Standards of Performance for Petroleum Refineries, 35838-35881 [E8-13498]
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Federal Register / Vol. 73, No. 122 / Tuesday, June 24, 2008 / Rules and Regulations
Planning and Standards, Sector Policies
and Programs Division, Coatings and
Chemicals Group (E143–01),
Environmental Protection Agency,
Research Triangle Park, NC 27711,
telephone number: (919) 541–0884; fax
number: (919) 541–0246; e-mail
address: lucas.bob@epa.gov.
SUPPLEMENTARY INFORMATION:
ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Part 60
[EPA–HQ–OAR–2007–0011; FRL–8563–2]
RIN 2060–AN72
Standards of Performance for
Petroleum Refineries
I. General Information
Environmental Protection
Agency (EPA).
ACTION: Final rule.
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AGENCY:
SUMMARY: EPA is issuing final
amendments to the current Standards of
Performance for Petroleum Refineries.
This action also promulgates separate
standards of performance for new,
modified, or reconstructed process units
at petroleum refineries. The final
standards for new process units include
emissions limitations and work practice
standards for fluid catalytic cracking
units, fluid coking units, delayed coking
units, fuel gas combustion devices, and
sulfur recovery plants. These final
standards reflect demonstrated
improvements in emissions control
technologies and work practices that
have occurred since promulgation of the
current standards.
DATES: These final rules are effective on
June 24, 2008. The incorporation by
reference of certain publications listed
in the final rules is approved by the
Director of the Federal Register as of
June 24, 2008.
ADDRESSES: EPA has established a
docket for this action under Docket ID
No. EPA–HQ–OAR–2007–0011. All
documents in the docket are listed in
the www.regulations.gov index.
Although listed in the index, some
information is not publicly available,
e.g., confidential business information
or other information whose disclosure is
restricted by statute. Certain other
material, such as copyrighted material,
is not placed on the Internet and will be
publicly available only in hard copy
form. Publicly available docket
materials are available either
electronically in www.regulations.gov
or in hard copy at the EPA Docket
Center, Standards of Performance for
Petroleum Refineries Docket, EPA West
Building, Room 3334, 1301 Constitution
Ave., NW., Washington, DC. The Public
Reading Room is open from 8:30 a.m. to
4:30 p.m., Monday through Friday,
excluding legal holidays. The telephone
number for the Public Reading Room is
(202) 566–1744, and the telephone
number for the Air Docket is (202) 566–
1742.
FOR FURTHER INFORMATION CONTACT: Mr.
Robert B. Lucas, Office of Air Quality
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A. Does this action apply to me?
Categories and entities potentially
regulated by these final rules include:
Category
NAICS
code 1
Examples of regulated entities
Industry ..............
32411
Federal government.
State/local/tribal
government.
............
Petroleum refiners.
Not affected.
............
Not affected.
1 North
System.
American
Industry
Classification
This table is not intended to be
exhaustive, but rather provides a guide
for readers regarding entities likely to be
regulated by this action. To determine
whether your facility would be
regulated by this action, you should
examine the applicability criteria in 40
CFR 60.100 and 40 CFR 60.100a. If you
have any questions regarding the
applicability of this proposed action to
a particular entity, contact the person
listed in the preceding FOR FURTHER
INFORMATION CONTACT section.
B. Where can I get a copy of this
document?
In addition to being available in the
docket, an electronic copy of this final
action is available on the Worldwide
Web (WWW) through the Technology
Transfer Network (TTN). Following
signature, a copy of this final action will
be posted on the TTN’s policy and
guidance page for newly proposed or
promulgated rules at https://
www.epa.gov/ttn/oarpg. The TTN
provides information and technology
exchange in various areas of air
pollution control.
C. Judicial Review
Under section 307(b)(1) of the Clean
Air Act (CAA), judicial review of these
final rules is available only by filing a
petition for review in the United States
Court of Appeals for the District of
Columbia Circuit by August 25, 2008.
Under section 307(b)(2) of the CAA, the
requirements established by these final
rules may not be challenged separately
in any civil or criminal proceedings
brought by EPA to enforce these
requirements.
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Section 307(d)(7)(B) of the CAA
further provides that ‘‘[o]nly an
objection to a rule or procedure which
was raised with reasonable specificity
during the period for public comment
(including any public hearing) may be
raised during judicial review.’’ This
section also provides a mechanism for
us to convene a proceeding for
reconsideration, ‘‘[i]f the person raising
an objection can demonstrate to the EPA
that it was impracticable to raise such
objection within [the period for public
comment] or if the grounds for such
objection arose after the period for
public comment (but within the time
specified for judicial review) and if such
objection is of central relevance to the
outcome of the rule.’’ Any person
seeking to make such a demonstration to
us should submit a Petition for
Reconsideration to the Office of the
Administrator, U.S. EPA, Room 3000,
Ariel Rios Building, 1200 Pennsylvania
Ave., NW., Washington, DC 20460, with
a copy to both the person(s) listed in the
preceding FOR FURTHER INFORMATION
CONTACT section, and the Associate
General Counsel for the Air and
Radiation Law Office, Office of General
Counsel (Mail Code 2344A), U.S. EPA,
1200 Pennsylvania Ave., NW.,
Washington, DC 20460.
D. How is this document organized?
The information presented in this
preamble is organized as follows:
I. General Information
A. Does this action apply to me?
B. Where can I get a copy of this
document?
C. Judicial Review
D. How is this document organized?
II. Background Information
III. Summary of the Final Rules and Changes
Since Proposal
A. What are the final amendments to the
standards for petroleum refineries (40
CFR part 60, subpart J)?
B. What are the final requirements for new
fluid catalytic cracking units and new
fluid coking units (40 CFR part 60,
subpart Ja)?
C. What are the final requirements for new
sulfur recovery plants (40 CFR part 60,
subpart Ja)?
D. What are the final requirements for new
fuel gas combustion devices (40 CFR part
60, subpart Ja)?
E. What are the final work practice
standards (40 CFR part 60, subpart Ja)?
F. What are the modification and
reconstruction provisions?
IV. Summary of Significant Comments and
Responses
A. PM Limits for Fluid Catalytic Cracking
Units
B. SO2 Limits for Fluid Catalytic Cracking
Units
C. NOX Limit for Fluid Catalytic Cracking
Units
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D. PM and SO2 Limits for Fluid Coking
Units
E. NOX Limit for Fluid Coking Units
F. SO2 Limits for Sulfur Recovery Plants
G. NOX Limit for Process Heaters
H. Fuel Gas Combustion Devices
I. Flares
J. Delayed Coking Units
K. Other Comments
V. Summary of Cost, Environmental, Energy,
and Economic Impacts
A. What are the impacts for petroleum
refineries?
B. What are the secondary impacts?
C. What are the economic impacts?
D. What are the benefits?
VI. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory
Planning and Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act
D. Unfunded Mandates Reform Act
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation
and Coordination With Indian Tribal
Governments
G. Executive Order 13045: Protection of
Children From Environmental Health
Risks and Safety Risks
H. Executive Order 13211: Actions
Concerning Regulations That
Significantly Affect Energy Supply,
Distribution, or Use
I. National Technology Transfer and
Advancement Act
J. Executive Order 12898: Federal Actions
to Address Environmental Justice in
Minority Populations and Low-Income
Populations
K. Congressional Review Act
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II. Background Information
New source performance standards
(NSPS) implement CAA section 111(b)
and are issued for categories of sources
which cause, or contribute significantly
to, air pollution which may reasonably
be anticipated to endanger public health
or welfare. The primary purpose of the
NSPS is to attain and maintain ambient
air quality by ensuring that the best
demonstrated emission control
technologies are installed as the
industrial infrastructure is modernized.
Since 1970, the NSPS have been
successful in achieving long-term
emissions reductions in numerous
industries by assuring cost-effective
controls are installed on new,
reconstructed, or modified sources.
Section 111 of the CAA requires that
NSPS reflect the application of the best
system of emission reductions which
(taking into consideration the cost of
achieving such emission reductions, any
non-air quality health and
environmental impact and energy
requirements) the Administrator
determines has been adequately
demonstrated. This level of control is
commonly referred to as best
demonstrated technology (BDT).
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Section 111(b)(1)(B) of the CAA
requires EPA to periodically review and
revise the standards of performance, as
necessary, to reflect improvements in
methods for reducing emissions. As a
result of our periodic review of the
NSPS for petroleum refineries (40 CFR
part 60, subpart J), we proposed
amendments to the current standards of
performance and separate standards of
performance for new process units (72
FR 27278, May 14, 2007). In response to
several requests, we extended the 60day comment period from July 13, 2007,
to August 27, 2007 (72 FR 35375, June
28, 2007). We also issued a notice of
data availability (NODA) (72 FR 69175,
December 7, 2007) to notify the public
that additional information had been
added to the docket; the NODA also
extended the public comment period on
the proposed rule to January 7, 2008.
We received a total of 38 comments
from refineries, industry trade
associations, and consultants; State and
local environmental and public health
agencies; environmental groups; and
members of the public during the
extended comment period, and 8
additional comments on the NODA.
These final rules reflect our full
consideration of all of the comments we
received. Detailed responses to the
comments not included in this preamble
are contained in the Response to
Comments document which is included
in the docket for this rulemaking.
III. Summary of the Final Rules and
Changes Since Proposal
We are promulgating several
amendments to provisions in the
existing NSPS in 40 CFR part 60,
subpart J. Many of these amendments
are technical clarifications and
corrections that are also included in the
final standards in 40 CFR part 60,
subpart Ja. For example, we are revising
the definition of ‘‘fuel gas’’ to indicate
that vapors collected and combusted to
comply with certain wastewater and
marine vessel loading provisions are not
considered fuel gas. Consequently, these
vapors are exempt from the sulfur
dioxide (SO2) treatment standard in 40
CFR 60.104(a)(1) and are not required to
be monitored. We are also finalizing
certain monitoring exemptions that we
proposed for fuel gases that are
identified as inherently low sulfur or
demonstrated to contain a low sulfur
content. See 40 CFR 60.105(a)(4)(iv). We
are also revising the coke burn-off
equation to account for oxygen (O2)—
enriched air streams. Other amendments
include clarification of definitions and
correction of grammatical and
typographical errors.
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The final standards in 40 CFR part 60,
subpart Ja include emission limits for
fluid catalytic cracking units (FCCU),
fluid coking units (FCU), sulfur recovery
plants (SRP), and fuel gas combustion
devices. Subpart Ja also includes work
practice standards for reducing
emissions of volatile organic
compounds (VOC) from flares,
minimizing SO2 emissions from fuel gas
combustion devices and SRP, and for
reducing emissions of VOC from
delayed coking units. Only those
affected facilities that commence
construction, modification, or
reconstruction after May 14, 2007 will
be affected by the standards in subpart
Ja. Units for which construction,
modification, or reconstruction
commenced on or before May 14, 2007
must continue to comply with the
applicable standards under the current
NSPS in 40 CFR part 60, subpart J, as
amended.
A. What are the final amendments to
the standards for petroleum refineries
(40 CFR part 60, subpart J)?
As proposed, we are amending the
definition of ‘‘fuel gas’’ to specifically
exclude vapors that are collected and
combusted in an air pollution control
device installed to comply with a
specified wastewater or marine vessel
loading emissions standard. The
thermal combustion control devices
themselves are still considered to be
affected fuel gas combustion devices if
they combust other gases that meet the
definition of fuel gas, and all auxiliary
fuel gas fired to these devices are subject
to the fuel gas limit; however,
continuous monitoring is not required
for the vapors collected from wastewater
or marine vessel loading operations that
are being incinerated because these
gases are not considered to be fuel gases
under the definition of ‘‘fuel gas’’ in 40
CFR part 60, subpart J.
We are also finalizing exemptions for
certain fuel gas streams from all
continuous monitoring requirements.
See 40 CFR 60.105(a)(4)(iv). Monitoring
is not required for combustion in a flare
of process upset gases or flaring of gases
from relief valve leakage or emergency
malfunctions since these streams are
exempt from the standard under 40 CFR
60.104(a)(1). Additionally, monitoring is
not required for inherently low sulfur
fuel gas streams since the emissions
generated by combusting such streams
will necessarily be well below the
standard. These streams include pilot
gas flames, gas streams that meet
commercial-grade product
specifications with a sulfur content of
30 parts per million by volume (ppmv)
or less, fuel gases produced by process
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units that are intolerant to sulfur
contamination, and fuel gas streams that
an owner or operator can demonstrate
are inherently low-sulfur. Owners and
operators are required to document the
exemption for which each fuel gas
stream applies and ensure that the
stream remains qualified for that
exemption.
For accuracy in the calculation of the
coke burn-off rate, we are revising the
coke burn-off rate equation in 40 CFR
60.106(b)(3) to be consistent with the
equation in 40 CFR 63.1564(b)(4)(i) of
the National Emission Standards for
Hazardous Air Pollutants for Petroleum
Refineries: Catalytic Cracking Units,
Catalytic Reforming Units, and Sulfur
Recovery Units (40 CFR part 63, subpart
UUU). This revision adds a fourth term
to the coke burn-off rate equation to
account for the use of O2-enriched air.
Other revisions to the equation change
the constant values and the units of the
resulting coke burn-off rate from
Megagrams per hour (Mg/hr) and tons
per hour (tons/hr) to kilograms per hour
(kg/hr) and pounds per hour (lb/hr).
We proposed to amend the definition
of ‘‘Claus sulfur recovery plant’’ in 40
CFR 60.101(i) to clarify that the SRP
may consist of multiple units and that
primary sulfur pits are considered part
of the Claus SRP consistent with the
Agency’s current position. Commenters
expressed concern that change to a 40
CFR part 60, subpart J definition that
could lead to retroactive noncompliance. We disagree with those
concerns as we believe the definition as
currently written provides for such
coverage. Nonetheless, we are not
amending this definition in the final
amendments for subpart J and will
continue to address individual
applicability issues under our
applicability determination procedures.
Similarly, we proposed revisions to the
subpart J definitions of ‘‘oxidation
control system’’ and ‘‘reduction control
system’’ in 40 CFR 60.101(j) and 40 CFR
60.101(k), respectively, to clarify that
these systems were intended to recycle
the sulfur back to the Claus SRP. The
proposed amendments needlessly limit
the types of tail gas treatment systems
that can be used; therefore, we are not
amending these definitions in the final
amendments for subpart J.
The final amendments also include
technical corrections to fix references
and other miscellaneous errors in 40
CFR part 60, subpart J. Table 1 of this
preamble describes the miscellaneous
technical corrections not previously
described in this preamble that are
included in the amendments to subpart
J.
TABLE 1.—TECHNICAL CORRECTIONS TO 40 CFR PART 60, SUBPART J
Section
Technical correction and reason
60.100 ........................
60.100(a) ...................
Replace instances of ‘‘construction or modification’’ with ‘‘construction, reconstruction, or modification.’’
Replace ‘‘except Claus plants of 20 long tons per day (LTD) or less’’ with ‘‘except Claus plants with a design capacity
for sulfur feed of 20 long tons per day (LTD) or less’’ to clarify that the size cutoff is based upon design capacity and
sulfur content in the inlet stream rather than the amount of sulfur produced.
Insert ending date for applicability of 40 CFR part 60, subpart J (one date for flares and another date for all other affected facilities); sources beginning construction, reconstruction, or modification after this date will be subject to 40
CFR part 60, subpart Ja.
Replace ‘‘g/MJ’’ with ‘‘grams per Gigajoule (g/GJ)’’ to correct units.
Replace ‘‘sulfur dioxide’’ with ‘‘SO2’’ and replace ‘‘50 ppm by volume (vppm)’’ with ‘‘50 ppm by volume (ppmv)’’ for consistency in unit and acronym definition.
Add ‘‘to reduce SO2 emissions’’ to the end of the phrase ‘‘Without the use of an add-on control device’’ at the beginning
of the paragraph to clarify the type of control device to which this paragraph refers; replace ‘‘sulfur dioxide’’ with
‘‘SO2’’ for consistency in acronym definition.
Add ‘‘either’’ before ‘‘an instrument for continuously monitoring’’ and replace ‘‘except where an H2S monitor is installed
under paragraph (a)(4)’’ with ‘‘or monitoring as provided in paragraph (a)(4)’’ to more accurately refer to the requirements of § 60.105(a)(4) and clarify that there is a choice of monitoring requirements.
Replace ‘‘accurately represents the S2 emissions’’ with ‘‘accurately represents the SO2 emissions’’ to correct a typographical error.
Replace ‘‘In place’’ with ‘‘Instead’’ at the beginning of this paragraph and add ‘‘for fuel gas combustion devices subject
to § 60.104(a)(1)’’ after ‘‘paragraph (a)(3) of this section’’ to clarify that there is a choice of monitoring requirements.
Replace ‘‘seeks to comply with § 60.104(b)(1)’’ with ‘‘seeks to comply specifically with the 90-percent reduction option
under § 60.104(b)(1)’’ to clearly identify the emission limit option to which the monitoring requirement in this paragraph
refers.
Change ‘‘shall be set 125 percent’’ to ‘‘shall be set at 125 percent’’ to correct a grammatical error; replace ‘‘sulfur dioxide’’ with ‘‘SO2’’ for consistency in acronym definition.
Replace the incorrect reference to 40 CFR 60.105(a)(1) with a correct reference to 40 CFR 60.104(a)(1); add ‘‘The
method ANSI/ASME PTC 19.10–1981, ‘‘Flue and Exhaust Gas Analyses,’’ (incorporated by reference—see § 60.17) is
an acceptable alternative to EPA Method 6 of Appendix A–4 to part 60.’’ after the first sentence of this paragraph to
include a voluntary consensus method.
Replace both occurrences of ‘‘50 vppm’’ with ‘‘50 ppmv’’ for consistency in unit definition.
Redesignate current 40 CFR 60.107(e) as 40 CFR 60.107(f) to allow space for a new paragraph (e).
Redesignate current 40 CFR 60.107(f) as 40 CFR 60.107(g) to allow space for a new paragraph (e).
Replace the incorrect reference to 40 CFR 60.107(e) with a correct reference to 40 CFR 60.107(f).
60.100(b) ...................
60.102(b) ...................
60.104(b)(1) ...............
60.104(b)(2) ...............
60.105(a)(3) ...............
60.105(a)(3)(iv) ..........
60.105(a)(4) ...............
60.105(a)(8) ...............
60.105(a)(8)(i) ............
60.106(e)(2) ...............
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60.107(c)(1)(i) ............
60.107(f) ....................
60.107(g) ...................
60.108(e) ...................
B. What are the final requirements for
new fluid catalytic cracking units and
new fluid coking units (40 CFR part 60,
subpart Ja)?
The final standards for new FCCU
include emission limits for particulate
matter (PM), SO2, nitrogen oxides
(NOX), and carbon monoxide (CO). The
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final standards include no universal
opacity limit because the opacity limit
in 40 CFR part 60, subpart J is intended
to ensure compliance with the PM limit.
40 CFR part 60, subpart Ja requires that
sources use direct PM monitoring, bag
leak detection systems, or parameter
monitoring (along with annual emission
tests) to ensure compliance with the PM
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limit. A provision for a site-specific
opacity operating limit is provided for
units that meet the PM emission limits
using a cyclone.
For PM emissions from new FCCU
and new FCU, we proposed a PM limit
of 0.5 pounds (lb)/1,000 lb coke burnoff
in the regenerator or (if a PM continuous
emission monitoring system (CEMS) is
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used), 0.020 grains per dry standard
cubic feet (gr/dscf) corrected to 0
percent excess air. We have revised the
final PM standards to establish separate
limits for modified or reconstructed
FCCU (1 lb/1,000 lb coke burn or 0.040
gr/dscf corrected to 0 percent excess air)
and newly constructed FCCU (0.5 lb/
1,000 lb coke burn or 0.020 gr/dscf
corrected to 0 percent excess air). The
final PM limit for new, modified, or
reconstructed FCU is 1 lb/1,000 lb coke
burn or 0.040 gr/dscf corrected to 0
percent excess air.
Initial compliance with the PM
emission limits for FCCU and FCU is
determined using EPA Method 5, 5B or
5F (40 CFR part 60, appendix A–3)
instead of being restricted to only EPA
Method 5 as previously proposed.
Procedures for computing the PM
emission rate using the total PM
concentration, effluent gas flow rate,
and coke burn-off rate are the same as
in 40 CFR part 60, subpart J, as
amended. To demonstrate ongoing
compliance, an owner or operator must
monitor PM emission control device
operating parameters and conduct
annual PM performance tests, use a PM
CEMS, or operate bag leak detection
systems and conduct annual PM
performance tests. A new alternative
allows refineries with wet scrubbers as
PM control devices to use the approved
alternative in 40 CFR 63.1573(a) for
determining exhaust gas flow rate
instead of a continuous parameter
monitoring system (CPMS). An
alternative to the requirements for
monitoring the pressure drop from wet
scrubbers that are equipped with jet
ejectors or atomizing spray nozzles is to
conduct a daily check of the air or water
pressure to the nozzles and record the
results of each inspection. The final rule
also includes procedures for
establishing an alternative opacity
operating limit for refiners that use
continuous opacity monitoring systems
(COMS); this alternative is allowed only
for units that choose to comply with the
PM limit using cyclones. If operating
parameters are used to demonstrate
ongoing compliance, the owner or
operator must monitor the same
parameters during the initial
performance test, and develop operating
parameter limits for the applicable
parameters. The operating limits must
be based on the three-run average of the
values for the applicable parameters
measured over the three test runs. If
ongoing compliance is demonstrated
using a PM CEMS, the CEMS must meet
the conditions in Performance
Specification 11 (40 CFR part 60,
appendix B) and the quality assurance
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(QA) procedures in Procedure 2, 40 CFR
part 60, appendix F. The relative
response audits must be conducted
annually (in lieu of annual performance
tests for units not employing a PM
CEMS) and response correlation audits
must be conducted once every 5 years.
For NOX emissions from the affected
FCCU and FCU, we proposed a limit of
80 ppmv based on a 7-day rolling
average (dry basis corrected to 0 percent
excess air) and co-proposed having no
limit for FCU. We are adopting the 80
ppmv NOX emission limits for FCCU
and FCU as proposed. Initial
compliance with the 80 ppmv emission
limit is demonstrated by conducting a
performance evaluation of the CEMS in
accordance with Performance
Specification 2 in 40 CFR part 60,
appendix B, with Method 7 (40 CFR part
60, appendix A–4) as the reference
method. Ongoing compliance with these
emission limits is determined using the
CEMS to measure NOX emissions as
discharged to the atmosphere, averaged
over 7-day periods.
No changes have been made to the
proposed SO2 emission limits for
affected FCCU and FCU. The final SO2
emission limits are to maintain SO2
emissions to the atmosphere less than or
equal to 50 ppmv on a 7-day rolling
average basis, and less than or equal to
25 ppmv on a 365-day rolling average
basis (both limits corrected to 0 percent
moisture and 0 percent excess air).
Initial compliance with the final SO2
emission limits are demonstrated by
conducting a performance evaluation of
the SO2 CEMS in accordance with
Performance Specification 2 (40 CFR
part 60, Appendix B) with Method 6,
6A, or 6C (40 CFR part 60, Appendix A–
4) as the reference method. Ongoing
compliance with both SO2 emission
limits is determined using the CEMS to
measure SO2 emissions as discharged to
the atmosphere, averaged over the 7-day
and 365-day averaging periods.
No changes have been made since
proposal to the CO limits. The final CO
emission limit for the affected FCCU
and FCU is 500 ppmv (1-hour average,
dry at 0 percent excess air). Initial
compliance with this emission limit is
demonstrated by conducting a
performance evaluation for the CEMS in
accordance with Performance
Specification 4 (40 CFR part 60,
appendix B) with Method 10 or 10A (40
CFR part 60, Appendix A–4) as the
reference method. For Method 10 (40
CFR part 60, Appendix A–4), the
integrated sampling technique is to be
used. Ongoing compliance with this
emission limit is determined on an
hourly basis using the CEMS to measure
CO emissions as discharged to the
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35841
atmosphere. An exemption from
monitoring may be requested for an
FCCU or FCU if the owner or operator
can demonstrate that ‘‘average CO
emissions’’ are less than 50 ppmv (dry
basis). As proposed, units that are
exempted from the CO monitoring
requirements must comply with control
device operating parameter limits.
C. What are the final requirements for
new sulfur recovery plants (40 CFR part
60, subpart Ja)?
For new, modified, and reconstructed
SRP with a capacity greater than 20 long
tons per day (LTD) (large SRP), we
proposed a limit of 250 ppmv total
sulfur (combined SO2 and reduced
sulfur compounds) as SO2 (dry basis at
0 percent excess air determined on a 12hour rolling average basis). The refinery
could comply with the limit for each
process train or release point or with a
flow rate weighted average of 250 ppmv
for all release points. For affected SRP
with a capacity less than 20 LTD (small
SRP), we proposed a mass emissions
limit for total sulfur equal to 1 weight
percent or less of sulfur recovered
(determined hourly on a 12-hour rolling
average basis).
In this final rule, we are adopting the
current limits in subpart J (which
include separate emission limits for
oxidative and reductive systems) for
affected large SRP. For these affected
SRP, the final limits for SRP having an
oxidation control system or a reduction
control system followed by incineration
is 250 ppmv (dry basis) of SO2 at zero
percent excess air. For an affected SRP
with a reduction control system not
followed by incineration, the final limit
is 300 ppmv of reduced sulfur
compounds and 10 ppmv of hydrogen
sulfide (H2S), each calculated as ppm
SO2 by volume (dry basis) at zero
percent excess air. If the SRP consists of
multiple process trains or release points,
the refinery can comply with the limit
for each process train or release point or
with a flow rate weighted average of 250
ppmv for all release points. A new
alternative allows refineries to use a
correlation to calculate their effective
emission limit for Claus SRP that use
oxygen enrichment in the Claus burner.
For a small affected SRP, the sulfur
recovery efficiency standard is based on
a sulfur recovery efficiency of 99
percent. However, due to the difficulties
associated with on-going monitoring of
SRP recovery efficiency, in this final
rule, we are promulgating concentration
limits that correlate with a sulfur
recovery efficiency of 99 percent. For a
Claus unit with an oxidative control
system or any small SRP followed by an
incinerator the emission limit is 2,500
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ppmv (dry basis) of SO2 at zero percent
excess air. For all other small SRP, the
emission limit is 3,000 ppmv reduced
sulfur compound and 100 ppmv H2S,
each calculated as ppm SO2 by volume
(dry basis) at zero percent excess air. A
similar correlation is provided for small
Claus SRP that use oxygen enrichment,
similar to that provided for large SRP.
The standards for small SRP apply to all
release points from the SRP combined
(note that secondary sulfur storage units
are not considered part of the SRP). We
are not promulgating the H2S limit of 10
ppmv (dry basis, at 0 percent excess air
determined on a 12-hour rolling average
basis) or related operating limits that
were included in § 60.102a(e) and (f) of
the proposed rule.
Initial compliance with the emission
limit for large SRP is demonstrated by
conducting a performance evaluation for
the SO2 CEMS in accordance with either
Performance Specification 2 (40 CFR
part 60, Appendix B) for SRP with
oxidation control systems or reduction
control systems followed by
incineration, or Performance
Specification 5 (40 CFR part 60,
Appendix B) for SRP with reduction
control systems not followed by
incineration. The owner or operator
must operate and maintain oxygen
monitors according to Performance
Specification 3 (40 CFR part 60,
Appendix B).
Ongoing compliance with the SO2
limits for large SRP is determined using
an SO2 CEMS (for oxidative or reductive
systems followed by incineration) or a
CEMS that uses an air or O2 dilution
and oxidation system to convert the
reduced sulfur to SO2 and then
measures the total resultant SO2
concentration (for reductive systems not
followed by incineration). An O2
monitor is also required for converting
the measured combined SO2
concentration to the concentration at 0
percent O2.
Initial and ongoing compliance
requirements for small SRP are the same
as for large SRP.
D. What are the final requirements for
new fuel gas combustion devices (40
CFR part 60, subpart Ja)?
In the subpart Ja proposal, we divided
fuel gas combustion devices into two
separate affected sources: ‘‘process
heaters’’ and ‘‘other fuel gas combustion
devices.’’ In response to comments, we
have eliminated the proposed definition
of ‘‘other fuel gas combustion devices’’
and revised the standards to either refer
to fuel gas combustion devices, which
include process heaters, or to refer
specifically to process heaters. This
revision makes the definition of ‘‘fuel
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gas combustion devices’’ consistent
with subpart J. Based on public
comments, we have also added a
definition of ‘‘flare’’ as a subcategory of
fuel gas combustion devices. The owner
or operator of an affected flare must
comply with the fuel gas combustion
device requirements as well as specific
provisions for flares as described in
section III.E of this preamble.
We proposed a primary sulfur dioxide
emission limit for fuel gas combustion
devices of 20 ppmv or less SO2 (dry at
0 percent excess air) on a 3-hour rolling
average basis and 8 ppmv or less on a
365-day rolling average basis. We also
proposed an alternative limit of 160
ppmv H2S or, in the case of cokerderived fuel gas, 160 ppmv total
reduced sulfur (TRS), on a 3-hour
rolling average basis and 60 ppmv or
less on a 365-day rolling average basis.
We are promulgating the 20 ppmv and
8 ppmv limits for SO2 as proposed. We
are also promulgating the alternative
limit except that the limits are
expressed and measured as H2S in all
cases. The alternative H2S limit is 162
ppmv or less in the fuel gas on a 3-hour
rolling average basis and 60 ppmv or
less in the fuel gas on a 365-day rolling
average basis. The alternative limit of
162 ppmv is based on standard
conditions, which are defined in the
NSPS General Provisions at 40 CFR 60.2
as being 68°F and 1 atmosphere. Using
these as standard conditions, the
subpart J emission limit is equivalent to
162 ppmv H2S rather than 160 ppmv.
The final rule does not include an
alternative TRS limit for SO2.
Initial compliance with the 20 ppmv
SO2 limit or the 162 ppmv H2S
concentration limits is demonstrated by
conducting a performance evaluation for
the CEMS. The performance evaluation
for an SO2 CEMS is conducted in
accordance with Performance
Specification 2 in 40 CFR part 60,
Appendix B. The performance
evaluation for an H2S CEMS is
conducted in accordance with
Performance Specification 7 in 40 CFR
part 60, Appendix B. Ongoing
compliance with the sulfur oxides
emission limits is determined using the
applicable CEMS to measure either SO2
in the exhaust gas to the atmosphere or
H2S in the fuel gas, averaged over the 3hour and 365-day averaging periods.
Similar to clarifications for 40 CFR
part 60, subpart J, the definition of ‘‘fuel
gas’’ includes exemptions for vapors
collected and combusted in an air
pollution control device installed to
comply with specified wastewater or
marine vessel loading provisions. We
are also streamlining the process for an
owner or operator to demonstrate that a
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Sfmt 4700
fuel gas stream not explicitly exempted
from continuous monitoring is
inherently low sulfur.
For new, modified, or reconstructed
process heaters with a rated capacity
greater than 20 million British thermal
units per hour (MMBtu/hr), we
proposed a NOX limit of 80 ppmv (dry
basis, corrected to 0 percent excess air)
on a 24-hour rolling average basis. The
final NOX emission limit for affected
process heaters is 40 ppmv on a 24-hour
rolling average basis (dry at 0 percent
excess air) for process heaters greater
than 40 MMBtu/hr. For process heaters
greater than 100 MMBtu/hr capacity,
initial compliance with the 40 ppmv
emission limit is demonstrated by
conducting a performance evaluation of
the CEMS in accordance with
Performance Specification 2 in 40 CFR
part 60, Appendix B. For process
heaters between 40 MMBtu/hr and 100
MMBtu/hr capacity, initial compliance
is demonstrated using EPA Method 7
(40 CFR part 60, Appendix A–4). For
process heaters greater than 100
MMBtu/hr capacity, ongoing
compliance with this emission limit is
determined using the CEMS to measure
NOX emissions as discharged to the
atmosphere, averaged over 24-hour
periods. For process heaters between 40
MMBtu/hr and 100 MMBtu/hr capacity,
ongoing compliance with this emission
limit is determined using biennial
performance tests.
E. What are the final work practice
standards (40 CFR part 60, subpart Ja)?
We proposed three work practice
standards to reduce SO2, VOC, and NOX
emissions from flares and from startup,
shutdown, and malfunction events and
to reduce VOC and SO2 emissions from
delayed coking units. We also coproposed to require only one of these
work practice standards: the
requirement to depressure delayed
coking units. This proposed standard
required new delayed coking units to
depressure to 5 pounds per square inch
gauge (psig) during reactor vessel
depressuring and vent the exhaust gases
to the fuel gas system.
We are promulgating a work practice
standard for delayed coking units and
modified requirements to reduce
emissions from flares. The final work
practice standard for delayed cokers
requires affected delayed coking units to
depressure to 5 pounds per square inch
gauge (psig) during reactor vessel
depressuring. We are requiring the
exhaust gases to be vented to the fuel
gas system as proposed or to a flare.
To reduce SO2 emissions from the
combustion of sour fuel gases, the final
rule requires refineries to conduct a root
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cause analysis of any emissions limit
exceedance or process start-up,
shutdown, upset, or malfunction that
causes a discharge into the atmosphere,
either directly or indirectly, from any
fuel gas combustion device or sulfur
recovery plant subject to the provisions
of subpart Ja that exceeds 500 pounds
per day (lb/day) of SO2. Recordkeeping
and reporting requirements apply in the
event of such a discharge. Newly
constructed and reconstructed flares
must comply with these requirements
immediately upon startup. Modified
flares must comply no later than the
first discharge that occurs after that flare
has been an affected flare for 1 year.
In response to comments regarding
the work practice standards for fuel gas
producing units and associated
difficulties with no routine flaring, we
re-evaluated the work practice standards
and have decided not to promulgate a
work practice standard for fuel gas
producing units. Rather, we have
decided to define a flare as an affected
facility and adopt regulations applicable
to it. Therefore, we are not promulgating
the proposed definition of ‘‘fuel gas
producing unit’’ and the proposed
requirement for ‘‘no routine flaring.’’
Instead, we are promulgating the
following requirements for flares that
become affected facilities after June 24,
2008: (1) Flare fuel gas flow rate
monitoring; (2) a flare fuel gas flow rate
limit; and (3) a flare management plan.
Affected flares cannot exceed a flow rate
of 250,000 standard cubic feet per day
(scfd) on a 30-day rolling average basis.
In cases where the flow would exceed
this value, the owner or operator would
install a flare gas recovery system or
implement other methods to reduce
flaring from the affected flare. To
demonstrate compliance with the flow
rate limitations, flow rate monitors must
be installed and operated. Newly
constructed and reconstructed flares
must comply with the flow rate
limitations and the monitoring
requirements immediately upon startup.
Modified flares must comply with the
flow rate limitations and the associated
monitoring provisions no later than 1
year after the flare becomes an affected
facility. A provision is provided for an
exclusion from the flow limitation for
times when the refinery can
demonstrate that the refinery produces
more fuel gas than it needs to fuel the
refinery combustion devices (i.e., it is
fuel gas rich) or that the flow is due to
an upset or malfunction, provided the
refinery follows procedures outlined in
the flare management plan. The flare
management plan should address
potential causes of fuel gas imbalances
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Jkt 214001
(i.e., excess fuel gas) and records to be
maintained to document these periods.
As described in 40 CFR 60.103a(a), the
flare management plan must include a
diagram illustrating all connections to
each affected flare, identification of the
flow rate monitoring device and a
detailed description of the
manufacturer’s specifications regarding
quality assurance procedures,
procedures to minimize flaring during
planned start-up and shut down events,
and procedures for implementing root
cause analysis when daily flow to the
flare exceeds 500,000 scfd. The root
cause analysis procedures should
address the evaluation of potential
causes of upsets or malfunctions and
records to be maintained to document
the cause of the upset or malfunction.
Newly constructed and reconstructed
flares must comply with the flare
management plan requirements
immediately upon startup. Modified
flares must comply with the flare
management plan requirements no later
than 1 year after the flare becomes an
affected facility. Additionally, as
described above, the owner or operator
of a modified flare must conduct the
first root cause analysis no later than the
first discharge that occurs after that flare
has been an affected flare for 1 year.
Excess emission events for the flow rate
limit of 250,000 scfd and the result of
root cause analysis must be reported in
the semi-annual compliance reports.
Because affected flares are also
affected fuel gas combustion devices,
the root cause analysis for SO2
emissions exceeding 500 lbs/day also
applies to all affected flares. However,
compliance with the 500 lb/day root
cause analysis will also require
continuous monitoring of total reduced
sulfur of all gases flared. Although all
fuel gas combustion devices are
required to comply with continuous H2S
monitoring of fuel gas, flares routinely
accept gases from upsets, malfunctions
and startup and shutdown events, and
H2S or sulfur monitoring is not
specifically required for these gases. In
subpart Ja, we explicitly require TRS
monitoring for flares that become
affected facilities after June 24, 2008 to
ensure that the 500 lb/day SO2 trigger is
accurately measured. The owner or
operator of a modified flare must install
and operate the TRS monitoring
instrument no later than 1 year after the
flare becomes an affected facility. The
owner or operator of a newly
constructed or reconstructed flare must
install and operate the TRS monitoring
instrument no later than start-up of the
flare.
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35843
F. What are the modification and
reconstruction provisions?
Existing affected facilities that
commence modification or
reconstruction after May 14, 2007, are
subject to the final standards in 40 CFR
part 60, subpart Ja. A modification is
any physical or operational change to an
existing affected facility which results
in an increase in the emission rate to the
atmosphere of any pollutant to which a
standard applies (see 40 CFR 60.14).
Changes to an existing affected facility
that do not result in an increase in the
emission rate, as well as certain changes
that have been exempted under the
General Provisions (see 40 CFR
60.14(e)), are not considered
modifications.
The intermittent operation of a flare
makes it difficult to use the criteria of
40 CFR 60.14 to determine when a flare
is modified; therefore, we have specified
in the final rule the criteria that define
a modification to a flare. A flare is
considered to be modified if: (1) Any
piping from a refinery process unit or
fuel gas system is newly connected to
the flare or (2) the flare is physically
altered to increase flow capacity. See
section IV.I of this preamble for further
explanation on the change in affected
source from a fuel gas producing unit to
the flare.
Petroleum refinery process units are
subject to the final standards in 40 CFR
part 60, subpart Ja if they meet the
criteria under the reconstruction
provisions, regardless of changes in
emission rate. Reconstruction means the
replacement of components of an
existing facility such that (1) the fixed
capital cost of the new components
exceeds 50 percent of the fixed capital
cost that would be required to construct
a comparable entirely new facility; and
(2) it is technologically and
economically feasible to meet the
applicable standards (40 CFR 60.15).
IV. Summary of Significant Comments
and Responses
As previously noted, we received a
total of 46 comments during the public
comment periods associated with the
proposed rule and NODA. These
comments were received from
refineries, industry trade associations,
and consultants; State and local
environmental and public health
agencies; environmental groups; and
members of the public. In response to
these public comments, most of the cost
and emission reduction impact
estimates were recalculated, resulting in
several changes to the final amendments
and new standards. The major
comments and our responses are
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summarized in the following sections. A
summary of the remainder of the
comments received during the comment
period and responses thereto can be
found in the docket for the final
amendments and new standards (Docket
ID No. EPA–OAR–HQ–2007–0011). The
docket also contains further details on
all the analyses summarized in the
responses below.
In responding to the public
comments, we re-evaluated the costs
and cost-effectiveness of the control
options and re-evaluated our BDT
determinations. In our BDT
determinations, we took all relevant
factors into account consistent with
other Agency decisions. It is important
to note that, due to the different health
and welfare effects associated with
different pollutants, the acceptable costeffectiveness value of a control option is
pollutant dependent. These pollutantspecific factors were considered along
with other factors in our BDT
determinations.
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A. PM Limits for Fluid Catalytic
Cracking Units
Comment: Several commenters
opposed the proposed tightening of the
FCCU PM standards relative to subpart
J and the concurrent change in PM
monitoring methods. Some commenters
supported the co-proposal to keep the 1
lb/1,000 lb coke burn PM emission limit
based on Method 5B and/or 5F; other
commenters either did not oppose or
supported the 0.5 lb/1,000 lb coke burn
emission limit for new ‘‘grassroots’’
units, provided EPA demonstrates it is
cost-effective and that the limit is based
on EPA Method 5B or 5F (40 CFR part
60, Appendix A–3).
Commenters stated that EPA should
only impose the more stringent
emission limits on new construction
because it is much more difficult and
costly to meet the proposed emission
limits for modified or reconstructed
equipment. Commenters suggested that
if EPA does include more stringent
limits on modifications, it should
exclude certain actions (like projects
implemented to meet consent decree
requirements) from the definition of a
modification.
Several commenters suggested that
the costs in Table 11 of the proposal
preamble are significantly
underestimated. Commenters contended
that the single ‘‘model plant’’ approach
used in EPA’s cost analysis does not
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realistically consider important factors
such as the inherent sulfur content of
the feed, partial-burn versus full-burn
regeneration, FCCU/regenerator size,
and sources that are already wellcontrolled due to other regulations.
Commenters asserted that the purchased
equipment costs escalated from
estimates that are 20 to 30 years old are
underestimated. Several commenters
provided estimates of costs and
emission reductions for several actual
projects, which they stated indicate that
EPA’s costs are significantly
underestimated and that the proposed
standards are much less cost-effective
than presented by EPA.
A number of commenters asserted
that the PM standards should be based
on EPA Methods 5B or 5F (40 CFR part
60, Appendix A–3), and not on EPA
Method 5 of Appendix A–3 to part 60.
According to these commenters, the
achievability of the proposed 0.5 lb/
1,000 lb coke burn PM limit based on
EPA Method 5 is questionable because
there are inadequate data on FCCU
using EPA Method 5, and controlling
combined condensable and filterable
PM to the 0.5 lb/1,000 lb coke burn level
has not been demonstrated to be costeffective.
On the other hand, several
commenters stated that any PM limit
must include condensable and filterable
PM as condensable PM account for a
large portion of refinery PM emissions
and all condensable PM is PM that is
less than 2.5 micrometers in diameter
(PM2.5), which has more adverse health
impacts than larger particles; the
commenters therefore agreed with the
use of EPA Method 5 to determine
filterable PM and requested that EPA
consider Method 202 (40 CFR part 51,
Appendix M) for condensable PM.
Commenters also stated that the limits
for PM and SO2 in subpart Ja should
apply to all new, reconstructed, and
modified FCCU. One commenter
recommended that a total PM limit
(filterable and condensable) be set at 1
lb/1,000 coke burn; another stated that
the total PM limit, including both
filterable and condensable PM, should
be 0.5 lb/1,000 lb coke burn, and EPA
has not demonstrated that current BDT
cannot achieve this limit. Finally, one
commenter suggested that EPA should
evaluate the cost of removing each
pollutant (PM and SO2) separately.
Response: In response to these
comments, we have revised our analysis
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to consider each unique existing FCCU
in the United States. By doing so, we
fully account for plant size, partial-burn
versus full-burn regeneration, existing
control configuration, and specific
consent decree requirements. (Details on
the specific revisions to the analysis can
be found in the docket.) With a revised
analysis, we were able to more directly
assess the impacts of process
modifications or reconstruction of
existing equipment. We also assessed
the effects of PM and SO2 standards
separately in this analysis.
In our revised analysis, we considered
three options for PM: (1) Maintain the
existing subpart J standard of 1.0 lb/
1,000 lb of coke burn-off (filterable PM
as measured by Method 5B or 5F); (2)
0.5 lb/1,000 lb of coke burn-off
(filterable PM as measured by Method
5B or 5F of Appendix A–3 to part 60);
and (3) 0.5 lb/1,000 lb of coke burn-off
(filterable PM as measured by Method 5
of Appendix A–3 to part 60). Similar to
the analysis for the proposed standards,
costs and emission reductions for each
option were estimated as the increment
between complying with subpart J and
subpart Ja. We note that none of the
available data suggest that a 0.5 lb/1,000
lb coke burn emission limit that
includes both filterable and condensable
PM as measured using EPA Method 202
is achievable in practice for the full
range of facilities using BDT controls, so
we disagree with the comments
suggesting this level is appropriate to
consider as an option for a total PM
limit in this rulemaking.
Option 1 includes the same emissions
and requirements for PM as the current
40 CFR part 60, subpart J, so it will
achieve no additional emissions
reductions. The PM limit in Option 2 is
the same numerical limit that was
proposed in subpart Ja, but the PM
emissions are determined using
Methods 5B and 5F (40 CFR part 60,
Appendix A–3). These test methods are
commonly used for PM tests of FCCU
and are the methods that were used to
generate a majority of the test data we
reviewed. Option 3 is a limit of 0.5 lb/
1,000 lb coke burn using Method 5 and
is the performance level that was
proposed for subpart Ja. The impacts of
these three options for new FCCU are
presented in Table 2 to this preamble;
the impacts for modified and
reconstructed FCCU are presented in
Table 3 to this preamble.
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TABLE 2.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR PM LIMITS CONSIDERED FOR NEW FLUID CATALYTIC
CRACKING UNITS SUBJECT TO 40 CFR PART 60, SUBPART JAa
Capital cost
($1,000)
Option
2 ...........................................................................................
3 ...........................................................................................
a PM
Total annual
cost
($1,000/yr)
3,600
7,100
Emission
reduction
(tons PM/yr)
1,100
1,700
240
300
Cost effectiveness ($/ton)
Overall
Incremental
5,600
6,700
5,600
11,000
cost-effectiveness calculated for PM-fine; 83.3 percent of the PM is PM-fine.
TABLE 3.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR PM LIMITS CONSIDERED FOR RECONSTRUCTED AND
MODIFIED FLUID CATALYTIC CRACKING UNITS SUBJECT TO 40 CFR PART 60, SUBPART JAa
Capital cost
($1,000)
Option
2 ...........................................................................................
3 ...........................................................................................
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a PM
Total annual
cost
($1,000/yr)
75,000
100,000
Emission
reduction
(tons PM/yr)
12,000
15,000
690
810
Cost effectiveness ($/ton)
Overall
Incremental
21,000
23,000
21,000
37,000
cost-effectiveness calculated for PM-fine; 83.3 percent of the PM is PM-fine.
The available data and impacts for the
options considered suggest that BDT for
new FCCU is different than BDT for
modified and reconstructed FCCU. For
new FCCU, the costs for Option 2 are
reasonable compared to the emission
reduction achieved. The incremental
cost between Option 2 and Option 3 of
$11,000 per ton PM-fine would
generally be considered reasonable, but
there are uncertainties in the
achievability of Option 3. The estimated
PM emission reduction achieved by
Option 3 compared to Option 2 equals
the amount of sulfates and other
condensable PM between 250 °F and
320 °F that would be measured by
Method 5 but not Method 5B or 5F (40
CFR part 60, Appendix A–3).
Additionally, available test data indicate
that electrostatic precipitators (ESP) and
wet scrubbers can reduce total filterable
PM to 0.5 lb/1,000 lb of coke burn or
less, as measured by Method 5equivalent test methods. Although there
were few test data points using Method
5-equivalent test methods, we
concluded at proposal that both
electrostatic precipitators and wet
scrubbers can achieve this level of PM
emissions. However, the data
supporting Option 3 are not extensive,
and it is unclear at this time whether a
limit of 0.5 kg/Mg of coke burn as
measured by Method 5 (40 CFR part 60,
Appendix A–3) could be met by all
configurations of FCCU. In addition,
while the Agency supports reducing
condensable PM emissions, the amount
of condensable PM captured by Method
5 is small relative to methods that
specifically target condensable PM, such
as Method 202 (40 CFR part 51,
Appendix M). We prefer to develop a
single performance standard that
considers all condensable PM rather
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than implementing phased standards
targeting different fractions of
condensable PM. Such an approach
would be costly and inefficient.
Therefore, we conclude that Option 2,
control of PM emissions (as measured
by Methods 5B and 5F of Appendix A–
3 to part 60) to 0.5 lb/1,000 lb of coke
burn or less, is BDT for newly
constructed FCCU. This option achieves
PM emission reductions of 240 tons per
year (tons/yr) from a baseline of 910
tons/yr at a cost of $5,600 per ton of PM.
For modified and reconstructed
FCCU, Option 1 is the baseline level of
control established by the existing
requirements of subpart J. It will achieve
no additional cost or emission
reduction. The overall costs and the
incremental costs for Options 2 and 3
are reasonable compared to the PM
emission reduction; however, as with
new FCCU, the performance of Option
3 has not been demonstrated, so it is
rejected. Most of the existing FCCU that
could become subject to subpart Ja
through modification or reconstruction
are either already subject to subpart J or
are covered by the consent decrees. The
consent decrees are generally based on
the existing subpart J. Industry has
made significant investments in
complying with these subpart J
requirements which may be abandoned
if they become subject to subpart Ja. In
addition, the additional costs could
create a disincentive to modernize
FCCU to make them more energy
efficient or to produce more refined
products. For these reasons, we reject
Option 2 for modified or reconstructed
FCCU and conclude that control of PM
emissions (as measured by Methods 5B
and 5F of Appendix A–3 to part 60) is
1.0 lb/1,000 lb of coke burn or less is
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BDT for reconstructed and modified
FCCU.
B. SO2 Limits for Fluid Catalytic
Cracking Units
Comment: Several commenters
supported the co-proposal for modified
and reconstructed FCCU to meet subpart
J and not the 25 ppmv 365-day rolling
average limit for SO2. Commenters
provided data to suggest that the
retrofits of existing sources are not cost
effective, particularly if catalyst
additives cannot be used. The current
subpart J includes three compliance
options: (1) If using an add-on control
device, reduce SO2 emissions by at least
90 percent or to less than 50 ppmv; (2)
if not using an add-on control device,
limit sulfur oxides emissions (calculated
as SO2) to no more than 9.8 kg/Mg of
coke burn-off; or (3) process in the fluid
catalytic cracking unit fresh feed that
has a total sulfur content no greater than
0.30 percent by weight. Several
commenters objected to the elimination
of the additional compliance options in
the existing subpart J for subpart Ja
because: (1) There are no data to show
that the SO2 limits proposed in subpart
Ja are BDT for all FCCU regenerator
configurations; (2) the three options are
already established as BDT and,
therefore, the CAA requires that EPA
make them available; and (3) the
substantial cost and other burdens for a
reconstructed or modified FCCU already
complying with one of the alternative
options in subpart J to change to daily
monitoring by Method 8 (40 CFR part
60, Appendix A–4) or to install CEMS
were not addressed in the proposal.
One commenter supported the
proposed SO2 limit under Ja for new
‘‘grassroots’’ FCCU if the standard is
demonstrated to be cost-effective.
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Response: As acknowledged in the
previous response on PM standards for
FCCU, we completely revised our
impacts analysis to evaluate SO2
standards for every existing FCCU that
may become subject to subpart Ja
through modification or reconstruction.
We did not have access to the inherent
sulfur content of the feed for each FCCU
so SO2 emissions are still estimated
using average emission factors relevant
to the type of control device used for
FCCU not subject to consent decree
requirements. Nonetheless, we
significantly revised the impact analysis
to fully account for FCCU-specific
throughput, existing controls, and
consent decree requirements. (Details on
the specific revisions to the analysis can
be found in Docket ID No. EPA–HQ–
OAR–2007–0011.) We evaluated two
options: (1) Current subpart J, including
all three compliance options; and (2) 50
ppmv SO2 on a 7-day average and 25
ppmv on a 365-day average. Data are not
available on which to base a more
stringent control level.
Option 1 includes the same emissions
and requirements as the current 40 CFR
part 60, subpart J, so it will achieve no
additional emissions reductions. Based
on information provided by vendors and
data submitted by petroleum refiners,
Option 2 can be met with catalyst
additives or a wet scrubber. Of 38 FCCU
currently subject to a 50/25 ppmv SO2
limit through consent decrees, 26 used
wet scrubbers and 12 used catalyst
additives or other (unspecified)
techniques. Given the number of FCCU
currently meeting the 50/25 ppmv SO2
emission limit, we conclude that this
limit is technically feasible.
The data in the record suggest that all
systems with wet scrubbers can meet
the 50/25 ppmv SO2 emission limit with
no additional cost. Further, based on
information from the consent decrees,
we believe that the owner or operator of
an existing FCCU that does not already
have a wet scrubber and is modified or
reconstructed such that it becomes
subject to subpart Ja can use catalyst
additives to meet the 50/25 ppmv SO2
emission limit. Therefore, the cost of
Option 2 is calculated using catalyst
additives as the method facilities choose
for meeting the standard. We reject the
idea that the 90 percent control
efficiency, the 9.8 kg/Mg coke burn-off
limit, or the 0.3 weight percent sulfur
content alternatives are equivalent to
the 50/25 ppmv SO2 emission limit.
Based on the original background
document for the subpart J standards,
these alternatives are expected to have
outlet SO2 concentrations of 200 to 400
ppmv. In reality the currently used wet
scrubbers and catalyst additives achieve
much higher SO2 removal efficiencies
and much lower outlet SO2
concentrations. The impacts of these
options are presented in Table 4 of this
preamble.
TABLE 4.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR SO2 LIMITS CONSIDERED FOR NEW, RECONSTRUCTED, AND
MODIFIED FLUID CATALYTIC CRACKING UNITS SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
2 ...........................................................................................
Based on the data we reviewed to
select the options and the estimated
impacts of those options, we conclude
that Option 2, control of SO2 emissions
to 25 ppmv or less averaged over 365
days and 50 ppmv or less averaged over
7 days, is technically feasible and costeffective for new, reconstructed, and
modified fluid catalytic cracking units.
This option has no capital cost and
achieves SO2 emission reductions of
4,400 tons/yr from a baseline of 5,900
tons/yr at a cost of $700 per ton of SO2.
Therefore, we conclude that control of
SO2 emissions to 25 ppmv or less
averaged over 365 days and 50 ppmv or
less averaged over 7 days is BDT for
new, reconstructed, or modified fluid
catalytic cracking units.
ebenthall on PRODPC60 with RULES4
C. NOX Limit for Fluid Catalytic
Cracking Units
Comment: Several commenters stated
that they would support a NOX limit of
80 ppmv for new sources only, provided
a corrected impact analysis considers
the different characteristics of FCCU
and demonstrates that the NOX limit for
new sources is truly cost-effective.
Commenters supported the co-proposal
for modified and reconstructed FCCU to
meet subpart J and not be subject to a
NOX emission limit. A few commenters
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Total annual
cost
($1,000/yr)
Emission
reduction
(tons SO2/yr)
0
3,000
4,400
provided cost data showing the cost of
NOX controls is high for modified and
reconstructed units due to the high cost
and space needed for add-on controls.
The commenters also stated that a large
number of existing FCCU in the U.S. are
covered by consent decrees, so
significant NOX reductions have already
been (or will soon be) achieved, and an
additional incremental reduction to 20
or 40 ppmv over a 365-day average are
not widely demonstrated and would not
be cost-effective.
One commenter stated that selective
noncatalytic reduction (SNCR), selective
catalytic reduction (SCR), and catalyst
additives have not been demonstrated
over significant periods of operational
life. Commenters also cited
environmental side-effects, such as the
generation of ammonia compounds that
contribute to condensable PM
emissions, as a reason not to require
these types of controls. Commenters
also asserted that technologies like flue
gas recirculation or advanced burner
design are typically only cost-effective
for new units and may be technically
infeasible for existing FCCU.
One commenter suggested that if a
limit is necessary for modified or
reconstructed FCCU, recent catalyst
additive trials support an emission limit
PO 00000
Frm 00010
Fmt 4701
Sfmt 4700
Cost effectiveness ($/ton)
Overall
Incremental
700
700
of approximately 150 ppmv on a 7-day
rolling average; this limit would only be
achievable if a 24-hour CO averaging
time was provided since lowering NOX
tends to increase CO emissions in
FCCU. The commenter noted that this
limit is equivalent to the 0.15 pounds
per million British thermal units (lb/
MMBtu) standard for reconstructed and
modified heaters and boilers in NSPS
subpart Db.
Other commenters supported the
inclusion of a NOX limit for FCCU and
opposed the co-proposal of no NOX
standard for modified and reconstructed
FCCU. These commenters also
recommended more stringent NOX
limits for FCCU and stated that 80 ppmv
does not represent an adequate level of
control given the evolution of emerging
technologies. In addition, a BDT of 80
ppmv on 7-day rolling average does not
look ‘‘toward what may be fairly
projected for the regulated future’’ as
required by Portland Cement I (486 F.
2d 375 at 384 (D.C. Cir. 1973)) and other
court decisions. The commenters
disagreed with the feasibility and cost
analyses for modified and reconstructed
FCCU and stated that FCCU under a
consent decree are achieving lower
levels than the 80 ppmv proposed by
EPA. Given the significant hazards to
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human health and the environment
posed by NOX emissions, the
commenters recommended limits of 20
ppmv over a 365-day rolling average
and 40 ppmv over a 7-day rolling
average for all FCCU. The commenters
noted that these limits have been
successfully achieved under consent
decrees and they are technically feasible
on new units at reasonable costs
without additional controls.
Response: As shown by the disparate
comments received, many commenters
suggest lower NOX emission limits are
achievable, while other commenters do
not believe the proposed NOX emission
limits are cost-effective. While we do
acknowledge that lower NOX emission
limits are technically achievable, the
incremental cost of achieving these
lower limits was high when we
evaluated options for the proposed
standards. Therefore, we concluded at
proposal that 20 or 40 ppmv NOX limits
were not BDT. In our BDT assessment,
we evaluated the various methods to
meet alternative NOX limits as BDT
rather than identifying one technology.
One of the reasons for this is that each
technology has its own advantages and
limitations. While non-platinum
oxidation promoters and advanced
oxidation controls do not achieve the
same reduction in NOX emissions as
add-on control devices such as SCR,
they do so without any significant
secondary impacts. The added NOX
reduction of SCR and SNCR must be
balanced with these secondary impacts.
Part of the basis for selecting control
methods to achieve an 80 ppmv NOX
emission limit as BDT included both
cost and secondary impacts. This
approach is necessary when conducting
our BDT analysis, thus ensuring the best
overall environmental benefit from the
subpart Ja standards.
To ensure that we addressed the
commenters’ concerns, we re-evaluated
the impacts for FCCU NOX controls. We
also collected additional data from
continuous NOX monitoring systems for
a variety of FCCU NOX control systems.
These data suggest that as refiners gain
more experience with the NOX control
systems (including catalyst additive
improvements), NOX control
performance has improved over the past
year or two. These data suggest that the
achievable level for combustion controls
and catalyst additives is 80 ppmv and
the achievable level for add-on control
systems is 20 ppmv. Therefore, we
evaluated three outlet NOX emission
level options as part of the BDT
determination: (1) 150 ppmv; (2) 80
ppmv; and (3) 20 ppmv. Each NOX
concentration is averaged over 7 days.
To estimate impacts for Option 1, we
estimated that some units have current
NOX emissions below 150 ppmv, and all
other units can meet this level with
combustion controls such as limiting
excess O2 or using non-platinum
catalyst combustion promoters and
other NOX-reducing catalyst additives in
a complete combustion catalyst
regenerator or a combination of NOXreducing combustion promoters and
catalyst additives with low-NOX burners
(LNB) in a CO boiler after a partial
combustion catalyst regenerator. Data
collected from FCCU complying with
consent decrees show that Option 2 can
also be met using combustion controls;
therefore, we estimated impacts for
Option 2 using a similar method as
Option 1. The main difference is that a
larger number of FCCU must use
combustion controls to meet the
emission limit (i.e., the FCCU with
current NOX emissions between 150 and
80 ppmv would not need controls under
Option 1 but would need controls under
Option 2). Option 3 is the level at which
we expect all units to install more costly
control technology such as LoTOxTM or
SCR. The estimated fifth-year emission
reductions and costs for each option for
new FCCU are summarized in Table 5
to this preamble; the impacts for
modified and reconstructed FCCU are
summarized in Table 6 to this preamble.
TABLE 5.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR NOX LIMITS CONSIDERED FOR NEW FLUID CATALYTIC
CRACKING UNITS SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
1 ...........................................................................................
2 ...........................................................................................
3 ...........................................................................................
Total annual
cost
($1,000/yr)
860
1,200
12,000
Emission
reduction
(tons NOX/yr)
320
640
3,600
370
860
1,400
Cost effectiveness ($/ton)
Overall
Incremental
880
750
2,600
880
650
5,800
TABLE 6.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR NOX LIMITS CONSIDERED FOR MODIFIED AND
RECONSTRUCTED FLUID CATALYTIC CRACKING UNITS SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
ebenthall on PRODPC60 with RULES4
1 ...........................................................................................
2 ...........................................................................................
3 ...........................................................................................
Options 1 and 2 provide cost-effective
NOX control with limited or no
secondary impacts. The costs of Option
1 and Option 2 are commensurate with
the emission reductions for new FCCU
as well as modified and reconstructed
FCCU. Option 3 would impose
compliance costs that are not warranted
for the emissions reductions that would
be achieved, as shown by the
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14:47 Jun 23, 2008
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Total annual
cost
($1,000/yr)
2,800
3,700
45,000
1,000
1,600
11,000
incremental cost-effectiveness values of
about $6,000 per ton of NOX emission
reduction between Option 2 and Option
3.
In evaluating these options, we also
considered the secondary impacts. In
addition to the direct PM impacts of
SNCR and SCR, SCR and LoTOxTM
units require additional electrical
consumption. The increased energy
PO 00000
Frm 00011
Fmt 4701
Sfmt 4700
Emission
reduction
(tons NOX/yr)
860
1,800
3,200
Cost-effectiveness ($/ton)
Overall
1,200
920
3,600
Incremental
1,200
660
6,800
consumption for Option 3 is 40,000
MW-hr/yr for new, modified, and
reconstructed units. We also evaluated
the secondary PM, SO2, and NOX
emission impacts of the additional
electrical consumption for Option 3.
Based on the energy impacts, Option 3
will generate secondary emissions of
PM, SO2, and NOX of 6, 150, and 57
tons/yr, respectively.
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Federal Register / Vol. 73, No. 122 / Tuesday, June 24, 2008 / Rules and Regulations
Based on the impacts shown in Table
5 and Table 6, and taking secondary
impacts into account, we conclude that
BDT is Option 2, a NOX emission limit
of 80 ppmv, for all affected FCCU. For
new FCCU, this option achieves NOX
emission reductions of 860 tons/yr from
a baseline of 1,500 tons/yr at a cost of
$750 per ton of NOX. For modified and
reconstructed FCCU, this option
achieves NOX emission reductions of
1,800 tons/yr from a baseline of 3,600
tons/yr at a cost of $920 per ton of NOX.
D. PM and SO2 Limits for Fluid Coking
Units
Comment: Several commenters stated
that EPA’s proposed standards for FCU
under subpart Ja are inappropriate and
not cost-effective. Commenters asserted
that based on the significant differences
between FCU and FCCU operations, a
separate BDT determination is needed
for FCCU and FCU. Commenters stated
that an FCU has higher particulate
loading; a heavier feedstock that
typically contains a higher
concentration of sulfur, increasing the
SO2 and sulfur trioxide (SO3) emissions;
and a wider range of feedstocks with
considerable variability in the nitrogen
content.
The commenters noted that the
impacts analysis performed for the FCU
has shortcomings similar to those in the
impacts analysis for FCCU (e.g., the
analysis did not properly consider the
additional costs and technical
difficulties of meeting the proposed
emission limits for modified or
reconstructed sources, existing units are
already controlled and thus the
emission reductions have already been
achieved). One commenter provided
site-specific engineering cost estimates
to indicate that the PM controls are
much less cost-effective than EPA
estimates. The commenter requested
that EPA consider instances when
wastewater limitations require
regenerative wet scrubbers and amend
the impact estimates accordingly. One
commenter stated that a newly installed
regenerative wet scrubber system on an
existing FCU could not meet the
proposed Ja PM standards.
Response: As described in the
preamble to the proposed standards, the
original analysis assumed that one of
the larger existing FCU will become a
modified or reconstructed source in the
next 5 years. However, the two larger
FCU in the U.S. are both subject to
consent decrees: one has installed
controls and the other is in the process
of installing controls. The remaining
two FCU are significantly smaller than
the original model FCU; therefore, a
new analysis was conducted using a
smaller model FCU indicative of the
size of the two remaining FCU that are
not subject to consent decree
requirements. In our new analysis, this
FCU has approximately one-half the
sulfur content as the larger FCU for
which we have data, based on
information received regarding the
variability in sulfur content across
different FCU in the public comments.
In addition to revising our impact
analysis, we also collected additional
source test data from the one FCU
operating a newly installed wet scrubber
system to better characterize the control
system’s performance. At proposal, we
had one FCU source test from this
source, which suggested that the FCU
wet scrubber could meet a PM limit of
0.5 lb/1,000 coke burn. However,
following proposal, we received an
additional performance test for this
same FCU wet scrubber with an
emission rate between 0.5 and 1.0 lb/
1,000 lb coke burn. There was no
indication of unusual performance
during either of these two tests, so we
conclude that these tests demonstrate
the variability of the emission source
and control system. Based on the
available data, therefore, we conclude
that an appropriate PM performance
level to consider for a BDT analysis is
1.0 lb/1,000 lb coke burn using EPA
Method 5B (40 CFR part 60, Appendix
A–3) for a FCU with a wet scrubber. We
also conclude that the PM emission
limit initially proposed for FCU had not
been adequately demonstrated as an
emission limit with which one must
comply at all times.
Using our revised model FCU and
based on the additional source test data,
we re-evaluated BDT for PM and SO2
emissions from FCU based on two
options: (1) No new standards, or
current subpart J; and (2) a PM limit of
1.0 lb/1,000 lb coke burn (as measured
using Methods 5B and 5F of 40 CFR part
60, Appendix A–3), a short-term SO2
limit of 50 ppmv averaged over 7 days,
and a long-term SO2 limit of 25 ppmv
averaged over 365 days. Unlike the
FCCU, catalyst additives cannot be used
in a FCU to reduce SO2, so a wet
scrubber is the most likely technology
(and the one demonstrated technology)
that would be used to meet the PM and
SO2 limits of Option 2. Therefore, we
estimated costs for an enhanced wet
scrubber to meet both the PM and SO2
limits. The resulting emission
reductions and costs for both of the
options are shown in Table 7 of this
preamble.
TABLE 7.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR PM AND SO2 LIMITS CONSIDERED FOR FLUID COKING UNITS
SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
ebenthall on PRODPC60 with RULES4
2 ...........................................................................................
2a .........................................................................................
One commenter indicated that we
should consider the costs of a
regenerative wet scrubber. This type of
system is not needed in most
applications; however, in the event such
a system were needed, we estimated the
cost of a regenerative wet scrubber to
meet Option 2. The results of this
analysis are also provided in Table 7 as
Option 2a. As presented in Table 7,
even under the most conservative
assumptions the costs associated with
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Total annual
cost
($1,000/yr)
10,000
100,000
3,200
18,600
the PM and SO2 emission reductions are
reasonable.
Based on the available technology and
the costs presented in Table 7 to this
preamble, we conclude that BDT is
Option 2, which requires technology
that reduces PM emissions to 1.0 lb/
1,000 of coke burn and reduces SO2
emissions to 50 ppmv averaged over 7
days and 25 ppmv averaged over 365
days. This option achieves PM emission
reductions of 1,000 tons/yr from a
PO 00000
Frm 00012
Fmt 4701
Sfmt 4700
Emission
reduction
(tons PM/yr)
1,000
1,000
Emission
reduction
(tons SO2/yr)
Cost effectiveness ($/ton
PM and SO2)
5,900
5,900
460
2,700
baseline of 1,100 tons/yr and SO2
emission reductions of 5,900 tons/yr
from a baseline of 6,100 tons/yr at a cost
of $460 per ton of PM and SO2
combined.
E. NOX Limit for Fluid Coking Units
Comment: A number of commenters
opposed the co-proposal of no NOX
standard for FCU, and some disagreed
with EPA’s 80 ppmv NOX limit for FCU.
These commenters recommended limits
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of 20 ppmv as a 365-day rolling average
and 40 ppmv as a 7-day rolling average
for FCU, as has been successfully
achieved under consent decrees. The
commenters noted that these limits are
achievable on new units without
additional controls.
One commenter supported the coproposal that no new NOX standard be
established for FCU.
Response: Similar to the revised
analysis for PM and SO2 impacts, we reevaluated BDT for the FCU NOX
controls for a smaller modified or
reconstructed FCU. We evaluated three
options: (1) No new standards, which is
the current subpart J; (2) outlet NOX
concentration of 80 ppmv; and (3) outlet
NOX concentration of 20 ppmv. Similar
to the analysis for FCCU NOX and
depending on the baseline emissions for
the FCU, we anticipate that Option 2
can be met using combustion controls
and Option 3 will require add-on
control technology. The results of this
analysis are shown in Table 8 to this
preamble.
TABLE 8.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR NOX LIMITS CONSIDERED FOR FLUID COKING UNITS
SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
2 ...........................................................................................
3 ...........................................................................................
The costs for Option 1 and Option 2
are commensurate with the emission
reductions, but the incremental impacts
for Option 3 are not reasonable, as
shown in Table 8. Option 3 achieves an
additional 90 tons per year NOX
reduction, but the incremental costs
between options 2 and 3 of achieving
this reduction is $5,000 per ton of NOX
removed. The cost of achieving this 12
percent additional emission reduction
nearly triples the total annualized cost
of operating the controls. As with FCCU,
the add-on NOX controls for FCU have
increased energy requirements and
secondary air pollution impacts. Based
on these projected impacts, we support
our original determination that BDT is
Option 2, or technology needed to meet
an outlet NOX concentration of 80 ppmv
or less. This option achieves NOX
emission reductions of 660 tons/yr from
a baseline of 800 tons/yr at a cost of
$1,300 per ton of NOX.
Total annual
cost
($1,000/yr)
3,700
6,000
Emission/
reduction
(tons NOX /yr)
850
1,300
F. SO2 Limit for Small Sulfur Recovery
Plants
Comment: One commenter stated that
no new requirements should be added
for SRP less than 20 LTD (small SRP)
because the controls are not costeffective. The commenter provided data
on tail gas treatment projects but noted
that these costs are for large SRP, and
controls for small SRP will be less costeffective. Several commenters noted that
if EPA does establish standards for
small SRP, the monitoring and
compliance evaluation methods for the
99 percent control standard are not
clearly specified in the rule and could
create difficulties in documenting
compliance for small Claus plants.
Therefore, the small SRP should be
allowed to comply with the 250 ppmv
SO2 emission limit provided to large
SRP. One commenter suggested that
non-Claus units should be subject to a
95 percent recovery efficiency standard.
Response: To ensure that we
addressed the commenters’ concerns
regarding cost-effectiveness, we re-
660
750
Cost-effectiveness ($/ton)
Overall
Incremental
1,300
1,700
1,300
5,000
evaluated the impacts for small SRP. We
adjusted our cost estimates upward
based on capital costs provided by
industry representatives. We evaluated
three SO2 control options as part of the
BDT determination for small SRP: (1)
No new standards, or current subpart J;
(2) 99 percent sulfur recovery; and (3)
99.9 percent sulfur recovery. As noted
in the preamble to the proposed
standards (section V.D), the 99 percent
and 99.9 percent recovery levels are
achievable for SRP of all sizes by
various types of SRP or tail gas
treatments.
The estimated fifth-year emission
reductions and costs for new SRP are
summarized in Table 9 to this preamble;
the impacts for modified and
reconstructed SRP are summarized in
Table 10 to this preamble. These values
reflect the impacts only for small SRP;
there are no additional cost impacts for
large Claus units because they would
already have to comply with the
existing standards in subpart J.
TABLE 9.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR SO2 LIMITS CONSIDERED FOR NEW SMALL SULFUR
RECOVERY PLANTS SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
2 ...........................................................................................
3 ...........................................................................................
Total annual
cost
($1,000/yr)
130
590
Emission
reduction
(tons SO2/yr)
63
230
42
52
Cost-effectiveness
($/ton)
Overall
Incremental
1,500
4,500
1,500
18,000
ebenthall on PRODPC60 with RULES4
TABLE 10.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR SO2 LIMITS CONSIDERED FOR MODIFIED AND
RECONSTRUCTED SMALL SULFUR RECOVERY PLANTS SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
2 ...........................................................................................
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PO 00000
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Total annual
cost
($1,000/yr)
1,600
Fmt 4701
Sfmt 4700
Emission
reduction
(tons SO2/yr)
670
E:\FR\FM\24JNR4.SGM
380
24JNR4
Cost-effectiveness
($/ton)
Overall
1,800
Incremental
1,800
35850
Federal Register / Vol. 73, No. 122 / Tuesday, June 24, 2008 / Rules and Regulations
TABLE 10.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR SO2 LIMITS CONSIDERED FOR MODIFIED AND
RECONSTRUCTED SMALL SULFUR RECOVERY PLANTS SUBJECT TO 40 CFR PART 60, SUBPART JA—Continued
Capital cost
($1,000)
Option
3 ...........................................................................................
ebenthall on PRODPC60 with RULES4
The costs for Option 2 are reasonable
considering the emission reductions
achieved, but the incremental impacts
shown in Table 9 and Table 10 for
Option 3 are beyond the costs that the
Agency believes are reasonable for these
small units to achieve an additional 100
tons per year of SO2 emission
reductions. The additional equipment
needed to achieve these reductions
quadruples the capital costs. These
smaller units would also generally be
found at small refineries. Based on these
projected impacts and available
performance data, we support our
original determination that BDT is
Option 2, or 99 percent sulfur recovery.
For new SRP, this option achieves SO2
emission reductions of 42 tons/yr from
a baseline of 150 tons/yr at a cost of
$1,500 per ton of SO2. For modified and
reconstructed SRP, this option achieves
SO2 emission reductions of 380 tons/yr
from a baseline of 1,400 tons/yr at a cost
of $1,800 per ton of SO2.
We note that we are also revising the
format of the standard in response to
public comments in terms of sulfur
outlet concentrations. Based on the
Option 2 BDT selection of a recovery
efficiency of 99 percent, the emission
limit for small SRP is either 2,500 ppmv
SO2 or 3,000 ppmv reduced sulfur
compounds and 100 ppmv of H2S, both
of which are determined on a dry basis,
corrected to 0 percent O2.
G. NOX Limit for Process Heaters
Comment: Several commenters stated
that the 80 ppmv NOX limit for process
heaters is not stringent enough.
Commenters stated that considering
recent settlement negotiations and
regulation development, NOX emissions
reductions well below 80 ppmv can be
achieved cost effectively. The
commenters stated that NOX emissions
of less than 40 ppmv at 0 percent O2 are
achievable with combustion
modifications such as LNB, ultra low—
NOX burners (ULNB), and flue gas
recirculation technologies; postcombustion controls such as SCR,
SNCR, and LoTOxTM achieve NOX
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Total annual
cost
($1,000/yr)
7,800
2,600
reductions an order of magnitude below
those from combustion modifications.
The commenters noted that Bay Area
Air Quality Management District
(BAAQMD) Regulation 9, Rule 10,
requires process heaters to meet a 0.033
lb/MMBtu NOX limit (roughly 32 ppmv
NOX at 0 percent oxygen). One
commenter stated that 30 ppmv has
been demonstrated under consent
decrees to be an achievable level and
ample technology exists. The
commenters also noted that 7 to 10
ppmv NOX limits (at 3 percent oxygen)
have been achieved in practice. One
commenter stated that NSPS subparts J
and Ja should impose NOX emission
limits on all fuel gas combustion
devices that are at least as stringent as
the most stringent consent decree. Some
consent decrees require next generation
ULNB designed to achieve NOX
emissions rates of 0.012 to 0.020 lb/
MMBtu (12 to 20 ppmv NOX at 0
percent oxygen). Commenters
recommending more stringent
requirements suggested limits ranging
from 7 ppmv NOX (at 3 percent oxygen)
to 30 ppmv for new process heaters
fueled by refinery fuel gas.
Other commenters stated that
alternative monitoring options should
be provided to small fuel gas
combustion devices due to the high
costs of CEMS relative to the emissions
from the small devices. One commenter
suggested an exemption from the fuel
gas monitoring requirements for process
heaters less than 50 MMBtu/hr. Another
commenter recommended an exemption
from the fuel gas monitoring
requirements for process heaters less
than 40 MMBtu/hr as used by South
Coast Air Quality Management District
(SCAQMD).
Response: We revisited the BDT
determination based on the public
comments and revised the methodology
used to calculate the cost and emission
reduction impacts for the proposed
standards. We evaluated three options
as part of the BDT determination. Each
option consists of a potential NOX
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Sfmt 4700
Emission
reduction
(tons SO2/yr)
470
Cost-effectiveness
($/ton)
Overall
5,700
Incremental
23,000
emission limit and applicability based
on process heater size. These differ
slightly from the proposal options based
o n commenter suggestions. Option 1
would limit NOX emissions to 80 ppmv
or less for all process heaters with a
capacity greater than 20 MMBtu/hr (the
proposed standards). Option 2 would
limit NOX emissions to 40 ppmv or less
for all process heaters with a capacity
greater than 40 MMBtu/hr. This option
is similar to many consent decrees that
set an emission limit of 0.040 lb/MMBtu
(roughly 40 ppmv NOX at 0 percent
oxygen) for process heaters greater than
40 MMBtu/hr. Option 3 would limit
NOX emissions to 20 ppmv or less for
all process heaters with a capacity
greater than 40 MMBtu/hr. In each
option, the NOX concentration is based
on a 24-hour rolling average.
The estimated fifth-year emission
reductions and costs for each option for
new process heaters are summarized in
Table 11 of this preamble; impacts for
modified and reconstructed process
heaters are summarized in Table 12 of
this preamble. Similar to the proposal
analysis, we considered LNB, ULNB,
flue gas recirculation, SCR, SNCR, and
LoTOxTM as feasible technologies. We
believe that nearly all process heaters at
refineries that will become subject to
subpart Ja can meet Option 1 or Option
2 using combustion controls (LNB or
ULNB). Most process heaters would
need to use more efficient control
technologies, such as LoTOxTM or SCR,
to meet the NOX concentration limit in
Option 3. Per commenters’ request to
focus on the larger units, Options 2 and
3 do not include process heaters
between 20 MMBtu/hr and 40 MMBtu/
hr. We evaluated the cost-effectiveness
of NOX control options for these units
to achieve the proposed standard of 80
ppmv. For these process heaters with
smaller capacities we found the costeffectiveness ranged from $3,500/ton to
$4,200/ton of NOX reduced, which was
determined not to be reasonable for
these small heaters, which would
primarily be located at small refineries.
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Federal Register / Vol. 73, No. 122 / Tuesday, June 24, 2008 / Rules and Regulations
TABLE 11.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR NOX LIMITS CONSIDERED FOR NEW PROCESS HEATERS
SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
1 ...........................................................................................
2 ...........................................................................................
3 ...........................................................................................
Total annual
cost
($1,000/yr)
9,000
9,000
110,000
Emission
reduction
(tons NOX/yr)
7,300
7,500
30,000
4,800
5,200
5,900
Cost-effectiveness
($/ton)
Overall
Incremental
1,500
1,400
5,100
1,500
500
37,000
TABLE 12.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR NOX LIMITS CONSIDERED FOR MODIFIED AND
RECONSTRUCTED PROCESS HEATERS SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
1 ...........................................................................................
2 ...........................................................................................
3 ...........................................................................................
Based on the impacts in Table 11 and
Table 12, the costs of Options 1 and 2
are reasonable compared to the emission
reductions. The incremental cost
between Options 2 and 3 of almost
$40,000/ton of NOX is not
commensurate with the additional 1,000
tons of emission reduction achieved for
new and modified or reconstructed
process heaters. Moreover, the capital
costs of Option 3 are about $150 million
greater than the capital costs for Option
2, which are only $23 million.
Therefore, we conclude that BDT for
process heaters greater than 40 MMBtu/
hr is technology that achieves an outlet
NOX concentration of 40 ppmv or less,
or Option 2. For new process heaters,
this option achieves NOX emission
reductions of 5,200 tons/yr from a
baseline of 7,500 tons/yr at a cost of
$1,400 per ton of NOX. For modified
and reconstructed process heaters, this
option achieves NOX emission
reductions of 2,200 tons/yr from a
baseline of 3,200 tons/yr at a cost of
$1,900 per ton of NOX. Although we
agree that lower NOX concentrations are
achievable, we determined that the
incremental cost to achieve these lower
NOX concentrations was not reasonable.
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H. Fuel Gas Combustion Devices
Comment: Several commenters
contended that the proposed standards
for fuel gas combustion devices were
not stringent enough; EPA should
ensure that the best demonstrated
emission control technologies are
installed as the industry is modernized.
Given the significant hazards to human
health and the environment posed by
SO2 emissions, the commenters
suggested that the 365-day average
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Total annual
cost
($1,000/yr)
12,000
14,000
64,000
4,000
4,300
15,000
limits should be 40 ppmv TRS and 5
ppmv SO2. The commenters also
recommended that EPA tighten the 3hour concentration limit to 100 ppmv
TRS. On the other hand, another
commenter contended that although
amine treatment applications for
product gases can achieve H2S
concentrations of 1 to 5 ppmv, a tighter
standard is not BDT for refinery fuel gas.
Several commenters objected to the
addition of the 60 ppmv H2S and 8
ppmv SO2 limits (365-day rolling
average) in the proposed subpart Ja
standards for fuel gas combustion
devices because they are infeasible and/
or not cost-effective. According to
commenters, EPA erroneously assumed
that the additional reductions could be
achieved with existing equipment.
Although this may be true in some
cases, commenters asserted that some
refineries would need to add additional
amine adsorber/regenerator capacity
and some may also need to add
additional sulfur recovery capacity (e.g.,
an additional Claus train and tail gas
treatment unit). One commenter
requested an exemption be provided for
refineries that cannot meet the tighter
long-term standard by simply increasing
their amine circulation rates. One
commenter stated that there will be
little incremental environmental benefit
from the long-term limit, and it
unnecessarily penalizes refineries that
designed their amine systems to treat to
levels near the proposed annual
standard. The commenters provided
cost data for examples of projects
requiring new amine adsorption units to
show that the proposed standards are
not cost-effective.
PO 00000
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Fmt 4701
Sfmt 4700
Emission
reduction
(tons NOX/yr)
2,100
2,200
2,500
Cost-effectiveness
($/ton)
Overall
1,900
1,900
5,900
Incremental
1,900
2,100
39,000
A number of commenters particularly
opposed the proposed revision to
include TRS limits for fuel gas produced
from coking units or any fuel gas mixed
with fuel gas produced from coking
units. One commenter noted that some
State and local agencies have specific
TRS standards, but these requirements
were not based on a BDT assessment.
According to commenters, EPA has
included no technical basis for the
achievability of the TRS fuel gas
standard or explanation of why control
of TRS is limited to fuel gas generated
by coking units. The commenters
recommended that EPA postpone
adoption of a TRS limit until it has
gathered and evaluated adequate data to
conclude that the limit is technically
feasible and cost effective.
Commenters stated that EPA did not
address the cost-effectiveness and nonair quality impacts of the TRS standards
and did not define BDT for the removal
of TRS. One commenter stated that
without an established de minimis level,
an entire fuel gas system could be
subject to the TRS limits if any amount
of coker gas enters the fuel gas system.
Amine scrubbing systems are selective
to H2S and are not suitable to other TRS
compounds such as mercaptans,
according to the commenters.
Commenters stated that the non-H2S
TRS compounds are not amenable to
amine treating and there is no
technology readily in-place at refineries
for reducing non-H2S TRS compounds.
Therefore, according to the commenters,
removing these other TRS compounds
would require significant capital outlay
for new equipment, costs that were not
considered in the impacts analysis.
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One commenter provided an example
of a treatment system installed to meet
a facility-wide fuel gas total sulfur
standard of 40 ppmv; the commenter
estimated the capital cost of the entire
system to be $150 million. The
commenter also indicated that low-BTU
gas from flexicoking units would need
to be specially treated at a capital cost
of $61 million to achieve a total sulfur
content of less than 150 ppmv, and the
treatment would increase energy
consumption, resulting in increases in
NOX and CO emissions. Another
commenter provided an order-ofmagnitude engineering estimate of $50
million to treat TRS down to 45 ppmv
(long-term average). Based on one
commenter’s experience with a new fuel
gas treating facility, non-acidic TRS
cannot be treated down to the proposed
levels utilizing Merox-amine treatment.
A cost-effective solution could be
natural gas blending at the affected
combustion device; however, this
option has the negative effect of
reducing the production of refinery fuel
gas and therefore reducing the refinery’s
capacity for making gasoline.
Several commenters stated that the
original BDT determination was based
on amine scrubbing of H2S and not on
SO2; the SO2 standard was simply a
compliance option that was calculated
to be equivalent to the H2S
concentration limit at 0 percent excess
air. They also asserted that EPA cannot
use the SO2 option as a basis for the TRS
standard because the SO2 option is not
BDT. On the other hand, one commenter
requested that EPA clarify the fuel gas
standards in subpart J to expressly
indicate that the 20 ppmv SO2 limit is
a valid compliance option (instead of
including it only in the monitoring
section). According to the commenter,
focus has been on H2S due to the
structure of the requirements of subpart
J and permits rarely require that
combustion sources demonstrate
compliance with the 20 ppmv SO2 limit.
The commenter stated that refiners
clearly should be allowed to comply
with the broader, more comprehensive
SO2 limit.
A few commenters noted that, as H2S
is part of TRS, the TRS standard is even
more stringent than the H2S standard.
One commenter recommended that no
change in the fuel gas standards be
made or that the standards focus on H2S
only with an alternative emission limit
for SO2. One commenter stated that EPA
developed the 160 ppmv H2S standard
to be more stringent than the 20 ppmv
SO2 standard specifically because H2S
did not represent all of the sulfur in the
fuel gas. Commenters stated that using
an F-factor approach (Method 19, 40
CFR part 60, Appendix A–7), the TRS
limit that is equivalent to the 20 ppmv
SO2 emission limit is 260 ppmv and the
TRS limit that is equivalent to the 8
ppmv SO2 emission limit is 104 ppmv.
Response: We initially concluded that
fuel gas generated by the coking unit
was mixed with other fuel gases that
were mostly H2S and that increasing the
amine circulation rate would result in
additional H2S removal that could be
used to meet the proposed standard.
However, based on a review of the
available data, non-H2S sulfur content
in coker fuel gas may be 300 to 500
ppmv. At these levels, specific
treatment to reduce these other sulfur
compounds would be needed. As
indicated by one commenter, a plantwide total sulfur limit of 40 ppmv has
been achieved in practice in at least one
refinery using a treatment train
consisting of a Merox system, sponge oil
absorbers, MEA absorbers, and caustic
wash towers. Therefore, total sulfur fuel
gas treatment methods are
demonstrated. We evaluated the cost of
this treatment based on information
provided in the public comments.
Based on the public comments and
additional data, we revisited the BDT
determination and assessed three
options for increasing SO2 control of
fuel gas combustion devices: (1) 20
ppmv SO2 or 162 ppmv H2S averaged
over 3 hours; (2) Option 1 plus 8 ppmv
SO2 or 60 ppmv H2S averaged over 365
days; and (3) a compliance option of 162
ppmv TRS averaged over 3 hours and 60
ppmv TRS averaged over 365 days for
fuel gas combustion devices combusting
fuel gas generated by a coking unit and
Option 2 for combustion devices
combusting fuel gas not generated by a
coking unit. Option 1 includes the same
limits that are in subpart J, so there are
no additional costs or emission
reductions beyond those expected from
the application of subpart J. To address
the commenters’ concerns that not all
facilities have available amine capacity
to ensure compliance with the new
long-term limits, we revised our
proposal analysis to include additional
costs for the estimated 10 percent of the
affected facilities that would increase
their amine capacity to achieve Option
2. We estimated costs for a separate
treatment train that can treat TRS for
Option 3 because, based on the public
comments received, we have concluded
that amine treatment systems are not
effective for non-H2S components of
TRS. The estimated fifth-year impacts of
each of these options for new fuel gas
combustion devices are presented in
Table 13 of this preamble; the impacts
for modified and reconstructed fuel gas
combustion devices are presented in
Table 14 of this preamble.
TABLE 13.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR SO2 LIMITS CONSIDERED FOR NEW FUEL GAS
COMBUSTION DEVICES SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
2 ...........................................................................................
3 ...........................................................................................
Total annual
cost
($1,000/yr)
1,200
100,000
Emission
reduction
(tons SO2/yr)
720
13,000
510
770
Cost-effectiveness
($/ton)
Overall
Incremental
1,400
17,000
1,400
47,000
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TABLE 14.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR SO2 LIMITS CONSIDERED FOR MODIFIED AND
RECONSTRUCTED FUEL GAS COMBUSTION DEVICES SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
2 ...........................................................................................
3 ...........................................................................................
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Total annual
cost
($1,000/yr)
33,000
1,700,000
Fmt 4701
Sfmt 4700
Emission
reduction
(tons SO2/yr)
11,000
200,000
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4,700
7,600
24JNR4
Cost-effectiveness
($/ton)
Overall
2,400
26,000
Incremental
2,400
63,000
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Overall costs for Options 1 and 2 are
reasonable compared to the emission
reduction achieved for new, modified
and reconstructed fuel gas combustion
devices. We further evaluated the
incremental costs and reductions
between the three options and found
that they were reasonable for Options 1
and 2, while the incremental cost for
Option 3 is not. While Option 3
provides significant additional SO2
emission reductions, the additional
capital cost of $1.7 billion is high and
could pose a significant barrier to future
refinery upgrades and expansions.
Based on these impacts and
consideration of current operating
practices, we conclude that BDT is use
of technology that reduces the emissions
from affected fuel gas combustion
devices to 20 ppmv SO2 or 162 ppmv
H2S averaged over 3 hours and 8 ppmv
SO2 or 60 ppmv H2S averaged over 365
days, or Option 2. For new fuel gas
combustion devices, this option
achieves SO2 emission reductions of 510
tons/yr from a baseline of 1,000 tons/yr
at a cost of $1,400 per ton of SO2. For
modified and reconstructed fuel gas
combustion devices, this option
achieves SO2 emission reductions of
4,700 tons/yr from a baseline of 10,000
tons/yr at a cost of $2,400 per ton of
SO2.
We note that although we have
determined that Option 3 is not BDT
and we will not limit the amount of SO2
emissions from combustion of sulfur
compounds other than H2S in subpart
Ja, we plan to continue to work with the
industry to understand the magnitude of
these SO2 emissions and to identify
technologies that can be cost effectively
applied to reduce the emissions. We
have learned through this process that
the SO2 emissions from combustion of
TRS in coker gas are generally not
reflected in emission inventories and we
plan to explore this issue in greater
detail in the future to determine where
SO2 emissions are underestimated and
the best way to correct the inventories.
Comment: Several commenters stated
that it is impossible for a refinery owner
or operator to specify, acquire, install,
and calibrate a continuous monitoring
system within 15 days of a change that
increases the H2S concentration such
that an exempt stream is no longer
exempt. One commenter suggested
quarterly stain tube sampling for 1 year
prior to revoking an exemption from
monitoring to confirm the change is
permanent. The commenter suggested
that after 1 year of confirmation, an
additional 12 months be provided to
specify, acquire, install, and calibrate
the continuous monitoring system. One
commenter suggested 1 year be
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14:47 Jun 23, 2008
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provided for installing a CEMS, while
another commenter suggested 180 days
be provided (with an allowance for an
additional extension) for installing a
CEMS, rather than the 15 days
proposed.
Response: We believe that in most
cases, the process change would be a
deliberate, planned act and that the
potential consequences of this
deliberate change would be evaluated.
That is, before the equipment is
modified, the refinery owner or operator
is expected to assess the impacts of this
change on the exempted fuel gas stream.
If the change is expected to increase the
sulfur content of the fuel gas, than the
owner or operator can plan to install the
required CEMS when modifying the
process. We recognize that some process
changes may have unexpected
consequences, and a modification that
was not expected to increase the sulfur
content of the fuel gas can result in an
increase in sulfur content. In this case,
it may be impossible to install the
required CEMS within 15 days.
However, quarterly sampling does not
provide any basis by which the refinery
owner or operator can demonstrate
compliance with the H2S concentration
standard. Instead, we have added
provisions that require an owner or
operator to install a CEMS as soon as
practicable and no later than 180 days
after a change that makes the stream no
longer exempt. Between the process
change and the time a CEMS is
installed, the owner or operator must
conduct daily stain tube sampling to
demonstrate compliance with the H2S
concentration standard. During this
time, a single daily sample exceeding
162 ppmv must be reported as an
exceedance of the 3-hour H2S
concentration limit and a rolling 365day average concentration must be
determined. A daily average H2S
concentration of 5 ppmv is to be used
for the days prior to the process change
for the previously exempt stream in
calculating the rolling 365-day average
concentration.
I. Flaring of Refinery Fuel Gas
Comment: Several commenters
supported the proposed work practice
standards to eliminate routine flaring
and develop startup, shutdown, and
malfunction (SSM) plans; the
commenters opposed the co-proposal of
no standards. One commenter
supported the determination that
elimination of routine flaring is BDT,
citing reductions in hydrocarbon, NOX,
SO2, and carbon dioxide (CO2)
emissions. One commenter stated that
both subparts J and Ja should explicitly
require that flaring be used only as a last
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35853
resort in unusual circumstances, such as
emergencies, and not on a routine basis.
Commenters asserted that monitoring on
an ongoing basis is needed to verify that
no flaring of nonexempt gases occurs.
Commenters stated that subpart Ja
should also require refiners to install a
flare gas recovery system, although such
requirements should not preclude
monitoring requirements. One
commenter stated that the NSPS should
require a SSM plan to eliminate venting
or flaring during such planned start-up,
shutdown, and maintenance activities
and explicitly prohibit venting or flaring
during these planned activities; proper
operation and maintenance practices
should completely eliminate the need to
use flares during these activities. One
commenter noted that those refineries
that have evaluated their startup and
shutdown procedures to reduce or
eliminate direct venting or flaring
during planned startup and shutdown
events have demonstrated the best
technology; therefore, their actions
represent BDT and should be adopted in
the NSPS. The commenters also
supported conducting a root cause
analysis (RCA) in the event of flaring
and other venting releases of 500 lb/day
SO2.
A number of commenters generally
supported the intent to reduce flaring
and the idea of SSM plans to address
flaring during planned startups and
shutdowns (one commenter also
included combustion of high sulfurcontaining fuel gases during a
malfunction), flare management plans,
and RCA for flare events in excess of
500 lb/day. However, they opposed the
work practice standard for elimination
of routine flaring and the proposed
creation of fuel gas producing units for
subpart Ja. The commenters stated that
the definition of ‘‘fuel gas producing
unit’’ is overly broad, making it difficult
to determine what constitutes a
modification or reconstruction, and the
proposed work practice standard for
these units is infeasible, unnecessary,
and not cost-effective. Facility operators
and regulators would have difficulty
discerning if a flaring event was caused
by an affected fuel gas producing unit or
a unit not subject to the standard. One
commenter indicated that there is no de
minimis level by which units that
produce insignificant quantities of fuel
gas can be excluded from the extensive
work practice standards.
Commenters recommended that the
affected source be the flare which is
already subject to the standard as a fuel
gas combustion device. The commenters
suggested that for each affected flare, the
facility would develop a written Flare
Management Plan designed to minimize
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Federal Register / Vol. 73, No. 122 / Tuesday, June 24, 2008 / Rules and Regulations
flaring of fuel gas during all periods of
operation. This plan, along with the
RCA, would ensure that all flaring
events with potential excess emissions
will be minimized. One commenter
noted that EPA could require a flare
management plan for any flare tied to a
fuel gas system that has an affected fuel
gas combustion device as a better
alternative to ‘‘fuel gas producing
units.’’ One commenter noted that an
exemption from the notification
requirements for modified or
reconstructed units could be provided
as an incentive for early adoption of the
flare management plan; another
commenter suggested that regulatory
incentives such as exemptions from
monitoring and developing flare
management plans should be provided
for facilities that have installed flare gas
recovery systems. One commenter
supported this type of requirement for
flares currently subject to subpart J,
assuming a minimum of 9 months is
provided for plan development and
implementation. On the other hand, one
commenter noted that the definitions of
the affected facility under subparts J and
Ja are different and recommended that
the distinction be made stronger so that
it is clear that existing process unit
facilities are ‘‘grandfathered’’ and
exempt from the flaring minimization
standards.
One commenter suggested that the
work practices language should be
clarified to indicate that routing offgas
to the flare system would be acceptable
if the system was equipped with a flare
gas recovery system. The prohibition
should be specific to the flare itself as
some flare systems are equipped with
recovery compressors, the use of which
should be encouraged rather than
discouraged.
Commenters stressed the need for
flares as safety devices; any flare
minimization program must not
interfere with the ability of the refinery
owner or operator to use flares for safety
reasons. The commenters stated that
‘‘routine’’ flaring cannot be adequately
defined in practice; therefore,
restrictions on ‘‘routine’’ flaring will
lead to unsafe operations in attempts to
avoid enforcement actions. The
commenters requested that EPA include
language in the regulation, consistent
with the preamble discussion, that:
‘‘Nothing in this rule should be
construed to compromise refinery
operations and practices with regard to
safety.’’
One commenter indicated that the
proposed work practice standards for
‘‘no routine flaring’’ interfere with flare
minimization plans implemented in
response to consent decrees. The
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14:47 Jun 23, 2008
Jkt 214001
proposed work practice standard could
be interpreted as prohibiting flaring
during start-up and shutdown, and EPA
has not determined this to be BDT. The
commenter stated that the BAAQMD
analysis applies to eliminating flaring
during normal operation [similar to
proposed § 60.103a(b)], not during startup and shutdown as in proposed
§ 60.103a(a). The commenter provided
cost estimates for one refinery to install
a recovery system to eliminate flaring
during start-up and shutdowns; the
costs ranged from $200,000 to $800,000
per ton of VOC reduced and higher for
other criteria pollutants. Therefore, they
contend § 60.103a(a) should clearly
exclude start-up and shutdown gases.
A few commenters provided overall
project costs for flare gas recovery
projects indicating the annual costs are
higher than those in the analysis
supporting the proposed work practice.
One commenter stated that EPA
underestimated the cost of flare gas
recovery systems and, given the
uncertainty in emission reductions,
contended that flare gas recovery
systems for the no-flaring option are not
cost-effective within the NSPS context.
The commenter also stated that the
regulation should include maintenance
provisions for flare gas recovery systems
(that allow flaring) during times of
routine and non-routine maintenance,
as no redundant capacity within the
flare system exists.
A number of commenters provided an
alternative to EPA’s proposed work
practice standards. The suggestions
included a 500 lb/day SO2 standard tied
with a flare management plan as an
alternative compliance option (to the
H2S concentration limit) for flares. The
commenters recommended that this
alternative compliance option be
provided in both subparts J and Ja and
noted that it could be used as an
incentive for the flare management plan
to cover all flares. One commenter also
noted that these requirements should be
applicable to flares that receive process
gas, fuel gas, or process upset gas; they
should not be applicable to flares used
solely as an air pollution control device,
such as a flare used exclusively to
control emissions from a gasoline
loading rack. Another commenter
clarified that if the refinery elects to
comply with this alternative for any
flare, all flares at the refinery would
need a flare management plan. The
commenter noted that EPA could
choose to set the 500 lb/day SO2 limit
as a total for all flares for which the
alternative compliance option is chosen
(i.e., if the alternative compliance
option is selected for two flares at a
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Fmt 4701
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refinery, the total emissions from both
flares would be limited to 500 lb/day).
Response: Although commenters
suggested that certain provisions be
made applicable to facilities subject to
subpart J, the following provisions are
only applicable to facilities subject to
subpart Ja as CAA section 111 provides
that new requirements apply only to
new sources. We considered these
comments and agree that the standards
are more straightforward when the
affected facility is defined as the flare.
Therefore, we have eliminated ‘‘fuel gas
producing units’’ as an affected facility
in this final rule, and we specifically
define a flare as a subset of fuel gas
combustion device, which is an affected
facility in this final rule. A ‘‘flare’’
means ‘‘an open-flame fuel gas
combustion device used for burning off
unwanted gas or flammable gas and
liquids. The flare includes the
foundation, flare tip, structural support,
burner, igniter, flare controls including
air injection or steam injection systems,
flame arrestors, knockout pots, piping
and header systems.’’
There are three general work practice
standards that were proposed for ‘‘fuel
gas producing units,’’ which may be
summarized as follows: (1) The ‘‘no
routine flaring’’ requirement; (2) flare
minimization plan for start-up,
shutdown, and malfunction events; and
(3) a root-cause analysis for SO2 releases
exceeding 500 lb/day (which was
proposed for all affected fuel gas
producing units). The ‘‘no routine
flaring’’ work practice was not intended
to prohibit flaring during SSM events;
the provisions were intended to apply
only during normal operating
conditions. We agree with the
commenter that suggested that nothing
in this rule should be construed to
compromise refinery operations and
practices with regard to safety.
Additionally, as discussed in the
preamble to the proposed rule, we
specifically rejected a prohibition on
flaring for planned start-up and
shutdown events. We agree with the
commenters that noted that numerous
refineries have demonstrated that flare
minimization during planned start-up
and shutdown activities can greatly
reduce flaring during these events. We
do believe, however, that a complete
elimination of flaring during these
events is very site-specific and although
it is reported to have been achieved at
a limited number of refineries, we do
not have information to suggest that it
has been adequately demonstrated for
universal application. As ‘‘no routine
flaring’’ is difficult to define in practice,
we have re-evaluated BDT using more
specific options.
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Option 1 is no additional standards
for flares. In Option 2, any routine
emissions event or any process start-up,
shutdown, upset or malfunction that
causes a discharge into the atmosphere
more than 500 pounds per day of SO2
(in excess of the allowable emission
limit) from an affected fuel gas
combustion device or sulfur recovery
plant would require a root cause
analysis to be performed. This approach
is similar to what is included in most
consent decrees. We are also including
a requirement for continuous
monitoring of TRS for all gases flared
(including those from upsets, startups,
shutdowns, and malfunction events), in
order to accurately measure SO2
emissions from affected flares.
Option 3 includes: (1) The SO2 root
cause analysis in Option 2; (2) a limit on
the fuel gas flow rate to the flare of
250,000 scfd; and (3) a flare
management plan for SSM events. The
flow limit of 250,000 scfd is based on
our cost analysis that indicates that for
typical gas streams in quantities above
this limit, the value of recovered fuel
completely offsets the costs of installing
and operating recovery systems. Many
refineries have implemented flare gas
recovery to reduce energy needs and
save money. The flare management plan
must: (1) Include a diagram illustrating
all connections to each affected flare; (2)
identify the flow rate monitoring device
and a detailed description of
manufacturer’s specifications regarding
quality assurance procedures; (3)
include standard operating procedures
for planned start-ups and shutdowns of
refinery process units that vent to the
flare (such as staging of process
shutdowns) to minimize flaring during
these events; (4) include procedures for
a root cause analysis of any process
upset or equipment malfunction that
causes a discharge to the flare in excess
of 500,000 scfd; and (5) include an
evaluation of potential causes of fuel gas
imbalances (i.e., excess fuel gas), upsets
or malfunctions and procedures to
minimize their occurrence and records
to be maintained to document periods of
excess fuel gas. Excess emission events
for the flow rate limit of 250,000 scfd
and the result of root cause analysis
must be reported in the semi-annual
compliance reports.
Option 4 is identical to Option 3
except that flaring is limited to 50,000
scfd. This level is estimated to be a
baseline level that accounts for the flow
requirement needed to maintain safe
operations of the flare (i.e., flow of
sweep gas and compressor cycle gas).
For both Option 3 and Option 4, the
limit on the flow rate does not apply
during malfunctions and unplanned
startups and shutdowns. The flow rate
limits in Options 3 and 4 were
developed to reduce VOC, SO2, and
NOX emissions; the limits are based on
30-day rolling average flow rate values.
It is anticipated that a flare gas
recovery system will be used to comply
with Options 3 and 4 when a flare is
currently used on a continuous basis,
and the recovered flare gas offsets
natural gas purchases. The costeffectiveness of the flare gas recovery
system is primarily dependent on the
35855
quantity of gas that the system can
recover. Many refineries have already
implemented similar work practices
through consent decrees and local rules
(BAAQMD and SCAQMD), and these
requirements have had a demonstrated
reduction in flaring events. Flare gas
recovery will reduce SO2, NOX, and
VOC emissions. However, if a refinery
produces more fuel gas than the refinery
needs to power its equipment, there is
no place the refinery can use the
recovered fuel gas and there is no
additional natural gas purchases to
offset. In these cases, flare gas recovery
is not considered technically feasible
because the excess fuel gas will have to
be flared. Therefore, we have included
specific provision within the flare
management plan to address instances
of excess fuel gas. For periods when the
refinery owner or operator can
demonstrate, through records of natural
gas purchases or other means as
described in their flare management
plan, that the refinery is fuel gas rich,
compliance with the flow limit is
demonstrated by implementing the
procedures described in the flare
management plan.
Impacts for each of the four options
are based on estimates of current flaring
quantities and include the root cause
analysis, flare management plan, and
flare gas recovery systems when needed.
The impacts for each option for new
flares are presented in Table 15 to this
preamble; impacts for modified and
reconstructed flares are presented in
Table 16 to this preamble.
TABLE 15.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR WORK PRACTICES CONSIDERED FOR NEW FLARING
DEVICES SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
2 ...................................
3 ...................................
4 ...................................
Total annual
cost
($1,000/yr)
0
8,800
15,000
Emission
reduction
(tons SO2/yr)
23
(1,300)
(840)
Emission
reduction
(tons NOX/yr)
Emission
reduction
(tons VOC/yr)
0
1
1
0
41
52
15
16
16
Cost-effectiveness ($/ton)
Overall
1,600
(23,000)
(12,000)
Incremental
1,600
(31,000)
43,000
TABLE 16.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR WORK PRACTICES CONSIDERED FOR MODIFIED AND
RECONSTRUCTED FLARING DEVICES SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
ebenthall on PRODPC60 with RULES4
2 ...................................
3 ...................................
4 ...................................
Total annual
cost
($1,000/yr)
0
35,000
59,000
92
(5,300)
(3,300)
Based on these impacts and
consideration of technically feasible
operating practices, we conclude that
BDT is Option 3. Option 3 includes a set
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14:47 Jun 23, 2008
Jkt 214001
Emission
reduction
(tons SO2/yr)
Emission
reduction
(tons NOX/yr)
Emission
reduction
(tons VOC/yr)
0
4
6
0
165
207
59
64
66
of work practice standards that requires
root cause analysis for a discharge into
the atmosphere in excess of 500 pounds
per day of SO2 (over the allowable
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Cost-effectiveness ($/ton)
Overall
1,600
(23,000)
(12,000)
Incremental
1,600
(31,000)
43,000
emission limit) from a fuel gas
combustion device or sulfur recovery
plant or in excess of 500,000 scfd flow
to a flare. It also includes a flare
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management plan. Finally, fuel gas flow
to the flare is limited to 250,000 scfd. To
support implementation of these
requirements, monitoring and reporting
of the flow rate and sulfur content is
required. For new flaring devices, this
option achieves SO2 emission
reductions of 16 tons/yr from a baseline
of 32 tons/yr, NOX emission reductions
of 1 tons/yr from a baseline of 2 tons/
yr, and VOC emission reductions of 41
tons/yr from a baseline of 67 tons/yr
with a net fuel savings of $23,000 per
ton of combined SO2, NOX, and VOC.
For modified and reconstructed flaring
devices, this option achieves SO2
emission reductions of 64 tons/yr from
a baseline of 129 tons/yr, NOX emission
reductions of 4 tons/yr from a baseline
of 7 tons/yr, and VOC emission
reductions of 165 tons/yr from a
baseline of 266 tons/yr with a net fuel
savings of $23,000 per ton of combined
SO2, NOX, and VOC.
The flare gas minimization
requirements included in the final
standards are important to reduce
criteria pollutant emissions and
conserve energy. However, we recognize
that owners and operators also need to
be able to make quick changes to
existing process units or flare systems to
avoid unsafe conditions. It could take an
owner or operator more time to
implement the flare requirements,
especially flow monitoring and any
physical changes needed to comply
with the limit on flow to the flare, than
it took to implement the change to the
flare that caused it to be an affected
facility. There is the potential for
serious safety concerns if the owner or
operator must wait until compliance has
been achieved with all of the flare gas
minimization requirements prior to
venting explosive vapors to the flare or
modifying the flare system, such as
adding a knockout pot for safety
reasons. Moreover, avoiding unsafe
conditions by requiring immediate
shutdown of all process units connected
to the potentially affected flare while
the owner or operator takes steps to
comply with the final provisions
specific to flare gas minimization results
in additional emissions, significant
costs, and large lost production of
refined products. By providing 1 year
for modified flares to comply with these
flare gas minimization provisions,
refinery owners and operators have
sufficient time to coordinate the
installation of the flow rate and sulfur
content monitors, to take whatever steps
necessary to meet the flow limitations,
to develop and implement the flare
management plan, and to make other
modifications, if needed, regarding
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14:47 Jun 23, 2008
Jkt 214001
safety and maintenance considerations
for other process equipment tied to the
flare.
Considering the cost and the energy
penalty from the reduction in refined
products (e.g., the need to shut down
the refinery until the flare gas
minimization requirements can be met)
and emissions associated with the
immediate application of these
requirements of the rule to modified
flares, we determined that BDT was to
phase in the requirements. The owner or
operator of a modified flare would have
to comply with the applicable H2S limit
immediately and would have 1 year to
implement the flare gas minimization
requirements. Therefore, the final
standards specify that for modified
flares, the H2S limits for fuel gas
combustion units apply immediately
and the flare gas minimization
requirements apply no later than 1 year
after the flare becomes an affected
facility. For newly constructed and
reconstructed flares, the H2S limits and
all of the flare gas minimization
requirements apply immediately upon
start-up of the affected flare.
Comment: Several commenters
requested clarification of how one
would assess a flare ‘‘modification.’’
Questions included: (1) How the
emission basis of a flare should be
calculated; (2) if the modification
determination would be based on flare
capacity or increase in discharge
capability of units connected to the
flare; (3) whether the modification
determination would include all
possible flaring events or just nonemergency flaring; (4) whether adding a
new line to a flare is considered to
increase the capacity of the flare and
cause a modification; (5) whether flare
tip replacements are considered routine
maintenance instead of a modification
of the flare, even if the new flare tip has
a different geometry (e.g., a larger
diameter to reduce noise); and (6) how
SSM streams are considered when
calculating baseline emissions for a
modification determination. The
commenters also suggested that EPA
should clarify whether and how the
exemption in § 60.14(e)(2) applies to a
flare, including how the production rate
for a flare would be defined.
Response: Section 60.14(a) defines
modification as follows: ‘‘Except as
provided in paragraphs (e) and (f) of this
section, any physical or operational
change to an existing facility which
results in an increase in the emission
rate to the atmosphere of any pollutant
to which a standard applies shall be
considered a modification.’’ Section
60.14(e) provides exclusions for
maintenance activities, increased
PO 00000
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Fmt 4701
Sfmt 4700
production rates, increased hours of
operation, etc. However, except for the
maintenance exclusion, the other
exemptions are either not applicable or
ambiguous when applied to a flare.
More importantly, § 60.14(f) states that
‘‘Applicable provisions set forth under
an applicable subpart of this part shall
supersede any conflicting provisions of
this section.’’ Therefore, to eliminate
ambiguity, we specifically define what
constitutes a flare modification in
subpart Ja.
A flare is considered to be modified
in one of two ways. First, a flare is
considered to be modified when any
piping from a refinery process unit or
fuel gas system is newly connected to
the flare. This new piping could allow
additional gas to be sent to the flare,
consequently increasing emissions from
the flare. Second, a flare is considered
to be modified if that flare is physically
altered to increase flow capacity.
While in most cases an affected
facility must comply with the final
standard if it commences construction,
reconstruction or modification after the
proposal date, section 111(a)(2) of the
CAA also provides that in certain
circumstances such a source only need
comply with the standard if it
commences construction after the final
date. Given the number of changes
between proposal and final, we have
concluded that this is one of the rare
cases in which the final, rather than
proposal, date applies.
In this case, we are promulgating a
newly defined affected facility, adding a
new provision specifically defining
what constitutes a modification of a
flare, adding several new requirements,
and adding a definition of a flare. All of
these changes significantly alter what
would be an affected facility and the
obligations of the affected facility for
purposes of reducing flaring.
Furthermore, while some of the
requirements that were proposed for the
fuel gas producing unit were transferred
to the flare as an affected source, the
scope of these requirements changed
significantly when they were applied to
a flare rather than a fuel gas producing
unit. Specifically, under the proposal,
only the gas stream from the modified
fuel gas producing unit was barred from
routine flaring. Under the final rule,
however all of the units connected to
the flare are now addressed, not just the
fuel gas producing unit that was new,
modified, or reconstructed.
Accordingly, we are providing in the
final standards that only those flares
commencing construction,
reconstruction, or modification after
June 24, 2008 must meet the
requirements in subpart Ja. Flares
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commencing construction,
reconstruction, or modification after
June 11, 1973, and on or before June 24,
2008 must meet the requirements in
subpart J regarding fuel gas combustion
devices (i.e., the H2S fuel gas limit).
J. Delayed Coking Units
Comment: Several commenters
supported the proposal that requires
delayed coking units to depressure the
coke drums to the fuel gas system down
to 5 psig. One commenter supported
venting the delayed coker gas to a flare
or to the atmosphere at pressures less
than 5 psig; at pressures greater than 5
psig, the commenter suggested that the
rule should only prohibit gases from
being sent to a flare and allow any other
disposition. That is, the commenter
stated that EPA should not restrict the
disposition of the coker
depressurization gas to only the fuel gas
system.
One commenter supported inclusion
of a coke drum pressure limit above
which the coke drum exhaust gases
must be sent to a recovery system,
disagreed that it is technically infeasible
to divert emissions for recovery at
pressures below 5 psig, and urged EPA
to require venting until the pressure
drops below 2 psig. The commenter
recently issued a permit including the 2
psig level, and although the
modification has not been completed,
the commenter believes the requirement
is technically feasible.
A number of commenters objected to
the finding that BDT is to depressure
delayed coking units to the fuel gas
system down to 5 psig. Commenters
provided examples of coking units
whose current mode of operations (e.g.,
set points or timed cycles) may divert to
a flare or to the atmosphere at pressures
of approximately 10 to 20 psig and that
it would not be cost-effective to modify
these units to comply with the proposed
work practice standard. One commenter
supported the premise that it is costeffective for delayed coking discharge to
be routed to fuel gas blowdown, but
depressurization down to 5 psig may
not be feasible with existing equipment;
the commenter recommended that the
work practice simply require a closed
blow down system following procedures
described in the facility’s SSM plan. At
a minimum, an alternative is needed for
existing units that would require capital
expenditure to meet the 5 psig proposal.
One commenter stated that compressors
cannot recover blowdown system gases
at pressures below the fuel gas recovery
compressor suction pressure. The
minimum pressure at which a suction
compressor can operate depends on the
35857
design of the coking unit and the
blowdown management system.
Because there is uncertainty
surrounding the available emission
information, the costs are not minimal
in most cases, and the emissions are
difficult to measure, the commenter
stated that EPA cannot determine that
controls on coker vents is BDT.
Response: Based on the public
comments, we re-evaluated BDT for
delayed coking units. We considered
three options: (1) Depressurization
down to 15 psig; (2) depressurization
down to 5 psig; and (3) depressurization
down to 2 psig. We estimated that the
baseline is, on average, depressurization
down to 15 psig and then venting to the
atmosphere. Therefore, there are no
impacts for Option 1. Impacts for
Options 2 and 3 were estimated based
on the baseline conditions, the size of
typical coke drums, and cost
information provided in public
comments. We also collected emissions
test data to support and verify the
projected emissions and emission
reductions. The impacts for each option
for new delayed coking units are
presented in Table 17 to this preamble;
impacts for modified and reconstructed
delayed coking units are presented in
Table 18 to this preamble.
TABLE 17.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR WORK PRACTICES CONSIDERED FOR NEW DELAYED
COKING UNITS SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
2 ...............................................................
3 ...............................................................
Total annual
cost
($1,000/yr)
2,400
24,000
Emission
reduction
(tons SO2/yr)
230
2,300
Emission
reduction
(tons VOC/yr)
170
230
Cost-effectiveness ($/ton)
Overall
2
3
1,300
9,900
Incremental
1,300
38,000
TABLE 18.—NATIONAL FIFTH YEAR IMPACTS OF OPTIONS FOR WORK PRACTICES CONSIDERED FOR MODIFIED AND
RECONSTRUCTED DELAYED COKING UNITS SUBJECT TO 40 CFR PART 60, SUBPART JA
Capital cost
($1,000)
Option
ebenthall on PRODPC60 with RULES4
2 ...............................................................
3 ...............................................................
14,000
54,000
Based on these impacts and
consideration of technically feasible
operating practices, we confirmed our
conclusion at proposal that BDT is
depressurization down to 5 psig, or
Option 2. For new delayed coking units,
this option achieves SO2 emission
reductions of 170 tons/yr from a
baseline of 520 tons/yr and VOC
emission reductions of 2 tons/yr from a
baseline of 7 tons/yr at a cost of $1,300
per ton of combined SO2 and VOC. For
modified and reconstructed delayed
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14:47 Jun 23, 2008
Jkt 214001
Total annual
cost
($1,000/yr)
Emission
reduction
(tons SO2/yr)
1,400
5,100
260
340
coking units, this option achieves SO2
emission reductions of 260 tons/yr from
a baseline of 780 tons/yr and VOC
emission reductions of 4 tons/yr from a
baseline of 11 tons/yr at a cost of $5,100
per ton of combined SO2 and VOC.
Although Option 3 has been established
in one refiner’s permit, this level of
depressurization has not been
demonstrated in practice. Additionally,
the difference in the quantity of gas
released when the set point is 2 psig
rather than 5 psig is relatively small, 80
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Sfmt 4700
Emission
reduction
(tons VOC/yr)
Cost-effectiveness ($/ton)
Overall
4
5
5,100
15,000
Incremental
5,100
47,000
tons of SO2 and 4 tons of VOC, and the
resulting incremental cost-effectiveness
from Option 2 to Option 3 is about
$40,000/ton, which is much greater.
Therefore, Option 3, or depressurization
down to 2 psig, is not BDT.
K. Other Comments
Comment: One commenter contested
the criteria EPA used in its Regulatory
Flexibility Act/Small Business
Regulatory Enforcement Fairness Act
(RFA/SBREFA) analysis for defining a
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small refiner as one with no more than
1,500 employees or more than 125,000
barrels per day (BPD) average crude
capacity and requested that EPA use
what the commenter alleged is the
commonly recognized definition in
other EPA programs of no more than
1,500 employees or more than 155,000
BPD average crude capacity. The
commenter noted that EPA did not
make any effort in the Regulatory
Impact Analysis or in the proposal
preamble to support its selection or
explain why it adopted this definition.
Response: Under the SBA regulations,
a small refiner is defined as a refinery
with no more than 1,500 employees. See
Table in 13 CFR 121.201, NAICS code
324110. Additionally, for government
procurement purposes only, footnote 4
to that Table further provides that a
small refinery must meet a certain
capacity threshold as follows: ‘‘For
purposes of Government procurement,
the petroleum refiner must be a concern
that has no more than 1,500 employees
nor more than 125,000 barrels per
calendar day total Operable
Atmospheric Crude Oil Distillation
capacity.’’ After reviewing our analysis,
we realized that we inadvertently used
the capacity limit to evaluate the
impacts on small refiners; the definition
that should have been used is 1,500
employees with no capacity limit. We
have recalculated the economic impact
on the small entities using the corrected
definition of small refiner, and our
conclusion that the rule will not have a
significant economic impact on a
substantial number of small entities has
not changed. See section VI.C of this
preamble and the Regulatory Impacts
Analysis (RIA) in the docket for
additional details.
The commenter is incorrect in
asserting that EPA uses any other
definition for small refiner than the SBA
definition when conducting its RFA/
SBREFA analysis in other rulemakings.
EPA consistently uses the SBA
definition of a small refiner for such
purposes. However, in promulgating
regulations, EPA may define a small
refiner differently when deciding what
standards and requirements apply to
these facilities. For example, in the fuel
standards promulgated by EPA (e.g.,
Control of Air Pollution From New
Motor Vehicles: Tier 2 Motor Vehicle
Emissions Standards and Gasoline
Sulfur Control Requirements (65 FR
6698)), EPA set different requirements
for small refiners than for all other
refiners, and the 155,000 BPD capacity
cutoff cited by the commenter is one of
the criteria used to define a small refiner
in those standards. See 40 CFR 80.225.
However, the RFA/SBREFA analysis
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Jkt 214001
conducted in that rulemaking regarding
whether those rules had a significant
economic impact on a substantial
number of small entities was not
conducted based on any capacity cutoff.
See 65 FR 6817.
Comment: One commenter stated that
EPA is required under section 111 of the
CAA to promulgate NSPS for each of the
pollutants emitted by the source
category that cause or contribute
significantly to air pollution which may
reasonably be anticipated to endanger
public health or welfare. The
commenter stated that there is scientific
consensus that greenhouse gases are a
leading cause of global warming, and
anthropogenic emissions of greenhouse
gases (GHG) such as CO2 and methane
(CH4) are increasing and driving the
warming. Petroleum refineries are a
significant source of fossil fuel CO2
emissions because they consume large
quantities of energy, and in fact, U.S.
petroleum refineries consume over 3.2
percent of the total U.S. energy
consumption. Petroleum refineries also
emit CH4 and are responsible for an
additional 0.6 teragrams of CO2
equivalence via CH4 emissions.
Therefore, the commenter believes that
EPA must set NSPS for CO2 and CH4
because petroleum refineries’ emissions
of CO2 and CH4 cause and contribute
significantly to air pollution which may
reasonably be anticipated to endanger
public health and welfare.
Two commenters cited the Supreme
Court decision in Massachusetts v. EPA,
where the Court found that carbon
dioxide and other GHG fit into the
statutory definition of ‘‘air pollutant’’ in
the CAA. Commenter 0128 stated that in
Massachusetts v. EPA, the Supreme
Court rejected EPA’s overly narrow
interpretation that greenhouse gases do
not fall under the definition. The Court
also voided EPA’s term ‘‘air pollution’’
and noted that because greenhouse
gases both enter the ambient air and
warm the atmosphere, they are
unquestionably agents of air pollution.
Another commenter contended that
while the decision in Massachusetts v.
EPA states that GHG are ‘‘air pollutants’’
as that term is used in CAA section 111,
section 111 does not require EPA to
address all air pollutants in NSPS.
Therefore, the Supreme Court’s decision
does not mean that EPA necessarily
must regulate GHG through NSPS.
Instead of beginning to address GHG in
specific NSPS, the commenter stated
that EPA should develop a
comprehensive plan for addressing GHG
that ensures that ‘‘any necessary
reductions in GHG emissions are
achieved in a consistent and equitable
manner across all industry sectors.’’ The
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commenter further stated that since the
issue of GHG emissions was not raised
in the proposal preamble for subparts J
and Ja, it would be inappropriate for
EPA to promulgate GHG standards in
those subparts without first proposing
the new standards.
Response: While section 111(b)(1)(B)
of the CAA permits EPA, under
appropriate circumstances, to add new
standards of performance for additional
pollutants concurrent with the 8-year
review of existing standards, for the
reasons set forth below, EPA declines to
promulgate performance standards for
GHG, including CO2 and CH4, from
petroleum refineries as part of this 8year review cycle.
Section 111(b)(1)(B) imposes two
obligations upon EPA for a source
category listed under section
111(b)(1)(A). First, within 1 year of
listing a source category, section
111(b)(1)(B) requires the Administrator
to ‘‘publish proposed regulations,
establishing Federal standards of
performance for new sources’’ within
such category. After providing
‘‘interested persons an opportunity for
written comment on such proposed
regulations,’’ EPA must then
‘‘promulgate, within one year after such
publication, such standards’’ as the
Administrator ‘‘deems appropriate.’’
The Agency has always interpreted this
initial requirement as providing the
Administrator with significant
flexibility in determining which
pollutants are appropriate for regulation
under section 111(b)(1)(B). See National
Lime Assoc. v. EPA, 627 F.2d 416, 426
(DC Cir. 1980) (explaining reasons for
not promulgating standards for NOX,
SO2, and CO from lime plants); see also
National Assoc. of Clean Air Agencies v.
EPA, 489 F.3d 1221, 1228–1230 (DC Cir.
2007) (finding that the ‘‘deems
appropriate’’ language in CAA section
231 provides a ‘‘delegation of authority’’
that is ‘‘both explicit and extraordinarily
broad,’’ giving EPA’s regulation
‘‘controlling weight unless it is
manifestly contrary to the statute’’).
Second, the statute requires that:
‘‘The Administrator shall, at least every 8
years, review and, if appropriate, revise such
standards following the procedure required
by this subsection for promulgation of such
standards. Notwithstanding the requirements
of the previous sentence, the Administrator
need not review any such standard if the
Administrator determines that such review is
not appropriate in light of readily available
information on the efficacy of such
standard.’’
Nothing in the 8-year review
provision mandates that EPA include a
new standard of performance for an air
pollutant not already covered by the
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standard of performance under review.
Instead, the 8-year review provision can
be reasonably understood as requiring
‘‘review’’ of only ‘‘such standards’’ 1 as
were previously promulgated. As there
would be no standard to review for an
air pollutant not already subject to the
standard, there would be no
requirement for promulgating a new
standard of performance since the
‘‘review’’ requirement in section
111(b)(1)(B) cannot be transformed into
a ‘‘promulgation’’ requirement.2
Moreover, as noted above, even if the 8year review provision were a
‘‘promulgation’’ requirement, such a
requirement still would not mandate
that EPA set performance standards for
all air pollutants emitted from the
source category. In the 1990 CAA
Amendments, Congress amended the
definition of ‘‘standard of performance’’
to be ‘‘a standard for emissions of air
pollutants,’’ specifically deleting the
word ‘‘any’’ from the phrase ‘‘any air
pollutant’’ that was contained in the
1977 definition. This amendment
restored the definition to the 1970
version. This deliberate change
demonstrates that Congress was aware
that the 1970 definition did not require
EPA to cover all air pollutants emitted
from a source category. Additionally, by
reinstating the 1970 definition through
the 1990 CAA amendments, Congress
was also indicating its understanding
that EPA is not required to regulate all
air pollutants emitted from a source
under section 111.
EPA has promulgated new
performance standards for pollutants
not previously covered concurrent with
some previous 8-year review
rulemakings. See 52 FR 24672, 24710
(July 1, 1987) (considering PM10
1 Commenters assert that ‘‘the term ‘such
standards’ incorporates the inclusive ‘any’ air
pollutant language in the definition of a ‘standard
of performance’ ’’ and therefore contemplates new
standards of performance during the 8-year review.
See Comments, pg. 3. However, the word ‘‘any’’
does not appear in the definition of ‘‘standard of
performance’’ in the manner quoted by
commenters. See CAA section 111(a)(1).
2 Commenters assert that EPA must develop
performance standards during the 8-year review
‘‘for any air pollutant’’ emitted by a source
‘‘provided that EPA finds those emissions cause or
contribute to air pollution’’ that may endanger
public health or welfare. See Comments, pg. 2. To
the extent any such finding were required, EPA
notes that no such finding has been made regarding
GHG emitted from refineries. Indeed, 111(b)(1)(A),
which contains the only endangerment finding
requirement in section 111, gives the Administrator
significant discretion on the timing of
endangerment findings after the initial set of source
category listings (‘‘from time to time thereafter shall
revise’’). Nothing in the statute ties the
endangerment and 8-year review requirements.
Hence, commenters’ own arguments lack merit and
EPA is under no obligation for promulgating GHG
performance standards for refineries.
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controls in future rulemakings); 71 FR
9866 (February 27, 2006) (new PM
standards for boilers). Additionally, as
commenters correctly point out, EPA is
promulgating a new standard of
performance for NOX emissions from
certain affected facilities at refineries in
this rulemaking. However, contrary to
commenters’ assertions,3 these actions
were discretionary; EPA may, but is not
required to, promulgate new standards
of performance concurrent with its 8year review. While it may often be
appropriate for EPA to exercise its
discretion by promulgating new
standards of performance concurrent
with an 8-year review, because it is in
the process of gathering information and
reviewing controls for an industry, for
the reasons set forth above, EPA
reasonably interprets section
111(b)(1)(B) to not mandate such a
result.
In this instance, it is reasonable for
EPA not to promulgate performance
standards for GHG emissions as part of
this 8-year review cycle. We believe that
the nature of GHG emissions renders
them readily distinguishable from other
air pollutants for which we have
previously promulgated new
performance standards concurrent with
an 8-year review of the existing
standards. Indeed, GHG emissions
present issues that we have never had
to address in the context of even an
initial NSPS rulemaking for a source
category. These differences warrant
proceeding initially through a more
deliberate process, i.e., the announced
advanced notice of proposed
rulemaking (ANPR), than in this source
category-specific rulemaking. While
commenters correctly note that we have
previously exercised our discretion to
promulgate new performance standards
concurrent with an 8-year review, and
indeed are doing so here with respect to
NOX, the exercise of that discretion had
limited impact as those air pollutants
were either already regulated elsewhere
under the Act or were emitted by a
sufficiently limited subset of source
categories. Here, promulgating new
performance standards for these air
pollutants in this one source category
could potentially mandate regulation for
numerous other source categories under
several other parts of the Act. Similarly,
our initial decision to regulate nonNational Ambient Air Quality Standards
(NAAQS) air pollutants in an NSPS has
3 Commenters again predicate their assertions on
a prerequisite endangerment finding. See
Comments, pg. 4. As explained in footnote 2, EPA
has made no such finding and therefore under
petitioners’ interpretation is under no obligation to
promulgate GHG performance standards for this
source category.
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35859
generally raised issues limited to the
source category before us. For example,
with the exception of landfill related air
pollutants,4 our decisions to regulate
non-NAAQS air pollutants were reached
at a time prior to the enactment of the
statutory Prevention of Significant
Deterioration (PSD) program and
accordingly did not implicate the many
complexities that we are struggling with
today and which we intend to address
in the ANPR discussed below. See 45
FR 52,676, 52,708–10 (Aug. 7, 1980).
In contrast to those circumstances, the
regulation of GHG emissions raises
numerous issues that are not well suited
to initial resolution in a rulemaking
directed at an individual source
category. To that end, as Administrator
Johnson announced on March 27, 2008,
in letters to Senator Barbara Boxer and
Representative John Dingell, it is his
intent to issue an ANPR in the very near
future that explores and seeks public
comment on the many complex
interconnections between the relevant
sections of the Clean Air Act, including
section 111, and lays the foundation for
a comprehensive path forward with
respect to regulation of all GHG.
We have previously noted that at this
stage it is most appropriate to address
these complexities in an ANPR
addressing a variety of interconnected
statutory provisions. In his April 10,
2008, testimony before the
Subcommittee on Energy and Air
Quality, Committee on Energy and
Commerce, U.S. House of
Representatives, Robert J. Meyers,
Principal Deputy Assistant
Administrator of the Office of Air and
Radiation, further elaborated on the
reasons for and anticipated content of
an ANPR and discussed some of these
complexities. For example, he noted the
potential complexities resulting from
implementation of the PSD
preconstruction review permitting
program:
For PSD purposes, major stationary sources
are those with the potential to emit 100 tons
per year of a regulated air pollutant in the
case of certain statutorily-listed source
categories, and 250 tons per year in the case
of all other source categories. New large
schools, nursing homes, and hospitals could
be considered a ‘‘major source’’ under this
section of the Clean Air Act. For
modifications, only those that increase
4 Because of the unique nature of landfill related
air pollutants the Agency determined it was
appropriate to define the air pollutants at issue as
emissions from landfills and thus limited the
potential implications for other programs. See 56
FR 24468, 24470 (May 30, 1991). In other words,
only landfills emit these particular air pollutants;
thus, it was appropriate that only this source
category was subject to the PSD program for this air
pollutant.
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emissions above a tonnage threshold
established by EPA for each regulated
pollutant through rulemaking triggers PSD.
Until EPA establishes this so-called
‘‘significance’’ level, however, any increase
in a regulated pollutant at a major stationary
source undergoing a modification would
trigger PSD permitting.
As noted previously, PSD sources are
required to install best available control
technology (BACT). BACT must be at least as
stringent as any applicable NSPS, and is to
reflect the maximum degree of emissions
reduction achievable for such a facility,
taking into account energy, environment and
economic impacts and other costs.
Controlling GHG emissions under any
section of the Clean Air Act could
significantly increase the number of
stationary sources subject to PSD permitting.
Because CO2 is typically emitted in larger
quantities than criteria and other traditional
air pollutants from combustion sources,
facilities not previously subject to Clean Air
Act permitting—such as large commercial
and residential buildings heated by natural
gas boilers—could qualify as major stationary
sources for PSD purposes. In addition, some
small industrial sources not now covered by
PSD could be expected to become subject to
PSD due to their GHG emissions.
Currently, our best estimate of the potential
impact of including GHG in the PSD program
is that the number of PSD permits issued
annually nationwide could rise by an order
of magnitude above the current 200–300 a
year. Such estimates are subject to significant
uncertainty. At present, we do not have
comprehensive information on GHG
emissions from the many categories of
stationary sources of such emissions; instead
we have relied on available information and
general engineering estimates.
Such a broadening of the PSD program
could pose significant implementation issues
for covered facilities (particularly newly
covered facilities) and permitting agencies.
EPA is examining the scope of these potential
difficulties and whether, for GHG, the
program could be limited to larger sources,
at least temporarily, in view of the very
substantial increase in administrative burden
that might otherwise occur. However, at
present it is unclear as to whether EPA has
the legal discretion to exempt sources above
the statutory thresholds. In addition, EPA is
exploring concepts for streamlining
implementation of the PSD program for
smaller sources, such as guidance on general
permits or source definitions for BACT
determinations and model permits for use by
permitting agencies. EPA will address
permitting issues in greater detail in the
planned ANPR.
Given the complexity of PSD issues
arising from regulation of GHG
emissions, among other complex issues
of regulating a pollutant—particularly a
pollutant global in nature—for the first
time under the CAA, it is reasonable for
the Agency to proceed first by
evaluating these issues, and other
potential complexities, in the previously
announced ANPR rather than by taking
action to promulgate performance
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standards for GHG emissions in this
rulemaking.
In addition to the reasons set forth
above, it is appropriate for EPA to
decline to promulgate performance
standards for GHG emissions concurrent
with this 8-year review as section
111(b)(1)(B) does not require that the
Agency revise the standards when
essential information becomes available
too late in the review period. The 8-year
review provision itself conditions the
need to review a standard on ‘‘readily
available information on the efficacy of
such standard.’’ CAA section
111(b)(1)(B). The legislative history of
the 1970 CAA predecessor for the
review provision also states that the
review obligation depends on the
availability of ‘‘new technology
processes or operating methods.’’ 1970
Sen. Comm. Rep. at 17. Additionally,
the Massachusetts decision, which held
that GHG are air pollutants, was handed
down merely four weeks before the
court-ordered deadline to propose the
standards for this 8-year review period.
As explained above, section 111(b)(1)(B)
contemplates a two-year period for
NSPS promulgation, and, as noted
below, the consent decree under which
EPA was acting contemplated a twoand-a-half year period for this 8-year
review; hence, EPA did not have
sufficient time within this rulemaking
for proposing and promulgating
performance standards for GHG
emissions from refineries. The following
discussion provides more information
regarding the timeline of events for this
particular rulemaking’s review period.
EPA entered into a consent decree
with the Sierra Club and Our Children’s
Earth Foundation on October 31, 2005,
that required EPA to conduct its review
of 40 CFR part 60, subpart J and propose
revisions by April 30, 2007, and to
promulgate a final rule by April 30,
2008. EPA began its review of subpart
J and drafted a proposal package.
Shortly before EPA sent the proposed
rule package to OMB for its review, the
U.S. Supreme Court, on April 2, 2007,
issued its decision in Massachusetts v.
EPA, holding that GHG are air
pollutants under the CAA, and
remanding the case for the Agency to
take action consistent with the Court’s
opinion. Less than one month later, EPA
was obligated under the terms of its
consent decree to propose revisions to
subpart J by April 30, 2007; this
proposed rule did not include
performance standards for GHG
emissions. On August 27, 2007, EPA
received comments from Earthjustice
asserting that EPA, as part of its 8-year
review under section 111(b)(1)(B), must
promulgate GHG emissions limits for
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petroleum refineries. On September 14,
2007, the Massachusetts case was
officially remanded to the Agency by
the DC Circuit Court of Appeals. Under
the terms of the consent decree, EPA
was obligated to finalize its subpart J
revisions by April 30, 2008. Considering
this timeline of events, and the
complexities of the issues involved,
EPA would not have had sufficient time
during this particular 8-year review of
subpart J to propose and promulgate
GHG performance standards for
refineries even if the Agency had
deemed such action appropriate. As
explained above, the Agency will use
the information it gathers through the
ANPR for determining what may be
appropriate for future rulemakings.
V. Summary of Cost, Environmental,
Energy, and Economic Impacts
A. What are the impacts for petroleum
refinery process units?
We are presenting estimates of the
impacts for the final requirements of
subpart Ja that change the performance
standards for the following: (1) The
emission limits for fluid catalytic
cracking units, sulfur recovery plants,
fluid coking units, fuel gas combustion
devices, and process heaters; and (2) the
work practice standards for flares and
delayed coking units. The final
amendments to 40 CFR part 60, subpart
J are clarifications to the existing rule
and they have no emission reduction
impacts. The cost, environmental, and
economic impacts presented in this
section are expressed as incremental
differences between the impacts of
petroleum refinery process units
complying with the final subpart Ja and
the current NSPS requirements of
subpart J (i.e., baseline). The impacts are
presented for petroleum refinery process
units that commence construction,
reconstruction, or modification over the
next 5 years. The analyses and the
documents referenced below can be
found in Docket ID No. EPA–HQ–OAR–
2007–0011.
In order to determine the incremental
costs and emission reductions of this
final rule, we first estimated baseline
impacts. For new sources, baseline costs
and emission reductions were estimated
for complying with subpart J;
incremental impacts for subpart Ja were
estimated as the costs to comply with
subpart J subtracted from the costs to
comply with final subpart Ja. Sources
that are modified or reconstructed over
the next 5 years must comply with
subpart J in the absence of final subpart
Ja. Prior to reconstruction or
modification, these sources will either
be subject to a consent decree
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(equivalent to about 77 percent of the
industry by capacity), complying with
subpart J or equivalent limits, and/or
complying with 40 CFR part 63, subpart
UUU (MACT II). Baseline costs and
emission reductions were estimated as
the effort needed to comply with
subpart J from one of those three starting
points. The costs and emission
reductions to comply with final subpart
Ja were estimated from those starting
points as well. For further detail on the
methodology of these calculations, see
35861
amendments will reduce emissions of
PM by 1,300 tons/yr, SO2 by 17,000
tons/yr, NOX by 11,000 tons/yr, and
VOC by 200 tons/yr from the baseline.
The estimated increase in annual cost,
including annualized capital costs, is
about $31 million (2006 dollars). The
overall cost-effectiveness is about
$1,070 per ton of combined pollutants
removed. The estimated nationwide 5year incremental emissions reductions
and cost impacts for the final standards
are summarized in Table 19 of this
preamble.
Docket ID No. EPA–HQ–OAR–2007–
0011.
When considering and selecting
emission limits for the final rule, we
evaluated the cost-effectiveness of each
option for new sources separately from
reconstructed and modified sources. In
most cases, our selections for each
process unit and pollutant were
consistent for modified and
reconstructed units and new units. In
this section, we are presenting our costs
and emission reductions for the overall
rule. We estimate that the final
TABLE 19.—NATIONAL INCREMENTAL EMISSION REDUCTIONS AND COST IMPACTS FOR PETROLEUM REFINERY UNITS
SUBJECT TO FINAL STANDARDS UNDER 40 CFR PART 60, SUBPART JA (FIFTH YEAR AFTER PROPOSAL)
Process unit
Total capital
cost
($1,000)
Total annual
cost
($1,000/yr)
Annual
emission
reductions
(tons PM/yr)
Annual
emission
reductions
(tons NOX/yr)
Annual
emission
reductions
(tons SO2/yr)
Annual
emission
reductions
(tons VOC/yr)
Cost
effectiveness
($/ton)
8,500
14,000
1,700
6,400
4,000
730
240
1,000
........................
4,300
5,900
420
2,600
660
........................
........................
........................
........................
890
530
1,700
34,000
23,000
40,000
17,000
8,300
12,000
12,000
¥7,000
1,600
1,000
........................
........................
........................
........................
........................
5,200
........................
80
440
300
........................
7,500
6
........................
........................
........................
........................
200
25
........................
2,300
1,600
¥23,000
3,400
3,400
Total ......................
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FCCU ...........................
FCU ..............................
SRP ..............................
Fuel gas combustion
devices .....................
Process heaters ...........
Flaring ..........................
Delayed coking units ....
Sulfur pits .....................
150,000
31,100
1,300
17,000
11,000
1,400
1,070
B. What are the secondary impacts?
Indirect or secondary air quality
impacts of this final rule will result
from the increased electricity usage
associated with the operation of control
devices. If plants purchase electricity
from a power plant, we estimate that the
final standards will increase secondary
emissions of criteria pollutants,
including PM, SO2, NOX, and CO from
power plants. For new, modified or
reconstructed sources, this final rule
will increase secondary PM emissions
by 56 Megagrams per year (Mg/yr) (62
tons/yr); secondary SO2 emissions by
about 1,400 Mg/yr (1,500 tons/yr); and
secondary NOX emissions by about 530
Mg/yr (580 tons/yr) for the 5 years
following proposal.
As explained earlier, we expect that
affected facilities will control emissions
from fluid catalytic cracking units by
installing and operating ESP or wet gas
scrubbers. We also expect that the
emissions from the affected FCU will be
controlled with a wet scrubber. For
these process units, we estimated solid
waste impacts for both types of control
devices and water impacts for wet gas
scrubbers. In addition, the controls
needed by small sulfur recovery plants
will generate condensate. We project
that this final rule will generate 1.6
billion gallons of water per year for the
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5 years following proposal. We also
estimate that this final rule will generate
2,200 Mg/yr (2,400 tons/yr) of solid
waste over those 5 years.
Energy impacts as defined in this
preamble section consist of the
electricity and steam needed to operate
control devices and other equipment
that would be required under the final
rule. Our estimate of the increased
energy demand includes the electricity
needed to produce the required amounts
of steam as well as direct electricity
demand. We project that this final rule
will increase overall energy demand by
about 410 gigawatt-hours per year (1,400
billion British thermal units per year).
An analysis of energy impacts that
accounts for reactions in affected
markets to the costs of this final rule can
be found in the section on Executive
Order 13211 found later in this
preamble.
C. What are the economic impacts?
Our economic impact analysis
estimated the impacts on product price
and output that the final NSPS would
have on five petroleum products—
motor gasoline, jet fuel, distillate fuel
oil, residual fuel oil, and liquefied
petroleum gases. This analysis estimates
in the fifth year after proposal that the
price of these petroleum products will
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increase less than 0.01 percent
nationally along with a corresponding
reduction in output of less than 0.01
percent. The overall total annual social
costs, which reflect changes in
consumer and producer behavior in
response to the compliance costs, are
$27 million ($2006) in the fifth year
after proposal or almost identical to the
compliance costs incurred by affected
producers of these petroleum products.
For more information, please refer to
the regulatory impact analysis (RIA) that
is in the docket for this final rule.
D. What are the benefits?
We estimate the monetized benefits of
this final rule to be $220 million to $1.9
billion (2006$) in the fifth year after
proposal. We base the benefits estimate
derived from the PM2.5 and PM2.5
precursor emission reductions on the
approach and methodology laid out in
the Technical Support Document that
accompanied the recently completed
Regulatory Impact Analysis (RIA) for the
revision to the National Ambient Air
Quality Standard for Ground-level
Ozone (NAAQS), March 2008. We
generated estimates that represent the
total monetized human health benefits
(the sum of premature mortality and
premature morbidity) of reducing one
ton of PM2.5 and PM2.5 precursor
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emissions. A summary of the range of
benefits estimates at discount rates of
3% and 7% is in Table 20 of this
preamble.
TABLE 20.—SUMMARY OF THE RANGE OF BENEFITS ESTIMATES FOR FINAL REFINERIES NSPS
Monetized benefits
per ton emission
reduction
(7% discount)
Direct PM2.5 ............................................
$68,000 to
$570,000.
$8,000 to $68,000
$1,300 to $11,000
$210 to $1,700 ......
$7,400 to $62,000
$1,200 to $9,600 ...
$190 to $1,500 ......
Total monetized
benefits (millions of
2006 dollars,
7% discount) 1
$72 to $600 ...........
$66 to $540.
16,714
10,786
230
Grand total
$130 to $1,100 ......
$14 to $110 ...........
$0.05 to $.38 .........
$220 to $1,900 ......
$120 to $1,000.
$13 to $100.
$0.04 to $.35.
$200 to $1,700.
$63,000 to
$520,000.
PM2.5 Precursor:
SO2 ..................................................
NOX .................................................
VOC .................................................
Total monetized
benefits (millions of
2006 dollars,
3% discount) 1
1,054
Monetized benefits
per ton emission
reduction
(3% discount)
Pollutant
Emission
reductions
(tons)
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1 All estimates are for the analysis year (fifth year after proposal, 2012), and are rounded to two significant figures so numbers may not sum
across columns. Emission reductions reflect the combination of selected options for both new and reconstructed/modified sources. The PM2.5
fraction of total PM emissions is estimated at 83.3%, and only the reduction in the PM2.5 fraction is monetized in this analysis. All fine particles
are assumed to have equivalent health effects, but the benefit per ton estimates vary because each ton of precursor reduced has a different propensity to become PM2.5. The monetized benefits incorporate the conversion from precursor emissions to ambient fine particles.
The specific estimates of benefits per
ton of pollutant reductions included in
this analysis are largely driven by the
concentration response function for
premature mortality, which is based on
the PM Expert Elicitation study
(Industrial Economics, Inc., September
2006. Expanded Expert Judgment
Assessment of the ConcentrationResponse Relationship Between PM2.5
Exposure and Mortality. Prepared for
the U.S. EPA, Office of Air Quality
Planning and Standards). The preamble
for the proposal indicated that EPA
would update the benefits estimates to
incorporate the results of the expert
elicitation for the final rule, and we
have done so. The range of benefits
estimates presented above represents
the range from the lowest expert
estimate to the highest expert estimate
to characterize the uncertainty in the
concentration response function. To
generate the benefit-per-ton estimates,
we used a model to convert emissions
of direct PM2.5 and PM2.5 precursors into
changes in PM2.5 air quality and another
model to estimate the changes in human
health based on that change in air
quality. Finally, the monetized health
benefits were divided by the emission
reductions to create the benefit-per-ton
estimates. Even though all fine particles
are assumed to have equivalent health
effects, the benefit-per-ton estimates
vary because each ton of precursor
reduced has a different propensity to
become PM2.5. For example, NOX has a
lower benefit-per-ton estimate than
direct PM2.5 because it does not form as
much PM2.5, thus the exposure would be
lower, and the monetized health
benefits would be lower.
This analysis does not include the
type of detailed uncertainty assessment
found in the PM NAAQS RIA because
we lack the necessary air quality input
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and monitoring data to run the benefits
model. However, the 2006 PM NAAQS
analysis provides an indication of the
sensitivity of our results to the use of
alternative concentration response
functions, including those derived from
the PM expert elicitation study.
The annualized costs of this
rulemaking are estimated at $31 million
(2006 dollars) in the fifth year after
proposal, and the benefits are estimated
at $220 million to $1.9 billion (2006
dollars) for that same year. Thus, net
benefits of this rulemaking are estimated
at $190 million to $1.8 billion (2006
dollars). EPA believes that the benefits
are likely to exceed the costs by a
significant margin even when taking
into account the uncertainties in the
cost and benefit estimates. It should be
noted that the range of benefits
estimates provided above does not
include ozone-related benefits from the
reductions in VOC and NOX emissions
expected to occur as a result of this final
rule, nor does this range include
benefits from the portion of total PM
emissions reduction that is not PM2.5.
We do not have sufficient information
or modeling available to provide such
estimates for this rulemaking. For more
information, please refer to the RIA for
this final rule that is available in the
docket.
VI. Statutory and Executive Order
Reviews
A. Executive Order 12866: Regulatory
Planning and Review
Under section 3(f)(1) of Executive
Order 12866 (58 FR 51735, October 4,
1993), this action is an ‘‘economically
significant regulatory action’’ because it
is likely to have an annual effect on the
economy of $100 million or more.
Accordingly, EPA submitted this action
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to the Office of Management and Budget
(OMB) for review under Executive
Order 12866 and any changes made in
response to OMB recommendations
have been documented in the docket for
this action.
In addition, EPA prepared an analysis
of the potential costs and benefits
associated with this action. This
analysis is contained in the RIA for the
Final Petroleum Refinery NSPS. A copy
of the analysis is available in the docket
for this action and the analysis is briefly
summarized here. The monetized
benefits of this action are estimated as
a range from $220 million to $1.9 billion
(2006 dollars), and the annualized costs
of this action are $31.1 million (2006
dollars). We also estimated the
economic impacts, small business
impacts, and energy impacts associated
with this action. These analyses are
included in the RIA and are
summarized elsewhere in this preamble.
B. Paperwork Reduction Act
The final amendments to the
standards of performance for petroleum
refineries (40 CFR part 60, subpart J) do
not impose any new information
collection burden. The final
amendments add a monitoring
exemption for fuel gas streams
combusted in a fuel gas combustion
device that are inherently low in sulfur
content. The exemption applies to fuel
gas streams that meet specified criteria
or that the owner or operator
demonstrates are low sulfur according
to the rule requirements. The owner or
operator is required to submit a written
application for the exemption
containing information needed to
document the low sulfur content. The
application is not a mandatory
requirement and the incremental
reduction in monitoring burden that
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will occur as a result of the exemption
is not significant compared to the
baseline burden estimates for the
existing rule. Therefore, we have not
revised the information collection
request (ICR) for the existing rule.
However, OMB has previously approved
the information collection requirements
in the existing rule (40 CFR part 60,
subpart J) under the provisions of the
Paperwork Reduction Act, 44 U.S.C.
3501, et seq., and has assigned OMB
control number 2060–0022, EPA ICR
number 1054.09. The OMB control
numbers for EPA’s regulations are listed
in 40 CFR part 9.
The information collection
requirements in the final standards of
performance for petroleum refineries (40
CFR part 60, subpart Ja) have been
submitted for approval to OMB under
the Paperwork Reduction Act, 44 U.S.C.
3501, et seq. The information collection
requirements are not enforceable until
OMB approves them.
The information collection
requirements in this final rule are
needed by the Agency to determine
compliance with the standards. These
requirements are based on
recordkeeping and reporting
requirements in the NSPS General
Provisions in 40 CFR part 60, subpart A,
and on specific requirements in subpart
J or subpart Ja which are mandatory for
all operators subject to new source
performance standards. These
recordkeeping and reporting
requirements are specifically authorized
by section 114 of the CAA (42 U.S.C.
7414). All information submitted to EPA
pursuant to the recordkeeping and
reporting requirements for which a
claim of confidentiality is made is
safeguarded according to EPA policies
set forth in 40 CFR part 2, subpart B.
The final standards of performance for
petroleum refineries include work
practice requirements for delayed
coking reactor vessel depressuring and
written plans to minimize emissions
from flares. Plants also are required to
analyze the cause of any exceedance
that releases more than 500 pounds per
day of SO2 from an affected fuel gas
combustion device. The final standards
also include testing, monitoring,
recordkeeping, and reporting
provisions. Monitoring requirements
include control device operating
parameters, bag leak detection systems,
or CEMS, depending on the type of
process, pollutant, and control device.
Exemptions are also included for small
emitters.
The annual burden for this
information collection averaged over the
first 3 years of this ICR is estimated to
total 5,340 labor-hours per year at a cost
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of $481,249 per year. The annualized
capital costs are estimated at $2,052,000
per year and operation and maintenance
costs are estimated at $1,117,440 per
year. We note that the capital costs as
well as the operation and maintenance
costs are for the continuous monitors;
these costs are also included in the cost
impacts presented in section V.A of this
preamble. Therefore, the burden costs
associated with the continuous monitors
presented in the ICR are not additional
costs incurred by affected sources
subject to final subpart Ja. Burden is
defined at 5 CFR 1320.3(b).
An agency may not conduct or
sponsor, and a person is not required to
respond to a collection of information
unless it displays a currently valid OMB
control number. The OMB control
numbers for EPA’s regulations are listed
in 40 CFR part 9. When this ICR is
approved by OMB, the Agency will
publish a technical amendment to 40
CFR part 9 in the Federal Register to
display the OMB control number for the
approved information collection
requirements contained in this final
rule.
C. Regulatory Flexibility Act
The Regulatory Flexibility Act (RFA)
generally requires an agency to prepare
a regulatory flexibility analysis of any
rule subject to notice and comment
rulemaking requirements under the
Administrative Procedure Act or any
other statute unless the agency certifies
that the rule will not have a significant
economic impact on a substantial
number of small entities. Small entities
include small businesses, small
organizations, and small governmental
jurisdictions.
For purposes of assessing the impact
of this final action on small entities,
small entity is defined as: (1) A small
business whose parent company has no
more than 1,500 employees, depending
on the size definition for the affected
NAICS code (as defined by Small
Business Administration (SBA) size
standards); (2) a small governmental
jurisdiction that is a government of a
city, county, town, school district, or
special district with a population of less
than 50,000; and (3) a small
organization that is any not-for-profit
enterprise which is independently
owned and operated and is not
dominant in its field.
After considering the economic
impact of this final rule on small
entities, I certify that this action will not
have a significant economic impact on
a substantial number of small entities.
The small entities directly regulated by
the current standards of performance for
petroleum refineries are small refineries.
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35863
After reviewing the small business
analysis for the proposed NSPS, we
realized that we inadvertently used the
capacity limit of 125,000 barrels/day
production as part of the small business
size standard to evaluate the impacts on
small refiners; the definition that should
have been used is 1,500 employees for
an ultimate parent entity with no
capacity limit in the United States. The
effect of this change in the small
business size standard for this analysis
is one additional small refiner. This
change in the small business size
standard does not lead to any effect on
the certification that there is no
significant economic impact on a
substantial number of small entities
resulting from today’s action. We have
determined that, of the 58 entities that
are in the affected industry, 25 of these
(or 43 percent) are classified as small
according to the SBA small business
size standard listed previously. Of these
25 affected entities, three are expected
to be affected by today’s action. None of
these three small entities is expected to
incur an annualized compliance cost of
more than 1.0 percent to comply with
this final action. For more information,
please refer to the economic impact
analysis that is in the public docket for
this rulemaking.
Although this final action will not
have a significant economic impact on
a substantial number of small entities,
EPA nonetheless has tried to reduce the
impact of this final action on small
entities by incorporating specific
standards for small sulfur recovery
plants and streamlining procedures for
exempting inherently low-sulfur fuel
gases from continuous monitoring.
D. Unfunded Mandates Reform Act
Title II of the Unfunded Mandates
Reform Act (UMRA) of 1995, Public
Law 104–4, establishes requirements for
Federal agencies to assess the effects of
their regulatory actions on State, local,
and tribal governments and the private
sector. Under section 202 of the UMRA,
EPA generally must prepare a written
statement, including a cost-benefit
analysis, for proposed and final rules
with ‘‘Federal mandates’’ that may
result in expenditures by State, local,
and tribal governments, in the aggregate,
or to the private sector, of $100 million
or more in any one year. Before
promulgating an EPA rule for which a
written statement is needed, section 205
of the UMRA generally requires EPA to
identify and consider a reasonable
number of regulatory alternatives and
adopt the least costly, most costeffective, or least burdensome
alternative that achieves the objectives
of the rule. The provisions of section
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205 do not apply when they are
inconsistent with applicable law.
Moreover, section 205 allows EPA to
adopt an alternative other than the least
costly, most cost-effective, or least
burdensome alternative if the
Administrator publishes with the final
rule an explanation why that alternative
was not adopted. Before EPA establishes
any regulatory requirements that may
significantly or uniquely affect small
governments, including tribal
governments, it must have developed
under section 203 of the UMRA a small
government agency plan. The plan must
provide for notifying potentially
affected small governments, enabling
officials of affected small governments
to have meaningful and timely input in
the development of EPA regulatory
proposals with significant Federal
intergovernmental mandates, and
informing, educating, and advising
small governments on compliance with
the regulatory requirements.
EPA has determined that this final
action does not contain a Federal
mandate that may result in expenditures
of $100 million or more for State, local,
and tribal governments, in the aggregate,
or the private sector in any one year. As
discussed earlier in this preamble, the
estimated expenditures for the private
sector in the fifth year after proposal are
an annualized cost of $31.1 million
(2006 dollars). Thus, this final action is
not subject to the requirements of
section 202 and 205 of the UMRA. In
addition, EPA has determined that this
final action contains no regulatory
requirements that might significantly or
uniquely affect small governments. This
final action contains no requirements
that apply to such governments,
imposes no obligations upon them, and
would not result in expenditures by
them of $100 million or more in any one
year or any disproportionate impacts on
them. Therefore, this final action is not
subject to the requirements of section
203 of the UMRA.
E. Executive Order 13132: Federalism
Executive Order 13132 (64 FR 43255,
August 10, 1999), requires EPA to
develop an accountable process to
ensure ‘‘meaningful and timely input by
State and local officials in the
development of regulatory policies that
have federalism implications.’’ ‘‘Policies
that have federalism implications’’ is
defined in the Executive Order to
include regulations that have
‘‘substantial direct effects on the States,
on the relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government.’’
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This final action does not have
federalism implications. It will not have
substantial direct effects on the States,
on the relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government, as specified in
Executive Order 13132. None of the
affected facilities are owned or operated
by State governments. Thus, Executive
Order 13132 does not apply to this final
action.
F. Executive Order 13175: Consultation
and Coordination With Indian Tribal
Governments
Executive Order 13175 (65 FR 67249,
November 9, 2000) requires EPA to
develop an accountable process to
ensure ‘‘meaningful and timely input by
tribal officials in the development of
regulatory policies that have tribal
implications.’’ This final action does not
have tribal implications, as specified in
Executive Order 13175. It will not have
substantial direct effects on tribal
governments, on the relationship
between the Federal government and
Indian tribes, or on the distribution of
power and responsibilities between the
Federal government and Indian tribes,
as specified in Executive Order 13175.
The final rules impose requirements on
owners and operators of specified
industrial facilities and not tribal
governments. Thus, Executive Order
13175 does not apply to this final
action.
G. Executive Order 13045: Protection of
Children From Environmental Health
Risks and Safety Risks
EPA interprets Executive Order 13045
(62 FR 19885, April 23, 1997) as
applying to those regulatory actions that
concern health or safety risks, such that
the analysis required under section 5–
501 of the Executive Order has the
potential to influence the regulation.
This action is not subject to Executive
Order 13045 because it is based solely
on technology performance.
H. Executive Order 13211: Actions
Concerning Regulations That
Significantly Affect Energy Supply,
Distribution, or Use
This rule is not a ‘‘significant energy
action’’ as defined in Executive Order
13211, ‘‘Actions Concerning Regulations
That Significantly Affect Energy Supply,
Distribution, or Use’’ (66 FR 28355, May
22, 2001) because it is not likely to have
a significant adverse effect on the
supply, distribution, or use of energy.
We prepared an analysis of the impacts
on energy markets as part of our RIA for
this final action. This analysis accounts
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for the increase in electricity generation
occurring due to additional control
requirements associated with this final
action. Our analysis shows that there is
a reduction in gasoline output of less
than 0.75 million gallons per year, or
less than 50 barrels of gasoline
production per day in the fifth year after
proposal of this final action. In addition,
our analysis shows that there is no
increase in gasoline prices in the fifth
year after proposal of this final action.
With no increase in domestic gasoline
prices, no significant increase in our
dependence on foreign energy supplies
should take place. Finally, this final
action will have no adverse effect on
crude oil supply, coal production,
electricity production, and energy
distribution. Further, we conclude that
this final action is not likely to have any
adverse energy effects. For more
information on this analysis, please
refer to the RIA available in the docket
for this rulemaking.
I. National Technology Transfer and
Advancement Act
Section 12(d) of the National
Technology Transfer and Advancement
Act of 1995 (‘‘NTTAA’’), Public Law No.
104–113 (15 U.S.C. 272 note) directs
EPA to use voluntary consensus
standards (VCS) in its regulatory
activities unless to do so would be
inconsistent with applicable law or
otherwise impractical. Voluntary
consensus standards are technical
standards (e.g., materials specifications,
test methods, sampling procedures, and
business practices) that are developed or
adopted by VCS bodies. NTTAA directs
EPA to provide Congress, through OMB,
explanations when the Agency decides
not to use available and applicable VCS.
This rulemaking involves technical
standards. EPA has decided to use the
VCS ANSI/ASME PTC 19.10–1981,
‘‘Flue and Exhaust Gas Analyses,’’ for
its manual methods of measuring the
content of the exhaust gas. These parts
of ANSI/ASME PTC 19.10–1981 are
acceptable alternatives to EPA Methods
3B, 6, 6A, 7, 7C, and 15A. This standard
is available from the American Society
of Mechanical Engineers (ASME), Three
Park Avenue, New York, NY 10016–
5990.
The EPA has also decided to use EPA
methods 1, 2, 3, 3A, 3B, 5, 5B, 5F, 5I,
6, 6A, 6C, 7, 7A, 7C, 7D, 7E, 10, 10A,
10B, 11, 15, 15A, 16, and 17 (40 CFR
part 60, Appendices A–1 through A6);
Performance Specifications 1, 2, 3, 4,
4A, 5, 7, and 11 (40 CFR part 60,
Appendix B); quality assurance
procedures in 40 CFR part 60, Appendix
F; and the Gas Processors Association
Standard 2377–86, ‘‘Test for Hydrogen
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Sulfide and Carbon Dioxide in Natural
Gas Using Length of Stain Tubes,’’ 1986
Revision. While the Agency has
identified 22 VCS as being potentially
applicable to this rule, we have decided
not to use these VCS in this rulemaking.
The use of these VCS would have been
impractical because they do not meet
the objectives of the standards cited in
this rule. See the docket for this rule for
the reasons for these determinations.
Under 40 CFR 60.13(i) of the NSPS
General Provisions, a source may apply
to EPA for permission to use alternative
test methods or alternative monitoring
requirements in place of any required
testing methods, performance
specifications, or procedures in the final
rule and amendments.
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J. Executive Order 12898: Federal
Actions To Address Environmental
Justice in Minority Populations and
Low-Income Populations
Executive Order 12898 (59 FR 7629,
February 16, 1994) establishes Federal
executive policy on environmental
justice. Its main provision directs
Federal agencies, to the greatest extent
practicable and permitted by law, to
make environmental justice part of their
mission by identifying and addressing,
as appropriate, disproportionately high
and adverse human health or
environmental effects of their programs,
policies, and activities on minority
populations and low-income
populations in the United States. EPA
has determined that these final
amendments to 40 CFR part 60, subpart
J will not have disproportionately high
and adverse human health or
environmental effects on minority or
low-income populations because they
do not affect the level of protection
provided to human health or the
environment. The final amendments are
clarifications which do not relax the
control measures on sources regulated
by the rule and, therefore, will not cause
emissions increases from these sources.
K. Congressional Review Act
The Congressional Review Act, 5
U.S.C. 801, et seq., as added by the
Small Business Regulatory Enforcement
Fairness Act of 1996, generally provides
that before a rule may take effect the
agency promulgating the rule must
submit a rule report, which includes a
copy of the rule, to each House of
Congress and to the Comptroller General
of the United States. The EPA will
submit a report containing these final
rules and other required information to
the U.S. Senate, the U.S. House of
Representatives, and the Comptroller
General of the United States prior to
publication of the final rules in the
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Federal Register. A major rule cannot
take effect until 60 days after it is
published in the Federal Register. This
action is not a ‘‘major rule’’ as defined
by 5 U.S.C. 804(2). This final rule will
be effective on June 24, 2008.
List of Subjects in 40 CFR Part 60
Environmental protection,
Administrative practice and procedure,
Air pollution control, Incorporations by
reference, Intergovernmental relations,
Reporting and recordkeeping
requirements.
Dated: April 30, 2008.
Stephen L. Johnson,
Administrator.
For the reasons stated in the preamble,
title 40, chapter I of the Code of Federal
Regulations is amended as follows:
I
PART 60—[AMENDED]
1. The authority citation for part 60
continues to read as follows:
I
Authority: 42 U.S.C. 7401, et seq.
Subpart A—[Amended]
2. Section 60.17 is amended by:
a. Revising paragraph (h)(4),
I b. Revising the last sentence of
paragraph (m) introductory text, and
I c. Revising paragraph (m)(1) to read as
follows:
I
I
§ 60.17
Incorporations by reference.
*
*
*
*
*
(h) * * *
(4) ANSI/ASME PTC 19.10–1981,
Flue and Exhaust Gas Analyses [Part 10,
Instruments and Apparatus], IBR
approved for § 60.106(e)(2) of subpart J,
§§ 60.104a(d)(3), (d)(5), (d)(6), (h)(3),
(h)(4), (h)(5), (i)(3), (i)(4), (i)(5), (j)(3),
and (j)(4), 60.105a(d)(4), (f)(2), (f)(4),
(g)(2), and (g)(4), 60.106a(a)(1)(iii),
(a)(2)(iii), (a)(2)(v), (a)(2)(viii), (a)(3)(ii),
and (a)(3)(v), and 60.107a(a)(1)(ii),
(a)(1)(iv), (a)(2)(ii), (c)(2), (c)(4), and
(d)(2) of subpart Ja, Tables 1 and 3 of
subpart EEEE, Tables 2 and 4 of subpart
FFFF, Table 2 of subpart JJJJ, and
§§ 60.4415(a)(2) and 60.4415(a)(3) of
subpart KKKK of this part.
*
*
*
*
*
(m) * * * You may inspect a copy at
EPA’s Air and Radiation Docket and
Information Center, Room 3334, 1301
Constitution Ave., NW., Washington,
DC 20460.
(1) Gas Processors Association
Standard 2377–86, Test for Hydrogen
Sulfide and Carbon Dioxide in Natural
Gas Using Length of Stain Tubes, 1986
Revision, IBR approved for
§§ 60.105(b)(1)(iv), 60.107a(b)(1)(iv),
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35865
60.334(h)(1), 60.4360, and
60.4415(a)(1)(ii).
*
*
*
*
*
Subpart J—[Amended]
3. Section 60.100 is amended by
revising the first sentence in paragraph
(a) and revising paragraphs (b) through
(d) to read as follows:
I
§ 60.100 Applicability, designation of
affected facility, and reconstruction.
(a) The provisions of this subpart are
applicable to the following affected
facilities in petroleum refineries: fluid
catalytic cracking unit catalyst
regenerators, fuel gas combustion
devices, and all Claus sulfur recovery
plants except Claus plants with a design
capacity for sulfur feed of 20 long tons
per day (LTD) or less. * * *
(b) Any fluid catalytic cracking unit
catalyst regenerator or fuel gas
combustion device under paragraph (a)
of this section other than a flare as
defined in § 60.101a which commences
construction, reconstruction, or
modification after June 11, 1973, and on
or before May 14, 2007, or any fuel gas
combustion device under paragraph (a)
of this section that meets the definition
of a flare as defined in § 60.101a which
commences construction,
reconstruction, or modification after
June 11, 1973, and on or before June 24,
2008, or any Claus sulfur recovery plant
under paragraph (a) of this section
which commences construction,
reconstruction, or modification after
October 4, 1976, and on or before May
14, 2007, is subject to the requirements
of this subpart except as provided under
paragraphs (c) and (d) of this section.
(c) Any fluid catalytic cracking unit
catalyst regenerator under paragraph (b)
of this section which commences
construction, reconstruction, or
modification on or before January 17,
1984, is exempted from § 60.104(b).
(d) Any fluid catalytic cracking unit
in which a contact material reacts with
petroleum derivatives to improve
feedstock quality and in which the
contact material is regenerated by
burning off coke and/or other deposits
and that commences construction,
reconstruction, or modification on or
before January 17, 1984, is exempt from
this subpart.
*
*
*
*
*
I 4. Section 60.101 is amended by
revising paragraph (d) to read as
follows:
§ 60.101
Definitions.
*
*
*
*
*
(d) Fuel gas means any gas which is
generated at a petroleum refinery and
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which is combusted. Fuel gas also
includes natural gas when the natural
gas is combined and combusted in any
proportion with a gas generated at a
refinery. Fuel gas does not include gases
generated by catalytic cracking unit
catalyst regenerators and fluid coking
burners. Fuel gas does not include
vapors that are collected and combusted
to comply with the wastewater
provisions in § 60.692, 40 CFR 61.343
through 61.348, or 40 CFR 63.647, or the
marine tank vessel loading provisions in
40 CFR 63.562 or 40 CFR 63.651.
*
*
*
*
*
I 5. Section 60.102 is amended by
revising paragraph (b) to read as follows:
§ 60.102
Standard for particulate matter.
*
*
*
*
*
(b) Where the gases discharged by the
fluid catalytic cracking unit catalyst
regenerator pass through an incinerator
or waste heat boiler in which auxiliary
or supplemental liquid or solid fossil
fuel is burned, particulate matter in
excess of that permitted by paragraph
(a)(1) of this section may be emitted to
the atmosphere, except that the
incremental rate of particulate matter
emissions shall not exceed 43 grams per
Gigajoule (g/GJ) (0.10 lb/million British
thermal units (Btu)) of heat input
attributable to such liquid or solid fossil
fuel.
I 6. Section 60.104 is amended by
revising paragraphs (b)(1) and (b)(2) to
read as follows:
§ 60.104
Standards for sulfur oxides.
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*
*
*
*
*
(b) * * *
(1) With an add-on control device,
reduce SO2 emissions to the atmosphere
by 90 percent or maintain SO2
emissions to the atmosphere less than or
equal to 50 ppm by volume (ppmv),
whichever is less stringent; or
(2) Without the use of an add-on
control device to reduce SO2 emissions,
maintain sulfur oxides emissions
calculated as SO2 to the atmosphere less
than or equal to 9.8 kg/Mg (20 lb/ton)
coke burn-off; or
*
*
*
*
*
I 7. Section 60.105 is amended by:
I a. Revising the first sentence of
paragraph (a)(3) introductory text;
I b. Revising paragraph (a)(3)(iv);
I c. Revising paragraph (a)(4)
introductory text;
I d. Adding paragraph (a)(4)(iv);
I e. Revising paragraph (a)(8)
introductory text;
I f. Revising paragraph (a)(8)(i); and
I g. Adding paragraph (b) to read as
follows:
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§ 60.105 Monitoring of emissions and
operations.
(a) * * *
(3) For fuel gas combustion devices
subject to § 60.104(a)(1), either an
instrument for continuously monitoring
and recording the concentration by
volume (dry basis, zero percent excess
air) of SO2 emissions into the
atmosphere or monitoring as provided
in paragraph (a)(4) of this
section). * * *
*
*
*
*
*
(iv) Fuel gas combustion devices
having a common source of fuel gas may
be monitored at only one location (i.e.,
after one of the combustion devices), if
monitoring at this location accurately
represents the SO2 emissions into the
atmosphere from each of the
combustion devices.
(4) Instead of the SO2 monitor in
paragraph (a)(3) of this section for fuel
gas combustion devices subject to
§ 60.104(a)(1), an instrument for
continuously monitoring and recording
the concentration (dry basis) of H2S in
fuel gases before being burned in any
fuel gas combustion device.
*
*
*
*
*
(iv) The owner or operator of a fuel
gas combustion device is not required to
comply with paragraph (a)(3) or (4) of
this section for fuel gas streams that are
exempt under § 60.104(a)(1) and fuel gas
streams combusted in a fuel gas
combustion device that are inherently
low in sulfur content. Fuel gas streams
meeting one of the requirements in
paragraphs (a)(4)(iv)(A) through (D) of
this section will be considered
inherently low in sulfur content. If the
composition of a fuel gas stream
changes such that it is no longer exempt
under § 60.104(a)(1) or it no longer
meets one of the requirements in
paragraphs (a)(4)(iv)(A) through (D) of
this section, the owner or operator must
begin continuous monitoring under
paragraph (a)(3) or (4) of this section
within 15 days of the change.
(A) Pilot gas for heaters and flares.
(B) Fuel gas streams that meet a
commercial-grade product specification
for sulfur content of 30 ppmv or less. In
the case of a liquefied petroleum gas
(LPG) product specification in the
pressurized liquid state, the gas phase
sulfur content should be evaluated
assuming complete vaporization of the
LPG and sulfur containing-compounds
at the product specification
concentration.
(C) Fuel gas streams produced in
process units that are intolerant to
sulfur contamination, such as fuel gas
streams produced in the hydrogen plant,
the catalytic reforming unit, the
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isomerization unit, and HF alkylation
process units.
(D) Other fuel gas streams that an
owner or operator demonstrates are lowsulfur according to the procedures in
paragraph (b) of this section.
*
*
*
*
*
(8) An instrument for continuously
monitoring and recording
concentrations of SO2 in the gases at
both the inlet and outlet of the SO2
control device from any fluid catalytic
cracking unit catalyst regenerator for
which the owner or operator seeks to
comply specifically with the 90 percent
reduction option under § 60.104(b)(1).
(i) The span value of the inlet monitor
shall be set at 125 percent of the
maximum estimated hourly potential
SO2 emission concentration entering the
control device, and the span value of the
outlet monitor shall be set at 50 percent
of the maximum estimated hourly
potential SO2 emission concentration
entering the control device.
*
*
*
*
*
(b) An owner or operator may
demonstrate that a fuel gas stream
combusted in a fuel gas combustion
device subject to § 60.104(a)(1) that is
not specifically exempted in
§ 60.105(a)(4)(iv) is inherently low in
sulfur. A fuel gas stream that is
determined to be low-sulfur is exempt
from the monitoring requirements in
paragraphs (a)(3) and (4) of this section
until there are changes in operating
conditions or stream composition.
(1) The owner or operator shall
submit to the Administrator a written
application for an exemption from
monitoring. The application must
contain the following information:
(i) A description of the fuel gas
stream/system to be considered,
including submission of a portion of the
appropriate piping diagrams indicating
the boundaries of the fuel gas stream/
system, and the affected fuel gas
combustion device(s) to be considered;
(ii) A statement that there are no
crossover or entry points for sour gas
(high H2S content) to be introduced into
the fuel gas stream/system (this should
be shown in the piping diagrams);
(iii) An explanation of the conditions
that ensure low amounts of sulfur in the
fuel gas stream (i.e., control equipment
or product specifications) at all times;
(iv) The supporting test results from
sampling the requested fuel gas stream/
system demonstrating that the sulfur
content is less than 5 ppmv. Sampling
data must include, at minimum, 2
weeks of daily monitoring (14 grab
samples) for frequently operated fuel gas
streams/systems; for infrequently
operated fuel gas streams/systems,
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seven grab samples must be collected
unless other additional information
would support reduced sampling. The
owner or operator shall use detector
tubes (‘‘length-of-stain tube’’ type
measurement) following the ‘‘Gas
Processors Association Standard 2377–
86, Test for Hydrogen Sulfide and
Carbon Dioxide in Natural Gas Using
Length of Stain Tubes,’’ 1986 Revision
(incorporated by reference—see § 60.17),
with ranges 0–10/0–100 ppm (N = 10/
1) to test the applicant fuel gas stream
for H2S; and
(v) A description of how the 2 weeks
(or seven samples for infrequently
operated fuel gas streams/systems) of
monitoring results compares to the
typical range of H2S concentration (fuel
quality) expected for the fuel gas
stream/system going to the affected fuel
gas combustion device (e.g., the 2 weeks
of daily detector tube results for a
frequently operated loading rack
included the entire range of products
loaded out, and, therefore, should be
representative of typical operating
conditions affecting H2S content in the
fuel gas stream going to the loading rack
flare).
(2) The effective date of the
exemption is the date of submission of
the information required in paragraph
(b)(1) of this section).
(3) No further action is required
unless refinery operating conditions
change in such a way that affects the
exempt fuel gas stream/system (e.g., the
stream composition changes). If such a
change occurs, the owner or operator
will follow the procedures in paragraph
(b)(3)(i), (b)(3)(ii), or (b)(3)(iii) of this
section.
(i) If the operation change results in
a sulfur content that is still within the
range of concentrations included in the
original application, the owner or
operator shall conduct an H2S test on a
grab sample and record the results as
proof that the concentration is still
within the range.
(ii) If the operation change results in
a sulfur content that is outside the range
of concentrations included in the
original application, the owner or
operator may submit new information
following the procedures of paragraph
(b)(1) of this section within 60 days (or
within 30 days after the seventh grab
sample is tested for infrequently
operated process units).
(iii) If the operation change results in
a sulfur content that is outside the range
of concentrations included in the
original application and the owner or
operator chooses not to submit new
information to support an exemption,
the owner or operator must begin H2S
monitoring using daily stain sampling to
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Jkt 214001
demonstrate compliance. The owner or
operator must begin monitoring
according to the requirements in
paragraphs (a)(1) or (a)(2) of this section
as soon as practicable but in no case
later than 180 days after the operation
change. During daily stain tube
sampling, a daily sample exceeding 162
ppmv is an exceedance of the 3-hour
H2S concentration limit. The owner or
operator must determine a rolling 365day average using the stain sampling
results; an average H2S concentration of
5 ppmv must be used for days prior to
the operation change.
*
*
*
*
*
I 8. Section 60.106 is amended by
revising paragraph (b)(3) introductory
text and revising the first sentence of
paragraph (e)(2) to read as follows:
§ 60.106
Test methods and procedures.
*
*
*
*
*
(b) * * *
(3) The coke burn-off rate (Rc) shall be
computed for each run using the
following equation:
Rc = K1Qr (%CO2 + %CO) + K2Qa¥K3Qr
(%CO/2 + %CO2 + %O2) + K3Qoxy
(%Ooxy)
Where:
Rc = Coke burn-off rate, kilograms per hour
(kg/hr) (lb/hr).
Qr = Volumetric flow rate of exhaust gas from
fluid catalytic cracking unit regenerator
before entering the emission control
system, dscm/min (dscf/min).
Qa = Volumetric flow rate of air to fluid
catalytic cracking unit regenerator, as
determined from the fluid catalytic
cracking unit control room
instrumentation, dscm/min (dscf/min).
Qoxy = Volumetric flow rate of O2 enriched
air to fluid catalytic cracking unit
regenerator, as determined from the fluid
catalytic cracking unit control room
instrumentation, dscm/min (dscf/min).
%CO2 = Carbon dioxide concentration in
fluid catalytic cracking unit regenerator
exhaust, percent by volume (dry basis).
%CO = CO concentration in FCCU
regenerator exhaust, percent by volume
(dry basis).
%O2 = O2 concentration in fluid catalytic
cracking unit regenerator exhaust,
percent by volume (dry basis).
%Ooxy = O2 concentration in O2 enriched air
stream inlet to the fluid catalytic
cracking unit regenerator, percent by
volume (dry basis).
K1 = Material balance and conversion factor,
0.2982 (kg-min)/(hr-dscm-%) [0.0186 (lbmin)/(hr-dscf-%)].
K2 = Material balance and conversion factor,
2.088 (kg-min)/(hr-dscm) [0.1303 (lbmin)/(hr-dscf)].
K3 = Material balance and conversion factor,
0.0994 (kg-min)/(hr-dscm-%) [0.00624
(lb-min)/(hr-dscf-%)].
*
*
*
(e) * * *
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*
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35867
(2) Where emissions are monitored by
§ 60.105(a)(3), compliance with
§ 60.104(a)(1) shall be determined using
Method 6 or 6C and Method 3 or 3A.
The method ANSI/ASME PTC 19.10–
1981, ‘‘Flue and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 6. * * *
*
*
*
*
*
I 9. Section 60.107 is amended by:
I a. Revising the first sentence of
paragraph (c)(1)(i);
I b. Redesignating paragraphs (e) and (f)
as (f) and (g); and
I c. Adding paragraph (e) to read as
follows:
§ 60.107 Reporting and recordkeeping
requirements.
*
*
*
*
*
(c) * * *
(1) * * *
(i) The average percent reduction and
average concentration of sulfur dioxide
on a dry, O2-free basis in the gases
discharged to the atmosphere from any
fluid cracking unit catalyst regenerator
for which the owner or operator seeks
to comply with § 60.104(b)(1) is below
90 percent and above 50 ppmv, as
measured by the continuous monitoring
system prescribed under § 60.105(a)(8),
or above 50 ppmv, as measured by the
outlet continuous monitoring system
prescribed under § 60.105(a)(9). * * *
*
*
*
*
*
(e) For each fuel gas stream
combusted in a fuel gas combustion
device subject to § 60.104(a)(1), if an
owner or operator determines that one
of the exemptions listed in
§ 60.105(a)(4)(iv) applies to that fuel gas
stream, the owner or operator shall
maintain records of the specific
exemption chosen for each fuel gas
stream. If the owner or operator applies
for the exemption described in
§ 60.105(a)(4)(iv)(D), the owner or
operator must keep a copy of the
application as well as the letter from the
Administrator granting approval of the
application.
*
*
*
*
*
I 10. Section 60.108 is amended by
revising the last sentence of paragraph
(e) to read as follows:
§ 60.108 Performance test and compliance
provisions.
*
*
*
*
*
(e) * * * The owner or operator shall
furnish the Administrator with a written
notification of the change in the
semiannual report required by
§ 60.107(f).
I 11. Part 60 is amended by adding
subpart Ja to read as follows:
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Subpart Ja—Standards of Performance for
Petroleum Refineries for Which
Construction, Reconstruction, or
Modification Commenced After May 14,
2007
Sec.
60.100a Applicability, designation of
affected facility, and reconstruction.
60.101a Definitions.
60.102a Emissions limitations.
60.103a Work practice standards.
60.104a Performance tests.
60.105a Monitoring of emissions and
operations for fluid catalytic cracking
units (FCCU) and fluid coking units
(FCU).
60.106a Monitoring of emissions and
operations for sulfur recovery plants.
60.107a Monitoring of emissions and
operations for process heaters and other
fuel gas combustion devices.
60.108a Recordkeeping and reporting
requirements.
60.109a Delegation of authority.
Subpart Ja—Standards of Performance
for Petroleum Refineries for Which
Construction, Reconstruction, or
Modification Commenced After May 14,
2007
ebenthall on PRODPC60 with RULES4
§ 60.100a Applicability, designation of
affected facility, and reconstruction.
(a) The provisions of this subpart
apply to the following affected facilities
in petroleum refineries: fluid catalytic
cracking units (FCCU), fluid coking
units (FCU), delayed coking units, fuel
gas combustion devices, including flares
and process heaters, and sulfur recovery
plants. The sulfur recovery plant need
not be physically located within the
boundaries of a petroleum refinery to be
an affected facility, provided it
processes gases produced within a
petroleum refinery.
(b) Except for flares, the provisions of
this subpart apply only to affected
facilities under paragraph (a) of this
section which commence construction,
modification, or reconstruction after
May 14, 2007. For flares, the provisions
of this subpart apply only to flares
which commence construction,
modification, or reconstruction, after
June 24, 2008.
(c) For the purposes of this subpart,
under § 60.14, a modification to a flare
occurs if:
(1) Any new piping from a refinery
process unit or fuel gas system is
physically connected to the flare (e.g.,
for direct emergency relief or some form
of continuous or intermittent venting);
or
(2) A flare is physically altered to
increase the flow capacity of the flare.
(d) For purposes of this subpart,
under § 60.15, the ‘‘fixed capital cost of
the new components’’ includes the fixed
capital cost of all depreciable
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14:47 Jun 23, 2008
Jkt 214001
components which are or will be
replaced pursuant to all continuous
programs of component replacement
which are commenced within any 2year period following May 14, 2007. For
purposes of this paragraph,
‘‘commenced’’ means that an owner or
operator has undertaken a continuous
program of component replacement or
that an owner or operator has entered
into a contractual obligation to
undertake and complete, within a
reasonable time, a continuous program
of component replacement.
§ 60.101a
Definitions.
Terms used in this subpart are
defined in the Clean Air Act, in § 60.2,
and in this section.
Coke burn-off means the coke
removed from the surface of the FCCU
catalyst by combustion in the catalyst
regenerator. The rate of coke burn-off is
calculated by the formula specified in
§ 60.104a.
Contact material means any substance
formulated to remove metals, sulfur,
nitrogen, or any other contaminant from
petroleum derivatives.
Delayed coking unit means one or
more refinery process units in which
high molecular weight petroleum
derivatives are thermally cracked and
petroleum coke is produced in a series
of closed, batch system reactors.
Flare means an open-flame fuel gas
combustion device used for burning off
unwanted gas or flammable gas and
liquids. The flare includes the
foundation, flare tip, structural support,
burner, igniter, flare controls including
air injection or steam injection systems,
flame arrestors, knockout pots, piping
and header systems.
Flexicoking unit means one or more
refinery process units in which high
molecular weight petroleum derivatives
are thermally cracked and petroleum
coke is continuously produced and then
gasified to produce a synthetic fuel gas.
Fluid catalytic cracking unit means a
refinery process unit in which
petroleum derivatives are continuously
charged and hydrocarbon molecules in
the presence of a catalyst suspended in
a fluidized bed are fractured into
smaller molecules, or react with a
contact material suspended in a
fluidized bed to improve feedstock
quality for additional processing and the
catalyst or contact material is
continuously regenerated by burning off
coke and other deposits. The unit
includes the riser, reactor, regenerator,
air blowers, spent catalyst or contact
material stripper, catalyst or contact
material recovery equipment, and
regenerator equipment for controlling
air pollutant emissions and for heat
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recovery. When fluid catalyst cracking
unit regenerator exhaust from two
separate fluid catalytic cracking units
share a common exhaust treatment (e.g.,
CO boiler or wet scrubber), the fluid
catalytic cracking unit is a single
affected facility.
Fluid coking unit means one or more
refinery process units in which high
molecular weight petroleum derivatives
are thermally cracked and petroleum
coke is continuously produced in a
fluidized bed system. The fluid coking
unit includes equipment for controlling
air pollutant emissions and for heat
recovery on the fluid coking burner
exhaust vent.
Fuel gas means any gas which is
generated at a petroleum refinery and
which is combusted. Fuel gas includes
natural gas when the natural gas is
combined and combusted in any
proportion with a gas generated at a
refinery. Fuel gas does not include gases
generated by catalytic cracking unit
catalyst regenerators and fluid coking
burners, but does include gases from
flexicoking unit gasifiers. Fuel gas does
not include vapors that are collected
and combusted to comply with the
wastewater provisions in § 60.692, 40
CFR 61.343 through 61.348, 40 CFR
63.647, or the marine tank vessel
loading provisions in 40 CFR 63.562 or
40 CFR 63.651.
Fuel gas combustion device means
any equipment, such as process heaters,
boilers, and flares, used to combust fuel
gas, except facilities in which gases are
combusted to produce sulfur or sulfuric
acid.
Fuel gas system means a system of
compressors, piping, knock-out pots,
mix drums, and units used to remove
sulfur contaminants from the fuel gas
(e.g., amine scrubbers) that collects
refinery fuel gas from one or more
sources for treatment as necessary prior
to combusting in process heaters or
boilers. A fuel gas system may have an
overpressure vent to a flare but the
primary purpose for a fuel gas system is
to provide fuel to the refinery.
Oxidation control system means an
emission control system which reduces
emissions from sulfur recovery plants
by converting these emissions to sulfur
dioxide (SO2) and recycling the SO2 to
the reactor furnace or the first-stage
catalytic reactor of the Claus sulfur
recovery plant or converting the SO2 to
a sulfur product.
Petroleum means the crude oil
removed from the earth and the oils
derived from tar sands, shale, and coal.
Petroleum refinery means any facility
engaged in producing gasoline,
kerosene, distillate fuel oils, residual
fuel oils, lubricants, asphalt (bitumen)
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or other products through distillation of
petroleum or through redistillation,
cracking, or reforming of unfinished
petroleum derivatives.
Process heater means an enclosed
combustion device used to transfer heat
indirectly to process stream materials
(liquids, gases, or solids) or to a heat
transfer material for use in a process
unit instead of steam.
Process upset gas means any gas
generated by a petroleum refinery
process unit as a result of upset or
malfunction.
Reduced sulfur compounds means
hydrogen sulfide (H2S), carbonyl
sulfide, and carbon disulfide.
Reduction control system means an
emission control system which reduces
emissions from sulfur recovery plants
by converting these emissions to H2S
and either recycling the H2S to the
reactor furnace or the first-stage
catalytic reactor of the Claus sulfur
recovery plant or converting the H2S to
a sulfur product.
Refinery process unit means any
segment of the petroleum refinery in
which a specific processing operation is
conducted.
Sulfur pit means the storage vessel in
which sulfur that is condensed after
each Claus catalytic reactor is initially
accumulated and stored. A sulfur pit
does not include secondary sulfur
storage vessels downstream of the initial
Claus reactor sulfur pits.
Sulfur recovery plant means all
process units which recover sulfur from
HS2 and/or SO2 at a petroleum refinery.
The sulfur recovery plant also includes
sulfur pits used to store the recovered
sulfur product, but it does not include
secondary sulfur storage vessels
downstream of the sulfur pits. For
example, a Claus sulfur recovery plant
includes: Reactor furnace and waste
heat boiler, catalytic reactors, sulfur
pits, and, if present, oxidation or
reduction control systems, or
incinerator, thermal oxidizer, or similar
combustion device. Multiple sulfur
recovery units are a single affected
facility only when the units share the
same source of sour gas. Sulfur recovery
plants that receive source gas from
completely segregated sour gas
treatment systems are separate affected
facilities.
ebenthall on PRODPC60 with RULES4
§ 60.102a
Emissions limitations.
(a) Each owner or operator that is
subject to the requirements of this
subpart shall comply with the emissions
limitations in paragraphs (b) through (h)
of this section on and after the date on
which the initial performance test,
required by § 60.8, is completed, but not
later than 60 days after achieving the
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Jkt 214001
maximum production rate at which the
affected facility will be operated, or 180
days after initial startup, whichever
comes first.
(b) An owner or operator subject to
the provisions of this subpart shall not
discharge or cause the discharge into the
atmosphere from any FCCU or FCU:
(1) Particulate matter (PM) in excess
of the limits in paragraphs (b)(1)(i), (ii),
or (iii) of this section.
(i) 1.0 kilogram per Megagram (kg/
Mg)(1 pound (lb) per 1,000 lb) coke
burn-off or, if a PM continuous emission
monitoring system (CEMS) is used,
0.040 grain per dry standard cubic feet
(gr/dscf) corrected to 0 percent excess
air for each modified or reconstructed
FCCU.
(ii) 0.5 gram per kilogram (g/kg) coke
burn-off (0.5 lb PM/1,000 lb coke burnoff) or, if a PM CEMS is used, 0.020 gr/
dscf corrected to 0 percent excess air for
each newly constructed FCCU.
(iii) 1.0 kg/Mg (1 lb/1,000 lb) coke
burn-off; or if a PM CEMS is used, 0.040
grain per dry standard cubic feet (gr/
dscf) corrected to 0 percent excess air
for each affected FCU.
(2) Nitrogen oxides (NOX) in excess of
80 parts per million by volume (ppmv),
dry basis corrected to 0 percent excess
air, on a 7-day rolling average basis.
(3) Sulfur dioxide (SO2) in excess of
50 ppmv dry basis corrected to 0
percent excess air, on a 7-day rolling
average basis and 25 ppmv, dry basis
corrected to 0 percent excess air, on a
365-day rolling average basis.
(4) Carbon monoxide (CO) in excess of
500 ppmv, dry basis corrected to 0
percent excess air, on an hourly average
basis.
(c) The owner or operator of a FCCU
or FCU that uses a continuous
parameter monitoring system (CPMS)
according to § 60.105a(b)(1) shall
comply with the applicable control
device parameter operating limit in
paragraph (c)(1) or (2) of this section.
(1) If the FCCU or FCU is controlled
using an electrostatic precipitator:
(i) The 3-hour rolling average total
power and secondary current to the
entire system must not fall below the
level established during the most recent
performance test; and
(ii) The daily average exhaust coke
burn-off rate must not exceed the level
established during the most recent
performance test.
(2) If the FCCU or FCU is controlled
using a wet scrubber:
(i) The 3-hour rolling average pressure
drop must not fall below the level
established during the most recent
performance test; and
(ii) The 3-hour rolling average liquidto-gas ratio must not fall below the level
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35869
established during the most recent
performance test.
(d) If an FCCU or FCU uses a
continuous opacity monitoring system
(COMS) according to the alternative
monitoring option in § 60.105a(e), the 3hour rolling average opacity of
emissions from the FCCU or FCU as
measured by the COMS must not exceed
the site-specific opacity limit
established during the most recent
performance test.
(e) The owner or operator of a FCCU
or FCU that is exempted from the
requirement for a CO continuous
emissions monitoring system under
§ 60.105a(h)(3) shall comply with the
parameter operating limits in paragraph
(e)(1) or (2) of this section.
(1) For a FCCU or FCU with no postcombustion control device:
(i) The hourly average temperature of
the exhaust gases exiting the FCCU or
FCU must not fall below the level
established during the most recent
performance test.
(ii) The hourly average oxygen (O2)
concentration of the exhaust gases
exiting the FCCU or FCU must not fall
below the level established during the
most recent performance test.
(2) For a FCCU or FCU with a postcombustion control device:
(i) The hourly average temperature of
the exhaust gas vent stream exiting the
control device must not fall below the
level established during the most recent
performance test.
(ii) The hourly average O2
concentration of the exhaust gas vent
stream exiting the control device must
not fall below the level established
during the most recent performance test.
(f) Except as provided in paragraph
(f)(3), each owner or operator of an
affected sulfur recovery plant shall
comply with the applicable emission
limits in paragraphs (f)(1) or (2) of this
section.
(1) For a sulfur recovery plant with a
capacity greater than 20 long tons per
day (LTD):
(i) For a sulfur recovery plant with an
oxidation control system or a reduction
control system followed by incineration,
the owner or operator shall not
discharge or cause the discharge of any
gases into the atmosphere in excess of
250 ppm by volume (dry basis) of sulfur
dioxide (SO2) at zero percent excess air.
If the sulfur recovery plant consists of
multiple process trains or release points
the owner or operator shall comply with
the 250 ppmv limit for each process
train or release point or comply with a
flow rate weighted average of 250 ppmv
for all release points from the sulfur
recovery plant; or
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volume of reduced sulfur compounds
and 10 ppm by volume of hydrogen
sulfide (HS2), each calculated as ppm
SO2 by volume (dry basis) at zero
percent excess air; or
(
E LS = k1 × −0.038 ∗ ( %O 2 ) + 11.53 ∗ %O 2 + 25.6
Where:
ELS = Emission rate of SO2 for large sulfur
recovery plant, ppmv;
k1 = Constant factor for emission limit
conversion: k1 = 1 for converting to SO2
limit and k1 = 1.2 for converting to the
reduced sulfur compounds limit; and
%O2 = O2 concentration to the SRP, percent
by volume (dry basis).
(2) For a sulfur recovery plant with a
capacity of 20 LTD or less:
(i) For a sulfur recovery plant with an
oxidation control system or a reduction
control system followed by incineration,
the owner or operator shall not
2
(
ebenthall on PRODPC60 with RULES4
(3) Periods of maintenance of the
sulfur pit, during which the emission
limits in paragraphs (f)(1) and (2) shall
not apply, shall not exceed 240 hours
per year. The owner or operator must
document the time periods during
which the sulfur pit vents were not
controlled and measures taken to
minimize emissions during these
periods. Examples of these measures
include not adding fresh sulfur or
shutting off vent fans.
(g) Each owner or operator of an
affected fuel gas combustion device
shall comply with the emission limits in
paragraphs (g)(1) through (3) of this
section.
(1) For each fuel gas combustion
device, the owner or operator shall
comply with either the emission limit in
paragraph (g)(1)(i) of this section or the
fuel gas concentration limit in
paragraph (g)(1)(ii) of this section.
(i) The owner or operator shall not
discharge or cause the discharge of any
gases into the atmosphere that contain
SO2 in excess of 20 ppmv (dry basis,
corrected to 0 percent excess air)
determined hourly on a 3-hour rolling
average basis and SO2 in excess of 8
ppmv (dry basis, corrected to 0 percent
excess air), determined daily on a 365
successive day rolling average basis; or
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Jkt 214001
)
discharge or cause the discharge of any
gases into the atmosphere in excess of
2,500 ppm by volume (dry basis) of SO2
at zero percent excess air. If the sulfur
recovery plant consists of multiple
process trains or release points the
owner or operator shall comply with the
2,500 ppmv limit for each process train
or release point or comply with a flow
rate weighted average of 2,500 ppmv for
all release points from the sulfur
recovery plant; or
(ii) For sulfur recovery plant with a
reduction control system not followed
ESS = k1 × −0.38 ∗ ( %O 2 ) + 115.3 ∗ %O 2 + 256
Where:
ESS = Emission rate of SO2 for small sulfur
recovery plant, ppmv.
(iii) For systems using oxygen
enrichment, the owner or operator shall
calculate the applicable emission limit
using Equation 1 of this section:
2
)
(ii) The owner or operator shall not
burn in any fuel gas combustion device
any fuel gas that contains H2S in excess
of 162 ppmv determined hourly on a 3hour rolling average basis and H2S in
excess of 60 ppmv determined daily on
a 365 successive calendar day rolling
average basis.
(2) For each process heater with a
rated capacity of greater than 40 million
British thermal units per hour (MMBtu/
hr), the owner or operator shall not
discharge to the atmosphere any
emissions of NOX in excess of 40 ppmv
(dry basis, corrected to 0 percent excess
air) on a 24-hour rolling average basis.
(3) Except as provided in paragraphs
(h) and (i) of this section, the owner or
operator of an affected flare shall not
allow flow to each affected flare during
normal operations of more than 7,080
standard cubic meters per day (m3/day)
(250,000 standard cubic feet per day
(scfd)) on a 30-day rolling average. The
owner or operator of a newly
constructed or reconstructed flare shall
comply with the emission limit in this
paragraph by no later than the date that
flare becomes an affected flare subject to
this subpart. The owner or operator of
a modified flare shall comply with the
emission limit in this paragraph by no
later than 1 year after that flare becomes
an affected flare subject to this subpart.
(h) The combustion in a flare of
process upset gases or fuel gas that is
PO 00000
Frm 00034
Fmt 4701
Sfmt 4700
(Eq. 1)
by incineration, the owner or operator
shall not discharge or cause the
discharge of any gases into the
atmosphere in excess of 3,000 ppm by
volume of reduced sulfur compounds
and 100 ppm by volume of hydrogen
sulfide (H2S), each calculated as ppm
SO2 by volume (dry basis) at zero
percent excess air; or
(iii) For systems using oxygen
enrichment, the owner or operator shall
calculate the applicable emission limit
using Equation 2 of this section:
(Eq. 2)
released to the flare as a result of relief
valve leakage or other emergency
malfunctions is exempt from paragraph
(g) of this section.
(i) In periods of fuel gas imbalance
that are described in the flare
management plan required in section
60.103a(a), compliance with the
emission limit in paragraph (g)(3) of this
section is demonstrated by following the
procedures and maintaining records
described in the flare management plan
to document the periods of excess fuel
gas.
§ 60.103a
Work practice standards.
(a) Each owner or operator that
operates a flare that is subject to this
subpart shall develop and implement a
written flare management plan. The
owner or operator of a newly
constructed or reconstructed flare must
develop and implement the flare
management plan by no later than the
date that flare becomes an affected flare
subject to this subpart. The owner or
operator of a modified flare must
develop and implement the flare
management plan by no later than 1
year after the flare becomes an affected
flare subject to this subpart. The plan
must include:
(1) A diagram illustrating all
connections to the flare;
(2) Methods for monitoring flow rate
to the flare, including a detailed
E:\FR\FM\24JNR4.SGM
24JNR4
ER24JN08.001
(ii) For sulfur recovery plant with a
reduction control system not followed
by incineration, the owner or operator
shall not discharge or cause the
discharge of any gases into the
atmosphere in excess of 300 ppm by
ER24JN08.000
35870
Federal Register / Vol. 73, No. 122 / Tuesday, June 24, 2008 / Rules and Regulations
§ 60.104a
Performance tests.
(a) The owner or operator shall
conduct a performance test for each
FCCU, FCU, sulfur recovery plant, and
fuel gas combustion device to
demonstrate initial compliance with
each applicable emissions limit in
§ 60.102a according to the requirements
of § 60.8. The notification requirements
of § 60.8(d) apply to the initial
performance test and to subsequent
performance tests required by paragraph
(b) of this section (or as required by the
Administrator), but does not apply to
performance tests conducted for the
purpose of obtaining supplemental data
because of continuous monitoring
system breakdowns, repairs, calibration
checks, and zero and span adjustments.
(b) The owner or operator of a FCCU
or FCU that elects to monitor control
device operating parameters according
to the requirements in § 60.105a(b), to
use bag leak detectors according to the
requirements in § 60.105a(c), or to use
COMS according to the requirements in
§ 60.105a(e) shall conduct a PM
performance test at least once every 12
months and furnish the Administrator a
written report of the results of each test.
(c) In conducting the performance
tests required by this subpart (or as
requested by the Administrator), the
owner or operator shall use the test
methods in 40 CFR part 60, Appendices
A–1 through A–8 or other methods as
specified in this section, except as
provided in § 60.8(b).
(d) The owner or operator shall
determine compliance with the PM,
NOX, SO2, and CO emissions limits in
§ 60.102a(b) for FCCU and FCU using
the following methods and procedures:
(1) Method 1 of Appendix A–1 to part
60 for sample and velocity traverses.
(
(2) Method 2 of Appendix A–1 to part
60 for velocity and volumetric flow rate.
(3) Method 3, 3A, or 3B of Appendix
A–2 to part 60 for gas analysis. The
method ANSI/ASME PTC 19.10–1981,
‘‘Flue and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 3B of Appendix A–2 to part 60.
(4) Method 5, 5B, or 5F of Appendix
A–3 to part 60 for determining PM
emissions and associated moisture
content from a FCCU or FCU without a
wet scrubber subject to the emissions
limit in § 63.102a(b)(1). Use Method 5 or
5B of Appendix A–3 to part 60 for
determining PM emissions and
associated moisture content from a
FCCU or FCU with a wet scrubber
subject to the emissions limit in
§ 63.102a(b)(1).
(i) The PM performance test consists
of 3 valid test runs; the duration of each
test run must be no less than 60
minutes.
(ii) The emissions rate of PM (EPM) is
computed for each run using Equation
3 of this section:
E=
(iii) The coke burn-off rate (Rc) is
computed for each run using Equation
4 of this section:
)
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Qoxy = Volumetric flow rate of O2 enriched
air to FCCU regenerator or fluid coking
unit, as determined from the unit’s
control room instrumentation, dscm/min
(dscf/min);
%CO2 = Carbon dioxide concentration in
FCCU regenerator or fluid coking burner
exhaust, percent by volume (dry basis);
%CO = CO concentration in FCCU
regenerator or fluid coking burner
exhaust, percent by volume (dry basis);
PO 00000
Frm 00035
Fmt 4701
Sfmt 4700
(Eq. 3)
Where:
E = Emission rate of PM, g/kg, lbs per 1,000
lbs (lb/1,000 lbs) of coke burn-off;
cs = Concentration of total PM, grams per dry
standard cubic meter (g/dscm), gr/dscf;
Qsd = Volumetric flow rate of effluent gas, dry
standard cubic meters per hour, dry
standard cubic feet per hour;
Rc = Coke burn-off rate, kilograms per hour
(kg/hr), lbs per hour (lbs/hr) coke; and
K = Conversion factor, 1.0 grams per gram
(7,000 grains per lb).
Rc = K1Qr ( %CO2 + %CO ) + K 2Qa − K 3Qr %CO + %CO2 + %O2 + K 3Qoxy ( %Ooxy )
2
Where:
Rc = Coke burn-off rate, kg/hr (lb/hr);
Qr = Volumetric flow rate of exhaust gas from
FCCU regenerator or fluid coking burner
before any emissions control or energy
recovery system that burns auxiliary
fuel, dry standard cubic meters per
minute (dscm/min), dry standard cubic
feet per minute (dscf/min);
Qa = Volumetric flow rate of air to FCCU
regenerator or fluid coking burner, as
determined from the unit’s control room
instrumentation, dscm/min (dscf/min);
cs Qsd
K Rc
(Eq. 4)
q
%O2 = O2 concentration in FCCU regenerator
or fluid coking burner exhaust, percent
by volume (dry basis);
%Ooxy = O2 concentration in O2 enriched air
stream inlet to the FCCU regenerator or
fluid coking burner, percent by volume
(dry basis);
K1 = Material balance and conversion factor,
0.2982 (kg-min)/(hr-dsc-%) [0.0186 (lbmin)/(hr-dscf-%)];
K2 = Material balance and conversion factor,
2.088 (kg-min)/(hr-dscm) [0.1303 (lbmin)/(hr-dscf)]; and
E:\FR\FM\24JNR4.SGM
24JNR4
ER24JN08.003
5 lb per square inch gauge (psig) during
reactor vessel depressuring and vent the
exhaust gases to the fuel gas system for
combustion in a fuel gas combustion
device.
ER24JN08.002
description of the manufacturer’s
specifications, including but not limited
to, make, model, type, range, precision,
accuracy, calibration, maintenance, and
quality assurance procedures for flare
gas monitoring devices;
(3) Procedures to minimize discharges
to the flare gas system during the
planned start-up and shutdown of the
refinery process units that are connected
to the affected flare;
(4) Procedures to conduct a root cause
analysis of any process upset or
malfunction that causes a discharge to
the flare in excess of 14,160 m3/day
(500,000 scfd);
(5) Procedures to reduce flaring in
cases of fuel gas imbalance (i.e., excess
fuel gas for the refinery’s energy needs);
and
(6) Explanation of procedures to
follow during times that the flare must
exceed the limit in § 60.102a(g)(3) (e.g.,
keep records of natural gas purchases to
support assertion that the refinery is
producing more fuel gas than needed to
operate the processes).
(b) Each owner or operator that
operates a fuel gas combustion device or
sulfur recovery plant subject to this
subpart shall conduct a root cause
analysis of any emission limit
exceedance or process start-up,
shutdown, upset, or malfunction that
causes a discharge to the atmosphere in
excess of 227 kilograms per day (kg/day)
(500 lb per day (lb/day)) of SO2. For any
root cause analysis performed, the
owner or operator shall record the
identification of the affected facility, the
date and duration of the discharge, the
results of the root cause analysis, and
the action taken as a result of the root
cause analysis. The first root cause
analysis for a modified flare must be
conducted no later than the first
discharge that occurs after the flare has
been an affected flare subject to this
subpart for 1 year.
(c) Each owner or operator of a
delayed coking unit shall depressure to
35871
Federal Register / Vol. 73, No. 122 / Tuesday, June 24, 2008 / Rules and Regulations
Qr =
Where:
Qr = Volumetric flow rate of exhaust gas from
FCCU regenerator or fluid coking burner
before any emission control or energy
recovery system that burns auxiliary
fuel, dscm/min (dscf/min);
Qa = Volumetric flow rate of air to FCCU
regenerator or fluid coking burner, as
determined from the unit’s control room
instrumentation, dscm/min (dscf/min);
Qoxy = Volumetric flow rate of O2 enriched
air to FCCU regenerator or fluid coking
unit, as determined from the unit’s
control room instrumentation, dscm/min
(dscf/min);
%CO2 = Carbon dioxide concentration in
FCCU regenerator or fluid coking burner
exhaust, percent by volume (dry basis);
%CO = CO concentration FCCU regenerator
or fluid coking burner exhaust, percent
by volume (dry basis). When no auxiliary
fuel is burned and a continuous CO
monitor is not required in accordance
79 × Qa + (100 − %Oxy ) × Qoxy
100 − %CO2 − %CO − %O2
Where:
Cadj = pollutant concentration adjusted to 0
percent excess air or O2, parts per
million (ppm) or g/dscm;
Cmeas = pollutant concentration measured on
a dry basis, ppm or g/dscm;
20.9c = 20.9 percent O2–0.0 percent O2
(defined O2 correction basis), percent;
20.9 = O2 concentration in air, percent; and
%O2 = O2 concentration measured on a dry
basis, percent.
(e) The owner or operator of a FCCU
or FCU that is controlled by an
electrostatic precipitator or wet scrubber
and that is subject to control device
(Eq. 5)
with § 60.105a(g)(3), assume %CO to be
zero;
%O2 = O2 concentration in FCCU regenerator
or fluid coking burner exhaust, percent
by volume (dry basis); and
%Ooxy = O2 concentration in O2 enriched air
stream inlet to the FCCU regenerator or
fluid coking burner, percent by volume
(dry basis).
(5) Method 6, 6A, or 6C of Appendix
A–4 to part 60 for moisture content and
for the concentration of SO2; the
duration of each test run must be no less
than 4 hours. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 6 or 6A of Appendix A–
4 to part 60.
(6) Method 7, 7A, 7C, 7D, or 7E of
Appendix A–4 to part 60 for moisture
20.9c
Cadj = Cmeas
( 20.9 − %O2 )
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Jkt 214001
operating parameter limits in
§ 60.102a(c) shall establish the limits
based on the performance test results
according to the following procedures:
(1) Reduce the parameter monitoring
data to hourly averages for each test run;
(2) Determine the hourly average
operating limit for each required
parameter as the average of the three test
runs.
(f) The owner or operator of an FCCU
or FCU that uses cyclones to comply
with the PM limit in § 60.102a(b)(1) and
elects to comply with the COMS
alternative monitoring option in
PMEmRst = PM emission rate measured
during the source test, lb/1,000 lbs coke
burn.
(g) The owner or operator of a FCCU
or FCU that is exempt from the
requirement to install and operate a CO
PO 00000
Frm 00036
Fmt 4701
Sfmt 4700
content and for the concentration of
NOX calculated as nitrogen dioxide
(NO2); the duration of each test run
must be no less than 4 hours. The
method ANSI/ASME PTC 19.10–1981,
‘‘Flue and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 7 or 7C of Appendix A–4 to part
60.
(7) Method 10, 10A, or 10B of
Appendix A–4 to part 60 for moisture
content and for the concentration of CO.
The sampling time for each run must be
60 minutes.
(8) The owner or operator shall adjust
PM, NOX, SO2, and CO pollutant
concentrations to 0 percent excess air or
0 percent O2 using Equation 6 of this
section:
(Eq. 6)
1lb/1,000 lb coke burn
Opacity Limit = Opacityst x
PMEmRst
Where:
Opacity limit = Maximum permissible hourly
average opacity, percent, or 10 percent,
whichever is greater;
Opacityst = Hourly average opacity measured
during the source test runs, percent; and
rates, the volumetric flow rate of Qr is
calculated using average exhaust gas
concentrations as measured by the
monitors in § 60.105a(b)(2), if
applicable, using Equation 5 of this
section:
§ 60.105a(d) shall establish a sitespecific opacity operating limit
according to the procedures in
paragraphs (f)(1) through (3) of this
section.
(1) Collect COMS data every 10
seconds during the entire period of the
PM performance test and reduce the
data to 6-minute averages.
(2) Determine and record the hourly
average opacity from all the 6-minute
averages.
(3) Compute the site-specific limit
using Equation 7 of this section:
(Eq. 7)
CEMS pursuant to § 60.105a(h)(3) and
that is subject to control device
operating parameter limits in
§ 60.102a(c) shall establish the limits
based on the performance test results
E:\FR\FM\24JNR4.SGM
24JNR4
ER24JN08.006
(iv) During the performance test, the
volumetric flow rate of exhaust gas from
catalyst regenerator (Qr) before any
emission control or energy recovery
system that burns auxiliary fuel is
measured using Method 2 of Appendix
A–1 to part 60.
(v) For subsequent calculations of
coke burn-off rates or exhaust gas flow
ER24JN08.005
K3 = Material balance and conversion factor,
0.0994 (kg-min)/(hr-dscm-%) [0.00624
(lb-min)/(hr-dscf-%)].
ER24JN08.004
35872
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Federal Register / Vol. 73, No. 122 / Tuesday, June 24, 2008 / Rules and Regulations
using the procedures in paragraphs
(g)(1) and (2) of this section.
(1) Reduce the temperature and O2
concentrations from the parameter
monitoring systems to hourly averages
for each test run.
(2) Determine the operating limit for
temperature and O2 concentrations as
the average of the average temperature
and O2 concentration for the three test
runs.
(h) The owner or operator shall
determine compliance with the SO2 and
H2S emissions limits for sulfur recovery
plants in §§ 60.102a(f)(1)(i),
60.102a(f)(1)(iii), 60.102a(f)(1)(iii),
60.102a(f)(2)(i), and 60.102a(f)(2)(iii)
and the reduced sulfur compounds and
H2S emissions limits for sulfur recovery
plants in § 60.102a(f)(1)(ii) and
§ 60.102a(f)(2)(ii) using the following
methods and procedures:
(1) Method 1 of Appendix A–1 to part
60 for sample and velocity traverses.
(2) Method 2 of Appendix A–1 to part
60 for velocity and volumetric flow rate.
(3) Method 3, 3A, or 3B of Appendix
A–2 to part 60 for gas analysis. The
method ANSI/ASME PTC 19.10–1981,
‘‘Flue and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 3B of Appendix A–2 to part 60.
(4) Method 6, 6A, or 6C of Appendix
A–4 to part 60 to determine the SO2
concentration. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 6 or 6A of Appendix A–
4 to part 60.
(5) Method 15 or 15A of Appendix A–
5 to part 60 or Method 16 of Appendix
A–6 to part 60 to determine the reduced
sulfur compounds and H2S
concentrations. The method ANSI/
ASME PTC 19.10–1981, ‘‘Flue and
Exhaust Gas Analyses,’’ (incorporated
by reference—see § 60.17) is an
acceptable alternative to EPA Method
15A of Appendix A–5 to part 60.
(i) Each run consists of 16 samples
taken over a minimum of 3 hours.
(ii) The owner or operator shall
calculate the average H2S concentration
after correcting for moisture and O2 as
the arithmetic average of the H2S
concentration for each sample during
the run (ppmv, dry basis, corrected to 0
percent excess air).
(iii) The owner or operator shall
calculate the SO2 equivalent for each
run after correcting for moisture and O2
as the arithmetic average of the SO2
equivalent of reduced sulfur compounds
for each sample during the run (ppmv,
dry basis, corrected to 0 percent excess
air).
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Jkt 214001
(iv) The owner or operator shall use
Equation 6 of this section to adjust
pollutant concentrations to 0 percent O2
or 0 percent excess air.
(i) The owner or operator shall
determine compliance with the SO2 and
NOX emissions limits in § 60.102a(g) for
a fuel gas combustion device according
to the following test methods and
procedures:
(1) Method 1 of Appendix A–1 to part
60 for sample and velocity traverses;
(2) Method 2 of Appendix A–1 to part
60 for velocity and volumetric flow rate;
(3) Method 3, 3A, or 3B of Appendix
A–2 to part 60 for gas analysis. The
method ANSI/ASME PTC 19.10–1981,
‘‘Flue and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 3B of Appendix A–2 to part 60;
(4) Method 6, 6A, or 6C of Appendix
A–4 to part 60 to determine the SO2
concentration. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 6 or 6A of Appendix A–
4 to part 60.
(i) The performance test consists of 3
valid test runs; the duration of each test
run must be no less than 1 hour.
(ii) If a single fuel gas combustion
device having a common source of fuel
gas is monitored as allowed under
§ 60.107a(a)(1)(v), only one performance
test is required. That is, performance
tests are not required when a new
affected fuel gas combustion device is
added to a common source of fuel gas
that previously demonstrated
compliance.
(5) Method 7, 7A, 7C, 7D, or 7E of
Appendix A–4 to part 60 for moisture
content and for the concentration of
NOX calculated as NO2; the duration of
each test run must be no less than 4
hours. The method ANSI/ASME PTC
19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 7 or 7C of Appendix A–
4 to part 60.
(j) The owner or operator shall
determine compliance with the H2S
emissions limit in § 60.102a(g) for a fuel
gas combustion device according to the
following test methods and procedures:
(1) Method 1 of Appendix A–1 to part
60 for sample and velocity traverses;
(2) Method 2 of Appendix A–1 to part
60 for velocity and volumetric flow rate;
(3) Method 3, 3A, or 3B of Appendix
A–2 to part 60 for gas analysis. The
method ANSI/ASME PTC 19.10–1981,
‘‘Flue and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 3B of Appendix A–2 to part 60;
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Fmt 4701
Sfmt 4700
35873
(4) Method 11, 15, or 15A of
Appendix A–5 to part 60 or Method 16
of Appendix A–6 to part 60 for
determining the H2S concentration for
affected plants using an H2S monitor as
specified in § 60.107a(a)(2). The method
ANSI/ASME PTC 19.10–1981, ‘‘Flue
and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 15A of Appendix A–5 to part
60. The owner or operator may
demonstrate compliance based on the
mixture used in the fuel gas combustion
device or for each individual fuel gas
stream used in the fuel gas combustion
device.
(i) For Method 11 of Appendix A–5 to
part 60, the sampling time and sample
volume must be at least 10 minutes and
0.010 dscm (0.35 dscf). Two samples of
equal sampling times must be taken at
about 1-hour intervals. The arithmetic
average of these two samples constitutes
a run. For most fuel gases, sampling
times exceeding 20 minutes may result
in depletion of the collection solution,
although fuel gases containing low
concentrations of H2S may necessitate
sampling for longer periods of time.
(ii) For Method 15 of Appendix A–5
to part 60, at least three injects over a
1-hour period constitutes a run.
(iii) For Method 15A of Appendix A–
5 to part 60, a 1-hour sample constitutes
a run. The method ANSI/ASME PTC
19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 15A of Appendix A–5
to part 60.
(iv) If monitoring is conducted at a
single point in a common source of fuel
gas as allowed under § 60.107a(a)(2)(iv),
only one performance test is required.
That is, performance tests are not
required when a new affected fuel gas
combustion device is added to a
common source of fuel gas that
previously demonstrated compliance.
§ 60.105a Monitoring of emissions and
operations for fluid catalytic cracking units
(FCCU) and fluid coking units (FCU).
(a) FCCU and FCU subject to PM
emissions limit. Each owner or operator
subject to the provisions of this subpart
shall monitor each FCCU and FCU
subject to the PM emissions limit in
§ 60.102a(b)(1) according to the
requirements in paragraph (b), (c), (d),
or (e) of this section.
(b) Control device operating
parameters. Each owner or operator of
a FCCU or FCU subject to the PM per
coke burn-off emissions limit in
§ 60.102a(b)(1) shall comply with the
requirements in paragraphs (b)(1)
through (3) of this section.
E:\FR\FM\24JNR4.SGM
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35874
Federal Register / Vol. 73, No. 122 / Tuesday, June 24, 2008 / Rules and Regulations
(1) The owner or operator shall
install, operate, and maintain
continuous parameter monitor systems
(CPMS) to measure and record operating
parameters for each control device
according to the requirements in
paragraph (b)(1)(i) through (iii) of this
section.
(i) For units controlled using an
electrostatic precipitator, the owner or
operator shall use CPMS to measure and
record the hourly average total power
input and secondary voltage to the
entire system.
(ii) For units controlled using a wet
scrubber, the owner or operator shall
use CPMS to measure and record the
hourly average pressure drop, liquid
feed rate, and exhaust gas flow rate. As
an alternative to a CPMS, the owner or
operator must comply with the
requirements in either paragraph
(b)(1)(ii)(A) or (B) of this section.
(A) As an alterative to pressure drop,
the owner or operator of a jet ejector
type wet scrubber or other type of wet
scrubber equipped with atomizing spray
nozzles must conduct a daily check of
the air or water pressure to the spray
nozzles and record the results of each
check.
(B) As an alternative to exhaust gas
flow rate, the owner or operator shall
comply with the approved alternative
for monitoring exhaust gas flow rate in
40 CFR 63.1573(a) of the National
Emission Standards for Hazardous Air
Pollutants for Petroleum Refineries:
Catalytic Cracking Units, Catalytic
Reforming Units, and Sulfur Recovery
Units.
(iii) The owner or operator shall
install, operate, and maintain each
CPMS according to the manufacturer’s
specifications and requirements.
(iv) The owner or operator shall
determine and record the average coke
burn-off rate and hours of operation for
each FCCU or FCU using the procedures
in § 60.104a(d)(4)(iii).
(v) If you use a control device other
than an electrostatic precipitator, wet
scrubber, fabric filter, or cyclone, you
may request approval to monitor
parameters other than those required in
paragraph (b)(1) of this section by
submitting an alternative monitoring
plan to the Administrator. The request
must include the information in
paragraphs (b)(1)(v)(A) through (E) of
this section.
(A) A description of each affected
facility and the parameter(s) to be
monitored to determine whether the
affected facility will continuously
comply with the emission limitations
and an explanation of the criteria used
to select the parameter(s).
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(B) A description of the methods and
procedures that will be used to
demonstrate that the parameter(s) can be
used to determine whether the affected
facility will continuously comply with
the emission limitations and the
schedule for this demonstration. The
owner or operator must certify that an
operating limit will be established for
the monitored parameter(s) that
represents the conditions in existence
when the control device is being
properly operated and maintained to
meet the emission limitation.
(C) The frequency and content of the
recordkeeping, recording, and reporting,
if monitoring and recording are not
continuous. The owner or operator also
must include the rationale for the
proposed monitoring, recording, and
reporting requirements.
(D) Supporting calculations.
(E) Averaging time for the alternative
operating parameter.
(2) For use in determining the coke
burn-off rate for an FCCU or FCU, the
owner or operator shall install, operate,
calibrate, and maintain an instrument
for continuously monitoring the
concentrations of CO2, O2 (dry basis),
and if needed, CO in the exhaust gases
prior to any control or energy recovery
system that burns auxiliary fuels.
(i) The owner or operator shall install,
operate, and maintain each monitor
according to Performance Specification
3 of Appendix B to part 60.
(ii) The owner or operator shall
conduct performance evaluations of
each CO2, O2, and CO monitor according
to the requirements in § 60.13(c) and
Performance Specification 3 of
Appendix B to part 60. The owner or
operator shall use Method 3 of
Appendix A–3 to part 60 for conducting
the relative accuracy evaluations.
(iii) The owner or operator shall
comply with the quality assurance
requirements of procedure 1 of
Appendix F to part 60, including
quarterly accuracy determinations for
CO2 and CO monitors, annual accuracy
determinations for O2 monitors, and
daily calibration drift tests.
(c) Bag leak detection systems. Each
owner or operator shall install, operate,
and maintain a bag leak detection
system for each baghouse or similar
fabric filter control device that is used
to comply with the PM per coke burnoff emissions limit in § 60.102a(b)(1) for
an FCCU or FCU according to paragraph
(c)(1) of this section; prepare and
operate by a site-specific monitoring
plan according to paragraph (c)(2) of
this section; take action according to
paragraph (c)(3) of this section; and
record information according to
paragraph (c)(4) of this section.
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(1) Each bag leak detection system
must meet the specifications and
requirements in paragraphs (c)(1)(i)
through (viii) of this section.
(i) The bag leak detection system must
be certified by the manufacturer to be
capable of detecting PM emissions at
concentrations of 0.00044 grains per
actual cubic foot or less.
(ii) The bag leak detection system
sensor must provide output of relative
PM loadings. The owner or operator
shall continuously record the output
from the bag leak detection system using
electronic or other means (e.g., using a
strip chart recorder or a data logger).
(iii) The bag leak detection system
must be equipped with an alarm system
that will sound when the system detects
an increase in relative particulate
loading over the alarm set point
established according to paragraph
(c)(1)(iv) of this section, and the alarm
must be located such that it can be
heard by the appropriate plant
personnel.
(iv) In the initial adjustment of the bag
leak detection system, the owner or
operator must establish, at a minimum,
the baseline output by adjusting the
sensitivity (range) and the averaging
period of the device, the alarm set
points, and the alarm delay time.
(v) Following initial adjustment, the
owner or operator shall not adjust the
averaging period, alarm set point, or
alarm delay time without approval from
the Administrator or delegated authority
except as provided in paragraph
(c)(1)(vi) of this section.
(vi) Once per quarter, the owner or
operator may adjust the sensitivity of
the bag leak detection system to account
for seasonal effects, including
temperature and humidity, according to
the procedures identified in the sitespecific monitoring plan required by
paragraph (c)(2) of this section.
(vii) The owner or operator shall
install the bag leak detection sensor
downstream of the baghouse and
upstream of any wet scrubber.
(viii) Where multiple detectors are
required, the system’s instrumentation
and alarm may be shared among
detectors.
(2) The owner or operator shall
develop and submit to the
Administrator for approval a sitespecific monitoring plan for each
baghouse and bag leak detection system.
The owner or operator shall operate and
maintain each baghouse and bag leak
detection system according to the sitespecific monitoring plan at all times.
Each monitoring plan must describe the
items in paragraphs (c)(2)(i) through
(vii) of this section.
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(i) Installation of the bag leak
detection system;
(ii) Initial and periodic adjustment of
the bag leak detection system, including
how the alarm set-point will be
established;
(iii) Operation of the bag leak
detection system, including quality
assurance procedures;
(iv) How the bag leak detection
system will be maintained, including a
routine maintenance schedule and spare
parts inventory list;
(v) How the bag leak detection system
output will be recorded and stored;
(vi) Procedures as specified in
paragraph (c)(3) of this section. In
approving the site-specific monitoring
plan, the Administrator or delegated
authority may allow owners and
operators more than 3 hours to alleviate
a specific condition that causes an alarm
if the owner or operator identifies in the
monitoring plan this specific condition
as one that could lead to an alarm,
adequately explains why it is not
feasible to alleviate this condition
within 3 hours of the time the alarm
occurs, and demonstrates that the
requested time will ensure alleviation of
this condition as expeditiously as
practicable; and
(vii) How the baghouse system will be
operated and maintained, including
monitoring of pressure drop across
baghouse cells and frequency of visual
inspections of the baghouse interior and
baghouse components such as fans and
dust removal and bag cleaning
mechanisms.
(3) For each bag leak detection
system, the owner or operator shall
initiate procedures to determine the
cause of every alarm within 1 hour of
the alarm. Except as provided in
paragraph (c)(2)(vi) of this section, the
owner or operator shall alleviate the
cause of the alarm within 3 hours of the
alarm by taking whatever action(s) are
necessary. Actions may include, but are
not limited to the following:
(i) Inspecting the baghouse for air
leaks, torn or broken bags or filter
media, or any other condition that may
cause an increase in particulate
emissions;
(ii) Sealing off defective bags or filter
media;
(iii) Replacing defective bags or filter
media or otherwise repairing the control
device;
(iv) Sealing off a defective baghouse
compartment;
(v) Cleaning the bag leak detection
system probe or otherwise repairing the
bag leak detection system; or
(vi) Shutting down the process
producing the particulate emissions.
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(4) The owner or operator shall
maintain records of the information
specified in paragraphs (c)(4)(i) through
(iii) of this section for each bag leak
detection system.
(i) Records of the bag leak detection
system output;
(ii) Records of bag leak detection
system adjustments, including the date
and time of the adjustment, the initial
bag leak detection system settings, and
the final bag leak detection system
settings; and
(iii) The date and time of all bag leak
detection system alarms, the time that
procedures to determine the cause of the
alarm were initiated, the cause of the
alarm, an explanation of the actions
taken, the date and time the cause of the
alarm was alleviated, and whether the
alarm was alleviated within 3 hours of
the alarm.
(d) Continuous emissions monitoring
systems (CEMS). An owner or operator
subject to the PM concentration
emission limit (in gr/dscf) in
§ 60.102a(b)(1) for an FCCU or FCU
shall install, operate, calibrate, and
maintain an instrument for
continuously monitoring and recording
the concentration (0 percent excess air)
of PM in the exhaust gases prior to
release to the atmosphere. The monitor
must include an O2 monitor for
correcting the data for excess air.
(1) The owner or operator shall
install, operate, and maintain each PM
monitor according to Performance
Specification 11 of appendix B to part
60. The span value of this PM monitor
is 0.08 gr/dscf PM.
(2) The owner or operator shall
conduct performance evaluations of
each PM monitor according to the
requirements in § 60.13(c) and
Performance Specification 11 of
appendix B to part 60. The owner or
operator shall use EPA Methods 5 or 5I
of Appendix A–3 to part 60 or Method
17 of Appendix A–6 to part 60 for
conducting the relative accuracy
evaluations.
(3) The owner or operator shall
install, operate, and maintain each O2
monitor according to Performance
Specification 3 of appendix B to part 60.
The span value of this O2 monitor must
be selected between 10 and 25 percent,
inclusive.
(4) The owner or operator shall
conduct performance evaluations of
each O2 monitor according to the
requirements in § 60.13(c) and
Performance Specification 3 of
Appendix B to part 60. Method 3, 3A,
or 3B of Appendix A–2 to part 60 shall
be used for conducting the relative
accuracy evaluations. The method
ANSI/ASME PTC 19.10–1981, ‘‘Flue
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35875
and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 3B of Appendix A–2 to part 60.
(5) The owner or operator shall
comply with the quality assurance
requirements of Procedure 2 of
Appendix B to part 60 for each PM
CEMS and Procedure 1 of Appendix F
to part 60 for each O2 monitor,
including quarterly accuracy
determinations for each PM monitor,
annual accuracy determinations for each
O2 monitor, and daily calibration drift
tests.
(e) Alternative monitoring option for
FCCU and FCU—COMS. Each owner or
operator of an FCCU or FCU that uses
cyclones to comply with the PM
emission limit in § 60.102a(b)(1) shall
monitor the opacity of emissions
according to the requirements in
paragraphs (e)(1) through (3) of this
section.
(1) The owner or operator shall
install, operate, and maintain an
instrument for continuously monitoring
and recording the opacity of emissions
from the FCCU or the FCU exhaust vent.
(2) The owner or operator shall
install, operate, and maintain each
COMS according to Performance
Specification 1 of Appendix B to part
60. The instrument shall be spanned at
20 to 60 percent opacity.
(3) The owner or operator shall
conduct performance evaluations of
each COMS according to § 60.13(c) and
Performance Specification 1 of
Appendix B to part 60.
(f) FCCU and FCU subject to NOX
limit. Each owner or operator subject to
the NOX emissions limit in
§ 60.102a(b)(2) for an FCCU or FCU
shall install, operate, calibrate, and
maintain an instrument for
continuously monitoring and recording
the concentration by volume (dry basis,
0 percent excess air) of NOX emissions
into the atmosphere. The monitor must
include an O2 monitor for correcting the
data for excess air.
(1) The owner or operator shall
install, operate, and maintain each NOX
monitor according to Performance
Specification 2 of Appendix B to part
60. The span value of this NOX monitor
is 200 ppmv NOX.
(2) The owner or operator shall
conduct performance evaluations of
each NOX monitor according to the
requirements in § 60.13(c) and
Performance Specification 2 of
Appendix B to part 60. The owner or
operator shall use Methods 7, 7A, 7C,
7D, or 7E of Appendix A–4 to part 60
for conducting the relative accuracy
evaluations. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
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Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 7 or 7C of Appendix A–
4 to part 60.
(3) The owner or operator shall
install, operate, and maintain each O2
monitor according to Performance
Specification 3 of Appendix B to part
60. The span value of this O2 monitor
must be selected between 10 and 25
percent, inclusive.
(4) The owner or operator shall
conduct performance evaluations of
each O2 monitor according to the
requirements in § 60.13(c) and
Performance Specification 3 of
Appendix B to part 60. Method 3, 3A,
or 3B of Appendix A–2 to part 60 shall
be used for conducting the relative
accuracy evaluations. The method
ANSI/ASME PTC 19.10–1981, ‘‘Flue
and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 3B of Appendix A–2 to part 60.
(5) The owner or operator shall
comply with the quality assurance
requirements of Procedure 1 of
Appendix F to part 60 for each NOX and
O2 monitor, including quarterly
accuracy determinations for NOX
monitors, annual accuracy
determinations for O2 monitors, and
daily calibration drift tests.
(g) FCCU and FCU subject to SO2
limit. The owner or operator subject to
the SO2 emissions limit in
§ 60.102a(b)(3) for an FCCU or an FCU
shall install, operate, calibrate, and
maintain an instrument for
continuously monitoring and recording
the concentration by volume (dry basis,
corrected to 0 percent excess air) of SO2
emissions into the atmosphere. The
monitor shall include an O2 monitor for
correcting the data for excess air.
(1) The owner or operator shall
install, operate, and maintain each SO2
monitor according to Performance
Specification 2 of Appendix B to part
60. The span value of this SO2 monitor
is 200 ppmv SO2.
(2) The owner or operator shall
conduct performance evaluations of
each SO2 monitor according to the
requirements in § 60.13(c) and
Performance Specification 2 of
Appendix B to part 60. The owner or
operator shall use Methods 6, 6A, or 6C
of Appendix A–4 to part 60 for
conducting the relative accuracy
evaluations. The method ANSI / ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 6 or 6A of Appendix A–
4 to part 60.
(3) The owner or operator shall
install, operate, and maintain each O2
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monitor according to Performance
Specification 3 of Appendix B to part
60. The span value of this O2 monitor
must be selected between 10 and 25
percent, inclusive.
(4) The owner or operator shall
conduct performance evaluations of
each O2 monitor according to the
requirements in § 60.13(c) and
Performance Specification 3 of
Appendix B to part 60. Method 3, 3A,
or 3B of Appendix A–2 to part 60 shall
be used for conducting the relative
accuracy evaluations. The method
ANSI/ASME PTC 19.10–1981, ‘‘Flue
and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 3B of Appendix A–2 to part 60.
(5) The owner or operator shall
comply with the quality assurance
requirements in Procedure 1 of
Appendix F to part 60 for each SO2 and
O2 monitor, including quarterly
accuracy determinations for SO2
monitors, annual accuracy
determinations for O2 monitors, and
daily calibration drift tests.
(h) FCCU and fluid coking units
subject to CO emissions limit. Except as
specified in paragraph (h)(3) of this
section, the owner or operator shall
install, operate, calibrate, and maintain
an instrument for continuously
monitoring and recording the
concentration by volume (dry basis) of
CO emissions into the atmosphere from
each FCCU and FCU subject to the CO
emissions limit in § 60.102a(b)(4).
(1) The owner or operator shall
install, operate, and maintain each CO
monitor according to Performance
Specification 4 or 4A of Appendix B to
part 60. The span value for this
instrument is 1,000 ppm CO.
(2) The owner or operator shall
conduct performance evaluations of
each CO monitor according to the
requirements in § 60.13(c) and
Performance Specification 4 or 4A of
Appendix B to part 60. The owner or
operator shall use Methods 10, 10A, or
10B of Appendix A–4 to part 60 for
conducting the relative accuracy
evaluations.
(3) A CO CEMS need not be installed
if the owner or operator demonstrates
that all hourly average CO emissions are
and will remain less than 50 ppmv (dry
basis) corrected to 0 percent excess air.
The Administrator may revoke this
exemption from monitoring upon a
determination that CO emissions on an
hourly average basis have exceeded 50
ppmv (dry basis) corrected to 0 percent
excess air, in which case a CO CEMS
shall be installed within 180 days.
(i) The demonstration shall consist of
continuously monitoring CO emissions
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for 30 days using an instrument that
meets the requirements of Performance
Specification 4 or 4A of Appendix B to
part 60. The span value shall be 100
ppm CO instead of 1,000 ppm, and the
relative accuracy limit shall be 10
percent of the average CO emissions or
5 ppm CO, whichever is greater. For
instruments that are identical to Method
10 of Appendix A–4 to part 60 and
employ the sample conditioning system
of Method 10A of Appendix A–4 to part
60, the alternative relative accuracy test
procedure in section 10.1 of
Performance Specification 2 of
Appendix B to part 60 may be used in
place of the relative accuracy test.
(ii) The owner or operator must
submit the following information to the
Administrator:
(A) The measurement data specified
in paragraph (h)(3)(i) of this section
along with all other operating data
known to affect CO emissions; and
(B) Descriptions of the CPMS for
exhaust gas temperature and O2 monitor
required in paragraph (h)(4) of this
section and operating limits for those
parameters to ensure combustion
conditions remain similar to those that
exist during the demonstration period.
(iii) The effective date of the
exemption from installation and
operation of a CO CEMS is the date of
submission of the information and data
required in paragraph (h)(3)(ii) of this
section.
(4) The owner or operator of a FCCU
or FCU that is exempted from the
requirement to install and operate a CO
CEMS in paragraph (h)(3) of this section
shall install, operate, calibrate, and
maintain CPMS to measure and record
the operating parameters in paragraph
(h)(4)(i) or (ii) of this section. The owner
or operator shall install, operate, and
maintain each CPMS according to the
manufacturer’s specifications.
(i) For a FCCU or FCU with no postcombustion control device, the
temperature and O2 concentration of the
exhaust gas stream exiting the unit.
(ii) For a FCCU or FCU with a postcombustion control device, the
temperature and O2 concentration of the
exhaust gas stream exiting the control
device.
(i) Excess emissions. For the purpose
of reports required by § 60.7(c), periods
of excess emissions for a FCCU or FCU
subject to the emissions limitations in
§ 60.102a(b) are defined as specified in
paragraphs (i)(1) through (6) of this
section. Note: Determine all averages,
except for opacity, as the arithmetic
average of the applicable 1-hour
averages, e.g., determine the rolling 3hour average as the arithmetic average
of three contiguous 1-hour averages.
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(1) If a CPMS is used according to
§ 60.105a(b)(1), all 3-hour periods
during which the average PM control
device operating characteristics, as
measured by the continuous monitoring
systems under § 60.105a(b)(1), fall
below the levels established during the
performance test.
(2) If a PM CEMS is used according to
§ 60.105a(d), all 7-day periods during
which the average PM emission rate, as
measured by the continuous PM
monitoring system under § 60.105a(d)
exceeds 0.040 gr/dscf corrected to 0
percent excess air for a modified or
reconstructed FCCU, 0.020 gr/dscf
corrected to 0 percent excess air for a
newly constructed FCCU, or 0.040 gr/
dscf for an affected fluid coking unit.
(3) If a COMS is used according to
§ 60.105a(e), all 3-hour periods during
which the average opacity, as measured
by the COMS under § 60.105a(e),
exceeds the site-specific limit
established during the most recent
performance test.
(4) All rolling 7-day periods during
which the average concentration of NOX
as measured by the NOX CEMS under
§ 60.105a(f) exceeds 80 ppmv for an
affected FCCU or FCU.
(5) Except as provided in paragraph
(i)(7) of this section, all rolling 7-day
periods during which the average
concentration of SO2 as measured by the
SO2 CEMS under § 60.105a(g) exceeds
50 ppmv, and all rolling 365-day
periods during which the average
concentration of SO2 as measured by the
SO2 CEMS exceeds 25 ppmv.
(6) All 1-hour periods during which
the average CO concentration as
measured by the CO continuous
monitoring system under §1A60.105a(h)
exceeds 500 ppmv or, if applicable, all
1-hour periods during which the
average temperature and O2
concentration as measured by the
continuous monitoring systems under
§ 60.105a(h)(4) fall below the operating
limits established during the
performance test.
ebenthall on PRODPC60 with RULES4
§ 60.106a Monitoring of emissions and
operations for sulfur recovery plants.
(a) The owner or operator of a sulfur
recovery plant that is subject to the
emissions limits in § 60.102a(f)(1) or
§ 60.102a(f)(2) shall:
(1) For sulfur recovery plants subject
to the SO2 emission limit in
§ 60.102a(f)(1)(i) or § 60.102a(f)(2)(i), the
owner or operator shall install, operate,
calibrate, and maintain an instrument
for continuously monitoring and
recording the concentration (dry basis,
zero percent excess air) of any SO2
emissions into the atmosphere. The
monitor shall include an oxygen
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monitor for correcting the data for
excess air.
(i) The span values for this monitor
are two times the applicable SO2
emission limit and between 10 and 25
percent O2, inclusive.
(ii) The owner or operator shall
install, operate, and maintain each SO2
CEMS according to Performance
Specification 2 of Appendix B to part
60.
(iii) The owner or operator shall
conduct performance evaluations of
each SO2 monitor according to the
requirements in § 60.13(c) and
Performance Specification 2 of
Appendix B to part 60. The owner or
operator shall use Methods 6 or 6C of
Appendix A–4 to part 60 and Method 3
or 3A of Appendix A–2 of part 60 for
conducting the relative accuracy
evaluations. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 6.
(2) For sulfur recovery plants that are
subject to the reduced sulfur compound
and H2S emission limit in
§ 60.102a(f)(1)(ii) or § 60.102a(f)(2)(ii),
the owner or operator shall install,
operate, calibrate, and maintain an
instrument for continuously monitoring
and recording the concentration of
reduced sulfur, H2S, and O2 emissions
into the atmosphere. The reduced sulfur
emissions shall be calculated as SO2
(dry basis, zero percent excess air).
(i) The span values for this monitor
are two times the applicable reduced
sulfur emission limit, two times the H2S
emission limit, and between 10 and 25
percent O2, inclusive.
(ii) The owner or operator shall
install, operate, and maintain each
reduced sulfur CEMS according to
Performance Specification 5 of
Appendix B to part 60.
(iii) The owner or operator shall
conduct performance evaluations of
each reduced sulfur monitor according
to the requirements in § 60.13(c) and
Performance Specification 5 of
Appendix B to part 60. The owner or
operator shall use Methods 15 or 15A of
Appendix A–5 to part 60 for conducting
the relative accuracy evaluations. The
method ANSI/ASME PTC 19.10–1981,
‘‘Flue and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 15A of Appendix A–5 to part
60.
(iv) The owner or operator shall
install, operate, and maintain each H2S
CEMS according to Performance
Specification 7 of Appendix B to part
60.
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(v) The owner or operator shall
conduct performance evaluations of
each reduced sulfur monitor according
to the requirements in § 60.13(c) and
Performance Specification 5 of
Appendix B to part 60. The owner or
operator shall use Methods 11, 15, or
15A of Appendix A–5 to part 60 or
Method 16 of Appendix A–6 to part 60
for conducting the relative accuracy
evaluations. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 15A of Appendix A–5
to part 60.
(vi) The owner or operator shall
install, operate, and maintain each O2
monitor according to Performance
Specification 3 of Appendix B to part
60.
(vii) The span value for the O2
monitor must be selected between 10
and 25 percent, inclusive.
(viii) The owner or operator shall
conduct performance evaluations for the
O2 monitor according to the
requirements of § 60.13(c) and
Performance Specification 3 of
Appendix B to part 60. The owner or
operator shall use Methods 3, 3A, or 3B
of Appendix A–2 to part 60 for
conducting the relative accuracy
evaluations. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 3B of Appendix A–2 to
part 60.
(ix) The owner or operator shall
comply with the applicable quality
assurance procedures of Appendix F to
part 60 for each monitor, including
annual accuracy determinations for each
O2 monitor, and daily calibration drift
determinations.
(3) In place of the reduced sulfur
monitor required in paragraph (a)(2) of
this section, the owner or operator shall
install, calibrate, operate, and maintain
an instrument using an air or O2
dilution and oxidation system to
convert any reduced sulfur to SO2 for
continuously monitoring and recording
the concentration (dry basis, 0 percent
excess air) of the total resultant SO2.
The monitor must include an O2
monitor for correcting the data for
excess O2.
(i) The span value for this monitor is
two times the applicable SO2 emission
limit.
(ii) The owner or operator shall
conduct performance evaluations of
each SO2 monitor according to the
requirements in § 60.13(c) and
Performance Specification 5 of
Appendix B to part 60. The owner or
operator shall use Methods 15 or 15A of
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Appendix A–5 to part 60 for conducting
the relative accuracy evaluations. The
method ANSI/ASME PTC 19.10–1981,
‘‘Flue and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 15A of Appendix A–5 to part
60.
(iii) The owner or operator shall
install, operate, and maintain each O2
monitor according to Performance
Specification 3 of Appendix B to part
60.
(iv) The span value for the O2 monitor
must be selected between 10 and 25
percent, inclusive.
(v) The owner or operator shall
conduct performance evaluations for the
O2 monitor according to the
requirements of § 60.13(c) and
Performance Specification 3 of
Appendix B to part 60. The owner or
operator shall use Methods 3, 3A, or 3B
of Appendix A–2 to part 60 for
conducting the relative accuracy
evaluations. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 3B of Appendix A–2 to
part 60.
(vi) The owner or operator shall
comply with the applicable quality
assurance procedures of Appendix F to
part 60 for each monitor, including
quarterly accuracy determinations for
each SO2 monitor, annual accuracy
determinations for each O2 monitor, and
daily calibration drift determinations.
(b) Excess emissions. For the purpose
of reports required by § 60.7(c), periods
of excess emissions for sulfur recovery
plants subject to the emissions
limitations in § 60.102a(f) are defined as
specified in paragraphs (b)(1) through
(3) of this section. Note: Determine all
averages as the arithmetic average of the
applicable 1-hour averages, e.g.,
determine the rolling 12-hour average as
the arithmetic average of 12 contiguous
1-hour averages.
(1) All 12-hour periods during which
the average concentration of SO2 as
measured by the SO2 continuous
monitoring system required under
paragraph (a)(1) of this section exceeds
the applicable emission limit (dry basis,
zero percent excess air); or
(2) All 12-hour periods during which
the average concentration of reduced
sulfur (as SO2) as measured by the
reduced sulfur continuous monitoring
system required under paragraph (a)(2)
of this section exceeds the applicable
emission limit; or
(3) All 12-hour periods during which
the average concentration of H2S as
measured by the H2S continuous
monitoring system required under
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paragraph (a)(2) of this section exceeds
the applicable emission limit (dry basis,
0 percent excess air).
§ 60.107a Monitoring of emissions and
operations for fuel gas combustion devices.
(a) Fuel gas combustion devices
subject to SO2 or H2S limit. The owner
or operator of a fuel gas combustion
device that is subject to the
requirements in § 60.102a(g) shall
comply with the requirements in
paragraph (a)(1) of this section for SO2
emissions or paragraph (a)(2) of this
section for H2S emissions.
(1) The owner or operator of a fuel gas
combustion device subject to the SO2
emissions limits in § 60.102a(g)(1)(i)
shall install, operate, calibrate, and
maintain an instrument for
continuously monitoring and recording
the concentration (dry basis, 0 percent
excess air) of SO2 emissions into the
atmosphere. The monitor must include
an O2 monitor for correcting the data for
excess air.
(i) The owner or operator shall install,
operate, and maintain each SO2 monitor
according to Performance Specification
2 of Appendix B to part 60. The span
value for the SO2 monitor is 50 ppm
SO2.
(ii) The owner or operator shall
conduct performance evaluations for the
SO2 monitor according to the
requirements of § 60.13(c) and
Performance Specification 2 of
Appendix B to part 60. The owner or
operator shall use Methods 6, 6A, or 6C
of Appendix A–4 to part 60 for
conducting the relative accuracy
evaluations. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 6 or 6A of Appendix A–
4 to part 60. Samples taken by Method
6 of Appendix A–4 to part 60 shall be
taken at a flow rate of approximately 2
liters/min for at least 30 minutes. The
relative accuracy limit shall be 20
percent or 4 ppm, whichever is greater,
and the calibration drift limit shall be 5
percent of the established span value.
(iii) The owner or operator shall
install, operate, and maintain each O2
monitor according to Performance
Specification 3 of Appendix B to part
60. The span value for the O2 monitor
must be selected between 10 and 25
percent, inclusive.
(iv) The owner or operator shall
conduct performance evaluations for the
O2 monitor according to the
requirements of § 60.13(c) and
Performance Specification 3 of
Appendix B to part 60. The owner or
operator shall use Methods 3, 3A, or 3B
of Appendix A–2 to part 60 for
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conducting the relative accuracy
evaluations. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 3B of Appendix A–2 to
part 60.
(v) The owner or operator shall
comply with the applicable quality
assurance procedures in Appendix F to
part 60, including quarterly accuracy
determinations for SO2 monitors, annual
accuracy determinations for O2
monitors, and daily calibration drift
tests.
(vi) Fuel gas combustion devices
having a common source of fuel gas may
be monitored at only one location (i.e.,
after one of the combustion devices), if
monitoring at this location accurately
represents the SO2 emissions into the
atmosphere from each of the
combustion devices.
(2) The owner or operator of a fuel gas
combustion device subject to the H2S
concentration limits in
§ 60.102a(g)(1)(ii) shall install, operate,
calibrate, and maintain an instrument
for continuously monitoring and
recording the concentration by volume
(dry basis) of H2S in the fuel gases
before being burned in any fuel gas
combustion device.
(i) The owner or operator shall install,
operate, and maintain each H2S monitor
according to Performance Specification
7 of Appendix B to part 60. The span
value for this instrument is 320 ppmv
H2S.
(ii) The owner or operator shall
conduct performance evaluations for
each H2S monitor according to the
requirements of § 60.13(c) and
Performance Specification 7 of
Appendix B to part 60. The owner or
operator shall use Method 11, 15, or
15A of Appendix A–5 to part 60 or
Method 16 of Appendix A–6 to part 60
for conducting the relative accuracy
evaluations. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 15A of Appendix A–5
to part 60.
(iii) The owner or operator shall
comply with the applicable quality
assurance procedures in Appendix F to
part 60 for each H2S monitor.
(iv) Fuel gas combustion devices
having a common source of fuel gas may
be monitored at only one location, if
monitoring at this location accurately
represents the concentration of H2S in
the fuel gas being burned.
(3) The owner or operator of a fuel gas
combustion device is not required to
comply with paragraph (a)(1) or (2) of
this section for fuel gas streams that are
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exempt under § 60.102a(h) and fuel gas
streams combusted in a process heater
or other fuel gas combustion device that
are inherently low in sulfur content.
Fuel gas streams meeting one of the
requirements in paragraphs (a)(3)(i)
through (iv) of this section will be
considered inherently low in sulfur
content.
(i) Pilot gas for heaters and flares.
(ii) Fuel gas streams that meet a
commercial-grade product specification
for sulfur content of 30 ppmv or less. In
the case of a liquefied petroleum gas
(LPG) product specification in the
pressurized liquid state, the gas phase
sulfur content should be evaluated
assuming complete vaporization of the
LPG and sulfur containing-compounds
at the product specification
concentration.
(iii) Fuel gas streams produced in
process units that are intolerant to
sulfur contamination, such as fuel gas
streams produced in the hydrogen plant,
catalytic reforming unit, isomerization
unit, and HF alkylation process units.
(iv) Other fuel gas streams that an
owner or operator demonstrates are lowsulfur according to the procedures in
paragraph (b) of this section.
(4) If the composition of an exempt
fuel gas stream changes, the owner or
operator must follow the procedures in
paragraph (b)(3) of this section.
(b) Exemption from H2S monitoring
requirements for low-sulfur fuel gas
streams. The owner or operator of a fuel
gas combustion device may apply for an
exemption from the H2S monitoring
requirements in paragraph (a)(2) of this
section for a fuel gas stream that is
inherently low in sulfur content. A fuel
gas stream that is demonstrated to be
low-sulfur is exempt from the
monitoring requirements of paragraphs
(a)(1) and (2) of this section until there
are changes in operating conditions or
stream composition.
(1) The owner or operator shall
submit to the Administrator a written
application for an exemption from
monitoring. The application must
contain the following information:
(i) A description of the fuel gas
stream/system to be considered,
including submission of a portion of the
appropriate piping diagrams indicating
the boundaries of the fuel gas stream/
system, and the affected fuel gas
combustion device(s) to be considered;
(ii) A statement that there are no
crossover or entry points for sour gas
(high H2S content) to be introduced into
the fuel gas stream/system (this should
be shown in the piping diagrams);
(iii) An explanation of the conditions
that ensure low amounts of sulfur in the
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fuel gas stream (i.e., control equipment
or product specifications) at all times;
(iv) The supporting test results from
sampling the requested fuel gas stream/
system demonstrating that the sulfur
content is less than 5 ppm H2S.
Sampling data must include, at
minimum, 2 weeks of daily monitoring
(14 grab samples) for frequently
operated fuel gas streams/systems; for
infrequently operated fuel gas streams/
systems, seven grab samples must be
collected unless other additional
information would support reduced
sampling. The owner or operator shall
use detector tubes (‘‘length-of-stain
tube’’ type measurement) following the
‘‘Gas Processors Association Standard
2377–86, Test for Hydrogen Sulfide and
Carbon Dioxide in Natural Gas Using
Length of Stain Tubes,’’ 1986 Revision
(incorporated by reference—see § 60.17),
with ranges 0–10/0–100 ppm (N = 10/
1) to test the applicant fuel gas stream
for H2S; and
(v) A description of how the 2 weeks
(or seven samples for infrequently
operated fuel gas streams/systems) of
monitoring results compares to the
typical range of H2S concentration (fuel
quality) expected for the fuel gas
stream/system going to the affected fuel
gas combustion device (e.g., the 2 weeks
of daily detector tube results for a
frequently operated loading rack
included the entire range of products
loaded out, and, therefore, should be
representative of typical operating
conditions affecting H2S content in the
fuel gas stream going to the loading rack
flare).
(2) The effective date of the
exemption is the date of submission of
the information required in paragraph
(b)(1) of this section.
(3) No further action is required
unless refinery operating conditions
change in such a way that affects the
exempt fuel gas stream/system (e.g., the
stream composition changes). If such a
change occurs, the owner or operator
shall follow the procedures in paragraph
(b)(3)(i), (b)(3)(ii), or (b)(3)(iii) of this
section.
(i) If the operation change results in
a sulfur content that is still within the
range of concentrations included in the
original application, the owner or
operator shall conduct an H2S test on a
grab sample and record the results as
proof that the concentration is still
within the range.
(ii) If the operation change results in
a sulfur content that is outside the range
of concentrations included in the
original application, the owner or
operator may submit new information
following the procedures of paragraph
(b)(1) of this section within 60 days (or
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35879
within 30 days after the seventh grab
sample is tested for infrequently
operated process units).
(iii) If the operation change results in
a sulfur content that is outside the range
of concentrations included in the
original application, and the owner or
operator chooses not to submit new
information to support an exemption,
the owner or operator must begin H2S
monitoring using daily stain sampling to
demonstrate compliance. The owner or
operator must begin monitoring
according to the requirements in
paragraphs (a)(1) or (a)(2) of this section
as soon as practicable but in no case
later than 180 days after the operation
change. During daily stain tube
sampling, a daily sample exceeding 162
ppmv is an exceedance of the 3-hour
H2S concentration limit. The owner or
operator must determine a rolling 365day average using the stain sampling
results; an average H2S concentration of
5 ppmv must be used for days prior to
the operation change.
(c) Process heaters subject to NOX
limit. The owner or operator of a process
heater subject to the NOX emission limit
in § 60.102a(g)(2) shall install, operate,
calibrate, and maintain an instrument
for continuously monitoring and
recording the concentration (dry basis, 0
percent excess air) of NOX emissions
into the atmosphere. The monitor must
include an O2 monitor for correcting the
data for excess air.
(1) The owner or operator shall
install, operate, and maintain each NOX
monitor according to Performance
Specification 2 of Appendix B to part
60. The span value of this NOX monitor
is 200 ppmv NOX.
(2) The owner or operator shall
conduct performance evaluations of
each NOX monitor according to the
requirements in § 60.13(c) and
Performance Specification 2 of
Appendix B to part 60. The owner or
operator shall use Methods 7, 7A, 7C,
7D, or 7E of Appendix A–4 to part 60
for conducting the relative accuracy
evaluations. The method ANSI/ASME
PTC 19.10–1981, ‘‘Flue and Exhaust Gas
Analyses,’’ (incorporated by reference—
see § 60.17) is an acceptable alternative
to EPA Method 7 or 7C of Appendix A–
4 to part 60.
(3) The owner or operator shall
install, operate, and maintain each O2
monitor according to Performance
Specification 3 of Appendix B to part
60. The span value of this O2 monitor
must be selected between 10 and 25
percent, inclusive.
(4) The owner or operator shall
conduct performance evaluations of
each O2 monitor according to the
requirements in § 60.13(c) and
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Performance Specification 3 of
Appendix B to part 60. Method 3, 3A,
or 3B of Appendix A–2 to part 60 shall
be used for conducting the relative
accuracy evaluations. The method
ANSI/ASME PTC 19.10–1981, ‘‘Flue
and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 3B of Appendix A–2 to part 60.
(5) The owner or operator shall
comply with the quality assurance
requirements in Procedure 1 of
Appendix F to part 60 for each NOX and
O2 monitor, including quarterly
accuracy determinations for NOX
monitors, annual accuracy
determinations for O2 monitors, and
daily calibration drift tests.
(6) The owner or operator of a process
heater that has a rated heating capacity
of less than 100 MMBtu and is equipped
with low-NOX burners (LNB) or ultra
low-NOX burners (ULNB) is not subject
to the monitoring requirements in
paragraphs (c)(1) through (5) of this
section. The owner or operator of such
a process heater must conduct biennial
performance tests to demonstrate
compliance.
(d) Sulfur monitoring for affected
flares. The owner or operator of an
affected flare subject to § 60.103a(b)
shall install, operate, calibrate, and
maintain an instrument for
continuously monitoring and recording
the concentration of reduced sulfur in
flare gas. The owner or operator of a
modified flare shall install this
instrument by no later than 1 year after
the flare becomes an affected flare
subject to this subpart.
(1) The owner or operator shall
install, operate, and maintain each
reduced sulfur CEMS according to
Performance Specification 5 of
Appendix B to part 60.
(2) The owner or operator shall
conduct performance evaluations of
each reduced sulfur monitor according
to the requirements in § 60.13(c) and
Performance Specification 5 of
Appendix B to part 60. The owner or
operator shall use Methods 15 or 15A of
Appendix A–5 to part 60 for conducting
the relative accuracy evaluations. The
method ANSI/ASME PTC 19.10–1981,
‘‘Flue and Exhaust Gas Analyses,’’
(incorporated by reference—see § 60.17)
is an acceptable alternative to EPA
Method 15A of Appendix A–5 to part
60.
(3) The owner or operator shall
comply with the applicable quality
assurance procedures in Appendix F to
part 60 for each reduced sulfur monitor.
(e) Flow monitoring for flares. The
owner or operator of an affected flare
subject to § 60.102a(g)(3) shall install,
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operate, calibrate, and maintain CPMS
to measure and record the exhaust gas
flow rate. The owner or operator of a
modified flare shall install this
instrument by no later than 1 year after
the flare becomes an affected flare
subject to this subpart.
(1) The CPMS must be able to correct
for the temperature and pressure of the
system and output flow in standard
conditions as defined in § 60.2.
(2) The owner or operator shall
install, operate, and maintain each
CPMS according to the manufacturer’s
specifications and requirements.
(f) Excess emissions. For the purpose
of reports required by § 60.7(c), periods
of excess emissions for fuel gas
combustion devices subject to the
emissions limitations in § 60.102a(g) are
defined as specified in paragraphs (f)(1)
through (4) of this section. Note:
Determine all averages as the arithmetic
average of the applicable 1-hour
averages, e.g., determine the rolling 3hour average as the arithmetic average
of three contiguous 1-hour averages.
(1) All rolling 3-hour periods during
which the average concentration of SO2
as measured by the SO2 continuous
monitoring system required under
paragraph (a)(1) of this section exceeds
20 ppmv, and all rolling 365-day
periods during which the average
concentration as measured by the SO2
continuous monitoring system required
under paragraph (a)(1) of this section
exceeds 8 ppmv; or
(2) All rolling 3-hour periods during
which the average concentration of H2S
as measured by the H2S continuous
monitoring system required under
paragraph (a)(2) of this section exceeds
162 ppmv, all days in which the
concentration of H2S as measured by
daily stain tube sampling required
under paragraph (b)(3)(iii) of this
section exceeds 162 ppmv, and all
rolling 365-day periods during which
the average concentration as measured
by the H2S continuous monitoring
system under paragraph (a)(2) of this
section exceeds 60 ppmv.
(3) All rolling 24-hour periods during
which the average concentration of NOX
as measured by the NOX continuous
monitoring system required under
paragraph (c) of this section exceeds 40
ppmv.
(4) All rolling 30-day periods during
which the average flow rate to an
affected flare as measured by the
monitoring system required under
paragraph (e) of this section exceeds
250,000 scfd.
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§ 60.108a Recordkeeping and reporting
requirements.
(a) Each owner or operator subject to
the emissions limitations in § 60.102a
shall comply with the notification,
recordkeeping, and reporting
requirements in § 60.7 and other
requirements as specified in this
section.
(b) Each owner or operator subject to
an emissions limitation in § 60.102a
shall notify the Administrator of the
specific monitoring provisions of
§§ 60.105a, 60.106a, and 60.107a with
which the owner or operator seeks to
comply. Notification shall be submitted
with the notification of initial startup
required by § 60.7(a)(3).
(c) The owner or operator shall
maintain the following records:
(1) A copy of the flare management
plan and each root cause analysis of a
discharge;
(2) Records of information to
document conformance with bag leak
detection system operation and
maintenance requirements in
§ 60.105a(c).
(3) Records of bag leak detection
system alarms and actions according to
§ 60.105a(c).
(4) For each FCCU and fluid coking
unit subject to the monitoring
requirements in § 60.105a(b)(1), records
of the average coke burn-off rate and
hours of operation.
(5) For each fuel gas stream to which
one of the exemptions listed in
§ 60.107a(a)(3) applies, records of the
specific exemption determined to apply
for each fuel stream. If the owner or
operator applies for the exemption
described in § 60.107a(a)(3)(iv), the
owner or operator must keep a copy of
the application as well as the letter from
the Administrator granting approval of
the application.
(6) The owner or operator shall record
and maintain records of discharges
greater than 500 lb/day SO2 from any
affected fuel gas combustion device or
sulfur recovery plant and discharges to
an affected flare in excess of 500,000
scfd. These records shall include:
(i) A description of the discharge.
(ii) For discharges greater than 500 lb/
day SO2, the date and time the discharge
was first identified and the duration of
the discharge.
(iii) The measured or calculated
cumulative quantity of gas discharged
over the discharge duration. If the
discharge duration exceeds 24 hours,
record the discharge quantity for each
24-hour period. Engineering
calculations are allowed for fuel gas
combustion devices other than flares.
(iv) For discharges greater than 500
lb/day SO2, the measured or estimated
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concentration of H2S, TRS and SO2 of
the stream discharged. Process
knowledge can be used to make these
estimates for fuel gas combustion
devices other than flares.
(v) For discharges greater than 500 lb/
day SO2, the cumulative quantity of H2S
and SO2 released into the atmosphere.
For releases controlled by flares, assume
99 percent conversion of reduced sulfur
to SO2. For other fuel gas combustion
devices, assume 99 percent conversion
of H2S to SO2.
(vi) Results of any root-cause analysis
conducted as required in § 60.103a(a)(4)
and § 60.103a(b).
(d) Each owner or operator subject to
this subpart shall submit an excess
emissions report for all periods of
excess emissions according to the
requirements of § 60.7(c) except that the
report shall contain the information
specified in paragraphs (d)(1) through
(7) of this section.
(1) The date that the exceedance
occurred;
(2) An explanation of the exceedance;
(3) Whether the exceedance was
concurrent with a startup, shutdown, or
malfunction of an affected facility or
control system; and
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(4) A description of the action taken,
if any.
(5) A root-cause summary report that
provides the information described in
paragraph (e)(6) of this section for all
discharges for which a root-cause
analysis was required by § 60.103a(a)(4)
and § 60.103a(b).
(6) For any periods for which
monitoring data are not available, any
changes made in operation of the
emission control system during the
period of data unavailability which
could affect the ability of the system to
meet the applicable emission limit.
Operations of the control system and
affected facility during periods of data
unavailability are to be compared with
operation of the control system and
affected facility before and following the
period of data unavailability.
(7) A written statement, signed by a
responsible official, certifying the
accuracy and completeness of the
information contained in the report.
§ 60.109a
Delegation of authority.
(a) This subpart can be implemented
and enforced by the U.S. EPA or a
delegated authority such as a State,
local, or tribal agency. You should
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35881
contact your U.S. EPA Regional Office
to find out if this subpart is delegated
to a State, local, or tribal agency within
your State.
(b) In delegating implementation and
enforcement authority of this subpart to
a State, local, or tribal agency, the
approval authorities contained in
paragraphs (b)(1) through (3) of this
section are retained by the
Administrator of the U.S. EPA and are
not transferred to the State, local, or
tribal agency.
(1) Approval of a major change to test
methods under § 60.8(b). A ‘‘major
change to test method’’ is defined in 40
CFR 63.90.
(2) Approval of a major change to
monitoring under § 60.13(i). A ‘‘major
change to monitoring’’ is defined in 40
CFR 63.90.
(3) Approval of a major change to
recordkeeping/reporting under § 60.7(b)
through (f). A ‘‘major change to
recordkeeping/reporting’’ is defined in
40 CFR 63.90.
[FR Doc. E8–13498 Filed 6–23–08; 8:45 am]
BILLING CODE 6560–50–P
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Agencies
[Federal Register Volume 73, Number 122 (Tuesday, June 24, 2008)]
[Rules and Regulations]
[Pages 35838-35881]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: E8-13498]
[[Page 35837]]
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Part IV
Environmental Protection Agency
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40 CFR Part 60
Standards of Performance for Petroleum Refineries; Final Rule
Federal Register / Vol. 73, No. 122 / Tuesday, June 24, 2008 / Rules
and Regulations
[[Page 35838]]
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ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 60
[EPA-HQ-OAR-2007-0011; FRL-8563-2]
RIN 2060-AN72
Standards of Performance for Petroleum Refineries
AGENCY: Environmental Protection Agency (EPA).
ACTION: Final rule.
-----------------------------------------------------------------------
SUMMARY: EPA is issuing final amendments to the current Standards of
Performance for Petroleum Refineries. This action also promulgates
separate standards of performance for new, modified, or reconstructed
process units at petroleum refineries. The final standards for new
process units include emissions limitations and work practice standards
for fluid catalytic cracking units, fluid coking units, delayed coking
units, fuel gas combustion devices, and sulfur recovery plants. These
final standards reflect demonstrated improvements in emissions control
technologies and work practices that have occurred since promulgation
of the current standards.
DATES: These final rules are effective on June 24, 2008. The
incorporation by reference of certain publications listed in the final
rules is approved by the Director of the Federal Register as of June
24, 2008.
ADDRESSES: EPA has established a docket for this action under Docket ID
No. EPA-HQ-OAR-2007-0011. All documents in the docket are listed in the
www.regulations.gov index. Although listed in the index, some
information is not publicly available, e.g., confidential business
information or other information whose disclosure is restricted by
statute. Certain other material, such as copyrighted material, is not
placed on the Internet and will be publicly available only in hard copy
form. Publicly available docket materials are available either
electronically in www.regulations.gov or in hard copy at the EPA Docket
Center, Standards of Performance for Petroleum Refineries Docket, EPA
West Building, Room 3334, 1301 Constitution Ave., NW., Washington, DC.
The Public Reading Room is open from 8:30 a.m. to 4:30 p.m., Monday
through Friday, excluding legal holidays. The telephone number for the
Public Reading Room is (202) 566-1744, and the telephone number for the
Air Docket is (202) 566-1742.
FOR FURTHER INFORMATION CONTACT: Mr. Robert B. Lucas, Office of Air
Quality Planning and Standards, Sector Policies and Programs Division,
Coatings and Chemicals Group (E143-01), Environmental Protection
Agency, Research Triangle Park, NC 27711, telephone number: (919) 541-
0884; fax number: (919) 541-0246; e-mail address: lucas.bob@epa.gov.
SUPPLEMENTARY INFORMATION:
I. General Information
A. Does this action apply to me?
Categories and entities potentially regulated by these final rules
include:
------------------------------------------------------------------------
Examples
of
Category NAICS code \1\ regulated
entities
------------------------------------------------------------------------
Industry 32411.............................................. Petroleum
refiners.
Federal ................................................... Not
governm affected.
ent
State/ ................................................... Not
local/ affected.
tribal
governm
ent
------------------------------------------------------------------------
\1\ North American Industry Classification System.
This table is not intended to be exhaustive, but rather provides a
guide for readers regarding entities likely to be regulated by this
action. To determine whether your facility would be regulated by this
action, you should examine the applicability criteria in 40 CFR 60.100
and 40 CFR 60.100a. If you have any questions regarding the
applicability of this proposed action to a particular entity, contact
the person listed in the preceding FOR FURTHER INFORMATION CONTACT
section.
B. Where can I get a copy of this document?
In addition to being available in the docket, an electronic copy of
this final action is available on the Worldwide Web (WWW) through the
Technology Transfer Network (TTN). Following signature, a copy of this
final action will be posted on the TTN's policy and guidance page for
newly proposed or promulgated rules at https://www.epa.gov/ttn/oarpg.
The TTN provides information and technology exchange in various areas
of air pollution control.
C. Judicial Review
Under section 307(b)(1) of the Clean Air Act (CAA), judicial review
of these final rules is available only by filing a petition for review
in the United States Court of Appeals for the District of Columbia
Circuit by August 25, 2008. Under section 307(b)(2) of the CAA, the
requirements established by these final rules may not be challenged
separately in any civil or criminal proceedings brought by EPA to
enforce these requirements.
Section 307(d)(7)(B) of the CAA further provides that ``[o]nly an
objection to a rule or procedure which was raised with reasonable
specificity during the period for public comment (including any public
hearing) may be raised during judicial review.'' This section also
provides a mechanism for us to convene a proceeding for
reconsideration, ``[i]f the person raising an objection can demonstrate
to the EPA that it was impracticable to raise such objection within
[the period for public comment] or if the grounds for such objection
arose after the period for public comment (but within the time
specified for judicial review) and if such objection is of central
relevance to the outcome of the rule.'' Any person seeking to make such
a demonstration to us should submit a Petition for Reconsideration to
the Office of the Administrator, U.S. EPA, Room 3000, Ariel Rios
Building, 1200 Pennsylvania Ave., NW., Washington, DC 20460, with a
copy to both the person(s) listed in the preceding FOR FURTHER
INFORMATION CONTACT section, and the Associate General Counsel for the
Air and Radiation Law Office, Office of General Counsel (Mail Code
2344A), U.S. EPA, 1200 Pennsylvania Ave., NW., Washington, DC 20460.
D. How is this document organized?
The information presented in this preamble is organized as follows:
I. General Information
A. Does this action apply to me?
B. Where can I get a copy of this document?
C. Judicial Review
D. How is this document organized?
II. Background Information
III. Summary of the Final Rules and Changes Since Proposal
A. What are the final amendments to the standards for petroleum
refineries (40 CFR part 60, subpart J)?
B. What are the final requirements for new fluid catalytic
cracking units and new fluid coking units (40 CFR part 60, subpart
Ja)?
C. What are the final requirements for new sulfur recovery
plants (40 CFR part 60, subpart Ja)?
D. What are the final requirements for new fuel gas combustion
devices (40 CFR part 60, subpart Ja)?
E. What are the final work practice standards (40 CFR part 60,
subpart Ja)?
F. What are the modification and reconstruction provisions?
IV. Summary of Significant Comments and Responses
A. PM Limits for Fluid Catalytic Cracking Units
B. SO2 Limits for Fluid Catalytic Cracking Units
C. NOX Limit for Fluid Catalytic Cracking Units
[[Page 35839]]
D. PM and SO2 Limits for Fluid Coking Units
E. NOX Limit for Fluid Coking Units
F. SO2 Limits for Sulfur Recovery Plants
G. NOX Limit for Process Heaters
H. Fuel Gas Combustion Devices
I. Flares
J. Delayed Coking Units
K. Other Comments
V. Summary of Cost, Environmental, Energy, and Economic Impacts
A. What are the impacts for petroleum refineries?
B. What are the secondary impacts?
C. What are the economic impacts?
D. What are the benefits?
VI. Statutory and Executive Order Reviews
A. Executive Order 12866: Regulatory Planning and Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act
D. Unfunded Mandates Reform Act
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation and Coordination With
Indian Tribal Governments
G. Executive Order 13045: Protection of Children From
Environmental Health Risks and Safety Risks
H. Executive Order 13211: Actions Concerning Regulations That
Significantly Affect Energy Supply, Distribution, or Use
I. National Technology Transfer and Advancement Act
J. Executive Order 12898: Federal Actions to Address
Environmental Justice in Minority Populations and Low-Income
Populations
K. Congressional Review Act
II. Background Information
New source performance standards (NSPS) implement CAA section
111(b) and are issued for categories of sources which cause, or
contribute significantly to, air pollution which may reasonably be
anticipated to endanger public health or welfare. The primary purpose
of the NSPS is to attain and maintain ambient air quality by ensuring
that the best demonstrated emission control technologies are installed
as the industrial infrastructure is modernized. Since 1970, the NSPS
have been successful in achieving long-term emissions reductions in
numerous industries by assuring cost-effective controls are installed
on new, reconstructed, or modified sources.
Section 111 of the CAA requires that NSPS reflect the application
of the best system of emission reductions which (taking into
consideration the cost of achieving such emission reductions, any non-
air quality health and environmental impact and energy requirements)
the Administrator determines has been adequately demonstrated. This
level of control is commonly referred to as best demonstrated
technology (BDT).
Section 111(b)(1)(B) of the CAA requires EPA to periodically review
and revise the standards of performance, as necessary, to reflect
improvements in methods for reducing emissions. As a result of our
periodic review of the NSPS for petroleum refineries (40 CFR part 60,
subpart J), we proposed amendments to the current standards of
performance and separate standards of performance for new process units
(72 FR 27278, May 14, 2007). In response to several requests, we
extended the 60-day comment period from July 13, 2007, to August 27,
2007 (72 FR 35375, June 28, 2007). We also issued a notice of data
availability (NODA) (72 FR 69175, December 7, 2007) to notify the
public that additional information had been added to the docket; the
NODA also extended the public comment period on the proposed rule to
January 7, 2008. We received a total of 38 comments from refineries,
industry trade associations, and consultants; State and local
environmental and public health agencies; environmental groups; and
members of the public during the extended comment period, and 8
additional comments on the NODA. These final rules reflect our full
consideration of all of the comments we received. Detailed responses to
the comments not included in this preamble are contained in the
Response to Comments document which is included in the docket for this
rulemaking.
III. Summary of the Final Rules and Changes Since Proposal
We are promulgating several amendments to provisions in the
existing NSPS in 40 CFR part 60, subpart J. Many of these amendments
are technical clarifications and corrections that are also included in
the final standards in 40 CFR part 60, subpart Ja. For example, we are
revising the definition of ``fuel gas'' to indicate that vapors
collected and combusted to comply with certain wastewater and marine
vessel loading provisions are not considered fuel gas. Consequently,
these vapors are exempt from the sulfur dioxide (SO2)
treatment standard in 40 CFR 60.104(a)(1) and are not required to be
monitored. We are also finalizing certain monitoring exemptions that we
proposed for fuel gases that are identified as inherently low sulfur or
demonstrated to contain a low sulfur content. See 40 CFR
60.105(a)(4)(iv). We are also revising the coke burn-off equation to
account for oxygen (O2)--enriched air streams. Other
amendments include clarification of definitions and correction of
grammatical and typographical errors.
The final standards in 40 CFR part 60, subpart Ja include emission
limits for fluid catalytic cracking units (FCCU), fluid coking units
(FCU), sulfur recovery plants (SRP), and fuel gas combustion devices.
Subpart Ja also includes work practice standards for reducing emissions
of volatile organic compounds (VOC) from flares, minimizing
SO2 emissions from fuel gas combustion devices and SRP, and
for reducing emissions of VOC from delayed coking units. Only those
affected facilities that commence construction, modification, or
reconstruction after May 14, 2007 will be affected by the standards in
subpart Ja. Units for which construction, modification, or
reconstruction commenced on or before May 14, 2007 must continue to
comply with the applicable standards under the current NSPS in 40 CFR
part 60, subpart J, as amended.
A. What are the final amendments to the standards for petroleum
refineries (40 CFR part 60, subpart J)?
As proposed, we are amending the definition of ``fuel gas'' to
specifically exclude vapors that are collected and combusted in an air
pollution control device installed to comply with a specified
wastewater or marine vessel loading emissions standard. The thermal
combustion control devices themselves are still considered to be
affected fuel gas combustion devices if they combust other gases that
meet the definition of fuel gas, and all auxiliary fuel gas fired to
these devices are subject to the fuel gas limit; however, continuous
monitoring is not required for the vapors collected from wastewater or
marine vessel loading operations that are being incinerated because
these gases are not considered to be fuel gases under the definition of
``fuel gas'' in 40 CFR part 60, subpart J.
We are also finalizing exemptions for certain fuel gas streams from
all continuous monitoring requirements. See 40 CFR 60.105(a)(4)(iv).
Monitoring is not required for combustion in a flare of process upset
gases or flaring of gases from relief valve leakage or emergency
malfunctions since these streams are exempt from the standard under 40
CFR 60.104(a)(1). Additionally, monitoring is not required for
inherently low sulfur fuel gas streams since the emissions generated by
combusting such streams will necessarily be well below the standard.
These streams include pilot gas flames, gas streams that meet
commercial-grade product specifications with a sulfur content of 30
parts per million by volume (ppmv) or less, fuel gases produced by
process
[[Page 35840]]
units that are intolerant to sulfur contamination, and fuel gas streams
that an owner or operator can demonstrate are inherently low-sulfur.
Owners and operators are required to document the exemption for which
each fuel gas stream applies and ensure that the stream remains
qualified for that exemption.
For accuracy in the calculation of the coke burn-off rate, we are
revising the coke burn-off rate equation in 40 CFR 60.106(b)(3) to be
consistent with the equation in 40 CFR 63.1564(b)(4)(i) of the National
Emission Standards for Hazardous Air Pollutants for Petroleum
Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and
Sulfur Recovery Units (40 CFR part 63, subpart UUU). This revision adds
a fourth term to the coke burn-off rate equation to account for the use
of O2-enriched air. Other revisions to the equation change
the constant values and the units of the resulting coke burn-off rate
from Megagrams per hour (Mg/hr) and tons per hour (tons/hr) to
kilograms per hour (kg/hr) and pounds per hour (lb/hr).
We proposed to amend the definition of ``Claus sulfur recovery
plant'' in 40 CFR 60.101(i) to clarify that the SRP may consist of
multiple units and that primary sulfur pits are considered part of the
Claus SRP consistent with the Agency's current position. Commenters
expressed concern that change to a 40 CFR part 60, subpart J definition
that could lead to retroactive non-compliance. We disagree with those
concerns as we believe the definition as currently written provides for
such coverage. Nonetheless, we are not amending this definition in the
final amendments for subpart J and will continue to address individual
applicability issues under our applicability determination procedures.
Similarly, we proposed revisions to the subpart J definitions of
``oxidation control system'' and ``reduction control system'' in 40 CFR
60.101(j) and 40 CFR 60.101(k), respectively, to clarify that these
systems were intended to recycle the sulfur back to the Claus SRP. The
proposed amendments needlessly limit the types of tail gas treatment
systems that can be used; therefore, we are not amending these
definitions in the final amendments for subpart J.
The final amendments also include technical corrections to fix
references and other miscellaneous errors in 40 CFR part 60, subpart J.
Table 1 of this preamble describes the miscellaneous technical
corrections not previously described in this preamble that are included
in the amendments to subpart J.
Table 1.--Technical Corrections to 40 CFR Part 60, Subpart J
------------------------------------------------------------------------
Section Technical correction and reason
------------------------------------------------------------------------
60.100...................... Replace instances of ``construction or
modification'' with ``construction,
reconstruction, or modification.''
60.100(a)................... Replace ``except Claus plants of 20 long
tons per day (LTD) or less'' with
``except Claus plants with a design
capacity for sulfur feed of 20 long tons
per day (LTD) or less'' to clarify that
the size cutoff is based upon design
capacity and sulfur content in the inlet
stream rather than the amount of sulfur
produced.
60.100(b)................... Insert ending date for applicability of 40
CFR part 60, subpart J (one date for
flares and another date for all other
affected facilities); sources beginning
construction, reconstruction, or
modification after this date will be
subject to 40 CFR part 60, subpart Ja.
60.102(b)................... Replace ``g/MJ'' with ``grams per
Gigajoule (g/GJ)'' to correct units.
60.104(b)(1)................ Replace ``sulfur dioxide'' with ``SO2''
and replace ``50 ppm by volume (vppm)''
with ``50 ppm by volume (ppmv)'' for
consistency in unit and acronym
definition.
60.104(b)(2)................ Add ``to reduce SO2 emissions'' to the end
of the phrase ``Without the use of an add-
on control device'' at the beginning of
the paragraph to clarify the type of
control device to which this paragraph
refers; replace ``sulfur dioxide'' with
``SO2'' for consistency in acronym
definition.
60.105(a)(3)................ Add ``either'' before ``an instrument for
continuously monitoring'' and replace
``except where an H2S monitor is
installed under paragraph (a)(4)'' with
``or monitoring as provided in paragraph
(a)(4)'' to more accurately refer to the
requirements of Sec. 60.105(a)(4) and
clarify that there is a choice of
monitoring requirements.
60.105(a)(3)(iv)............ Replace ``accurately represents the S2
emissions'' with ``accurately represents
the SO2 emissions'' to correct a
typographical error.
60.105(a)(4)................ Replace ``In place'' with ``Instead'' at
the beginning of this paragraph and add
``for fuel gas combustion devices subject
to Sec. 60.104(a)(1)'' after
``paragraph (a)(3) of this section'' to
clarify that there is a choice of
monitoring requirements.
60.105(a)(8)................ Replace ``seeks to comply with Sec.
60.104(b)(1)'' with ``seeks to comply
specifically with the 90-percent
reduction option under Sec.
60.104(b)(1)'' to clearly identify the
emission limit option to which the
monitoring requirement in this paragraph
refers.
60.105(a)(8)(i)............. Change ``shall be set 125 percent'' to
``shall be set at 125 percent'' to
correct a grammatical error; replace
``sulfur dioxide'' with ``SO2'' for
consistency in acronym definition.
60.106(e)(2)................ Replace the incorrect reference to 40 CFR
60.105(a)(1) with a correct reference to
40 CFR 60.104(a)(1); add ``The method
ANSI/ASME PTC 19.10-1981, ``Flue and
Exhaust Gas Analyses,'' (incorporated by
reference--see Sec. 60.17) is an
acceptable alternative to EPA Method 6 of
Appendix A-4 to part 60.'' after the
first sentence of this paragraph to
include a voluntary consensus method.
60.107(c)(1)(i)............. Replace both occurrences of ``50 vppm''
with ``50 ppmv'' for consistency in unit
definition.
60.107(f)................... Redesignate current 40 CFR 60.107(e) as 40
CFR 60.107(f) to allow space for a new
paragraph (e).
60.107(g)................... Redesignate current 40 CFR 60.107(f) as 40
CFR 60.107(g) to allow space for a new
paragraph (e).
60.108(e)................... Replace the incorrect reference to 40 CFR
60.107(e) with a correct reference to 40
CFR 60.107(f).
------------------------------------------------------------------------
B. What are the final requirements for new fluid catalytic cracking
units and new fluid coking units (40 CFR part 60, subpart Ja)?
The final standards for new FCCU include emission limits for
particulate matter (PM), SO2, nitrogen oxides
(NOX), and carbon monoxide (CO). The final standards include
no universal opacity limit because the opacity limit in 40 CFR part 60,
subpart J is intended to ensure compliance with the PM limit. 40 CFR
part 60, subpart Ja requires that sources use direct PM monitoring, bag
leak detection systems, or parameter monitoring (along with annual
emission tests) to ensure compliance with the PM limit. A provision for
a site-specific opacity operating limit is provided for units that meet
the PM emission limits using a cyclone.
For PM emissions from new FCCU and new FCU, we proposed a PM limit
of 0.5 pounds (lb)/1,000 lb coke burnoff in the regenerator or (if a PM
continuous emission monitoring system (CEMS) is
[[Page 35841]]
used), 0.020 grains per dry standard cubic feet (gr/dscf) corrected to
0 percent excess air. We have revised the final PM standards to
establish separate limits for modified or reconstructed FCCU (1 lb/
1,000 lb coke burn or 0.040 gr/dscf corrected to 0 percent excess air)
and newly constructed FCCU (0.5 lb/1,000 lb coke burn or 0.020 gr/dscf
corrected to 0 percent excess air). The final PM limit for new,
modified, or reconstructed FCU is 1 lb/1,000 lb coke burn or 0.040 gr/
dscf corrected to 0 percent excess air.
Initial compliance with the PM emission limits for FCCU and FCU is
determined using EPA Method 5, 5B or 5F (40 CFR part 60, appendix A-3)
instead of being restricted to only EPA Method 5 as previously
proposed. Procedures for computing the PM emission rate using the total
PM concentration, effluent gas flow rate, and coke burn-off rate are
the same as in 40 CFR part 60, subpart J, as amended. To demonstrate
ongoing compliance, an owner or operator must monitor PM emission
control device operating parameters and conduct annual PM performance
tests, use a PM CEMS, or operate bag leak detection systems and conduct
annual PM performance tests. A new alternative allows refineries with
wet scrubbers as PM control devices to use the approved alternative in
40 CFR 63.1573(a) for determining exhaust gas flow rate instead of a
continuous parameter monitoring system (CPMS). An alternative to the
requirements for monitoring the pressure drop from wet scrubbers that
are equipped with jet ejectors or atomizing spray nozzles is to conduct
a daily check of the air or water pressure to the nozzles and record
the results of each inspection. The final rule also includes procedures
for establishing an alternative opacity operating limit for refiners
that use continuous opacity monitoring systems (COMS); this alternative
is allowed only for units that choose to comply with the PM limit using
cyclones. If operating parameters are used to demonstrate ongoing
compliance, the owner or operator must monitor the same parameters
during the initial performance test, and develop operating parameter
limits for the applicable parameters. The operating limits must be
based on the three-run average of the values for the applicable
parameters measured over the three test runs. If ongoing compliance is
demonstrated using a PM CEMS, the CEMS must meet the conditions in
Performance Specification 11 (40 CFR part 60, appendix B) and the
quality assurance (QA) procedures in Procedure 2, 40 CFR part 60,
appendix F. The relative response audits must be conducted annually (in
lieu of annual performance tests for units not employing a PM CEMS) and
response correlation audits must be conducted once every 5 years.
For NOX emissions from the affected FCCU and FCU, we
proposed a limit of 80 ppmv based on a 7-day rolling average (dry basis
corrected to 0 percent excess air) and co-proposed having no limit for
FCU. We are adopting the 80 ppmv NOX emission limits for
FCCU and FCU as proposed. Initial compliance with the 80 ppmv emission
limit is demonstrated by conducting a performance evaluation of the
CEMS in accordance with Performance Specification 2 in 40 CFR part 60,
appendix B, with Method 7 (40 CFR part 60, appendix A-4) as the
reference method. Ongoing compliance with these emission limits is
determined using the CEMS to measure NOX emissions as
discharged to the atmosphere, averaged over 7-day periods.
No changes have been made to the proposed SO2 emission
limits for affected FCCU and FCU. The final SO2 emission
limits are to maintain SO2 emissions to the atmosphere less
than or equal to 50 ppmv on a 7-day rolling average basis, and less
than or equal to 25 ppmv on a 365-day rolling average basis (both
limits corrected to 0 percent moisture and 0 percent excess air).
Initial compliance with the final SO2 emission limits are
demonstrated by conducting a performance evaluation of the
SO2 CEMS in accordance with Performance Specification 2 (40
CFR part 60, Appendix B) with Method 6, 6A, or 6C (40 CFR part 60,
Appendix A-4) as the reference method. Ongoing compliance with both
SO2 emission limits is determined using the CEMS to measure
SO2 emissions as discharged to the atmosphere, averaged over
the 7-day and 365-day averaging periods.
No changes have been made since proposal to the CO limits. The
final CO emission limit for the affected FCCU and FCU is 500 ppmv (1-
hour average, dry at 0 percent excess air). Initial compliance with
this emission limit is demonstrated by conducting a performance
evaluation for the CEMS in accordance with Performance Specification 4
(40 CFR part 60, appendix B) with Method 10 or 10A (40 CFR part 60,
Appendix A-4) as the reference method. For Method 10 (40 CFR part 60,
Appendix A-4), the integrated sampling technique is to be used. Ongoing
compliance with this emission limit is determined on an hourly basis
using the CEMS to measure CO emissions as discharged to the atmosphere.
An exemption from monitoring may be requested for an FCCU or FCU if the
owner or operator can demonstrate that ``average CO emissions'' are
less than 50 ppmv (dry basis). As proposed, units that are exempted
from the CO monitoring requirements must comply with control device
operating parameter limits.
C. What are the final requirements for new sulfur recovery plants (40
CFR part 60, subpart Ja)?
For new, modified, and reconstructed SRP with a capacity greater
than 20 long tons per day (LTD) (large SRP), we proposed a limit of 250
ppmv total sulfur (combined SO2 and reduced sulfur
compounds) as SO2 (dry basis at 0 percent excess air
determined on a 12-hour rolling average basis). The refinery could
comply with the limit for each process train or release point or with a
flow rate weighted average of 250 ppmv for all release points. For
affected SRP with a capacity less than 20 LTD (small SRP), we proposed
a mass emissions limit for total sulfur equal to 1 weight percent or
less of sulfur recovered (determined hourly on a 12-hour rolling
average basis).
In this final rule, we are adopting the current limits in subpart J
(which include separate emission limits for oxidative and reductive
systems) for affected large SRP. For these affected SRP, the final
limits for SRP having an oxidation control system or a reduction
control system followed by incineration is 250 ppmv (dry basis) of
SO2 at zero percent excess air. For an affected SRP with a
reduction control system not followed by incineration, the final limit
is 300 ppmv of reduced sulfur compounds and 10 ppmv of hydrogen sulfide
(H2S), each calculated as ppm SO2 by volume (dry
basis) at zero percent excess air. If the SRP consists of multiple
process trains or release points, the refinery can comply with the
limit for each process train or release point or with a flow rate
weighted average of 250 ppmv for all release points. A new alternative
allows refineries to use a correlation to calculate their effective
emission limit for Claus SRP that use oxygen enrichment in the Claus
burner. For a small affected SRP, the sulfur recovery efficiency
standard is based on a sulfur recovery efficiency of 99 percent.
However, due to the difficulties associated with on-going monitoring of
SRP recovery efficiency, in this final rule, we are promulgating
concentration limits that correlate with a sulfur recovery efficiency
of 99 percent. For a Claus unit with an oxidative control system or any
small SRP followed by an incinerator the emission limit is 2,500
[[Page 35842]]
ppmv (dry basis) of SO2 at zero percent excess air. For all
other small SRP, the emission limit is 3,000 ppmv reduced sulfur
compound and 100 ppmv H2S, each calculated as ppm
SO2 by volume (dry basis) at zero percent excess air. A
similar correlation is provided for small Claus SRP that use oxygen
enrichment, similar to that provided for large SRP. The standards for
small SRP apply to all release points from the SRP combined (note that
secondary sulfur storage units are not considered part of the SRP). We
are not promulgating the H2S limit of 10 ppmv (dry basis, at
0 percent excess air determined on a 12-hour rolling average basis) or
related operating limits that were included in Sec. 60.102a(e) and (f)
of the proposed rule.
Initial compliance with the emission limit for large SRP is
demonstrated by conducting a performance evaluation for the
SO2 CEMS in accordance with either Performance Specification
2 (40 CFR part 60, Appendix B) for SRP with oxidation control systems
or reduction control systems followed by incineration, or Performance
Specification 5 (40 CFR part 60, Appendix B) for SRP with reduction
control systems not followed by incineration. The owner or operator
must operate and maintain oxygen monitors according to Performance
Specification 3 (40 CFR part 60, Appendix B).
Ongoing compliance with the SO2 limits for large SRP is determined
using an SO2 CEMS (for oxidative or reductive systems followed by
incineration) or a CEMS that uses an air or O2 dilution and oxidation
system to convert the reduced sulfur to SO2 and then measures the total
resultant SO2 concentration (for reductive systems not followed by
incineration). An O2 monitor is also required for converting the
measured combined SO2 concentration to the concentration at 0 percent
O2.
Initial and ongoing compliance requirements for small SRP are the
same as for large SRP.
D. What are the final requirements for new fuel gas combustion devices
(40 CFR part 60, subpart Ja)?
In the subpart Ja proposal, we divided fuel gas combustion devices
into two separate affected sources: ``process heaters'' and ``other
fuel gas combustion devices.'' In response to comments, we have
eliminated the proposed definition of ``other fuel gas combustion
devices'' and revised the standards to either refer to fuel gas
combustion devices, which include process heaters, or to refer
specifically to process heaters. This revision makes the definition of
``fuel gas combustion devices'' consistent with subpart J. Based on
public comments, we have also added a definition of ``flare'' as a
subcategory of fuel gas combustion devices. The owner or operator of an
affected flare must comply with the fuel gas combustion device
requirements as well as specific provisions for flares as described in
section III.E of this preamble.
We proposed a primary sulfur dioxide emission limit for fuel gas
combustion devices of 20 ppmv or less SO2 (dry at 0 percent excess air)
on a 3-hour rolling average basis and 8 ppmv or less on a 365-day
rolling average basis. We also proposed an alternative limit of 160
ppmv H2S or, in the case of coker-derived fuel gas, 160 ppmv total
reduced sulfur (TRS), on a 3-hour rolling average basis and 60 ppmv or
less on a 365-day rolling average basis. We are promulgating the 20
ppmv and 8 ppmv limits for SO2 as proposed. We are also promulgating
the alternative limit except that the limits are expressed and measured
as H2S in all cases. The alternative H2S limit is 162 ppmv or less in
the fuel gas on a 3-hour rolling average basis and 60 ppmv or less in
the fuel gas on a 365-day rolling average basis. The alternative limit
of 162 ppmv is based on standard conditions, which are defined in the
NSPS General Provisions at 40 CFR 60.2 as being 68[deg]F and 1
atmosphere. Using these as standard conditions, the subpart J emission
limit is equivalent to 162 ppmv H2S rather than 160 ppmv. The final
rule does not include an alternative TRS limit for SO2.
Initial compliance with the 20 ppmv SO2 limit or the 162 ppmv H2S
concentration limits is demonstrated by conducting a performance
evaluation for the CEMS. The performance evaluation for an SO2 CEMS is
conducted in accordance with Performance Specification 2 in 40 CFR part
60, Appendix B. The performance evaluation for an H2S CEMS is conducted
in accordance with Performance Specification 7 in 40 CFR part 60,
Appendix B. Ongoing compliance with the sulfur oxides emission limits
is determined using the applicable CEMS to measure either SO2 in the
exhaust gas to the atmosphere or H2S in the fuel gas, averaged over the
3-hour and 365-day averaging periods.
Similar to clarifications for 40 CFR part 60, subpart J, the
definition of ``fuel gas'' includes exemptions for vapors collected and
combusted in an air pollution control device installed to comply with
specified wastewater or marine vessel loading provisions. We are also
streamlining the process for an owner or operator to demonstrate that a
fuel gas stream not explicitly exempted from continuous monitoring is
inherently low sulfur.
For new, modified, or reconstructed process heaters with a rated
capacity greater than 20 million British thermal units per hour (MMBtu/
hr), we proposed a NOX limit of 80 ppmv (dry basis, corrected to 0
percent excess air) on a 24-hour rolling average basis. The final NOX
emission limit for affected process heaters is 40 ppmv on a 24-hour
rolling average basis (dry at 0 percent excess air) for process heaters
greater than 40 MMBtu/hr. For process heaters greater than 100 MMBtu/hr
capacity, initial compliance with the 40 ppmv emission limit is
demonstrated by conducting a performance evaluation of the CEMS in
accordance with Performance Specification 2 in 40 CFR part 60, Appendix
B. For process heaters between 40 MMBtu/hr and 100 MMBtu/hr capacity,
initial compliance is demonstrated using EPA Method 7 (40 CFR part 60,
Appendix A-4). For process heaters greater than 100 MMBtu/hr capacity,
ongoing compliance with this emission limit is determined using the
CEMS to measure NOX emissions as discharged to the atmosphere, averaged
over 24-hour periods. For process heaters between 40 MMBtu/hr and 100
MMBtu/hr capacity, ongoing compliance with this emission limit is
determined using biennial performance tests.
E. What are the final work practice standards (40 CFR part 60, subpart
Ja)?
We proposed three work practice standards to reduce SO2, VOC, and
NOX emissions from flares and from startup, shutdown, and malfunction
events and to reduce VOC and SO2 emissions from delayed coking units.
We also co-proposed to require only one of these work practice
standards: the requirement to depressure delayed coking units. This
proposed standard required new delayed coking units to depressure to 5
pounds per square inch gauge (psig) during reactor vessel depressuring
and vent the exhaust gases to the fuel gas system.
We are promulgating a work practice standard for delayed coking
units and modified requirements to reduce emissions from flares. The
final work practice standard for delayed cokers requires affected
delayed coking units to depressure to 5 pounds per square inch gauge
(psig) during reactor vessel depressuring. We are requiring the exhaust
gases to be vented to the fuel gas system as proposed or to a flare.
To reduce SO2 emissions from the combustion of sour fuel gases, the
final rule requires refineries to conduct a root
[[Page 35843]]
cause analysis of any emissions limit exceedance or process start-up,
shutdown, upset, or malfunction that causes a discharge into the
atmosphere, either directly or indirectly, from any fuel gas combustion
device or sulfur recovery plant subject to the provisions of subpart Ja
that exceeds 500 pounds per day (lb/day) of SO2. Recordkeeping and
reporting requirements apply in the event of such a discharge. Newly
constructed and reconstructed flares must comply with these
requirements immediately upon startup. Modified flares must comply no
later than the first discharge that occurs after that flare has been an
affected flare for 1 year.
In response to comments regarding the work practice standards for
fuel gas producing units and associated difficulties with no routine
flaring, we re-evaluated the work practice standards and have decided
not to promulgate a work practice standard for fuel gas producing
units. Rather, we have decided to define a flare as an affected
facility and adopt regulations applicable to it. Therefore, we are not
promulgating the proposed definition of ``fuel gas producing unit'' and
the proposed requirement for ``no routine flaring.'' Instead, we are
promulgating the following requirements for flares that become affected
facilities after June 24, 2008: (1) Flare fuel gas flow rate
monitoring; (2) a flare fuel gas flow rate limit; and (3) a flare
management plan. Affected flares cannot exceed a flow rate of 250,000
standard cubic feet per day (scfd) on a 30-day rolling average basis.
In cases where the flow would exceed this value, the owner or operator
would install a flare gas recovery system or implement other methods to
reduce flaring from the affected flare. To demonstrate compliance with
the flow rate limitations, flow rate monitors must be installed and
operated. Newly constructed and reconstructed flares must comply with
the flow rate limitations and the monitoring requirements immediately
upon startup. Modified flares must comply with the flow rate
limitations and the associated monitoring provisions no later than 1
year after the flare becomes an affected facility. A provision is
provided for an exclusion from the flow limitation for times when the
refinery can demonstrate that the refinery produces more fuel gas than
it needs to fuel the refinery combustion devices (i.e., it is fuel gas
rich) or that the flow is due to an upset or malfunction, provided the
refinery follows procedures outlined in the flare management plan. The
flare management plan should address potential causes of fuel gas
imbalances (i.e., excess fuel gas) and records to be maintained to
document these periods. As described in 40 CFR 60.103a(a), the flare
management plan must include a diagram illustrating all connections to
each affected flare, identification of the flow rate monitoring device
and a detailed description of the manufacturer's specifications
regarding quality assurance procedures, procedures to minimize flaring
during planned start-up and shut down events, and procedures for
implementing root cause analysis when daily flow to the flare exceeds
500,000 scfd. The root cause analysis procedures should address the
evaluation of potential causes of upsets or malfunctions and records to
be maintained to document the cause of the upset or malfunction. Newly
constructed and reconstructed flares must comply with the flare
management plan requirements immediately upon startup. Modified flares
must comply with the flare management plan requirements no later than 1
year after the flare becomes an affected facility. Additionally, as
described above, the owner or operator of a modified flare must conduct
the first root cause analysis no later than the first discharge that
occurs after that flare has been an affected flare for 1 year. Excess
emission events for the flow rate limit of 250,000 scfd and the result
of root cause analysis must be reported in the semi-annual compliance
reports.
Because affected flares are also affected fuel gas combustion
devices, the root cause analysis for SO2 emissions exceeding 500 lbs/
day also applies to all affected flares. However, compliance with the
500 lb/day root cause analysis will also require continuous monitoring
of total reduced sulfur of all gases flared. Although all fuel gas
combustion devices are required to comply with continuous H2S
monitoring of fuel gas, flares routinely accept gases from upsets,
malfunctions and startup and shutdown events, and H2S or sulfur
monitoring is not specifically required for these gases. In subpart Ja,
we explicitly require TRS monitoring for flares that become affected
facilities after June 24, 2008 to ensure that the 500 lb/day SO2
trigger is accurately measured. The owner or operator of a modified
flare must install and operate the TRS monitoring instrument no later
than 1 year after the flare becomes an affected facility. The owner or
operator of a newly constructed or reconstructed flare must install and
operate the TRS monitoring instrument no later than start-up of the
flare.
F. What are the modification and reconstruction provisions?
Existing affected facilities that commence modification or
reconstruction after May 14, 2007, are subject to the final standards
in 40 CFR part 60, subpart Ja. A modification is any physical or
operational change to an existing affected facility which results in an
increase in the emission rate to the atmosphere of any pollutant to
which a standard applies (see 40 CFR 60.14). Changes to an existing
affected facility that do not result in an increase in the emission
rate, as well as certain changes that have been exempted under the
General Provisions (see 40 CFR 60.14(e)), are not considered
modifications.
The intermittent operation of a flare makes it difficult to use the
criteria of 40 CFR 60.14 to determine when a flare is modified;
therefore, we have specified in the final rule the criteria that define
a modification to a flare. A flare is considered to be modified if: (1)
Any piping from a refinery process unit or fuel gas system is newly
connected to the flare or (2) the flare is physically altered to
increase flow capacity. See section IV.I of this preamble for further
explanation on the change in affected source from a fuel gas producing
unit to the flare.
Petroleum refinery process units are subject to the final standards
in 40 CFR part 60, subpart Ja if they meet the criteria under the
reconstruction provisions, regardless of changes in emission rate.
Reconstruction means the replacement of components of an existing
facility such that (1) the fixed capital cost of the new components
exceeds 50 percent of the fixed capital cost that would be required to
construct a comparable entirely new facility; and (2) it is
technologically and economically feasible to meet the applicable
standards (40 CFR 60.15).
IV. Summary of Significant Comments and Responses
As previously noted, we received a total of 46 comments during the
public comment periods associated with the proposed rule and NODA.
These comments were received from refineries, industry trade
associations, and consultants; State and local environmental and public
health agencies; environmental groups; and members of the public. In
response to these public comments, most of the cost and emission
reduction impact estimates were recalculated, resulting in several
changes to the final amendments and new standards. The major comments
and our responses are
[[Page 35844]]
summarized in the following sections. A summary of the remainder of the
comments received during the comment period and responses thereto can
be found in the docket for the final amendments and new standards
(Docket ID No. EPA-OAR-HQ-2007-0011). The docket also contains further
details on all the analyses summarized in the responses below.
In responding to the public comments, we re-evaluated the costs and
cost-effectiveness of the control options and re-evaluated our BDT
determinations. In our BDT determinations, we took all relevant factors
into account consistent with other Agency decisions. It is important to
note that, due to the different health and welfare effects associated
with different pollutants, the acceptable cost-effectiveness value of a
control option is pollutant dependent. These pollutant-specific factors
were considered along with other factors in our BDT determinations.
A. PM Limits for Fluid Catalytic Cracking Units
Comment: Several commenters opposed the proposed tightening of the
FCCU PM standards relative to subpart J and the concurrent change in PM
monitoring methods. Some commenters supported the co-proposal to keep
the 1 lb/1,000 lb coke burn PM emission limit based on Method 5B and/or
5F; other commenters either did not oppose or supported the 0.5 lb/
1,000 lb coke burn emission limit for new ``grassroots'' units,
provided EPA demonstrates it is cost-effective and that the limit is
based on EPA Method 5B or 5F (40 CFR part 60, Appendix A-3).
Commenters stated that EPA should only impose the more stringent
emission limits on new construction because it is much more difficult
and costly to meet the proposed emission limits for modified or
reconstructed equipment. Commenters suggested that if EPA does include
more stringent limits on modifications, it should exclude certain
actions (like projects implemented to meet consent decree requirements)
from the definition of a modification.
Several commenters suggested that the costs in Table 11 of the
proposal preamble are significantly underestimated. Commenters
contended that the single ``model plant'' approach used in EPA's cost
analysis does not realistically consider important factors such as the
inherent sulfur content of the feed, partial-burn versus full-burn
regeneration, FCCU/regenerator size, and sources that are already well-
controlled due to other regulations. Commenters asserted that the
purchased equipment costs escalated from estimates that are 20 to 30
years old are underestimated. Several commenters provided estimates of
costs and emission reductions for several actual projects, which they
stated indicate that EPA's costs are significantly underestimated and
that the proposed standards are much less cost-effective than presented
by EPA.
A number of commenters asserted that the PM standards should be
based on EPA Methods 5B or 5F (40 CFR part 60, Appendix A-3), and not
on EPA Method 5 of Appendix A-3 to part 60. According to these
commenters, the achievability of the proposed 0.5 lb/1,000 lb coke burn
PM limit based on EPA Method 5 is questionable because there are
inadequate data on FCCU using EPA Method 5, and controlling combined
condensable and filterable PM to the 0.5 lb/1,000 lb coke burn level
has not been demonstrated to be cost-effective.
On the other hand, several commenters stated that any PM limit must
include condensable and filterable PM as condensable PM account for a
large portion of refinery PM emissions and all condensable PM is PM
that is less than 2.5 micrometers in diameter (PM2.5), which has more
adverse health impacts than larger particles; the commenters therefore
agreed with the use of EPA Method 5 to determine filterable PM and
requested that EPA consider Method 202 (40 CFR part 51, Appendix M) for
condensable PM. Commenters also stated that the limits for PM and SO2
in subpart Ja should apply to all new, reconstructed, and modified
FCCU. One commenter recommended that a total PM limit (filterable and
condensable) be set at 1 lb/1,000 coke burn; another stated that the
total PM limit, including both filterable and condensable PM, should be
0.5 lb/1,000 lb coke burn, and EPA has not demonstrated that current
BDT cannot achieve this limit. Finally, one commenter suggested that
EPA should evaluate the cost of removing each pollutant (PM and SO2)
separately.
Response: In response to these comments, we have revised our
analysis to consider each unique existing FCCU in the United States. By
doing so, we fully account for plant size, partial-burn versus full-
burn regeneration, existing control configuration, and specific consent
decree requirements. (Details on the specific revisions to the analysis
can be found in the docket.) With a revised analysis, we were able to
more directly assess the impacts of process modifications or
reconstruction of existing equipment. We also assessed the effects of
PM and SO2 standards separately in this analysis.
In our revised analysis, we considered three options for PM: (1)
Maintain the existing subpart J standard of 1.0 lb/1,000 lb of coke
burn-off (filterable PM as measured by Method 5B or 5F); (2) 0.5 lb/
1,000 lb of coke burn-off (filterable PM as measured by Method 5B or 5F
of Appendix A-3 to part 60); and (3) 0.5 lb/1,000 lb of coke burn-off
(filterable PM as measured by Method 5 of Appendix A-3 to part 60).
Similar to the analysis for the proposed standards, costs and emission
reductions for each option were estimated as the increment between
complying with subpart J and subpart Ja. We note that none of the
available data suggest that a 0.5 lb/1,000 lb coke burn emission limit
that includes both filterable and condensable PM as measured using EPA
Method 202 is achievable in practice for the full range of facilities
using BDT controls, so we disagree with the comments suggesting this
level is appropriate to consider as an option for a total PM limit in
this rulemaking.
Option 1 includes the same emissions and requirements for PM as the
current 40 CFR part 60, subpart J, so it will achieve no additional
emissions reductions. The PM limit in Option 2 is the same numerical
limit that was proposed in subpart Ja, but the PM emissions are
determined using Methods 5B and 5F (40 CFR part 60, Appendix A-3).
These test methods are commonly used for PM tests of FCCU and are the
methods that were used to generate a majority of the test data we
reviewed. Option 3 is a limit of 0.5 lb/1,000 lb coke burn using Method
5 and is the performance level that was proposed for subpart Ja. The
impacts of these three options for new FCCU are presented in Table 2 to
this preamble; the impacts for modified and reconstructed FCCU are
presented in Table 3 to this preamble.
[[Page 35845]]
Table 2.--National Fifth Year Impacts of Options for PM Limits Considered for New Fluid Catalytic Cracking Units
Subject to 40 CFR Part 60, Subpart Ja\a\
----------------------------------------------------------------------------------------------------------------
Total annual Emission Cost effectiveness ($/ton)
Option Capital cost cost ($1,000/ reduction -------------------------------
($1,000) yr) (tons PM/yr) Overall Incremental
----------------------------------------------------------------------------------------------------------------
2............................... 3,600 1,100 240 5,600 5,600
3............................... 7,100 1,700 300 6,700 11,000
----------------------------------------------------------------------------------------------------------------
\a\ PM cost-effectiveness calculated for PM-fine; 83.3 percent of the PM is PM-fine.
Table 3.--National Fifth Year Impacts of Options for PM Limits Considered for Reconstructed and Modified Fluid
Catalytic Cracking Units Subject to 40 CFR Part 60, Subpart Ja\a\
----------------------------------------------------------------------------------------------------------------
Total annual Emission Cost effectiveness ($/ton)
Option Capital cost cost ($1,000/ reduction -------------------------------
($1,000) yr) (tons PM/yr) Overall Incremental
----------------------------------------------------------------------------------------------------------------
2............................... 75,000 12,000 690 21,000 21,000
3............................... 100,000 15,000 810 23,000 37,000
----------------------------------------------------------------------------------------------------------------
\a\ PM cost-effectiveness calculated for PM-fine; 83.3 percent of the PM is PM-fine.
The available data and impacts for the options considered suggest
that BDT for new FCCU is different than BDT for modified and
reconstructed FCCU. For new FCCU, the costs for Option 2 are reasonable
compared to the emission reduction achieved. The incremental cost
between Option 2 and Option 3 of $11,000 per ton PM-fine would
generally be considered reasonable, but there are uncertainties in the
achievability of Option 3. The estimated PM emission reduction achieved
by Option 3 compared to Option 2 equals the amount of sulfates and
other condensable PM between 250 [deg]F and 320 [deg]F that would be
measured by Method 5 but not Method 5B or 5F (40 CFR part 60, Appendix
A-3). Additionally, available test data indicate that electrostatic
precipitators (ESP) and wet scrubbers can reduce total filterable PM to
0.5 lb/1,000 lb of coke burn or less, as measured by Method 5-
equivalent test methods. Although there were few test data points using
Method 5-equivalent test methods, we concluded at proposal that both
electrostatic precipitators and wet scrubbers can achieve this level of
PM emissions. However, the data supporting Option 3 are not extensive,
and it is unclear at this time whether a limit of 0.5 kg/Mg of coke
burn as measured by Method 5 (40 CFR part 60, Appendix A-3) could be
met by all configurations of FCCU. In addition, while the Agency
supports reducing condensable PM emissions, the amount of condensable
PM captured by Method 5 is small relative to methods that specifically
target condensable PM, such as Method 202 (40 CFR part 51, Appendix M).
We prefer to develop a single performance standard that considers all
condensable PM rather than implementing phased standards targeting
different fractions of condensable PM. Such an approach would be costly
and inefficient. Therefore, we conclude that Option 2, control of PM
emissions (as measured by Methods 5B and 5F of Appendix A-3 to part 60)
to 0.5 lb/1,000 lb of coke burn or less, is BDT for newly constructed
FCCU. This option achieves PM emission reductions of 240 tons per year
(tons/yr) from a baseline of 910 tons/yr at a cost of $5,600 per ton of
PM.
For modified and reconstructed FCCU, Option 1 is the baseline level
of control established by the existing requirements of subpart J. It
will achieve no additional cost or emission reduction. The overall
costs and the incremental costs for Options 2 and 3 are reasonable
compared to the PM emission reduction; however, as with new FCCU, the
performance of Option 3 has not been demonstrated, so it is rejected.
Most of the existing FCCU that could become subject to subpart Ja
through modification or reconstruction are either already subject to
subpart J or are covered by the consent decrees. The consent decrees
are generally based on the existing subpart J. Industry has made
significant investments in complying with these subpart J requirements
which may be abandoned if they become subject to subpart Ja. In
addition, the additional costs could create a disincentive to modernize
FCCU to make them more energy efficient or to produce more refined
products. For these reasons, we reject Option 2 for modified or
reconstructed FCCU and conclude that control of PM emissions (as
measured by Methods 5B and 5F of Appendix A-3 to part 60) is 1.0 lb/
1,000 lb of coke burn or less is BDT for reconstructed and modified
FCCU.
B. SO2 Limits for Fluid Catalytic Cracking Units
Comment: Several commenters supported the co-proposal for modified
and reconstructed FCCU to meet subpart J and not the 25 ppmv 365-day
rolling average limit for SO2. Commenters provided data to suggest that
the retrofits of existing sources are not cost effective, particularly
if catalyst additives cannot be used. The current subpart J includes
three compliance options: (1) If using an add-on control device, reduce
SO2 emissions by at least 90 percent or to less than 50 ppmv; (2) if
not using an add-on control device, limit sulfur oxides emissions
(calculated as SO2) to no more than 9.8 kg/Mg of coke burn-off; or (3)
process in the fluid catalytic cracking unit fresh feed that has a
total sulfur content no greater than 0.30 percent by weight. Several
commenters objected to the elimination of the additional compliance
options in the existing subpart J for subpart Ja because: (1) There are
no data to show that the SO2 limits proposed in subpart Ja are BDT for
all FCCU regenerator configurations; (2) the three options are already
established as BDT and, therefore, the CAA requires that EPA make them
available; and (3) the substantial cost and other burdens for a
reconstructed or modified FCCU already complying with one of the
alternative options in subpart J to change to daily monitoring by
Method 8 (40 CFR part 60, Appendix A-4) or to install CEMS were not
addressed in the proposal.
One commenter supported the proposed SO2 limit under Ja
for new ``grassroots'' FCCU if the standard is demonstrated to be cost-
effective.
[[Page 35846]]
Response: As acknowledged in the previous response on PM standards
for FCCU, we completely revised our impacts analysis to evaluate SO2
standards for every existing FCCU that may become subject to subpart Ja
through modification or reconstruction. We did not have access to the
inherent sulfur content of the feed for each FCCU so SO2 emissions are
still estimated using average emission factors relevant to the type of
control device used for FCCU not subject to consent decree
requirements. Nonetheless, we significantly revised the impact analysis
to fully account for FCCU-specific throughput, existing controls, and
consent decree requirements. (Details on the specific revisions to the
analysis can be found in Docket ID No. EPA-HQ-OAR-2007-0011.) We
evaluated two options: (1) Current subpart J, including all three
compliance options; and (2) 50 ppmv SO2 on a 7-day average and 25 ppmv
on a 365-day average. Data are not available on which to base a more
stringent control level.
Option 1 includes the same emissions and requirements as the
current 40 CFR part 60, subpart J, so it will achieve no additional
emissions reductions. Based on information provided by vendors and data
submitted by petroleum refiners, Option 2 can be met with catalyst
additives or a wet scrubber. Of 38 FCCU currently subject to a 50/25
ppmv SO2 limit through consent decrees, 26 used wet scrubbers and 12
used catalyst additives or other (unspecified) techniques. Given the
number of FCCU currently meeting the 50/25 ppmv SO2 emission limit, we
conclude that this limit is technically feasible.
The data in the record suggest that all systems with wet scrubbers
can meet the 50/25 ppmv SO2 emission limit with no additional cost.
Further, based on information from the consent decrees, we believe that
the owner or operator of an existing FCCU that does not already have a
wet scrubber and is modified or reconstructed such that it becomes
subject to subpart Ja can use catalyst additives to meet the 50/25 ppmv
SO2 emission limit. Therefore, the cost of Option 2 is calculated using
catalyst additives as the method facilities choose for meeting the
standard. We re