Protection of Stratospheric Ozone: Listing of Substitutes for Ozone-Depleting Substances-Hydrocarbon Refrigerants, 25799-25815 [2010-10959]
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Federal Register / Vol. 75, No. 89 / Monday, May 10, 2010 / Proposed Rules
Submit comments,
identified by docket number [EPA–R09–
OAR–2010–0286], by one of the
following methods:
1. Federal eRulemaking Portal:
www.regulations.gov. Follow the on-line
instructions.
2. E-mail: steckel.andrew@epa.gov.
3. Mail or deliver: Andrew Steckel
(Air-4), U.S. Environmental Protection
Agency Region IX, 75 Hawthorne Street,
San Francisco, CA 94105–3901.
Instructions: All comments will be
included in the public docket without
change and may be made available
online at www.regulations.gov,
including any personal information
provided, unless the comment includes
Confidential Business Information (CBI)
or other information whose disclosure is
restricted by statute. Information that
you consider CBI or otherwise protected
should be clearly identified as such and
should not be submitted through
www.regulations.gov or e-mail.
www.regulations.gov is an ‘‘anonymous
access’’ system, and EPA will not know
your identity or contact information
unless you provide it in the body of
your comment. If you send e-mail
directly to EPA, your e-mail address
will be automatically captured and
included as part of the public comment.
If EPA cannot read your comment due
to technical difficulties and cannot
contact you for clarification, EPA may
not be able to consider your comment.
Electronic files should avoid the use of
special characters, any form of
encryption, and be free of any defects or
viruses.
Docket: The index to the docket for
this action is available electronically at
www.regulations.gov and in hard copy
at EPA Region IX, 75 Hawthorne Street,
San Francisco, California. While all
documents in the docket are listed in
the index, some information may be
publicly available only at the hard copy
location (e.g., copyrighted material), and
some may not be publicly available in
either location (e.g., CBI). To inspect the
hard copy materials, please schedule an
appointment during normal business
hours with the contact listed in the FOR
FURTHER INFORMATION CONTACT section.
FOR FURTHER INFORMATION CONTACT:
Idalia Perez, EPA Region IX, (415) 972–
3248, perez.idalia@epa.gov.
SUPPLEMENTARY INFORMATION: This
proposal addresses the following local
rules:
1. Rule 2.37, Natural Gas-Fired Water
Heaters and Small Boilers
2. Rule 2.42, Nitric Acid Production.
In the Rules and Regulations section
of this Federal Register, we are
approving these local rules in a direct
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ADDRESSES:
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final action without prior proposal
because we believe these SIP revisions
are not controversial. If we receive
adverse comments, however, we will
publish a timely withdrawal of the
direct final rule and address the
comments in subsequent action based
on this proposed rule. Please note that
if we receive adverse comment on an
amendment, paragraph, or section of
these rules and if that provision may be
severed from the remainder of these
rules, we may adopt as final those
provisions of the rules that are not the
subject of an adverse comment.
We do not plan to open a second
comment period, so anyone interested
in commenting should do so at this
time. If we do not receive adverse
comments, no further activity is
planned. For further information, please
see the direct final action.
Dated: April 1, 2010.
Jared Blumenfeld,
Regional Administrator, Region IX.
[FR Doc. 2010–10944 Filed 5–7–10; 8:45 am]
BILLING CODE 6560–50–P
ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Part 82
[EPA–HQ–OAR–2009–0286; FRL–9147–9]
RIN 2060–AP54
Protection of Stratospheric Ozone:
Listing of Substitutes for OzoneDepleting Substances—Hydrocarbon
Refrigerants
AGENCY: Environmental Protection
Agency, (EPA).
ACTION: Proposed rulemaking.
SUMMARY: Pursuant to the U.S.
Environmental Protection Agency’s
Significant New Alternatives Policy
program, this action proposes to list
isobutane, propane, HCR–188C, and
HCR–188C1 as ‘‘acceptable, subject to
use conditions,’’ as substitutes for
chlorofluorocarbon (CFC)–12, also
referred to as R–12, CCl2F2 and
dichlorodifluoromethane and
hydrochlorofluorocarbon (HCFC)–22,
also referred to as R–22, CHClF2,
chlorodifluoromethane and
difluorochloromethane, in household
refrigerators, freezers, and combination
refrigerator and freezers and commercial
refrigeration (retail food refrigerators
and freezers—stand-alone units only).
DATES: Comments must be received on
or before July 9, 2010, unless a public
hearing is requested. Comments must
then be received on or before July 26,
2010. Any party requesting a public
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25799
hearing must notify the contact listed
below under FOR FURTHER INFORMATION
CONTACT by 5 p.m. Eastern Daylight
Time on May 20, 2010. If a hearing is
held, it will take place on May 25, 2010
in Washington, DC and further
information will be provided on EPA’s
Stratospheric Ozone World Wide Web
site at https://www.epa.gov/ozone/snap.
ADDRESSES: Submit your comments,
identified by Docket ID No. EPA–HQ–
OAR–2009–0286, by one of the
following methods:
• https://www.regulations.gov. Follow
the on-line instructions for submitting
comments.
• E-mail: A-And-R-Docket@epa.gov.
• Mail: Air and Radiation Docket,
Environmental Protection Agency,
Mailcode 6102T, 1200 Pennsylvania
Ave., NW., Washington, DC 20460,
Attention Docket ID No. EPA–HQ–
OAR–2009–0286.
• Hand Delivery: EPA Docket Center,
(EPA/DC) EPA West, Room 3334, 1301
Constitution Ave., NW., Washington,
DC, Attention Docket ID No. EPA–HQ–
OAR–2009–0286. Such deliveries are
only accepted during the Docket’s
normal hours of operation, and special
arrangements should be made for
deliveries of boxed information.
Instructions: Direct your comments to
Docket ID No. EPA–HQ–OAR–2009–
0286. EPA’s policy is that all comments
received will be included in the public
docket without change and may be
made available online at https://
www.regulations.gov, including any
personal information provided, unless
the comment includes information
claimed to be Confidential Business
Information (CBI) or other information
whose disclosure is restricted by statute.
Do not submit information that you
consider to be CBI or otherwise
protected through https://
www.regulations.gov or e-mail. The
www.regulations.gov Web sites is an
‘‘anonymous access’’ system, which
means EPA will not know your identity
or contact information unless you
provide it in the body of your comment.
If you send an e-mail comment directly
to EPA without going through
www.regulations.gov, your e-mail
address will be automatically captured
and included as part of the comment
that is placed in the public docket and
made available on the Internet. If you
submit an electronic comment, EPA
recommends that you include your
name and other contact information in
the body of your comment and with any
disk or CD–ROM you submit. If EPA
cannot read your comment due to
technical difficulties and cannot contact
you for clarification, EPA may not be
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able to consider your comment.
Electronic files should avoid the use of
special characters, any form of
encryption, and be free of any defects or
viruses. For additional instructions on
submitting comments, go to Section I.B.
of the SUPPLEMENTARY INFORMATION
section of this document.
Docket: All documents in the docket
are listed in the https://
www.regulations.gov index. Although
listed in the index, some information is
not publicly available, i.e., CBI or other
information whose disclosure is
restricted by statute. Certain other
material, such as copyrighted material,
is not placed on the Internet and will be
publicly available only in hard copy
form. Publicly available docket
materials are available either
electronically in https://
www.regulations.gov or in hard copy at
the Air and Radiation Docket, EPA/DC,
EPA West, Room 3334, 1301
Constitution Ave., NW., Washington,
DC. The Public Reading Room is open
from 8:30 a.m. to 4:30 p.m., Monday
through Friday, excluding legal
holidays. The telephone number for the
Public Reading Room is (202) 566–1744,
and the telephone number for the Air
and Radiation Docket is (202) 566–1742.
FOR FURTHER INFORMATION CONTACT:
Monica Shimamura, Stratospheric
Protection Division, Office of
Atmospheric Programs, Mail Code
6205J, Environmental Protection
Agency, 1200 Pennsylvania Ave., NW.,
Washington, DC 20460; telephone
number (202) 343–9337; fax number
(202) 343–2362, e-mail address:
shimamura.monica@epa.gov. Notices
and rulemakings under EPA’s
Significant New Alternatives Policy
(SNAP) program are available on EPA’s
Stratospheric Ozone World Wide Web
site at www.epa.gov/ozone/snap/regs.
SUPPLEMENTARY INFORMATION:
Table of Contents
I. General Information
A. Background
B. Does this action apply to me?
C. What should I consider as I prepare my
comments for EPA?
D. What acronyms and abbreviations are
used in the preamble?
II. How does the Significant New
Alternatives Policy (SNAP) program
work?
A. What are the statutory requirements and
authority for the SNAP program?
B. What are EPA’s regulation implementing
section 612?
C. How do the regulations for the SNAP
program work?
D. Where can I get additional information
about the SNAP program?
III. What substitutes for ozone-depleting
substances in what end-uses are
considered in this rule?
A. What is EPA proposing in this action?
B. What are isobutane, propane, HCR–188C
and HCR–188C1?
C. What end-uses are included in our
proposed decision?
D. Where can I find the regulatory text for
these proposed listing decisions?
E. What does an acceptability
determination with use conditions for
isobutane, propane, HCR–188C, and
HCR–188C1 mean?
IV. What criteria did EPA consider in
preparing this proposal?
A. Impacts on the Environment
B. Flammability and Fire Safety
C. Toxicity
V. Why is EPA proposing these specifics use
conditions?
A. New Equipment Only; Not Intended for
Use as a Retrofit Alternative
B. Standards
C. Charge Size
D. Color-Coded Hoses and Piping
E. Labeling
F. Unique Fittings
G. Small Containers
VI. What recommendations does EPA have
for safe use of hydrocarbon refrigerants?
VII. What other options did EPA consider?
VIII. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory
Planning and Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act (RFA)
D. Unfunded Mandates Reform Act
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation
and Coordination With Indian Tribal
Governments
G. Executive Order 13045: Protection of
Children From Environmental Health
and Safety Risks
H. Executive Order 13211: Actions That
Significantly Affect Energy Supply,
Distribution, or Use
I. National Technology Transfer and
Advancement Act
J. Executive Order 12898: Federal Actions
to Address Environmental Justice in
Minority Populations and Low-Income
Populations
IX. References
I. General Information
A. Background
This rule pertains to four hydrocarbon
refrigerants: isobutane, propane and
HCR–188C and HCR–188C1. Globally,
hydrocarbon refrigerants have been in
use for over 10 years including in
countries such as Germany, the United
Kingdom, Australia, and Japan. In
Europe and Asia, equipment
manufactures have designed and tested
household and commercial refrigerators
and freezers to account flammability
and safety concerns associated with
using hydrocarbon refrigerants. Due to
the fact that hydrocarbon refrigerants
have zero ozone depletion potential
(ODP) and very low global warming
potential (GWP), many companies are
interested in using hydrocarbon
refrigerants in the United States (U.S.)
as well. In this action EPA has received
four SNAP submissions for use of
hydrocarbon refrigerants in household
refrigerators, freezers, combination
refrigerator and freezers and retail food
refrigerators and freezers (stand-alone
only).
B. Does this action apply to me?
This notice of proposed rulemaking
(NPRM) would regulate the use of four
alternative refrigerants used in:
Household refrigerators and freezers and
commercial refrigeration (retail food
refrigeration—stand-alone units only).1
Potentially entities that may wish to use
isobutane (R–600a), propane (R–290),
HCR–188C, or HCR–188C1 in these enduses, include:
TABLE 1—POTENTIALLY REGULATED ENTITIES BY NORTH AMERICAN INDUSTRIAL CLASSIFICATION SYSTEM (NAICS) CODE
OR SUBSECTOR
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Category
NAICS code
or subsector
Industry ................................
333415
Industry
Industry
Industry
Industry
Industry
443111
445120
445110
722211
238220
................................
................................
................................
................................
................................
1 HCR–188C and HCR–188C1 submissions
included window air conditioners as an end use.
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Description of regulated entities
Manufactures of refrigerators, freezers, and other refrigerating or freezing equipment, electric or
other; heat pumps not elsewhere specified or included (NESOI); and parts thereof.
Appliance Stores: Household-type.
Convenience Stores.
Supermarkets and Other Grocery (except Convenience) Stores.
Limited-Service Restaurants.
Plumbing, Heating, and Air Conditioning Contractors.
EPA is acting on this end use in a separate rule
making.
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25801
TABLE 1—POTENTIALLY REGULATED ENTITIES BY NORTH AMERICAN INDUSTRIAL CLASSIFICATION SYSTEM (NAICS) CODE
OR SUBSECTOR—Continued
Category
Industry
Industry
Industry
Industry
................................
................................
................................
................................
NAICS code
or subsector
811412
541380
423620
423740
Description of regulated entities
Appliance Repair and Maintenance.
Environmental Testing Laboratories.
Electrical and Electronic Appliance, Television, and Radio Set Merchant Wholesalers.
Refrigeration Equipment and Supplies Merchant Wholesalers.
• Provide specific examples to
illustrate your concerns, and suggest
alternatives.
• Explain your views as clearly as
possible, avoiding the use of profanity
or personal threats.
• Make sure to submit your
comments by the comment period
deadline identified.
C. What should I consider as I prepare
my comments for EPA?
D. What acronyms and abbreviations
are used in the preamble?
1. Submitting Confidential Business
Information (CBI).
Do not submit confidential
information to EPA through
www.regulations.gov or e-mail. Clearly
mark the part or all of the information
that you claim to be CBI. For CBI
information in a disk or CD–ROM that
you mail to EPA, mark the outside of the
disk or CD–ROM as CBI and then
identify electronically within the disk or
CD–ROM the specific information that
is claimed as CBI. In addition to one
complete version of the comment that
includes information claimed as CBI, a
copy of the comment that does not
contain the information claimed as CBI
must be submitted for inclusion in the
public docket. Information marked as
CBI will not be disclosed except in
accordance with procedures set forth in
40 Code of Federal Regulations (CFR)
Part 2.
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This table is not intended to be
exhaustive, but rather a guide regarding
entities likely to use the substitute
whose use is regulated by this action. If
you have any questions about whether
this action applies to a particular entity,
consult the person listed in the
preceding section, FOR FURTHER
INFORMATION CONTACT.
Below is a list of acronyms and
abbreviations used in the preamble of
this NPRM.
2. Tips for Preparing Your Comments.
When submitting comments,
remember to:
• Identify the rulemaking by docket
number and other identifying
information (subject heading, Federal
Register date, and page number).
• Follow directions—The agency may
ask you to respond to specific questions
or organize comments by referencing a
CFR part or section number.
• Explain why you agree or disagree;
suggest alternatives and substitute
language for your requested changes.
• Describe any assumptions and
provide any technical information and/
or data that you used.
• If you estimate potential costs or
burdens, explain how you arrived at
your estimate in sufficient detail to
allow for it to be reproduced.
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ACH—air changes per hour
AEGL—Acute Exposure Guideline Level
ASHRAE—American Society of Heating,
Refrigerating and Air-Conditioning
Engineers, Inc.
ANSI—American National Standards
Institute
CAA—Clean Air Act
CAS Reg. No—Chemical Abstracts Service
Registry Identification Number
CBI—Confidential Business Information
CFC—chlorofluorocarbon
cfm—cubic feet per minute
CFR—Code of Federal Regulations
EPA—the United States Environmental
Protection Agency
FR—Federal Register
GWP—global warming potential
HC—hydrocarbon
HCFC—hydrochlorofluorocarbon
HFC—hydroflurocarbon
ICF—ICF International, Inc.
IDLH—Immediately dangerous to life or
health
ICR—Information Collection Request
LFL—lower flammability limit
mg/l—milligrams per liter
MSDS—Material Safety Data Sheet
NAICS—North American Industrial
Classification System
NIOSH—the U.S. National Institute for
Occupational Safety and Health
NPRM—Notice of Proposed Rulemaking
OEM—original equipment manufacturer
ODP—ozone depletion potential
ODS—ozone-depleting substance
OMB—the United States Office of
Management and Budget
OSHA—the United States Occupational
Safety and Health Administration
PELs —permissible exposure limits
ppm—parts per million
REL—Recommended exposure limit
RFA—Regulatory Flexibility Act
RfC—reference concentration
SNAP—Significant New Alternatives Policy
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TSCA—Toxic Substances Control Act
TWA —time weighted average
UL—Underwriters Laboratories Inc.
VOC—volatile organic compound
II. How does the Significant New
Alternatives Policy (SNAP) program
work?
A. What are the statutory requirements
and authority for the SNAP program?
Section 612 of the Clean Air Act
(CAA) requires EPA to develop a
program for evaluating alternatives to
ozone-depleting substances (ODS). EPA
refers to this program as the Significant
New Alternatives Policy (SNAP)
program. The major provisions of
section 612 are:
1. Rulemaking
Section 612(c) requires EPA to
promulgate rules making it unlawful to
replace any class I (i.e.,
chlorofluorocarbon, halon, carbon
tetrachloride, methyl chloroform,
methyl bromide, and
hydrobromofluorocarbon) or class II
(i.e., hydrochlorofluorocarbon)
substance with any substitute that the
Administrator determines may present
adverse effects to human health or the
environment where the Administrator
has identified an alternative that (1)
reduces the overall risk to human health
and the environment, and (2) is
currently or potentially available.
2. Listing of Unacceptable/Acceptable
Substitutes
Section 612(c) requires EPA to
publish a list of the substitutes
unacceptable for specific uses and to
publish a corresponding list of
acceptable alternatives for specific uses.
The list of acceptable substitutes is
found at https://www.epa.gov/Ozone/
snap/lists/ and the lists of
‘‘unacceptable’’, ‘‘acceptable subject to
use conditions’’, and ‘‘acceptable subject
to narrowed use limits’’ is found at 40
CFR part 82 subpart G.
3. Petition Process
Section 612(d) grants the right to any
person to petition EPA to add a
substance to, or delete a substance from,
the lists published in accordance with
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section 612(c). The Agency has 90 days
to grant or deny a petition. Where the
Agency grants the petition, EPA must
publish the revised lists within an
additional six months.
4. 90-Day Notification
Section 612(e) directs EPA to require
any person who produces a chemical
substitute for a class I substance to
notify the Agency not less than 90 days
before new or existing chemicals are
introduced into interstate commerce for
significant new uses as substitutes for a
class I substance. The producer must
also provide the Agency with the
producer’s unpublished health and
safety studies on such substitutes.
5. Outreach
Section 612(b)(1) states that the
Administrator shall seek to maximize
the use of Federal research facilities and
resources to assist users of class I and
II substances in identifying and
developing alternatives to the use of
such substances in key commercial
applications.
6. Clearinghouse
Section 612(b)(4) requires the Agency
to set up a public clearinghouse of
alternative chemicals, product
substitutes, and alternative
manufacturing processes that are
available for products and
manufacturing processes which use
class I and II substances.
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B. What are EPA’s regulations
implementing section 612?
On March 18, 1994, EPA published
the original rulemaking (59 FR 13044)
which established the process for
administering the SNAP program and
issued EPA’s first lists identifying
acceptable and unacceptable substitutes
in the major industrial use sectors (40
CFR part 82, subpart G). These sectors
include: Refrigeration and air
conditioning; foam blowing; cleaning
solvents; fire suppression and explosion
protection; sterilants; aerosols;
adhesives, coatings and inks; and
tobacco expansion. These sectors
compose the principal industrial sectors
that historically consumed the largest
volumes of ODS.
Section 612 of the CAA requires EPA
to ensure that substitutes found
acceptable do not prevent a significantly
greater risk to human health and the
environment as compared with other
substitutes that are currently or
potentially available.
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C. How do the regulations for the SNAP
program work?
Under the SNAP regulations, anyone
who plans to market or produce a
substitute for class I or II ODS in one of
the eight major industrial use sectors
must provide the Agency with health
and safety studies on the substitute at
least 90 days before introducing it into
interstate commerce for significant new
use as an alternative. This requirement
applies to the person planning to
introduce the substitute into interstate
commerce,2 typically chemical
manufacturers, but may also include
importers, formulators, equipment
manufacturers, or end-users 3 when they
are responsible for introducing a
substitute into commerce. In this
proposed rule we are addressing SNAP
submissions from three companies
interested in introducing into interstate
commerce products that contain
hydrocarbon refrigerants.
The Agency has identified four
possible decision categories for
substitutes: Acceptable; acceptable
subject to use conditions; acceptable
subject to narrowed use limits; and
unacceptable. Use conditions and
narrowed use limits are both considered
‘‘use restrictions’’ and are explained
below. Substitutes that are deemed
acceptable with no use restrictions (no
use conditions or narrowed use limits)
can be used for all applications within
the relevant end-uses within the sector.
Substitutes that are acceptable subject to
use restrictions may be used only in
accordance with those restrictions. It is
illegal to replace an ODS with a
substitute listed as unacceptable, unless
certain exceptions (e.g. test marketing,
research and development) provided by
the regulation are met.
After reviewing a substitute, the
Agency may make a determination that
a substitute is acceptable only if certain
conditions in the way that the substitute
is used are met to minimize risks to
human health and the environment.
EPA describes such substitutes as
‘‘acceptable subject to use conditions.’’
2 As defined at 40 CFR 82.104 ‘‘interstate
commerce’’ means the distribution or transportation
of any product between one state, territory,
possession or the District of Columbia, and another
state, territory, possession or the District of
Columbia, or the sale, use or manufacture of any
product in more than one state, territory, possession
or District of Columbia. The entry points for which
a product is introduced into interstate commerce
are the release of a product from the facility in
which the product was manufactured, the entry into
a warehouse from which the domestic manufacturer
releases the product for sale or distribution, and at
the site of United States Customs clearance.
3 As defined at 40 CFR 82.17 ‘‘end-use’’ means
processes or classes of specific applications within
major industrial sectors where a substitute is used
to replace an ozone-depleting substance.
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Entities that use these substitutes
without meeting the associated use
conditions are in violation of section
612 of the Clean Air Act.
For some substitutes, the Agency may
permit a narrowed range of use within
an end-use or sector. For example, the
Agency may limit the use of a substitute
to certain end-uses or specific
applications within an industry sector.
The Agency requires a user of a
narrowed use substitute to demonstrate
that no other acceptable substitutes are
available for their specific application
by conducting comprehensive studies.
EPA describes these substitutes as
‘‘acceptable subject to narrowed use
limits.’’ A person using a substitute that
is acceptable subject to narrowed use
limits in applications and end-uses that
are not consistent with the narrowed
use limit, are using these substitutes in
an unacceptable manner and are in
violation of section 612 of the Clean Air
Act.
The Agency publishes its SNAP
program decisions in the Federal
Register (FR). EPA publishes decisions
concerning substitutes that are deemed
acceptable subject to use restrictions
(use conditions and/or narrowed use
limits), or for substitutes deemed
unacceptable, as proposed rulemakings
to allow the public opportunity to
comment, before publishing final
decisions.
In contrast, EPA publishes substitutes
that are deemed acceptable with no
restrictions in ‘‘notices of acceptability,’’
rather than as proposed and final rules.
As described in the rule initially
implementing the SNAP program (59 FR
13044), EPA does not believe that
rulemaking procedures are necessary to
list alternatives that are acceptable
without restrictions because such
listings neither impose any sanction nor
prevent anyone from using a substitute.
Many SNAP listings include
‘‘comments’’ or ‘‘further information’’ to
provide additional information on
substitutes. Since this additional
information is not part of the regulatory
decision, these statements are not
binding for use of the substitute under
the SNAP program. However, regulatory
requirements so listed are binding under
other regulatory programs. The ‘‘further
information’’ classification does not
necessarily include all other legal
obligations pertaining to the use of the
substitute. While the items listed are not
legally binding under the SNAP
program, EPA encourages users of
substitutes to apply all statements in the
‘‘further information’’ column in their
use of these substitutes. In many
instances, the information simply refers
to sound operating practices that have
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in place of the requirements in the UL
Standard;
4. The refrigerator, freezer, or
combination refrigerator and freezer
must have red, Pantone Matching
System (PMS) #185 marked pipes,
hoses, or other devices through which
D. Where can I get additional
the refrigerant passes to indicate the use
information about the SNAP program?
of a flammable refrigerant. This color
must be applied at all service ports and
For copies of the comprehensive
where service puncturing or otherwise
SNAP lists of substitutes or additional
creating an opening from the refrigerant
information on SNAP, refer to EPA’s
circuit to the atmosphere might be
Ozone Depletion Web site at https://
expected and must extend a minimum
www.epa.gov/ozone/snap/.
of one (1) inch in both directions from
For more information on the Agency’s
such locations;
process for administering the SNAP
5. Similar to clauses SA6.1.1 to
program or criteria for evaluation of
SA6.1.2 of UL standard 250, the
substitutes, refer to the SNAP final
following markings, or the equivalent,
rulemaking published March 18, 1994
shall be provided and shall be
(59 FR 13044), codified at 40 CFR part
82, subpart G. A complete chronology of permanent:
(a) ‘‘DANGER—Risk of Fire or
SNAP decisions and the appropriate
Explosion. Flammable Refrigerant Used.
citations are found at https://
Do Not Use Mechanical Devices To
www.epa.gov/ozone/snap/chron.html.
Defrost Refrigerator. Do Not Puncture
III. What substitutes for ozoneRefrigerant Tubing.’’
depleting substances in what end-uses
(b) ‘‘DANGER—Risk of Fire or
are considered in this rule?
Explosion. Flammable Refrigerant Used.
A. What is EPA proposing in this action? Do Not Use Mechanical Devices. To Be
Repaired Only By Trained Service
In this action, EPA proposes to list the Personnel. Do Not Puncture Refrigerant
following:
Tubing.’’
(1) Isobutane, also referred to by the
(c) ‘‘CAUTION—Risk of Fire or
American Society of Heating,
Explosion. Flammable Refrigerant Used.
Refrigerating and Air Conditioning
Consult Repair Manual/Owner’s Guide
Engineers (ASHRAE) refrigerant
Before Attempting To Service This
designation R–600a, and the proprietary Product. All Safety Precautions Must be
hydrocarbon blends HCR–188C and
Followed.’’
HCR–188C1, as acceptable subject to use
(d) ‘‘CAUTION—Risk of Fire or
conditions as a substitute for CFC–12 4
Explosion. Dispose of Properly In
in household refrigerators, freezers, and Accordance With Federal Or Local
combination refrigerator and freezers.
Regulations. Flammable Refrigerant
EPA proposes the following use
Used.’’
(e) ‘‘CAUTION—Risk of Fire or
conditions:
Explosion Due To Puncture Of
1. The quantity of the substitute
Refrigerant Tubing; Follow Handling
refrigerant (i.e., ‘‘charge size’’) shall not
Instructions Carefully. Flammable
exceed 57 grams (2.0 ounces) in any
Refrigerant Used.’’
refrigerator, freezer, or combination
The marking described in clause (a)
refrigerator and freezers;
2. These refrigerants may be used only above shall be permanently attached on
in new equipment designed specifically or near any evaporators that can be
and clearly identified for the refrigerant contacted by the consumer. The
markings described in clauses (b) and
(i.e., none of these substitutes may be
(c) above shall be permanently attached
used as a conversion or ‘‘retrofit’’
near the machine compartment. The
refrigerant for existing equipment);
3. These refrigerants may be used only markings described in clause (d) above
shall be permanently attached on the
in refrigerators or freezers or
exterior of the refrigerator. The marking
combination refrigerator and freezers
described in clause (e) above shall be
that meet all requirements listed in the
10th edition of Underwriters Laboratory permanently attached near any and all
exposed refrigerant tubing. All of these
(UL) Standard 250. In cases where the
markings shall be in letters no less than
final rule includes requirements more
6.4 mm (1⁄4 inch) high.
stringent than those of the 10th edition
6. Household refrigerators, freezers,
of UL Standard 250, the appliance must
and combination refrigerator and
meet the requirements of the final rule
freezers using these refrigerants must
have service aperture fittings that are
4 CFC–12 is also referred to as R–12, CCl F and
2 2
colored red as described above in use
dichlorodifluoromethane. Its CAS Reg. No. is 75–
71–8.
condition number four and which differ
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already been identified in existing
industry and/or building-codes or
standards. Thus, many of the comments,
if adopted, would not require the
affected user to make significant
changes in existing operating practices.
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from fittings used in equipment or
containers using non-flammable
refrigerant. ‘‘Differ’’ means that either
that the diameter must differ by at least
1⁄16 inch or the thread direction must be
reversed (i.e., right handed vs. left
handed). These different fittings must be
permanently affixed to the unit and may
not be accessed with an adaptor until
the end-of-life of the unit;
7. These refrigerants may not be sold
for use as a refrigerant in containers
designed to contain less than five
pounds (2.8 kg) of refrigerant.
(2) Propane, R–290,5 as acceptable
subject to use conditions as a substitute
for CFC–12, R–502, or HCFC–22, in
retail food refrigerators and freezers:
1. The charge size for the retail food
refrigerator or freezer using R–290 shall
not exceed 150 grams (5.3 ounces);
2. This refrigerant may be used only
in new equipment specifically designed
and clearly identified for the refrigerant;
3. This substitute may only be used in
equipment that meets all requirements
in the 9th edition of UL Standard 471.
In cases where the final rule includes
requirements more stringent than those
of the 9th edition of UL Standard 471,
the appliance must meet the
requirements of the final rule in place
of the requirements in the UL Standard;
4. The refrigerator or freezer must
have red, Pantone Matching System
(PMS) #185 marked pipes, hoses, and
other devices through which the
refrigerant passes to indicate the use of
a flammable refrigerant. This color must
be applied at all service ports and where
service puncturing or otherwise creating
an opening from the refrigerant circuit
to the atmosphere might be expected,
and must extend a minimum of one (1)
inch in both directions from such
locations;
5. Similar to clauses SB6.1.2 to
SB6.1.5 of UL Standard 471, the
following markings, or the equivalent,
shall be provided and shall be
permanent:
(a) ‘‘DANGER—Risk of Fire or
Explosion. Flammable Refrigerant Used.
Do Not Use Mechanical Devices To
Defrost Refrigerator. Do Not Puncture
Refrigerant Tubing.’’
(b) ‘‘DANGER—Risk of Fire or
Explosion. Flammable Refrigerant Used.
To Be Repaired Only By Trained Service
Personnel. Do Not Puncture Refrigerant
Tubing.’’
(c) ‘‘CAUTION—Risk of Fire or
Explosion. Flammable Refrigerant Used.
Consult Repair Manual/Owner’s Guide
Before Attempting To Service This
5 Propane is also known as R–290, HC–290,
CH3CH2CH3 and C3H8. Its CAS Reg. No. is 74–98–
6.
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Product. All Safety Precautions Must be
Followed.’’
(d) ‘‘CAUTION—Risk of Fire or
Explosion. Dispose of Property In
Accordance With Federal Or Local
Regulations. Flammable Refrigerant
Used.’’
(e) ‘‘CAUTION—Risk of Fire or
Explosion Due To Puncture Of
Refrigerant Tubing; Follow Handling
Instructions Carefully. Flammable
Refrigerant Used.’’ This marking shall be
provided near all exposed refrigerant
tubing.
The marking described in clause (a)
above shall be permanently attached or
near any evaporators that can be
contacted by the consumer. The
markings described in clauses (b) and
(c) above shall be located near the
machine compartment. The marking
described in clause (d) above shall be
permanently attached on the exterior of
the refrigerator. The marking described
in clause (e) above shall be permanently
attached near any and all exposed
refrigerant tubing. All of these markings
shall be in letters no less than 6.4 mm
(1⁄4 inch) high.
6. Retail food refrigeration using R–
290 must have fittings that are colored
red as described above in use condition
number four and which differ from
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1. Household Refrigerators, Freezers,
and Combination Refrigerator and
Freezers
Household refrigerators, freezers, and
combination refrigerator and freezers are
intended primarily for residential use,
although they may be used outside the
home. Household freezers only offer
storage space at freezing temperatures,
unlike household refrigerators. Products
with both a refrigerator and freezer in a
single unit are most common. In this
16:19 May 07, 2010
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B. What are isobutane, propane, HCR–
188C, and HCR–188C1?
Hydrocarbons are flammable organic
compounds made up of hydrogen and
carbon. Isobutane has four carbons
while propane has three carbons. HCR–
188C and HCR–188C1 are proprietary
blends consisting of primarily or
exclusively of hydrocarbons. The
chemical formula for isobutane, also
called 2-methylpropane, is C4H10, also
written as CH(CH3)2-CH3 to distinguish
it from butane. Isobutane’s
identification number in the Chemical
Abstracts Service’s registry (CAS Reg.
No.) is 75–28–5. The chemical formula
for propane is C3H8 and its CAS Reg.
No. is 74–98–6. As refrigerants, propane
and isobutane can be referred to by the
NPRM, EPA is limiting the scope of our
acceptability decisions to refrigerators
and freezers and combination
refrigerator and freezers with a
refrigerant charge of 57 grams (2.0
ounces) or less.
C. What end-uses are included in our
proposed decision?
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fittings used in equipment or containers
using non-flammable refrigerant.
‘‘Differ’’ means that either the diameter
must differ by at least 1⁄16 inch or the
thread direction must be reversed (i.e.,
right handed vs. left handed). These
fittings must be permanently affixed to
the unit, and may not be accessed with
an adaptor, until the end-of-life of the
unit;
7. R–290 may not be sold as a
refrigerant in containers containing less
than five pounds (2.8 kg) of refrigerant.
2. Retail Food Refrigeration
Retail food refrigeration includes the
refrigeration systems, including cold
storage cases, designed to chill food or
keep it at a cold temperature for
commercial sale. For the purpose of this
proposal we are considering the use of
hydrocarbons only in stand-alone
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ASHRAE designations R–290 and R–
600a, respectively.
ANSI/ASHRAE Standard 34–2007
categorizes isobutane, propane, and
components of HCR–188C and HCR–
188C1 in the A3 Safety Group.
ASHRAE’s safety group classification
consists of two alphanumeric characters
(e.g., A2 or B1). The capital letter
indicates the toxicity and the numeral
denotes the flammability. ASHRAE
classifies Class A refrigerants as
refrigerants for which toxicity has not
been identified at concentrations less
than or equal to 400 ppm by volume,
based on data used to determine
threshold limit value-time-weighted
average (TLV–TWA) or consistent
indices. Class B signifies refrigerants for
which there is evidence of toxicity at
concentrations below 400 ppm by
volume, based on data used to
determine TLV–TWA or consistent
indices. The refrigerants are then
assigned a flammability classification
from one of three classes—1, 2, or 3
based on flammability. Tests are
conducted in accordance with ASTM
E681 using a spark ignition source
(ASHRAE 2007). Figure 1 in ANSI/
ASHRAE Standard 15–2007 uses the
same safety group but limits its
concentration to 3400 ppm.
equipment. A stand-alone appliance is
one utilizing a sealed hermetic
compressor and for which all
refrigerant-containing components,
including but not limited to the
compressor, condenser and evaporator,
are assembled into a single piece of
equipment before delivery to the
ultimate consumer or user, such
equipment not requiring the addition or
removal of refrigerant when placed into
initial operation. Stand-alone
equipment is used to store chilled
beverages or frozen products (e.g.,
reach-in beverage coolers and stand-
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alone ice cream cabinets). This
proposed decision does not apply to
large refrigeration systems such, as but
not limited to, direct expansion
refrigeration systems typically found in
retail food stores. We are proposing as
a use condition that stand-alone
equipment using a hydrocarbon
refrigerant have a refrigerant charge less
than 150 grams (5.3 ounces).
D. Where Can I Find the Regulatory Text
For These Proposed Listing Decisions?
Our proposed decisions appear in a
table at the end of the document and if
finalized will be codified at 40 CFR 82
subpart G. The proposed regulatory text
contains proposed listing decisions for
the above end-uses. EPA is proposing to
find isobutane, propane, HCR–188C,
and HCR–188C1 acceptable with use
conditions. We note that there may be
other legal obligations pertaining to the
manufacture, use, handling, and
disposal of hydrocarbons that are not
included in the information listed in the
tables (e.g., section 608 prohibition on
venting refrigerant or Department of
Transport requirements for transport of
flammable gases).
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E. What Does An Acceptability
Determination With Use Conditions For
Isobutane, Propane, HCR–188C, and
HCR–188C1 Mean?
In this action, EPA is proposing to
find isobutane, propane, HCR–188C,
and HCR–188C1 acceptable subject to
use conditions as substitutes for CFC–
12, HCFC–22, and R–502 in certain
refrigeration end-uses. If this proposal
were to become final, it would be legal
to use isobutane, propane, HCR–188C,
and HCR–188C1 in the specified types
of equipment under the conditions
outlined above as a substitute for ozonedepleting substances (ODS). If this
proposal became final, use in the
specified types of equipment that is not
consistent with the use conditions
would be a violation of CAA section 612
and EPA’s implementing regulations.
EPA seeks comment regarding this
proposal and, in particular, whether the
proposed use conditions are adequate to
ensure the safe and appropriate
handling of hydrocarbon refrigerants.
IV. What criteria did EPA consider in
preparing this proposal?
Section 612(c) of the Clean Air Act
directs EPA to publish a list of
acceptable replacement substances
(‘‘substitutes’’) for class I and class II
ODS, where the Administrator
determines they are safe for specific
uses when compared with other
currently or potentially available
substitutes, and a list of prohibited
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substitutes for specific uses. EPA
compares the risks to human health and
the environment of a substitute to the
risks associated with other substitutes
that are currently or potentially
available. EPA also considers whether
the substitute for class I and class II
ODSs ‘‘reduces the overall risk to human
health and the environment’’ compared
to the ODSs historically used in the end
use. The criteria for review are listed at
40 CFR 82.180(a)(7). These criteria are
(i) atmospheric effects and related
health and environmental impacts; (ii)
General population risks from ambient
exposure to compounds with direct
toxicity and to increased ground-level
ozone; (iii) Ecosystem risks; (iv)
Occupational risks; (v) Consumer risks;
(vi) Flammability; and (vii) Cost and
availability of the substitute.
EPA evaluated each of the criteria
separately and then considered overall
risk to human health and the
environment in comparison to other
available or potentially available
alternatives in the same end-uses. EPA
proposes to conclude that, overall,
environmental risks posed by the four
reviewed substitutes were not greater
than the environmental risks posed by
other substitutes in the reviewed enduses. Because these four substitutes
have zero ozone depletion potential
(ODP), very low global warming
potential (GWP), and are volatile
organic compounds (VOCs) but
insignificantly affect local air quality,
the environmental risks associated with
ODP GWP, and VOC effects are lower
than or comparable to other acceptable
substitutes. These and other
environmental risks are discussed
below. In addition, EPA has placed in
the docket an analysis table comparing
the four substitutes being proposed in
this action and several substitutes that
have been found acceptable in the
refrigeration and air conditioning end
use. The flammability risks to public
health are of concern because household
and retail food refrigerators and freezers
have traditionally used refrigerants that
are not flammable. Without mitigation,
the risks posed by these refrigerants
would be higher than other nonflammable refrigerants because
individuals may not be aware that their
actions could potentially cause a fire,
and existing equipment has not been
designed specifically to minimize
flammable risks. Therefore, EPA is
proposing use conditions to mitigate
these risks to ensure that the overall risk
to human health and the environment
posed by these four substitutes is not
greater than the overall risk posed by
other substitutes in the same end use.
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A. Impacts on the ecosystem
This section will include the
substitutes’ impact on the environment
including ODP, GWP, and VOC. The
ODP is the ratio of the impact on
stratospheric ozone of a chemical
compared to the impact of an identical
mass of CFC–11. Thus, the ODP of CFC–
11 is defined to be one (1.0). Other CFCs
and HCFCs have ODPs that range from
0.01 to one (1.0). All four refrigerant
substitutes in this proposal have an ODP
of zero,6 lower than the ODP of the
substances that they would replace:
CFC–12 (ODP = 1.0); HCFC–22 (ODP =
0.055); and R–502 (ODP = 0.334) (WMO,
2006). The most commonly used
substitutes in these two end-uses also
have an ODP of zero (e.g. R–404A, R–
134a, R–410A, R–407C).
The GWP index is a means of
quantifying the potential integrated
climate forcing of various greenhouse
gases relative to carbon dioxide. The
100-year integrated GWPs of isobutane,
propane, HCR–188C, and HCR–188C1
are estimated to be eight, three, less than
five, and less than five, respectively,
compared to a value of one for CO2
(WMO, 2006). These are significantly
lower than the 100-year integrated
GWPs of the substances that they would
be replacing: CFC–12 (GWP = 10,890);
HCFC–22 (GWP = 1,810); and R–502
(GWP = 4,660) (WMO, 2006). The GWPs
for hydrocarbons (including the four
being reviewed here) are minimal and
are significantly lower than those of
other acceptable refrigerants in these
end-uses (e.g. GWPs of R–134a, R–404A,
R–407C, and R–410A are about 1430,
3920, 1770, and 2090, respectively).
The greenhouse gas (GHG) impacts of
these refrigerants also depend upon the
energy use by appliances, since the
‘‘indirect’’ GHG emissions associated
with electricity consumption typically
exceed those from refrigerants over the
full lifecycle of refrigerant-containing
products. (Citation: J. Sand, S. Fischer,
and V. Baxter, ‘‘Energy and Global
Warming Impacts of HFC Refrigerants
and Emerging Technologies,’’ 1997, Oak
Ridge National Lab) If hydrocarbonusing appliances are less energy
efficient than the appliances they
replace, then it is possible that these
appliances will result in higher lifecycle
greenhouse gas emissions even if
refrigerant emissions are lower.
Conversely, higher energy efficiency of
these appliances would lead to lower
GHG emissions than the reduction from
6 CFCs and HCFCs are examples of ozonedepleting compounds unlike HCs which contain no
chlorine. CFCs and HCFCs bring chlorine to the
stratosphere, which cause depletion of the ozone
layer.
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refrigerants alone. We have not
quantified the full lifecycle GHG
emissions associated with substituting
traditional ODS refrigerants with
hydrocarbons but acknowledge that they
also depend on the appliance’s
electricity consumption and the fuel
used to generate that electricity.
Hydrocarbons are VOCs under CAA
regulations addressing the development
of State Implementation Plans to attain
and maintain National Ambient Air
Quality Standards for ground-level
ozone, which is a respiratory irritant
(see 40 CFR 51.100(s)). Potential
emissions of VOCs from all substitutes
for all end-uses in the refrigeration and
air conditioning sector are estimated to
be insignificant relative to VOCs from
all other sources (i.e., other industries,
mobile sources, and biogenic sources)
(ICF, May 22, 2009, May 26, 2009, and
July 17, 2009).
determine whether flammability would
be a concern for service and
manufacture personnel or for
consumers, EPA conducted a reasonable
worst-case scenario analysis to model
catastrophic release of the refrigerant.
The worst-case scenario analysis
revealed that even if the unit’s full
charge is emitted within one minute,
none of these four hydrocarbons
reached the LFL (ICF, May 22, 2009,
May 26, 2009, July 17, 2009, and
November 6, 2009). However, as
mentioned above, hydrocarbons
refrigerants are flammable and service
and manufacture personnel or
consumers are not familiar with these
refrigerator or freezer or combination
refrigerators and freezers containing a
flammable refrigerant; therefore, use
conditions are necessary to create
awareness of a flammable refrigerant
and ensure safe handling. Detailed
analysis of the modeling results are
discussed below in the ‘‘toxicity’’ section
of the preamble. EPA also reviewed the
submitters’ detailed assessments of the
probability of events that might create a
fire and engineering approaches to
avoid sparking from the refrigeration
equipment.
B. Flammability and Fire Safety
Due to their flammable nature,
isobutane, propane, HCR–188C, and
HCR–188C1 could pose a significant
safety concern for workers and
consumers if they are not handled
correctly. In the presence of an ignition
source (e.g., static electricity spark
resulting from closing a door, using a
torch during service, or a short circuit
in wiring that controls the motor of a
compressor), an explosion or a fire
could occur when the concentration of
isobutane, propane, HCR–188C or HCR–
188C1 exceeds its lower flammability
limit 7 (LFL) of 18,000 ppm, 21,000
ppm, 20,000 ppm, or 16,000 ppm,
respectively. Therefore, in order for
these substitutes to be used safely, it is
important to minimize the presence of
potential ignition sources and to reduce
the likelihood that the levels of
isobutane, propane, HCR–188C, or
HCR–188C1 will exceed the LFL. In
production facilities or other facilities
where large quantities of the refrigerant
would be stored, proper safety
precautions should be in place to
minimize the risk of explosion. EPA
recommends these facilities be
equipped with proper ventilation
systems to minimize the risks of
explosion and should be properly
designed to reduce possible ignition
sources. EPA also understands that
these hydrocarbon refrigerants will be
used by original equipment
manufacturers (OEMs) in specifically
redesigned refrigerators and freezers.
For all four hydrocarbon refrigerants
considered in this proposal, to
C. Toxicity
In evaluating potential human health
impacts of isobutane, propane, HCR–
188C, and HCR–188C1, EPA considered
impacts both on exposed manufacture
personnel, store employees, technicians
herein defined as ‘‘worker,’’ and on
consumers. EPA investigated the risk of
asphyxiation and of exposure to toxic
levels of refrigerant for a worst-case
scenario and a typical use scenario for
isobutane, propane, HCR–188C, and
HCR–188C1. EPA believes that the use
of any of these hydrocarbons in the enduses reviewed does not pose a
significant risk of asphyxiation or of
exposure to toxic levels to workers or
consumers.
EPA estimated the maximum time
weighted average 8 (TWA) exposure for
each exposure scenario and compared
this value to relevant industry and
government exposure limits for
isobutane, propane, HCR–188C, and
HCR–188C1 (including potential
impurities in the substitutes). The
modeling results indicate that both the
short-term (15-minute and 30-minute)
and long-term (8-hour) worker exposure
concentrations at no point are likely to
exceed 2 percent (for isobutane), 50
percent (for propane), 4 percent (for
HCR–188C), or 2 percent (for HCR–
7 Lower flammability limit (LFL) = Lower
Flammability Limit, the minimum concentration in
air at which flame propagation occurs.
8 Time weighted average (TWA) = An allowable
exposure concentration averaged over a normal 8hour workday or a 40-hour workweek.
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188C1) of the Occupational Safety and
Health Administration (OSHA)
permissible exposure limit (PEL) and
National Institute for Occupational
Safety and Health (NIOSH)
recommended exposure limit (REL) of
the component refrigerants (for
isobutane and propane) or the
refrigerants components for HCR–188C
and HCR–188C1(ICF, 2009).
EPA performed a consumer exposure
analysis that examined potential
catastrophic release of the substitute
under a reasonable worst-case scenario.
Estimates for acute/short-term consumer
exposures resulting from catastrophic
leakage of refrigerant from residential
refrigerators were examined. The
analysis was undertaken to determine
the 15-minute and 30-minute TWA
exposure levels for the substitute, which
were then compared to the standard
toxicity limits to assess the risk to
consumers. However, the TWA values
were conservative, as the analysis did
not consider opened windows, fans
operating, conditioned airflow (either
heated or cooled), and other variables
that would likely reduce the levels to
which individuals would be exposed.
This analysis assumed that 100
percent of the unit’s charge would be
released during a time span of one
minute, at which time the concentration
of refrigerant would peak and then
steadily decline. Refrigerant
concentrations were modeled under two
air change scenarios, believed to
represent the baseline of potential flow
rates for a home, assuming flow rates of
2.5 and 4.5 air changes per hour (ACH)
(Sheldon 1989). The highest
concentrations of the refrigerant occur
in the lower stratum of the room when
assuming lower ventilation levels of 2.5
ACH. Using a 2.5 ACH to calculate the
TWA achieves a higher concentration
than using 4.5 ACH to calculate the
TWA. Because EPA looked at the worst
case scenario it was only necessary to
evaluate the TWA values using 2.5 ACH
as 4.5 ACH TWA values would be in the
acceptable range if the 2.5ACH TWA
values were within the acceptable range.
OSHA (2004) states no toxic effects
are reported with exposures to
isobutane below 18,000 ppm. Even
under the very conservative
assumptions used in the consumer
exposure modeling, both the estimated
15-minute and 30-minute consumer
exposures to isobutane (5,025 ppm and
3,844 ppm, respectively) are much
lower than 18,000 ppm, and thus should
not pose a toxicity threat.
EPA also evaluated the same scenario
with HCR–188C and HCR–188C1. The
highest concentrations of HCR–188C
and HCR–188C1 occur in the lower
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stratum of the room when assuming
lower ventilation levels of 2.5 ACH.
Even under the conservative
assumptions used in the consumer
exposure modeling, both the estimated
15-minute and 30-minute consumer
exposure levels of HCR–188C and HCR–
188C1 are at least 50 percent lower than
the 30-minute acute exposure guideline
level (AEGL)-1 values for the individual
components of the blend and thus
should not pose a toxicity threat.
To assess end-use exposures to
propane, an Acute Exposure Guideline
Level (AEGL) was chosen as the most
appropriate toxicological limit. This
limit is an emergency guideline for
exposures to the general population
(including susceptible populations) and
is not time-weighted; it also considers
the chemical’s flammability in addition
to its toxicity. A time-weighted limit
was deemed inappropriate for this
scenario because, due to the nature of a
time-weighted calculation. As TWA are
exposure concentrations averaged over a
normal eight (8) hour work-day, it could
allow a room occupant to be exposed to
levels higher than the limit for a brief
period of time. This is a concern for
propane due to its flammability, as a
higher exposure could approach the
chemical’s lower flammability limit
(LFL—propane has an LFL of 21,000
ppm).
The EPA develops a set of AEGL
values for a chemical for five exposure
periods (10 and 30 minutes, 1 hour, 4
hours and 8 hours). For each exposure
period, three different AEGL values are
developed to address different levels of
toxicological impacts. Of relevance for
the modeled scenario is the AEGL–1
(10,000 ppm), which is defined as: ‘‘the
airborne concentration, expressed as
parts per million or milligrams per
cubic meter (ppm or mg/m3) of a
substance above which it is predicted
that the general population, including
susceptible individuals, could
experience notable discomfort,
irritation, or certain asymptomatic
nonsensory effects. However, the effects
are not disabling and are transient and
reversible upon cessation of exposure.’’
While permanent toxicological effects
are not expected up to the AEGL–2
value (17,000 ppm for propane), this
limit is not relevant for this analysis
because at that level, flammability
would be a greater concern.
EPA analyzed consumer and worker
exposure to propane in commercial food
cabinets with a 150 gram charge size.
The highest expected levels of exposure
for this end-use occur in the lower
stratum of the room. The result for
propane is a 15-minute TWA of 10,414
ppm and a 30-minute TWA of 7,963
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ppm. The 10-minute (AEGL)–1 value for
propane is 10,000 ppm.9 Specifically,
for propane at the end-use, the modeled
15-minute time-weighted average
exposure is 10,414 ppm (for practical
purposes, there is no difference
toxicologically speaking between this
value and 10,000 ppm (the AEGL–1
value), especially as this is a modeled
concentration and is based on a worstcase scenario). As this exposure
concentration is marginally higher than
the AEGL–1 and significantly lower
than the AEGL–2, serious or permanent
toxicological effects are not expected for
room occupants at the end-use.
Therefore, it is believed that even under
the very conservative assumptions used
in this model, exposures to propane
should not pose a toxicity threat. As the
AEGL is an emergency guideline, and
flammability is a concern for this
chemical, it is recommended that room
occupants should evacuate the space
immediately following the accidental
release of this refrigerant. As our
submitters have stated an accidental
release would be caused during service
and maintenance therefore the service
technicians would know to evacuate.
For further information regarding
accidental releases or fault tree analyses
see the docket number EPA–HQ–OAR–
2009–0286.
V. Why is EPA proposing these specific
use conditions?
EPA is proposing to find isobutane,
HCR–188C, and HCR–188C1 acceptable
with use conditions in new household
refrigerators and freezers and
combination refrigerator and freezers
(with a charge of 57 grams (2.0 ounces)
or less) and propane acceptable with use
conditions in stand-alone retail food
refrigerators and freezers (with a charge
of 150 grams (5.3 ounces) or less) that
are designed and manufactured
specifically to use these alternatives.
The proposed listings with the specific
use conditions are intended to allow for
the use of isobutane, propane, HCR–
188C, and HCR–188C1 where the
current evidence shows that they can be
used safely within specified parameters.
We also seek comment on the proposed
listing as well as the specific use
conditions discussed below.
A. New Equipment Only; Not Intended
for Use as a Retrofit Alternative
EPA is proposing that the four
refrigerants considered in this proposal
must be used only in new equipment
that has been designed and
9 https://www.epa.gov/opptintr/aegl/pubs/
results96.htm EPA Web site accessed August 17,
2009.
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manufactured specifically for use with
the listed alternative refrigerant, as
follows:
• Isobutane—household refrigerators,
freezers, and combination refrigerator
and freezers;
• Propane—retail food refrigeration
(stand-alone only);
• HCR–188C—household
refrigerators and freezers and
combination refrigerator and freezers;
and
• HCR–188C1—household
refrigerators and freezers and
combination refrigerator and freezers.
The four refrigerants were not
submitted under the SNAP program to
be used in retrofitted equipment.
Existing equipment designed for other
refrigerants may not be converted or
retrofitted to use any of these four
hydrocarbon refrigerants. These
substitutes may be used only in new
equipment that is designed to address
concerns unique to flammable
refrigerants.
B. Standards
EPA is proposing the refrigerants may
be used only in equipment that meets
all requirements in UL Standard 250
10th edition (for isobutane, HCR–188C,
and HCR–188C1 in household
refrigerators and freezers) or UL 471 9th
edition (for propane in retail food
equipment specifically in stand-alone
refrigeration and freezers).10 UL has
tested equipment for flammability risk
in both household and retail food
refrigeration. Further, UL has developed
acceptable safety standards including
requirements for construction, for
markings, and for performance tests
concerning refrigerant leakage, ignition
of switching components, surface
temperature of parts, and component
strength after being scratched.
C. Charge Size
EPA is proposing a limitation on
charge size for refrigerators and freezers
that reflects the UL 250 and UL 471
standards. EPA is proposing a charge
size not to exceed 57grams (2.0 ounces)
for household refrigerators and freezers
and 150 grams (5.3 ounces) for retail
food refrigeration in stand-alone units.
To place this in comparison, EPA
estimates the charge size of a disposable
lighter is equal to 30 grams (1.1
10 EPA is referencing the UL Standard 250
Supplement SA; ‘‘Requirements for Refrigerators
and Freezers Employing a Flammable Refrigerant in
the Refrigerating System’’, UL 250 10th edition (for
isobutane, HCR–188C, and HCR–188C1 in home
refrigerators and freezers) and UL 471 9th edition
Supplement SB; ‘‘Requirements for Refrigerators
and Freezers Employing a Flammable Refrigerant in
the Refrigerating System’’ (for propane in
commercial refrigerators and freezers).
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ounce).11 Therefore we estimate that
charge size of household refrigerators
and freezers are equivalent to
approximately two disposable lighters
while retail stand-alone refrigerators
and freezers are equivalent to
approximately five disposable lighters
or less. In comparison, the household
refrigerator and freezer and retail food
refrigerator charge size is significantly
less than refillable butane lighter fluid
which contains 340 grams (12 ounces).
The refrigerant charge is smaller than
the disposable propane fuel cylinders
used for camping which contains 468
grams (16.4 ounces).
The UL 250 standard limits the
amount of refrigerant that may leak to
50 grams (1.8 ounces). EPA selected 57
grams (2.0 ounces) to allow for up to 7
grams (0.2 ounces) of refrigerant charge
that might be solubilized in the oil (and
assumed not to not leak or immediately
vaporize with the refrigerant in the case
of a leak). UL standard 471 limits the
amount leaked to 150 grams (5.3
ounces). Furthermore, the charge size
limit for propane (for retail food
refrigeration) is in line with the IEC
60335–2–89 standard for commercial
appliances, which has a charge size
limit of 150 grams (5.3 ounces). EPA did
not include an additional 7grams (0.2
ounces) of refrigerant that would be
solubilized in the oil as we did in the
household refrigerator and freezers end
use. This is because 157 grams (5.5
ounces) would be over the international
charge size standard for retail food
refrigeration. As the international
household refrigerator and freezers
standard’s charge size limit is 150 grams
(5.3 ounces) larger than UL 250
standard, EPA’s suggested charge size
for household refrigerator and freezers
would be well below the international
charge size limit. EPA is taking
comment on the charge size limit on
both the household refrigerator and
freezers and retail food refrigeration end
use.
D. Color-Coded Hoses and Piping
EPA proposes that equipment must
have distinguishing color-coded hoses
and piping to indicate use of a
flammable refrigerant. This will help
technicians immediately identify the
use of a flammable refrigerant, thereby
potentially reducing the risk of using
sparking equipment or otherwise having
an ignition source nearby. The air
conditioning and refrigeration industry
currently uses distinguishing colors as
means for identifying different
11 Study conducted by Ben and Jerry’s/Unilever
on the weight of butane contained in disposable
lighters.
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refrigerants. Likewise, distinguishing
coloring has been used elsewhere to
indicate an unusual and potentially
dangerous situation, for example in the
use of orange-insulated wires in hybrid
electric vehicles. EPA is proposing that
all such refrigerator tubing be colored
red Pantone Matching System (PMS)
#185 to match the red band displayed
on the container of flammable
refrigerants under the Air Conditioning,
Heating and Refrigeration Institute
(AHRI) Guideline ‘‘N’’ 2008, ‘‘2008
Guideline for Assignment of Refrigerant
Container Colors.’’ EPA believes that one
color is sufficient for both household
refrigerator and freezers and retail food
refrigeration (stand-alone units) to
indicate the equipment contains a
flammable refrigerant.
EPA wants to ensure that there is no
doubt that a flammable refrigerant is
being used within the equipment or
appliance. Currently, no industry
standard exists for color-coded hoses or
pipes for isobutane, propane, HCR–
188C, or HCR–188C1. EPA is taking
comment on the potential development
of an industry-wide standard for hoses
and pipes for flammable refrigerants.
One mechanism to distinguish hoses
and pipes that EPA would find
acceptable is to add a colored plastic
sleeve or cap to the service tube. The
colored plastic sleeve or cap would have
to be forcibly removed in order to access
the service tube. This would signal to
the technician that the refrigeration
circuit that she/he was about to access
contained a flammable refrigerant, even
if all warning labels were somehow
removed. This sleeve could be boldly
marked with a specific color or graphic
to indicate the refrigerant was
flammable. This could be a costeffective means as an alternative to
painting or dying the hose or pipe. EPA
is taking comment on this mechanism of
distinguishing the pipe and hose by
adding a colored plastic sleeve or cap to
the pipe or hose.
EPA is particularly concerned with
ensuring adequate and proper
notification for servicing and disposal of
appliances containing flammable
refrigerants. EPA believes the use of
color-coded hoses, as well as the use of
warning labels and unique fittings
discussed below, would be reasonable
and would be consistent with other
general industry practices. EPA requests
comment on whether such color coding
would provide, in combination with
other proposed use conditions, adequate
warning of the use of a flammable
refrigerant and, if so, whether such
color-coding should be required for all
tubing or just some, e.g., around service
ports.
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E. Labeling
As a use condition, EPA is proposing
to require labeling of household and
retail refrigerators and freezers. EPA is
proposing the warning labels on the
equipment contain letters at least 1⁄4
inch high. The label must be
permanently affixed to the refrigerator
until the refrigerator’s end of life.
Warning label language for household
refrigerators and freezers is found in UL
250 as SA6.1 and for commercial
refrigerators and freezers in UL 471 as
SB6.1.
EPA believes that it would be difficult
to see the warning labels with UL 250
and 471’s minimum lettering height
requirement of 1⁄8 inch. Therefore, EPA
is proposing the minimum height must
be 1⁄4 inch as opposed to 1⁄8 inch for
lettering, which will make it easier for
technicians, consumers, retail
storeowners, and emergency first
responders to view the warning labels.
EPA is requesting comment on requiring
labeling, the height of the lettering,
whether specific colors or symbols are
also needed, and the likelihood of labels
remaining on a product throughout the
lifecycle of the product, including its
disposal.
F. Unique Fittings
EPA is proposing that household and
retail refrigerators and freezers using
these refrigerants must have fittings
unique to flammable refrigerants (with
unique color and unique thread
direction or fitting diameter to the
refrigerant). Instead of having separate
fittings for each type of flammable
refrigerant, EPA believes one unique
fitting for all flammable refrigerants is
sufficient. We believe that using
flammable refrigerants with a unique set
of fittings will prevent the accidental
mixing of flammable and nonflammable refrigerants. These fittings
(male or female, as appropriate) are
attachment points on the equipment
itself, on all recovery equipment, on
charging equipment, and on all
refrigerant containers. Unique fittings
are defined in 64 FR 22983, April 28,
1999 as: ‘‘For screw-on-fittings, ‘‘differ’’
means that either the diameter must
differ by at least 1/16 inch or the thread
direction must be reversed (i.e., right
handed vs. left handed). Simply
changing the thread pitch is not
sufficient. For quick-connect fittings,
‘‘differ’’ means that a person using
normal force and normal tools
(including wrenches) must not be able
to cross-connect fittings.’’
EPA believes that service ports are
necessary to facilitate recovery of
refrigerant during service or disposal of
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appliances. EPA notes that service
apertures on small appliances using
class I and class II substances is
required by the CAA section 608(b)(2).
Service ports allow for the proper
recovery of refrigerant during service or
disposal of refrigerators and freezers
because service ports act as an access
point for recovery equipment. As
required by 40 CFR 82.154(a)(1), no
refrigerant may be knowingly vented.
Therefore, prior to disposal of the
equipment all refrigerants must be
recovered. Without the service port on
the equipment, there is no mechanism
to recover the refrigerant without
cutting into the refrigerant lines.
In addition, EPA is requiring that
flammable refrigerant fittings must be
designed to mechanically prevent crosscharging with another non-flammable
refrigerant. EPA believes that it is likely
that technicians servicing hydrocarbon
appliances will also service appliances
containing CFC, HCFC, and HFC
refrigerants. The multitude of
refrigerants could lead to unintentional
mixing of recovered refrigerant resulting
in emissions of contaminated refrigerant
that might not be able to be
economically separated and/or
reclaimed. EPA believes that unique
fittings will aid in the prevention of
such contamination that might prevent
recycling and reclamation of otherwise
useful non-flammable refrigerant. This
is especially important as the HCFC
allocation rule becomes effective on
January 1, 2010, it is expected the
supply of HCFC–22 will become limited
during the middle of the coming decade.
Recycling and reclamation of HCFC–22
will be necessary to maintain an ample
supply of HCFC–22.
Traditionally the refrigeration
industry has not used unique fittings;
however, it has been required in the
motor vehicle air conditioning industry
since June 13, 1995 (60 FR 31096). For
further clarification please refer to April
28, 1999 (64 FR 22983) where EPA
defined uniqueness of fittings for motor
vehicle air conditioners using
substitutes under SNAP. EPA believes
that the use of unique fittings in
stationary refrigeration and air
conditioning are appropriate for
flammable refrigerants. Unique fittings
would help maintain the separation of
flammable refrigerants from equipment
designed for non-flammable refrigerants
because the equipment for charging
flammable refrigerants would not be
able to be used on other equipment.
This should reduce the risk of fire by
ensuring that flammable refrigerants are
used only in equipment designed for
flammable refrigerants. In addition, the
use of unique fittings can help in
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identifying the refrigerant being used
and reducing the likelihood that
flammable refrigerant might
contaminate supplies of recovered
nonflammable refrigerant containing
CFCs, HCFCs, or HFCs.
EPA requests comments on the
potential use of unique fittings, whether
one such unique fitting is adequate to
cover all flammable refrigerants, the
adequacy of the definition of unique
fittings, and the likelihood that such
fitting would achieve the objectives of
avoiding refrigerant contamination and
maintaining safety in a market where
both flammable and non-flammable
refrigerants may be utilized. EPA is also
requesting comment on the applicability
of the ANSI/ASHRAE 34–2007 standard
for flammability and whether these use
conditions are appropriate to ensure
safety.
as a result, damage the equipment or
appliance or create a fire hazard. To
prevent refrigerant contamination,
addition of the incorrect refrigerant, or
incorrect disposal of canisters and to
avoid the risk of explosions or fire, EPA
proposes a use condition prohibiting
small containers of isobutane, propane,
HCR–188C, and HCR–188C1, i.e.,
containers of less than five lbs (2.8 kg).
EPA is seeking comment on this
restriction on small canisters of
refrigerant grade hydrocarbons such as
R–600a, R–290, HCR–188C, and HCR–
188C1. EPA is also requesting comment
on the potential cost of the containers of
hydrocarbon refrigerant and if the cost
of such containers of hydrocarbon
refrigerants would be different from the
current cost of a similar quantity of
propane or isobutane currently sold for
other purposes.
G. Small Containers
EPA is proposing that these four
refrigerants may not be sold for use in
the listed end uses as a refrigerant in
containers in quantities of less than five
pounds (2.8 kg). This restriction would
ban the sale of small canisters of
refrigerant-grade hydrocarbons. The
purpose of this proposal is to prevent
purchase by untrained people who
would not have the appropriate skills or
equipment to properly recover or charge
the refrigerant. Larger containers of
flammable refrigerant would also
typically be purchased by technicians
rather than untrained people because
the larger amount of refrigerant would
be less useful to individual users, who
would typically need only a small
amount, and the larger quantity could
be cost prohibitive to individual users.
Therefore this would reduce the
possibility that untrained people would
handle the flammable refrigerant,
accidentally add flammable refrigerants
to a CFC, HCFC, or HFC refrigerant, or
would incorrectly dispose of the
containers.
Contaminating a CFC, HCFC, or HFC
refrigerant will cause the refrigerant to
be potentially unusable. Mixing of
refrigerants is counter to overall Title VI
implementation. Consequently, the
wasted refrigerant would have to be
disposed of properly rather than reused,
potentially further limiting the tight
supply of HCFC–22 in the coming
decade. The SNAP program, together
with other Title VI regulations, seeks to
ensure a smooth transition as we
continue to phase out ODS, including
HCFC–22. In addition to contaminating
the refrigerant, an untrained person
could potentially add a flammable
refrigerant to equipment that is not
designed for flammable refrigerant and,
VI. What recommendations does EPA
have for safe use of hydrocarbon
refrigerants?
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EPA proposes to recommend that only
technicians specifically trained in
handling flammable refrigerants service
or dispose of refrigerators and freezers
containing these refrigerants.
Technicians must know how to
minimize the risk of fire and the
procedures for using flammable
refrigerants safely. Releases of large
quantities of refrigerant during servicing
and manufacturing, especially in areas
where large amounts of refrigerant are
stored, could cause an explosion if an
ignition source exists nearby. For these
reasons, it is important that only
properly trained technicians handle
flammable refrigerants when servicing
or disposing of household and retail
food refrigerators and freezers.
EPA is unaware of any existing
industry-wide technician training
program or standard that fully covers
the safe use of flammable refrigerants.
EPA has reviewed several training
programs provided as part of SNAP
submissions from persons interested in
flammable refrigerants. EPA intends to
update the CAA section 608 technician
certification test bank provided to
organizations that administer the
certification exams in accordance with
40 CFR 82.161 to specifically address
flammable refrigerants. EPA requests
any information on an industry-wide
flammable refrigerant training program,
whether such a program is under
development, the burden on the
technicians to take an industry wide
safety training, and the timeline likely
needed to develop such a program in
order to begin training a nation-wide
fleet of technicians.
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VII. What other options did EPA
consider?
EPA considered several different
options in preparing this proposed rule.
Although EPA is not proposing these
options, which are discussed below, we
seek comment on them.
EPA considered allowing isobutane
and propane as a refrigerant for use only
in the original equipment
manufacturers’ (OEM) specific
appliances, described in a SNAP
application. The reason for such a
limitation is the concern that equipment
from other manufacturers would not be
designed with spark-proof engineering
as prescribed by the submitter, nor
would the manufacturers be able to
develop recovery equipment compatible
with flammable refrigerants.
Limiting use to SNAP reviewed
equipment would be time consuming
and costly for all parties involved. EPA
would have to consider each refrigerator
and freezer model for both household
and retail separately. This would
increase the burden on industry, with
little added benefit for health and safety,
since the engineering of such equipment
and the requirements needed to meet a
national safety standard are already
rigorous. Although there is the potential
that some OEMs might not develop
proper equipment, EPA believes that the
potential liability associated with
selling equipment not designed to safely
use these refrigerants should ensure that
this does not occur. Therefore, EPA
decided to not propose to limit use to
equipment reviewed by EPA through
the SNAP program.
EPA also considered a specific use
condition requiring ‘‘spark proof’’
circuits in the design of equipment
using hydrocarbon refrigerants. EPA
believes it would be unnecessary to
further require ‘‘spark proof circuits’’ as
a use condition because UL 250 and UL
471 already require strict standards, to
prevent fire or explosion, which must be
met in order to obtain certification. We
believe that all OEMs will also take into
account flammability risks when
designing the appliance to meet the
charge size requirement.
EPA also considered proposing as a
use condition that recovery equipment
used to recapture these refrigerants must
be able to handle flammable
refrigerants. In accordance with CAA
Section 608 regulations, refrigerant
cannot be vented to the atmosphere and
instead must be recaptured and
recycled, reclaimed if possible, or
disposed of in accordance with Federal
and state regulations. For safety
concerns, recovery equipment
appropriate for flammable refrigerants
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will be needed. EPA seeks data on
whether there currently is an industry
standard for recovery units for
flammable refrigerants and whether
there are available specific recovery
units that are compatible with
isobutane, propane, HCR–188C, and
HCR–188C1. At this time, EPA is
unaware of any recovery units that are
designed specifically for hydrocarbons
and which are readily available in the
U.S. EPA did not propose that recovery
equipment used to recapture
hydrocarbon refrigerants because this is
better addressed under Section 608.
Under Section 608 of the CAA,
venting of hydrocarbons for household
refrigerators and freezers and retail food
refrigeration (stand-alone refrigerators
and freezers) could be allowed if EPA
determines that such venting, releasing,
or disposing of such substance does not
pose a threat to the environment. EPA
is not proposing such a determination in
this rule making, but requests comment
on whether hydrocarbon refrigerants
should be exempted from the Section
608 venting prohibition. As appropriate,
EPA would address these issues in a
separate
EPA also considered other approaches
such as:
• Requiring only one use condition
for each refrigerant; to meet the UL 250
or 471 standards;
• Finding hydrocarbon refrigerants
unacceptable until an industry-wide
standard exists for servicing refrigerator
using hydrocarbon refrigerant.
EPA is taking comment on the above
alternate approaches.
VIII. Statutory and Executive Order
Reviews
A. Executive Order 12866: Regulatory
Planning and Review
Under Executive Order (EO) 12866
(58 FR 51735, October 4, 1993), this
action is a ‘‘significant regulatory
action.’’ It raises novel legal or policy
issues arising out of legal mandates, the
President’s priorities, or the principles
set forth in the Executive Order.
Accordingly, EPA submitted this action
to the Office of Management and Budget
(OMB) for review under EO 12866 and
any changes made in response to OMB
recommendations have been
documented in the docket for this
action.
B. Paperwork Reduction Act
This action does not impose any new
information collection burden. This
proposed rule is an Agency
determination. It contains no new
requirements for reporting. The only
new recordkeeping requirement
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involves customary business practice.
The Office of Management and Budget
(OMB) has previously approved the
information collection requirements
contained in the existing regulations in
subpart G of 40 CFR part 82 under the
provisions of the Paperwork Reduction
Act, 44 U.S.C. 3501 et seq. and has
assigned OMB control number 2060–
0226. This Information Collection
Request (ICR) included five types of
respondent reporting and recordkeeping
activities pursuant to SNAP regulations:
Submission of a SNAP petition, filing a
SNAP/TSCA Addendum, notification
for test marketing activity,
recordkeeping for substitutes acceptable
subject to use restrictions, and
recordkeeping for small volume uses.
The OMB control numbers for EPA’s
regulations are listed in 40 CFR part 9
and 48 CFR Chapter 15.C.
C. Regulatory Flexibility Act (RFA)
The RFA generally requires an agency
to prepare a regulatory flexibility
analysis of any rule subject to notice
and comment rulemaking requirements
under the Administrative Procedure Act
or any other statute unless the agency
certifies that the rule will not have a
significant economic impact on a
substantial number of small entities.
Small entities include small businesses,
small organizations, and small
governmental jurisdictions. For
purposes of assessing the impacts of this
rule on small entities, small entity is
defined as: (1) A small business as
defined by the Small Business
Administration’s (SBA) regulations at 13
CFR 121.201; (2) a small governmental
jurisdiction that is a government of a
city, county, town, school district or
special district with a population of less
than 50,000; and (3) a small
organization that is any not-for-profit
enterprise which is independently
owned and operated and is not
dominant in its field.
After considering the economic
impacts of this proposed rule on small
entities, I certify that this action will not
have a significant economic impact on
a substantial number of small entities.
The requirements of this proposed rule
impact household and commercial
refrigerator and freezer manufacturers.
This rule indirectly affects users,
technician testing organizations, and
technicians. Today’s action, if finalized,
would allow users the additional
options of using isobutane, propane,
HCR–188C, and HCR–188C1. Because
isobutane, propane, HCR–188C and
HCR–188C1 refrigeration systems are
not manufactured yet, no change in
business practice would be required to
meet the use conditions and thus the
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Federal Register / Vol. 75, No. 89 / Monday, May 10, 2010 / Proposed Rules
rule would not impose any new costs on
small entities if finalized as proposed.
EPA continues to be interested in the
potential impacts of the proposed rule
on small entities and welcomes
comments on issues related to such
impacts.
mstockstill on DSKH9S0YB1PROD with PROPOSALS
D. Unfunded Mandates Reform Act
This action contains no Federal
mandates under the provisions of Title
II of the Unfunded Mandate Reform Act
of 1995 (UMRA), 2 U.S.C. 1531–1538 for
State, local, or tribal governments or the
private sector. This action imposes no
enforceable duty on any State, local, or
tribal governments or the private sector.
The enforceable requirements of this
proposed rule related to integrating risk
mitigation devices, markings, and
procedures for maintaining safety of
household refrigerators, freezers, and
combination refrigerator and freezer
systems using hydrocarbon refrigerants
affect only a small number of
manufacturers of household and
commercial refrigerators, freezers, and
combination refrigerator and freezers
and their technicians. This proposal
provides additional refrigerant options,
allowing greater flexibility for industry
in designing consumer products.
Further, equipment using hydrocarbon
refrigerants is not yet being produced in
the U.S. therefore we do not expect
impacts on existing users. Thus, this
rule is not subject to the requirements
of sections 202 and 205 of the UMRA.
This action is also not subject to the
requirements of section 203 of UMRA
because it contains no regulatory
requirements that might significantly or
uniquely affect small governments. This
regulation applies directly to facilities
that use these substances and not to
governmental entities. The acceptability
with use conditions of isobutane,
propane, HCR–188C, and HCR–188C1
does not impact the private sector
because manufacturers are not
producing systems under the current
regulation. This proposed rule does not
mandate a switch to these substitutes;
consequently, there is no direct
economic impact on entities from this
rulemaking.
E. Executive Order 13132: Federalism
This action does not have Federalism
implications. It will not have substantial
direct effects on the States, on the
relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government, as specified in
Executive Order 13132. This regulation
applies directly to facilities that use
these substances and not to
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16:19 May 07, 2010
Jkt 220001
governmental entities. Thus, Executive
Order 13132 does not apply to this
action. In the spirit of Executive Order
13132, and consistent with EPA policy
to promote communications between
EPA and State and local governments,
EPA specifically solicits comments on
this proposed action from State and
local officials.
F. Executive Order 13175: Consultation
and Coordination With Indian Tribal
Governments
This action does not have tribal
implications, as specified in Executive
Order 13175 (65 FR 67249, November 9,
2000). It will not have substantial direct
effects on tribal governments, on the
relationship between the Federal
government and Indian tribes, or on the
distribution of power and
responsibilities between the Federal
government and Indian tribes, as
specified in Executive Order 13175.
EPA specifically solicits additional
comment on this proposed action from
tribal officials.
G. Executive Order 13045: Protection of
Children From Environmental Health
and Safety Risks
This action is not subject to Executive
Order 13045 (62 FR 19885, April 23,
1997) because it is not economically
significant as defined in EO 12866, and
because the Agency does not believe the
environmental health or safety risks
addressed by this action present a
disproportionate risk to children. This
proposed rule provides both regulatory
restrictions and recommended
guidelines based upon risk screens
conducted in order to reduce risk of fire
and explosion. The public is invited to
submit comments or identify peerreviewed studies and data that assess
effects of early life exposure to the
refrigerants addressed in this action.
H. Executive Order 13211: Actions That
Significantly Affect Energy Supply,
Distribution, or Use
This action is not a ‘‘significant energy
action’’ as defined in Executive Order
13211, (66 FR 28355 (May 22, 2001))
because it is not likely to have a
significant adverse effect on the supply,
distribution, or use of energy.
Preliminary information indicates that
these new systems may be more energy
efficient than currently available
systems in some climates. Further, we
have concluded that this rule is not
likely to have any adverse energy
effects.
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25811
I. National Technology Transfer and
Advancement Act
Section 12(d) of the National
Technology Transfer and Advancement
Act of 1995 (‘‘NTTAA’’), Public Law
104–113, (15 U.S.C. 272 note) directs
EPA to use voluntary consensus
standards in its regulatory activities
unless to do so would be inconsistent
with applicable law or otherwise
impractical. Voluntary consensus
standards are technical standards (e.g.,
materials specifications, test methods,
sampling procedures, and business
practices) that are developed or adopted
by voluntary consensus standards
bodies. The NTTAA directs EPA to
provide Congress, through OMB,
explanations when the Agency decides
not to use available and applicable
voluntary consensus standards.
This proposed rule involves technical
standards. EPA proposes to use the
Underwriters Laboratory (UL) standards
250 and 471, which was revised to
include requirements for safety and
reliability for flammable refrigerants.
This proposed rule regulates the safety
and deployment of new substitutes for
household and commercial refrigerators
and freezers.
EPA welcomes comment on this
aspect of the proposed rulemaking and,
specifically invites the public to identify
potentially applicable voluntary
consensus standards and to explain why
such standards should be used in this
regulation.
J. Executive Order 12898: Federal
Actions To Address Environmental
Justice in Minority Populations and
Low-Income Populations
Executive Order (EO) 12898 (59 FR
7629 (Feb. 16, 1994)) establishes Federal
executive policy on environmental
justice. Its main provision directs
Federal agencies, to the greatest extent
practicable and permitted by law, to
make environmental justice part of their
mission by identifying and addressing,
as appropriate, disproportionately high
and adverse human health or
environmental effects of their programs,
policies, and activities on minority
populations and low-income
populations in the United States.
EPA has determined that this
proposed rule will not have
disproportionately high and adverse
human health or environmental effects
on minority or low-income populations
because it increases the level of
environmental protection for all affected
populations without having any
disproportionately high and adverse
human health or environmental effects
on any population, including any
E:\FR\FM\10MYP1.SGM
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Federal Register / Vol. 75, No. 89 / Monday, May 10, 2010 / Proposed Rules
minority or low-income population.
This proposed rule would provide
refrigerant substitutes that have no ODP
and low GWP. The reduction in ODS
and GWP emissions would assist in
restoring the stratospheric ozone layer
and provide climate benefits.
IX. References
The documents below are referenced
in the preamble. All documents are
located in the Air Docket at the address
listed in Section I.B.1 at the beginning
of this document. Unless specified
otherwise, all documents are available
electronically through the Federal
Docket Management System, Docket
#EPA–HQ–OAR–2009–0286. Numbers
listed after the reference indicates the
docket and item numbers.
ACGIH. 1991. Propane. In:
Documentation of the threshold limit
values and biological exposure
indices. 6th ed. Cincinnati, OH:
American Conference of
Governmental Industrial Hygienists,
pp. 1286–1287.
ASHRAE. 2007. ‘‘Standard 34–2007
(Supersedes ANSI/ASHRAE Standard
34–2004) Designation and Safety
Classification of Refrigerants.’’
Braker W, Mossman AL. 1980.
Matheson gas data book. 6th ed.
Secaucus, NJ: Matheson Gas Products,
pp. 615–623.
EPA 1994. Significant New Alternatives
Policy Technical Background
Document: Risk Screen on the Use of
Substitutes for Class I OzoneDepleting Substances: Refrigeration
and Air Conditioning. Stratospheric
Protection Division. March, 1994.
ICF, 2009. ICF Consulting. ‘‘Significant
New Alternatives Policy Program
Refrigeration and Air Conditioning
Sector—Risk Screen on Substitutes for
CFC–12 in Household Refrigerators
and Household Freezers—Substitute:
Isobutane’’, May 22, 2009.
ICF, 2009. ICF Consulting. ‘‘Significant
New Alternatives Policy Program
Refrigeration and Air Conditioning
Sector—Risk Screen on Substitutes for
CFC–12, HCFC–22 and R502 in Retail
Food Refrigeration—Substitute:
Propane’’, May 26, 2009.
ICF, 2009. ICF Consulting. ‘‘Significant
New Alternatives Policy Program in
the Household Refrigeration Sector—
Risk Screen on Substitutes for CFC–12
and HCFC–22 in Household
Refrigerators, Household Freezers and
Window AC Units—Substitute: HCR–
188C’’, July 17, 2009.
ICF, 2009. ICF Consulting. ‘‘Significant
New Alternatives Policy Program in
the Household Refrigeration Sector—
Risk Screen on Substitutes for CFC–12
and HCFC–22 in Household
Refrigerators and Freezers–
Substitute: HCR–188C1’’, November 6,
2009
NIOSH. 1996. Propane: IDLH
Documentation. August 1996.
Accessed 17 February 2009. Available
online at: https://www.cdc.gov/niosh/
idlh/74986.html.
OSHA. 2004. ‘‘Safety and Health Topics:
Isobutane.’’ February 2004. Available
online at: https://www.osha.gov/dts/
chemicalsampling/data/CH_
247840.html.
Sheldon, L.S., et al. 1989. ‘‘An
Investigation of Infiltration and
Indoor Air Quality.’’ New York State
Energy Research & Development
Authority, Report 90–11.
List of Subjects in 40 CFR Part 82
Environmental protection,
Administrative practice and procedure,
Air pollution control, Reporting and
recordkeeping requirements.
Dated: April 29, 2010.
Lisa P. Jackson,
Administrator.
For the reasons set out in the
preamble, 40 CFR part 82 is proposed to
be amended as follows:
PART 82—PROTECTION OF
STRATOSPHERIC OZONE
1. The authority citation for Part 82
continues to read as follows:
Authority: 42 U.S.C. 7414, 7601, 7671–
7671q.
Subpart G—Significant New
Alternatives Policy Program
2. Subpart G is amended by adding
Appendix R to read as follows:
Appendix R to Subpart G—Substitutes
Subject To Use Restrictions and
Unacceptable Substitutes
Listed in the [publication date of final rule]
final rule. Effective (date of effective date of
the final rule).
SUBSTITUTES THAT ARE ACCEPTABLE SUBJECT TO USE CONDITIONS
End use
Substitute
Isobutane, R–600a,
as a substitute for
CFC–12 and
HCFC–22.
New Only ...................
mstockstill on DSKH9S0YB1PROD with PROPOSALS
Household refrigerators and freezers
and combination refrigerators and
freezers.
Decision
Use conditions
Further information
Acceptable With Use
Conditions.
1. The quantity of the substitute refrigerant
(i.e., ‘‘charge size’’) shall not exceed 57
grams (2.0 ounces) in any refrigerator,
freezer, or combination refrigerator and
freezers;
Technicians and equipment manufactures
should wear appropriate personal protective equipment, including chemical goggles and protective gloves when handling
isobutane, HCR–188C, and HCR–188C1.
Special care should be taken to avoid
contact with the skin since isobutane,
HCR–188C, and HCR–188C1 like many
refrigerants, can cause freeze burns on
the skin.
• A class B dry powder type fire extinguisher should be kept nearby.
HCR–188C as a substitute for CFC–12
and HCFC–22.
2. These refrigerants may be used only in
new equipment designed specifically and
clearly identified for the refrigerant (i.e.,
none of these substitutes may be used as
a conversion or ‘‘retrofit’’ refrigerant for existing equipment);
12 OSHA regulation 29 CFR 1910.110 considers
ventilation adequate ‘‘when the concentration of the
gas in a gas-air mixture does not exceed 25 percent
of the lower flammable limit.’’
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17:15 May 07, 2010
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13 OSHA regulation 29 CFR 1910.110 considers
ventilation adequate ‘‘when the concentration of the
gas in a gas-air mixture does not exceed 25 percent
of the lower flammable limit.’’
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Federal Register / Vol. 75, No. 89 / Monday, May 10, 2010 / Proposed Rules
25813
SUBSTITUTES THAT ARE ACCEPTABLE SUBJECT TO USE CONDITIONS—Continued
End use
Substitute
Decision
Household refrigerators and freezers
and combination refrigerators and
freezers.
New Only ...................
mstockstill on DSKH9S0YB1PROD with PROPOSALS
• Proper ventilation should be maintained at
all times during the manufacture of equipment containing hydrocarbon refrigerant
through adherence to good manufacturing
practices as per 29 CFR 1910.110.12 If refrigerant levels in the air surrounding the
equipment rise above one-fourth of the
lower flammability limit,1 the space should
be evacuated and re-entry should only
occur after the space has been properly
ventilated.
• Technicians should only use spark proof
tools when working refrigerators and
freezers with R–600a, HCR–188C, and
HCR–188C1.
• Recovery equipment designed for flammable refrigerants should be used.
• Only technicians specifically trained in
handling flammable refrigerants should
service refrigerators and freezers containing these refrigerants. Technicians
should gain an understanding of minimizing the risk of fire and the steps to use
flammable refrigerants safely.
• In production facilities or other facilities
where large quantities of the refrigerant
would be stored, proper safety precautions should be in place to minimize
the risk of explosion. These facilities
should be equipped with proper ventilation
systems to minimize the risks of explosion
and should be properly designed and operated to reduce possible ignition sources.
• Room occupants should evacuate the
space immediately following the accidental release of this refrigerant.
Isobutane, R–600a,
as a substitute for
CFC–12 and
HCFC–22.
Acceptable With Use
Conditions.
5. Similar to clauses SA6.1.1 to SA6.1.2 of
UL standard 250, the following markings,
or the equivalent, shall be provided and
shall be permanent:
HCR–188C as a substitute for CFC–12
and HCFC–22.
....................................
(a) ‘‘DANGER—Risk of Fire or Explosion.
Flammable Refrigerant Used. Do Not Use
Mechanical Devices To Defrost Refrigerator. Do Not Puncture Refrigerant Tubing.’’
(b) ‘‘DANGER—Risk of Fire or Explosion.
Flammable Refrigerant Used. Do Not Use
Mechanical Devices. To Be Repaired Only
By Trained Service Personnel. Do Not
Puncture Refrigerant Tubing.’’
(c) ‘‘CAUTION—Risk of Fire or Explosion.
Flammable Refrigerant Used. Consult Repair Manual/Owner’s Guide Before Attempting To Service This Product. All
Safety Precautions Must be Followed.’’
(d) ‘‘CAUTION—Risk of Fire or Explosion.
Dispose of Properly In Accordance With
Federal Or Local Regulations. Flammable
Refrigerant Used.’’
(e) ‘‘CAUTION—Risk of Fire or Explosion
Due To Puncture Of Refrigerant Tubing;
Follow Handling Instructions Carefully.
Flammable Refrigerant Used.’’
The marking described in clause (a) above
shall be provided on or near any evaporators that can be contacted by the consumer. The markings described in clauses
(b) and (c) above shall be permanently attached near the machine compartment.
The markings described in clause (d)
above shall be permanently attached on
the exterior of the refrigerator. The marking described in clause (e) above shall be
permanently attached near any and all exposed refrigerant tubing. All of these
markings shall be in letters no less than
6.4 mm (1⁄4 inch) high.
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Fmt 4702
HCR–188C1 as a
substitute for CFC–
12 and HCFC–22.
VerDate Mar<15>2010
Further information
3. These refrigerants may be used only in
refrigerators or freezers or combination refrigerator and freezers that meet all requirements listed in the 10th edition of
Underwriters Laboratory (UL) Standard
250. In cases where the final rule includes
requirements more stringent than those of
the 10th edition of UL Standard 250, the
appliance must meet the requirements of
the final rule in place of the requirements
in the UL Standard;
4. The refrigerator, freezer, or combination
refrigerator and freezer must have red,
Pantone Matching System (PMS) #185
marked pipes, hoses, or other devices
through which the refrigerant passes to indicate the use of a flammable refrigerant.
This color must be applied at all service
ports and where service puncturing or otherwise creating an opening from the refrigerant circuit to the atmosphere might
be expected and must extend a minimum
of one (1) inch in both directions from
such locations;
HCR–188C1 as a
substitute for CFC–
12 and HCFC–22.
Use conditions
16:19 May 07, 2010
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10MYP1
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Federal Register / Vol. 75, No. 89 / Monday, May 10, 2010 / Proposed Rules
SUBSTITUTES THAT ARE ACCEPTABLE SUBJECT TO USE CONDITIONS—Continued
End use
Substitute
Household refrigerators and freezers
and combination refrigerators and
freezers.
Isobutane, R–600a,
as a substitute for
CFC–12 and
HCFC–22.
New Only ...................
Decision
Use conditions
Acceptable With Use
Conditions.
6. Household refrigerators, freezers, and
combination refrigerator and freezers
using these refrigerants must have service
aperture fittings that are colored red as
described above in use condition number
four and which differ from fittings used in
equipment or containers using non-flammable refrigerant. ‘‘Differ’’ means that either the diameter must differ by at least 1/
16 inch or the thread direction must be reversed (i.e., right handed vs. left handed).
The unique fittings must be permanently
affixed to the unit and may not be
accessed with an adaptor until the end-oflife of the unit;
HCR–188C as a substitute for CFC–12
and HCFC–22.
HCR–188C1 as a
substitute for CFC–
12 and HCFC–22.
Retail Food Refrigeration (stand-alone
only).
Propane, R–290, as a
substitute for CFC–
12 and HCFC–22.
Acceptable subject to
use conditions.
New Only ...................
7. These refrigerants may not be sold for
use as a refrigerant in containers designed to contain less than five pounds
(2.8 kg) of refrigerant.
1. The charge size for the retail food refrigerator or freezer using R–290 shall not
exceed 150 grams (5.3 ounces);
2. This refrigerant may be used only in new
equipment specifically designed and clearly identified for the refrigerant;
3. This substitute may only be used in
equipment that meets all requirements in
the 9th edition of UL Standard 471. In
cases where the final rule includes requirements more stringent than those of
the 9th edition of UL Standard 471, the
appliance must meet the requirements of
the final rule in place of the requirements
in the UL Standard;
4. The refrigerator or freezer must have red,
Pantone Matching System (PMS) #185
marked pipes, hoses, and other devices
through which the refrigerant passes to indicate the use of a flammable refrigerant.
This color must be applied at all service
ports and where service puncturing or otherwise creating an opening from the refrigerant circuit to the atmosphere might
be expected, and must extend a minimum
of one (1) inch in both directions from
such locations;
mstockstill on DSKH9S0YB1PROD with PROPOSALS
Retail Food Refrigeration (stand-alone
only).
Propane, R–290, as a
substitute for CFC–
12 and HCFC–22.
Acceptable subject to
use conditions.
New Only ...................
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16:19 May 07, 2010
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PO 00000
Frm 00030
5. Similar to clauses SB6.1.2 to SB6.1.5 of
UL Standard 471, the following markings,
or the equivalent, shall be provided and
shall be permanent:
(a) ‘‘DANGER—Risk of Fire or Explosion.
Flammable Refrigerant Used. Do Not Use
Mechanical Devices To Defrost Refrigerator. Do Not Puncture Refrigerant Tubing.’’
(b) ‘‘DANGER—Risk of Fire or Explosion.
Flammable Refrigerant Used. To Be Repaired Only By Trained Service Personnel. Do Not Puncture Refrigerant Tubing.’’
Fmt 4702
Sfmt 4702
E:\FR\FM\10MYP1.SGM
Further information
Technicians and equipment manufactures
should wear appropriate personal protective equipment, including chemical goggles and protective gloves when handling
isobutane. Special care should be taken
to avoid contact with the skin since propane, like many refrigerants, can cause
freeze burns on the skin.
• A class B dry powder type fire extinguisher should be kept nearby.
• Proper ventilation should be maintained at
all times during the manufacture of equipment containing hydrocarbon refrigerant
through adherence to good manufacturing
practices as per 29 CFR 1910.110.13 If refrigerant levels in the air surrounding the
equipment rise above one-fourth of the
lower flammability limit,2 the space should
be evacuated and re-entry should only
occur after the space has been properly
ventilated.
• Technicians should only use spark proof
tools when working refrigerators and
freezers with R–290.
• Recovery equipment designed for flammable refrigerants should be used.
• Only technicians specifically trained in
handling flammable refrigerants should
service refrigerators and freezers containing these refrigerants. Technicians
should gain an understanding of minimizing the risk of fire and the steps to use
flammable refrigerants safely.
• In production facilities or other facilities
where large quantities of the refrigerant
would be stored, proper safety precautions should be in place to minimize
the risk of explosion. These facilities
should be equipped with proper ventilation
systems to minimize the risks of explosion
and should be properly designed and operated to reduce possible ignition sources.
• Room occupants should evacuate the
space immediately following the accidental release of this refrigerant.
10MYP1
Federal Register / Vol. 75, No. 89 / Monday, May 10, 2010 / Proposed Rules
25815
SUBSTITUTES THAT ARE ACCEPTABLE SUBJECT TO USE CONDITIONS—Continued
End use
Substitute
Retail Food Refrigeration (stand-alone
only) New Only.
Propane, R–290, as a
substitute for CFC–
12 and HCFC–22.
Decision
Acceptable subject to
use conditions.
Use conditions
Further information
(c) ‘‘CAUTION—Risk of Fire or Explosion.
Flammable Refrigerant Used. Consult Repair Manual/Owner’s Guide Before Attempting To Service This Product. All
Safety Precautions Must be Followed.’’
(d) ‘‘CAUTION—Risk of Fire or Explosion.
Dispose of Properly In Accordance With
Federal Or Local Regulations. Flammable
Refrigerant Used.’’
(e) ‘‘CAUTION—Risk of Fire or Explosion
Due To Puncture Of Refrigerant Tubing;
Follow Handling Instructions Carefully.
Flammable Refrigerant Used.’’ This marking shall be provided near all exposed refrigerant tubing.
The marking described in clause (a) above
shall be permanently attached on or near
any evaporators that can be contacted by
the consumer. The markings described in
clauses (b) and (c) above shall be located
near the machine compartment. The
marking described in clause (d) above
shall be permanently attached on the exterior of the refrigerator. The marking described in clause (e) above shall be permanently attached near any and all exposed refrigerant tubing. All of these
markings shall be in letters no less than
6.4 mm (1⁄4 inch) high.
7. Retail food refrigeration using R–290
must have fittings colored red as described above in use condition number
four and which differ from fittings used in
equipment or containers using non-flammable refrigerant. ‘‘Differ’’ means that either the diameter must differ by at least
1⁄16 inch or the thread direction must be
reversed (i.e., right handed vs. left handed). The unique fittings must be permanently affixed to the unit, and may not be
accessed with an adaptor, until the endof-life of the unit;
8. R–290 may not be sold as a refrigerant in
containers containing less than five
pounds (2.8 kg) of refrigerant.
Note: In accordance with the limitations provided in Section 310(a) of the Clean Air Act (42 U.S.C. 7610(a)), nothing in this table shall affect the Occupational Safety and Health Administrations’ authority to promulgate and enforce standards and other requirements under the Occupational Safety and Health Act of 1970 (29
U.S.C. 651 et seq.)
[FR Doc. 2010–10959 Filed 5–7–10; 8:45 am]
BILLING CODE 6560–50–P
DEPARTMENT OF TRANSPORTATION
Office of the Secretary
49 CFR Part 26
[Docket No. OST–2010–0118]
RIN 2105–AD75
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Disadvantaged Business Enterprise:
Program Improvements
AGENCY:
Office of the Secretary (OST),
DOT.
ACTION: Notice of proposed rulemaking
(NPRM).
SUMMARY: This notice of proposed
rulemaking (NPRM) would propose to
improve the administration of the
Disadvantaged Business Enterprise
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16:19 May 07, 2010
Jkt 220001
(DBE) program by increasing
accountability for recipients with
respect to good faith efforts to meet
overall goals, modifying and updating
certification requirements, adjusting the
personal net worth (PNW) threshold for
inflation, providing for expedited
interstate certification, adding
provisions to foster small business
participation and improve post-award
oversight, and addressing other issues.
DATES: Comments on this proposed rule
must be received by July 9, 2010.
ADDRESSES: You may submit comments
(identified by the agency name and DOT
Docket ID Number OST–2010–0118) by
any of the following methods:
• Federal eRulemaking Portal: Go to
https://www.regulations.gov and follow
the online instructions for submitting
comments.
• Mail: Docket Management Facility:
U.S. Department of Transportation, 1200
New Jersey Avenue, SE., West Building
PO 00000
Frm 00031
Fmt 4702
Sfmt 4702
Ground Floor, Room W12–140,
Washington, DC 20590–0001
• Hand Delivery or Courier: West
Building Ground Floor, Room W12–140,
1200 New Jersey Avenue, SE., between
9 a.m. and 5 p.m. ET, Monday through
Friday, except Federal holidays.
• Fax: 202–493–2251
Instructions: You must include the
agency name (Office of the Secretary,
DOT) and Docket number (OST–2010–
0118) for this notice at the beginning of
your comments. You should submit two
copies of your comments if you submit
them by mail or courier. Note that all
comments received will be posted
without change to https://
www.regulations.gov including any
personal information provided and will
be available to internet users. You may
review DOT’s complete Privacy Act
Statement in the Federal Register
published on April 11, 2000 (65 FR
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10MYP1
Agencies
[Federal Register Volume 75, Number 89 (Monday, May 10, 2010)]
[Proposed Rules]
[Pages 25799-25815]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: 2010-10959]
-----------------------------------------------------------------------
ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 82
[EPA-HQ-OAR-2009-0286; FRL-9147-9]
RIN 2060-AP54
Protection of Stratospheric Ozone: Listing of Substitutes for
Ozone-Depleting Substances--Hydrocarbon Refrigerants
AGENCY: Environmental Protection Agency, (EPA).
ACTION: Proposed rulemaking.
-----------------------------------------------------------------------
SUMMARY: Pursuant to the U.S. Environmental Protection Agency's
Significant New Alternatives Policy program, this action proposes to
list isobutane, propane, HCR-188C, and HCR-188C1 as ``acceptable,
subject to use conditions,'' as substitutes for chlorofluorocarbon
(CFC)-12, also referred to as R-12, CCl2F2 and
dichlorodifluoromethane and hydrochlorofluorocarbon (HCFC)-22, also
referred to as R-22, CHClF2, chlorodifluoromethane and
difluorochloromethane, in household refrigerators, freezers, and
combination refrigerator and freezers and commercial refrigeration
(retail food refrigerators and freezers--stand-alone units only).
DATES: Comments must be received on or before July 9, 2010, unless a
public hearing is requested. Comments must then be received on or
before July 26, 2010. Any party requesting a public hearing must notify
the contact listed below under FOR FURTHER INFORMATION CONTACT by 5
p.m. Eastern Daylight Time on May 20, 2010. If a hearing is held, it
will take place on May 25, 2010 in Washington, DC and further
information will be provided on EPA's Stratospheric Ozone World Wide
Web site at https://www.epa.gov/ozone/snap.
ADDRESSES: Submit your comments, identified by Docket ID No. EPA-HQ-
OAR-2009-0286, by one of the following methods:
https://www.regulations.gov. Follow the on-line
instructions for submitting comments.
E-mail: A-And-R-Docket@epa.gov.
Mail: Air and Radiation Docket, Environmental Protection
Agency, Mailcode 6102T, 1200 Pennsylvania Ave., NW., Washington, DC
20460, Attention Docket ID No. EPA-HQ-OAR-2009-0286.
Hand Delivery: EPA Docket Center, (EPA/DC) EPA West, Room
3334, 1301 Constitution Ave., NW., Washington, DC, Attention Docket ID
No. EPA-HQ-OAR-2009-0286. Such deliveries are only accepted during the
Docket's normal hours of operation, and special arrangements should be
made for deliveries of boxed information.
Instructions: Direct your comments to Docket ID No. EPA-HQ-OAR-
2009-0286. EPA's policy is that all comments received will be included
in the public docket without change and may be made available online at
https://www.regulations.gov, including any personal information
provided, unless the comment includes information claimed to be
Confidential Business Information (CBI) or other information whose
disclosure is restricted by statute. Do not submit information that you
consider to be CBI or otherwise protected through https://www.regulations.gov or e-mail. The www.regulations.gov Web sites is an
``anonymous access'' system, which means EPA will not know your
identity or contact information unless you provide it in the body of
your comment. If you send an e-mail comment directly to EPA without
going through www.regulations.gov, your e-mail address will be
automatically captured and included as part of the comment that is
placed in the public docket and made available on the Internet. If you
submit an electronic comment, EPA recommends that you include your name
and other contact information in the body of your comment and with any
disk or CD-ROM you submit. If EPA cannot read your comment due to
technical difficulties and cannot contact you for clarification, EPA
may not be
[[Page 25800]]
able to consider your comment. Electronic files should avoid the use of
special characters, any form of encryption, and be free of any defects
or viruses. For additional instructions on submitting comments, go to
Section I.B. of the SUPPLEMENTARY INFORMATION section of this document.
Docket: All documents in the docket are listed in the https://www.regulations.gov index. Although listed in the index, some
information is not publicly available, i.e., CBI or other information
whose disclosure is restricted by statute. Certain other material, such
as copyrighted material, is not placed on the Internet and will be
publicly available only in hard copy form. Publicly available docket
materials are available either electronically in https://www.regulations.gov or in hard copy at the Air and Radiation Docket,
EPA/DC, EPA West, Room 3334, 1301 Constitution Ave., NW., Washington,
DC. The Public Reading Room is open from 8:30 a.m. to 4:30 p.m., Monday
through Friday, excluding legal holidays. The telephone number for the
Public Reading Room is (202) 566-1744, and the telephone number for the
Air and Radiation Docket is (202) 566-1742.
FOR FURTHER INFORMATION CONTACT: Monica Shimamura, Stratospheric
Protection Division, Office of Atmospheric Programs, Mail Code 6205J,
Environmental Protection Agency, 1200 Pennsylvania Ave., NW.,
Washington, DC 20460; telephone number (202) 343-9337; fax number (202)
343-2362, e-mail address: shimamura.monica@epa.gov. Notices and
rulemakings under EPA's Significant New Alternatives Policy (SNAP)
program are available on EPA's Stratospheric Ozone World Wide Web site
at www.epa.gov/ozone/snap/regs.
SUPPLEMENTARY INFORMATION:
Table of Contents
I. General Information
A. Background
B. Does this action apply to me?
C. What should I consider as I prepare my comments for EPA?
D. What acronyms and abbreviations are used in the preamble?
II. How does the Significant New Alternatives Policy (SNAP) program
work?
A. What are the statutory requirements and authority for the
SNAP program?
B. What are EPA's regulation implementing section 612?
C. How do the regulations for the SNAP program work?
D. Where can I get additional information about the SNAP
program?
III. What substitutes for ozone-depleting substances in what end-
uses are considered in this rule?
A. What is EPA proposing in this action?
B. What are isobutane, propane, HCR-188C and HCR-188C1?
C. What end-uses are included in our proposed decision?
D. Where can I find the regulatory text for these proposed
listing decisions?
E. What does an acceptability determination with use conditions
for isobutane, propane, HCR-188C, and HCR-188C1 mean?
IV. What criteria did EPA consider in preparing this proposal?
A. Impacts on the Environment
B. Flammability and Fire Safety
C. Toxicity
V. Why is EPA proposing these specifics use conditions?
A. New Equipment Only; Not Intended for Use as a Retrofit
Alternative
B. Standards
C. Charge Size
D. Color-Coded Hoses and Piping
E. Labeling
F. Unique Fittings
G. Small Containers
VI. What recommendations does EPA have for safe use of hydrocarbon
refrigerants?
VII. What other options did EPA consider?
VIII. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory Planning and Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act (RFA)
D. Unfunded Mandates Reform Act
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation and Coordination With
Indian Tribal Governments
G. Executive Order 13045: Protection of Children From
Environmental Health and Safety Risks
H. Executive Order 13211: Actions That Significantly Affect
Energy Supply, Distribution, or Use
I. National Technology Transfer and Advancement Act
J. Executive Order 12898: Federal Actions to Address
Environmental Justice in Minority Populations and Low-Income
Populations
IX. References
I. General Information
A. Background
This rule pertains to four hydrocarbon refrigerants: isobutane,
propane and HCR-188C and HCR-188C1. Globally, hydrocarbon refrigerants
have been in use for over 10 years including in countries such as
Germany, the United Kingdom, Australia, and Japan. In Europe and Asia,
equipment manufactures have designed and tested household and
commercial refrigerators and freezers to account flammability and
safety concerns associated with using hydrocarbon refrigerants. Due to
the fact that hydrocarbon refrigerants have zero ozone depletion
potential (ODP) and very low global warming potential (GWP), many
companies are interested in using hydrocarbon refrigerants in the
United States (U.S.) as well. In this action EPA has received four SNAP
submissions for use of hydrocarbon refrigerants in household
refrigerators, freezers, combination refrigerator and freezers and
retail food refrigerators and freezers (stand-alone only).
B. Does this action apply to me?
This notice of proposed rulemaking (NPRM) would regulate the use of
four alternative refrigerants used in: Household refrigerators and
freezers and commercial refrigeration (retail food refrigeration--
stand-alone units only).\1\ Potentially entities that may wish to use
isobutane (R-600a), propane (R-290), HCR-188C, or HCR-188C1 in these
end-uses, include:
---------------------------------------------------------------------------
\1\ HCR-188C and HCR-188C1 submissions included window air
conditioners as an end use. EPA is acting on this end use in a
separate rule making.
Table 1--Potentially Regulated Entities by North American Industrial Classification System (NAICS) Code or
Subsector
----------------------------------------------------------------------------------------------------------------
NAICS code or
Category subsector Description of regulated entities
----------------------------------------------------------------------------------------------------------------
Industry.................................... 333415 Manufactures of refrigerators, freezers, and other
refrigerating or freezing equipment, electric or
other; heat pumps not elsewhere specified or
included (NESOI); and parts thereof.
Industry.................................... 443111 Appliance Stores: Household-type.
Industry.................................... 445120 Convenience Stores.
Industry.................................... 445110 Supermarkets and Other Grocery (except
Convenience) Stores.
Industry.................................... 722211 Limited-Service Restaurants.
Industry.................................... 238220 Plumbing, Heating, and Air Conditioning
Contractors.
[[Page 25801]]
Industry.................................... 811412 Appliance Repair and Maintenance.
Industry.................................... 541380 Environmental Testing Laboratories.
Industry.................................... 423620 Electrical and Electronic Appliance, Television,
and Radio Set Merchant Wholesalers.
Industry.................................... 423740 Refrigeration Equipment and Supplies Merchant
Wholesalers.
----------------------------------------------------------------------------------------------------------------
This table is not intended to be exhaustive, but rather a guide
regarding entities likely to use the substitute whose use is regulated
by this action. If you have any questions about whether this action
applies to a particular entity, consult the person listed in the
preceding section, FOR FURTHER INFORMATION CONTACT.
C. What should I consider as I prepare my comments for EPA?
1. Submitting Confidential Business Information (CBI).
Do not submit confidential information to EPA through
www.regulations.gov or e-mail. Clearly mark the part or all of the
information that you claim to be CBI. For CBI information in a disk or
CD-ROM that you mail to EPA, mark the outside of the disk or CD-ROM as
CBI and then identify electronically within the disk or CD-ROM the
specific information that is claimed as CBI. In addition to one
complete version of the comment that includes information claimed as
CBI, a copy of the comment that does not contain the information
claimed as CBI must be submitted for inclusion in the public docket.
Information marked as CBI will not be disclosed except in accordance
with procedures set forth in 40 Code of Federal Regulations (CFR) Part
2.
2. Tips for Preparing Your Comments.
When submitting comments, remember to:
Identify the rulemaking by docket number and other
identifying information (subject heading, Federal Register date, and
page number).
Follow directions--The agency may ask you to respond to
specific questions or organize comments by referencing a CFR part or
section number.
Explain why you agree or disagree; suggest alternatives
and substitute language for your requested changes.
Describe any assumptions and provide any technical
information and/or data that you used.
If you estimate potential costs or burdens, explain how
you arrived at your estimate in sufficient detail to allow for it to be
reproduced.
Provide specific examples to illustrate your concerns, and
suggest alternatives.
Explain your views as clearly as possible, avoiding the
use of profanity or personal threats.
Make sure to submit your comments by the comment period
deadline identified.
D. What acronyms and abbreviations are used in the preamble?
Below is a list of acronyms and abbreviations used in the preamble
of this NPRM.
ACH--air changes per hour
AEGL--Acute Exposure Guideline Level
ASHRAE--American Society of Heating, Refrigerating and Air-
Conditioning Engineers, Inc.
ANSI--American National Standards Institute
CAA--Clean Air Act
CAS Reg. No--Chemical Abstracts Service Registry Identification
Number
CBI--Confidential Business Information
CFC--chlorofluorocarbon
cfm--cubic feet per minute
CFR--Code of Federal Regulations
EPA--the United States Environmental Protection Agency
FR--Federal Register
GWP--global warming potential
HC--hydrocarbon
HCFC--hydrochlorofluorocarbon
HFC--hydroflurocarbon
ICF--ICF International, Inc.
IDLH--Immediately dangerous to life or health
ICR--Information Collection Request
LFL--lower flammability limit
mg/l--milligrams per liter
MSDS--Material Safety Data Sheet
NAICS--North American Industrial Classification System
NIOSH--the U.S. National Institute for Occupational Safety and
Health
NPRM--Notice of Proposed Rulemaking
OEM--original equipment manufacturer
ODP--ozone depletion potential
ODS--ozone-depleting substance
OMB--the United States Office of Management and Budget
OSHA--the United States Occupational Safety and Health
Administration
PELs --permissible exposure limits
ppm--parts per million
REL--Recommended exposure limit
RFA--Regulatory Flexibility Act
RfC--reference concentration
SNAP--Significant New Alternatives Policy
TSCA--Toxic Substances Control Act
TWA --time weighted average
UL--Underwriters Laboratories Inc.
VOC--volatile organic compound
II. How does the Significant New Alternatives Policy (SNAP) program
work?
A. What are the statutory requirements and authority for the SNAP
program?
Section 612 of the Clean Air Act (CAA) requires EPA to develop a
program for evaluating alternatives to ozone-depleting substances
(ODS). EPA refers to this program as the Significant New Alternatives
Policy (SNAP) program. The major provisions of section 612 are:
1. Rulemaking
Section 612(c) requires EPA to promulgate rules making it unlawful
to replace any class I (i.e., chlorofluorocarbon, halon, carbon
tetrachloride, methyl chloroform, methyl bromide, and
hydrobromofluorocarbon) or class II (i.e., hydrochlorofluorocarbon)
substance with any substitute that the Administrator determines may
present adverse effects to human health or the environment where the
Administrator has identified an alternative that (1) reduces the
overall risk to human health and the environment, and (2) is currently
or potentially available.
2. Listing of Unacceptable/Acceptable Substitutes
Section 612(c) requires EPA to publish a list of the substitutes
unacceptable for specific uses and to publish a corresponding list of
acceptable alternatives for specific uses. The list of acceptable
substitutes is found at https://www.epa.gov/Ozone/snap/lists/
and the lists of ``unacceptable'', ``acceptable subject to use
conditions'', and ``acceptable subject to narrowed use limits'' is
found at 40 CFR part 82 subpart G.
3. Petition Process
Section 612(d) grants the right to any person to petition EPA to
add a substance to, or delete a substance from, the lists published in
accordance with
[[Page 25802]]
section 612(c). The Agency has 90 days to grant or deny a petition.
Where the Agency grants the petition, EPA must publish the revised
lists within an additional six months.
4. 90-Day Notification
Section 612(e) directs EPA to require any person who produces a
chemical substitute for a class I substance to notify the Agency not
less than 90 days before new or existing chemicals are introduced into
interstate commerce for significant new uses as substitutes for a class
I substance. The producer must also provide the Agency with the
producer's unpublished health and safety studies on such substitutes.
5. Outreach
Section 612(b)(1) states that the Administrator shall seek to
maximize the use of Federal research facilities and resources to assist
users of class I and II substances in identifying and developing
alternatives to the use of such substances in key commercial
applications.
6. Clearinghouse
Section 612(b)(4) requires the Agency to set up a public
clearinghouse of alternative chemicals, product substitutes, and
alternative manufacturing processes that are available for products and
manufacturing processes which use class I and II substances.
B. What are EPA's regulations implementing section 612?
On March 18, 1994, EPA published the original rulemaking (59 FR
13044) which established the process for administering the SNAP program
and issued EPA's first lists identifying acceptable and unacceptable
substitutes in the major industrial use sectors (40 CFR part 82,
subpart G). These sectors include: Refrigeration and air conditioning;
foam blowing; cleaning solvents; fire suppression and explosion
protection; sterilants; aerosols; adhesives, coatings and inks; and
tobacco expansion. These sectors compose the principal industrial
sectors that historically consumed the largest volumes of ODS.
Section 612 of the CAA requires EPA to ensure that substitutes
found acceptable do not prevent a significantly greater risk to human
health and the environment as compared with other substitutes that are
currently or potentially available.
C. How do the regulations for the SNAP program work?
Under the SNAP regulations, anyone who plans to market or produce a
substitute for class I or II ODS in one of the eight major industrial
use sectors must provide the Agency with health and safety studies on
the substitute at least 90 days before introducing it into interstate
commerce for significant new use as an alternative. This requirement
applies to the person planning to introduce the substitute into
interstate commerce,\2\ typically chemical manufacturers, but may also
include importers, formulators, equipment manufacturers, or end-users
\3\ when they are responsible for introducing a substitute into
commerce. In this proposed rule we are addressing SNAP submissions from
three companies interested in introducing into interstate commerce
products that contain hydrocarbon refrigerants.
---------------------------------------------------------------------------
\2\ As defined at 40 CFR 82.104 ``interstate commerce'' means
the distribution or transportation of any product between one state,
territory, possession or the District of Columbia, and another
state, territory, possession or the District of Columbia, or the
sale, use or manufacture of any product in more than one state,
territory, possession or District of Columbia. The entry points for
which a product is introduced into interstate commerce are the
release of a product from the facility in which the product was
manufactured, the entry into a warehouse from which the domestic
manufacturer releases the product for sale or distribution, and at
the site of United States Customs clearance.
\3\ As defined at 40 CFR 82.17 ``end-use'' means processes or
classes of specific applications within major industrial sectors
where a substitute is used to replace an ozone-depleting substance.
---------------------------------------------------------------------------
The Agency has identified four possible decision categories for
substitutes: Acceptable; acceptable subject to use conditions;
acceptable subject to narrowed use limits; and unacceptable. Use
conditions and narrowed use limits are both considered ``use
restrictions'' and are explained below. Substitutes that are deemed
acceptable with no use restrictions (no use conditions or narrowed use
limits) can be used for all applications within the relevant end-uses
within the sector. Substitutes that are acceptable subject to use
restrictions may be used only in accordance with those restrictions. It
is illegal to replace an ODS with a substitute listed as unacceptable,
unless certain exceptions (e.g. test marketing, research and
development) provided by the regulation are met.
After reviewing a substitute, the Agency may make a determination
that a substitute is acceptable only if certain conditions in the way
that the substitute is used are met to minimize risks to human health
and the environment. EPA describes such substitutes as ``acceptable
subject to use conditions.'' Entities that use these substitutes
without meeting the associated use conditions are in violation of
section 612 of the Clean Air Act.
For some substitutes, the Agency may permit a narrowed range of use
within an end-use or sector. For example, the Agency may limit the use
of a substitute to certain end-uses or specific applications within an
industry sector. The Agency requires a user of a narrowed use
substitute to demonstrate that no other acceptable substitutes are
available for their specific application by conducting comprehensive
studies. EPA describes these substitutes as ``acceptable subject to
narrowed use limits.'' A person using a substitute that is acceptable
subject to narrowed use limits in applications and end-uses that are
not consistent with the narrowed use limit, are using these substitutes
in an unacceptable manner and are in violation of section 612 of the
Clean Air Act.
The Agency publishes its SNAP program decisions in the Federal
Register (FR). EPA publishes decisions concerning substitutes that are
deemed acceptable subject to use restrictions (use conditions and/or
narrowed use limits), or for substitutes deemed unacceptable, as
proposed rulemakings to allow the public opportunity to comment, before
publishing final decisions.
In contrast, EPA publishes substitutes that are deemed acceptable
with no restrictions in ``notices of acceptability,'' rather than as
proposed and final rules. As described in the rule initially
implementing the SNAP program (59 FR 13044), EPA does not believe that
rulemaking procedures are necessary to list alternatives that are
acceptable without restrictions because such listings neither impose
any sanction nor prevent anyone from using a substitute.
Many SNAP listings include ``comments'' or ``further information''
to provide additional information on substitutes. Since this additional
information is not part of the regulatory decision, these statements
are not binding for use of the substitute under the SNAP program.
However, regulatory requirements so listed are binding under other
regulatory programs. The ``further information'' classification does
not necessarily include all other legal obligations pertaining to the
use of the substitute. While the items listed are not legally binding
under the SNAP program, EPA encourages users of substitutes to apply
all statements in the ``further information'' column in their use of
these substitutes. In many instances, the information simply refers to
sound operating practices that have
[[Page 25803]]
already been identified in existing industry and/or building-codes or
standards. Thus, many of the comments, if adopted, would not require
the affected user to make significant changes in existing operating
practices.
D. Where can I get additional information about the SNAP program?
For copies of the comprehensive SNAP lists of substitutes or
additional information on SNAP, refer to EPA's Ozone Depletion Web site
at https://www.epa.gov/ozone/snap/. For more information on
the Agency's process for administering the SNAP program or criteria for
evaluation of substitutes, refer to the SNAP final rulemaking published
March 18, 1994 (59 FR 13044), codified at 40 CFR part 82, subpart G. A
complete chronology of SNAP decisions and the appropriate citations are
found at https://www.epa.gov/ozone/snap/chron.html.
III. What substitutes for ozone-depleting substances in what end-uses
are considered in this rule?
A. What is EPA proposing in this action?
In this action, EPA proposes to list the following:
(1) Isobutane, also referred to by the American Society of Heating,
Refrigerating and Air Conditioning Engineers (ASHRAE) refrigerant
designation R-600a, and the proprietary hydrocarbon blends HCR-188C and
HCR-188C1, as acceptable subject to use conditions as a substitute for
CFC-12 \4\ in household refrigerators, freezers, and combination
refrigerator and freezers. EPA proposes the following use conditions:
---------------------------------------------------------------------------
\4\ CFC-12 is also referred to as R-12,
CCl2F2 and dichlorodifluoromethane. Its CAS
Reg. No. is 75-71-8.
---------------------------------------------------------------------------
1. The quantity of the substitute refrigerant (i.e., ``charge
size'') shall not exceed 57 grams (2.0 ounces) in any refrigerator,
freezer, or combination refrigerator and freezers;
2. These refrigerants may be used only in new equipment designed
specifically and clearly identified for the refrigerant (i.e., none of
these substitutes may be used as a conversion or ``retrofit''
refrigerant for existing equipment);
3. These refrigerants may be used only in refrigerators or freezers
or combination refrigerator and freezers that meet all requirements
listed in the 10th edition of Underwriters Laboratory (UL) Standard
250. In cases where the final rule includes requirements more stringent
than those of the 10th edition of UL Standard 250, the appliance must
meet the requirements of the final rule in place of the requirements in
the UL Standard;
4. The refrigerator, freezer, or combination refrigerator and
freezer must have red, Pantone Matching System (PMS) 185
marked pipes, hoses, or other devices through which the refrigerant
passes to indicate the use of a flammable refrigerant. This color must
be applied at all service ports and where service puncturing or
otherwise creating an opening from the refrigerant circuit to the
atmosphere might be expected and must extend a minimum of one (1) inch
in both directions from such locations;
5. Similar to clauses SA6.1.1 to SA6.1.2 of UL standard 250, the
following markings, or the equivalent, shall be provided and shall be
permanent:
(a) ``DANGER--Risk of Fire or Explosion. Flammable Refrigerant
Used. Do Not Use Mechanical Devices To Defrost Refrigerator. Do Not
Puncture Refrigerant Tubing.''
(b) ``DANGER--Risk of Fire or Explosion. Flammable Refrigerant
Used. Do Not Use Mechanical Devices. To Be Repaired Only By Trained
Service Personnel. Do Not Puncture Refrigerant Tubing.''
(c) ``CAUTION--Risk of Fire or Explosion. Flammable Refrigerant
Used. Consult Repair Manual/Owner's Guide Before Attempting To Service
This Product. All Safety Precautions Must be Followed.''
(d) ``CAUTION--Risk of Fire or Explosion. Dispose of Properly In
Accordance With Federal Or Local Regulations. Flammable Refrigerant
Used.''
(e) ``CAUTION--Risk of Fire or Explosion Due To Puncture Of
Refrigerant Tubing; Follow Handling Instructions Carefully. Flammable
Refrigerant Used.''
The marking described in clause (a) above shall be permanently
attached on or near any evaporators that can be contacted by the
consumer. The markings described in clauses (b) and (c) above shall be
permanently attached near the machine compartment. The markings
described in clause (d) above shall be permanently attached on the
exterior of the refrigerator. The marking described in clause (e) above
shall be permanently attached near any and all exposed refrigerant
tubing. All of these markings shall be in letters no less than 6.4 mm
(\1/4\ inch) high.
6. Household refrigerators, freezers, and combination refrigerator
and freezers using these refrigerants must have service aperture
fittings that are colored red as described above in use condition
number four and which differ from fittings used in equipment or
containers using non-flammable refrigerant. ``Differ'' means that
either that the diameter must differ by at least \1/16\ inch or the
thread direction must be reversed (i.e., right handed vs. left handed).
These different fittings must be permanently affixed to the unit and
may not be accessed with an adaptor until the end-of-life of the unit;
7. These refrigerants may not be sold for use as a refrigerant in
containers designed to contain less than five pounds (2.8 kg) of
refrigerant.
(2) Propane, R-290,\5\ as acceptable subject to use conditions as a
substitute for CFC-12, R-502, or HCFC-22, in retail food refrigerators
and freezers:
---------------------------------------------------------------------------
\5\ Propane is also known as R-290, HC-290,
CH3CH2CH3 and
C3H8. Its CAS Reg. No. is 74-98-6.
---------------------------------------------------------------------------
1. The charge size for the retail food refrigerator or freezer
using R-290 shall not exceed 150 grams (5.3 ounces);
2. This refrigerant may be used only in new equipment specifically
designed and clearly identified for the refrigerant;
3. This substitute may only be used in equipment that meets all
requirements in the 9th edition of UL Standard 471. In cases where the
final rule includes requirements more stringent than those of the 9th
edition of UL Standard 471, the appliance must meet the requirements of
the final rule in place of the requirements in the UL Standard;
4. The refrigerator or freezer must have red, Pantone Matching
System (PMS) 185 marked pipes, hoses, and other devices
through which the refrigerant passes to indicate the use of a flammable
refrigerant. This color must be applied at all service ports and where
service puncturing or otherwise creating an opening from the
refrigerant circuit to the atmosphere might be expected, and must
extend a minimum of one (1) inch in both directions from such
locations;
5. Similar to clauses SB6.1.2 to SB6.1.5 of UL Standard 471, the
following markings, or the equivalent, shall be provided and shall be
permanent:
(a) ``DANGER--Risk of Fire or Explosion. Flammable Refrigerant
Used. Do Not Use Mechanical Devices To Defrost Refrigerator. Do Not
Puncture Refrigerant Tubing.''
(b) ``DANGER--Risk of Fire or Explosion. Flammable Refrigerant
Used. To Be Repaired Only By Trained Service Personnel. Do Not Puncture
Refrigerant Tubing.''
(c) ``CAUTION--Risk of Fire or Explosion. Flammable Refrigerant
Used. Consult Repair Manual/Owner's Guide Before Attempting To Service
This
[[Page 25804]]
Product. All Safety Precautions Must be Followed.''
(d) ``CAUTION--Risk of Fire or Explosion. Dispose of Property In
Accordance With Federal Or Local Regulations. Flammable Refrigerant
Used.''
(e) ``CAUTION--Risk of Fire or Explosion Due To Puncture Of
Refrigerant Tubing; Follow Handling Instructions Carefully. Flammable
Refrigerant Used.'' This marking shall be provided near all exposed
refrigerant tubing.
The marking described in clause (a) above shall be permanently
attached or near any evaporators that can be contacted by the consumer.
The markings described in clauses (b) and (c) above shall be located
near the machine compartment. The marking described in clause (d) above
shall be permanently attached on the exterior of the refrigerator. The
marking described in clause (e) above shall be permanently attached
near any and all exposed refrigerant tubing. All of these markings
shall be in letters no less than 6.4 mm (\1/4\ inch) high.
6. Retail food refrigeration using R-290 must have fittings that
are colored red as described above in use condition number four and
which differ from fittings used in equipment or containers using non-
flammable refrigerant. ``Differ'' means that either the diameter must
differ by at least \1/16\ inch or the thread direction must be reversed
(i.e., right handed vs. left handed). These fittings must be
permanently affixed to the unit, and may not be accessed with an
adaptor, until the end-of-life of the unit;
7. R-290 may not be sold as a refrigerant in containers containing
less than five pounds (2.8 kg) of refrigerant.
B. What are isobutane, propane, HCR-188C, and HCR-188C1?
Hydrocarbons are flammable organic compounds made up of hydrogen
and carbon. Isobutane has four carbons while propane has three carbons.
HCR-188C and HCR-188C1 are proprietary blends consisting of primarily
or exclusively of hydrocarbons. The chemical formula for isobutane,
also called 2-methylpropane, is C4H10, also
written as CH(CH3)2-CH3 to distinguish
it from butane. Isobutane's identification number in the Chemical
Abstracts Service's registry (CAS Reg. No.) is 75-28-5. The chemical
formula for propane is C3H8 and its CAS Reg. No.
is 74-98-6. As refrigerants, propane and isobutane can be referred to
by the ASHRAE designations R-290 and R-600a, respectively.
ANSI/ASHRAE Standard 34-2007 categorizes isobutane, propane, and
components of HCR-188C and HCR-188C1 in the A3 Safety Group. ASHRAE's
safety group classification consists of two alphanumeric characters
(e.g., A2 or B1). The capital letter indicates the toxicity and the
numeral denotes the flammability. ASHRAE classifies Class A
refrigerants as refrigerants for which toxicity has not been identified
at concentrations less than or equal to 400 ppm by volume, based on
data used to determine threshold limit value-time-weighted average
(TLV-TWA) or consistent indices. Class B signifies refrigerants for
which there is evidence of toxicity at concentrations below 400 ppm by
volume, based on data used to determine TLV-TWA or consistent indices.
The refrigerants are then assigned a flammability classification from
one of three classes--1, 2, or 3 based on flammability. Tests are
conducted in accordance with ASTM E681 using a spark ignition source
(ASHRAE 2007). Figure 1 in ANSI/ASHRAE Standard 15-2007 uses the same
safety group but limits its concentration to 3400 ppm.
[GRAPHIC] [TIFF OMITTED] TP10MY10.026
C. What end-uses are included in our proposed decision?
1. Household Refrigerators, Freezers, and Combination Refrigerator and
Freezers
Household refrigerators, freezers, and combination refrigerator and
freezers are intended primarily for residential use, although they may
be used outside the home. Household freezers only offer storage space
at freezing temperatures, unlike household refrigerators. Products with
both a refrigerator and freezer in a single unit are most common. In
this NPRM, EPA is limiting the scope of our acceptability decisions to
refrigerators and freezers and combination refrigerator and freezers
with a refrigerant charge of 57 grams (2.0 ounces) or less.
2. Retail Food Refrigeration
Retail food refrigeration includes the refrigeration systems,
including cold storage cases, designed to chill food or keep it at a
cold temperature for commercial sale. For the purpose of this proposal
we are considering the use of hydrocarbons only in stand-alone
equipment. A stand-alone appliance is one utilizing a sealed hermetic
compressor and for which all refrigerant-containing components,
including but not limited to the compressor, condenser and evaporator,
are assembled into a single piece of equipment before delivery to the
ultimate consumer or user, such equipment not requiring the addition or
removal of refrigerant when placed into initial operation. Stand-alone
equipment is used to store chilled beverages or frozen products (e.g.,
reach-in beverage coolers and stand-
[[Page 25805]]
alone ice cream cabinets). This proposed decision does not apply to
large refrigeration systems such, as but not limited to, direct
expansion refrigeration systems typically found in retail food stores.
We are proposing as a use condition that stand-alone equipment using a
hydrocarbon refrigerant have a refrigerant charge less than 150 grams
(5.3 ounces).
D. Where Can I Find the Regulatory Text For These Proposed Listing
Decisions?
Our proposed decisions appear in a table at the end of the document
and if finalized will be codified at 40 CFR 82 subpart G. The proposed
regulatory text contains proposed listing decisions for the above end-
uses. EPA is proposing to find isobutane, propane, HCR-188C, and HCR-
188C1 acceptable with use conditions. We note that there may be other
legal obligations pertaining to the manufacture, use, handling, and
disposal of hydrocarbons that are not included in the information
listed in the tables (e.g., section 608 prohibition on venting
refrigerant or Department of Transport requirements for transport of
flammable gases).
E. What Does An Acceptability Determination With Use Conditions For
Isobutane, Propane, HCR-188C, and HCR-188C1 Mean?
In this action, EPA is proposing to find isobutane, propane, HCR-
188C, and HCR-188C1 acceptable subject to use conditions as substitutes
for CFC-12, HCFC-22, and R-502 in certain refrigeration end-uses. If
this proposal were to become final, it would be legal to use isobutane,
propane, HCR-188C, and HCR-188C1 in the specified types of equipment
under the conditions outlined above as a substitute for ozone-depleting
substances (ODS). If this proposal became final, use in the specified
types of equipment that is not consistent with the use conditions would
be a violation of CAA section 612 and EPA's implementing regulations.
EPA seeks comment regarding this proposal and, in particular,
whether the proposed use conditions are adequate to ensure the safe and
appropriate handling of hydrocarbon refrigerants.
IV. What criteria did EPA consider in preparing this proposal?
Section 612(c) of the Clean Air Act directs EPA to publish a list
of acceptable replacement substances (``substitutes'') for class I and
class II ODS, where the Administrator determines they are safe for
specific uses when compared with other currently or potentially
available substitutes, and a list of prohibited substitutes for
specific uses. EPA compares the risks to human health and the
environment of a substitute to the risks associated with other
substitutes that are currently or potentially available. EPA also
considers whether the substitute for class I and class II ODSs
``reduces the overall risk to human health and the environment''
compared to the ODSs historically used in the end use. The criteria for
review are listed at 40 CFR 82.180(a)(7). These criteria are (i)
atmospheric effects and related health and environmental impacts; (ii)
General population risks from ambient exposure to compounds with direct
toxicity and to increased ground-level ozone; (iii) Ecosystem risks;
(iv) Occupational risks; (v) Consumer risks; (vi) Flammability; and
(vii) Cost and availability of the substitute.
EPA evaluated each of the criteria separately and then considered
overall risk to human health and the environment in comparison to other
available or potentially available alternatives in the same end-uses.
EPA proposes to conclude that, overall, environmental risks posed by
the four reviewed substitutes were not greater than the environmental
risks posed by other substitutes in the reviewed end-uses. Because
these four substitutes have zero ozone depletion potential (ODP), very
low global warming potential (GWP), and are volatile organic compounds
(VOCs) but insignificantly affect local air quality, the environmental
risks associated with ODP GWP, and VOC effects are lower than or
comparable to other acceptable substitutes. These and other
environmental risks are discussed below. In addition, EPA has placed in
the docket an analysis table comparing the four substitutes being
proposed in this action and several substitutes that have been found
acceptable in the refrigeration and air conditioning end use. The
flammability risks to public health are of concern because household
and retail food refrigerators and freezers have traditionally used
refrigerants that are not flammable. Without mitigation, the risks
posed by these refrigerants would be higher than other non-flammable
refrigerants because individuals may not be aware that their actions
could potentially cause a fire, and existing equipment has not been
designed specifically to minimize flammable risks. Therefore, EPA is
proposing use conditions to mitigate these risks to ensure that the
overall risk to human health and the environment posed by these four
substitutes is not greater than the overall risk posed by other
substitutes in the same end use.
A. Impacts on the ecosystem
This section will include the substitutes' impact on the
environment including ODP, GWP, and VOC. The ODP is the ratio of the
impact on stratospheric ozone of a chemical compared to the impact of
an identical mass of CFC-11. Thus, the ODP of CFC-11 is defined to be
one (1.0). Other CFCs and HCFCs have ODPs that range from 0.01 to one
(1.0). All four refrigerant substitutes in this proposal have an ODP of
zero,\6\ lower than the ODP of the substances that they would replace:
CFC-12 (ODP = 1.0); HCFC-22 (ODP = 0.055); and R-502 (ODP = 0.334)
(WMO, 2006). The most commonly used substitutes in these two end-uses
also have an ODP of zero (e.g. R-404A, R-134a, R-410A, R-407C).
---------------------------------------------------------------------------
\6\ CFCs and HCFCs are examples of ozone-depleting compounds
unlike HCs which contain no chlorine. CFCs and HCFCs bring chlorine
to the stratosphere, which cause depletion of the ozone layer.
---------------------------------------------------------------------------
The GWP index is a means of quantifying the potential integrated
climate forcing of various greenhouse gases relative to carbon dioxide.
The 100-year integrated GWPs of isobutane, propane, HCR-188C, and HCR-
188C1 are estimated to be eight, three, less than five, and less than
five, respectively, compared to a value of one for CO2 (WMO,
2006). These are significantly lower than the 100-year integrated GWPs
of the substances that they would be replacing: CFC-12 (GWP = 10,890);
HCFC-22 (GWP = 1,810); and R-502 (GWP = 4,660) (WMO, 2006). The GWPs
for hydrocarbons (including the four being reviewed here) are minimal
and are significantly lower than those of other acceptable refrigerants
in these end-uses (e.g. GWPs of R-134a, R-404A, R-407C, and R-410A are
about 1430, 3920, 1770, and 2090, respectively).
The greenhouse gas (GHG) impacts of these refrigerants also depend
upon the energy use by appliances, since the ``indirect'' GHG emissions
associated with electricity consumption typically exceed those from
refrigerants over the full lifecycle of refrigerant-containing
products. (Citation: J. Sand, S. Fischer, and V. Baxter, ``Energy and
Global Warming Impacts of HFC Refrigerants and Emerging Technologies,''
1997, Oak Ridge National Lab) If hydrocarbon-using appliances are less
energy efficient than the appliances they replace, then it is possible
that these appliances will result in higher lifecycle greenhouse gas
emissions even if refrigerant emissions are lower. Conversely, higher
energy efficiency of these appliances would lead to lower GHG emissions
than the reduction from
[[Page 25806]]
refrigerants alone. We have not quantified the full lifecycle GHG
emissions associated with substituting traditional ODS refrigerants
with hydrocarbons but acknowledge that they also depend on the
appliance's electricity consumption and the fuel used to generate that
electricity.
Hydrocarbons are VOCs under CAA regulations addressing the
development of State Implementation Plans to attain and maintain
National Ambient Air Quality Standards for ground-level ozone, which is
a respiratory irritant (see 40 CFR 51.100(s)). Potential emissions of
VOCs from all substitutes for all end-uses in the refrigeration and air
conditioning sector are estimated to be insignificant relative to VOCs
from all other sources (i.e., other industries, mobile sources, and
biogenic sources) (ICF, May 22, 2009, May 26, 2009, and July 17, 2009).
B. Flammability and Fire Safety
Due to their flammable nature, isobutane, propane, HCR-188C, and
HCR-188C1 could pose a significant safety concern for workers and
consumers if they are not handled correctly. In the presence of an
ignition source (e.g., static electricity spark resulting from closing
a door, using a torch during service, or a short circuit in wiring that
controls the motor of a compressor), an explosion or a fire could occur
when the concentration of isobutane, propane, HCR-188C or HCR-188C1
exceeds its lower flammability limit \7\ (LFL) of 18,000 ppm, 21,000
ppm, 20,000 ppm, or 16,000 ppm, respectively. Therefore, in order for
these substitutes to be used safely, it is important to minimize the
presence of potential ignition sources and to reduce the likelihood
that the levels of isobutane, propane, HCR-188C, or HCR-188C1 will
exceed the LFL. In production facilities or other facilities where
large quantities of the refrigerant would be stored, proper safety
precautions should be in place to minimize the risk of explosion. EPA
recommends these facilities be equipped with proper ventilation systems
to minimize the risks of explosion and should be properly designed to
reduce possible ignition sources. EPA also understands that these
hydrocarbon refrigerants will be used by original equipment
manufacturers (OEMs) in specifically redesigned refrigerators and
freezers.
---------------------------------------------------------------------------
\7\ Lower flammability limit (LFL) = Lower Flammability Limit,
the minimum concentration in air at which flame propagation occurs.
---------------------------------------------------------------------------
For all four hydrocarbon refrigerants considered in this proposal,
to determine whether flammability would be a concern for service and
manufacture personnel or for consumers, EPA conducted a reasonable
worst-case scenario analysis to model catastrophic release of the
refrigerant. The worst-case scenario analysis revealed that even if the
unit's full charge is emitted within one minute, none of these four
hydrocarbons reached the LFL (ICF, May 22, 2009, May 26, 2009, July 17,
2009, and November 6, 2009). However, as mentioned above, hydrocarbons
refrigerants are flammable and service and manufacture personnel or
consumers are not familiar with these refrigerator or freezer or
combination refrigerators and freezers containing a flammable
refrigerant; therefore, use conditions are necessary to create
awareness of a flammable refrigerant and ensure safe handling. Detailed
analysis of the modeling results are discussed below in the
``toxicity'' section of the preamble. EPA also reviewed the submitters'
detailed assessments of the probability of events that might create a
fire and engineering approaches to avoid sparking from the
refrigeration equipment.
C. Toxicity
In evaluating potential human health impacts of isobutane, propane,
HCR-188C, and HCR-188C1, EPA considered impacts both on exposed
manufacture personnel, store employees, technicians herein defined as
``worker,'' and on consumers. EPA investigated the risk of asphyxiation
and of exposure to toxic levels of refrigerant for a worst-case
scenario and a typical use scenario for isobutane, propane, HCR-188C,
and HCR-188C1. EPA believes that the use of any of these hydrocarbons
in the end-uses reviewed does not pose a significant risk of
asphyxiation or of exposure to toxic levels to workers or consumers.
EPA estimated the maximum time weighted average \8\ (TWA) exposure
for each exposure scenario and compared this value to relevant industry
and government exposure limits for isobutane, propane, HCR-188C, and
HCR-188C1 (including potential impurities in the substitutes). The
modeling results indicate that both the short-term (15-minute and 30-
minute) and long-term (8-hour) worker exposure concentrations at no
point are likely to exceed 2 percent (for isobutane), 50 percent (for
propane), 4 percent (for HCR-188C), or 2 percent (for HCR-188C1) of the
Occupational Safety and Health Administration (OSHA) permissible
exposure limit (PEL) and National Institute for Occupational Safety and
Health (NIOSH) recommended exposure limit (REL) of the component
refrigerants (for isobutane and propane) or the refrigerants components
for HCR-188C and HCR-188C1(ICF, 2009).
---------------------------------------------------------------------------
\8\ Time weighted average (TWA) = An allowable exposure
concentration averaged over a normal 8-hour workday or a 40-hour
workweek.
---------------------------------------------------------------------------
EPA performed a consumer exposure analysis that examined potential
catastrophic release of the substitute under a reasonable worst-case
scenario. Estimates for acute/short-term consumer exposures resulting
from catastrophic leakage of refrigerant from residential refrigerators
were examined. The analysis was undertaken to determine the 15-minute
and 30-minute TWA exposure levels for the substitute, which were then
compared to the standard toxicity limits to assess the risk to
consumers. However, the TWA values were conservative, as the analysis
did not consider opened windows, fans operating, conditioned airflow
(either heated or cooled), and other variables that would likely reduce
the levels to which individuals would be exposed.
This analysis assumed that 100 percent of the unit's charge would
be released during a time span of one minute, at which time the
concentration of refrigerant would peak and then steadily decline.
Refrigerant concentrations were modeled under two air change scenarios,
believed to represent the baseline of potential flow rates for a home,
assuming flow rates of 2.5 and 4.5 air changes per hour (ACH) (Sheldon
1989). The highest concentrations of the refrigerant occur in the lower
stratum of the room when assuming lower ventilation levels of 2.5 ACH.
Using a 2.5 ACH to calculate the TWA achieves a higher concentration
than using 4.5 ACH to calculate the TWA. Because EPA looked at the
worst case scenario it was only necessary to evaluate the TWA values
using 2.5 ACH as 4.5 ACH TWA values would be in the acceptable range if
the 2.5ACH TWA values were within the acceptable range.
OSHA (2004) states no toxic effects are reported with exposures to
isobutane below 18,000 ppm. Even under the very conservative
assumptions used in the consumer exposure modeling, both the estimated
15-minute and 30-minute consumer exposures to isobutane (5,025 ppm and
3,844 ppm, respectively) are much lower than 18,000 ppm, and thus
should not pose a toxicity threat.
EPA also evaluated the same scenario with HCR-188C and HCR-188C1.
The highest concentrations of HCR-188C and HCR-188C1 occur in the lower
[[Page 25807]]
stratum of the room when assuming lower ventilation levels of 2.5 ACH.
Even under the conservative assumptions used in the consumer exposure
modeling, both the estimated 15-minute and 30-minute consumer exposure
levels of HCR-188C and HCR-188C1 are at least 50 percent lower than the
30-minute acute exposure guideline level (AEGL)-1 values for the
individual components of the blend and thus should not pose a toxicity
threat.
To assess end-use exposures to propane, an Acute Exposure Guideline
Level (AEGL) was chosen as the most appropriate toxicological limit.
This limit is an emergency guideline for exposures to the general
population (including susceptible populations) and is not time-
weighted; it also considers the chemical's flammability in addition to
its toxicity. A time-weighted limit was deemed inappropriate for this
scenario because, due to the nature of a time-weighted calculation. As
TWA are exposure concentrations averaged over a normal eight (8) hour
work-day, it could allow a room occupant to be exposed to levels higher
than the limit for a brief period of time. This is a concern for
propane due to its flammability, as a higher exposure could approach
the chemical's lower flammability limit (LFL--propane has an LFL of
21,000 ppm).
The EPA develops a set of AEGL values for a chemical for five
exposure periods (10 and 30 minutes, 1 hour, 4 hours and 8 hours). For
each exposure period, three different AEGL values are developed to
address different levels of toxicological impacts. Of relevance for the
modeled scenario is the AEGL-1 (10,000 ppm), which is defined as: ``the
airborne concentration, expressed as parts per million or milligrams
per cubic meter (ppm or mg/m3) of a substance above which it is
predicted that the general population, including susceptible
individuals, could experience notable discomfort, irritation, or
certain asymptomatic nonsensory effects. However, the effects are not
disabling and are transient and reversible upon cessation of
exposure.'' While permanent toxicological effects are not expected up
to the AEGL-2 value (17,000 ppm for propane), this limit is not
relevant for this analysis because at that level, flammability would be
a greater concern.
EPA analyzed consumer and worker exposure to propane in commercial
food cabinets with a 150 gram charge size. The highest expected levels
of exposure for this end-use occur in the lower stratum of the room.
The result for propane is a 15-minute TWA of 10,414 ppm and a 30-minute
TWA of 7,963 ppm. The 10-minute (AEGL)-1 value for propane is 10,000
ppm.\9\ Specifically, for propane at the end-use, the modeled 15-minute
time-weighted average exposure is 10,414 ppm (for practical purposes,
there is no difference toxicologically speaking between this value and
10,000 ppm (the AEGL-1 value), especially as this is a modeled
concentration and is based on a worst-case scenario). As this exposure
concentration is marginally higher than the AEGL-1 and significantly
lower than the AEGL-2, serious or permanent toxicological effects are
not expected for room occupants at the end-use. Therefore, it is
believed that even under the very conservative assumptions used in this
model, exposures to propane should not pose a toxicity threat. As the
AEGL is an emergency guideline, and flammability is a concern for this
chemical, it is recommended that room occupants should evacuate the
space immediately following the accidental release of this refrigerant.
As our submitters have stated an accidental release would be caused
during service and maintenance therefore the service technicians would
know to evacuate. For further information regarding accidental releases
or fault tree analyses see the docket number EPA-HQ-OAR-2009-0286.
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\9\ https://www.epa.gov/opptintr/aegl/pubs/results96.htm EPA Web
site accessed August 17, 2009.
---------------------------------------------------------------------------
V. Why is EPA proposing these specific use conditions?
EPA is proposing to find isobutane, HCR-188C, and HCR-188C1
acceptable with use conditions in new household refrigerators and
freezers and combination refrigerator and freezers (with a charge of 57
grams (2.0 ounces) or less) and propane acceptable with use conditions
in stand-alone retail food refrigerators and freezers (with a charge of
150 grams (5.3 ounces) or less) that are designed and manufactured
specifically to use these alternatives. The proposed listings with the
specific use conditions are intended to allow for the use of isobutane,
propane, HCR-188C, and HCR-188C1 where the current evidence shows that
they can be used safely within specified parameters. We also seek
comment on the proposed listing as well as the specific use conditions
discussed below.
A. New Equipment Only; Not Intended for Use as a Retrofit Alternative
EPA is proposing that the four refrigerants considered in this
proposal must be used only in new equipment that has been designed and
manufactured specifically for use with the listed alternative
refrigerant, as follows:
Isobutane--household refrigerators, freezers, and
combination refrigerator and freezers;
Propane--retail food refrigeration (stand-alone only);
HCR-188C--household refrigerators and freezers and
combination refrigerator and freezers; and
HCR-188C1--household refrigerators and freezers and
combination refrigerator and freezers.
The four refrigerants were not submitted under the SNAP program to
be used in retrofitted equipment. Existing equipment designed for other
refrigerants may not be converted or retrofitted to use any of these
four hydrocarbon refrigerants. These substitutes may be used only in
new equipment that is designed to address concerns unique to flammable
refrigerants.
B. Standards
EPA is proposing the refrigerants may be used only in equipment
that meets all requirements in UL Standard 250 10th edition (for
isobutane, HCR-188C, and HCR-188C1 in household refrigerators and
freezers) or UL 471 9th edition (for propane in retail food equipment
specifically in stand-alone refrigeration and freezers).\10\ UL has
tested equipment for flammability risk in both household and retail
food refrigeration. Further, UL has developed acceptable safety
standards including requirements for construction, for markings, and
for performance tests concerning refrigerant leakage, ignition of
switching components, surface temperature of parts, and component
strength after being scratched.
---------------------------------------------------------------------------
\10\ EPA is referencing the UL Standard 250 Supplement SA;
``Requirements for Refrigerators and Freezers Employing a Flammable
Refrigerant in the Refrigerating System'', UL 250 10th edition (for
isobutane, HCR-188C, and HCR-188C1 in home refrigerators and
freezers) and UL 471 9th edition Supplement SB; ``Requirements for
Refrigerators and Freezers Employing a Flammable Refrigerant in the
Refrigerating System'' (for propane in commercial refrigerators and
freezers).
---------------------------------------------------------------------------
C. Charge Size
EPA is proposing a limitation on charge size for refrigerators and
freezers that reflects the UL 250 and UL 471 standards. EPA is
proposing a charge size not to exceed 57grams (2.0 ounces) for
household refrigerators and freezers and 150 grams (5.3 ounces) for
retail food refrigeration in stand-alone units. To place this in
comparison, EPA estimates the charge size of a disposable lighter is
equal to 30 grams (1.1
[[Page 25808]]
ounce).\11\ Therefore we estimate that charge size of household
refrigerators and freezers are equivalent to approximately two
disposable lighters while retail stand-alone refrigerators and freezers
are equivalent to approximately five disposable lighters or less. In
comparison, the household refrigerator and freezer and retail food
refrigerator charge size is significantly less than refillable butane
lighter fluid which contains 340 grams (12 ounces). The refrigerant
charge is smaller than the disposable propane fuel cylinders used for
camping which contains 468 grams (16.4 ounces).
---------------------------------------------------------------------------
\11\ Study conducted by Ben and Jerry's/Unilever on the weight
of butane contained in disposable lighters.
---------------------------------------------------------------------------
The UL 250 standard limits the amount of refrigerant that may leak
to 50 grams (1.8 ounces). EPA selected 57 grams (2.0 ounces) to allow
for up to 7 grams (0.2 ounces) of refrigerant charge that might be
solubilized in the oil (and assumed not to not leak or immediately
vaporize with the refrigerant in the case of a leak). UL standard 471
limits the amount leaked to 150 grams (5.3 ounces). Furthermore, the
charge size limit for propane (for retail food refrigeration) is in
line with the IEC 60335-2-89 standard for commercial appliances, which
has a charge size limit of 150 grams (5.3 ounces). EPA did not include
an additional 7grams (0.2 ounces) of refrigerant that would be
solubilized in the oil as we did in the household refrigerator and
freezers end use. This is because 157 grams (5.5 ounces) would be over
the international charge size standard for retail food refrigeration.
As the international household refrigerator and freezers standard's
charge size limit is 150 grams (5.3 ounces) larger than UL 250
standard, EPA's suggested charge size for household refrigerator and
freezers would be well below the international charge size limit. EPA
is taking comment on the charge size limit on both the household
refrigerator and freezers and retail food refrigeration end use.
D. Color-Coded Hoses and Piping
EPA proposes that equipment must have distinguishing color-coded
hoses and piping to indicate use of a flammable refrigerant. This will
help technicians immediately identify the use of a flammable
refrigerant, thereby potentially reducing the risk of using sparking
equipment or otherwise having an ignition source nearby. The air
conditioning and refrigeration industry currently uses distinguishing
colors as means for identifying different refrigerants. Likewise,
distinguishing coloring has been used elsewhere to indicate an unusual
and potentially dangerous situation, for example in the use of orange-
insulated wires in hybrid electric vehicles. EPA is proposing that all
such refrigerator tubing be colored red Pantone Matching System (PMS)
185 to match the red band displayed on the container of
flammable refrigerants under the Air Conditioning, Heating and
Refrigeration Institute (AHRI) Guideline ``N'' 2008, ``2008 Guideline
for Assignment of Refrigerant Container Colors.'' E