Mandatory Reporting of Greenhouse Gases: Additional Sources of Fluorinated GHGs, 18652-18723 [2010-6768]
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Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Part 98
[EPA–HQ–OAR–2009–0927; FRL–9130–7]
RIN 2060–AQ00
Mandatory Reporting of Greenhouse
Gases: Additional Sources of
Fluorinated GHGs
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AGENCY: Environmental Protection
Agency (EPA).
ACTION: Proposed rule.
SUMMARY: EPA is revising and
supplementing its initial proposed
actions to require reporting of
fluorinated greenhouse gas (fluorinated
GHG) emissions from certain source
categories. Specifically, EPA is revising
and supplementing its initial proposal
to require reporting of fluorinated GHG
emissions from electronics
manufacturing, production of
fluorinated gases, and use of electrical
transmission and distribution
equipment. EPA is also proposing to
require such reporting from
manufacture or refurbishment of
electrical equipment and import and
export of pre-charged equipment and
closed cell foams. This proposed rule
would not require control of greenhouse
gases; rather it would require only that
sources above certain threshold levels
monitor and report emissions.
DATES: Comments must be received on
or before June 11, 2010. There will be
a public hearing from 9 a.m. to 12 noon
on April 20, 2010 at 1310 L St., NW.,
Room 152, Washington, DC 20005.
ADDRESSES: Submit your comments,
identified by docket ID EPA–HQ–OAR–
2009–0927 by one of the following
methods:
• Federal eRulemaking Portal: https://
www.regulations.gov. Follow the online
instructions for submitting comments.
• E-mail:
GHGReportingFGHG@epa.gov.
• Fax: (202) 566–1741.
• Mail: EPA Docket Center, Attention
Docket OAR–2009–0927, Mail code
2822T, 1200 Pennsylvania Avenue,
NW., Washington, DC 20460.
• Hand/Courier Delivery: EPA Docket
Center, Public Reading Room, Room
3334, EPA West Building, Attention
Docket OAR–2009–0927, 1301
Constitution Avenue, NW., Washington,
DC 20004. Such deliveries are only
accepted during the Docket’s normal
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hours of operation, and special
arrangements should be made for
deliveries of boxed information.
Instructions: Direct your comments to
Docket ID No. EPA–HQ–OAR–2009–
0927. EPA’s policy is that all comments
received will be included in the public
docket without change and may be
made available online at https://
www.regulations.gov, including any
personal information provided, unless
the comment includes information
claimed to be CBI or other information
whose disclosure is restricted by statute.
Do not submit information that you
consider to be CBI or otherwise
protected through https://
www.regulations.gov or e-mail. The
https://www.regulations.gov Web site is
an ‘‘anonymous access’’ system, which
means EPA will not know your identity
or contact information unless you
provide it in the body of your comment.
If you send an e-mail comment directly
to EPA without going through https://
www.regulations.gov your e-mail
address will be automatically captured
and included as part of the comment
that is placed in the public docket and
made available on the Internet. If you
submit an electronic comment, EPA
recommends that you include your
name and other contact information in
the body of your comment and with any
disk or CD–ROM you submit. If EPA
cannot read your comment due to
technical difficulties and cannot contact
you for clarification, EPA may not be
able to consider your comment.
Electronic files should avoid the use of
special characters, any form of
encryption, and be free of any defects or
viruses.
Docket: All documents in the docket
are listed in the https://
www.regulations.gov index. Although
listed in the index, some information is
not publicly available, e.g., CBI or other
information whose disclosure is
restricted by statute. Certain other
material, such as copyrighted material,
will be publicly available only in hard
copy. Publicly available docket
materials are available either
electronically in https://
www.regulations.gov or in hard copy at
EPA’s Docket Center, Public Reading
Room, EPA West Building, Room 3334,
1301 Constitution Ave., NW.,
Washington, DC 20004. This Docket
Facility is open from 8:30 a.m. to 4:30
p.m., Monday through Friday, excluding
legal holidays. The telephone number
for the Public Reading Room is (202)
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566–1744, and the telephone number for
the Air Docket is (202) 566–1742.
FOR FURTHER INFORMATION CONTACT:
Carole Cook, Climate Change Division,
Office of Atmospheric Programs (MC–
6207J), Environmental Protection
Agency, 1200 Pennsylvania Ave., NW.,
Washington, DC 20460; telephone
number: (202) 343–9263; fax number:
(202) 343–2342; e-mail address:
GHGReportingRule@epa.gov. For
technical information contact the
Greenhouse Gas Reporting Rule e-mail:
ghgmrr@epa.gov. To obtain information
about the public hearings or to register
to speak at the hearings, please go to
https://www.epa.gov/climatechange/
emissions/ghgrulemaking.html.
SUPPLEMENTARY INFORMATION:
Additional Information on Submitting
Comments: To expedite review of your
comments by Agency staff, you are
encouraged to send a separate copy of
your comments, in addition to the copy
you submit to the official docket, to
Carole Cook, U.S. EPA, Office of
Atmospheric Programs, Climate Change
Division, Mail Code 6207–J,
Washington, DC 20460, telephone (202)
343–9263, e-mail
GHGReportingRule@epa.gov.
As indicated above, although EPA
previously proposed a version of some
parts of this rule, that proposal has not
become final. This proposal partly
supplements and partly replaces that
initial proposal. Comments on the
initial proposal will be considered only
to the extent they remain relevant. To
ensure that their comments on newly
proposed or re-proposed provisions are
considered, parties should submit or resubmit them at this time.
Regulated Entities. The Administrator
determined that this action is subject to
the provisions of Clean Air Act (CAA)
section 307(d). See CAA section
307(d)(1)(V) (the provisions of section
307(d) apply to ‘‘such other actions as
the Administrator may determine.’’).
This is a proposed regulation. If
finalized, these regulations would affect
owners or operators of electronics
manufacturing facilities, fluorinated gas
production facilities, electric power
systems, and electrical equipment
manufacturing facilities, as well as
importers and exporters of pre-charged
equipment and closed-cell foams.
Regulated categories and entities would
include those listed in Table 1 of this
preamble:
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TABLE 1—EXAMPLES OF AFFECTED ENTITIES BY CATEGORY
Category
NAICS
Electronics Manufacturing ................................................
Importers and Exporters of Pre-charged Equipment and
Closed-Cell Foams.
Table 1 of this preamble is not
intended to be exhaustive, but rather
provides a guide for readers regarding
facilities likely to be affected by this
action. Table 1 lists the types of
facilities that EPA is now aware could
be potentially affected by the reporting
requirements. Other types of facilities
and companies not listed in the table
could also be subject to reporting
requirements. To determine whether
you are affected by this action, you
should carefully examine the
applicability criteria found in 40 CFR
part 98, subpart A and the relevant
423730
Microcomputers manufacturing facilities.
Semiconductor, photovoltaic (solid-state) device manufacturing facilities.
LCD unit screens manufacturing facilities.
MEMS manufacturing facilities.
Industrial gases manufacturing facilities.
Electric bulk power transmission and control facilities.
Power transmission and distribution switchgear and specialty transformers
manufacturing facilities.
Air-conditioning equipment (except room units) merchant wholesalers.
333415
423620
443111
326150
335313
423610
Fluorinated GHG Production ............................................
Electrical Equipment Use .................................................
Electrical Equipment Manufacture or Refurbishment ......
334111
334413
334419
334419
325120
221121
33531
Examples of affected facilities
Air-conditioning equipment (except motor vehicle) manufacturing.
Air-conditioners, room, merchant wholesalers.
Household Appliance Stores.
Polyurethane foam products manufacturing.
Circuit breakers, power, manufacturing.
Circuit breakers merchant wholesalers.
criteria in the proposed subparts related
to electronics manufacturing facilities,
fluorinated gas production facilities,
electrical equipment use, electrical
equipment manufacturing or
refurbishment facilities, and importers
and exporters of pre-charged equipment
and closed-cell foams. If you have
questions regarding the applicability of
this action to a particular facility,
consult the person listed in the
preceding FOR FURTHER INFORMATION
CONTACT section.
Many facilities that would be affected
by the proposed rule have GHG
emissions from multiple source
categories listed in 40 CFR part 98 or in
this proposed rule. Table 2 of this
preamble has been developed as a guide
to help potential reporters in the source
categories subject to the proposed rule
identify the source categories (by
subpart) that they may need to (1)
consider in their facility applicability
determination, and/or (2) include in
their reporting. The table should only be
seen as a guide. Additional subparts in
40 CFR part 98 may be relevant for a
given reporter. Similarly, not all listed
subparts are relevant for all reporters.
TABLE 2—SOURCE CATEGORIES AND RELEVANT SUBPARTS
Source category (and main applicable subpart)
Subparts recommended for review to determine
applicability
Electricity Generation ...............................................................
Electronics Manufacturing ........................................................
Fluorinated GHG Production ....................................................
Electrical Equipment Use .........................................................
Imports and Exports of Fluorinated GHGs Inside Pre-charged
Equipment and Closed-Cell Foams.
Electrical Equipment Use.
General Stationary Fuel Combustion.
General Stationary Fuel Combustion. Suppliers of Industrial Greenhouse Gases.
General Stationary Fuel Combustion.
Suppliers of Industrial Greenhouse Gases.
Electrical Equipment Manufacture or Refurbishment ..............
Sulfur Hexafluoride and PFCs from Electrical Equipment Manufacture and Refurbishment.
General Stationary Fuel Combustion
Imports and Exports of Fluorinated GHGs Inside Pre-charged Equipment and
Closed-Cell Foams.
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Acronyms and Abbreviations. The
following acronyms and abbreviations
are used in this document.
ASTM American Society for Testing and
Materials
BAMM Best Available Monitoring Methods
CAA Clean Air Act
CARB California Air Resources Board
CBI confidential business information
CFC chlorofluorocarbon
CFR Code of Federal Regulations
CO2 carbon dioxide
CO2e CO2-equivalent
EIA Economic Impact Analysis
EO Executive Order
EPA U.S. Environmental Protection Agency
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FERC Federal Energy Regulatory
Commission
F–GHG fluorinated greenhouse gas
FTIR fourier transform infrared
(spectroscopy)
FID flame ionization detector
GC gas chromatography
GHG greenhouse gas
GWP global warming potential
HCFC hydrochlorofluorocarbon
HFC hydrofluorocarbon
HFE hydrofluoroether
HTF heat transfer fluid
ICR information collection request
IPCC Intergovernmental Panel on Climate
Change
kg kilograms
PO 00000
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LCD liquid crystal displays
MEMS microelectromechanical devices
MMTCO2e million metric tons carbon
dioxide equivalent
MRR mandatory greenhouse gas reporting
rule
MS mass spectrometry
N2O nitrous oxide
NACAA National Association of Clean Air
Agencies
NAICS North American Industry
Classification System
NERC North American Energy Reliability
Corporation
NESHAP National Emissions Standard for
Hazardous Air Pollutants
NF3 nitrogen trifluoride
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NMR nuclear magnetic resonance
NSPS New Source Performance Standards
OMB Office of Management and Budget
PFC perfluorocarbon
PSD Prevention of Significant Deterioration
PV photovoltaic cells
QA quality assurance
QA/QC quality assurance/quality control
R&D research and development
RFA Regulatory Flexibility Act
RGGI Regional Greenhouse Gas Initiative
RIA Regulatory Impact Analysis
SSM startup, shutdown, and malfunction
SF6 sulfur hexafluoride
TCR The Climate Registry
TSD technical support document
U.S. United States
UMRA Unfunded Mandates Reform Act of
1995
VOC volatile organic compound(s)
WCI Western Climate Initiative
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Table of Contents
I. Background
A. Organization of This Preamble
B. Background on the Proposed Rule
C. Legal Authority
D. Relationship to other Federal, State and
Regional Programs
II. Summary of and Rationale for the
Reporting, Recordkeeping and
Verification Requirements for Specific
Source Categories
A. Electronics Manufacturing
B. Fluorinated Gas Production
C. Electric Transmission and Distribution
Equipment Use
D. Imports and Exports of Fluorinated
GHGs inside pre-charged equipment and
closed-cell foams
E. Electrical Equipment Manufacture or
Refurbishment
F. Subpart A Revisions
III. Economic Impacts on the Rule
A. How were compliance costs estimated?
B. What are the costs of the rule?
C. What are the economic impacts of the
rule?
D. What are the impacts of the rule on
small businesses?
E. What are the benefits of the rule for
society?
IV. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory
Planning and Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act (RFA)
D. Unfunded Mandates Reform Act
(UMRA)
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation
and Coordination with Indian Tribal
Governments
G. Executive Order 13045: Protection of
Children from Environmental Health
Risks and Safety Risks
H. Executive Order 13211: Actions that
Significantly Affect Energy Supply,
Distribution, or Use
I. National Technology Transfer and
Advancement Act
J. Executive Order 12898: Federal Actions
to Address Environmental Justice in
Minority Populations and Low-Income
Populations
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I. Background
A. Organization of This Preamble
This preamble is broken into several
large sections, as detailed above in the
Table of Contents. The paragraphs
below describe the layout of the
preamble and provide a brief summary
of each section.
The first section of this preamble
contains the basic background
information about the origin of this
proposed rule, including a brief
discussion of the initial proposed
requirements for electronics, fluorinated
gas production, and use of electrical
transmission and distribution
equipment. This section also discusses
EPA’s use of our legal authority under
the CAA to collect the proposed data,
and the benefits of collecting the data.
The second section of this preamble
provides a brief summary of, and
rationale for, the key design elements on
which EPA is seeking comment today
for each subpart. Depending on the
subpart, this section may include EPA’s
rationale for (i) the definition of the
source category, (ii) selection of
reporting threshold, (iii) selection of
proposed reporting and monitoring
methods, (iv) selection of procedures for
estimating missing data, (v) selection of
data reporting requirements, and (vi)
selection of records that must be
retained. EPA describes the proposed
options for each design element, as well
as the other options considered.
Throughout this discussion, EPA
highlights specific issues on which we
solicit comment. Please refer to the
specific source category of interest for
more details.
The third section provides the
summary of the cost impacts, economic
impacts, and benefits of this proposed
rule from the Economic Analysis.
Finally, the last section discusses the
various statutory and executive order
requirements applicable to this
proposed rulemaking.
B. Background on the Proposed Rule
The Final Mandatory GHG Reporting
Rule (Final MRR), (40 CFR part 98) was
signed by EPA Administrator Lisa
Jackson on September 22, 2009 and
published in the Federal Register on
October 30, 2009 (74 FR 56260). The
Final MRR, which became effective on
December 29, 2009, included reporting
of GHGs from the facilities and
suppliers that EPA determined should
be included to appropriately respond to
the direction in the 2008 Consolidated
Appropriations Act.1 These source
1 Consolidated Appropriations Act, 2008, Public
Law 110–161, 121 Stat. 1844, 2128.
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categories capture approximately 85
percent of U.S. GHG emissions through
reporting by direct emitters as well as
suppliers of fossil fuels and industrial
gases.
In the April 2009 proposed mandatory
GHG reporting rule, the electronics,
fluorinated GHG production, and
electrical equipment use source
categories were included as subparts I,
L, and DD. In addition, EPA requested
comment on requiring reporting under
subpart OO of the quantities of
fluorinated GHGs imported and
exported inside pre-charged equipment
and foams. EPA received a number of
lengthy, detailed comments regarding
proposed subparts I and L, several
comments regarding the definition of
‘‘facility’’ under subpart DD, and several
comments regarding a reporting
requirement for imports and exports of
fluorinated GHGs contained inside precharged equipment and foams. These
comments, which are described in more
detail in the discussions of the
individual source categories below,
raised concerns about the costs and
technical feasibility of implementing
subparts I and L as initially proposed,
requested clarification of how ‘‘facility’’
should be interpreted under subpart DD,
and both favored and opposed a
requirement to report imports of
fluorinated GHGs contained in imported
and exported pre-charged equipment
and closed-cell foams.
EPA recognized the concerns raised
by stakeholders, and decided not to
finalize subparts I, L, and DD with the
Final MRR, but instead to re-propose
significant pieces of these subparts. For
subparts I and L this proposal
incorporates a number of changes
including, but not limited to, the
addition of different methodologies that
provide improved emissions coverage at
a lower cost burden to facilities as
compared to the initial proposal. Where
aspects of the initial proposals for
subparts I and L are retained in this
proposal, such as in the basic massbalance methodology for subpart L (as
an option for some facilities) and in
many of the equations for subpart I,
today’s proposal adds more flexibility in
how and how frequently the underlying
data are gathered. In addition, EPA is
proposing requirements to report
emissions from manufacture or
refurbishment of electrical equipment
and to report the quantities of
fluorinated GHGs imported and
exported inside pre-charged equipment
and foams.
We believe the monitoring approaches
proposed in this action, which combine
direct measurement and facility-specific
calculations, effectively balance
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accuracy and costs, and that they are
warranted even though the rule does not
contain any emissions reduction
requirements. As we stated in the Final
MRR, the data collected by the rule are
expected to be used in analyzing and
developing a range of potential CAA
GHG policies and programs. A
consistent and accurate data set is
crucial to serve this intended purpose.
Under this proposed rule, facilities
not already reporting but required to
report under this rule would begin data
collection in 2011 following the
methods outlined in the proposed rule
and would submit data to EPA by March
31, 2012. As is the case under the Final
MRR, facilities would have the option to
use Best Available Monitoring Methods
(BAMM) for the first quarter of the first
reporting year for the source categories
included in this proposed rule. Thus,
for these source categories, facilities
could use BAMM through March 31,
2011.
C. Legal Authority
EPA is proposing this rule under its
existing CAA authority, specifically
authorities provided in CAA section
114. As discussed further below and in
‘‘Mandatory Greenhouse Gas Reporting
Rule: EPA’s Response to Public
Comments, Legal Issues’’ (available in
EPA–HQ–OAR–2008–0508), EPA is not
citing the FY 2008 Consolidated
Appropriations Act as the statutory
basis for this action. While that law
required that EPA spend no less than
$3.5 million on a rule requiring the
mandatory reporting of GHG emissions,
it is the CAA, not the Appropriations
Act, that EPA is citing as the authority
to gather the information proposed by
this rule.
As stated in the Final MRR, CAA
section 114 provides EPA broad
authority to require the information
proposed by this rule because such data
would inform and are relevant to EPA’s
carrying out a wide variety of CAA
provisions. As discussed in the initial
proposed rule (74 FR 16448, April 10,
2009), CAA section 114(a)(1) authorizes
the Administrator to require emissions
sources, persons subject to the CAA, or
persons whom the Administrator
believes may have necessary
information to monitor and report
emissions and provide such other
information the Administrator requests
for the purposes of carrying out any
provision of the CAA. EPA notes that
while climate change legislation
approved by the U.S. House of
Representatives, and pending in the
U.S. Senate, would provide EPA
additional authority for a GHG registry
similar to this proposed rule, and would
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do so for purposes of that pending
legislation, this proposed rule is
authorized by, and the information
being gathered by this proposed rule is
relevant to implementing, the existing
CAA. EPA expects, however, that the
information collected by this proposed
rule would also prove useful to
legislative efforts to address GHG
emissions.
For further information about EPA’s
legal authority, see the proposed and
Final MRR.
D. Relationship to Other Federal, State
and Regional Programs
In developing this proposed rule, EPA
reviewed monitoring methods included
in international guidance (e.g.,
Intergovernmental Panel on Climate
Change), as well as Federal voluntary
programs (e.g., EPA PFC Reduction/
Climate Partnership for the
Semiconductor Industry and the U.S.
Department of Energy Voluntary
Reporting of Greenhouse Gases Program
(1605(b) of the Energy Policy Act),
corporate protocols (e.g., World
Resources Institute and World Business
Council for Sustainable Development
GHG Protocol) and industry guidance
(e.g., 2006 ISMI Guideline for
Environmental Characterization of
Semiconductor Process Equipment).
EPA also reviewed State reporting
programs (e.g., California and New
Mexico) and Regional partnerships (e.g.,
Regional Greenhouse Gas Initiative,
Western Climate Initiative, The Climate
Registry). These are important programs
that not only led the way in reporting
of GHG emissions before the Federal
government acted but also assist in
quantifying the GHG reductions
achieved by various policies. Many of
these programs collect different or
additional data as compared to this
proposed rule. For example, State
programs may establish lower
thresholds for reporting, request
information on areas not addressed in
EPA’s reporting rule, or include
different data elements to support other
programs (e.g., offsets). For further
discussion on the relationship of this
proposed rule to other programs, please
refer to the preamble to the Final MRR.
II. Summary of and Rationale for the
Reporting, Recordkeeping and
Verification Requirements for Specific
Source Categories
A. Electronics Manufacturing
1. Overview of Reporting Requirements
Electronics manufacturing includes,
but is not limited to, the manufacture of
semiconductors, liquid crystal displays
(LCDs), micro-electro-mechanical
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systems (MEMS), and photovoltaic cells
(PV). The electronics industry uses
multiple long-lived fluorinated
greenhouse gases (fluorinated GHGs)
such as perfluorocarbons (PFCs),
hydrofluorocarbons (HFCs), sulfur
hexafluoride (SF6), and nitrogen
trifluoride (NF3), as well as nitrous
oxide (N2O). This proposed rule would
apply to electronics manufacturing
facilities where emissions from
electronics manufacturing processes
such as plasma etching, chemical vapor
deposition, chamber cleaning, and heat
transfer fluid use as well as stationary
fuel combustion units equal or exceed
25,000 metric tons of CO2e per year.2 In
this action, we are proposing methods to
estimate emissions from cleaning and
etching for semiconductor, LCD, MEMS,
and PV manufacture and also methods
for estimating N2O emissions from
chemical vapor deposition and other
manufacturing processes such as
chamber cleaning. We are also clarifying
methods for estimating emissions from
heat transfer fluids. And lastly, we are
proposing methods for reporting
controlled emissions from abatement
systems.
2. Major Changes Since Initial Rule
Proposed
In the initial proposal for electronics
manufacturing, we included the
following provisions for reporting
emissions from electronics manufacture:
(1) A capacity-based threshold for
semiconductors, LCDs, and MEMS
facilities and an emissions-based
threshold for PV facilities; (2) methods
for estimating fluorinated GHG
emissions from etching and cleaning; (3)
methods for estimating N2O emissions
during etching and cleaning; (4)
methods for verifying destruction or
removal efficiency (DRE) of abatement
systems; and (5) methods for estimating
emissions from heat transfer fluids.
As noted in the preamble to the Final
MRR, we received a number of lengthy,
detailed comments regarding the
electronics manufacturing subpart. In
total, we received comments from
approximately 10 entities on the
proposed rule regarding electronics
manufacture. The commenters generally
opposed the proposed reporting
requirements for large semiconductor
facilities and stated that excessive
monitoring and reporting were required.
For example, commenters asserted that
they do not currently collect the data
required to report using an IPCC Tier 3
2 As discussed further below, EPA is proposing
that uncontrolled emissions be used for purposes of
determining whether a facility’s emissions are equal
to or greater than 25,000 mtCO2e.
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approach, and that to collect such data
would entail significant burden and
capital costs. In most cases, commenters
provided alternative approaches to each
of the reporting requirements.
We have carefully reviewed the
comments, issues, and suggestions
raised by stakeholders regarding
electronics manufacturing. In response,
we are revising our initial proposal and
are proposing the following reporting
provisions for electronics manufacture:
(1) A single emissions-based reporting
threshold for all semiconductor, LCD,
MEMS, and PV facilities; (2) modified
methods for estimating emissions from
cleaning and etching activities for
semiconductor facilities and other
electronics facilities including those
that manufacture LCDs, MEMS, and
PVs; (3) modified methods for
estimating facility N2O emissions; (4)
clarified methods for estimating
emissions from heat transfer fluids; and
(5) revised methods for reporting
controlled emissions from abatement
systems.
In the paragraphs below, we
summarize the main provisions
included in the initial proposal for
reporting emissions from electronics
manufacturing and we briefly
summarize the major changes that are
being proposed today. For more detailed
information on the initial proposal, see
the electronics manufacturing section of
EPA’s proposed MRR (74 FR 16448,
April 10, 2009).
Reporting Threshold. In the initial
proposal, we proposed a capacity-based
threshold, requiring those facilities with
emissions equal to or greater than the
thresholds to report their GHG
emissions. We proposed production
capacity-based thresholds of 1,080 m 2,
1,020 m 2, and 236,000 m 2 of substrate
for semiconductor, MEMS, and LCD
manufacturing facilities, respectively.
The capacity-based threshold proposed
were equivalent to 25,000 mtCO2e using
the IPCC 2006 Tier 1 default factors and
assumed no abatement. Where IPCC
2006 Tier 1 default emission factors
were unavailable (i.e., MEMS), the
emission factor was estimated based on
relevant IPCC Tier 1 emission factors for
semiconductor production. Due to a
lack of information on use and
emissions of fluorinated GHGs for PV
manufacture, we proposed an
emissions-based threshold of 25,000
mtCO2e for those facilities. We proposed
to use a capacity-based threshold based
on the published capacities of facilities,
as opposed to an emissions-based
threshold, where possible, because we
believed that it simplified the
applicability determination.
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Several commenters stated that the
proposed capacity-based threshold
created ambiguity. For example, one
commenter noted that it was unclear
how production capacity was defined as
actual manufacturing levels could
fluctuate year by year. In response to
these comments, we are now proposing
a single emissions-based threshold
equal to or greater than 25,000 metric
tons of CO2e per year for electronics
manufacturing facilities. We have
concluded that a single emissions-based
threshold will simplify the applicability
determination and that by applying the
method for determining whether the
threshold is met, a facility will be able
to quickly determine whether they must
report under this rule.
Estimating Emissions from Cleaning
and Etching Processes. With respect to
estimating emissions from chamber
cleaning and etching, in our initial
proposal, we outlined two different
methods; one method for relatively large
semiconductor facilities, and another
method for all other semiconductor
facilities and LCD, MEMS, and PV
facilities required to report. We defined
large semiconductor facilities as those
facilities with annual capacities of
greater than 10,500 m2 silicon
(equivalent to 29 out of 175 total
semiconductor manufacturing facilities).
For large semiconductor facilities we
proposed an approach based on the
IPCC Tier 3 method that required the
use of company-specific data for (1) gas
consumption, (2) gas utilization,3 (3) byproduct formation 4, and (4) DRE for all
emissions abatement processes at the
facility. As we stated in the initial
proposal, we had concluded that large
semiconductor facilities were already
using Tier 3 methods and/or had the
necessary data readily available either
in-house or from suppliers to apply the
highest Tier method. For smaller
semiconductor facilities and LCD,
MEMS, and PV facilities, we proposed
an approach based on the IPCC Tier 2b
method, which required using default
emission factors for process utilization,
by-product formation, and site-specific
DRE measurements.
3 For purposes of electronics manufacturing, we
are using the term ‘‘gas utilization’’ to describe the
fraction of input N2O or fluorinated GHG converted
to other substances during the etching, deposition,
and/or chamber/wafer cleaning processes. Gas
utilization is expressed as a rate or factor for
specific manufacturing processes. ‘‘Utilization’’
should not be confused with ‘‘use;’’ ‘‘use’’ refers to
gas consumption or the quantity of gas fed into
process at an electronics manufacturing facility.
4 For purposes of electronics manufacturing, ‘‘byproduct formation’’ is the quantity of fluorinated
GHGs created during electronics manufacturing
processes. Fluorinated GHG by-products may also
be formed by abatement devices.
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Comments received in response to our
initial proposal stated that the 2006
IPCC Tier 3 method would be overly
burdensome for semiconductor
manufacturers and that process-specific
emission factors do not exist for many
tools and processes. The commenters
noted that most semiconductor facilities
do not track gas consumption by tool or
process-type and that currently, only
one large semiconductor company uses
the Tier 3 method. Generally,
commenters requested the use of the
2006 IPCC Tier 2b method.
In response to these comments, we are
now proposing the use of a ‘‘Refined
Method’’ for estimating these emissions
from semiconductor facilities. Our
revised methodology includes a simpler
approach to estimating emissions from
cleaning and etching as compared to the
Tier 3 method that was initially
proposed for larger semiconductor
facilities. To this end, we estimate that
our proposed methodology will result in
a reduction in burden compared to the
Tier 3 method for those facilities
previously defined as large
semiconductor facilities, and an
improvement in accuracy of the
emissions estimate as compared to the
2006 IPCC Tier 2b method.
Furthermore, since we anticipate that all
semiconductor facilities already have, or
have ready access to, the information
required by this proposed methodology,
we are also proposing to require all
semiconductor facilities required to
report to estimate emissions using the
Refined Method. We have concluded
the method we are proposing is the most
appropriate method taking into account
both the cost to the reporter as well as
accuracy of emissions achieved.
For LCD, MEMS, and PV facilities, in
this action we are proposing to require
an approach based on a slightly
modified 2006 IPCC Tier 2b method
which would include (1) gas-and
facility-specific heel factors (consistent
with the requirements we are proposing
for semiconductor facilities), (2) gas
consumption apportioned to 2006 IPCC
Tier 2b process categories (i.e. clean and
etch), (3) default factors consistent with
the 2006 IPCC Tier 2b factors, and (4)
methods for reporting controlled
emissions from abatement systems (as
proposed below). The main difference
between the method proposed in this
revised proposal and in the initial
proposal is the addition of a gas-and
facility-specific heel factor to determine
overall gas consumption. We did not
receive any comments on the Tier 2b
method that we proposed for LCD,
MEMS, and PV facilities in our initial
proposal. We are proposing to add the
requirement of gas-and-facility specific
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heel factors based on comments
received from semiconductor facilities
in response to the initial proposal. It is
our understanding that LCD, MEMS,
and PV facilities have the data required
to develop a gas-and-facility specific
heel factors and that it can be
implemented with minimal burden.
Estimating Facility N2O Emissions. In
our initial proposal, our approach
required that facilities estimate annual
N2O emissions using a simple massbalance method. This method assumed
that all N2O consumed is emitted (i.e.,
not converted or destroyed). We also
requested comment on utilization
factors for N2O as well as on data on
N2O by-product formation.
In response to our initial proposal, we
received comments that clarified that
N2O is used primarily in the chemical
vapor deposition process. Commenters
opposed our proposed method for
estimating N2O emissions, which
assumed 100 percent N2O used is
emitted, and asserted that
semiconductor facilities should be
permitted to use measured N2O
emission factors where these factors
were measured using methods
consistent with the December 2006
International SEMATECH
Manufacturing Initiative’s Guideline for
Environmental Characterization of
Semiconductor Process Equipment
(2006 ISMI Guidelines). Commenters
also noted that facilities that have not
developed N2O emission factors should
be allowed to use a default emission
factor of 60 percent, reflecting N2O
utilization of 40 percent.5 Lastly,
commenters asserted that those
companies that have a measured DRE
for N2O abatement be allowed to apply
these DREs in the emission estimates.
We are now proposing two methods
for estimating N2O emissions from
electronics manufacturing: one for
estimating N2O emissions from
chemical vapor deposition and another
for estimating N2O emissions from all
other manufacturing processes such as
chamber cleaning.
Reporting Controlled Emissions From
Abatement Systems. The emissions
estimation method originally proposed
accounted for destruction by abatement
systems only if facilities verified the
performance of their systems using one
of two methods. In particular, we
proposed to require that the DRE be
verified by either (1) measurement by
the facility using the methods described
in EPA’s Protocol for Measuring
Destruction or Removal Efficiency of
Fluorinated Greenhouse Gas Abatement
Equipment in Electronics
Manufacturing (EPA’s DRE Protocol), or
(2) purchase by the facility of abatement
systems that were tested by a third party
using a standard protocol such as EPA’s
DRE Protocol.
We also proposed to require that
facilities use the systems within the
manufacturer’s specified system
lifetime, operate the system within the
manufacturer specific limits for the gas
mix and exhaust flow rate intended for
the fluorinated GHG destruction, and
maintain the equipment according to
the manufacturer’s guidelines.
In response to the initial proposal,
commenters were generally opposed to
EPA’s initial approach for measuring
DRE, noting that according to the
Results of the ISMI ESH Technology
Center Greenhouse Gas Facility Survey,
less than one percent of installed
abatement systems have been properly
tested using the draft EPA Protocol and
that generally, facilities use the IPCC
default factors or manufacturer-supplied
measurements. In addition, commenters
were also opposed to EPA’s proposed
requirement that facilities rely on
manufacturer-specified system lifetime
as properly maintained and serviced
abatement systems can last beyond the
manufactures’ specified lifetime. For
purposes of this reporting rule, we are
now proposing that facilities that wish
to document and report fluorinated
GHG and N2O emissions reflecting the
use of abatement systems adhere to a
method that would require (1)
documentation to certify that the
abatement device is installed, operated,
and maintained according to
manufacturers’ specifications, (2)
accounting for the system’s uptime, and
(3) either certification that the
abatement system is specifically
designed for fluorinated GHG and N2O
abatement and the use of EPA default
DRE value, or directly and properly
measured DRE (i.e., in accordance with
EPA DRE Protocol) confirming
abatement system’s performance.
Estimating Emissions from Heat
Transfer Fluids. To estimate the
emissions from heat transfer fluids we
proposed to require that electronics
manufacturers use the 2006 IPCC Tier 2
approach, which is based on a massbalance method. As we stated in the
initial proposal, the 2006 IPCC Tier 2
approach uses company-specific data
and accounts for differences among
5 The 40% utilization rate (60% emission factor)
was identified based on a survey of industry
facilities’ heat transfer fluids, leak rates,
and service practices.
In comments we received on our
initial proposal, it was noted that our
proposed method for estimating
emissions from heat transfer fluids
would require companies to compile a
detailed inventory of all fluorinated heat
transfer equipment and its nameplate
capacity. Comments stated that such a
mass balance approach would be overly
burdensome.
In evaluating these comments, we
believe that there was some confusion
regarding our intended method. As a
result, we are not changing the broad
outlines of our initial proposal, but we
are clarifying required data elements.
conducted by ISMI and provided in comments in
response to the initial proposal.
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3. Definition of the Source Category
The electronics industry uses
multiple long-lived fluorinated GHGs
such as PFCs, HFCs, SF6, and NF3, as
well as N2O, during manufacturing of
semiconductors, LCDs, MEMS, and PV.
We understand that there are other
electronics manufacturers such as those
facilities that manufacture light-emitting
diodes (LEDs) and disk readers that use
fluorinated GHGs in similar
manufacturing processes as
semiconductors. As a result, we are
seeking information on fluorinated GHG
and N2O emissions associated with the
manufacture of these products and also
comment on whether to include them as
part of the electronics manufacturing
source category. It is our intent to
include these other sources as part of
the electronics manufacturing source
category in the final rule where their
emissions meet or exceed our proposed
threshold of 25,000 mtCO2e.
Fluorinated GHGs are used for plasma
etching of silicon materials, cleaning
deposition tool chambers, and wafer
cleaning. N2O is also used in depositing
certain films and chamber cleaning.
Additionally, electronics manufacturing
employs fluorinated GHGs (typically
liquids at ambient temperature) as heat
transfer fluids. The most common
fluorinated GHGs in use for these
purposes are CHF3 (HFC–23), CF4, C2F6,
NF3, SF6 and FluorinertTM and Galden®
heat transfer fluids; other compounds
such as perfluoropropane (C3F8) and
perfluorocyclobutane (c-C4F8) are also
used in smaller quantities (EPA, 2008a).
Table 3 of this preamble presents
fluorinated GHGs typically used during
manufacture of electronics devices.
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TABLE 3—EXAMPLES OF FLUORINATED GHGS USED BY THE ELECTRONICS INDUSTRY
Product type
Fluorinated GHGs used during manufacture
Electronics (e.g., Semiconductor, MEMS, LCD, PV) ...............
CF4, C2F6, C3F8, c-C4F8, c-C4F8O, C4F6, C5F8, CHF3, CH2F2, NF3, SF6, and Heat
Transfer Fluids (CF3–(O–CF(CF3)–CF2)n-(O–CF2)m-O–CF3, CnF2n+2,
CnF2n+1(O)CmF2m+1, CnF2nO, (CnF2n+1)3N) a
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
a IPCC Guidelines do not specify the fluorinated GHGs used for MEMS production. Literature reviews revealed that among others CF , SF ,
4
6
and the Bosch process (consisting of alternating steps of SF6 and c-C4F8) are used to manufacture MEMS. For further information, see the Electronics Manufacturing TSD in the docket for this rulemaking (EPA–HQ–OAR–2009–0927).
Description of Electronics
Manufacturing Processes and Activities.
Fluorinated GHG and N2O emissions
result from the following electronics
processes and activities:
(1) Plasma etching;
(2) Chemical vapor deposition;
(3) Chamber cleaning;
(4) Wafer cleaning; and
(5) Heat transfer fluid use.
Plasma etching, essential to
fabricating intricate, nanometer size
features in contemporary electronic
devices, is the removal of solid material
from a substrate surface with gaseous
reactants, in plasma, to produce gaseous
products, which are then pumped away
and disposed. Unless abated, unreacted
fluorinated reactants or fluorinated GHG
by-products from etching are emitted
into the atmosphere.
Typical fluorinated GHG etching
reagents, used either individually or in
combination, are CF4, CHF3, C2F6 and
c–C4F8 for silicon dioxide and nitride
films; CF4, NF3 and SF6 for polysilicon
films; and CHF3 for aluminum and SF6
for tungsten films. A typical fluorinated
GHG by-product from etching processes
is CF4; in some instances C2F6 may also
be formed.
Deposition is a fundamental step in
the fabrication of a variety of electronic
devices. During deposition, layers of
dielectric, barrier, or electrically
conductive films are deposited or grown
on a wafer or other substrate. Chemical
vapor deposition enables the deposition
of dielectric or metal films. During the
chemical vapor deposition process,
gases that contain atoms of the material
to be deposited react on the wafer
surface to form a thin film of solid
material. Films deposited by chemical
vapor deposition may be silicon oxide,
single-layer crystal epitaxial silicon,
amorphous silicon, silicon nitride,
dielectric anti-reflective coatings, low k
dielectric, aluminum, titanium, titanium
nitride, polysilicon, tungsten, refractory
metals or silicides. Nitrous oxide may
be the oxidizer of choice during
deposition of silicon oxide films.
Chambers used for depositing
polysilicon, dielectric and metal films
are cleaned periodically using
fluorinated GHGs, N2O, and other gases.
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During the cleaning cycle, the gas is
converted to fluorine atoms in plasma,
which etches away residual siliconcontaining material from chamber walls,
electrodes, and chamber hardware.
Undissociated fluorinated gases and
other fluorinated and non-fluorinated
products pass from the chamber to
waste streams and, unless emissions
control systems are employed, into the
atmosphere.
Typical fluorinated GHGs used for
chamber cleaning are NF3, C2F6 and
C3F8. N2O may also be used to reduce
particle formation during chamber
cleaning. As with etching films,
fluorinated GHG by-products may be
formed during chamber cleaning,
typically CF4.
During wafer processing, any residual
photoresist material can be removed
through an ashing process, which
consists of placing partially processed
wafers in an oxygen plasma to which
CF4 may be added. The edges of wafers
(the bevel) may require additional
cleaning to remove yield-reducing
residual material. Bevel cleaning may
also use a plasma process with
fluorinated gas chemistry. In both of
these wafer cleaning processes, unused
fluorinated GHGs are emitted unless
abated.
Fluorinated GHG liquids (at ambient
temperature) such as fully fluorinated
linear, branched or cyclic alkanes,
ethers, tertiary amines and aminoethers,
and mixtures thereof are used as heat
transfer fluids at several semiconductor
facilities to cool process equipment,
control temperature during device
testing, and solder semiconductor
devices to circuit boards. The
fluorinated heat transfer fluid’s high
vapor pressures can lead to evaporative
losses during use.6
Our understanding is that heat
transfer fluids are widely used within
semiconductor manufacturing. We are
seeking comment on the extent of use
and annual replacement quantities of
heat transfer fluids in other electronics
sectors, such as their use for cooling or
cleaning during LCD manufacture.
6 Electronics Manufacturing TSD (EPA–HQ–
OAR–2009–0927); 2006 IPCC Guidelines.
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Total U.S. Emissions From Electronics
Manufacturing. Emissions of fluorinated
GHGs from 216 electronics facilities
were estimated to be 6.1 million metric
tons CO2e in 2006. Below is a
breakdown of emissions by electronics
product type.
Semiconductors. Emissions of
fluorinated GHGs, including heat
transfer fluids, from 175 semiconductor
facilities were estimated to be 5.9
million metric tons CO2e in 2006. Of the
total estimated semiconductor
emissions, 5.4 million metric tons CO2e
are from etching/chamber cleaning and
0.5 million metric tons CO2e are from
heat transfer fluid usage.
MEMS. Emissions of fluorinated
GHGs from 12 MEMS facilities were
estimated to be 0.1 million metric tons
CO2e in 2006.
LCDs. Emissions of fluorinated GHGs
from 9 LCD facilities were estimated to
be 0.02 million metric tons CO2e in
2006.
PV. Emissions of fluorinated GHGs
from 20 PV facilities were estimated to
be 0.07 million metric tons CO2e in
2006. We request comment on the
number and capacity of PV facilities
that employ thin film technologies (i.e.,
amorphous silicon) and other PV
manufacturing facilities in the United
States using fluorinated GHGs.
For additional background
information on the electronics industry,
refer to the Electronics Manufacturing
Technical Support Document (TSD) in
the docket for this rulemaking (EPA–
HQ–OAR–2009–0927).
4. Threshold for Reporting
For facilities that manufacture
semiconductors, LCD, MEMS, and PV,
we are proposing an emissions-based
threshold of 25,000 mtCO2e. Consistent
with other sections of the Final MRR,
EPA is proposing that for the purposes
of determining whether a facility emits
amounts equal to or greater than 25,000
mtCO2e, a facility must include
emissions from all source categories for
which methods are provided in the rule.
For purposes of the threshold
determination under subpart I, we are
proposing two different methods,
depending on whether the facility
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manufacturers semiconductors, MEMS,
LCDs or PVs (see proposed section
98.91). It is important to note that these
methods are only for determining
whether a facility exceeds the threshold;
the proposed methods required for
monitoring and reporting emissions data
are presented in section 5 below.
To determine whether a manufacturer
falls above or below the proposed
25,000 mtCO2e threshold, we are
proposing that semiconductor, MEMS,
and LCD facilities use gas specific
emission factors assuming 100 percent
manufacturing capacity to calculate
annual metric tons of emissions in CO2
equivalents. Because we understand
that heat transfer fluids are widely used
within semiconductor manufacturing,
we are proposing that semiconductor
manufacturers add 10 percent of total
clean and etch emissions at a facility to
their estimate. For applicability
purposes, we propose that
manufacturing capacity means the
facility’s full planned design capacity.
The gas specific emission factors we
are proposing to use for threshold
applicability for semiconductors and
LCD facilities are consistent with the
2006 IPCC Tier 1 emission factors. For
MEMS, because there are no IPCC
factors available, we are assuming that
SF6 accounts for 100 percent of the
sector’s total emissions. The emission
factor we are proposing for threshold
applicability is based on the assumption
that the MEMS SF6 emission factor is
equivalent to the IPCC Tier 1 SF6
emission factor for semiconductors,
scaled up by a factor of 5.7
We are proposing that PV facilities
multiply annual fluorinated GHG
purchases or consumption by the gasappropriate 100-year GWPs, as defined
in Table A–1 of subpart A of part 98, to
calculate annual metric tons of
emissions in CO2 equivalents. None of
these calculations would account for
emission abatement systems.
We are proposing to require an
emissions estimating method that does
not account for destruction by
abatement systems because actual
emissions from facilities employing
abatement systems may exceed
estimates when based on the
manufacturers’ rated DREs of the
equipment and may therefore exceed
the 25,000 mtCO2e threshold without
the knowledge of the facility operators.
When abatement equipment is used,
electronics manufacturers often estimate
their emissions using the manufacturersupplied DRE for the system. However,
an abatement system may fail to achieve
its rated DRE either because it was not
installed properly, is not being properly
operated and maintained, or because the
DRE value itself was incorrectly
measured due to a failure to properly
account for the effects of dilution. For
example, reported DREs for CF4 can be
overstated by as much as a factor of 20
to 50, and the corresponding figure for
C2F6 can be overstated by a factor of up
to 10 because of failure to properly
account for dilution (Burton, 2007).
In our analysis of the emissions
thresholds, we considered thresholds of
1,000 mtCO2e, 10,000 mtCO2e, 25,000
mtCO2e, and 100,000 mtCO2e per year.
To estimate the number of
semiconductor facilities that would
have to report under each of the various
thresholds, we estimated emissions for
each facility in the U.S. by using IPCC
Tier 1 emission factors. These emissions
estimates were then evaluated to
determine how many facilities would
meet the various thresholds. To estimate
the collective emissions from the
facilities that would have to report
under the various thresholds, we used
information from EPA’s PFC Reduction/
Climate Partnership for Semiconductors
and the EPA PFC Emissions Vintaging
Model.
To estimate the number of LCD and
PV facilities that would have to report
under the various thresholds, as well as
the collective emissions from these
facilities, we used IPCC Tier 1 emission
factors. Because IPCC emission factors
for MEMS are not available, the number
of facilities that would have to report
and the collective emissions from these
facilities were determined using an
emission factor based on a relevant IPCC
Tier 1 emission factor for semiconductor
production.8 All of our analyses
assumed no abatement.
Table 4 of this preamble shows
emissions and facilities that would be
captured by the respective emissions
thresholds.
TABLE 4—THRESHOLD ANALYSIS FOR ELECTRONICS INDUSTRY
1,000 ....................................................................................
10,000 ..................................................................................
25,000 ..................................................................................
100,000 ................................................................................
We selected the 25,000 mtCO2e per
year threshold because it maximizes
emissions reporting, while excluding
small facilities that do not contribute
Emissions covered
Total
national
emissions
Emission threshold level metric tons CO2e/yr
Total number
of facilities
5,984,463
5,984,463
5,984,463
5,984,463
216
216
216
216
significantly to the overall GHG
emissions.
Table 5 of this preamble shows the
estimated emissions and number of
metric tons
CO2e/yr
Facilities covered
Percent
5,962,091
5,813,200
5,622,570
4,737,622
Facilities
99.6
97
94
79
Percent
165
114
94
55
76
53
44
26
facilities that would report for each type
of source under the proposed emissionsbased thresholds.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
TABLE 5—SUMMARY OF RULE APPLICABILITY UNDER THE PROPOSED THRESHOLDS
Emissions source
Semi-conductors .................
Threshold
17:39 Apr 09, 2010
Total emissions of
source
(metric tons
CO2e)
metric tons
CO2e/yr
175
5,741,676
5,492,066
25,000 Mt CO2 Eq. .............
7 For a more detailed explanation of MEMS
default factor, please refer to the Electronics
Manufacturing TSD (EPA–HQ–OAR–2009–0927).
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facilities
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8 For a more detailed explanation of MEMS
default emission factor, please refer to the
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Emissions covered
Facilities covered
Percent
96
Facilities
Percent
91
Electronics Manufacturing TSD (EPA–HQ–OAR–
2009–0927).
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TABLE 5—SUMMARY OF RULE APPLICABILITY UNDER THE PROPOSED THRESHOLDS—Continued
Emissions source
MEMS .................................
LCD .....................................
PV .......................................
Threshold
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
5. Selection of Proposed Monitoring
Methods
We are proposing methods to monitor
and estimate fluorinated GHG and N2O
emissions from semiconductor, LCD,
MEMS, and PV manufacture. The
proposed methods discussed below
include the following: (a) Estimating
emissions from cleaning and etching
processes; (b) estimating facility N2O
emissions; (c) estimating emissions from
heat transfer fluids; and (d) reporting
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Total emissions of
source
(metric tons
CO2e)
metric tons
CO2e/yr
12
9
20
146,115
23,632
73,039
96,164
0
34,340
25,000 Mt CO2 Eq. .............
25,000 Mt CO2 Eq. .............
25,000 Mt CO2 Eq. .............
The proposed emissions-based
thresholds are estimated to include
approximately 50 percent of
semiconductor facilities and between
approximately 5 percent and 17 percent
of the facilities manufacturing PV and
MEMS, respectively. At the same time,
the thresholds are expected to cover
nearly 96 percent of fluorinated GHG
emissions from semiconductor facilities,
66 percent of fluorinated GHG
emissions from facilities manufacturing
MEMS, and 47 percent of fluorinated
GHG emissions from facilities
manufacturing PV. Combined, these
emissions are estimated to account for
close to 94 percent of fluorinated GHG
emissions from the electronics industry
as a whole.
Based on our current analysis,
facilities manufacturing LCDs are not
expected to meet the proposed
threshold. In addition, only 2 MEMS
facilities and 1 PV facility are expected
to be covered. The data and information
that we currently have on MEMS, LCD,
and PV manufacturing, however, is
limited and incomplete. We are
including these sectors because they
have similar fluorinated GHG and N2O
use and manufacturing processes as
those of semiconductor manufacturing
and they are high growth sectors. We
estimate that emissions from MEMS,
LCD, and PV may be higher than our
data show currently and we expect them
to increase in the future.
For additional background
information on the threshold analysis,
refer to the Electronics Manufacturing
TSD. For specific information on costs,
including unamortized first year capital
expenditures, please refer to the EIA
and the EIA cost appendix.
Jkt 220001
Emissions covered
Total national
facilities
controlled emissions from abatement
equipment. The methods described and
proposed in this section are for
estimating emissions that would be
required to be reported under this
subpart (see proposed sections 98.93
and 98.94). It is important to note that
these methods differ from those
proposed in the section above which are
for determining applicability of the
subpart.
a. Methods for Estimating Emissions
From Cleaning and Etching Processes
We are proposing different methods
for estimating fluorinated GHG
emissions from etching and cleaning
based on whether the facility is a
semiconductor manufacturer or an LCD,
MEMS, or PV manufacturer.
Method for Semiconductor Facilities.
Under this proposal, all semiconductor
manufacturers that have emissions
equal to or greater than 25,000 mtCO2e
would be required to estimate and
report emissions from etching and
cleaning using one of two approaches.
First, we are proposing an approach,
hereinafter referred to as the ‘‘Refined
Method,’’ that is based on:
(1) Gas consumption as calculated
using the facility’s purchase records,
inventory, and gas- and facility-specific
heel factors,
(2) Facility-specific methods for
apportioning gas consumption by
process category 9 using indicators of
GHG-using activity (e.g., wafer passes),
(3) Emission factors for utilization and
by-product formation rates based on
refined process categories (e.g.,
categories with more specificity than the
simpler cleaning and etching categories
listed in the 2006 IPCC Guidelines), and
(4) Methods for reporting controlled
emissions (as proposed below).
Alternatively, we are proposing to
permit those facilities that have
monitoring infrastructure or the
necessary data to estimate emissions
9 For purposes of electronic manufacturing,
‘‘process category’’ is a set of similar manufacturing
steps, performed for the same purpose, associated
with substrate (e.g., wafer) processing during device
manufacture for which fluorinated GHG and N2O
emissions and fluorinated GHG and N2O usages are
calculated and reported.
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Facilities covered
Percent
66
0
47
Facilities
Percent
2
0
1
17
0
5
obtained through recipe-specific
measurements to report their emissions
using their data by following an
approach consistent with the 2006 IPCC
Tier 3 method. In addition, for those
semiconductor manufacturers that
fabricate electronic devices on wafers of
measuring greater than 300 mm in
diameter, we are proposing to require
that they estimate and report their
emissions using recipe-specific
measurements and follow an approach
consistent with the IPCC Tier 3 method.
Each of these approaches is discussed
below.
Refined Method.
The Refined Method would apply to
all covered semiconductor facilities and
would not make a distinction between
relatively large and other facilities. In
the paragraphs below, we discuss in
detail each one of the components we
are proposing to require under this
approach.
Gas consumption as calculated using
the facility’s purchase records,
inventory, and gas- and facility-specific
heel factors. Notwithstanding the
definition of ‘‘heel’’ in subpart A of this
rule,10 we are proposing that for
purposes of electronics manufacturing
that a heel means, ‘‘the amount of gas
that remains in a gas cylinder or
container after it is discharged or offloaded (this may vary by cylinder or
container type and facility).’’ We are not
planning to use the subpart A definition
because it contains a default value of 10
percent. In this action, we are proposing
to require facilities to calculate gas- and
facility-specific heel factors rather than
using a default value.
As part of determining each facility’s
overall usage of each gas for a reporting
period, we are proposing that a facility
use their purchase records, inventory,
and gas- and facility-specific heel
factors. More specifically, for each
cylinder/container type for each gas
used, we are proposing that
semiconductor facilities be required to
base their heel factors on the residual
10 Pursuant to subpart A of the Final MRR, ‘‘heel’’
means the amount of gas that remains in a shipping
container after it is discharged or off-loaded (that is
no more than ten percent of the volume of the
container).
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weight or pressure of the gas cylinder or
container that a facility uses to change
out that cylinder/container. This is
common practice in the industry and is
typically referred to as the ‘‘trigger point
for change out.’’ These points, one for
each gas and cylinder/container type,
together with the initial container mass
or pressure, are used to calculate the
unused gas for each container, which
when expressed as a fraction of the
initial amount in the container is the
‘‘heel’’ (or unused fraction of the
container). This gas- and facilityspecific heel factor would then be
applied to each container for that gas to
determine the net amount of that gas
used at a facility. In cases where the
‘‘trigger point for change out’’ used at a
facility differs by more than one
percentage point from that used to
calculate the previous gas-specific heel
factor, we propose that the gas- and
facility-specific heel factor must be
recalculated.
Currently most semiconductor
facilities rely upon the IPCC default heel
factor of 10 percent and apply that value
to each cylinder/container. Based on
information provided in an industry
study of facility-specific, gas-specific
heel factors, the heel factor in a given
facility for individual cylinders/
containers can vary from 3 percent to 25
percent. Given this variation, we
conclude that gas- and facility-specific
heel factors would provide improved
accuracy in emissions estimates over the
use of the IPCC default heel factor.
We understand that there are
exceptional circumstances when
facilities do not always change
cylinders/containers exactly when they
reach the targeted residual weight or
pressure. In those instances, which we
expect are infrequent, we are proposing
that the cylinder/container must be
weighed or the pressure measured using
a pressure gauge; as opposed to using
the facility-wide gas-specific heel factor
as part of determining the net amount of
gas used at a facility. We are proposing
to define an exceptional circumstance as
one which the cylinder/container is
changed at a residual mass or pressure
that differs by more than 20 percent
from the ‘‘trigger point for change out.’’
We request comment on the frequency
of these exceptional circumstances and
also the percentage difference (i.e. 20
percent) for which we are proposing to
require that the exceptional cylinder/
container be weighed or the pressure
measured.
When taking an annual inventory, we
understand that multiple cylinders/
containers are in service. We request
comment on the significance of
accounting for the quantity of
fluorinated GHGs or N2O remaining in
cylinders/containers in service at the
end of the reporting period. We also
request comment and detailed
information on other methods and
technologies (i.e. other than purchase
records) that facilities may be using for
determining annual gas consumption
(e.g., recorded data from an automated
gas inventory system).
We are proposing that all flowmeters,
weigh scales, pressure gauges, and
thermometers used to measure
quantities that are monitored or used in
calculations in this proposal have an
accuracy and precision of 1 percent of
full scale or better. We request comment
on this requirement including
alternative accuracy and precision
requirements and detailed information
about why particular instruments can
not meet the proposed 1 percent
standard.
Apportioning gas consumption to
process categories. Estimating facility
emissions requires apportioning annual
facility-wide gas consumption across a
facility’s emitting process categories by
way of applying facility-specific
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apportioning factors. A facility’s
uncontrolled emissions are the product
of that apportioned gas consumption
and the corresponding emission factor.
To determine the share of each gas used
by each process category, we are
proposing to require that semiconductor
facilities use a quantifiable indicator (or
metric) of gas usage activity. More
specifically, we are proposing facilities
track wafer passes as an indicator of
activity with which to apportion the
facility’s gas consumption. Wafer passes
is a count of the number of times a
silicon wafer is processed for a specific
process category. The total number of
wafer passes over a reporting year is the
number of wafer passes per tool times
the number of operational process tools
during the reporting year.
To illustrate a case where wafer
passes is used as a facility-specific
engineering model, consider a facility
that uses NF3 for chamber cleaning with
remote plasma systems and for etching
polysilicon and oxide films. With
knowledge of the NF3-specfic heel and
the number of NF3 containers used, the
facility knows the amount of NF3
consumed. To estimate emissions, the
facility must now apportion NF3 usage
between the chamber cleaning and
oxide and polysilicon etching processes.
To do this it might use the total number
of wafer passes through each and every
NF3-cleaning system together with the
time and nominal (not measured actual)
gas flow rate for each and every NF3cleaning system and the corresponding
figures for oxide and polysilicon etch
processes to arrive at the proportion of
NF3 used for cleaning chambers and
etching oxide and polysilicon films.
Once developed, these apportioning
factors would be used to estimate NF3
gas usage for the cleaning and etching
process categories proposed in our
method. This example is illustrated
further in Table 6 of this preamble.
TABLE 6—ILLUSTRATIVE CALCULATION FOR NF3 EXAMPLE AT ONE FACILITY
Apportioning
factor
Gas type—annual usage, kg.
Process category
NF3—56,286 kg ...............................................................
RPS Chamber Cleaning ..................................................
Polysilicon Etch ................................................................
Oxide Etch .......................................................................
82%
17%
1%
Process category gas
usage, kg.
46,202
9,561
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Annual gas usage presented is the modeled usage not the nominal usage.
We request comment on using wafer
passes as an appropriate quantifiable
indicator of activity, and on our
description and example of how it
would be used.
We recognize that facilities may use
other types of quantifiable indicators of
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gas-usage activity data to develop
facility-specific engineering models to
estimate gas consumption. We may
include additional indicators as options
in the final rule if they are quantifiable
and if we receive adequate information
regarding how they were developed and
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how they are used, including
descriptions, examples, and any
additional information that may be
necessary to understand how such
indicators of activity would be
developed and used in a facility-specific
engineering model to apportion annual
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facility-wide gas usage across a facility’s
emitting process categories. The use of
engineering judgment, for example, is
not based on a quantitative metric and
would not be considered an acceptable
quantifiable indicator of gas usage. We
also request comment on the use of a
representative sampling method for
tracking activity indicators such as
wafer passes that may be used in the
engineering model.
In many cases, EPA anticipates that
the development of apportioning factors
will result in a facility-wide
consumption estimates that are
independent of the estimates calculated
using purchase records, inventory, and
facility-specific heel factors. In such
cases, we propose that facilities report
these consumption estimates.
Emission factors for refined process
categories. We are proposing that
semiconductor facilities estimate their
emissions using a specific set of process
categories. Our proposed method would
simplify the reporting requirements as
compared to the 2006 IPCC Tier 3
method by lowering the number of
emitting process categories from up to
455 per facility down to a fixed figure
of approximately nine. Our goal in
establishing the process categories is to
account for most of the variability in
emission factors across processes while
limiting the total number of process
categories whose gas usage must be
tracked by semiconductor facilities.
Under this approach, we are
proposing to require reporting of
fluorinated GHG emissions for the
following nine emitting process
categories: four subcategories for wafer
patterning (etching), three subcategories
for chamber cleaning, and two
subcategories for wafer cleaning. The
nine process categories we are
proposing account for distinct and
widely-used manufacturing activities
during production of discrete, logic and
memory devices. We anticipate that
these nine categories effectively capture
current and projected processes and the
differences in emission factors across
various semiconductor manufacturing
technologies.
Our proposed definitions of these
nine emitting categories are:
Wafer patterning subcategories:
Oxide etch means any process using
fluorinated GHG reagents to selectively
remove SiO2, SiOx-based or fully
organic-based thin-film material that has
been deposited on a wafer during
semiconductor device manufacturing.
Nitride etch means any process using
fluorinated GHG reagents to selectively
remove SiN, SiON, Si3N4, SiC, SiCO,
SiCN, etc. (represented by the general
chemical formula, SiwOxNyXz where
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w,x,y and z are zero or integers and X
can be some other element such as
carbon) that has been deposited on a
wafer during semiconductor
manufacturing.
Silicon etch also often called
polysilicon etch means any process
using fluorinated GHG reagents to
selectively remove silicon during
semiconductor manufacturing.
Metal etch means any process using
fluorinated GHG reagents associated
with removing metal films (such as
aluminum or tungsten) that have been
deposited on a wafer during
semiconductor manufacturing.
Chamber cleaning subcategories:
In situ plasma means cleaning thinfilm production chambers, after
processing one or more wafers, with a
fluorinated GHG cleaning reagent that is
dissociated into its cleaning
constituents by a plasma generated
inside the chamber where the film was
produced.
Remote plasma system means
cleaning thin-film production chambers,
after processing one or more wafers,
with a fluorinated GHG cleaning reagent
dissociated by a remotely located (e.g.,
upstream) plasma source.
In situ thermal means cleaning thinfilm production chambers, after
processing one or more wafers, with a
fluorinated GHG cleaning reagent that is
thermally dissociated into its cleaning
constituents inside the chamber where
the thin-film (or thin films) was (were)
produced.
Wafer cleaning subcategories:
Bevel cleaning means any process
using fluorinated GHG reagents with
plasma to clean the edges of wafers
during semiconductor manufacture.
Ashing means any process using
fluorinated GHG reagents with plasma
to remove photoresist materials during
wafer manufacture.
We request comment on the nine
process categories we are proposing,
their definitions as specified above, and
whether they clearly define a specific
process without ambiguity. In addition
we request comment on whether the
categories should be further refined to
better capture the variability in emission
rates among fluorinated GHG using
manufacturing activities (e.g., whether
any additional categories should be
added or whether the proposed
categories should be combined, and the
definition of those categories).
Under this approach of defining a
specific set of process categories, we are
also considering additional patterning
and chamber cleaning subcategories.
The alternative patterning subcategories,
which may replace or complement the
four thin-film based subcategories
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defined previously, are: contact etch,
self-alignment contact etch, gate etch,
deep trench etch, isolation trench etch,
through silicon vias and regular vias.
Each of these subcategories represents a
specific feature achieved through
etching (instead of subcategories based
on the type of thin film etched).
Alternative chamber cleaning
categories may distinguish between the
types of films being removed from the
chamber during cleaning. These might
include distinguishing between
chambers coated with tungsten and
silicon-based films, or distinguishing
between thin-film deposition equipment
manufacturers. We request comment on
these additional process categories and
whether or not we should include
alternative process categories in
addition to the nine process categories
that we are proposing. We also request
comment on other methods of
categorizing processes and detailed
information on those categories.
We are proposing nine process
categories differentiated by production
technology generation (i.e., wafer size).
For each of the proposed nine process
categories, we are proposing to establish
a default emission factor within a range
of values presented in Tables I–6, I–7,
I–8 of subpart I. Within each process
category, factors account for (1) the mass
fraction of the input gas that is utilized
during (i.e., not emitted from) the
process and (2) the mass of each
fluorinated GHG by-product formed as a
fraction of the mass of the dominant
fluorinated GHG input gas used.11 EPA
is proposing a range of values for each
default emission factor because the
Agency has not yet received sufficient
data to select a specific value within
each range.
To develop the proposed ranges for
each emission factor, EPA requested
from semiconductor device
manufacturers and equipment suppliers,
information on utilization and byproduct formation rates and details on
the associated measurement approach
(e.g., measured in accordance with the
2006 ISMI Guidelines). EPA evaluated
the data received as well as the standard
deviations provided in Table 6.9 from
Chapter 3 of the 2006 IPCC Guidelines.
For additional information on how the
ranges were developed, please refer to
the Electronics Manufacturing TSD
(EPA–HQ–OAR–2009–0927).
In a final rule, EPA intends to publish
default emission factors for gas
utilization and by-product formation
rates for each process category,
11 In the case of mixtures of fluorinated GHGs, the
‘‘dominant’’ fluorinated GHG constitutes the largest
mass of gas used for that process.
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differentiating amongst 150 mm, 200
mm and 300 mm wafer technology to
the extent feasible. To this end, EPA
requests additional utilization and byproduct formation rates and supporting
information on how they were
developed. More specifically, EPA
requests emission factors and byproduct formation rates and information
including but not limited to the specific
measurement method used (e.g.,
measurement using the 2006 ISMI
Guidelines), the date of measurement,
achievement of fluorine mass balance,
associated standard deviations of
measured factors, the relevant emissions
process types and categories (for the
patterning/etching process type noting
both film type and etched feature where
applicable), substrate size (i.e., 150 mm,
200 mm, or 300 mm), the number of
wafers used in the measurement study,
and the equipment manufacturer name
and model number where not
considered confidential.
Using additional data received, EPA
intends to develop default emission
factors for each process category using
a method of aggregation similar to the
2006 IPCC factor development
methodology.12 Where available
emission factor data are very limited or
produce highly uncertain average
factors, EPA may develop emissions
factors that are conservative and less
likely to underestimate actual
emissions. If additional data are
received in a timely fashion, EPA may
develop draft emission factors prior to
issuance of the final rule and will
determine an appropriate way to
promptly and clearly inform the
regulated community. We welcome
comments on such draft emission
factors, recognizing that depending on
when the emission factors are made
available, such comments could be
submitted after the close of the formal
comment period. We will make every
effort to consider such comments,
including late comments, to the extent
practicable in the development of the
final rule.
In developing emission factors for the
final rule, EPA is also considering
developing weighted average emission
factors, for each wafer technology, with
the weights based on the market
penetration rates of process recipes used
in current device manufacturing
practices.13 Such weighted emission
12 For additional information on the 2006 IPCC
factor development methodology, see Emission
Factors for Semiconductor Manufacturing: Sources,
Methods, and Results (February 2006) available in
the docket (EPA–HQ–OAR–2009–0927).
13 Note, in the creation of the IPCC factors,
sufficient information was not available to weigh
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factors, if possible, may better represent
actual emissions from installed
manufacturing equipment and operating
processes. We request comment on
using a weighting scheme and detailed
information on how it would be
developed and implemented.
The uncertainties associated with the
2006 IPCC Tier 2b method are
associated with aggregating, for each
gas, all usage into just two process
categories (i.e., etching and chamber
cleaning) and all wafer technologies
(i.e., 150 mm, 200 mm, and 300 mm
wafer sizes) into one, and giving equal
weights to all process recipes. A method
based on refined processes categories
keeps those processes separate, which
reflects actual device manufacturing
practices and as a result, produces a
more representative and accurate
emissions estimate.
As an alternative, we are also
considering an approach where each
facility would develop for themselves or
acquire from process equipment
manufacturers emission factors (i.e., gas
utilization and by-product formation
rates) for the nine process categories.
Under this approach, we would require
the gas utilization and by-product
formation rates to be developed using
the 2006 ISMI Guidelines. Facilities
would be required to construct and
apply averages for each process
category. One advantage of this
approach is that these facility-specific
emission factors would be expected to
be more representative of the particular
processes at that facility than the default
emission factors. On the other hand, we
estimate the burden associated with
each facility developing its own
emission factors would be greater
compared to using the factors published
by EPA. We request comment on this
approach.
We recognize that given the dynamic
manufacturing processes by the
industry, updates to the process
categories and emission factors may be
necessary. We request comment on the
frequency with which those should be
updated.
We estimate that our Refined Method
will result in a reduction in burden for
the large semiconductor facilities
(annual capacities greater than 10,000
m 2 silicon) and an increase in accuracy
as compared to the IPCC Tier 2b
method. We estimate the uncertainty
from using a set of refined process
categories to be roughly one-half the
uncertainty of the Tier 2b method,
assuming similar methods for
apportioning gas usage for each method.
each general process type (i.e., etch and clean
categories for the IPCC Tier 2b method).
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For the Tier 2b method the fluorinated
GHG consuming processes used during
semiconductor production are collapsed
into just two categories, resulting in
considerable variability for each
category. For the Refined Method there
are nine fluorinated GHG-using
categories, resulting in less variability,
on average, per category. Please refer to
the Electronics Manufacturing TSD for a
more detailed discussion of our
uncertainty analysis.
For the relatively smaller
semiconductor facilities (annual
production of less than 10,500 m 2 of
silicon) we estimate an increase in
burden as compared to our initial
proposal where we required the use of
the 2006 IPCC Tier 2b method; however,
we anticipate that these facilities have
the necessary data available to comply.
The increase in burden for estimating
emissions using the Refined Method, as
opposed to the IPCC Tier 2b method,
can be attributed to the increased level
of effort to distinguish between nine
refined process categories in
comparison to two broad clean and etch
categories, respectively.
Recipe-specific measurements. As an
alternative to the Refined Method where
EPA default factors would be used, we
are also proposing to permit those
facilities that have monitoring
infrastructure or the necessary data to
estimate emissions obtained through
recipe-specific measurements to report
their emissions using their data (see
proposed sections in 98.93 98.94(d)).
This approach, consistent with the 2006
IPCC Tier 3 method, is based on (1) gas
consumption as calculated using the
facility’s purchase records, inventory,
and gas-and facility-specific heel factors
(as described above), (2) facility-specific
methods for apportioning gas
consumption by individual process
using indicators of GHG-using activity,
(3) recipe-specific gas utilization and
by-product formation factors, and also
(4) methods for reporting controlled
emissions from abatement devices (as
proposed below). Under this approach,
gas utilization and by-product formation
rates would be required to be developed
using the 2006 ISMI Guidelines for all
fluorinated GHG-using process types at
that facility.
According to information provided by
one of the commenters in response to
our initial proposal, only one company
currently estimates their emissions
using an approach consistent with the
Tier 3 method. Nevertheless, if a facility
is using a method that provides more
accurate data, then we believe that they
should be permitted to use such
method. We request comment on the
number of companies that are currently
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or expecting to in the near future, report
their emissions using this method.
We are also proposing to require
semiconductor manufacturers that
fabricate devices on wafers measuring
larger than 300 mm in diameter to
estimate their emissions based on an
approach consistent with the IPCC Tier
3 method and gas- and facility-specific
heel factors for estimating and reporting
GHG emissions. Under this approach,
gas utilization and by-product formation
rates would be required to be developed
using the 2006 ISMI Guidelines for all
fluorinated GHG using process types at
that facility. We understand the
industry’s conversion to 450 mm is
expected to begin in 2011 or shortly
thereafter. We are proposing this
requirement because we estimate that
this method that uses recipe-specific gas
utilization and by-product formation
factors results in the most accurate
facility-specific emission estimate. By
including this requirement for only the
450 mm or larger wafers in this
proposal, we anticipate a reduction in
burden as compared to requiring
existing large semiconductor facilities to
estimate their emissions using an
approach consistent with the IPCC Tier
3 method for the smaller sized wafers as
well (i.e. 300 mm and smaller). We
anticipate a reduction in burden
because emission factors (i.e. gas
utilization and by-product formation
rates) can be developed over a number
of years as semiconductor
manufacturers begin to transition to 450
mm tools and develop the estimating
and reporting infrastructure. The
commissioning process for new tools is
an ideal opportunity for emission factor
development and/or verification. We
request comment on requiring
semiconductor manufacturers that
fabricate electronic devices on wafers of
diameter 450 mm or larger to estimate
their emissions based on an approach
consistent with the IPCC Tier 3 method.
During the development of this
proposal, the 2006 International
SEMATECH Manufacturing Initiative’s
Guideline for Environmental
Characterization of Semiconductor
Process Equipment was revised and
republished (December 2009). We
request comment on requiring the use of
the revised version of the ISMI
Guidelines to measure emission factors
as opposed to the 2006 version of the
ISMI Guidelines, and also information
on emission factors (including
utilization by-product formation rates)
measured using the revised ISMI
Guidelines.
Method for LCD, MEMS, and PV
Facilities. In this action for LCD, MEMS,
and PV facilities, we are proposing an
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approach based on a slightly modified
2006 IPCC Tier 2b method which would
include (1) gas consumption calculated
using the facility’s purchase records,
inventory, and gas- and facility-specific
heel factors (as described above for
semiconductor manufacturing facilities),
(2) gas consumption apportioned to
2006 IPCC Tier 2b broad process
categories, clean and etch, (3) default
emission factors consistent with the
2006 IPCC Tier 2b factors, and (4)
methods for reporting controlled
emissions from abatement equipment
(as proposed below).
The method proposed to develop the
gas- and facility-specific heel factors for
LCD, MEMS, and PV facilities is the
same as proposed for semiconductor
facilities including the provisions for
exceptional circumstances. Although we
don’t have complete information on
how LCD, MEMS, and PV facilities are
currently estimating their emissions
from manufacture and how they are
currently accounting for heels, their gas
use and manufacturing processes are
similar to that of semiconductor
manufacturing. As a result, we have
concluded these facilities have the data
required to develop a gas- and facilityspecific heel factors and this method
can be implemented with minimal
burden. Similar to the semiconductor
manufacturing case, the use of a gasand facility-specific heel factor is
expected to result in improved accuracy
when compared to the IPCC’s 10 percent
default factor. We request comment on
our proposal to require LCD, MEMS,
and PV facilities to use gas- and facilityspecific heel factors and our
understanding that these facilities have
the data to develop such a factor with
minimal burden.
Under this approach consistent with
the 2006 IPCC Tier 2b method, we
propose that LCD, MEMS, and PV
manufacturing facilities use the
calculated mass of gas consumed and
apportion this amount to the simplified
process categories (i.e. etch and
chemical vapor deposition chamber
cleaning.) The associated emission
factors including utilization and byproduct formation rates, would then be
used to calculate uncontrolled
fluorinated GHG emissions. The
emission factors being proposed are
consistent with the 2006 IPCC default
values. For MEMS manufacturing,
where an IPCC default value does not
exist, we propose the use of factors
consistent with the 2006 IPCC Tier 2b
factors for semiconductor
manufacturing. We selected these
factors because we understand MEMS
manufacturing is silicon wafer-based
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and uses processes similar to those
found in semiconductor manufacturing.
Additionally, we are proposing that
LCD, MEMS, and PV manufacturing
facilities abide by the requirements
proposed for reporting controlled
emissions from abatement systems as
proposed below.
We are requesting information on
emissions and emission factors from
LCD, MEMS, and PV manufacturing. We
are requesting such information as a
means to verify that the Tier 2b
emission factors for each of the
manufacturing types are reflective of
current fluorinated GHG emitting
processes. Based on new information we
receive, we may consider updating the
emission factors in the final rule.
We expect that LCD, MEMS, and PV
manufacturers may also use engineering
models and quantifiable indicators (e.g.,
substrate-area based) of manufacturing
activity for apportioning gas
consumption by process category
similar to the approach described for
semiconductors above (e.g., wafer
passes). We request detailed information
on those indicators, how they were
developed, and how they are used in a
facility-specific engineering model to
apportion annual facility-wide gas usage
across a facility’s emitting process
categories.
We request comment on permitting
those LCD, MEMS, and PV
manufacturing facilities that have
monitoring infrastructure or the
necessary data to estimate emissions
obtained through recipe-specific
measurements to report their emissions
using their data by following an
approach consistent with the 2006 IPCC
Tier 3 method.
Review of Existing Reporting
Programs and Methodologies and
Consideration of Alternative Methods.
EPA considered various methods for
estimating emissions from etching and
cleaning processes for electronics
manufacturing facilities including the
2006 IPCC Tier 1, 2a, 2b, and Tier 3
method as well as a Tier 2b/3 hybrid
which would apply Tier 3 to the most
heavily used fluorinated GHGs in all
facilities. For a detailed description of
our evaluation of these options, please
see the Electronics Manufacturing
section of the initial Mandatory
Reporting Rule (74 FR 16499).
For this proposal, to estimate
emissions from all semiconductor
manufacturing facilities, we are also
considering the alternative of a modified
Tier 2b method (our preferred option for
other electronics manufacturers) which
would require the use of the 2006 IPCC
Tier 2b default factors and gas- and
facility-specific data on heels and gas
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use by process category. This approach
would be based on a modified version
of the 2006 IPCC Tier 2b method for
estimating emissions and would require
semiconductor facilities to report
emissions using (1) gas consumption as
calculated using the facility’s purchase
records, inventory, and gas- and facilityspecific heel factors (as described
above), (2) facility-specific methods for
apportioning gas usage by process
category using indicators of activity (as
described above, e.g., wafer pass), (3)
IPCC Tier 2b emission factors, and (4)
methods for reporting controlled
emissions using our proposed approach
discussed below. We request comment
on this approach.
As an alternative to the Refined
Method, we are also considering
requiring all semiconductor
manufacturing facilities to estimate their
emissions using an approach consistent
with the IPCC Tier 3 method based on
(1) gas consumption as calculated using
the facility’s purchase records,
inventory, and gas- and facility-specific
heel factors, (2) facility-specific methods
for apportioning gas consumption by
individual process using indicators of
GHG-using activity, (3) recipe-specific
gas utilization and by-product formation
factors, and also (4) methods for
reporting controlled emissions from
abatement devices (as proposed below).
Under this approach, facilities would be
required to develop gas utilization and
by-product formation rates using the
2006 ISMI Guidelines for all fluorinated
GHG-using process types at that facility.
We request comment on this approach.
Another option we are considering is
to evaluate emissions from electronics
manufacturing using continuous
emission monitoring system(s) (CEMS).
Under this approach, facilities would be
required to install and operate CEMS to
measure process emissions. A typical
electronics manufacturing facility may
have many individual process tools that
influence emissions. Process tool
exhaust is managed within the facility
using stainless steel plumbing and
ductwork. Due to the complexity of the
manufacturing layout, CEMS would be
attached either to every tool or to one
or more final exhaust points (e.g.,
scrubber stacks). One possible option is
to use Fourier Transform Infrared
Spectrometers (FTIRs) in scrubber
stacks to measure facility emissions.
FTIR spectroscopy is presently used to
conduct short-term fluorinated GHG
emission measurements from single
tools. EPA requests comment on the use
of CEMS at electronics manufacturing
facilities. We also request data and other
information evaluating the use of CEMS
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in electronics facilities to determine
fluorinated GHG and N2O emissions.
(b) Method for Estimating N2O
Emissions
We are proposing that electronics
manufacturers estimate N2O emissions
from chemical vapor deposition
processes and all other electronics
manufacturing processes such as
chamber cleaning, and that they
estimate those emissions using the
following proposed methods.
To estimate N2O emissions from
chemical vapor deposition we are
proposing the use of a facility-specific
emission factor based on facility
measurements of N2O utilization for
chemical vapor deposition, using 2006
ISMI Guidelines. Under this approach,
we propose to permit the facility to
apply the average N2O utilization
emission factor to all N2O using
chemical vapor deposition recipes. In
cases where a facility has not developed
a facility-specific N2O utilization factor
for chemical vapor deposition
processes, we are proposing a default
value in the range of 0 to 40 percent. We
are taking comment on this range due to
a lack of information for N2O utilization
for chemical vapor deposition
processes.
In comments received in response to
our initial proposal, industry provided
information to support a N2O utilization
factor of 40 percent, primarily in 300
mm chemical vapor deposition
processes. Taking the industry-provided
40 percent utilization into account, we
propose to select a N2O utilization factor
in the range from 0 to 40 percent. In the
industry’s survey, the measured
utilization factors are largely from
newer 300 mm manufacturing
equipment. We do not expect these data
fairly represent the entire population of
all N2O processes and installed
equipment, many of which are older
tools. In addition, the industry
comments did not fully identify the
specific processes from which the
average N2O utilization factor was
calculated. For these reasons, and
because we understand that N2O is most
commonly used for chemical vapor
deposition as opposed to other
processes, we are proposing to establish
a default value within a range of values
with 40 percent as the upper bound and
0 percent as the lower bound to be
conservative, reducing potential for
underestimating emissions.
To estimate N2O emissions from all
other manufacturing processes (e.g.,
chamber cleaning), we are proposing
either a facility-specific utilization
factor based on measurements using
2006 ISMI Guidelines, or applying a
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default utilization factor of 0 percent
which assumes N2O is not converted or
destroyed during the manufacturing
process. We are proposing this method
due to a lack of information regarding
other processes for which N2O is used
and N2O utilization data in those
processes.
We request comment on values within
the range that we are proposing to
estimate N2O emissions from chemical
vapor deposition processes and our
approach for estimating N2O emissions
from all other manufacturing processes.
We also request additional information
on N2O uses and N2O utilization in
electronics manufacturing processes.
More specifically, we request N2O
emission factors and detailed
supporting information including but
not limited to the specific measurement
method used, date of measurement,
standard deviation of measured factors,
identification of manufacturing process
or process category, substrate size, and
equipment manufacturer name and
model number where not considered
confidential.
In addition, we request comment on
using wafer passes or other appropriate
quantifiable indictors of activity for
apportioning N2O consumption to
chemical vapor deposition and other
manufacturing processes.
We are proposing that as part of
determining annual facility N2O
emissions, if a facility employs
abatement systems and it wishes to
report N2O emission reductions due to
these systems it must adhere to the
methods for reporting controlled
emissions included in this proposal.
(c) Method for Estimating Emissions of
Heat Transfer Fluids
To estimate the emissions of heat
transfer fluids, we propose that
electronics manufacturers use the 2006
IPCC Tier 2b approach, which is a massbalance approach. We are not changing
the broad outlines of our initial
proposal; however, we are clarifying
required data elements.
In evaluating the comments we
received, we understand that there was
some confusion regarding our intended
method. The proposed method required
data on the total nameplate capacity 14
of equipment that ‘‘is installed during
the reporting year.’’ We intended
‘‘installed during the reporting year’’ to
mean newly installed during the period,
14 Nameplate capacity means the full and proper
charge of gas specified by the equipment
manufacturer to achieve the equipment’s specified
performance. The nameplate capacity is typically
indicated on the equipment’s nameplate; it is not
necessarily the actual charge, which may be
influenced by leakage and other emissions.
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not in place from the beginning of that
period. To eliminate confusion, we are
clarifying that facilities are required to
provide the total nameplate capacity
(charge) of equipment that is ‘‘newly
installed’’ during the reporting year. We
anticipate that facilities will find it
straightforward to track the nameplate
capacities of equipment that is newly
installed or retired during the reporting
year.
In addition, we are also clarifying that
a facility may only subtract the amount
of fluorinated heat transfer fluids sent
off site if the heat transfer fluids are
properly recovered, stored, and sent off
site for verifiable recycling or
destruction during the reporting year.
We are adding this clarification because
we understand that facilities may be
recovering, storing, and removing from
their facility, fluorinated heat transfer
fluids in a manner that does not
effectively prevent the substance(s) from
evaporating to the atmosphere. In such
cases, the users of the chemicals would
be required to account for these
emissions using the mass-balance
calculation provided.
As we stated in our initial proposal,
in developing our proposal for
estimating heat transfer fluid emissions,
we reviewed both the IPCC Tier 1 and
IPCC Tier 2 approaches. The Tier 1
approach for heat transfer fluid
emissions is based on the utilization
capacity of the semiconductor facility
multiplied by a default emission factor.
Although the Tier 1 approach has the
advantages of simplicity, it is less
accurate than the Tier 2 approach
according to the 2006 IPCC Guidelines.
The IPCC Tier 2 approach uses
company-specific data and accounts for
differences among facilities’ heat
transfer fluids (which vary in their
GWPs), leak rates, and service practices.
It has an uncertainty on the order of ±20
percent at the 95 percent confidence
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interval according to the 2006 IPCC
Guidelines.
(d) Method for Reporting Controlled
Emissions From Abatement Systems
For this proposed rule, we are
defining DRE as the efficiency of a
control system designed to destroy or
remove fluorinated GHGs, N2O, or both.
The DRE is equal to one minus the ratio
of the mass of all relevant GHGs exiting
the emission abatement system to the
mass of GHGs entering the emission
abatement system. When fluorinated
GHGs are formed in an abatement
system, DRE is expressed as one minus
the ratio of amounts of exiting GHGs to
the amounts entering the system in
units of CO2-equivalents. In addition,
we are clarifying facilities may account
for all abatement systems (e.g., multichamber POU, central devices) provided
that they abide by the requirements
below.
We are proposing to use the term
destruction or removal efficiency (DRE)
as opposed to ‘‘destruction efficiency’’ or
‘‘destruction,’’ terms that are already
defined in subpart A of the Final MRR.
We are proposing to use DRE because it
is the term generally used by the
electronics manufacturing industry.
Furthermore, in addition to capturing
the destruction of materials in the
exhaust, the term also captures
materials in the exhaust that are
recycled or captured for reuse.
For purposes of this reporting rule, we
propose that facilities that wish to
document and report fluorinated GHG
and N2O emissions reflecting the use of
abatement systems adhere to a method
that would require: (1) Documentation
to certify that the abatement system is
installed, operated, and maintained in
accordance with manufacturers’
specifications, (2) accounting for the
system’s uptime,15 and (3) either
15 Uptime means the total time during the
reporting year when the abatement system for
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certification that the abatement system
is specifically designed for fluorinated
GHG and N2O abatement and the use of
an EPA default DRE value, or direct,
proper DRE measurement to confirm the
performance of the abatement system.
Proper DRE measurement means
measured in accordance with EPA’s
Protocol for Measuring Destruction or
Removal Efficiency of Fluorinated
Greenhouse Gas Abatement Equipment
in Electronics Manufacturing (EPA’s
DRE Protocol). EPA’s DRE Protocol is
available for review in the docket (EPA–
HQ–OAR–2009–0927). Our proposed
approach is depicted as a decision tree
in Figure 1 of this preamble.
The proposed approach requires
annual certification to ensure that
abatement systems for which controlled
emissions are reported are installed,
operating, and maintained according to
manufacturers’ specifications. Our
approach would also require that any
DRE used in reporting emissions be
based on an EPA default DRE value or
on recent on-site measurements and
actual uptime of the system, accounting
for system redundancy. When process
tools are equipped with multiple
abatement systems designed for
fluorinated GHGs and N2O, the facility
may account for the combined uptime
for the specific calculation of controlled
emissions. Each one of these
components is discussed in detail in the
paragraphs below. We anticipate this
method for reporting controlled
emissions will ensure that abatement
systems have been properly installed,
operated and maintained during each
reporting period and that best available
measured DRE values are used to
estimate and report emissions.
BILLING CODE 6560-50-P
which controlled emissions will be reported was
properly installed, operated, and maintained.
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BILLING CODE 6560-50-C
Proper Installation, Operation, and
Maintenance. We are proposing that all
facilities that use abatement systems
and would like to reflect these
emissions reductions in their annual
emissions estimations be required to
document and certify the abatement
equipment’s proper installation,
operation, and maintenance. There are
many manufacturers, and for each
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manufacturer multiple models, that are
marketed as fluorinated GHGdestruction capable (Beu, 2005). While
some abatement systems may be capable
of destroying some fluorinated GHGs,
they may not be effective in abating CF4
(Beu, 2005), which in some processes
can constitute 10 percent—20 percent
(by volume) of fluorinated GHG exhaust
composition (EPA, 2006). It appears that
this variability may be partially
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attributable to installation as well as
operating and maintenance practices
although variations in how destruction
is measured may also contribute to this
variability (Beu, 2005). Evidence
indicates abatement devices must be
properly installed to ensure
achievement of the manufacturer’s
design goals. For this reason, we
propose devices be installed in
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accordance with manufacturers’
specifications.
In terms of operation and
maintenance, we also propose to require
that abatement systems be operated and
maintained in accordance with the
manufacturers’ specifications. It is well
known across the industry that
abatement system performance varies
greatly depending on a variety of
abatement device and process
parameters such as temperature, flow
and exhaust composition (Beu, 2005,
EPA 2006, 2007)). Our proposed
requirement that abatement systems be
operated and maintained in accordance
with manufacturers’ specifications is
intended to ensure best performance.
We understand that many times a
facility may have an independent
quality assurance expert certify the
installation, operation, and maintenance
of abatement equipment. We are
considering the inclusion in the final
rule, a requirement for annual, on-site
independent inspections of abatement
system installation, operation, and
maintenance, which could include a
review of records and physical
inspection of installed equipment. We
request comment on whether to require
an independent quality assurance audit/
inspection for abatement system
installation, operation, and
maintenance.
Accounting for Abatement System
Uptime. We are proposing that facilities
account for abatement systems’ uptime
to report controlled emissions. Uptime
is the total time during the reporting
year when the abatement systems for
which controlled emissions are being
reporting was properly installed,
operated, and maintained. Uptime is
calculated as the sum of time during the
reporting period that an abatement
system is in a standby, productive, and
engineering state as described in SEMI
Standard E10–0304, Specification for
Definition and Measurement of
Equipment Reliability, Availability, and
Maintainability (2004). Abatement
system uptime is expressed as the sum
of an abatement system’s operational
productive, standby, and engineering
times divided by the total operations
time of its associated manufacturing
tool. For example, the time during
which a system is in by-pass mode,
undergoing maintenance, or not
operating with O2-flow (in the case of a
CF4 combustion system) is not included
in uptime. An exception to this is time
during which exhaust flows are passed
through a redundant abatement system
that is in the same abatement system
class (discussed below) as the primary
abatement system. Such time may be
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included in the uptime of the primary
system.
We are proposing this requirement
because we anticipate accounting for
uptime (i.e., tracking incidents when
abatement systems may be ‘‘bypassed’’
or otherwise not in service) will
produce a more accurate emissions
estimate. We request comment on our
proposal to account for and report the
uptime of abatement systems. We also
request detailed information on how
uptime may be monitored and
calculated.
EPA Default DRE Value. In addition
to certifying that an abatement system is
installed, operated, and maintained
according to manufacturers’
specifications, and accounting for the
system’s uptime, the first approach we
are proposing includes the following
two key elements: (1) Certification that
the abatement system is specifically
designed for fluorinated GHG and N2O
abatement, and (2) an EPA default DRE
value. By applying the EPA default DRE
value, the facility is not required to
measure the DRE of their abatement
system(s). We are proposing the use of
a default DRE value of 60 percent if the
facility certifies that the abatement
systems for which this value is applied
are specifically designed for fluorinated
GHG and N2O abatement.
To develop the default DRE of 60
percent, we reviewed the individual
DREs measured under our in-fab DRE
measurement program and selected
those that constituted discrete values 16
for systems that had been properly
installed, operated and maintained. Of
the data from the DRE measurement
program, those that met the stated
criteria were values for CF4. We
calculated the mean and the lower one
sided tolerance interval of the (CF4) DRE
data set. This yielded an understated,
default DRE, reducing the likelihood
that the DRE of any particular system
will be either overestimated or greatly
underestimated. For additional
information on how the EPA default
DRE was developed, please refer to the
Electronics Manufacturing TSD.
While we are now proposing the use
of an EPA default DRE value, consistent
with our initial proposal we are not
planning to permit use of the 2006 IPCC
default factors or the manufacturer’s
DRE values. We are not permitting their
use because once installed, abatement
equipment may fail to achieve the
default or a supplier’s claimed DRE.
DRE performance claimed by equipment
suppliers and upon which the 2006
16 Using
data available from the in-fab DRE
measurement program, we selected discrete
numbers rather than the lower bound (e.g., ≥ 99%).
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IPCC default factors were based may
have been incorrectly measured due to
a failure to account for the effects of
dilution (e.g., CF4 can be off by as much
as a factor of 20 to 50 and C2F6 can be
off by a factor of up to 10 [Burton,
2007].) This understanding is supported
by industry assessments as presented in
Beu, 2005.
We are permitting the use of our
default DRE value because we estimate
that it strikes an appropriate balance
between being conservative and being
representative where equipment is
properly operated and maintained. Our
default DRE value was calculated using
data from measurements assured to
properly account for the effects of
dilution. In addition, the tested systems
were properly installed, operated, and
maintained.
We request comment on our proposed
default DRE value, and additional data
and supporting documentation on DREs
from studies that have been conducted
on properly installed, operated, and
maintained abatement systems and
consistent with EPA’s DRE Protocol.
Proper Measurement of the
Abatement DRE. The second proposed
approach for quantifying, documenting,
and reporting controlled emissions from
abatement systems, described below,
would require proper measurement of
the abatement system DRE in addition
to documentation to certify that the
abatement system is installed, operated,
and maintained in accordance with
manufacturers’ specifications, and
accounting for uptime.
Consistent with our initial proposal,
this second proposed method permits
facilities to account for destruction if
the abatement system performance is
measured and verified using EPA’s DRE
Protocol. To measure DRE, we propose
requiring facilities to conduct annual
sampling through a random sampling
abatement system testing program
(RSASTP), spanning all abatement
classes using the methods outlined in
EPA’s DRE Protocol. ‘‘Class’’ refers to a
category of abatement systems grouped
by manufacturer model number(s) and
by gas for which the system is used to
abate, including N2O and CF4 direct and
by-product formation, and all other
fluorinated GHG gas direct and byproduct formation.17 ‘‘Classes’’ may also
include any other abatement systems for
which the reporting facility wishes to
report controlled emissions provided
that class is identified. For each class,
the representative or average DRE
17 CF is a very stable chemical and especially
4
difficult to effectively destroy. It may be used as an
input gas and generated as a byproduct of other
fluorinated GHG process reactions.
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factors would then be applied to the yet
unmeasured abatement devices of that
class.
An annual representative sample as
part of the RSASTP would consist of
three or 20 percent of installed
abatement systems, whichever is
greater, for each class each year,
measuring the DRE for a different three
or 20 percent set of systems each year.
Where 20 percent of total abatement
systems do not equal a whole number,
the number of systems to be tested
would be rounded up to the nearest
integer (e.g., 16 abatement devices, 20
percent of which equals 3.2; therefore,
four abatement systems would be
measured each year). Using the RSASTP
and our rounding convention, all
systems in each class would be tested
within a five-year period. EPA is
seeking comment on the required
frequency of abatement system
performance measurement.
When reporting controlled emissions
from manufacturing, we propose that
the facility either use the measured DRE
or, in those instances where an
individual abatement system has not yet
undergone proper DRE testing, a simple
average of the measured DREs for
systems of that class would be used. If
redundant abatement systems were used
during periods of maintenance or repair,
then we propose that the measured or
average DRE for that system’s class
would be used. In any of these cases, the
DRE used to report emissions would be
adjusted to account for the actual
uptime of the system. For example, if
the uptime for a device is 98 percent
over the reporting period, then the
measured DRE (or class average of
measured DREs when a system has not
yet been measured) would be multiplied
by 0.98.
Under the RSASTP, all systems in
each class would be tested within a fiveyear period, after which the process
would be repeated as long as controlled
emissions were reported. There are two
reasons for requiring the DRE to be
measured for each abatement device
over a time period and by specific class.
Some fluorinated GHGs, particularly
CF4, are harder to destroy than others;
thus, the performance of abatement
systems with one fluorinated GHG
cannot necessarily be assumed to apply
to other fluorinated GHGs.18 Second,
even if abatement systems rely on the
18 There are many manufacturers, and for each
manufacturer many models, that are marketed as
fluorinated GHGs-destruction capable (Beu, 2005).
While some abatement devices may be capable of
destroying some fluorinated GHGs, they may not be
effective in abating CF4 (Beu, 2005), which in some
processes can constitute 10%–20% (by volume) of
fluorinated GHGs exhaust composition (EPA, 2006).
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same operating principle (e.g., thermal
oxidation) and are used on the same
gases, their performance can vary
depending on their operation and
maintenance.19 Moreover, maintenance
that is adequate for abatement systems
in some applications may not be
adequate for abatement systems in
others (e.g., those that handle high
volumes of etched or cleaned material,
which can be deposited inside
abatement equipment and clog lines).
This argues for gradually testing all of
the abatement systems within a class,
and for retesting individual abatement
systems over time.
We request comment on the method
proposed for proper measurement of
DRE at a facility and the proposed
RSASTP for abatement systems by class.
6. Selection of Procedures for Estimating
Missing Data
In general, it is not expected that data
to estimate emissions from electronics
manufacturing would be missing; gas
consumption data and indicators of
activity data (e.g., wafer passes) is
collected as business as usual. For this
reason, we are not proposing procedures
for estimating missing data from
emissions from cleaning, etching or
deposition processes. Because our
proposal includes an EPA default DRE
value for estimating and reporting
controlled emissions, we propose that
no missing data procedures would
apply.
When estimating heat transfer fluid
emissions during electronics
manufacture, the use of the massbalance approach requires facilities to
correct records for all inputs. Should the
facility be missing records for a given
input, heat transfer fluid emissions may
be estimated using the arithmetic
average of the emission rates for the year
immediately preceding the period of
missing data and the months
immediately following the period of
missing data. Alternatively it may be
possible that the heat transfer fluid
supplier has information in their
records for the facility.
7. Selection of Data Reporting
Requirements
We are proposing that owners and
operators be required to report
fluorinated GHG and N2O emissions for
the facility for each electronics
manufacturing process as well as all
heat transfer fluid use. In addition,
facilities would be required to report the
19 Some variability in performance may be
partially attributable to installation as well as
operating and maintenance practices although
variations in how destruction is measured may also
contribute to this variability (Beu, 2005).
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following: method used to calculate
emissions; factors used for gas
utilization and by-product formation
rates and the source for each factor for
each fluorinated GHG and N2O;
production in terms of substrate surface
area (e.g., silicon, PV-cell, LCD); for
each fluorinated GHG and N2O, annual
gas consumed during the reporting year
and gas- and facility-specific heel
factors used; the apportioning factors
used, a description of the engineering
model used for apportioning gas usage,
and facility-wide consumption
estimates based upon development of
the apportioning factors, independent of
the consumption value calculated using
purchase records; fraction of each gas
fed into each process type that is fed
into tools with abatement systems;
descriptions and information about
abatement systems through which
fluorinated GHGs and N2O flow; inputs
in the mass-balance equation (for heat
transfer fluid emissions); and example
calculations. Where process categories
defined in the Refined Method and/or
default gas utilization and by-product
formation rates are not used, we propose
that facilities provide descriptions of
individual processes or processes
categories used to estimate emissions
consistent with the IPCC Tier 3 method.
For each abatement system for which
a facility is reporting controlled
emissions, we propose that facilities be
required to report the following:
certification that the abatement device is
installed, operated, and maintained
according to manufacturers’
specifications; the uptime and the
calculations to determine uptime for
that reporting year; the DRE used (i.e.
either the EPA default DRE value or a
properly measured DRE); and
documentation for the EPA default DRE
value or a properly measured DRE.
These data form the basis of the
calculations and are needed for us to
understand the reported emissions and
verify their reasonableness.
8. Selection of Records That Must Be
Retained
We propose that facilities keep
records of data used to estimate
emissions, records supporting values
used to estimate emissions, purchase
records, and invoices for gas purchases
and sales. For those facilities that use
facility-specific, recipe-specific gas
utilization and by-production formation
rates, we are proposing that the
following records be maintained:
documentation that the rates were
measured using the 2006 ISMI
Guidelines, documentation that the
measurements made are representative
of fluorinated GHG and N2O emitting
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processes at the facility, and the date
and results of the initial and any
subsequent tests to determine process
tool gas utilization and by-product
formation rates.
For those facilities that are reporting
controlled emissions, we propose that
the following records be kept:
documentation to certify that each
abatement device used at the facility is
installed, maintained, and operated in
accordance with manufacturers’
specifications; records of the uptime
and the calculations to determine
uptime; abatement system calibration
and maintenance records;
documentation for the EPA default DRE
value or a properly measured DRE.
These records consist of values that
are directly used to calculate the
emissions that are reported and are
necessary to enable verification that the
GHG emissions monitoring and
calculations are done correctly.
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B. Fluorinated Gas Production
1. Overview of Reporting Requirements
Under this proposal, subpart L would
require facilities that produce
fluorinated gases to report their
fluorinated GHG emissions from
fluorinated gas production and
transformation and from fluorinated
GHG destruction. Fluorinated gases
include fluorinated GHGs (HFCs, PFCs,
SF6, NF3, HFEs, etc.), CFCs, and HCFCs.
Certain emissions subject to other
subparts or authorities are excluded
from this subpart. Specifically,
emissions of HFC–23 from HCFC–22
production are addressed under subpart
O and are therefore excluded from this
subpart. Similarly, as discussed in the
Final MRR, emissions of ozone
depleting substances (e.g., CFCs and
HCFCs) are subject to Title VI of the
CAA and are therefore excluded from
this subpart.
Under this proposed rule, facilities
would be required to estimate their
emissions from fluorinated GHG
production processes using either a
mass-balance approach or an approach
based on measured (or in some cases,
calculated) emission factors. Facilities
would be required to estimate their
emissions from CFC and HCFC
production processes and from
fluorinated gas transformation processes
using an emission-factor-based
approach. Consistent with the Final
MRR, this proposal would establish an
annual frequency for reporting and
would include provisions to ensure the
accuracy of emissions data through
monitoring, reporting, and
recordkeeping requirements. Reporting
would be at the facility level.
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2. Summary of Major Changes Since
Initial Proposal
In the April 2009 proposed mandatory
GHG reporting rule (74 FR 16448; April
10, 2009), the fluorinated GHG
production source category was
included as proposed subpart L. That
initial proposal would have required
reporting from facilities emitting more
than 25,000 mtCO2e from fluorinated
GHG production and other source
categories (e.g., stationary combustion).
We proposed monitoring based on a
daily mass-balance or yield approach
that included measurements of the
reactants and the fluorinated GHG
product and byproducts. Under that
approach, facilities would have had to
calculate the difference between the
expected production of each fluorinated
GHG based on the consumption of
reactants and the measured production
of that fluorinated GHG, accounting for
yield losses related to byproducts and
wastes and accounting for streams that
were recaptured and destroyed.
Facilities would have been required to
measure the various inputs and outputs
daily using scales and flow meters with
an accuracy and precision of 0.2 percent
of full scale, and to measure
concentrations in streams using
methods with an accuracy and precision
of 5 percent. (For more detailed
information on the initial proposal, see
the fluorinated gas production section of
the April 10, 2009 proposed rule.)
We received numerous comments on
the proposed approach. Commenters
stated that there may be significant
uncertainty associated with the massbalance approach, that EPA’s stated
accuracy and precision requirement of
0.2 percent for flow meters and weigh
equipment was costly and not
technically achievable for many
streams, that daily calculations were
excessive and likely to introduce errors,
that it was sometimes impracticable to
perform a mass-balance for more than
one reactant, and that the mass-balance
approach was not appropriate for batch
processes.
Commenters also suggested
alternatives to the mass-balance
approach. Several commenters focused
on the use of site-specific or processspecific emission factors. These
commenters noted that many facilities
in this source category already measure
emissions during performance testing to
verify compliance with their emission
limits under other EPA regulations.
Commenters also noted that some
fluorinated GHG producers currently
estimate their emissions of fluorinated
GHG using the emission factor approach
and that this approach is both more cost
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effective and more accurate than the
mass-balance approach. One commenter
using the emission factor approach
stated that the estimated uncertainty of
its overall fluorinated GHG emissions
estimate was 13 percent (expressed as
one standard deviation) and that the
uncertainty associated with the
estimates that it would develop using
the proposed mass-balance approach
would be significantly higher.
Commenters suggested both emissions
testing and chemical engineering
calculations as appropriate techniques
to develop site-specific emissions
factors.
Partly in response to the comments
received on the April 2009 proposed
MRR (74 FR 16448; April 10, 2009),
today’s proposed subpart L rule
incorporates a number of changes
compared to the original proposal,
including but not limited to:
• Inclusion of additional emission
estimation methodologies, including
process-specific, site-specific emission
factors, which allow facilities to
estimate emissions using methods that
may already be in place;
• Revisions to the mass-balance
approach, including provisions to allow
monthly rather than daily monitoring;
greater flexibility in the accuracy and
precision of flowmeters, weigh scales,
and concentration measurements (as
long as the final estimate meets an
overall accuracy and precision
requirement); and the use of one rather
than two reactants in the mass-balance
equation;
• Inclusion of fluorinated GHGs
emitted as a by-product of the
production of CFCs and HCFCs; and
• Inclusion of fluorinated GHGs
emitted as a feedstock or by-product of
transformation processes that are not
intended to produce any fluorinated
gases (when those transformation
processes are co-located with
fluorinated gas production processes).
3. Definition of Source Category
This source category covers emissions
of fluorinated GHGs that occur during
the production of fluorinated gases,
where fluorinated gases include
fluorinated GHGs (HFCs, PFCs, SF6,
NF3, and fluorinated ethers, among
others), CFCs, and HCFCs (except
HCFC–22).20 It also covers emissions of
20 In the April 2009 proposal, EPA requested
comment on whether emissions of fluorinated
GHGs from CFC and HCFC production processes
should be subject to the subpart L reporting
requirements. While no public comments were
received on this topic, EPA has determined that
HFCs and PFCs are likely to be generated during the
production of several CFCs and HCFCs, and that the
quantities generated may be significant. According
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fluorinated GHGs from transformation
and destruction processes that occur at
fluorinated gas production facilities.
EPA estimates that total emissions from
this source category were 10.6 million
metric tons of CO2e in 2006.
Emissions from fluorinated gas
production facilities can occur from
vents, from leaks at flanges and
connections in the production line, and
from control devices (e.g., thermal
oxidizers). Undesired by-products may
be deliberately vented, and some
product (or reactant) may be vented at
the same time due to imperfect
separation of by-products, products, and
reactants. Emissions can also occur
during occasional service work on the
production equipment, during blending
and recycling of fluorinated GHGs, and
during the evacuation and filling of
tanks or other containers that are
distributed by the producer (e.g., on
trucks and railcars).
Fluorinated GHG Emissions from
Fluorinated GHG Production. Emissions
that occur during fluorinated GHG
production include fluorinated GHG
products that are emitted before the
production measurement and
fluorinated GHG byproducts that are
generated and emitted either without or
despite recapture or destruction.21
These emissions are not counted as
‘‘mass produced’’ under the final
requirements for suppliers of industrial
GHGs in 40 CFR part 98, subpart OO (74
FR 56260; October 30, 2009).
Fluorinated GHG emissions from U.S.
facilities producing fluorinated GHGs
are estimated to range from 0.8 percent
to 2 percent of the amount of fluorinated
GHG produced, depending on the
facility. In 2006, 12 U.S. facilities
produced over 350 million metric tons
CO2e of HFCs, PFCs, SF6, and NF3, and
an additional 6 facilities produced
approximately 1 million metric tons
CO2e of fluorinated anesthetics. Based
on an emission rate of 1.5 percent,
facilities are estimated to have emitted
to the 2006 IPCC Guidelines and fluorinated gas
producers, production of CFCs and HCFCs can
generate and emit fluorinated GHGs such as various
HFCs and some PFCs. (These HFCs exclude HFC–
23 generated during HCFC–22 production, which is
already covered under Subpart O). These emissions
are by-product emissions that occur due to the
chemical similarities between HFCs, PFCs, HCFCs,
and CFCs and the common use of halogen
replacement chemistry to produce them. HFC–23
generated during HCFC–22 production is already
covered under Subpart O.
21 Byproducts that are emitted or destroyed at the
production facility are excluded from the Subpart
OO definition of ‘‘produce a fluorinated GHG.’’ Any
HFC–23 generated during the production of HCFC–
22 is also excluded from this definition, even if the
HFC–23 is recaptured. However, other fluorinated
GHG byproducts that are recaptured for any reason
are considered to be ‘‘produced.’’
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approximately 5.3 million metric tons
CO2e of HFCs, PFCs, SF6, and NF3, and
approximately 15,000 metric tons CO2e
of fluorinated anesthetics.
Fluorinated GHG Emissions from CFC
and HCFC Production. Our proposal to
include fluorinated GHG emissions that
occur during CFC and HCFC production
processes is based on two important
considerations. First, while the quantity
of by-product emissions is uncertain, we
believe that it is significant and could be
similar to total estimated emissions
from fluorinated GHG production.
Second, many CFC and HCFC
production processes are co-located
with fluorinated GHG production
facilities, allowing for efficiencies in the
application of estimation methods and
monitoring and reporting
infrastructures. These issues are
discussed in more detail in the
Fluorinated Gas Production Technical
Support Document in the docket for this
rulemaking (EPA–HQ–OAR–2009–
0927).
Although we do not have precise
estimates of the magnitude of
fluorinated GHG emissions from
production of CFCs and HCFCs, we
estimate that if CFC and HCFC
production processes emitted
fluorinated GHGs equivalent to one
percent of their CFC and HCFC
production (excepting HCFC–22
production), U.S. emissions from this
source would be 5.3 mtCO2e, the same
as from fluorinated GHG production.
EPA requests comment on the extent to
which fluorinated GHGs are generated
and emitted during CFC and HCFC
production. EPA also requests comment
on the extent to which fluorinated GHGs
may be generated and emitted during
production of other ozone-depleting
substances such as methyl chloroform
and carbon tetrachloride and on
whether such emissions should be
reported under this rule.
CFCs and HCFCs are often produced
at the same facilities that produce
fluorinated GHGs. In these cases, these
facilities would need to quantify their
fluorinated GHG emissions from a few
processes in addition to those producing
fluorinated GHGs. In other cases, CFCs
or HCFCs are produced at facilities that
do not produce fluorinated GHGs. In
these cases, which EPA estimates
include 2 facilities, the facilities would
not have been covered by the initially
proposed subpart L, but would be
covered by today’s proposal. This
coverage is reflected in the threshold
analysis discussed below.
Fluorinated GHG Emissions from
Other Processes. Facilities producing
fluorinated gases would also be required
to report emissions of fluorinated GHG
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18671
feedstocks that occur during the
transformation of these feedstocks into
other fluorinated substances such as
fluoropolymers, as well as emissions of
fluorinated GHGs that occur during
destruction of fluorinated GHGs that are
removed from the supply of industrial
gases.
The reasons for requiring reporting of
fluorinated GHG emissions from
transformation processes that are colocated with fluorinated gas production
processes are similar to those for
requiring reporting of fluorinated GHG
emissions from CFC and HCFC
production. First, although EPA does
not have precise estimates of the
magnitude of fluorinated GHG
emissions from transformation
processes, discussions with
fluoropolymer producers indicate that
these emissions do occur. Second,
facilities could apply similar methods
and monitoring approaches to estimate
emissions from both fluorinated gas
production and fluorinated gas
transformation. The rationale for
requiring reporting of emissions from
the destruction of fluorinated GHGs that
are removed from the supply of
industrial gases is discussed below
under Relationship between emissions
covered under subpart L and those
covered under subpart OO.
EPA is also considering requiring
reporting of fluorinated GHG emissions
from two other types of processes. The
first type includes processes (other than
CFC and HCFC production processes) in
which fluorinated GHGs are neither
reactants nor products of the process but
are nevertheless generated as byproducts or intermediates. To the extent
that such processes may generate or
emit significant amounts of fluorinated
GHGs, it may be appropriate to require
reporting of those emissions. This
would be particularly true if the
processes were co-located with
fluorinated GHG production processes,
permitting effiencies in the application
of estimation methods and reporting
infrastructures. EPA requests comment
on whether, how often, and where such
processes occur (i.e., at fluorinated gas
production facilities or elsewhere). The
second type of process includes
fluorinated gas transformation processes
that are not co-located with fluorinated
gas production facilities. Again, it may
be appropriate to require reporting of
fluorinated GHG emissions from such
processes if these emissions are
significant. EPA requests comment on
both of these options.
Relationship between emissions
covered under subpart L and those
covered under subpart OO. Subpart L
would require reporting from many of
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the same facilities (fluorinated GHG
producers) that are required to report
under subpart OO, which contains the
industrial gas supply reporting
provisions of the final MRR. In general,
subpart OO is intended to capture the
quantities of fluorinated GHGs that are
entering and leaving the U.S. supply of
industrial gases,22 while subpart L is
intended to capture the quantities of
fluorinated GHGs emitted at fluorinated
gas production facilities.
There are several areas of possible
overlap between the emissions that
could be reported under this subpart
and those reported under subpart OO.
The areas of overlap all concern
emissions that occur at the fluorinated
GHG production facility after
(downstream of) the fluorinated GHG
production measurement. These include
emissions from:
• Fluorinated GHG transformation
processes (including polymerization),
• Destruction of fluorinated GHGs
that are removed from the supply of
industrial gases,
• Cylinder filling (if this occurs after
the production measurement),
• Blending of fluorinated GHGs,
• Recycling or reclamation of
fluorinated GHGs, and
• Evacuation of fluorinated GHG
heels from returned cylinders.
The MRR is intended to inform a
range of possible policies for reducing
emissions of GHGs, including both
upstream and downstream approaches.
Under a policy that focused primarily
on supply, the fluorinated GHGs added
to and subtracted from the gas supply
would be tracked, and only the on-site
emissions that occurred before
(upstream of) the fluorinated GHG
production measurement would need to
be covered for completeness. On-site
emissions that occurred after the
production measurement would be
assumed to be captured by the
production measurement. Under a
policy that focused on actual emissions
(i.e., ‘‘downstream coverage’’) rather than
supply, on-site emissions that occurred
both before and after the production
measurement would need to be tracked.
Maintaining flexibility to adopt either
upstream or downstream approaches
argues for some counting under L of
emissions that are counted upstream (as
supply) under OO.23 (See the October
30, 2009 Final MRR, 74 FR 56260, for
more discussion of the rationale for
including both upstream and
downstream emissions under the rule.)
As noted above, EPA is proposing to
require reporting of fluorinated GHG
emissions from transformation and
destruction processes that are located at
fluorinated gas production facilities.
However, EPA is also considering
requiring reporting of fluorinated GHG
emissions from the other activities that
occur at fluorinated GHG production
facilities downstream of the production
measurement. EPA requests comment
on the magnitude of these other on-site
emissions and on whether or not they
should be required to be reported under
subpart L.
4. Selection of Reporting Threshold
Under today’s proposed rule, owners
and operators of fluorinated gas
production facilities would be required
to estimate and report GHG emissions if
those emissions, including both
combustion and fluorinated GHG
emissions, would exceed 25,000 mtCO2e
in the absence of control technology
(e.g., thermal oxidation).24
In developing the threshold, we
considered multiple controlled and
uncontrolled emissions thresholds,
including 1,000, 10,000, 25,000, and
100,000 metric tons CO2e. For
fluorinated GHG production processes
(including fluorinated anesthetics
production processes), uncontrolled
(pre-control) emissions were estimated
by multiplying a factor of 3 percent by
the estimated production at each
facility. For CFC and HCFC production
processes (except for HCFC–22
production processes), uncontrolled
emissions were estimated by
multiplying a factor of 2 percent by the
estimated production at each facility.
Uncontrolled emissions are strongly
influenced by by-product generation
rates, which are known to vary between
zero and several percent for fluorinated
gas production processes; thus, these
estimates are uncertain. Controlled
emissions were assumed to be half of
uncontrolled emissions at each facility.
Because EPA has little information on
combustion-related emissions at
fluorinated gas production facilities,
these emissions were not included in
the analysis. The results of the analysis
for production of HFCs, PFCs, SF6, NF3,
CFCs, and HCFCs are shown in Tables
7 and 8 of this preamble.
TABLE 7—THRESHOLD ANALYSIS FOR FLUORINATED GHG EMISSIONS FROM PRODUCTION OF HFCS, PFCS, SF6, NF3,
CFCS, AND HCFCS
[Uncontrolled Emissions]
Total national
emissions
(metric tons
CO2e )
Threshold level
(metric tons CO2e/r)
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1,000 ........................................................................................
10,000 ......................................................................................
25,000 ......................................................................................
100,000 ....................................................................................
22 Specifically, subpart OO tracks the quantities of
fluorinated GHGs that are (1) produced, (2)
transformed, (3) destroyed, (4) imported, and (5)
exported.
23 In theory, it might be possible to track
emissions from transformation and destruction
simply using quantities reported under OO.
However, this would require that (1) fluorinated
GHGs that are produced only to be transformed or
destroyed be tracked separately, (2) production,
transformation, and destruction be measured to
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Number
of facilities
10,600,000
10,600,000
10,600,000
10,600,000
Emissions covered
Metric tons
CO2e
14
14
14
14
very good precision and accuracy (e.g., 0.2 percent),
and (3) that no by-products be formed or emitted
during these processes. If all of these conditions
were met, emissions could be equated to the
differences between production and transformation
and production and destruction. In practice,
however, it would be difficult to meet all of these
conditions.
24 Following the precedents set by other Clean Air
Act regulations, EPA is using the term
‘‘uncontrolled’’ to describe such emissions.
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Facilities covered
Percent
10,600,000
10,600,000
10,600,000
10,600,000
100
100
100
100
Number
14
14
14
13
Percent
100
100
100
93
Specifically, EPA is proposing to define
‘‘uncontrolled fluorinated GHG emissions’’ as a gas
stream containing fluorinated GHG which has
exited the process (or process condenser, where
applicable), but which has not yet been introduced
into an air pollution control device to reduce the
mass of fluorinated GHGs in the stream. The term
does not imply that the emissions are never
controlled, but is synonymous with ‘‘pre-control
emissions.’’
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TABLE 8—THRESHOLD ANALYSIS FOR FLUORINATED GHG EMISSIONS FROM PRODUCTION OF HFCS, PFCS, SF6, NF3,
CFCS, AND HCFCS
[Controlled Emissions]
Total national
emissions
(metric tons
CO2e )
Threshold level
(metric tons CO2e/r)
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1,000 ........................................................................................
10,000 ......................................................................................
25,000 ......................................................................................
100,000 ....................................................................................
As can be seen from the tables, most
HFC, PFC, SF2e , NF3, CFC, and HCFC
production facilities would be covered
by all the thresholds considered.
Although we do not have facilityspecific production information for
producers of fluorinated anesthetics, we
believe that few or none of these
facilities are likely to have uncontrolled
emissions above the proposed
threshold.
EPA is proposing to use a threshold
based on uncontrolled (pre-control)
rather than controlled (post-control)
emissions to ensure that facilities that
generate significant quantities
fluorinated GHGs fully characterize and
quantify their emissions, even if they
initially believe those emissions to be
small. Discussions with fluorinated gas
manufacturers indicate that
occasionally, fluorinated GHG byproducts may be generated and emitted
from production processes
unexpectedly. If these by-products are
relatively difficult to destroy (e.g., CF4),
facilities’ post-control emissions may be
significantly higher than expected.25
The initial scoping test described in the
next section is intended to identify the
full range of fluorinated GHGs in
potentially emitted streams. Applying
the full methodologies on the basis of
the initial scoping study will provide
EPA and the facilities with critical
information on the extent to which
control technologies are actually
reducing emissions and therefore on the
actual emissions from the facility.
EPA is requesting comment on an
alternative approach in which all
fluorinated gas production facilities,
regardless of their estimated pre-control
emissions, would analyze their
emissions using the initial scoping test
discussed in the next section. This
approach would ensure that facilities
25 It is important to note that even if a threshold
based on controlled emissions were adopted, failure
to report as required when a source’s actual
emissions were above that threshold would be a
violation of these regulations and the Clean Air Act.
Lack of test data or other errors of omission do not
excuse such violations as the Clean Air Act is a
strict liability statute.
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Number
of facilities
10,600,000
10,600,000
10,600,000
10,600,000
Emissions covered
Metric tons
CO2e
14
14
14
14
understood the identities, and therefore
the GWPs, of the fluorinated GHGs
potentially emitted. EPA requests
comment on this option, as well as on
the option of simply eliminating the
threshold for fluorinated gas production
facilities and making this an ‘‘all-in’’
category.
As is true for the source categories
covered by the Final MRR, fluorinated
GHG production facilities could cease
reporting if their controlled (postcontrol) emissions were less than 25,000
mtCO2e per year for five consecutive
years or less than 15,000 mtCO2e per
year for three consecutive years. This
approach may be appropriate if control
technologies are effective and there is
no evidence of unexpected uncontrolled
emissions. However, EPA requests
comment on an alternative ‘‘off-ramp’’
for this source category. Under this
alternative approach, the 25,000 and
15,000 mtCO2e triggers would be based
on the level of emissions that is
estimated before accounting for the use
of any control technology (e.g., thermal
oxidation). EPA is requesting comment
on this approach because emissions can
become quite large if the destruction
device malfunctions, is not operated
properly, or is not used for some other
reason.
As noted above, EPA estimates that
under this proposal, all HFC, PFC, SF6,
and NF3 production facilities would be
covered, and few or no anesthetics
producing facilities would be covered.
However, it is possible that EPA has
underestimated total pre-control
emissions from anesthetics. In its
threshold analysis for fluorinated GHG
production, EPA has assumed that
emissions have GWPs similar to those of
the product produced. However,
fluorinated anesthetics are
hydrofluoroethers, and other HFE
production processes of which EPA is
aware generate by-products with higher
GWPs than the product. EPA requests
comment on this issue.
A full discussion of the threshold
selection analysis is available in the
revised Fluorinated Gas Production
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Facilities covered
Percent
10,600,000
10,600,000
10,600,000
10,300,000
100
100
100
97
Number
Percent
14
14
14
10
100
100
100
71
TSD. For specific information on costs,
including unamortized first year capital
expenditures, please refer to the
Economic Impact Analysis (EIA) for this
rulemaking.
5. Selection of Proposed Monitoring
Methods
a. Summary of Proposed Monitoring
Methods
We are proposing to allow facilities to
use either a mass-balance approach or a
site-specific, process-vent-specific
emission factor (PSEF) approach to
estimate their fluorinated GHG
emissions from fluorinated GHG
production. Facilities would be required
to use the PSEF approach to estimate
their fluorinated GHG emissions from
CFC and HCFC production or from
fluorinated gas transformation. The
mass-balance approach is similar to that
proposed in April, 2009, but has been
modified in some details in response to
comments. Facilities using either
approach would be required to perform
a one-time scoping test to identify the
fluorinated GHGs in certain emitted
streams and to verify the destruction
efficiency (DE) of any destruction
devices every five years. These
approaches are discussed in more detail
below.
b. Initial Scoping Test of Potentially
Emitted Fluorinated GHGs
In today’s action, we are proposing
that facilities that produce fluorinated
gases perform an initial scoping test
(proposed 40 CFR part 98.124(a)). The
purpose of the scoping test is to ensure
that all of the fluorinated GHGs that
occur in emitted streams are properly
identified. EPA is concerned that
without the test, facilities could
mischaracterize the set of fluorinated
GHGs that was emitted, leading to
inaccurate emissions estimates. We are
aware that in general, facilities will have
already identified most if not all of the
fluorinated GHGs occurring in emitted
streams during process design and
bench and pilot scale testing. However,
as noted above, we are also aware of
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situations in which producers have
analyzed process or emissions streams
and found fluorinated GHGs that they
were not expecting. Such by-product
fluorinated GHGs can have high GWPs,
making their CO2-equivalent emissions
significant.
Under this requirement, which would
be one-time for any given process,
facilities would be required to sample
the vent(s) or stream(s) that, alone or
together, would be expected to contain
all the fluorinated GHG by-products of
the process. Facilities would be required
to use EPA Method 18 (GC/ECD, GC/
MS), EPA Method 320 (FTIR), or ASTM
D6348–03 (FTIR) to identify fluorinated
GHGs that occur in concentrations
above 0.1 percent in emitted streams.
For facilities using the mass-balance
approach, the scoping test could be used
to determine whether some emissions
that are assumed to occur in the form of
the product are actually occurring as byproducts. For facilities using the
process-vent-specific emission factor
approach (PSEF), the test would identify
by-products to measure in subsequent
emissions testing to develop emission
factors.
To avoid the need to survey a large
number of processes with relatively
small fluorinated GHG emissions, EPA
is proposing to limit the scoping test
requirement to processes that would
emit more than one metric ton per year
of fluorinated GHGs before the
imposition of control technologies. We
are proposing a limit in tons of
fluorinated GHGs rather than in tons of
CO2e because the identities, and
therefore the GWPs, of some fluorinated
GHG constituents of the stream may not
be known. Acquiring this information is
the purpose of the test. We developed
the one-ton limit by starting with a limit
of 10,000 mtCO2e for each process and
making the reasonably conservative
assumption that the unknown
fluorinated GHG could have a GWP of
10,000. For purposes of estimating the
mass of fluorinated GHG emitted from
the process, facilities could use the
same types of engineering calculations
that they would use to determine
whether process vent testing was
required under the PSEF approach
(described in more detail below). They
could assume that the mass of carbon,
fluorine, or another relevant element is
emitted in the form of fluorinated GHGs
that were previously identified in
bench- or pilot-scale testing.
We are proposing that the one-metricton trigger be applied to emissions
before rather than after control because
some byproducts, particularly CF4, are
very difficult to destroy. If these byproducts occurred unexpectedly in a
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stream and if the trigger were applied to
emissions after control, the facility
would underestimate controlled
emissions. Consequently, the facility
could fail to undertake the scoping test
when it was actually appropriate and
could overlook the occurrence and
emissions of the by-products.26 We are
proposing that facilities test the streams
before the control device because
emissions streams are often diluted
during destruction processes (e.g., due
to fuel and air feeds), which would
make it more difficult to detect and
identify fluorinated GHGs that survived
the destruction process. However, we
request comment on this requirement as
well as on the scoping test requirement
as a whole.
c. Mass-Balance Approach
We are proposing that facilities
producing fluorinated GHGs have the
option of monitoring emissions using
the mass-balance approach. In this
approach, facilities would calculate the
difference between the expected
production of each fluorinated GHG
based on the consumption of reactants
and the measured production of that
fluorinated GHG, accounting for yield
losses related to byproducts (including
intermediates permanently removed
from the process) and wastes. Yield
losses that could not be accounted for
would be attributed to emissions of the
fluorinated GHG product. This
calculation could be performed for any
fluorine- or carbon-containing reactant
(e.g., HF or hydrocarbon) to estimate
emissions of the fluorinated GHG
product for that reactant (i.e., the mass
balance may be based on a carbon
balance or a fluorine balance). If
fluorinated GHG byproducts were
produced and were not completely
recaptured or completely destroyed,
facilities would also estimate emissions
of each fluorinated GHG by-product.
Because the mass-balance approach
assumes that losses from the process are
emissions of the product, EPA believes
that the mass-balance approach would
only be appropriate for estimating
emissions from fluorinated GHG
production, not production of CFCs,
HCFCs, or polymers. (In the last three
situations, the product is not a
26 For example, suppose that a facility believed
that all of the fluorinated GHG by-products from a
certain process consisted of HFCs, which its
destruction device destroyed with a destruction
efficiency of 99.9 percent, but that one of these byproducts was actually CF4, which the destruction
device destroyed with an efficiency of only 50
percent. In this case, the facility could
underestimate its fluorinated GHG emissions by
more than an order of magnitude, neither seeking
nor finding the CF4 that it was actually emitting.
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fluorinated GHG.) However, EPA
requests comment on this issue.
To be eligible to use the mass-balance
approach, facilities would have to
demonstrate that their planned
measurements could meet a statistical
error limit required in the rule
(described below). If the facility could
not demonstrate that it could meet the
error limit, it would have to improve the
accuracy and/or precision of its
monitoring and measurement devices or
opt to use another monitoring approach
offered in the rule.
To carry out the mass-balance
approach, the facility would choose a
reactant for yield calculation purposes.
The facility would then weigh or meter
the mass of that reactant fed into the
process, any primary fluorinated GHG
produced by the process, the mass of the
reactant permanently removed from the
process (i.e., sent to the thermal oxidizer
or other equipment, not immediately
recycled back into the process), any
fluorinated GHG byproducts generated,
and any streams that contain the
product or fluorinated GHG byproducts
and that are recaptured or destroyed.
These measurements would be tracked
monthly or more frequently and
consolidated and recorded on a monthly
basis. If monitored streams (including
relevant process streams, emissions
streams, and destroyed streams)
included more than one component
(product, byproducts, or other materials)
in more than trace concentrations,27 the
facility would be required to monitor
concentrations of products and
byproducts in these streams. Finally, the
facility would be required to perform
monthly mass-balance calculations for
each product produced.
Statistical Error Estimate. To estimate
the statistical error associated with use
of the mass-balance approach, facilities
would be required to use error
propagation, considering the accuracy
and precision of their measurements
and the calculation methods of the
mass-balance approach. This approach
is described in more detail in the TSD
for this proposal. Under this approach,
EPA would not specify precision and
accuracy requirements for individual
mass or concentration measurements.
Instead, EPA would require that the
error associated with the overall
estimate of fluorinated GHG emissions
fall under 30 percent (relative error) or
under 3,000 mtCO2e (absolute error).
(Both errors are expressed as halves of
95 percent confidence intervals; for
normal distributions, this is quite close
27 EPA is proposing to define ‘‘trace
concentration’’ as any concentration less than 0.1
percent by mass of the stream.
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to two standard deviations). Facilities
could achieve this level of precision
however they chose.
We are proposing to require the error
estimate to ensure that the use of the
mass-balance approach yields accurate
emission estimates. As observed by
several groups that commented on the
initial proposal, the mass-balance
approach can result in large errors if
measurements of the flow of fluorinated
GHGs in one or more streams have
significant errors.28 We recognize that
the proposed approach requires
facilities to calculate the overall error of
their own estimates, which adds
complication and introduces
opportunities for mistakes. We therefore
plan to develop a calculation tool that
would permit reporters to develop an
error estimate, reducing both their
burden and the likelihood of errors.
We are proposing a maximum relative
error of 30 percent because this error is
comparable to that cited by the facility
that has used an emission factor
approach to estimate its fluorinated
GHG emissions.29 It is also comparable
to the error that EPA calculates for a
facility with an emission rate of two
percent and with good precisions and
accuracies for its mass flow
measurements (+/¥0.2 percent) and for
its concentration measurement (+/¥10
percent) of a waste stream constituting
five percent of the process’s fluorinated
GHG output flow.
For facilities whose emissions
constitute a very small share of their
inputs and outputs (e.g., one percent or
less), a relative error of 30 percent will
be very difficult to achieve using a
mass-balance approach. At the same
time, the absolute error of such a
facility’s estimate may be smaller than
the absolute error of a facility that meets
the relative error test but that has a
higher emission rate. EPA is therefore
proposing a maximum permissible
absolute error of 3,000 mtCO2e for
facilities whose estimates have relative
28 The mass-balance approach works by
subtracting the masses of process outputs from
those of process inputs. As a result, errors that are
a relatively small share of these masses become a
large share of the difference between them. Errors
are particularly a concern for streams where the
fluorinated GHG is only one component of the total
flow, and where, therefore, fluorinated GHG
concentrations must be measured. In general, the
accuracy and precision of concentration
measurements is expected to be approximately +/
¥10 percent, although this can be as low as five
percent and as high as 20 percent, depending on the
circumstances. If this 10 percent error applies to a
stream that constitutes a significant input or (more
likely) output of the process, it can lead to an
emissions estimate with a high relative error.
29 A 13 percent error expressed as a standard
deviation translates into a 26 percent error
expressed as one half of a 95 percent confidence
interval.
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errors greater than 30 percent. This
absolute error is equivalent to 30
percent of the 10,000 mtCO2e threshold
that is used elsewhere in the subpart to
establish requirements for different
sources (e.g., process vents). Under this
approach, processes whose emissions
were lower than 10,000 mtCO2e could
have relative errors higher than 30
percent so long as they met the limit on
absolute error. This approach avoids
penalizing processes and facilities with
low emissions. EPA requests comment
on the absolute error limit of 3,000
mtCO2e. EPA is also considering a
higher limit, e.g., 5,000 mtCO2e.
Another approach that would avoid
penalizing facilities with low emission
rates would be to express the maximum
relative error as a fraction of the total
mass of reactants fed into (or consumed
by) the process. For a given process, this
mass would remain relatively constant
regardless of the emission rate. For the
model facility described above, with
errors of 0.2 percent in its mass flow
measurements and of 10 percent in its
concentration measurements, the error
of the emissions estimate relative to the
total mass of reactants is about 0.3
percent. One advantage of this approach
compared to the absolute limit is that
this approach limits the relative errors
for processes with small throughputs,
while the absolute limit could permit
very large relative errors for processes
with small throughputs. EPA requests
comment on this approach.
In developing the approach to
specifying maximum absolute and/or
relative errors for the overall emissions
estimate, we considered the alternative
of specifying the maximum allowable
errors (precisions and accuracies) of the
individual measurements that feed into
the mass-balance equation. This is the
approach that EPA took in the initial
proposal. This approach limits error, but
it also limits flexibility, a concern raised
by several commenters. Even a facility
with a relatively large error in one
stream may be able to bring the total
error of its emissions estimate to a
tolerable level by improving the
accuracy and precision of other
measurements that are used in the massbalance equation, such as the mass
flows of reactants and products.
Nevertheless, EPA requests comment on
the option of reverting to specific
tolerances for individual measurements
that feed into the mass-balance
equation, as originally proposed.
Choice of Reactant Whose Yield Is
Measured. EPA is today proposing to
allow facilities to estimate emissions
under the mass-balance approach using
one of the reactants rather than both as
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originally proposed.30 Some fluorinated
GHG producers noted that, for various
reasons, it is sometimes considerably
more difficult to track the yields of some
reactants than others (e.g., HF vs. an
organic feedstock). EPA notes that
facilities estimating their emissions
based on the yield of one reactant would
still need to be able to demonstrate that
their estimate passed the statistical error
test discussed above. EPA requests
comment on this approach.
Frequency of Measurement and
Calculation. In today’s proposed rule,
EPA is proposing to require that
facilities using the mass-balance
approach measure and calculate their
emissions monthly. A number of
fluorocarbon producers who
commented on the initial proposal
noted that daily measurements were
burdensome and led to large errors in
the estimates of daily emissions. They
observed that many streams contain
acidic and reactive constituents such as
HF, and that sampling from these
streams can create safety hazards. They
also noted that daily yield
measurements can vary significantly
(sometimes exceeding 100 percent) for
three reasons. First, when continuous
processes are first started, there is a lag
time between the time the reactants are
fed into the process and the time
products emerge. Second, even after the
process has been running for a while,
the quantity of material in the process
can vary based on weather, changes in
production rates, and other conditions.
Third, the relatively large errors in
measurements of in-process product
holding tanks (e.g., based on sight-glass
readings) have a significant impact on
daily mass balances. Over time, all of
these effects smooth out, making longer
term mass balances far more reliable
than daily mass balances.
EPA has carefully considered these
comments. The goal of the rule is to
gather information on annual, not daily,
emissions. The advantage of more
frequent measurements and calculations
is that, where mass flows and
concentrations are variable, more
frequent measurements and calculations
will lead to more accurate and precise
estimates than less frequent
measurements and calculations.
However, in this case the disadvantages
of daily measurement and calculation
30 Under the initial proposed rule, facilities
would have been required to perform the massbalance calculations for each reactant (e.g., both HF
and the chlorocarbon or hydrocarbon) and to take
the average of the two results as the emissions
estimate. This would be expected to lead to the
most robust estimate (i.e., the estimate with the
lowest uncertainty) if the uncertainties in both yield
calculations were similar.
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appear to outweigh the advantages. EPA
believes that monthly mass-balance
calculations will lead to acceptably
accurate estimates at reasonable cost.
Nevertheless, EPA requests comment on
whether the variability of the mass
flows or concentrations in some
production processes may be
sufficiently large to justify more
frequent measurement and calculation,
e.g., weekly.
EPA also requests comment on
whether annual or less frequent
characterizations of fluorinated GHG
concentrations in some streams should
be permitted under the mass-balance
approach. Some fluorinated GHG
producers have stated that it is difficult
to measure fluorinated GHG
concentrations in some streams. In some
cases, this is because waste streams
contain hydrofluoric acid (HF), which,
due to its acidity and reactivity, can
damage sampling and analytical
equipment. As discussed in the TSD,
there may be technical solutions to this
problem. To the extent that these
approaches could be relatively difficult
or expensive to implement, however, it
might be appropriate to permit very
infrequent measurements. The
disadvantage of this approach is that it
might lead to large errors, particularly
for processes that vary over time. A
series of measurements might be
required to (1) reduce the error and (2)
quantify the error for purposes of the
statistical error test. Such measurements
would be analogous to those used to
develop emission factors.
Reactant and Byproduct Emissions.
EPA recognizes that the proposed massbalance approach would assume that all
yield losses that are not accounted for
are attributable to emissions of the
fluorinated GHG product. In some cases,
the losses may be untracked emissions
(or other losses) of reactants or
fluorinated by-products. In general, EPA
understands that reactant flows are
measured at the inlet to the reactor;
thus, any losses of reactant that occur
between the point of measurement and
the reactor are likely to be small.
However, reactants that are recovered
from the process, whether they are
recycled back into it or removed
permanently, may experience some
losses that the proposed method does
not account for.
Fluorocarbon by-products, according
to the IPCC Guidelines, generally have
‘‘radiative forcing properties similar to
those of the desired fluorochemical.’’
However, EPA is aware of at least one
facility where byproducts often have
much larger GWPs than the products. In
this case, assuming by-product
emissions are product emissions would
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lead to large errors in estimating overall
fluorinated GHG emissions. EPA
believes that the initial scoping test of
emitted streams that is discussed above
would help to determine whether this
was an issue for a given process.31 If it
was, then the facility could elect to
pursue the PSEF approach rather than
the mass-balance approach for that
process, or, if the facility was still
interested in pursuing the mass-balance
approach, it could perform more
emissions testing to develop a robust
break-out among the fluorinated GHGs
assumed to be emitted under the massbalance approach. Such emissions
testing would be similar to that
performed for the PSEF approach below,
except it would focus on the
partitioning of emissions among the
various fluorinated GHGs. This
approach is discussed in more detail in
the TSD. EPA requests comment on this
and other possible approaches for
distinguishing between emissions of
fluorinated GHG products and
emissions of fluorinated by-products
under the mass-balance approach.
Alternative approach based on
measurements of balanced element (e.g.,
total fluorine). EPA is considering an
alternative to the mass-balance
approach described above in which
facilities would not be required to
speciate their streams (including
relevant process streams, destroyed
streams, and emitted streams) monthly.
Instead, they could make monthly
measurements of the total fluorine (or
other element of interest other than
carbon) in the streams, e.g., by burning
them. This approach, which is
described in more detail in the TSD,
could be particularly useful for
processes with multiple by-products.
Facilities would still be required to
perform an initial survey of the
fluorinated GHGs in the stream(s) to
identify the fluorinated GHG
constituents. In addition, as discussed
above, it may be appropriate to require
facilities to perform emissions testing to
ensure that emissions are properly
allocated among the product and
various by-products. However, facilities
would perform this testing relatively
infrequently (e.g., every five years)
rather than monthly. One potential
concern regarding this variant of the
mass-balance approach is the potential
difficulty of performing analysis of
combustion products that are likely to
include HF and HCl. It may be
31 For example, if the survey indicated that
attributing all unaccounted-for losses to product
emissions would lead to more than a ten percent
error in the CO2e emitted, the facility could be
required to adjust its emissions estimate to account
for by-product losses.
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appropriate to require facilities to
validate this approach against the massbalance method described above. EPA
requests comment on this approach.
d. Process-Specific Emission Factor
Approach
EPA is proposing an additional
monitoring approach based on sitespecific, process-specific emissions
factors. This approach includes either
calculation or measurement of process
vent emission factors depending on the
size and fate of the emissions from the
vent. Under this approach, facilities
would develop preliminary emissions
estimates to determine the level of
annual uncontrolled emissions from
each process vent in processes subject to
this subpart. For process vents with
uncontrolled emissions of less than
10,000 mtCO2e (or less than 1 metric ton
for emissions that include a fluorinated
GHG whose GWP does not appear in
Table A–1 of subpart A), facilities could
conduct either engineering calculations
or emissions testing to develop emission
factors. Facilities could also conduct
either engineering calculations or
emissions testing to develop emission
factors for emissions that were vented to
a destruction device demonstrated to
achieve a destruction efficiency of 99.9
percent (for fluorinated GHGs), as long
as equipment or procedures 32 were in
place to ensure that uncontrolled
emissions did not occur. For other
vented emissions, facilities would be
required to conduct emissions testing to
determine the process vent emission
factor.
To estimate annual fluorinated GHG
emissions from each vent, facilities
would multiply each emission factor by
the appropriate activity data and
account for the use (and uptime) of
destruction devices. The fluorinated
GHG emissions for all vents at the
facility would be summed to obtain the
total emissions from process vents for
the facility as a whole.
To ensure that the emissions estimate
encompassed all sources of emissions
within the processes that would be
subject to this subpart, facilities using
the emission factor approach would also
be required to estimate emissions from
equipment leaks.33 Leaks would be
32 Such equipment or procedures could include,
for example, holding tank capacity, monitoring of
by-pass streams, or compulsory process shutdowns
in the event the destruction device remains off line.
33 As noted above, process vents are only one of
the sources of emissions from production,
transformation, and destruction processes. Another
source is equipment leaks, specifically, leaks from
piping and connections. The mass-balance
approach does not need to be supplemented with
equipment leak assessment because it accounts for
all emissions between the measurements of inputs
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monitored annually using EPA Method
21 and the Protocol for Equipment Leak
Estimates U.S. Environmental
Protection Agency, EPA Publication No.
EPA–453/R–95–017, November 1995.
EPA is proposing less demanding
measurement requirements for small
and destroyed emission streams to
ensure that the effort and resources
expended to measure emissions are
commensurate with the size of those
emissions. This principle has been
adopted both for other source categories
in the MRR and for numerous other EPA
programs. However, EPA is requesting
comment on some aspects of its
proposed approaches.
First, we request comment on the
appropriateness of the CO2e cutoff
below which calculations are permitted.
One potential concern associated with
this approach is that 10,000 mtCO2e
equates to relatively low mass emissions
of fluorinated GHGs with high GWPs.
For example, 10,000 mtCO2e equates to
923 pounds of SF6 and 1,282 pounds of
NF3. Our understanding is that SF6 can
be detected at extremely low emission
rates and concentrations, but we request
comment on whether emissions of other
high-GWP compounds at this level may
be difficult to detect. An option on
which we are requesting comment is to
relax the CO2e emissions cutoff and to
include an unweighted emissions cutoff
(i.e., in tons of fluorinated GHG) along
with it. For example, for process vents
with less than 25,000 mtCO2e
uncontrolled and less than 10,000
pounds of fluorinated GHG
uncontrolled, facilities would have the
option to conduct emissions testing or
engineering calculations or assessments.
Second, EPA requests comment on its
criteria for allowing use of engineering
calculations to characterize the
emissions of process vents that vent to
destruction devices. EPA understands
that many and perhaps most destruction
devices used at fluorinated GHG
production facilities can achieve DEs of
99.9 percent or better. EPA also
understands that many facilities have
equipment or procedures in place to
prevent uncontrolled emissions, though
some do not. It is important to note that
uncontrolled emissions during device
downtime can reduce the effective
(time-weighted average) DE to 90
percent or less, increasing emissions by
a factor of 100 or more. However, one
alternative to the proposed approach
and outputs, whether these emissions occur from
vents or leaks. (This assumes that the production
measurement used to estimate and report emissions
under the mass-balance approach is the same as
that used to report additions to the industrial gas
supply. EPA is proposing that these two
measurements be identical.)
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would be to allow the use of engineering
calculations for any vent whose
emissions, considering both the DE and
the historical uptime of the destruction
device, fell below the 10,000 mtCO2e
cutoff. For purposes of this calculation,
the annual time of uncontrolled
emissions could be equated to the
longest annual time of uncontrolled
emissions observed over the previous
five years. EPA requests comment on
this alternative approach.
Preliminary estimates. To develop
preliminary emissions estimates for
each vent, facilities would be permitted
to use the same types of previous
measurements, engineering calculations,
and engineering assessments that they
would be permitted to use to develop
emission calculation factors. These are
described below under ‘‘Process-specific
Emission Calculation Factor Approach.’’
Process vent emissions testing. For
process vent emissions testing, facilities
would be required to use EPA reference
methods, including EPA Method 18 and
EPA Method 320, or ASTM D6348–03.34
Alternative testing methods could be
used if validated using EPA Method
301. EPA reference methods are
included in the rule requirements for
determining sample and velocity
traverses, velocity and volumetric flow
rates, gas analysis, and stack gas
moisture, along with several alternative
flow rate determination methods, such
as OTM–24 and ALT–012. Commenters
who have previously estimated their
emissions of fluorinated GHGs stated
that they used these approaches to do
so.
The testing periods would be required
to include representative process
operation and to exclude atypical events
(such as process upsets or
malfunctions).35 Within any given
operating scenario (discussed further
below), the full range of process
operation would be required to be
represented, i.e. the emissions data must
be representative of typical process
operation while also including process
variability. Facilities would be required
to consider process parameters that may
potentially cause variability of the
emissions, such as catalyst degradation,
seasonal variability, raw material
34 EPA Method 320 and the ASTM method are
Fourier Transform Infrared (FTIR) methods. For
such methods, compounds are identified by
characteristic spectra, and libraries providing
spectra for the range of compounds likely to be
found in emissions streams can greatly facilitate
analysis. EPA requests comment on whether such
spectral libraries are available for fluorinated GHGs,
and if not, on whether EPA might play a role in
assembling a spectral library for fluorinated GHGs.
35 EPA is proposing an exception if monitoring is
sufficiently long to ensure that such events are not
overrepresented in the emission factor.
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suppliers, etc. For example, where a
facility uses a catalyst, test runs would
have to be conducted at various points
over the life of the catalyst. The
production level during the testing
periods would be required to be
representative of normal operation.
To develop process-specific emissions
factors, facilities would be required to
conduct at least three test runs and to
analyze the relative standard deviation
(RSD) of the emission factors
corresponding to each run to determine
whether additional runs were necessary.
The emission factors and their RSD
would be calculated across all
fluorinated GHGs emitted from the vent
in CO2e terms. If the RSD exceeded
twenty percent, the facility would be
required to conduct an additional three
tests. The rationale for the RSD test is
that if the variability of a population or
parameter is large, then more samples
are required to obtain a robust estimate
of the mean (average) of that parameter.
EPA estimates that at a relative standard
deviation of 20 percent, an emission
factor calculated as the mean of three
test runs has a 95 percent chance of
being within 50 percent of the actual
mean emission rate of the process. The
reasoning and calculations behind this
conclusion are discussed in more detail
in the TSD.
An alternative approach would be to
conduct additional runs until the
change in the running average emission
factor fell under 10 percent. This
approach is similar to requirements for
measuring emission factors (slope
coefficients) in subpart F (Primary
Aluminum) and could provide
representative emissions from the
process and address variability.
However, it has two potential
drawbacks in the context of fluorinated
gas production. First, for processes
whose variability is predictable (e.g.,
due to catalyst age) rather than random,
the fourth sample could satisfy the
running average requirement but lead to
a biased emission factor, for example if
two of the four samples were taken
when the catalyst was new. Second,
facilities could find it inconvenient to
analyze samples and calculate emission
factors between each test run after the
first three. EPA requests comment on
this alternative approach.
For continuous process vents,
facilities would conduct 1-hour test
runs, and for batch process vents,
facilities would test during emissions
episodes of the batch. We request
comment on the appropriate number of
test runs to conduct for continuous and
batch process vents and the appropriate
RSD that facilities should meet. We also
request comment of the appropriateness
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of testing batch process vents during
emissions episodes only. Another
option is to require testing of vents for
the full duration of the batch process,
but this could significantly increase the
expense of the emissions test without
necessarily improving its accuracy.
Where multiple processes vent into a
common vent or control device, EPA is
proposing that facilities do one of the
following: sample each process in the
ducts before the emissions are
combined, sample when only one
process is operating, or sample the
combined emissions at representative
combinations of capacity utilizations for
all the processes. If the last option were
selected, facilities would be required to
perform 3 times n test runs, where n is
the number of processes feeding into the
common vent or add-on control device.
The emission factor would be calculated
by dividing the total emissions by the
summed activity across the processes
venting to the common vent, and the
PSEF would be applied whenever one
or more of the processes was operating.
Process activity data would have to be
collected simultaneously with the
emissions data during the emissions
test. The process activity data would be
used to develop the emissions factor.
Process activity data that could be used
in development of the emissions factor
includes raw material feed, amount of
product produced, or other process
activity known to have a direct effect on
emissions.
Facilities would be required to define
the operating scenario that encompasses
the range of operating conditions that
represent typical operation for the
process and to develop representative
emissions factors for each operating
scenario. To define the process
operating scenario, a facility would
include information including the
process description and the specific
process equipment used; the process
vents, emission episodes and durations,
and the quantity of uncontrolled
fluorinated GHG emissions; the control
device or destruction device used to
control emissions; and the manifolding
of process vents within the process and
from other processes. Alternative
operating scenarios would also be
defined for differences in operating
conditions that affect emissions.
Examples of situations where process
differences may warrant separate
operating scenarios include the
following: Making small volumes of a
product in one set of batch process
equipment part of the year and making
larger volumes in larger batch process
equipment part of the year; use of two
different types of catalyst in the same
process; deliberate alterations in process
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conditions such as temperature or
pressure to shift the reaction to a
particular product; and making small
volumes of a product in a batch process
part of the year and making large
volumes in a continuous process part of
the year. A facility is required to
develop a representative emissions
factor for each process operating
scenario because each operating
scenario for a process will result in
different emissions levels.
In general, emissions testing during
process startups and shutdowns would
not be expected to lead to representative
emission factors, because emission rates
tend to fluctuate during such events.
Exceptions to this could include longterm monitoring that would not overrepresent startup or shutdown
conditions in the resulting emission
factor, and monitoring specifically to
obtain emission factors for startups and
shutdowns conditions. Several
companies indicated that they have
analyzed the emissions profile during
startup events and during shutdown
events. They found that the emission
rates during these events departed from
those at steady state conditions, but that
emissions profiles were consistent
between one startup event and another.
The uncertainty of the process-ventspecific emission factor approach is
anticipated to be roughly 10 percent; the
uncertainty of the emissions testing is
estimated to be approximately 10
percent (as calibration requirements for
most test methods require ±10 percent
accuracy and precision), and the
uncertainty of the process activity
measurement is ±1 percent. While
emissions testing must continue if the
first three test runs exhibit an RSD or
0.2 or greater, the RSD is expected to be
a measure of the variability of the
process rather than the error of the
measurement.
EPA is proposing that emission
factors would need to be developed
before December 31, 2011, the end of
the first year of reporting under this
subpart. Throughout 2011, facilities
would be responsible for gathering
monthly activity data to which the
emission factors, once developed,
would be applied to estimate monthly
and annual emissions from each
process.
Updates to Emission Factors. After
developing their initial process-ventspecific emission factors, facilities
would be required to update them every
5 years or when there was a process or
equipment change that would alter the
process operating scenario. Process or
equipment changes would include
changes in raw materials, equipment,
production levels, or operating
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conditions that would be expected to
affect the level of emissions. EPA is
proposing periodic updates of the
emission factors because facilities that
have measured and re-measured their
emission factors over a period of several
years have found that gradual,
incremental changes to the process (e.g.,
to improve yields) have significantly
changed emission factors over time. The
proposed five-year frequency is
consistent with that required for some
source categories covered in the MRR
(e.g., for process vents used in HCFC–
22 production processes under subpart
O) but is higher than that required for
others (e.g., the 10-year frequency for
measurement of slope factors for
aluminum processes). EPA requests
comment on the proposed frequency of
measurement.
An alternative to regular updates to
emission factors would be updates
triggered by changes to other indicators
of emission rates, such as process
yields. Under such an approach,
facilities could calculate how their
emission factor would change if the
change in yield were attributable solely
to a change in the emission rate. If this
change exceeded 15 percent (as a
fraction of the current emission factor),
the emission factor would need to be remeasured. EPA requests comment on
this alternative.
Measurements performed before the
effective date of this rule. We are
proposing that emission factor
measurements performed before the
effective date of this rule could be used
to estimate GHG emissions if the
measurements were performed in
accordance with the requirements of the
rule less than five years before the
effective date. We believe that it may
also be appropriate to permit use of
previously measured emission factors
whose measurement departed in some
particulars from the requirements of the
rule but still substantially met most of
the requirements, making it likely that
the emission factors were
representative. In this case, facilities
could submit information to EPA on
areas where measurements departed
from the requirements from the rule,
and EPA could review the
measurements to verify that they still
substantially met most of the
requirements. We request comment on
this option.
Process-Specific Emission Calculation
Factor Approach. As noted above,
facilities could use engineering
calculations to estimate emissions from
vents that either (1) had annual
emissions below 1,000 mtCO2e or (2)
vented to a control device with a
destruction efficiency of 99.9 percent
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and had equipment and procedures in
place to prevent uncontrolled
emissions. We are proposing an
emission factor approach that includes
both emissions testing and engineering
calculations, with the required approach
depending on the magnitude of
uncontrolled emissions from the process
vent.
Engineering calculations use basic
chemical engineering principles and
component property data to calculate
emissions (and develop emission
factors) rather than actually measuring
emissions. Calculations for various
emissions episodes could be conducted
using standard equations presented in
EPA’s Emissions Inventory
Improvement Process guidance
documents, Pharmaceutical NESHAP,
and Miscellaneous Organic NESHAP.
Calculations highlighted in these
documents and in codified rule text
include vapor displacement, purging,
heating, depressurization, vacuum
systems, gas evolution, air drying, and
empty vessel purging.
Engineering assessments may be
conducted using previous test data or
other information available on the
process. Engineering assessments
include use of previous test reports
where the emissions are representative
of current operating practices; benchscale or pilot-scale test data that are
representative of full-scale process
operating conditions; design analysis
based on chemical engineering
principles, measurable process
parameters, or physical or chemical
laws or properties. The data used in
engineering assessments must be
documented.
Process activity data must be
measured in conjunction with the
emissions estimate based on
calculations and assessments. This
process activity data is needed to
develop the emissions calculation
factor.
Just as for emission factor
development, facilities are required to
define the operating scenario for the
emission calculation factor
development. Alternative operating
scenarios would also be defined for
differences in operating conditions that
affect emissions. As discussed
previously for the emission factor
approach, a facility would be required
to develop a representative emission
calculation factor for each process
operating scenario because each
operating scenario for a process will
result in different emission levels (see
discussion above).
Facilities would update the processvent-specific emission calculation
factors every five years or when there is
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a process or equipment change that
would alter the process operating
scenario.
Potential use of continuous emissions
monitors to measure emissions from
vents. Another option we are
considering is to require that facilities
measure emissions from fluorinated gas
production facilities using continuous
emissions monitors (CEMS). Under this
approach, facilities would be required to
install and operate CEMS capable of
measuring fluorinated GHGs to measure
process emissions. The requirements for
the CEMs would be similar to those in
subpart C, adjusted, as appropriate, to
accommodate CEMS for fluorinated
gases. One possible option is to use
Fourier Transform Infrared
Spectrometers (FTIRs) in scrubber
stacks to measure emissions. FTIR
spectroscopy is presently used to
conduct short-term fluorinated GHG
emission measurements from processes.
If properly selected and maintained,
CEMS would be expected to provide
estimates of emissions more accurate
than either the mass-balance or the
process-vent approach. However,
potential drawbacks to requiring CEMS
are that they would be relatively
expensive to install and they may not
tolerate the acidic and reactive
environments found in vents at many
fluorinated gas production facilities.
(The latter concern might be mitigated
by installing CEMS after a scrubber, if
this is practicable.) Given these
potential concerns, it may be
appropriate to require CEMS for
particularly large emission streams, e.g.,
those resulting in emissions of more
than 50,000 mtCO2e annually. EPA
requests comment on the use and
implementation of CEMS at fluorinated
gas production facilities. We also
request data or other information
evaluating the use of CEMS in
fluorinated gas production facilities to
determine fluorinated GHG emissions.
Equipment Leak Emissions Estimates.
For completeness, EPA is proposing that
monitoring of process vents be
supplemented by monitoring of
equipment leaks, whose emissions do
not occur through process vents. To
estimate emissions from equipment
leaks, we would require use of EPA
Method 21 and the Protocol for
Equipment Leak Estimates (EPA–453/R–
95–017). Leak monitoring would be
performed annually. The Protocol
includes four methods for estimating
equipment leaks. These are, from least
to most accurate, the Average Emission
Factor Approach, the Screening Ranges
Approach, EPA Correlation Approach,
and the Unit-Specific Correlation
Approach. We are proposing that the
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facility use one of the last three
methods. To use these methods, the
facility would need to have (or develop)
Response Factors relating
concentrations of the target fluorinated
GHG (or surrogate gas co-occurring in
the stream) to concentrations of the gas
with which the leak detector is
calibrated. Our understanding is that
flame ionization detectors (FIDs) are
generally insensitive to fluorinated
GHGs, and that they are therefore not
likely to be effective for detecting and
quantifying fluorinated GHG leaks. An
exception to this would be a situation in
which the fluorinated GHG occurred in
a stream along with a substance (e.g., a
hydrocarbon) to which the FID was
sensitive; in this case, the other
substance could be used as a surrogate
to quantify leaks from the stream. We
understand that at least two
fluorocarbon producers currently use
methods in the Protocol to quantify
their emissions of fluorinated GHGs
with different levels of accuracy and
precision.36 Other analytical techniques
that are sensitive to fluorinated
compounds may be available to monitor
concentrations of equipment leaks,
including photoionization, ultraviolet,
infrared, and others. EPA requests
comment on the availability and use of
portable monitoring instruments for
equipment leak monitoring of
fluorinated GHG.
Another approach for monitoring
leaks from pieces of equipment includes
use of the Alternative Work Practice
(AWP) for EPA Method 21 (similar to
monitoring requirements under 40 CFR
part 60, subpart A, 40 CFR part 60.18;
40 CFR part 63, subpart A, 40 CFR part
63.11; or 40 CFR part 65, subpart A, 40
CFR part 65.7). This approach would
include monitoring leaking equipment
with an optical gas imaging instrument.
Emissions from those pieces of
equipment found to be leaking could be
estimated based on emission factors.
Under this approach, facilities would be
required to image each piece of
equipment associated with processes
covered under subpart L and in
fluorinated GHG service, and all
36 One producer estimates HFC and other
fluorocarbon emissions by using the Average
Emission Factor Approach. This approach simply
assigns an average emission factor to each
component without any evaluation of whether or
how much that component is actually leaking. The
second producer estimates emissions using the
Screening Ranges Approach, which assigns
different emission factors to components based on
whether the concentrations of the target chemical
are above or below 10,000 ppmv. This producer has
developed a Response Factor for HCFC–22, which
is present in the same streams as the HFC–23 whose
leaks are being estimated. (HFC–23 emissions are
discussed in Section O of the October 30, 2009
MRR.)
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emissions imaged by the optical gas
imaging instrument would be
considered leaks and would be subject
to emissions estimation. EPA requests
comment on the technical feasibility
and accuracy of this approach for
fluorinated GHG emissions.
Other Potentially Significant Emission
Points. We are requesting comment on
the inclusion of fluorinated GHG
emissions from storage tanks,
wastewater, and container filling,
particularly where these emissions
occur before the production
measurement at fluorinated GHG
production facilities. We anticipate that
emissions from wastewater and storage
tanks would be small to insignificant
due to the low solubility of most
fluorinated GHGs in water and the use
of pressurized tanks for storage.
However, we request comment on the
emission levels expected from these
emission points.
Our current understanding is that
most fluorinated GHG production
facilities measure their production
before container filling, e.g., by using
flowmeters just upstream of the
container connection to measure the
mass flowing into the containers. If this
is the case, emissions that occur during
or after filling (e.g., from hoses and
connections) would have been included
in the production (supply)
measurement. However, if production is
measured by weighing containers before
and after filling, then emissions during
container filling would not have been
included in the production
measurement. In these cases, facilities
using the emission factor approach
would need to quantify container filling
emissions for completeness. Possible
methods for tracking these emissions
include engineering estimates, default
or site-specific emission factors, and
mass balances. These methods are
discussed in more detail in the TSD.
Destruction Device Performance
Testing. EPA is proposing to require
fluorinated gas producers that destroy
fluorinated GHGs to conduct an
emissions test every five years to
determine the destruction efficiency
(DE) of the destruction device. As
discussed further in the TSD, the testing
for determining the DE would be similar
to the emissions testing required to
develop process-specific emission
factors, described above. Facilities
would be required to conduct their
testing when operating at high loads
reasonably expected to occur and when
destroying the most-difficult-to-destroy
fluorinated GHG fed into the device (or
when destroying a surrogate that was
more difficult to destroy than that
fluorinated GHG). The last point is
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particularly important because some
fluorinated GHGs (e.g., CF4 and SF6) are
extremely difficult to destroy; DEs
determined for other fluorinated GHGs
would overestimate the destruction of
these fluorinated GHGs.
Facilities that have conducted an
emissions test on their destruction
device within the five years prior to the
effective date of the rule would be
allowed to use the DE determined
during that test if the test was
conducted in accordance with the
proposed test requirements. Facilities
could also use the DREs determined
during principal organic hazardous
constituent testing and hazardous waste
combustor testing, provided those tests
determined the DRE based on the mostdifficult-to-destroy fluorinated GHG fed
into the device (or based on a surrogate
that was more difficult to destroy than
the most-difficult-to-destroy fluorinated
GHG).
EPA is proposing to require reporting
of fluorinated GHG emissions from
destruction of fluorinated GHGs; we
request comment on whether we should
also require reporting of by-product
fluorinated GHG emissions from
destruction of CFCs and HCFCs.
Specifically, we request comment on the
extent to which fluorinated GHGs may
be generated and emitted during
destruction of CFCs and HCFCs at
facilities producing these chemicals.
Testing of destruction devices used in
the electronics sector has shown that
destruction of one fluorinated
compound can lead to the emission of
others under some circumstances.
6. Selection of Procedures for Estimating
Missing Data
In the event that a scale or flowmeter
normally used to measure reactants,
products, by-products, or wastes fails to
meet a test to verify its accuracy or
precision, malfunctions, or is rendered
inoperable, we are proposing that
facilities be required to estimate these
quantities using other measurements
where these data are available. For
example, facilities that ordinarily
measure production by metering the
flow into the day tank could use the
weight of product charged into shipping
containers for sale and distribution as a
substitute. It is our understanding that
the types of flowmeters and scales used
to measure fluorocarbon production
(e.g., Coriolis meters) are generally quite
reliable, and therefore that it should
rarely be necessary to rely solely on
secondary production measurements. In
general, production facilities rely on
accurate monitoring and reporting of the
inputs and outputs of the production
process. Nevertheless, EPA is also
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proposing that if a secondary mass
measurement for the stream is not
available, producers can use a related
parameter and the historical
relationship between the related
parameter and the missing parameter to
estimate the flow.
If concentration measurements are
unavailable for some period, we are
proposing that the facility use the
average of the concentration
measurements from just before and just
after the period of missing data.
We request comment on these
proposed methods for estimating
missing data.
7. Selection of Data Reporting
Requirements
Under the proposed rule, owners and
operators of facilities producing
fluorinated gases would be required to
report both their fluorinated GHG
emissions and the quantities used to
estimate them on a process-specific
basis. They would also be required to
report the results of each scoping study,
specifically, the chemical identities of
the contents of potentially emitted
streams. Facilities using the massbalance approach would report the
masses of the reactants, products, byproducts, and wastes, and, if applicable,
the quantities of any product in the byproducts and/or wastes (if that product
is emitted at the facility). The chemical
identities of reactants, products, and byproducts would also be reported, along
with the chemical equations used to
estimate emissions. Facilities using the
emission factor approach would report
the activity data used to calculate
emissions (e.g., the quantity produced,
transformed, or destroyed) and the
emission factors used to estimate them.
We are proposing that owners and
operators report annual totals of these
quantities by process and facility.
Where fluorinated GHG production
facilities have estimated missing data,
the facility would be required to report
the reason the data were missing, the
length of time the data were missing, the
method used to estimate the missing
data, and the estimates of those data.
We propose that facilities report these
data because the data are necessary to
verify facilities’ calculations of
fluorinated GHG emissions. We request
comment on these proposed reporting
requirements.
8. Selection of Records That Must Be
Retained
Maintaining records of the
information used to determine the
reported GHG emissions is necessary to
enable us to verify that the GHG
emissions monitoring and calculations
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were done correctly. Under the
proposed rule, owners and operators of
facilities producing fluorinated GHGs
would be required to retain records
documenting the data reported,
including records of monthly emission
estimation calculations, all data that
went in to the calculations, calibration
records for flowmeters, scales, and gas
chromatographs, and documentation of
emission factor development activities.
These records are necessary to verify
that the GHG emissions monitoring and
calculations were performed correctly.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
C. Electric Transmission and
Distribution Equipment Use
In the April 2009 proposed MRR (74
FR 16448; April 10, 2009), EPA
proposed mandatory reporting of SF6
and PFC emissions from electric power
transmission and distribution system
equipment in subpart DD. As initially
proposed, this source category would
comprise electric power transmission
and distribution systems that operate
using gas-insulated substations, circuit
breakers and other switchgear, or power
transformers containing sulfur
hexafluoride (SF6) or perfluorocarbons
(PFCs) and emissions would represent
the annual facility-wide emissions of
SF6 and PFCs for the reporting facility.
EPA received comment from
approximately 22 entities, many of
whom requested elaboration on what is
included in an electric power system for
purposes of this source category as well
as the relationship of an electric power
system to a facility. The requirements of
40 CFR part 98 apply to owners and
operators of any ‘‘facility’’.37 EPA is
issuing this supplemental proposal to
provide additional detail on this source
category.
In doing so, our objective is to clarify
and solicit further comment on the
scope of an ‘‘electric power system’’ and
what constitutes a facility for this
subpart. We also provide further detail
on options we considered. We are
proposing to integrate the Energy
Information Administration of the
Department of Energy (EIA) list of
examples of electric power entities into
the definition of a facility for this
subpart. The EIA lists the following as
electric power entities: ‘‘a company; an
37 Unless otherwise specified in an individual
subpart, facility means any physical property, plant,
building, structure, source, or stationary equipment
located on one or more contiguous or adjacent
properties in actual physical contact or separated
solely by a public roadway or other public right-ofway and under common ownership or common
control, that emits or may emit any greenhouse gas.
Operators of military installations may classify such
installations as more than a single facility based on
distinct and independent functional groupings
within contiguous military properties.
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electric cooperative; a public electric
supply corporation as the Tennessee
Valley authority; a similar Federal
department or agency such as the
Bonneville Power Administration; the
Bureau of Reclamation or the Corps of
Engineers; a municipally owned electric
department offering service to the
public; or an electric public utility
district (a ‘‘PUD’’); also a jointly owned
electric supply project such as the
Keystone.’’ 38 We are proposing to
incorporate the EIA list of electric
power entities because it is widely used
in the industry and includes the
spectrum of energy supply participants
with relevant operations, i.e., vertically
integrated, generate and transmit only,
transmit and distribute only, transmit
only and distribute only.
We are also seeking comment on
whether it would be appropriate to use
the Regional Greenhouse Gas Initiative
(RGGI) definition of a transmission and/
or distribution entity in our definition of
electric power system.39 RGGI defines
an entity as ‘‘the assets and equipment
used to transmit and distribute
electricity from an electric generator to
the electrical load of a customer.’’ It
includes all related assets and
equipment located within the service
territory of the entity, defined as the
service territory of a load-serving entity
specified by the applicable State
regulatory agency. In particular, EPA
seeks comment on whether the RGGI
definition includes the spectrum of
entities identified in the EIA list and
captures the full universe of SF6emitting entities in the United States.
EPA is requesting comments on only
40 CFR 98.300 Definition of the Source
Category in proposed subpart DD. EPA
is not seeking further comment on other
elements of the initial proposal such as
the selection of the threshold and the
proposed monitoring methods.
1. Definition of the Source Category
EPA proposes to define the source
category as follows: ‘‘The electric
equipment use source category includes
electric power systems as described in
this paragraph. Notwithstanding the
definition of facility in subpart A, for
purposes of this subpart, ‘‘facility’’
means an electric power system. Electric
power system means the collection of
SF6- and PFC-insulated equipment
linked through electric power
transmission or distribution lines and
operated as an integrated unit by one
electric power entity or several entities
38 Energy Information Administration of the U.S.
Department of Energy, Energy Glossary: Energy
terms and definitions; https://www.eia.gov/glossary.
39 Regional Greenhouse Gas Initiative Model
Rule, 2008.
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that have a single owner. SF6- and PFCinsulated equipment includes gasinsulated substations, circuit breakers,
other switchgear, gas-insulated lines,
and power transformers containing SF6
or PFCs. Equipment also includes gas
containers such as pressurized
cylinders, gas carts, new equipment
owned but not yet installed, or other
containers.’’
The largest use of SF6 is as an
electrical insulator and interrupter in
equipment intended for use in
connection with generation,
transmission, distribution, and
conversion of electric energy. The gas
has been employed by the electric
power industry in the United States
since the 1950s because of its dielectric
strength and arc-quenching
characteristics. SF6 has replaced
flammable insulating oils in many
applications and allows for more
compact substations in dense urban
areas. It has also facilitated expansion of
the electric power grid through longdistance transmission at high and extrahigh voltages. SF6 is used in gasinsulated substations, circuit breakers
and other switchgear, transformers, and
gas-insulated lines. The types and
location of gas-insulated equipment
used varies depending on a number of
technical, system design, geographic
and historic factors. Currently, there are
no available substitutes for SF6 in highvoltage applications. For further
information, see the SF6 from Electrical
Equipment TSD in the docket for this
rulemaking (EPA–HQ–OAR–2009–
0927).
Since SF6 is used in pressurized
equipment, unintended emissions of
SF6 occur over the life cycle of the
equipment. SF6 can escape from gasinsulated substations and switchgear
through seals, especially from older
equipment. The gas can also be released
during installation, servicing, and
equipment disposal. Emissions of SF6
from electric power systems were
estimated to be 12.4 million metric tons
of CO2e in 2006. Emissions from
electrical equipment manufacture and
refurbishing are being covered in
subpart SS.
PFCs are sometimes used as dielectric
and as heat transfer fluids in power
transformers. PFCs are also used for
retrofitting CFC–113 cooled
transformers. The common PFC used in
this application is perfluorohexane
(C6F14). In terms of both absolute and
carbon-weighted emissions, PFC
emissions from electrical equipment are
generally believed to be much smaller
than SF6 emissions. EPA does not
currently have an estimate of PFC
emissions from this source category.
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PFCs, however, are very potent and
persistent greenhouse gases and an
accurate inventory of use and emissions
from all sources is important.
Consequently, as stated in our initial
proposal, we are proposing to include
emissions of PFCs in this subpart.
Reference to gas-insulated equipment
implies SF6 and PFCs.
The electric transmission and
distribution equipment use source
category includes all gas-insulated
electrical equipment such as gasinsulated substations, circuit breakers,
other switchgear, gas-insulated lines,
and power transformers. This
equipment is used as part of an
interconnected group of electric
transmission lines and associated
equipment for the movement or transfer
of electric energy in bulk between
points of supply and points at which it
is transformed for delivery to the
ultimate customer. This equipment,
along with lines and other associated
equipment used for the movement or
transfer of electric energy, operates as
part of a contemporaneous network in
real-time and in a synchronous manner
to provide stable and reliable electricity
to customers.
A clear definition of a facility for this
source category is important in order to
determine whether a collection of
electrical equipment meets the reporting
threshold and to ensure that double or
under reporting of emissions is
minimized. In defining a facility, we
reviewed current definitions used in the
CAA and by the Federal Energy
Regulatory Commission (FERC), North
American Energy Reliability
Corporation (NERC), California Air
Resources Board (CARB), RGGI and EIA;
consulted with industry; and reviewed
current regulations relevant to the
industry. Typically, the various
regulations under the CAA define a
facility as a group of emissions sources
all located in a contiguous area and
under the control of the same person (or
persons under common control). The
subpart A definition of facility would
require all SF6 equipment included in
the facility be located on contiguous or
adjacent properties. We are proposing
not to use the exact definition of
‘‘facility’’ found in subpart A because the
completeness and accuracy of emissions
data for this source category are
dependent on reporting on all
equipment regardless of location. For
completeness, reporting needs to
account for and report on all sources
and activities within the facility. The
purpose of transmission is to move
energy over long distances. Similarly,
distribution can occur over large
geographical areas. Therefore, it is
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neither practical nor appropriate to
exclude certain types of equipment
solely based on its lack of physical
proximity. Emissions from gas-insulated
equipment occur during installation,
operation, servicing and
decommissioning. Accuracy of reporting
requires that emissions are
systematically neither over nor under
actual emissions; consequently
including all equipment at all periods of
the life cycle is necessary. Thus, EPA
has concluded that strict adherence to
the subpart A definition is not
appropriate for this source category.
In deciding where to draw the
boundary between one facility and the
next, we considered the following levels
of reporting: Per piece of equipment, by
substation or switchyard, corporatelevel, and aggregation of total
equipment by system. Reporting per
piece of equipment was deemed costly
and highly impractical for reporters.
Reporting by substation or switchyard,
where multiple pieces of equipment is
often located, would also be
burdensome, given that a specific
reporting protocol using the proposed
mass-balance reporting method would
have to be set up for each substation,
requiring cylinder inventory and other
data collection to be done on a per
substation basis. Although this may be
practical for some system owners, others
have responsibility for dozens or
hundreds of substations. Finally, EPA
considered corporate-level reporting
based on comments submitted on our
initial proposal. We concluded,
however, that given the complex and
varied corporate structures within the
electric power industry that approach
would not be practical and appropriate
for this source. The full results of our
assessment can be found in the SF6 from
Electrical Equipment TSD.
For this source category, EPA is
proposing to define the facility as an
‘‘electric power system,’’ which would
mean that reporting would occur at a
‘‘system-wide’’ level. The electric power
system would be defined as all electric
power equipment insulated with SF6 or
PFCs regardless of location linked
through electric power transmission or
distribution lines and operated as an
integrated unit by one electric power
entity or several entities that have a
single owner. Reporting by the electric
power system would comprise all gasinsulated equipment located between
the point of generation and the point at
which the ultimate customer receives
the electricity. Such equipment includes
gas-insulated substations, circuit
breakers, other switchgear, gas-insulated
lines, or power transformers containing
SF6 or PFCs. EPA proposes to define an
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electric power entity as a company; an
electric cooperative; a public electric
supply corporation as the Tennessee
Valley Authority; a similar Federal
department or agency such as the
Bonneville Power Administration; the
Bureau of Reclamation or the Corps of
Engineers; a municipally owned electric
department offering service to the
public; or an electric public utility
district (a ‘‘PUD’’); also a jointly owned
electric supply project such as the
Keystone. Although the size of these
facilities will vary, and some are
expected to cross State lines, a facility
is likely to encompass more than a
thousand miles of lines and hundreds of
pieces of equipment located at multiple
substations or switchyards. Equipment
also includes gas containers such as
pressurized cylinders, gas carts, new
equipment owned but not yet installed,
or other containers.
EPA believes the proposed definition
of ‘‘facility’’ for this source category is
appropriate and analogous to the 40
CFR part 98 subpart A definition of a
‘‘facility’’ used for other source
categories due to the physical
interconnection and operational
dependence of the components of the
system. It is also consistent with the
concept of a ‘‘transmission and
distribution system,’’ which is a
standard term used by the industry. The
transfer of energy is dependent on the
collective functioning of all components
of the system which must operate as a
contemporaneous network in real-time
and in a synchronous manner. Without
system-wide use of gas-insulated
equipment, operation and system
reliability is not possible. Furthermore,
system-wide reporting is consistent with
the reported servicing and maintenance
practices of many SF6-insulated
equipment owners making this
approach less burdensome and more
efficient than using a substation or per
piece of equipment source definition.
This is also consistent with the
approach used by over 80 systems from
across the United States that are
participating in the ‘‘EPA SF6 Emission
Reduction Partnership for Electric
Power Systems’’, and has proven to be
a practical and reasonable approach for
the collection of emissions data. In
addition, the burden of using the massbalance method proposed for
monitoring is lowest at a system-wide
level.
EPA is requesting comment on
whether one electric power system
should be distinguished from the next
on the basis of operation, ownership, or
some combination of the two. EPA is
proposing that the electric power system
be the collection of equipment operated
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as an integrated unit by one electric
power entity or several entities that
have a single owner because it best
reflects the functional aspect of the
system (transmitting and distributing
power) and emphasizes the physical
interconnection and operational
dependence of the system components.
It also reflects current voluntary best
practices for GHG reporting from this
source category. This proposed
definition would not relieve entities that
own but do not operate equipment of
the obligation to report under 40 CFR
98.3. Regardless of the role that
operation or ownership plays in the
final source category definition, the
obligation to report will apply to both
owners and operators.
Under the proposed definition of
facility, total emissions would be
derived from the entire collection of
servicing inventory (cylinders stored)
and gas-insulated equipment. Reporting
would be based on the aggregation of
emissions of all servicing inventory and
equipment.
Installation of Electrical Equipment at
Electric Power Systems. In section E
below, EPA is requesting comment on
two issues related to equipment
installation and commissioning that is
performed by equipment manufacturers
at electric power systems. These issues
affect both users and manufacturers of
electrical equipment and could affect
the calculation methods required under
both subpart DD and subpart SS. Please
see section E for a discussion of these
issues.
D. Imports and Exports of Fluorinated
GHGs Inside Pre-Charged Equipment
and Closed-Cell Foams
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
1. Overview of Reporting Requirements
Under today’s proposed rule,
importers and exporters of pre-charged
equipment and closed-cell foams would
be required to report their imports and
exports to EPA if either their imports or
their exports contained a total of more
than 25,000 mtCO2e of fluorinated
GHGs. The reports would be similar to
those required of importers and
exporters of bulk GHGs under subpart
OO of the final MRR published on
October 28, 2009. In addition,
equipment importers would be required
to report the types and charge sizes of
equipment and the number of pieces of
each type of equipment that they
imported or exported, while foam
importers would be required to report
the volume of foam and fluorinated
GHG density of the foam that they
imported. Importers and exporters
would report at the corporate level.
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2. Summary of Initial Proposed Rule
and Comments Received
In the proposed MRR published on
April 10, 2009, we did not propose to
require reporting of the quantities of
GHGs imported and exported inside
products. We were concerned that it
would be difficult for importers and
exporters to identify and quantify the
quantities of GHGs inside some
products and that the number of
importers and exporters would be high.
However, we requested comment on the
option of requiring reporting of imports
and exports of HFCs and SF6 contained
in pre-charged air-conditioning,
refrigeration, and electrical equipment
and in closed cell foams. We noted that
for these products, information on the
size and chemical identity of the charge
or blowing agent is likely to be readily
available to importers and exporters
(e.g., from nameplates affixed to
equipment, servicing manuals, and
product information for foams).
Moreover, as noted above, the total
quantities of imported and exported
fluorinated GHGs in pre-charged
equipment and foams are significant.
We received a range of comments on
whether or not we should require
reporting of fluorinated GHGs imported
or exported inside of pre-charged
equipment and closed-cell foams.
Several manufacturers and importers of
fluorinated GHGs supported such a
requirement, noting that the identities
and quantities of fluorinated GHGs
inside equipment and foams are wellknown, that imported and exported
quantities are significant in aggregate,
that the number of importers and
exporters is small, and that information
on fluorinated GHGs imported or
exported inside of equipment could
help to inform legislation being
considered by Congress, which would
include fluorinated GHGs imported in
pre-charged equipment under emissions
caps. Some of these commenters stated
that failure to require reporting of
imported equipment and foams would
be unfair to domestic manufacturers,
who would be subject to reporting from
which foreign manufacturers would be
exempted. They observed that this
inequity could drive production
offshore, harming the U.S. economy and
possibly increasing global GHG
emissions if less efficient manufacturers
in developing countries took over the
lost U.S. production.
Equipment importers and a
fluorocarbon producer opposed a
requirement to report imports and
exports of fluorinated GHGs in precharged equipment and foams, stating
that such a requirement would be
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18683
unnecessary and costly. These
commenters stated that the quantities of
fluorinated GHGs inside individual
pieces of equipment are small, ranging
from ounces to pounds, and that
emissions from such equipment are
extremely small because the systems are
hermetically sealed.
After carefully considering the
comments and available information on
imports and exports of fluorinated
GHGs inside pre-charged equipment
and closed-cell foams, we are proposing
to require reporting of these imports and
exports.
3. Definition of the Source Category
This source category includes
importers and exporters of pre-charged
equipment and closed-cell foams that
contain fluorinated GHGs. Pre-charged
equipment includes air-conditioning
equipment or equipment components
that contain HFCs and electrical
equipment or equipment components
that contain SF6 or PFCs. Closed-cell
foams include closed-cell foams blown
with HFC blowing agents.
Air-conditioning and refrigeration
equipment generally uses HFC
refrigerants. In this application, HFCs
serve as substitutes for ozone-depleting
substances (ODSs), which are being
phased out under the Montreal Protocol
and Title VI of the CAA. Because some
ODSs (i.e., HCFCs) are only beginning to
be phased out, the use of HFCs in
equipment such as window and
residential air-conditioners is expected
to grow very quickly over the next
decade. Imports and exports of HFC precharged equipment may grow as well.
Although the quantities of chemical
contained in each unit are small in
absolute terms (i.e., a few pounds or
less), they are more significant in CO2equivalent terms, ranging up to eleven
mtCO2e per unit for pre-charged
commercial air-conditioners. This
significance is due to the high GWPs of
the HFCs.
HFCs are also used as blowing agents
during the manufacture of foams. Opencell foams are assumed to emit 100
percent of the blowing agent in the year
they are manufactured, whereas closedcell foams emit only a fraction of their
total HFC content upon manufacture.
Foam products that are closed-cell and
imported or exported as a finished foam
product therefore have potential to emit
the blowing agent remaining in the foam
after manufacture. Closed cell foams
that are imported or exported include:
polyurethane (PU) rigid foam used as
insulation in domestic refrigerators and
freezers; commercial refrigeration foam;
PU rigid sandwich panel continuous
and discontinuous foam; extruded
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polystyrene (XPS) sheet foam; and XPS
boardstock foam.
SF6 is used as an electrical insulator
and arc-quenching gas in electrical
transmission equipment, including
circuit breakers and gas-insulated
substations. Again, the quantities of SF6
in each unit are often small in absolute
terms (around 14 pounds per circuit
breaker), but are larger in CO2equivalent terms (around 150 mtCO2e
per circuit breaker).40
Our analysis indicates that the
quantities of fluorinated GHGs imported
and exported inside of pre-charged
equipment and foams are significant.
Imports are estimated to total about 21
million mtCO2e, while exports are
estimated to total about 8 million
mtCO2e. For further information, please
see the TSD for Imports and Exports of
Pre-Charged Equipment and Foams
(Revised) in the docket for this
rulemaking (EPA–HQ–OAR–2009–
0927).
We are proposing to require reporting
for a number of reasons. First, we have
determined that exports and particularly
imports of pre-charged equipment and
foam have a substantial impact on the
total U.S. supply of fluorinated GHGs
and of industrial GHGs generally. Based
on the estimates above, imports
constitute between seven and ten
percent of the net U.S. supply of
fluorinated GHGs, while exports are
equivalent to between three and four
percent of that total. (The range is based
on slightly different estimates of the net
U.S. supply based on bottom-up and
top-down approaches.) We estimate that
22 million pieces of equipment and 66
million board-feet of foam are imported
annually. Although the quantities of
HFCs and SF6 in individual pieces of
equipment may be small in terms of the
mass of chemical, the high GWPs of
these chemicals can make them
significant in CO2-equivalent terms. For
example, a pre-charged residential air
conditioner (unitary) contains about 7
tons of CO2e, while an average size
circuit breaker with a shipping charge of
SF6 (20 percent of a full, operational
charge) contains over 150 tons of CO2e.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
40 Emissions from use and manufacture of
electrical equipment are addressed under subparts
DD and SS of this rule; subpart QQ addresses only
the import and export of such equipment.
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Imported and exported fluorinated
GHGs are added to or subtracted from
the U.S. supply of fluorinated GHGs
regardless of whether they are imported
in bulk or in equipment. Every year, a
part of the U.S. fluorinated GHG supply
is used to charge new equipment or to
blow closed-cell foams. If equipment is
imported already containing a charge,
that charge offsets demand that would
otherwise have occurred for fluorinated
GHGs that are produced domestically or
imported in bulk. Accounting for the
quantities of fluorinated GHGs in
equipment therefore significantly
improves our understanding of the U.S.
supply of fluorinated GHGs. Although
commenters who opposed reporting
noted that leak rates from some types of
imported equipment are low, this does
not distinguish fluorinated GHGs
imported inside of equipment from
fluorinated GHGs that are charged into
the same type of equipment after its
import or domestic manufacture. Any
imported or domestically produced
fluorinated GHG may be stored for many
years inside equipment before being
emitted or destroyed.41
The second reason that we are
proposing to require reporting of
imports and exports of fluorinated
GHGs inside pre-charged equipment
and foams is that discussions with
industry experts indicate that the
numbers of importers and exporters are
relatively small, limiting the
administrative burden of the rule and
increasing the cost-effectiveness of the
data gathering. Experts from the airconditioning and refrigeration industry
estimate that there are approximately 50
importers and 25 exporters of precharged air-conditioning and
refrigeration equipment, and experts
from the electrical equipment industry
estimate that there are approximately 8
importers and 10 exporters of precharged electrical equipment. Based on
the membership of various trade
organizations including foam
manufacturers and distributors, EPA
estimates that there are approximately
41 Even if the fluorinated GHG is recovered from
the equipment at the end of the equipment’s life,
it will ultimately be either emitted or destroyed.
Recycling delays emission or destruction (and
reduces demand for new fluorinated GHG), but it
does not avoid it.
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50 entities that import and 25 entities
that export foams. These numbers are
considerably smaller than the number of
importers and exporters of bulk
fluorinated GHGs that are covered by
the final rule published October 30,
2009.
Third, we estimate that the costs
associated with identifying, quantifying,
and reporting the quantities of
fluorinated GHGs imported and
exported inside pre-charged products
and foams are reasonably modest. As
noted above, information on the
chemical identities and sizes of
equipment charges should be readily
available to importers and exporters,
and the same is true for the identities
and densities of the HFCs in foams,
which strongly influence the insulating
capacities of the foams.
Inclusion of other products that
contain fluorinated GHGs. EPA’s
understanding is that pre-charged
equipment and closed-cell foams
account for the great majority of
fluorinated GHGs that are imported in
or exported from the United States
inside of products. However, a variety of
products containing fluorinated
greenhouse gases (fluorinated GHGs),
nitrous oxide (N2O), and carbon dioxide
(CO2) are imported into and exported
from the United States, including, for
example, aerosols containing HFCs. EPA
requests comment on the magnitude of
imports and exports of these other
products and on whether such imports
and exports should be reported under
this subpart.
4. Selection of Reporting Threshold
We are proposing to require that
importers and exporters of fluorinated
GHGs contained in pre-charged
equipment and closed cell foams report
their imports and exports if either their
total imports or their total exports, in
equipment, foams, and in bulk, exceed
25,000 mtCO2e per year. This threshold
is the same as that for bulk imports and
exports.
Tables 9 and 10 of this preamble show
the estimated imports and exports (in
mtCO2e) and facilities (corporations)
that would be covered under the various
thresholds for imports and exports of
equipment and foam.
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TABLE 9—THRESHOLD ANALYSIS FOR FLUORINATED GHGS IMPORTED INSIDE PRE-CHARGED EQUIPMENT AND CLOSEDCELL FOAMS
SF6 electrical equipment
HFC refrigeration/AC
equipment
Threshold level
Imports
covered
1,000 ................................................................................
10,000 ..............................................................................
25,000 ..............................................................................
100,000 ............................................................................
Importers
covered
15,733,523
15,733,523
15,733,523
15,733,523
50
50
50
50
Imports
covered
Closed-cell foams
Importers
covered
1,888,932
1,888,932
1,888,932
1,888,932
8
8
8
8
Imports
covered
3,025,285
3,025,285
3,025,285
0
Importers
covered
50
50
50
0
TABLE 10—THRESHOLD ANALYSIS FOR FLUORINATED GHGS EXPORTED INSIDE PRE-CHARGED EQUIPMENT AND CLOSEDCELL FOAMS
Exports
covered
Threshold level
1,000 ................................................................................
10,000 ..............................................................................
25,000 ..............................................................................
100,000 ............................................................................
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
In the absence of importer- and
exporter-specific information, we
assumed that within the three general
categories of products, each importer
and exporter imported or exported the
same quantity of fluorinated GHGs.
(Exports of SF6 in electrical equipment
were the sole exception to this.) This
assumption led to the conclusion that
100 percent of imported and exported
pre-charged equipment and foams
(except exported electrical equipment)
would be reported at the 25,000 mtCO2e
threshold. In fact, imports and exports
are likely to be concentrated among a
subset of importers and exporters, and
fewer entities are therefore likely to
report at the 25,000 mtCO2e threshold.
We request comment on the distribution
of imports and exports among importers
and exporters and on the likely coverage
(in percentage terms) of imported and
exported equipment and foams at the
25,000 mtCO2e threshold. An alternative
approach would be to lower the
threshold or to require reporting by all
importers and exporters of pre-charged
equipment and closed cell foams, but
EPA is concerned that this approach
could burden many small importers and
exporters with reporting while gaining
little additional coverage of imports and
exports in equipment and foams.
5. Selection of Proposed Monitoring
Methods
We are proposing to require importers
and exporters of equipment and foams
to estimate their imports and exports of
each fluorinated GHG by multiplying
the mass of the fluorinated GHG
contained in each type of equipment or
foam by the number of pieces of
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Jkt 220001
Exporters
covered
5,247,905
5,247,905
5,247,905
5,247,905
25
25
25
25
Exports
covered
153,323
107,326
0
0
equipment or by the volume of foam, as
appropriate. As noted above, we believe
that information on fluorinated GHG
identity and charge size (or density, for
foams) should be readily available to
importers and exporters.
Under the current MRR, bulk
importers and exporters of fluorinated
GHGs are not required to report
individual shipments totaling less than
250 mtCO2e of fluorinated GHGs. This
exemption was intended to exclude
small shipments, e.g., of chemical
samples being shipped for analysis,
from reporting. We established the
exemption after an analysis of import
and export shipments showed that it
would decrease reporting by less than
0.1 percent. We are not proposing a
similar exemption for small shipments
of equipment and foams because we do
not believe it would be necessary and
because we are concerned that it might
lead to the exclusion of a significant
share of imports and exports of these
products. We do not believe the smallshipment exemption would be
necessary because the definition of
import in subpart A already excludes
the bringing into the United States of
household effects such as refrigerators
and window air conditioners. We are
concerned that the exemption may
result in excluding a significant share of
imports and exports because 250
mtCO2e equates to a large number of
pieces of some types of equipment (e.g.,
over 1,300 household refrigerators).
6. Selection of Data To Be Reported
EPA is proposing to require importers
and exporters of pre-charged equipment
and closed cell foams to report the
following:
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Exporters
covered
10
5
................
................
Exports
covered
3,025,285
3,025,285
3,025,285
3,025,285
Exporters
covered
25
25
25
25
(1) The total mass in metric tons of
each fluorinated GHG imported or
exported in pre-charged equipment or
closed-cell foams.
(2) For each type of pre-charged
equipment, the identity of the
fluorinated GHG used as a refrigerant or
electrical insulator, charge size (holding
charge,42 if applicable), and number
imported or exported.
(3) For closed-cell foams that are
imported or exported inside of
appliances, the identity of the
fluorinated GHG contained in the foam,
the quantity of fluorinated GHG
contained in the foam in each
appliance, and the number of
appliances imported for each type of
appliance.
(4) For closed cell-foams that are not
inside of appliances, the identity of the
fluorinated GHG, the density of the
fluorinated GHG in the foam (kg
fluorinated GHG/cubic foot), and the
quantity of foam imported or exported
(cubic feet) for each type of closed-cell
foam.
(5) Dates on which the pre-charged
equipment or closed-cell foams were
imported or exported.
(6) Ports of entry through which the
pre-charged equipment or closed-cell
foams passed.
(7) Countries from or to which the
pre-charged equipment or closed-cell
foams were imported or exported.
We are proposing to collect this
information because it is necessary
either to understand the total volume of
fluorinated GHGs imported or exported
42 This refers to any holding charge consisting of
a fluorinated GHG. Holding charges consisting of
other gases, such as nitrogen, are not included.
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inside of pre-charged equipment and
foams (and thereby contributing to the
U.S. supply of fluorinated GHGs) or to
verify submitted information.
7. Selection of Recordkeeping
Requirements
EPA is proposing to require importers
and exporters of equipment and closed
cell foams to retain the following
records:
(1) A copy of the bill of lading for the
import or export,
(2) The invoice for the import or
export, and
(3) For imports, the U.S. Customs
entry form.
This information is necessary to verify
submitted information.
E. Electrical Equipment Manufacture or
Refurbishment
1. Definition of the Source Category
This source category comprises
electrical equipment manufacturers and
refurbishers of SF6 or PFC-insulated
closed-pressure equipment and sealedpressure equipment including gasinsulated substations, circuit breakers
and other switchgear, gas-insulated
lines, or power transformers containing
sulfur-hexafluoride (SF6) or
perfluorocarbons (PFCs).
Electrical equipment employed to
transmit and distribute electricity
constitutes the largest use of SF6 in the
world. The dielectric strength and arcquenching characteristics of SF6 make it
an extremely effective electrical
insulator and interrupter. For this
reason, the electric power industry in
the United States has used this gas since
the 1950s in both closed-pressure and
sealed-pressure equipment including
gas-insulated substations, circuit
breakers and other switchgear, and gasinsulated lines. Closed-pressure
equipment requires periodic refilling
(topping up) with gas during its lifetime,
whereas sealed-pressure equipment
generally does not. SF6 has replaced
flammable insulating oils in many
applications and allows for more
compact substations in dense urban
areas. SF6 insulated equipment has also
made expansion of the grid through
transmission over significantly longer
distances economically practical.
Currently, there are no available
substitutes for SF6 in this application.
For further information, see the SF6
from Electrical Equipment
Manufacturers TSD in the docket for
this rulemaking (EPA–HQ–OAR–2009–
0927).
Manufacturers of gas insulated
electrical equipment purchase bulk SF6
gas to: (1) Install a holding or shipping
charge in high-voltage closed-pressure
equipment, (2) ship alongside closedpressure equipment for topping off at
installation site, (3) fill sealed-pressure
equipment with its intended lifetime
supply of SF6, and (4) develop and test
equipment.
Emissions of SF6 from equipment
manufacturers can occur during the
development and testing of equipment
and during equipment filling, but
emissions can also occur during the
other uses of SF6 at manufacturing
facilities. Refurbishment of equipment
generally occurs at facilities used to
manufacture new equipment and
emissions typically occur during the
leak test operations for gas-containing
components as well as the disassembly
and reassembly of equipment.
PFCs are sometimes used as
dielectrics and heat transfer fluids in
power transformers. PFCs are also used
for retrofitting CFC–113 cooled
transformers. The most common PFC
used in this application is
perfluorohexane (C6F14). In terms of
both absolute and carbon-weighted
emissions, PFC emissions from
electrical equipment are generally
believed to be much smaller than SF6
emissions from electrical equipment.
According to the U.S. Inventory of
Greenhouse Gas Emissions and Sinks:
1990–2007 (EPA 2009), total U.S.
estimated emissions of SF6 from
electrical equipment manufacturers
were 0.81 million metric tons CO2e in
2006. EPA is proposing to require
reporting from electrical equipment
manufacture and refurbishment
facilities because these operations
represent a significant source,
approximately 5 percent of U.S. SF6
emissions. It is estimated that ten
equipment manufacturers were
responsible for these emissions.
EPA is seeking comment on whether
transformers using PFCs are currently
manufactured in the United States EPA
is also seeking comment on whether
PFC emissions associated with the
production of this equipment occur at
the same rate as SF6 emissions from
equipment manufacture and whether
emissions occur during the same
processes. EPA is proposing to include
emissions of PFCs emitted during the
manufacture or refurbishment of PFCcontaining power transformers because
while PFCs are known to be used in this
application, the National Inventory has
no information on the magnitude of this
source. PFCs are very potent and
persistent greenhouse gases and an
accurate inventory of use and emissions
from all sources is important.
2. Selection of Reporting Threshold
We propose to require electrical
equipment manufacturers to report their
SF6 and PFC emissions if their total
annual purchases of SF6 and PFCs
exceed 23,000 lbs. This consumptionbased threshold is equivalent to an
emissions-based threshold of 25,000
metric tons CO2 Eq., assuming an
average manufacturer emission rate of
10 percent.43
In developing this proposed
threshold, we considered several
emission-based threshold options
including 1,000 metric tons CO2e;
10,000 metric tons CO2e; 25,000 metric
tons CO2e: and 100,000 metric tons
CO2e. SF6 and PFC consumption
thresholds of 922; 9,220; and 92,200 lbs
of SF6 and PFC were also considered,
corresponding to the emission threshold
options of 1,000; 10,000; and 100,000
metric tons CO2e, respectively.
Summaries of the threshold options
(consumption-based and emissionsbased) and the number of equipment
manufacturers and emissions covered
under each threshold are presented in
Table 11 of this preamble.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
TABLE 11—THRESHOLD ANALYSIS FOR ELECTRICAL EQUIPMENT MANUFACTURE
Emission threshold level
(metric tons CO2e/yr)
Total national
emissions
1,000 ........................................................................................
10,000 ......................................................................................
25,000 ......................................................................................
43 The 10 percent emission rate is the average of
the ‘‘ideal’’ and ‘‘realistic’’ manufacturing emission
rates (4 percent and 17 percent, respectively)
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Total
number
of facilities
814,128
814,128
814,128
10
10
10
identified in a paper prepared under the auspices
of the International Council on Large Electric
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Emissions covered
Metric tons
CO2e/yr
Facilities covered
Percent
814,128
814,128
814,128
100
100
100
Facilities
10
10
10
Percent
100
100
100
Systems (CIGRE) in February 2002 (O’Connell et al.
2002).
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TABLE 11—THRESHOLD ANALYSIS FOR ELECTRICAL EQUIPMENT MANUFACTURE—Continued
Emission threshold level
(metric tons CO2e/yr)
Total national
emissions
100,000 ....................................................................................
The proposed consumption threshold
and the corresponding emissions
threshold level is consistent with
general requirements of the Final MRR
(74 FR 56260) and provides
comprehensive coverage of emissions
for this sector. A consumption-based
threshold was selected because it
permits equipment manufacturers to
quickly determine whether they are
covered by referring to SF6 and PFC
purchase records.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
3. Selection of Proposed Monitoring
Methods
We are proposing that all electrical
equipment manufacturing facilities
where SF6 and PFC purchases exceed
23,000 lbs per year report all SF6 and
PFC emissions using a mass-balance
approach. This would include all
emissions from equipment testing,
manufacturing (including filling),
decommissioning and disposal,
refurbishing, and from storage cylinders.
We are proposing this approach because
it is the most accurate and because all
equipment manufacturers should be
able to conduct the mass-balance
analysis using readily available
information.
The proposed monitoring methods are
similar to the methodologies described
in the 2006 IPCC Guidelines Tier 3
methods for emissions from electrical
equipment manufacturing. These
methodologies outline a mass-balance
approach that is comparable to the
proposed approach for subpart DD
Electric Power System Equipment.
The mass-balance approach we are
proposing for electrical equipment
manufacturers works by tracking and
systematically accounting for all facility
uses of SF6 and PFCs during the
reporting year. The quantities of SF6 and
PFCs that cannot be accounted for are
assumed to have been emitted to the
atmosphere. The emissions of SF6 and
PFCs would be estimated and reported
separately.
The following equation describes the
proposed facility-level mass-balance
approach. (For brevity, the equation
refers only to SF6; however, the method
would also apply to PFCs in power
transformers.)
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Total
number
of facilities
814,128
Emissions covered
Metric tons
CO2e/yr
5
Equipment Manufacturing Emissions =
Decrease in SF6 Inventory + Acquisitions
of SF6¥Disbursements of SF6
Where:
Decrease in SF6 Inventory = SF6 stored in
containers at the beginning of the
year¥SF6 stored in containers at the end
of the year
Acquisitions of SF6 = SF6 purchased from
chemical producers or distributors in
bulk + SF6 returned by equipment users
or distributors with or inside equipment
+ SF6 returned to site after off-site
recycling
Disbursements of SF6 = SF6 contained in
new equipment delivered to customers +
SF6 delivered to equipment users in
containers + SF6 returned to suppliers +
SF6 sent off-site for recycling + SF6 sent
to destruction facilities.
EPA is seeking comment on the
proposed methods for determining
disbursements of SF6 or PFCs,
specifically, with respect to SF6 or PFCs
contained in new equipment delivered
to customers and SF6 or PFCs delivered
to equipment users in cylinders. Two
methods are being proposed.
Disbursement of SF6 or PFCs to
customers in new equipment or
cylinders could be estimated by
weighing containers before and after gas
from the containers was used to fill
equipment or cylinders, or by using
flow meters to measure the amount of
gas used to fill equipment or cylinders.
EPA requests comment on these two
options.
Alone, both of these options would
inappropriately count as
‘‘disbursements’’ emissions that
occurred between the flow meter or
weighed container and the equipment
being filled. These emissions could
include losses from coupling and
decoupling of fill valves and leaks from
hoses or other flow lines that connect
the container to the equipment that
being filled. EPA is therefore proposing
to require that these emissions be
quantified and subtracted from the
disbursement total.
Specifically, EPA is proposing to
require that these emissions be
estimated using measurements and/or
engineering assessments or calculations
based on chemical engineering
principles or physical or chemical laws
or properties. Such assessments or
calculations could be based on, as
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Facilities covered
Percent
569,890
70
Facilities
5
Percent
50
applicable, the internal volume of the
hose or line that was open to the
atmosphere during coupling and
decoupling activities, the internal
pressure of the hose or line, the time the
hose or line was open to the atmosphere
during coupling and decoupling
activities, the frequency with which the
hose or line was purged and the flow
rate during purges. Such methods could
also include the use of leak detection
methods (e.g., EPA Method 21 and the
Protocol for Equipment Leak Emission
Estimates) to determine a loss factor
appropriate to calculate emissions.
Unexpected or accidental emissions
from the filling lines or hoses would be
required to be included in the total.
EPA is seeking comment on the
specific methods that should be
employed to estimate emission losses
from hoses or flow lines and on whether
a particular method or set of methods
should be required for this estimate. In
addition, EPA requests comment on
whether emissions downstream of the
containers dispensing the SF6 or PFCs
consist solely of emissions from lines or
hoses. EPA’s understanding is that
electrical equipment is at a vacuum and
is sealed prior to being filled with SF6
or PFCs; however, if it contains air or
nitrogen and this gas is purged during
the filling process, then the method
should also account for SF6 and PFC
emissions that occur during such
purging.
EPA is also considering other options
for accurately measuring the quantities
of SF6 or PFCs disbursed to equipment
users in equipment. (These options are
described in more detail in the TSD.)
One option being considered is to
assume that the mass of SF6 or PFCs
disbursed to customers in equipment is
equal to the nameplate capacity of the
equipment (or, where the equipment is
shipped with a partial charge, equal to
the nameplate capacity of the
equipment times the ratio of the
densities of the partial charge and the
full charge.) Although the nominal
nameplate capacity could be used for
this calculation, EPA is concerned that
the actual mass of SF6 or PFCs charged
into each piece of equipment may vary
by a few percent from the nominal
capacity (e.g., because there is some
variability in the internal volume of the
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equipment or in the density to which
the equipment is charged). Because the
mass-balance approach requires precise
inputs, inaccuracies of even two or three
percent could lead to very large
inaccuracies in the facility’s emissions
estimate.
One way of developing a more precise
estimate of the nameplate capacity of
equipment would be to fill the
equipment with a fluid and then to
carefully recover the fluid, measuring
what was recovered. This fluid could be
SF6, another gas, or a liquid. If SF6 was
used, the equipment would be charged
to its operational or shipping SF6
density using the facility’s usual
methods and then emptied. The mass of
the SF6 recovered, adjusted slightly for
the residual pressure of the SF6 that
would remain in the equipment even at
a deep vacuum, could be equated to the
full or shipping charge, as applicable.
One advantage of this approach is that
it would reflect the actual SF6 charging
practices of the facility; one
disadvantage is that it could result in
small SF6 emissions during the charging
and recovery steps.
If a liquid was used, the equipment
would be filled carefully, ensuring that
the full volume was filled, and then
emptied. The volume of the liquid
recovered would be equated to the
internal volume of the equipment.44
This volume times the SF6 density at the
full charge would yield the nameplate
capacity of the equipment.
To account for variability, a certain
number of these measurements would
need to be performed to develop a
robust and representative average
nameplate capacity (or shipping charge)
for each make and model. The specific
number of measurements would depend
on the variability of the nameplate
capacity within each make and model,
as discussed in the TSD. It may be
appropriate to select equipment samples
filled at different times to reflect day-today variability in the facility’s filling
practices and conditions. EPA seeks
comment on these other options for
accurately measuring the quantities of
SF6 and PFCs disbursed to customers in
equipment and/or cylinders.
Another option is to require that the
equipment filled with SF6 or the PFC
from the container be weighed before
and after filling. The tare weight of the
equipment would then be subtracted
from the weight of the filled equipment
to determine the weight of the gas in the
equipment, and therefore, the weight of
the actual disbursement. One potential
44 The temperature of the liquid would need to be
kept constant throughout this exercise to obtain an
accurate measurement of the volume.
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concern regarding this option is that the
mass of the SF6 or PFC charged into the
equipment is likely to be low relative to
the mass of the equipment; thus, it may
be difficult to obtain a precise
measurement of the mass of the SF6 or
PFC using this method (i.e., within 1
percent) even if the scale is precise and
accurate to within 1 percent of full
scale. EPA requests comment on this
approach.
Installation of Electrical Equipment at
Electric Power Systems. EPA also
requests comment on two issues related
to equipment installation and
commissioning that is performed by
equipment manufacturers at electric
power systems. The first issue is
whether an equipment installation
mass-balance equation is required to
measure emissions from equipment
installation and commissioning that is
performed by equipment manufacturers
at utility locations. Where the
manufacturer filled the equipment
before transferring custody to the
equipment user, EPA is assuming that
the manufacturer would be responsible
for the associated emissions. This would
also apply to equipment that was filled
at the factory but whose charge leaked
out before being delivered to the
customer. Quantitative methods for
addressing these issues are discussed in
more detail in the TSD.
The second issue is whether
manufacturers should be required to
certify to equipment users the actual
quantity (mass) of SF6 or PFCs charged
into the equipment at installation. EPA
understands that in some cases,
manufacturers may deliberately exceed
the nameplate capacity of equipment
when charging it, e.g., to postpone the
re-fill of the equipment in the event that
the equipment develops a leak. If this is
the case, then the actual initial charge
of the equipment should be conveyed
clearly to the equipment user, and the
mass-balance approach used by the
equipment user should be adjusted to
reflect the over-charge. If it is not, the
user will underestimate emissions.
(These issues are discussed in more
detail in the TSD.) EPA requests
comment on how frequently equipment
is over-charged at installation, and on
quantitative methods for compensating
for this overcharge in user emissions
estimates (i.e., under proposed subpart
DD).
Other Options Considered. In
developing the proposed approach, we
reviewed the 2006 IPCC Guidelines, the
United States GHG Inventory, DOE
1605(b), EPA’s Climate Leaders
Program, and The Climate Registry. In
our review of the IPCC Guidelines, we
also considered the IPCC Tier 1 and the
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IPCC Tier 2 methods for calculating and
reporting SF6 and PFC emissions.
Although the IPCC Tier 1 and IPCC Tier
2 methods are simple, IPCC does not
provide default emission factors for the
United States due to lack of data.
Furthermore, SF6 use in electrical
equipment manufacturing is largely
dependent on the type of equipment
being produced and the specific
handling practices at facilities.
Applying an emission factor to all
equipment manufacturers would not
take into account the different types of
equipment being produced at each
facility or the variation in handling
practices among facilities. Nor would it
provide data of sufficient accuracy for
the source or on a per facility basis. As
a result, we are not proposing the IPCC
Tier 1 or Tier 2 method.
We are not proposing to require
continuous emissions monitoring
(CEMs) because of insufficient
information on which to base a decision
and because CEMs is not expected to be
practical for this source category at this
time due to the intermittent and
widespread nature of the emissions.
EPA seeks comment on whether
continuous emissions monitoring is
technically feasible for this source
category.
4. Selection of Procedures for Estimating
Missing Data
It is expected that equipment
manufacturers should be able to obtain
100 percent of the data needed to
perform the mass-balance calculations
for both SF6 and PFCs. The use of the
mass-balance approach requires correct
records for all inputs. However, if
needed, missing data can be replaced
using data from similar manufacturing
operations, and from similar equipment
testing and decommissioning activities
for which data are available.
5. QA/QC Requirements
We propose that electrical equipment
manufacturers be required to use
flowmeters or scales that are accurate
and precise to within one percent of full
scale. In addition, we are proposing to
require manufacturers to establish
procedures for and document their
measurements and calculations under
this subpart, including check-out sheets
and weigh-in procedures for cylinders,
residual gas amounts in cylinders sent
back to suppliers, invoices for gas and
equipment purchases or sales, and
documentation of recycling and
destruction. The records that are being
proposed are the minimum needed to
reproduce and confirm emission
calculations.
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6. Selection of Data Reporting
Requirements
We propose annual reporting for the
electrical equipment manufacturing and
refurbishing industry. Equipment
manufacturers would report all SF6 and
PFC emissions, including those from
equipment testing, equipment
manufacturing, and bulk SF6 and PFC
handling. However, the emissions
would not need to be broken down and
reported separately for testing,
manufacturing, or bulk SF6 and PFC
handling. Along with their emissions,
electrical equipment manufacturers
would be required to submit the
following supplemental data: SF6 and
PFCs with or inside equipment
delivered to customers, the nameplate
capacity of the equipment delivered to
customers, SF6 and PFCs returned by
customers with or inside equipment,
bulk SF6 and PFC purchases, SF6 and
PFCs sent off-site for destruction or to
be recycled, SF6 and PFCs returned from
offsite after recycling, SF6 and PFCs
stored in containers at the beginning
and end of the year, SF6 and PFCs
returned to suppliers. For any missing
data, manufacturers would be required
to report the reason the data were
missing, the length of time the data were
missing, the method used to estimate
emissions in their absence, and the
quantity of emissions thereby estimated.
These data would be submitted
because they are the minimum data that
are needed to understand and reproduce
the emission calculations that are the
basis of the reported emissions.
7. Selection of Records That Must Be
Retained
We propose that electrical equipment
manufacturers be required to keep
records documenting (1) their adherence
to the QA/QC requirements specified in
the proposed rule, and (2) the data that
would be included in their emission
reports, as specified above.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
F. Subpart A Revisions
Amendments to the General
Provisions. In a separate rulemaking
package that was recently published
(March 16, 2010), EPA issued minor
harmonizing changes to the general
provisions for the GHG reporting rule
(40 CFR part 98, subpart A) to
accommodate the addition of source
categories not included in the 2009 final
rule (e.g., subparts proposed in April
2009 but not finalized in 2009, any new
subparts that may be proposed in the
future). The changes update 98.2(a) on
rule applicability and 98.3 regarding the
reporting schedule to accommodate any
additional subparts and the schedule for
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their reporting obligations (e.g., source
categories finalized in 2010 would not
begin data collection until 2011 and
reporting in 2012).
In particular, we restructured 40 CFR
98.2(a) to move the lists of source
categories from the text into tables. A
table format improves clarity and
facilitates the addition of source
categories that were not included in
calendar year 2010 reporting and would
begin reporting in future years. A table,
versus list, approach allows other
sections of the rule to be updated
automatically when the table is
updated; a list approach requires
separate updates to the various list
references each time the list is changed.
In addition to reformatting the
98.2(a)(1)–(2) lists into tables, other
sections of subpart A were reworded to
refer to the source category tables
because the tables make it clear which
source categories are to be considered
for determining the applicability
threshold and reporting requirements
for calendar years 2010, 2011, and
future years.
The source categories proposed in this
notice would be added within 40 CFR
98.2 as follows. The following source
categories would be added to the list of
‘‘all-in’’ source categories referenced in
40 CFR 98.2(a)(1), because they have a
production capacity or gas consumption
threshold rather than a CO2e emission
threshold:
• Electric power systems that include
electrical equipment with a total
nameplate capacity that exceeds 17,820
lbs (7,838 kg) of SF6 or perfluorocarbons
(PFCs) (subpart DD).
• Electric power equipment
manufacturing with total annual SF6
and PFC purchases (combined) that
exceed 23,000 lbs per year (subpart SS).
The following source categories
would be subject to the rule if facility
emissions exceed 25,000 metric tons
CO2e per year. Therefore, these source
categories would be added to the list of
emission threshold source categories
referenced in 40 CFR 98.2(a)(2).
• Fluorinated gas production
facilities whose emissions would exceed
25,000 mtCO2e in the absence of control
technologies (subpart L).
• Facilities with electronics
manufacturing processes (as defined in
proposed 40 CFR part 98, subpart I).
In addition, importers and exporters
of pre-charged equipment or closed-cell
foam products containing fluorinated
GHGs, N2O, or CO2 would be added to
the list of suppliers referenced in 40
CFR 98.2(a)(4). For all of these source
categories, facilities would be required
to begin collecting data in 2011 for
reporting in 2012.
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18689
Today’s proposed rule includes a
number of definitions applicable to
specific source categories. The agency is
not planning to add these definitions to
the definitions section in Subpart A
because these definitions relate to these
specific subparts and do not have
broader applicability to EPA’s
mandatory reporting regulations.
Instead, EPA intends to include these
definitions in the applicable subparts.
EPA has sought to avoid any conflict
between these subpart-specific
definitions and the definitions in
Subpart A. In one instance, the
supplemental proposal for electric
power systems, EPA is proposing to use
a category-specific definition of facility
rather than the general definition of
facility in the General Provisions. The
reasons for this category-specific
definition of facility are set forth in
section II.C of this preamble. The
remaining definitions are intended as
supplements to the definitions section
in the General Provisions. EPA does not
believe these definitions create conflicts
with the General Provisions, although it
welcomes comments on this issue. To
the extent regulated entities are in doubt
as to which definition applies, they
should assume that the category-specific
definitions are controlling.
We propose to amend 40 CFR 98.7
(incorporation by reference) to include
standard methods used in the proposed
subparts. In particular, we would add
the 2006 International SEMATECH
Manufacturing Initiative’s Guidelines
for Environmental Characterization of
Semiconductor Process Equipment and
SEMI E10–0304 Specification for
Definition and Measurement of
Equipment Reliability, Availability, and
Maintainability (2006), which are
referenced in proposed 40 CFR 98.94
(Monitoring and QA/QC Requirements
for 40 CFR part 98, subpart I, electronics
manufacturing) and 40 CFR 98.97
(Records that must be retained). In
addition, we propose to revise the
paragraphs listing several ASME
standards that are already contained in
40 CFR 98.7 to indicate that these
standards are also referenced by
proposed 40 CFR 98.124 (Monitoring
and QA/QC requirements in proposed
40 CFR part 98, subpart L, fluorinated
gas production).
III. Economic Impacts of the Rule
This section of the preamble examines
the costs and economic impacts of the
proposed rulemaking and the estimated
economic impacts of the rule on affected
entities, including estimated impacts on
small entities. Complete detail of the
economic impacts of the proposed rule
can be found in the text of the economic
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impact analysis (EIA) in the docket for
this rulemaking (EPA–HQ–OAR–2009–
0927).
A. How were compliance costs
estimated?
1. Summary of Method Used To
Estimate Compliance Costs
EPA used available industry and EPA
data to characterize conditions at
affected sources. Incremental
monitoring, recordkeeping, and
reporting activities were then identified
for each type of facility and the
associated costs were estimated. The
annual costs reported in 2006$. EPA’s
estimated costs of compliance are
discussed below and in greater detail in
section 4 of the economic impact
analysis (EIA).
Labor Costs. The vast majority of the
reporting costs include the time of
managers, technical, and administrative
staff in both the private sector and the
public sector. Staff hours are estimated
for activities, including:
• Monitoring (private): Staff hours to
operate and maintain emissions
monitoring systems.
• Recordkeeping and Reporting
(private): Staff hours to gather and
process available data and reporting it to
EPA through electronic systems.
• Assuring and releasing data
(public): Staff hours to quality assure,
analyze, and release reports.
Staff activities and associated labor
costs will potentially vary over time.
Thus, cost estimates are developed for
start-up and first-time reporting, and
subsequent reporting. Wage rates to
monetize staff time are obtained from
the Bureau of Labor Statistics (BLS).
Equipment Costs. Equipment costs
include both the initial purchase price
and any facility modification that may
be required. Based on expert judgment,
the engineering costs analyses
annualized capital equipment costs with
appropriate lifetime and interest rate
assumptions. One-time capital costs are
amortized over a 10-year cost recovery
period at a rate of 7 percent.
B. What are the costs of the rule?
1. Summary of Costs
The total annualized costs incurred
under the fluorinated GHG reporting
rule would be approximately $6.1
million in the first year and $3.9 million
in subsequent years ($2006). This
includes a public sector burden estimate
of $384,000 for program implementation
and verification activities. EPA also
considered an alternative national cost
scenario in order to assess national cost
estimates if selected subpart I facilities
validate the DRE of abatement devices.
Under this scenario, the total
annualized costs incurred under the
fluorinated GHG reporting rule would
be approximately $1.7 million higher (or
$7.8 million first year; $5.6 million
subsequent years). Table 12 shows the
first year and subsequent year costs by
subpart. In addition, it presents the cost
per ton reported, and the relative share
of the total cost represented by each
subpart.
TABLE 12—NATIONAL ANNUALIZED MANDATORY REPORTING COSTS ESTIMATES (2008$): SUBPARTS I, L, OO AND SS
First year
Subpart
Millions
2006$
$/ton
Subsequent years
Share
(%)
Millions
2006$
$/ton
Share
(%)
Subpart I—Electronics Industry .................................
Subpart L—Fluorinated Gas Production ....................
Subpart OO—Imports and Exports of Fluorinated
GHGs ......................................................................
Subpart SS—Electrical Equipment Manufacture and
Refurbishment and Manufacturing of Electrical
Components ...........................................................
$2.9
2.1
$0.51
0.20
42
47
$2.6
0.3
$0.45
0.08
67
7
0.7
0.02
10
0.6
0.02
16
0.02
0.01
0.02
0.01
1
Private Sector, Total ...........................................
5.7
....................
94
3.5
....................
90
Public Sector, Total ............................................
0.4
....................
6
0.4
....................
10
Total .............................................................
6.1
....................
100
3.9
....................
100
C. What are the economic impacts of the
rule?
1. Summary of Economic Impacts
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
EPA prepared an economic analysis to
evaluate the impacts of the proposed
rule on affected industries. To estimate
the economic impacts, EPA first
conducted a screening assessment,
comparing the estimated total
annualized compliance costs by
industry, where industry is defined in
0.3
terms of North American Industry
Classification System (NAICS) code,
with industry average revenues. Average
cost-to-sales ratios for establishments in
affected NAICS codes are typically less
than 1 percent.
These low average cost-to-sales ratios
indicate that the rule is unlikely to
result in significant changes in firms’
production decisions or other
behavioral changes, and thus unlikely to
result in significant changes in prices or
quantities in affected markets. Thus,
EPA followed its Guidelines for
Preparing Economic Analyses (EPA,
2002, p. 124–125) and used the
engineering cost estimates to measure
the social cost of the rule, rather than
modeling market responses and using
the resulting measures of social cost.
Table 13 of this preamble summarizes
cost-to-sales ratios for affected
industries.
TABLE 13—ESTIMATED COST-TO-SALES RATIOS FOR AFFECTED ENTITIES
[First Year, 2006$]
NAICS
NAICS description
334413 ..................
Semiconductor and Related Device Manufacturing (Semiconductors) ...........
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Average cost
per entity
($/entity)
Subpart
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I
12APP4
$31,748
All
enterprises
0.05%
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TABLE 13—ESTIMATED COST-TO-SALES RATIOS FOR AFFECTED ENTITIES—Continued
[First Year, 2006$]
NAICS
334413
334413
334119
325120
326140
326150
333415
NAICS description
..................
..................
..................
..................
..................
..................
..................
335313 ..................
336391 ..................
423610 ..................
423620 ..................
423720 ..................
423730 ..................
423740 ..................
443111 ..................
443112 ..................
424610 b ................
33361 ....................
33531 ....................
b The
Subpart
Semiconductor and Related Device Manufacturing (MEMS) ..........................
Semiconductor and Related Device Manufacturing (LCD) ..............................
Other Computer Peripheral Equipment Manufacturing (Photovoltaics) ...........
Industrial Gas Manufacturing ...........................................................................
Polystyrene Foam Product Manufacturing .......................................................
Urethane and Other Foam Product (except Polystyrene) Manufacturing .......
Air-Conditioning and Warm Air Heating Equipment and Commercial and Industrial Refrigeration Equipment Manufacturing.
Switchgear and Switchboard Apparatus Manufacturing ..................................
Motor Vehicle Air-Conditioning Manufacturing .................................................
Electrical Apparatus and Equipment, Wiring Supplies, and Related Equipment Merchant Wholesalers.
Electrical and Electronic Appliance, Television, and Radio Set Merchant
Wholesalers.
Plumbing and Heating Equipment and Supplies (Hydronics) Merchant
Wholesalers.
Warm Air Heating and Air-Conditioning Equipment and Supplies Merchant
Wholesalers.
Refrigeration Equipment and Supplies Merchant Wholesalers .......................
Household Appliance Stores ............................................................................
Radio, Television and Other Electronics Stores ..............................................
Plastics Materials and Basic Forms and Shapes Merchant Wholesalers .......
Engine, Turbine, and Power Transmission Equipment Manufacturing ............
Electrical Equipment Manufacturing .................................................................
Average cost
per entity
($/entity)
All
enterprises
I
I
I
L
OO
OO
OO
5,239
7,598
8,777
151,045
3,364
3,364
3,364
0.01
0.01
0.04
1.44
0.03
0.03
0.01
OO
OO
OO
3,364
3,364
3,364
0.02
0.01
0.05
OO
3,364
0.02
OO
3,364
0.05
OO
3,364
0.07
OO
OO
OO
OO
SS
SS
3,364
3,364
3,364
3,364
2,213
2,213
0.10
0.27
0.15
0.04
0.01
0.02
2002 SUSB data uses 1997 NAICS codes. For this industry, the relevant code is NAICS 422610.
D. What are the impacts of the rule on
small businesses?
1. Summary of Impacts on Small
Businesses
As required by the RFA and SBREFA,
EPA assessed the potential impacts of
the rule on small entities (small
businesses, governments, and non-profit
organizations). (See Section IV.C of this
preamble for definitions of small
entities.)
EPA conducted a screening
assessment comparing compliance costs
for affected industry sectors to industryspecific receipts data for establishments
owned by small businesses. This ratio
constitutes a ‘‘sales’’ test that computes
the annualized compliance costs of this
rule as a percentage of sales and
determines whether the ratio exceeds
some level (e.g., 1 percent or 3 percent).
The cost-to-sales ratios were
constructed at the establishment level
(average reporting program costs per
establishment/average establishment
receipts) for several business size
ranges. This allowed EPA to account for
receipt differences between
establishments owned by large and
small businesses and differences in
small business definitions across
affected industries. The results of the
screening assessment are shown in
Table 14 of this preamble.
As shown, the cost-to-sales ratios are
typically less than 1 percent for
establishments owned by small
businesses that EPA considers most
likely to be covered by the reporting
program (e.g., establishments owned by
businesses with 20 or more employees).
TABLE 14—ESTIMATED COST-TO-SALES RATIOS BY INDUSTRY AND ENTERPRISE SIZE
[First Year, 2006$] a
NAICS
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334413 .......
334413 .......
334413 .......
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Subpart
NAICS description
Semiconductor and ReI
lated Device Manufacturing (Semiconductors).
Semiconductor and ReI
lated Device Manufacturing (MEMS).
Semiconductor and ReI
lated Device Manufacturing (LCD).
17:39 Apr 09, 2010
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SBA
size
standard
(effective
March
11,
2008)
Average
cost per
entity
($/entity)
All
enterprises
500
$31,748
500
500
Frm 00041
Owned by enterprises with:
1 to 20
employees
20 to
99 employees
100 to
499
employees
500 to
749
employees
750 to
999
employees
1,000
to
1,499
employees
0.05%
2.07%
0.40%
0.12%
0.08%
0.02%
0.04%
5,239
0.01%
0.34%
0.07%
0.02%
0.01%
0.00%
0.01%
7,598
0.01%
0.50%
0.10%
0.03%
0.02%
0.01%
0.01%
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TABLE 14—ESTIMATED COST-TO-SALES RATIOS BY INDUSTRY AND ENTERPRISE SIZE—Continued
[First Year, 2006$] a
NAICS
Other Computer Peripheral Equipment Manufacturing (Photovoltaics).
Industrial Gas Manufacturing.
Polystyrene Foam Product Manufacturing.
Urethane and Other Foam
Product (except Polystyrene) Manufacturing.
Air-Conditioning and
Warm Air Heating
Equipment and Commercial and Industrial
Refrigeration Equipment
Manufacturing.
Switchgear and Switchboard Apparatus Manufacturing.
Motor Vehicle Air-Conditioning Manufacturing.
Electrical Apparatus and
Equipment, Wiring Supplies, and Related
Equipment Merchant
Wholesalers.
Electrical and Electronic
Appliance, Television,
and Radio Set Merchant Wholesalers.
Plumbing and Heating
Equipment and Supplies (Hydronics) Merchant Wholesalers.
Warm Air Heating and
Air-Conditioning Equipment and Supplies Merchant Wholesalers.
Refrigeration Equipment
and Supplies Merchant
Wholesalers.
Household Appliance
Stores.
Radio, Television and
Other Electronics
Stores.
Plastics Materials and
Basic Forms and
Shapes Merchant
Wholesalers.
Engine, Turbine, and
Power Transmission
Equipment Manufacturing.
Electrical Equipment Manufacturing.
325120 .......
326140 .......
326150 .......
333415 .......
335313 .......
336391 .......
423610 .......
423620 .......
423720 .......
423730 .......
423740 .......
443111 .......
443112 .......
424610 b .....
33361 .........
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Average
cost per
entity
($/entity)
33531 .........
Owned by enterprises with:
I
1,000
8,777
L
1,000
OO
1 to 20
employees
20 to
99 employees
100 to
499
employees
500 to
749
employees
750 to
999
employees
1,000
to
1,499
employees
0.04%
0.56%
0.09%
0.03%
0.01%
0.02%
0.01%
151,045
1.44%
31.03%
1.03%
4.26%
NA
NA
NA
500
3,364
0.03%
0.28%
0.07%
0.04%
NA
NA
0.01%
OO
500
3,364
0.03%
0.21%
0.06%
0.02%
0.02%
NA
NA
OO
750
3,364
0.01%
0.25%
0.04%
0.02%
0.01%
0.01%
0.01%
OO
750
3,364
0.02%
0.26%
0.06%
0.02%
NA
NA
NA
OO
750
3,364
0.01%
0.37%
0.08%
NA
NA
NA
NA
OO
100
3,364
0.05%
0.11%
0.03%
0.04%
0.05%
0.03%
0.04%
OO
100
3,364
0.02%
0.08%
0.02%
0.01%
0.00%
0.01%
0.01%
OO
100
3,364
0.05%
0.12%
0.02%
0.04%
0.07%
0.03%
0.10%
OO
100
3,364
0.07%
0.15%
0.06%
0.06%
0.12%
0.03%
NA
OO
100
3,364
0.10%
0.18%
0.05%
0.11%
0.09%
0.05%
NA
OO
$9 M
3,364
0.27%
0.47%
0.10%
0.08%
NA
NA
NA
OO
$9 M
3,364
0.15%
0.59%
0.17%
0.26%
NA
NA
NA
OO
100
3,364
0.04%
0.10%
0.03%
0.02%
0.01%
0.01%
0.06%
SS
500–
1,000
2,213
0.01%
0.19%
0.03%
0.01%
0.01%
0.01%
0.01%
SS
750–
1,000
2,213
0.02%
0.22%
0.04%
0.01%
0.01%
0.00%
0.01%
Subpart
NAICS description
334119 .......
SBA
size
standard
(effective
March
11,
2008)
All
enterprises
a The Census Bureau defines an enterprise as a business organization consisting of one or more domestic establishments that were specified
under common ownership or control. The enterprise and the establishment are the same for single-establishment firms. Each multi-establishment
company forms one enterprise—the enterprise employment and annual payroll are summed from the associated establishments. Enterprise size
designations are determined by the summed employment of all associated establishments. Since the SBA’s business size definitions (https://
www.sba.gov/size) apply to an establishment’s ultimate parent company, we assume in this analysis that the enterprise definition above is consistent with the concept of ultimate parent company that is typically used for Small Business Regulatory Enforcement Fairness Act (SBREFA)
screening analyses.
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b The
18693
2002 SUSB data uses 1997 NAICS codes. For this industry, the relevant code is NAICS 422610.
EPA acknowledges that several
enterprise categories have ratios that
exceed this threshold (e.g., enterprise
with one to 20 employees). The
Industrial Gas Manufacturing industry
(NAICS 325120) has sales test results
over 1 percent for all enterprises. The
following enterprise categories have
sales test results over 1 percent and for
entities with less than 20 employees:
Industrial Gas Manufacturing (325120)
and Semiconductor and Related Device
Manufacturing (334413).
EPA took a more detailed look at the
categories noted above as having sales
test ratios above 1 percent. EPA
collected information on the entities
likely to be covered by the rule as part
of the expert sub-group process.
Industrial Gas Manufacturing
(325120). Subpart L covers facilities
included in NAICS codes for Industrial
Gas Manufacturing (NAICS 325120).
Within this subpart, EPA identified 13
ultimate parent company names covered
by the proposed rule. Using publicly
available sources (e.g., Hoovers.com),
we collected parent company sales and
employment data and found that only
one company could be classified as a
small entity. Using the cost data for a
representative entity (see Section 4),
EPA determined the small entity’s costto-sales ratio is below one percent.
Electronic Computer Manufacturing
(334111) and Semiconductor and
Related Device Manufacturing (334413).
Data on the number of electronics
facilities comes from the World Fab
Watch and the Flat Panel Display Fabs
on Disk datasets. The census data
categories cover more establishments
than just those facilities covered in the
rule. Subpart I covers facilities included
in NAICS codes for Semiconductor and
Related Device Manufacturing (334413)
and Other Computer Peripheral
Equipment Manufacturing (334119).
The World Fab Watch dataset includes
216 facilities (94 of which exceed the
25,000 ton threshold), while the sum of
the two NAICS codes include 1,903
establishments. Covered facilities with
emissions greater than 25,000 MtCO2e
per year are unlikely to be included in
the 1 to 20 employees size category.
Emissions are roughly proportional to
production, and establishments with 1
to 20 employees total only 1.6 percent
of total receipts, while the proposed
threshold excludes 6 percent of industry
emissions from the least-emitting
facilities. Although this rule will not
have a significant economic impact on
a substantial number of small entities,
EPA nonetheless took several steps to
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17:39 Apr 09, 2010
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reduce the impact of this rule on small
entities. For example, EPA is proposing
monitoring and reporting requirements
that build off of the UIC program. In
addition, EPA is proposing equipment
and methods that may already be in use
by a facility for compliance with its UIC
permit. Also, EPA is requiring annual
reporting instead of more frequent
reporting.
In addition to the public hearing that
EPA plans to hold, EPA has an open
door policy, similar to the outreach
conducted during the development of
the proposed and final MRR. Details of
these meetings are available in the
docket (EPA–HQ–OAR–2009–0927).
E. What are the benefits of the rule for
society?
EPA examined the potential benefits
of the Fluorinated GHG Reporting Rule.
EPA’s previous analysis of the GHG
reporting rule discussed the benefits of
a reporting system with respect to
policy making relevance, transparency
issues, market efficiency. Instead of a
quantitative analysis of the benefits,
EPA conducted a systematic literature
review of existing studies including
government, consulting, and scholarly
reports.
A mandatory reporting system will
benefit the public by increased
transparency of facility emissions data.
Transparent, public data on emissions
allows for accountability of polluters to
the public stakeholders who bear the
cost of the pollution. Citizens,
community groups, and labor unions
have made use of data from Pollutant
Release and Transfer Registers to
negotiate directly with polluters to
lower emissions, circumventing greater
government regulation. Publicly
available emissions data also will allow
individuals to alter their consumption
habits based on the GHG emissions of
producers.
The greatest benefit of mandatory
reporting of industry GHG emissions to
government will be realized in
developing future GHG policies. For
example, in the EU’s Emissions Trading
System, a lack of accurate monitoring at
the facility level before establishing CO2
allowance permits resulted in allocation
of permits for emissions levels an
average of 15 percent above actual levels
in every country except the United
Kingdom.
Benefits to industry of GHG emissions
monitoring include the value of having
independent, verifiable data to present
to the public to demonstrate appropriate
environmental stewardship, and a better
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understanding of their emission levels
and sources to identify opportunities to
reduce emissions. Such monitoring
allows for inclusion of standardized
GHG data into environmental
management systems, providing the
necessary information to achieve and
disseminate their environmental
achievements.
Standardization will also be a benefit
to industry, once facilities invest in the
institutional knowledge and systems to
report emissions, the cost of monitoring
should fall and the accuracy of the
accounting should improve. A
standardized reporting program will
also allow for facilities to benchmark
themselves against similar facilities to
understand better their relative standing
within their industry.
IV. Statutory and Executive Order
Reviews
A. Executive Order 12866: Regulatory
Planning and Review
Under Section 3(f)(1) of Executive
Order 12866 (58 FR 51735, October 4,
1993), this proposed action is not by
itself an ‘‘economically significant
regulatory action’’ because it is unlikely
to have an annual economic effect of
less than $100 million. EPA’s cost
analysis, presented in Section 4 of the
Economic Impact Analysis (EIA),
estimates that for the minimum
reporting under the recommended
regulatory option, the total annualized
cost of the rule will be approximately
$6.1 million (in 2006$) during the first
year of the program and $3.9 million in
subsequent years (including $0.4
million of programmatic costs to the
Agency). This proposed action adds
subparts I, L, OO, and SS to the MRR,
which was a significant regulatory
action. Thus, EPA has chosen to analyze
the impacts of this proposed rule as if
it were significant. EPA submitted this
proposed action to the Office of
Management and Budget (OMB) for
review under Executive Order 12866,
and any changes made in response to
OMB recommendations have been
documented in the docket for this
proposed action.
In addition, EPA prepared an analysis
of the potential costs associated with
this proposed action. This analysis is
contained in the Economic Impact
Analysis (EIA), Economic Impact
Analysis for the Mandatory Reporting of
Greenhouse Gas Emissions F–Gases
Subparts I, L, OO, and SS (EPA–HQ–
OAR–2009–0927). A copy of the
analysis is available in the docket for
this action and the analysis is briefly
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summarized here. In this report, EPA
has identified the regulatory options
considered, their costs, the emissions
that would likely be reported under
each option, and explained the selection
of the option chosen for the rule.
Overall, EPA has concluded that the
costs of the F-Gases Rule are
outweighed by the potential benefits of
more comprehensive information about
GHG emissions.
B. Paperwork Reduction Act
The information collection
requirements in this proposed rule have
been submitted for approval to the
Office of Management and Budget
(OMB) under the Paperwork Reduction
Act, 44 U.S.C. 3501 et seq. The
Information Collection Request (ICR)
document prepared by EPA has been
assigned EPA ICR number [2373.01].
EPA has identified the following goals
of the mandatory GHG reporting system:
• Obtain data that is of sufficient
quality that it can be used to analyze
and inform the development of a range
of future climate change policies and
potential regulations.
• Balance the rule’s coverage to
maximize the amount of emissions
reported while excluding small emitters.
• Create reporting requirements that
are, to the extent possible and
appropriate, consistent with existing
GHG reporting programs in order to
reduce reporting burden for all parties
involved.
The information from fluorinated
GHG facilities will allow EPA to make
well-informed decisions about whether
and how to use the CAA to regulate
these facilities and encourage voluntary
reductions. Because EPA does not yet
know the specific policies that will be
adopted, the data reported through the
mandatory reporting system should be
of sufficient quality to inform policy
and program development. Also,
consistent with the Appropriations Act,
the reporting rule covers a broad range
of sectors of the economy.
This information collection is
mandatory and will be carried out under
CAA section 114. Information identified
and marked as Confidential Business
Information (CBI) will not be disclosed
except in accordance with procedures
set forth in 40 CFR Part 2. However,
emissions information collected under
CAA section 114 generally cannot be
claimed as CBI and will be made
public.45
45 Although CBI determinations are usually made
on a case-by-case basis, EPA has issued guidance
in an earlier Federal Register notice on what
constitutes emissions data that cannot be
considered CBI (956 FR 7042–7043, February 21,
1991). As discussed in Section II.R of the preamble
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17:39 Apr 09, 2010
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Since OMB is required to make a
decision concerning the ICR between 30
and 60 days after [date of publication],
a comment to OMB is best assured of
having its full effect if OMB receives it
by [publication plus 30]. The final rule
will respond to any OMB or public
comments on the information collection
requirements contained in this proposal.
The projected cost and hour
respondent burden in the ICR, averaged
over the first three years after
promulgation, is $4.51 million and
81,500 hours per year. The estimated
average burden per response is 272
hours; the frequency of response is
annual for all respondents that must
comply with the rule’s reporting
requirements; and the estimated average
number of likely respondents per year is
276. The cost burden to respondents
resulting from the collection of
information includes the total capital
and start-up cost annualized over the
equipment’s expected useful life
(averaging $44,000 per year) a total
operation and maintenance component
(averaging $24,000 per year), and a labor
cost component (averaging $4.44
million per year). Burden is defined at
5 CFR Part 1320.3(b).
These cost numbers differ from those
shown elsewhere in the EIA because
ICR costs represent the average cost over
the first three years of the rule, but costs
are reported elsewhere in the EIA for the
first year of the rule. Also, the total cost
estimate of the rule in the EIA includes
the cost to the Agency to administer the
program. The ICR differentiates between
respondent burden and cost to the
Agency, estimated to be $384,000.
An agency may not conduct or
sponsor, and a person is not required to
respond to, a collection of information
unless it displays a currently valid OMB
control number. The OMB control
numbers for EPA’s regulations in 40
CFR are listed in 40 CFR part 9. When
this ICR is approved by OMB, the
Agency will publish a technical
amendment to 40 CFR part 9 in the
Federal Register to display the OMB
control number for the approved
information collection requirements
contained in the final rule.
To comment on the Agency’s need for
this information, the accuracy of the
provided burden estimates, and any
suggested methods for minimizing
respondent burden, EPA has established
a public docket for this proposed rule,
which includes this ICR, under Docket
ID number EPA–HQ–OAR–2009–0927.
Submit any comments related to the ICR
to EPA and OMB. See ADDRESSES
section at the beginning of this notice
for where to submit comments to EPA.
Send comments to OMB at the Office of
Information and Regulatory Affairs,
Office of Management and Budget, 725
17th Street, NW., Washington, DC
20503, Attention: Desk Office for EPA.
The RFA generally requires an agency
to prepare a regulatory flexibility
analysis of any rule subject to notice
and comment rulemaking requirements
under the Administrative Procedure Act
or any other statute unless the agency
certifies that the rule will not have a
significant economic impact on a
substantial number of small entities.
Small entities include small businesses,
small organizations, and small
governmental jurisdictions.
For purposes of assessing the impacts
of today’s rule on small entities, For the
fluorinated GHG Reporting Rule, small
entity is defined as a small business as
defined by the Small Business
Administration’s regulations at 13 CFR
121.201; according to these size
standards, criteria for determining if
ultimate parent companies owning
affected facilities are categorized as
small vary by NAICS. Small entity
criteria range from total number of
employees at the firm fewer than 100 to
number of employees fewer than 1000;
one affected NAICS, 44311, defines
small entities as those with sales below
$9 million. EIA tables 5–11 and 5–12
present small business criteria and
enterprise size distribution data for
affected NAICS.EPA assessed the
potential impacts of the proposed rule
on small entities using a sales test,
defined as the ratio of total annualized
compliance costs to firm sales. Details
are provided in section 5.3 of the EIA.
These sales tests examine the average
establishment’s total annualized
mandatory reporting costs to the average
establishment receipts for enterprises
within several employment categories.46
The average entity costs used to
compute the sales test are the same
across all of these enterprise size
categories. As a result, the sales-test will
overstate the cost-to-receipt ratio for
establishments owned by small
businesses, because the reporting costs
are likely lower than average entity
estimates provided by the engineering
cost analysis.
to the Final MRR, EPA will be initiating a separate
notice and comment process to make CBI
determinations for the data collected under this
proposed rulemaking.
46 For the one to 20 employee category, we
exclude SUSB data for enterprises with zero
employees. These enterprises did not operate the
entire year.
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C. Regulatory Flexibility Act (RFA)
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The results of the screening analysis
show that for most NAICS, the costs are
estimated to be less than 1 percent of
sales in all firm size categories. For two
NAICS, however, the costs exceed 1
percent of sales for the 1–20 employee
size category; for these NAICS, a more
detailed assessment was conducted. For
NAICS 334413, firms with fewer than 20
employees produce less than 2 percent
of output; firms below the 25,000 Mt
CO2e threshold release approximately 6
percent of emissions. Because emissions
and production levels are highly
correlated, firms with fewer than 20
employees are generally not expected to
be affected by the proposed rule; if they
are, their costs are likely to be lower
than the overall average costs used in
the screening analysis. Thus, EPA does
not expect the proposed rule to impose
significant costs to a substantial number
of small entities in NAICS 334413.
Subpart L covers facilities included in
NAICS codes for Industrial Gas
Manufacturing (NAICS 325120). Within
this subpart, EPA identified 13 ultimate
parent company names covered by the
proposed rule. Using publicly available
sources (e.g.,hoovers.com), we collected
parent company sales and employment
data and found that only one company
could be classified as a small entity.
Using the cost data for a representative
entity (see Section 4 of the EA), EPA
determined the small entity’s cost-tosales ratio is below one percent.
After considering the economic
impacts of today’s proposed rule on
small entities, I therefore certify that
this proposed rule will not have a
significant economic impact on a
substantial number of small entities.
Although this rule would not have a
significant economic impact on a
substantial number of small entities, the
Agency nonetheless tried to reduce the
impact of this rule on small entities,
including seeking input from a wide
range of private- and public-sector
stakeholders. When developing the rule,
the Agency took special steps to ensure
that the burdens imposed on small
entities were minimal. The Agency
conducted several meetings with
industry trade associations to discuss
regulatory options and the
corresponding burden on industry, such
as recordkeeping and reporting. The
Agency investigated alternative
thresholds and analyzed the marginal
costs associated with requiring smaller
entities with lower emissions to report.
The Agency also selected a hybrid
method for reporting, which provides
flexibility to entities and helps
minimize reporting costs.
In addition to the public hearing that
EPA plans to hold, EPA has an open
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door policy, similar to the outreach
conducted during the development of
the proposed and final MRR.
Details of these meetings are available
in the docket (EPA–HQ–OAR–2009–
0927).
D. Unfunded Mandates Reform Act
(UMRA)
Title II of the Unfunded Mandates
Reform Act of 1995 (UMRA), Public
Law 104–4, establishes requirements for
Federal agencies to assess the effects of
their regulatory actions on State, local,
and Tribal governments and the private
sector. Under Section 202 of the UMRA,
EPA generally must prepare a written
statement, including a cost-benefit
analysis, for final rules with ‘‘Federal
mandates’’ that may result in
expenditures to State, local, and Tribal
governments, in the aggregate, or to the
private sector, of $100 million or more
in any one year.
This proposed rule does not contain
a Federal mandate that may result in
expenditures of $100 million or more
for State, local, and Tribal governments,
in the aggregate, or the private sector in
any one year. Overall, EPA estimates
that the total annualized costs of this
proposed rule are approximately $6.1
million in the first year, and $3.9
million per year in subsequent years.
Thus, this proposed rule is not subject
to the requirements of sections 202 or
205 of UMRA.
This proposed rule is also not subject
to the requirements of section 203 of
UMRA because it contains no regulatory
requirements that might significantly or
uniquely affect small governments.
Facilities subject to the proposed rule
include facilities that manufacture, sell,
import or export fluorinated GHG
related products. None of the facilities
currently known to undertake these
activities are owned by small
governments.
E. Executive Order 13132: Federalism
This action does not have federalism
implications. It will not have substantial
direct effects on the States, on the
relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government, as specified in
Executive Order 13132. This regulation
applies to facilities that manufacture,
sell, import, or export fluorinated GHG
related products. Few State or local
government facilities would be affected.
This regulation also does not limit the
power of States or localities to collect
GHG data and/or regulate GHG
emissions. Thus, Executive Order 13132
does not apply to this action.
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18695
In the spirit of Executive Order 13132,
and consistent with EPA policy to
promote communications between EPA
and State and local governments, EPA
specifically solicits comment on this
proposed action from State and local
officials.
F. Executive Order 13175: Consultation
and Coordination With Indian Tribal
Governments
Executive Order 13175, entitled
‘‘Consultation and Coordination with
Indian Tribal Governments’’ (59 FR
22951, November 6, 2000), requires EPA
to develop an accountable process to
ensure ‘‘meaningful and timely input by
Tribal officials in the development of
regulatory policies that have Tribal
implications.’’
This proposed rule is not expected to
have Tribal implications, as specified in
Executive Order 13175. This regulation
applies to facilities that manufacture,
sell, import, or export fluorinated GHG
related products. Few facilities expected
to be affected by the rule are likely to
be owned by Tribal governments. Thus,
Executive Order 13175 does not apply
to this proposed rule.
Although Executive Order 13175 does
not apply to this proposed rule, EPA
sought opportunities to provide
information to Tribal governments and
representatives during development of
the MRR rule. In consultation with
EPA’s American Indian Environment
Office, EPA’s outreach plan included
Tribes. During the proposal phase, EPA
staff provided information to Tribes
through conference calls with multiple
Indian working groups and
organizations at EPA that interact with
Tribes and through individual calls with
two Tribal board members of TCR. In
addition, EPA prepared a short article
on the GHG reporting rule that appeared
on the front page of a Tribal
newsletter—Tribal Air News—that was
distributed to EPA/OAQPS’s network of
Tribal organizations. EPA gave a
presentation on various climate efforts,
including the mandatory reporting rule,
at the National Tribal Conference on
Environmental Management in June,
2008. In addition, EPA had copies of a
short information sheet distributed at a
meeting of the National Tribal Caucus.
EPA participated in a conference call
with Tribal air coordinators in April
2009 and prepared a guidance sheet for
Tribal governments on the proposed
rule. It was posted on the MRR Web site
and published in the Tribal Air
Newsletter. For a complete list of Tribal
contacts, see the ‘‘Summary of EPA
Outreach Activities for Developing the
Greenhouse Gas Reporting Rule,’’ in the
Docket for the initial proposed rule
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Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
(EPA–HQ–OAR–2008–0508–055). In
addition to the consultation activities
supporting the MRR, EPA continues to
provide requested information to Tribal
governments and representatives during
development of the Track II rules such
as this proposed rulemaking. EPA
specifically solicits additional comment
on this proposed action from Tribal
officials.
G. Executive Order 13045: Protection of
Children From Environmental Health
Risks and Safety Risks
EPA interprets EO 13045 (62 FR
19885, April 23, 1997) as applying only
to those regulatory actions that concern
health or safety risks, such that the
analysis required under section 5–501 of
the EO has the potential to influence the
regulation. This proposed action is not
subject to EO 13045 because it does not
establish an environmental standard
intended to mitigate health or safety
risks.
H. Executive Order 13211: Actions That
Significantly Affect Energy Supply,
Distribution, or Use
This proposed rule is not a
‘‘significant energy action’’ as defined in
EO 13211 (66 FR 28355, May 22, 2001)
because it is not likely to have a
significant adverse effect on the supply,
distribution, or use of energy. Further,
we have concluded that this proposed
rule is not likely to have any adverse
energy effects. This proposed rule
relates to monitoring, reporting and
recordkeeping at facilities that
manufacture, sell, import, or export
fluorinated GHG related products and
does not impact energy supply,
distribution or use. Therefore, we
conclude that this proposed rule is not
likely to have any adverse effects on
energy supply, distribution, or use.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
I. National Technology Transfer and
Advancement Act
Section 12(d) of the National
Technology Transfer and Advancement
Act of 1995 (NTTAA), Public Law 104–
113 (15 U.S.C. 272 note) directs EPA to
use voluntary consensus standards in its
regulatory activities unless to do so
would be inconsistent with applicable
law or otherwise impractical. Voluntary
consensus standards are technical
standards (e.g., materials specifications,
test methods, sampling procedures, and
business practices) that are developed or
adopted by voluntary consensus
standards bodies. NTTAA directs EPA
to provide Congress, through OMB,
explanations when the Agency decides
not to use available and applicable
voluntary consensus standards.
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This proposed rulemaking involves
technical standards. EPA will use
voluntary consensus standards from at
least seven different voluntary
consensus standards bodies, including
the following: ASTM, ASME, ISO, Gas
Processors Association, American Gas
Association, American Petroleum
Institute, and National Lime
Association. These voluntary consensus
standards will help facilities monitor,
report, and keep records of GHG
emissions. No new test methods were
developed for this proposed rule.
Instead, from existing rules for source
categories and voluntary greenhouse gas
programs, EPA identified existing
means of monitoring, reporting, and
keeping records of greenhouse gas
emissions. The existing methods
(voluntary consensus standards) include
a broad range of measurement
techniques, such as methods to measure
gas or liquid flow; and methods to gauge
and measure petroleum and petroleum
products. The test methods are
incorporated by reference into the
proposed rule and are available as
specified in 40 CFR 98.7.
By incorporating voluntary consensus
standards into this proposed rule, EPA
is both meeting the requirements of the
NTTAA and presenting multiple
options and flexibility in complying
with the proposed rule. EPA welcomes
comments on this aspect of the
proposed rulemaking and, specifically,
invites the public to identify
potentially-applicable voluntary
consensus standards and to explain why
such standards should be used in this
proposed regulation.
J. Executive Order 12898: Federal
Actions To Address Environmental
Justice in Minority Populations and
Low-Income Populations
EO 12898 (59 FR 7629, February 16,
1994) establishes Federal executive
policy on environmental justice. Its
main provision directs Federal agencies,
to the greatest extent practicable and
permitted by law, to make
environmental justice part of their
mission by identifying and addressing,
as appropriate, disproportionately high
and adverse human health or
environmental effects of their programs,
policies, and activities on minority
populations and low-income
populations in the United States.
Mandatory Reporting of Greenhouse
Gases: Additional Sources of
Fluorinated GHGs (Page 229 of 363)
EPA has determined that this
proposed rule will not have
disproportionately high and adverse
human health or environmental effects
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on minority or low-income populations
because it does not affect the level of
protection provided to human health or
the environment. This proposed rule
does not affect the level of protection
provided to human health or the
environment because it is a rule
addressing information collection and
reporting procedures.
List of Subjects in 40 CFR Part 98
Environmental protection,
Administrative practice and procedure,
Greenhouse gases, Incorporation by
reference, Suppliers, Reporting and
recordkeeping requirements.
Dated: March 22, 2010.
Lisa P. Jackson,
Administrator.
For the reasons stated in the
preamble, title 40, chapter I, of the Code
of Federal Regulations is proposed to be
amended as follows:
PART 98—[AMENDED]
1. The authority citation for part 98
continues to read as follows:
Authority: 42 U.S.C. 7401, et seq.
2. Section 98.7 is amended as follows:
a. By revising paragraph (d)(1).
b. By revising paragraph (d)(2).
c. By revising paragraph (d)(3).
d. By revising paragraph (d)(4).
e. By revising paragraph (d)(5).
f. By revising paragraph (d)(6).
g. By revising paragraph (d)(7).
h. By revising paragraph (d)(8).
i. By revising paragraph (e)(30).
j. By adding paragraph (k).
k. By adding paragraph (l).
§ 98.7 What standardized methods are
incorporated by reference into this part?
*
*
*
*
*
(d) * * *
(1) ASME MFC–3M–2004
Measurement of Fluid Flow in Pipes
Using Orifice, Nozzle, and Venturi,
incorporation by reference (IBR)
approved for § 98.34(b), § 98.124(k),
§ 98.244(b), § 98.254(c), § 98.344(c), and
§ 98.364(e).
(2) ASME MFC–4M–1986 (Reaffirmed
1997) Measurement of Gas Flow by
Turbine Meters, IBR approved for
§ 98.34(b), § 98.124(k), § 98.244(b),
§ 98.254(c), § 98.344(c), and § 98.364(e).
(3) ASME MFC–5M–1985 (Reaffirmed
1994) Measurement of Liquid Flow in
Closed Conduits Using Transit-Time
Ultrasonic Flowmeters, IBR approved
for § 98.34(b), § 98.124(k), and
§ 98.244(b).
(4) ASME MFC–6M–1998
Measurement of Fluid Flow in Pipes
Using Vortex Flowmeters, IBR approved
for § 98.34(b), § 98.124(k), § 98.244(b),
§ 98.254(c), § 98.344(c), and § 98.364(e).
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§ 98.90
Definition of the source category.
(a) The electronics source category
consists of any of the processes listed in
paragraphs (a)(1) through (a)(6) of this
section. Electronics manufacturing
facilities include, but are not limited to,
facilities that manufacture
semiconductors, liquid crystal displays
(LCDs), micro-electro-mechanical
systems (MEMS), and photovoltaic cells
(PV).
(1) Each electronics manufacturing
production process in which the etching
process uses plasma-generated fluorine
atoms and other reactive fluorinecontaining fragments, which chemically
react with exposed thin-films (e.g.,
dielectric, metals) and silicon to
selectively remove portions of material.
(2) Each electronics manufacturing
production process in which chambers
used for depositing thin films are
cleaned periodically using plasmagenerated fluorine atoms and other
reactive fluorine-containing fragments
from fluorinated and other gases.
(3) Each electronics manufacturing
production process in which wafers are
cleaned using plasma generated fluorine
atoms or other reactive fluorinecontaining fragments to remove residual
material from wafer surfaces.
(4) Each electronics manufacturing
production process in which some
fluorinated compounds can be
transformed in the plasma processes
into different fluorinated compounds
which are then exhausted, unless
abated, into the atmosphere.
(5) Each electronics manufacturing
production process in which the
chemical vapor deposition process or
other manufacturing processes use N2O.
(6) Each electronics manufacturing
production process in which fluorinated
GHGs are used as heat transfer fluids to
cool process equipment, control
temperature during device testing, and
solder semiconductor devices to circuit
boards.
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§ 98.91
Reporting threshold.
You must report GHG emissions
under this subpart if your facility
contains an electronics manufacturing
process and the facility meets the
requirements of either § 98.2(a)(1) or
(a)(2). To calculate GHG emissions for
comparison to the 25,000 metric ton
CO2e per year emission threshold in
paragraph § 98.2(a)(2), calculate process
emissions from electronics manufacture
by using either paragraph (a), (b), (c), or
(d) of this section, as appropriate.
(a) Semiconductor manufacturers
shall calculate process emissions for
applicability purposes using the default
emission factors shown in Table I–1 of
this subpart and Equation I–1 of this
section.
E T = 1.1 ∗ ∑ S ∗ EFi ∗ 0.001
(Eq. I-1)
i
Where:
ET = Total annual process emissions for
applicability purposes (metric tons).
1.1 = Factor accounting for heat transfer
fluid emissions, estimated as 10 percent
of total clean and etch emissions at a
facility.
S = 100 percent of manufacturing capacity
of a facility (m2).
EFi = Emission factor for input gas i.
0.001 = Conversion factor from kg to metric
tons.
(b) LCD manufacturers shall calculate
process emissions for applicability
purposes using the default emission
factors shown in Table I–1 of this
subpart and Equation I–2 of this section.
E T = ∑ S ∗ EFi ∗ 0.000001
(Eq. I-2)
i
Where:
ET = Total annual process emissions for
applicability purposes (metric tons).
S = 100 percent of manufacturing capacity
of a facility (m2).
EFi = Emission factor for input gas i.
0.000001 = Conversion factor from g to
metric tons.
(c) MEMS manufacturers shall
calculate process emissions for
applicability purposes using the default
emission factors shown in Table I–1 of
this subpart and Equation I–3 of this
section.
E T = ∑ S ∗ EFi ∗ 0.001
(Eq. I-3)
i
Where:
ET = Total annual process emissions for
applicability purposes (metric tons).
S = 100 percent of manufacturing capacity
of a facility (m2).
EFi = Emission factor for input gas i.
0.001 = Conversion factor from kg to metric
tons.
E:\FR\FM\12APP4.SGM
12APP4
EP12AP10.040
Subpart I—Electronics Manufacturing
(b) [Reserved]
EP12AP10.039
Subpart I—Electronics Manufacturing
Sec.
98.90 Definition of the source category.
98.91 Reporting threshold.
98.92 GHGs to report.
98.93 Calculating GHG emissions.
98.94 Monitoring and QA/QC requirements.
98.95 Procedures for estimating missing
data.
98.96 Data reporting requirements.
98.97 Records that must be retained.
98.98 Definitions.
Table I–1 of Subpart I—Default Emission
Factors for Threshold Applicability
Determination
Table I–2 of Subpart I—Examples of
Fluorinated GHGs Used by the
Electronics Industry
Table I–3 of Subpart I—Default Emission
Factors for MEMS Manufacturing
Table I–4 of Subpart I—Default Emission
Factors for LCD Manufacturing
Table I–5 of Subpart I—Default Emission
Factors for PV Manufacturing
Table I–6 of Subpart I–Default Emission
Factors for Refined Process Categories for
Semiconductor Manufacturing for 150
mm Wafer Size
Table I–7 of Subpart I–Default Emission
Factors for Refined Process Categories for
Semiconductor Manufacturing for 200
mm Wafer Size
Table I–8 of Subpart I–Default Emission
Factors for Refined Process Categories for
Semiconductor Manufacturing for 300
mm Wafer Size
EP12AP10.038
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
(5) ASME MFC–7M–1987 (Reaffirmed
1992) Measurement of Gas Flow by
Means of Critical Flow Venturi Nozzles,
IBR approved for § 98.34(b), § 98.124(k),
§ 98.244(b), § 98.254(c), § 98.344(c), and
§ 98.364(e).
(6) ASME MFC–9M–1988 (Reaffirmed
2001) Measurement of Liquid Flow in
Closed Conduits by Weighing Method,
IBR approved for § 98.34(b), § 98.124(k),
and § 98.244(b).
(7) ASME MFC–11M–2006
Measurement of Fluid Flow by Means of
Coriolis Mass Flowmeters, IBR
approved for § 98.124(k), § 98.244(b),
§ 98.254(c), and § 98.344(c).
(8) ASME MFC–14M–2003
Measurement of Fluid Flow Using Small
Bore Precision Orifice Meters, IBR
approved for § 98.124(k), § 98.244(b),
§ 98.254(c), § 98.344(c), and § 98.364(e).
*
*
*
*
*
(e) * * *
*
*
*
*
*
(30) ASTM D6348–03 Standard Test
Method for Determination of Gaseous
Compounds by Extractive Direct
Interface Fourier Transform Infrared
(FTIR) Spectroscopy, IBR approved for
§ 98.54(b), § 98.124(c), and § 98.224(b).
*
*
*
*
*
(k) The following material is available
from the International SEMATECH
Manufacturing Initiative, https://
ismi.sematech.org.
(1) Guideline for Environmental
Characterization of Semiconductor
Process Equipment, International
SEMATECH Manufacturing Initiative
Technology Transfer #06124825B–ENG.
(2006).
(l) The following material is available
for purchase from SEMI, 3081 Zanker
Road, San Jose, CA 95134, (408) 943–
6900, https://www.semi.org.
(1) SEMI E10–0304 Specification for
Definition and Measurement of
Equipment Reliability, Availability, and
Maintainability (2004).
(2) [Reserved]
3. Add subpart I to read as follows:
18697
18698
(Eq. I-4)
i
Where:
ET = Total annual process emissions for
applicability purposes (metric tons).
Ci = Annual fluorinated GHG (gas i)
purchases or consumption (kg).
GWPi = Gas-appropriate GWP.
0.001 = Conversion factor from kg to metric
tons.
§ 98.92
GHGs to report.
(a) You shall report emissions of N2O
and fluorinated GHGs (as defined in
§ 98.6). The fluorinated GHGs that are
emitted from electronics production
processes include, but are not limited
to, those listed in Table I–2 of this
subpart. You must report:
(1) Fluorinated GHGs from plasma
etching.
(2) Fluorinated GHGs from chamber
cleaning.
(3) Fluorinated GHGs from wafer
cleaning.
(4) N2O from chemical vapor
deposition and other manufacturing
processes.
(5) Fluorinated GHGs from heat
transfer fluid use.
(b) CO2, CH4, and N2O combustion
emissions from each stationary
combustion unit. You must calculate
and report these emissions under
subpart C of this part (General
Stationary Fuel Combustion Sources) by
following the requirements of subpart C.
§ 98.93
Calculating GHG emissions.
(a) You shall calculate annual facilitylevel emissions for each fluorinated
GHG used at your facility, for each
process type used at your facility
(plasma etching, chamber cleaning, or
wafer cleaning) as appropriate, using
equations I–5 and I–6 of this section and
according to the procedures in
paragraph (a)(1), (a)(2), or (a)(3) of this
section.
N
processtypeEi = ∑ Eij
(Eq. I-5)
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j =1
Where:
processtypeEi = Annual emissions of input
gas i from the processes type (metric
tons).
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N
processtypeBEk = ∑ ∑ BEkij
(Eq. I-6)
j =1 i
Where:
processtypeBEk = Annual emissions of byproduct gas k from the processes type
(metric tons).
BEkij = Annual emissions of by-product k
formed from input gas i during
individual process j or process category
j (metric tons).
N = The total number of individual
processes j or process categories j, which
depend on the electronics manufacturing
facility and emission calculation
methodology.
(1) Semiconductor facilities that
fabricate devices on wafers measuring
300 mm or less in diameter shall
calculate annual facility-level emissions
of each fluorinated GHG used at a
facility for each fluorinated GHG-using
process type, either from all individual
processes at that facility in accordance
with § 98.94(d), or from process
categories as defined in this paragraph
(a)(1).
(i) All etching process categories for
which annual fluorinated GHG
emissions shall be calculated are
defined in this paragraph (a)(1)(i).
(A) Oxide etch means any process
using fluorinated GHG reagents to
selectively remove SiO2, SiOx-based or
fully organic-based thin-film material
that has been deposited on a wafer
during semiconductor device
manufacturing.
(B) Nitride etch means any process
using fluorinated GHG reagents to
selectively remove SiN, SiON, Si3N4,
SiC, SiCO, SiCN, etc. (represented by
the general chemical formula,
SiwOxNyXz where w, x, y and z are zero
or integers and X can be some other
element such as carbon) that has been
deposited on a wafer during
semiconductor manufacturing.
(C) Silicon etch also often called
polysilicon etch means any process
using fluorinated GHG reagents to
selectively remove silicon during
semiconductor manufacturing.
(D) Metal etch means any process
using fluorinated GHG reagents
associated with removing metal films
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(such as aluminum or tungsten) that
have been deposited on a wafer during
semiconductor manufacturing.
(ii) All chamber cleaning process
categories for which annual fluorinated
GHG emissions shall be calculated are
defined in this paragraph (a)(1)(ii).
(A) In situ plasma means cleaning
thin-film production chambers, after
processing one or more wafers, with a
fluorinated GHG cleaning reagent that is
dissociated into its cleaning
constituents by a plasma generated
inside the chamber where the film was
produced.
(B) Remote plasma system means
cleaning thin-film production chambers,
after processing one or more wafers,
with a fluorinated GHG cleaning reagent
dissociated by a remotely located (e.g.,
upstream) plasma source.
(C) In situ thermal means cleaning
thin-film production chambers, after
processing one or more wafers, with a
fluorinated GHG cleaning reagent that is
thermally dissociated into its cleaning
constituents inside the chamber where
the thin-film (or thin films) was (were)
produced.
(iii) All wafer cleaning process
categories for which annual fluorinated
GHG emissions shall be calculated are
defined in this paragraph (a)(1)(iii).
(A) Bevel cleaning means any process
using fluorinated GHG reagents with
plasma to clean the edges of wafers
during semiconductor manufacture.
(B) Ashing means any process using
fluorinated GHG reagents with plasma
to remove photoresist materials during
wafer manufacture.
(2) Semiconductor facilities that
fabricate devices on wafers measuring
greater than 300 mm in diameter shall
calculate annual facility-level emissions
of each fluorinated GHG used at a
facility for all individual processes at
that facility in accordance with
§ 98.94(d).
(3) All other electronics facilities shall
calculate annual facility-level emissions
of each fluorinated GHG used at a
facility for each process type, including
etching and chemical vapor deposition
chamber cleaning.
(b) You shall calculate annual facilitylevel emissions for each fluorinated
GHG used at your facility, for each
individual process, process category, or
process type used at your facility as
appropriate, using Equations I–7 and I–
8 of this section, and according to the
procedures in either paragraph (b)(1),
(b)(2), or (b)(3) of this section.
E:\FR\FM\12APP4.SGM
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EP12AP10.042
E T = ∑ Ci ∗ GWP ∗ 0.001
i
Eij = Annual emissions of input gas i from
individual process j or process category
j (metric tons).
N = The total number of individual
processes j or process categories j, which
depend on the electronics manufacturing
facility and emission calculation
methodology.
EP12AP10.041
(d) PV manufacturers shall calculate
process emissions for applicability
purposes using gas-appropriate GWP
values shown in Table A–1 to subpart
A and equation I–4 of this section.
EP12AP10.043
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)
I–10 (kg) of this section and apportioned
pursuant to § 98.94(c).
Uij = Process utilization for input gas i
during individual process, process
category, or process type j.
aij = Fraction of input gas i used in
individual process, process category, or
process type j with abatement systems.
(
)
BEijk = Bijk ∗ Cij ∗ 1 − aij ∗ dkj ∗ 0.001
Where:
BEijk = Annual emissions of by-product k
formed from input gas i during
individual process, process category, or
process type j (metric tons).
Bijk = Amount of gas k created as a byproduct per amount of input gas i (kg)
consumed in individual process, process
category, or process type j (kg).
Cij = Amount of input gas i consumed in
individual process, process category, or
process type j, as calculated in Equation
I–10 of this section (kg) and apportioned
pursuant to § 98.94(c).
aij = Fraction of input gas i used in
individual process, process category, or
process type j with abatement systems.
dkj = Fraction of by-product gas k
destroyed in abatement systems
connected to individual process, process
category, or process type j, accounting
for uptime as specified in § 98.94(f)(2).
This is zero unless the facility adheres to
requirements in § 98.94(f).
0.001 = Conversion factor from kg to metric
tons.
(1) Semiconductor facilities that
fabricate devices on wafers measuring
300 mm or less in diameter shall use the
procedures in either paragraph (b)(1)(i)
or (b)(1)(ii) of this section.
(i) Except as provided in paragraph
(b)(1)(ii), you shall use default process
category emission factors for process
utilization and by-product formation
rates shown in Tables I–6, I–7, and I–
8 of this subpart as appropriate.
(Eq. I-8)
(ii) You may use recipe-specific
measurements instead of the process
category default factors provided that
you follow methods in § 98.94(d).
(2) Semiconductor facilities that
fabricate devices on wafers measuring
greater than 300 mm in diameter shall
use recipe-specific measurements and
follow methods in § 98.94(d) to
calculate emissions from each
fluorinated GHG-using process type.
You shall use Equations I–5 through I–
8 of this section to calculate fluorinated
GHG emissions from all fluorinated
GHG-using process recipes.
(3) All other electronics facilities shall
use the default process type-specific
emission factors for process utilization
and by-product formation rates shown
in Tables I–3, I–4, and I–5 of this
subpart for MEMS, LCD, and PV
manufacturing, respectively.
(c) You shall calculate annual facilitylevel N2O emissions from electronics
manufacturing processes, using
Equation I–9 of this section and the
methods in this paragraph (c).
(1) You shall use a factor for N2O
utilization for chemical vapor
deposition processes pursuant to either
paragraph (c)(1)(i) or (c)(1)(ii) of this
section.
(i) You shall develop a facilityspecific N2O utilization factor averaged
over all N2O-using recipes used for
(
) (
dij = Fraction of input gas i destroyed in
abatement systems connected to
individual process, process category, or
process type j, accounting for uptime as
specified in § 98.94(f)(2). This is zero
unless the facility adheres to
requirements in § 98.94(f).
0.001 = Conversion factor from kg to metric
tons.
chemical vapor deposition processes in
accordance with § 98.94(e).
(ii) If you do not use a facility-specific
N2O utilization factor for chemical
vapor deposition processes, you shall
use 20 percent as the default utilization
factor for N2O from chemical vapor
deposition processes.
(2) You shall use a factor for N2O
utilization for other manufacturing
processes pursuant to either paragraph
(c)(2)(i) or (c)(2)(ii) of this section.
(i) You shall develop a facilityspecific N2O utilization factor averaged
over all N2O-using recipes used for
manufacturing processes other than
chemical vapor deposition processes in
accordance with § 98.94(e).
(ii) If you do not use a facility-specific
N2O utilization factor for manufacturing
processes other than chemical vapor
deposition, you shall use the default
utilization factor of 0 percent for N2O
from manufacturing processes other
than chemical vapor deposition.
(3) If your facility employs abatement
systems and you wish to quantify and
document N2O emission reductions due
to these systems, you must adhere to the
requirements in § 98.94(f).
(4) You shall calculate annual facilitylevel N2O emissions for all processes at
your facility using Equation I–9 of this
section.
)
E ( N2 O ) = ∑ CN2O, j ∗ 1 − UN2O, j ∗ 1 − a N2O, j ∗ dN2O, j ∗ 0.001
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
j
Where:
E(N2O) = Annual emissions of N2O (metric
tons/year).
CN2O,j = Amount of N2O consumed for N2Ousing process j, as calculated in Equation
I–10 of this section and apportioned to
N2O process j (kg).
UN2O,j = Process utilization for N2O-using
process j.
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aN2O,j = Fraction of N2O used in N2O-using
process j with abatement systems.
dN2O,j = Fraction of N2O for N2O-using
process j destroyed by abatement
systems connected to process j,
accounting for uptime as specified in
§ 98.94(f)(2). This is zero unless the
facility adheres to requirements in
§ 98.94(f).
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(Eq. I-9)
0.001 = Conversion factor from kg to metric
tons.
(d) You shall calculate gas
consumption for each fluorinated GHG
and N2O used at your facility using
facility-wide gas-specific heel factors, as
determined in § 98.94(b), and using
Equation I–10 of this section.
E:\FR\FM\12APP4.SGM
12APP4
EP12AP10.046
Where:
Eij = Annual emissions of input gas i from
individual process, process category, or
process type j (metric tons).
Cij = Amount of input gas i consumed in
individual process, process category, or
process type j, as calculated in Equation
(Eq. I-7)
EP12AP10.045
) (
EP12AP10.044
(
Eij = Cij ∗ 1 − Uij ∗ 1 − aij ∗ dij ∗ 0.001
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)
(e) You shall calculate disbursements
of gas i using Equation I–11 of this
section.
Di = hi ∗ Ni ∗ Fi + Xi
(Eq. I-11)
Where:
Di = Disbursements of gas i through sales
or other transactions during the year,
including heels in cylinders or other
containers returned by the electronics
manufacturing facility to the gas
distributor (kg).
hi = Facility-wide gas-specific heel factor
for input gas i (%), as determined in
§ 98.94(b) of this subpart.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
EHi = density ∗ ( Iio + P − Nit + Rit − Iit − Dit ) ∗ 0.001
it
Where:
EHi = Emissions of fluorinated GHG heat
transfer fluid i, (metric tons/year).
Density = Density of fluorinated heat
transfer fluid i (kg/l).
Iio = Inventory of fluorinated heat transfer
fluid i (kg) (in containers, not
equipment) at the beginning of the
reporting year (l). The inventory at the
beginning of the reporting year must be
the same as the inventory at the end of
the previous reporting year.
Pit = Acquisitions of fluorinated heat
transfer fluid i (kg) during the current
reporting year (l). Includes amounts
purchased from chemical suppliers,
amounts purchased from equipment
suppliers with or inside of equipment,
and amounts returned to the facility after
off-site recycling.
Nit = Total nameplate capacity (full and
proper charge) of equipment that uses
fluorinated heat transfer fluid i and that is
newly installed during the reporting year
(kg).
Rit = Total nameplate capacity (full and
proper charge) of equipment that uses
fluorinated heat transfer fluid i and that is
removed from service during the current
reporting year (kg).
Iit = Inventory of fluorinated heat transfer
fluid i (kg) (in containers, not equipment)
at the end of current reporting year (l).
Dit = Disbursements of fluorinated heat
transfer fluid i (kg) during the current
reporting year (l). Includes amounts
returned to chemical suppliers, sold with
or inside of equipment, and sent off site for
verifiable recycling or destruction.
Disbursements should include only
amounts that are properly stored and
transported so as to prevent emissions in
transit.
0.001 = Conversion factor from kg to metric
tons.
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§ 98.94 Monitoring and QA/QC
requirements.
(a) For calendar year 2011 monitoring,
you may follow the provisions of
§ 98.3(d)(1) through (d)(3) for best
available monitoring methods rather
than follow the monitoring
requirements of this section. For
purposes of subpart I, any reference to
the year 2010 in § 98.3(d)(1) through
(d)(3) shall mean 2011.
(b) For purposes of Equation I–10 of
this section, you must estimate facilitywide gas-specific heel factors for each
cylinder/container type for each gas
used according to the procedures in
paragraphs (b)(1) through (b)(6) of this
section.
(1) You shall base your facility-wide
gas-specific heel factors on the residual
weight or pressure of a gas cylinder/
container that your facility uses to
change out that cylinder/container for
each cylinder/container type for each
gas used.
(2) The residual weight or pressure
you use for § 98.94(b)(1) shall be
determined by monitoring the mass or
the pressure of your cylinders/
containers. If you monitor the pressure,
you shall convert the pressure to mass
using the ideal gas law, as displayed in
Equation I–13 of this section, with an
appropriately selected Z value.
pV = ZnRT
(Eq. I-13)
Where:
p = Absolute pressure of the gas (Pa)
V = Volume of the gas (m3)
Z = Compressibility factor
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Ni = Number of cylinders or other
containers returned to the gas distributor
containing the standard heel of gas i.
Fi = Full capacity of cylinders or other
containers containing gas i (kg).
Xi = Disbursements under exceptional
circumstances of gas i through sales or
other transactions during the year. These
include returns of containers whose
contents have been weighed due to an
exceptional circumstance as specified in
§ 98.94(b)(5) of this subpart (kg).
(f) For facilities that use fluorinated
heat transfer fluids, you shall report the
annual emissions of fluorinated GHG
heat transfer fluids using the mass
balance approach described in Equation
I–12 of this section.
(Eq. I-12)
n = Amount of substance of the gas (moles)
R = Gas constant (8.314 Joule/Kelvin mole)
T = Absolute temperature (K)
(3) You shall use the facility-wide
gas–specific cylinder/container residual
mass, determined from § 98.94(b)(1) and
(b)(2), to calculate the unused gas for
each container, which when expressed
as fraction of the initial mass in the
cylinder/container is the heel factor.
(4) The initial mass used to calculate
the facility-wide gas-specific heel factor
may be based on the weight of the gas
provided to you in the gas supplier
documents; however, you remain
responsible for the accuracy of these
masses and weights under this subpart.
(5) In the exceptional circumstance
that you change a cylinder/container at
a residual mass or pressure that differs
by more than 20 percent from your
facility-wide gas-specific determined
values, you shall weigh that cylinder, or
measure the pressure of that cylinder
with a pressure gauge, in place of using
a heel factor.
(6) You shall recalculate facility-wide
gas-specific heel factors applied at your
facility in the event that the residual
weight or pressure of the gas cylinder/
container that your facility uses to
change out that cylinder/container
differs by more than 1 percentage point
from that used to calculate the previous
gas-specific heel factor.
(c) Semiconductor facilities shall
apportion fluorinated GHG
consumption by process category, as
defined in § 98.93(a)(1)(i) through
(a)(1)(iii), or by individual process using
E:\FR\FM\12APP4.SGM
12APP4
EP12AP10.050
supplier, calculated using equation I–11
of this section (kg).
0.001 = Conversion factor from kg to metric
tons.
EP12AP10.049
Where:
Ci = Annual consumption of input gas i
(metric tons/year).
IBi = Inventory of input gas i stored in
cylinders or other containers at the
beginning of the year, including heels
(kg).
IEi = Inventory of input gas i stored in
cylinders or other containers at the end
of the year, including heels (kg).
Ai = Acquisitions of gas i during the year
through purchases or other transactions,
including heels in cylinders or other
containers returned to the electronics
manufacturing facility (kg).
Di = Disbursements under exceptional
circumstances of gas i through sales or
other transactions during the year,
including heels in cylinders or other
containers returned by the electronics
manufacturing facility to the chemical
(Eq. I-10)
EP12AP10.048
(
Ci = IBi − IEi + A i − Di ∗ 0.001
EP12AP10.047
18700
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a facility-specific engineering model
based on wafer passes.
(d) If you use factors for fluorinated
GHG process utilization and by-product
formation rates other than the defaults
provided in Tables I–6 through I–8 of
this subpart, you must use factors that
have been measured using the
International SEMATECH
Manufacturing Initiative’s Guideline for
Environmental Characterization of
Semiconductor Process Equipment
(December 2006). You may use factors
for fluorinated GHG process utilization
and by-product formation rates
measured by manufacturing equipment
suppliers if the conditions in paragraphs
(d)(1) and (d)(2) of this section are met.
(1) The manufacturing equipment
supplier has measured the GHG
emission factors for process utilization
and by-product formation rates using
the International SEMATECH
Manufacturing Initiative’s Guideline for
Environmental Characterization of
Semiconductor Process Equipment
(December 2006).
(2) The conditions under which the
measurements were made are
representative of your facility’s
fluorinated GHG emitting processes.
(e) If you use N2O utilization factors
other than those defaults provided in
§ 98.93(c)(1)(ii) or (c)(2)(ii), you must
use factors that have been measured
using the International SEMATECH
Manufacturing Initiative’s Guideline for
Environmental Characterization of
Semiconductor Process Equipment
(December 2006). You may use
utilization factors measured by
manufacturing equipment suppliers if
the conditions in paragraphs (e)(1) and
(e)(2) of this section are met.
(1) The manufacturing equipment
supplier has measured the N2O
utilization factors using the
International SEMATECH
Manufacturing Initiative’s Guideline for
Environmental Characterization of
Semiconductor Process Equipment
(December 2006).
(2) The conditions under which the
measurements were made are
representative of your facility’s N2O
emitting processes.
(f) If your facility employs abatement
systems and you wish to reflect
emission reductions due to these
systems in appropriate calculations in
§ 98.93, you must adhere to the
procedures in paragraphs (f)(1) and (f)(2)
of this section. If you use the default
destruction or removal efficiency of 60
percent, you must adhere to procedures
in paragraph (f)(3) of this section. If you
use either a properly measured
destruction or removal efficiency, or a
class average of properly measured
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destruction or removal efficiencies
during a reporting year, you must
adhere to procedures in paragraph (f)(4)
of this section.
(1) You must certify and document
that the systems are properly installed,
operated, and maintained according to
manufacturers’ specifications by
adhering to the procedures in
paragraphs (f)(1)(i) and (f)(1)(ii) of this
section.
(i) Proper installation must be verified
by certifying the systems are installed in
accordance with the manufacturers’
specifications.
(ii) Proper operation and maintenance
must be verified by certifying the
systems are operated and maintained in
accordance with the manufacturers’
specifications.
(2) You shall take into account and
report the uptime of abatement systems
when using destruction or removal
efficiencies to reflect emission
reductions. Abatement system uptime is
expressed as the sum of an abatement
system’s operational productive,
standby, and engineering times divided
by the total operations time of its
associated manufacturing tool(s) as
referenced in SEMI Standard E–10–0340
Specification for Definition and
Measurement of Equipment Reliability,
Availability, and Maintainability (2004).
(3) To report controlled emissions
using the default destruction or removal
efficiency, you shall certify and
document that the abatement systems at
the facility for which you are reporting
controlled emissions are specifically
designed for fluorinated GHG and N2O
abatement and you shall use a default
destruction or removal efficiency of 60
percent for those abatement systems.
(4) If you do not use the default
destruction or removal efficiency value
to report controlled emissions, you shall
use either a properly measured
destruction or removal efficiency, or a
class average of properly measured
destruction or removal efficiencies
during a reporting year, determined in
accordance with procedures in
paragraphs (f)(4)(i) through (f)(4)(v) of
this section.
(i) Destruction or removal efficiencies
must be properly measured in
accordance with EPA’s Protocol for
Measuring Destruction or Removal
Efficiency of Fluorinated Greenhouse
Gas Abatement Equipment in
Electronics Manufacturing (March
2010).
(ii) A facility must annually select and
properly measure the destruction or
removal efficiency for a random sample
of abatement systems to include in a
random sampling abatement system
testing program (RSASTP) in
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18701
accordance with procedures in
paragraphs (f)(3)(ii)(A) and (f)(3)(ii)(B) of
this section.
(A) Each reporting year a random
sample of three or 20 percent of
installed abatement systems, whichever
is greater, for each abatement system
class shall be tested. In instances where
20 percent of the total number of
abatement systems in each class does
not equate to a whole number, the
number of systems to be tested shall be
determined by rounding up to the
nearest integer.
(B) You shall select the random
sample each reporting year for the
RSASTP without repetition of systems
in the sample, until all systems in each
class are properly measured in a 5-year
period.
(iii) If a facility has measured the
destruction or removal efficiency of a
particular abatement system during the
previous two-year period, the facility
shall calculate emissions from that
system using the destruction or removal
efficiency most recently measured for
that particular system.
(iv) If an individual abatement system
has not yet undergone proper
destruction or removal efficiency testing
during the previous two-year period, the
facility may apply a simple average of
the properly measured destruction or
removal efficiencies for all systems of
that class, in accordance with the
RSASTP. The facility shall maintain or
exceed the RSASTP schedule and
regime if it wishes to apply class
average destruction or removal
efficiency factors to abatement systems
that have not been properly measured as
per the RSASTP.
(v) In instances where redundant
abatement systems are used, the facility
may account for the total abatement
system uptime calculated for a specific
exhaust stream during the reporting
year.
(g) You shall adhere to the QA/QC
procedures of this paragraph when
estimating fluorinated GHG and N2O
emissions from all electronics
manufacturing processes:
(1) You shall follow the QA/QC
procedures in the International
SEMATECH Manufacturing Initiative’s
Guideline for Environmental
Characterization of Semiconductor
Process Equipment (December 2006)
when estimating facility-specific,
recipe-specific fluorinated GHG and
N2O utilization and by-product
formation rates.
(2) You shall follow the QA/QC
procedures in EPA’s Protocol for
Measuring Destruction or Removal
Efficiency of Fluorinated Greenhouse
Gas Abatement Equipment in
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Electronics Manufacturing (March 2010)
when estimating abatement systems
destruction or removal efficiency.
(3) You shall certify that gas
consumption is tracked to a high degree
of precision as part of normal facility
operations ensuring that the inventory
at the beginning of the reporting is the
same as the inventory at the end of the
previous year.
(h) You shall adhere to the QA/QC
procedures of this paragraph when
estimating fluorinated GHG emissions
from heat transfer fluid use and annual
gas consumption for each fluorinated
GHG and N2O used at your facility:
(1) You shall review all inputs to
Equations I–10 and I–12 of this section
to ensure that all inputs and outputs to
the facility’s system are accounted for.
(2) You shall not enter negative inputs
into the mass balance Equations I–10
and I–12 of this section and shall ensure
that no negative emissions are
calculated.
(3) You shall ensure that the
beginning of year inventory matches the
end of year inventory from the previous
year.
(i) All instruments (e.g., mass
spectrometers and fourier transform
infrared measuring systems) used to
determine the concentration of
fluorinated GHG and N2O in process
streams shall be calibrated just prior to
destruction or removal efficiency, gas
utilization, or by-product formation
measurement through analysis of
certified standards with known
concentrations of the same chemicals in
the same ranges (fractions by mass) as
the process samples. Calibration gases
prepared from a high-concentration
certified standard using a gas dilution
system that meets the requirements
specified in Method 205, 40 CFR part
51, Appendix M may also be used.
(j) All flowmeters, weigh scales,
pressure gauges, and thermometers used
to measure quantities that are monitored
under this section or used in
calculations under § 98.93 shall have an
accuracy and precision of one percent of
full scale or better.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
§ 98.95
data.
Procedures for estimating missing
(a) Except as provided in paragraph
§ 98.95(b), a complete record of all
measured parameters used in the
fluorinated GHG and N2O emissions
calculations in § 98.93 and § 98.94 is
required.
(b) If you use heat transfer fluids at
your facility and are missing data for
one or more of the parameters in
Equation I–12 of this subpart, you shall
estimate heat transfer fluid emissions
using the arithmetic average of the
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Jkt 220001
emission rates for the year immediately
preceding the period of missing data
and the months immediately following
the period of missing data.
Alternatively, you may estimate missing
information using records from the heat
transfer fluid supplier. You shall
document the method used and values
estimated for all missing data values.
§ 98.96
Data reporting requirements.
In addition to the information
required by § 98.3(c), you shall include
in each annual report the following
information for each electronics facility.
(a) Annual emissions of each
fluorinated GHG and N2O emitted from
each individual process, process
category, or process type as applicable
and from all heat transfer fluid use as
applicable.
(b) The method of emissions
calculation used in § 98.93.
(c) Production in terms of substrate
surface area (e.g., silicon, PV-cell, LCD).
(d) Emission factors used for process
utilization and by-product formation
rates and the source for each factor for
each fluorinated GHG and N2O.
(e) Where process categories for
semiconductor facilities as defined in
§ 98.93(a)(1)(i) through (a)(1)(iii) are not
used, descriptions of individual
processes or process categories used to
estimate emissions.
(f) For each fluorinated GHG and N2O,
annual gas consumed during the
reporting year and facility-wide gasspecific heel-factors used.
(g) The apportioning factors for each
process category (i.e., fractions of each
gas fed into each individual process or
process category used to calculate
fluorinated GHG and N2O emissions)
and a description of the engineering
model used for apportioning gas usage
per § 98.94(c). If the method used to
develop the apportioning factors
permits the development of facilitywide consumption estimates that are
independent of the estimates calculated
in Equation I–10 of this subpart (e.g.,
that are based on wafer passes for each
individual process or process category),
you shall report the independent
facility-wide consumption estimate for
each fluorinated GHG and N2O.
(h) Fraction of each gas fed into each
process type that is fed into tools with
abatement systems.
(i) Description of all abatement
systems through which fluorinated
GHGs or N2O flow at your facility,
including the number of devices of each
manufacturer, model numbers,
manufacturers guaranteed destruction or
removal efficiencies, if any, and record
of destruction or removal efficiency
measurements over its in-use life. The
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inventory of abatement systems shall
also include a description of the
associated tools and/or processes for
which these systems treat exhaust.
(j) For each abatement system through
which fluorinated GHGs or N2O flow at
your facility, for which you are
reporting controlled emissions, the
following:
(1) Certification that each abatement
system used at your facility is installed,
maintained, and operated in accordance
with manufacturers’ specifications.
(2) The uptime and the calculations to
determine uptime for that reporting
year.
(3) The default destruction or removal
efficiency value or properly measured
destruction or removal efficiencies for
each abatement system used in that
reporting year to reflect controlled
emissions.
(4) Where the default destruction or
removal efficiency value is used to
report controlled emissions,
certification that the abatement systems
for which controlled emissions are
being reported are specifically designed
for fluorinated GHG and N2O abatement.
(5) Where properly measured
destruction or removal efficiencies or
class averages of destruction or removal
efficiencies are used to report controlled
emissions, the following:
(i) A description of the class including
the abatement system manufacturer and
model number, and the fluorinated GHG
and N2O in the process effluent stream;
(ii) The total number of systems in
that class for the reporting year.
(iii) The total number of systems for
which destruction or removal efficiency
was measured in that class for the
reporting year.
(iv) A description of the calculation
used to determine the class average,
including all inputs of the calculation.
(vi) A description of method of
randomly selecting class members for
testing.
(k) For heat transfer fluid emissions,
inputs in the mass-balance equation,
Equation I–12 of this subpart for each
fluorinated GHG.
(l) Example calculations for
fluorinated GHG, N2O, and heat transfer
fluid emissions.
§ 98.97
Records that must be retained.
In addition to the information
required by § 98.3(g), you must retain
the following records:
(a) Data and copies of calculations
used to estimate emissions including all
spreadsheets.
(b) Documentation for the values used
for fluorinated GHG and N2O utilization
and by-product formation rates. If you
use facility-specific, recipe-specific gas
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utilization and by-product formation
rates, the following records must be
retained:
(1) Documentation that these were
measured using the International
SEMATECH Manufacturing Initiative’s
Guideline for Environmental
Characterization of Semiconductor
Process Equipment (December 2006).
(2) Documentation that the
measurements made are representative
of fluorinated GHG and N2O emitting
processes at your facility.
(3) The date and results of the initial
and any subsequent tests to determine
process tool gas utilization and byproduct formation rates.
(c) For each abatement system
through which fluorinated GHGs or N2O
flows at your facility, for which you are
reporting controlled emissions, the
following:
(1) Documentation to certify that each
abatement system used at your facility
is installed, maintained, and operated in
accordance with manufacturers’
specifications.
(2) Records of the uptime and the
calculations to determine how the
uptime was accounted for at your
facility.
(3) Abatement system calibration and
maintenance records.
(4) Where the default destruction or
removal efficiency value was used,
documentation from the abatement
system supplier describing the
equipment’s designed purpose and
emission control capabilities.
(5) Where properly measured
destruction or removal efficiency is
used to report controlled emissions,
dated certification by the technician
who made the measurement that the
destruction or removal efficiency was
calculated according to methods in
EPA’s Protocol for Measuring
Destruction or Removal Efficiency of
Fluorinated Greenhouse Gas Abatement
Equipment in Electronics
Manufacturing, complete
documentation of the results of any
initial and subsequent tests, and the
final report as specified in EPA’s
Protocol for Measuring Destruction or
Removal Efficiency of Fluorinated
Greenhouse Gas Abatement Equipment
in Electronics Manufacturing (March
2010).
(d) Purchase records for gas
purchased.
(e) Invoices for gas purchases and
sales.
§ 98.98
Definitions.
Except as provided below, all of the
terms used in this subpart have the
same meaning given in the Clean Air
Act and subpart A of this part. If a
conflict exists between a definition
provided in this subpart and a
definition provided in subpart A, the
definition in this subpart shall take
precedence for the reporting
requirements in this subpart.
Abatement system means a device or
equipment that destroys or removes
fluorinated GHGs and/or N2O in waste
streams from one or more electronics
manufacturing tool chamber(s).
By-product formation means the
creation of fluorinated GHGs during
electronics manufacturing processes or
the creation of fluorinated GHGs by an
abatement system. By-product formation
is expressed as rate of the mass of the
by-product formed to the mass of the
fluorinated GHG used with the largest
flow rate.
Destruction or removal efficiency
means the efficiency of a control system
to destroy or remove fluorinated GHGs,
N2O, or both. The destruction or
removal efficiency is equal to one minus
the ratio of the mass of all relevant
GHGs exiting the emission abatement
system to the mass of GHG entering the
emission abatement system. When
fluorinated GHGs are formed in an
abatement system, destruction or
removal efficiency is expressed as one
minus the ratio of amounts of exiting
GHGs to the amounts entering the
system in units of CO2-equivalents.
Gas utilization means the fraction of
input N2O or fluorinated GHG converted
to other substances during the etching,
deposition, and/or wafer and chamber
cleaning processes. Gas utilization is
expressed as a rate or factor for specific
manufacturing processes.
Heat transfer fluids are fluorinated
GHGs used for temperature control,
device testing, and soldering in certain
types of electronic manufacturing. Heat
transfer fluids used in the electronics
sector include perfluoropolyethers,
perfluoroalkanes, perfluoroethers,
tertiary perfluoroamines, and
perfluorocyclic ethers. Heat transfer
fluids commonly used in electronics
manufacturing include those sold under
the trade names ‘‘Galden®’’ and
‘‘FluorinertTM.’’ Electronics
manufacturers may also use these same
fluorinated chemicals to clean substrate
surfaces and other parts.
Heel means the amount of gas that
remains in a gas cylinder or container
after it is discharged or off-loaded (this
may vary by cylinder or container type
and facility).
Nameplate capacity means the full
and proper charge of gas specified by
the equipment manufacturer to achieve
the equipment’s specified performance.
The nameplate capacity is typically
indicated on the equipment’s
nameplate; it is not necessarily the
actual charge, which may be influenced
by leakage and other emissions.
Proper destruction or removal
efficiency measurement means
measured in accordance with EPA’s
Protocol for Measuring Destruction or
Removal Efficiency of Fluorinated
Greenhouse Gas Abatement Equipment
in Electronics Manufacturing (March
2010).
Uptime means the total time during
the reporting year when the abatement
system for which controlled emissions
will be reported was properly installed,
operated, and maintained.
Wafer passes is a count of the number
of times a silicon wafer is processed in
a specific process category. The total
number of wafer passes over a reporting
year is the number of wafer passes per
tool times the number of operational
process tools in use during the reporting
year.
Process category is a set of similar
manufacturing steps, performed for the
same purpose, associated with substrate
(e.g., wafer) processing during device
manufacture for which fluorinated GHG
and N2O emissions and fluorinated GHG
and N2O usages are calculated and
reported.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
TABLE I–1 OF SUBPART I—DEFAULT EMISSION FACTORS FOR THRESHOLD APPLICABILITY DETERMINATION
Emission factors EFi
Product type
CF4
Semiconductors (kg/m2 Si) ......................
LCD (g/m2 LCD) .......................................
MEMs (kg/m2 Si) ......................................
C2F6
0.90
0.50
NA
CHF3
1.00
NA
NA
C3F8
0.04
NA
NA
NF3
0.05
NA
NA
Notes: NA denotes not applicable based on currently available information.
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SF6
0.04
0.90
NA
0.20
4.00
1.02
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Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
TABLE I–2 OF SUBPART I—EXAMPLES OF FLUORINATED GHGS USED BY THE ELECTRONICS INDUSTRY
Product type
Fluorinated GHGs used during manufacture
Electronics .................
CF4, C2F6, C3F8, c-C4F8, c-C4F8O, C4F6, C5F8, CHF3, CH2F2, NF3, SF6, and HTFs (CF3-(O-CF(CF3)-CF2)n-(O-CF2)mO-CF3, CnF2n+2, CnF2n+1(O)CmF2m+1, CnF2nO, (CnF2n+1)3N).
TABLE I–3 OF SUBPART I—DEFAULT EMISSION FACTORS FOR MEMS MANUFACTURING
Process Gas i
Process type factors
CF4
Etch 1–Ui ...........................................................
Etch BCF4 .........................................................
Etch BC2F6 ........................................................
CVD 1–Ui ..........................................................
CVD BCF4 .........................................................
CVD BC3F8 ........................................................
0.7
NA
NA
0.9
NA
NA
C2F6
CHF3
CH2F2
1 0.4
1 0.4
1 0.06
1 0.4
1 0.07
1 0.08
NA
0.6
0.1
NA
NA
NA
NA
NA
NA
NA
NA
NA
C3F8
NF3 remote
c-C4F8
NA
NA
NA
0.4
0.1
NA
1 0.2
NF3
NA
NA
NA
0.02
2 0.02
NA
0.2
0.2
0.1
0.1
NA
C4F6a
SF6
0.2
NA
NA
0.2
2 0.1
NA
0.2
NA
NA
NA
NA
NA
C5F8a
0.1
0.2
0.2
0.2
0.1
0.1
NA
1 0.3
1 0.2
NA
NA
NA
C4F8Oa
NA
NA
NA
0.1
0.1
0.4
Notes: NA denotes not applicable based on currently available information.
1 Estimate includes multi-gas etch processes.
2 Estimate reflects presence of low-k, carbide and multi-gas etch processes that may contain a C-containing fluorinated GHG additive.
TABLE I–4 OF SUBPART I—DEFAULT EMISSION FACTORS FOR LCD MANUFACTURING
Process gas i
Process type factors
CF4
Etch 1–Ui ..........................................................................
Etch BCF4 ........................................................................
Etch BCHF3 ......................................................................
Etch BC2F6 .......................................................................
CVD 1–Ui .........................................................................
C2F6
0.6
NA
NA
NA
NA
NA
NA
NA
NA
NA
CHF3
0.2
0.07
NA
0.05
NA
CH2F2
NA
NA
NA
NA
NA
c-C4F8
C3F8
NA
NA
NA
NA
NA
NF3 remote
0.1
0.009
0.02
NA
NA
NA
NA
NA
NA
0.03
NF3
NA
NA
NA
NA
0.3
SF6
0.3
NA
NA
NA
0.9
Notes: NA denotes not applicable based on currently available information.
TABLE I–5 OF SUBPART I—DEFAULT EMISSION FACTORS FOR PV MANUFACTURING
Process Gas i
Process type factors
CF4
Etch 1–Ui ..........................................................................
Etch BCF4 ........................................................................
Etch BC2F6 .......................................................................
CVD 1–Ui .........................................................................
CVD BCF4 ........................................................................
C2F6
0.7
NA
NA
NA
NA
CHF3
0.4
0.2
NA
0.6
0.2
0.4
NA
NA
NA
NA
CH2F2
NA
NA
NA
NA
NA
C3F8
c-C4F8
NA
NA
NA
0.1
0.2
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
Notes: NA denotes not applicable based on currently available information.
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0.2
0.1
0.1
0.1
0.1
NF3
Remote
NA
NA
NA
NA
NA
NF3
NA
NA
NA
0.3
NA
SF6
0.4
NA
NA
0.4
NA
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12APP4
Bevel cleaning:
1–Ui ................................................
BCF4 ...............................................
BC2F6 ..............................................
BC3F8 ..............................................
Ashing:
1–Ui ................................................
BCF4 ...............................................
BC2F6 ..............................................
In situ plasma cleaning:
1–Ui ................................................
BCF4 ...............................................
BC2F6 ..............................................
BC3F8 ..............................................
Remote plasma cleaning:
1–Ui ................................................
BCF4 ...............................................
BC2F6 ..............................................
BC3F8 ..............................................
In situ thermal cleaning:
1–Ui ................................................
BCF4 ...............................................
BC2F6 ..............................................
BC3F8 ..............................................
Oxide etch:
1–Ui ................................................
BCF4 ...............................................
BC2F6 ..............................................
BC3F8 ..............................................
Nitride etch:
1–Ui ................................................
BCF4 ...............................................
BC2F6 ..............................................
BC3F8 ..............................................
Silicon etch:
1–Ui ................................................
BCF4 ...............................................
BC2F6 ..............................................
BC3F8 ..............................................
Metal etch:
1–Ui ................................................
BCF4 ...............................................
BC2F6 ..............................................
BC3F8 ..............................................
Refined process category
0.2–0.7
0.05–0.5
NA
NA
C2F6
0.2–0.7
0.05–0.5
NA
NA
0.2–0.8
NA
NA
NA
0.2–0.8
NA
NA
NA
0.4–0.8
0.05–0.2
NA
NA
0.2–0.7
0.05–0.5
NA
NA
0.2–0.8
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.8–0.95
NA
NA
NA
0.2–0.7
0.05–0.5
NA
NA
0.2–0.8
NA
NA
NA
CF4
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.2–0.7
0.01–0.8
NA
NA
0.2–0.7
0.01–0.8
NA
NA
0.2–0.7
0.01–0.8
NA
NA
0.2–0.7
0.01–0.8
NA
NA
CHF3
C3F8
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.2–0.6
0.05–0.2
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
WAFER CLEANING
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
CHAMBER CLEANING
0.02–0.3
0.05–0.1
NA
NA
0.02–0.3
0.05–0.1
NA
NA
0.02–0.3
0.05–0.1
NA
NA
0.02–0.3
0.05–0.1
NA
NA
PATTERNING/ETCHING
CH2F2
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.05–0.3
0.05–0.2
NA
NA
0.1–0.3
0.01–0.3
0.01–0.3
NA
0.1–0.3
0.01–0.3
0.01–0.3
NA
0.1–0.3
0.01–0.3
0.01–0.3
NA
0.1–0.3
0.01–0.3
0.01–0.3
NA
c-C4F8
Process gas i
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.05–0.3
0.05–0.2
NA
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
NF3
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
SF6
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.05–0.2
0.02–0.4
0.02–0.3
NA
0.05–0.2
0.02–0.4
0.02–0.3
NA
0.05–0.2
0.02–0.4
0.02–0.3
NA
0.05–0.2
0.02–0.4
0.02–0.3
NA
C4F6
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.05–0.2
0.05–0.2
NA
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
C5F8
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.05–0.2
0.05–0.2
NA
0.02–0.08
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
C4F8O
TABLE I–6 OF SUBPART I—DEFAULT EMISSION FACTORS FOR REFINED PROCESS CATEGORIES FOR SEMICONDUCTOR MANUFACTURING FOR 150 MM WAFER
SIZE
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
18705
VerDate Nov<24>2008
CF4
NA
C2F6
NA
NA
CHF3
Notes: NA denotes not applicable based on currently available information.
BC3F8 ..............................................
Refined process category
NA
CH2F2
C3F8
NA
NA
c-C4F8
Process gas i
NF3
NA
SF6
NA
C4F6
NA
C5F8
NA
NA
C4F8O
TABLE I–6 OF SUBPART I—DEFAULT EMISSION FACTORS FOR REFINED PROCESS CATEGORIES FOR SEMICONDUCTOR MANUFACTURING FOR 150 MM WAFER
SIZE—Continued
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
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Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
TABLE I–7 OF SUBPART I—DEFAULT EMISSION FACTORS FOR REFINED PROCESS CATEGORIES FOR SEMICONDUCTOR
MANUFACTURING FOR 200 MM WAFER SIZE
Refined process
category
Process gas i
CF4
C2F6
CHF3
CH2F2
C3F8
c-C4F8
NF3
SF6
C4F6
C5F8
C4F8O
PATTERNING/ETCHING
Oxide etch:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
Nitride etch:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
Silicon etch:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
Metal etch:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
0.2–0.8
NA
NA
NA
0.2–0.7
0.05–0.5
NA
NA
0.2–0.7
0.01–0.8
NA
NA
0.02–0.3
0.05–0.1
NA
NA
NA
NA
NA
NA
0.1–0.3
0.01–0.3
0.01–0.3
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.05–0.5
0.02–0.4
0.02–0.3
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
NA
NA
NA
NA
0.2–0.8
NA
NA
NA
0.2–0.7
0.05–0.5
NA
NA
0.1–0.7
0.01–0.8
NA
NA
0.02–0.3
0.05–0.1
NA
NA
NA
NA
NA
NA
0.05–0.3
0.02–0.3
0.005–0.3
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.05–0.2
0.02–0.4
0.02–0.3
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
NA
NA
NA
NA
0.2–0.8
NA
NA
NA
0.2–0.7
0.05–0.5
NA
NA
0.2–0.7
0.01–0.8
NA
NA
0.02–0.3
0.05–0.1
NA
NA
NA
NA
NA
NA
0.1–0.3
0.01–0.3
0.01–0.3
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.05–0.2
0.02–0.4
0.02–0.3
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
NA
NA
NA
NA
0.2–0.8
NA
NA
NA
0.2–0.7
0.05–0.5
NA
NA
0.2–0.7
0.01–0.8
NA
NA
0.02–0.3
0.05–0.1
NA
NA
NA
NA
NA
NA
0.1–0.3
0.01–0.3
0.01–0.3
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.05–0.2
0.02–0.4
0.02–0.3
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
NA
NA
NA
NA
CHAMBER CLEANING
In situ plasma
cleaning:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
Remote plasma
cleaning:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
In situ thermal
cleaning:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
0.8–0.95
NA
NA
NA
0.4–0.8
0.05–0.2
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.2–0.6
0.05–0.2
NA
NA
005–0.3
0.05–0.2
NA
NA
0.05–0.2
0.05–0.1
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.05–0.2
0.05–0.2
NA
NA
0.05–0.2
0.05–0.2
NA
0.02–0.08
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.005–0.03
0.0001–0.2
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
WAFER CLEANING
Bevel cleaning:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
Ashing:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Note: NA denotes not applicable based on currently available information.
TABLE I–8 OF SUBPART I—DEFAULT EMISSION FACTORS FOR REFINED PROCESS CATEGORIES FOR SEMICONDUCTOR
MANUFACTURING FOR 300 MM WAFER SIZE
Refined process
category
Process gas i
CF4
C2F6
CHF3
CH2F2
C3F8
c-C4F8
NF3
SF6
C4F6
C5F8
C4F8O
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
PATTERNING/ETCHING
Oxide etch:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
Nitride etch:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
VerDate Nov<24>2008
0.2–0.8
NA
NA
NA
0.2–0.7
0.05–0.5
NA
NA
0.2–0.4
0.005–0.03
NA
NA
0.1–0.8
0.001–0.01
NA
NA
NA
NA
NA
NA
0.05–0.3
0.005–0.1
0.005–0.1
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
NA
NA
NA
NA
0.2–0.8
NA
NA
NA
0.2–0.7
0.05–0.5
NA
NA
0.2–0.4
0.003–0.1
NA
NA
0.1–0.8
0.01–0.1
NA
NA
NA
NA
NA
NA
0.08–0.3
0.02–0.3
0.02–0.3
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.05–0.2
0.05–0.4
0.05–0.4
NA
0.05–0.3
0.05–0.4
0.05–0.4
NA
NA
NA
NA
NA
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Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
TABLE I–8 OF SUBPART I—DEFAULT EMISSION FACTORS FOR REFINED PROCESS CATEGORIES FOR SEMICONDUCTOR
MANUFACTURING FOR 300 MM WAFER SIZE—Continued
Refined process
category
Silicon etch:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
Metal etch:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
Process gas i
CF4
C2F6
CHF3
CH2F2
0.2–0.8
NA
NA
NA
0.2–0.7
0.05–0.5
NA
NA
0.2–0.7
0.01–0.8
NA
NA
0.02–0.3
0.05–0.1
NA
NA
0.2–0.8
NA
NA
NA
0.2–0.7
0.05–0.5
NA
NA
0.2–0.7
0.01–0.8
NA
NA
C3F8
0.02–0.3
0.05–0.1
NA
NA
c-C4F8
NF3
SF6
C4F6
C5F8
C4F8O
NA
NA
NA
NA
0.1–0.3
0.01–0.3
0.01–0.3
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.05–0.2
0.02–0.4
0.02–0.3
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.1–0.3
0.01–0.3
0.01–0.3
NA
0.1–0.4
NA
NA
NA
0.1–0.4
NA
NA
NA
0.05–0.2
0.02–0.4
0.02–0.3
NA
0.05–0.3
0.02–0.4
0.02–0.3
NA
NA
NA
NA
NA
CHAMBER CLEANING
In situ plasma
cleaning:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
Remote plasma
cleaning:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
In situ thermal
cleaning:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.1–0.4
0.001–0.6
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.002–0.03
0.001–0.05
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.1–0.4
0.005-.05
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
WAFER CLEANING
Bevel cleaning:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
Ashing:
1-Ui ...........
BCF4 .........
BC2F6 .......
BC3F8 .......
0.3–0.8
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.3–0.8
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Notes: NA denotes not applicable based on currently available information.
4. Add subpart L to read as follows:
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
Subpart L—Fluorinated Gas Production
Sec.
98.120 Definition of the source category.
98.121 Reporting threshold.
98.122 GHGs to report.
98.123 Calculating GHG emissions.
98.124 Monitoring and QA/QC
requirements.
98.125 Procedures for estimating missing
data.
98.126 Data reporting requirements.
98.127 Records that must be retained.
98.128 Definitions.
Subpart L—Fluorinated Gas
Production
§ 98.120
Definition of the source category.
(a) The fluorinated gas production
source category consists of processes
that produce a fluorinated gas from any
raw material or feedstock chemical,
except for processes that generate HFC–
23 during the production of HCFC–22.
VerDate Nov<24>2008
17:39 Apr 09, 2010
Jkt 220001
(b) To produce a fluorinated gas
means to manufacture a fluorinated gas
from any raw material or feedstock
chemical. Producing a fluorinated gas
includes producing a fluorinated GHG
as defined at § 98.410(b). Producing a
fluorinated gas also includes the
manufacture of a chlorofluorocarbon
(CFC) or hydrochlorofluorocarbon
(HCFC) from any raw material or
feedstock chemical, including
manufacture for use in a process that
will result in the transformation of the
CFC or HCFC either at or outside of the
production facility. Producing a
fluorinated gas does not include the
reuse or recycling of a fluorinated gas,
the creation of HFC–23 during the
production of HCFC–22, or the creation
of by-products that are released or
destroyed at the production facility.
PO 00000
Frm 00058
Fmt 4701
Sfmt 4702
§ 98.121
Reporting threshold.
You must report GHG emissions
under this subpart if your facility
contains a fluorinated gas production
process that generates or emits
fluorinated GHG and the facility meets
the requirements of either § 98.2(a)(1) or
(a)(2) of this part. To calculate GHG
emissions for comparison to the 25,000
metric ton CO2e per year emission
threshold in § 98.2(a)(2), calculate
process emissions from fluorinated gas
production using uncontrolled GHG
emissions.
§ 98.122
GHGs to report.
(a) You must report CO2, CH4, and
N2O combustion emissions from each
stationary combustion unit. You must
calculate and report these emissions
under subpart C of this part (General
Stationary Fuel Combustion Sources) by
following the requirements of subpart C.
E:\FR\FM\12APP4.SGM
12APP4
Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
Where:
eSA = absolute error of the sum, expressed
as one half of a 95 percent confidence
interval.
ea = relative error of a, expressed as one
half of a 95 percent confidence interval.
eb = relative error of b, expressed as one
half of a 95 percent confidence interval.
ec = relative error of c, expressed as one
half of a 95 percent confidence interval.
(2) Equation L–2 of this section
provides the general formula for
)
2
2⎤
+ ( c ∗ ec ) ⎥
⎦
eSR =
esA
(a +b+ c)
(Eq. L-2)
Where:
eSR = relative error of the sum, expressed
as one half of a 95 percent confidence
interval.
eSA = absolute error of the sum, expressed
as one half of a 95 percent confidence
interval.
(
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
(4) Equation L–4 of this section
provides the general formula for
VerDate Nov<24>2008
17:39 Apr 09, 2010
Jkt 220001
(Eq. L-1)
calculating the relative errors of sums
and differences:
2
2
ePA = ( a ∗ b ∗ c ) ea + e2 + ec
b
Where:
ePA = absolute error of the product,
expressed as one half of a 95 percent
confidence interval.
ea = relative error of a, expressed as one
half of a 95 percent confidence interval.
eb = relative error of b, expressed as one
half of a 95 percent confidence interval.
ec = relative error of c, expressed as one
half of a 95 percent confidence interval.
12
)
12
ePA
(a ∗ b ∗ c)
(Eq. L-4)
Where:
ePR = relative error of the product,
expressed as one half of a 95 percent
confidence interval.
PO 00000
Frm 00059
Fmt 4701
Sfmt 4702
(3) Equation L–3 provides the general
formula for calculating the absolute
errors of products (e.g., flow rates of
GHGs calculated as the product of the
flow rate of the stream and the
concentration of the GHG in the stream),
where the product, P, is the result of
multiplying the variables measured, a,
b, c, etc. (e.g., P = a*b*c):
(Eq. L-3)
calculating the relative errors of
products:
ePR =
a+b+c = sum of the variables measured.
EP12AP10.054
((
⎡
2
e SA = ⎢( a ∗ ea ) + b ∗ eb
⎣
ePA = absolute error of the product,
expressed as one half of a 95 percent
confidence interval.
a*b*c = product of the variables measured.
(5) The total mass of each fluorinated
GHG product emitted annually from all
fluorinated gas production processes
shall be estimated by using Equation
L–5 of this section:
E:\FR\FM\12APP4.SGM
12APP4
EP12AP10.053
Calculating GHG emissions.
For fluorinated GHG production
processes, you must calculate the
fluorinated GHG emissions from each
process using either the mass balance
method specified in paragraph (a) of this
section or the emission factor or
Instead, you must use the emission
factor approach detailed in paragraphs
(b), (c), and (d) of this section to
estimate emissions from the process. To
perform the calculation, you shall first
calculate the absolute and relative errors
associated with the quantities calculated
using Equations L–8 through L–11.
Once errors have been calculated for the
quantities in these equations, those
errors shall be used to calculate the
errors in Equations L–7 and L–12.
Where the measured quantity is a mass,
the error in the mass shall be equated to
the accuracy or precision (whichever is
larger) of the flowmeter, scale, or
combination of volumetric and density
measurements at the flow rate or mass
measured. Where the measured quantity
is a concentration, the error of the
concentration shall be equated to the
accuracy or precision (whichever is
larger) of the analytical technique used
to measure the concentration at the
concentration measured.
(1) Equation L–1 of this section
provides the general formula for
calculating the absolute errors of sums
and differences where the sum, S, is the
summation of variables measured, a, b,
c, etc. (e.g., S = a + b + c):
EP12AP10.052
§ 98.123
emission calculation factor method
specified in paragraphs (b), (c), and (d)
of this section, as appropriate. For
processes that manufacture CFCs or
HCFCs or that transform fluorinated
gases into substances other than
fluorinated GHGs, you must use the
procedures in paragraphs (b), (c), and
(d) of this section. For destruction
processes that destroy fluorinated GHGs
that were previously ‘‘produced’’ as
defined at 98.410(b), you must use the
procedures in paragraph (e) of this
section.
(a) Mass balance method. Before
using the mass balance approach to
estimate your fluorinated GHG
emissions from a process, you must
estimate the absolute and relative errors
associated with using the mass balance
approach on that process using
Equations L–1 through L–4 of this
section in conjunction with Equations
L–7 through L–12 of this section. If this
calculation shows that use of the massbalance approach to estimate emissions
from the process will result in an
absolute error exceeding 3,000 metric
tons CO2e per year and a relative error
exceeding 30 percent, then you cannot
use the mass-balance approach to
estimate emissions from the process.
EP12AP10.051
(b) You must report under subpart O
of this part (HCFC–22 Production and
HFC–23 Destruction) the emissions of
HFC–23 from HCFC–22 production
processes and HFC–23 destruction
processes. Do not report the generation
and emissions of HFC–23 from HCFC–
22 production under this subpart.
(c) You must report the total mass of
each fluorinated GHG from:
(1) Each fluorinated gas production
process and all fluorinated gas
production processes combined.
(2) Each fluorinated gas
transformation process that is not part of
a fluorinated gas production process
and all such fluorinated gas
transformation processes combined.
(3) Each fluorinated gas destruction
process that is not part of a fluorinated
gas production process or a fluorinated
gas transformation process and all such
fluorinated gas destruction processes
combined.
18709
18710
Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
fluorinated gas production processes
shall be estimated by using Equation L–
6 of this section:
Where:
EBk = Total mass of fluorinated GHG byproduct k emitted annually from all
production processes (metric tons).
EBkip = Total mass of fluorinated GHG byproduct k emitted from production
process i over the period p (metric tons,
defined in Equation L–8 on this section).
n = Number of concentration and flow
measurement periods for the year.
q
u
R ∗ MWP ∗ SCP
− P − ∑ ( CP ∗ WDj ) − ∑ LBkip
MWR ∗ SCR
j =1
k =1
Where:
EPip = Total mass of each fluorinated GHG
product emitted from production process
i over the period p (metric tons).
P = Total mass of the fluorinated GHG
produced by production process i over
the period p (metric tons).
R = Total mass of the reactant that is
consumed by production process i over
the period p (metric tons, defined in
Equation L–8 of this section).
MWP = Molecular weight of the fluorinated
GHG produced.
MWR = Molecular weight of the reactant.
SCP = Stoichiometric coefficient of the
fluorinated GHG produced.
SCR = Stoichiometric coefficient of the
reactant.
CP = Concentration (mass fraction) of the
fluorinated GHG product in stream j of
destroyed wastes. If this concentration is
only a trace concentration, CP is equal to
zero.
WDj = Mass of wastes removed from
production process i in stream j and
destroyed over the period p (metric tons,
defined in Equation L–9 of this section).
(9) The mass of wastes removed from
production process i in stream j and
destroyed over the period p shall be
estimated using Equation L–9 of this
section:
(8) The total mass of the reactant that
is consumed by production process i
over the period p shall be estimated by
using Equation L–8 of this section:
Where:
WDj = The mass of wastes removed from
production process i in stream j and
destroyed over the period p (metric
tons).
WFj = The total mass of wastes removed
from production process i in stream j and
fed into the destruction device over the
period p (metric tons).
DE = Destruction efficiency of the
destruction device (fraction).
R = RF − RR
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
17:39 Apr 09, 2010
Jkt 220001
(Eq. L-8)
Where:
R = Total mass of the reactant that is
consumed by production process i over
the period p (metric tons).
RF = Total mass of the reactant that is fed into
production process i over the period p
(metric tons).
RR = Total mass of the reactant that is
permanently removed from production
process i over the period p (metric tons).
(B
kip
∗ MWP ∗ MEBk )
( MW
Bk
Where:
LBkip = Yield loss related to by-product k
for production process i over the period
p (metric tons).
Bkip = Mass of by-product k generated by
production process i over the period p
(metric tons, defined in Equation L–11 of
this section).
MWP = Molecular weight of the fluorinated
GHG produced.
MEBk = Moles of the element shared by the
reactant, product, and by-product k per
mole of by-product k.
MWBk = Molecular weight of by-product k.
(Eq. L-7)
LBkip = Yield loss related to by-product k for
production process i over the period p
(metric tons, defined in Equation L–10 of
this section).
q = Number of waste streams destroyed in
production process i.
u = Number of by-products generated in
production process i.
LBkip =
VerDate Nov<24>2008
(Eq. L-6)
p =1 i =1
∗ ME p )
WDj = WFj ∗ DE
(10) Yield loss related to by-product k
for production process i over period p
shall be estimated using Equation L–10
of this section:
(Eq. L-10)
MEP = Moles of the element shared by the
reactant, product, and by-product k per
mole of the product.
(11) If by-product k is responsible for
yield loss in production process i and
occurs in any stream (including process
streams, emissions streams, or destroyed
streams) in more than trace
concentrations, the mass of by-product
k generated by production process i over
the period p shall be estimated using
Equation L–11 of this section:
PO 00000
Frm 00060
Fmt 4701
Sfmt 4702
(Eq. L-9)
EP12AP10.061
EPip =
m
EP12AP10.060
(6) The total mass of fluorinated GHG
by-product k emitted annually from all
n
EBk = ∑ ∑ EBkip
EP12AP10.059
Where:
EP = Total mass of each fluorinated GHG
product emitted annually from all
production processes (metric tons).
EPip = Total mass of the fluorinated GHG
product emitted from production process
i over the period p (metric tons, defined
in Equation L–7 of this section).
n = Number of concentration and flow
measurement periods for the year.
m = Number of production processes.
(7) The total mass of each fluorinated
GHG product emitted from production
process i over the period p shall be
estimated at least monthly by
calculating the difference between the
expected production of the fluorinated
GHG based on the consumption of one
of the reactants (e.g., HF or a
chlorocarbon reactant) and the
measured production of the fluorinated
GHG, accounting for yield losses related
to by-products and wastes. This
calculation shall be performed using
Equation L–7 of this section.
q
Bkip =
∑c
Bjk
∗Sj
(Eq. L-11)
j
Where:
Bkip = Mass of by-product k generated by
production process i over the period p
(metric tons).
cBkj = Concentration (mass fraction) of the
by-product k in stream j of production
process i over the period p. If this
concentration is only a trace
concentration, cBkj is equal to zero.
Sj = Mass flow of stream j of production
process i over the period p.
E:\FR\FM\12APP4.SGM
12APP4
EP12AP10.058
p =1 i =1
m = Number of production processes.
EP12AP10.057
(Eq. L-5)
EP12AP10.056
m
EP12AP10.055
n
E p = ∑ ∑ EPip
Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
(12) If by-product k is responsible for
yield loss, is a fluorinated GHG, occurs
in any stream (including process
streams, emissions streams, or destroyed
streams) in more than trace
concentrations, and is not completely
recaptured or completely destroyed; the
q
x
j =1
l =1
EBkip = Bkip − ∑ cBkj ∗ WDj − ∑ cBkl ∗ SRl
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
Where:
EBkip = Mass of by-product k emitted from
production process i over the period p
(metric tons).
Bkip = Mass of by-product k generated by
production process i over the period p
(metric tons).
cBkj = Concentration (mass fraction) of the
by-product k in stream j of destroyed
wastes over the period p. If this
concentration is only a trace
concentration, cBjk is equal to zero.
WDj = The mass of wastes that are removed
from production process i in stream j and
that are destroyed over the period p
(metric tons, defined in Equation L–9 of
this section).
cBkl = The concentration (mass fraction) of
the by-product k in stream l of
recaptured material over the period p. If
this concentration is only a trace
concentration, cBkl is equal to zero.
SRl = The mass of materials that are
removed from production process i in
stream l and that are recaptured over the
period p.
q = Number of waste streams destroyed in
production process i.
x = Number of streams recaptured in
production process i.
(b) Emission factor and emission
calculation factor methods. To use the
method in this paragraph, you must first
make a preliminary estimate of the
emissions from each individual process
vent under paragraph (b)(1) of this
section. Then, compare the preliminary
estimate to the criteria in paragraph
(b)(2) of this section to determine
whether the process vent meets the
criteria for using the emission factor
method described in paragraph (b)(3) of
this section or whether the process vent
meets the criteria for using the emission
calculation factor method described in
paragraph (b)(4) of this section.
(1) Preliminary estimate of emissions
by process vent. You must estimate the
annual uncontrolled emissions of
fluorinated GHG for each process vent
within a process. You may determine
uncontrolled emissions of fluorinated
GHG by process vent using existing
measurements and/or calculations based
on chemical engineering principles and
chemical property data or you may
conduct an engineering assessment. You
must document all data, assumptions,
and procedures used in the calculations
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17:39 Apr 09, 2010
Jkt 220001
(Eq. L-12)
or engineering assessment and keep a
record of the uncontrolled emissions
determination (in § 98.127(a)).
(i) Engineering calculations. For
process vent emission calculations, you
may use paragraph (b)(1)(i)(A), (B), or
(C) of this section.
(A) Emissions Inventory Improvement
Process, Volume II: Chapter 16, Methods
for Estimating Air Emissions from
Chemical Manufacturing Facilities. U.S.
Environmental Protection Agency,
August 2007.
(B) You may determine the
uncontrolled fluorinated GHG emissions
from any process vent within the
process using the procedures specified
in 40 CFR § 63.1257(d)(2)(i), except as
specified in paragraphs (b)(1)(i)(B)(1)
through (b)(1)(i)(B)(7) of this section.
For the purposes of this subpart, use of
the term ‘‘HAP’’ in § 63.1257(d)(2)(i)
shall mean ‘‘fluorinated GHG’’.
(1) To calculate emissions caused by
the heating of a vessel without a process
condenser to a temperature lower than
the boiling point, you must use the
procedures in § 63.1257(d)(2)(i)(C)(3).
(2) To calculate emissions from
depressurization of a vessel without a
process condenser, you must use the
procedures in § 63.1257(d)(2)(i)(D)(10).
(3) To calculate emissions from
vacuum systems, the terms used in
Equation 33 to 40 CFR part 63, subpart
GGG, are defined as follows:
(i) Psystem = absolute pressure of the
receiving vessel;
(ii) Pi = partial pressure of the
fluorinated GHG determined at the exit
temperature and exit pressure
conditions of the condenser or at the
conditions of the dedicated receiver;
(iii) Pj = partial pressure of
condensables (including fluorinated
GHG) determined at the exit
temperature and exit pressure
conditions of the condenser or at the
conditions of the dedicated receiver;
(iv) MWFluorinated GHG = molecular
weight of the fluorinated GHG
determined at the exit temperature and
exit pressure conditions of the
condenser or at the conditions of the
dedicated receiver.
(4) To calculate uncontrolled
emissions when a vessel is equipped
PO 00000
total mass of by-product k emitted from
production process i over the period p
shall be estimated at least monthly
using Equation L–12 of this section:
Frm 00061
Fmt 4701
Sfmt 4702
with a process condenser, you must use
the procedures in 40 CFR
63.1257(d)(3)(i)(B), except as follows:
(i) You must determine the flowrate of
gas (or volume of gas), partial pressures
of condensables, temperature (T), and
fluorinated GHG molecular weight
(MWFluorinated GHG) at the exit
temperature and exit pressure
conditions of the condenser or at the
conditions of the dedicated receiver.
(ii) You must assume that all of the
components contained in the condenser
exit vent stream are in equilibrium with
the same components in the exit
condensate stream (except for
noncondensables).
(iii) You must perform a material
balance for each component.
(iv) For the emissions from gas
evolution, the term for time, t, must be
used in Equation 12 to 40 CFR part 63,
subpart GGG.
(v) Emissions from empty vessel
purging shall be calculated using
Equation 36 to 40 CFR part 63, subpart
GGG and the exit temperature and exit
pressure conditions of the condenser or
the conditions of the dedicated receiver.
(C) Commercial software products
that follow chemical engineering
principles, including the calculation
methodologies in paragraphs (b)(1)(i)(A)
and (B) of this section.
(ii) Engineering assessments. For
process vent emissions determinations,
you may conduct an engineering
assessment to calculate uncontrolled
emissions for each emission episode. An
engineering assessment includes, but is
not limited to, the following:
(A) Previous test results, provided the
tests are representative of current
operating practices of the process.
(B) Bench-scale or pilot-scale test data
representative of the process under
representative operating conditions.
(C) Maximum flow rate, fluorinated
GHG emission rate, concentration, or
other relevant parameters specified or
implied within a permit limit applicable
to the process vent.
(D) Design analysis based on chemical
engineering principles, measureable
process parameters, or physical or
chemical laws or properties.
E:\FR\FM\12APP4.SGM
12APP4
EP12AP10.062
q = Number of streams in production
process i.
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Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
compulsory process shutdowns) in
place that ensure that uncontrolled
emissions do not occur. For each
process, you should either track the
amount of production or other process
activity that is vented to the destruction
device or track production or other
process activity that by-passes the
destruction device.
(ii) If the individual process vent does
not meet the criteria in either paragraph
(b)(2)(i)(A) or (b)(2)(i)(B) of this section,
then the facility must comply with the
emission factor method specified in
paragraph (b)(3) of this section.
(3) Process-vent-specific emission
factor method. For each process vent,
conduct an emission test and measure
uncontrolled fluorinated GHG emissions
from the process and measure the
process activity, such as the feed rate,
production rate, or other process
activity rate, during the test as described
in this paragraph (b)(3). All emissions
test data and procedures used in
(2) Process vent annual mass limit
and control determination.
(i) If the individual process vent
meets the criteria in either paragraph
(b)(2)(i)(A) or (b)(2)(i)(B) of this section,
then you may comply with either
paragraph (b)(3) (Emission Factor
approach) or paragraph (b)(4) (Emission
Calculation Factor approach).
(A) Uncontrolled fluorinated GHG
emissions for the individual process
vent as estimated using procedures in
paragraph (b)(1) of this section are less
than 10,000 metric tons CO2e per year
or, for emissions including fluorinated
GHGs whose GWPs are not listed in
Table A–1, 1 metric ton per year.
(B) The individual process vent is
vented to a destruction device
demonstrated to achieve a destruction
efficiency of 99.9 percent for the
fluorinated GHGs in the vent stream,
and the facility has equipment (e.g.,
holding tank capacity; monitoring of bypass streams) or procedures (e.g.,
EContPV =
Where:
EContPV = Mass of fluorinated GHG f
emitted from process vent v from
production process i during the emission
test during test run r (kg/hr).
CPV
6
10
∗ MW ∗ QPV ∗
1
1 60
∗
∗
SV 103 1
developing emission factors shall be
documented according to § 98.127.
(i) You must measure the process
activity, such as the process feed rate,
process production rate, or other
process activity rate, as applicable,
during the emission test according to
the procedures in § 98.124 and calculate
the rate for the test period, in kg per
hour or in kg per batch.
(ii) For continuous processes, you
must calculate the hourly uncontrolled
fluorinated GHG emission rate using
Equation L–13 of this section and
determine the hourly uncontrolled
fluorinated GHG emission rate per
process vent for the test run. For batch
processes, you must calculate the
uncontrolled fluorinated GHG emissions
during each emission episode over the
batch using Equation L–14 of this
section and determine the fluorinated
GHG emissions per process based on the
batch runs conducted for the test.
(Eq. L-13)
CPV = Concentration of fluorinated GHG f
during test run r of the emission test
(ppmv).
MW = Molecular weight of fluorinated
GHG f (g/g-mole).
QPV = Flow rate of the process vent stream
during test run r of the emission test (m3/
min).
SV = Standard molar volume of gas (0.0240
m3/g-mole at 68° F and 1 atm).
1/103 = Conversion factor (1 kilogram/
1,000 gram).
60/1 = Conversion factor (60 minutes/1
hour).
ee
10
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
Where:
EBatchPV = Mass of fluorinated GHG f
emitted from process vent v from
production process i during the emission
test during test run r (kg/batch).
CPV-ee = Concentration of fluorinated GHG
f during emission episode ee during test
run r of the emission test (ppmv).
QPV-ee = Flow rate of the process vent
stream during emission episode ee
during test run r of the emission test (m3/
min).
(iii) You must calculate a site-specific,
process-vent-specific emission factor for
EFPV =
17:39 Apr 09, 2010
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1
1
∗ 3
SV 10
Dee = Duration of emission episode ee
during test run r of the emission test
(minutes).
MW = Molecular weight of fluorinated
GHG f (g/g-mole).
SV = Standard molar volume of gas (0.0240
m3/g-mole at 68°F and 1 atm).
1/103 = Conversion factor (1 kilogram/
1,000 gram).
ee = Number of emission episodes ee from
process vent v during process i.
r
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∗ MW ∗
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1
⎝
E
∑ ⎜ Activity PV
Frm 00062
EmissionTest
⎞
⎟
⎠
r
Fmt 4701
Sfmt 4702
(Eq. L-14)
each process vent, in kg of uncontrolled
fluorinated GHG per process activity
rate (e.g., kg of feed or production), as
applicable, using Equation L–15 of this
section. For continuous processes,
divide the hourly fluorinated GHG
emission rate during the test by the
hourly process activity rate during the
test runs. For batch processes, divide
the fluorinated GHG emissions by the
process activity rate for the batch runs.
(Eq. L-15)
E:\FR\FM\12APP4.SGM
EP12AP10.065
6
EP12AP10.064
1
12APP4
EP12AP10.063
EBatchPV =
∑ CPV -ee ∗ QPV -ee ∗ Dee
Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
(kg emitted/hr for continuous, kg
emitted/batch for batch).
ActivityEmissionTest = Process feed, process
production, or other process activity rate
during the emission test during test run
r (e.g., kg product/hr for continuous,
calculated in Equation L–13 of this
section, kg product/batch for batch,
calculated in Equation L–14 of this
section).
EPV -RptPeriod = EFPV ∗ ActivityRptPeriod
(iv) You must calculate fluorinated
GHG emissions for the process vent for
the reporting period by multiplying the
process-vent-specific emission factor by
the total process activity, as applicable,
for the reporting period, using Equation
L–16 of this section.
(Eq. L-16)
Where:
EPV–RptPeriod = Mass of fluorinated GHG f
emitted from process vent v from
production process i, for the reporting
period, either monthly or annually,
considering destruction efficiency (kg/
month or kg/year).
EFPV = Emission factor for fluorinated GHG
f emitted from process vent v during
production process i (kg emitted/kg
product).
ActivityRptPeriod-U = Total process feed,
process production, or other process
activity during the reporting period for
which the process vent is not vented to
the destruction device (e.g., kg product).
ActivityRptPeriod-C = Total process feed,
process production, or other process
activity during the reporting period for
which the process vent is vented to the
destruction device (e.g., kg product).
DE = Demonstrated destruction efficiency
of the destruction device (weight
fraction).
(vi) Sum the emissions from all
process vents in the process for the
reporting period to estimate total
fluorinated GHG process emissions,
using Equation L–18 of this section.
v
EPfi = ∑ EPV - RptPeriod
(Eq. L-18)
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
1
EPfi = Mass of fluorinated GHG f emitted
from production process i, for the
reporting period, either monthly or
annually (kg).
EPV–RptPeriod = Mass of fluorinated GHG f
emitted from process vent v from
production process i, for the reporting
period, either monthly or annually,
considering destruction efficiency (kg/
month or kg/year).
v = Number of process vents in production
process i.
(vii) Sum the emissions from all
processes for the reporting period to
estimate total fluorinated GHG process
vent emissions, using Equation L–19 of
this section.
i
EP = ∑ EPfi
Where:
EP = Mass of fluorinated GHG f emitted
from all process vents at the facility, for
the reporting period, either monthly or
annually (kg).
EPij = Mass of fluorinated GHG f emitted
from production process i, for the
reporting period, either monthly or
annually (kg).
i = Number of production processes i at the
facility.
(4) Process-vent-specific emission
calculation factor method. For each
Where:
ECFPV =
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17:39 Apr 09, 2010
(Eq. L-19)
1
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EPV
ActivityRe presentative
Frm 00063
Fmt 4701
Sfmt 4725
)
(Eq. L-17)
process vent, determine fluorinated
GHG emissions by calculations and
determine the process activity rate, such
as the feed rate, production rate, or
other process activity rate, associated
with the emission rate.
(i) You must calculate uncontrolled
emissions of fluorinated GHG by
individual process vent, EPV, using
measurements and/or calculations based
on chemical engineering principles and
chemical property data or you may
conduct an engineering assessment,
using the procedures in paragraphs
(b)(1)(i) or (ii) of this section, except
paragraph (b)(1)(ii)(C) of this section.
The uncontrolled emissions must be
based on a typical batch or production
rate under a defined operating scenario.
The process activity rate associated with
the uncontrolled emissions must be
determined. All data, assumptions, and
procedures used in the calculations or
engineering assessment shall be
documented according to § 98.127.
(ii) You must calculate a site-specific,
process-vent-specific emission
calculation factor for each process vent,
in kg of fluorinated GHG per activity
rate (e.g., kg of feed or production) as
applicable, using Equation L–20 of this
section.
(Eq. L-20)
E:\FR\FM\12APP4.SGM
EP12AP10.070
(
EPV - RptPeriod = EFPV ∗ ActivityRptPeriod -U + ActivityRptPeriod -C ∗ (1 − DE)
EP12AP10.069
(v) If the process vent is vented to a
destruction device, apply the
demonstrated destruction efficiency of
the device to the fluorinated GHG
emissions for the process vent, using
Equation L–17 of this section. You may
apply the destruction efficiency only to
the portion of the process activity that
is vented to the destruction device (i.e.,
controlled).
EP12AP10.068
vent v during production process i (kg
emitted/activity) (e.g., kg emitted/kg
product).
ActivityRptPeriod = Process feed, process
production, or other process activity
during the reporting period.
EP12AP10.067
Where:
EPV–RptPeriod = Mass of fluorinated GHG f
emitted from process vent v from
production process i, for the reporting
period, either monthly or annually (kg/
month or kg/year).
EFPV = Average emission factor for
fluorinated GHG f emitted from process
r = Number of test runs (i.e., batches)
performed during the emission test.
12APP4
EP12AP10.066
Where:
EFPV = Average emission factor for
fluorinated GHG f emitted from process
vent v during production process i (kg
emitted/kg product).
EPV = Mass of fluorinated GHG f emitted
from process vent v from production
process i during the emission test during
test run r, for either continuous or batch
18713
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Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
emissions were calculated, for either
continuous or batch (kg emitted/hr for
continuous, kg emitted/batch for batch).
ActivityRepresentative = Process feed, process
production, or other process activity rate
corresponding to average mass of
emissions based on calculations (e.g., kg
product/hr for continuous, kg product/
batch for batch).
(iv) If the process vent is vented to a
destruction device, apply the
demonstrated destruction efficiency of
the device to the fluorinated GHG
emissions for the process vent, using
Equation L–22 of this section. You may
apply the destruction efficiency only to
the portion of the process activity that
is vented to the destruction device (i.e.,
controlled).
(
EPV - RptPeriod = ECFPV ∗ ActivityRptPeriod -U + ActivityRptPeriod -C ∗ (1 − DE )
Where:
EPV–RptPeriod = Mass of fluorinated GHG f
emitted from process vent v from
production process i, for the reporting
period, either monthly or annually,
considering destruction efficiency (kg/
month or kg/year).
ECFPV = Emission calculation factor for
fluorinated GHG f emitted from process
vent v during production process i (kg
emitted/kg product).
ActivityRptPeriod-U = Total process feed,
process production, or other process
activity during the reporting period for
which the process vent is not vented to
the destruction device (e.g., kg product).
ActivityRptPeriod-C = Total process feed,
process production, or other process
activity during the reporting period for
which the process vent is vented to the
destruction device (e.g., kg product).
DE = Demonstrated destruction efficiency of
the destruction device (weight fraction).
(v) Sum the fluorinated GHG
emissions from all process vents in the
process for the reporting period to
estimate total process emissions, using
Equation L–23 of this section.
v
EPfi = ∑ EPV - RptPeriod
(Eq. L-23)
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
1
Where:
EPfi = Mass of fluorinated GHG f emitted from
production process i, for the reporting
period, either monthly or annually (kg).
EPV–RptPeriod = Mass of fluorinated GHG f
emitted from process vent v from
production process i, for the reporting
period, either monthly or annually,
considering destruction efficiency (kg/
month or kg/year).
v = Number of process vents in production
process i.
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17:39 Apr 09, 2010
Jkt 220001
(vi) Sum the emissions from all
processes for the reporting period to
estimate total fluorinated GHG process
emissions, using Equation L–24 of this
section.
i
EP = ∑ EPfi
(Eq. L-24)
1
Where:
EP = Mass of fluorinated GHG f emitted from
all processes at the facility, for the
reporting period, either monthly or
annually (kg).
EPij = Mass of fluorinated GHG f emitted from
production process i, for the reporting
period, either monthly or annually (kg).
i = Number of production processes i at the
facility.
(c) Calculate fluorinated GHG
emissions for equipment leaks (EL). If
you comply with paragraph (b) of this
section, you must calculate the
fluorinated GHG emissions from pieces
of equipment associated with processes
covered under this subpart and in
fluorinated GHG service. The emissions
from equipment leaks must be
calculated using one of the following
methods in the Protocol for Equipment
Leak Emission Estimates, U.S.
Environmental Protection Agency, EPA
Publication No. EPA–453/R–95–017,
November 1995: the Screening Ranges
Approach; the EPA Correlation
Approach; or the Unit-Specific
Correlation Approach. You may not use
the procedure in the protocol for
Average Emission Factor Approach.
(1) You must develop response factors
for each fluorinated GHG or for each
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)
(Eq. L-22)
surrogate to be measured using EPA
Method 21, 40 CFR part 60, Appendix
A–7. For each fluorinated GHG
measured, the response factor shall be
less than 10. The response factor is the
ratio of the known concentration of a
fluorinated GHG to the observed meter
reading when measured using an
instrument calibrated with the reference
compound.
(2) You must collect information on
the number of each type of equipment;
the service of each piece of equipment
(gas, light liquid, heavy liquid); the
concentration of each fluorinated GHG
in the stream; and the time period each
piece of equipment was in service.
Depending on which approach you
follow, you must collect information for
equipment on the associated screening
data concentrations for greater than or
equal to 10,000 ppmv and associated
screening data concentrations for less
than 10,000 ppmv; associated actual
screening data concentrations; and
associated screening data and leak rate
data (i.e., bagging) used to develop a
unit-specific correlation.
(3) Calculate and sum the emissions
of each fluorinated GHG in kg/yr for
equipment pieces for all processes, EEL.
(d) Calculate total fluorinated GHG
emissions for the facility/source
category. Estimate annually the total
mass of fluorinated GHG emissions from
process vents in either paragraph (c)(3)
or (c)(4) of this section, as appropriate,
and from equipment leak emissions in
paragraph (d) using Equation L–25 of
this section.
E:\FR\FM\12APP4.SGM
12APP4
EP12AP10.074
vent v during production process i (kg
emitted/activity) (e.g., kg emitted/kg
product).
ActivityRptPeriod = Process feed, process
production, or other process activity
during the reporting period.
EP12AP10.073
Where:
EPV–RptPeriod = Mass of fluorinated GHG f
emitted from process vent v from
production process i, for the reporting
period, either monthly or annually (kg/
month or kg/year).
ECFPV = Emission calculation factor for
fluorinated GHG f emitted from process
(Eq. L-21)
EP12AP10.072
EPV - RptPeriod = ECFPV ∗ ActivityRptPeriod
(iii) You must calculate fluorinated
GHG emissions for the process vent for
the reporting period by multiplying the
process-vent-specific emission
calculation factor by the total process
activity, as applicable, for the reporting
period, using Equation L–21 of this
section.
EP12AP10.071
Where:
ECFPV = Emission calculation factor for
fluorinated GHG f emitted from process
vent v during production process i (kg
emitted/kg product).
EPV = Average mass of fluorinated GHG f
emitted, based on calculations, from
process vent v from production process
i during the period or batch for which
(Eq. L-25)
Where:
E = Total mass of each fluorinated GHG f
emitted from the facility, annual basis
(kg/year).
EP = Mass of fluorinated GHG f emitted from
all process vents at the facility, annually
(kg).
EEL = Mass of fluorinated GHG f emitted from
equipment leaks for pieces of equipment
for the facility, annually (kg/year).
(e) Calculate fluorinated GHG
emissions from destruction of
fluorinated GHGs that were previously
‘‘produced’’ as defined at 98.410(b).
Estimate annually the total mass of
fluorinated GHGs emitted from
destruction of fluorinated GHGs that
were previously ‘‘produced’’ as defined
at 98.410(b) using Equation L–26 of this
section:
ED = RED ∗ (1 − DE )
(Eq. L-26)
Where:
ED = The mass of fluorinated GHGs emitted
annually from destruction of fluorinated
GHGs that were previously ‘‘produced’’
as defined at 98.410(b) (metric tons).
RED = The mass of fluorinated GHGs that
were previously ‘‘produced’’ as defined at
98.410(b) and that are fed annually into
the destruction device (metric tons).
DE = Destruction efficiency of the destruction
device (fraction).
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
§ 98.124 Monitoring and QA/QC
requirements.
(a) Initial scoping test for fluorinated
GHGs. You must conduct an initial
scoping test to identify all fluorinated
GHGs that may be generated from
processes that are subject to this subpart
and that have uncontrolled emissions
(i.e., pre-control emissions levels) of 1.0
metric ton or more of fluorinated GHGs.
For each process, you must conduct the
initial scoping test on the stream(s)
(including process streams or destroyed
streams) or process vent(s) that would
be expected to individually or
collectively contain all of the
fluorinated GHG by-products of the
process. Initial scoping testing must be
conducted according to the procedures
in paragraph (c)(4)(v) of this section.
(b) Mass Balance monitoring. If you
determine fluorinated GHG emissions
using the mass balance method under
§ 98.123(a), you must estimate the total
mass of each fluorinated GHG emitted
from the process at least monthly.
(1) You must conduct the following
mass measurements on a monthly or
more frequent basis using flowmeters,
weigh scales, or a combination of
volumetric and density measurements
with accuracy and precision that allow
the facility to meet the error criteria in
§ 98.123(a):
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17:39 Apr 09, 2010
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(i) Total mass of each fluorinated GHG
produced shall be estimated using the
methods and measurements set forth in
§ 98.413(a) and (b) and in § 98.414(a)
and (b). For each fluorinated GHG, the
mass produced used for the massbalance calculation shall be the same as
the mass produced that is reported
under subpart OO.
(ii) Total mass of each reactant fed
into the production process shall be
measured.
(iii) Total mass of each reactant
permanently removed from the
production process shall be measured.
(iv) If the waste permanently removed
from the production process and fed
into the destruction device contains
more than trace concentrations of
fluorinated GHG product, then the mass
of waste fed into the destruction device
shall be measured.
(v) If a by-product is responsible for
yield loss and occurs in any stream
(including process steams, emissions
streams, or destroyed streams) in more
than trace concentrations, then the mass
flow of each stream that contains more
than trace concentrations of the byproduct shall be measured.
(vi) If a by-product is a fluorinated
GHG (other than HFC-23 generated
during HCFC-22 production), occurs in
more than trace concentrations in any
stream (including process streams,
emissions streams, or destroyed
streams), occurs in more than trace
concentrations in any stream that is
recaptured or is fed into a destruction
device, and is not completely
recaptured or completely destroyed,
then the mass flow of each stream that
contains more than trace concentrations
of the by-product and that is recaptured
or is fed into the destruction device
shall be measured.
(2) The following concentration
measurements shall be measured on a
regular basis using equipment and
methods (e.g., gas chromatography) with
an accuracy and precision that allow the
facility to meet the error criteria in
§ 98.123(a):
(i) If the waste permanently removed
from the production process and fed
into the destruction device contains
more than trace concentrations of
fluorinated GHG product and if the
stream mass includes more than trace
concentrations of materials other than
the product, then the concentration of
the product shall be measured.
(ii) If a by-product is responsible for
yield loss and occurs in any stream
(including process streams, emissions
streams, or destroyed streams) in more
than trace concentrations and if the
stream mass includes more than trace
concentrations of materials other than
PO 00000
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Sfmt 4702
the by-product, then the concentration
of the by-product shall be measured.
(iii) If a by-product is a fluorinated
GHG, occurs in more than trace
concentrations in any stream (including
process streams, emissions streams, or
destroyed streams), occurs in more than
trace concentrations in any stream that
is recaptured or is fed into a destruction
device, and is not completely
recaptured or completely destroyed, and
if the measured stream mass includes
more than trace concentrations of
materials other than the by-product,
then the concentration of the by-product
shall be measured.
(c) Emission factor testing. If you
determine fluorinated GHG emissions
using the site-specific process-ventspecific emission factor, you must meet
the requirements in paragraphs (c)(1)
through (c)(8) of this section.
(1) Process vent testing. Conduct an
emissions test every 5 years that is
based on representative performance
(i.e., performance based on the normal
operating scenario) of the affected
process. For each continuous process
vent, develop a process-vent-specific
emission factor for the representative
operating scenario. For each batch
process vent, develop a process-ventspecific emission factor for the
representative operating scenario, i.e.,
the typical batch process. Atypical
events, such as process shutdowns or
startups, may be included in the
monitoring for batch processes and may
be included for continuous process, if
the monitoring is sufficiently long or
comprehensive to ensure that such
events are not overrepresented in the
emission factor. Malfunction events
shall not be included in the monitoring.
(2) Different operating conditions.
Develop separate process-vent-specific
emission factor for other operating
scenarios as needed. If your process
operates under different conditions as
part of normal operations, you must
perform emission testing and develop
separate emission factors for these
different process operating scenarios.
For continuous process vents, determine
the emissions based on the process
activity at each specific different
condition. For batch process vents,
determine emissions based on the
process feed rate, process production
rate, or other process activity rate for
each typical batch operating scenario
(i.e., each specific condition).
(3) Number of runs. For continuous
processes, sample the process vent for a
minimum of 3 runs of 1 hour each. For
batch processes, sample the process
vent for all emission episodes over a
minimum of 3 complete batch cycles. If
the RSD of the emission factor
E:\FR\FM\12APP4.SGM
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EP12AP10.076
E = EP + EEL
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jlentini on DSKJ8SOYB1PROD with PROPOSALS4
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calculated based on the first 3 runs is
greater than or equal to 0.2 for the
emissions factor, continue to sample the
process vent for an additional 3 runs of
1 hour each or an additional 3 batch
cycles. If more than one fluorinated
GHG is measured, and if all measured
fluorinated GHGs have GWPs listed in
Table A–1, the emissions factor and
RSD shall be expressed in terms of total
CO2 equivalents. Otherwise, the
emissions factor and RSD shall be
expressed in terms of kilograms of each
species.
(4) Emission Test Methods. Conduct
the emissions testing using the
following methods:
(i) Sample and velocity traverses. Use
EPA Method 1 or 1A in Appendix A–
1 of 40 CFR part 60.
(ii) Velocity and volumetric flow
rates. Use EPA Method 2, 2A, 2B, 2C, or
2D, 2F, or 2G in Appendix A–1 of 40
CFR part 60. Alternatives that may be
used for determining flow rates include
Other Test Method 24 (OTM–24)
(incorporated by reference, see § 98.7)
and Emission Measurement Center
Alternative Test Method (EMC ALT–
012) (incorporated by reference, see
§ 98.7).
(iii) Gas analysis. Use EPA Method 3,
3A, or 3B in Appendix A–1 of 40 CFR
part 60.
(iv) Stack gas moisture. Use EPA
Method 4 in Appendix A–1 of 40 CFR
part 60.
(v) Fluorinated GHG concentrations.
Use EPA Method 18 (with GC and either
MS or ECD) in Appendix A–1 of 40 CFR
part 60; EPA Method 320 in Appendix
A of 40 CFR part 63; Draft EPA DRE
Protocol; or ASTM D6348–03
(incorporated by reference in § 98.7).
(vi) Alternative fluorinated GHG
concentration methods. Alternatives
that may be used for determining
fluorinated GHG concentrations include
EPA TO–15 or other alternative test
methods conducted in conjunction with
EPA Method 301 for validation.
(5) Process activity measurements.
Determine the mass rate of process feed,
process production, or other process
activity as applicable during the test
using flow meters, weigh scales, or other
measurement devices or instruments
with an accuracy and precision of ±1
percent of full scale or better. These
devices may be the same plant
instruments or procedures that are used
for accounting purposes (such as weigh
hoppers, belt weigh feeders,
combination of volume measurements
and bulk density, etc.) if these devices
or procedures meet the requirement. For
monitoring ongoing process activity, use
flow meters, weigh scales, or other
measurement devices or instruments
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with an accuracy and precision of ±1
percent of full scale or better.
(6) Sample each process. If process
vents from separate processes are
manifolded together to a common vent
or to a common destruction device, you
must sample each process in the ducts
before the emissions are combined,
sample when only one process is
operating, or sample the combined
emissions at representative
combinations of capacity utilizations for
all the processes. If the last option is
selected, 3 times n test runs shall be
required, where n is the number of
processes feeding into the common vent
or destruction device, and the processvent-specific emission factor shall be
applied whenever one or more of the
processes is operating. In this case,
calculate the emission factor for each
sample by dividing the total emissions
by the summed process activity across
the processes venting to the common
vent. Derive the process-vent-specific
emission factor by averaging the 3n
emission factors.
(7) Emission test results. The results
of an emission test must include the
analysis of samples, determination of
emissions, and raw data. The emissions
test report must contain all information
and data used to derive the processvent-specific emission factor, as well as
key process conditions during the test.
Key process conditions include those
that are normally monitored for process
control purposes and may include but
are not limited to yields, pressures,
temperatures, etc. (e.g., of reactor
vessels, distillation columns).
(8) Previous measurements. If you
have conducted an emissions test less
than 5 years before the effective date of
this rule, and the emissions testing
meets the requirements in paragraph
(c)(1) through (7) of this section, you
may use the previous emissions testing
to develop process-vent-specific
emission factors.
(d) Emission calculation factor
monitoring. If you determine fluorinated
GHG emissions using the site-specific
process-vent-specific emission
calculation factor, you must meet the
requirements in paragraphs (d)(1)
through (d)(3) of this section.
(1) Revise the emission calculation
factor for each process every 5 years
based on representative operation (i.e.,
performance based on the normal
operating scenario) of the affected
process. For each continuous process
vent, develop the emission calculation
factor for the representative operating
scenario. For each batch process vent,
develop the emission calculation factor
for the representative operating
scenario, i.e., the typical batch process.
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(2) Different operating conditions.
You must develop separate emissions
calculation factors for other operating
scenarios as needed. If your process
operates under different conditions as
part of normal operations, you must
conduct emissions calculations and
develop separate emission factors for
these different process operating
scenarios. For continuous process vents,
determine the emissions based on the
process activity at each specific
different condition. For batch process
vents, determine emissions based on the
process feed rate, process production
rate, or other process activity rate for
each typical batch operating scenario
and for each non-typical batch operating
scenario (i.e., each specific condition).
(3) Process activity measurements.
Use flow meters, weigh scales, or other
measurement devices or instruments
with an accuracy and precision of ±1
percent of full scale or better for
monitoring ongoing process activity.
(e) Emission monitoring for pieces of
equipment. Conduct the screening level
concentration measurements using EPA
Method 21 in 40 CFR part 60, appendix
A–7 to determine the screening level
concentration data or actual screening
level concentration data for the
Screening Ranges Approach or the EPA
Correlation Approach. Conduct the
screening level concentration
measurements using EPA Method 21
and the bagging procedures to measure
mass emissions for developing the UnitSpecific Correlation Approach in the
Protocol for Equipment Leak Emission
Estimates, U.S. Environmental
Protection Agency, EPA Publication No.
EPA–453/R–95–017, November 1995.
Concentration measurements of bagged
samples must be conducted using gas
chromatography following EPA Method
18 analytical procedures. Use methane
as the calibration gas.
(f) Destruction device performance
testing. If you vent fluorinated GHG
emissions or otherwise feed fluorinated
GHGs into a destruction device and
apply the destruction efficiency of the
device in § 98.123, you must conduct an
emissions test every 5 years to
determine the destruction efficiency.
(1) You must sample the inlet and
outlet of the destruction device for a
minimum of three runs of 1 hour each
to determine the destruction efficiency.
You must conduct the emissions testing
using the methods in paragraph (c)(4) of
this section. To determine the
destruction efficiency, emission testing
shall be conducted when operating at
high loads reasonably expected to occur
(i.e., representative of high total
fluorinated GHG load that will be sent
to the device) and when destroying the
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most-difficult-to-destroy fluorinated
GHG (or a surrogate that is still more
difficult to destroy) that is fed into the
device from the processes subject to this
subpart.
(2) Previous testing. If you have
conducted an emissions test within the
last 5 years prior to the effective date of
this rule, and the emissions testing
meets the requirements in paragraph
(f)(1) of this section, you may use the
destruction efficiency determined
during this previous emissions testing.
(3) Part 264, 266, and 270 principal
organic hazardous constituent (POHC)
testing. If a destruction device used to
destroy fluorinated GHG is subject to 40
CFR part 264 or 266 and is permitted
under 40 CFR part 270 with a
demonstrated DRE of at least 99.99
percent for the most-difficult-to-destroy
fluorinated GHG fed into the device
from the processes subject to this
subpart, the emissions testing under
paragraph (f)(1) of this section is not
required and you may use the
destruction efficiency determined
during this previous testing.
(4) Hazardous Waste Combustor
testing. If a destruction device used to
destroy fluorinated GHG is subject to 40
CFR part 63, subpart EEE and has a
demonstrated DRE of at least 99.99
percent for the most-difficult-to-destroy
fluorinated GHG fed into the device
from the processes subject to this
subpart, the emissions testing under
paragraph (f)(1) of this section is not
required and you may use the
destruction efficiency determined
during this previous testing.
(5) Process change. For process
changes that require a new or revised
operating scenario, you must determine
whether the concentrations and the
fluorinated gas compounds vented to
the destruction device following the
process change affects the DE (i.e.,
compare the post-process-change
fluorinated GHG load and the mostdifficult-to-combust fluorinated GHG
with the test conditions). If the
operating conditions and DE
demonstrated in the destruction device
performance testing are not sufficient to
achieve the DE for the concentrations
and fluorinated gas compounds vented
to the destruction device following the
process change then, you must conduct
another emissions test to demonstrate
the DE.
(g) Mass of previously produced
fluorinated GHGs fed into destruction
device. You must measure the mass of
fluorinated GHGs that are fed into the
destruction device and that were
previously produced as defined at
98.410(b). Such fluorinated GHGs
include but are not limited to quantities
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that are shipped to the facility by
another facility for destruction and
quantities that are returned to the
facility for reclamation but are found to
be irretrievably contaminated and are
therefore destroyed. You must use
flowmeters, weigh scales, or a
combination of volumetric and density
measurements with an accuracy and
precision of 1 percent of full scale or
better. If the measured mass includes
more than trace concentrations of
materials other than the fluorinated
GHG being destroyed, you must
measure the concentrations of
fluorinated GHG being destroyed. You
must multiply this concentration (mass
fraction) by the mass measurement to
obtain the mass of the fluorinated GHG
fed into the destruction device.
(h) Emissions due to deviations of
destruction device. In their estimates of
the mass of fluorinated GHG destroyed,
fluorinated GHG production facilities
that destroy fluorinated GHGs shall
account for any temporary reductions in
the destruction efficiency that result
from any malfunctions of the
destruction device, including deviations
from the operating conditions defined in
State or local permitting requirements
and/or oxidizer manufacturer
specifications.
(i) Emissions due to process startup,
shutdown, or malfunctions. Fluorinated
GHG production facilities shall account
for fluorinated GHG emissions that
occur as a result of startups, shutdowns,
and malfunctions, either recording
fluorinated GHG emissions during these
events, or documenting that these
events do not result in significant
fluorinated GHG emissions.
(j) Initial scoping testing, emissions
testing, and emissions factor
development must be completed by
December 31, 2011.
(k) Calibrate all flow meters, weigh
scales, and combinations of volumetric
and density measures using monitoring
instruments traceable to the
International System of Units (SI)
through the National Institute of
Standards and Technology (NIST) or
other recognized national measurement
institute. Recalibrate all flow meters,
weigh scales, and combinations of
volumetric and density measures at the
minimum frequency specified by the
manufacturer. Use any of the following
applicable flow meter test methods or
the calibration procedures specified by
the flow meter, weigh-scale, or other
volumetric or density measure
manufacturer.
(1) ASME MFC–3M–2004,
Measurement of Fluid Flow in Pipes
Using Orifice, Nozzle, and Venturi
(incorporated by reference, see § 98.7).
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(2) ASME MFC–4M–1986 (Reaffirmed
1997), Measurement of Gas Flow by
Turbine Meters (incorporated by
reference, see § 98.7).
(3) ASME–MFC–5M–1985,
(Reaffirmed 1994), Measurement of
Liquid Flow in Closed Conduits Using
Transit-Time Ultrasonic Flowmeters
(incorporated by reference, see § 98.7).
(4) ASME MFC–6M–1998,
Measurement of Fluid Flow in Pipes
Using Vortex Flowmeters (incorporated
by reference, see § 98.7).
(5) ASME MFC–7M–1987 (Reaffirmed
1992), Measurement of Gas Flow by
Means of Critical Flow Venturi Nozzles
(incorporated by reference, see § 98.7).
(6) ASME MFC–9M–1988 (Reaffirmed
2001), Measurement of Liquid Flow in
Closed Conduits by Weighing Method
(incorporated by reference, see § 98.7).
(7) ASME MFC–11M–2006,
Measurement of Fluid Flow by Means of
Coriolis Mass Flowmeters (incorporated
by reference, see § 98.7).
(8) ASME MFC–14M–2003,
Measurement of Fluid Flow Using Small
Bore Precision Orifice Meters
(incorporated by reference, see § 98.7).
(l) All analytical equipment,
including gas chromatographs, GC/MS,
GC/ECD, FTIR and NMR devices, used
to determine the concentration of
fluorinated GHG in streams shall be
calibrated at least monthly through
analysis of certified standards with
known concentrations of the same
chemicals in the same ranges (fractions
by mass) as the process samples.
Calibration gases prepared from a highconcentration certified standard using a
gas dilution system that meets the
requirements specified in Method 205,
40 CFR Part 51, Appendix M may also
be used.
(m) For calendar year 2011
monitoring, you may follow the
provisions of § 98.3(d)(1) through (3) for
best available monitoring methods
rather than follow the monitoring
requirements of this section. For
purposes of subpart L, any reference to
the year 2010 in § 98.3(d)(1) through (3)
shall mean 2011.
§ 98.125 Procedures for estimating
missing data.
(a) A complete record of all measured
parameters used in the GHG emissions
calculations in § 98.123 is required.
Therefore, whenever a quality-assured
value of a required parameter is
unavailable, a substitute data value for
the missing parameter shall be used in
the calculations as specified in
paragraphs (b) and (c) of this section.
You must document and keep records of
the procedures used for all such
estimates.
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(b) For each missing value of the
fluorinated GHG concentration, the
substitute data value shall be the
arithmetic average of the quality-assured
values of that parameter immediately
preceding and immediately following
the missing data incident.
(c) For each missing value of the mass
produced, fed into the production
process, fed into the transformation
process, fed into destruction devices,
sent to another facility for
transformation, or sent to another
facility for destruction, the substitute
value of that parameter shall be a
secondary mass measurement where
such a measurement is available. For
example, if the mass produced is
usually measured with a flowmeter at
the inlet to the day tank and that
flowmeter fails to meet an accuracy or
precision test, malfunctions, or is
rendered inoperable, then the mass
produced may be estimated by
calculating the change in volume in the
day tank and multiplying it by the
density of the product. Where a
secondary mass measurement is not
available, the substitute value of the
parameter shall be an estimate based on
a related parameter. For example, if a
flowmeter measuring the mass fed into
a destruction device is rendered
inoperable, then the mass fed into the
destruction device may be estimated
using the production rate and the
previously observed relationship
between the production rate and the
mass flow rate into the destruction
device.
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§ 98.126
Data reporting requirements.
(a) All facilities. In addition to the
information required by § 98.3(c), you
shall report the following information.
(1) The chemical identities of the
contents of the stream(s) (including
process, emissions, and destroyed
streams) analyzed under the initial
scoping test of fluorinated GHG at
§ 98.124(a), by process.
(2) The location and function of the
stream(s) (including process streams,
emissions streams, and destroyed
streams) that were analyzed under the
initial scoping test of fluorinated GHG at
§ 98.124(a), by process.
(3) The annual emissions of each
fluorinated GHG by process, for
equipment leaks, and for the facility as
a whole.
(4) The method used to determine the
mass emissions of each fluorinated
GHG, i.e., mass balance, process-ventspecific emission factor, or processvent-specific emission calculation
factor, for each process and process vent
at the facility.
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(5) The chemical formula and total
mass produced of the fluorinated gas
product in metric tons, by chemical and
process.
(b) Reporting for mass balance
approach. For processes whose
emissions are determined using the
mass-balance approach under
§ 98.123(a), you shall report the
following for each process:
(1) The absolute and relative
uncertainties calculated under
paragraphs § 98.123(a)(1) through (a)(4),
as well as the data (including quantities
and their uncertainties) used in these
calculations.
(2) The balanced chemical equation
that describes the reaction used to
manufacture the fluorinated GHG
product (specifically, the equation that
provides the stoichiometric coefficients
in Equation L–7 of this subpart).
(3) The total mass and chemical
formula of each reactant fed into the
production process in metric tons, by
chemical.
(4) The total mass of each reactant
permanently removed from the
production process in metric tons, by
chemical.
(5) The total mass of the fluorinated
GHG product removed from the
production process and destroyed.
(6) The mass and chemical formula of
each by-product generated.
(7) The mass of each by-product
destroyed at the facility.
(9) The mass of each by-product
recaptured and sent off-site for
destruction.
(10) The mass of each by-product
recaptured for other purposes.
(c) Reporting for emission factor and
emission calculation factor approach.
For processes whose emissions are
determined using the emission factor
approach under § 98.123(b)(3) or the
emission calculation factor under
§ 98.123(b)(4), you shall report the
following for each process:
(1) The process activity used to
estimate emissions (e.g., tons of product
produced or tons of reactant consumed).
(2) The site-specific, process-ventspecific emission factor or emission
calculation factor for each process vent.
(3) The mass of each fluorinated GHG
emitted, including the mass of each
fluorinated GHG emitted from
equipment leaks.
(d) Reporting for missing data. Where
missing data have been estimated
pursuant to § 98.125, you shall report
the reason the data were missing, the
length of time the data were missing, the
method used to estimate the missing
data, and the estimates of those data.
(e) Reporting of destruction device
monitoring data. A fluorinated GHG
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production facility that destroys
fluorinated GHGs shall report the
monitoring results for the destruction
device that are deviations from the
monitoring limit set (e.g., parametric
monitoring of incinerator temperature,
outlet concentration checks, etc.) during
the emissions test.
(f) Reporting of destruction device
testing. A fluorinated GHG production
facility that destroys fluorinated GHGs
shall submit the emissions test report
for the emission test conducted every 5
years. The emissions testing report must
contain the following information:
(1) Destruction efficiency (DE) of each
destruction unit for each fluorinated
GHG, or if a surrogate was used, the DE
of the surrogate.
(2) Test methods used to determine
the destruction efficiency.
(3) Methods used to record the mass
of fluorinated GHG destroyed.
(4) Chemical identity of the
fluorinated GHG(s) used in the
performance test conducted to
determine DE, including surrogates, and
information on why the surrogate is
sufficient to demonstrate DE for all
fluorinated GHG vented to the
destruction unit.
(5) Name of all applicable Federal or
State regulations that may apply to the
destruction process.
(6) If process changes affect the
destruction efficiency of the destruction
device or the methods used to record
mass of fluorinated GHG destroyed,
then the revised emission testing report
must be submitted to reflect the
changes. The revised report must be
submitted to EPA within 60 days of the
change.
(g) Reporting for destruction of
previously produced fluorinated GHGs.
A fluorinated GHG production facility
that destroys fluorinated GHGs shall
report the following for each previously
produced fluorinated GHG destroyed:
(1) The mass of the fluorinated GHG
fed into the destruction device.
(2) The mass of the fluorinated GHG
emitted from the destruction device.
§ 98.127
Records that must be retained.
In addition to the records required by
§ 98.3(g), you must retain the dated
records specified in paragraphs (a)
through (h) of this section, as
applicable.
(a) Process information records.
(1) Identify all products and processes
subject to this subpart. Include the unit
identification as appropriate.
(2) Monthly and annual records of all
analyses and calculations conducted,
including all information reported as
required under §§ 98.123 and 98.126.
(b) Emission factor and emission
calculation factor method. Retain the
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following records for each process at the
facility.
(1) Identify all process vents above
and below the 10,000 metric tons CO2e
per year uncontrolled emission limit for
fluorinated GHG.
(2) For vents above the 10,000 metric
tons CO2e per year uncontrolled
emission limit, identify those that vent
to a destruction device demonstrated to
achieve a destruction efficiency of 99.9
percent for fluorinated GHGs, and for
which the facility has equipment (e.g.,
holding tank capacity; monitoring of bypass streams) or procedures (e.g.,
compulsory process shutdowns) in
place that ensure that uncontrolled
emissions do not occur.
(3) For each vent, identify the method
used to develop the factor (i.e., emission
factor by emissions test or emissions
calculation factor).
(4) The emissions test data and
reports and the calculations used to
determine the process-vent-specific
emissions factor, including the actual
process-vent-specific emission factor,
the average hourly fluorinated GHG
emission rate from the process vent
during the test or the average
fluorinated GHG emissions per batch
and the process feed rate, process
production rate, or other process
activity rate during the test.
(5) The calculations used to determine
the process-vent-specific emissions
calculation factor and the actual
emissions calculation factor.
(6) The ongoing monthly, campaign,
or batch process production quantity
and annual process production quantity
or other process activity information in
the appropriate units, along with the
dates and time period during which the
process was operating.
(7) For continuous processes, identify
whether the process was representative
or whether it was another operating
scenario. For batch processes, identify
whether each batch operated was
considered a typical batch or whether it
was another operating scenario. For
both continuous and batch processes,
identify and provide the measurements
during the test of the key process
parameters that define the operating
scenario (e.g., process equipment,
process vents, destruction device)).
(8) Calculations used to determine
annual emissions of each fluorinated
GHG for each process and the total
fluorinated GHG emissions for all
processes, i.e., total for facility.
(9) The dates and time periods when
the process vent emissions from a
campaign or batch were vented to the
destruction device.
(c) Missing data records. Where
missing data have been estimated
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pursuant to § 98.125, you shall record
the reason the data were missing, the
length of time the data were missing, the
method used to estimate the missing
data, and the estimates of those data.
(d) 5-year process vent emission
testing. A fluorinated GHG production
facility that conducts process vent
emission testing to determine processvent-specific emission factor for
fluorinated GHGs shall retain the results
of the emission testing, including data
in § 98.124(c)(7) and:
(1) Test methods used to determine
the flow rate and fluorinated GHG
concentrations of the process vent
stream.
(2) Flow rate of fluorinated GHG
stream.
(3) Concentration (mass fraction) of
each fluorinated GHG.
(4) Emission factor calculated from
paragraph (b)(4) of this section in metric
tons per activity.
(e) 5-year destruction efficiency
testing. A fluorinated GHG production
facility that destroys fluorinated GHGs
shall retain the emissions performance
testing report containing the following
information:
(1) Destruction efficiency (DE) of each
destruction device.
(2) Test methods used to determine
the destruction efficiency.
(3) Methods used to record the mass
of fluorinated GHG destroyed.
(4) Chemical identity of the
fluorinated GHG(s) used in the
performance test conducted to
determine DE.
(5) Name of all applicable Federal or
State regulations that may apply to the
destruction process.
(6) If process changes affect the
destruction efficiency of the destruction
device or the methods used to record
mass of fluorinated GHG destroyed,
then the revised emission testing report
must be submitted to reflect the
changes. The revised report must be
submitted to EPA within 60 days of the
change.
(7) Records of test reports and other
information documenting the facility’s
five-year destruction efficiency report in
§ 98.126(e) and (g).
(f) Equipment leak records. If you are
subject to § 98.123(c) of this subpart,
you must maintain information on the
number of each type of equipment; the
service of each piece of equipment (gas,
light liquid, heavy liquid); the
concentration of each fluorinated GHG
in the stream; the time period each
piece of equipment was in service, and
the emission calculations for each
fluorinated GHG for all processes.
Depending on which equipment leak
monitoring approach you follow, you
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must maintain information for
equipment on the associated screening
data concentrations for greater than or
equal to 10,000 ppmv and associated
screening data concentrations for less
than 10,000 ppmv; associated actual
screening data concentrations; and
associated screening data and leak rate
data (i.e., bagging) used to develop a
unit-specific correlation.
(g) All facilities. Dated records
documenting the initial and periodic
calibration of the gas chromatographs,
GC/MS, GC/ECD, FTIR, and NMR
devices, weigh scales, flowmeters, and
volumetric and density measures used
to measure the quantities reported
under this subpart, including the
industry standards or manufacturer
directions used for calibration pursuant
to § 98.124(c), (e), (f), (k) and (l).
§ 98.128
Definitions.
Except as provided below, all of the
terms used in this subpart have the
same meaning given in the Clean Air
Act and subpart A of this part. If a
conflict exists between a definition
provided in this subpart and a
definition provided in subpart A, the
definition in this subpart shall take
precedence for the reporting
requirements in this subpart.
Batch process or batch operation
means a noncontinuous operation
involving intermittent or discontinuous
feed into equipment, and, in general,
involves the emptying of the equipment
after the batch operation ceases and
prior to beginning a new operation.
Addition of raw material and
withdrawal of product do not occur
simultaneously in a batch operation.
Batch emission episode means a
discrete venting episode associated with
a vessel in a process; a vessel may have
more than one batch emission episode.
For example, a displacement of vapor
resulting from the charging of a vessel
with a feed material will result in a
discrete emission episode that will last
through the duration of the charge and
will have an average flow rate equal to
the rate of the charge. If the vessel is
then heated, there will also be another
discrete emission episode resulting from
the expulsion of expanded vapor. Other
emission episodes also may occur from
the same vessel and other vessels in the
process, depending on process
operations.
Completely destroyed means
destroyed with a destruction efficiency
of 99.99 percent or greater.
Completely recaptured means 99.99
percent or greater of each fluorinated
GHG is removed from a stream.
Continuous process or operation
means a process where the inputs and
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outputs flow continuously throughout
the duration of the process. Continuous
processes are typically steady state.
Destruction process means a process
used to destroy fluorinated GHG in a
destruction device such as a thermal
incinerator or catalytic oxidizer.
Equipment (for the purposes of 40
CFR part 98, subpart L only) means each
pump, compressor, agitator, pressure
relief device, sampling connection
system, open-ended valve or line, valve,
connector, and instrumentation system
in fluorinated GHG service for a process
subject to this subpart; and any
destruction devices or closed-vent
systems to which processes subject to
this subpart are vented.
Fluorinated gas means any
fluorinated GHG, CFC, or HCFC.
In fluorinated GHG service means that
a piece of equipment either contains or
contacts a feedstock, byproduct, or
product that contains fluorinated GHG.
Isolated intermediate means a product
of a process that is stored before
subsequent processing. An isolated
intermediate is usually a product of
chemical synthesis. Storage of an
isolated intermediate marks the end of
a process. Storage occurs at any time the
intermediate is placed in equipment
used solely for storage.
Operating scenario means any
specific operation of a process and
includes for each process: (1) A
description of the process and the
specific process equipment used; (2) An
identification of related process vents,
their associated emissions episodes and
durations, and calculations and
engineering analyses to show the annual
uncontrolled fluorinated GHG emissions
from the process vent; (3) The control or
destruction devices used, as applicable,
including a description of operating
and/or testing conditions for any
associated destruction device; (4) The
process vents (including those from
other processes) that are simultaneously
routed to the control or destruction
device(s); and (5) The applicable
monitoring requirements and any
parametric level that assures destruction
or removal for all emissions routed to
the control or destruction device. A
change to any of these elements not
previously reported, except for item (4)
of this definition, shall constitute a
different operating scenario.
Process means all equipment which
collectively function to produce a
fluorinated gas product, including an
isolated intermediate (which is also a
fluorinated gas product), or to transform
a fluorinated gas product. A process
may consist of one or more unit
operations. For the purposes of this
subpart, process includes any, all, or a
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combination of reaction, recovery,
separation, purification, or other
activity, operation, manufacture, or
treatment which are used to produce a
fluorinated gas product. For a
continuous process, cleaning operations
conducted may be considered part of
the process, at the discretion of the
facility. For a batch process, cleaning
operations are part of the process.
Ancillary activities are not considered a
process or part of any process under this
subpart. Ancillary activities include
boilers and incinerators, chillers and
refrigeration systems, and other
equipment and activities that are not
directly involved (i.e., they operate
within a closed system and materials are
not combined with process fluids) in the
processing of raw materials or the
manufacturing of a fluorinated gas
product.
Process condenser means a condenser
whose primary purpose is to recover
material as an integral part of a process.
All condensers recovering condensate
from a process vent at or above the
boiling point or all condensers in line
prior to a vacuum source are considered
process condensers. Typically, a
primary condenser or condensers in
series are considered to be integral to
the process if they are capable of and
normally used for the purpose of
recovering chemicals for fuel value (i.e.,
net positive heating value), use, reuse or
for sale for fuel value, use, or reuse.
Process vent (for the purposes of 40
CFR part 98, subpart L only) means a
vent from a process vessel or vents from
multiple process vessels within a
process that are manifolded together
into a common header, through which
a fluorinated GHG-containing gas stream
is, or has the potential to be, released to
the atmosphere. Examples of process
vents include, but are not limited to,
vents on condensers used for product
recovery, bottoms receivers, surge
control vessels, reactors, filters,
centrifuges, and process tanks. Process
vents do not include vents on storage
tanks or pieces of equipment.
Typical batch means a batch process
operated within a range of operating
conditions that are documented in an
operating scenario. Emissions from a
typical batch are based on the operating
conditions that result in representative
emissions. The typical batch defines the
uncontrolled emissions for each
emission episode defined under the
operating scenario.
Uncontrolled fluorinated GHG
emissions means a gas stream
containing fluorinated GHG which has
exited the process (or process
condenser, where applicable), but
which has not yet been introduced into
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a destruction device to reduce the mass
of fluorinated GHG in the stream. If the
emissions from the process are not
routed to a destruction device,
uncontrolled emissions are those
fluorinated GHG emissions released to
the atmosphere.
5. Add subpart QQ to read as follows:
Subpart QQ—Importers and Exporters of
Fluorinated Greenhouse Gases Contained
in Pre-Charged Equipment or Closed-Cell
Foams
Sec.
98.430 Definition of the source category.
98.431 Reporting threshold.
98.432 GHGs to report.
98.433 Calculating GHG emissions.
98.434 Monitoring and QA/QC
requirements.
98.435 Procedures for estimating missing
data.
98.436 Data reporting requirements.
98.437 Records that must be retained.
98.438 Definitions.
Subpart QQ—Importers and Exporters
of Fluorinated Greenhouse Gases
Contained in Pre-Charged Equipment
or Closed-Cell Foams
§ 98.430
Definition of the source category.
(a) The source category, importers and
exporters of fluorinated GHGs contained
in pre-charged equipment or closed-cell
foams, consists of the following
suppliers: any entity that is importing or
exporting pre-charged equipment that
contains a fluorinated GHG, and any
entity that is importing or exporting
closed-cell foams that contain a
fluorinated GHG.
§ 98.431
Reporting threshold.
Any importer or exporter of
fluorinated GHGs contained in precharged equipment or closed-cell foams
who meets the requirements of
§ 98.2(a)(4) must report each fluorinated
GHG contained in the imported or
exported pre-charged equipment or
closed-cell foams.
§ 98.432
GHGs to report.
You must report the quantity of each
fluorinated GHG contained in precharged equipment or closed-cell foams
that you import or export during the
calendar year.
§ 98.433 Calculating GHG contained in
pre-charged equipment or closed-cell
foams.
(a) The total mass of each fluorinated
GHG imported and exported inside
equipment or foams shall be estimated
using Equation QQ–1 of this section:
I = ∑ St ∗ Nt ∗ 0.001
(Eq. QQ-1)
t
Where:
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Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
I = Total mass of the fluorinated GHG
imported or exported by the entity
annually (metric tons)
t = Type of equipment/foam containing the
fluorinated GHG
St = Mass of fluorinated GHG per unit of
equipment or foam type t (charge per
piece of equipment or kg/cubic foot of
foam, kg)
Nt = Number of units of equipment or foam
type t imported or exported annually
(pieces of equipment or cubic feet of
foam)
0.001 = Factor converting kg to metric tons
§ 98.434 Monitoring and QA/QC
requirements.
(a) For calendar year 2011 monitoring,
you may follow the provisions of
§ 98.3(d)(1) through (d)(3) for best
available monitoring methods rather
than follow the monitoring
requirements of this section. For
purposes of this subpart, any reference
to the year 2010 in § 98.3(d)(1) through
(3) shall mean 2011.
(b) The inputs to the annual
submission shall be reviewed against
the import or export transaction records
to ensure that the information submitted
to EPA is being accurately transcribed as
the correct chemical or blend in the
correct pre-charged equipment or
closed-cell foam in the correct
quantities (metric tons) and units (cubic
feet and kg/cubic foot).
§ 98.435 Procedures for estimating
missing data.
Procedures for estimating missing
data are not provided for importers and
exporters of fluorinated GHGs contained
in pre-charged equipment or closed-cell
foams. A complete record of all
measured parameters used in tracking
fluorinated GHGs contained in precharged equipment or closed-cell foams
is required.
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
§ 98.436
Data reporting requirements.
(a) Each importer of fluorinated GHGs
contained in pre-charged equipment or
closed-cell foams shall submit an
annual report that summarizes its
imports at the corporate level, except for
transshipments, as specified:
(1) Total mass in metric tons of each
fluorinated GHG imported in precharged equipment or closed-cell foams.
(2) For each type of pre-charged
equipment, the identity of the
fluorinated GHG used as a refrigerant or
electrical insulator, charge size (holding
charge, if applicable), and number
imported.
(3) For closed-cell foams that are
imported inside of appliances, the
identity of the fluorinated GHG
contained in the foam, the quantity of
fluorinated GHG contained in the foam
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in each appliance, and the number of
appliances imported for each type of
appliance.
(4) For imported closed cell-foams
that are not imported inside of
appliances, the identity of the
fluorinated GHG, the density of the
fluorinated GHG in the foam (kg
fluorinated GHG/cubic foot), and the
quantity of foam imported (cubic feet)
for each type of closed-cell foam.
(5) Dates on which the pre-charged
equipment or closed-cell foams were
imported.
(6) Ports of entry through which the
pre-charged equipment or closed-cell
foams passed.
(7) Countries from which the precharged equipment or closed-cell foams
were imported.
(b) Each exporter of fluorinated GHGs
contained in pre-charged equipment or
closed-cell foams shall submit an
annual report that summarizes its
exports at the corporate level, except for
transshipments, as specified:
(1) Total mass in metric tons of each
fluorinated GHG exported in precharged equipment or closed-cell foams.
(2) For each type of pre-charged
equipment, the identity of the
fluorinated GHG used as a refrigerant or
electrical insulator, charge size
(including holding charge, if
applicable), and number exported. (3)
For closed-cell foams that are exported
inside of appliances, the identity of the
fluorinated GHG contained in the foam,
the quantity of fluorinated GHG
contained in the foam in each
appliance, and the number of
appliances exported for each type of
appliance.
(4) For exported closed cell-foams that
are not exported inside of appliances,
the identity of the fluorinated GHG, the
density of the fluorinated GHG in the
foam (kg fluorinated GHG/cubic foot),
and the quantity of foam exported
(cubic feet) for each type of closed-cell
foam.
(5) Dates on which the pre-charged
equipment or closed-cell foams were
exported.
(6) Ports of exit through which the
pre-charged equipment or closed-cell
foams passed.
(7) Countries to which the precharged equipment or closed-cell foams
were exported.
§ 98.437
Records that must be retained.
(a) In addition to the data required by
§ 98.3(g), importers of fluorinated-GHGs
in pre-charged equipment and closedcell foams shall retain the following
records substantiating each of the
imports that they report:
(1) A copy of the bill of lading for the
import.
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18721
(2) The invoice for the import.
(3) The U.S. Customs entry form.
(b) In addition to the data required by
§ 98.3(g), exporters of fluorinated GHGs
in pre-charged equipment and closedcell foams shall retain the following
records substantiating each of the
exports that they report:
(1) A copy of the bill of lading for the
export and
(2) The invoice for the export.
(c) Persons who transship pre-charged
equipment and closed cell foams
containing fluorinated GHGs shall
maintain records that indicated that the
pre-charged equipment or foam
originated in a foreign country and was
destined for another foreign country and
did not enter into commerce in the
United States.
§ 98.438
Definitions.
Except as provided below, all of the
terms used in this subpart have the
same meaning given in the Clean Air
Act and subpart A of this part. If a
conflict exists between a definition
provided in this subpart and a
definition provided in subpart A, the
definition in this subpart shall take
precedence for the reporting
requirements in this subpart.
Appliance means any device which
contains and uses a fluorinated
greenhouse gas refrigerant and which is
used for household or commercial
purposes, including any air conditioner,
refrigerator, chiller, or freezer.
Closed cell foam means any foam
product constructed with a closed cell
structure and a blowing agent
containing a fluorinated GHG, including
but not limited to polyurethane (PU)
appliance foam, PU continuous and
discontinuous panel foam, PU one
component foam, PU spray foam,
extruded polystyrene (XPS) boardstock
foam, and XPS sheet foam.
Electrical Equipment means gasinsulated substations, circuit breakers,
other switchgear, gas-insulated lines, or
power transformers.
Fluorinated GHG refrigerant means,
for purposes of this subpart, any
substance consisting in part or whole of
a fluorinated greenhouse gas and that is
used for heat transfer purposes and
provides a cooling effect.
Pre-charged appliance means any
appliance charged with fluorinated
greenhouse gas refrigerant prior to sale
or distribution or offer for sale or
distribution in interstate commerce.
This includes both appliances that
contain the full charge necessary for
operation and appliances that contain a
partial ‘‘holding’’ charge of the
fluorinated greenhouse gas refrigerant
(e.g., for shipment purposes).
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Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
Subpart SS—Sulfur Hexafluoride and
Perfluorocarbons From Electrical
Equipment Manufacture or
Refurbishment
§ 98.450
Definition of the source category.
The electrical equipment
manufacturing category consists of
processes that manufacture or refurbish
gas-insulated substations, circuit
breakers, other switchgear, gas-insulated
lines, or power transformers (including
gas-containing components of such
equipment) containing sulfurhexafluoride (SF6) or perfluorocarbons
(PFCs).
§ 98.452
GHGs to report.
(a) You must report annual SF6 and
PFC emissions (including emissions
from equipment testing, manufacturing,
decommissioning and disposal,
refurbishing, and from storage cylinders
and other containers) from any facility
associated with the manufacture or
refurbishment of closed-pressure and
sealed-pressure equipment (including
components of such equipment).
(b) You must report CO2, N2O and
CH4 combustion-related emissions from
each stationary combustion unit. You
must calculate and report these
emissions under subpart C of this part
(General Stationary Fuel Combustion
Sources) by following the requirements
of subpart C.
§ 98.453
Calculating GHG emissions.
(a) For each electrical equipment
manufacturer, you must estimate the
annual SF6 and PFC emissions using the
mass-balance approach in Equation SS–
1 of this section:
User Emissions = ( Decrease in SF6 Inventory ) + ( Acquisitions of SF6 ) − ( Disbursements of SF6 )
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
Where:
Decrease in SF6 Inventory = (SF6 stored in
containers at the beginning of the year)—
(SF6 stored in containers at the end of
the year).
Acquisitions of SF6 = (SF6 purchased from
chemical producers or distributors in
bulk) + (SF6 returned by equipment users
or distributors in equipment or
containers) + (SF6 returned to site after
off-site recycling).
Disbursements of SF6 = (SF6 contained in
new equipment delivered to customers)
+ (SF6 delivered to equipment users in
containers) + (SF6 returned to suppliers)
+ (SF6 sent off site for recycling) + (SF6
sent to destruction facilities).
(b) The mass-balance method in
paragraph (a) of this section shall be
used to estimate emissions of PFCs
associated with the manufacture or
refurbishment of power transformers,
substituting the relevant PFC(s) for SF6
in Equation SS–1.
(c) The disbursements of SF6 or PFCs
to customers in new equipment or
cylinders shall be estimated using
Equation SS–2 of this section:
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DGHG =
n
∑ Qp
(Eq. SS-2)
p =1
Where:
DGHG = The disbursement of SF6 or PFCs
over the period to customers in new
equipment or cylinders.
Qp = The mass of the SF6 or PFCs charged
into equipment or containers over the
period p sent to customers or sent off-site
for other purposes including for
recycling, for destruction or to be
returned to suppliers.
n = The number of periods in the year.
(d) The mass of SF6 or PFCs disbursed
to customers in new equipment or
cylinders over the period p may be
estimated by monitoring the mass flow
of the SF6 or PFCs into the new
equipment or cylinders using a flow
meter or by weighing containers before
and after gas from containers is used to
fill equipment or cylinders.
(e) If the mass of SF6 or the PFC
disbursed to customers in new
equipment or cylinders over the period
p is estimated by weighing containers
before and after gas from containers is
used to fill equipment or cylinders, this
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(Eq. SS-1)
quantity shall be estimated by using
Equation SS–3 of this section:
Qp = M B − M E − EL
(Eq. SS-3)
Where:
Qp = The mass of SF6 or the PFC disbursed
to customers over the period p.
MB = The mass of the contents of the
containers used to fill equipment or
cylinders at the beginning of period p.
ME = The mass of the contents of the
containers used to fill equipment or
cylinders at the end of period p.
EL = The mass of SF6 or the PFC emitted
during the period p downstream of the
containers used to fill equipment or
cylinders (e.g., emissions from hoses or
other flow lines that connect the
container to the equipment or cylinder
that is being filled).
(f) If the mass of SF6 or the PFC
disbursed to customers in new
equipment or cylinders over the period
p is determined using a flow meter, this
quantity shall be estimated using
Equation SS–4 of this section:
Qp = M mr − EL
Where:
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(Eq. SS-4)
EP12AP10.081
Sec.
98.450 Definition of the source category.
98.451 Reporting threshold.
98.452 GHGs to report.
98.453 Calculating GHG emissions.
98.454 Monitoring and QA/QC
requirements.
98.455 Procedures for estimating missing
data.
98.456 Data reporting requirements.
98.457 Records that must be retained.
98.458 Definitions
Reporting threshold.
You must report GHG emissions
under this subpart if your facility
contains an electrical equipment
manufacturing process and the facility
meets the requirements of either
§ 98.2(a)(1) or (a)(2).
EP12AP10.080
Subpart SS—Sulfur Hexafluoride and
Perfluorocarbons From Electrical
Equipment Manufacture or Refurbishment
§ 98.451
EP12AP10.079
6. Add subpart SS to read as follows:
EP12AP10.078
Pre-charged appliance component
means any portion of an appliance,
including but not limited to condensers,
compressors, line sets, and coils, that is
charged with fluorinated greenhouse gas
refrigerant prior to sale or distribution
or offer for sale or distribution in
interstate commerce.
Pre-charged equipment means any
pre-charged appliance, pre-charged
appliance component, pre-charged
electrical equipment, or pre-charged
electrical equipment component.
Pre-charged electrical equipment
means any electrical equipment,
including but not limited to gasinsulated substations, circuit breakers,
other switchgear, gas-insulated lines, or
power transformers containing a
fluorinated GHG prior to sale or
distribution, or offer for sale or
distribution in interstate commerce.
This includes both equipment that
contain the full charge necessary for
operation and equipment that contain a
partial ‘‘holding’’ charge of the
fluorinated GHG (e.g., for shipment
purposes).
Pre-charged electrical equipment
component means any portion of
electrical equipment that is charged
with SF6 or PFCs prior to sale or
distribution or offer for sale or
distribution in interstate commerce.
Federal Register / Vol. 75, No. 69 / Monday, April 12, 2010 / Proposed Rules
Qp = The mass of SF6 or the PFC disbursed
to customers over the period p.
Mmr = The mass of the SF6 or the PFC that
has flowed through the flow meter
during the period p.
EL = The mass of SF6 or the PFC emitted
downstream of the flowmeter during the
period p (e.g., emissions from hoses or
other flow lines that connect the
container to the equipment that is being
filled).
jlentini on DSKJ8SOYB1PROD with PROPOSALS4
§ 98.454 Monitoring and QA/QC
requirements.
(a) For calendar year 2011 monitoring,
you may follow the provisions of
§ 98.3(d)(1) through (d)(3) for best
available monitoring methods rather
than follow the monitoring
requirements of this section. For
purposes of subpart SS any reference to
the year 2010 in § 98.3(d)(1) through
(d)(3) shall mean 2011.
(b) Ensure that all the quantities
required by the equations of this subpart
have been measured using scales or flow
meters that are certified with an
accuracy and precision to within one
percent of the true mass or weight or
better, and is periodically recalibrated
per the manufacturer’s specifications.
Account for the tare weights of the
containers. Either measure new or
residual gas (the amount of gas
remaining in returned cylinders) or have
the gas supplier measure them. If the gas
supplier weighs the new or residual gas,
obtain from the gas supplier a detailed
monthly accounting, within 1 percent,
of new or residual gas amounts in the
cylinders returned to the gas supplier.
You remain responsible for the accuracy
of these masses and weights under this
subpart.
(c) For purposes of Equations SS–3
and SS–4 of this subpart, the mass of
SF6 or the PFC emitted downstream of
the container or flowmeter during the
period p shall be estimated using
measurements and/or engineering
assessments or calculations based on
chemical engineering principles or
physical or chemical laws or properties.
Such assessments or calculations may
be based on, as applicable, the internal
volume of hose or line that is open to
the atmosphere during coupling and
decoupling activities, the internal
pressure of the hose or line, the time the
hose or line is open to the atmosphere
during coupling and decoupling
activities, the frequency with which the
hose or line is purged and the flow rate
during purges. The estimated mass of
SF6 or the PFC emitted downstream of
the container or flowmeter during the
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period p shall include unexpected or
accidental losses.
(d) Calibrate all flow meters, weigh
scales, and combinations of volumetric
and density measures that are used to
measure or calculate quantities that are
to be reported under this subpart prior
to the first year for which GHG
emissions are reported under this part.
Calibrations performed prior to the
effective date of this rule satisfy this
requirement. Recalibrate all flow meters,
weigh scales, and combinations of
volumetric and density measures at the
minimum frequency specified by the
manufacturer. Use National Institute of
Standards and Technology-traceable
standards and suitable methods
published by a consensus standards
organization (e.g., ASTM, ASME, ISO,
or others).
(e) Ensure the following QA/QC
methods are employed throughout the
year:
(1) Ensure that procedures are in
place and followed to track and weigh
all cylinders or other containers at the
beginning and end of the year.
(2) Ensure all domestic electrical
equipment manufacturing locations
have provided information to the
manager compiling the emissions report
(if it is not already handled through an
electronic inventory system).
(f) You must adhere to the following
QA/QC methods for reviewing the
completeness and accuracy of reporting:
(1) Review inputs to Equation SS–1 of
this subpart to ensure inputs and
outputs to the company’s system are
included.
(2) Do not enter negative inputs and
confirm that negative emissions are not
calculated. However, the decrease in
SF6 inventory may be calculated as
negative.
(3) Ensure that beginning-of-year
inventory matches end-of-year
inventory from the previous year.
(4) Ensure that in addition to SF6
purchased from bulk gas distributors,
SF6 returned from equipment users with
or inside equipment and SF6 returned
from off-site recycling are also
accounted for among the total additions.
§ 98.455 Procedures for estimating
missing data.
A complete record of all measured
parameters used in the GHG emissions
calculations is required. Replace
missing data, if needed, based on data
from similar manufacturing operations,
and from similar equipment testing and
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18723
decommissioning activities for which
data are available.
§ 98.456
Data reporting requirements.
In addition to the information
required by § 98.3(c), each annual report
must contain the following information
at each facility level, by chemical:
(a) SF6 and PFC sales and purchases.
(b) SF6 and PFCs sent off site for
destruction.
(c) SF6 and PFCs sent off site to be
recycled.
(d) SF6 and PFCs returned from off
site after recycling.
(e) SF6 and PFCs returned by
equipment users with or inside
equipment.
(f) SF6 and PFCs stored in containers
at the beginning and end of the year.
(g) SF6 and PFCs inside equipment
delivered to customers.
(h) SF6 and PFCs returned to
suppliers.
(i) The nameplate capacity of the
equipment delivered to customers with
SF6 or PFCs inside, if different from the
quantity in paragraph (g) of this section.
(j) A description of the engineering
methods and calculations used to
determine emissions from hoses or other
flow lines that connect the container to
the equipment that is being filled.
(k) For any missing data, you must
report the reason the data were missing,
the length of time the data were missing,
the method used to estimate emissions
in their absence, and the quantity of
emissions thereby estimated.
§ 98.457
Records that must be retained.
In addition to the information
required by § 98.3(g), you must retain
the following records:
(a) All information reported and listed
in § 98.456.
(b) Accuracy certifications and
calibration records for all scales and
monitoring equipment, including the
method or manufacturer’s specification
used for calibration.
(c) Check-out and weigh-in sheets and
procedures for cylinders.
(d) Residual gas amounts in cylinders
sent back to suppliers.
(e) Invoices for gas purchases and
sales.
§ 98.458
Definitions.
All terms used in this subpart have
the same meaning given in the Clean Air
Act and subpart A of this part.
[FR Doc. 2010–6768 Filed 4–9–10; 8:45 am]
BILLING CODE 6560–50–P
E:\FR\FM\12APP4.SGM
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Agencies
[Federal Register Volume 75, Number 69 (Monday, April 12, 2010)]
[Proposed Rules]
[Pages 18652-18723]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: 2010-6768]
[[Page 18651]]
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Part IV
Environmental Protection Agency
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40 CFR Part 98
Mandatory Reporting of Greenhouse Gases: Additional Sources of
Fluorinated GHGs; Proposed Rule
Federal Register / Vol. 75 , No. 69 / Monday, April 12, 2010 /
Proposed Rules
[[Page 18652]]
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ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 98
[EPA-HQ-OAR-2009-0927; FRL-9130-7]
RIN 2060-AQ00
Mandatory Reporting of Greenhouse Gases: Additional Sources of
Fluorinated GHGs
AGENCY: Environmental Protection Agency (EPA).
ACTION: Proposed rule.
-----------------------------------------------------------------------
SUMMARY: EPA is revising and supplementing its initial proposed actions
to require reporting of fluorinated greenhouse gas (fluorinated GHG)
emissions from certain source categories. Specifically, EPA is revising
and supplementing its initial proposal to require reporting of
fluorinated GHG emissions from electronics manufacturing, production of
fluorinated gases, and use of electrical transmission and distribution
equipment. EPA is also proposing to require such reporting from
manufacture or refurbishment of electrical equipment and import and
export of pre-charged equipment and closed cell foams. This proposed
rule would not require control of greenhouse gases; rather it would
require only that sources above certain threshold levels monitor and
report emissions.
DATES: Comments must be received on or before June 11, 2010. There will
be a public hearing from 9 a.m. to 12 noon on April 20, 2010 at 1310 L
St., NW., Room 152, Washington, DC 20005.
ADDRESSES: Submit your comments, identified by docket ID EPA-HQ-OAR-
2009-0927 by one of the following methods:
Federal eRulemaking Portal: https://www.regulations.gov.
Follow the online instructions for submitting comments.
E-mail: GHGReportingFGHG@epa.gov.
Fax: (202) 566-1741.
Mail: EPA Docket Center, Attention Docket OAR-2009-0927,
Mail code 2822T, 1200 Pennsylvania Avenue, NW., Washington, DC 20460.
Hand/Courier Delivery: EPA Docket Center, Public Reading
Room, Room 3334, EPA West Building, Attention Docket OAR-2009-0927,
1301 Constitution Avenue, NW., Washington, DC 20004. Such deliveries
are only accepted during the Docket's normal hours of operation, and
special arrangements should be made for deliveries of boxed
information.
Instructions: Direct your comments to Docket ID No. EPA-HQ-OAR-
2009-0927. EPA's policy is that all comments received will be included
in the public docket without change and may be made available online at
https://www.regulations.gov, including any personal information
provided, unless the comment includes information claimed to be CBI or
other information whose disclosure is restricted by statute. Do not
submit information that you consider to be CBI or otherwise protected
through https://www.regulations.gov or e-mail. The https://www.regulations.gov Web site is an ``anonymous access'' system, which
means EPA will not know your identity or contact information unless you
provide it in the body of your comment. If you send an e-mail comment
directly to EPA without going through https://www.regulations.gov your
e-mail address will be automatically captured and included as part of
the comment that is placed in the public docket and made available on
the Internet. If you submit an electronic comment, EPA recommends that
you include your name and other contact information in the body of your
comment and with any disk or CD-ROM you submit. If EPA cannot read your
comment due to technical difficulties and cannot contact you for
clarification, EPA may not be able to consider your comment. Electronic
files should avoid the use of special characters, any form of
encryption, and be free of any defects or viruses.
Docket: All documents in the docket are listed in the https://www.regulations.gov index. Although listed in the index, some
information is not publicly available, e.g., CBI or other information
whose disclosure is restricted by statute. Certain other material, such
as copyrighted material, will be publicly available only in hard copy.
Publicly available docket materials are available either electronically
in https://www.regulations.gov or in hard copy at EPA's Docket Center,
Public Reading Room, EPA West Building, Room 3334, 1301 Constitution
Ave., NW., Washington, DC 20004. This Docket Facility is open from 8:30
a.m. to 4:30 p.m., Monday through Friday, excluding legal holidays. The
telephone number for the Public Reading Room is (202) 566-1744, and the
telephone number for the Air Docket is (202) 566-1742.
FOR FURTHER INFORMATION CONTACT: Carole Cook, Climate Change Division,
Office of Atmospheric Programs (MC-6207J), Environmental Protection
Agency, 1200 Pennsylvania Ave., NW., Washington, DC 20460; telephone
number: (202) 343-9263; fax number: (202) 343-2342; e-mail address:
GHGReportingRule@epa.gov. For technical information contact the
Greenhouse Gas Reporting Rule e-mail: ghgmrr@epa.gov. To obtain
information about the public hearings or to register to speak at the
hearings, please go to https://www.epa.gov/climatechange/emissions/ghgrulemaking.html.
SUPPLEMENTARY INFORMATION: Additional Information on Submitting
Comments: To expedite review of your comments by Agency staff, you are
encouraged to send a separate copy of your comments, in addition to the
copy you submit to the official docket, to Carole Cook, U.S. EPA,
Office of Atmospheric Programs, Climate Change Division, Mail Code
6207-J, Washington, DC 20460, telephone (202) 343-9263, e-mail
GHGReportingRule@epa.gov.
As indicated above, although EPA previously proposed a version of
some parts of this rule, that proposal has not become final. This
proposal partly supplements and partly replaces that initial proposal.
Comments on the initial proposal will be considered only to the extent
they remain relevant. To ensure that their comments on newly proposed
or re-proposed provisions are considered, parties should submit or re-
submit them at this time.
Regulated Entities. The Administrator determined that this action
is subject to the provisions of Clean Air Act (CAA) section 307(d). See
CAA section 307(d)(1)(V) (the provisions of section 307(d) apply to
``such other actions as the Administrator may determine.''). This is a
proposed regulation. If finalized, these regulations would affect
owners or operators of electronics manufacturing facilities,
fluorinated gas production facilities, electric power systems, and
electrical equipment manufacturing facilities, as well as importers and
exporters of pre-charged equipment and closed-cell foams. Regulated
categories and entities would include those listed in Table 1 of this
preamble:
[[Page 18653]]
Table 1--Examples of Affected Entities by Category
------------------------------------------------------------------------
Examples of affected
Category NAICS facilities
------------------------------------------------------------------------
Electronics Manufacturing......... 334111 Microcomputers
manufacturing
facilities.
334413 Semiconductor,
photovoltaic (solid-
state) device
manufacturing
facilities.
334419 LCD unit screens
manufacturing
facilities.
334419 MEMS manufacturing
facilities.
Fluorinated GHG Production........ 325120 Industrial gases
manufacturing
facilities.
Electrical Equipment Use.......... 221121 Electric bulk power
transmission and control
facilities.
Electrical Equipment Manufacture 33531 Power transmission and
or Refurbishment. distribution switchgear
and specialty
transformers
manufacturing
facilities.
Importers and Exporters of Pre- 423730 Air-conditioning
charged Equipment and Closed-Cell equipment (except room
Foams. units) merchant
wholesalers.
333415 Air-conditioning
equipment (except motor
vehicle) manufacturing.
423620 Air-conditioners, room,
merchant wholesalers.
443111 Household Appliance
Stores.
326150 Polyurethane foam
products manufacturing.
335313 Circuit breakers, power,
manufacturing.
423610 Circuit breakers merchant
wholesalers.
------------------------------------------------------------------------
Table 1 of this preamble is not intended to be exhaustive, but
rather provides a guide for readers regarding facilities likely to be
affected by this action. Table 1 lists the types of facilities that EPA
is now aware could be potentially affected by the reporting
requirements. Other types of facilities and companies not listed in the
table could also be subject to reporting requirements. To determine
whether you are affected by this action, you should carefully examine
the applicability criteria found in 40 CFR part 98, subpart A and the
relevant criteria in the proposed subparts related to electronics
manufacturing facilities, fluorinated gas production facilities,
electrical equipment use, electrical equipment manufacturing or
refurbishment facilities, and importers and exporters of pre-charged
equipment and closed-cell foams. If you have questions regarding the
applicability of this action to a particular facility, consult the
person listed in the preceding FOR FURTHER INFORMATION CONTACT section.
Many facilities that would be affected by the proposed rule have
GHG emissions from multiple source categories listed in 40 CFR part 98
or in this proposed rule. Table 2 of this preamble has been developed
as a guide to help potential reporters in the source categories subject
to the proposed rule identify the source categories (by subpart) that
they may need to (1) consider in their facility applicability
determination, and/or (2) include in their reporting. The table should
only be seen as a guide. Additional subparts in 40 CFR part 98 may be
relevant for a given reporter. Similarly, not all listed subparts are
relevant for all reporters.
Table 2--Source Categories and Relevant Subparts
------------------------------------------------------------------------
Source category (and main applicable Subparts recommended for review
subpart) to determine applicability
------------------------------------------------------------------------
Electricity Generation................. Electrical Equipment Use.
Electronics Manufacturing.............. General Stationary Fuel
Combustion.
Fluorinated GHG Production............. General Stationary Fuel
Combustion. Suppliers of
Industrial Greenhouse Gases.
Electrical Equipment Use............... General Stationary Fuel
Combustion.
Imports and Exports of Fluorinated GHGs Suppliers of Industrial
Inside Pre-charged Equipment and Greenhouse Gases.
Closed-Cell Foams.
Sulfur Hexafluoride and PFCs
from Electrical Equipment
Manufacture and Refurbishment.
Electrical Equipment Manufacture or General Stationary Fuel
Refurbishment. Combustion
Imports and Exports of
Fluorinated GHGs Inside Pre-
charged Equipment and Closed-
Cell Foams.
------------------------------------------------------------------------
Acronyms and Abbreviations. The following acronyms and
abbreviations are used in this document.
ASTM American Society for Testing and Materials
BAMM Best Available Monitoring Methods
CAA Clean Air Act
CARB California Air Resources Board
CBI confidential business information
CFC chlorofluorocarbon
CFR Code of Federal Regulations
CO2 carbon dioxide
CO2e CO2-equivalent
EIA Economic Impact Analysis
EO Executive Order
EPA U.S. Environmental Protection Agency
FERC Federal Energy Regulatory Commission
F-GHG fluorinated greenhouse gas
FTIR fourier transform infrared (spectroscopy)
FID flame ionization detector
GC gas chromatography
GHG greenhouse gas
GWP global warming potential
HCFC hydrochlorofluorocarbon
HFC hydrofluorocarbon
HFE hydrofluoroether
HTF heat transfer fluid
ICR information collection request
IPCC Intergovernmental Panel on Climate Change
kg kilograms
LCD liquid crystal displays
MEMS microelectromechanical devices
MMTCO2e million metric tons carbon dioxide equivalent
MRR mandatory greenhouse gas reporting rule
MS mass spectrometry
N2O nitrous oxide
NACAA National Association of Clean Air Agencies
NAICS North American Industry Classification System
NERC North American Energy Reliability Corporation
NESHAP National Emissions Standard for Hazardous Air Pollutants
NF3 nitrogen trifluoride
[[Page 18654]]
NMR nuclear magnetic resonance
NSPS New Source Performance Standards
OMB Office of Management and Budget
PFC perfluorocarbon
PSD Prevention of Significant Deterioration
PV photovoltaic cells
QA quality assurance
QA/QC quality assurance/quality control
R&D research and development
RFA Regulatory Flexibility Act
RGGI Regional Greenhouse Gas Initiative
RIA Regulatory Impact Analysis
SSM startup, shutdown, and malfunction
SF6 sulfur hexafluoride
TCR The Climate Registry
TSD technical support document
U.S. United States
UMRA Unfunded Mandates Reform Act of 1995
VOC volatile organic compound(s)
WCI Western Climate Initiative
Table of Contents
I. Background
A. Organization of This Preamble
B. Background on the Proposed Rule
C. Legal Authority
D. Relationship to other Federal, State and Regional Programs
II. Summary of and Rationale for the Reporting, Recordkeeping and
Verification Requirements for Specific Source Categories
A. Electronics Manufacturing
B. Fluorinated Gas Production
C. Electric Transmission and Distribution Equipment Use
D. Imports and Exports of Fluorinated GHGs inside pre-charged
equipment and closed-cell foams
E. Electrical Equipment Manufacture or Refurbishment
F. Subpart A Revisions
III. Economic Impacts on the Rule
A. How were compliance costs estimated?
B. What are the costs of the rule?
C. What are the economic impacts of the rule?
D. What are the impacts of the rule on small businesses?
E. What are the benefits of the rule for society?
IV. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory Planning and Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act (RFA)
D. Unfunded Mandates Reform Act (UMRA)
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation and Coordination with
Indian Tribal Governments
G. Executive Order 13045: Protection of Children from
Environmental Health Risks and Safety Risks
H. Executive Order 13211: Actions that Significantly Affect
Energy Supply, Distribution, or Use
I. National Technology Transfer and Advancement Act
J. Executive Order 12898: Federal Actions to Address
Environmental Justice in Minority Populations and Low-Income
Populations
I. Background
A. Organization of This Preamble
This preamble is broken into several large sections, as detailed
above in the Table of Contents. The paragraphs below describe the
layout of the preamble and provide a brief summary of each section.
The first section of this preamble contains the basic background
information about the origin of this proposed rule, including a brief
discussion of the initial proposed requirements for electronics,
fluorinated gas production, and use of electrical transmission and
distribution equipment. This section also discusses EPA's use of our
legal authority under the CAA to collect the proposed data, and the
benefits of collecting the data.
The second section of this preamble provides a brief summary of,
and rationale for, the key design elements on which EPA is seeking
comment today for each subpart. Depending on the subpart, this section
may include EPA's rationale for (i) the definition of the source
category, (ii) selection of reporting threshold, (iii) selection of
proposed reporting and monitoring methods, (iv) selection of procedures
for estimating missing data, (v) selection of data reporting
requirements, and (vi) selection of records that must be retained. EPA
describes the proposed options for each design element, as well as the
other options considered. Throughout this discussion, EPA highlights
specific issues on which we solicit comment. Please refer to the
specific source category of interest for more details.
The third section provides the summary of the cost impacts,
economic impacts, and benefits of this proposed rule from the Economic
Analysis. Finally, the last section discusses the various statutory and
executive order requirements applicable to this proposed rulemaking.
B. Background on the Proposed Rule
The Final Mandatory GHG Reporting Rule (Final MRR), (40 CFR part
98) was signed by EPA Administrator Lisa Jackson on September 22, 2009
and published in the Federal Register on October 30, 2009 (74 FR
56260). The Final MRR, which became effective on December 29, 2009,
included reporting of GHGs from the facilities and suppliers that EPA
determined should be included to appropriately respond to the direction
in the 2008 Consolidated Appropriations Act.\1\ These source categories
capture approximately 85 percent of U.S. GHG emissions through
reporting by direct emitters as well as suppliers of fossil fuels and
industrial gases.
---------------------------------------------------------------------------
\1\ Consolidated Appropriations Act, 2008, Public Law 110-161,
121 Stat. 1844, 2128.
---------------------------------------------------------------------------
In the April 2009 proposed mandatory GHG reporting rule, the
electronics, fluorinated GHG production, and electrical equipment use
source categories were included as subparts I, L, and DD. In addition,
EPA requested comment on requiring reporting under subpart OO of the
quantities of fluorinated GHGs imported and exported inside pre-charged
equipment and foams. EPA received a number of lengthy, detailed
comments regarding proposed subparts I and L, several comments
regarding the definition of ``facility'' under subpart DD, and several
comments regarding a reporting requirement for imports and exports of
fluorinated GHGs contained inside pre-charged equipment and foams.
These comments, which are described in more detail in the discussions
of the individual source categories below, raised concerns about the
costs and technical feasibility of implementing subparts I and L as
initially proposed, requested clarification of how ``facility'' should
be interpreted under subpart DD, and both favored and opposed a
requirement to report imports of fluorinated GHGs contained in imported
and exported pre-charged equipment and closed-cell foams.
EPA recognized the concerns raised by stakeholders, and decided not
to finalize subparts I, L, and DD with the Final MRR, but instead to
re-propose significant pieces of these subparts. For subparts I and L
this proposal incorporates a number of changes including, but not
limited to, the addition of different methodologies that provide
improved emissions coverage at a lower cost burden to facilities as
compared to the initial proposal. Where aspects of the initial
proposals for subparts I and L are retained in this proposal, such as
in the basic mass-balance methodology for subpart L (as an option for
some facilities) and in many of the equations for subpart I, today's
proposal adds more flexibility in how and how frequently the underlying
data are gathered. In addition, EPA is proposing requirements to report
emissions from manufacture or refurbishment of electrical equipment and
to report the quantities of fluorinated GHGs imported and exported
inside pre-charged equipment and foams.
We believe the monitoring approaches proposed in this action, which
combine direct measurement and facility-specific calculations,
effectively balance
[[Page 18655]]
accuracy and costs, and that they are warranted even though the rule
does not contain any emissions reduction requirements. As we stated in
the Final MRR, the data collected by the rule are expected to be used
in analyzing and developing a range of potential CAA GHG policies and
programs. A consistent and accurate data set is crucial to serve this
intended purpose.
Under this proposed rule, facilities not already reporting but
required to report under this rule would begin data collection in 2011
following the methods outlined in the proposed rule and would submit
data to EPA by March 31, 2012. As is the case under the Final MRR,
facilities would have the option to use Best Available Monitoring
Methods (BAMM) for the first quarter of the first reporting year for
the source categories included in this proposed rule. Thus, for these
source categories, facilities could use BAMM through March 31, 2011.
C. Legal Authority
EPA is proposing this rule under its existing CAA authority,
specifically authorities provided in CAA section 114. As discussed
further below and in ``Mandatory Greenhouse Gas Reporting Rule: EPA's
Response to Public Comments, Legal Issues'' (available in EPA-HQ-OAR-
2008-0508), EPA is not citing the FY 2008 Consolidated Appropriations
Act as the statutory basis for this action. While that law required
that EPA spend no less than $3.5 million on a rule requiring the
mandatory reporting of GHG emissions, it is the CAA, not the
Appropriations Act, that EPA is citing as the authority to gather the
information proposed by this rule.
As stated in the Final MRR, CAA section 114 provides EPA broad
authority to require the information proposed by this rule because such
data would inform and are relevant to EPA's carrying out a wide variety
of CAA provisions. As discussed in the initial proposed rule (74 FR
16448, April 10, 2009), CAA section 114(a)(1) authorizes the
Administrator to require emissions sources, persons subject to the CAA,
or persons whom the Administrator believes may have necessary
information to monitor and report emissions and provide such other
information the Administrator requests for the purposes of carrying out
any provision of the CAA. EPA notes that while climate change
legislation approved by the U.S. House of Representatives, and pending
in the U.S. Senate, would provide EPA additional authority for a GHG
registry similar to this proposed rule, and would do so for purposes of
that pending legislation, this proposed rule is authorized by, and the
information being gathered by this proposed rule is relevant to
implementing, the existing CAA. EPA expects, however, that the
information collected by this proposed rule would also prove useful to
legislative efforts to address GHG emissions.
For further information about EPA's legal authority, see the
proposed and Final MRR.
D. Relationship to Other Federal, State and Regional Programs
In developing this proposed rule, EPA reviewed monitoring methods
included in international guidance (e.g., Intergovernmental Panel on
Climate Change), as well as Federal voluntary programs (e.g., EPA PFC
Reduction/Climate Partnership for the Semiconductor Industry and the
U.S. Department of Energy Voluntary Reporting of Greenhouse Gases
Program (1605(b) of the Energy Policy Act), corporate protocols (e.g.,
World Resources Institute and World Business Council for Sustainable
Development GHG Protocol) and industry guidance (e.g., 2006 ISMI
Guideline for Environmental Characterization of Semiconductor Process
Equipment).
EPA also reviewed State reporting programs (e.g., California and
New Mexico) and Regional partnerships (e.g., Regional Greenhouse Gas
Initiative, Western Climate Initiative, The Climate Registry). These
are important programs that not only led the way in reporting of GHG
emissions before the Federal government acted but also assist in
quantifying the GHG reductions achieved by various policies. Many of
these programs collect different or additional data as compared to this
proposed rule. For example, State programs may establish lower
thresholds for reporting, request information on areas not addressed in
EPA's reporting rule, or include different data elements to support
other programs (e.g., offsets). For further discussion on the
relationship of this proposed rule to other programs, please refer to
the preamble to the Final MRR.
II. Summary of and Rationale for the Reporting, Recordkeeping and
Verification Requirements for Specific Source Categories
A. Electronics Manufacturing
1. Overview of Reporting Requirements
Electronics manufacturing includes, but is not limited to, the
manufacture of semiconductors, liquid crystal displays (LCDs), micro-
electro-mechanical systems (MEMS), and photovoltaic cells (PV). The
electronics industry uses multiple long-lived fluorinated greenhouse
gases (fluorinated GHGs) such as perfluorocarbons (PFCs),
hydrofluorocarbons (HFCs), sulfur hexafluoride (SF6), and
nitrogen trifluoride (NF3), as well as nitrous oxide
(N2O). This proposed rule would apply to electronics
manufacturing facilities where emissions from electronics manufacturing
processes such as plasma etching, chemical vapor deposition, chamber
cleaning, and heat transfer fluid use as well as stationary fuel
combustion units equal or exceed 25,000 metric tons of CO2e
per year.\2\ In this action, we are proposing methods to estimate
emissions from cleaning and etching for semiconductor, LCD, MEMS, and
PV manufacture and also methods for estimating N2O emissions
from chemical vapor deposition and other manufacturing processes such
as chamber cleaning. We are also clarifying methods for estimating
emissions from heat transfer fluids. And lastly, we are proposing
methods for reporting controlled emissions from abatement systems.
---------------------------------------------------------------------------
\2\ As discussed further below, EPA is proposing that
uncontrolled emissions be used for purposes of determining whether a
facility's emissions are equal to or greater than 25,000
mtCO2e.
---------------------------------------------------------------------------
2. Major Changes Since Initial Rule Proposed
In the initial proposal for electronics manufacturing, we included
the following provisions for reporting emissions from electronics
manufacture: (1) A capacity-based threshold for semiconductors, LCDs,
and MEMS facilities and an emissions-based threshold for PV facilities;
(2) methods for estimating fluorinated GHG emissions from etching and
cleaning; (3) methods for estimating N2O emissions during
etching and cleaning; (4) methods for verifying destruction or removal
efficiency (DRE) of abatement systems; and (5) methods for estimating
emissions from heat transfer fluids.
As noted in the preamble to the Final MRR, we received a number of
lengthy, detailed comments regarding the electronics manufacturing
subpart. In total, we received comments from approximately 10 entities
on the proposed rule regarding electronics manufacture. The commenters
generally opposed the proposed reporting requirements for large
semiconductor facilities and stated that excessive monitoring and
reporting were required. For example, commenters asserted that they do
not currently collect the data required to report using an IPCC Tier 3
[[Page 18656]]
approach, and that to collect such data would entail significant burden
and capital costs. In most cases, commenters provided alternative
approaches to each of the reporting requirements.
We have carefully reviewed the comments, issues, and suggestions
raised by stakeholders regarding electronics manufacturing. In
response, we are revising our initial proposal and are proposing the
following reporting provisions for electronics manufacture: (1) A
single emissions-based reporting threshold for all semiconductor, LCD,
MEMS, and PV facilities; (2) modified methods for estimating emissions
from cleaning and etching activities for semiconductor facilities and
other electronics facilities including those that manufacture LCDs,
MEMS, and PVs; (3) modified methods for estimating facility
N2O emissions; (4) clarified methods for estimating
emissions from heat transfer fluids; and (5) revised methods for
reporting controlled emissions from abatement systems.
In the paragraphs below, we summarize the main provisions included
in the initial proposal for reporting emissions from electronics
manufacturing and we briefly summarize the major changes that are being
proposed today. For more detailed information on the initial proposal,
see the electronics manufacturing section of EPA's proposed MRR (74 FR
16448, April 10, 2009).
Reporting Threshold. In the initial proposal, we proposed a
capacity-based threshold, requiring those facilities with emissions
equal to or greater than the thresholds to report their GHG emissions.
We proposed production capacity-based thresholds of 1,080 m \2\, 1,020
m \2\, and 236,000 m \2\ of substrate for semiconductor, MEMS, and LCD
manufacturing facilities, respectively. The capacity-based threshold
proposed were equivalent to 25,000 mtCO2e using the IPCC
2006 Tier 1 default factors and assumed no abatement. Where IPCC 2006
Tier 1 default emission factors were unavailable (i.e., MEMS), the
emission factor was estimated based on relevant IPCC Tier 1 emission
factors for semiconductor production. Due to a lack of information on
use and emissions of fluorinated GHGs for PV manufacture, we proposed
an emissions-based threshold of 25,000 mtCO2e for those
facilities. We proposed to use a capacity-based threshold based on the
published capacities of facilities, as opposed to an emissions-based
threshold, where possible, because we believed that it simplified the
applicability determination.
Several commenters stated that the proposed capacity-based
threshold created ambiguity. For example, one commenter noted that it
was unclear how production capacity was defined as actual manufacturing
levels could fluctuate year by year. In response to these comments, we
are now proposing a single emissions-based threshold equal to or
greater than 25,000 metric tons of CO2e per year for
electronics manufacturing facilities. We have concluded that a single
emissions-based threshold will simplify the applicability determination
and that by applying the method for determining whether the threshold
is met, a facility will be able to quickly determine whether they must
report under this rule.
Estimating Emissions from Cleaning and Etching Processes. With
respect to estimating emissions from chamber cleaning and etching, in
our initial proposal, we outlined two different methods; one method for
relatively large semiconductor facilities, and another method for all
other semiconductor facilities and LCD, MEMS, and PV facilities
required to report. We defined large semiconductor facilities as those
facilities with annual capacities of greater than 10,500 m\2\ silicon
(equivalent to 29 out of 175 total semiconductor manufacturing
facilities). For large semiconductor facilities we proposed an approach
based on the IPCC Tier 3 method that required the use of company-
specific data for (1) gas consumption, (2) gas utilization,\3\ (3) by-
product formation \4\, and (4) DRE for all emissions abatement
processes at the facility. As we stated in the initial proposal, we had
concluded that large semiconductor facilities were already using Tier 3
methods and/or had the necessary data readily available either in-house
or from suppliers to apply the highest Tier method. For smaller
semiconductor facilities and LCD, MEMS, and PV facilities, we proposed
an approach based on the IPCC Tier 2b method, which required using
default emission factors for process utilization, by-product formation,
and site-specific DRE measurements.
---------------------------------------------------------------------------
\3\ For purposes of electronics manufacturing, we are using the
term ``gas utilization'' to describe the fraction of input
N2O or fluorinated GHG converted to other substances
during the etching, deposition, and/or chamber/wafer cleaning
processes. Gas utilization is expressed as a rate or factor for
specific manufacturing processes. ``Utilization'' should not be
confused with ``use;'' ``use'' refers to gas consumption or the
quantity of gas fed into process at an electronics manufacturing
facility.
\4\ For purposes of electronics manufacturing, ``by-product
formation'' is the quantity of fluorinated GHGs created during
electronics manufacturing processes. Fluorinated GHG by-products may
also be formed by abatement devices.
---------------------------------------------------------------------------
Comments received in response to our initial proposal stated that
the 2006 IPCC Tier 3 method would be overly burdensome for
semiconductor manufacturers and that process-specific emission factors
do not exist for many tools and processes. The commenters noted that
most semiconductor facilities do not track gas consumption by tool or
process-type and that currently, only one large semiconductor company
uses the Tier 3 method. Generally, commenters requested the use of the
2006 IPCC Tier 2b method.
In response to these comments, we are now proposing the use of a
``Refined Method'' for estimating these emissions from semiconductor
facilities. Our revised methodology includes a simpler approach to
estimating emissions from cleaning and etching as compared to the Tier
3 method that was initially proposed for larger semiconductor
facilities. To this end, we estimate that our proposed methodology will
result in a reduction in burden compared to the Tier 3 method for those
facilities previously defined as large semiconductor facilities, and an
improvement in accuracy of the emissions estimate as compared to the
2006 IPCC Tier 2b method. Furthermore, since we anticipate that all
semiconductor facilities already have, or have ready access to, the
information required by this proposed methodology, we are also
proposing to require all semiconductor facilities required to report to
estimate emissions using the Refined Method. We have concluded the
method we are proposing is the most appropriate method taking into
account both the cost to the reporter as well as accuracy of emissions
achieved.
For LCD, MEMS, and PV facilities, in this action we are proposing
to require an approach based on a slightly modified 2006 IPCC Tier 2b
method which would include (1) gas-and facility-specific heel factors
(consistent with the requirements we are proposing for semiconductor
facilities), (2) gas consumption apportioned to 2006 IPCC Tier 2b
process categories (i.e. clean and etch), (3) default factors
consistent with the 2006 IPCC Tier 2b factors, and (4) methods for
reporting controlled emissions from abatement systems (as proposed
below). The main difference between the method proposed in this revised
proposal and in the initial proposal is the addition of a gas-and
facility-specific heel factor to determine overall gas consumption. We
did not receive any comments on the Tier 2b method that we proposed for
LCD, MEMS, and PV facilities in our initial proposal. We are proposing
to add the requirement of gas-and-facility specific
[[Page 18657]]
heel factors based on comments received from semiconductor facilities
in response to the initial proposal. It is our understanding that LCD,
MEMS, and PV facilities have the data required to develop a gas-and-
facility specific heel factors and that it can be implemented with
minimal burden.
Estimating Facility N2O Emissions. In our initial proposal, our
approach required that facilities estimate annual N2O
emissions using a simple mass-balance method. This method assumed that
all N2O consumed is emitted (i.e., not converted or
destroyed). We also requested comment on utilization factors for
N2O as well as on data on N2O by-product
formation.
In response to our initial proposal, we received comments that
clarified that N2O is used primarily in the chemical vapor
deposition process. Commenters opposed our proposed method for
estimating N2O emissions, which assumed 100 percent
N2O used is emitted, and asserted that semiconductor
facilities should be permitted to use measured N2O emission
factors where these factors were measured using methods consistent with
the December 2006 International SEMATECH Manufacturing Initiative's
Guideline for Environmental Characterization of Semiconductor Process
Equipment (2006 ISMI Guidelines). Commenters also noted that facilities
that have not developed N2O emission factors should be
allowed to use a default emission factor of 60 percent, reflecting
N2O utilization of 40 percent.\5\ Lastly, commenters
asserted that those companies that have a measured DRE for
N2O abatement be allowed to apply these DREs in the emission
estimates.
---------------------------------------------------------------------------
\5\ The 40% utilization rate (60% emission factor) was
identified based on a survey of industry conducted by ISMI and
provided in comments in response to the initial proposal.
---------------------------------------------------------------------------
We are now proposing two methods for estimating N2O
emissions from electronics manufacturing: one for estimating
N2O emissions from chemical vapor deposition and another for
estimating N2O emissions from all other manufacturing
processes such as chamber cleaning.
Reporting Controlled Emissions From Abatement Systems. The
emissions estimation method originally proposed accounted for
destruction by abatement systems only if facilities verified the
performance of their systems using one of two methods. In particular,
we proposed to require that the DRE be verified by either (1)
measurement by the facility using the methods described in EPA's
Protocol for Measuring Destruction or Removal Efficiency of Fluorinated
Greenhouse Gas Abatement Equipment in Electronics Manufacturing (EPA's
DRE Protocol), or (2) purchase by the facility of abatement systems
that were tested by a third party using a standard protocol such as
EPA's DRE Protocol.
We also proposed to require that facilities use the systems within
the manufacturer's specified system lifetime, operate the system within
the manufacturer specific limits for the gas mix and exhaust flow rate
intended for the fluorinated GHG destruction, and maintain the
equipment according to the manufacturer's guidelines.
In response to the initial proposal, commenters were generally
opposed to EPA's initial approach for measuring DRE, noting that
according to the Results of the ISMI ESH Technology Center Greenhouse
Gas Facility Survey, less than one percent of installed abatement
systems have been properly tested using the draft EPA Protocol and that
generally, facilities use the IPCC default factors or manufacturer-
supplied measurements. In addition, commenters were also opposed to
EPA's proposed requirement that facilities rely on manufacturer-
specified system lifetime as properly maintained and serviced abatement
systems can last beyond the manufactures' specified lifetime. For
purposes of this reporting rule, we are now proposing that facilities
that wish to document and report fluorinated GHG and N2O
emissions reflecting the use of abatement systems adhere to a method
that would require (1) documentation to certify that the abatement
device is installed, operated, and maintained according to
manufacturers' specifications, (2) accounting for the system's uptime,
and (3) either certification that the abatement system is specifically
designed for fluorinated GHG and N2O abatement and the use
of EPA default DRE value, or directly and properly measured DRE (i.e.,
in accordance with EPA DRE Protocol) confirming abatement system's
performance.
Estimating Emissions from Heat Transfer Fluids. To estimate the
emissions from heat transfer fluids we proposed to require that
electronics manufacturers use the 2006 IPCC Tier 2 approach, which is
based on a mass-balance method. As we stated in the initial proposal,
the 2006 IPCC Tier 2 approach uses company-specific data and accounts
for differences among facilities' heat transfer fluids, leak rates, and
service practices.
In comments we received on our initial proposal, it was noted that
our proposed method for estimating emissions from heat transfer fluids
would require companies to compile a detailed inventory of all
fluorinated heat transfer equipment and its nameplate capacity.
Comments stated that such a mass balance approach would be overly
burdensome.
In evaluating these comments, we believe that there was some
confusion regarding our intended method. As a result, we are not
changing the broad outlines of our initial proposal, but we are
clarifying required data elements.
3. Definition of the Source Category
The electronics industry uses multiple long-lived fluorinated GHGs
such as PFCs, HFCs, SF6, and NF3, as well as
N2O, during manufacturing of semiconductors, LCDs, MEMS, and
PV. We understand that there are other electronics manufacturers such
as those facilities that manufacture light-emitting diodes (LEDs) and
disk readers that use fluorinated GHGs in similar manufacturing
processes as semiconductors. As a result, we are seeking information on
fluorinated GHG and N2O emissions associated with the
manufacture of these products and also comment on whether to include
them as part of the electronics manufacturing source category. It is
our intent to include these other sources as part of the electronics
manufacturing source category in the final rule where their emissions
meet or exceed our proposed threshold of 25,000 mtCO2e.
Fluorinated GHGs are used for plasma etching of silicon materials,
cleaning deposition tool chambers, and wafer cleaning. N2O
is also used in depositing certain films and chamber cleaning.
Additionally, electronics manufacturing employs fluorinated GHGs
(typically liquids at ambient temperature) as heat transfer fluids. The
most common fluorinated GHGs in use for these purposes are
CHF3 (HFC-23), CF4, C2F6,
NF3, SF6 and FluorinertTM and
Galden[reg] heat transfer fluids; other compounds such as
perfluoropropane (C3F8) and perfluorocyclobutane
(c-C4F8) are also used in smaller quantities
(EPA, 2008a). Table 3 of this preamble presents fluorinated GHGs
typically used during manufacture of electronics devices.
[[Page 18658]]
Table 3--Examples of Fluorinated GHGs Used by the Electronics Industry
------------------------------------------------------------------------
Fluorinated GHGs used during
Product type manufacture
------------------------------------------------------------------------
Electronics (e.g., Semiconductor, MEMS, CF4, C2F6, C3F8, c-C4F8, c-
LCD, PV). C4F8O, C4F6, C5F8, CHF3,
CH2F2, NF3, SF6, and Heat
Transfer Fluids (CF3-(O-
CF(CF3)-CF2)n-(O-CF2)m-O-CF3,
CnF2n+2, CnF2n+1(O)CmF2m+1,
CnF2nO, (CnF2n+1)3N) \a\
------------------------------------------------------------------------
\a\ IPCC Guidelines do not specify the fluorinated GHGs used for MEMS
production. Literature reviews revealed that among others CF4, SF6,
and the Bosch process (consisting of alternating steps of SF6 and c-
C4F8) are used to manufacture MEMS. For further information, see the
Electronics Manufacturing TSD in the docket for this rulemaking (EPA-
HQ-OAR-2009-0927).
Description of Electronics Manufacturing Processes and Activities.
Fluorinated GHG and N2O emissions result from the following
electronics processes and activities:
(1) Plasma etching;
(2) Chemical vapor deposition;
(3) Chamber cleaning;
(4) Wafer cleaning; and
(5) Heat transfer fluid use.
Plasma etching, essential to fabricating intricate, nanometer size
features in contemporary electronic devices, is the removal of solid
material from a substrate surface with gaseous reactants, in plasma, to
produce gaseous products, which are then pumped away and disposed.
Unless abated, unreacted fluorinated reactants or fluorinated GHG by-
products from etching are emitted into the atmosphere.
Typical fluorinated GHG etching reagents, used either individually
or in combination, are CF4, CHF3,
C2F6 and c-C4F8 for silicon
dioxide and nitride films; CF4, NF3 and
SF6 for polysilicon films; and CHF3 for aluminum
and SF6 for tungsten films. A typical fluorinated GHG by-
product from etching processes is CF4; in some instances
C2F6 may also be formed.
Deposition is a fundamental step in the fabrication of a variety of
electronic devices. During deposition, layers of dielectric, barrier,
or electrically conductive films are deposited or grown on a wafer or
other substrate. Chemical vapor deposition enables the deposition of
dielectric or metal films. During the chemical vapor deposition
process, gases that contain atoms of the material to be deposited react
on the wafer surface to form a thin film of solid material. Films
deposited by chemical vapor deposition may be silicon oxide, single-
layer crystal epitaxial silicon, amorphous silicon, silicon nitride,
dielectric anti-reflective coatings, low k dielectric, aluminum,
titanium, titanium nitride, polysilicon, tungsten, refractory metals or
silicides. Nitrous oxide may be the oxidizer of choice during
deposition of silicon oxide films.
Chambers used for depositing polysilicon, dielectric and metal
films are cleaned periodically using fluorinated GHGs, N2O,
and other gases. During the cleaning cycle, the gas is converted to
fluorine atoms in plasma, which etches away residual silicon-containing
material from chamber walls, electrodes, and chamber hardware.
Undissociated fluorinated gases and other fluorinated and non-
fluorinated products pass from the chamber to waste streams and, unless
emissions control systems are employed, into the atmosphere.
Typical fluorinated GHGs used for chamber cleaning are
NF3, C2F6 and
C3F8. N2O may also be used to reduce
particle formation during chamber cleaning. As with etching films,
fluorinated GHG by-products may be formed during chamber cleaning,
typically CF4.
During wafer processing, any residual photoresist material can be
removed through an ashing process, which consists of placing partially
processed wafers in an oxygen plasma to which CF4 may be
added. The edges of wafers (the bevel) may require
additional cleaning to remove yield-reducing residual material. Bevel
cleaning may also use a plasma process with fluorinated gas chemistry.
In both of these wafer cleaning processes, unused fluorinated GHGs are
emitted unless abated.
Fluorinated GHG liquids (at ambient temperature) such as fully
fluorinated linear, branched or cyclic alkanes, ethers, tertiary amines
and aminoethers, and mixtures thereof are used as heat transfer fluids
at several semiconductor facilities to cool process equipment, control
temperature during device testing, and solder semiconductor devices to
circuit boards. The fluorinated heat transfer fluid's high vapor
pressures can lead to evaporative losses during use.\6\
---------------------------------------------------------------------------
\6\ Electronics Manufacturing TSD (EPA-HQ-OAR-2009-0927); 2006
IPCC Guidelines.
---------------------------------------------------------------------------
Our understanding is that heat transfer fluids are widely used
within semiconductor manufacturing. We are seeking comment on the
extent of use and annual replacement quantities of heat transfer fluids
in other electronics sectors, such as their use for cooling or cleaning
during LCD manufacture.
Total U.S. Emissions From Electronics Manufacturing. Emissions of
fluorinated GHGs from 216 electronics facilities were estimated to be
6.1 million metric tons CO2e in 2006. Below is a breakdown
of emissions by electronics product type.
Semiconductors. Emissions of fluorinated GHGs, including heat
transfer fluids, from 175 semiconductor facilities were estimated to be
5.9 million metric tons CO2e in 2006. Of the total estimated
semiconductor emissions, 5.4 million metric tons CO2e are
from etching/chamber cleaning and 0.5 million metric tons
CO2e are from heat transfer fluid usage.
MEMS. Emissions of fluorinated GHGs from 12 MEMS facilities were
estimated to be 0.1 million metric tons CO2e in 2006.
LCDs. Emissions of fluorinated GHGs from 9 LCD facilities were
estimated to be 0.02 million metric tons CO2e in 2006.
PV. Emissions of fluorinated GHGs from 20 PV facilities were
estimated to be 0.07 million metric tons CO2e in 2006. We
request comment on the number and capacity of PV facilities that employ
thin film technologies (i.e., amorphous silicon) and other PV
manufacturing facilities in the United States using fluorinated GHGs.
For additional background information on the electronics industry,
refer to the Electronics Manufacturing Technical Support Document (TSD)
in the docket for this rulemaking (EPA-HQ-OAR-2009-0927).
4. Threshold for Reporting
For facilities that manufacture semiconductors, LCD, MEMS, and PV,
we are proposing an emissions-based threshold of 25,000
mtCO2e. Consistent with other sections of the Final MRR, EPA
is proposing that for the purposes of determining whether a facility
emits amounts equal to or greater than 25,000 mtCO2e, a
facility must include emissions from all source categories for which
methods are provided in the rule. For purposes of the threshold
determination under subpart I, we are proposing two different methods,
depending on whether the facility
[[Page 18659]]
manufacturers semiconductors, MEMS, LCDs or PVs (see proposed section
98.91). It is important to note that these methods are only for
determining whether a facility exceeds the threshold; the proposed
methods required for monitoring and reporting emissions data are
presented in section 5 below.
To determine whether a manufacturer falls above or below the
proposed 25,000 mtCO2e threshold, we are proposing that
semiconductor, MEMS, and LCD facilities use gas specific emission
factors assuming 100 percent manufacturing capacity to calculate annual
metric tons of emissions in CO2 equivalents. Because we
understand that heat transfer fluids are widely used within
semiconductor manufacturing, we are proposing that semiconductor
manufacturers add 10 percent of total clean and etch emissions at a
facility to their estimate. For applicability purposes, we propose that
manufacturing capacity means the facility's full planned design
capacity.
The gas specific emission factors we are proposing to use for
threshold applicability for semiconductors and LCD facilities are
consistent with the 2006 IPCC Tier 1 emission factors. For MEMS,
because there are no IPCC factors available, we are assuming that
SF6 accounts for 100 percent of the sector's total
emissions. The emission factor we are proposing for threshold
applicability is based on the assumption that the MEMS SF6
emission factor is equivalent to the IPCC Tier 1 SF6
emission factor for semiconductors, scaled up by a factor of 5.\7\
---------------------------------------------------------------------------
\7\ For a more detailed explanation of MEMS default factor,
please refer to the Electronics Manufacturing TSD (EPA-HQ-OAR-2009-
0927).
---------------------------------------------------------------------------
We are proposing that PV facilities multiply annual fluorinated GHG
purchases or consumption by the gas-appropriate 100-year GWPs, as
defined in Table A-1 of subpart A of part 98, to calculate annual
metric tons of emissions in CO2 equivalents. None of these
calculations would account for emission abatement systems.
We are proposing to require an emissions estimating method that
does not account for destruction by abatement systems because actual
emissions from facilities employing abatement systems may exceed
estimates when based on the manufacturers' rated DREs of the equipment
and may therefore exceed the 25,000 mtCO2e threshold without
the knowledge of the facility operators. When abatement equipment is
used, electronics manufacturers often estimate their emissions using
the manufacturer-supplied DRE for the system. However, an abatement
system may fail to achieve its rated DRE either because it was not
installed properly, is not being properly operated and maintained, or
because the DRE value itself was incorrectly measured due to a failure
to properly account for the effects of dilution. For example, reported
DREs for CF4 can be overstated by as much as a factor of 20
to 50, and the corresponding figure for C2F6 can
be overstated by a factor of up to 10 because of failure to properly
account for dilution (Burton, 2007).
In our analysis of the emissions thresholds, we considered
thresholds of 1,000 mtCO2e, 10,000 mtCO2e, 25,000
mtCO2e, and 100,000 mtCO2e per year. To estimate
the number of semiconductor facilities that would have to report under
each of the various thresholds, we estimated emissions for each
facility in the U.S. by using IPCC Tier 1 emission factors. These
emissions estimates were then evaluated to determine how many
facilities would meet the various thresholds. To estimate the
collective emissions from the facilities that would have to report
under the various thresholds, we used information from EPA's PFC
Reduction/Climate Partnership for Semiconductors and the EPA PFC
Emissions Vintaging Model.
To estimate the number of LCD and PV facilities that would have to
report under the various thresholds, as well as the collective
emissions from these facilities, we used IPCC Tier 1 emission factors.
Because IPCC emission factors for MEMS are not available, the number of
facilities that would have to report and the collective emissions from
these facilities were determined using an emission factor based on a
relevant IPCC Tier 1 emission factor for semiconductor production.\8\
All of our analyses assumed no abatement.
---------------------------------------------------------------------------
\8\ For a more detailed explanation of MEMS default emission
factor, please refer to the Electronics Manufacturing TSD (EPA-HQ-
OAR-2009-0927).
---------------------------------------------------------------------------
Table 4 of this preamble shows emissions and facilities that would
be captured by the respective emissions thresholds.
Table 4--Threshold Analysis for Electronics Industry
----------------------------------------------------------------------------------------------------------------
Emissions covered Facilities covered
Emission threshold level metric tons Total Total number ------------------------------------------------
CO2e/yr national of metric tons
emissions facilities CO2e/yr Percent Facilities Percent
----------------------------------------------------------------------------------------------------------------
1,000............................... 5,984,463 216 5,962,091 99.6 165 76
10,000.............................. 5,984,463 216 5,813,200 97 114 53
25,000.............................. 5,984,463 216 5,622,570 94 94 44
100,000............................. 5,984,463 216 4,737,622 79 55 26
----------------------------------------------------------------------------------------------------------------
We selected the 25,000 mtCO2e per year threshold because
it maximizes emissions reporting, while excluding small facilities that
do not contribute significantly to the overall GHG emissions.
Table 5 of this preamble shows the estimated emissions and number
of facilities that would report for each type of source under the
proposed emissions-based thresholds.
Table 5--Summary of Rule Applicability Under the Proposed Thresholds
--------------------------------------------------------------------------------------------------------------------------------------------------------
Total Emissions covered Facilities covered
Total emissions ------------------------------------------------
Emissions source Threshold national of source
facilities (metric metric tons Percent Facilities Percent
tons CO2e) CO2e/yr
--------------------------------------------------------------------------------------------------------------------------------------------------------
Semi-conductors............................. 25,000 Mt CO2 Eq.............. 175 5,741,676 5,492,066 96 91 52
[[Page 18660]]
MEMS........................................ 25,000 Mt CO2 Eq.............. 12 146,115 96,164 66 2 17
LCD......................................... 25,000 Mt CO2 Eq.............. 9 23,632 0 0 0 0
PV.......................................... 25,000 Mt CO2 Eq.............. 20 73,039 34,340 47 1 5
--------------------------------------------------------------------------------------------------------------------------------------------------------
The proposed emissions-based thresholds are estimated to include
approximately 50 percent of semiconductor facilities and between
approximately 5 percent and 17 percent of the facilities manufacturing
PV and MEMS, respectively. At the same time, the thresholds are
expected to cover nearly 96 percent of fluorinated GHG emissions from
semiconductor facilities, 66 percent of fluorinated GHG emissions from
facilities manufacturing MEMS, and 47 percent of fluorinated GHG
emissions from facilities manufacturing PV. Combined, these emissions
are estimated to account for close to 94 percent of fluorinated GHG
emissions from the electronics industry as a whole.
Based on our current analysis, facilities manufacturing LCDs are
not expected to meet the proposed threshold. In addition, only 2 MEMS
facilities and 1 PV facility are expected to be covered. The data and
information that we currently have on MEMS, LCD, and PV manufacturing,
however, is limited and incomplete. We are including these sectors
because they have similar fluorinated GHG and N2O use and
manufacturing processes as those of semiconductor manufacturing and
they are high growth sectors. We estimate that emissions from MEMS,
LCD, and PV may be higher than our data show currently and we expect
them to increase in the future.
For additional background information on the threshold analysis,
refer to the Electronics Manufacturing TSD. For specific information on
costs, including unamortized first year capital expenditures, please
refer to the EIA and the EIA cost appendix.
5. Selection of Proposed Monitoring Methods
We are proposing methods to monitor and estimate fluorinated GHG
and N2O emissions from semiconductor, LCD, MEMS, and PV
manufacture. The proposed methods discussed below include the
following: (a) Estimating emissions from cleaning and etching
processes; (b) estimating facility N2O emissions; (c)
estimating emissions from heat transfer fluids; and (d) reporting
controlled emissions from abatement equipment. The methods described
and proposed in this section are for estimating emissions that would be
required to be reported under this subpart (see proposed sections 98.93
and 98.94). It is important to note that these methods differ from
those proposed in the section above which are for determining
applicability of the subpart.
a. Methods for Estimating Em