Federal Requirements Under the Underground Injection Control (UIC) Program for Carbon Dioxide (CO2, 44802-44813 [E9-20920]
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(h) * * *
(2) Registration. Active Duty sponsors
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(3) * * *
(v) Public facility use. (A) An ECHO
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(j) Effective date. All changes to this
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Dated: August 21, 2009.
Patricia Toppings,
OSD Federal Register Liaison Officer,
Department of Defense.
[FR Doc. E9–20685 Filed 8–28–09; 8:45 am]
BILLING CODE 5001–06–P
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ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Part 146
[EPA–HQ–OW–2008–0390; FRL–8951–3]
RIN 2040–AE98
Federal Requirements Under the
Underground Injection Control (UIC)
Program for Carbon Dioxide (CO2)
Geologic Sequestration (GS) Wells;
Notice of Data Availability and Request
for Comment
AGENCY: Environmental Protection
Agency (EPA).
ACTION: Data availability; request for
comment.
SUMMARY: Today’s Notice supplements
the proposed ‘‘Federal Requirements
Under the Underground Injection
Control (UIC) Program for Carbon
Dioxide (CO2) Geologic Sequestration
(GS) Wells’’ of July 25, 2008, presents
new data and information, and requests
public comment on related issues that
have evolved in response to comments
on the original proposal. This Notice
contains preliminary field data from the
Department of Energy-sponsored
Regional Carbon Sequestration
Partnership projects, the results of GSrelated studies conducted by the
Lawrence Berkeley National Laboratory,
and additional GS-related research.
Today’s Notice also discusses comments
and presents an alternative the Agency
is considering related to the proposed
injection depth requirements for Class
VI wells.
DATES: Comments on the contents of
this NODA must be received on or
before October 15, 2009. EPA does not
plan to extend the comment period for
this Notice. EPA will hold a public
hearing from 9 a.m. to 12 p.m. and 1
p.m. to 4 p.m., CDT, September 17, 2009
in Chicago, IL.
ADDRESSES: The public hearing will be
held at the Ralph H. Metcalfe Federal
Building, 77 W. Jackson Boulevard,
Chicago, IL 60604. Due to capacity
limitations, we encourage you to
indicate your intent to participate
through pre-registration. To pre-register,
for directions, and for site specific
information, please visit the following
Web site: https://
gshearing.cadmusweb.com/.
Submit your comments, identified by
Docket ID No. EPA–HQ–OW–2008–
0390, by one of the following methods:
• https://www.regulations.gov: Follow
the on-line instructions for submitting
comments.
• Mail: Water Docket, Environmental
Protection Agency, Mailcode: 4101T,
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1200 Pennsylvania Ave., NW.,
Washington, DC 20460.
• Hand Delivery: Water Docket, EPA
Docket Center (EPA/DC), Public Reading
Room, Room 3334, EPA West, 1301
Constitution Ave., NW., Washington,
DC. Such deliveries are only accepted
during the Docket’s normal hours of
operation which are 8:30 a.m. to 4:30
p.m., and special arrangements should
be made for deliveries of boxed
information.
Instructions: Direct your comments to
Docket ID No. EPA–HQ–OW–2008–
0390. EPA’s policy is that all comments
received will be included in the public
docket without change and may be
made available online at https://
www.regulations.gov, including any
personal information provided, unless
the comment includes information
claimed to be Confidential Business
Information (CBI) or other information
whose disclosure is restricted by statute.
Do not submit information that you
consider to be CBI or otherwise
protected through https://
www.regulations.gov or e-mail. Contact
EPA directly (see the FOR FURTHER
INFORMATION CONTACT section) prior to
submitting CBI. The https://
www.regulations.gov Web site is an
‘‘anonymous access’’ system, which
means EPA will not know your identity
or contact information unless you
provide it in the body of your comment.
If you send an e-mail comment directly
to EPA without going through https://
www.regulations.gov your e-mail
address will be automatically captured
and included as part of the comment
that is placed in the public docket and
made available on the Internet. If you
submit an electronic comment, EPA
recommends that you include your
name and other contact information in
the body of your comment and with any
disk or CD–ROM you submit. If EPA
cannot read your comment due to
technical difficulties and cannot contact
you for clarification, EPA may not be
able to consider your comment.
Electronic files should avoid the use of
special characters, any form of
encryption, and be free of any defects or
viruses.
Docket: All documents in the docket
are listed in the https://
www.regulations.gov index. Although
listed in the index, some information is
not publicly available, e.g., CBI or other
information whose disclosure is
restricted by statute. Certain other
material, such as copyrighted material,
will be publicly available only in hard
copy. Publicly available docket
materials are available either
electronically in https://
www.regulations.gov or in hard copy at
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the Water Docket, EPA Docket Center
(EPA/DC), Public Reading Room, Room
3334, EPA West, 1301 Constitution
Ave., NW., Washington, DC. The Public
Reading Room is open from 8:30 a.m. to
4:30 p.m., Monday through Friday,
excluding legal holidays. The telephone
number for the Public Reading Room is
(202) 566–1744, and the telephone
number for the EPA Docket Center is
(202) 566–2426.
FOR FURTHER INFORMATION CONTACT:
Mary Rose Bayer, Underground
Injection Control Program, Drinking
Water Protection Division, Office of
Ground Water and Drinking Water (MC–
4606M), Environmental Protection
Agency, 1200 Pennsylvania Ave., NW.,
Washington, DC 20460; telephone
number: (202) 564–1981; e-mail
address: bayer.maryrose@epa.gov. For
general information, contact the Safe
Drinking Water Hotline, telephone
number: (800) 426–4791. The Safe
Drinking Water Hotline is open Monday
through Friday, excluding legal
holidays, from 10 a.m. to 4 p.m. Eastern
time. For general information about the
public hearing, please contact Sean
Porse by phone (202) 564–5990, by
e-mail at porse.sean@epa.gov, or by mail
at: US Environmental Protection
Agency, Mail Code 4606M, 1200
Pennsylvania Ave., NW., Washington,
DC 20460.
SUPPLEMENTARY INFORMATION:
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I. General Information
This Notice of Data Availability
(NODA) presents new information and
data related to geologic sequestration
(GS) of CO2 obtained after publication of
the July 25, 2008, proposed rule,
‘‘Federal Requirements Under the
Underground Injection Control (UIC)
Program for Carbon Dioxide (CO2)
Geologic Sequestration (GS) Wells’’ (73
FR 43492). The proposal is available
online at https://www.epa.gov/fedrgstr/
EPA-WATER/2008/July/Day-25/
w16626.htm. Availability of this new
information could change EPA’s
approach to the final rulemaking.
The purpose of this NODA is to
request public comment on new data
and on related issues that have evolved
in response to comments on the original
proposal. This Notice provides
additional information and data on the
topic of injection depth as described in
the July 25, 2008, proposal (73 FR
43492) and presents an alternative that
responds to comments received on this
issue. Therefore, EPA is providing the
opportunity for notice and comment on
the information provided in this Notice
as a supplement to the proposed rule.
The Agency seeks further public
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comment on any and all aspects of the
specific data and alternatives it has
identified in this Notice. EPA continues
to review the comments received on the
proposed rule and will address those
comments and the comments submitted
in response to this Notice in the final
action.
Persons interested in recent research
related to GS and proposed injection
depth requirements are encouraged to
read and respond to this NODA.
Additionally, owners and operators,
States, Tribes, and State co-regulators
involved in GS activities may wish to
comment on this publication.
Abbreviations and Acronyms
AL: Action Level
AoR: Area of Review
CBI: Confidential Business Information
CFR: Code of Federal Regulations
CCS: Carbon Capture and Storage
CO2: Carbon Dioxide
DOE: Department of Energy
EGR: Enhanced Gas Recovery
EPA: Environmental Protection Agency
EOR: Enhanced Oil Recovery
GS: Geologic Sequestration
GHG: Greenhouse Gas
IPCC: Intergovernmental Panel on Climate
Change
km: kilometer
LBNL: Lawrence Berkeley National Lab
m: meter
mg/l: milligrams per liter
Mt: Megaton
MCL: Maximum Contaminant Level
NETL: National Energy Technology
Laboratory
NWIS: National Water Information System
NODA: Notice of Data Availability
ORD: Office of Research and Development
PWS: Public Water System
PWSS: Public Water Supply Supervision
RCSPs: Regional Carbon Sequestration
Partnerships
SDWA: Safe Drinking Water Act
SECARB: Southeast Regional Carbon
Sequestration Partnership
STAR: Science to Achieve Results
SWP: Southwest Regional Partnership on
Carbon Sequestration
TDS: Total Dissolved Solids
UIC: Underground Injection Control
US: United States
USDW: Underground Source of Drinking
Water
USGS: United States Geological Survey
Definitions
Action Level (AL): The concentration
of lead or copper in water specified in
40 CFR 141.80(c) which determines, in
some cases, the treatment requirements
contained in subpart I of this part that
a water system is required to complete.
Area of review (AoR): The region
surrounding the geologic sequestration
project that may be impacted by the
injection activity. The area of review is
based on computational modeling that
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accounts for the physical and chemical
properties of all phases of the injected
carbon dioxide stream.
Buoyancy: Upward force on one phase
(e.g., a fluid) produced by the
surrounding fluid (e.g., a liquid or a gas)
in which it is fully or partially
immersed, caused by differences in
pressure or density.
Capillary force: Adhesive force that
holds a fluid in a capillary or a pore
space. Capillary force is a function of
the properties of the fluid, and surface
and dimensions of the space. If the
attraction between the fluid and surface
is greater than the interaction of fluid
molecules, the fluid will be held in
place.
Carbon Capture and Storage (CCS):
The process of capturing CO2 from an
emission source, (typically) converting
it to a supercritical state, transporting it
to an injection site, and injecting it into
deep subsurface rock formations for
long-term storage.
Carbon dioxide plume: The extent
underground, in three dimensions, of an
injected carbon dioxide stream.
Carbon dioxide (CO2) stream: Carbon
dioxide that has been captured from an
emission source (e.g., a power plant),
plus incidental associated substances
derived from the source materials and
the capture process, and any substances
added to the stream to enable or
improve the injection process. This
subpart does not apply to any carbon
dioxide stream that meets the definition
of a hazardous waste under 40 CFR part
261.
Class VI wells: Wells used for geologic
sequestration of carbon dioxide beneath
the lowermost formation containing a
USDW.
Confining zone: A geologic formation,
group of formations, or part of a
formation stratigraphically overlying the
injection zone that acts as a barrier to
fluid movement.
Corrective action: The use of Director
approved methods to assure that wells
within the area of review do not serve
as conduits for the movement of fluids
into underground sources of drinking
water (USDWs).
Director: The person responsible for
permitting, implementation, and
compliance of the UIC program. For UIC
programs administered by EPA, the
Director is the EPA Regional
Administrator; for UIC programs in
Primacy States, the Director is the
person responsible for permitting,
implementation, and compliance of the
State, Territorial, or Tribal UIC program.
Enhanced Oil or Gas Recovery (EOR/
EGR): Typically, the process of injecting
a fluid (e.g., water, brine, or CO2) into
an oil or gas bearing formation to
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recover residual oil or natural gas. The
injected fluid thins (decreases the
viscosity) or displaces small amounts of
extractable oil and gas, which is then
available for recovery. This is also
known as secondary or tertiary recovery.
Formation or geological formation: A
layer of rock that is made up of a certain
type of rock or a combination of types.
Geologic sequestration (GS): The longterm containment of a gaseous, liquid or
supercritical carbon dioxide stream in
subsurface geologic formations. This
term does not apply to its capture or
transport.
Geologic sequestration project: An
injection well or wells used to emplace
a CO2 stream beneath the lowermost
formation containing a USDW. It
includes the subsurface threedimensional extent of the carbon
dioxide plume, associated pressure
front, and displaced brine, as well as the
surface area above that delineated
region.
Injectate: The fluids injected. For the
purposes of this rule, this is also known
as the CO2 stream.
Injection zone: A geologic formation,
group of formations, or part of a
formation that is of sufficient areal
extent, thickness, porosity, and
permeability to receive carbon dioxide
through a well or wells associated with
a geologic sequestration project.
Maximum Contaminant Level (MCL):
The maximum permissible level of a
contaminant in water which is delivered
to any user of a public water system.
Model: A representation or simulation
of a phenomenon or process that is
difficult to observe directly or that
occurs over long time frames. Models
that support GS can predict the flow of
CO2 within the subsurface, accounting
for the properties and fluid content of
the subsurface formations and the
effects of injection parameters.
Pore space: Open spaces in rock or
soil. These are filled with water or other
fluids such as brine (i.e., salty fluid).
CO2 injected into the subsurface can
displace pre-existing fluids to occupy
some of the pore spaces of the rocks in
the injection zone.
Public Water System (PWS): A system
for the provision to the public of water
for human consumption through pipes
or, after August 5, 1998, other
constructed conveyances, if such system
has at least fifteen service connections
or regularly serves an average of at least
twenty-five individuals daily at least 60
days out of the year. Such term
includes: any collection, treatment,
storage, and distribution facilities under
control of the operator of such system
and used primarily in connection with
such system; and any collection or
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pretreatment storage facilities not under
such control which are used primarily
in connection with such system. Such
term does not include any ‘‘special
irrigation district.’’ A public water
system is either a ‘‘community water
system’’ or a ‘‘noncommunity water
system.’’
Pressure front: The zone of elevated
pressure that is created by the injection
of carbon dioxide into the subsurface.
For GS projects, the pressure front of a
CO2 plume refers to the zone where
there is a pressure differential sufficient
to cause the movement of injected fluids
or formation fluids into a USDW.
Saline formations: Deep and
geographically extensive sedimentary
rock layers saturated with waters or
brines that have a high total dissolved
solids (TDS) content (i.e., over 10,000
mg/l TDS). Saline formations offer great
potential for CO2 storage capacity.
Stratigraphic zone (unit): A layer of
rock (or stratum) that is recognized as a
unit based on lithology, fossil content,
age or other properties.
Total Dissolved Solids (TDS): The
measurement, usually in mg/l, for the
amount of all inorganic and organic
substances suspended in liquid as
molecules, ions, or granules. For
injection operations, TDS typically
refers to the saline (i.e., salt) content of
water-saturated underground
formations.
Transmissive fault or fracture: A fault
or fracture that has sufficient
permeability and vertical extent to allow
fluids to move between formations.
Trapping: The physical and
geochemical processes by which
injected CO2 is sequestered in the
subsurface. Physical trapping occurs
when buoyant CO2 rises in the
formation until it reaches a layer that
inhibits further upward migration or is
immobilized in pore spaces due to
capillary forces. Geochemical trapping
occurs when chemical reactions
between dissolved CO2 and minerals in
the formation lead to the precipitation
of solid carbonate minerals.
Underground Source of Drinking
Water (USDW): as defined under 40 CFR
part 144.3, an aquifer or portion of an
aquifer that supplies any public water
system or that contains a sufficient
quantity of ground water to supply a
public water system, and currently
supplies drinking water for human
consumption, or that contains fewer
than 10,000 mg/l total dissolved solids
and is not an exempted aquifer.
Special Accommodations: For
information on access or
accommodations for individuals with
disabilities, please contact Sean Porse at
(202) 564–5990 or by e-mail at
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porse.sean@epa.gov. Please allow at
least 10 days prior to the meeting, to
give EPA time to process your request.
II. What Did EPA Propose?
On July 25, 2008, EPA published the
proposed ‘‘Federal Requirements Under
the Underground Injection Control (UIC)
Program for Carbon Dioxide (CO2)
Geologic Sequestration (GS) Wells.’’ (73
FR 43492) The Agency proposed a new
class of injection well (Class VI) along
with technical criteria for permitting GS
wells, including criteria for geologic site
characterization, area of review (AoR)
and corrective action, well construction,
operation, mechanical integrity testing,
monitoring, well plugging, postinjection site care, and site closure.
These standards, if finalized, would
protect underground sources of drinking
water (USDWs) under the Safe Drinking
Water Act (SDWA). The technical
criteria in the proposed rule are based
on the existing UIC regulatory
framework under the SDWA for deep
injection wells, with modifications to
address the unique nature of CO2
injection for GS.
Existing GS project experience,
natural and industrial analogs, research,
and current regulatory experience with
underground injection were considered
in the development of the proposed
rule. Ongoing research builds upon the
existing foundation of substantial
literature on CO2 injection and storage,
some of which is available in the docket
for this rulemaking. While CO2 injection
to extract oil and gas has taken place for
many years, the use of UIC wells to
inject large quantities of CO2 for longterm storage is a relatively new practice.
There are current projects and research
underway that examine and
demonstrate the effectiveness of
underground injection as a tool for
sequestering CO2.
For example, there are four
commercial projects in operation today:
• Sleipner (Norwegian North Sea)—1
Mt CO2/yr injected since 1996;
• Weyburn (Canada)—1 Mt CO2/yr
injected since 2000;
• In Salah (Algeria)—1.2 Mt CO2/yr
injected since 2004;
• Snohvit (Norway)—0.7 Mt CO2/yr
injected since 2008.
Many additional large-scale projects
are funded and under development
worldwide.
The purpose of this NODA is to
provide an update on newly available
information and data related to research
focused specifically on GS for long-term
storage—with particular emphasis on
data, research, and information that has
become available since the July proposal
publication.
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In addition, the proposed rule
contains a discussion of injection depth.
In the July 2008 FR Notice, EPA
proposed that the injection of CO2 be
confined to areas below the lowermost
USDW (in the absence of an aquifer
exemption). This approach is consistent
with the approach used for other deep
UIC wells; however, circumstances in a
few States may warrant an alternative
approach. Today’s Notice provides
additional discussion on an alternative
the Agency is considering related to
injection depth for GS wells.
EPA received a number of comments
indicating that the Agency should
further explore environmental and
regulatory issues beyond the scope of
the proposed SDWA requirements for
underground injection of CO2 for GS.
EPA recognizes that a more
comprehensive framework may be
needed and that some stakeholders
remain uncertain with respect to the
potential applicability of other Federal
environmental statutes such as the
Clean Air Act, the Resource
Conservation and Recovery Act, and the
Comprehensive Environmental
Response, Compensation, and Liability
Act to various aspects of geologic
sequestration of CO2. The Agency is
currently evaluating the need for a more
comprehensive regulatory framework to
provide legal guidance regarding this
emerging technology. If the Agency
chooses to pursue a more
comprehensive regulatory approach to
this subject, it will seek public comment
on any proposal it develops for this
framework and will also endeavor to
issue a more comprehensive rule in the
same time frame as it has planned for
the stand-alone UIC GS rulemaking.
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III. Research, Data Analysis, and
Findings
A. Content of NODA and Summary of
Comments
In this Notice, EPA is providing a
short summary of several ongoing GS
studies and interim information on
current GS projects relevant to topics
within the proposed GS regulation. This
information and data were provided or
made available after publication of the
proposal in July 2008. More detailed
information on the GS research and
projects discussed below is available for
review online as part of the docket for
this rulemaking. EPA is providing this
data and associated project summaries
because the Agency expects that there
may be additional studies and data on
other GS projects, the use of existing
technologies, and GS-related research
that may inform the Agency’s regulatory
development process for GS. Such data
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could contribute to the Agency’s
understanding of site characterization,
well construction, operation, and
monitoring requirements. The Agency
requests comment on data and research
discussed in today’s Notice and how the
Agency might use this data and research
in developing the final rule. The Agency
also requests submission of additional
GS studies related to the data and
research discussed in this Notice to
inform the GS rulemaking.
In the preamble of the proposed rule,
EPA described an adaptive approach to
developing regulations for GS. This
approach would allow the Agency to
establish regulations to protect USDWs
and enable the Agency to make changes
to regulations over time as information
from demonstration projects and other
studies becomes available. EPA received
comments from stakeholders requesting
that additional data be made available to
the public before a final rulemaking
(particularly related to specific areas of
GS) and indicating that more research is
needed to support GS in general. Many
commenters suggested that
supplementary research on GS is
necessary prior to rule promulgation
and that EPA should wait until the
Department of Energy (DOE)-sponsored
Phase II and Phase III pilot projects are
complete before finalizing the GS rule.
Others believed that a final rulemaking
should proceed and that new
information and data from ongoing GS
research should be considered and
incorporated over time as part of an
adaptive rulemaking process. Comments
on the proposal encouraged additional
research and investigations on areas
including (but not limited to): Confining
zone characterization; modeling; CO2
plume movement; geochemistry;
impacts of GS on saline formations;
leakage from abandoned wells caused
by material and cement degradation;
potential pathways for contamination of
USDWs; leak mitigation and
remediation; and criteria for
determining that the CO2 plume has
stabilized.
The Agency is actively tracking the
progress of the Regional Carbon
Sequestration Partnership (RCSP) GS
and carbon capture and storage projects.
The RCSPs have been compiling
information related to their pilot and
demonstration projects and have been
developing research projects related to
these efforts. A summary of several of
these projects is available in today’s
Notice.
In addition, EPA’s Office of Research
and Development is conducting
intramural and extramural research
activities to develop modeling and
monitoring tools for protecting
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underground sources of drinking water.
Laboratory, modeling, and field
investigations are focusing on a variety
of injection and storage scenarios and
candidate injection sites. Analytic and
semi-analytic models are being
developed and evaluated for
determining the area of review based on
geologic and hydrologic conditions.
Comprehensive laboratory tests are
being applied to the development and
field-testing of monitoring strategies that
can detect migration of fluids into
shallow aquifers and assess potential
geochemical impacts. The ultimate goal
of these research activities is to provide
more robust tools for permitting,
monitoring, and evaluating GS sites
from injection through post-injection
site care and site closure to prevent
endangerment of USDWs. EPA is also
funding six projects for the study of
ground water and human health impacts
of GS through the Science To Achieve
Results (STAR) grant program. The
awards will be announced this fall on
EPA’s Web site (https://es.epa.gov/ncer/).
Furthermore, EPA and DOE have
jointly supported GS-related studies at
Lawrence Berkeley National Lab
(LBNL), described in Section II.B. These
studies use modeling to predict the
potential impacts on ground water from
GS activities.
B. DOE-Sponsored Regional Carbon
Sequestration Partnership Projects
Currently, DOE’s National Energy
Technology Laboratory (NETL) is
developing and/or operating
approximately 30 GS projects, a number
of which have either completed
injection or are in the process of
injecting CO2. The purpose of these
projects is to ‘‘help determine the best
approaches for capturing and
permanently storing gases that can
contribute to global climate change’’ and
to determine ‘‘the most suitable
technologies, regulations, and
infrastructure needs for carbon capture,
storage, and sequestration in different
parts of the country’’ (https://
www.netl.doe.gov/technologies/
carbon_seq/partnerships/
partnerships.html). Through
cooperation with DOE, EPA has
obtained pilot project data from several
of these GS projects. RCSPs are
conducting pilot and demonstration
projects to study: site characterization
(including injection and confining
formation information, core data and
site selection information); well
construction (well depth, construction
materials, and proximity to USDWs);
frequency and types of tests and
monitoring conducted (on the well and
on the project site); modeling and
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monitoring results; and injection
operation (injection rates, pressures, and
volumes, CO2 source and co-injectates).
In addition to information available in
the docket for this NODA, information
on some of these projects is available at
https://www.netl.doe.gov/publications/
proceedings/08/rcsp/. The following is a
short summary of select project
activities and data generated.
Escatawpa, Mississippi (MS); Southeast
Regional Carbon Sequestration
Partnership (SECARB)
SECARB is conducting a CO2
injection test in Jackson County, MS
into a deep saline reservoir along the
Gulf Coast that had not previously been
characterized for oil and gas
exploration. The injection zone, 9,500
feet (2,896 meters) deep in the Lower
Tuscaloosa Massive Sand Unit, is
overlain by two confining layers. The
site is near the Victor J. Daniel Power
Plant, the source of the CO2, which was
delivered to the injection site via truck.
Characterization of the site is based
on a wealth of geophysical and corederived information, including well
core samples, open-hole and cased-hole
well logging, baseline vertical seismic
profiling, and pressure transient testing.
Baseline sampling and analysis of
formation fluids and soil flux sampling
were also performed. The SECARB team
performed a 3-dimensional simulation
to estimate injectivity, storage capacity,
and long-term fate of the injected CO2.
The model estimated that the plume
would extend up to 350 feet (106.7
meters) at the end of the injection test.
An injection well and a monitoring
well were drilled at the site. The
injection well is permitted by the
Mississippi Department of
Environmental Quality as a UIC Class V
experimental well. Both the injection
and monitoring well were constructed
with surface and long-string casing that
was cemented from the injection zone to
the surface. Pre-injection mechanical
integrity tests of the injection and
monitoring well (annulus pressure test,
radioactive tracer survey, differential
temperature survey, and pressure fall-off
tests) met UIC Class I requirements.
In October of 2008, 3,027 tons (2,746
tonnes) of CO2 were injected into the
well; injection rates averaged 170 to 180
tons/day (154 to 163 tonnes/day).
Continuous monitoring devices were
used to record (at 30 second intervals):
Injection pressure, annular pressure,
temperature, and rate. The injection was
complete on October 28, 2008.
SECARB is continuing to monitor
activities at the site through surface or
near-surface monitoring for upward CO2
seepage via groundwater sampling, soil
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flux sampling and tracer detection. The
purpose of this monitoring and
sampling is to determine whether CO2 is
migrating upward from the injection
zone. To date, there has been no
indication of the return of the injected
CO2 in the shallow subsurface. SECARB
also plans to employ time-lapse seismic
and geophysical tools to determine the
deep subsurface fate of the injectate.
This SECARB project employs,
demonstrates, and validates the EPA’s
proposed Class VI well construction,
operational, and monitoring
requirements. The use of surface and
near-surface monitoring techniques
provides the EPA with preliminary
information regarding the efficacy and
appropriateness of these technologies at
certain sites; and supports the need for
a site-specific monitoring plan that will
allow use of a range of monitoring
technologies suitable for each unique
GS site. This information and public
comments on this research will be used
to inform the Agency’s final rulemaking.
For additional information about the
Escatawpa Project, see the full report in
the docket for today’s publication.
Aneth Field, Paradox Basin, Southeast
Utah (UT); Southwest Regional
Partnership on Carbon Sequestration
(SWP)
The Aneth Field is the site of an
experimental combined EOR–GS test by
the Southwest Partnership. The primary
CO2 injection target is the carbonate
Paradox Formation, which is
approximately 5,600 to 5,800 feet (1,707
to 1,768 meters) deep, and is overlain by
the low-permeability Gothic Shale.
Petrographic, geochemical and
mechanical analyses of the Gothic Shale
are underway or planned.
CO2 injection began in August 2007,
and approximately 150,000 tons
(136,077 tonnes) of CO2 have been
injected to date. Extensive monitoring of
the site is complete or underway.
Monitoring activities at the site include
time-lapse vertical seismic profiling,
microseismic monitoring, geochemical
and tracer tests, CO2 soil flux
measurements, a surface fracture and
banding study, and self-potential
monitoring.
Monitoring data are being used to
establish parameters for state-of-the-art
mathematical reservoir models, which
include coupling of multiphase CO2ground water flow, rock deformation,
and chemical reactions to evaluate
residence times, migration patterns and
rates, and effects of CO2 injection on
fluid pressures and rock strain.
The Aneth Field project confirms the
need for a project design with a robust
monitoring plan, and tests the
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importance of monitoring and modeling
agreement in GS projects. In addition,
the project demonstrates the utility of
various monitoring technologies that
may be used by owners and operators of
Class VI wells. This information and
public comments on this research will
be used to inform the Agency’s final
rulemaking.
Pump Canyon Site, Near Archuleta,
New Mexico (NM); Southwest Regional
Partnership on Carbon Sequestration
(SWP)
The SWP is conducting a Phase II
project of CO2 injection into deep,
unmineable coal seams at the Pump
Canyon Site near Archuleta, NM. To
support characterization of the site, the
SWP is performing a ‘‘seal analysis’’ of
the ability of the Kirtland Formation to
act as a barrier to the movement of CO2
or other reservoir fluids. The Kirtland
Formation is a major, regional aquitard
and reservoir seal that directly overlies
the geologic formation containing the
coal seams.
To characterize the Kirtland
Formation, detailed studies of geological
core samples, downhole geophysical
logs, and outcrop studies were
conducted. Complete and in-progress
laboratory analyses include electron
microscopic studies of petrographic and
petrophysical properties; capillary
pressure measurements; multiscale
fracture characterization using well logs
and core analysis; descriptions of
stratigraphic columns and sedimentary
structures based on cores; pore size
distributions analysis using BET
(Brunauer-Emmett-Teller), and
geomechanical analyses of the caprock
and overlying aquifer.
Operators are actively monitoring
potential surface deformation from
injection through the use of tilt meters
and radar-based Interferrometric
Synthetic Aperture Radar (InSAR) in
addition to monitoring the site’s
injection pressure. They are also
tracking the CO2 plume through
continuous sampling of immediate
offset production wells and through
perfluorocarbon gas tracers (PFT) and
naphthalene sulfonate water tracers
(NST) introduced into the CO2 injection
stream. These tracers are used for
identification in the unlikely event of
reservoir leakage.
The Agency sought comment on using
unmineable coal seams for GS in the
proposed rule. The investigation at
Pump Canyon will inform a
determination on whether CO2 can be
effectively and safely sequestered in
coal seams.
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1. Ground Water Quality Changes
Related to the Mobilization of Trace
Elements
C. Lawrence Berkeley National
Laboratory (LBNL) Studies
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For further information on aspects of
the Pump Canyon project, please refer to
data available in the NODA docket.
Summary
LBNL used a comprehensive
computational model to evaluate the
potential impact of CO2 leaking from
deep geologic sequestration sites on the
concentrations of trace elements in
potable ground waters (Birkholzer et al.,
2008a). LBNL estimated the amount of
trace elements from native mineral
species that could potentially be
mobilized by the intrusion of CO2, and
the potential ground water
concentrations that could result. LBNL
then compared these estimates to EPA’s
Maximum Contaminant Levels (MCLs)
and Action Levels (ALs) for drinking
water to determine the potential for
drinking water standards to be
exceeded. It is important to note that
model results were dependent on
several assumptions and parameter
values with a large degree of
uncertainty, such as dissolution and
dissociation constants. LBNL
recommended that further studies
should be conducted, including
laboratory or field experiments and
evaluation of natural analogues.
LBNL conducted multiple model runs
to assess a variety of scenarios and
aquifer conditions and, as discussed
below, found that if injected CO2 comes
into contact with shallow USDWs, some
trace element concentrations such as
arsenic could increase.
An improperly managed GS project
has the potential to endanger USDWs.
The factors that increase the risk of
USDW contamination are complex and
can include improper siting,
construction, operation and monitoring
of GS projects. The proposed GS
requirements address endangerment to
USDWs by establishing new Federal
requirements for the proper
management of CO2 injection and
storage. Risks to USDWs from
improperly managed GS projects can
include CO2 migration into USDWs,
causing the leaching and mobilization of
contaminants (e.g., arsenic, lead, and
organic compounds), changes in
regional groundwater flow, and the
movement of greater salinity formation
fluids into USDWs, causing degradation
of water quality. As mentioned in
Section II of this Notice and in the
proposal, CO2 has been injected on large
scales at four sites: at Sleipner in the
North Sea, at In Salah in Algeria, at
Snohvit in Norway, and in the Weyburn
Field in Alberta, Canada. There have
been no documented cases of leakage
from these projects. Additionally, for
decades, the oil and gas industry has
been safely injecting CO2 for the
purpose of enhanced oil and gas
recovery.
LBNL is studying the potential effects
of CO2 injection on ground water and
surrounding formations to determine
the potential for impacts on USDWs and
human health in the event that a GS
project is not properly sited, operated,
or managed. Specifically, LBNL is
evaluating the potential for GS to cause
changes in ground water quality as a
result of CO2 leakage and subsequent
mobilization of trace elements such as
arsenic, barium, cadmium, mercury,
lead, antimony, selenium, zinc, and
uranium. In addition, LBNL is
evaluating basin-scale hydrological
impacts of large-volume injection of CO2
on groundwater aquifers and in
particular, the pressure front impacts
caused by GS. Summaries of the interim
results for these research areas are
discussed below. The full publications
are available in the docket and on
LBNL’s Web site at https://esd.lbl.gov/
GCS/projects/CO2/index_CO2.html.
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Identification of Trace Elements of
Concern
An important step in developing the
model used to assess the different
scenarios was the identification of
naturally occurring minerals that could
act as a source of trace elements in
ground water if they were to come into
contact with CO2. This identification
was accomplished through an extensive
review of the scientific literature,
through which potential minerals of
concern were identified. The presence
of these minerals in aquifer rocks was
indirectly substantiated through an
evaluation of more than 38,000 waterquality analyses from potable aquifers
reported in the United States Geological
Survey’s (USGS) National Water
Information System (NWIS). While the
abundances of these host minerals are
typically very small, all trace elements
targeted for study occur frequently in
soils, sediments, and aquifer rocks.
A preliminary assessment of CO2related water quality changes, including
pH, was conducted by calculating the
expected equilibrium concentrations of
trace elements as a function of the
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amount of CO2 in a representative
potable groundwater. Results of this
modeling obtained for typical aquifers
under reducing conditions indicate that
arsenic could potentially exceed Federal
drinking water standards at elevated
CO2 concentrations (40 CFR 141.62
(b)(16)). Other trace elements, such as
barium, cadmium, lead, antimony, and
zinc, may also be mobilized in certain
circumstances, but the majority of
results did not show mobilization at
levels exceeding the MCL or AL.
LBNL used reactive-transport
modeling to further study the fate and
transport of arsenic and lead in a
representative potable aquifer as
influenced by leakage of CO2. This
study is described as follows:
Prediction of the Fate and Transport of
Trace Elements
LBNL used the reactive-transport
model TOUGHREACT to 1) study and
predict the transport of CO2 within a
shallow aquifer, 2) estimate potential
geochemical changes caused by the
presence of CO2, and 3) estimate the fate
and transport of mobilized trace
elements. LBNL conducted sensitivity
studies to account for a range of
conditions found in potable aquifers
throughout the US and to evaluate the
uncertainty associated with geochemical
processes and model parameters.
Starting with a representative ground
water under equilibrium conditions, the
model was used to estimate the impact
of CO2 leakage into the aquifer for 100
years. For this analysis, the investigators
assumed a hypothetical release scenario
based on CO2 escape from a deep
geologic sequestration site via a
preferential pathway, such as a fault
zone, entering the shallow aquifer at a
constant rate.
Results from this model simulation
suggest that if CO2 were to leak into a
shallow aquifer, the potential for
mobilization of lead and arsenic could
be enhanced, causing increases in the
concentration of these trace elements in
ground water. While LBNL studies did
suggest that CO2 interaction could cause
significant concentration increases
compared to the initial water
composition, the MCL for arsenic was
exceeded in only a few simulation
scenarios, while the lead concentrations
remained below the AL under all
scenarios. It is important to emphasize
that these studies looked at potential
consequences of CO2 leakage into the
USDW, not the likelihood of such
leakage occurring. The goal of the UIC
program and these regulations is to
ensure that injectate does not
contaminate USDWs in the first place.
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The Agency will use these
preliminary results and public
comments on this research as well as
potential site-specific analyses, to refine
and inform site characterization,
monitoring, and remediation
requirements and guidance, if
necessary, in the Agency’s final
rulemaking. The Agency seeks comment
on this research and any additional
studies related to a) mobilization of
constituents and b) the likelihood or
frequency of such leakage/risks.
2. Basin-Scale Hydrologic Impacts of
CO2 Storage
Summary
Pressure build-up from large volume
CO2 sequestration has been researched
since the early 1990s. Recent studies
have focused on better understanding
large-scale pressure responses for future
geologic sequestration projects (Zhou et
al., 2008; Van der Meer and Yavuz,
2008; Nicot, 2008; Birkholzer et al.,
2009). LBNL studied a hypothetical,
future scenario of GS in a sedimentary
basin as an illustrative example to
demonstrate the potential for basin-scale
hydrologic impacts of CO2 storage
(Birkholzer et al., 2008b).
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Sedimentary Basin Case Study
The example basin considered in this
case study contains deep saline
formations that are potential targets for
large-scale CO2 storage projects because
they are geologically favorable for
permanent CO2 storage and the region
has many large stationary sources of
CO2. The basin contains a thick,
extensive, high porosity, high
permeability sandstone that is the
primary target for CO2 storage. A
superior confining shale layer is also
present, making it an ideal site for
geologic sequestration projects.
LBNL used a preliminary
computational hydrogeologic model of
the basin to simulate regional ground
water flow patterns as influenced by
large-scale deployment of GS in the
region. The model assumed a scenario
where 20 independent GS projects
spaced throughout the center of a 570
kilometers (km) by 550 km (354 miles
by 342 miles) model domain each
injected 5 million tonnes (5.51 million
tons) of CO2 per year over 50 years. (The
largest injection today is on the order of
a million/tons/per year). Modeling
results for this simulation indicated that
the maximum size of each CO2 plume
was 6–8 km (3.7–5 miles) with lateral
separation between each GS project of
about 30 km (18.6 miles). These model
results suggest that the basin is
favorable for effective trapping of CO2.
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In addition, simulation runs indicated
that injection pressures did not exceed
fracture pressure or the maximum value
used in the model for this basin.
However, results also indicated that farfield pressure changes could propagate
as far away as 200 km (124 miles) from
the core injection area where the
geologic sequestration projects are
located. After CO2 injection ended in
the simulation, pressure buildup in the
injection zone began to dissipate while
the far-field pressure response
continued to increase and expand. For
this simulation example, a pressure
increase of 0.5 bar existed at an areal
extent of nearly 400 km by 400 km (249
miles by 249 miles) after 50 years. These
model results indicate that basin-wide
pressure influences can be large and
may have intersecting pressure
perturbations in a multiple-site
scenario. While simulated changes in
salinity within the storage formation
were relatively small, the predicted
pressure changes could push saline
water upward into overlying aquifers if
localized pathways such as conductive
faults existed. As these large scale
simulations indicated, limitations on
injection volumes related to basin-scale
pressure build-up should be considered
during CO2 capacity estimation.
EPA believes that the example studied
by LBNL illustrates the importance of
basin-scale evaluation of reservoir
pressures and far-field pressures
resulting from CO2 injection. EPA
requests comment on this study and
welcomes additional studies that
provide information on the need for
basin-scale evaluations for GS injection.
D. Additional GS Research
There are international, consensusbased and peer-reviewed reports on
CCS, including the Intergovernmental
Panel on Climate Change (IPCC) Special
Report on Carbon Dioxide Capture and
Storage (IPCC, 2005), which specifically
includes a chapter on GS drawn from
published literature and research
studies. Comprehensive reviews of the
results from GS research are also
available (e.g., Holloway, 2001;
Friedman, 2007; Tsang et al., 2008).
EPA will continue to track research
project development and literature
published by DOE and international
governments and organizations
including the International Energy
Agency (IEA), IEA Greenhouse Gas
Programme, and other major
international CCS initiatives.
With respect to geologic and reservoir
modeling, EPA has conducted one such
synthesis and analysis of GS research to
inform the rulemaking efforts. Schnaar
and Digiulio (2009) present a research
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review of over forty GS modeling
studies spanning from 1993–2008. This
review found that GS models are based
on pre-existing codes that have been
developed for predicting the movement
of water and solutes in soil, the behavior
of groundwater contaminants at
hazardous waste sites, and the recovery
of oil and gas from petroleum-bearing
formations. However, modeling the
injection and sequestration of CO2 poses
unique challenges, such as the need to
properly characterize CO2 transport
properties across a large range of
temperatures and pressures, and the
need to couple multiphase flow,
reactive transport, and geomechanical
processes. The authors reviewed studies
that demonstrated the use of modeling
in project design, site characterization,
assessments of leakage, and site
monitoring.
The complete modeling review is
available in the online public docket at
https://www.regulations.gov. A list of
recent publications addressing potential
environmental risks and risk
management approaches for GS sites is
also available in the docket. The Agency
may use information generated from
these studies to identify implementation
guidance needs and refine the proposed
requirements. EPA seeks comment on
these studies and requests other
research on geologic and reservoir
modeling as well as research associated
with potential environmental risks and
risk management approaches for GS.
IV. Injection Depth for GS Projects
A. What did EPA propose for Class VI
well injection depth relative to the
location of USDWs?
In the proposed rule, EPA defined
Class VI injection wells as wells used
for GS (injection) of CO2 beneath the
lowermost formation containing a
USDW. In Section III.A.4 of the
preamble, EPA discussed Injection
Depth in Relation to USDWs to further
clarify the Agency’s expectations
regarding injection depth for Class VI
wells. The proposed requirements
would preclude injection of CO2 into
zones in between and above USDWs.
EPA is aware that confining Class VI
CO2 injection to below the lowermost
USDW may restrict the use of
sequestration in areas of the country
with deep USDWs where well
construction would be technically
impractical or infeasible. As proposed,
the definition would also preclude
injection of CO2 into shallow formations
such as coal seams and basalts. The
Agency requested comment on
alternative approaches that would allow
injection between and/or above the
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lowermost USDW and thus potentially
allow for more areas to be available for
GS while continuing to prevent
endangerment of USDWs.
Approaches on which the Agency
sought comment in the preamble, as
alternatives to the proposed injection
depth requirements included:
• Allowing Class VI CO2 injection
above the lowermost USDW when the
Director determines that geologic
conditions exist that will prevent fluid
movement into adjacent USDWs;
• Allowing the use of an aquifer
exemption process for Class VI
injection; and,
• Establishing, by regulation, a
minimum injection depth for GS of CO2.
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B. Why did EPA propose that Class VI
wells inject below the lowermost USDW?
EPA initiated the regulatory
development process for GS and
proposed new, tailored Federal
requirements appropriate for the unique
nature of injecting large volumes of CO2
for long-term storage to ensure that
USDWs are not endangered. The
proposed injection depth requirements
for Class VI wells are consistent with
the siting and operational requirements
for deep, technically sophisticated Class
I wells and are an important component
of the UIC program.
The basis of these requirements is the
principle that placing distance between
the injection formation and USDWs
decreases risks to USDWs. In these
deep-well injection scenarios, the added
depth and distance between the
injection zone and overlying formations
serve both as a buffer allowing for
pressure dissipation and as a zone for
monitoring that may detect any
excursions (of the injectate) out of the
injection zone. Additional distance also
allows trapping mechanisms, including
dissolution of CO2 in native fluids and
mineralization, to occur over time—
thereby reducing risks that CO2 may
migrate from the injection zone and
endanger USDWs. Additionally, the
depth and distance below the lowermost
USDW allow the potential for the
presence of additional confining layers
(between the injection zone and
overlying formations/USDWs).
C. Injection Depth Comments, Data, and
Research
EPA received a range of comments
both in support of, and opposed to, the
proposed injection depth requirements
for Class VI wells.
Comments Supporting the Proposed
Injection Depth Requirements
Comments that supported the
proposed requirements indicated that
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injection should be constrained to
below the lowermost USDW (should not
be allowed above and/or between
USDWs) because:
• SDWA requires the UIC program to
promulgate regulations (including
injection depth requirements) that
maximize USDW protection;
• Injection below the lowermost
USDW is a long-standing principle of
UIC deep well injection;
• In many cases, injection below the
lowermost USDW ensures a greater
distance between the injection zone and
USDWs;
• GS is a new/unproven technology
(at large scale) and, in the early years of
deployment, injection depth limitations
are prudent. These requirements could
be relaxed in the future as information
is learned about GS injection;
• Keeping injection below the
lowermost USDW will reduce the
likelihood of wells (e.g., water, mineral,
and/or hydrocarbon production) being
drilled through a CO2 plume in the
future.
These comments and concerns about
injection depth are further supported by
ongoing research, data, and activities
related to water use, availability, and
planning; some of this research and data
were submitted to the proposed rule
docket (e.g., EPA–HQ–OW–2008–0390–
0181.1). Water availability research in
the United States indicates that water
treatment of higher salinity waters (in
excess of the USDW protectiveness
threshold of 10,000 ppm TDS) may be
more cost effective than the cost of
obtaining water rights or surface water
elsewhere in the area (Sengebush, 2008).
Additionally, as technologies advance,
treatment of increasingly deeper and/or
higher salinity waters may become a
common practice employed in many
communities throughout the US. Other
studies support the need to consider
long-term drinking water protection and
the confluence of population growth
and constrained water resources in parts
of the US when developing injection
depth requirements (US Government
Accountability Office, 2003; Davidson,
et al., 2008).
Comments Opposed to the Proposed
Injection Depth Requirements
Those opposed to the proposed
requirements supported allowing
injection above and between USDWs.
These commenters indicated that such
injection should be allowed under the
following conditions and based on the
following arguments:
• At any depth without limitations;
• Based on site-specific information
and in certain geologic settings, where
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44809
there are adequate confining systems
above and below the injection zone;
• Where formations have been
exempted (for other injection purposes)
and/or where the formations are greater
than 10,000 ppm TDS;
• Based on geographically delineated
exemptions (e.g., specifically delineated
formations, basins, or regions where
injection could occur at depths above/
between USDW);
• Because many parts of the country
will be excluded from GS activities and
as a result CCS deployment may be
restricted (if this requirement is
maintained as written);
• Because Class II, Class III, and Class
V operations are already injecting above
the lowermost USDW without any
potential for threats to underlying (or
overlying) USDWs; and,
• Because there should not be a
blanket prohibition for Class VI GS
wells.
Research, information, and comments
that support allowing injection above
and between USDWs have focused on
climate change mitigation, CO2 geologic
storage capacity assessments, and
current UIC injection practices.
Commenters interested in climate
change mitigation emphasized the role
that GS will play in reducing
greenhouse gas (GHG) emissions while
national GS capacity estimates focus on
formations irrespective of depth (above/
below the lowermost USDW).
Furthermore, some specific research on
CO2 injection for GS into various
formations including shallow, volcanic
rocks such as flood basalts (McGrail, et
al., 2006) and coal seam injection
(Dooley, et al., 2006; IPCC, 2005; MIT
2007; White et al., 2005) illustrates the
potential for GS in these formations, but
only if there is depth requirement
flexibility. Certain States have indicated
that where USDWs are very deep (e.g.,
15,000 ft/4,572 meters and deeper) and
layered (stratified) these regions would
become unavailable for large-scale GS
projects because injectors would not be
able to comply with the current
injection depth (and well construction)
requirements. These States suggest that
GS should be allowed in certain areas if
a site-specific demonstration can be
made that USDWs will be protected.
Some comments support the
suggestion that current Class II, Class III,
and Class V injection activities
occurring above and between USDWs
may serve as a viable analogue for GS
injection depth requirements. Class II
and Class III owners and operators of
sites where injection is taking place
above and between USDWs must
identify and demonstrate upper and
lower impermeable confining units.
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These confining units serve as barriers
to fluid movement and pressure and
must ensure continuous injectate
isolation, confinement, and USDW
protection. Identification of such units
is conducted through analysis of sonic
and resistivity logs, drill stem tests, and
wire line tests.
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D. Evaluation of Concerns About
Injection Depth for Class VI GS Wells
Discussion
Under Section 1421 of the Safe
Drinking Water Act (SDWA), UIC
regulations must prevent underground
injection that endangers USDWs. While
EPA has met this statutory requirement
in the past by requiring injection below
the lowermost USDW, for some of the
injection activities that may pose
increased risks, the Act allows other
approaches as well (Kobelski, et al.,
2005).
In today’s NODA, EPA is providing
additional information on an alternative
for addressing injection depth in limited
circumstances where there are deep
USDWs. EPA believes that a waiver
process may respond to the range of
comments, both for and against the
proposed requirement that Class VI
wells inject below the lowermost
USDW. The goals of this approach are
to: (1) Provide flexibility to UIC Program
Directors and owner/operators that will
undertake CO2 injection for GS; (2)
respond to concerns about local and
regional geologic storage capacity
limitations imposed by the proposed
injection depth requirements; (3) allow
for a more site-specific assessment; (4)
accommodate injection into different
formation types; and, (5) consider the
concept that CO2 injection for GS above
and/or between USDWs could be as safe
and effective as injection below the
lowermost USDW as evidenced by past
experiences with some Class II, III and
V injection wells. EPA believes this
approach may additionally
accommodate requests for geographic
flexibility while placing such
determinations at the State or Regional
level. Lastly, the approach is designed
to acknowledge and accommodate
comments and concerns about drinking
water resource availability and the
potential/known future needs, and to
afford such water resources protection.
EPA is considering a number of topics
and the implications of the various
commenters’ concerns related to this
potential alternative as follows:
There have been a number of national
GS capacity estimates developed (e.g.,
by DOE’s National laboratories, USGS,
etc.). Some of these assessments have
broadly identified porous, permeable
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formations that may receive and store
CO2 at a range of depths beneath the
ground surface (Burruss, R.C., et al,
2009; DOE, 2007; Davidson et al., 2008;
MIT, 2007; Dooley, 2006). In developing
injection depth requirements, EPA
acknowledges that these capacity
estimates do not directly address
specific site suitability attributes that
would be identified through the UIC
permitting site-characterization process.
Additionally, these formations
(identified through capacity estimates)
may be stratified, stacked, or layered
and in combination, their cumulative
capacity could be limited (i.e., less than
assessed). In the absence of such sitespecific information, it is currently
difficult to identify what percentage of
assessed national capacity is actually
suitable for GS. In addition, very small
geologic storage sites, even when
aggregated within a given area, may not
be conducive to/appropriate for largescale, commercial GS projects. However,
the approach described in this Notice
allows for such a determination to be
made on a site-specific basis.
Second, the alternative under
consideration does not prohibit
injection into any specific formation
types (e.g., basalts and/or coal seams). It
affords all formations equal treatment
and allows specific regions of the
country the regulatory flexibility to
determine if any injection at a particular
site and depth is the appropriate
approach. It will also help to manage
injection in areas where there may be
multiple, stratified formations with
significant assessed cumulative
capacity.
Third, because the Agency believes
that it is necessary to address the
specific, unique characteristics of Class
VI injection (e.g., large injection
volumes, viscosity, and buoyancy) and
the Agency does not have information
or data indicating that Class II
operations are entirely analogous to
Class VI, large-scale injection, this
alternative allows Class VI injection
depth considerations to be tailored for
GS. A number of dominant differences
between Class II and Class VI operations
indicate that these well classes warrant
different treatment. EPA received
comment during the public comment
period supporting the need for such a
distinction. These differences include:
the risk profiles for these operations; the
greater total injection volumes (of CO2)
for Class VI GS; and, differences in
formation pressures (potentially higher
for GS), greater opportunities for
mobilization of constituents, and
injection rates and operating conditions.
The alternative EPA is considering
relies on the principle of site-suitability
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for GS: injection zones/formations that
have suitable upper and lower confining
units, appropriate lateral and vertical
extent to receive and contain the
injected CO2, and an appropriate
management scheme to ensure that the
water and other resources contained
within the injection zone will not be
needed in the future. The management
scheme will also ensure that there is a
strategy developed to address future
needs to access formations below the
injection zone.
This approach would allow regulators
and communities (e.g., States, etc.) to
assess the most appropriate injection
depth for a given project, in a given
geographic or geologic area. It may also
allow communities, local, and State
authorities to plan resource use
appropriately and, if necessary,
circumvent the need to drill through a
CO2 filled zone/formation/plume to
exploit resources (both water and
hydrocarbon) in or below the injection
zone.
Conversely, EPA is weighing the fact
that this alternative would be a
divergence from the existing UIC deepwell injection requirements for
industrial and hazardous waste
injection. It will result in greater
injection depth variability throughout
the United States and may result in
emplacement of fluids by injection in
closer proximity to USDWs than would
occur under the proposed requirements.
Additionally, adoption of this
alternative could potentially add a new
administrative burden to UIC programs
pursuing the waiver approach.
Consideration of New Approach
Based on new information and data
from comments received on the
proposed rule, the Agency is
considering a waiver process to allow
GS injection above and between USDWs
under specific conditions in lieu of a
blanket prohibition on injection above
and between USDWs. The proposed
Class VI GS injection depth
requirements would remain unchanged
but would allow an owner or operator
seeking to inject above and/or between
USDWs to apply for a waiver from the
proposed injection depth requirements.
The owner or operator would be
required to demonstrate to regulatory
authorities that such injection can be
undertaken and completed in a manner
that prevents fluid movement into
overlying (and underlying) USDWs,
thereby preventing the endangerment of
public health from USDW
contamination. This process would be
separate from aquifer exemptions and
has no effect on 40 CFR parts 144.7 and
146.4.
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Under this alternative, an owner or
operator applying for an injection depth
waiver would need to consider and
submit additional, specific information
to the UIC Program Director and the
Public Water Supply Supervision
(PWSS) Program Director for review
prior to completing a Class VI permit
application. EPA is considering that
such information would likely include:
• Site characterization: Site
characterization data will be critical in
determining appropriateness of a given
formation and depth for GS injection.
The waiver application would need to
demonstrate: (1) Laterally continuous,
impermeable confining units above and
below the injection zone adequate to
prevent fluid movement and pressure
buildup; (2) A laterally continuous
injection zone/formation with adequate
injectability, including sufficient
porosity and permeability, and
appropriate soil-rock chemistry (so as to
ensure that the injection matrix is not
dissolved as a result of injection); (3) An
injection zone and confining formations
free of transmissive fractures and faults;
and, (4) A characterization of regional
fracture properties and a demonstration
that such fractures will not interfere
with injection, serve as conduits, or
endanger USDWs.
• AoR and corrective action: Due to
the potential risk that artificial
penetrations pose as fluid/injectate
conduits, the owner/operator would
need to map and identify all artificial
penetrations in the AoR that penetrate
the injection zone, the upper and lower
confining zones, and all USDWs in the
area. The purpose of this demonstration
would be to ensure that public water
supplies, private wells, and potential
future water resources are identified and
the location of artificial penetrations
into such formations are known and
these artificial penetrations can be
appropriately plugged during the
permitting phase.
• Emergency and remedial response
and financial responsibility: The owner
or operator would need to supplement
the emergency and remedial response
plan (submitted as part of the waiver
application process and as part of the
UIC Class VI permit) to ensure
protection of USDWs above and below
the injection zone. The purpose of this
plan would be to explain that the owner
or operator has considered regional
water resource issues and has explored
alternative water supplies or water
treatment options to address
unanticipated movement of the injectate
or formation fluids (e.g., CO2, brine, or
other fluids) into any overlying or
underlying USDWs. The owner/operator
would also demonstrate sufficient,
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additional financial responsibility to
address any potential contamination of
USDWs above or below the injection
zone.
Upon compliance with the waiver
process requirements, the owner/
operator would need to submit the
information jointly to the UIC Program
Director and the PWSS Program
Director. These Directors would
consider factors such as:
• The integrity of the upper and
lower confining units (certified by a
Professional Geologist or a Professional
Engineer);
• The suitability of the injection zone
(e.g., lateral continuity; lack of
transmissive faults and fractures;
knowledge of current or planned
artificial penetrations into it or
formations below the injection zone);
• The potential capacity of the
geologic formation to sequester CO2,
accounting for the availability of
alternative injection sites;
• All other site characterization data,
the proposed emergency and remedial
response plan, and a demonstration of
financial responsibility;
• Community needs, demands, and
supply from drinking water resources;
• Planned needs, potential and/or
future use of USDWs and non-USDWs
in the area;
• Planned (or permitted) water,
hydrocarbon, or mineral resource
exploitation potential of the proposed
injection formation and other
formations both above and below the
injection zone—to determine if there are
any plans to drill through the formation
to access resources in or beneath the
proposed injection zone/formation;
• The proposed plan for securing
alternative resources or treating USDW
formation waters in the event of
contamination related to the Class VI
injection activity; and,
• Any other locally applicable
considerations.
The waiver may also be subject to
local notice and public hearing.
Following a public hearing and waiver
approval by both Program Directors, the
owner/operator may complete and
submit the Class VI permit application.
The owner/operator may be required to
comply with additional requirements
that apply as a result of receipt of the
waiver, designed to ensure the
protection of USDWs both above and
below the injection zone. These
requirements could include: more
specific construction and preoperational testing requirements to
reduce the chances of upward fluid
movement or inter-formational flow;
enhanced operating requirements such
as more stringent injection pressure
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44811
limitations; a site-specific monitoring
regime that includes increased
formation fluid and ground water
sampling and monitoring above and
below the injection zone in concert with
local water suppliers; seismic plume
tracking and monitoring of pressure
changes above and below the injection
zone; supplemented financial
responsibility and emergency and
remedial response requirements
(consistent with those in the waiver);
and identification of the location of
PWS and private drinking water wells
in developing and executing the postinjection site care and site closure plan
at the GS site.
Adoption of the Waiver Requirements
Due to the range of concerns and
comments related to the injection depth
requirements and the nature of the
suggested waiver approval procedure,
EPA believes that adoption of any such
injection depth waiver process, as
previously described, should be at the
discretion of the UIC Program Director.
Because deep USDWs do not exist in
every State, EPA expects that not all
States would choose to adopt the waiver
process. UIC Programs in such States
may instead adopt and enforce the
proposed requirement that injection for
GS be below the lowermost USDW.
EPA also recognizes that States and
UIC Directors have the discretion to be
more stringent in writing regulations for
GS and/or adopting Federal UIC
requirements. As a result, States could
include a minimum injection depth
requirement in their regulations or a
Director may impose such requirements
on a site-specific basis.
The Agency is requesting comment on
the merits and possible disadvantages of
the injection depth waiver process.
Specifically, should an approach such
as the one described in this Notice be
considered and if so, should there be
additional, fewer, or different elements?
Some stakeholders are concerned about
the risks associated with the use of
formations other than deep saline and
depleted reservoirs (e.g., coal seams,
basalts, etc.). EPA is seeking comment
on whether the waiver process should
apply to formations other than these.
Additionally, the Agency is interested
in:
(1) Information on specific areas of
the United States where injection depth
and USDW depth are of concern
(including formation depth, location,
and assessed capacity; demonstrated
confinement and GS suitability; and,
formation salinity/TDS) as determined
by well-log analyses, cross sections, and
formation fluid analyses;
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(2) Data, information, and evidence
from owners and operators constructing
and operating injection wells through
existing CO2 plumes to access resources
(e.g., water, hydrocarbon, etc.) below the
injection zone and whether or not such
operations are safe and do not endanger
USDWs; and,
(3) Strategies that States, Tribes, and
regions are considering to manage
competing GS and resource issues.
V. State Statutes, Regulations, and
Activities Related to Geologic
Sequestration
Throughout the regulatory
development process for the Class VI
proposal, EPA has made it a priority to
engage States and State organizations.
The EPA has honored a commitment to
working with State co-regulators to
address regulatory issues related to GS
through a series of stakeholder and
technical workshops, public hearings,
and EPA participation with national
organizations including the Ground
Water Protection Council, the Interstate
Oil and Gas Compact Commission, and
the American Association of State
Geologists. EPA values coordination
with States and State co-regulators and
will continue an open dialogue as the
Agency moves forward in the regulatory
development process.
EPA recognizes the complexity and
importance of the States’ approaches to
managing GS and does not want to
unduly hinder State activities as
indicated in an April 2008 EPA letter to
the States (available in the docket for
this regulatory action). The Agency is
aware that States are currently in
various stages of developing statutory
frameworks, regulations, workgroups,
technical guidance, and strategies for
addressing CCS and GS. Much of the
expertise and infrastructure currently
exists within State UIC Programs. These
programs will form the foundation for
managing GS wells. Additionally, States
can use multiple authorities beyond
those afforded under the SDWA and
UIC regulations including surface access
and land rights, unitization of fields,
pore space ownership, mineral rights,
worker safety and emergency
preparedness, and maximization of
State oil and gas resource exploitation.
At present, several States have
published GS regulations, while a
number of other States are investigating
and developing strategies to address
dual purpose injection wells (EOR/EGR
and GS simultaneously). Some States
are using natural gas storage regulations
as a platform for developing these
regulations. Additionally, as States
develop regulations and statutes, they
are examining which State Agency can
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most appropriately manage
implementation for GS wells. EPA is
continuing to collaborate with States
and will consider this information as
EPA develops guidance on the primacy
application and approval process for
Class VI wells. Information about these
State activities may be found in the
Docket for today’s publication. EPA also
seeks comment on current State
activities addressing GS. This
information will assist EPA in
developing guidance for UIC program
implementers.
VI. Conclusions
In conclusion, today’s Notice
supplements the proposed ‘‘Federal
Requirements Under the Underground
Injection Control (UIC) Program for
Carbon Dioxide (CO2) Geologic
Sequestration (GS) Wells’’ of July 25,
2008 (73 FR 43492), presents new data
and information, and requests public
comment on related issues that have
evolved in response to comments on the
original proposal. This Notice contains
preliminary field data from Department
of Energy-sponsored Regional Carbon
Sequestration Partnership projects, the
results of GS-related studies conducted
by the Lawrence Berkeley National
Laboratory, and additional GS related
research. Today’s Notice also discusses
comments and presents an alternative
the Agency is considering related to the
proposed injection depth requirements.
VII. References
Birkholzer, J.T., Q. Zhou, and C.F. Tsang.
2009. Large-Scale Impact of CO2 Storage
in Deep Saline Aquifers: A Sensitivity
Study on the Pressure Response in
Stratified Systems. International Journal
of Greenhouse Gas Control, 3(2), 181–
194.
Birkholzer, J., J. Apps, L. Zheng, Y. Zhang,
T. Xu, and C.-F. Tsang. 2008a. Research
Project on CO2 Geological Storage and
Groundwater Resources: Water Quality
Effects Caused by CO2 Intrusion into
Shallow Groundwater. Technical Report,
LBNL–1251E, October 2008.
Birkholzer, J., Q. Zhou, K. Zhang, P. Jordan,
J. Rutqvist, and C.-F. Tsang. 2008b.
Research Project on CO2 Geological
Storage and Groundwater Resources:
Large-Scale Hydrological Evaluation and
Modeling of the Impact on Groundwater
Systems. NETL Project Annual Report,
October 1, 2007 to September 30, 2008.
Burruss, R.C., Brennan, S.T., Freeman, P.A.,
Merrill, M.D., Ruppert, L.F., Becker,
M.F., Herkelrath, W.N., Kharaka, Y.K.,
Neuzil, C.E., Swanson, S.M., Cook, T.A.,
Klett, T.R., Nelson, P.H., and C.J. Schenk.
2009. Development of a Probabilistic
Assessment Methodology for Evaluation
of Carbon Dioxide Storage: US
Geological Survey Open-File Report
2009–1035, 81 p. https://pubs.usgs.gov/
of/2009/1035/.
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Davidson, C.L., J.J. Dooley, and R.T.
Dahowski. 2008. Assessing the Impacts
of Future Demand for Saline
Groundwater on Commercial
Deployment of CCS in the United States.
9th International Conference on
Greenhouse Gas Control Technologies,
(November 2008). Washington, DC.
Dooley, J.J., R.T. Dahowski, C.L. Davidson,
M.A. Wise, N. Gupta, S.H. Kim, and E.L.
Malone. 2006. Carbon Dioxide Capture
and Geologic Storage: A Core Element of
a Global Energy Technology Strategy to
Address Climate Change. A Technology
Report from the Second Phase of the
Global Energy Technology Strategy
Program. April, 2006.
Friedman, S. J. 2007. Geological Carbon
Dioxide Sequestration. Elements, 3, 179–
184.
Holloway, S. 2001. Storage of Fossil FuelDerived Carbon Dioxide Beneath the
Surface of the Earth. Annual Review of
Energy and the Environment, 26, 145–66.
IPCC. 2005. IPCC Special Report on Carbon
Dioxide Capture and Storage. Prepared
by Working Group III of the
Intergovernmental Panel on Climate
Change. Metz, B., O. Davidson, H. C. de
Coninck, M. Loos, and L. A. Meyer
(eds.). New York: Cambridge University
Press.
Kobelski, B.J., R.E. Smith, and A.L.
Whitehurst. 2005. An Interpretation of
the Safe Drinking Water Act’s ‘‘NonEndangerment’’ Standard for the
Underground Injection Control (UIC)
Program. In Developments in Water
Science: Underground Injection Science
and Technology, 52, 39–43.
McGrail, B.P., H.T. Schaef, A.M. Ho, Y.
Chien, J.J. Dooley, and C.L. Davidson.
2006. Potential for Carbon Dioxide
Sequestration in Flood Basalts. Journal of
Geophysical Research, III B12201.
MIT. 2007. Massachusetts Institute of
Technology. The Future of Coal—
Options for a Carbon Constrained World.
Nicot, J.P. 2008. Evaluation of Large-Scale
Carbon Storage on Fresh-Water Section
of Aquifers: A Texas Study. International
Journal of Greenhouse Gas Control, 2(4),
582–593.
Schnaar, G. and D. Digiulio. 2009.
Computational Modeling of the Geologic
Sequestration of Carbon Dioxide. Vadose
Zone Journal, 8(2), 389–403.
Sengebush, R.M. 2008. Deep Brackish Water
Considered for New Mexico
Development. Southwest Hydrology,
March/April 2008, 8.
Tsang, C.-F., J. Birkholzer and J. Rutqvist.
2008. A Comparative Review of
Hydrologic Issues Involved in Geologic
Storage of CO2 and Injection Disposal of
Liquid Waste. Environmental Geology,
54, 1723–1737.
U.S. DOE. 2007 Carbon Sequestration Atlas
of the United States and Canada. US
Department of Energy, Office of Fossil
Energy, national Energy Technology
Laboratory. March, 2007. https://
www.netl.doe.gov/technologies/
carbon_seq/refshelf/atlas/.
U.S. Government Accountability Office.
2003. Freshwater Supply: States’ Views
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of House Federal Agencies Could Help
Them Meet the Challenges of Expected
Shortages (GAO–03–514). July, 2003.
van der Meer, L.G.H. and F. Yavuz. 2008.
CO2 Storage Capacity Calculations for
the Dutch Subsurface. 9th International
Conference on Greenhouse Gas Control
Technologies, (November 2008).
Washington, DC.
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White, C.M., D.H. Smith, K.L. Jones, A.L.
Goodman, S.A. Jikich, R.B. LaCount, S.B.
DuBose, E. Ozdemir, B.I. Morsi, and k.T.
Schroeder. 2005. Sequestration of Carbon
Dioxide In Coal With Enhanced Coalbed
Methane Recovery—A Review. Energy
Fuels, 19(3), 659–724.
Zhou, Q., J.T. Birkholzer, C.F. Tsang, and J.
Rutqvist. 2008. A Method for Quick
Assessment of CO2 Storage Capacity in
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Closed and Semi-Closed Saline
Formations. International Journal of
Greenhouse Gas Control, 2(4), 626–639.
Dated: August 21, 2009.
Peter S. Silva,
Assistant Administrator, Office of Water.
[FR Doc. E9–20920 Filed 8–28–09; 8:45 am]
BILLING CODE 6560–50–P
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[Federal Register Volume 74, Number 167 (Monday, August 31, 2009)]
[Proposed Rules]
[Pages 44802-44813]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: E9-20920]
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ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 146
[EPA-HQ-OW-2008-0390; FRL-8951-3]
RIN 2040-AE98
Federal Requirements Under the Underground Injection Control
(UIC) Program for Carbon Dioxide (CO2) Geologic
Sequestration (GS) Wells; Notice of Data Availability and Request for
Comment
AGENCY: Environmental Protection Agency (EPA).
ACTION: Data availability; request for comment.
-----------------------------------------------------------------------
SUMMARY: Today's Notice supplements the proposed ``Federal Requirements
Under the Underground Injection Control (UIC) Program for Carbon
Dioxide (CO2) Geologic Sequestration (GS) Wells'' of July
25, 2008, presents new data and information, and requests public
comment on related issues that have evolved in response to comments on
the original proposal. This Notice contains preliminary field data from
the Department of Energy-sponsored Regional Carbon Sequestration
Partnership projects, the results of GS-related studies conducted by
the Lawrence Berkeley National Laboratory, and additional GS-related
research. Today's Notice also discusses comments and presents an
alternative the Agency is considering related to the proposed injection
depth requirements for Class VI wells.
DATES: Comments on the contents of this NODA must be received on or
before October 15, 2009. EPA does not plan to extend the comment period
for this Notice. EPA will hold a public hearing from 9 a.m. to 12 p.m.
and 1 p.m. to 4 p.m., CDT, September 17, 2009 in Chicago, IL.
ADDRESSES: The public hearing will be held at the Ralph H. Metcalfe
Federal Building, 77 W. Jackson Boulevard, Chicago, IL 60604. Due to
capacity limitations, we encourage you to indicate your intent to
participate through pre-registration. To pre-register, for directions,
and for site specific information, please visit the following Web site:
https://gshearing.cadmusweb.com/.
Submit your comments, identified by Docket ID No. EPA-HQ-OW-2008-
0390, by one of the following methods:
https://www.regulations.gov: Follow the on-line
instructions for submitting comments.
Mail: Water Docket, Environmental Protection Agency,
Mailcode: 4101T, 1200 Pennsylvania Ave., NW., Washington, DC 20460.
Hand Delivery: Water Docket, EPA Docket Center (EPA/DC),
Public Reading Room, Room 3334, EPA West, 1301 Constitution Ave., NW.,
Washington, DC. Such deliveries are only accepted during the Docket's
normal hours of operation which are 8:30 a.m. to 4:30 p.m., and special
arrangements should be made for deliveries of boxed information.
Instructions: Direct your comments to Docket ID No. EPA-HQ-OW-2008-
0390. EPA's policy is that all comments received will be included in
the public docket without change and may be made available online at
https://www.regulations.gov, including any personal information
provided, unless the comment includes information claimed to be
Confidential Business Information (CBI) or other information whose
disclosure is restricted by statute. Do not submit information that you
consider to be CBI or otherwise protected through https://www.regulations.gov or e-mail. Contact EPA directly (see the FOR
FURTHER INFORMATION CONTACT section) prior to submitting CBI. The
https://www.regulations.gov Web site is an ``anonymous access'' system,
which means EPA will not know your identity or contact information
unless you provide it in the body of your comment. If you send an e-
mail comment directly to EPA without going through https://www.regulations.gov your e-mail address will be automatically captured
and included as part of the comment that is placed in the public docket
and made available on the Internet. If you submit an electronic
comment, EPA recommends that you include your name and other contact
information in the body of your comment and with any disk or CD-ROM you
submit. If EPA cannot read your comment due to technical difficulties
and cannot contact you for clarification, EPA may not be able to
consider your comment. Electronic files should avoid the use of special
characters, any form of encryption, and be free of any defects or
viruses.
Docket: All documents in the docket are listed in the https://www.regulations.gov index. Although listed in the index, some
information is not publicly available, e.g., CBI or other information
whose disclosure is restricted by statute. Certain other material, such
as copyrighted material, will be publicly available only in hard copy.
Publicly available docket materials are available either electronically
in https://www.regulations.gov or in hard copy at
[[Page 44803]]
the Water Docket, EPA Docket Center (EPA/DC), Public Reading Room, Room
3334, EPA West, 1301 Constitution Ave., NW., Washington, DC. The Public
Reading Room is open from 8:30 a.m. to 4:30 p.m., Monday through
Friday, excluding legal holidays. The telephone number for the Public
Reading Room is (202) 566-1744, and the telephone number for the EPA
Docket Center is (202) 566-2426.
FOR FURTHER INFORMATION CONTACT: Mary Rose Bayer, Underground Injection
Control Program, Drinking Water Protection Division, Office of Ground
Water and Drinking Water (MC-4606M), Environmental Protection Agency,
1200 Pennsylvania Ave., NW., Washington, DC 20460; telephone number:
(202) 564-1981; e-mail address: bayer.maryrose@epa.gov. For general
information, contact the Safe Drinking Water Hotline, telephone number:
(800) 426-4791. The Safe Drinking Water Hotline is open Monday through
Friday, excluding legal holidays, from 10 a.m. to 4 p.m. Eastern time.
For general information about the public hearing, please contact Sean
Porse by phone (202) 564-5990, by e-mail at porse.sean@epa.gov, or by
mail at: US Environmental Protection Agency, Mail Code 4606M, 1200
Pennsylvania Ave., NW., Washington, DC 20460.
SUPPLEMENTARY INFORMATION:
I. General Information
This Notice of Data Availability (NODA) presents new information
and data related to geologic sequestration (GS) of CO2
obtained after publication of the July 25, 2008, proposed rule,
``Federal Requirements Under the Underground Injection Control (UIC)
Program for Carbon Dioxide (CO2) Geologic Sequestration (GS)
Wells'' (73 FR 43492). The proposal is available online at https://www.epa.gov/fedrgstr/EPA-WATER/2008/July/Day-25/w16626.htm.
Availability of this new information could change EPA's approach to the
final rulemaking.
The purpose of this NODA is to request public comment on new data
and on related issues that have evolved in response to comments on the
original proposal. This Notice provides additional information and data
on the topic of injection depth as described in the July 25, 2008,
proposal (73 FR 43492) and presents an alternative that responds to
comments received on this issue. Therefore, EPA is providing the
opportunity for notice and comment on the information provided in this
Notice as a supplement to the proposed rule. The Agency seeks further
public comment on any and all aspects of the specific data and
alternatives it has identified in this Notice. EPA continues to review
the comments received on the proposed rule and will address those
comments and the comments submitted in response to this Notice in the
final action.
Persons interested in recent research related to GS and proposed
injection depth requirements are encouraged to read and respond to this
NODA. Additionally, owners and operators, States, Tribes, and State co-
regulators involved in GS activities may wish to comment on this
publication.
Abbreviations and Acronyms
AL: Action Level
AoR: Area of Review
CBI: Confidential Business Information
CFR: Code of Federal Regulations
CCS: Carbon Capture and Storage
CO2: Carbon Dioxide
DOE: Department of Energy
EGR: Enhanced Gas Recovery
EPA: Environmental Protection Agency
EOR: Enhanced Oil Recovery
GS: Geologic Sequestration
GHG: Greenhouse Gas
IPCC: Intergovernmental Panel on Climate Change
km: kilometer
LBNL: Lawrence Berkeley National Lab
m: meter
mg/l: milligrams per liter
Mt: Megaton
MCL: Maximum Contaminant Level
NETL: National Energy Technology Laboratory
NWIS: National Water Information System
NODA: Notice of Data Availability
ORD: Office of Research and Development
PWS: Public Water System
PWSS: Public Water Supply Supervision
RCSPs: Regional Carbon Sequestration Partnerships
SDWA: Safe Drinking Water Act
SECARB: Southeast Regional Carbon Sequestration Partnership
STAR: Science to Achieve Results
SWP: Southwest Regional Partnership on Carbon Sequestration
TDS: Total Dissolved Solids
UIC: Underground Injection Control
US: United States
USDW: Underground Source of Drinking Water
USGS: United States Geological Survey
Definitions
Action Level (AL): The concentration of lead or copper in water
specified in 40 CFR 141.80(c) which determines, in some cases, the
treatment requirements contained in subpart I of this part that a water
system is required to complete.
Area of review (AoR): The region surrounding the geologic
sequestration project that may be impacted by the injection activity.
The area of review is based on computational modeling that accounts for
the physical and chemical properties of all phases of the injected
carbon dioxide stream.
Buoyancy: Upward force on one phase (e.g., a fluid) produced by the
surrounding fluid (e.g., a liquid or a gas) in which it is fully or
partially immersed, caused by differences in pressure or density.
Capillary force: Adhesive force that holds a fluid in a capillary
or a pore space. Capillary force is a function of the properties of the
fluid, and surface and dimensions of the space. If the attraction
between the fluid and surface is greater than the interaction of fluid
molecules, the fluid will be held in place.
Carbon Capture and Storage (CCS): The process of capturing
CO2 from an emission source, (typically) converting it to a
supercritical state, transporting it to an injection site, and
injecting it into deep subsurface rock formations for long-term
storage.
Carbon dioxide plume: The extent underground, in three dimensions,
of an injected carbon dioxide stream.
Carbon dioxide (CO2) stream: Carbon dioxide that has been captured
from an emission source (e.g., a power plant), plus incidental
associated substances derived from the source materials and the capture
process, and any substances added to the stream to enable or improve
the injection process. This subpart does not apply to any carbon
dioxide stream that meets the definition of a hazardous waste under 40
CFR part 261.
Class VI wells: Wells used for geologic sequestration of carbon
dioxide beneath the lowermost formation containing a USDW.
Confining zone: A geologic formation, group of formations, or part
of a formation stratigraphically overlying the injection zone that acts
as a barrier to fluid movement.
Corrective action: The use of Director approved methods to assure
that wells within the area of review do not serve as conduits for the
movement of fluids into underground sources of drinking water (USDWs).
Director: The person responsible for permitting, implementation,
and compliance of the UIC program. For UIC programs administered by
EPA, the Director is the EPA Regional Administrator; for UIC programs
in Primacy States, the Director is the person responsible for
permitting, implementation, and compliance of the State, Territorial,
or Tribal UIC program.
Enhanced Oil or Gas Recovery (EOR/EGR): Typically, the process of
injecting a fluid (e.g., water, brine, or CO2) into an oil
or gas bearing formation to
[[Page 44804]]
recover residual oil or natural gas. The injected fluid thins
(decreases the viscosity) or displaces small amounts of extractable oil
and gas, which is then available for recovery. This is also known as
secondary or tertiary recovery.
Formation or geological formation: A layer of rock that is made up
of a certain type of rock or a combination of types.
Geologic sequestration (GS): The long-term containment of a
gaseous, liquid or supercritical carbon dioxide stream in subsurface
geologic formations. This term does not apply to its capture or
transport.
Geologic sequestration project: An injection well or wells used to
emplace a CO2 stream beneath the lowermost formation
containing a USDW. It includes the subsurface three-dimensional extent
of the carbon dioxide plume, associated pressure front, and displaced
brine, as well as the surface area above that delineated region.
Injectate: The fluids injected. For the purposes of this rule, this
is also known as the CO2 stream.
Injection zone: A geologic formation, group of formations, or part
of a formation that is of sufficient areal extent, thickness, porosity,
and permeability to receive carbon dioxide through a well or wells
associated with a geologic sequestration project.
Maximum Contaminant Level (MCL): The maximum permissible level of a
contaminant in water which is delivered to any user of a public water
system.
Model: A representation or simulation of a phenomenon or process
that is difficult to observe directly or that occurs over long time
frames. Models that support GS can predict the flow of CO2
within the subsurface, accounting for the properties and fluid content
of the subsurface formations and the effects of injection parameters.
Pore space: Open spaces in rock or soil. These are filled with
water or other fluids such as brine (i.e., salty fluid). CO2
injected into the subsurface can displace pre-existing fluids to occupy
some of the pore spaces of the rocks in the injection zone.
Public Water System (PWS): A system for the provision to the public
of water for human consumption through pipes or, after August 5, 1998,
other constructed conveyances, if such system has at least fifteen
service connections or regularly serves an average of at least twenty-
five individuals daily at least 60 days out of the year. Such term
includes: any collection, treatment, storage, and distribution
facilities under control of the operator of such system and used
primarily in connection with such system; and any collection or
pretreatment storage facilities not under such control which are used
primarily in connection with such system. Such term does not include
any ``special irrigation district.'' A public water system is either a
``community water system'' or a ``noncommunity water system.''
Pressure front: The zone of elevated pressure that is created by
the injection of carbon dioxide into the subsurface. For GS projects,
the pressure front of a CO2 plume refers to the zone where
there is a pressure differential sufficient to cause the movement of
injected fluids or formation fluids into a USDW.
Saline formations: Deep and geographically extensive sedimentary
rock layers saturated with waters or brines that have a high total
dissolved solids (TDS) content (i.e., over 10,000 mg/l TDS). Saline
formations offer great potential for CO2 storage capacity.
Stratigraphic zone (unit): A layer of rock (or stratum) that is
recognized as a unit based on lithology, fossil content, age or other
properties.
Total Dissolved Solids (TDS): The measurement, usually in mg/l, for
the amount of all inorganic and organic substances suspended in liquid
as molecules, ions, or granules. For injection operations, TDS
typically refers to the saline (i.e., salt) content of water-saturated
underground formations.
Transmissive fault or fracture: A fault or fracture that has
sufficient permeability and vertical extent to allow fluids to move
between formations.
Trapping: The physical and geochemical processes by which injected
CO2 is sequestered in the subsurface. Physical trapping
occurs when buoyant CO2 rises in the formation until it
reaches a layer that inhibits further upward migration or is
immobilized in pore spaces due to capillary forces. Geochemical
trapping occurs when chemical reactions between dissolved
CO2 and minerals in the formation lead to the precipitation
of solid carbonate minerals.
Underground Source of Drinking Water (USDW): as defined under 40
CFR part 144.3, an aquifer or portion of an aquifer that supplies any
public water system or that contains a sufficient quantity of ground
water to supply a public water system, and currently supplies drinking
water for human consumption, or that contains fewer than 10,000 mg/l
total dissolved solids and is not an exempted aquifer.
Special Accommodations: For information on access or accommodations
for individuals with disabilities, please contact Sean Porse at (202)
564-5990 or by e-mail at porse.sean@epa.gov. Please allow at least 10
days prior to the meeting, to give EPA time to process your request.
II. What Did EPA Propose?
On July 25, 2008, EPA published the proposed ``Federal Requirements
Under the Underground Injection Control (UIC) Program for Carbon
Dioxide (CO2) Geologic Sequestration (GS) Wells.'' (73 FR
43492) The Agency proposed a new class of injection well (Class VI)
along with technical criteria for permitting GS wells, including
criteria for geologic site characterization, area of review (AoR) and
corrective action, well construction, operation, mechanical integrity
testing, monitoring, well plugging, post-injection site care, and site
closure. These standards, if finalized, would protect underground
sources of drinking water (USDWs) under the Safe Drinking Water Act
(SDWA). The technical criteria in the proposed rule are based on the
existing UIC regulatory framework under the SDWA for deep injection
wells, with modifications to address the unique nature of
CO2 injection for GS.
Existing GS project experience, natural and industrial analogs,
research, and current regulatory experience with underground injection
were considered in the development of the proposed rule. Ongoing
research builds upon the existing foundation of substantial literature
on CO2 injection and storage, some of which is available in
the docket for this rulemaking. While CO2 injection to
extract oil and gas has taken place for many years, the use of UIC
wells to inject large quantities of CO2 for long-term
storage is a relatively new practice. There are current projects and
research underway that examine and demonstrate the effectiveness of
underground injection as a tool for sequestering CO2.
For example, there are four commercial projects in operation today:
Sleipner (Norwegian North Sea)--1 Mt CO2/yr
injected since 1996;
Weyburn (Canada)--1 Mt CO2/yr injected since
2000;
In Salah (Algeria)--1.2 Mt CO2/yr injected
since 2004;
Snohvit (Norway)--0.7 Mt CO2/yr injected since
2008.
Many additional large-scale projects are funded and under
development worldwide.
The purpose of this NODA is to provide an update on newly available
information and data related to research focused specifically on GS for
long-term storage--with particular emphasis on data, research, and
information that has become available since the July proposal
publication.
[[Page 44805]]
In addition, the proposed rule contains a discussion of injection
depth. In the July 2008 FR Notice, EPA proposed that the injection of
CO2 be confined to areas below the lowermost USDW (in the
absence of an aquifer exemption). This approach is consistent with the
approach used for other deep UIC wells; however, circumstances in a few
States may warrant an alternative approach. Today's Notice provides
additional discussion on an alternative the Agency is considering
related to injection depth for GS wells.
EPA received a number of comments indicating that the Agency should
further explore environmental and regulatory issues beyond the scope of
the proposed SDWA requirements for underground injection of
CO2 for GS. EPA recognizes that a more comprehensive
framework may be needed and that some stakeholders remain uncertain
with respect to the potential applicability of other Federal
environmental statutes such as the Clean Air Act, the Resource
Conservation and Recovery Act, and the Comprehensive Environmental
Response, Compensation, and Liability Act to various aspects of
geologic sequestration of CO2. The Agency is currently
evaluating the need for a more comprehensive regulatory framework to
provide legal guidance regarding this emerging technology. If the
Agency chooses to pursue a more comprehensive regulatory approach to
this subject, it will seek public comment on any proposal it develops
for this framework and will also endeavor to issue a more comprehensive
rule in the same time frame as it has planned for the stand-alone UIC
GS rulemaking.
III. Research, Data Analysis, and Findings
A. Content of NODA and Summary of Comments
In this Notice, EPA is providing a short summary of several ongoing
GS studies and interim information on current GS projects relevant to
topics within the proposed GS regulation. This information and data
were provided or made available after publication of the proposal in
July 2008. More detailed information on the GS research and projects
discussed below is available for review online as part of the docket
for this rulemaking. EPA is providing this data and associated project
summaries because the Agency expects that there may be additional
studies and data on other GS projects, the use of existing
technologies, and GS-related research that may inform the Agency's
regulatory development process for GS. Such data could contribute to
the Agency's understanding of site characterization, well construction,
operation, and monitoring requirements. The Agency requests comment on
data and research discussed in today's Notice and how the Agency might
use this data and research in developing the final rule. The Agency
also requests submission of additional GS studies related to the data
and research discussed in this Notice to inform the GS rulemaking.
In the preamble of the proposed rule, EPA described an adaptive
approach to developing regulations for GS. This approach would allow
the Agency to establish regulations to protect USDWs and enable the
Agency to make changes to regulations over time as information from
demonstration projects and other studies becomes available. EPA
received comments from stakeholders requesting that additional data be
made available to the public before a final rulemaking (particularly
related to specific areas of GS) and indicating that more research is
needed to support GS in general. Many commenters suggested that
supplementary research on GS is necessary prior to rule promulgation
and that EPA should wait until the Department of Energy (DOE)-sponsored
Phase II and Phase III pilot projects are complete before finalizing
the GS rule. Others believed that a final rulemaking should proceed and
that new information and data from ongoing GS research should be
considered and incorporated over time as part of an adaptive rulemaking
process. Comments on the proposal encouraged additional research and
investigations on areas including (but not limited to): Confining zone
characterization; modeling; CO2 plume movement;
geochemistry; impacts of GS on saline formations; leakage from
abandoned wells caused by material and cement degradation; potential
pathways for contamination of USDWs; leak mitigation and remediation;
and criteria for determining that the CO2 plume has
stabilized.
The Agency is actively tracking the progress of the Regional Carbon
Sequestration Partnership (RCSP) GS and carbon capture and storage
projects. The RCSPs have been compiling information related to their
pilot and demonstration projects and have been developing research
projects related to these efforts. A summary of several of these
projects is available in today's Notice.
In addition, EPA's Office of Research and Development is conducting
intramural and extramural research activities to develop modeling and
monitoring tools for protecting underground sources of drinking water.
Laboratory, modeling, and field investigations are focusing on a
variety of injection and storage scenarios and candidate injection
sites. Analytic and semi-analytic models are being developed and
evaluated for determining the area of review based on geologic and
hydrologic conditions. Comprehensive laboratory tests are being applied
to the development and field-testing of monitoring strategies that can
detect migration of fluids into shallow aquifers and assess potential
geochemical impacts. The ultimate goal of these research activities is
to provide more robust tools for permitting, monitoring, and evaluating
GS sites from injection through post-injection site care and site
closure to prevent endangerment of USDWs. EPA is also funding six
projects for the study of ground water and human health impacts of GS
through the Science To Achieve Results (STAR) grant program. The awards
will be announced this fall on EPA's Web site (https://es.epa.gov/ncer/
).
Furthermore, EPA and DOE have jointly supported GS-related studies
at Lawrence Berkeley National Lab (LBNL), described in Section II.B.
These studies use modeling to predict the potential impacts on ground
water from GS activities.
B. DOE-Sponsored Regional Carbon Sequestration Partnership Projects
Currently, DOE's National Energy Technology Laboratory (NETL) is
developing and/or operating approximately 30 GS projects, a number of
which have either completed injection or are in the process of
injecting CO2. The purpose of these projects is to ``help
determine the best approaches for capturing and permanently storing
gases that can contribute to global climate change'' and to determine
``the most suitable technologies, regulations, and infrastructure needs
for carbon capture, storage, and sequestration in different parts of
the country'' (https://www.netl.doe.gov/technologies/carbon_seq/partnerships/partnerships.html). Through cooperation with DOE, EPA has
obtained pilot project data from several of these GS projects. RCSPs
are conducting pilot and demonstration projects to study: site
characterization (including injection and confining formation
information, core data and site selection information); well
construction (well depth, construction materials, and proximity to
USDWs); frequency and types of tests and monitoring conducted (on the
well and on the project site); modeling and
[[Page 44806]]
monitoring results; and injection operation (injection rates,
pressures, and volumes, CO2 source and co-injectates). In
addition to information available in the docket for this NODA,
information on some of these projects is available at https://www.netl.doe.gov/publications/proceedings/08/rcsp/. The following is a
short summary of select project activities and data generated.
Escatawpa, Mississippi (MS); Southeast Regional Carbon Sequestration
Partnership (SECARB)
SECARB is conducting a CO2 injection test in Jackson
County, MS into a deep saline reservoir along the Gulf Coast that had
not previously been characterized for oil and gas exploration. The
injection zone, 9,500 feet (2,896 meters) deep in the Lower Tuscaloosa
Massive Sand Unit, is overlain by two confining layers. The site is
near the Victor J. Daniel Power Plant, the source of the
CO2, which was delivered to the injection site via truck.
Characterization of the site is based on a wealth of geophysical
and core-derived information, including well core samples, open-hole
and cased-hole well logging, baseline vertical seismic profiling, and
pressure transient testing. Baseline sampling and analysis of formation
fluids and soil flux sampling were also performed. The SECARB team
performed a 3-dimensional simulation to estimate injectivity, storage
capacity, and long-term fate of the injected CO2. The model
estimated that the plume would extend up to 350 feet (106.7 meters) at
the end of the injection test.
An injection well and a monitoring well were drilled at the site.
The injection well is permitted by the Mississippi Department of
Environmental Quality as a UIC Class V experimental well. Both the
injection and monitoring well were constructed with surface and long-
string casing that was cemented from the injection zone to the surface.
Pre-injection mechanical integrity tests of the injection and
monitoring well (annulus pressure test, radioactive tracer survey,
differential temperature survey, and pressure fall-off tests) met UIC
Class I requirements.
In October of 2008, 3,027 tons (2,746 tonnes) of CO2
were injected into the well; injection rates averaged 170 to 180 tons/
day (154 to 163 tonnes/day). Continuous monitoring devices were used to
record (at 30 second intervals): Injection pressure, annular pressure,
temperature, and rate. The injection was complete on October 28, 2008.
SECARB is continuing to monitor activities at the site through
surface or near-surface monitoring for upward CO2 seepage
via groundwater sampling, soil flux sampling and tracer detection. The
purpose of this monitoring and sampling is to determine whether
CO2 is migrating upward from the injection zone. To date,
there has been no indication of the return of the injected
CO2 in the shallow subsurface. SECARB also plans to employ
time-lapse seismic and geophysical tools to determine the deep
subsurface fate of the injectate.
This SECARB project employs, demonstrates, and validates the EPA's
proposed Class VI well construction, operational, and monitoring
requirements. The use of surface and near-surface monitoring techniques
provides the EPA with preliminary information regarding the efficacy
and appropriateness of these technologies at certain sites; and
supports the need for a site-specific monitoring plan that will allow
use of a range of monitoring technologies suitable for each unique GS
site. This information and public comments on this research will be
used to inform the Agency's final rulemaking.
For additional information about the Escatawpa Project, see the
full report in the docket for today's publication.
Aneth Field, Paradox Basin, Southeast Utah (UT); Southwest Regional
Partnership on Carbon Sequestration (SWP)
The Aneth Field is the site of an experimental combined EOR-GS test
by the Southwest Partnership. The primary CO2 injection
target is the carbonate Paradox Formation, which is approximately 5,600
to 5,800 feet (1,707 to 1,768 meters) deep, and is overlain by the low-
permeability Gothic Shale. Petrographic, geochemical and mechanical
analyses of the Gothic Shale are underway or planned.
CO2 injection began in August 2007, and approximately
150,000 tons (136,077 tonnes) of CO2 have been injected to
date. Extensive monitoring of the site is complete or underway.
Monitoring activities at the site include time-lapse vertical seismic
profiling, microseismic monitoring, geochemical and tracer tests,
CO2 soil flux measurements, a surface fracture and banding
study, and self-potential monitoring.
Monitoring data are being used to establish parameters for state-
of-the-art mathematical reservoir models, which include coupling of
multiphase CO2-ground water flow, rock deformation, and
chemical reactions to evaluate residence times, migration patterns and
rates, and effects of CO2 injection on fluid pressures and
rock strain.
The Aneth Field project confirms the need for a project design with
a robust monitoring plan, and tests the importance of monitoring and
modeling agreement in GS projects. In addition, the project
demonstrates the utility of various monitoring technologies that may be
used by owners and operators of Class VI wells. This information and
public comments on this research will be used to inform the Agency's
final rulemaking.
Pump Canyon Site, Near Archuleta, New Mexico (NM); Southwest Regional
Partnership on Carbon Sequestration (SWP)
The SWP is conducting a Phase II project of CO2
injection into deep, unmineable coal seams at the Pump Canyon Site near
Archuleta, NM. To support characterization of the site, the SWP is
performing a ``seal analysis'' of the ability of the Kirtland Formation
to act as a barrier to the movement of CO2 or other
reservoir fluids. The Kirtland Formation is a major, regional aquitard
and reservoir seal that directly overlies the geologic formation
containing the coal seams.
To characterize the Kirtland Formation, detailed studies of
geological core samples, downhole geophysical logs, and outcrop studies
were conducted. Complete and in-progress laboratory analyses include
electron microscopic studies of petrographic and petrophysical
properties; capillary pressure measurements; multiscale fracture
characterization using well logs and core analysis; descriptions of
stratigraphic columns and sedimentary structures based on cores; pore
size distributions analysis using BET (Brunauer-Emmett-Teller), and
geomechanical analyses of the caprock and overlying aquifer.
Operators are actively monitoring potential surface deformation
from injection through the use of tilt meters and radar-based
Interferrometric Synthetic Aperture Radar (InSAR) in addition to
monitoring the site's injection pressure. They are also tracking the
CO2 plume through continuous sampling of immediate offset
production wells and through perfluorocarbon gas tracers (PFT) and
naphthalene sulfonate water tracers (NST) introduced into the
CO2 injection stream. These tracers are used for
identification in the unlikely event of reservoir leakage.
The Agency sought comment on using unmineable coal seams for GS in
the proposed rule. The investigation at Pump Canyon will inform a
determination on whether CO2 can be effectively and safely
sequestered in coal seams.
[[Page 44807]]
For further information on aspects of the Pump Canyon project,
please refer to data available in the NODA docket.
C. Lawrence Berkeley National Laboratory (LBNL) Studies
An improperly managed GS project has the potential to endanger
USDWs. The factors that increase the risk of USDW contamination are
complex and can include improper siting, construction, operation and
monitoring of GS projects. The proposed GS requirements address
endangerment to USDWs by establishing new Federal requirements for the
proper management of CO2 injection and storage. Risks to
USDWs from improperly managed GS projects can include CO2
migration into USDWs, causing the leaching and mobilization of
contaminants (e.g., arsenic, lead, and organic compounds), changes in
regional groundwater flow, and the movement of greater salinity
formation fluids into USDWs, causing degradation of water quality. As
mentioned in Section II of this Notice and in the proposal,
CO2 has been injected on large scales at four sites: at
Sleipner in the North Sea, at In Salah in Algeria, at Snohvit in
Norway, and in the Weyburn Field in Alberta, Canada. There have been no
documented cases of leakage from these projects. Additionally, for
decades, the oil and gas industry has been safely injecting
CO2 for the purpose of enhanced oil and gas recovery.
LBNL is studying the potential effects of CO2 injection
on ground water and surrounding formations to determine the potential
for impacts on USDWs and human health in the event that a GS project is
not properly sited, operated, or managed. Specifically, LBNL is
evaluating the potential for GS to cause changes in ground water
quality as a result of CO2 leakage and subsequent
mobilization of trace elements such as arsenic, barium, cadmium,
mercury, lead, antimony, selenium, zinc, and uranium. In addition, LBNL
is evaluating basin-scale hydrological impacts of large-volume
injection of CO2 on groundwater aquifers and in particular,
the pressure front impacts caused by GS. Summaries of the interim
results for these research areas are discussed below. The full
publications are available in the docket and on LBNL's Web site at
https://esd.lbl.gov/GCS/projects/CO2/index_CO2.html.
1. Ground Water Quality Changes Related to the Mobilization of Trace
Elements
Summary
LBNL used a comprehensive computational model to evaluate the
potential impact of CO2 leaking from deep geologic
sequestration sites on the concentrations of trace elements in potable
ground waters (Birkholzer et al., 2008a). LBNL estimated the amount of
trace elements from native mineral species that could potentially be
mobilized by the intrusion of CO2, and the potential ground
water concentrations that could result. LBNL then compared these
estimates to EPA's Maximum Contaminant Levels (MCLs) and Action Levels
(ALs) for drinking water to determine the potential for drinking water
standards to be exceeded. It is important to note that model results
were dependent on several assumptions and parameter values with a large
degree of uncertainty, such as dissolution and dissociation constants.
LBNL recommended that further studies should be conducted, including
laboratory or field experiments and evaluation of natural analogues.
LBNL conducted multiple model runs to assess a variety of scenarios
and aquifer conditions and, as discussed below, found that if injected
CO2 comes into contact with shallow USDWs, some trace
element concentrations such as arsenic could increase.
Identification of Trace Elements of Concern
An important step in developing the model used to assess the
different scenarios was the identification of naturally occurring
minerals that could act as a source of trace elements in ground water
if they were to come into contact with CO2. This
identification was accomplished through an extensive review of the
scientific literature, through which potential minerals of concern were
identified. The presence of these minerals in aquifer rocks was
indirectly substantiated through an evaluation of more than 38,000
water-quality analyses from potable aquifers reported in the United
States Geological Survey's (USGS) National Water Information System
(NWIS). While the abundances of these host minerals are typically very
small, all trace elements targeted for study occur frequently in soils,
sediments, and aquifer rocks.
A preliminary assessment of CO2-related water quality
changes, including pH, was conducted by calculating the expected
equilibrium concentrations of trace elements as a function of the
amount of CO2 in a representative potable groundwater.
Results of this modeling obtained for typical aquifers under reducing
conditions indicate that arsenic could potentially exceed Federal
drinking water standards at elevated CO2 concentrations (40
CFR 141.62 (b)(16)). Other trace elements, such as barium, cadmium,
lead, antimony, and zinc, may also be mobilized in certain
circumstances, but the majority of results did not show mobilization at
levels exceeding the MCL or AL.
LBNL used reactive-transport modeling to further study the fate and
transport of arsenic and lead in a representative potable aquifer as
influenced by leakage of CO2. This study is described as
follows:
Prediction of the Fate and Transport of Trace Elements
LBNL used the reactive-transport model TOUGHREACT to 1) study and
predict the transport of CO2 within a shallow aquifer, 2)
estimate potential geochemical changes caused by the presence of
CO2, and 3) estimate the fate and transport of mobilized
trace elements. LBNL conducted sensitivity studies to account for a
range of conditions found in potable aquifers throughout the US and to
evaluate the uncertainty associated with geochemical processes and
model parameters. Starting with a representative ground water under
equilibrium conditions, the model was used to estimate the impact of
CO2 leakage into the aquifer for 100 years. For this
analysis, the investigators assumed a hypothetical release scenario
based on CO2 escape from a deep geologic sequestration site
via a preferential pathway, such as a fault zone, entering the shallow
aquifer at a constant rate.
Results from this model simulation suggest that if CO2
were to leak into a shallow aquifer, the potential for mobilization of
lead and arsenic could be enhanced, causing increases in the
concentration of these trace elements in ground water. While LBNL
studies did suggest that CO2 interaction could cause
significant concentration increases compared to the initial water
composition, the MCL for arsenic was exceeded in only a few simulation
scenarios, while the lead concentrations remained below the AL under
all scenarios. It is important to emphasize that these studies looked
at potential consequences of CO2 leakage into the USDW, not
the likelihood of such leakage occurring. The goal of the UIC program
and these regulations is to ensure that injectate does not contaminate
USDWs in the first place.
[[Page 44808]]
The Agency will use these preliminary results and public comments
on this research as well as potential site-specific analyses, to refine
and inform site characterization, monitoring, and remediation
requirements and guidance, if necessary, in the Agency's final
rulemaking. The Agency seeks comment on this research and any
additional studies related to a) mobilization of constituents and b)
the likelihood or frequency of such leakage/risks.
2. Basin-Scale Hydrologic Impacts of CO2 Storage
Summary
Pressure build-up from large volume CO2 sequestration
has been researched since the early 1990s. Recent studies have focused
on better understanding large-scale pressure responses for future
geologic sequestration projects (Zhou et al., 2008; Van der Meer and
Yavuz, 2008; Nicot, 2008; Birkholzer et al., 2009). LBNL studied a
hypothetical, future scenario of GS in a sedimentary basin as an
illustrative example to demonstrate the potential for basin-scale
hydrologic impacts of CO2 storage (Birkholzer et al.,
2008b).
Sedimentary Basin Case Study
The example basin considered in this case study contains deep
saline formations that are potential targets for large-scale
CO2 storage projects because they are geologically favorable
for permanent CO2 storage and the region has many large
stationary sources of CO2. The basin contains a thick,
extensive, high porosity, high permeability sandstone that is the
primary target for CO2 storage. A superior confining shale
layer is also present, making it an ideal site for geologic
sequestration projects.
LBNL used a preliminary computational hydrogeologic model of the
basin to simulate regional ground water flow patterns as influenced by
large-scale deployment of GS in the region. The model assumed a
scenario where 20 independent GS projects spaced throughout the center
of a 570 kilometers (km) by 550 km (354 miles by 342 miles) model
domain each injected 5 million tonnes (5.51 million tons) of
CO2 per year over 50 years. (The largest injection today is
on the order of a million/tons/per year). Modeling results for this
simulation indicated that the maximum size of each CO2 plume
was 6-8 km (3.7-5 miles) with lateral separation between each GS
project of about 30 km (18.6 miles). These model results suggest that
the basin is favorable for effective trapping of CO2.
In addition, simulation runs indicated that injection pressures did
not exceed fracture pressure or the maximum value used in the model for
this basin. However, results also indicated that far-field pressure
changes could propagate as far away as 200 km (124 miles) from the core
injection area where the geologic sequestration projects are located.
After CO2 injection ended in the simulation, pressure
buildup in the injection zone began to dissipate while the far-field
pressure response continued to increase and expand. For this simulation
example, a pressure increase of 0.5 bar existed at an areal extent of
nearly 400 km by 400 km (249 miles by 249 miles) after 50 years. These
model results indicate that basin-wide pressure influences can be large
and may have intersecting pressure perturbations in a multiple-site
scenario. While simulated changes in salinity within the storage
formation were relatively small, the predicted pressure changes could
push saline water upward into overlying aquifers if localized pathways
such as conductive faults existed. As these large scale simulations
indicated, limitations on injection volumes related to basin-scale
pressure build-up should be considered during CO2 capacity
estimation.
EPA believes that the example studied by LBNL illustrates the
importance of basin-scale evaluation of reservoir pressures and far-
field pressures resulting from CO2 injection. EPA requests
comment on this study and welcomes additional studies that provide
information on the need for basin-scale evaluations for GS injection.
D. Additional GS Research
There are international, consensus-based and peer-reviewed reports
on CCS, including the Intergovernmental Panel on Climate Change (IPCC)
Special Report on Carbon Dioxide Capture and Storage (IPCC, 2005),
which specifically includes a chapter on GS drawn from published
literature and research studies. Comprehensive reviews of the results
from GS research are also available (e.g., Holloway, 2001; Friedman,
2007; Tsang et al., 2008). EPA will continue to track research project
development and literature published by DOE and international
governments and organizations including the International Energy Agency
(IEA), IEA Greenhouse Gas Programme, and other major international CCS
initiatives.
With respect to geologic and reservoir modeling, EPA has conducted
one such synthesis and analysis of GS research to inform the rulemaking
efforts. Schnaar and Digiulio (2009) present a research review of over
forty GS modeling studies spanning from 1993-2008. This review found
that GS models are based on pre-existing codes that have been developed
for predicting the movement of water and solutes in soil, the behavior
of groundwater contaminants at hazardous waste sites, and the recovery
of oil and gas from petroleum-bearing formations. However, modeling the
injection and sequestration of CO2 poses unique challenges,
such as the need to properly characterize CO2 transport
properties across a large range of temperatures and pressures, and the
need to couple multiphase flow, reactive transport, and geomechanical
processes. The authors reviewed studies that demonstrated the use of
modeling in project design, site characterization, assessments of
leakage, and site monitoring.
The complete modeling review is available in the online public
docket at https://www.regulations.gov. A list of recent publications
addressing potential environmental risks and risk management approaches
for GS sites is also available in the docket. The Agency may use
information generated from these studies to identify implementation
guidance needs and refine the proposed requirements. EPA seeks comment
on these studies and requests other research on geologic and reservoir
modeling as well as research associated with potential environmental
risks and risk management approaches for GS.
IV. Injection Depth for GS Projects
A. What did EPA propose for Class VI well injection depth relative to
the location of USDWs?
In the proposed rule, EPA defined Class VI injection wells as wells
used for GS (injection) of CO2 beneath the lowermost
formation containing a USDW. In Section III.A.4 of the preamble, EPA
discussed Injection Depth in Relation to USDWs to further clarify the
Agency's expectations regarding injection depth for Class VI wells. The
proposed requirements would preclude injection of CO2 into
zones in between and above USDWs. EPA is aware that confining Class VI
CO2 injection to below the lowermost USDW may restrict the
use of sequestration in areas of the country with deep USDWs where well
construction would be technically impractical or infeasible. As
proposed, the definition would also preclude injection of
CO2 into shallow formations such as coal seams and basalts.
The Agency requested comment on alternative approaches that would allow
injection between and/or above the
[[Page 44809]]
lowermost USDW and thus potentially allow for more areas to be
available for GS while continuing to prevent endangerment of USDWs.
Approaches on which the Agency sought comment in the preamble, as
alternatives to the proposed injection depth requirements included:
Allowing Class VI CO2 injection above the
lowermost USDW when the Director determines that geologic conditions
exist that will prevent fluid movement into adjacent USDWs;
Allowing the use of an aquifer exemption process for Class
VI injection; and,
Establishing, by regulation, a minimum injection depth for
GS of CO2.
B. Why did EPA propose that Class VI wells inject below the lowermost
USDW?
EPA initiated the regulatory development process for GS and
proposed new, tailored Federal requirements appropriate for the unique
nature of injecting large volumes of CO2 for long-term
storage to ensure that USDWs are not endangered. The proposed injection
depth requirements for Class VI wells are consistent with the siting
and operational requirements for deep, technically sophisticated Class
I wells and are an important component of the UIC program.
The basis of these requirements is the principle that placing
distance between the injection formation and USDWs decreases risks to
USDWs. In these deep-well injection scenarios, the added depth and
distance between the injection zone and overlying formations serve both
as a buffer allowing for pressure dissipation and as a zone for
monitoring that may detect any excursions (of the injectate) out of the
injection zone. Additional distance also allows trapping mechanisms,
including dissolution of CO2 in native fluids and
mineralization, to occur over time--thereby reducing risks that
CO2 may migrate from the injection zone and endanger USDWs.
Additionally, the depth and distance below the lowermost USDW allow the
potential for the presence of additional confining layers (between the
injection zone and overlying formations/USDWs).
C. Injection Depth Comments, Data, and Research
EPA received a range of comments both in support of, and opposed
to, the proposed injection depth requirements for Class VI wells.
Comments Supporting the Proposed Injection Depth Requirements
Comments that supported the proposed requirements indicated that
injection should be constrained to below the lowermost USDW (should not
be allowed above and/or between USDWs) because:
SDWA requires the UIC program to promulgate regulations
(including injection depth requirements) that maximize USDW protection;
Injection below the lowermost USDW is a long-standing
principle of UIC deep well injection;
In many cases, injection below the lowermost USDW ensures
a greater distance between the injection zone and USDWs;
GS is a new/unproven technology (at large scale) and, in
the early years of deployment, injection depth limitations are prudent.
These requirements could be relaxed in the future as information is
learned about GS injection;
Keeping injection below the lowermost USDW will reduce the
likelihood of wells (e.g., water, mineral, and/or hydrocarbon
production) being drilled through a CO2 plume in the future.
These comments and concerns about injection depth are further
supported by ongoing research, data, and activities related to water
use, availability, and planning; some of this research and data were
submitted to the proposed rule docket (e.g., EPA-HQ-OW-2008-0390-
0181.1). Water availability research in the United States indicates
that water treatment of higher salinity waters (in excess of the USDW
protectiveness threshold of 10,000 ppm TDS) may be more cost effective
than the cost of obtaining water rights or surface water elsewhere in
the area (Sengebush, 2008). Additionally, as technologies advance,
treatment of increasingly deeper and/or higher salinity waters may
become a common practice employed in many communities throughout the
US. Other studies support the need to consider long-term drinking water
protection and the confluence of population growth and constrained
water resources in parts of the US when developing injection depth
requirements (US Government Accountability Office, 2003; Davidson, et
al., 2008).
Comments Opposed to the Proposed Injection Depth Requirements
Those opposed to the proposed requirements supported allowing
injection above and between USDWs. These commenters indicated that such
injection should be allowed under the following conditions and based on
the following arguments:
At any depth without limitations;
Based on site-specific information and in certain geologic
settings, where there are adequate confining systems above and below
the injection zone;
Where formations have been exempted (for other injection
purposes) and/or where the formations are greater than 10,000 ppm TDS;
Based on geographically delineated exemptions (e.g.,
specifically delineated formations, basins, or regions where injection
could occur at depths above/between USDW);
Because many parts of the country will be excluded from GS
activities and as a result CCS deployment may be restricted (if this
requirement is maintained as written);
Because Class II, Class III, and Class V operations are
already injecting above the lowermost USDW without any potential for
threats to underlying (or overlying) USDWs; and,
Because there should not be a blanket prohibition for
Class VI GS wells.
Research, information, and comments that support allowing injection
above and between USDWs have focused on climate change mitigation,
CO2 geologic storage capacity assessments, and current UIC
injection practices. Commenters interested in climate change mitigation
emphasized the role that GS will play in reducing greenhouse gas (GHG)
emissions while national GS capacity estimates focus on formations
irrespective of depth (above/below the lowermost USDW). Furthermore,
some specific research on CO2 injection for GS into various
formations including shallow, volcanic rocks such as flood basalts
(McGrail, et al., 2006) and coal seam injection (Dooley, et al., 2006;
IPCC, 2005; MIT 2007; White et al., 2005) illustrates the potential for
GS in these formations, but only if there is depth requirement
flexibility. Certain States have indicated that where USDWs are very
deep (e.g., 15,000 ft/4,572 meters and deeper) and layered (stratified)
these regions would become unavailable for large-scale GS projects
because injectors would not be able to comply with the current
injection depth (and well construction) requirements. These States
suggest that GS should be allowed in certain areas if a site-specific
demonstration can be made that USDWs will be protected.
Some comments support the suggestion that current Class II, Class
III, and Class V injection activities occurring above and between USDWs
may serve as a viable analogue for GS injection depth requirements.
Class II and Class III owners and operators of sites where injection is
taking place above and between USDWs must identify and demonstrate
upper and lower impermeable confining units.
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These confining units serve as barriers to fluid movement and pressure
and must ensure continuous injectate isolation, confinement, and USDW
protection. Identification of such units is conducted through analysis
of sonic and resistivity logs, drill stem tests, and wire line tests.
D. Evaluation of Concerns About Injection Depth for Class VI GS Wells
Discussion
Under Section 1421 of the Safe Drinking Water Act (SDWA), UIC
regulations must prevent underground injection that endangers USDWs.
While EPA has met this statutory requirement in the past by requiring
injection below the lowermost USDW, for some of the injection
activities that may pose increased risks, the Act allows other
approaches as well (Kobelski, et al., 2005).
In today's NODA, EPA is providing additional information on an
alternative for addressing injection depth in limited circumstances
where there are deep USDWs. EPA believes that a waiver process may
respond to the range of comments, both for and against the proposed
requirement that Class VI wells inject below the lowermost USDW. The
goals of this approach are to: (1) Provide flexibility to UIC Program
Directors and owner/operators that will undertake CO2
injection for GS; (2) respond to concerns about local and regional
geologic storage capacity limitations imposed by the proposed injection
depth requirements; (3) allow for a more site-specific assessment; (4)
accommodate injection into different formation types; and, (5) consider
the concept that CO2 injection for GS above and/or between
USDWs could be as safe and effective as injection below the lowermost
USDW as evidenced by past experiences with some Class II, III and V
injection wells. EPA believes this approach may additionally
accommodate requests for geographic flexibility while placing such
determinations at the State or Regional level. Lastly, the approach is
designed to acknowledge and accommodate comments and concerns about
drinking water resource availability and the potential/known future
needs, and to afford such water resources protection.
EPA is considering a number of topics and the implications of the
various commenters' concerns related to this potential alternative as
follows:
There have been a number of national GS capacity estimates
developed (e.g., by DOE's National laboratories, USGS, etc.). Some of
these assessments have broadly identified porous, permeable formations
that may receive and store CO2 at a range of depths beneath
the ground surface (Burruss, R.C., et al, 2009; DOE, 2007; Davidson et
al., 2008; MIT, 2007; Dooley, 2006). In developing injection depth
requirements, EPA acknowledges that these capacity estimates do not
directly address specific site suitability attributes that would be
identified through the UIC permitting site-characterization process.
Additionally, these formations (identified through capacity estimates)
may be stratified, stacked, or layered and in combination, their
cumulative capacity could be limited (i.e., less than assessed). In the
absence of such site-specific information, it is currently difficult to
identify what percentage of assessed national capacity is actually
suitable for GS. In addition, very small geologic storage sites, even
when aggregated within a given area, may not be conducive to/
appropriate for large-scale, commercial GS projects. However, the
approach described in this Notice allows for such a determination to be
made on a site-specific basis.
Second, the alternative under consideration does not prohibit
injection into any specific formation types (e.g., basalts and/or coal
seams). It affords all formations equal treatment and allows specific
regions of the country the regulatory flexibility to determine if any
injection at a particular site and depth is the appropriate approach.
It will also help to manage injection in areas where there may be
multiple, stratified formations with significant assessed cumulative
capacity.
Third, because the Agency believes that it is necessary to address
the specific, unique characteristics of Class VI injection (e.g., large
injection volumes, viscosity, and buoyancy) and the Agency does not
have information or data indicating that Class II operations are
entirely analogous to Class VI, large-scale injection, this alternative
allows Class VI injection depth considerations to be tailored for GS. A
number of dominant differences between Class II and Class VI operations
indicate that these well classes warrant different treatment. EPA
received comment during the public comment period supporting the need
for such a distinction. These differences include: the risk profiles
for these operations; the greater total injection volumes (of
CO2) for Class VI GS; and, differences in formation
pressures (potentially higher for GS), greater opportunities for
mobilization of constituents, and injection rates and operating
conditions.
The alternative EPA is considering relies on the principle of site-
suitability for GS: injection zones/formations that have suitable upper
and lower confining units, appropriate lateral and vertical extent to
receive and contain the injected CO2, and an appropriate
management scheme to ensure that the water and other resources
contained within the injection zone will not be needed in the future.
The management scheme will also ensure that there is a strategy
developed to address future needs to access formations below the
injection zone.
This approach would allow regulators and communities (e.g., States,
etc.) to assess the most appropriate injection depth for a given
project, in a given geographic or geologic area. It may also allow
communities, local, and State authorities to plan resource use
appropriately and, if necessary, circumvent the need to drill through a
CO2 filled zone/formation/plume to exploit resources (both
water and hydrocarbon) in or below the injection zone.
Conversely, EPA is weighing the fact that this alternative would be
a divergence from the existing UIC deep-well injection requirements for
industrial and hazardous waste injection. It will result in greater
injection depth variability throughout the United States and may result
in emplacement of fluids by injection in closer proximity to USDWs than
would occur under the proposed requirements. Additionally, adoption of
this alternative could potentially add a new administrative burden to
UIC programs pursuing the waiver approach.
Consideration of New Approach
Based on new information and data from comments received on the
proposed rule, the Agency is considering a waiver process to allow GS
injection above and between USDWs under specific conditions in lieu of
a blanket prohibition on injection above and between USDWs. The
proposed Class VI GS injection depth requirements would remain
unchanged but would allow an owner or operator seeking to inject above
and/or between USDWs to apply for a waiver from t