tolerances, the
Agency believes it is appropriate to
revoke tolerances for unregistered
pesticides in order to prevent potential
misuse.
Furthermore, as a general matter, the
Agency believes that retention of import
tolerances not needed to cover any
imported food may result in
unnecessary restriction on trade of
pesticides and foods. Under section 408
of FFDCA, a tolerance/tolerance
exemption may only be established or
maintained if EPA determines that the
tolerance is safe based on a number of
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factors, including an assessment of the
aggregate exposure to the pesticide and
an assessment of the cumulative effects
of such pesticide and other substances
that have a common mechanism of
toxicity. In doing so, EPA must consider
potential contributions to such exposure
from all tolerances. If the cumulative
risk is such that the tolerances in
aggregate are not safe, then every one of
these tolerances is potentially
vulnerable to revocation. Furthermore,
if unneeded tolerances are included in
the aggregate and cumulative risk
assessments, the estimated exposure to
the pesticide would be inflated.
Consequently, it may be more difficult
for others to obtain needed tolerances or
to register needed new uses. To avoid
potential trade restrictions, the Agency
is proposing to revoke tolerances/
tolerance exemptions for residues on
crops uses for which FIFRA
registrations no longer exist, unless
someone expresses a need for such
tolerances/tolerance exemptions.
Through this proposed rule, the Agency
is inviting individuals who need these
import tolerances to identify themselves
and the tolerances that are needed to
cover imported commodities.
Parties interested in retention of the
tolerances/tolerance exemptions should
be aware that additional data may be
needed to support retention. These
parties should be aware that, under
FFDCA section 408(f), if the Agency
determines that additional information
is reasonably required to support the
continuation of a tolerance, EPA may
require that parties interested in
maintaining the tolerances provide the
necessary information. If the requisite
information is not submitted, EPA may
issue an order revoking the tolerance/
tolerance exemption at issue.
When EPA establishes tolerances for
pesticide residues in or on raw
agricultural commodities, consideration
must be given to the possible residues
of those chemicals in meat, milk,
poultry, and/or eggs produced by
animals that are fed agricultural
products (for example, grain or hay)
containing pesticides residues (40 CFR
180.6). When considering this
possibility, EPA can conclude that:
1. Finite residues will exist in meat,
milk, poultry, and/or eggs.
2. There is a reasonable expectation
that finite residues will exist.
3. There is a reasonable expectation
that finite residues will not exist. If
there is no reasonable expectation of
finite pesticide residues in or on meat,
milk, poultry, or eggs, tolerances do not
need to be established for these
commodities (40 CFR 180.6(b) and (c)).
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EPA has evaluated certain specific
meat, milk, poultry, and egg tolerances
proposed for revocation in this
document and has concluded that there
is no reasonable expectation of finite
pesticide residues of concern in or on
those commodities.
C. When Do These Actions Become
Effective?
With the exception of certain
tolerances for cacodylic acid, dicloran,
disulfoton, ethoprop, malathion,
methamidophos, and methyl bromide
for which EPA is proposing specific
expiration/revocation dates, the Agency
is proposing that these revocations,
modifications, establishment of
tolerances, and revisions of tolerance
nomenclature become effective on the
date of publication of the final rule in
the Federal Register. With the exception
of the proposed revocation of specific
tolerances for cacodylic acid, dicloran,
disulfoton, ethoprop, malathion,
methamidophos, and methyl bromide,
the Agency believes that existing stocks
of pesticide products labeled for the
uses associated with the tolerances
proposed for revocation have been
completely exhausted and that treated
commodities have cleared the channels
of trade. EPA is proposing expiration/
revocation dates of January 1, 2012 for
the cacodylic acid tolerance on cotton,
undelinted seed; November 2, 2011 for
the dicloran tolerance on carrot, roots,
postharvest; December 31, 2012 for the
disulfoton tolerances on bean, lima;
bean, snap, succulent; broccoli; Brussels
sprouts; cabbage; cauliflower; cotton,
undelinted seed; lettuce, head; lettuce,
leaf; and asparagus; June 30, 2013 for
the disulfoton tolerance on coffee, green
bean; January 9, 2012 for the ethoprop
tolerance on pineapple; July 15, 2011 for
the malathion tolerance on cranberry;
December 31, 2012 for the
methamidophos tolerances on broccoli;
cabbage; cotton, undelinted seed;
tomato; and potato; October 19, 2010 for
the methyl bromide tolerance on
timothy, hay, postharvest; and October
31, 2011 for the methyl bromide
tolerances on alfalfa, hay, postharvest
and cotton, undelinted seed,
postharvest. The Agency believes that
these revocation dates allow users to
exhaust stocks and allows sufficient
time for passage of treated commodities
through the channels of trade. However,
if EPA is presented with information
that existing stocks would still be
available and that information is
verified, the Agency will consider
extending the expiration date of the
tolerance. If you have comments
regarding existing stocks and whether
the effective date allows sufficient time
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for treated commodities to clear the
channels of trade, please submit
comments as described under
SUPPLEMENTARY INFORMATION.
Any commodities listed in this
proposal treated with the pesticides
subject to this proposal, and in the
channels of trade following the
tolerance revocations, shall be subject to
FFDCA section 408(l)(5), as established
by FQPA. Under this unit, any residues
of these pesticides in or on such food
shall not render the food adulterated so
long as it is shown to the satisfaction of
the Food and Drug Administration that:
1. The residue is present as the result
of an application or use of the pesticide
at a time and in a manner that was
lawful under FIFRA, and
2. The residue does not exceed the
level that was authorized at the time of
the application or use to be present on
the food under a tolerance or exemption
from tolerance. Evidence to show that
food was lawfully treated may include
records that verify the dates when the
pesticide was applied to such food.
III. International Residue Limits
In making its tolerance decisions, EPA
seeks to harmonize U.S. tolerances with
international standards whenever
possible, consistent with U.S. food
safety standards and agricultural
practices. EPA considers the
international MRLs established by the
Codex Alimentarius Commission
(Codex), as required by FFDCA section
408(b)(4). The Codex Alimentarius is a
joint U.N. Food and Agriculture
Organization/World Health
Organization food standards program,
and it is recognized as an international
food safety standards-setting
organization in trade agreements to
which the United States is a party. EPA
may establish a tolerance that is
different from a Codex MRL; however,
FFDCA section 408(b)(4) requires that
EPA explain the reasons for departing
from the Codex level.
The Codex has not established a MRL
for cacodylic acid, dicamba, EPTC,
hexazinone, N-octyl bicycloheptene
dicarboximide, picloram, propazine,
pyrethrum, thiodicarb, and thiophanatemethyl, or MRL in or on corn, pop,
grain; corn, pop, stover; or pineapple for
ethoprop; or MRL in or on citrus, dried
pulp; citrus, oil; fruit, citrus, group 10;
or garlic for fenamiphos; or MRL for
citrus, dried pulp; cranberry; peanut,
hay; peanut, postharvest; raisins;
safflower, seed; safflower, refined oil;
sunflower, seed, postharvest; fat, meat,
and meat byproducts of cattle, goats,
hogs, horses, poultry, and sheep; egg;
milk, fat; or nonmedicated cattle feed
concentrate blocks for malathion; or
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MRL in or on alfalfa, hay, postharvest;
cotton, undelinted seed; mango,
postharvest; papaya, postharvest; or
timothy, hay, postharvest for bromide
ion or methyl bromide; or MRL in or on
leek; strawberry; or watercress for
methomyl; or MRL in or on broccoli;
Brussels sprouts; cabbage; lettuce; or
tomato for methamidophos.
The Codex has established MRLs for
dicloran in or on commodities including
carrot, postharvest at 15 mg/kg. This
MRL is different than the current
tolerance established for dicloran at 10
ppm in the United States, which EPA is
proposing herein to revoke. The
tolerance was reassessed in the RED at
10 ppm and was harmonized with
Codex at that time.
The Codex has established MRLs for
diquat in or on commodities including
sorghum at 2 mg/kg and soya bean (dry)
at 0.2 mg/kg. These MRLs are the same
as the current tolerances for diquat in or
on sorghum, grain, grain and soybean,
seed in the United States, which EPA is
proposing herein to revoke.
The Codex has established MRLs for
disulfoton in or on commodities
including asparagus at 0.02 mg/kg;
cotton seed at 0.1 mg/kg. These MRLs
are different than the current tolerances
established for disulfoton in or on
asparagus at 0.1 ppm and cotton,
undelinted seed at 0.75 ppm in the
United States, both of which EPA is
proposing herein to revoke. The
tolerances were reassessed in the RED
and were not harmonized with Codex
levels because of differences in good
agricultural practices. The Codex MRL
for disulfoton in or on coffee beans is
the same as the current tolerance for
disulfoton in or on coffee, green bean,
which EPA is proposing herein to
revoke.
The Codex has established MRLs for
methamidophos in or on commodities
including cauliflower at 0.5 mg/kg;
cotton seed at 0.2 mg/kg; chili peppers
at 2 mg/kg; sweet peppers at 1 mg/kg;
and potato at 0.05 mg/kg. These MRLs
are different than the current tolerances
established for methamidophos from
methamidophos application in or on
cauliflower at 1.0 ppm; cotton,
undelinted seed at 0.1 ppm; pepper at
1.0 ppm; and potato at 0.1 ppm in the
United States, all of which EPA is
proposing herein to revoke. The
tolerances were reassessed in the RED
and were not harmonized with the
Codex levels because of differences in
good agricultural practices. While
methamidophos is a metabolite of
acephate and EPA is proposing herein
the re-instatement of certain
methamidophos tolerances as a result of
the application of acephate, Codex has
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established MRLs for acephate but for
compliance purposes has defined them
as only acephate residues.
The Codex has established MRLs for
phosmet in or on commodities
including cotton seed at 0.05 mg/kg.
This MRL is different than the current
tolerance established for phosmet in or
on cotton, undelinted seed at 0.1 ppm
in the United States, which EPA is
proposing herein to revoke. The
tolerance was reassessed in the RED and
was not harmonized with the Codex
level because of differences in good
agricultural practices and tolerance
expression where total residues for U.S.
tolerances included phosmet’s oxygen
analog.
IV. Statutory and Executive Order
Reviews
In this proposed rule, EPA is
proposing to establish tolerances under
FFDCA section 408(e), and also modify
and revoke specific tolerances/tolerance
exemptions established under FFDCA
section 408. The Office of Management
and Budget (OMB) has exempted these
types of actions (e.g., establishment and
modification of a tolerance and
tolerance revocation for which
extraordinary circumstances do not
exist) from review under Executive
Order 12866, entitled Regulatory
Planning and Review (58 FR 51735,
October 4, 1993). Because this proposed
rule has been exempted from review
under Executive Order 12866 due to its
lack of significance, this proposed rule
is not subject to Executive Order 13211,
entitled Actions Concerning Regulations
That Significantly Affect Energy Supply,
Distribution, or Use (66 FR 28355, May
22, 2001). This proposed rule does not
contain any information collections
subject to OMB approval under the
Paperwork Reduction Act (PRA), 44
U.S.C. 3501 et seq., or impose any
enforceable duty or contain any
unfunded mandate as described under
Title II of the Unfunded Mandates
Reform Act of 1995 (UMRA) (Public
Law 104–4). Nor does it require any
special considerations as required by
Executive Order 12898, entitled Federal
Actions to Address Environmental
Justice in Minority Populations and
Low-Income Populations (59 FR 7629,
February 16, 1994); or OMB review or
any other Agency action under
Executive Order 13045, entitled
Protection of Children from
Environmental Health Risks and Safety
Risks (62 FR 19885, April 23, 1997).
This action does not involve any
technical standards that would require
Agency consideration of voluntary
consensus standards pursuant to section
12(d) of the National Technology
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Transfer and Advancement Act of 1995
(NTTAA), Public Law 104–113, section
12(d) (15 U.S.C. 272 note). Pursuant to
the Regulatory Flexibility Act (RFA) (5
U.S.C. 601 et seq.), the Agency
previously assessed whether
establishment of tolerances, exemptions
from tolerances, raising of tolerance
levels, expansion of exemptions, or
revocations might significantly impact a
substantial number of small entities and
concluded that, as a general matter,
these actions do not impose a significant
economic impact on a substantial
number of small entities. These analyses
for tolerance establishments and
modifications, and for tolerance
revocations were published on May 4,
1981 (46 FR 24950) and on December
17, 1997 (62 FR 66020) (FRL–5753–1),
respectively, and were provided to the
Chief Counsel for Advocacy of the Small
Business Administration. Taking into
account this analysis, and available
information concerning the pesticides
listed in this proposed rule, the Agency
hereby certifies that this proposed rule
will not have a significant negative
economic impact on a substantial
number of small entities. In a
memorandum dated May 25, 2001, EPA
determined that eight conditions must
all be satisfied in order for an import
tolerance or tolerance exemption
revocation to adversely affect a
significant number of small entity
importers, and that there is a negligible
joint probability of all eight conditions
holding simultaneously with respect to
any particular revocation. (This Agency
document is available in the docket of
this proposed rule). Furthermore, for the
pesticides named in this proposed rule,
the Agency knows of no extraordinary
circumstances that exist as to the
present proposal that would change the
EPA’s previous analysis. Any comments
about the Agency’s determination
should be submitted to the EPA along
with comments on the proposal, and
will be addressed prior to issuing a final
rule. In addition, the Agency has
determined that this action will not
have a substantial direct effect on States,
on the relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government, as specified in
Executive Order 13132, entitled
Federalism (64 FR 43255, August 10,
1999). Executive Order 13132 requires
EPA to develop an accountable process
to ensure ‘‘meaningful and timely input
by State and local officials in the
development of regulatory policies that
have federalism implications.’’ ‘‘Policies
that have federalism implications’’ is
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defined in the Executive order to
include regulations that have
‘‘substantial direct effects on the States,
on the relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government.’’ This proposed
rule directly regulates growers, food
processors, food handlers, and food
retailers, not States. This action does not
alter the relationships or distribution of
power and responsibilities established
by Congress in the preemption
provisions of section 408(n)(4) of
FFDCA. For these same reasons, the
Agency has determined that this
proposed rule does not have any ‘‘tribal
implications’’ as described in Executive
Order 13175, entitled Consultation and
Coordination with Indian Tribal
Governments (65 FR 67249, November
9, 2000). Executive Order 13175,
requires EPA to develop an accountable
process to ensure ‘‘meaningful and
timely input by tribal officials in the
development of regulatory policies that
have tribal implications.’’ ‘‘Policies that
have tribal implications’’ is defined in
the Executive order to include
regulations that have ‘‘substantial direct
effects on one or more Indian tribes, on
the relationship between the Federal
Government and the Indian tribes, or on
the distribution of power and
responsibilities between the Federal
Government and Indian tribes.’’ This
proposed rule will not have substantial
direct effects on tribal governments, on
the relationship between the Federal
Government and Indian tribes, or on the
distribution of power and
responsibilities between the Federal
Government and Indian tribes, as
specified in Executive Order 13175.
Thus, Executive Order 13175 does not
apply to this proposed rule.
List of Subjects in 40 CFR Part 180
Environmental protection,
Administrative practice and procedure,
Agricultural commodities, Pesticides
and pests, Reporting and recordkeeping
requirements.
Dated: May 5, 2010.
Steven Bradbury,
Acting Director, Office of Pesticide Programs.
Therefore, it is proposed that 40 CFR
chapter I be amended as follows:
PART 180—[AMENDED]
1. The authority citation for part 180
continues to read as follows:
Authority: 21 U.S.C. 321(q), 346a and 371.
2. Section 180.108 is amended as
follows:
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a. Revise the introductory text to
paragraph (a)(1).
b. Revise footnote 1 to the table in
paragraph (a)(1).
c. Revise paragraph (a)(2).
d. Add paragraph (a)(3).
e. Revise paragraph (c).
§ 180.108 Acephate; tolerances for
residues.
(a) *
*
* (1) Tolerances are
established for residues of acephate,
O,S-dimethyl acetyl
phosphoramidothioate, including its
metabolites and degradates other than
methamidophos, in or on the
commodities in the table in this
paragraph. Compliance with the
tolerance levels specified in this
paragraph is to be determined by
measuring only acephate, O,S-dimethyl
acetyl phosphoramidothioate, in or on
the commodity.
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Commodity1
Parts per million
dimethyl phosphoramidothioate,
including its metabolites and
degradates, in or on the commodities in
the table in this paragraph as a result of
the application of acephate. Compliance
with the tolerance levels specified in
this paragraph is to be determined by
measuring only methamidophos, O,Sdimethyl phosphoramidothioate, in or
on the commodity.
Parts per
million
Commodity
Bean, dry, seed ........................
Bean, succulent ........................
Brussels sprouts .......................
Cauliflower ................................
Celery .......................................
Cranberry ..................................
Lettuce, head ............................
Pepper ......................................
Peppermint, tops ......................
Spearmint, tops ........................
*
*
*
*
(c) Tolerances with regional
registrations. A tolerance with a regional
*
*
*
*
*
registration is established for residues of
1 Where
there is a direct use of
methamidophos on the commodity, residues of acephate, O,S-dimethyl acetyl
methamidophos resulting from methamidophos phosphoramidothioate, including its
application are regulated under 40 CFR metabolites and degradates other than
180.315.
methamidophos, in or on the
commodity in the table in this
(2) A tolerance of 0.02 ppm is
paragraph. Compliance with the
established for residues of acephate,
tolerance level specified in this
O,S-dimethyl acetyl
paragraph is to be determined by
phosphoramidothioate, including its
measuring only acephate, O,S-dimethyl
metabolites and degradates other than
methamidophos, in or on all food items
acetyl phosphoramidothioate, in or on
(other than those already covered by a
the commodity.
higher tolerance as a result of use on
Parts per
growing crops) in food handling
Commodity1
million
establishments where food and food
products are held, processed, prepared
Nut, macadamia .......................
0.05
and served, including food service,
1 Where
there is a direct use of
manufacturing and processing
methamidophos on the commodity, residues of
establishments, such as restaurants,
methamidophos resulting from methamidophos
cafeterias, supermarkets, bakeries,
application are regulated under 40 CFR
breweries, dairies, meat slaughtering
180.315.
and packing plants, and canneries,
*
*
*
*
*
where application of acephate shall be
3. Amend § 180.111 as follows:
limited solely to spot and/or crack and
a. Revise the table in paragraph (a)(1).
crevice treatment (a coarse, lowb. Remove paragraphs (a)(3), (a)(4),
pressure spray shall be used to avoid
(a)(5), (a)(6), and (a)(7).
atomization or splashing of the spray for
spot treatments; equipment capable of
§ 180.111 Malathion; tolerances for
delivering a pin-stream of insecticide
residues.
shall be used for crack and crevice
(a) * * * (1) * * *
treatments). Spray concentration shall
be limited to a maximum of 1.0 percent
Expiration/
Parts per
active ingredient. Contamination of food
Commodity
Revocation
million
Date
or food-contact surfaces shall be
avoided. Compliance with the tolerance
Alfalfa, forage ...
135
None
levels specified in this paragraph is to
Alfalfa, hay ........
135
None
be determined by measuring only
Almond, hulls ....
50
None
acephate, O,S-dimethyl acetyl
Almond,
phosphoramidothioate, in or on the
postharvest ....
8
None
commodity.
Apple .................
8
None
(3) Tolerances are established for
Apricot ...............
8
None
Asparagus .........
8
None
residues of methamidophos, O,S-
VerDate Mar<15>2010
16:10 May 18, 2010
Jkt 220001
*
1
1
0.5
0.5
1
0.1
1
1
1
1
PO 00000
Frm 00019
Fmt 4701
Sfmt 4702
Commodity
Avocado ............
Barley, grain,
postharvest ....
Bean, dry, seed
Bean, succulent
Beet, garden,
roots ..............
Beet, garden,
tops ...............
Beet, sugar,
roots ..............
Beet, sugar,
tops ...............
Blackberry .........
Blueberry ..........
Boysenberry ......
Carrot, roots ......
Chayote, fruit ....
Chayote, roots ..
Cherry ...............
Chestnut ...........
Clover, forage ...
Clover, hay .......
Corn, field, forage ................
Corn, field,
grain,
postharvest ....
Corn, pop, grain,
postharvest ....
Corn, sweet, forage ................
Corn, sweet,
kernel plus
cob with
husks removed ...........
Cowpea, forage
Cowpea, hay .....
Cranberry ..........
Cucumber .........
Currant ..............
Date, dried fruit
Dewberry ..........
Eggplant ............
Fig .....................
Flax, seed .........
Garlic, bulb .......
Gooseberry .......
Grape ................
Grapefruit ..........
Guava ...............
Hazelnut ............
Hop, dried
cones .............
Horseradish ......
Kumquat ...........
Leek ..................
Lemon ...............
Lentil, seed .......
Lespedeza, hay
Lime ..................
Loganberry ........
Lupin, seed .......
Mango ...............
Melon ................
Mushroom .........
Nectarine ..........
Nut, macadamia
Oat, grain,
postharvest ....
Okra ..................
E:\FR\FM\19MYP2.SGM
19MYP2
Expiration/
Revocation
Date
Parts per
million
8
None
8
8
8
None
None
None
8
None
8
None
1
None
8
8
8
8
8
8
8
8
1
135
135
None
None
None
None
None
None
None
None
None
None
None
8
None
8
None
8
None
8
None
2
135
135
8
8
8
8
8
8
8
0.1
8
8
8
8
8
1
None
None
None
7/15/11
None
None
None
None
None
None
None
None
None
None
None
None
None
1
8
8
8
8
8
135
8
8
8
8
8
8
8
1
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
8
8
None
None
28174
Federal Register / Vol. 75, No. 96 / Wednesday, May 19, 2010 / Proposed Rules
jlentini on DSKJ8SOYB1PROD with PROPOSALS2
Onion, bulb .......
Onion, green .....
Orange ..............
Papaya ..............
Parsnip ..............
Passionfruit .......
Pea ...................
Pea, field, hay ...
Pea, field, vines
Peach ................
Pear ..................
Pecan ................
Pepper ..............
Peppermint, tops
Pineapple ..........
Plum ..................
Plum, prune ......
Potato ...............
Pumpkin ............
Quince ..............
Radish ...............
Raspberry .........
Rice, grain,
postharvest ....
Rice, wild ..........
Rutabaga ..........
Rye, grain,
postharvest ....
Salsify, roots .....
Salsify, tops ......
Shallot, bulb ......
Sorghum, grain,
forage ............
Sorghum, grain,
grain,
postharvest ....
Soybean, forage
Soybean, hay ....
Soybean, seed ..
Soybean, vegetable, succulent .............
Spearmint, tops
Squash, summer
Squash, winter ..
Strawberry ........
Sweet potato,
roots ..............
Tangerine ..........
Tomato ..............
Trefoil, forage ...
Trefoil, hay ........
Turnip, greens ..
Turnip, roots .....
Vegetable, brassica, leafy,
group 5 ..........
Vegetable, leafy,
except brassica, group 4
Vetch, hay .........
Walnut ...............
Wheat, grain,
postharvest ....
*
Expiration/
Revocation
Date
Parts per
million
Commodity
8
8
8
1
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
8
8
8
None
None
None
8
8
8
8
None
None
None
None
8
None
8
135
135
8
None
None
None
None
8
8
8
8
8
None
None
None
None
None
1
8
8
135
135
8
8
None
None
None
None
None
None
None
8
Parts per
million
Commodity
Alfalfa, forage ...........................
Alfalfa, hay ................................
Almond ......................................
Almond, hulls ............................
Bean, dry, seed ........................
Bean, succulent ........................
Beet, garden, roots ...................
Beet, garden, tops ....................
Beet, sugar, molasses ..............
Beet, sugar, roots .....................
Beet, sugar, tops ......................
Clover, forage ...........................
Clover, hay ...............................
Corn, field, forage .....................
Corn, field, grain .......................
Corn, field, stover .....................
Corn, pop, grain ........................
Corn, pop, stover ......................
Corn, sweet, forage ..................
Corn, sweet, kernel plus cob
with husks removed ..............
Corn, sweet, stover ..................
Cotton, gin byproducts .............
Cotton, undelinted seed ...........
Fruit, citrus, group 10 ...............
Lespedeza, forage ....................
Lespedeza, hay ........................
Pea, succulent ..........................
Potato .......................................
Safflower, seed .........................
Sunflower, seed ........................
Sweet potato, roots ..................
Tomato ......................................
Trefoil, forage ...........................
Trefoil, hay ................................
Walnut .......................................
0.2
0.6
0.08
0.08
0.08
0.08
0.1
0.5
0.4
0.1
0.5
0.1
0.1
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.20
0.08
0.1
0.1
0.1
0.08
0.1
0.08
0.08
0.1
0.08
0.1
0.1
0.08
None
8
135
8
None
None
None
8
None
*
*
*
*
4. Revise § 180.117 to read as follows:
§ 180.117 S-Ethyl dipropylthiocarbamate;
tolerances for residues.
(a) General. Tolerances are
established for residues of the herbicide
VerDate Mar<15>2010
S-ethyl dipropylthiocarbamate,
including its metabolites and
degradates, in or on the commodities in
the table in this paragraph. Compliance
with the tolerance levels specified in
this paragraph is to be determined by
measuring only the sum of S-ethyl
dipropylthiocarbamate, S-ethyl (2hydroxypropyl)propylcarbamothioate,
S-(2hydroxyethyl)dipropylcarbamothioate,
and S-ethyl (3hydroxypropyl)propylcarbamothioate,
calculated as the stoichiometric
equivalent of S-ethyl
dipropylthiocarbamate, in or on the
commodity.
16:10 May 18, 2010
Jkt 220001
(b) Section 18 emergency exemptions.
[Reserved]
(c) Tolerances with regional
registrations. [Reserved]
(d) Indirect or inadvertent residues.
[Reserved]
5. In § 180.123 revise the table in
paragraph (a)(1) to read as follows:
§ 180.123 Inorganic bromide residues
resulting from fumigation with methyl
bromide; tolerances for residues.
Commodity
Alfalfa, hay,
postharvest ....
Almond,
postharvest ....
Apple,
postharvest ....
Apricot,
postharvest ....
Artichoke, jerusalem,
postharvest ....
Asparagus,
postharvest ....
Avocado,
postharvest ....
Barley, grain,
postharvest ....
Bean, lima,
postharvest ....
Bean,
postharvest ....
Bean, snap, succulent,
postharvest ....
Bean, succulent,
postharvest ....
Beet, garden,
roots,
postharvest ....
Beet, sugar,
roots,
postharvest ....
Blueberry,
postharvest ....
Butternut,
postharvest ....
Cabbage,
postharvest ....
Cacao bean,
roasted bean,
postharvest ....
Cantaloupe,
postharvest ....
Carrot, roots,
postharvest ....
Cashew,
postharvest ....
Cherry, sweet,
postharvest ....
Cherry, tart,
postharvest ....
Chestnut,
postharvest ....
Cippolini, bulb,
postharvest ....
Citron, citrus,
postharvest ....
Coconut, copra,
postharvest ....
Coffee, bean,
green,
postharvest ....
Corn, field,
grain,
postharvest ....
Corn, pop,
postharvest ....
(a) * * * (1) * * *
PO 00000
Frm 00020
Fmt 4701
Sfmt 4702
E:\FR\FM\19MYP2.SGM
19MYP2
Parts per
million
Expiration/
Revocation
Date
50.0
10/31/11
200.0
None
5.0
None
20.0
None
30.0
None
100.0
None
75.0
None
50.0
None
50.0
None
50.0
None
50.0
None
50.0
None
30.0
None
30.0
None
20.0
None
200.0
None
50.0
None
50.0
None
20.0
None
30.0
None
200.0
None
20.0
None
20
None
200.0
None
50.0
None
30.0
None
100.0
None
75.0
None
50.0
None
240.0
None
28175
Federal Register / Vol. 75, No. 96 / Wednesday, May 19, 2010 / Proposed Rules
Parts per
million
jlentini on DSKJ8SOYB1PROD with PROPOSALS2
Commodity
Corn, sweet,
kernel plus
cob with
husks removed,
postharvest ....
Cotton,
undelinted
seed,
postharvest ....
Cucumber,
postharvest ....
Cumin, seed,
postharvest ....
Eggplant,
postharvest ....
Garlic,
postharvest ....
Ginger,
postharvest ....
Grape,
postharvest ....
Grapefruit,
postharvest ....
Hazelnut,
postharvest ....
Horseradish,
postharvest ....
Kumquat,
postharvest ....
Lemon,
postharvest ....
Lime,
postharvest ....
Melon, honeydew,
postharvest ....
Muskmelon,
postharvest ....
Nectarine,
postharvest ....
Nut, brazil,
postharvest ....
Nut, hickory,
postharvest ....
Nut, macadamia,
postharvest ....
Oat, postharvest
Okra,
postharvest ....
Onion, bulb,
postharvest ....
Onion, green,
postharvest ....
Orange,
postharvest ....
Parsnip, roots,
postharvest ....
Peach,
postharvest ....
Peanut,
postharvest ....
Pear,
postharvest ....
Pea, blackeyed,
postharvest ....
Pea, postharvest
Pecan,
postharvest ....
Pepper,
postharvest ....
VerDate Mar<15>2010
50.0
Expiration/
Revocation
Date
None
200.0
10/31/11
30.0
None
100.0
None
20.0
None
50.0
None
100.0
None
20.0
None
30.0
None
200.0
None
30.0
None
30.0
None
30.0
None
30.0
None
20.0
None
20.0
None
20.0
None
200.0
None
200.0
None
200.0
50.0
None
None
30.0
None
20.0
None
20.0
None
30.0
None
30.0
None
20.0
None
200.0
None
50.0
50.0
None
None
30.0
16:10 May 18, 2010
Pimento,
postharvest ....
Pineapple,
postharvest ....
Pistachio,
postharvest ....
Plum,
postharvest ....
Pomegranate,
postharvest ....
Potato,
postharvest ....
Pumpkin,
postharvest ....
Quince,
postharvest ....
Radish,
postharvest ....
Rice, grain,
postharvest ....
Rutabaga, roots,
postharvest ....
Rutabaga, tops,
postharvest ....
Rye, grain,
postharvest ....
Salsify, roots,
postharvest ....
Sorghum, grain,
grain,
postharvest ....
Soybean,
postharvest ....
Squash, summer,
postharvest ....
Squash, winter,
postharvest ....
Squash, zucchini,
postharvest ....
Strawberry,
postharvest ....
Sweet potato,
postharvest ....
Tangerine,
postharvest ....
Timothy, hay,
postharvest ....
Tomato,
postharvest ....
Turnip, roots,
postharvest ....
Walnut,
postharvest ....
Watermelon,
postharvest ....
Wheat ...............
Expiration/
Revocation
Date
30.0
None
20.0
None
200.0
None
20.0
None
100.0
None
75.0
None
20.0
None
5.0
None
30.0
None
50.0
None
30.0
30.0
50.0
None
30.0
None
50.0
None
200.0
None
30.0
None
20.0
None
20.0
None
75.0
None
30.0
None
50.0
10/19/10
20.0
None
30.0
None
200.0
None
20.0
50.0
None
None
§ 180.183 Disulfoton; tolerances for
residues.
Frm 00021
Fmt 4701
Bean, lima .....
Bean, snap,
succulent ...
Broccoli .........
Brussels
sprouts ......
Cabbage .......
Cauliflower ....
Coffee, green
bean ..........
Cotton,
undelinted
seed ..........
Lettuce, head
Lettuce, leaf ..
*
*
PO 00000
Parts per
million
Expiration/
Revocation
Date
None
60.0
Commodity
None
(a) General. Tolerances are
established for residues of the
None insecticide disulfoton, O,O-diethyl S-(2(ethylthio)ethyl) phosphorodithioate,
None including its metabolites and
Jkt 220001
degradates, in or on the commodities in
the table in this paragraph. Compliance
with the tolerance levels specified in
this paragraph is to be determined by
measuring only the sum of disulfoton,
O,O-diethyl S-(2-(ethylthio)ethyl)
phosphorodithioate, and its metabolites
demeton-S, O,O-diethyl S-(2(ethylthio)ethyl) phosphorothioate;
disulfoton sulfoxide, O,O-diethyl S-(2(ethylsulfinyl)ethyl)
phosphorodithioate; disulfoton oxygen
analog sulfoxide, O,O-diethyl S-(2(ethylsulfinyl)ethyl) phosphorothioate,
disulfoton sulfone, O,O-diethyl S-(2(ethylsulfonyl)ethyl)
phosphorodithioate; and disulfoton
oxygen analog sulfone, O,O-diethyl S-(2(ethylsulfonyl)ethyl) phosphorothioate;
calculated as the stoichiometric
equivalent of disulfoton, in or on the
commodity.
None
*
*
*
*
6. In § 180.183 revise the section
heading, and paragraphs (a) and (c) to
None
read as follows:
5.0
200.0
Parts per
million
Commodity
Sfmt 4702
0.75
12/31/12
0.75
0.75
12/31/12
12/31/12
0.75
0.75
0.75
12/31/12
12/31/12
12/31/12
0.2
6/30/13
0.75
0.75
2
12/31/12
12/31/12
12/31/12
*
*
*
*
(c) Tolerances with regional
registrations. A tolerance with regional
registration is established for residues of
the insecticide disulfoton, O,O-diethyl
S-(2-(ethylthio)ethyl)
phosphorodithioate, including its
metabolites and degradates, in or on the
commodity in the table in this
paragraph. Compliance with the
tolerance levels specified in this
paragraph is to be determined by
measuring only the sum of disulfoton,
O,O-diethyl S-(2-(ethylthio)ethyl)
phosphorodithioate, and its metabolites
demeton-S,O,O-diethyl S-(2(ethylthio)ethyl) phosphorothioate;
disulfoton sulfoxide, O,O-diethyl S-(2(ethylsulfinyl)ethyl) phosphorodi
thioate; disulfoton oxygen analog
sulfoxide, O,O-diethyl S-(2(ethylsulfinyl)ethyl) phosphorothioate,
disulfoton sulfone, O,O-diethyl S-(2(ethylsulfonyl)ethyl) phosphorodi
thioate; and disulfoton oxygen analog
sulfone, O,O-diethyl S-(2(ethylsulfonyl)ethyl)p phosphorothioate;
calculated as the stoichiometric
E:\FR\FM\19MYP2.SGM
19MYP2
28176
Federal Register / Vol. 75, No. 96 / Wednesday, May 19, 2010 / Proposed Rules
§ 180.227 Dicamba; tolerances for
residues.
equivalent of disulfoton, in or on the
commodity.
(a) *
*
*. (1) Tolerances are
established for residues of the herbicide
Parts per
Commodity
dicamba, 3,6-dichloro-o-anisic acid,
million
including its metabolites and
Asparagus .....
0.1
12/31/12 degradates, in or on the commodities in
the table in this paragraph. Compliance
with the tolerance levels specified in
*
*
*
*
*
this paragraph is to be determined by
7. In § 180.200 revise paragraph (a)(1) measuring only the sum of dicamba, 3,6to read as follows:
dichloro-o-anisic acid, and its
metabolite, 3,6-dichloro-5-hydroxy-o§ 180.200 Dicloran; tolerances for
anisic acid, calculated as the
residues.
stoichiometric equivalent of dicamba, in
(a) General. (1) Tolerances are
or on the commodity.
established for residues of the fungicide
dicloran, 2,6-dichloro-4-nitroaniline,
Parts per
Commodity
million
including its metabolites and
degradates, in or on the commodities in
Barley, grain .............................
6.0
the table in this paragraph. Compliance
Barley, hay ................................
2.0
with the tolerance levels specified in
Barley, straw .............................
15.0
this paragraph is to be determined by
Corn, field, forage .....................
3.0
measuring only dicloran, 2,6-dichloro-4- Corn, field, grain .......................
0.1
nitroaniline, in or on the commodity.
Corn, field, stover .....................
3.0
Corn, pop, grain ........................
0.1
Unless otherwise specified, the
Corn, pop, stover ......................
3.0
tolerances prescribed in the following
Corn, sweet, forage ..................
0.50
table provide for residues from
Corn, sweet, kernel plus cob
preharvest application only.
Expiration/
Revocation
Date
Parts per
million
Commodity
jlentini on DSKJ8SOYB1PROD with PROPOSALS2
Apricot,
postharvest ....
Bean, snap, succulent .............
Carrot, roots,
postharvest ....
Celery ...............
Cherry, sweet,
postharvest ....
Cucumber .........
Endive ...............
Garlic ................
Grape ................
Lettuce ..............
Nectarine,
postharvest ....
Onion ................
Peach,
postharvest ....
Plum, prune,
fresh,
postharvest ....
Potato ...............
Rhubarb ............
Sweet potato,
postharvest ....
Tomato ..............
Expiration/
Revocation
Date
20
None
20
None
10
15
11/2/11
None
20
5
10
5
10
10
None
None
None
None
None
None
20
10
None
None
20
None
15
0.25
10
with husks removed ..............
Corn, sweet, stover ..................
Cotton, undelinted seed ...........
Grass, forage, fodder and hay,
group 17, forage ...................
Grass, forage, fodder and hay,
group 17, hay ........................
Millet, proso, forage ..................
Millet, proso, grain ....................
Millet, proso, hay ......................
Millet, proso, straw ...................
Oat, forage ................................
Oat, grain ..................................
Oat, hay ....................................
Oat, straw .................................
Rye, forage ...............................
Rye, grain .................................
Rye, straw .................................
Sorghum, grain, forage .............
Sorghum, grain, grain ...............
Sorghum, grain, stover .............
Sugarcane, cane ......................
Sugarcane, molasses ...............
Wheat, forage ...........................
Wheat, grain .............................
Wheat, hay ...............................
Wheat, straw .............................
None
None
None
0.04
0.50
0.2
125.0
200.0
90.0
2.0
40.0
30.0
90.0
2.0
40.0
30.0
90.0
2.0
30.0
3.0
4.0
10.0
0.3
5.0
90.0
2.0
40.0
30.0
(2) Tolerances are established for
residues of the herbicide dicamba, 3,6dichloro-o-anisic acid, including its
10
None metabolites and degradates, in or on the
5
None commodities in the table in this
paragraph. Compliance with the
*
*
*
*
*
tolerance levels specified in this
paragraph is to be determined by
§ 180.226 [Amended]
measuring only the sum of dicamba, 3,68. In § 180.226 remove the entries for
dichloro-o-anisic acid, and its
‘‘sorghum, grain, grain’’ and ‘‘soybean,
metabolite, 3,6-dichloro-2seed’’ from the table in paragraph (a)(1).
hydroxybenzoic acid, calculated as the
9. In § 180.227 revise paragraph (a)(1), stoichiometric equivalent of dicamba, in
or on the commodity.
and the introductory text in paragraphs
(a)(2) and (a)(3) to read as follows:
*
*
*
*
*
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(3) Tolerances are established for
residues of the herbicide dicamba, 3,6dichloro-o-anisic acid, including its
metabolites and degradates, in or on the
commodities in the table in this
paragraph. Compliance with the
tolerance levels specified in this
paragraph is to be determined by
measuring only the sum of dicamba, 3,6dichloro-o-anisic acid, and its
metabolites, 3,6-dichloro-5-hydroxy-oanisic acid, and 3,6-dichloro-2hydroxybenzoic acid, calculated as the
stoichiometric equivalent of dicamba, in
or on the commodity.
*
*
*
*
*
10. Revise § 180.243 to read as
follows:
§ 180.243 Propazine; tolerances for
residues.
(a) General. Tolerances are
established for residues of the herbicide
propazine, 2-chloro-4,6bis(isopropylamino)-s-triazine,
including its metabolites and
degradates, in or on the commodities in
the table in this paragraph. Compliance
with the tolerance levels specified in
this paragraph is to be determined by
measuring only the sum of propazine, 2chloro-4,6-bis(isopropylamino)-striazine, and its two chlorinated
degradates, 2-amino-4-chloro-6isopropylamino-s-triazine and 2,4diamino-6-chloro-s-triazine, calculated
as the stoichiometric equivalent of
propazine, in or on the commodity.
Commodity
Parts per
million
Sorghum, grain, forage .............
Sorghum, grain, grain ...............
Sorghum, grain, stover .............
0.25
0.25
0.25
(b) Section 18 emergency exemptions.
[Reserved]
(c) Tolerances with regional
registrations. [Reserved]
(d) Indirect or inadvertent residues.
[Reserved]
§ 180.253
[Amended]
11. In § 180.253 remove the entries for
‘‘leek,’’ ‘‘strawberry,’’ and ‘‘watercress’’
from the table in paragraph (a).
12. In § 180.261 revise the section
heading, paragraph (a) and paragraph (c)
to read as follows:
§180.261 Phosmet; tolerances for
residues.
(a) General. Tolerances are
established for residues of the
insecticide phosmet, N(mercaptomethyl) phthalimide S-(O,Odimethyl phosphorodithioate),
including its metabolites and
degradates, in or on the commodities in
E:\FR\FM\19MYP2.SGM
19MYP2
Federal Register / Vol. 75, No. 96 / Wednesday, May 19, 2010 / Proposed Rules
the table in this paragraph. Compliance
with the tolerance levels specified in
this paragraph is to be determined by
measuring only the sum of phosmet, N(mercaptomethyl) phthalimide S-(O,Odimethyl phosphorodithioate), and its
oxygen analog, N-(mercaptomethyl)
phthalimide S-(O,O-dimethyl
phosphorothioate, calculated as the
stoichiometric equivalent of phosmet, in
or on the commodity.
Commodity
Parts per
million
Alfalfa, forage ...........................
Alfalfa, hay ................................
Almond, hulls ............................
Apple .........................................
Apricot .......................................
Blueberry ..................................
Cattle, fat ..................................
Cattle, meat ..............................
Cattle, meat byproducts ...........
Cherry .......................................
Cranberry ..................................
Fruit, citrus, group 10 ...............
Goat, fat ....................................
Goat, meat ................................
Goat, meat byproducts .............
Grape ........................................
Hog, fat .....................................
Hog, meat .................................
Hog, meat byproducts ..............
Horse, fat ..................................
Horse, meat ..............................
Horse, meat byproducts ...........
Kiwifruit .....................................
Milk ...........................................
Nectarine ..................................
Nut, tree, group 14 ...................
Pea, dry, seed ..........................
Pea, field, hay ...........................
Pea, field, vines ........................
Pea, succulent ..........................
Peach ........................................
Pear ..........................................
Plum, prune, fresh ....................
Potato .......................................
Sheep, fat .................................
Sheep, meat .............................
Sheep, meat byproducts ..........
Sweet potato, roots ..................
20
40
10
10
5
10
0.2
0.1
0.1
10
10
5
0.1
0.1
0.1
10
0.2
0.04
0.04
0.1
0.1
0.1
25
0.1
5
0.1
0.5
20
10
1
10
10
5
0.1
0.1
0.1
0.1
12
jlentini on DSKJ8SOYB1PROD with PROPOSALS2
*
*
*
*
*
(c) Tolerances with regional
registrations. Tolerances with regional
registration are established for residues
of the insecticide phosmet, N(mercaptomethyl) phthalimide S-(O,Odimethyl phosphorodithioate),
including its metabolites and
degradates, in or on the commodities in
the table in this paragraph. Compliance
with the tolerance levels specified in
this paragraph is to be determined by
measuring only the sum of phosmet, N(mercaptomethyl) phthalimide S-(O,Odimethyl phosphorodithioate), and its
oxygen analog, N-(mercaptomethyl)
phthalimide S-(O,O-dimethyl
phosphorothioate, calculated as the
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stoichiometric equivalent of phosmet, in
or on the commodity.
commodities in the table in this
paragraph from its application in the
acid form or in the form of its salts.
Parts per
Compliance with the tolerance levels
Commodity
million
specified in this paragraph is to be
Crabapple .................................
20 determined by measuring only
Pistachio ...................................
0.1 picloram, 4-amino-3,5,6trichloropicolinic acid, in or on the
commodity.
*
*
*
*
*
13. In § 180.262 revise paragraph (a)
Parts per
to read as follows:
Commodity
million
§180.262 Ethoprop; tolerances for
residues.
(a) General. Tolerances are
established for residues of the
nematocide and insecticide ethoprop,
O-ethyl S,S-dipropyl
phosphorodithioate, including its
metabolites and degradates, in or on the
commodities in the table in this
paragraph. Compliance with the
tolerance levels specified in this
paragraph is to be determined by
measuring only ethoprop, O-ethyl S,Sdipropyl phosphorodithioate, in or on
the commodity.
Parts per
million
Commodity
Banana .............
Bean, lima .........
Bean, snap, succulent .............
Cabbage ...........
Corn, field, forage ................
Corn, field, grain
Corn, field, stover .................
Corn, sweet, forage ................
Corn, sweet,
kernel plus
cob with
husks removed ...........
Corn, sweet,
stover ............
Cucumber .........
Hop, dried
cones .............
Peppermint, tops
Pineapple ..........
Potato ...............
Spearmint, tops
Sugarcane, cane
Sweet potato,
roots ..............
Expiration/
Revocation
Date
0.02
0.02
None
None
0.02
0.02
None
None
0.02
0.02
None
None
0.02
None
0.02
None
0.02
None
0.02
0.02
None
None
0.02
0.02
0.02
0.02
0.02
0.02
None
None
1/9/12
None
None
None
0.02
None
*
*
*
*
*
14. In § 180.292 revise paragraph (a)
to read as follows:
§180.292 Picloram; tolerances for
residues.
(a) General. Tolerances are
established for residues of the herbicide
picloram, 4-amino-3,5,6trichloropicolinic acid, including its
metabolites and degradates, in or on the
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Barley, grain .............................
Barley, pearled barley ..............
Barley, straw .............................
Cattle, fat ..................................
Cattle, meat ..............................
Cattle, meat byproducts ...........
Egg ...........................................
Goat, fat ....................................
Goat, meat ................................
Goat, meat byproducts .............
Grain, aspirated fractions .........
Grass, forage ............................
Grass, hay ................................
Hog, fat .....................................
Hog, meat .................................
Hog, meat byproducts ..............
Horse, fat ..................................
Horse, meat ..............................
Horse, meat byproducts ...........
Milk ...........................................
Oat, forage ................................
Oat, grain ..................................
Oat, groats/rolled oats ..............
Oat, straw .................................
Poultry, fat ................................
Poultry, meat ............................
Poultry, meat byproducts ..........
Sheep, fat .................................
Sheep, meat .............................
Sheep, meat byproducts ..........
Wheat, bran ..............................
Wheat, forage ...........................
Wheat, germ .............................
Wheat, grain .............................
Wheat, middlings ......................
Wheat, shorts ...........................
Wheat, straw .............................
0.5
3.0
1.0
0.4
0.4
15
0.05
0.4
0.4
15
4.0
400
225
0.05
0.05
0.05
0.4
0.4
15
0.25
1.0
0.5
3.0
1.0
0.05
0.05
0.05
0.4
0.4
15
3.0
1.0
3.0
0.5
3.0
3.0
1.0
*
*
*
*
*
15. In § 180.311 revise paragraph (a)
to read as follows:
§180.311 Cacodylic acid; tolerances for
residues.
(a) General. A tolerance is established
for residues of the defoliant cacodylic
acid, dimethylarsinic acid, including its
metabolites and degradates, in or on the
commodity in the table in this
paragraph. Compliance with the
tolerance level specified in this
paragraph is to be determined by
measuring only those cacodylic acid
residues convertible to As2O3, expressed
as the stoichiometric equivalent of
cacodylic acid, in or on the commodity.
E:\FR\FM\19MYP2.SGM
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28178
Commodity
Federal Register / Vol. 75, No. 96 / Wednesday, May 19, 2010 / Proposed Rules
Parts per
million
Expiration/
Revocation
Date
§180.349 Fenamiphos; tolerances for
residues.
§180.371 Thiophanate-methyl; tolerances
for residues.
(a) General. Tolerances are
established for residues of the
Cotton,
nematicide/insecticide fenamiphos,
undelinted
seed ..............
2.8
1/1/12 ethyl 3-methyl-4-(methylthio)phenyl 1(methylethyl)phosphoramidate,
*
*
*
*
*
including its metabolites and
degradates, in or on the commodities in
16. Revise § 180.315 to read as
the table in this paragraph. Compliance
follows:
with the tolerance levels specified in
§180.315 Methamidophos; tolerances for
this paragraph is to be determined by
residues.
measuring only the sum of fenamiphos,
ethyl 3-methyl-4-(methylthio)phenyl 1(a) General. Tolerances are
(methylethyl)phosphoramidate, and its
established for residues of
cholinesterase inhibiting metabolites
methamidophos, O,S-dimethyl
ethyl 3-methyl-4-(methylsulfinyl)phenyl
phosphoramidothioate, including its
metabolites and degradates, in or on the 1-(methylethyl)phosphoramidate and
ethyl 3-methyl-4commodities in the table in this
(methylsulfonyl)phenyl 1paragraph as a result of the application
(methylethyl)phosphoramidate,
of methamidophos. Compliance with
calculated as the stoichiometric
the tolerance levels specified in this
equivalent of fenamiphos, in or on the
paragraph is to be determined by
commodity.
measuring only methamidophos, O,Sdimethyl phosphoramidothioate, in or
Parts per
on the commodity.
Commodity
million
Commodity
Broccoli1 .......
Cabbage2 ......
Cotton,
undelinted
seed ..........
Potato ...........
Parts per
million
Expiration/
Revocation
Date
1.0
1.0
12/31/12
12/31/12
0.1
0.1
12/31/12
12/31/12
1 There are no U.S. registrations since
1989.
2 There are no U.S. registrations since
2001.
jlentini on DSKJ8SOYB1PROD with PROPOSALS2
(b) Section 18 emergency exemptions.
[Reserved]
(c) Tolerances with regional
registrations. A tolerance with a regional
registration is established for residues of
methamidophos, O,S-dimethyl
phosphoramidothioate, including its
metabolites and degradates, in or on the
commodity in the table in this
paragraph as a result of the application
of methamidophos. Compliance with
the tolerance level specified in this
paragraph is to be determined by
measuring only methamidophos, O,Sdimethyl phosphoramidothioate, in or
on the commodity.
Banana1 ....................................
Grape1 ......................................
Grape, raisin1 ...........................
Pineapple1 ................................
0.1
0.1
0.3
0.3
1 There are no U.S. registrations as of May
31, 2007.
*
*
*
*
*
(c) Tolerances with regional
registrations. [Reserved]
*
*
*
*
*
18. In § 180.367 revise paragraph (a)
to read as follows:
§180.367 N-octyl bicycloheptene
dicarboximide; tolerances for residues.
(a) General. A tolerance of 5 parts per
million is established for residues of the
insecticide synergist N-octyl
bicycloheptene dicarboximide,
including its metabolites and
degradates, in or on all food items in
food handling establishments where
food and food products are held,
processed, prepared and/or served,
provided that the food is removed or
covered prior to such use, except for
bagged food in warehouse storage which
need not be removed or covered prior to
applications of formulations containing
Expiration/
Parts per
N-octyl bicycloheptene dicarboximide.
Commodity
Revocation
million
Compliance with the tolerance level
Date
specified in this paragraph is to be
Tomato ..........
2.0
12/31/12 determined by measuring only N-octyl
bicycloheptene dicarboximide, in or on
the commodity.
(d) Indirect or inadvertent residues.
[Reserved]
*
*
*
*
*
17. In § 180.349 revise paragraph (a)
19. Revise § 180.371 to read as
and paragraph (c) to read as follows:
follows:
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(a) General. Tolerances are
established for residues of thiophanatemethyl, dimethyl ((1,2-phenylene) bis
(iminocarbonothioyl)) bis(carbamate),
including its metabolites and
degradates, in or on the commodities in
the table in this paragraph. Compliance
with the tolerance levels specified in
this paragraph is to be determined by
measuring only the sum of thiophanatemethyl, dimethyl ((1,2-phenylene) bis
(iminocarbonothioyl)) bis(carbamate),
and its metabolite, methyl 2benzimidazoyl carbamate (MBC),
calculated as the stoichiometric
equivalent of thiophanate-methyl, in or
on the commodity.
Commodity
Almond ......................................
Almond, hulls ............................
Apple .........................................
Apricot .......................................
Banana .....................................
Bean, dry, seed ........................
Bean, snap, succulent ..............
Beet, sugar, roots .....................
Cherry, sweet ...........................
Cherry, tart ................................
Grain, aspirated fractions .........
Grape ........................................
Onion, bulb ...............................
Onion, green .............................
Peach ........................................
Peanut ......................................
Peanut, hay ..............................
Pear ..........................................
Pecan ........................................
Pistachio ...................................
Plum ..........................................
Potato .......................................
Soybean, hulls ..........................
Soybean, seed ..........................
Strawberry ................................
Vegetable, cucurbit, group 9 ....
Wheat, forage ...........................
Wheat, grain .............................
Wheat, hay ...............................
Wheat, straw .............................
Parts per
million
0.1
0.5
2.0
15.0
2.0
0.2
2.0
0.2
20.0
20.0
12
5.0
0.5
3.0
3.0
0.1
5.0
3.0
0.1
0.1
0.5
0.1
1.5
0.2
7.0
1.0
1.1
0.1
0.1
0.1
(b) Section 18 emergency exemptions.
[Reserved]
(c) Tolerances with regional
registrations. A tolerance with a regional
registration is established for residues of
thiophanate-methyl, dimethyl ((1,2phenylene) bis (iminocarbonothioyl))
bis(carbamate), including its metabolites
and degradates, in or on the commodity
in the table in this paragraph.
Compliance with the tolerance level
specified in this paragraph is to be
determined by measuring only the sum
of thiophanate-methyl, dimethyl ((1,2phenylene) bis (iminocarbonothioyl))
bis(carbamate), and its metabolite,
methyl 2-benzimidazoyl carbamate
(MBC), calculated as the stoichiometric
E:\FR\FM\19MYP2.SGM
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Federal Register / Vol. 75, No. 96 / Wednesday, May 19, 2010 / Proposed Rules
28179
paragraph is to be determined by
measuring only the sum of hexazinone,
3-cyclohexyl-6-(dimethylamino)-1Pineapple ..................................
0.6 methyl-1,3,5-triazine-2,4-(1H, 3H)Parts per milCommodity
Sugarcane, cane ......................
0.6 dione, and its metabolites: metabolite B,
lion
Sugarcane, molasses ...............
4.0
3-cyclohexyl-6-(methylamino)-1-methylCanola, seed ........................
0.1
1,3,5-triazine-2,4-(1H, 3H)-dione,
(2) Tolerances are established for
(d) Indirect or inadvertent residues.
residues of the herbicide hexazinone, 3- metabolite C, 3-(4-hydroxycyclohexyl)6-(methylamino)-1-methyl-1,3,5[Reserved]
cyclohexyl-6-(dimethylamino)-1triazine-2,4-(1H, 3H)-dione, metabolite
20. In § 180.396 revise paragraph (a),
methyl-1,3,5-triazine-2,4-(1H, 3H)C-2, 3-(3-hydroxycyclohexyl)-6and paragraph (c) to read as follows:
dione, including its metabolites and
degradates, in or on the commodities in (methylamino)-1-methyl-1,3,5-triazine§180.396 Hexazinone; tolerances for
2,4-(1H, 3H)-dione, and metabolite F, 3the table in this paragraph. Compliance
residues.
cyclohexyl-6-amino-1-methyl-1,3,5with the tolerance levels specified in
(a) General. (1) Tolerances are
triazine-2,4-(1H, 3H)-dione, calculated
this paragraph is to be determined by
established for residues of the herbicide
as the stoichiometric equivalent of
measuring only the sum of hexazinone,
hexazinone, 3-cyclohexyl-6hexazinone, in or on the commodity.
3-cyclohexyl-6-(dimethylamino)-1(dimethylamino)-1-methyl-1,3,5methyl-1,3,5-triazine-2,4-(1H, 3H)triazine-2,4-(1H, 3H)-dione, including
Parts per
Commodity
dione, and its animal tissue metabolites:
million
its metabolites and degradates, in or on
metabolite B, 3-cyclohexyl-6the commodities in the table in this
(methylamino)-1-methyl-1,3,5-triazineMilk ...........................................
11
paragraph. Compliance with the
2,4-(1H, 3H)-dione, and metabolite F, 3tolerance levels specified in this
cyclohexyl-6-amino-1-methyl-1,3,5*
*
*
*
*
paragraph is to be determined by
triazine-2,4-(1H, 3H)-dione, calculated
(c) Tolerances with regional
measuring only the sum of hexazinone,
as the stoichiometric equivalent of
registrations. [Reserved]
3-cyclohexyl-6-(dimethylamino)-1hexazinone, in or on the commodity.
*
*
*
*
*
methyl-1,3,5-triazine-2,4-(1H, 3H)dione, and its plant metabolites:
§ 180.407 [Amended]
Parts per
metabolite A, 3-(4-hydroxycyclohexyl)Commodity
million
21. In § 180.407 remove the entry for
6-(dimethylamino)-1-methyl-1,3,5‘‘cotton, hulls’’ from the table in
triazine-2,4-(1H, 3H)-dione, metabolite
Cattle, fat ..................................
0.1
B, 3-cyclohexyl-6-(methylamino)-1Cattle, meat ..............................
0.5 paragraph (a).
22. Revise § 180.905 to read as
methyl-1,3,5-triazine-2,4-(1H, 3H)Cattle, meat byproducts ...........
4.0
Goat, fat ....................................
0.1 follows:
dione, metabolite C, 3-(40.5
hydroxycyclohexyl)-6-(methylamino)-1- Goat, meat ................................
Goat, meat byproducts .............
4.0 §180.905 Pesticide chemicals; exemptions
methyl-1,3,5-triazine-2,4-(1H, 3H)Hog, fat .....................................
0.1 from the requirement of a tolerance.
dione, metabolite D, 3-cyclohexyl-10.5
(a) When applied to growing crops, in
methyl-1,3,5-triazine-2,4,6-(1H, 3H, 5H)- Hog, meat .................................
Hog, meat byproducts ..............
4.0 accordance with good agricultural
trione, and metabolite E, 3-(4Horse, fat ..................................
0.1 practice, the following pesticide
hydroxycyclohexyl)-1-methyl-1,3,5Horse, meat ..............................
0.5 chemicals are exempt from the
triazine-2,4,6-(1H, 3H, 5H)-trione,
Horse, meat byproducts ...........
4.0
requirement of a tolerance:
calculated as the stoichiometric
Sheep, fat .................................
0.1
(1) Petroleum oils.
Sheep, meat .............................
0.5
equivalent of hexazinone, in or on the
(2) Piperonyl butoxide.
Sheep, meat byproducts ..........
4.0
commodity.
(3) Pyrethrins.
(4) Rotenone or derris or cube roots.
(3) A tolerance is established for
Parts per
Commodity
million
residues of the herbicide hexazinone, 3(5) Sabadilla.
cyclohexyl-6-(dimethylamino)-1(b) These pesticides are not exempted
Alfalfa, forage ...........................
2.0 methyl-1,3,5-triazine-2,4-(1H, 3H)from the requirement of a tolerance
Alfalfa, hay ................................
4.0
when applied to a crop at the time of or
Alfalfa, seed ..............................
2.0 dione, including its metabolites and
after harvest.
Blueberry ..................................
0.6 degradates, in or on the commodity in
[FR Doc. 2010–11845 Filed 5–18–10; 8:45 am]
Grass, forage ............................
250 the table in this paragraph. Compliance
Grass, hay ................................
230 with the tolerance level specified in this BILLING CODE 6560–50–S
jlentini on DSKJ8SOYB1PROD with PROPOSALS2
equivalent of thiophanate-methyl, in or
on the commodity.
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million
Commodity
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E:\FR\FM\19MYP2.SGM
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Agencies
[Federal Register Volume 75, Number 96 (Wednesday, May 19, 2010)]
[Proposed Rules]
[Pages 28156-28179]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: 2010-11845]
[[Page 28155]]
-----------------------------------------------------------------------
Part III
Environmental Protection Agency
-----------------------------------------------------------------------
40 CFR Part 180
Acephate, Cacodylic acid, Dicamba, Dicloran et al.; Proposed Tolerance
Actions; Proposed Rule
Federal Register / Vol. 75, No. 96 / Wednesday, May 19, 2010 /
Proposed Rules
[[Page 28156]]
-----------------------------------------------------------------------
ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 180
[EPA-HQ-OPP-2010-0262; FRL-8821-3]
Acephate, Cacodylic acid, Dicamba, Dicloran et al.; Proposed
Tolerance Actions
AGENCY: Environmental Protection Agency (EPA).
ACTION: Proposed rule.
-----------------------------------------------------------------------
SUMMARY: EPA is proposing to revoke certain tolerances for the
fungicides dicloran and thiophanate-methyl; the herbicides EPTC,
hexazinone, picloram, and propazine; the defoliant and herbicide
cacodylic acid; the plant growth regulator and herbicide diquat, the
insecticides disulfoton, malathion, methamidophos, methomyl, phosmet,
piperonyl butoxide, pyrethrins, and thiodicarb; the fumigant
antimicrobial and insecticide methyl bromide, the nematicides/
insecticides ethoprop and fenamiphos, the insecticide synergist N-octyl
bicycloheptene dicarboximide, and the tolerance exemptions for the
insecticide/miticide pyrethrum and insecticide synergist N-octyl
bicycloheptene dicarboximide. In addition, EPA is proposing to remove
certain expired tolerances for disulfoton, fenamiphos, and thiophanate-
methyl. Also, EPA is proposing to modify certain tolerances for the
fungicide thiophanate-methyl, herbicides dicamba, EPTC, hexazinone and
picloram, and insecticide synergist N-octyl bicycloheptene
dicarboximide. In addition, EPA is proposing to establish new
tolerances for the fungicide thiophanate-methyl and the herbicides
EPTC, hexazinone, and picloram. Also, EPA is proposing to reinstate
specific tolerances for methamidophos residues as a result of the
application of the insecticide acephate. The regulatory actions
proposed in this document are in follow-up to the Agency's
reregistration program under the Federal Insecticide, Fungicide, and
Rodenticide Act (FIFRA), and tolerance reassessment program under the
Federal Food, Drug, and Cosmetic Act (FFDCA), section 408(q).
DATES: Comments must be received on or before July 19, 2010.
ADDRESSES: Submit your comments, identified by docket identification
(ID) number EPA-HQ-OPP-2010-0262, by one of the following methods:
Federal eRulemaking Portal: https://www.regulations.gov.
Follow the on-line instructions for submitting comments.
Mail: Office of Pesticide Programs (OPP) Regulatory Public
Docket (7502P), Environmental Protection Agency, 1200 Pennsylvania
Ave., NW., Washington, DC 20460-0001.
Delivery: OPP Regulatory Public Docket (7502P),
Environmental Protection Agency, Rm. S-4400, One Potomac Yard (South
Bldg.), 2777 S. Crystal Dr., Arlington, VA. Deliveries are only
accepted during the Docket Facility's normal hours of operation (8:30
a.m. to 4 p.m., Monday through Friday, excluding legal holidays).
Special arrangements should be made for deliveries of boxed
information. The Docket Facility telephone number is (703) 305-5805.
Instructions: Direct your comments to docket ID number EPA-HQ-OPP-
2010-0262. EPA's policy is that all comments received will be included
in the docket without change and may be made available on-line at
https://www.regulations.gov, including any personal information
provided, unless the comment includes information claimed to be
Confidential Business Information (CBI) or other information whose
disclosure is restricted by statute. Do not submit information that you
consider to be CBI or otherwise protected through regulations.gov or e-
mail. The regulations.gov website is an ``anonymous access'' system,
which means EPA will not know your identity or contact information
unless you provide it in the body of your comment. If you send an e-
mail comment directly to EPA without going through regulations.gov,
your e-mail address will be automatically captured and included as part
of the comment that is placed in the docket and made available on the
Internet. If you submit an electronic comment, EPA recommends that you
include your name and other contact information in the body of your
comment and with any disk or CD-ROM you submit. If EPA cannot read your
comment due to technical difficulties and cannot contact you for
clarification, EPA may not be able to consider your comment. Electronic
files should avoid the use of special characters, any form of
encryption, and be free of any defects or viruses.
Docket: All documents in the docket are listed in the docket index
available at https://www.regulations.gov. Although listed in the index,
some information is not publicly available, e.g., CBI or other
information whose disclosure is restricted by statute. Certain other
material, such as copyrighted material, is not placed on the Internet
and will be publicly available only in hard copy form. Publicly
available docket materials are available either in the electronic
docket at https://www.regulations.gov, or, if only available in hard
copy, at the OPP Regulatory Public Docket in Rm. S-4400, One Potomac
Yard (South Bldg.), 2777 S. Crystal Dr., Arlington, VA. The hours of
operation of this Docket Facility are from 8:30 a.m. to 4 p.m., Monday
through Friday, excluding legal holidays. The Docket Facility telephone
number is (703) 305-5805.
FOR FURTHER INFORMATION CONTACT: Joseph Nevola, Pesticide Re-evaluation
Division (7508P), Office of Pesticide Programs, Environmental
Protection Agency, 1200 Pennsylvania Ave, NW., Washington, DC 20460-
0001; telephone number: (703) 308-8037; e-mail address:
nevola.joseph@epa.gov.
SUPPLEMENTARY INFORMATION:
I. General Information
A. Does this Action Apply to Me?
You may be potentially affected by this action if you are an
agricultural producer, food manufacturer, or pesticide manufacturer.
Potentially affected entities may include, but are not limited to:
Crop production (NAICS code 111).
Animal production (NAICS code 112).
Food manufacturing (NAICS code 311).
Pesticide manufacturing (NAICS code 32532).
This listing is not intended to be exhaustive, but rather provides
a guide for readers regarding entities likely to be affected by this
action. Other types of entities not listed in this unit could also be
affected. The North American Industrial Classification System (NAICS)
codes have been provided to assist you and others in determining
whether this action might apply to certain entities. To determine
whether you or your business may be affected by this action, you should
carefully examine the applicability provisions in Unit II.A. If you
have any questions regarding the applicability of this action to a
particular entity, consult the person listed under FOR FURTHER
INFORMATION CONTACT.
B. What Should I Consider as I Prepare My Comments for EPA?
1. Submitting CBI. Do not submit this information to EPA through
regulations.gov or e-mail. Clearly mark the part or all of the
information that you claim to be CBI. For CBI information in a disk or
CD-ROM that you mail to EPA, mark the outside of the disk or CD-ROM as
CBI and then identify electronically within the disk or CD-ROM the
specific information that is
[[Page 28157]]
claimed as CBI. In addition to one complete version of the comment that
includes information claimed as CBI, a copy of the comment that does
not contain the information claimed as CBI must be submitted for
inclusion in the public docket. Information so marked will not be
disclosed except in accordance with procedures set forth in 40 CFR part
2.
2. Tips for preparing your comments. When submitting comments,
remember to:
i. Identify the document by docket ID number and other identifying
information (subject heading, Federal Register date and page number).
ii. Follow directions. The Agency may ask you to respond to
specific questions or organize comments by referencing a Code of
Federal Regulations (CFR) part or section number.
iii. Explain why you agree or disagree; suggest alternatives and
substitute language for your requested changes.
iv. Describe any assumptions and provide any technical information
and/or data that you used.
v. If you estimate potential costs or burdens, explain how you
arrived at your estimate in sufficient detail to allow for it to be
reproduced.
vi. Provide specific examples to illustrate your concerns and
suggest alternatives.
vii. Explain your views as clearly as possible, avoiding the use of
profanity or personal threats.
viii. Make sure to submit your comments by the comment period
deadline identified.
C. What Can I do if I Wish the Agency to Maintain a Tolerance that the
Agency Proposes to Revoke?
This proposed rule provides a comment period of 60 days for any
person to state an interest in retaining a tolerance proposed for
revocation. If EPA receives a comment within the 60-day period to that
effect, EPA will not proceed to revoke the tolerance immediately.
However, EPA will take steps to ensure the submission of any needed
supporting data and will issue an order in the Federal Register under
FFDCA section 408(f), if needed. The order would specify data needed
and the timeframes for its submission, and would require that within 90
days some person or persons notify EPA that they will submit the data.
If the data are not submitted as required in the order, EPA will take
appropriate action under FFDCA.
EPA issues a final rule after considering comments that are
submitted in response to this proposed rule. In addition to submitting
comments in response to this proposal, you may also submit an objection
at the time of the final rule. If you fail to file an objection to the
final rule within the time period specified, you will have waived the
right to raise any issues resolved in the final rule. After the
specified time, issues resolved in the final rule cannot be raised
again in any subsequent proceedings.
II. Background
A. What Action is the Agency Taking?
EPA is proposing to revoke, modify, and establish specific
tolerances for residues of the fungicides dicloran and thiophanate-
methyl; the herbicides dicamba, EPTC, hexazinone, picloram, and
propazine; the defoliant and herbicide cacodylic acid; the plant growth
regulator and herbicide diquat, the insecticides disulfoton, malathion,
methamidophos, methomyl, phosmet, piperonyl butoxide, pyrethrins, and
thiodicarb; the fumigant antimicrobial and insecticide methyl bromide,
the nematicides/insecticides ethoprop and fenamiphos; and the
insecticide synergist N-octyl bicycloheptene dicarboximide; revoke the
tolerance exemptions for the insecticide/miticide pyrethrum and
insecticide synergist N-octyl bicycloheptene dicarboximide; remove
certain expired tolerances for disulfoton, fenamiphos, and thiophanate-
methyl; and reinstate specific tolerances for methamidophos residues as
a result of the application of the insecticide acephate in or on
commodities listed in the regulatory text.
EPA is proposing these tolerance/tolerance exemption actions to
implement the tolerance recommendations made during the reregistration
and tolerance reassessment processes (including follow-up on canceled
or additional uses of pesticides). As part of these processes, EPA is
required to determine whether each of the amended tolerances meets the
safety standard of FFDCA. The safety finding determination of
``reasonable certainty of no harm'' is discussed in detail in each
Reregistration Eligibility Decision (RED) and Report of the Food
Quality Protection Act (FQPA) Tolerance Reassessment Progress and Risk
Management Decision (TRED) for the active ingredient. REDs and TREDs
recommend the implementation of certain tolerance actions, including
modifications to reflect current use patterns, meet safety findings,
and change commodity names and groupings in accordance with new EPA
policy. Printed copies of many REDs and TREDs may be obtained from
EPA's National Service Center for Environmental Publications (EPA/
NSCEP), P.O. Box 42419, Cincinnati, OH 45242-2419; telephone number: 1-
800-490-9198; fax number: 1-513-489-8695; Internet at https://www.epa.gov/ncepihom and from the National Technical Information
Service (NTIS), 5285 Port Royal Rd., Springfield, VA 22161; telephone
number: 1-800-553-6847 or (703) 605-6000; Internet at https://www.ntis.gov. Electronic copies of REDs and TREDs are available on the
Internet in public dockets; REDs for cacodylic acid (EPA-HQ-OPP-2006-
0201), dicamba (EPA-HQ-OPP-2005-0479), ethoprop (EPA-HQ-OPP-2002-0269),
malathion (EPA-HQ-OPP-2004-0348), N-octyl bicycloheptene dicarboximide
(EPA-HQ-OPP-2005-0040), pyrethrum (see pyrethrins RED in EPA-HQ-OPP-
2005-0043), and thiophanate-methyl (EPA-HQ-OPP-2004-0265), and TREDs
for hexazinone (EPA-HQ-OPP-2002-0188) and propazine (EPA-HQ-OPP-2005-
0496) at https://www.regulations.gov and REDs for acephate, EPTC,
methamidophos, phosmet, and picloram at https://www.epa.gov/pesticides/reregistration/status.htm.
The selection of an individual tolerance level is based on crop
field residue studies designed to produce the maximum residues under
the existing or proposed product label. Generally, the level selected
for a tolerance is a value slightly above the maximum residue found in
such studies, provided that the tolerance is safe. The evaluation of
whether a tolerance is safe is a separate inquiry. EPA recommends the
raising of a tolerance when data show that:
Lawful use (sometimes through a label change) may result
in a higher residue level on the commodity.
The tolerance remains safe, notwithstanding increased
residue level allowed under the tolerance.
In REDs, Chapter IV on ``Risk management, Reregistration, and Tolerance
reassessment'' typically describes the regulatory position, FQPA
assessment, cumulative safety determination, determination of safety
for U.S. general population, and safety for infants and children. In
particular, the human health risk assessment document which supports
the RED describes risk exposure estimates and whether the Agency has
concerns. In TREDs, the Agency discusses its evaluation of the dietary
risk associated with the active ingredient and whether it can determine
that there is a reasonable certainty (with appropriate mitigation) that
no harm to any population subgroup will result from
[[Page 28158]]
aggregate exposure. EPA also seeks to harmonize tolerances with
international standards set by the Codex Alimentarius Commission, as
described in Unit III.
Explanations for proposed modifications in tolerances can be found
in the RED and TRED document and in more detail in the Residue
Chemistry Chapter document which supports the RED and TRED. Copies of
the Residue Chemistry Chapter documents are found in the Administrative
Record and electronic copies for dicamba, ethoprop (Data Requirements
and Tolerance Reassessment), hexazinone, malathion, N-octyl
bicycloheptene dicarboximide, propazine, pyrethrum (see pyrethrins),
and thiophanate-methyl can be found under their respective public
docket ID numbers, identified in Unit II.A. Electronic copies are also
available in public dockets for acephate (EPA-HQ-OPP-2007-0445),
cacodylic acid (EPA-HQ-OPP-2006-0201), methamidophos (EPA-HQ-OPP-2007-
0261), and phosmet (EPA-HQ-OPP-2008-0834), and for EPTC in the public
docket for this proposed rule. Electronic copies are available through
EPA's electronic public docket and comment system, regulations.gov at
https://www.regulations.gov. You may search for this proposed rule under
docket ID number EPA-HQ-OPP-2010-0262, then click on that docket ID
number to view its contents.
EPA has determined that the aggregate exposures and risks are not
of concern for the above mentioned pesticide active ingredients based
upon the data identified in the RED or TRED which lists the submitted
studies that the Agency found acceptable.
EPA has found that the tolerances/tolerance exemptions that are
proposed in this document to be modified, are safe; i.e., that there is
a reasonable certainty that no harm will result to infants and children
from aggregate exposure to the pesticide chemical residues, in
accordance with FFDCA section 408(b)(2)(C). (Note that changes to
tolerance nomenclature do not constitute modifications of tolerances).
These findings are discussed in detail in each RED or TRED. The
references are available for inspection as described in this document
under SUPPLEMENTARY INFORMATION.
In addition, EPA is proposing to revoke certain specific
tolerances/tolerance exemptions because either they are no longer
needed or are associated with food uses that are no longer registered
under FIFRA. Those instances where registrations were canceled were
because the registrant failed to pay the required maintenance fee and/
or the registrant voluntarily requested cancellation of one or more
registered uses of the pesticide. It is EPA's general practice to
propose revocation of those tolerances/tolerance exemptions for
residues of pesticide active ingredients on crop uses for which there
are no active registrations under FIFRA, unless any person in comments
on the proposal indicates a need for the tolerance to cover residues in
or on imported commodities or legally treated domestic commodities.
1. Acephate. In order to describe more clearly the measurement and
scope or coverage of the tolerances, EPA is proposing to revise the
introductory text containing the tolerance expression in 40 CFR
180.108(a)(1) to read as follows:
Tolerances are established for residues of acephate, O,S-
dimethyl acetyl phosphoramidothioate, including its metabolites and
degradates other than methamidophos, in or on the commodities in the
table in this paragraph. Compliance with the tolerance levels
specified in this paragraph is to be determined by measuring only
acephate, O,S-dimethyl acetyl phosphoramidothioate, in or on the
commodity.
In the Federal Register of January 29, 2008 (73 FR 5104) (FRL-8348-
8), EPA revised the tolerance expression for acephate in 40 CFR 180.108
from the combined residues of acephate, O,S-dimethyl acetyl
phosphoramidothioate, and methamidophos, O,S-dimethyl
phosphoramidothioate, to residues of acephate per se, removed the
terminology ``of which no more than 1 ppm, 0.5 ppm, or 0.1 ppm is O,S-
dimethyl phosphoramidothioate'' from tolerances on bean (succulent and
dry); Brussels sprouts; cauliflower; celery; cranberry; lettuce, head;
mint hay, and pepper; and footnoted that residues of the acephate
metabolite, methamidophos, are regulated under 40 CFR 180.315. However,
the basis for this action was in error, as methamidophos tolerances for
bean, dry, seed; bean, succulent; cranberry; peppermint, tops; and
spearmint, tops had not in fact been established in 40 CFR 180.315. To
remedy this inadvertent error, the Agency proposes to reinstate the 40
CFR 180.108 tolerances. Consequently, EPA is proposing to separate
tolerances for residues of methamidophos from the application of
acephate in newly designated 40 CFR 180.108(a)(3), with the
introductory text to read as follows:
Tolerances are established for residues of methamidophos, O,S-
dimethyl phosphoramidothioate, including its metabolites and
degradates, in or on the commodities in the table in this paragraph
as a result of the application of acephate. Compliance with the
tolerance levels specified in this paragraph is to be determined by
measuring only methamidophos, O,S-dimethyl phosphoramidothioate, in
or on the commodity.
In addition, EPA is proposing to reinstate the tolerances in 40 CFR
180.108(a)(3) on bean, dry, seed at 1 ppm; bean, succulent at 1 ppm;
Brussels sprouts at 0.5 ppm; cauliflower at 0.5 ppm (which is in
harmony with the Codex maximumn residue limits (MRL) of 0.5 milligrams/
kilogram (mg/kg) on cauliflower); celery 1 ppm; cranberry at 0.1 ppm;
lettuce, head at 1 ppm; pepper at 1 ppm; and reinstate mint hay,
revising the tolerance terminology to peppermint, tops at 1 ppm and
spearmint, tops at 1 ppm. On January 29, 2008, EPA published a final
rule in the Federal Register (73 FR 5104) (FRL-8348-8), which finalized
tolerance actions for several active ingredients, including acephate,
and which increased the tolerances in 40 CFR 180.108(a)(1) for acephate
residues in or on mint hay (peppermint, tops and spearmint, tops) from
15.0 to 27.0 ppm. Consequently, methamidophos residues resulting from
acephate application are expected by the Agency to be increased from
1.0 to 2.0 ppm in or on peppermint, tops and spearmint, tops. However,
the Agency is not proposing an increase on the peppermint, tops and
spearmint, tops tolerances for methamidophos residues at this time.
Based on available data that showed residues of acephate were as
high as 0.02 ppm for only one of seven exposed food items following
both a spot treatment and crack/crevice treatment for rooms treated
with acephate at the 1x rate and residues of methamidophos were
undetectable from these acephate treatments, the Agency determined that
a tolerance level of 0.02 ppm for acephate residues was appropriate and
that there was no expectation of methamidophos residues and therefore
no methamidophos tolerance was needed concerning food handling
establishments. Consequently, compliance with the tolerance at 0.02 ppm
in 40 CFR 180.108(a)(2) should continue to be determined by measuring
only acephate residues. However, in order to describe more clearly the
measurement and scope or coverage of the tolerances, EPA is proposing
to revise the introductory text containing the tolerance expression in
40 CFR 180.108(a)(2), to read as follows:
A tolerance of 0.02 ppm is established for residues of acephate,
O,S-dimethyl acetyl phosphoramidothioate, including its metabolites
and degradates other than methamidophos, in or on all food items
[[Page 28159]]
(other than those already covered by a higher tolerance as a result
of use on growing crops) in food handling establishments where food
and food products are held, processed, prepared and served,
including food service, manufacturing and processing establishments,
such as restaurants, cafeterias, supermarkets, bakeries, breweries,
dairies, meat slaughtering and packing plants, and canneries, where
application of acephate shall be limited solely to spot and/or crack
and crevice treatment (a coarse, low-pressure spray shall be used to
avoid atomization or splashing of the spray for spot treatments;
equipment capable of delivering a pin-stream of insecticide shall be
used for crack and crevice treatments). Spray concentration shall be
limited to a maximum of 1.0 percent active ingredient. Contamination
of food or food-contact surfaces shall be avoided. Compliance with
the tolerance levels specified in this paragraph is to be determined
by measuring only acephate, O,S-dimethyl acetyl
phosphoramidothioate, in or on the commodity.
Because EPA is proposing to revise 40 CFR 180.108(a)(2) and include
text from 40 CFR 180.108(a)(2)(i) and (a)(2)(ii), existing paragraphs
(a)(2)(i) and (a)(2)(ii) are no longer needed. Therefore, EPA is
proposing to remove 40 CFR 180.108(a)(2)(i) and (a)(2)(ii).
In order to describe more clearly the measurement and scope or
coverage of the tolerances, EPA is proposing to revise the introductory
text containing the regional tolerance expression in 40 CFR 180.108(c)
to read as follows:
A tolerance with a regional registration is established for
residues of acephate, O,S-dimethyl acetyl phosphoramidothioate,
including its metabolites and degradates other than methamidophos,
in or on the commodity in the table in this paragraph. Compliance
with the tolerance level specified in this paragraph is to be
determined by measuring only acephate, O,S-dimethyl acetyl
phosphoramidothioate, in or on the commodity.
Also, EPA is proposing to revise the table footnote in 40 CFR
180.108(a)(1) and add a table footnote in 40 CFR 180.108(c) to read as
follows:
Where there is a direct use of methamidophos on the commodity,
residues of methamidophos resulting from methamidophos application
are regulated under 40 CFR 180.315.
There are Codex MRLs for acephate, including those on beans, except
broad bean and soya bean at 5 mg/kg, cauliflower at 2 mg/kg, cranberry
at 0.5 mg/kg, peppers, chili (dry) at 50 mg/kg, and other commodities.
2. Cacodylic acid. In the Federal Register notice of July 8, 2009
(74 FR 32596) (FRL-8422-6), EPA issued a notice regarding EPA's
announcement of the receipt of requests from registrants to voluntarily
cancel certain registrations, including ones for cacodylic acid (and
sodium salt) and therefore terminate the last cacodylic acid (and
sodium salt) uses in or on cotton. After the close of the 30-day
comment period, EPA approved cancellation of certain registrations,
including the cacodylic acid (and sodium salt) registrations for uses
in or on cotton and issued a cancellation order in the Federal Register
notice of September 30, 2009 (74 FR 50187)(FRL-8437-7), made them
effective on September 30, 2009, and prohibited the registrants for the
canceled cacodylic acid (and sodium salt) registrations to sell and
distribute existing stocks after December 31, 2009. Also, EPA
prohibited persons other than the registrant to sell and distribute the
canceled cacodylic acid (and sodium salt) existing stocks after
December 31, 2010. The Agency believes that end users will have had
sufficient time to exhaust those existing stocks and for treated cotton
commodities to have cleared the channels of trade by January 1, 2012.
The termination of the last cacodylic acid (and sodium salt) uses in or
on cotton means that the tolerance will no longer be needed and should
be revoked with an expiration/revocation date. Therefore, EPA is
proposing to revoke the tolerance in 40 CFR 180.311(a) on cotton,
undelinted seed with an expiration/revocation date of January 1, 2012.
Currently, tolerances are expressed for the defoliant cacodylic
acid in 40 CFR 180.311(a) for residues of cacodylic acid
(dimethylarsinic acid), expressed as As2O3. In
order to describe more clearly the measurement and scope or coverage of
the tolerances, EPA is proposing to revise the introductory text
containing the tolerance expression in 40 CFR 180.311(a) to read as
follows:
A tolerance is established for residues of the defoliant
cacodylic acid, dimethylarsinic acid, including its metabolites and
degradates, in or on the commodity in the table in this paragraph.
Compliance with the tolerance level specified in this paragraph is
to be determined by measuring only those cacodylic acid residues
convertible to As2O3, expressed as the
stoichiometric equivalent of cacodylic acid, in or on the commodity.
There are no Codex MRLs for cacodylic acid.
3. Dicamba. Based on available processing data that showed an
average concentration factor of 24.4X for molasses and the Highest
Average Field Trial (HAFT) residue of 0.183 ppm for sugarcane, EPA
determined that the expected combined dicamba residues of concern in
sugarcane molasses are 4.465 ppm, and that the currently established
tolerance of 2.0 ppm for sugarcane molasses should be increased from
2.0 to 5.0 ppm. Therefore, the Agency is proposing to increase the
tolerance in 40 CFR 180.227(a)(1) on sugarcane, molasses to 5.0 ppm.
The Agency determined that the increased tolerance is safe; i.e., there
is a reasonable certainty that no harm will result from aggregate
exposure to the pesticide chemical residue.
Based on available sugarcane field trial data that showed combined
dicamba residues of concern as high as 0.2 ppm in or on sugarcane
harvested 87-173 days following a single layby application at 2.0 lb
dicamba acid equivalents per acre (ae/A), EPA determined that the
tolerance should be increased from 0.1 to 0.3 ppm. While the available
data, conducted at an application rate of 2.0 lb dicamba ae/A, do not
support the maximum seasonal single/yearly rate of 2.8 lb dicamba ae/A
that was listed in the Dicamba Master Use Profile, the Agency
determined that the available data was adequate provided the
registrants revise their product labels to specify a maximum seasonal
rate of 2.0 lb dicamba ae/A and an 87-day preharvest interval (PHI) for
sugarcane or submit additional data on sugarcane reflecting a maximum
single/yearly rate of 2.8 lb dicamba ae/A. In response to the Data
Call-In (DCI) of June 27, 2008 that was issued to registrants,
including the basic manufacturer BASF, BASF requested a waiver of the
sugarcane study at 2.8 lb dicamba ae/A and cited MRID 44089302, and
accepted rate limitations of 1 lb dicamba ae/A for single application,
and an annual rate limitation of 2 lb dicamba ae/A. The Agency
considers that available data to be sufficient provided product labels
specify a maximum seasonal rate of 2.0 lb dicamba ae/A and an 87-day
PHI for sugarcane. Therefore, because the current tolerance on
sugarcane, cane at 0.1 ppm is too low, based on the available data, EPA
is proposing to increase the tolerance in 40 CFR 180.227(a)(1) on
sugarcane, cane to 0.3 ppm. The Agency determined that the increased
tolerance is safe; i.e., there is a reasonable certainty that no harm
will result from aggregate exposure to the pesticide chemical residue.
In order to describe more clearly the measurement and scope or
coverage of the tolerances, EPA is proposing to revise the introductory
text containing the tolerance expression in 40 CFR 180.227(a)(1) to
read as follows:
Tolerances are established for residues of the herbicide
dicamba, 3,6-dichloro-o-anisic
[[Page 28160]]
acid, including its metabolites and degradates, in or on the
commodities in the table in this paragraph. Compliance with the
tolerance levels specified in this paragraph is to be determined by
measuring only the sum of dicamba, 3,6-dichloro-o-anisic acid, and
its metabolite, 3,6-dichloro-5-hydroxy-o-anisic acid, calculated as
the stoichiometric equivalent of dicamba, in or on the commodity.
In order to describe more clearly the measurement and scope or
coverage of the tolerances, EPA is proposing to revise the introductory
text containing the tolerance expression in 40 CFR 180.227(a)(2) to
read as follows:
Tolerances are established for residues of the herbicide
dicamba, 3,6-dichloro-o-anisic acid, including its metabolites and
degradates, in or on the commodities in the table in this paragraph.
Compliance with the tolerance levels specified in this paragraph is
to be determined by measuring only the sum of dicamba, 3,6-dichloro-
o-anisic acid, and its metabolite, 3,6-dichloro-2-hydroxybenzoic
acid, calculated as the stoichiometric equivalent of dicamba, in or
on the commodity.
In order to describe more clearly the measurement and scope or
coverage of the tolerances, EPA is proposing to revise the introductory
text containing the tolerance expression in 40 CFR 180.227(a)(3) to
read as follows:
Tolerances are established for residues of the herbicide
dicamba, 3,6-dichloro-o-anisic acid, including its metabolites and
degradates, in or on the commodities in the table in this paragraph.
Compliance with the tolerance levels specified in this paragraph is
to be determined by measuring only the sum of dicamba, 3,6-dichloro-
o-anisic acid, and its metabolites, 3,6-dichloro-5-hydroxy-o-anisic
acid, and 3,6-dichloro-2-hydroxybenzoic acid, calculated as the
stoichiometric equivalent of dicamba, in or on the commodity.
There are no Codex MRLs for dicamba.
4. Dicloran (DCNA). On December 2, 2009, EPA published a notice in
the Federal Register (74 FR 63151) (FRL-8800-4) that announced the
Agency's receipt of requests from the registrants to voluntarily amend
certain dicloran registrations and therefore terminate the last
dicloran uses on carrots. EPA approved amendment of the affected DCNA
registrations by publishing a cancellation order on March 31, 2010 in
the Federal Register (75 FR 16105) (FRL-8815-8) and made them effective
on November 2, 2010, and permitted the dicloran registrant to sell and
distribute existing dicloran stocks (concerning the last uses for
carrots) until November 2, 2010. For all affected dicloran products,
the Agency permitted persons other than the registrant to sell and
distribute existing stocks and use of those cancelled products until
exhaustion. However, the Agency believes that end users will have had
sufficient time to exhaust those existing stocks and for treated carrot
commodities to have cleared the channels of trade by November 2, 2011.
Therefore, EPA is proposing to revoke the tolerance in 40 CFR
180.200(a)(1) for carrot, roots, postharvest with an expiration/
revocation date of November 2, 2011.
In order to describe more clearly the measurement and scope or
coverage of the tolerances, EPA is proposing to revise the introductory
text containing the tolerance expression in 40 CFR 180.200(a)(1) to
read as follows:
Tolerances are established for residues of the fungicide
dicloran, 2,6-dichloro-4-nitroaniline, including its metabolites and
degradates, in or on the commodities in the table in this paragraph.
Compliance with the tolerance levels specified in this paragraph is
to be determined by measuring only dicloran, 2,6-dichloro-4-
nitroaniline, in or on the commodity. Unless otherwise specified,
these tolerances prescribed in this paragraph provide for residues
from preharvest application only.
There are Codex MRLs for dicloran, including an MRL on carrot at 15
mg/kg, and MRLs on other plant commodities.
5. Diquat. Currently, the only active registrations for diquat use
on both sorghum grain and soybeans are for seed crops, and both uses
have restrictions to not graze or feed treated forage to livestock and
not use seed from treated plants for food, feed, or oil purposes. Given
the restrictions, such uses are considered by the Agency to be non-
food, and therefore the tolerances are no longer needed and should be
revoked. Consequently, EPA is proposing to revoke the tolerances in 40
CFR 180.226(a)(1) on sorghum, grain, grain and soybean, seed.
There are Codex MRLs for diquat on sorghum at 2 mg/kg and on
soybean (dry) at 0.2 mg/kg.
6. Disulfoton. On July 22, 2009, EPA published a notice in the
Federal Register (74 FR 36204) (FRL-8427-2) that announced the Agency's
receipt of requests from the registrants to voluntarily cancel all
disulfoton and methamidophos registrations and therefore terminate the
last disulfoton and methamidophos products registered for use in the
United States, including the last disulfoton uses on asparagus, lima
and snap beans, broccoli, Brussels sprouts, cabbage, cauliflower,
coffee, cotton, and lettuce. EPA approved cancellation of the
registrations by publishing a cancellation order on September 23, 2009
in the Federal Register (74 FR 48551) (FRL-8437-1) and made them
effective on September 23, 2009, and permitted the disulfoton
registrants to sell and distribute existing disulfoton stocks
(concerning the last uses for asparagus, lima and snap beans, broccoli,
Brussels sprouts, cabbage, cauliflower, cotton, and lettuce) until
December 31, 2010 and stocks of a single registration (264-723) with
the last coffee use until June 30, 2011. For all affected disulfoton
products, the Agency permitted persons other than the registrant to
sell and distribute existing stocks and use of those cancelled products
until exhaustion. However, the Agency believes that end users will have
had sufficient time to exhaust those existing stocks and for treated
asparagus, lima and snap beans, broccoli, Brussels sprouts, cabbage,
cauliflower, cotton, and lettuce commodities to have cleared the
channels of trade by December 31, 2012 and treated coffee commodities
to have cleared the channels of trade by June 30, 2013. Therefore, EPA
is proposing to revoke the tolerances in 40 CFR 180.183(a) for bean,
lima; bean, snap, succulent; broccoli; Brussels sprouts; cabbage;
cauliflower; cotton, undelinted seed; lettuce, head; and lettuce, leaf
with expiration/revocation dates of December 31, 2012. Also, because
there had been only active FIFRA section 24(c) registrations for use of
disulfoton on asparagus, EPA is proposing to revoke the regional
tolerance in 40 CFR 180.183(c) on asparagus with an expiration/
revocation date of December 31, 2012. In addition, EPA is proposing to
revoke the tolerance in 40 CFR 180.183(a) for coffee, green bean with
an expiration/revocation date of June 30, 2013.
Because the tolerances for combined disulfoton residues of concern
expired on October 14, 2009, EPA is proposing to remove the tolerances
in 40 CFR 180.183(a) on spinach and tomato. Also, because the
tolerances for combined disulfoton residues of concern expired on
January 30, 2010, EPA is proposing to remove the tolerances in 40 CFR
180.183(a) on barley, grain; barley, straw; cattle, fat; cattle, meat;
cattle, meat byproducts; goat, fat; goat, meat; goat, meat byproducts;
grain, aspirated fractions; hog, fat; hog, meat; hog, meat byproducts;
horse, fat; horse, meat; horse, meat byproducts; milk; peanut; pepper;
potato; sheep, fat; sheep, meat; sheep, meat byproducts; wheat, grain;
wheat, hay; and wheat, straw.
In order to describe more clearly the measurement and scope or
coverage of the tolerances, EPA is proposing to revise the section
heading in 40 CFR 180.183 from O,O-diethyl S-(2-
[[Page 28161]]
(ethylthio)ethyl) phosphorodithioate to disulfoton and revise the
introductory text containing the tolerance expression in 40 CFR
180.183(a) to read as follows:
Tolerances are established for residues of the insecticide
disulfoton, O,O-diethyl S-(2-(ethylthio)ethyl) phosphorodithioate,
including its metabolites and degradates, in or on the commodities
in the table in this paragraph. Compliance with the tolerance levels
specified in this paragraph is to be determined by measuring only
the sum of disulfoton, O,O-diethyl S-(2-(ethylthio)ethyl)
phosphorodithioate, and its metabolites demeton-S,O,O-diethyl S-(2-
(ethylthio)ethyl) phosphorothioate; disulfoton sulfoxide, O,O-
diethyl S-(2-(ethylsulfinyl)ethyl) phosphorodithioate; disulfoton
oxygen analog sulfoxide, O,O-diethyl S-(2-(ethylsulfinyl)ethyl)
phosphorothioate, disulfoton sulfone, O,O-diethyl S-(2-
(ethylsulfonyl)ethyl) phosphorodithioate; and disulfoton oxygen
analog sulfone, O,O-diethyl S-(2-(ethylsulfonyl)ethyl)
phosphorothioate; calculated as the stoichiometric equivalent of
disulfoton, in or on the commodity.
In order to describe more clearly the measurement and scope or
coverage of the tolerances, EPA is proposing to revise the introductory
text containing the regional tolerance expression in 40 CFR 180.183(c)
to read as follows:
A tolerance with regional registration is established for
residues of the insecticide disulfoton, O,O-diethyl S-(2-
(ethylthio)ethyl) phosphorodithioate, including its metabolites and
degradates, in or on the commodity in the table in this paragraph.
Compliance with the tolerance levels specified in this paragraph is
to be determined by measuring only the sum of disulfoton, O,O-
diethyl S-(2-(ethylthio)ethyl) phosphorodithioate, and its
metabolites demeton-S, O,O-diethyl S-(2-(ethylthio)ethyl)
phosphorothioate; disulfoton sulfoxide, O,O-diethyl S-(2-
(ethylsulfinyl)ethyl) phosphorodithioate; disulfoton oxygen analog
sulfoxide, O,O-diethyl S-(2-(ethylsulfinyl)ethyl) phosphorothioate,
disulfoton sulfone, O,O-diethyl S-(2-(ethylsulfonyl)ethyl)
phosphorodithioate; and disulfoton oxygen analog sulfone, O,O-
diethyl S-(2-(ethylsulfonyl)ethyl) phosphorothioate; calculated as
the stoichiometric equivalent of disulfoton, in or on the commodity.
There are Codex MRLs for disulfoton, including those on asparagus
at 0.02 mg/kg, coffee beans at 0.2 mg/kg, common bean (pods and/or
immature seeds) at 0.2 mg/kg, cotton, seed at 0.1 mg/kg, and other
commodities.
7. EPTC. Because cotton forage is no longer considered by the
Agency to be a significant livestock feed commodity as delineated in
``Table 1.--Raw Agricultural and Processed Commodities and Feedstuffs
Derived from Crops,'' which is found in Residue Chemistry Test
Guidelines OPPTS 860.1000, dated August 1996 (available at https://www.epa.gov/opptsfrs/publications/OPPTS_Harmonized/860_Residue_Chemistry_Test_Guidelines/Series/), EPA determined that the tolerance
is no longer needed, and therefore should be revoked. Consequently, the
Agency is proposing to revoke the tolerance in 40 CFR 180.117 for
residues of S-ethyl dipropylthiocarbamate (EPTC) in or on cotton,
forage.
Because there have been no active S-ethyl dipropylthiocarbamate
registrations in the United States for use on asparagus, small fruits
(including strawberries), flax seeds, and pineapples for more than 10
years, the tolerances are no longer needed and therefore should be
revoked. Consequently, EPA is proposing to revoke the tolerances in 40
CFR 180.117 on asparagus; fruit, small; strawberry; flax, seed; and
pineapple.
Because castor beans and oil products are not consumed by humans or
livestock, EPA determined that the tolerance is no longer needed and
therefore should be revoked. Consequently, EPA is proposing to revoke
the tolerance in 40 CFR 180.117 on castorbean, seed.
EPA is proposing, in 40 CFR 180.117, to remove the ``(N)''
designation from all entries to conform to current Agency
administrative practice (``N'' designation means negligible residues).
Also, tolerances are currently established in 40 CFR 180.117 for
negligible residues of the herbicide S-ethyl dipropylthiocarbamate,
also called EPTC. EPA determined that EPTC plant residues of
toxicological concern are EPTC, EPTC sulfoxide, EPTC sulfone, and the
EPTC conjugates (glutathione, cysteine, N-malonyl cysteine, S-lactic
acid, and O-malonyl S-lactic acid conjugates). However, the Agency
concurred with the registrant's position that development of a single
enforcement analytical method that can detect each of these residues
was not feasible. Because development of an enforcement analytical
method for the hydroxylated metabolites (S-ethyl (2-
hydroxypropyl)propylcarbamothioate, S-(2-
hydroxyethyl)dipropylcarbamothioate, and S-ethyl (3-
hydroxypropyl)propylcarbamothioate) was feasible, the Agency concurred
with the registrant's recommendation that EPTC and its hydroxylated
metabolites be used as marker residues of EPTC residues of
toxicological concern. Therefore, in order to describe more clearly the
measurement and scope or coverage of the tolerances, EPA is proposing
to redesignate the existing paragraph from 40 CFR 180.117 to 180.117(a)
and revise the introductory text containing the tolerance expression in
newly designated 40 CFR 180.117(a) to include its hydroxylated
metabolites as marker residues of S-ethyl dipropylthiocarbamate
residues of toxicological concern (i.e., markers of EPTC, EPTC
sulfoxide, EPTC sulfone, and the EPTC conjugates resulting from the
glutathione-S-transferase pathway), to read as follows:
Tolerances are established for residues of the herbicide S-ethyl
dipropylthiocarbamate, including its metabolites and degradates, in
or on the commodities in the table in this paragraph. Compliance
with the tolerance levels specified in this paragraph is to be
determined by measuring only the sum of S-ethyl
dipropylthiocarbamate, S-ethyl (2-
hydroxypropyl)propylcarbamothioate, S-(2-
hydroxyethyl)dipropylcarbamothioate, and S-ethyl (3-
hydroxypropyl)propylcarbamothioate, calculated as the stoichiometric
equivalent of S-ethyl dipropylthiocarbamate, in or on the commodity.
The majority of the current crop groupings for residues of EPTC are
based on obsolete crop groupings and, for many, the minimum data
requirements for the establishment of crop group tolerances were not
satisfied. Therefore, in the EPTC RED, the Agency recommended
revocation of crop group tolerances, concomitant with the establishment
of individual tolerances for the affected commodities.
Based on available field trial data that showed residues of S-ethyl
dipropylthiocarbamate and its hydroxylated metabolites were <0.09 ppm
in or on potatoes and <0.11 ppm in on sugar beet roots, the Agency
determined that the tolerance for the obsolete group, vegetable, root,
should be revoked and individual tolerances should be established for
beet, garden, roots; beet, sugar, roots; potato; and sweet potato
(based on translation of available data from potatoes). Therefore, EPA
is proposing in newly designated and revised 40 CFR 180.117(a) to
revoke the tolerance on vegetable, root at 0.1 ppm and establish
tolerances on beet, garden, roots at 0.1 ppm; beet, sugar, roots at 0.1
ppm; potato at 0.1 ppm; and sweet potato, roots at 0.1 ppm. Also, based
on processing data that showed combined residues of EPTC and its
hydroxylated metabolites were as high as <0.80 ppm in molasses that was
processed from the raw agricultural commodity (sugar beet roots) with
residues as high as <0.2 ppm (after application at 2X the maximum
exposure rate), the Agency determined that combined residues had
concentrated in molasses by a factor of 4X and that after a 1X
application on sugar beet roots, residues in molasses
[[Page 28162]]
would be expected at <0.1 ppm. Therefore, EPA is proposing to establish
a tolerance in newly designated and revised 40 CFR 180.117(a) on beet,
sugar, molasses at 0.4 ppm.
Based on available field trial data that showed residues of S-ethyl
dipropylthiocarbamate and its hydroxylated metabolites were non-
detectable (<0.05 ppm and <0.01 ppm for each of the three hydroxylated
metabolites; i.e., the Limit of Quantitation (LOQ) of the enforcement
method for EPTC and its hydroxylated metabolites, respectively) in or
on almond nutmeats and hulls, and walnut nutmeats, the Agency
determined that the tolerance for the obsolete group, nut, should be
revoked and individual tolerances should be established for almond,
nutmeat and walnut, nutmeat; each at 0.08 ppm (0.05 ppm for EPTC and
0.03 ppm for the combined hydroxylated metabolites), and decrease
almond, hulls from 0.1 ppm to 0.08 ppm. Therefore, EPA is proposing in
newly designated and revised 40 CFR 180.117(a) to revoke the tolerance
on nut at 0.1 ppm and establish tolerances on almond at 0.08 ppm and
walnut at 0.08 ppm, and decrease the tolerance on almond, hulls to 0.08
ppm.
Based on available field trial data that showed residues of S-ethyl
dipropylthiocarbamate and its hydroxylated metabolites were non-
detectable (<0.05 ppm and <0.01 ppm for each of the three hydroxylated
metabolites; i.e., the LOQ of the enforcement method for EPTC and its
hydroxylated metabolites, respectively) in or on tomatoes, the Agency
determined that the tolerance for the obsolete group, vegetable,
fruiting, should be revoked and an individual tolerance should be
established for tomato at 0.08 ppm (0.05 ppm for EPTC and 0.03 ppm for
the combined hydroxylated metabolites). Therefore, EPA is proposing in
newly designated and revised 40 CFR 180.117(a) to revoke the tolerance
on vegetable, fruiting at 0.1 ppm and establish a tolerance on tomato
at 0.08 ppm.
Based on available field trial data that showed residues of S-ethyl
dipropylthiocarbamate were non-detectable (<0.05 ppm) in or on alfalfa
forage and hay, and clover forage and hay, and maximum total residues
of EPTC hydroxylated metabolites were 0.18 ppm in or on alfalfa forage,
0.61 ppm in or on alfalfa hay, 0.01 ppm in or on clover forage, and
0.05 ppm in or on clover hay, the Agency determined that the tolerance
for the obsolete group, legume, forage, should be revoked and
individual tolerances should be established for alfalfa, forage at 0.2
ppm and alfalfa, hay at 0.6 ppm, clover, forage at 0.1 ppm, and clover,
hay at 0.1 ppm. Also, the Agency determined that the data for clover
forage and hay can be translated to the forage and hay of trefoil and
lespedeza, and therefore individual tolerances for each of them should
be established at 0.1 ppm. Consequently, EPA is proposing in newly
designated and revised 40 CFR 180.117(a) to revoke the tolerance on
legume, forage at 0.1 ppm and establish tolerances on alfalfa, forage
at 0.2 ppm, alfalfa, hay at 0.6 ppm, clover, forage at 0.1 ppm, clover,
hay at 0.1 ppm, lespedeza, forage at 0.1 ppm, lespedeza, hay at 0.1
ppm, trefoil, forage at 0.1 ppm, and trefoil, hay at 0.1 ppm.
Based on available field trial data that showed residues of S-ethyl
dipropylthiocarbamate were non-detectable (<0.05 ppm) in or on sugar
beet tops, and maximum total residues of EPTC and its hydroxylated
metabolites were <0.47 ppm in or on sugar beet tops, the Agency
determined that the tolerance for the obsolete group, vegetable, leafy,
should be revoked and individual tolerances should be established for
beet, garden, tops at 0.5 ppm and beet, sugar, tops at 0.5 ppm.
Therefore, EPA is proposing in newly designated and revised 40 CFR
180.117(a) to revoke the tolerance on vegetable, leafy at 0.1 ppm and
establish tolerances on beet, garden, tops at 0.5 ppm and beet, sugar,
tops at 0.5 ppm.
Based on available field trial data that showed residues of S-ethyl
dipropylthiocarbamate and its hydroxylated metabolites were non-
detectable (<0.05 ppm and <0.01 ppm for each of the three hydroxylated
metabolites; i.e., the LOQ of the enforcement method for EPTC and its
hydroxylated metabolites, respectively) in or on beans (succulent and
dry), the Agency determined that the tolerance for the obsolete group,
vegetable, seed and pod, should be revoked and individual tolerances
should be established for bean, dry, seed; bean, succulent; and pea,
succulent (based on translation of available data from succulent
beans); each at 0.08 ppm (0.05 ppm for EPTC and 0.03 ppm for the
combined hydroxylated metabolites). Therefore, EPA is proposing in
newly designated and revised 40 CFR 180.117(a) to revoke the tolerance
on vegetable, seed and pod at 0.1 ppm and establish tolerances on bean,
dry, seed at 0.08 ppm, bean, succulent at 0.08 ppm, and pea, succulent
at 0.08 ppm.
Based on available field trial data that showed residues of S-ethyl
dipropylthiocarbamate and its hydroxylated metabolites were non-
detectable (<0.05 ppm and <0.01 ppm for each of the three hydroxylated
metabolites; i.e., the LOQ of the enforcement method for EPTC and its
hydroxylated metabolites, respectively) in or on field corn grain or
sweet corn ear, the Agency determined that the tolerance for the
obsolete group, grain, crop, should be revoked, data could be
translated from field corn grain to popcorn grain, and individual
tolerances should be established for corn, field, grain; corn, pop,
grain; and corn, sweet, kernel plus cob with husks removed; each at
0.08 ppm (0.05 ppm for EPTC and 0.03 ppm for the combined hydroxylated
metabolites). Therefore, EPA is proposing in newly designated and
revised 40 CFR 180.117(a) to revoke the tolerance on grain, crop at 0.1
ppm and establish tolerances on corn, field, grain at 0.08 ppm, corn,
pop, grain at 0.08 ppm, and corn, sweet, kernel plus cob with husks
removed at 0.08 ppm.
Based on available field trial data that showed residues of S-ethyl
dipropylthiocarbamate and its hydroxylated metabolites were non-
detectable (<0.05 ppm and <0.01 ppm for each of the three hydroxylated
metabolites; i.e., the LOQ of the enforcement method for EPTC and its
hydroxylated metabolites, respectively) in or on field corn forage and
stover, and sweet corn forage and ears, the Agency determined that the
tolerance for the obsolete group, grass, forage, should be revoked,
data could be translated from field corn stover to popcorn stover, and
individual tolerances should be established for corn, field, forage;
corn, field, stover; corn, pop, stover; corn, sweet, forage; and corn,
sweet, stover; each at 0.08 ppm (0.05 ppm for EPTC and 0.03 ppm for the
combined hydroxylated metabolites). Therefore, EPA is proposing in
newly designated and revised 40 CFR 180.117(a) to revoke the tolerance
on grass, forage at 0.1 ppm and establish tolerances on corn, field,
forage at 0.08 ppm, corn, field, stover at 0.08 ppm, corn, pop, stover
at 0.08 ppm, corn, sweet, forage at 0.08 ppm, and corn, sweet, stover
at 0.08 ppm.
Based on available field trial data that showed residues of S-ethyl
dipropylthiocarbamate and its hydroxylated metabolites were non-
detectable (<0.05 ppm and <0.01 ppm for each of the three hydroxylated
metabolites; i.e., the LOQ of the enforcement method for EPTC and its
hydroxylated metabolites, respectively) in or on cottonseed, safflower
seeds, and sunflower seeds, the Agency determined that the tolerances
on cottonseed, safflower seed, and sunflower seed should be decreased
from 0.1 to 0.08
[[Page 28163]]
ppm (0.05 ppm for EPTC and 0.03 ppm for the combined hydroxylated
metabolites). Therefore, EPA is proposing in newly designated and
revised 40 CFR 180.117(a) to decrease the tolerances on cotton,
undelinted seed to 0.08 ppm; safflower, seed to 0.08 ppm; and
sunflower, seed to 0.08 ppm.
Based on available field trial data that showed residues of S-ethyl
dipropylthiocarbamate and its hydroxylated metabolites were <0.05 ppm
for EPTC and each of the three hydroxylated metabolites (total combined
residues were <0.20 ppm) in or on cotton gin byproducts, the Agency
determined that a tolerance should be established at 0.20 ppm.
Therefore, EPA is proposing in newly designated and revised 40 CFR
180.117(a) to establish a tolerance on cotton, gin byproducts at 0.20
ppm.
In accordance with current Agency practice, EPA is proposing to
revise 40 CFR 180.117 by adding separate paragraphs (b), (c), and (d),
and reserving those paragraphs with tolerance exemptions for section 18
emergency exemptions, tolerances with regional registrations, and
tolerances with indirect or inadvertent residues, respectively. Also
EPA is proposing to revise the nomenclature and tolerance in newly
designated and revised 40 CFR 180.117(a) from ``fruit, citrus'' to
``fruit, citrus, group 10.''
There are no Codex MRLs for EPTC.
8. Ethoprop. On May 27, 2009, EPA published a notice in the Federal
Register (74 FR 25237) (FRL-8418-2) that announced the Agency's receipt
of request from the registrant to voluntarily amend a registration and
therefore terminate the last ethoprop use in the United States on
pineapple. EPA approved amendment of the registration by issuing a
cancellation order on July 9, 2009 to the registrant, made it effective
on July 23, 2009, and permitted the registrant to sell and distribute
existing ethoprop stocks of the amended registration (concerning
pineapple use deletion) for 18 months after July 9, 2009; i.e., until
January 9, 2011. The Agency permitted persons other than the registrant
to sell and distribute existing stocks and use of the affected ethoprop
product until exhaustion. However, the Agency believes that end users
will have had sufficient time to exhaust those existing stocks and for
ethoprop treated pineapple commodities to have cleared the channels of
trade by January 9, 2012. Therefore, EPA is proposing to revoke the
tolerance in 40 CFR 180.262(a) for pineapple with an expiration/
revocation date of January 9, 2012.
Because there have been no active registrations in the United
States for ethoprop use on popcorn for more than 10 years, and
therefore, tolerances covering popcorn use are no longer needed, EPA is
proposing to revoke the tolerances in 40 CFR 180.262(a) on corn, pop,
grain and corn, pop, stover.
In order to describe more clearly the measurement and scope or
coverage of the tolerances, EPA is proposing to revise the introductory
text containing the tolerance expression in 40 CFR 180.262(a) to read
as follows:
Tolerances are established for residues of the nematocide and
insecticide ethoprop, O-ethyl S,S-dipropyl phosphorodithioate,
including its metabolites and degradates, in or on the commodities
in the table in this paragraph. Compliance with the tolerance levels
specified in this paragraph is to be determined by measuring only
ethoprop, O-ethyl S,S-dipropyl phosphorodithioate, in or on the
commodity.
There are no Codex MRLs for ethoprophos on pineapple or corn, but
there are MRLs for ethoprophos on other commodities.
9. Fenamiphos. There have been no active food use registrations for
fenamiphos in the United States since 2007. In a proposed rule that EPA
published in the Federal Register on February 6, 2008 (73 FR 6867)
(FRL-8345-2), the Agency proposed specific tolerances for multiple
pesticide active ingredients, including fenamiphos, and stated that
Bayer CropScience informed the Agency that it would support fenamiphos
tolerances on citrus and garlic, among others, for import purposes
since there were no active domestic registrations for those uses. In
January 2010, Bayer CropScience informed EPA that it no longer was
interested in supporting import tolerances for residues of fenamiphos
in or on citrus and garlic, but would continue to support import
tolerances for residues of fenamiphos in or on banana, grape, and
pineapple. Because no one other than Bayer CropScience expressed an
interest in retaining the fenamiphos tolerances on citrus and garlic,
there is no longer a need for them. Therefore, EPA is proposing to
revoke the tolerances in 40 CFR 180.349(a) on citrus, dried pulp;
citrus, oil; fruit, citrus, group 10; and garlic; add a missing
footnote to the tolerance for grape, raisin to reflect that it has no
U.S. registrations, and revise the footnoted information for all
remaining tolerances to reflect the effective cancellation date of the
last fenamiphos registrations in the United States to be as of May 31,
2007.
Because the tolerances expired on December 31, 2009, EPA is
proposing to remove the tolerances in 40 CFR 180.349(a) on apple;
Brussels sprouts; cabbage; cherry, sweet; cherry, tart; eggplant; okra;
peach; peanut; raspberry; and strawberry; in 180.349(c) on asparagus;
beet, garden, roots; beet, garden, tops; cabbage, Chinese, bok choy;
kiwifruit; and pepper, nonbell; and reserve paragraph (c).
Also, in order to describe more clearly the measurement and scope
or coverage of the tolerances, EPA is proposing to revise the
introductory text containing the tolerance expression in 40 CFR
180.349(a) to read as follows:
Tolerances are established for residues of the nematicide/
insecticide fenamiphos, ethyl 3-methyl-4-(methylthio)phenyl 1-
(methylethyl)phosphoramidate, including its metabolites and
degradates, in or on the commodities in the table in this paragraph.
Compliance with the tolerance levels specified in this paragraph is
to be determined by measuring only the sum of fenamiphos, ethyl 3-
methyl-4-(methylthio)phenyl 1-(methylethyl)phosphoramidate, and its
cholinesterase inhibiting metabolites ethyl 3-methyl-4-
(methylsulfinyl)phenyl 1-(methylethyl)phosphoramidate and ethyl 3-
methyl-4-(methylsulfonyl)phenyl 1-(methylethyl)phosphoramidate,
calculated as the stoichiometric equivalent of fenamiphos, in or on
the commodity.
There are Codex MRLs for fenamiphos, including those on apple;
banana; Brussels sprouts; cabbages, head; and peanut at 0.05 mg/kg, and
other commodities.
10. Hexazinone. Currently, tolerances are expressed for the
herbicide hexazinone in 40 CFR 180.396(a)(1) for the combined residues
of hexazinone (3-cyclohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine-
2,4-(1H, 3H)-dione) and its plant metabolites; A (3-(4-
hydroxycyclohexyl)-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4-(1H,
3H)-dione, B (3-cyclohexyl-6-(methylamino)-1-methyl-1,3,5-triazine-2,4-
(1H, 3H)-dione), C (3-(4-hydroxycyclohexyl)-6-(methylamino)-1-methyl-
1,3,5-triazine-2,4-(1H, 3H)-dione), D (3-cyclohexyl)-1-methyl-1,3,5-
triazine-2,4,6-(1H, 3H, 5H)-trione), and E (3-(4-hydroxycyclohexyl)-1-
methyl-1,3,5-triazine-2,4,6-(1H, 3H, 5H)-trione) (calculated as
hexazinone). In order to describe more clearly the measurement and
scope or coverage of the tolerances, EPA is proposing to revise the
introductory text containing the tolerance expression in 40 CFR
180.396(a)(1) to read as follows:
Tolerances are established for residues of the herbicide
hexazinone, 3-cyclohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine-
2,4-(1H, 3H)-dione, including its metabolites and degradates, in or
on the commodities in the
[[Page 28164]]
table in this paragraph. Compliance with the tolerance levels
specified in this paragraph is to be determined by measuring only
the sum of hexazinone, 3-cyclohexyl-6-(dimethylamino)-1-methyl-
1,3,5-triazine-2,4-(1H, 3H)-dione, and its plant metabolites:
metabolite A, 3-(4-hydroxycyclohexyl)-6-(dimethylamino)-1-methyl-
1,3,5-triazine-2,4-(1H, 3H)-dione, metabolite B, 3-cyclohexyl-6-
(methylamino)-1-methyl-1,3,5-triazine-2,4-(1H, 3H)-dione, metabolite
C, 3-(4-hydroxycyclohexyl)-6-(methylamino)-1-methyl-1,3,5-triazine-
2,4-(1H, 3H)-dione, metabolite D, 3-cyclohexyl-1-methyl-1,3,5-
triazine-2,4,6-(1H, 3H, 5H)-trione, and metabolite E, 3-(4-
hydroxycyclohexyl)-1-methyl-1,3,5-triazine-2,4,6-(1H, 3H, 5H)-
trione, calculated as the stoichiometric equivalent of hexazinone,
in or on the commodity.
Based on available field trial data that showed combined hexazinone
residues of concern as high as 183 ppm in or on grass forage at a 0-day
PHI and 133 ppm in or on grass, hay at a 14 to 38-day PHI, EPA
determined that the tolerance for grass forage should be increased from
10 to 250 ppm, and a tolerance for grass hay should be established at
230 ppm. Therefore, EPA is proposing to increase the tolerance in 40
CFR 180.396(a)(1) on grass, forage to 250 ppm and establish a tolerance
in 40 CFR 180.396(a)(1) on grass, hay at 230 ppm. The Agency determined
that the increased tolerance is safe; i.e., there is a reasonable
certainty that no harm will result from aggregate exposure to the
pesticide chemical residue.
Based on available field trial data that showed combined hexazinone
residues of concern as high as <3.33 ppm in or on alfalfa hay, EPA
determined that the tolerance on alfalfa hay should be decreased from
8.0 to 4.0 ppm. Therefore, the Agency is proposing in 40 CFR
180.396(a)(1) to decrease the tolerance on alfalfa, hay to 4.0 ppm.
In order to describe more clearly the measurement and scope or
coverage of the tolerances, EPA is proposing to revise the introductory
text containing the tolerance expression in 40 CFR 180.396(a)(2) to
read as follows:
Tolerances are established for residues of the herbicide
hexazinone, 3-cyclohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine-
2,4-(1H, 3H)-dione, including its metabolites and degradates, in or
on the commodities in the table in this paragraph. Compliance with
the tolerance levels specified in this paragraph is to be determined
by measuring only the sum of hexazinone, 3-cyclohexyl-6-
(dimethylamino)-1-methyl-1,3,5-triazine-2,4-(1H, 3H)-dione, and its
animal tissue metabolites: metabolite B, 3-cyclohexyl-6-
(methylamino)-1-methyl-1,3,5-triazine-2,4-(1H, 3H)-dione, and
metabolite F, 3-cyclohexyl-6-amino-1-methyl-1,3,5-triazine-2,4-(1H,
3H)-dione, calculated as the stoichiometric equivalent of
hexazinone, in or on the