National Volatile Organic Compound Emission Standards for Aerosol Coatings, 38952-38991 [E7-13108]
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Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
40 CFR Parts 51 and 59
[EPA–HQ–OAR–2006–0971; FRL–8336–5]
RIN 2060–AN69
National Volatile Organic Compound
Emission Standards for Aerosol
Coatings
Environmental Protection
Agency (EPA).
ACTION: Proposed rule.
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AGENCY:
SUMMARY: This action proposes a
national reactivity-based volatile
organic compound (VOC) emissions
regulation for the aerosol coatings
(aerosol spray paints) category under
section 183(e) of the Clean Air Act
(CAA). The proposed standards
implement section 183(e) of the CAA, as
amended in 1990, which requires the
Administrator to control VOC emissions
from certain categories of consumer and
commercial products for purposes of
minimizing VOC emissions contributing
to ozone formation and causing nonattainment. This regulation will
establish a nationwide reactivity-based
standard for aerosol coatings. States
have promulgated rules for the aerosol
coatings category based upon reductions
of VOC by mass; however, the Agency
believes that a national rule based upon
the relative reactivity approach may
achieve more reduction in ozone
formation than can be achieved by a
mass-based approach for this specific
product category. EPA believes that this
rule will better control a product’s
contribution to ozone formation by
encouraging the use of less reactive VOC
ingredients, rather than treating all VOC
in a product alike through the
traditional mass-based approach. We are
also proposing to revise EPA’s
regulatory definition of VOC exempt
compounds for purposes of this
regulation in order to account for all the
reactive compounds in aerosol coatings
that contribute to ozone formation.
Therefore, compounds that would not
be VOC under the otherwise applicable
definition will count towards a
product’s reactivity limits under this
proposed regulation. The initial listing
of product categories and schedule for
regulation was published on March 23,
1995 (60 FR 15264). This proposed
action announces EPA’s final decision
to list aerosol coatings for regulation
under group III of the consumer and
commercial product category for which
regulations are mandated under section
183 (e) of the Act.
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Comments. Written comments
on the proposed regulation must be
received by EPA by August 15, 2007,
unless a public hearing is requested by
July 26, 2007. If a hearing is requested,
written comments must be received by
August 30, 2007.
Public Hearing. If anyone contacts
EPA requesting to speak at a public
hearing concerning the proposed
regulation by July 26, 2007, we will
hold a public hearing on July 31, 2007.
ADDRESSES: Comments. Submit your
comments, identified by Docket ID No.
EPA–HQ–OAR–2006–0971, by one of
the following methods:
• Federal eRulemaking Portal: https://
www.regulations.gov. Follow the on-line
instructions for submitting comments.
• E-mail: a-and-r-docket@epa.gov.
• Fax: (202) 566–1741.
• Mail: Air and Radiation Docket,
Environmental Protection Agency,
Mailcode 6102T, 1200 Pennsylvania
Avenue, NW., Washington, DC 20460.
Please include a total of two copies. We
request that a separate copy also be sent
to the contact person identified below
(see FOR FURTHER INFORMATION CONTACT).
In addition, please mail a copy of your
comments on the information collection
provisions to the Office of Information
and Regulatory Affairs, Office of
Management and Budget (OMB), Attn:
Desk Officer for EPA, 725 17th St., NW.,
Washington, DC 20503.
• Hand Delivery: EPA Docket Center,
Public Reading Room, EPA West, Room
3334, 1301 Constitution Ave., NW.,
Washington, DC 20460. Such deliveries
are only accepted during the Docket’s
normal hours of operation, and special
arrangements should be made for
deliveries of boxed information.
Instructions: Direct your comments to
the applicable docket. EPA’s policy is
that all comments received will be
included in the public docket without
change and may be made available
online at https://www.regulations.gov,
including any personal information
provided, unless the comment includes
information claimed to be confidential
business information (CBI) or other
information whose disclosure is
restricted by statute. Do not submit
information that you consider to be CBI
or otherwise protected through
www.regulations.gov or e-mail. The
www.regulations.gov Web site is an
‘‘anonymous access’’ system, which
means EPA will not know your identity
or contact information unless you
provide it in the body of your comment.
If you send an e-mail comment directly
to EPA without going through
www.regulations.gov, your e-mail
address will be automatically captured
DATES:
ENVIRONMENTAL PROTECTION
AGENCY
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and included as part of the comment
that is placed in the public docket and
made available on the Internet. If you
submit an electronic comment, EPA
recommends that you include your
name and other contact information in
the body of your comment and with any
disk or CD–ROM you submit. If EPA
cannot read your comment due to
technical difficulties and cannot contact
you for clarification, EPA may not be
able to consider your comment.
Electronic files should avoid the use of
special characters, any form of
encryption, and be free of any defects or
viruses.
Public Hearing. If a public hearing is
held, it will be held at 10 a.m. on July
31, 2007 at Building C on the EPA
campus in Research Triangle Park, NC,
or at an alternate site nearby. Persons
interested in presenting oral testimony
must contact Ms. Dorothy Apple, U.S.
EPA, Office of Air Quality Planning and
Standards, Sector Policies and Programs
Division, Natural Resources and
Commerce Group (E143–03), Research
Triangle Park, North Carolina 27711,
telephone number: (919) 541–4487, fax
number (919) 541–3470, e-mail address:
apple.dorothy@epa.gov, no later than
July 26, 2007 in the Federal Register.
Persons interested in attending the
public hearing must also call Ms. Apple
to verify the time, date, and location of
the hearing. If no one contacts Ms.
Apple by July 26, 2007 in the Federal
Register with a request to present oral
testimony at the hearing, we will cancel
the hearing.
Docket: All documents in the docket
are listed in the www.regulations.gov
index. Although listed in the index,
some information is not publicly
available, e.g., CBI or other information
whose disclosure is restricted by statute.
Certain other material, such as
copyrighted material, is not placed on
the Internet and will be publicly
available only in hard copy form.
Publicly available docket materials are
available either electronically through
www.regulations.gov or in hard copy at
the EPA Docket Center, Public Reading
Room, EPA West, Room 3334, 1301
Constitution Ave., NW., Washington,
DC 20460. The Public Reading Room is
open from 8:30 a.m. to 4:30 p.m.,
Monday through Friday, excluding legal
holidays. The telephone number for the
Public Reading Room is (202) 566–1742,
and the telephone number for the Air
Docket is (202) 566–1744.
FOR FURTHER INFORMATION CONTACT: For
information concerning the aerosol
coatings rule, contact Ms. J. Kaye
Whitfield, U.S. EPA, Office of Air
Quality Planning and Standards, Sector
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Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
Policies and Programs Division, Natural
Resources and Commerce Group (E143–
03), Research Triangle Park, North
Carolina 27711, telephone number:
(919) 541–2509, fax number (919) 541–
3470, e-mail address:
whitfield.kaye@epa.gov. For information
concerning the CAA section 183(e)
consumer and commercial products
program, contact Mr. Bruce Moore, U.S.
EPA, Office of Air Quality Planning and
Standards, Sector Policies and Programs
Division, Natural Resources and
Commerce Group (E143–03), Research
Triangle Park, North Carolina 27711,
telephone number: (919) 541–5460, fax
number (919) 541–3470, e-mail address:
moore.bruce@epa.gov.
Entities
Potentially Affected by this Action. The
entities potentially regulated by the
proposed regulation encompass aerosol
coatings operations. This includes
SUPPLEMENTARY INFORMATION:
Paint and coating manufacturing ................................................
32551
All other miscellaneous chemical production and preparation
manufacturing.
325998
manufacturers, processors, wholesale
distributors, or importers of aerosol
coatings for sale or distribution in the
United States, or manufacturers,
processors, wholesale distributors, or
importers that supply the entities listed
with aerosol coatings for sale or
distribution in interstate commerce in
the United States. The entities
potentially affected by this action
include:
Examples of regulated
entities
NAICS code a
Category
38953
Manufacturing of lacquers, varnishes, enamels, epoxy coatings, oil and alkyd vehicle, plastisols, polyurethane, primers,
shellacs, stains, water repellant coatings.
Aerosol can filling, aerosol packaging services.
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a https://www.census.gov/epcd/www/naics.html.
This table is not intended to be
exhaustive, but rather provides a guide
for readers regarding entities likely to be
affected by this action. To determine
whether you would be affected by this
action, you should examine the
applicable industry description in
section I.E of this notice. If you have any
questions regarding the applicability of
this action to a particular entity, consult
the appropriate EPA contact listed in
the FOR FURTHER INFORMATION CONTACT
section of this notice.
Preparation of Comments. Do not
submit information containing CBI to
EPA through www.regulations.gov or email. Send or deliver information
identified as CBI only to the following
address: Mr. Roberto Morales, OAQPS
Document Control Officer (C404–02),
U.S. EPA, Office of Air Quality Planning
and Standards, Research Triangle Park,
North Carolina 27711, Attention: Docket
ID EPA–HQ–OAR–2006–0971. Clearly
mark the part or all of the information
that you claim to be CBI. For CBI
information in a disk or CD ROM that
you mail to EPA, mark the outside of the
disk or CD ROM as CBI and then
identify electronically within the disk or
CD ROM the specific information that is
claimed as CBI. In addition to one
complete version of the comment that
includes information claimed as CBI, a
copy of the comment that does not
contain the information claimed as CBI
must be submitted for inclusion in the
public docket. Information so marked
will not be disclosed except in
accordance with procedures set forth in
40 CFR part 2.
World Wide Web (WWW). In addition
to being available in the docket, an
electronic copy of this proposed action
will also be available on the Worldwide
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Web (WWW) through the Technology
Transfer Network (TTN). Following
signature, a copy of the proposed action
will be posted on the TTN’s policy and
guidance page for newly proposed or
promulgated rules at the following
address: https://www.epa.gov/ttn/oarpg/.
The TTN provides information and
technology exchange in various areas of
air pollution control.
Organization of This Document. The
information presented in this notice is
organized as follows:
I. Background
A. The Ozone Problem
B. Statutory and Regulatory Background
C. What is Photochemical Reactivity?
D. Role of Reactivity in VOC/Ozone
Regulations
E. The Aerosol Coating Industry
II. Summary of Proposed Standards
A. Applicability of the Standards and
Regulated Entities
B. Regulated Pollutant
C. Regulatory Limits
D. Compliance Requirements
E. Labeling Requirements
F. Recordkeeping and Reporting
G. Variance
H. Test Methods
III. Summary of Impacts
A. Environmental Impacts
B. Energy Impacts
C. Cost and Economic Impacts
IV. Rationale
A. Applicability
B. Regulated Pollutant
C. Regulatory Approach
D. VOC Regulatory Limits
E. Compliance Demonstration
Requirements
F. Labeling Requirements
G. Recordkeeping and Reporting
Requirements
H. Variance Criteria
I. Test Methods
V. Statutory and Executive Order (EO)
Reviews
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A. Executive Order 12866: Regulatory
Planning and Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act
D. Unfunded Mandates Reform Act
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation
and Coordination with Indian Tribal
Governments
G. Executive Order 13045: Protection of
Children from Environmental Health and
Safety Risks
H. Executive Order 13211: Actions
Concerning Regulations That
Significantly Affect Energy Supply,
Distribution, or Use
I. National Technology Transfer and
Advancement Act
J. Executive Order 12898: Federal Actions
to Address Environmental Justice in
Minority Populations and Low-Income
Populations
I. Background
A. The Ozone Problem
Ground-level ozone, a major
component of smog, is formed in the
atmosphere by reactions of VOC and
oxides of nitrogen in the presence of
sunlight. The formation of ground-level
ozone is a complex process that is
affected by many variables.
Exposure to ground-level ozone is
associated with a wide variety of human
health effects, as well as agricultural
crop loss, and damage to forests and
ecosystems. Controlled human exposure
studies show that acute health effects
are induced by short-term (1 to 2 hour)
exposures (observed at concentrations
as low as 0.12 parts per million (ppm)),
generally while individuals are engaged
in moderate or heavy exertion, and by
prolonged (6 to 8 hour) exposures to
ozone (observed at concentrations as
low as 0.08 ppm and possibly lower),
typically while individuals are engaged
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in moderate exertion. Transient effects
from acute exposures include
pulmonary inflammation, respiratory
symptoms, effects on exercise
performance, and increased airway
responsiveness. Epidemiological studies
have shown associations between
ambient ozone levels and increased
susceptibility to respiratory infection,
increased hospital admissions and
emergency room visits. Groups at
increased risk of experiencing elevated
exposures include active children,
outdoor workers, and others who
regularly engage in outdoor activities.
Those most susceptible to the effects of
ozone include those with preexisting
respiratory disease, children, and older
adults. The literature suggests the
possibility that long-term exposures to
ozone may cause chronic health effects
(e.g., structural damage to lung tissue
and accelerated decline in baseline lung
function).
B. Statutory and Regulatory Background
Under section 183(e) of the CAA, EPA
conducted a study of VOC emissions
from the use of consumer and
commercial products to assess their
potential to contribute to levels of ozone
that violate the National Ambient Air
Quality Standards (NAAQS) for ozone,
and to establish criteria for regulating
VOC emissions from these products.
Section 183(e) of the CAA directs EPA
to list for regulation those categories of
products that account for at least 80
percent of the VOC emissions, on a
reactivity-adjusted basis, from consumer
and commercial products in areas that
violate the NAAQS for ozone (i.e., ozone
nonattainment areas), and to divide the
list of categories to be regulated into
four groups.
EPA published the initial list in the
Federal Register on March 23, 1995 (60
FR 15264). In that notice, EPA stated
that it may amend the list of products
for regulation, and the groups of product
categories, in order to achieve an
effective regulatory program in
accordance with the Agency’s discretion
under CAA section 183(e). EPA has
revised the list several times. Most
recently, in May 2006, EPA revised the
list to add one product category,
portable fuel containers, and to remove
one product category, petroleum dry
cleaning solvents. See 71 FR 28320
(May 16, 2006). The aerosol spray paints
(aerosol coatings) category currently is
listed for regulation as part of Group III
of the CAA section 183(e) list.
CAA section 183(e) directs EPA to
regulate Consumer and Commercial
Products using ‘‘best available controls’’
(BAC). CAA section 183(e)(1)(A) defines
BAC as ‘‘the degree of emissions
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reduction that the Administrator
determines, on the basis of
technological and economic feasibility,
health, environmental, and energy
impacts, is achievable through the
application of the most effective
equipment, measures, processes,
methods, systems or techniques,
including chemical reformulation,
product or feedstock substitution,
repackaging, and directions for use,
consumption, storage, or disposal.’’
CAA section 183(e) also provides EPA
with authority to use any system or
systems of regulation that EPA
determines is the most appropriate for
the product category. Under CAA
section 183(e)(4), EPA can impose ‘‘any
system or systems of regulation as the
Administrator deems appropriate,
including requirements for registration
and labeling, self-monitoring and
reporting, prohibitions, limitations, or
economic incentives (including
marketable permits and auctions of
emissions rights) concerning the
manufacture, processing, distribution,
use, consumption or disposal of the
product.’’ Under these provisions, EPA
has previously issued national
regulations for architectural coatings,
autobody refinishing coatings, consumer
products, and portable fuel
containers.1, 2, 3, 4, 5
For any category of consumer or
commercial products, the Administrator
may issue control techniques guidelines
(CTGs) in lieu of national regulations if
the Administrator determines that such
guidance will be substantially as
effective as regulations in reducing
emissions of volatile organic
compounds which contribute to ozone
levels in areas which violate the
national ambient air quality standard for
ozone. In many cases, CTGs can be
effective regulatory approaches to
reduce emissions of VOC in
nonattainment areas because of the
nature of the specific product and the
uses of such product. A critical
distinction between a national rule and
a CTG is that a CTG may include
provisions that affect the users of the
products. For other product categories,
such as wood furniture coatings and
1 National Volatile Organic Compound Emission
Standards for Architectural Coatings’’ 63 FR 48848,
(September 11, 1998).
2 ‘‘National Volatile Organic Compound Emission
Standards for Automobile Refinish Coatings’’ 63 FR
48806, (September 11, 1998).
3 ‘‘Consumer and Commercial Products: Schedule
for Regulation’’ 63 FR 48792, (September 11, 1998).
4 ‘‘National Volatile Organic Compound Emission
Standards for Consumer Products’’ 63 FR 48819,
(September 11, 1998).
5 ‘‘National Volatile Organic Compound Emission
Standards for Portable Fuel Containers’’ 72 FR
8428, (February 26, 2007).
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shipbuilding coatings, EPA has
previously determined that, under CAA
section 183(e)(3)(C), a CTG would be
substantially as effective as a national
rule and, therefore, issued CTGs to
provide guidance to States for
development of appropriate State
regulations.
For the category of aerosol coatings,
EPA has determined that a national rule
applicable nationwide is the best system
of regulation to achieve necessary VOC
emission reductions from this type of
product. Aerosol coatings are typically
used in relatively small amounts by
consumers and others on an occasional
basis and at varying times and locations.
Under such circumstances,
reformulation of the VOC content of the
products is a more feasible way to
achieve VOC emission reductions,
rather than through a CTG approach that
would only affect a smaller number of
relatively large users. Aerosol coatings
regulations are already in place in three
States (California, Oregon, and
Washington), and other States are
considering developing regulations for
these products. For the companies that
market aerosol coatings in different
States, trying to fulfill the differing
requirements of State rules may create
administrative, technical, and marketing
problems. A Federal rule is expected to
provide some degree of consistency,
predictability, and administrative ease
for the industry. A national rule also
helps States reduce compliance
problems associated with noncompliant
coatings being transported into
nonattainment areas from neighboring
areas and neighboring States. A national
rule will also enable States to obtain
needed VOC emission reductions from
this sector in the near term, without
having to expend their limited resources
to develop similar rules in each State.6
C. What Is Photochemical Reactivity?
There are thousands of individual
species of VOC chemicals that can
participate in a series of reactions
involving nitrogen oxides (NOX) and the
energy from sunlight, resulting in the
formation of ozone. The impact of a
given species of VOC on formation of
ground-level ozone is sometimes
referred to as its ‘‘reactivity.’’ It is
generally understood that not all VOC
are equal in their effects on ground-level
ozone formation. Some VOC react
extremely slowly and changes in their
emissions have limited effects on ozone
pollution episodes. Some VOC form
ozone more quickly than other VOCs, or
they may form more ozone than other
6 ALARM Caucus v. EPA, 215 F.3d 61,76 (D.C.
Cir. 2000), cert. denied, 532 U.S. 1018 (2001).
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VOC. Other VOC not only form ozone
themselves, but also act as catalysts and
enhance ozone formation from other
VOC. By distinguishing between more
reactive and less reactive VOC,
however, EPA believes that it may be
possible to develop regulations that will
decrease ozone concentrations further or
more efficiently than by controlling all
VOC equally.
Assigning a value to the reactivity of
a specific VOC species is a complex
undertaking. Reactivity is not simply a
property of the compound itself; it is a
property of both the compound and the
environment in which the compound is
found. Therefore, the reactivity of a
specific VOC varies with VOC:NOX
ratios, meteorological conditions, the
mix of other VOC in the atmosphere,
and the time interval of interest.
Designing an effective regulation that
takes account of these interactions is
difficult. Implementing and enforcing
such a regulation requires an extra
burden for both industry and regulators,
as those impacted by the rule must
characterize and track the full chemical
composition of VOC emissions rather
than only having to track total VOC
content as is required by traditional
mass-based rules. EPA’s September 13,
2005 final rule 7 to approve a
comparable reactivity-based aerosol
coating rule as part of the California
State Implementation Plan for ozone
contains additional background
information on photochemical
reactivity. Recently, EPA issued interim
guidance to States regarding the use of
VOC reactivity information in the
development of ozone control
measures.8
1. What Research Has Been Conducted
in Reactivity?
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Much of the initial work on reactivity
scales was funded by the California Air
Resources Board (CARB), which was
interested in comparing the reactivity of
emissions from different alternative
fueled vehicles. In the late 1980s, CARB
provided funding to William P. L. Carter
at the University of California to
develop a reactivity scale. Carter
investigated 18 different methods of
ranking the reactivity of individual VOC
in the atmosphere using a single-cell
trajectory model with a state-of-the-art
7 ‘‘Revisions to the California State
Implementation Plan and Revision to the Definition
of Volatile Organic Compounds (VOC)–Removal of
VOC Exemptions for California’s Aerosol Coating
Products Reactivity-based Regulation’’ 70 FR 53930,
(September 13, 2005).
8 ‘‘Interim Guidance on Control of Volatile
Organic Compounds in Ozone State
Implementation Plans’’) 70 FR 54046, (September
13, 2005).
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chemical reaction mechanism.9 Carter
suggested three scales for further
consideration:
i. Maximum Incremental Reactivity
(MIR) scale-an ozone yield scale derived
by adjusting the NOX emissions in a
base case to yield the highest
incremental reactivity of the base
reactive organic gas mixture.
ii. Maximum Ozone Incremental
Reactivity (MOIR) scale-an ozone yield
scale derived by adjusting the NOX
emission in a base case to yield the
highest peak ozone concentration.
iii. Equal Benefit Incremental
Reactivity (EBIR) scale-an ozone yield
scale derived by adjusting the NOX
emissions in a base case scenario so
VOC and NOX reductions are equally
effective in reducing ozone.
Carter concluded that, if only one
scale is used for regulatory purposes,
the maximum incremental reactivity
(MIR) scale is the most appropriate.10
The MIR scale is defined in terms of
environmental conditions where ozone
production is most sensitive to changes
in hydrocarbon emissions and,
therefore, represents conditions where
hydrocarbon controls would be the most
effective. CARB therefore used the MIR
scale to establish fuel-neutral VOC
emissions limits in its low-emitting
vehicle and alternative fuels
regulation.11, 12 Subsequently, Carter has
updated the MIR scale several times as
the chemical mechanisms in the model
used to derive the scale have evolved
with new scientific information. CARB
incorporated a 1999 version of the MIR
scale in its own aerosol coatings rule.
The latest revision to the MIR scale was
issued in 2003.
In addition to Carter’s work, there
have been other attempts to create
reactivity scales. One such effort is the
work of R.G. Derwent and coworkers,
who have published articles on a scale
called the photochemical ozone creation
potential (POCP) scale.13, 14 This scale
9 Carter, W. P. L. (1994) ‘‘Development of ozone
reactivity scales for organic gases,’’ J. Air Waste
Manage. Assoc., 44: 881–899.
10 ‘‘Initial Statement of Reasons for the California
Aerosol Coatings Regulation, California Air
Resources Board,’’ 2000.
11 California Air Resources Board ‘‘Proposed
Regulations for Low-Emission Vehicles and Clean
Fuels—Staff Report and Technical Support
Document,’’ State of California, Air Resources
Board, P.O. Box 2815, Sacramento, CA 95812,
August 13, 1990.
12 California Air Resources Board ‘‘Proposed
Regulations for Low-Emission Vehicles and Clean
Fuels—Final Statement of Reasons,’’ State of
California, Air Resources Board, July 1991.
13 Derwent, R.G., M.E. Jenkin, S.M. Saunders and
M.J. Pilling (2001) ‘‘Characterization of the
Reactivities of Volatile Organic Compounds Using
a Master Chemical Mechanism,’’ J. Air Waste
Management Assoc., 51: 699–707.
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38955
was designed for the emissions and
meteorological conditions prevalent in
Europe. The POCP scale is generally
consistent with that of Carter, although
there are some differences because it
uses a different model, chemical
mechanism, and emission and
meteorological scenarios. Despite these
differences, there is a good correlation
of r2=0.9 between the results of the
POCP and the MIR scales12.
As CARB worked to develop
reactivity-based regulations in
California, EPA began to explore the
implications of applying reactivity
scales in other parts of the country. In
developing its regulations, CARB has
maintained that the MIR scale is the
most appropriate metric for application
in California, but cautions that its
research has focused on California
atmospheric conditions and that the
suitability of the MIR scale for
regulatory purposes in other areas has
not been demonstrated. In particular,
specific concerns have been raised
about the suitability of using the MIR
scale in relation to multi-day stagnation
or transport scenarios or over
geographic regions with very different
VOC:NOX ratios than those of
California.
In 1998, EPA participated in the
formation of the Reactivity Research
Working Group (RRWG), which was
organized to help develop an improved
scientific basis for reactivity-related
regulatory policies.15 All interested
parties were invited to participate. Since
that time, representatives from EPA,
CARB, Environment Canada, States,
academia, and industry have met in
public RRWG meetings to discuss and
coordinate research that would support
this goal.
The RRWG has organized a series of
research efforts to explore:
i. The sensitivity of ozone to VOC
mass reductions and changes in VOC
composition under a variety of
environmental conditions;
ii. The derivation and evaluation of
reactivity scales using photochemical
airshed models under a variety of
environmental conditions;
iii. The development of emissions
inventory processing tools for exploring
reactivity-based strategies; and
iv. The fate of VOC emissions and
their availability for atmospheric
reactions.
This research has led to a number of
findings that increase our confidence in
14 Derwent, R.G., M.E. Jenkin, S.M. Saunders and
M.J. Pilling (1998) ‘‘Photochemical Ozone Creation
Potentials for Organic Compounds in Northwest
Europe Calculated with a Master Chemical
Mechanism,’’ Atmos. Env., 32(14/15):2429–2441.
15 See https://www.narsto.org/section.src?SID=10.
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the ability to develop regulatory
approaches that differentiate between
specific VOC on the basis of relative
reactivity. The first two research
objectives listed above were explored in
a series of three parallel modeling
studies that resulted in four reports and
one journal article.16, 17, 18, 19, 20 EPA
commissioned a review of these reports
to address a series of policy-relevant
science questions.21 In 2007, an
additional peer review was
commissioned by EPA to assess the
appropriateness of basing a national
aerosol coatings regulation on reactivity.
Generally, the peer reviews support the
appropriateness of the use of the boxmodel based MIR metric nationwide for
the aerosol coatings category. The
results are available in the rulemaking
docket.
The results of the RRWG-organized
study and the subsequent reviews
suggest that there is good correlation
between different relative reactivity
metrics calculated with photochemical
airshed models, regardless of the choice
of model, model domain, scenario, or
averaging times. Moreover, the scales
calculated with photochemical airshed
models correlate relatively well with the
MIR metric derived with a single cell,
one-dimensional box model. Prior to the
RRWG-organized studies, little analysis
of the robustness of the box-model
derived MIR metric and its applicability
to environmental conditions outside
California had been conducted.
Although these studies were not
specifically designed to test the
robustness of the box-model derived
MIR metrics, the results suggest that the
MIR metric is relatively robust.
16 Carter, W.P.L., G. Tonnesen, and G. Yarwood
(2003) Investigation of VOC Reactivity Effects Using
Existing Regional Air Quality Models, Report to
American Chemistry Council, Contract SC–20.0–
UCR–VOC–RRWG, April 17, 2003.
17 Hakami, A., M.S. Bergin, and A.G. Russell
(2003) Assessment of the Ozone and Aerosol
Formation Potentials (Reactivities) of Organic
Compounds over the Eastern United States, Final
Report, Prepared for California Air Resources
Board, Contract No. 00–339, January 2003.
18 Hakami, A., M.S. Bergin, and A.G. Russell
(2004a) Ozone Formation Potential of Organic
Compounds in the Eastern United States: A
Comparison of Episodes, Inventories, and Domains,
Environ. Sci. Technol. 2004, 38, 6748–6759.
19 Hakami, A., M. Arhami, and A.G. Russell
(2004b) Further Analysis of VOC Reactivity Metrics
and Scales, Final Report to the U.S. EPA, Contract
#4D–5751–NAEX, July 2004.
20 Arunachalam S., R. Mathur, A. Holland, M.R.
Lee, D. Olerud, Jr., and H. Jeffries (2003)
Investigation of VOC Reactivity Assessment with
Comprehensive Air Quality Modeling, Prepared for
U.S. EPA, GSA Contract # GS–35F–0067K, Task
Order ID: 4TCG68022755, June 2003.
21 Derwent, R.G. (2004) Evaluation and
Characterization of Reactivity Metrics, Final Draft,
Report to the U.S. EPA, Order No. 4D–5844–NATX,
November 2004.
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D. Role of Reactivity in VOC/Ozone
Regulations
Historically, EPA’s general approach
to regulation of VOC emissions has been
based upon control of total VOC by
mass, without distinguishing between
individual species of VOC. EPA
considered the regulation of VOC by
mass to be the most effective and
practical approach based upon the
scientific and technical information
available when EPA developed its VOC
control policy.
EPA issued the first version of its
VOC control policy in 1971, as part of
EPA’s State Implementation Plan (SIP)
preparation guidance.22 In that
guidance, EPA emphasized the need to
reduce the total mass of VOC emissions,
but also suggested that substitution of
one compound for another might be
useful when it would result in a clearly
evident decrease in reactivity and thus
tend to reduce photochemical oxidant
formation. This latter statement
encouraged States to promulgate SIPs
with VOC emission substitution
provisions similar to the Los Angeles
County Air Pollution Control District’s
(LACAPCD) Rule 66, which allowed
some VOC that were believed to have
low to moderate reactivity to be
exempted from control. The exempt
status of many of those VOC was
questioned a few years later, when
research results indicated that, although
some of those compounds do not
produce much ozone close to the
source, they may produce significant
amounts of ozone after they are
transported downwind from urban
areas.
In 1977, further research led EPA to
issue a revised VOC policy under the
title ‘‘Recommended Policy on Control
of Volatile Organic Compounds,’’ (42 FR
35314, July 8, 1977), offering its own,
more limited list of exempt organic
compounds. The 1977 policy identified
four compounds that have very low
photochemical reactivity and
determined that their contribution to
ozone formation and accumulation
could be considered negligible. The
policy exempted these ‘‘negligibly
reactive’’ compounds from VOC
emissions limitations in programs
designed to meet the ozone NAAQS.
Since 1977, the EPA has added other
compounds to the list of negligibly
reactive compounds based on new
information as it has been developed. In
1992, the EPA adopted a formal
regulatory definition of VOC for use in
SIP, which explicitly excludes
22 ‘‘Requirements for Preparation, Adoption and
Submittal of Implementation Plans’’, Appendix B,
36 FR 15495, (August 14, 1971).
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compounds that have been identified as
negligibly reactive (40 CFR 51.100(s)).
To date, EPA has exempted 54
compounds or classes of compounds in
this manner. In effect, EPA’s current
VOC exemption policy has generally
resulted in a two bin system in which
most compounds are treated equally as
VOC and are controlled and a separate
smaller group of compounds are treated
as negligibly reactive and are exempt
from VOC control.23 This approach was
intended to encourage the reduction of
emissions of all VOC that participate in
ozone formation. From one perspective,
it appears that this approach has been
relatively successful. EPA estimates
that, between 1970 and 2003, VOC
emissions from man-made sources
nationwide declined by 54 percent. This
decline in VOC emissions has helped to
decrease average ozone concentration by
29 percent (based on 1-hour averages)
and 21 percent (based on 8-hour
averages) between 1980 and 2003. These
reductions occurred even though,
between 1970 and 2003, population,
vehicle miles traveled, and gross
domestic product rose 39 percent, 155
percent and 176 percent respectively.24
On the other hand, some have argued
that a reactivity-based approach for
reducing VOC emissions would be more
effective than the current mass-based
approach. One group of researchers
conducted a detailed modeling study of
the Los Angeles area and concluded
that, compared to the current approach,
a reactivity-based approach could
achieve the same reductions in ozone
concentrations at significantly less cost
or, for a given cost, could achieve a
significantly greater reduction in ozone
concentrations.25 Although the
traditional approach to VOC control
focused on reducing the overall mass of
emissions may be adequate in some
areas of the country, EPA’s recent
guidance on control of VOC in ozone
SIPs recognizes that approaches to VOC
control that differentiate between VOC
23 For some analytical purposes, EPA has
distinguished between VOC and ‘‘highly reactive’’
VOC, such as in the Agency’s initial evaluation of
consumer products for regulation. See, ‘‘Final
Listing,’’ 63 FR 48792, 48795–6 (Sept. 11, 1998)
(explaining EPA’s approach); see also, ALARM
Caucus v. EPA, 215 F. 3d 61, 69—73 (D.C. Cir.
2000), cert. denied, 532 U.S. 1018 (2001) (approving
EPA’s approach as meeting the requirements of
CAA section 183(e)).
24 ‘‘Latest Findings on National Air Quality: 2002
Status and Trends,’’ EPA 454/K–03–001, (August
2003); and ‘‘The Ozone Report Measuring Progress
through 2003,’’ EPA 454/K–04–001, (April 2004);
Environmental Protection Agency, Office of Air
Quality Planning and Standards, Research Triangle
Park, North Carolina.
25 A. Russell, J. Milford, M. S. Bergin, S. McBride,
L. McNair, Y. Yang, W. R. Stockwell, B. Croes,
‘‘Urban Ozone Control and Atmospheric Reactivity
of Organic Gases,’’ Science, 269: 491–495, (1995).
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based on relative reactivity are likely to
be more effective and efficient under
certain circumstances.26 In particular,
reactivity-based approaches are likely to
be important in areas for which
aggressive VOC control is a key strategy
for reducing ozone concentrations. Such
areas include:
• Areas with persistent ozone
nonattainment problems;
• Urbanized or other NOX-rich areas
where ozone formation is particularly
sensitive to changes in VOC emissions;
• Areas that have already
implemented VOC RACT measures and
need additional VOC emission
reductions.
In these areas, there are a variety of
possible ways of addressing VOC
reactivity in the SIP development
process, including:
• Developing accurate, speciated VOC
emissions inventories.
• Prioritizing control measures using
reactivity metrics.
• Targeting emissions of highlyreactive VOC compounds with specific
control measures.
• Encouraging VOC substitution and
composition changes using reactivityweighted emission limits.
The CARB aerosol coatings rule is an
example of this last application of the
concept of reactivity. CARB’s reactivitybased rule encouraged the use of
compounds that were less effective at
producing ozone. It contained limits for
aerosol coatings expressed as grams of
ozone formed per gram of product
instead of the more traditional limits
expressed as percent VOC. EPA
approved CARB’s aerosol coatings rule
as part of the California SIP for ozone.
EPA’s national aerosol coatings rule
builds largely upon CARB’s efforts to
regulate this product category based
upon relative reactivity.
E. The Aerosol Coating Industry
Aerosol coatings include all coatings
that are specially formulated and
packaged for use in pressurized cans.
They are used by both professional and
by do-it-yourself (DIY) consumers. The
DIY segment accounts for approximately
80 percent of all sales. The remainder of
aerosol coatings is sold for industrial
maintenance and original equipment
manufacturer use. Aerosol coatings are
used for a number of applications
including small domestic coating jobs,
field and construction site marking, and
touch-up of marks and scratches in
paintwork of automobiles, appliances
and machinery.
26 ‘‘Interim Guidance on Control of Volatile
Organic Compounds in Ozone State
Implementation Plans,’’ 70 FR 54046, September
13, 2005).
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The aerosol coatings industry
includes the formulators and
manufacturers of the concentrated
product. These manufacturers may
package the product or they may use toll
fillers (processors). These toll fillers
may work not only with the large
manufacturers, but for other coating
manufacturers who do not have the
specialized equipment to fill aerosol
containers. The fillers may then supply
the product to coating dealers, home
supply stores, distributors, companyowned stores, and industrial customers.
An aerosol consists of a gas in which
liquid or solid substances may be
dispensed. Aerosol coatings are
pressurized coatings that, like other
coatings, consist of pigments and resins
and solvents. However, aerosol coatings
also contain a propellant that dispenses
the product ingredients. A controlled
amount of propellant in the product
vaporizes as it leaves the container,
creating the aerosol spray. The
combination of product and propellant
is finely tuned to produce the correct
concentration and spray pattern for an
effective product.
Aerosol coatings can be packaged in
disposable cans for hand-held
applications or for use in specialized
equipment in ground traffic/marking
applications. As with other coatings,
aerosol coatings are available in both
solvent-based and water-based
formulations.
In developing the proposed national
rule for aerosol coatings, EPA is using
the same coating categories, and the
same definitions for those categories,
previously identified by CARB in its
comparable regulation for aerosol
coatings. We believe these categories
adequately categorize the industry and
encompass the range of products
included in our own analysis of this
category that we conducted in preparing
the Report to Congress (EPA–453/R–94–
066–A). Use of the same definitions and
categories has the added benefit of
providing regulated entities with
consistency between the CARB and
national rules. The categories we
propose include six general categories
and 30 specialty categories. Based on a
survey of aerosol coating manufacturers
conducted by CARB in 1997, VOC
emissions from the six general
categories together with the specialty
category of Ground Traffic/Marking
Coatings account for approximately 85
percent of the ozone formed as a result
of the use of aerosol coatings. These
categories are defined in this proposed
regulation and are described in more
detail in the docket to this rulemaking.
There are currently no national
regulations addressing VOC emissions
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from aerosol coatings. California,
Oregon and Washington are the only
States that currently regulate aerosol
coating products and Oregon’s and
Washington’s rules are identical to the
Tier 1 VOC mass-based limits developed
by CARB that became effective in 1996.
Unlike other EPA or State regulations
and previous CARB regulations for
aerosol coatings that regulate VOC
ingredients by mass in the traditional
approach, the current California
regulation for aerosol coatings is
designed to limit the ozone formed from
VOC emissions from aerosol coatings by
establishing limits on the reactivity of
the cumulative VOC ingredients of such
coatings. A more thorough discussion of
the reactivity approach and the
proposed reactivity limits are presented
later in this preamble (section IV.D).
II. Summary of Proposed Standards
A. Applicability of the Standards and
Regulated Entities
The proposed Aerosol Coatings
Reactivity Rule (ACRR) will apply to
manufacturers, processors, wholesale
distributors, or importers of aerosol
coatings used by both the general
population (i.e., the ‘‘Do It Yourself’’
market) and industrial applications (e.g.,
at original equipment manufacturers
and other industrial sites). This
regulation will also apply to distributors
if those distributors are responsible for
any of the labeling of the aerosol
products. The proposed rule includes an
exemption from the limits in Table 1 of
subpart E of the rule for those
manufacturers that manufacture very
limited amounts of aerosol coatings, i.e.,
products with a total VOC content by
mass of no more than 7,500 kilograms
of VOC per year in the aggregate for all
products. EPA notes that an exemption
under EPA’s national rule for aerosol
coatings under section 183(e) does not
alter any requirements under any
applicable State or local regulations.
B. Regulated Pollutant
The regulated pollutants under this
proposed regulation are VOC, as that
term is defined in 40 CFR 51.100(s).
However, the listed exempt compounds
that are normally excluded from the
definition of VOC in 40 CFR 51.100(s)(1)
will be regulated as VOC for purposes
of this regulation. Because all of these
compounds contribute to ozone
formation, we are proposing to amend
the regulatory definition of VOC for
purposes of this rule. While the
regulated pollutants will be VOCs, the
emission limits in the standard will be
expressed in terms of weight of ozone
generated from the VOC ingredients per
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weight of coating material, rather than
the traditional weight of VOC
ingredients per weight or volume of
product. We believe that this approach
will allow us to reduce the overall
amount of ozone that results from the
VOCs emitted to the atmosphere from
these products, while providing
manufacturers with the flexibility to
select VOC ingredients for their
products. This approach provides
incentives to manufacturers to
reformulate their products using VOC
ingredients that will likely result in less
ozone production.
C. Regulatory Limits
The proposed regulatory limits for the
ACRR are a series of reactivity limits for
six general coating categories and 30
subcategories of specialty coatings.
These reactivity limits are expressed in
terms of mass of ozone generation per
gram of product. In addition to
compliance with the reactivity limits, a
regulated entity is also required to
comply with labeling, recordkeeping,
and reporting requirements.
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D. Compliance Requirements
The proposed rule requires all
regulated entities to comply by January
1, 2009. The proposed rule includes a
provision that allows regulated entities
that have not previously manufactured,
imported, or distributed for sale or
distribution in California any product
that complies with applicable California
regulations for aerosol coatings to seek
an extension of the compliance date
until January 1, 2011.
After the compliance date, the
regulated entity under this proposed
rule will be required to conduct initial
compliance demonstration calculations
for all coating formulations
manufactured or filled at each of their
facilities. These calculations must be
maintained on-site for 5 years after the
product is manufactured, processed,
distributed, or imported, and must be
submitted to the Agency upon request.
The regulated entity may use
formulation data to make the
compliance calculations; however, EPA
is proposing to adopt California’s
Method 310 as the underlying test
method (i.e., formulation data should be
verifiable with CARB 310, if requested).
Facilities will also be allowed to use
EPA’s Test Method 311.
E. Labeling Requirements
The proposed rule also includes
labeling requirements to facilitate
implementation and enforcement of the
limits. Labels must clearly identify the
product category or the category code
provided in Table 1 of the regulation,
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the limit for that category, and the
product date code. If the date code is
not easily discernable, an explanation of
the code would need to be included in
the initial notification discussed below.
F. Recordkeeping and Reporting
The proposed rule includes a
requirement for an initial notification
report from all regulated entities to EPA
90 days before the compliance date.
This report will provide basic
information about the regulated entity
and will identify all manufacturers,
processors, wholesale distributors, or
importers of aerosol coatings. In
addition, this report will need to
explain the date code system used to
label products and it must include a
statement certifying that all of the
company’s products will be in
compliance with the limits by the
compliance date.
The regulated entity is required to
maintain compliance calculations for
each of its aerosol coatings
formulations. For each batch of a
particular formulation, the regulated
entity must maintain records of the
date(s) the batch was manufactured, the
volume of the batch, and the VOC
formula for the formulation. Records of
these calculations must be maintained 5
years after the product is manufactured,
processed, distributed for wholesale, or
imported for sale or distribution in
interstate commerce in the United
States.
The proposed rule does not include
any regular, ongoing reporting
requirements for most regulated entities.
Reporting after the initial compliance
report is only required when a
manufacturer adds a new coating
category. When this happens, a new
notification is required. However, the
EPA also invites public comment on the
feasibility and need for additional
reporting requirements.
The proposed rule requires those
small manufactures that qualify for
exemption from the limits of Table 1 of
subpart E of the rule to make an annual
report to EPA providing necessary
information and documentation to
establish that the products made by the
entity should be exempt.
G. Variance
The proposed rule allows regulated
entities to submit a written application
to the Agency requesting a temporary
variance if, for reasons beyond their
reasonable control, they cannot comply
with the requirements of the rule. An
approved variance order would specify
a final compliance date and a condition
that imposes increments of progress
necessary to assure timely compliance.
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A variance would end immediately if
the regulated entity failed to comply
with any term or condition of the
variance. The Administrator will
provide special consideration to
variance requests from regulated
entities, particularly small businesses
that have not marketed their products in
areas subject to State regulations for
these products prior to this rulemaking.
EPA notes that a variance under EPA’s
national rule for aerosol coatings under
section 183(e) does not alter any
requirements under any applicable state
or local regulations.
H. Test Methods
Although regulated entities may use
formulation data to demonstrate
compliance with the reactivity limits,
EPA believes it is also necessary to have
test methods in place that can be used
to verify the accuracy of the formulation
data. Therefore, we have included two
test methods that can be used by
regulated entities or the Administrator
to determine compliance with the
reactivity limits. In those cases where
the formulation data and test data are
not in agreement, data collected using
the approved test methods will prevail.
Regulated entities or regulatory agencies
may use either CARB Method 310—
Determination of Volatile Organic
Compounds in Consumer Products and
Reactive Organic Compounds in Aerosol
Coating Products or EPA Method 311—
Analysis of Hazardous Air Pollutant
Compounds in Paints and Coatings to
determine the reactive organic
compound content of an aerosol coating.
CARB Method 310 includes some test
procedures that are not required to
determine the VOC content of aerosol
coatings; for example, Method 310
incorporates EPA Method 24 for
determining the VOC content of a
coating. We have identified those
sections of Method 310 that are not
required for compliance demonstration
purposes in the regulation. EPA Method
311 was originally developed for liquid
coatings; so, it does not include
provisions for the collection of the
propellant portion of an aerosol coating.
Therefore, those choosing to use Method
311 must separate the aerosol propellant
from the coating using either ASTM
D3063–94 or ASTM D 3074–94.
III. Summary of Impacts
This section presents a summary of
the impacts expected as a result of this
proposed rule. To ensure that the
impacts are not minimized, we followed
an approach that would provide
conservative estimates for each impact.
For environmental impacts, we ensured
that our estimated positive impact (i.e.,
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emission reduction) was not overstated
(i.e., conservatively low). For cost and
economic impacts, we ensured that our
estimated impacts were not understated
(i.e., conservatively high). This
approach ensures that conclusions
drawn on the overall impact on
facilities, including small businesses,
are based on conservative assumptions.
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A. Environmental Impacts
In accordance with section 183(e),
EPA has evaluated what regulatory
approach would constitute ‘‘best
available controls’’ for this product
category, taking into account the
considerations noted in the statute. EPA
has evaluated the incremental increase
or decrease in air pollution, water
pollution, and solid waste reduction
that would result from implementing
the proposed standards.
1. Air Pollution Impacts
The proposed rule will reduce both
VOC emissions and the amount of ozone
generated from the use of aerosol
coatings. Because most States will use
the VOC emission reductions resulting
from this rule in their ozone SIP
planning, we have calculated the
reductions associated with the rule in
terms of mass VOC emissions and we
will refer to a reduction in mass VOC
emissions when discussing the impacts
of the proposed regulation. EPA believes
this is appropriate because the reactivity
limits were designed to ensure that the
ozone reductions that would be
achieved by the limits were equivalent
to the mass VOC reductions that would
have been achieved by the CARB 2002
mass-based VOC limits. However,
because the limits actually reduce the
amount of ozone generated from the
VOC used in aerosol coatings rather
than VOC content by mass, the VOC
reductions that we refer to are more
accurately described as an ‘‘equivalent
reduction in VOC emissions.’’ We will
use the term ‘‘reduction’’ in subsequent
discussions. Additional information on
the method used to calculate the air
impacts of the proposed rule are
included in the impacts calculation
memo contained in the docket to this
rulemaking.
As proposed, EPA believes that this
rule would reduce nationwide
emissions of VOC from the use of
aerosol coatings by an estimated 15,570
Mg (17,130 tons) from the 1990 baseline.
This represents a 19.4 percent reduction
from the 1990 baseline of 80,270 Mg
(88,300 tons) of VOC emissions from the
product category. While we believe that
the above numbers accurately assess the
impacts of the proposed rule for SIP
credit purposes, we recognize that
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significant reductions have already
occurred as the result of the
implementation of the CARB aerosol
coatings regulations. Because many
manufacturers sell ‘‘CARB compliant’’
coatings across the country, some of
these VOC emission reductions have
already been achieved outside of
California. We estimate that
approximately 18 percent of the total
products sold are not compliant with
EPA’s proposed limits. Therefore, we
estimate that this rule will result in
additional VOC reductions equivalent to
3,100 tons per year (i.e., 18 percent of
17,130). We request comment on our
estimate of the products that are not
compliant with these limits specifically,
and on our evaluation of the potential
VOC emission reductions generally.
The 18 percent reduction in VOC
emissions represents new reductions.
However, for ozone SIP purposes, we
plan to give States that do not currently
have aerosol coating regulations in place
full credit for the 19.4 percent reduction
from the 1990 baseline. This 19.4
percent reduction is equivalent to a
0.114 pound of VOC reduction per
capita.
Although we have not quantified the
anticipated impacts of this rule on HAP
emissions, EPA expects that the
proposed rule would reduce emissions
of toluene and xylene, two highly
reactive toxic compounds. Toluene and
xylene are hazardous air pollutants that
manufacturers have historically used
extensively in some aerosol coating
formulations. However, both of these
compounds are also highly reactive
VOCs. Therefore, it will be difficult for
regulated entities to continue to use
these compounds in significant
concentrations and still meet the
reactivity limits in the proposed rule.
EPA believes that the proposed rule
based upon VOC reactivity, rather than
VOC mass, will provide a significant
incentive for manufacturers to cease or
reduce use of toluene and xylene in
their products.
Due to the reduction in equivalent
VOC emissions and ozone formation
and the anticipated reduction in
hazardous air pollutant emissions, we
believe the rule will improve human
health and the environment.
2. Water and Solid Waste Impacts
There are no adverse solid waste
impacts anticipated from the
compliance with this rule. Because
companies can continue to sell and
distribute coatings that do not meet the
reactivity limits after the compliance
date as long as those coatings were
manufactured before the compliance
date the industry does not have to
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dispose of aerosol cans containing
noncompliant product, which would
result in an increase in solid waste. It is
possible that the proposed rule will
actually result in a reduction in solid
waste as more concentrated higher
solids coatings may be used as an option
for meeting the proposed limits. This
will result in fewer containers requiring
disposal when the same volume of
solids is applied by product users.
There are no anticipated adverse
water impacts from this rulemaking.
B. Energy Impacts
There are no adverse energy impacts
anticipated from compliance with this
proposed rule. EPA believes that
regulated entities will comply through
product reformulation which will not
significantly alter energy impacts. The
proposed rule does not include add-on
controls or other measures that would
add to energy usage or other impacts.
C. Cost and Economic Impacts
There are four types of facilities that
will be impacted by the proposed rule.
These include the aerosol coating
manufacturers, aerosol coating
processors, and aerosol coating
wholesale distributors, and importers of
aerosol coatings. For some products, the
manufacturer is also the filler and
distributor, while for other products the
manufacturing process, the filling
process, and the distribution may be
done by three separate companies. The
primary focus of our cost and economic
analysis is the aerosol coating
manufacturers as we anticipate that the
costs to the fillers, distributors, or
importers will be minimal.
For the aerosol coating manufacturer,
we evaluated three components in
determining the total cost of the
proposed rule. These three components
include the cost of the raw materials
that the manufacturer will use to
formulate coatings that comply with the
proposed rule, the cost of research and
development efforts that will be
necessary to develop compliant
formulations, and the cost of the
recordkeeping and reporting
requirements associated with the
proposed rule. Because we have limited
information on aerosol coating sales for
the aerosol coating manufacturers that
we have identified, we evaluated each
of these costs on a per can basis for each
of the 36 coating categories. A brief
discussion of each of these cost
components is presented below. A more
detailed discussion of the cost analysis
is presented in the cost analysis
memorandum that is included in the
docket.
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The proposed rule is based on
reactivity limits established for six
general coating categories and 30
specialty coating categories. To meet the
limits, aerosol coating manufacturers
may have to reformulate their existing
coatings with different solvents and
propellants, or at least different
combinations of those compounds. The
difference in the cost of the solvents and
propellants used for formulating the
complying coatings and those used for
formulating the noncomplying coatings
is the basis for the raw material costs.
To determine the raw material costs,
we used data compiled by CARB from
its 1997 survey of the aerosol coatings
industry. Using the data from the
survey, CARB developed a typical
formulation for a complying coating for
each category and a typical formulation
for a noncomplying coating for each
category. We then compared the cost of
the materials used in each formulation
to determine the raw material costs per
can for each category. The raw material
costs per can ranged from a cost savings
of $0.04/can, that is, the cost of the raw
materials used in the complying coating
was less than the cost of the raw
materials used in the noncomplying
coating, to a cost increase of $0.12/can.
Aerosol coating manufacturers not
only have to develop formulations that
meet the reactivity limits in the
proposed rule, but they also must
ensure that the reformulated coatings
have the same performance
characteristics and the coatings that
they will replace. We anticipate that this
may require manufacturers to invest
resources in research and development
efforts. For the purposes of this analysis,
we assumed that each aerosol coating
manufacturer would have to hire one
additional chemist to assist in
reformulation efforts.
Using a list of aerosol coating
manufacturers and the categories of
coatings they manufactured that was
developed by CARB using its 1997
survey data, we assigned chemists to
each coating category based on the
number of companies manufacturing
coatings in that category. Because most
companies manufacture coatings in
more than one category, we assigned the
chemists for each company based on the
number of categories they
manufactured. For example, if a
company manufactured products in two
categories, we assigned 0.5 chemists to
that category. We then totaled the
number of chemists required for each
category.
Using data from the American
Chemical Society on chemist salaries
and the number of chemists for each
category, we then developed annualized
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research and development costs for each
category. The annualized costs were
based on a period of 10 years and an
interest rate of 7 percent. These
annualized research and development
costs for each category were then
divided by the number of aerosol cans
manufactured in each category to
determine the total research and
development costs per can for each
coating category. Research and
development costs ranged from $0.00/
can to $0.109/can.
Aerosol coating manufacturers will
also have costs associated with the
recordkeeping and reporting
requirements in the proposed rule.
These costs include the time required
for such activities as reading and
understanding the reporting
requirements of the rule, reviewing the
compliance calculations required under
the rule and implementing an approach
for performing those calculations, and
preparing the initial compliance report.
Because the reactivity approach is new
to coating manufacturers, we assumed
that a supervisor would be performing
each of these tasks. We estimated the
total cost for recordkeeping and
reporting for the industry at $670,140
per year which equates to $0.002/can.
The total cost per can for raw
materials, research and development,
and recordkeeping and reporting
requirements ranges from $0.002 to
$0.141. Based on data from the U.S.
Census Bureau on the volume of aerosol
paint concentrates produced for
packaging in aerosol coatings and
information provided by the National
Paint and Coatings Association (NPCA)
on the amount of concentrate in a can,
we estimated that 329,536,000 10.5
ounce cans were produced in 2005. If all
of these cans required reformulation, the
total nationwide cost of the proposed
rule would be $20,360,521. However,
we know that significant progress has
already been made in reformulating
aerosol coatings to meet the proposed
limits. Even before CARB’s regulation
became effective, its survey data showed
that for 10 coating categories, 100
percent of the coatings were complying
with the proposed limits in 1997. For
the remaining categories, all but two
had complying market shares greater
than 20 percent in 1997. With CARB’s
regulation in place, we anticipate that
the number of coatings already meeting
the proposed limits has increased
significantly.
As discussed earlier, we do not think
that fillers and distributors will incur
additional costs from the proposed rule.
The filler would incur additional costs
only if the proposed rule would require
them to invest in new equipment and
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we do not anticipate that this will be the
case. The mix of propellants and
solvents used by the manufacturer is
expected to change, but the changes will
not be so significant that the fillers will
be unable to continue to use their
existing equipment. The only potential
costs to the distributor are the labeling
requirements and any costs associated
with not being able to sell noncompliant
coatings. However, the proposed rule
does not require the information to be
included on the paper label and most
manufacturers are meeting the labeling
requirements associated with CARB’s
regulation by using an ink stamp on the
bottom of the can. Therefore, the
labeling requirements are not expected
to have a cost impact on the distributor.
The proposed rule also allows
distributors to continue to sell products
that were manufactured before the
compliance date as long as necessary so
they will have no lost revenue from the
noncompliant coatings.
IV. Rationale
A. Applicability
CAA section 183(e)(1)(C) of the CAA
defines ‘‘regulated entities’’ as:
(i) Manufacturers, processors, wholesale
distributors, or importers of consumer or
commercial products for sale or distribution
in interstate commerce in the United States;
or
(ii) manufacturers, processors, wholesale
distributors, or importers that supply the
entities listed under clause(i) with such
products for sale or distribution in interstate
commerce in the United States.
The proposed ACRR will regulate
manufacturers, processors, wholesale
distributors, or importers of aerosol
coatings. This includes those regulated
entities that make aerosol coatings for
the DIY market and for the industrial
markets. Regulated entities include
processors commonly referred to as
‘‘fillers’’ that obtain the liquid and
propellant portions of the coating
separately and fill the aerosol can. In
addition, the rule will regulate
distributors of aerosol coatings if those
facilities have any responsibility for the
labeling of the coatings.
We are proposing an exemption from
the limits of the rule for those entities
that manufacture only a small amount of
aerosol coatings. We believe that this
exemption will serve to mitigate the
impacts of the rule upon small
manufacturers for whom compliance
with the rule could impose
disproportionately high costs through
reformulation of products produced
only in small volumes. Given this
objective, and in order to avoid
unnecessary excess VOC emissions that
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could be significant in the aggregate, we
are proposing that this exemption from
the limits would be available only for
those manufacturers that have annual
production of aerosol coatings products
with total VOC content not in excess of
7,500 kg of VOC in all aerosol coating
product categories. We emphasize that
this to be determined by total VOC
content by mass, in all product
categories manufactured by the entity.
We consider making this distinction
based upon total VOC mass, rather than
some reactivity-adjusted calculation,
necessary both to minimize the
analytical impacts upon the entity
seeking the exemption from the rule,
and to provide for more effective
implementation and enforcement of this
aspect of the rule.
A manufacturer that qualifies for the
exemption must notify EPA of this in
the initial notification report required in
proposed section 59.511. As a condition
for the exemption from the limits, the
proposed rule also requires the entity to
file an annual report with EPA
providing the information necessary to
evaluate and to establish that the
products manufactured by the entity are
properly exempt from the limits of rule.
This information is necessary to assure
that the entity is in compliance, even if
its products do not meet the limits of
the rule. EPA notes that an exemption
under EPA’s national rule for aerosol
coatings under section 183(e) does not
alter any requirements under any
applicable state or local regulations.
We specifically request comment on
whether there is a need for an
exemption of this type for very small
manufacturers. In addition, we request
comment on the features of the
exemption as we have proposed it.
Finally, in order to get better
information about the number of
manufactures that would potentially use
such an exemption, we specifically
request that interested commenters
indicate whether they would elect to
use the exemption from the limits.
The proposed rule requires all
regulated entities to comply by January
1, 2009. EPA believes that compliance
by this date is readily achievable by
most, if not all, regulated entities subject
to this rule. However, in the case of
regulated entities that have not
previously met the limits already
imposed by regulation in the State of
California, EPA believes that it may be
appropriate to provide an extension of
the compliance date on a case by case
basis. Therefore, the proposed rule
includes a provision that will allow
regulated entities that have not
previously manufactured, imported, or
distributed for sale or distribution in
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California any product in any category
listed in Table 1 of this subpart that
complies with applicable California
regulations for aerosol coatings to seek
an extension of the compliance date.
Such extensions will be granted at the
discretion of the Administrator. The
grant or denial of a compliance date
extension does not affect the right of the
regulated entity to seek a variance under
this rule.
B. Regulated Pollutant
Under CAA section 183(e), Congress
has directed EPA to issue regulations to
reduce VOC emissions from consumer
and commercial products. Traditionally,
we have regulated the mass of VOC
ingredients of the products to attain this
end. This regulation will regulate VOC,
but will take a different approach. With
this regulation, EPA is proposing a rule
intended to limit the amount of ozone
that is generated by the specific VOC
ingredients of the aerosol coating
products rather than limit the VOC mass
content of the product. This approach
will allow EPA to regulate different
species of VOC differently, depending
on their relative contribution to ozone
formation once emitted into the
atmosphere. We believe that this
approach will achieve reductions in the
overall amount of ozone formed by the
VOC emitted to the atmosphere from
these products, and provide
manufacturers with flexibility to
formulate products using VOC
ingredients. We believe that this
approach provides incentives to
manufacturers to use VOC ingredients
with less reactivity and therefore
contribute to less ozone formation.
Under 40 CFR 51.100(s), we have
previously excluded compounds from
the definition of VOC in recognition of
the fact that individual organic
compounds differ with respect to their
incremental contribution to ozone
formation. EPA’s approach to VOC
exemptions separates organic
compounds into reactive and negligibly
reactive compounds. The reactivity
based approach that EPA uses in the
proposed rule, however, recognizes that
all such compounds contribute to the
formation of ozone. The differences in
the amount of ozone that may be formed
from a particular VOC are reflected in
the reactivity factors assigned to each
VOC in Table 2 of the rule. Compounds
that EPA previously identified as
negligibly reactive have low reactivity
factors, while those that are more
reactive have higher reactivity factors.
The use of reactivity factors makes the
distinction between negligibly reactive
and reactive compounds unnecessary
for the proposed aerosol coatings rule.
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These previously exempted compounds
will continue to be excluded from the
Federal definition of VOC for other
purposes.
C. Regulatory Approach
Section 183(e) of the CAA directs EPA
to issue national regulations to achieve
VOC emission reductions from those
categories of consumer products that
EPA has identified on the list of product
categories. As an alternative, EPA is also
authorized to issue a CTG in lieu of
such a national regulation if the CTG
would be substantially as effective as
the rule in achieving the necessary VOC
emission reductions. We have
determined that a national rule is the
best approach for this category.
When developing a regulation under
CAA section 183(e), EPA has broad
discretion to develop the most effective
approach to achieve the intended VOC
emission reductions from a category of
consumer products. Specifically, CAA
section 183(e)(4) states:
(4) Systems of regulation.—The regulations
under this subsection may include any
system or systems of regulation as the
Administrator may deem appropriate,
including requirements for registration and
labeling, self-monitoring and reporting,
prohibitions, limitations, or economic
incentives (including marketable permits and
auctions of emissions rights) concerning the
manufacture, processing, distribution, use,
consumption, or disposal of the product.
This proposed regulation includes a
combination of reactivity limits,
labeling requirements, recordkeeping
requirements, and reporting
requirements. We have concluded that
the only technologically and
economically feasible option for
reducing the VOC emissions from
aerosol coatings and the ozone that is
formed as a result of these emissions is
to set VOC content limits that will result
in reformulation. This conclusion is
based on the fact that once a
manufacturer uses a VOC as an
ingredient in an aerosol coating, it will
ultimately be emitted to the atmosphere
(i.e., when the product is used). For
stationary industrial sources of VOC
emissions, EPA has evaluated add-on
control devices as a potential option for
reducing emissions. Installing such
devices to reduce the emissions from an
aerosol coating can is neither
technologically nor economically
feasible. Although EPA could
theoretically achieve VOC emission
reductions through requirements
imposed on product users, CAA section
183(e) only allows the regulation of
users through the mechanism of a CTG.
EPA has determined that a CTG is not
the appropriate mechanism for aerosol
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coatings because of the nature of the
product category and its users. In
developing this regulation, we have,
therefore, focused on reformulation
options for reducing the amount of
ozone formed from VOC emissions from
aerosol coating products.
Most EPA and State coating standards
include limits in terms of weight of VOC
per weight (or volume) of product.
However, for reasons discussed below
in D.1, we are proposing to regulate this
product category based upon the
relative reactivity of the VOC
ingredients. In addition to these coating
limits, the standard includes other
regulatory requirements necessary to
facilitate effective implementation and
enforcement of the coating limits.
D. VOC Regulatory Limits
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1. Evolution of Reactivity-Based
Requirements
CAA section 183(e) requires EPA to
regulate VOC emissions from consumer
products for the purpose of reducing
ozone. Although EPA has traditionally
focused on reducing VOC ingredients by
mass in developing regulations under
CAA section 183(e), EPA believes that is
has authority under that section to
devise alternative approaches to reduce
VOC emissions from consumer products
where appropriate. The statute directs
EPA to evaluate what would constitute
‘‘best available controls’’ (BAC) for a
product category, and we believe that
provision authorizes EPA to consider
different approaches for different
products.
In determining what would be BAC
for aerosol coatings, we are proposing a
new approach to achieve the goal of the
CAA 183(e) program: A reduction in the
formation of ozone. As discussed in
section I.C. of this preamble, we believe
that the scientific understanding of VOC
reactivity has progressed sufficiently to
support a reactivity-based regulation for
the purposes of this product category.
As discussed previously, EPA has
concluded that the only reasonable
approach for limiting ozone formation
from aerosol coatings is to impose limits
that encourage reformulation to reduce
ozone formation. A brief overview of the
various types of rulemakings available
to use, and the selection of
reformulation levels is presented below.
The labeling and other requirements are
addressed in future sections.
i. Traditional VOC Mass-Based Limits.
In previous national rules developed
under section 183(e), EPA has
established limits on the VOC content of
coatings by mass. For the consumer
products rule and the automotive
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refinishing rule, these limits were based
on the weight percent of VOC in the
coating. For the architectural and
industrial maintenance (AIM) coatings
rule, the limits were based on the
weight of VOC per volume of coating.
To meet traditional VOC content limits,
coating manufacturers have several
options. For example, increasing the
solids content of the coating will result
in a lower VOC content per unit of
volume or weight. Replacing some of
the organic solvent in a coating with
water can also decrease the VOC content
of the coating. Over the years, EPA has
also determined that some compounds
are negligibly reactive compared to
other VOC; that is, they produce less
ozone or produce ozone less quickly
than other VOC. We have exempted
these compounds from the generally
applicable regulatory definition of VOC.
To achieve compliance with other CAA
section 183(e) regulations,
manufacturers can use these exempt
compounds in place of other VOCs and
thereby reduce the VOC content of their
coatings for regulatory purposes.
The approach a manufacturer chooses
to use to reduce the VOC content of its
coatings varies depending upon many
factors including the intended use of the
product, the cost of the reformulated
product, the performance of the
reformulated product, and other
environmental impacts of the
reformulated product. For each coating
in the aerosol coating category, the
approach for reducing the VOC content
may be different because each category,
and even each product within the
category, has different performance
requirements.
Even though reducing the VOC
content of aerosol coatings could have a
significant impact on the ozone
resulting from emissions of VOC from
aerosol coatings, this approach does
have limitations. With an aerosol
coating, manufacturers are more limited
on how high the solids content of the
coating compared to coatings applied
using spray techniques or brushing. In
addition, as the solids content increases,
manufacturers are often forced to use
more of VOC such as toluene and xylene
that are more effective solvents but are
also more reactive and hazardous air
pollutants. Increasing water content in
aerosol coatings can be a problem
because water-based coatings take
longer to dry, which is a particular
concern in humid environments. A
coating that takes longer to dry may
impact production at an industrial
facility where many specialty aerosol
coatings are used. Replacing some VOC
ingredients with others that are exempt
from the regulatory definition of VOC
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can also have some negative
implications. For example, acetone is
extremely volatile and may dry too fast
for some applications. We are also
concerned about the environmental
impacts of increasing the use of such
solvents as methylene chloride, which
although exempt from the definition of
VOC is listed as a hazardous air
pollutant.
Although potential limitations exist
for establishing limits on the VOC
content of aerosol coatings, we believe
that it is a technologically feasible
alternative for reducing the formation of
ozone from the use of aerosol coatings.
It is an approach we have used in many
regulatory programs, including 183(e).
Our evaluation of BAC options for
aerosol coatings includes two options
for limiting the VOC content of coatings.
ii. Reactivity-Based Limits.
EPA recognizes that individual VOC
can react differently in the atmosphere
and can vary in the amount of ozone
generated. Organic compounds can
produce varying amounts of ozone
because they react at different rates and
via different reaction mechanisms. One
concern expressed by industry is that if
the VOC content limits are too low
manufacturers may be forced to use
more reactive solvents to achieve
comparable product performance. For
example, as discussed earlier,
manufacturers may have to increase the
usage of toluene and xylene in order to
reformulate to a higher solids coating.
Both toluene and xylene are very
reactive compounds and have the
potential to form significantly larger
quantities of ozone than many other
solvents. If manufacturers use VOC with
higher reactivities, it is possible that
decreasing the VOC content of the
coating potentially increases the actual
ozone formation.
This situation of a decrease in VOC
emissions by mass but a potential
increase in ozone formation has already
been seen to occur in California. For
example, Table 11–2 of California’s
2005 Architectural Coatings Survey,
(draft report), indicates that between
2001 and 2005, the sales volume for flat
coatings increased by 7 percent (to 37.3
million gallons) while the total mass of
VOC for this category for the same
period decreased by 11 percent.
However, even though the total
emissions of VOC by mass decreased,
the total ozone formed as a result of
those VOC is estimated to have
increased 5.4 percent (1.88 tpd) during
the same period. This potential increase
in ozone formation, notwithstanding
decreased VOC emissions by mass, is a
result of manufacturers using smaller
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amounts total VOC, but an increased
amount of more reactive VOC in order
to meet tighter VOC limits (See
California’s 2001 Architectural Coatings
Survey Final Reactivity Analysis—Table
2–6 (March 2005) and 2005
Architectural Coatings Survey DRAFT
Reactivity Analysis—Table 2–2 (January
2007)). [For a complete copy of this
report, please see
https://www.arb.ca.gov/coatings/arch/
survey/2005/
Draft_2005_Survey_Rpt.pdf. https://
www.arb.ca.gov/coatings/arch/
reactivity/Draft_Reactivity_Rpt.pdf.
https://www.arb.ca.gov/coatings/arch/
reactivity/
final_reactivity_analysis_rpt.pdf.
EPA believes that the use of relative
reactivity is appropriate for aerosol
coatings in particular, because there is
a limit to the extent that solids contents
can be increased and still have a coating
that can be dispensed through an
aerosol canister. This limitation
precludes the range of reformulation
with higher solids content that can be
achieved for other types of coatings.
In the past, EPA has expressed
reservations about using the concept of
VOC relative reactivity in regulations for
consumer products due to limitations in
scientific studies and practical concerns
about developing an effective regulation
based on this concept. More recently,
the California Air Resources Board
(CARB) has worked to develop an
effective way to regulate based upon
this concept. In developing its own
standards for aerosol coatings, CARB
established limits are intended to limit
the amount of ozone that is formed by
a particular coating, rather than limit
the VOC content of the coatings by
mass. To develop a reactivity-based
rule, CARB first identified the relative
reactivity of each VOC ingredient used
in aerosol coatings. CARB evaluated this
using the Maximum Incremental
Reactivity scale developed by Dr.
William Carter.27 In developing this
scale, Dr. Carter identified and
quantified each mechanism for ozone
production that would exist for specific
VOC, including those used in aerosol
coatings. The final MIR value for each
VOC is expressed in units of weight of
ozone production per weight of VOC.28
CARB used MIR values and the
uncertainty values assigned particular
bins of chemicals with product
formulation data to derive, through an
iterative process, a limit for the overall
27 Carter, W. P. L. (1994) ‘‘Development of ozone
reactivity scales for organic gases,’’ J. Air Waste
Manage. Assoc., 44: 881–899.
28 ‘‘Initial Statement of Reasons for the California
Aerosol Coatings Regulation, California Air
Resources Board,’’ May 5, 2005.
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mass of ozone production allowed per
mass of product. Because all organic
compounds can contribute to the
formation of ozone, CARB’s reactivity
limits include ozone formed by all VOC
ingredients included in the coating,
including compounds that EPA had
previously exempted from the
regulatory definition of VOC.
After review of Dr. Carter’s work, the
CARB rule, and recent studies organized
under the RRWG (described earlier in
the background section), we believe that
the reactivity approach is a viable
option for reducing the ozone that
results from VOC emissions from the
aerosol coatings category. These
previous studies have indicated that the
use of VOC reactivity can be effective
for controlling ozone in episodes where
NOX is at its highest levels, such as in
urban areas. For these types of VOClimited conditions, ozone formation is
more sensitive to VOC emissions. In
such situations, limiting the reactivity of
the VOC emissions can be more
effective than merely limiting the
overall mass of the VOC emissions.
EPA notes that metrics other than the
MIR scale for characterizing reactivity
have been studied, for example, the
Maximum Ozone Incremental Reactivity
(MOIR) or the Regional Average Ozone
metric, but the box model MIR is the
scale that has been most widely used
and analyzed. Recent studies of 9
different ways of defining VOC
reactivity have shown that all major
methods are directionally consistent
and highly correlated.29 Derwent (2004)
further concluded that ‘‘the most
promising reactivity metrics are EKMAMIR and Regional MIR or MIR–3D.’’
Because the only metrics with detailed
values available for all chemical species
of interest are the box model (EKMA)
metrics, and the box model MIR has
been used extensively in formulations
under the California rule, we believe
that the box model MIR is the most
feasible metric for VOC relative
reactivity to use at the current time. One
important characteristic of the box
model MIR is that it has the widest
range of all metrics, which provides the
best incentive for the substitution of
higher reactive VOC with lower-reactive
VOC. While this might allow a larger
mass of VOC to be emitted than other
metrics, tight limits will ensure that the
increased mass will be restricted to the
least reactive VOC.
Previous studies of large-scale, equalozone substitutions of VOC species have
29 Carter, et al., 2003, Derwent, R.G. (2004)
‘‘Evaluation and Characterization of Reactivity
Metrics,’’ Final Draft, Report to the U.S. EPA, Order
No. 4D–5844–NATX, November 2004.
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shown that downwind ozone could
increase due to upwind substitutions of
larger amounts of lesser reactive VOCs,
but any increases tended to be much
smaller than the magnitude of
concurrent ozone decreases. The
substitutions had a larger effect on
reducing the higher ozone
concentrations in the area upwind than
they did on increasing downwind
concentrations. Even in the extreme
substitution scenarios that have been
studied, the benefits for ozone
(reduction in ozone peak) were
significant. We believe that realistic
changes in formulation using the MIR,
especially if limited to aerosol coatings,
are unlikely to result in a noticeable
increase in ozone downwind. First,
downwind areas are usually NOXlimited, so small amounts of additional
VOC will not influence ozone formation
significantly. Furthermore, in cases
where downwind areas are VOClimited, potential downwind ozone
increases will be counteracted to some
extent by ozone decreases resulting from
VOC substitution occurring
simultaneously in the downwind area.
Thus, we expect VOC reformulations
based on the MIR scale to lead to an
overall net decrease in ozone formation
and exposure.
In the past, there has been some
concern over the applicability of MIR
values across the entire country,
however studies 30 now demonstrate
that the calculated MIR scales do not
have significant geographical or
temporal variation. Based on this
information, we believe that using the
MIR values to establish the relative
reactivity of VOC ingredients in a
reactivity-based approach is a viable
option for consideration in a national
rule.
While the chemical mechanisms for
ozone production for many individual
chemicals are somewhat to highly
uncertain, this uncertainty is smaller for
the majority of the organic compounds
used as ingredients in aerosol coatings.
Most of the VOC used in the products
covered by this rule have been
characterized as category 1 or 2
uncertainty, which Carter classifies as
relatively certain (category 1) or
uncertainty less than a factor of 2
(category 2).31
30 Hakami, A., M.S. Bergin, and A.G. Russell
(2004a) ‘‘Ozone Formation Potential of Organic
Compounds in the Eastern United States: A
Comparison of Episodes, Inventories, and
Domains,’’ Environ. Sci. Technol. 2004, 38, 6748–
6759.
31 Carter, W.P.L. (2003) ‘‘The SAPRC–99
Chemical Mechanism and Updated VOC Reactivity
Scales,’’ Report to the California Air Resources
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Furthermore, uncertainty in the
reactivity scales can be taken into
account in the selection of reactivity
limits as CARB did in defining the
limits in its aerosol coatings regulation.
CARB assigned each compound in its
table of MIR values to one of six bins
based on expert judgment about the
level of uncertainty in the chemical
mechanisms used to calculate the MIR
value. CARB assigned an uncertainty
factor to each of the six bins. CARB then
adjusted the MIR values used in the
calculation of the reactivity limits by
multiplying each MIR by its assigned
uncertainty factor. By applying this
uncertainty factor, the resulting
reactivity limits are more stringent than
they would be calculated based on the
MIR values alone, and provide some
protection against setting values too low
based on incomplete understanding of
the chemistry of specific compounds.
For some compounds used in aerosol
coatings for which no MIR value has
been calculated, CARB assigned an
upper limit MIR value based on
theoretical limits of the ozone that could
be formed by the compound. This
approach is also conservative, providing
some protection against setting
reactivity limits too low or allowing
reformulations that would increase
ozone formation. We have set the
reactivity factors in the proposed rule
equal to the MIR or upper limit MIR
used by CARB. This ensures that the
limits in our proposed rule are
equivalent to CARB’s current rule, but
allows EPA flexibility in the future to
change this approach, if warranted.
All of the VOC that we have identified
as common VOC components of aerosol
coatings have been assigned reactivity
factors. However, it is possible that a
novel compound could be used in a
product affected by this rule. In CARB’s
rule, if a VOC has not been assigned a
MIR or upper limit MIR value, it cannot
be used in a product to comply with
that rule. In EPA’s proposed rule, if a
VOC is not assigned a reactivity factor,
then the compound is assigned the
maximum reactivity factor for any
compound listed in the rule.
Manufacturers and other interested
parties can petition the Administrator to
add a reactivity factor to the table in the
rule for such a compound and are
encouraged to provide sufficient
evidence to allow the Administrator to
assign a reactivity factor that is
consistent with values assigned to the
other listed compounds. This approach
ensures that the reformulations allowed
Board, Contracts No. 92–329 and 95–308. https://
pah.cert.ucr.edu/~carter/reactdat.htm.
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by the rule will not increase ozone
formation.
Based on the information that we
have about VOC used in aerosol
coatings, we believe that the relative
reactivity approach for this particular
consumer product category is
appropriate. However, there may be
other source categories EPA considers
for regulation where the organic
compounds and their relative reactivity
have not been as well-characterized.
EPA has determined that it is
appropriate to use the MIR values as the
reactivity factors for this particular
regulation. If a more suitable reactivity
scale is developed in the future, EPA
will evaluate that scale for possible
regulatory use.
Therefore, our determination that the
reactivity approach using the MIR
values as the reactivity factors is
currently only applicable to the aerosol
coatings category. EPA has not
concluded that it is appropriate to use
the MIR scale for all applications. In
developing future regulations, EPA may
determine that a reactivity approach is
not appropriate for a particular context
or that a reactivity approach should be
based upon reactivity factors other than
the MIR values. EPA will make such
future determinations on a case-by-case
basis.
Based on EPA’s determination that
the reactivity approach can be effective
in reducing the amount of ozone formed
from the use of aerosol coatings, EPA
has included the evaluation of limits
based on reactivity in selecting BAC for
the aerosol coatings category. The
options EPA considered in developing
BAC are presented in the following
section.
2. Assessment of Best Available
Controls.
CAA section 183(e) directs EPA to
regulate Consumer and Commercial
Products using ‘‘best available
controls.’’ The term ‘‘best available
controls’’ is defined in CAA section
183(e)(1)(A) as:
The degree of emissions reduction that the
Administrator determines, on the basis of
technological and economic feasibility,
health, environmental, and energy impacts, is
achievable through the application of the
most effective equipment, measures,
processes, methods, systems or techniques,
including chemical reformulation, product or
feedstock substitution, repackaging, and
directions for use, consumption, storage, or
disposal.
EPA believes that CAA section 183(e)
thus authorizes EPA to evaluate what
approach would be ‘‘best’’ for this
product category in light of various
relevant factors.
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In order to evaluate what would
constitute BAC for this source category,
EPA examined the approaches already
attempted in other regulations by States.
As discussed above, the California Air
Resources Board (CARB) has a history of
regulating VOC emissions from the
aerosol coatings category. While several
other States have regulations under
consideration, only Oregon and
Washington have existing standards and
both of those States’ regulations are
based on CARB’s 1996 Tier 1 VOC massbased limits. Based on the experiences
of CARB, EPA has considered both
mass-based and reactivity-based limits
for this product category. We considered
three possible options for BAC for this
category based upon past CARB
regulations:
i. CARB 1996 VOC mass-based limits
(Tier 1);
ii. CARB 2002 VOC mass-based limits
(Tier 2); and,
iii. CARB 2002 reactivity-based limits.
In 1996, CARB implemented its first
aerosol coatings regulation. The 1996
regulation contained two tiers of massbased VOC limits. The first tier took
effect in 1996 and the second tier,
which contained more stringent massbased VOC limits, was scheduled to take
effect in 1999. CARB was required to
conduct a public hearing on or before
December 31, 1998, on the technological
and commercial feasibility of achieving
the 1999 limits and could grant an
extension of time not to exceed 5 years
if their Board determined that the
second tier of limits was not
technologically or commercially feasible
by December 31, 1999.
On November 19, 1998, CARB
adopted amendments to its aerosol
coatings regulation by modifying the
December 31, 1999, mass-based VOC
limits and extended the effective date
for those limits to 2002. However,
CARB’s Board recognized that some of
the second tier limits would still be
technologically challenging and
directed CARB staff to develop a
compliance option based on VOC
reactivity. On June 22, 2000, CARB
amended its regulation to replace the
2002 mass-based VOC limits with
reactivity-based VOC limits intended to
achieve the same degree of ozone
reduction.
EPA did not consider the 1999 massbased limits in our BAC analysis
because CARB determined that those
limits were not technologically feasible
and never implemented the limits.
CARB replaced the 1999 mass-based
limits with more stringent limits in
some categories and less stringent limits
in other categories. We did include
these 2002 VOC mass-based limits that
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replaced the 1999 VOC mass-based
limits in our BAC analysis.
Each of the three options EPA
considered is discussed below. See the
docket to this rulemaking for the tables
of limits for each option.
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i. CARB 1996 VOC Limits.
In 1995, CARB proposed limits on the
VOC content of aerosol coatings. These
limits were based on limits established
by the Bay Area Air Quality
Management District (BAAQMD) in
Rule 8–49 in 1990. CARB’s regulation
included limits on six general categories
of aerosol coating products and 29
specialty coating categories. The
regulation established limits on the
maximum VOC content, based on
percent by weight, for each coating
category. The standards were effective
January 8, 1996; therefore they are
referred to throughout this preamble as
‘‘CARB 1996 VOC limits.’’
According to CARB’s Initial Statement
of Reasons, the support document
prepared by CARB for the new
regulation, the 1996 limits were
expected to reduce VOC emissions from
the use of aerosol coatings in California
by 12 percent. CARB determined that
for most of the aerosol coating product
categories covered by the rule, there
were already products in the
marketplace that met the 1996 limits.
Comments made by industry members
on the regulation indicated that industry
believed the limits were feasible.
We believe that the 1996 VOC massbased limits established by CARB for
aerosol coatings are both technologically
and economically feasible. Industry has
complied with the 1996 limits in
California for many years. CARB
estimated that the 1996 limits would
achieve a reduction of approximately 12
percent in VOC emissions and we
believe that implementing these limits
nationwide would result in a similar
reduction. In 1997, CARB conducted a
survey of aerosol coating manufacturers.
For each of the major categories of
aerosol coatings, the sales-weighted
average VOC content for the category
met or was lower than the 1996 limit.
We know of no reason why these limits
could not be established on a
nationwide basis for the aerosol coatings
category, providing a similar level of
emission reduction.
ii. CARB 2002 VOC Mass-Based Limits.
As discussed earlier, CARB’s 1995
regulation established two tiers of massbased limits that took effect in 1996 and
1999. In 1997, CARB conducted a
survey of manufacturers supplying
aerosol coatings in California. The
survey requested formulation and cost
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data for existing products in each
category and information on the
manufacturer’s research and
development efforts to reduce the VOC
content of coatings.
Using the results from the 1997
survey and input from manufacturers,
CARB revised the second tier aerosol
coatings limits and extended the
compliance date from 1999 to January 1,
2002. These limits are referred to as
‘‘CARB 2002 VOC Limits’’ in this
preamble. The new limits were more
stringent than the 1996 limits for all of
the coating categories. CARB estimated
that the 2002 limits would result in a
VOC reduction of 3.1 tons VOC/day (or
8.4 percent) from the 1997 emission
levels.
Based on CARB’s 1997 survey data
and CARB’s later conclusion that the
second tier mass-based VOC limits may
not be feasible, EPA is concerned about
the technological feasibility and
availability of coatings to meet the 2002
VOC limits. Although the limits appear
to be both feasible and available for
some categories of aerosol coatings, the
survey data indicate that this may not be
true for all of the categories. For
example, for the category of flat coating
products, the survey showed that out of
a total of 129 products, none met the
2002 VOC limits. For primers, only 5 of
162 products, less than 1 percent of the
market, met the 2002 VOC limits. The
market share for non-flat coatings
meeting the limit was only 5 percent.
These three categories, flat coatings,
non-flat coatings, and primers, represent
three of the four largest categories of
aerosol coatings. While not dispositive,
we think the absence of products
meeting the limits is indicative of
technological and feasibility constraints
that would make the limits difficult to
achieve.
Although the CARB survey was
conducted in 1997 and it is possible that
the technology has advanced since that
time in order to meet such stringent
mass based limits, we are concerned
that this may not have happened.
Although CARB adopted the 2002 VOC
limits, these mass-based limits never
took effect because CARB replaced the
2002 VOC limits when CARB adopted
new reactivity-based limits for aerosol
coatings in June 2000. It is likely that
coating manufacturers have adjusted
their research and development efforts
towards reducing the reactivity of the
VOC content of their coatings rather
than the VOC mass content of their
coatings. In some cases, a reduction in
the reactivity may coincide with a
reduction in VOC content but as
discussed earlier, this is not necessarily
the case. In fact, it may be possible to
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increase the VOC content of a coating
while reducing the overall reactivity of
the VOC ingredients. Because of this, we
presume that industry may be no closer
to meeting the 2002 VOC mass limits
than they were in 1997.
In the March 2000 edition of the
‘‘Issue Backgrounder,’’ NPCA’s quarterly
newsletter, NPCA states that the 2002
limits ‘‘would be technologically
impossible for water-based coatings.’’
CARB has also indicated that some of
the limits may be difficult to meet with
water-based technology. As water-based
coatings are among the most
environmentally friendly coatings, we
are reluctant to base a rule on limits that
could preclude the use of this
technology.
Although we believe the 2002 VOC
limits would have a significant
environmental benefit, we have
concerns about the technological
feasibility and availability of coatings
that meet these limits and therefore
whether these limits represent BAC for
the aerosol coatings industry.
iii. CARB 2002 Reactivity Limits.
As directed by its Board in 1998,
CARB worked with industry to evaluate
a VOC reactivity-based approach for the
aerosol coatings category that would
achieve a reduction in the formation of
ozone equivalent to the 2002 massbased VOC limits. Although CARB
initially planned the reactivity-based
approach as an alternative compliance
method to the 2002 VOC mass-based
limits, it ultimately concluded that
having simultaneous mass-based and
reactivity-based limits would cause
confusion and decided to have only
reactivity-based limits. To ensure the
reactivity-based limits would achieve, at
a minimum, an equivalent reduction in
the formation of ozone to the 2002 VOC
mass-based limits, CARB based its 2002
reactivity limits on the 2002 VOC limits.
CARB first determined the amount of
ozone reduction that it anticipated
would be achieved from the
implementation of the 2002 mass-based
VOC limits. CARB then calculated,
through an iterative process, an
equivalent reactivity-based limit, so that
the reactivity-based limit would result
in the same ozone reduction as the
mass-based limit. As described earlier,
the required amount of ozone reduction
was adjusted upwards to account for the
possible uncertainty in reactivity
values.32
32 ‘‘Initial Statement of Reasons for the Proposed
Amendments to the Regulation for Reducing
Volatile Organic Compound Emissions from
Aerosol Coating Products—California Air Resources
Board,’’ Chapter IV, May 5, 2000.
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The data from the 1997 survey
demonstrated that complying products
for the aerosol coatings reactivity limits
were available in all but two specialty
categories even in 1997. CARB has only
received one variance request for the
reactivity-based aerosol coating limits
(https://www.arb.ca.gov/consprod/
variance/variance.htm). NPCA has
supported both the reactivity approach
and the established limits. Based on a
review of the limits and the supporting
data, we believe that the reactivity
limits established by CARB for the
aerosol coatings category are
technologically feasible and available as
contemplated in section 183(e).
3. Determination of Best Available
Controls (BAC)
We believe that the 1996 VOC limits
developed by CARB are technologically
feasible and, based on CARB’s cost
analysis, are also economically feasible.
Therefore, they are certainly
‘‘available.’’ However, these limits were
based on technology that was available
in 1995, when CARB first proposed the
limits. During the last 10 years,
manufacturers of all types of paints and
coatings have made significant
technological advances in coating
technology in response to the
development of various state and
national rules limiting both the VOC
and HAP content of coatings. The 12
percent reduction in VOC emissions
that could be achieved through the
implementation of the 1996 limits is
significantly less than the estimated 20
percent reduction in VOC emissions
achieved by the implementation of the
other national rules established under
CAA section 183(e). We believe that the
CARB 1996 VOC limits do not represent
BAC for the aerosol coatings category if
more stringent levels are available.
Although we believe the industry is
capable of meeting limits more stringent
than the 1996 VOC limits, we are
concerned about the technological
feasibility of the 2002 VOC mass-based
limits. The 2002 VOC limits are more
stringent than the 1996 limits. CARB’s
survey data indicated that many
manufacturers would have a difficult
time achieving the VOC content limits
proposed for several of the major
categories of aerosol coatings (See
https://www.arb.ca.gov/regact/conspro/
aerosol/isor.pdf). In addition, NPCA’s
concern that the limits may not be
achievable through the use of waterbased technology is of particular
concern to us. Water-based coatings are
an environmentally friendly technology
that we do not want to be lost as an
option to manufacturers. So long as
VOC emission reductions contemplated
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by CAA section 183(e) are achieved, we
believe that it is important that
manufacturers retain as much flexibility
as possible in selecting a reformulation
technology to ensure they can
manufacture coatings that meet the
performance specifications required. In
addition, we remain concerned that if
water-based coatings are not an option
to meet the limits, higher-solids coatings
will be the primary alternative.
Although we support the use of highersolids coatings as an alternative to high
VOC content coatings, we are concerned
that if the limits are too stringent
industry will be driven to increase its
use of toluene, xylene, and other
aromatic compounds. These aromatic
compounds are all extremely effective
solvents for use in higher-solids
coatings, but they are also highly
reactive compounds that generate more
ozone than other solvents commonly
used by the aerosols coating category.
As discussed earlier, we believe the
reactivity approach is appropriate for
the aerosol coatings category because
the organic compounds used by the
industry are well-characterized. Because
the 2002 reactivity limits developed by
CARB are based on the VOC reduction
associated with the 2002 VOC limits,
they ensure that the reactivity limits
will achieve an equivalent
environmental benefit to the 2002 VOC
limits. The reactivity limits also offer
industry significantly more flexibility in
achieving that environmental benefit.
Industry can substitute to lower
reactivity solvents, use water-based
technology, use higher-solids
technology (without the potential
drawbacks associated with the use of
this technology in a mass-based VOC
standard), or any combination of these
approaches to meet the limits.
We have concluded that the reactivity
limits established by CARB are based on
sound scientific principles and
represent an equivalent environmental
benefit to even the most stringent 2002
VOC limits. It is likely that if EPA were
to use a mass-based VOC approach for
the aerosol coatings category, we would
be required to set less stringent limits,
perhaps based on the 1996 limits. Such
an approach would achieve less
environmental benefit.
EPA then evaluated the cost and
economic impacts of the reactivitybased limits. The economic impact
assessment focuses on changes in
market prices and output levels. A more
detailed discussion of the economic
impacts is presented in the economic
impact analysis memorandum that is
included in the docket.
Both the magnitude of control costs
needed to comply with the proposed
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rule and the distribution of these costs
among affected facilities can have a role
in determining how the market prices
and quantities will change in response
to the proposed rule when finalized. In
this case, at the facility level, we have
some uncertainty concerning both the
amount of individual products being
produced and whether the products
currently comply with the proposed
rule, or whether additional costs
associated with reformulating the
products will be required. Because
California has a similar rule and
products sold in California have already
complied with the California rule, the
costs imposed by the proposed EPA rule
would entail only minor additional
recordkeeping and recording costs. We
also know that facilities are involved in
production of other products not
covered by this rule. We have no
quantitative information on the relative
contribution to revenue of products not
covered by the rule in comparison to
products covered by the rule.
Provided with the cost analysis is a
cost per can estimate of going from a
non-complying formulation to a
complying formulation, and a sales
price per can for each of the six general
coating categories and the thirty
specialty coating categories. Also
provided is an estimate of the fraction
of each coating category that complied
before the imposition of the CARB rule.
Finally, with the cost analysis is a list
of facilities producing products covered
by the CARB rule from a 1997 CARB
survey and which categories are
produced at each facility.
The cost per can, as a percentage of
prices per can for going from noncomplying to complying on a category
basis, ranges from a cost savings to cost
of 2.71 percent for the exact match
finish industrial category. In order to
provide a very rough measure of the
impact on a per facility basis, the cost
per price measure for each category
produced by a particular facility was
multiplied by the pre-CARB rule noncomplying percentage and averaged
across categories using a weighting of
industry-wide market share from the
pre-CARB rule survey.
The highest cost-to-sales ratio is 1.42
percent. Since this does not include
revenues from other products, or the
reduction in cost due to the CARB rule,
it is very unlikely that the cost-to-sales
ratio for any facility would exceed 1
percent. Thus a significant impact is not
expected for a substantial number of
small entities.
No significant market impact is
expected because of the small cost
increase compared to the price. Neither
full cost absorption nor full cost pass-
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In evaluating options for BAC, EPA
must evaluate not only the positive
environmental benefits of BAC but any
potential negative environmental or
health benefit. While reducing the
population’s exposure to ground-level
ozone is important, exposing the
population to increased levels of
potentially toxic VOC is also a concern.
This could occur since the use of
relative reactivity encourages the use of
specific (i.e., low reactivity) compounds
to reduce ozone, despite other potential
environmental and public health
concerns. One compound that we are
concerned about is methylene chloride,
which has an extremely low MIR value
and has also been listed as a HAP under
section 112 of the Clean Air Act because
of its potential toxic effects on human
health and the environment. We remain
concerned about the potential impact of
an increase in the use of this compound.
There are some HAP that would be
reduced as a result of a regulation with
a reactivity-based approach. For
example, HAP such as toluene are
highly reactive and accordingly have
high MIR values. Therefore, they are
unlikely to be used in large quantities in
any aerosol coatings subject to a relative
reactivity based regulation. In fact, we
expect their use to be reduced. Thus,
although CAA section 183(e) directs
EPA to control VOC emissions from
consumer products only for purposes of
achieving the ozone NAAQS, we
anticipate that choices made to regulate
VOC can have collateral benefits or
disbenefits in ways not related to the
ozone NAAQS.
We are seeking comment on possible
approaches to address the HAP
emissions from aerosol coatings,
including the use of a voluntary
program. A voluntary program would
seek to provide incentives to industry
that voluntarily reduce the use of HAP
in their product formulations. We
request comment and suggestions on
how this program could be identified,
E. Compliance Demonstration
Requirements
EPA is proposing compliance
demonstration requirements necessary
to ensure compliance with the rule.
Initial compliance demonstration with
this rule requires the regulated entity to
complete initial compliance
calculations for all coatings and develop
and submit the initial notification.
Ongoing compliance demonstration and
reporting is only required when a
regulated entity becomes responsible for
a coating category that was not included
in the original notification.
1. Determination of Coating Content
The ACRR allows a facility to
determine compliance using either VOC
formulation data or through the use of
California’s Test Method 310 or EPA’s
Test Method 311 (see Selection of Test
Method). If formulation data are used,
the regulated entity would need to
identify and maintain records of all
VOC present in the coating and
propellant portions of the final aerosol
product at a level equal to or greater
than 0.1 percent. The same levels of
recordkeeping would be required if
CARB Method 310 or EPA Method 311
were used. In the event of an
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PWR p = WRF1 + WRF2 + ... + WRFn
Where:
PWRp = Product weighted reactivity for
product P, g O3/g product
WRF1 = Weighted reactivity factor for
component 1, g O3/g component
WRF2 = Weighted reactivity factor for
component 2, g O3/g component
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Both of these steps are incorporated
into a single equation:
Frm 00017
Fmt 4701
Sfmt 4702
2. Calculation of Reactivity of Coating
Once the coating (including coating
liquid and propellant) formulation data
are known (i.e., either through
formulation calculations or use of an
approved test method), the calculation
of the reactivity value for the product is
relatively simple. Tables 2A, 2B, and 2C
of the regulation contain reactivity
factors that are currently based on the
MIR values, and in some cases the
upper limit MIR values, used by CARB
in its regulation. These reactivity factors
are used in conjunction with the
formulation data to demonstrate
compliance with the reactivity limits.
First the compound Weighted Reactivity
Factor (WRF) is calculated by
multiplying the weight fraction of the
individual ingredient (obtained from the
formulation data) by the reactivity factor
(RF) for that ingredient obtained from
Table 2 of the regulation.
WRFi = ( WFi ) ∗ ( RFi )
Equation 1
Where:
WRFi = Weighted reactivity factor for
component i, g O3/g product
WFi = Weight fraction of component i
RFi = reactivity factor for component i, g
O3/compound i
The WRFs for each component in the
total coating are then summed to obtain
the Product Weighted Reactivity (PWR).
Equation 2
WRFn = Weighted reactivity factor for
component n, g O3/g component
PO 00000
inconsistency between the results of
Method 310 or 311 test data and a
calculation based upon formulation
data, the Method 310/311 data will
govern the compliance calculation.
These formulation data will then be
used to calculate the reactivity value for
the coatings, which would be compared
to the limits presented in Table 1 of the
rule.
We are aware that a single regulated
entity may have tens, or even hundreds,
of different product formulations,
especially if different colors of the same
basic product have slightly different
formulations. It is not our intent to
create unnecessary burden and we seek
comment on how to limit this burden
and still ensure compliance.
EP16JY07.006
4. Consideration of Other Factors
tracked, and recognized, including
suggestions on the following:
• Whether the program would
recognize only those formulations that
reduced HAP content from a baseline
before this rule was promulgated or if it
should recognize all ‘‘low HAP’’
coatings.
• What should constitute ‘‘low HAP.’’
This could potentially be a set amount
(percent or absolute) reduction or a
maximum overall HAP content.
• What type of documentation should
be required to document that the
voluntary reduction has occurred. We
are concerned that the documentation
not be so burdensome as to be
prohibitive; however, we want to ensure
that facilities claiming ‘‘low HAP’’
coatings are meeting these requirements.
• What type of acknowledgement can
be provided. We believe that some type
of labeling of the product would be an
option, but welcome other suggestions.
n
PWR p = ∑ ( WFi ) ∗ ( RFi )
i =1
Equation 3
Where:
PWRp = Product weighted reactivity for
product P, g O3/g product
WFi = Weight fraction of component i
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RFi = Reactivity factor for component i, g
O3/compound i
n = Number of components in product P
The reactivity factor equals zero for
non-solid components without carbon.
Solid components, including but not
limited to resins, pigments, fillers,
plasticizers and extenders do not need
to be included in this equation since the
reactivity factor for all solids is zero. If
a VOC component is not listed in Table
2, it is assigned a RF equal to the
maximum value listed in the table.
The PWR for each product must then
be compared to the limit for the specific
coating category, provided in Table 1 of
the regulation, to determine compliance.
mstockstill on PROD1PC66 with PROPOSALS2
F. Labeling Requirements
Section 183(e) of the CAA explicitly
authorizes the EPA to require labeling
and other requirements as part of a
regulation. We are proposing to include
labeling requirements that are necessary
to implement the regulations effectively
and to assure compliance. The
requirements we propose pertain to the
date the aerosol can is filled, the coating
category of the product, and the
applicable ACRR limit for the product.
The proposed regulation requires that
containers for all subject coatings
display the date of manufacture (or a
code indicating the date). The date of
manufacture on the label or can allows
enforcement personnel to determine
whether the coating was manufactured
prior to or after the compliance date.
The coating category and reactivity limit
allow enforcement personnel to select a
can of aerosol coating, test it using
either CARB Method 310 or EPA
Method 311, and compare the test
results to the reactivity limit on the can.
G. Recordkeeping and Reporting
Requirements
CAA section 183(e) also authorizes
EPA to impose recordkeeping and
reporting requirements. We are
proposing recordkeeping and reporting
requirements that are necessary to
ensure compliance with the regulation.
We propose to require an initial
notification report for regulated entities.
This report will provide basic
information on the regulated entity (e.g.
name, location) and will identify all
coating categories that are manufactured
at the facility. This will provide the EPA
Regional Offices with a listing of
companies in their areas that are
manufacturing, processing, distributing,
or importing aerosol coatings so that the
appropriate Regional Office can follow
up with those companies in the event a
compliance issue arises. Furthermore,
this report will explain the date code
system used to label products, if the
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date code is not immediately obvious
(e.g., month-day-year format). This will
assist EPA in identifying products that
were manufactured after the compliance
date and are therefore subject to this
regulation. Finally, the affected entity is
required to include an explanation of
how the term ‘‘batch’’ will be
interpreted for each formulation. This
report is due 90 days before the
compliance date for the rule.
Under the proposed rule, the
regulated entity is required to conduct
compliance calculations for each
coating formulation. These calculations
must be maintained onsite, for 5 years.
However, we are proposing that no
reporting of these calculations or the
results to EPA is required unless a
specific request for those results is made
by the Administrator (defined in the
regulation to include EPA Regional
Offices). We are also proposing that the
regulated entity must maintain records
of the date each batch of a particular
formulation was manufactured, the
volume of each batch, the number of
cans manufactured in each batch and
each formulation, and the recipe used
for formulating each batch.
After the initial compliance report, we
are proposing to require additional
reporting if a regulated entity adds a
new coating category or changes other
information in the initial report (e.g.,
contact information, file location).
Specifically, when this happens, we are
proposing to require a new notification
containing the updated information.
We are also requesting comment on
whether the proposed recordkeeping
and reporting requirements included in
this proposed rule should be expanded
to ensure that the Agency can verify a
regulated entity’s compliance with the
regulation. To verify compliance of an
individual product with the applicable
limit, it is necessary to analyze its VOC
composition and calculate the productweighted reactivity of the mixture.
Without prior information about
product composition, identifying the
VOC composition of a product is
difficult. Therefore, we request
comment on the feasibility and need for
a requirement for regulated entities to
submit to the Agency their VOC
formulations for each product or
product formulation in the initial report
and on a periodic basis thereafter. We
anticipate that such a report would
consist of a simple listing of the
following items: (1) A manufacturer
identifier, (2) a product identifier, (3)
the applicable product-weighted
reactivity-based limit, (4) the Chemical
Abstract Service number of each VOC
component, (5) the maximum mass
fraction of the VOC component in the
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product, and (6) the applicable
reactivity factor for the VOC component.
Because CAA section 183(e) is intended
to achieve VOC emission reductions for
purposes of reducing ozone, the
composition information provided in
the report would be limited to the VOC
components of the coating and would
not include information on the resins or
other non-VOC components. Because
each unit of product must meet the
applicable limits of the rule, the report
would only need to address VOC
composition and would not include
information on the quantity of each
product produced or sold.
Given that regulated entities are
required to keep such composition
information to demonstrate compliance
under the proposed rule, a requirement
to submit this information to EPA
periodically in a simple format should
impose minimal additional burden or
cost for industry provided that the
reporting mechanism is easy to access
and use. Such a report would provide
regulated entities an opportunity to
review their products’ compliance with
the applicable standards and therefore
help to assure compliance.
EPA notes that the VOC composition
of coatings subject to this proposed rule
is ‘‘emissions data’’ under section 114 of
the CAA, and EPA’s regulatory
definition of such term in 40 CFR part
2, because the information is necessary
to determine compliance with
applicable limits. As such, this
information must be available to the
public regardless of whether EPA
obtains the information through a
reporting requirement or through a
specific request to the regulated entity.
Therefore, such information is not
eligible for treatment as ‘‘confidential
business information’’ under proposed
section 59.516.
We specifically solicit comment on
the following questions related to the
initial report and any potential periodic
reporting requirement for information
related to VOC composition of products
subject to this rule: (1) Whether there is
a need for such a reporting requirement
to allow for more effective
implementation and enforcement of the
regulation; and (2) what specific
contents should be required in such
reports. With respect to any potential
periodic reporting requirement, we also
request comment on what frequency or
under what circumstances such
reporting should be required. As to the
mechanism or method for submitting
initial or periodic reports to EPA, we
specifically solicit comment on
whether, given the nature of the reports
under consideration, it would be
advantageous for regulated entities to
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submit reports electronically. Electronic
reporting to a centralized electronic
database could help to decrease the
burden and cost to regulated entities. A
database of composition information
would also help EPA track the effect of
the rule on VOC emissions composition
and provide information that is
necessary for effective implementation
and enforcement of the rule. For each of
these questions, EPA solicits comment
regarding the burdens and cost that
reporting requirements might impose,
and what EPA could do to minimize the
burdens and cost, especially with
respect to small entities.
We are proposing an exemption from
the limits of the rule for those entities
that manufacturer only a small amount
of aerosol coatings. We believe that this
exemption will serve to mitigate the
impacts of the rule upon small
manufacturers for whom compliance
with the rule could impose
disproportionately high costs through
reformulation of products produced
only in small volumes. Given this
objective, and in order to avoid
unnecessary excess VOC emissions that
could be significant in the aggregate, we
are proposing that this exemption from
the limits would be available only for
those manufacturers that have annual
production of aerosol coatings products
with total VOC content not in excess of
7,500 kg of VOC in all aerosol coating
product categories. We emphasize that
this to be determined by total VOC
content by mass, in all product
categories manufactured by the entity.
We consider making this distinction
based upon total VOC mass, rather than
some reactivity-adjusted calculation,
necessary both to minimize the
analytical impacts upon the entity
seeking the exemption from the rule,
and to provide for more effective
implementation and enforcement of this
aspect of the rule.
A manufacturer that qualifies for the
exemption must notify EPA of this in
the initial notification report required in
proposed section 59.511. As a condition
for the exemption from the limits, the
proposed rule also requires the entity to
file an annual report with EPA
providing the information necessary to
evaluate and to establish that the
products manufactured by the entity are
properly exempt from the limits of rule.
This information is necessary to assure
that the entity is in compliance, even if
its products do not meet the limits of
the rule. EPA notes that an exemption
under EPA’s national rule for aerosol
coatings under section 183(e) does not
alter any requirements under any
applicable state or local regulations.
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We specifically request comment on
whether there is a need for an
exemption of this type for very small
manufacturers. In addition, we request
comment on the features of the
exemption as we have proposed it.
Finally, in order to get better
information about the number of
manufactures that would potentially use
such an exemption, we specifically
request that interested commenters
indicate whether they would elect to
use the exemption from the limits.
The proposed rule requires all
regulated entities to comply by January
1, 2009. EPA believes that compliance
by this date is readily achievable by
most, if not all, regulated entities subject
to this rule. However, in the case of
regulated entities that have not
previously met the limits already
imposed by regulation in the State of
California, EPA believes that it may be
appropriate to provide an extension of
the compliance date on a case by case
basis. Therefore, the proposed rule
includes a provision that will allow
regulated entities that have not
previously manufactured, imported, or
distributed for sale or distribution in
California any product in any category
listed in Table 1 of this subpart that
complies with applicable California
regulations for aerosol coatings to seek
an extension of the compliance date.
Such extensions will be granted at the
discretion of the Administrator. The
grant or denial of a compliance date
extension does not affect the right of the
regulated entity to seek a variance under
this rule.
H. Variance Criteria
The proposed ACRR includes a
variance provision. Companies may
require a variance for several reasons.
The regulated entity may be responsible
for a coating that has more extensive
performance requirements than other
coatings in the category so that
reformulating that coating to meet the
reactivity limits is more difficult than it
is for other coatings. In some cases, a
regulated entity may experience an
interruption in the supply of a
particular compound necessary to the
performance of a coating due to a fire or
other exceptional event at the supplier’s
facility. Furthermore, small companies
may require longer to reformulate a
coating due to limited resources. The
proposed rule requires regulated entities
to submit a written application to the
Administrator requesting a variance if,
for reasons beyond their reasonable
control, they cannot comply with the
requirements of the proposed rule. The
application must include the following
information:
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(1) The specific products for which
the variance is sought;
(2) The specific provisions of the
subpart for which the variance is
sought;
(3) The specific grounds upon which
the variance is sought;
(4) The proposed date(s) by which
compliance with the provisions of the
rule will be achieved; and
(5) A compliance plan detailing the
method(s) by which compliance will be
achieved.
Upon receipt of the variance
application, the Administrator will
determine whether a variance is
warranted.
The Administrator may grant a
variance if the following criteria are
met:
(1) Complying with the provisions of
this subpart would not be
technologically or economically
feasible.
(2) The compliance plan proposed by
the applicant can reasonably be
implemented and will achieve
compliance as expeditiously as possible.
The approved variance order will
designate a final compliance date and a
condition that specifies increments of
progress necessary to assure timely
compliance. A variance shall end
immediately upon the failure of the
regulated entity to comply with any
term or condition of the variance.
The EPA understands that some
regulated entities may face more
challenges in meeting the limits of the
regulation than others. Therefore, the
Administrator will carefully evaluate
requests from regulated entities’
facilities, particularly small businesses
that have not marketed their products in
regulated areas prior to this rulemaking.
I. Test Methods
To demonstrate compliance with the
proposed reactivity limits, it is
necessary to identify the species of
reactive organic compounds that are
present in the coating and the percent
weight of each compound. While
regulated entities may use formulation
data to demonstrate compliance with
this rule, the rule requires that the
results of calculations using formulation
data be consistent with results of
calculations obtained from approved
test methods. CARB’s Method 310 is the
primary test method we have included
in the regulation for demonstrating
compliance with the reactivity limits.
Method 310 is essentially a
compendium of methods developed by
other agencies (for example, ASTM, U.S.
EPA, NIOSH) that focus on identifying
and quantifying the components of an
aerosol coating. Manufacturers and
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regulatory agencies using Method 310 to
determine the compliance status of a
coating must select the appropriate
methods from Method 310 that will
ensure the necessary data are generated.
There is no one method that will
provide the necessary data. For
example, as a minimum, it will be
necessary to use one of the ASTM
methods referenced in Method 310 to
separate the propellant from the liquid
portion of the coating and another
method, or in some cases, multiple
methods, to analyze the propellant and
liquid portions for VOC content.
Although Method 310 is complex, EPA
believes that it is an appropriate method
to incorporate into the aerosol coatings
regulation. The method has been used
in California to demonstrate compliance
with the reactivity limits developed for
aerosol coatings in that state and EPA
believes it is an effective method for
demonstrating compliance with this
regulation. [Other issues associated with
this method are identified in a
memorandum included in the docket to
this rule (EPA–HQ–OAR–2006–0971)].
We have also included EPA’s Test
Method 311—Analysis of Hazardous Air
Pollutant Compounds in Paints and
Coatings—as an alternative test method
to CARB’s Method 310. Aerosol coating
manufacturers and regulatory agencies
can elect to use Method 311 to
demonstrate compliance with the
reactivity limits. As the title of Method
311 suggests, EPA originally developed
this method to analyze the HAP content
of coatings. However, EPA believes that
the method is applicable to the
identification and quantification of
organic compounds that may be present
in aerosol coatings.
As with Method 310, it is necessary
that the analyst be provided with a list
of the compounds in the coating so that
the analyst can properly calibrate the
gas chromatograph that will be used for
the analysis. Because Method 311 was
developed specifically for the analysis
of coatings, it is in many ways a simpler
and more straightforward method than
310. The results from Method 311 are
based on percent by weight, so it is not
necessary to convert the results to
another metric. The sample preparation
instructions in Method 311, with the
exception of the aerosol portion of the
coating, do not require any adjustments
since they were specifically developed
for the analysis of liquid samples. We
know of no reason why the data
collected using Method 311 should be
any less accurate than those collected
using Method 310. For these reasons, we
have decided to include Method 311 as
an alternative to Method 310.
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Because Method 311 was developed
for the analysis of liquid coatings and
aerosol coatings containing both liquid
and gaseous components, those electing
to use Method 311 must also use either
ASTM Method D3063–94 or D3074–94
to collect the propellant for analysis. As
discussed earlier, this is also true for
those running Method 310. The only
difference is that the ASTM methods are
specifically referenced in Method 310.
V. Statutory and Executive Order (EO)
Reviews
A. Executive Order 12866: Regulatory
Planning and Review
Under Executive Order (EO) 12866
(58 FR 51735, October 4, 1993), this
action is a ‘‘significant regulatory
action’’ since it raises novel legal or
policy issues. Accordingly, EPA
submitted this action to the Office of
Management and Budget (OMB) for
review under EO 12866 and any
changes made in response to OMB
recommendations have been
documented in the docket for this
action.
B. Paperwork Reduction Act
The information collection
requirements in this proposed rule have
been submitted for approval to the OMB
under the Paperwork Reduction Act, 44
U.S.C. 3501 et seq. The Information
Collection Request (ICR) document
prepared by EPA has been assigned EPA
ICR number 2266.01.
The information collection
requirements are based on
recordkeeping and reporting
requirements. These recordkeeping and
reporting requirements are specifically
authorized by CAA section 114 (42
U.S.C. 7414). All information submitted
to EPA pursuant to the recordkeeping
and reporting requirements for which a
claim of confidentiality is made is
safeguarded according to Agency
policies set forth in 40 CFR part 2,
subpart B.
The proposed standards would
require regulated entities to submit an
initial notification and other reports as
outlined in section IV.F.
We estimate that about 62 regulated
entities would be subject to the
proposed standards. New and existing
regulated entities would have no capital
costs associated with the information
collection requirements in the proposed
standards.
The estimated recordkeeping and
reporting burden in the 3rd year after
the effective date of the promulgated
rule is estimated to be 7986 labor hours
at a cost of $472,386.00. This estimate
includes the cost of reporting, including
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reading instructions, information
gathering, preparation of initial and
supplemental reports, and variance
applications. Recordkeeping cost
estimates include reading instructions,
planning activities, calculation of
reactivity, and maintenance of batch
information. The average hours and cost
per regulated entity would be 128 hours
and $7,619.00. About 62 facilities would
respond per year.
Burden means the total time, effort, or
financial resources expended by persons
to generate, maintain, retain, or disclose
or provide information to or for a
Federal Agency. This includes the time
needed to review instructions; develop,
acquire, install, and utilize technology
and systems for the purposes of
collecting, validating, and verifying
information, processing and
maintaining information, and disclosing
and providing information; adjust the
existing ways to comply with any
previously applicable instructions and
requirements; train personnel to be able
to respond to a collection of
information; search data sources;
complete and review the collection of
information; and transmit or otherwise
disclose the information.
An agency may not conduct or
sponsor, and a person is not required to
respond to a collection of information
unless it displays a currently valid OMB
control number. The OMB control
numbers for EPA’s regulations in 40
CFR are listed in 40 CFR part 9.
To comment on the Agency’s need for
this information, the accuracy of the
provided burden estimates, and any
suggested methods for minimizing
respondent burden, including the use of
automated collection techniques, EPA
has established a public docket for this
rule, which includes this ICR, under
Docket ID number EPA–HQ–OAR–
2006–0971. Submit any comments
related to the ICR for this proposed rule
to EPA and OMB. See ADDRESSES
section at the beginning of this notice
for where to submit comments to EPA.
Send comments to OMB at the Office of
Information and Regulatory Affairs,
Office of Management and Budget, 725
17th Street, NW., Washington, DC
20503, Attention: Desk Officer for EPA.
Since OMB is required to make a
decision concerning the ICR between 30
and 60 days after July 16, 2007 in the
Federal Register, a comment to OMB is
best assured of having its full effect if
OMB receives it by August 15, 2007 in
the Federal Register. The final rule will
respond to any OMB or public
comments on the information collection
requirements contained in this proposal.
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C. Regulatory Flexibility Act
The Regulatory Flexibility Act (RFA)
generally requires an agency to prepare
a regulatory flexibility analysis of any
rule subject to notice and comment
rulemaking requirements under the
Administrative Procedure Act or any
other statute unless the agency certifies
that the rule will not have a significant
economic impact on a substantial
number of small entities. Small entities
include small businesses, small
organizations, and small governmental
jurisdictions.
For purposes of assessing the impacts
of this proposed rule on small entities,
small entity is defined as: (1) A small
business as defined by the Small
Business Administration’s (SBA)
regulations at 13 CFR 121.201; (2) a
small governmental jurisdiction that is a
government of a city, county, town,
school district, or special district with a
population of less than 50,000; and (3)
a small organization that is any not-forprofit enterprise which is independently
owned and operated and is not
dominant in its field.
After considering the economic
impacts of this proposed regulatory
action, I certify that this action will not
have a significant economic impact on
a substantial number of small entities
because the cost to sales ratio is small
for all of the facilities owned by small
entities. The small entities directly
regulated by this proposed rule are
small manufacturers, processors,
wholesale distributors, or importers of
aerosol coatings for sale or distribution
in interstate commerce in the United
States. Our analysis indicates that all 43
of the identified small entities (seventytwo percent of all identified facilities)
will likely experience a cost impact of
less than one percent of revenues.
Although this proposed rule will not
have a significant economic impact on
a substantial number of small entities,
EPA nonetheless has tried to reduce the
impact of this rule on small entities in
two ways. First, the proposed rule
considers issuance of a special
compliance extension that extends the
date of compliance by two years for
regulated entities that have never
manufactured, imported, or distributed
aerosol coatings for sale or distribution
in California in compliance with
California’s Regulation for Reducing
Ozone Formed from Aerosol Coating
Product Emissions, Title 17, California
Code of Regulations, Sections 94520–
94528. Finally, the proposed rule
includes an exemption from the limits
in Table 1 of subpart E of the rule for
those manufacturers that manufacture
very limited amounts of aerosol
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coatings, i.e., products with a total VOC
content by mass of no more than 7,500
kilograms of VOC per year in the
aggregate for all products. We continue
to be interested in the potential impacts
of the proposed rule on small entities
and welcome comments on issues
related to such impacts.
D. Unfunded Mandates Reform Act
Title II of the Unfunded Mandates
Reform Act of 1995 (UMRA), Public
Law 104–4, establishes requirements for
Federal agencies to assess the effects of
their regulatory actions on State, local,
and tribal governments and the private
sector. Under section 202 of the UMRA,
EPA generally must prepare a written
statement, including a cost-benefit
analysis, for proposed and final rules
with ‘‘Federal mandates’’ that may
result in expenditures to State, local,
and tribal governments, in the aggregate,
or to the private sector, of $100 million
or more in any one year. Before
promulgating an EPA rule for which a
written statement is needed, section 205
of the UMRA generally requires EPA to
identify and consider a reasonable
number of regulatory alternatives, and
adopt the least costly, most costeffective or least burdensome alternative
that achieves the objectives of the rule.
The provisions of section 205 do not
apply when they are inconsistent with
applicable law. Moreover, section 205
allows EPA to adopt an alternative other
than the least costly, most cost-effective
or least burdensome alternative if the
Administrator publishes with the final
rule an explanation why that alternative
was not adopted. Before EPA establishes
any regulatory requirements that may
significantly or uniquely affect small
governments, including tribal
governments, it must have developed
under section 203 of the UMRA a small
government agency plan. The plan must
provide for notifying potentially
affected small governments, enabling
officials of affected small governments
to have meaningful and timely input in
the development of EPA regulatory
proposals with significant Federal
intergovernmental mandates, and
informing, educating, and advising
small governments on compliance with
the regulatory requirements.
EPA has determined that the
proposed regulatory action does not
contain a Federal mandate that may
result in expenditures of $100 million or
more for State, local, or tribal
governments, in the aggregate, or the
private sector in any one year. Thus,
this proposed action is not subject to the
requirements of sections 202 and 205 of
the UMRA. In addition, we have
determined that the proposed regulatory
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action contains no regulatory
requirements that might significantly or
uniquely affect small governments
because they contain no regulatory
requirements that apply to such
governments or impose obligations
upon them. Therefore, this action is not
subject to the requirements of section
203 of UMRA.
E. Executive Order 13132: Federalism
Executive Order 13132, entitled
‘‘Federalism’’ (64 FR 43255, August 10,
1999), requires EPA to develop an
accountable process to ensure
‘‘meaningful and timely input by State
and local officials in the development of
regulatory policies that have federalism
implications.’’ ‘‘Policies that have
federalism implications’’ is defined in
the EO to include regulations that have
‘‘substantial direct effects on the States,
on the relationship between the national
government and the States, or on the
distribution of power and
responsibilities among the various
levels of government.’’
The proposed regulatory action does
not have federalism implications. The
action does not have substantial direct
effects on the States, on the relationship
between the national government and
the States, or on the distribution of
power and responsibilities among the
various levels of government, as
specified in EO 13132. The CAA
establishes the relationship between the
Federal Government and the States, and
this action does not impact that
relationship. Thus, EO 13132 does not
apply to the proposed regulatory action.
However, in the spirit of EO 13132, and
consistent with EPA policy to promote
communications between EPA and State
and local governments, EPA is soliciting
comment on the proposed regulatory
action from State and local officials.
F. Executive Order 13175: Consultation
and Coordination with Indian Tribal
Governments
EO 13175, entitled ‘‘Consultation and
Coordination with Indian Tribal
Governments’’ (65 FR 67249, November
9, 2000), requires EPA to develop an
accountable process to ensure
‘‘meaningful and timely input by Tribal
officials in the development of
regulatory policies that have Tribal
implications.’’
The proposed action does not have
Tribal implications as defined by EO
13175. The proposed regulatory action
does not have a substantial direct effect
on one or more Indian Tribes, in that the
proposed action imposes no regulatory
burdens on tribes. Furthermore, the
proposed action does not affect the
relationship or distribution of power
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and responsibilities between the Federal
Government and Indian Tribes. The
CAA and the Tribal Authority Rule
(TAR) establish the relationship of the
Federal Government and Tribes in
implementing the Clean Air Act.
Because the proposed rule does not
have Tribal implications, EO 13175 does
not apply.
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G. Executive Order 13045: Protection of
Children from Environmental Health
and Safety Risks
Executive Order 13045, ‘‘Protection of
Children from Environmental Health
and Safety Risks’’ (62 FR 19885, April
23, 1997) applies to any rule that (1) is
determined to be ‘‘economically
significant’’ as defined under EO 12866,
and (2) concerns an environmental
health or safety risk that EPA has reason
to believe may have a disproportionate
effect on children. If the regulatory
action meets both criteria, section 5B501
of the EO directs the Agency to evaluate
the environmental health or safety
effects of the planned rule on children,
and explain why the planned regulation
is preferable to other potentially
effective and reasonably feasible
alternatives considered by the Agency.
The proposed regulatory action is not
subject to Executive Order 13045
because it is not an economically
significant regulatory action as defined
by Executive Order 12866. In addition,
EPA interprets Executive Order 13045
as applying only to those regulatory
actions that are based on health and
safety risks, such that the analysis
required under section 5–501 of the
Executive Order has the potential to
influence the regulations. The proposed
regulatory action is not subject to
Executive Order 13045 because it does
not include regulatory requirements
based on health or safety risks.
H. Executive Order 13211: Actions
Concerning Regulations That
Significantly Affect Energy Supply,
Distribution, or Use
This rule is not a ‘‘significant energy
action’’ as defined in Executive Order
13211, ‘‘Actions Concerning Regulations
That Significantly Affect Energy Supply,
Distribution, or Use’’ (66 FR 28355 (May
22, 2001)) because it is not likely to
have a significant adverse effect on the
supply, distribution, or use of energy.
Further, we have concluded that this
rule is not likely to have any adverse
energy effects.
I. National Technology Transfer and
Advancement Act
Section 12(d) of the National
Technology Transfer and Advancement
Act (NTTAA) of 1995 (Pub. L. No. 104–
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113, Section 12(d), 15 U.S.C. 272 note)
directs EPA to use voluntary consensus
standards (VCS) in its regulatory
activities, unless to do so would be
inconsistent with applicable law or
otherwise impractical. The VCS are
technical standards (e.g., materials
specifications, test methods, sampling
procedures, and business practices) that
are developed or adopted by VCS
bodies. The NTTAA directs EPA to
provide Congress, through OMB,
explanations when the Agency does not
use available and applicable VCS.
This proposed rule involves technical
standards. The EPA cites the following
standards in this rule: California Air
Resources Board (ARB) Method 310,
‘‘Determination of Volatile Organic
Compounds (VOC) in Consumer
Products and Reactive Organic
Compounds in Aerosol Coating
Products;’’ EPA Method 311 in 40 CFR
part 60, appendix B, in conjunction
with American Society of Testing and
Materials (ASTM) method D3063–94 or
D3074–94 for analysis of the propellant
portion of the coating; South Coast Air
Quality Management District
(SCAQMD) method 318–95,
‘‘Determination of Weight Percent
Elemental Metal in Coatings by X-ray
Diffraction’’ for metal content; ASTM
D523–89 (1999) for specular gloss of flat
and nonflat coatings; and ASTM D1613–
03, ‘‘Standard Test Method for Acidity
in Volatile Solvents and Chemical
Intermediates Used in Paint, Varnish,
Lacquer, and Related Products’’ for acid
content of rust converters.
The EPA Method 311 also is a
compilation of voluntary consensus
standards. The following are
incorporated by reference in Method
311: ASTM D1979–91, ASTM D3432–
89, ASTM D4457–85, ASTM D4747–87,
ASTM D4827–93, and ASTM PS9–94.
Consistent with the NTTAA, EPA
conducted searches to identify
voluntary consensus standards in
addition to these methods. No
applicable voluntary consensus
standards were identified.
For the methods required by the
proposed rule, a source may apply to
EPA for permission to use alternative
test methods or alternative monitoring
requirements in place of any required
testing methods, performance
specifications, or procedures under
sections 63.7(f) and 63.8(f) of Subpart A
of the General Provisions.
J. Executive Order 12898: Federal
Actions to Address Environmental
Justice in Minority Populations and
Low-Income Populations
Executive Order (EO) 12898 (59 FR
7629 (Feb. 16, 1994)) establishes federal
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executive policy on environmental
justice. Its main provision directs
federal agencies, to the greatest extent
practicable and permitted by law, to
make environmental justice part of their
mission by identifying and addressing,
as appropriate, disproportionately high
and adverse human health or
environmental effects of their programs,
policies, and activities on minority
populations and low-income
populations in the United States.
EPA has determined that this
proposed rule will not have
disproportionately high and adverse
human health or environmental effects
on minority or low-income populations
because it increases the level of
environmental protection for all affected
populations without having any
disproportionately high and adverse
human health or environmental effects
on any population, including any
minority or low-income populations.
Further, it establishes national emission
standards for VOC in aerosol coatings.
List of Subjects
40 CFR Part 51
Environmental protection,
Administrative practice and procedure,
Air pollution control, Carbon monoxide,
Intergovernmental relations, Lead,
Nitrogen dioxide, Ozone, Particulate
matter, Reporting and recordkeeping
requirements, Sulfur oxides, Volatile
organic compound.
40 CFR Part 59
Environmental protection,
Administrative practice and procedure,
Air pollution control, Intergovernmental
relations, Reporting and recordkeeping
requirements, Consumer products,
Aerosol coatings.
Dated: June 29, 2007.
Stephen L. Johnson,
Administrator.
For the reasons set out in the
preamble, part 59 of title 40 of the Code
of Federal Regulations is proposed to be
amended as follows:
PART 51—[AMENDED]
1. The authority citation for Part 51
continues to read as follows:
Authority: 23 U.S.C. 101; 42 U.S.C. 7401–
7671q.
2. Section 51.100 is amended by
adding paragraph (s)(7) to read as
follows:
§ 51.100
Definitions.
*
*
*
*
*
(s) * * *
(7) For the purposes of determining
compliance with EPA’s aerosol coatings
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reactivity based regulation (as described
in Part 59—National Volatile Organic
Compound Emission Standards for
Consumer and Commercial Products)
any organic compound in the volatile
portion of an aerosol coating is counted
towards the product’s reactivity-based
limit. Therefore, the compounds
identified in paragraph (s) of this
section as negligibly reactive and
excluded from EPA’s definition of VOC
are to be counted towards a product’s
reactivity limit for the purposes of
determining compliance with EPA’s
aerosol coatings reactivity-based
national regulation.
*
*
*
*
*
PART 59—[AMENDED]
3. The authority citation for part 59
continues to read as follows:
Authority: 42 U.S.C. 7414 and 7511b(e).
4. Subpart E is added to read as
follows:
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Subpart E—National Volatile Organic
Compound Emission Standards for Aerosol
Coatings
Sec.
59.500 What is the purpose of this subpart?
59.501 Am I subject to this subpart?
59.502 When do I have to comply with this
subpart?
59.503 What definitions apply to this
subpart?
59.504 What limits must I meet?
59.505 How do I demonstrate compliance
with the reactivity limits?
59.506 How do I demonstrate compliance if
I manufacture multi-component kits?
59.507 What are the labeling requirements
for aerosol coatings?
59.508 What test methods must I use?
59.509 Can I get a variance?
59.510 What records am I required to
maintain?
59.511 What reports must I submit?
59.512 Addresses of EPA regional offices.
59.513 State authority.
59.514 Circumvention.
59.515 Incorporations by reference.
59.516 Availability of information and
confidentiality
Table 1 to Subpart E to Part 59—ProductWeighted Reactivity Limits by Coating
Category
Table 2A to Subpart E to Part 59—
Reactivity Factors
Table 2B to Subpart E to Part 59—
Reactivity Factors for Aliphatic Hydrocarbon
Solvent Mixtures
Table 2C to Subpart E to Part 59—
Reactivity Factors for Aromatic Hydrocarbon
Solvent Mixtures
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Subpart E—National Volatile Organic
Compound Emission Standards for
Aerosol Coatings
§ 59.500 What is the purpose of this
subpart?
This subpart establishes the product
weighted reactivity (PWR) limits
regulated entities must meet to in order
to comply with the national rule for
volatile organic compounds emitted
from aerosol coatings. This subpart also
establishes labeling, and recordkeeping
and reporting requirements for regulated
entities.
§ 59.501
Am I subject to this subpart?
(a) You are a regulated entity under
this rule and subject to this subpart if
you are listed in either paragraph (a)(1)
or (a)(2) of this section.
(1) Manufacturers, processors,
wholesale distributors, or importers of
aerosol coatings for sale or distribution
in interstate commerce in the United
States; or
(2) Manufacturers, processors,
wholesale distributors, or importers that
supply the entities listed in paragraph
(a)(1) with such products for sale or
distribution in interstate commerce in
the United States.
(b) Except as provided in paragraph
(e) of this section, as a manufacturer or
importer of the product, you are subject
to the product weighted reactivity limits
presented in § 59.504 even if you are not
named on the label. If you are a
distributor named on the label, you are
responsible for compliance with all
sections of this subpart except for the
limits presented in § 59.504.
Distributors that are not named on the
label are not subject to this subpart. If
there is no distributor named on the
label, then the manufacturer or importer
is responsible for complying with all
sections of this subpart.
(c) Except as provided in paragraph
(e) of this section, the provisions of this
subpart apply to aerosol coatings
manufactured on or after January 1,
2009 for sale or distribution in the
United States.
(d) You are not a regulated entity
under this subpart if you manufacture
coatings (in or outside of the United
States) that are exclusively for sale
outside the United States.
(e) If you are a manufacture of aerosol
coatings but the total amount of VOC by
mass in the products you manufacture,
in the aggregate, is less than 7,500 kg
per year, then the products you
manufacture in such year are exempt
from the product-weighted reactivity
limits presented in § 59.504, so long as
you are in compliance with the other
applicable provisions of this subpart.
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38973
§ 59.502 When do I have to comply with
this subpart?
(a) Except as provided in § 59.509 and
paragraph (b) of this section, you must
be in compliance with all provisions of
this subpart by January 1, 2009.
(b) The Administrator will consider
issuance of a special compliance
extension that extends the date of
compliance until January 1, 2011, to
regulated entities that have never
manufactured, imported, or distributed
aerosol coatings for sale or distribution
in California in compliance with
California’s Regulation for Reducing
Ozone Formed from Aerosol Coating
Product Emissions, Title 17, California
Code of Regulations, Sections 94520–
94528. In order to be considered for an
extension of the compliance date, you
must submit a special compliance
extension application to the EPA
Administrator no later than 90 days
before the compliance date or within 90
days before the date that you first
manufacture aerosol coatings,
whichever is later. This application
must contain the information in
paragraphs (b)(1) through (b)(5) of the
section:
(1) Company name;
(2) A signed certification by a
responsible company official that the
regulated entity has not at any time
manufactured, imported, or distributed
for sale or distribution in California any
product in any category listed in Table
1 of this subpart that complies with
California’s Regulation for Reducing
Ozone Formed From Aerosol Coating
Product Emissions, Title 17, California
Code of Regulations, Sections 94520–
94528;
(3) A statement that the regulated
entity will, to the extent possible within
its reasonable control, take appropriate
action to achieve compliance with this
subpart by January 1, 2011;
(4) A list of the product categories in
Table 1 of this subpart that the regulated
entity manufactures, imports, or
distributes; and,
(5) Name, title, address, telephone, email address, and signature of the
certifying company official.
(6) If a regulated entity remains
unable to comply with the limits of this
rule by January 1, 2011, the regulated
entity may seek a variance in
accordance with § 59.509.
§ 59.503 What definitions apply to this
subpart?
The following terms are defined for
the purposes of this subpart only.
Administrator means the
Administrator of the United States
Environmental Protection Agency (U.S.
EPA) or an authorized representative.
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Aerosol Coating Product means a
pressurized coating product containing
pigments or resins that dispenses
product ingredients by means of a
propellant and is packaged in a
disposable can for hand-held
application or for use in specialized
equipment for ground traffic/marking
applications. For the purpose of this
regulation, applicable aerosol coatings
categories are listed in Table 1 of this
subpart.
Art Fixative or Sealant means a clear
coating, including art varnish, workable
art fixative, and ceramic coating, which
is designed and labeled exclusively for
application to paintings, pencil, chalk,
or pastel drawings, ceramic art pieces,
or other closely related art uses, in order
to provide a final protective coating or
to fix preliminary stages of artwork
while providing a workable surface for
subsequent revisions. ASTM means the
American Society for Testing and
Materials.
Autobody Primer means an
automotive primer or primer surfacer
coating designed and labeled
exclusively to be applied to a vehicle
body substrate for the purposes of
corrosion resistance and building a
repair area to a condition in which, after
drying, it can be sanded to a smooth
surface.
Automotive Bumper and Trim
Product means a product, including
adhesion promoters and chip sealants,
designed and labeled exclusively to
repair and refinish automotive bumpers
and plastic trim parts.
Aviation Propeller Coating means a
coating designed and labeled
exclusively to provide abrasion
resistance and corrosion protection for
aircraft propellers. Aviation or Marine
Primer means a coating designed and
labeled exclusively to meet federal
specification TT–P–1757.
Clear Coating means a coating which
is colorless, containing resins but no
pigments except flatting agents, and is
designed and labeled to form a
transparent or translucent solid film.
Coating Solids means the nonvolatile
portion of an aerosol coating product,
consisting of the film forming
ingredients, including pigments and
resins.
Commercial Application means the
use of aerosol coating products in the
production of goods, or the providing of
services for profit, including touch-up
and repair.
Corrosion Resistant Brass, Bronze, or
Copper Coating means a clear coating
designed and labeled exclusively to
prevent tarnish and corrosion of
uncoated brass, bronze, or copper metal
surfaces.
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Distributor means any person to
whom an aerosol coating product is sold
or supplied for the purposes of resale or
distribution in commerce, except that
manufacturers, retailers, and consumers
are not distributors.
Enamel means a coating which cures
by chemical cross-linking of its base
resin and is not resoluble in its original
solvent.
Engine Paint means a coating
designed and labeled exclusively to coat
engines and their components.
Exact Match Finish, Automotive
means a topcoat which meets all of the
following criteria:
(1) The product is designed and
labeled exclusively to exactly match the
color of an original, factory-applied
automotive coating during the touch-up
of automobile finishes;
(2) The product is labeled with the
manufacturer’s name for which they
were formulated; and
(3) The product is labeled with one of
the following:
(i) The original equipment
manufacturer’s (O.E.M.) color code
number;
(ii) The color name; or
(iii) Other designation identifying the
specific O.E.M. color to the purchaser.
Not withstanding the foregoing,
automotive clear coatings designed and
labeled exclusively for use over
automotive exact match finishes to
replicate the original factory applied
finish shall be considered to be
automotive exact match finishes.
Exact Match Finish, Engine Paint
means a coating which meets all of the
following criteria:
(1) The product is designed and
labeled exclusively to exactly match the
color of an original, factory-applied
engine paint;
(2) The product is labeled with the
manufacturer’s name for which they
were formulated; and
(3) The product is labeled with one of
the following:
(i) The original equipment
manufacturer’s (O.E.M.) color code
number;
(ii) The color name; or
(iii) Other designation identifying the
specific original equipment
manufacturer (O.E.M.) color to the
purchaser.
Exact Match Finish, Industrial means
a coating which meets all of the
following criteria:
(1) The product is designed and
labeled exclusively to exactly match the
color of an original, factory-applied
industrial coating during the touch-up
of manufactured products;
(2) The product is labeled with the
manufacturer’s name for which they
were formulated; and
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(3) The product is labeled with one of
the following:
(i) O.E.M. color code number; (ii) the
color name; or (iii) other designation
identifying the specific O.E.M. color to
the purchaser.
Flat Paint Products means a coating
which, when fully dry, registers
specular gloss less than or equal to 15
on an 85° gloss meter, or less than or
equal to 5 on a 60° gloss meter, or which
is labeled as a flat coating.
Flatting Agent means a compound
added to a coating to reduce the gloss
of the coating without adding color to
the coating.
Floral Spray means a coating designed
and labeled exclusively for use on fresh
flowers, dried flowers, or other items in
a floral arrangement for the purposes of
coloring, preserving or protecting their
appearance.
Fluorescent Coating means a coating
labeled as such, which converts
absorbed incident light energy into
emitted light of a different hue.
Glass Coating means a coating
designed and labeled exclusively for use
on glass or other transparent material to
create a soft, translucent light effect, or
to create a tinted or darkened color
while retaining transparency.
Ground Traffic/Marking Coating
means a coating designed and labeled
exclusively to be applied to dirt, gravel,
grass, concrete, asphalt, warehouse
floors, or parking lots. Such coatings
must be in a container equipped with a
valve and spray head designed to direct
the spray toward the surface when the
can is held in an inverted vertical
position.
High Temperature Coating means a
coating, excluding engine paint, which
is designed and labeled exclusively for
use on substrates which will, in normal
use, be subjected to temperatures in
excess of 400°F.
Hobby/Model/Craft Coating means a
coating which is designed and labeled
exclusively for hobby applications and
is sold in aerosol containers of 6 ounces
by weight or less.
Impurity means an individual
chemical compound present in a raw
material which is incorporated in the
final aerosol coatings formulation, if the
compound is present in amounts below
the following in the raw material:
(1) For individual compounds that are
carcinogens each compound must be
present in an amount less than 0.1
percent by weight;
(2) For all other compounds present
in a raw material, a compound must be
present in an amount less than 1 percent
by weight.
Ingredient means a component of an
aerosol coating product.
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Lacquer means a thermoplastic filmforming material dissolved in organic
solvent, which dries primarily by
solvent evaporation, and is resoluble in
its original solvent.
Manufacturer means any person who
imports, manufactures, assembles,
produces, packages, repackages, or
relabels a consumer product.
Marine Spar Varnish means a coating
designed and labeled exclusively to
provide a protective sealant for marine
wood products.
Metallic Coating means a topcoat
which contains at least 0.5 percent by
weight elemental metallic pigment in
the formulation, including propellant,
and is labeled as ‘‘metallic’’, or with the
name of a specific metallic finish such
as ‘‘gold’’, ‘‘silver’’, or ‘‘bronze.’’
Multi-Component Kit means an
aerosol spray paint system which
requires the application of more than
one component (e.g. foundation coat
and top coat), where both components
are sold together in one package.
Nonflat Paint Product means a coating
which, when fully dry, registers a
specular gloss greater than 15 on an 85°
gloss meter or greater than five on a 60°
gloss meter.
Ozone means a colorless gas with a
pungent odor, having the molecular
form O3.
Photograph Coating means a coating
designed and labeled exclusively to be
applied to finished photographs to
allow corrective retouching, protection
of the image, changes in gloss level, or
to cover fingerprints.
Pleasure Craft means privately owned
vessels used for noncommercial
purposes.
Pleasure Craft Finish Primer/
Surfacer/Undercoater means a coating
designed and labeled exclusively to be
applied prior to the application of a
pleasure craft topcoat for the purpose of
corrosion resistance and adhesion of the
topcoat, and which promotes a uniform
surface by filling in surface
imperfections.
Pleasure Craft Topcoat means a
coating designed and labeled
exclusively to be applied to a pleasure
craft as a final coat above the waterline
and below the waterline when stored
out of water. This category does not
include clear coatings.
Polyolefin Adhesion Promoter means
a coating designed and labeled
exclusively to be applied to a polyolefin
or polyolefin copolymer surface of
automotive body parts, bumpers, or trim
parts to provide a bond between the
surface and subsequent coats.
Primer means a coating labeled as
such, which is designed to be applied to
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a surface to provide a bond between that
surface and subsequent coats.
Product Weighted Reactivity (PWR)
Limit means the maximum ‘‘productweighted reactivity,’’ as calculated in
§ 59.505, allowed in an aerosol coating
product that is subject to the limits
specified in § 59.504 for a specific
category, expressed as g O3/g product.
Propellant means a liquefied or
compressed gas that is used in whole or
in part, such as a co-solvent, to expel a
liquid or any other material from the
same self-pressurized container or from
a separate container.
Reactivity Factor (RF) is a measure of
the change in mass of ozone formed by
adding a gram of a VOC to the ambient
atmosphere, expressed to hundredths of
a gram (g O3/g VOC). The RF values for
individual compounds and hydrocarbon
solvents are specified in Tables 2A, 2B,
and 2C of this subpart.
Regulated Entity means the company,
firm, or establishment which is listed on
the product’s label. If the label lists two
companies, firms or establishments, the
responsible party is the party which the
product was ‘‘manufactured for’’ or
‘‘distributed by’’, as noted on the label.
Retailer means any person who sells,
supplies, or offers aerosol coating
products for sale directly to consumers.
Retail Outlet means any establishment
where consumer products are sold,
supplied, or offered for sale, directly to
consumers.
Shellac Sealer means a clear or
pigmented coating formulated solely
with the resinous secretion of the lac
beetle (Laccifer lacca), thinned with
alcohol, and formulated to dry by
evaporation without a chemical
reaction.
Slip-Resistant Coating means a
coating designed and labeled
exclusively as such, which is
formulated with synthetic grit and used
as a safety coating.
Spatter Coating/Multicolor Coating
means a coating labeled exclusively as
such wherein spots, globules, or spatters
of contrasting colors appear on or
within the surface of a contrasting or
similar background.
Stain means a coating which is
designed and labeled to change the
color of a surface but not conceal the
surface.
Vinyl/Fabric/Leather/Polycarbonate
Coating means a coating designed and
labeled exclusively to coat vinyl, fabric,
leather, or polycarbonate substrates or to
coat flexible substrates including rubber
or thermoplastic substrates.
Volatile Organic Compound (VOC)
means any organic compound as
defined in § 51.100(s) of this chapter.
Exemptions from the definition of VOC
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38975
in § 51.100(s)(1) are inapplicable for
purposes of this subpart.
Webbing/Veiling Coating means a
coating designed and labeled
exclusively to provide a stranded to
spider webbed appearance when
applied.
Weight Fraction means the weight of
an ingredient divided by the total net
weight of the product, expressed to
thousandths of a gram of ingredient per
gram of product (excluding container
and packaging).
Weld-Through Primer means a coating
designed and labeled exclusively to
provide a bridging or conducting effect
for corrosion protection following
welding.
Wood Stain means a coating which is
formulated to change the color of a
wood surface but not conceal the
surface.
Wood Touch-Up/Repair/Restoration
means a coating designed and labeled
exclusively to provide an exact color or
sheen match on finished wood
products.
Working Day means any day between
Monday and Friday, inclusive, except
for days that are federal holidays.
§ 59.504
What limits must I meet?
(a) Except as provided in § 59.509,
each aerosol coating product you
manufacture or import for sale or use in
the United States must meet the PWR
limits presented in Table 1 of this
subpart. These limits apply to the final
aerosol coating, including the
propellant. The PWR limits specified in
Table 1 of this subpart are also
applicable to any aerosol coating
product that is assembled by adding
bulk coating to aerosol containers of
propellant.
(b) If a product can be included in
both a general coating category and a
specialty coating category, and the
product meets all of the criteria of the
specialty coating category, then the
specialty coating limit will apply
instead of the general coating limit,
unless the product is a high temperature
coating. High-temperature coatings that
contain at least 0.5 percent by weight of
an elemental metallic pigment in the
formulation, including propellant, are
subject to the limit specified for metallic
coatings.
(c) Except as provided in paragraph
(b) of this section, if anywhere on the
container of any aerosol coating product
subject to the limits in Table 1 of this
subpart, or on any sticker or label
affixed to such product, or in any sales
or advertising literature, the
manufacturer, importer or distributor of
the product makes any representation
that the product may be used as, or is
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suitable for use as a product for which
a lower limit is specified, then the
lowest applicable limit will apply.
§ 59.505 How do I demonstrate compliance
with the reactivity limits?
(a) To demonstrate compliance with
the PWR limits presented in Table 1 of
this subpart, you must calculate the
product weighted reactivity (PWR) for
each coating as described in paragraphs
(a)(1) through (2) of this section:
(1) Calculate the weighted reactivity
factor (WRF) for each propellant and
coating component using Equation 1:
WRFi = RFi × WFi
Equation 1
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Where:
PWRp = Product weighted reactivity for
product P, g O3/g product.
WRF1 = weighted reactivity factor for
component 1, g O3/g component.
WRF2 = weighted reactivity factor for
component 2, g O3/g component.
WRFn = weighted reactivity factor for
component n, g O3/g component.
(b) In calculating the PWR you should
follow the guidelines in paragraphs
(b)(1) through (b)(3) of this section.
(1) Any ingredient which does not
contain carbon is assigned a RF value of
0.
(2) Any aerosol coating solid,
including but not limited to resins,
pigments, fillers, plasticizers, and
extenders is assigned a RF of 0. These
items do not have to be identified
individually in the calculation.
(3) All individual compounds present
in the coating in an amount equal to or
exceeding 0.1 percent will be
considered ingredients regardless of
whether or not the ingredient is
reported to the manufacturer.
(4) Any component that is a VOC but
is not listed in Table 2A, 2B, or 2C of
this subpart is assigned the maximum
RF value for all compounds listed in
Table 2A, 2B, or 2C of this subpart.
(c) You may use either formulation
data (including information for both the
liquid and propellant phases), CARB’s
Method 310 [Determination of Volatile
Organic Compounds (VOC) in
Consumer Products and Reactive
Organic Compounds in Aerosol Coating
Products], or EPA’s Method 311
[Analysis of Hazardous Air Pollutant
Compounds in Paints and Coatings] of
40 CFR part 63 to calculate the Product
Weighed Reactivity. However, if there
are inconsistencies between the
formulation data and the Method 310 or
Method 311 results, the Method 310 or
311 results will govern.
(d) If you manufacture a coating
containing either an aromatic or
aliphatic hydrocarbon solvent mixture,
you may use the appropriate reactivity
factor for that mixture provided in Table
2B or 2C of this subpart when
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(2) Calculate the product weighted
reactivity (PWR) of each product using
Equation 2:
Where:
PWR p = ( WRF)1 + ( WRF) 2 + ... + ( WRF) n
WRFi = Weighted reactivity factor of
component i, g O3/g component i.
RFi = reactivity factor of component i, g O3/
g component i, from Table 2A, 2B, or 2C.
WFi = weight fraction of component i in the
product.
Equation 2
calculating the PWR using formulation
data. However, when calculating the
PWR for a coating containing these
mixtures using data from EPA Method
310 of 40 CFR part 63 or CARB Method
311, you must identify the individual
compounds that are present in the
solvent mixture and use the weight
fraction of those individual compounds
and their reactivity factors from Table
2A of this subpart in the calculation.
(e) If a VOC is not listed in Table 2A,
2B, or 2C of this subpart, the Reactivity
Factor is assumed to be 22.04 g O3/g
VOC. Regulated entities may petition
the Administrator to add a compound to
Table 2A, 2B, or 2C of this subpart.
Petitions should provide adequate data
for the Administrator to evaluate the
reactivity of the compound and assign a
RF value consistent with the values for
the other compounds listed in Table 2
of this subpart.
(f) In calculating the PWR value for a
coating containing an aromatic
hydrocarbon solvent with a boiling
range different from the ranges specified
in Table 2C of this subpart, you must
assign a reactivity factor as described in
paragraphs (f)(1) and (f)(2) of this
section:
(1) If the solvent boiling point is lower
than or equal to 420 degrees F, then you
should use the reactivity factor in Table
2C of this subpart specified for bin 3;
(2) If the solvent boiling point is
higher than 420 degrees F, then you
should use the reactivity factor specified
in Table 2C of this subpart for bin 24.
(g) For purposes of compliance with
the PWR limits, all VOC compounds
must be included in the calculation. The
exemptions from the definition of VOC
in § 59.100(s)(1) are inapplicable for
purposes of this subpart.
(b) You can calculate the Kit Product
Weighted Reactivity and the Total
Reactivity Limit as follows:
(1) KIT PWR = (PWR(1) × W1) +
(PWR(2) × W2)+. ...+(PWR(n) × Wn)
(2) Total Reactivity Limit = (RL1 × W1)
+ (RL2 × W2) +...+ (RLn × Wn).
(3) Kit PWR ≤ Total Reactivity Limit.
§ 59.506 How do I demonstrate compliance
if I manufacture multi-component kits?
§ 59.508
(a) If you manufacture multicomponent kits as defined in § 59.503,
then the Kit Product Weighted
Reactivity must not exceed the Total
Reactivity Limit.
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Where:
W = The weight of the product contents
(excluding container)
RL = the Product Weighted Reactivity Limit
specified in Table 1 of this subpart.
Subscript 1 denotes the first component
product in the kit
Subscript 2 denotes the second component
product in the kit
Subscript n denotes any additional
component product
§ 59.507 What are the labeling
requirements for aerosol coatings?
(a) Aerosol coatings manufactured
after January 1, 2009 must be labeled
with the following information:
(1) The aerosol coating category or
category code shown in Table 1 of this
subpart, as defined in § 59.503;
(2) The applicable PWR limit for the
product specified in Table 1 of this
subpart;
(3) The day, month, and year on
which the product was manufactured,
or a code indicating such date;
(4) The name and a contact address
for the manufacturer, distributor, or
importer that is the regulated entity
under this rule.
(b) The label on the product must be
displayed in such a manner that it is
readily observable without removing or
disassembling any portion of the
product container or packaging. The
information may be displayed on the
bottom of the container as long as it is
clearly legible without removing any
product packaging.
What test methods must I use?
(a) Except as provided in § 59.505(c),
you must use the procedures in CARB’s
Method 310 [Determination of Volatile
Organic Compounds (VOC) in
Consumer Products and Reactive
Organic Compounds in Aerosol Coating
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Products] or EPA’s Method 311
[Analysis of Hazardous Air Pollutant
Compounds in Paints and Coatings] to
determine the speciated ingredients and
weight percentage of each ingredient of
each aerosol coating product. Method
311 should be used in conjunction with
ASTM Method D3063–94 or D3074–94
for analysis of the propellant portion of
the coating. Those choosing to use
Method 310 should follow the
procedures specified in section 5.0 of
that method with the exception of
section 5.3.1, which requires the
analysis of the VOC content of the
coating. For the purposes of this
regulation, you are not required to
determine the VOC content of the
aerosol coating. For both Method 310
and Method 311, you must have a
listing of the VOC ingredients in the
coating before conducting the analysis.
(b) To determine the metal content of
metallic aerosol coating products, you
must use SCAQMD Method 318–95,
‘‘Determination of Weight Percent
Elemental Metal in Coatings by X-ray
Diffraction.’’
(c) To determine the specular gloss of
flat and nonflat coatings you must use
ASTM Method D–523–89 (1999).
(d) To determine the acid content of
rust converters you must use ASTM
Method D–1613–03, ‘‘Standard Test
Method for Acidity in Volatile Solvents
and Chemical Intermediates Used in
Paint, Varnish, Lacquer, and Related
Products.’’
mstockstill on PROD1PC66 with PROPOSALS2
§ 59.509
Can I get a variance?
(a) Any regulated entity that cannot
comply with the requirements of this
subpart because of circumstances
beyond its reasonable control may apply
in writing to the Administrator for a
temporary variance. The variance
application must include the
information specified in paragraphs
(a)(1) through (a)(5) of this section.
(1) The specific products for which
the variance is sought.
(2) The specific provisions of the
subpart for which the variance is
sought.
(3) The specific grounds upon which
the variance is sought.
(4) The proposed date(s) by which the
regulated entity will achieve
compliance with the provisions of this
subpart. This date must be no later than
3 years after the issuance of a variance.
(5) A compliance plan detailing the
method(s) by which the regulated entity
will achieve compliance with the
provisions of this subpart.
(b) Within 30 days of receipt of the
original application and within 30 days
of receipt of any supplementary
information that is submitted, the
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Administrator will send a regulated
entity written notification of whether
the application contains sufficient
information to make a determination. If
an application is incomplete, the
Administrator will specify the
information needed to complete the
application, and provide the
opportunity for the regulated entity to
submit written supplementary
information or arguments to the
Administrator to enable further action
on the application. The regulated entity
must submit this information to the
Administrator within 30 days of being
notified that its application is
incomplete.
(c) Within 60 days of receipt of
sufficient information to evaluate the
application, the Administrator will send
a regulated entity written notification of
approval or disapproval of a variance
application. This 60-day period will
begin after the regulated entity has been
sent written notification that its
application is complete.
(d) The Administrator will issue a
variance if the criteria specified in
paragraphs (d)(1) and (d)(2) of this
section are met to the satisfaction of the
Administrator.
(1) Complying with the provisions of
this subpart would not be
technologically or economically
feasible.
(2) The compliance plan proposed by
the applicant can reasonably be
implemented and will achieve
compliance as expeditiously as possible.
(e) A variance may specify dates by
which the regulated entity will achieve
increments of progress towards
compliance, and will specify a final
compliance date by which the regulated
entity will achieve compliance with this
subpart.
(f) A variance will cease to be
effective upon failure of the party to
whom the variance was issued to
comply with any term or condition of
the variance.
§ 59.510 What records am I required to
maintain?
(a) Beginning January 1, 2009, you are
required to maintain records of the
following at the location specified in
§ 59.511(a)(4) for each product subject to
the PWR limits in Table 1 of this
subpart: The product category, all
product calculations, the Product
Weighted Reactivity, and the weight
fraction of all ingredients including:
Water, solids, each VOC, and any
compounds assigned a reactivity factor
of zero as specified in § 59.505. If an
individual VOC is present in an amount
less than 0.1 percent by weight, then it
does not need to be reported as an
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38977
ingredient. In addition, an impurity that
meets the definition provided in
§ 59.503 does not have to be reported as
an ingredient. For each batch of each
product subject to the PWR limits, you
must maintain records of the date the
batch was manufactured, the volume of
the batch, the recipe used for
formulating the batch, and the number
of cans manufactured in each batch and
each formulation.
(b) A copy of each notification that
you submit to comply with this subpart,
the documentation supporting each
notification, and a copy of the label for
each product.
(c) If you claim the exemption under
§ 59.501(e), a copy of the initial report
and each annual report that you submit
to EPA, and the documentation
supporting such report.
(d) You must maintain all records
required by this subpart for a period of
5 years.
§ 59.511
What reports must I submit?
(a) You must submit an initial
notification report no later than 90 days
before the compliance date or within 90
days before the date that you first
manufacture, distribute, or import
aerosol coatings, whichever is later. The
initial report must include the
information in paragraphs (a)(1) through
(a)(6) of this section.
(1) Company name;
(2) Name, title, number, address,
telephone number, e-mail address, and
signature of certifying company official;
(3) A list of the product categories
from Table 1 of this subpart that you
manufacture, import or distribute;
(4) The street address of each of your
facilities in the United States that is
manufacturing, packaging, or importing
aerosol coatings that are subject to the
provisions of this subpart and the street
address where compliance records are
maintained for each site, if different;
(5) A description of date coding
systems, clearly explaining how the date
of manufacture is marked on each sales
unit;
(6) For each product category, an
explanation of how the manufacturer,
distributor, or importer will define a
batch for the purpose of the
recordkeeping requirements; and
(7) A statement certifying that all
products manufactured by the company
that are subject to the limits in Table 1
of this subpart will be in compliance
with those limits.
(b) If you change any information
included in the initial notification
report, including the list of aerosol
categories, contact information, records
location, or the date coding system
reported according to paragraph (a)(5) of
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this section, you must notify the
Administrator of such changes within
30 days following the change.
(c) Upon 60 days written notice, you
must submit to the Administrator a
written report with all the information
in paragraphs (c)(1) through (c)(5) of this
section for each product you
manufacture, distribute, or import under
your name or another company’s name.
(1) The brand name of the product;
(2) A copy of the product label;
(3) The owner of the trademark or
brand names;
(4) The product category as defined in
§ 59.503;
(5) Product formulation data for each
formulation manufactured including the
PWR and the weight fraction of all
ingredients including: Water, solids,
each VOC present in an amount greater
than or equal to 0.1 percent, and any
compounds assigned a reactivity factor
of zero.
(d) If you claim the exemption under
§ 59.501(e), you must submit an initial
notification report no later than 90 days
before the compliance date or within 90
days before the date that you first
manufacture aerosol coatings,
whichever is later. The initial report
must include the information in
paragraphs (a)(1) through (a)(6) of this
section.
(1) Company name;
(2) Name, title, number, address,
telephone number, e-mail address, and
signature of certifying company official;
(3) A list of the product categories
from Table 1 of this subpart that you
manufacture;
(4) The total amount of product you
manufacture in each category and the
total VOC mass content of such
products for the preceding calendar
year;
(5) The street address of each of your
facilities in the United States that is
manufacturing aerosol coatings that are
subject to the provisions of this subpart
and the street address where
compliance records are maintained for
each site, if different; and
(6) A list of the States in which you
sell or otherwise distribute the products
you manufacture.
After the initial report, you must file
an annual report for each year in which
you claim an exemption from the limits
of this subpart. Such annual report must
be filed by March 1 of the year following
the year in which you manufactured the
products. The annual report shall
include the same information required
in paragraphs (a)(1) through (6) of this
section.
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§ 59.512
offices.
Addresses of EPA regional
All requests (including variance
requests), reports, submittals, and other
communications to the Administrator
pursuant to this regulation shall be
submitted to the Regional Office of the
EPA which serves the State or territory
for the address that is listed on the
aerosol coating product in question.
These areas are indicated in the
following list of EPA Regional Offices.
EPA Region I (Connecticut, Maine,
Massachusetts, New Hampshire, Rhode
Island, Vermont), Director, Office of
Environmental Stewardship, Mailcode:
SAA, JFK Building, Boston, MA 02203.
EPA Region II (New Jersey, New York,
Puerto Rico, Virgin Islands), Director,
Division of Enforcement and
Compliance Assistance, 290 Broadway,
New York, NY 10007–1866.
EPA Region III (Delaware, District of
Columbia, Maryland, Pennsylvania,
Virginia, West Virginia), Air Protection
Division, 1650 Arch Street,
Philadelphia, PA 19103.
EPA Region IV (Alabama, Florida,
Georgia, Kentucky, Mississippi, North
Carolina, South Carolina, Tennessee),
Director, Air, Pesticides and Toxics,
Management Division, 345 Courtland
Street, NE., Atlanta, GA 30365.
EPA Region V (Illinois, Indiana,
Michigan, Minnesota, Ohio, Wisconsin),
Director, Air and Radiation Division, 77
West Jackson Blvd., Chicago, IL 60604–
3507.
EPA Region VI (Arkansas, Louisiana,
New Mexico, Oklahoma, Texas),
Director, Air, Pesticides and Toxics
Division, 1445 Ross Avenue, Dallas, TX
75202–2733.
EPA Region VII (Iowa, Kansas,
Missouri, Nebraska), Director, Air and
Toxics Division, 726 Minnesota Avenue,
Kansas City, KS 66101.
EPA Region VIII (Colorado, Montana,
North Dakota, South Dakota, Utah,
Wyoming), Director, Air and Toxics
Division, 999 18th Street, 1 Denver
Place, Suite 500, Denver, Colorado
80202–2405.
EPA Region IX (American Samoa,
Arizona, California, Guam, Hawaii,
Nevada), Director, Air Division, 75
Hawthorne Street, San Francisco, CA
94105.
EPA Region X (Alaska, Oregon, Idaho,
Washington), Director, Air and Toxics
Division, 1200 Sixth Avenue, Seattle,
WA 98101.
§ 59.513
State authority.
The provisions in this regulation will
not be construed in any manner to
preclude any State or political
subdivision thereof from:
(a) Adopting and enforcing any
emission standard or limitation
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applicable to a manufacturer, distributor
or importer of aerosol coatings or
components in addition to the
requirements of this subpart.
(b) Requiring the manufacturer,
distributor or importer of aerosol
coatings or components to obtain
permits, licenses, or approvals prior to
initiating construction, modification, or
operation of a facility for manufacturing
an aerosol coating or component.
§ 59.514
Circumvention.
Each manufacturer, distributor, and
importer of an aerosol coating or
component subject to the provisions of
this subpart must not alter, destroy, or
falsify any record or report, to conceal
what would otherwise be
noncompliance with this subpart. Such
concealment includes, but is not limited
to, refusing to provide the Administrator
access to all required records and datecoding information, altering the PWR
content of a coating or component
batch, or altering the results of any
required tests to determine the PWR.
§ 59.515
Incorporations by reference.
(a) The following material is
incorporated by reference (IBR) in the
paragraphs noted in § 59.508. These
incorporations by reference were
approved by the Director of the Federal
Register in accordance with 5 U.S.C.
552(a) and 1 CFR part 51. These
materials are incorporated as they exist
on the date of approval, and notice of
any changes in these materials will be
published in the Federal Register.
(1) California Air Resources Board
Method 310, Determination of Volatile
Organic Compounds (VOC) in
Consumer Products and Reactive
Organic Compounds in Aerosol Coating
Products, IBR approved for § 59.508.
(2) South Coast Air Quality
Management District (SCAQMD) Test
Method 318–95, Determination of
Weight Percent Elemental Metal in
Coatings by X-ray Diffraction, IBR
approved for § 59.508.
(3) ASTM Method D–523–89 (1999),
Specular Gloss of Flat and Nonflat
Coatings, IBR approved for § 59.508.
(4) ASTM Method D–1613–03,
Standard Test Method for Acidity in
Volatile Solvents and Chemical
Intermediates Used in Coating, Varnish,
Lacquer and Related Products, IBR
approved for § 59.508.
(5) EPA Method 311—Analysis of
Hazardous Air Pollutant Compounds in
Paints and Coatings by Direct Injection
into a Gas Chromatograph, IBR
approved for § 59.508.
(b) The materials are available for
inspection at the National Archives and
Records Administration (NARA). For
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information on the availability of this
material at NARA, call 202–741–6030,
or go to https://www.archives.gov/
federal_register/
code_of_federal_regulations/
ibr_locations.html; the Air and
Radiation Docket and Information
Center, U.S. EPA, 401 M Street, SW.,
Washington, DC; and at the EPA Library
(Mail Code C267–07), U.S. EPA,
Research Triangle Park, North Carolina.
(c) Reports and Applications. The
content of all reports and applications
required to be submitted to the Agency
under § 59.511, § 59.509 or § 59.502 of
this subpart are not entitled to
protection under section 114(c) of the
Clean Air Act.
§ 59.516 Availability of information and
confidentiality.
(a) Availability of information. The
availability to the public of information
provided to or otherwise obtained by
the Administrator under this part shall
be governed by part 2 of this chapter.
(b) Confidentiality. All confidential
business information entitled to
protection under section 114(c) of the
Clean Air Act that must be submitted or
maintained by each regulated entity
pursuant to this subpart shall be treated
in accordance with 40 CFR part 2,
subpart B.
Tables to Subpart E
TABLE 1 TO SUBPART E OF PART 59.—PRODUCT-WEIGHTED REACTIVITY LIMITS BY COATING CATEGORY
(g Ozone/g product)
Coating category
Category
code
Clear Coatings ...............................................................................................................................................................
Flat Coatings ..................................................................................................................................................................
Fluorescent Coatings .....................................................................................................................................................
Metallic Coatings ...........................................................................................................................................................
Non-Flat Coatings ..........................................................................................................................................................
Primers ...........................................................................................................................................................................
Ground Traffic/Marking ..................................................................................................................................................
Art Fixatives or Sealants ...............................................................................................................................................
Auto body primers .........................................................................................................................................................
Automotive Bumper and Trim Products ........................................................................................................................
Aviation or Marine Primers ............................................................................................................................................
Aviation Propellor Coatings ...........................................................................................................................................
Corrosion Resistant Brass, Bronze, or Copper Coatings .............................................................................................
Exact Match Finish—Engine Enamel ............................................................................................................................
Exact Match Finish—Automotive ...................................................................................................................................
Exact Match Finish—Industrial ......................................................................................................................................
Floral Sprays ..................................................................................................................................................................
Glass Coatings ..............................................................................................................................................................
High Temperature Coatings ..........................................................................................................................................
Hobby/Model/Craft Coatings, Enamel ...........................................................................................................................
Hobby/Model/Craft Coatings, Lacquer ..........................................................................................................................
Hobby/Model/Craft Coatings, Clear or Metallic .............................................................................................................
Marine Spar Varnishes ..................................................................................................................................................
Photograph Coatings .....................................................................................................................................................
Pleasure Craft Primers, Surfacers or Undercoaters .....................................................................................................
Pleasure Craft Topcoats ................................................................................................................................................
Polyolefin Adhesion Promoters .....................................................................................................................................
Shellac Sealers, Clear ...................................................................................................................................................
Shellac Sealers, Pigmented ..........................................................................................................................................
Slip-Resistant Coatings .................................................................................................................................................
Spatter/Multicolor Coatings ............................................................................................................................................
Vinyl/Fabric/Leather/Polycarbonate Coatings ................................................................................................................
Webbing/Veiling Coatings ..............................................................................................................................................
Weld-Through Primers ...................................................................................................................................................
Wood Stains ..................................................................................................................................................................
Wood Touch-up/Repair or Restoration Coatings ..........................................................................................................
CCP .........
FCP .........
FLP ..........
MCP .........
NFP .........
PCP .........
GTM .........
AFS ..........
ABP .........
ABT ..........
AMP .........
APC .........
CRB .........
EEE .........
EFA ..........
EFI ...........
FSP ..........
GCP .........
HTC .........
HME .........
HML .........
HMC ........
MSV .........
PHC .........
PCS .........
PCT .........
PAP .........
SSC .........
SSP .........
SRC .........
SMC .........
VFL ..........
WFC ........
WTP .........
WSP ........
WTR ........
Reactivity
limit
1.50
1.20
1.75
1.90
1.40
1.20
1.20
1.80
1.55
1.75
2.00
2.50
1.80
1.70
1.50
2.05
1.70
1.40
1.85
1.45
2.70
1.60
0.90
1.00
1.05
0.60
2.50
1.00
0.95
2.45
1.05
1.55
0.85
1.00
1.40
1.50
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
Carbon Monoxide ................................................................................................................................................................................
Methane ...............................................................................................................................................................................................
Ethane ..................................................................................................................................................................................................
Propane ...............................................................................................................................................................................................
n-Butane ..............................................................................................................................................................................................
n-Pentane ............................................................................................................................................................................................
n-Hexane .............................................................................................................................................................................................
n-Heptane ............................................................................................................................................................................................
n-Octane ..............................................................................................................................................................................................
n-Nonane .............................................................................................................................................................................................
n-Decane .............................................................................................................................................................................................
n-Undecane .........................................................................................................................................................................................
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0.06
0.01
0.31
0.56
1.33
1.54
1.45
1.28
1.11
0.95
0.83
0.74
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TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
n-Dodecane .........................................................................................................................................................................................
n-Tridecane ..........................................................................................................................................................................................
n-Tetradecane ......................................................................................................................................................................................
n-Pentadecane .....................................................................................................................................................................................
n-C16 ...................................................................................................................................................................................................
n-C17 ...................................................................................................................................................................................................
n-C18 ...................................................................................................................................................................................................
n-C19 ...................................................................................................................................................................................................
n-C20 ...................................................................................................................................................................................................
n-C21 ...................................................................................................................................................................................................
n-C22 ...................................................................................................................................................................................................
Isobutane .............................................................................................................................................................................................
Isopentane ...........................................................................................................................................................................................
Neopentane .........................................................................................................................................................................................
Branched C5 Alkanes ..........................................................................................................................................................................
2,2-Dimethyl Butane ............................................................................................................................................................................
2,3-Dimethyl Butane ............................................................................................................................................................................
2-Methyl Pentane (Isohexane) ............................................................................................................................................................
3-Methyl Pentane .................................................................................................................................................................................
Branched C6 Alkanes ..........................................................................................................................................................................
2,2,3-Trimethyl Butane ........................................................................................................................................................................
2,2-Dimethyl Pentane ..........................................................................................................................................................................
2,3-Dimethyl Pentane ..........................................................................................................................................................................
2,4-Dimethyl Pentane ..........................................................................................................................................................................
2-Methyl Hexane ..................................................................................................................................................................................
3,3-Dimethyl Pentane ..........................................................................................................................................................................
3-Methyl Hexane ..................................................................................................................................................................................
Branched C7 Alkanes ..........................................................................................................................................................................
2,2,3,3-Tetramethyl Butane .................................................................................................................................................................
2,2,4-Trimethyl Pentane (Isooctane) ...................................................................................................................................................
2,2-Dimethyl Hexane ...........................................................................................................................................................................
2,3,4-Trimethyl Pentane ......................................................................................................................................................................
2,3-Dimethyl Hexane ...........................................................................................................................................................................
2,4-Dimethyl Hexane ...........................................................................................................................................................................
2,5-Dimethyl Hexane ...........................................................................................................................................................................
2-Methyl Heptane ................................................................................................................................................................................
3-Methyl Heptane ................................................................................................................................................................................
4-Methyl Heptane ................................................................................................................................................................................
Branched C8 Alkanes ..........................................................................................................................................................................
2,2,5-Trimethyl Hexane .......................................................................................................................................................................
2,3,5-Trimethyl Hexane .......................................................................................................................................................................
2,4-Dimethyl Heptane ..........................................................................................................................................................................
2-Methyl Octane ..................................................................................................................................................................................
3,3-Diethyl Pentane .............................................................................................................................................................................
3,5-Dimethyl Heptane ..........................................................................................................................................................................
4-Ethyl Heptane ...................................................................................................................................................................................
4-Methyl Octane ..................................................................................................................................................................................
Branched C9 Alkanes ..........................................................................................................................................................................
2,4-Dimethyl Octane ............................................................................................................................................................................
2,6-Dimethyl Octane ............................................................................................................................................................................
2-Methyl Nonane .................................................................................................................................................................................
3,4-Diethyl Hexane ..............................................................................................................................................................................
3-Methyl Nonane .................................................................................................................................................................................
4-Methyl Nonane .................................................................................................................................................................................
4-Propyl Heptane .................................................................................................................................................................................
Branched C10 Alkanes ........................................................................................................................................................................
2,6-Dimethyl Nonane ...........................................................................................................................................................................
3,5-Diethyl Heptane .............................................................................................................................................................................
3-Methyl Decane ..................................................................................................................................................................................
4-Methyl Decane ..................................................................................................................................................................................
Branched C11 Alkanes ........................................................................................................................................................................
2,3,4,6-Tetramethyl Heptane ...............................................................................................................................................................
2,6-Diethyl Octane ...............................................................................................................................................................................
3,6-Dimethyl Decane ...........................................................................................................................................................................
3-Methyl Undecane ..............................................................................................................................................................................
5-Methyl Undecane ..............................................................................................................................................................................
Branched C12 Alkanes ........................................................................................................................................................................
2,3,5,7-Tetramethyl Octane .................................................................................................................................................................
3,6-Dimethyl Undecane .......................................................................................................................................................................
3,7-Diethyl Nonane ..............................................................................................................................................................................
3-Methyl Dodecane ..............................................................................................................................................................................
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16JYP2
0.66
0.62
0.58
0.56
0.52
0.49
0.47
0.44
0.42
0.40
0.38
1.35
1.68
0.69
1.68
1.33
1.14
1.80
2.07
1.53
1.32
1.22
1.55
1.65
1.37
1.32
1.86
1.63
0.44
1.44
1.13
1.23
1.34
1.80
1.68
1.20
1.35
1.48
1.57
1.33
1.33
1.48
0.96
1.35
1.63
1.44
1.08
1.25
1.09
1.27
0.86
1.20
0.89
0.99
1.24
1.09
0.95
1.21
0.77
0.80
0.87
1.26
1.09
0.88
0.70
0.72
0.80
1.06
0.82
1.08
0.64
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
38981
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
5-Methyl Dodecane ..............................................................................................................................................................................
Branched C13 Alkanes ........................................................................................................................................................................
2,4,6,8-Tetramethyl Nonane ................................................................................................................................................................
2,3,6-Trimethyl 4-Isopropyl Heptane ...................................................................................................................................................
3,7-Dimethyl Dodecane .......................................................................................................................................................................
3,8-Diethyl Decane ..............................................................................................................................................................................
3-Methyl Tridecane ..............................................................................................................................................................................
6-Methyl Tridecane ..............................................................................................................................................................................
Branched C14 Alkanes ........................................................................................................................................................................
2,4,5,6,8-Pentamethyl Nonane ............................................................................................................................................................
2-Methyl 3,5-Diisopropyl Heptane .......................................................................................................................................................
3,7-Dimethyl Tridecane ........................................................................................................................................................................
3,9-Diethyl Undecane ..........................................................................................................................................................................
3-Methyl Tetradecane ..........................................................................................................................................................................
6-Methyl Tetradecane ..........................................................................................................................................................................
Branched C15 Alkanes ........................................................................................................................................................................
2,6,8-Trimethyl 4-Isopropyl Nonane ....................................................................................................................................................
3-Methyl Pentadecane .........................................................................................................................................................................
4,8-Dimethyl Tetradecane ...................................................................................................................................................................
7-Methyl Pentadecane .........................................................................................................................................................................
Branched C16 Alkanes ........................................................................................................................................................................
2,7-Dimethyl 3,5-Diisopropyl Heptane .................................................................................................................................................
Branched C17 Alkanes ........................................................................................................................................................................
Branched C18 Alkanes ........................................................................................................................................................................
Cyclopropane .......................................................................................................................................................................................
Cyclobutane .........................................................................................................................................................................................
Cyclopentane .......................................................................................................................................................................................
Cyclohexane ........................................................................................................................................................................................
Isopropyl Cyclopropane .......................................................................................................................................................................
Methylcyclopentane .............................................................................................................................................................................
C6 Cycloalkanes ..................................................................................................................................................................................
1,3-Dimethyl Cyclopentane ..................................................................................................................................................................
Cycloheptane .......................................................................................................................................................................................
Ethyl Cyclopentane ..............................................................................................................................................................................
Methylcyclohexane ..............................................................................................................................................................................
C7 Cycloalkanes ..................................................................................................................................................................................
C8 Bicycloalkanes ...............................................................................................................................................................................
1,3-Dimethyl Cyclohexane ...................................................................................................................................................................
Cyclooctane .........................................................................................................................................................................................
Ethylcyclohexane .................................................................................................................................................................................
Propyl Cyclopentane ............................................................................................................................................................................
C8 Cycloalkanes ..................................................................................................................................................................................
C9 Bicycloalkanes ...............................................................................................................................................................................
1,1,3-Trimethyl Cyclohexane ...............................................................................................................................................................
1-Ethyl-4-Methyl Cyclohexane .............................................................................................................................................................
Propyl Cyclohexane .............................................................................................................................................................................
C9 Cycloalkanes ..................................................................................................................................................................................
C10 Bicycloalkanes .............................................................................................................................................................................
1,3-Diethyl Cyclohexane ......................................................................................................................................................................
1,4-Diethyl Cyclohexane ......................................................................................................................................................................
1-Methyl-3-Isopropyl Cyclohexane ......................................................................................................................................................
Butyl Cyclohexane ...............................................................................................................................................................................
C10 Cycloalkanes ................................................................................................................................................................................
C11 Bicycloalkanes .............................................................................................................................................................................
1,3-Diethyl-5-Methyl Cyclohexane .......................................................................................................................................................
1-Ethyl-2-Propyl Cyclohexane .............................................................................................................................................................
Pentyl Cyclohexane .............................................................................................................................................................................
C11 Cycloalkanes ................................................................................................................................................................................
C12 Bicycloalkanes .............................................................................................................................................................................
C12 Cycloalkanes ................................................................................................................................................................................
1,3,5-Triethyl Cyclohexane ..................................................................................................................................................................
1-Methyl-4-Pentyl Cyclohexane ...........................................................................................................................................................
Hexyl Cyclohexane ..............................................................................................................................................................................
C13 Bicycloalkanes .............................................................................................................................................................................
1,3-Diethyl-5-Propyl Cyclohexane .......................................................................................................................................................
1-Methyl-2-Hexyl Cyclohexane ............................................................................................................................................................
Heptyl Cyclohexane .............................................................................................................................................................................
C13 Cycloalkanes ................................................................................................................................................................................
C14 Bicycloalkanes .............................................................................................................................................................................
1,3-Dipropyl-5-Ethyl Cyclohexane .......................................................................................................................................................
1-Methyl-4-Heptyl Cyclohexane ...........................................................................................................................................................
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16JYP2
0.64
0.73
0.94
1.24
0.74
0.68
0.57
0.62
0.67
1.11
0.78
0.64
0.62
0.53
0.57
0.60
0.76
0.50
0.58
0.51
0.54
0.69
0.51
0.48
0.10
1.05
2.69
1.46
1.52
2.42
1.46
2.15
2.26
2.27
1.99
1.99
1.75
1.72
1.73
1.75
1.91
1.75
1.57
1.37
1.62
1.47
1.55
1.29
1.34
1.49
1.26
1.07
1.27
1.01
1.11
0.95
0.91
0.99
0.88
0.87
1.06
0.81
0.75
0.79
0.96
0.70
0.66
0.78
0.71
0.94
0.58
38982
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
Octyl Cyclohexane ...............................................................................................................................................................................
C14 Cycloalkanes ................................................................................................................................................................................
C15 Bicycloalkanes .............................................................................................................................................................................
1,3,5-Tripropyl Cyclohexane ................................................................................................................................................................
1-Methyl-2-Octyl Cyclohexane .............................................................................................................................................................
Nonyl Cyclohexane ..............................................................................................................................................................................
C15 Cycloalkanes ................................................................................................................................................................................
1,3-Dipropyl-5-Butyl Cyclohexane .......................................................................................................................................................
1-Methyl-4-Nonyl Cyclohexane ............................................................................................................................................................
Decyl Cyclohexane ..............................................................................................................................................................................
C16 Cycloalkanes ................................................................................................................................................................................
Ethene ..................................................................................................................................................................................................
Propene (Propylene) ............................................................................................................................................................................
1-Butene ..............................................................................................................................................................................................
C4 Terminal Alkenes ...........................................................................................................................................................................
1-Pentene ............................................................................................................................................................................................
3-Methyl-1-Butene ...............................................................................................................................................................................
C5 Terminal Alkenes ...........................................................................................................................................................................
1-Hexene .............................................................................................................................................................................................
3,3-Dimethyl-1-Butene .........................................................................................................................................................................
3-Methyl-1-Pentene .............................................................................................................................................................................
4-Methyl-1-Pentene .............................................................................................................................................................................
C6 Terminal Alkenes ...........................................................................................................................................................................
1-Heptene ............................................................................................................................................................................................
1-Octene ..............................................................................................................................................................................................
C8 Terminal Alkenes ...........................................................................................................................................................................
1-Nonene .............................................................................................................................................................................................
C9 Terminal Alkenes ...........................................................................................................................................................................
1-Decene .............................................................................................................................................................................................
C10 Terminal Alkenes .........................................................................................................................................................................
1-Undecene .........................................................................................................................................................................................
C11 Terminal Alkenes .........................................................................................................................................................................
C12 Terminal Alkenes .........................................................................................................................................................................
1-Dodecene .........................................................................................................................................................................................
1-Tridecene ..........................................................................................................................................................................................
C13 Terminal Alkenes .........................................................................................................................................................................
1-Tetradecene ......................................................................................................................................................................................
C14 Terminal Alkenes .........................................................................................................................................................................
1-Pentadecene .....................................................................................................................................................................................
C15 Terminal Alkenes .........................................................................................................................................................................
2-Methyl Pentene (Isobutene) .............................................................................................................................................................
2-Methyl-1-Butene ...............................................................................................................................................................................
2,3-Dimethyl-1-Butene .........................................................................................................................................................................
2-Ethyl-1-Butene ..................................................................................................................................................................................
2-Methyl-1-Pentene .............................................................................................................................................................................
2,3,3-Trimethyl-1-Butene .....................................................................................................................................................................
C7 Terminal Alkenes ...........................................................................................................................................................................
3-Methyl-2-Isopropyl-1-Butene ............................................................................................................................................................
cis-2-Butene .........................................................................................................................................................................................
trans-2-Butene .....................................................................................................................................................................................
C4 Internal Alkenes .............................................................................................................................................................................
2-Methyl-2-Butene ...............................................................................................................................................................................
cis-2-Pentene .......................................................................................................................................................................................
trans-2-Pentene ...................................................................................................................................................................................
2-Pentenes ...........................................................................................................................................................................................
C5 Internal Alkenes .............................................................................................................................................................................
2,3-Dimethyl-2-Butene .........................................................................................................................................................................
2-Methyl-2-Pentene .............................................................................................................................................................................
cis-2-Hexene ........................................................................................................................................................................................
cis-3-Hexene ........................................................................................................................................................................................
cis-3-Methyl-2-Pentene ........................................................................................................................................................................
cis-3-Methyl-2-Hexene .........................................................................................................................................................................
trans 3-Methyl-2-Hexene .....................................................................................................................................................................
trans 4-Methyl-2-Hexene .....................................................................................................................................................................
trans-2-Hexene ....................................................................................................................................................................................
trans-3-Hexene ....................................................................................................................................................................................
2-Hexenes ............................................................................................................................................................................................
C6 Internal Alkenes .............................................................................................................................................................................
2,3-Dimethyl-2-Hexene ........................................................................................................................................................................
cis-3-Heptene .......................................................................................................................................................................................
trans-4,4-Dimethyl-2-Pentene ..............................................................................................................................................................
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16JYP2
0.60
0.71
0.69
0.90
0.60
0.54
0.68
0.77
0.55
0.50
0.61
9.08
11.58
10.29
10.29
7.79
6.99
7.79
6.17
6.06
6.22
6.26
6.17
4.56
3.45
3.45
2.76
2.76
2.28
2.28
1.95
1.95
1.72
1.72
1.55
1.55
1.41
1.41
1.37
1.37
6.35
6.51
4.77
5.04
5.18
4.62
4.56
3.29
13.22
13.91
13.57
14.45
10.24
10.23
10.23
10.23
13.32
12.28
8.44
8.22
12.84
13.38
14.17
7.88
8.44
8.16
8.44
8.44
10.41
6.96
6.99
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
38983
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
trans-2-Heptene ...................................................................................................................................................................................
trans-3-Heptene ...................................................................................................................................................................................
2-Heptenes ..........................................................................................................................................................................................
C7 Internal Alkenes .............................................................................................................................................................................
cis-4-Octene .........................................................................................................................................................................................
trans-2,2-Dimethyl-3-Hexene ...............................................................................................................................................................
trans-2,5-Dimethyl-3-Hexene ...............................................................................................................................................................
trans-3-Octene .....................................................................................................................................................................................
trans-4-Octene .....................................................................................................................................................................................
3-Octenes ............................................................................................................................................................................................
C8 Internal Alkenes .............................................................................................................................................................................
2,4,4-Trimethyl-2-Pentene ...................................................................................................................................................................
3-Nonenes ...........................................................................................................................................................................................
C9 Internal Alkenes .............................................................................................................................................................................
trans-4-Nonene ....................................................................................................................................................................................
3,4-Diethyl-2-Hexene ...........................................................................................................................................................................
cis-5-Decene ........................................................................................................................................................................................
trans-4-Decene ....................................................................................................................................................................................
C10 3-Alkenes .....................................................................................................................................................................................
C10 Internal Alkenes ...........................................................................................................................................................................
trans-5-Undecene ................................................................................................................................................................................
C11 3-Alkenes .....................................................................................................................................................................................
C11 Internal Alkenes ...........................................................................................................................................................................
C12 2-Alkenes .....................................................................................................................................................................................
C12 3-Alkenes .....................................................................................................................................................................................
C12 Internal Alkenes ...........................................................................................................................................................................
trans-5-Dodecene ................................................................................................................................................................................
trans-5-Tridecene .................................................................................................................................................................................
C13 3-Alkenes .....................................................................................................................................................................................
C13 Internal Alkenes ...........................................................................................................................................................................
trans-5-Tetradecene ............................................................................................................................................................................
C14 3-Alkenes .....................................................................................................................................................................................
C14 Internal Alkenes ...........................................................................................................................................................................
trans-5-Pentadecene ...........................................................................................................................................................................
C15 3-Alkenes .....................................................................................................................................................................................
C15 Internal Alkenes ...........................................................................................................................................................................
C4 Alkenes ..........................................................................................................................................................................................
C5 Alkenes ..........................................................................................................................................................................................
C6 Alkenes ..........................................................................................................................................................................................
C7 Alkenes ..........................................................................................................................................................................................
C8 Alkenes ..........................................................................................................................................................................................
C9 Alkenes ..........................................................................................................................................................................................
C10 Alkenes ........................................................................................................................................................................................
C11 Alkenes ........................................................................................................................................................................................
C12 Alkenes ........................................................................................................................................................................................
C13 Alkenes ........................................................................................................................................................................................
C14 Alkenes ........................................................................................................................................................................................
C15 Alkenes ........................................................................................................................................................................................
Cyclopentene .......................................................................................................................................................................................
1-Methyl Cyclopentene ........................................................................................................................................................................
Cyclohexene ........................................................................................................................................................................................
1-Methyl Cyclohexene .........................................................................................................................................................................
4-Methyl Cyclohexene .........................................................................................................................................................................
1,2-Dimethyl Cyclohexene ...................................................................................................................................................................
1,3-Butadiene .......................................................................................................................................................................................
Isoprene ...............................................................................................................................................................................................
C6 Cyclic or Di-olefins .........................................................................................................................................................................
C7 Cyclic or Di-olefins .........................................................................................................................................................................
C8 Cyclic or Di-olefins .........................................................................................................................................................................
C9 Cyclic or Di-olefins .........................................................................................................................................................................
C10 Cyclic or Di-olefins .......................................................................................................................................................................
C11 Cyclic or Di-olefins .......................................................................................................................................................................
C12 Cyclic or Di-olefins .......................................................................................................................................................................
C13 Cyclic or Di-olefins .......................................................................................................................................................................
C14 Cyclic or Di-olefins .......................................................................................................................................................................
C15 Cyclic or Di-olefins .......................................................................................................................................................................
Cyclopentadiene ..................................................................................................................................................................................
3-Carene ..............................................................................................................................................................................................
a-Pinene (Pine Oil) ..............................................................................................................................................................................
b-Pinene ...............................................................................................................................................................................................
d-Limonene (Dipentene or Orange Terpene) ......................................................................................................................................
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16JYP2
7.33
6.96
6.96
6.96
5.94
5.97
5.44
6.13
5.90
6.13
5.90
5.85
5.31
5.31
5.23
3.95
4.89
4.50
4.50
4.50
4.23
4.23
4.23
3.75
3.75
3.75
3.74
3.38
3.38
3.38
3.08
3.08
3.08
2.82
2.82
2.82
11.93
9.01
6.88
5.76
4.68
4.03
3.39
3.09
2.73
2.46
2.28
2.06
7.38
13.95
5.45
7.81
4.48
6.77
13.58
10.69
8.65
7.49
6.01
5.40
4.56
4.29
3.79
3.42
3.11
2.85
7.61
3.21
4.29
3.28
3.99
38984
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
Sabinene ..............................................................................................................................................................................................
Terpene ................................................................................................................................................................................................
Styrene .................................................................................................................................................................................................
a-Methyl Styrene ..................................................................................................................................................................................
C9 Styrenes .........................................................................................................................................................................................
C10 Styrenes .......................................................................................................................................................................................
Benzene ...............................................................................................................................................................................................
Toluene ................................................................................................................................................................................................
Ethyl Benzene ......................................................................................................................................................................................
Cumene (Isopropyl Benzene) ..............................................................................................................................................................
n-Propyl Benzene ................................................................................................................................................................................
C9 Monosubstituted Benzenes ............................................................................................................................................................
s-Butyl Benzene ...................................................................................................................................................................................
C10 Monosubstituted Benzenes ..........................................................................................................................................................
n-Butyl Benzene ..................................................................................................................................................................................
C11 Monosubstituted Benzenes ..........................................................................................................................................................
C12 Monosubstituted Benzenes ..........................................................................................................................................................
C13 Monosubstituted Benzenes ..........................................................................................................................................................
m-Xylene ..............................................................................................................................................................................................
o-Xylene ...............................................................................................................................................................................................
p-Xylene ...............................................................................................................................................................................................
C8 Disubstituted Benzenes .................................................................................................................................................................
m-Ethyl Toluene ...................................................................................................................................................................................
p-Ethyl Toluene ....................................................................................................................................................................................
o-Ethyl Toluene ....................................................................................................................................................................................
C9 Disubstituted Benzenes .................................................................................................................................................................
o-Diethyl Benzene ...............................................................................................................................................................................
m-Diethyl Benzene ..............................................................................................................................................................................
p-Diethyl Benzene ...............................................................................................................................................................................
C10 Disubstituted Benzenes ...............................................................................................................................................................
C11 Disubstituted Benzenes ...............................................................................................................................................................
C12 Disubstituted Benzenes ...............................................................................................................................................................
C13 Disubstituted Benzenes ...............................................................................................................................................................
Isomers of Ethylbenzene .....................................................................................................................................................................
1,2,3-Trimethyl Benzene ......................................................................................................................................................................
1,2,4-Trimethyl Benzene ......................................................................................................................................................................
1,3,5-Trimethyl Benzene ......................................................................................................................................................................
C9 Trisubstituted Benzenes ................................................................................................................................................................
Isomers of Propylbenzene ...................................................................................................................................................................
1,2,3,5-Tetramethyl Benzene ..............................................................................................................................................................
C10 Tetrasubstituted Benzenes ..........................................................................................................................................................
C10 Trisubstituted Benzenes ..............................................................................................................................................................
Isomers of Butylbenzene .....................................................................................................................................................................
C11 Pentasubstituted Benzenes .........................................................................................................................................................
C11 Tetrasubstituted Benzenes ..........................................................................................................................................................
C11 Trisubstituted Benzenes ..............................................................................................................................................................
Isomers of Pentylbenzene ...................................................................................................................................................................
C12 Pentasubstituted Benzenes .........................................................................................................................................................
C12 Hexasubstituted Benzenes ..........................................................................................................................................................
C12 Tetrasubstituted Benzenes ..........................................................................................................................................................
C12 Trisubstituted Benzenes ..............................................................................................................................................................
Isomers of Hexylbenzene ....................................................................................................................................................................
C13 Trisubstituted Benzenes ..............................................................................................................................................................
Indene ..................................................................................................................................................................................................
Indane ..................................................................................................................................................................................................
Naphthalene .........................................................................................................................................................................................
Tetralin .................................................................................................................................................................................................
Methyl Indans ......................................................................................................................................................................................
Methyl Naphthalenes ...........................................................................................................................................................................
1-Methyl Naphthalene ..........................................................................................................................................................................
2-Methyl Naphthalene ..........................................................................................................................................................................
C11 Tetralin or Indane .........................................................................................................................................................................
2,3-Dimethyl Naphthalene ...................................................................................................................................................................
C12 Disubstituted Naphthalenes .........................................................................................................................................................
Dimethyl Naphthalenes ........................................................................................................................................................................
C12 Monosubstituted Naphthalenes ...................................................................................................................................................
C12 Tetralin or Indane .........................................................................................................................................................................
C13 Disubstituted Naphthalenes .........................................................................................................................................................
C13 Trisubstituted Naphthalenes ........................................................................................................................................................
C13 Monosubstituted Naphthalenes ...................................................................................................................................................
Acetylene .............................................................................................................................................................................................
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16JYP2
3.67
3.79
1.95
1.72
1.72
1.53
0.81
3.97
2.79
2.32
2.20
2.20
1.97
1.97
1.97
1.78
1.63
1.50
10.61
7.49
4.25
7.48
9.37
3.75
6.61
6.61
5.92
8.39
3.36
5.92
5.35
4.90
4.50
5.16
11.26
7.18
11.22
9.90
6.12
8.25
8.86
8.86
5.48
8.03
8.03
8.03
4.96
7.33
7.33
7.33
7.33
4.53
6.75
3.21
3.17
3.26
2.83
2.83
4.61
4.61
4.61
2.56
5.54
5.54
5.54
4.20
2.33
5.08
5.08
3.86
1.25
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
38985
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
Methyl Acetylene .................................................................................................................................................................................
2-Butyne ...............................................................................................................................................................................................
Ethyl Acetylene ....................................................................................................................................................................................
Methanol ..............................................................................................................................................................................................
Ethanol .................................................................................................................................................................................................
Isopropanol (2-Propanol or Isopropyl Alcohol) ....................................................................................................................................
n-Propanol (n-Propyl Alcohol) .............................................................................................................................................................
Isobutanol (Isobutyl Alcohol) ...............................................................................................................................................................
1-Butanol (n-Butyl Alcohol) ..................................................................................................................................................................
2-Butanol (s-Butyl Alcohol) ..................................................................................................................................................................
t-Butyl Alcohol ......................................................................................................................................................................................
Cyclopentanol ......................................................................................................................................................................................
2-Pentanol ............................................................................................................................................................................................
3-Pentanol ............................................................................................................................................................................................
n-Pentanol (Amyl Alcohol) ...................................................................................................................................................................
Isoamyl Alcohol (3-Methyl-1-Butanol) ..................................................................................................................................................
2-Methyl-1-Butanol ...............................................................................................................................................................................
Cyclohexanol .......................................................................................................................................................................................
1-Hexanol .............................................................................................................................................................................................
2-Hexanol .............................................................................................................................................................................................
4-Methyl-2-Pentanol (Methyl Isobutyl Carbinol) ..................................................................................................................................
1-Heptanol ...........................................................................................................................................................................................
Dimethylpentanol (2,3-Dimethyl-1-Pentanol) .......................................................................................................................................
1-Octanol .............................................................................................................................................................................................
2-Ethyl-1-Hexanol (Ethyl Hexyl Alcohol) .............................................................................................................................................
2-Octanol .............................................................................................................................................................................................
3-Octanol .............................................................................................................................................................................................
4-Octanol .............................................................................................................................................................................................
5-Methyl-1-Heptanol ............................................................................................................................................................................
Trimethylcyclohexanol .........................................................................................................................................................................
Dimethylheptanol (2,6-Dimethyl-2-Heptanol) .......................................................................................................................................
2,6-Dimethyl-4-Heptanol ......................................................................................................................................................................
Menthol ................................................................................................................................................................................................
Isodecyl Alcohol (8-Methyl-1-Nonanol) ................................................................................................................................................
1-Decanol .............................................................................................................................................................................................
3,7-Dimethyl-1-Octanol ........................................................................................................................................................................
Trimethylnonanolthreoerythro; 2,6,8-Trimethyl-4Nonanol ...................................................................................................................
Ethylene Glycol ....................................................................................................................................................................................
Propylene Glycol ..................................................................................................................................................................................
1,2-Butanediol ......................................................................................................................................................................................
Glycerol (1,2,3-Propanetriol) ................................................................................................................................................................
1,4-Butanediol ......................................................................................................................................................................................
Pentaerythritol ......................................................................................................................................................................................
1,2-Dihydroxy Hexane .........................................................................................................................................................................
2-Methyl-2,4-Pentanediol .....................................................................................................................................................................
2-Ethyl-1,3-Hexanediol ........................................................................................................................................................................
Dimethyl Ether .....................................................................................................................................................................................
Trimethylene Oxide ..............................................................................................................................................................................
1,3-Dioxolane .......................................................................................................................................................................................
Dimethoxymethane ..............................................................................................................................................................................
Tetrahydrofuran ...................................................................................................................................................................................
Diethyl Ether ........................................................................................................................................................................................
1,4-Dioxane ..........................................................................................................................................................................................
Alpha-Methyltetrahydrofuran ................................................................................................................................................................
Tetrahydropyran ...................................................................................................................................................................................
Ethyl Isopropyl Ether ...........................................................................................................................................................................
Methyl n-Butyl Ether ............................................................................................................................................................................
Methyl t-Butyl Ether .............................................................................................................................................................................
2,2-Dimethoxypropane .........................................................................................................................................................................
Di n-Propyl Ether .................................................................................................................................................................................
Ethyl n-Butyl Ether ...............................................................................................................................................................................
Ethyl t-Butyl Ether ................................................................................................................................................................................
Methyl t-Amyl Ether .............................................................................................................................................................................
Di-isopropyl Ether ................................................................................................................................................................................
Ethylene Glycol Diethyl Ether; 1,2Diethoxyethane ..............................................................................................................................
Acetal (1,1-Diethoxyethane) ................................................................................................................................................................
4,4-Dimethyl-3-Oxahexane ..................................................................................................................................................................
2-Butyl Tetrahydrofuran .......................................................................................................................................................................
Di-Isobutyl Ether ..................................................................................................................................................................................
Di-n-butyl Ether ....................................................................................................................................................................................
2-Methoxy-1-(2-Methoxy-1-Methylethoxy)Propane .............................................................................................................................
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16JYP2
6.45
16.33
6.20
0.71
1.69
0.71
2.74
2.24
3.34
1.60
0.45
1.96
1.74
1.73
3.35
2.73
2.60
2.25
2.74
2.46
2.89
2.21
2.51
2.01
2.20
2.16
2.57
3.07
1.95
2.17
1.07
2.37
1.70
1.23
1.22
1.42
1.55
3.36
2.75
2.21
3.27
3.22
2.42
2.75
1.04
2.62
0.93
5.22
5.47
1.04
4.95
4.01
2.71
4.62
3.81
3.86
3.66
0.78
0.52
3.24
3.86
2.11
2.14
3.56
2.84
3.68
2.03
2.53
1.29
3.17
2.09
38986
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
Di-n-Pentyl Ether .................................................................................................................................................................................
Ethylene Glycol Monomethyl Ether (2Methoxyethanol) ......................................................................................................................
Propylene Glycol Monomethyl Ether (1-Methoxy2-Propanol) .............................................................................................................
2-Ethoxyethanol ...................................................................................................................................................................................
2-Methoxy-1-Propanol .........................................................................................................................................................................
3-Methoxy-1-Propanol .........................................................................................................................................................................
Diethylene Glycol .................................................................................................................................................................................
Tetrahydro-2-Furanmethanol ...............................................................................................................................................................
Propylene Glycol Monoethyl Ether (1-Ethoxy-2Propanol) ...................................................................................................................
Ethylene Glycol Monopropyl Ether (2Propoxyethanol) .......................................................................................................................
3-Ethoxy-1-Propanol ............................................................................................................................................................................
3-Methoxy-1-Butanol ............................................................................................................................................................................
Diethylene Glycol Methyl Ether [2-(2Methoxyethoxy) Ethanol] ...........................................................................................................
Propylene Glycol Monopropyl Ether (1-Propoxy2-Propanol) ..............................................................................................................
Ethylene Glycol Monobutyl Ether [2Butoxyethanol] ............................................................................................................................
3-Methoxy-3-Methyl-Butanol ................................................................................................................................................................
n-Propoxypropanol ...............................................................................................................................................................................
2-(2-Ethoxyethoxy) Ethanol .................................................................................................................................................................
Dipropylene Glycol ...............................................................................................................................................................................
Triethylene Glycol ................................................................................................................................................................................
Propylene Glycol t-Butyl Ether (1-tert-Butoxy-2Propanol) ...................................................................................................................
2-tert-Butoxy-1-Propanol ......................................................................................................................................................................
n-Butoxy-2-Propanol ............................................................................................................................................................................
Dipropylene Glycol Methyl Ether Isomer (1Methoxy-2-[2-Hydroxypropoxy]-Propane) .......................................................................
Dipropylene Glycol Methyl Ether Isomer (2-[2Methoxypropoxy]-1-Propanol) .....................................................................................
2-Hexyloxyethanol ...............................................................................................................................................................................
2-(2-Propoxyethoxy) Ethanol ...............................................................................................................................................................
2,2,4-Trimethyl-1,3-Pentanediol ...........................................................................................................................................................
2-(2-Butoxyethoxy)-Ethanol .................................................................................................................................................................
2-[2-(2-Methoxyethoxy) Ethoxy] Ethanol .............................................................................................................................................
Dipropylene Glycol Ethyl Ether ............................................................................................................................................................
Ethylene Glycol 2-Ethylhexyl Ether [2-(2Ethylhexyloxy) Ethanol] .......................................................................................................
2-[2-(2-Ethoxyethoxy) Ethoxy] Ethanol ................................................................................................................................................
Tetraethylene Glycol ............................................................................................................................................................................
1-(Butoxyethoxy)-2-Propanol ...............................................................................................................................................................
2-(2-Hexyloxyethoxy) Ethanol ..............................................................................................................................................................
Glycol Ether dpnb (1-(2-Butoxy-1-Methylethoxy)2-Propanol) .............................................................................................................
2-[2-(2-Propoxyethoxy) Ethoxy] Ethanol ..............................................................................................................................................
2-[2-(2-Butoxyethoxy) Ethoxy] Ethanol ................................................................................................................................................
Tripropylene Glycol Monomethyl Ether ...............................................................................................................................................
2,5,8,11-Tetraoxatridecan-13-ol ...........................................................................................................................................................
3,6,9,12-Tetraoxahexadecan-1-ol ........................................................................................................................................................
Cumene Hydroperoxide (1-Methyl-1Phenylethylhydroperoxide) .........................................................................................................
Methyl Formate ....................................................................................................................................................................................
Ethyl Formate ......................................................................................................................................................................................
Methyl Acetate .....................................................................................................................................................................................
gamma-Butyrolactone ..........................................................................................................................................................................
Ethyl Acetate ........................................................................................................................................................................................
Methyl Propionate ................................................................................................................................................................................
n-Propyl Formate .................................................................................................................................................................................
Isopropyl Formate ................................................................................................................................................................................
Ethyl Propionate ..................................................................................................................................................................................
Isopropyl Acetate .................................................................................................................................................................................
Methyl Butyrate ....................................................................................................................................................................................
Methyl Isobutyrate ...............................................................................................................................................................................
n-Butyl Formate ...................................................................................................................................................................................
Propyl Acetate .....................................................................................................................................................................................
Ethyl Butyrate ......................................................................................................................................................................................
Isobutyl Acetate ...................................................................................................................................................................................
Methyl Pivalate (2,2-Dimethyl Propanoic Acid Methyl Ester) ..............................................................................................................
n-Butyl Acetate ....................................................................................................................................................................................
n-Propyl Propionate .............................................................................................................................................................................
s-Butyl Acetate .....................................................................................................................................................................................
t-Butyl Acetate .....................................................................................................................................................................................
Butyl Propionate ..................................................................................................................................................................................
Amyl Acetate ........................................................................................................................................................................................
n-Propyl Butyrate .................................................................................................................................................................................
Isoamyl Acetate (3-Methylbutyl Acetate) .............................................................................................................................................
2-Methyl-1-Butyl Acetate .....................................................................................................................................................................
EEP Solvent (Ethyl 3-Ethoxy Propionate) ...........................................................................................................................................
2,3-Dimethylbutyl Acetate ....................................................................................................................................................................
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16JYP2
2.64
2.98
2.62
3.78
3.01
4.01
3.55
3.54
3.25
3.52
4.24
0.97
2.90
2.86
2.90
1.74
3.84
3.19
2.48
3.41
1.71
1.81
2.70
2.21
3.02
2.45
3.00
1.74
2.70
2.62
2.75
1.71
2.66
2.84
2.08
2.03
1.96
2.46
2.24
1.90
2.15
1.90
12.61
0.06
0.52
0.07
1.15
0.64
0.71
0.93
0.42
0.79
1.12
1.18
0.70
0.95
0.87
1.25
0.67
0.39
0.89
0.93
1.43
0.20
0.89
0.96
1.17
1.18
1.17
3.61
0.84
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
38987
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
2-Methylpentyl Acetate ........................................................................................................................................................................
3-Methylpentyl Acetate ........................................................................................................................................................................
4-Methylpentyl Acetate ........................................................................................................................................................................
Isobutyl Isobutyrate ..............................................................................................................................................................................
n-Butyl Butyrate ...................................................................................................................................................................................
n-Hexyl Acetate (Hexyl Acetate) .........................................................................................................................................................
Methyl Amyl Acetate (4-Methyl-2-Pentanol Acetate) ..........................................................................................................................
n-Pentyl Propionate .............................................................................................................................................................................
2,4-Dimethylpentyl Acetate ..................................................................................................................................................................
2-Methylhexyl Acetate .........................................................................................................................................................................
3-Ethylpentyl Acetate ...........................................................................................................................................................................
3-Methylhexyl Acetate .........................................................................................................................................................................
4-Methylhexyl Acetate .........................................................................................................................................................................
5-Methylhexyl Acetate .........................................................................................................................................................................
Isoamyl Isobutyrate ..............................................................................................................................................................................
n-Heptyl Acetate (Heptyl Acetate) .......................................................................................................................................................
2,4-Dimethylhexyl Acetate ...................................................................................................................................................................
2-Ethyl-Hexyl Acetate ..........................................................................................................................................................................
3,4-Dimethylhexyl Acetate ...................................................................................................................................................................
3,5-Dimethylhexyl Acetate ...................................................................................................................................................................
3-Ethylhexyl Acetate ............................................................................................................................................................................
3-Methylheptyl Acetate ........................................................................................................................................................................
4,5-Dimethylhexyl Acetate ...................................................................................................................................................................
4-Methylheptyl Acetate ........................................................................................................................................................................
5-Methylheptyl Acetate ........................................................................................................................................................................
n-Octyl Acetate ....................................................................................................................................................................................
2,3,5-Trimethylhexyl Acetate ...............................................................................................................................................................
2,3-Dimethylheptyl Acetate ..................................................................................................................................................................
2,4-Dimethylheptyl Acetate ..................................................................................................................................................................
2,5-Dimethylheptyl Acetate ..................................................................................................................................................................
2-Methyloctyl Acetate ..........................................................................................................................................................................
3,5-Dimethylheptyl Acetate ..................................................................................................................................................................
3,6-Dimethylheptyl Acetate ..................................................................................................................................................................
3-Ethylheptyl Acetate ...........................................................................................................................................................................
4,5-Dimethylheptyl Acetate ..................................................................................................................................................................
4,6-Dimethylheptyl Acetate ..................................................................................................................................................................
4-Methyloctyl Acetate ..........................................................................................................................................................................
5-Methyloctyl Acetate ..........................................................................................................................................................................
n-Nonyl Acetate ...................................................................................................................................................................................
3,6-Dimethyloctyl Acetate ....................................................................................................................................................................
3-Isopropylheptyl Acetate ....................................................................................................................................................................
4,6-Dimethyloctyl Acetate ....................................................................................................................................................................
3,5,7-Trimethyloctyl Acetate ................................................................................................................................................................
3-Ethyl-6-Methyloctyl Acetate ..............................................................................................................................................................
4,7-Dimethylnonyl Acetate ...................................................................................................................................................................
Methyl Dodecanoate (Methyl Laurate) ................................................................................................................................................
2,3,5,7-Tetramethyloctyl Acetate .........................................................................................................................................................
3,5,7-Trimethylnonyl Acetate ...............................................................................................................................................................
3,6,8-Trimethylnonyl Acetate ...............................................................................................................................................................
2,4,6,8-Tetramethylnonyl Acetate ........................................................................................................................................................
3-Ethyl-6,7-Dimethylnonyl Acetate ......................................................................................................................................................
4,7,9-Trimethyldecyl Acetate ...............................................................................................................................................................
Methyl Myristate (Methyl Tetradecanoate) ..........................................................................................................................................
2,3,5,6,8-Pentaamethylnonyl Acetate ..................................................................................................................................................
3,5,7,9-Tetramethyldecyl Acetate ........................................................................................................................................................
5-Ethyl-3,6,8-Trimethylnonyl Acetate ...................................................................................................................................................
Dimethyl Carbonate .............................................................................................................................................................................
Propylene Carbonate (4-Methyl-1,3-Dioxolan-2one) ...........................................................................................................................
Methyl Lactate .....................................................................................................................................................................................
2-Methoxyethyl Acetate .......................................................................................................................................................................
Ethyl Lactate ........................................................................................................................................................................................
Methyl Isopropyl Carbonate .................................................................................................................................................................
Propylene Glycol Monomethyl Ether Acetate (1Methoxy-2-Propyl Acetate) ......................................................................................
2-Ethoxyethyl Acetate ..........................................................................................................................................................................
2-Methoxy-1-Propyl Acetate ................................................................................................................................................................
Methoxypropanol Acetate ....................................................................................................................................................................
Dimethyl Succinate ..............................................................................................................................................................................
Ethylene Glycol Diacetate ...................................................................................................................................................................
1,2-Propylene Glycol Diacetate ...........................................................................................................................................................
Diisopropyl Carbonate .........................................................................................................................................................................
Dimethyl Glutarate ...............................................................................................................................................................................
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16JYP2
1.11
1.31
0.92
0.61
1.12
0.87
1.46
0.79
0.98
0.89
1.24
1.01
0.91
0.79
0.89
0.73
0.93
0.79
1.16
1.09
1.03
0.76
0.86
0.72
0.73
0.64
0.86
0.84
0.88
0.86
0.63
1.01
0.87
0.71
0.96
0.83
0.68
0.67
0.58
0.88
0.71
0.85
0.83
0.80
0.64
0.53
0.74
0.76
0.72
0.63
0.76
0.55
0.47
0.74
0.58
0.77
0.06
0.25
2.75
1.18
2.71
0.69
1.71
1.90
1.12
1.97
0.23
0.72
0.94
1.04
0.51
38988
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
Ethylene Glycol Monobutyl Ether Acetate (2Butoxyethyl Acetate) .....................................................................................................
Dimethyl Adipate ..................................................................................................................................................................................
2-(2-Ethoxyethoxy) Ethyl Acetate ........................................................................................................................................................
Dipropylene Glycol n-Propyl Ether Isomer #1 .....................................................................................................................................
Dipropylene Glycol Methyl Ether Acetate Isomer #1 ..........................................................................................................................
Dipropylene Glycol Methyl Ether Acetate Isomer #2 ..........................................................................................................................
Dipropylene Glycol Methyl Ether Acetate ............................................................................................................................................
Glyceryl Triacetate ...............................................................................................................................................................................
2-(2-Butoxyethoxy) Ethyl Acetate ........................................................................................................................................................
Substituted C7 Ester (C12) .................................................................................................................................................................
1-Hydroxy-2,2,4-Trimethylpentyl-3-Isobutyrate ....................................................................................................................................
3-Hydroxy-2,2,4-Trimethylpentyl-1-Isobutyrate ....................................................................................................................................
Hydroxy-2,2,4-Trimethylpentyl Isobutyrate Isomers (2,2,4-Trimethyl-1,3-Pentanediol Monoisobutyrate) ..........................................
Substituted C9 Ester (C12) .................................................................................................................................................................
Dimethyl Sebacate ...............................................................................................................................................................................
Diisopropyl Adipate ..............................................................................................................................................................................
Ethylene Oxide ....................................................................................................................................................................................
Propylene Oxide ..................................................................................................................................................................................
1,2-Epoxybutane (Ethyl Oxirane) ........................................................................................................................................................
Formic Acid ..........................................................................................................................................................................................
Acetic Acid ...........................................................................................................................................................................................
Glycolic Acid (Hydroxyacetic Acid) ......................................................................................................................................................
Peracetic Acid (Peroxyacetic Acid) .....................................................................................................................................................
Acrylic Acid ..........................................................................................................................................................................................
Propionic Acid ......................................................................................................................................................................................
Methacrylic Acid ...................................................................................................................................................................................
Isobutyric Acid .....................................................................................................................................................................................
Butanoic Acid .......................................................................................................................................................................................
Malic Acid ............................................................................................................................................................................................
3-Methylbutanoic Acid .........................................................................................................................................................................
Adipic Acid ...........................................................................................................................................................................................
2-Ethyl Hexanoic Acid .........................................................................................................................................................................
Methyl Acrylate ....................................................................................................................................................................................
Vinyl Acetate ........................................................................................................................................................................................
2-Methyl-2-Butene-3-ol (1,2-Dimethylpropyl-1en-1-ol) ........................................................................................................................
Ethyl Acrylate .......................................................................................................................................................................................
Methyl Methacrylate .............................................................................................................................................................................
Hydroxypropyl Acrylate ........................................................................................................................................................................
n-Butyl Acrylate ....................................................................................................................................................................................
Isobutyl Acrylate ..................................................................................................................................................................................
Butyl Methacrylate ...............................................................................................................................................................................
Isobutyl Methacrylate ...........................................................................................................................................................................
Isobornyl Methacrylate .........................................................................................................................................................................
a-Terpineol ...........................................................................................................................................................................................
2-Ethyl-Hexyl Acrylate .........................................................................................................................................................................
Furan ....................................................................................................................................................................................................
Formaldehyde ......................................................................................................................................................................................
Acetaldehyde .......................................................................................................................................................................................
Propionaldehyde ..................................................................................................................................................................................
2-Methylpropanal .................................................................................................................................................................................
Butanal .................................................................................................................................................................................................
C4 Aldehydes ......................................................................................................................................................................................
2,2-Dimethylpropanal (Pivaldehyde) ....................................................................................................................................................
3-Methylbutanal (Isovaleraldehyde) .....................................................................................................................................................
Pentanal (Valeraldehyde) ....................................................................................................................................................................
C5 Aldehydes ......................................................................................................................................................................................
Glutaraldehyde .....................................................................................................................................................................................
Hexanal ................................................................................................................................................................................................
C6 Aldehydes ......................................................................................................................................................................................
Heptanal ...............................................................................................................................................................................................
C7 Aldehydes ......................................................................................................................................................................................
2-Methyl-Hexanal .................................................................................................................................................................................
Octanal .................................................................................................................................................................................................
C8 Aldehydes ......................................................................................................................................................................................
Glyoxal .................................................................................................................................................................................................
Methyl Glyoxal .....................................................................................................................................................................................
Acrolein ................................................................................................................................................................................................
Crotonaldehyde ....................................................................................................................................................................................
Methacrolein ........................................................................................................................................................................................
Hydroxy Methacrolein ..........................................................................................................................................................................
Benzaldehyde ......................................................................................................................................................................................
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E:\FR\FM\16JYP2.SGM
16JYP2
1.67
1.95
1.50
2.13
1.41
1.58
1.49
0.57
1.38
0.92
0.92
0.88
0.89
0.89
0.48
1.42
0.05
0.32
1.02
0.08
0.71
2.67
12.62
11.66
1.16
18.78
1.22
1.78
7.51
4.26
3.37
4.41
12.24
3.26
5.12
8.78
15.84
5.56
5.52
5.05
9.09
8.99
8.64
5.16
2.42
16.54
8.97
6.84
7.89
5.87
6.74
6.74
5.40
5.52
5.76
5.76
4.79
4.98
4.98
4.23
4.23
3.97
3.65
3.65
14.22
16.21
7.60
10.07
6.23
6.61
0.00
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
38989
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
Tolualdehyde .......................................................................................................................................................................................
Acetone ................................................................................................................................................................................................
Cyclobutanone .....................................................................................................................................................................................
Methyl Ethyl Ketone (2-Butanone) ......................................................................................................................................................
Cyclopentanone ...................................................................................................................................................................................
C5 Cyclic Ketones ...............................................................................................................................................................................
Methyl Propyl Ketone (2-Pentanone) ..................................................................................................................................................
3-Pentanone ........................................................................................................................................................................................
C5 Ketones ..........................................................................................................................................................................................
Methyl Isopropyl Ketone ......................................................................................................................................................................
2,4-Pentanedione .................................................................................................................................................................................
Cyclohexanone ....................................................................................................................................................................................
C6 Cyclic Ketones ...............................................................................................................................................................................
Methyl Isobutyl Ketone (4-Methyl-2-Pentanone) .................................................................................................................................
Methyl n-Butyl Ketone (2-Hexanone) ..................................................................................................................................................
Methyl t-Butyl Ketone ..........................................................................................................................................................................
C6 Ketones ..........................................................................................................................................................................................
C7 Cyclic Ketones ...............................................................................................................................................................................
Methyl Amyl Ketone (2-Heptanone) ....................................................................................................................................................
2-Methyl-3-Hexanone ..........................................................................................................................................................................
Di-Isopropyl Ketone .............................................................................................................................................................................
C7 Ketones ..........................................................................................................................................................................................
3-Methyl-2-Hexanone ..........................................................................................................................................................................
Methyl Isoamyl Ketone (5-Methyl-2-Hexanone) ..................................................................................................................................
C8 Cyclic Ketones ...............................................................................................................................................................................
2-Octanone ..........................................................................................................................................................................................
C8 Ketones ..........................................................................................................................................................................................
C9 Cyclic Ketones ...............................................................................................................................................................................
2-Propyl Cyclohexanone ......................................................................................................................................................................
4-Propyl Cyclohexanone ......................................................................................................................................................................
2-Nonanone .........................................................................................................................................................................................
Di-Isobutyl Ketone (2,6-Dimethyl-4-Heptanone) ..................................................................................................................................
C9 Ketones ..........................................................................................................................................................................................
C10 Cyclic Ketones .............................................................................................................................................................................
2-Decanone .........................................................................................................................................................................................
C10 Ketones ........................................................................................................................................................................................
2,6,8-Trimethyl-4-Nonanone; Isobutyl Heptyl Ketone .........................................................................................................................
Biacetyl ................................................................................................................................................................................................
Methylvinyl ketone ...............................................................................................................................................................................
Mesityl Oxide (2-Methyl-2-Penten-4-one) ............................................................................................................................................
Isophorone (3,5,5-Trimethyl-2-Cyclohexenone) ..................................................................................................................................
1-Nonene-4-one ...................................................................................................................................................................................
Hydroxy Acetone .................................................................................................................................................................................
Dihydroxyacetone ................................................................................................................................................................................
Methoxy Acetone .................................................................................................................................................................................
Diacetone Alcohol (4-Hydroxy-4-Methyl-2Pentanone) ........................................................................................................................
Phenol ..................................................................................................................................................................................................
C7 Alkyl Phenols .................................................................................................................................................................................
m-Cresol ..............................................................................................................................................................................................
p-Cresol ...............................................................................................................................................................................................
o-Cresol ...............................................................................................................................................................................................
C8 Alkyl Phenols .................................................................................................................................................................................
C9 Alkyl Phenols .................................................................................................................................................................................
C10 Alkyl Phenols ...............................................................................................................................................................................
C11 Alkyl Phenols ...............................................................................................................................................................................
C12 Alkyl Phenols ...............................................................................................................................................................................
2-Phenoxyethanol; Ethylene Glycol Phenyl Ether ...............................................................................................................................
1-Phenoxy-2-Propanol .........................................................................................................................................................................
Nitrobenzene ........................................................................................................................................................................................
Para Toluene Isocyanate .....................................................................................................................................................................
Toluene Diisocyanate (Mixed Isomers) ...............................................................................................................................................
Methylene Diphenylene Diisocyanate .................................................................................................................................................
N-Methyl Acetamide ............................................................................................................................................................................
Dimethyl Amine ....................................................................................................................................................................................
Ethyl Amine ..........................................................................................................................................................................................
Trimethyl Amine ...................................................................................................................................................................................
Triethyl Amine ......................................................................................................................................................................................
Diethylenetriamine ...............................................................................................................................................................................
Ethanolamine .......................................................................................................................................................................................
Dimethylaminoethanol .........................................................................................................................................................................
Monoisopropanol Amine (1-Amino-2-Propanol) ..................................................................................................................................
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0.00
0.43
0.68
1.49
1.43
1.43
3.07
1.45
3.07
1.64
1.02
1.61
1.61
4.31
3.55
0.78
3.55
1.41
2.80
1.79
1.63
2.80
2.81
2.10
1.25
1.66
1.66
1.13
1.71
2.08
1.30
2.94
1.30
1.02
1.06
1.06
1.86
20.73
8.73
17.37
10.58
3.39
3.08
4.02
2.14
0.68
1.82
2.34
2.34
2.34
2.34
2.07
1.86
1.68
1.54
1.42
3.61
1.73
0.07
0.93
0.00
0.79
19.70
9.37
7.80
7.06
16.60
13.03
5.97
4.76
13.42
38990
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
TABLE 2A TO SUBPART E OF PART 59.—REACTIVITY FACTORS—Continued
Reactivity
factor
mstockstill on PROD1PC66 with PROPOSALS2
Organic compound
2-Amino-2-Methyl-1-Propanol ..............................................................................................................................................................
Diethanol Amine ..................................................................................................................................................................................
Triethanolamine ...................................................................................................................................................................................
Methyl Pyrrolidone (N-Methyl-2-Pyrrolidone) ......................................................................................................................................
Morpholine ...........................................................................................................................................................................................
Nitroethane ..........................................................................................................................................................................................
Nitromethane .......................................................................................................................................................................................
1-Nitropropane .....................................................................................................................................................................................
2-Nitropropane .....................................................................................................................................................................................
Dexpanthenol (Pantothenylol) .............................................................................................................................................................
Methyl Ethyl Ketoxime (Ethyl Methyl Ketone Oxime) .........................................................................................................................
Hydroxyethylethylene Urea ..................................................................................................................................................................
Methyl Chloride ....................................................................................................................................................................................
Methylene Chloride (Dichloromethane) ...............................................................................................................................................
Methyl Bromide ....................................................................................................................................................................................
Chloroform ...........................................................................................................................................................................................
Carbon Tetrachloride ...........................................................................................................................................................................
Methylene Bromide ..............................................................................................................................................................................
Vinyl Chloride .......................................................................................................................................................................................
Ethyl Chloride ......................................................................................................................................................................................
1,1-Dichloroethane ...............................................................................................................................................................................
1,2-Dichloroethane ...............................................................................................................................................................................
Ethyl Bromide ......................................................................................................................................................................................
1,1,1-Trichloroethane ...........................................................................................................................................................................
1,1,2-Trichloroethane ...........................................................................................................................................................................
1,2-Dibromoethane ..............................................................................................................................................................................
n-Propyl Bromide .................................................................................................................................................................................
n-Butyl Bromide ...................................................................................................................................................................................
trans-1,2-Dichloroethene .....................................................................................................................................................................
Trichloroethylene .................................................................................................................................................................................
Perchloroethylene ................................................................................................................................................................................
2-(Chloro-Methyl)-3-Chloro Propene ...................................................................................................................................................
Monochlorobenzene ............................................................................................................................................................................
p-Dichlorobenzene ...............................................................................................................................................................................
Benzotrifluoride ....................................................................................................................................................................................
PCBTF (p-Trifluoromethyl-Cl-Benzene) ...............................................................................................................................................
HFC–134a (1,1,1,2-Tetrafluoroethane) ...............................................................................................................................................
HFC–152a (1,1-Difluoroethane) ..........................................................................................................................................................
Dimethyl Sulfoxide ...............................................................................................................................................................................
Unspeciated C6 Alkanes .....................................................................................................................................................................
Unspeciated C7 Alkanes .....................................................................................................................................................................
Unspeciated C8 Alkanes .....................................................................................................................................................................
Unspeciated C9 Alkanes .....................................................................................................................................................................
Unspeciated C10 Alkanes ...................................................................................................................................................................
Unspeciated C11 Alkanes ...................................................................................................................................................................
Unspeciated C12 Alkanes ...................................................................................................................................................................
Unspeciated C13 Alkanes ...................................................................................................................................................................
Unspeciated C14 Alkanes ...................................................................................................................................................................
Unspeciated C15 Alkanes ...................................................................................................................................................................
Unspeciated C16 Alkanes ...................................................................................................................................................................
Unspeciated C17 Alkanes ...................................................................................................................................................................
Unspeciated C18 Alkanes ...................................................................................................................................................................
Unspeciated C10 Aromatics ................................................................................................................................................................
Unspeciated C11 Aromatics ................................................................................................................................................................
Unspeciated C12 Aromatics ................................................................................................................................................................
Base ROG Mixture ..............................................................................................................................................................................
Alkane, Mixed—Predominantly (Minimally 94%) C13–14 ...................................................................................................................
Oxo-Hexyl Acetate ...............................................................................................................................................................................
Oxo-Heptyl Acetate ..............................................................................................................................................................................
Oxo-Octyl Acetate ................................................................................................................................................................................
Oxo-Nonyl Acetate ...............................................................................................................................................................................
Oxo-Decyl Acetate ...............................................................................................................................................................................
Oxo-Dodecyl Acetate ...........................................................................................................................................................................
Oxo-Tridecyl Acetate ...........................................................................................................................................................................
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15.08
4.05
2.76
2.56
15.43
12.79
7.86
16.16
16.16
9.35
22.04
14.75
0.03
0.07
0.02
0.03
0.00
0.00
2.92
0.25
0.10
0.10
0.11
0.00
0.06
0.05
0.35
0.60
0.81
0.60
0.04
1.13
0.36
0.20
0.26
0.11
0.00
0.00
6.90
1.48
1.79
1.64
2.13
1.16
0.90
0.81
0.73
0.67
0.61
0.55
0.52
0.49
5.48
4.96
4.53
3.71
0.67
1.03
0.97
0.96
0.85
0.83
0.72
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Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 / Proposed Rules
38991
TABLE 2B TO SUBPART E OF PART 59.—REACTIVITY FACTORS FOR ALIPHATIC HYDROCARBON SOLVENT MIXTURES
Bin
1 ...............................................
2 ...............................................
3 ...............................................
4 ...............................................
5 ...............................................
6 ...............................................
7 ...............................................
8 ...............................................
9 ...............................................
10 .............................................
11 .............................................
12 .............................................
13 .............................................
14 .............................................
15 .............................................
16 .............................................
17 .............................................
18 .............................................
19 .............................................
20 .............................................
Average Boiling Point*
(degrees F)
80–205
80–205
80–205
80–205
80–205
>205–340
>205–340
>205–340
>205–340
>205–340
>340–460
>340–460
>340–460
>340–460
>340–460
>460–580
>460–580
>460–580
>460–580
>460–580
Reactivity
factor
Criteria
Alkanes (<2% Aromatics) .................................................................................
N– & Iso-Alkanes (≥90% and <2% Aromatics) ................................................
Cyclo-Alkanes (≥90% and <2% Aromatics) ......................................................
Alkanes (2 to <8% Aromatics) ..........................................................................
Alkanes (8 to 22% Aromatics) ..........................................................................
Alkanes (<2% Aromatics) .................................................................................
N– & Iso-Alkanes (≥90% and <2% Aromatics) ................................................
Cyclo-Alkanes (≥90% and <2% Aromatics) ......................................................
Alkanes (2 to <8% Aromatics) ..........................................................................
Alkanes (8 to 22% Aromatics) ..........................................................................
Alkanes (<2% Aromatics) .................................................................................
N– & Iso-Alkanes (≥90% and <2% Aromatics) ................................................
Cyclo-Alkanes (≥90% and <2% Aromatics) ......................................................
Alkanes (2 to <8% Aromatics) ..........................................................................
Alkanes (8 to 22% Aromatics) ..........................................................................
Alkanes (<2% Aromatics) .................................................................................
N– & Iso-Alkanes (≥90% and <2% Aromatics) ................................................
Cyclo-Alkanes (>90% and <2% Aromatics) .....................................................
Alkanes (2 to <8% Aromatics) ..........................................................................
Alkanes (8 to 22% Aromatics) ..........................................................................
2.08
1.59
2.52
2.24
2.56
1.41
1.17
1.65
1.62
2.03
0.91
0.81
1.01
1.21
1.82
0.57
0.51
0.63
0.88
1.49
* Average Boiling Point = (Initial Boiling Point + Dry Point)/2(b) Aromatic Hydrocarbon Solvents
TABLE 2C TO SUBPART E OF PART 63.—REACTIVITY FACTORS FOR AROMATIC HYDROCARBON SOLVENT MIXTURES
Bin
21
22
23
24
.............................................
.............................................
.............................................
.............................................
Boiling range
(degrees F)
280–290
320–350
355–420
450–535
Reactivity
factor
Criteria
Aromatic
Aromatic
Aromatic
Aromatic
Content
Content
Content
Content
(≥98%)
(≥98%)
(≥98%)
(≥98%)
.................................................................................
.................................................................................
.................................................................................
.................................................................................
[FR Doc. E7–13108 Filed 7–13–07; 8:45 am]
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5.00
Agencies
[Federal Register Volume 72, Number 135 (Monday, July 16, 2007)]
[Proposed Rules]
[Pages 38952-38991]
From the Federal Register Online via the Government Printing Office [www.gpo.gov]
[FR Doc No: E7-13108]
[[Page 38951]]
-----------------------------------------------------------------------
Part IV
Environmental Protection Agency
-----------------------------------------------------------------------
40 CFR Parts 51 and 59
National Volatile Organic Compound Emission Standards for Aerosol
Coatings; Proposed Rule
Federal Register / Vol. 72, No. 135 / Monday, July 16, 2007 /
Proposed Rules
[[Page 38952]]
-----------------------------------------------------------------------
ENVIRONMENTAL PROTECTION AGENCY
40 CFR Parts 51 and 59
[EPA-HQ-OAR-2006-0971; FRL-8336-5]
RIN 2060-AN69
National Volatile Organic Compound Emission Standards for Aerosol
Coatings
AGENCY: Environmental Protection Agency (EPA).
ACTION: Proposed rule.
-----------------------------------------------------------------------
SUMMARY: This action proposes a national reactivity-based volatile
organic compound (VOC) emissions regulation for the aerosol coatings
(aerosol spray paints) category under section 183(e) of the Clean Air
Act (CAA). The proposed standards implement section 183(e) of the CAA,
as amended in 1990, which requires the Administrator to control VOC
emissions from certain categories of consumer and commercial products
for purposes of minimizing VOC emissions contributing to ozone
formation and causing non-attainment. This regulation will establish a
nationwide reactivity-based standard for aerosol coatings. States have
promulgated rules for the aerosol coatings category based upon
reductions of VOC by mass; however, the Agency believes that a national
rule based upon the relative reactivity approach may achieve more
reduction in ozone formation than can be achieved by a mass-based
approach for this specific product category. EPA believes that this
rule will better control a product's contribution to ozone formation by
encouraging the use of less reactive VOC ingredients, rather than
treating all VOC in a product alike through the traditional mass-based
approach. We are also proposing to revise EPA's regulatory definition
of VOC exempt compounds for purposes of this regulation in order to
account for all the reactive compounds in aerosol coatings that
contribute to ozone formation. Therefore, compounds that would not be
VOC under the otherwise applicable definition will count towards a
product's reactivity limits under this proposed regulation. The initial
listing of product categories and schedule for regulation was published
on March 23, 1995 (60 FR 15264). This proposed action announces EPA's
final decision to list aerosol coatings for regulation under group III
of the consumer and commercial product category for which regulations
are mandated under section 183 (e) of the Act.
DATES: Comments. Written comments on the proposed regulation must be
received by EPA by August 15, 2007, unless a public hearing is
requested by July 26, 2007. If a hearing is requested, written comments
must be received by August 30, 2007.
Public Hearing. If anyone contacts EPA requesting to speak at a
public hearing concerning the proposed regulation by July 26, 2007, we
will hold a public hearing on July 31, 2007.
ADDRESSES: Comments. Submit your comments, identified by Docket ID No.
EPA-HQ-OAR-2006-0971, by one of the following methods:
Federal eRulemaking Portal: https://www.regulations.gov.
Follow the on-line instructions for submitting comments.
E-mail: a-and-r-docket@epa.gov.
Fax: (202) 566-1741.
Mail: Air and Radiation Docket, Environmental Protection
Agency, Mailcode 6102T, 1200 Pennsylvania Avenue, NW., Washington, DC
20460. Please include a total of two copies. We request that a separate
copy also be sent to the contact person identified below (see FOR
FURTHER INFORMATION CONTACT). In addition, please mail a copy of your
comments on the information collection provisions to the Office of
Information and Regulatory Affairs, Office of Management and Budget
(OMB), Attn: Desk Officer for EPA, 725 17th St., NW., Washington, DC
20503.
Hand Delivery: EPA Docket Center, Public Reading Room, EPA
West, Room 3334, 1301 Constitution Ave., NW., Washington, DC 20460.
Such deliveries are only accepted during the Docket's normal hours of
operation, and special arrangements should be made for deliveries of
boxed information.
Instructions: Direct your comments to the applicable docket. EPA's
policy is that all comments received will be included in the public
docket without change and may be made available online at https://
www.regulations.gov, including any personal information provided,
unless the comment includes information claimed to be confidential
business information (CBI) or other information whose disclosure is
restricted by statute. Do not submit information that you consider to
be CBI or otherwise protected through www.regulations.gov or e-mail.
The www.regulations.gov Web site is an ``anonymous access'' system,
which means EPA will not know your identity or contact information
unless you provide it in the body of your comment. If you send an e-
mail comment directly to EPA without going through www.regulations.gov,
your e-mail address will be automatically captured and included as part
of the comment that is placed in the public docket and made available
on the Internet. If you submit an electronic comment, EPA recommends
that you include your name and other contact information in the body of
your comment and with any disk or CD-ROM you submit. If EPA cannot read
your comment due to technical difficulties and cannot contact you for
clarification, EPA may not be able to consider your comment. Electronic
files should avoid the use of special characters, any form of
encryption, and be free of any defects or viruses.
Public Hearing. If a public hearing is held, it will be held at 10
a.m. on July 31, 2007 at Building C on the EPA campus in Research
Triangle Park, NC, or at an alternate site nearby. Persons interested
in presenting oral testimony must contact Ms. Dorothy Apple, U.S. EPA,
Office of Air Quality Planning and Standards, Sector Policies and
Programs Division, Natural Resources and Commerce Group (E143-03),
Research Triangle Park, North Carolina 27711, telephone number: (919)
541-4487, fax number (919) 541-3470, e-mail address:
apple.dorothy@epa.gov, no later than July 26, 2007 in the Federal
Register. Persons interested in attending the public hearing must also
call Ms. Apple to verify the time, date, and location of the hearing.
If no one contacts Ms. Apple by July 26, 2007 in the Federal Register
with a request to present oral testimony at the hearing, we will cancel
the hearing.
Docket: All documents in the docket are listed in the
www.regulations.gov index. Although listed in the index, some
information is not publicly available, e.g., CBI or other information
whose disclosure is restricted by statute. Certain other material, such
as copyrighted material, is not placed on the Internet and will be
publicly available only in hard copy form. Publicly available docket
materials are available either electronically through
www.regulations.gov or in hard copy at the EPA Docket Center, Public
Reading Room, EPA West, Room 3334, 1301 Constitution Ave., NW.,
Washington, DC 20460. The Public Reading Room is open from 8:30 a.m. to
4:30 p.m., Monday through Friday, excluding legal holidays. The
telephone number for the Public Reading Room is (202) 566-1742, and the
telephone number for the Air Docket is (202) 566-1744.
FOR FURTHER INFORMATION CONTACT: For information concerning the aerosol
coatings rule, contact Ms. J. Kaye Whitfield, U.S. EPA, Office of Air
Quality Planning and Standards, Sector
[[Page 38953]]
Policies and Programs Division, Natural Resources and Commerce Group
(E143-03), Research Triangle Park, North Carolina 27711, telephone
number: (919) 541-2509, fax number (919) 541-3470, e-mail address:
whitfield.kaye@epa.gov. For information concerning the CAA section
183(e) consumer and commercial products program, contact Mr. Bruce
Moore, U.S. EPA, Office of Air Quality Planning and Standards, Sector
Policies and Programs Division, Natural Resources and Commerce Group
(E143-03), Research Triangle Park, North Carolina 27711, telephone
number: (919) 541-5460, fax number (919) 541-3470, e-mail address:
moore.bruce@epa.gov.
SUPPLEMENTARY INFORMATION: Entities Potentially Affected by this
Action. The entities potentially regulated by the proposed regulation
encompass aerosol coatings operations. This includes manufacturers,
processors, wholesale distributors, or importers of aerosol coatings
for sale or distribution in the United States, or manufacturers,
processors, wholesale distributors, or importers that supply the
entities listed with aerosol coatings for sale or distribution in
interstate commerce in the United States. The entities potentially
affected by this action include:
------------------------------------------------------------------------
Examples of
Category NAICS code \a\ regulated entities
------------------------------------------------------------------------
Paint and coating manufacturing... 32551 Manufacturing of
lacquers,
varnishes, enamels,
epoxy coatings, oil
and alkyd vehicle,
plastisols,
polyurethane,
primers, shellacs,
stains, water
repellant coatings.
All other miscellaneous chemical 325998 Aerosol can filling,
production and preparation aerosol packaging
manufacturing. services.
------------------------------------------------------------------------
\a\ https://www.census.gov/epcd/www/naics.html.
This table is not intended to be exhaustive, but rather provides a
guide for readers regarding entities likely to be affected by this
action. To determine whether you would be affected by this action, you
should examine the applicable industry description in section I.E of
this notice. If you have any questions regarding the applicability of
this action to a particular entity, consult the appropriate EPA contact
listed in the FOR FURTHER INFORMATION CONTACT section of this notice.
Preparation of Comments. Do not submit information containing CBI
to EPA through www.regulations.gov or e-mail. Send or deliver
information identified as CBI only to the following address: Mr.
Roberto Morales, OAQPS Document Control Officer (C404-02), U.S. EPA,
Office of Air Quality Planning and Standards, Research Triangle Park,
North Carolina 27711, Attention: Docket ID EPA-HQ-OAR-2006-0971.
Clearly mark the part or all of the information that you claim to be
CBI. For CBI information in a disk or CD ROM that you mail to EPA, mark
the outside of the disk or CD ROM as CBI and then identify
electronically within the disk or CD ROM the specific information that
is claimed as CBI. In addition to one complete version of the comment
that includes information claimed as CBI, a copy of the comment that
does not contain the information claimed as CBI must be submitted for
inclusion in the public docket. Information so marked will not be
disclosed except in accordance with procedures set forth in 40 CFR part
2.
World Wide Web (WWW). In addition to being available in the docket,
an electronic copy of this proposed action will also be available on
the Worldwide Web (WWW) through the Technology Transfer Network (TTN).
Following signature, a copy of the proposed action will be posted on
the TTN's policy and guidance page for newly proposed or promulgated
rules at the following address: https://www.epa.gov/ttn/oarpg/. The TTN
provides information and technology exchange in various areas of air
pollution control.
Organization of This Document. The information presented in this
notice is organized as follows:
I. Background
A. The Ozone Problem
B. Statutory and Regulatory Background
C. What is Photochemical Reactivity?
D. Role of Reactivity in VOC/Ozone Regulations
E. The Aerosol Coating Industry
II. Summary of Proposed Standards
A. Applicability of the Standards and Regulated Entities
B. Regulated Pollutant
C. Regulatory Limits
D. Compliance Requirements
E. Labeling Requirements
F. Recordkeeping and Reporting
G. Variance
H. Test Methods
III. Summary of Impacts
A. Environmental Impacts
B. Energy Impacts
C. Cost and Economic Impacts
IV. Rationale
A. Applicability
B. Regulated Pollutant
C. Regulatory Approach
D. VOC Regulatory Limits
E. Compliance Demonstration Requirements
F. Labeling Requirements
G. Recordkeeping and Reporting Requirements
H. Variance Criteria
I. Test Methods
V. Statutory and Executive Order (EO) Reviews
A. Executive Order 12866: Regulatory Planning and Review
B. Paperwork Reduction Act
C. Regulatory Flexibility Act
D. Unfunded Mandates Reform Act
E. Executive Order 13132: Federalism
F. Executive Order 13175: Consultation and Coordination with
Indian Tribal Governments
G. Executive Order 13045: Protection of Children from
Environmental Health and Safety Risks
H. Executive Order 13211: Actions Concerning Regulations That
Significantly Affect Energy Supply, Distribution, or Use
I. National Technology Transfer and Advancement Act
J. Executive Order 12898: Federal Actions to Address
Environmental Justice in Minority Populations and Low-Income
Populations
I. Background
A. The Ozone Problem
Ground-level ozone, a major component of smog, is formed in the
atmosphere by reactions of VOC and oxides of nitrogen in the presence
of sunlight. The formation of ground-level ozone is a complex process
that is affected by many variables.
Exposure to ground-level ozone is associated with a wide variety of
human health effects, as well as agricultural crop loss, and damage to
forests and ecosystems. Controlled human exposure studies show that
acute health effects are induced by short-term (1 to 2 hour) exposures
(observed at concentrations as low as 0.12 parts per million (ppm)),
generally while individuals are engaged in moderate or heavy exertion,
and by prolonged (6 to 8 hour) exposures to ozone (observed at
concentrations as low as 0.08 ppm and possibly lower), typically while
individuals are engaged
[[Page 38954]]
in moderate exertion. Transient effects from acute exposures include
pulmonary inflammation, respiratory symptoms, effects on exercise
performance, and increased airway responsiveness. Epidemiological
studies have shown associations between ambient ozone levels and
increased susceptibility to respiratory infection, increased hospital
admissions and emergency room visits. Groups at increased risk of
experiencing elevated exposures include active children, outdoor
workers, and others who regularly engage in outdoor activities. Those
most susceptible to the effects of ozone include those with preexisting
respiratory disease, children, and older adults. The literature
suggests the possibility that long-term exposures to ozone may cause
chronic health effects (e.g., structural damage to lung tissue and
accelerated decline in baseline lung function).
B. Statutory and Regulatory Background
Under section 183(e) of the CAA, EPA conducted a study of VOC
emissions from the use of consumer and commercial products to assess
their potential to contribute to levels of ozone that violate the
National Ambient Air Quality Standards (NAAQS) for ozone, and to
establish criteria for regulating VOC emissions from these products.
Section 183(e) of the CAA directs EPA to list for regulation those
categories of products that account for at least 80 percent of the VOC
emissions, on a reactivity-adjusted basis, from consumer and commercial
products in areas that violate the NAAQS for ozone (i.e., ozone
nonattainment areas), and to divide the list of categories to be
regulated into four groups.
EPA published the initial list in the Federal Register on March 23,
1995 (60 FR 15264). In that notice, EPA stated that it may amend the
list of products for regulation, and the groups of product categories,
in order to achieve an effective regulatory program in accordance with
the Agency's discretion under CAA section 183(e). EPA has revised the
list several times. Most recently, in May 2006, EPA revised the list to
add one product category, portable fuel containers, and to remove one
product category, petroleum dry cleaning solvents. See 71 FR 28320 (May
16, 2006). The aerosol spray paints (aerosol coatings) category
currently is listed for regulation as part of Group III of the CAA
section 183(e) list.
CAA section 183(e) directs EPA to regulate Consumer and Commercial
Products using ``best available controls'' (BAC). CAA section
183(e)(1)(A) defines BAC as ``the degree of emissions reduction that
the Administrator determines, on the basis of technological and
economic feasibility, health, environmental, and energy impacts, is
achievable through the application of the most effective equipment,
measures, processes, methods, systems or techniques, including chemical
reformulation, product or feedstock substitution, repackaging, and
directions for use, consumption, storage, or disposal.'' CAA section
183(e) also provides EPA with authority to use any system or systems of
regulation that EPA determines is the most appropriate for the product
category. Under CAA section 183(e)(4), EPA can impose ``any system or
systems of regulation as the Administrator deems appropriate, including
requirements for registration and labeling, self-monitoring and
reporting, prohibitions, limitations, or economic incentives (including
marketable permits and auctions of emissions rights) concerning the
manufacture, processing, distribution, use, consumption or disposal of
the product.'' Under these provisions, EPA has previously issued
national regulations for architectural coatings, autobody refinishing
coatings, consumer products, and portable fuel
containers.1, 2, 3, 4, 5
---------------------------------------------------------------------------
\1\ National Volatile Organic Compound Emission Standards for
Architectural Coatings'' 63 FR 48848, (September 11, 1998).
\2\ ``National Volatile Organic Compound Emission Standards for
Automobile Refinish Coatings'' 63 FR 48806, (September 11, 1998).
\3\ ``Consumer and Commercial Products: Schedule for
Regulation'' 63 FR 48792, (September 11, 1998).
\4\ ``National Volatile Organic Compound Emission Standards for
Consumer Products'' 63 FR 48819, (September 11, 1998).
\5\ ``National Volatile Organic Compound Emission Standards for
Portable Fuel Containers'' 72 FR 8428, (February 26, 2007).
---------------------------------------------------------------------------
For any category of consumer or commercial products, the
Administrator may issue control techniques guidelines (CTGs) in lieu of
national regulations if the Administrator determines that such guidance
will be substantially as effective as regulations in reducing emissions
of volatile organic compounds which contribute to ozone levels in areas
which violate the national ambient air quality standard for ozone. In
many cases, CTGs can be effective regulatory approaches to reduce
emissions of VOC in nonattainment areas because of the nature of the
specific product and the uses of such product. A critical distinction
between a national rule and a CTG is that a CTG may include provisions
that affect the users of the products. For other product categories,
such as wood furniture coatings and shipbuilding coatings, EPA has
previously determined that, under CAA section 183(e)(3)(C), a CTG would
be substantially as effective as a national rule and, therefore, issued
CTGs to provide guidance to States for development of appropriate State
regulations.
For the category of aerosol coatings, EPA has determined that a
national rule applicable nationwide is the best system of regulation to
achieve necessary VOC emission reductions from this type of product.
Aerosol coatings are typically used in relatively small amounts by
consumers and others on an occasional basis and at varying times and
locations. Under such circumstances, reformulation of the VOC content
of the products is a more feasible way to achieve VOC emission
reductions, rather than through a CTG approach that would only affect a
smaller number of relatively large users. Aerosol coatings regulations
are already in place in three States (California, Oregon, and
Washington), and other States are considering developing regulations
for these products. For the companies that market aerosol coatings in
different States, trying to fulfill the differing requirements of State
rules may create administrative, technical, and marketing problems. A
Federal rule is expected to provide some degree of consistency,
predictability, and administrative ease for the industry. A national
rule also helps States reduce compliance problems associated with
noncompliant coatings being transported into nonattainment areas from
neighboring areas and neighboring States. A national rule will also
enable States to obtain needed VOC emission reductions from this sector
in the near term, without having to expend their limited resources to
develop similar rules in each State.\6\
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\6\ ALARM Caucus v. EPA, 215 F.3d 61,76 (D.C. Cir. 2000), cert.
denied, 532 U.S. 1018 (2001).
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C. What Is Photochemical Reactivity?
There are thousands of individual species of VOC chemicals that can
participate in a series of reactions involving nitrogen oxides
(NOX) and the energy from sunlight, resulting in the
formation of ozone. The impact of a given species of VOC on formation
of ground-level ozone is sometimes referred to as its ``reactivity.''
It is generally understood that not all VOC are equal in their effects
on ground-level ozone formation. Some VOC react extremely slowly and
changes in their emissions have limited effects on ozone pollution
episodes. Some VOC form ozone more quickly than other VOCs, or they may
form more ozone than other
[[Page 38955]]
VOC. Other VOC not only form ozone themselves, but also act as
catalysts and enhance ozone formation from other VOC. By distinguishing
between more reactive and less reactive VOC, however, EPA believes that
it may be possible to develop regulations that will decrease ozone
concentrations further or more efficiently than by controlling all VOC
equally.
Assigning a value to the reactivity of a specific VOC species is a
complex undertaking. Reactivity is not simply a property of the
compound itself; it is a property of both the compound and the
environment in which the compound is found. Therefore, the reactivity
of a specific VOC varies with VOC:NOX ratios, meteorological
conditions, the mix of other VOC in the atmosphere, and the time
interval of interest. Designing an effective regulation that takes
account of these interactions is difficult. Implementing and enforcing
such a regulation requires an extra burden for both industry and
regulators, as those impacted by the rule must characterize and track
the full chemical composition of VOC emissions rather than only having
to track total VOC content as is required by traditional mass-based
rules. EPA's September 13, 2005 final rule \7\ to approve a comparable
reactivity-based aerosol coating rule as part of the California State
Implementation Plan for ozone contains additional background
information on photochemical reactivity. Recently, EPA issued interim
guidance to States regarding the use of VOC reactivity information in
the development of ozone control measures.\8\
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\7\ ``Revisions to the California State Implementation Plan and
Revision to the Definition of Volatile Organic Compounds (VOC)-
Removal of VOC Exemptions for California's Aerosol Coating Products
Reactivity-based Regulation'' 70 FR 53930, (September 13, 2005).
\8\ ``Interim Guidance on Control of Volatile Organic Compounds
in Ozone State Implementation Plans'') 70 FR 54046, (September 13,
2005).
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1. What Research Has Been Conducted in Reactivity?
Much of the initial work on reactivity scales was funded by the
California Air Resources Board (CARB), which was interested in
comparing the reactivity of emissions from different alternative fueled
vehicles. In the late 1980s, CARB provided funding to William P. L.
Carter at the University of California to develop a reactivity scale.
Carter investigated 18 different methods of ranking the reactivity of
individual VOC in the atmosphere using a single-cell trajectory model
with a state-of-the-art chemical reaction mechanism.\9\ Carter
suggested three scales for further consideration:
---------------------------------------------------------------------------
\9\ Carter, W. P. L. (1994) ``Development of ozone reactivity
scales for organic gases,'' J. Air Waste Manage. Assoc., 44: 881-
899.
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i. Maximum Incremental Reactivity (MIR) scale-an ozone yield scale
derived by adjusting the NOX emissions in a base case to
yield the highest incremental reactivity of the base reactive organic
gas mixture.
ii. Maximum Ozone Incremental Reactivity (MOIR) scale-an ozone
yield scale derived by adjusting the NOX emission in a base
case to yield the highest peak ozone concentration.
iii. Equal Benefit Incremental Reactivity (EBIR) scale-an ozone
yield scale derived by adjusting the NOX emissions in a base
case scenario so VOC and NOX reductions are equally
effective in reducing ozone.
Carter concluded that, if only one scale is used for regulatory
purposes, the maximum incremental reactivity (MIR) scale is the most
appropriate.\10\ The MIR scale is defined in terms of environmental
conditions where ozone production is most sensitive to changes in
hydrocarbon emissions and, therefore, represents conditions where
hydrocarbon controls would be the most effective. CARB therefore used
the MIR scale to establish fuel-neutral VOC emissions limits in its
low-emitting vehicle and alternative fuels regulation.11, 12
Subsequently, Carter has updated the MIR scale several times as the
chemical mechanisms in the model used to derive the scale have evolved
with new scientific information. CARB incorporated a 1999 version of
the MIR scale in its own aerosol coatings rule. The latest revision to
the MIR scale was issued in 2003.
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\10\ ``Initial Statement of Reasons for the California Aerosol
Coatings Regulation, California Air Resources Board,'' 2000.
\11\ California Air Resources Board ``Proposed Regulations for
Low-Emission Vehicles and Clean Fuels--Staff Report and Technical
Support Document,'' State of California, Air Resources Board, P.O.
Box 2815, Sacramento, CA 95812, August 13, 1990.
\12\ California Air Resources Board ``Proposed Regulations for
Low-Emission Vehicles and Clean Fuels--Final Statement of Reasons,''
State of California, Air Resources Board, July 1991.
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In addition to Carter's work, there have been other attempts to
create reactivity scales. One such effort is the work of R.G. Derwent
and coworkers, who have published articles on a scale called the
photochemical ozone creation potential (POCP) scale.13, 14
This scale was designed for the emissions and meteorological conditions
prevalent in Europe. The POCP scale is generally consistent with that
of Carter, although there are some differences because it uses a
different model, chemical mechanism, and emission and meteorological
scenarios. Despite these differences, there is a good correlation of
r\2\=0.9 between the results of the POCP and the MIR scales\12\.
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\13\ Derwent, R.G., M.E. Jenkin, S.M. Saunders and M.J. Pilling
(2001) ``Characterization of the Reactivities of Volatile Organic
Compounds Using a Master Chemical Mechanism,'' J. Air Waste
Management Assoc., 51: 699-707.
\14\ Derwent, R.G., M.E. Jenkin, S.M. Saunders and M.J. Pilling
(1998) ``Photochemical Ozone Creation Potentials for Organic
Compounds in Northwest Europe Calculated with a Master Chemical
Mechanism,'' Atmos. Env., 32(14/15):2429-2441.
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As CARB worked to develop reactivity-based regulations in
California, EPA began to explore the implications of applying
reactivity scales in other parts of the country. In developing its
regulations, CARB has maintained that the MIR scale is the most
appropriate metric for application in California, but cautions that its
research has focused on California atmospheric conditions and that the
suitability of the MIR scale for regulatory purposes in other areas has
not been demonstrated. In particular, specific concerns have been
raised about the suitability of using the MIR scale in relation to
multi-day stagnation or transport scenarios or over geographic regions
with very different VOC:NOX ratios than those of California.
In 1998, EPA participated in the formation of the Reactivity
Research Working Group (RRWG), which was organized to help develop an
improved scientific basis for reactivity-related regulatory
policies.\15\ All interested parties were invited to participate. Since
that time, representatives from EPA, CARB, Environment Canada, States,
academia, and industry have met in public RRWG meetings to discuss and
coordinate research that would support this goal.
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\15\ See https://www.narsto.org/section.src?SID=10.
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The RRWG has organized a series of research efforts to explore:
i. The sensitivity of ozone to VOC mass reductions and changes in
VOC composition under a variety of environmental conditions;
ii. The derivation and evaluation of reactivity scales using
photochemical airshed models under a variety of environmental
conditions;
iii. The development of emissions inventory processing tools for
exploring reactivity-based strategies; and
iv. The fate of VOC emissions and their availability for
atmospheric reactions.
This research has led to a number of findings that increase our
confidence in
[[Page 38956]]
the ability to develop regulatory approaches that differentiate between
specific VOC on the basis of relative reactivity. The first two
research objectives listed above were explored in a series of three
parallel modeling studies that resulted in four reports and one journal
article.16, 17, 18, 19, 20 EPA commissioned a review of
these reports to address a series of policy-relevant science
questions.\21\ In 2007, an additional peer review was commissioned by
EPA to assess the appropriateness of basing a national aerosol coatings
regulation on reactivity. Generally, the peer reviews support the
appropriateness of the use of the box-model based MIR metric nationwide
for the aerosol coatings category. The results are available in the
rulemaking docket.
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\16\ Carter, W.P.L., G. Tonnesen, and G. Yarwood (2003)
Investigation of VOC Reactivity Effects Using Existing Regional Air
Quality Models, Report to American Chemistry Council, Contract SC-
20.0-UCR-VOC-RRWG, April 17, 2003.
\17\ Hakami, A., M.S. Bergin, and A.G. Russell (2003) Assessment
of the Ozone and Aerosol Formation Potentials (Reactivities) of
Organic Compounds over the Eastern United States, Final Report,
Prepared for California Air Resources Board, Contract No. 00-339,
January 2003.
\18\ Hakami, A., M.S. Bergin, and A.G. Russell (2004a) Ozone
Formation Potential of Organic Compounds in the Eastern United
States: A Comparison of Episodes, Inventories, and Domains, Environ.
Sci. Technol. 2004, 38, 6748-6759.
\19\ Hakami, A., M. Arhami, and A.G. Russell (2004b) Further
Analysis of VOC Reactivity Metrics and Scales, Final Report to the
U.S. EPA, Contract 4D-5751-NAEX, July 2004.
\20\ Arunachalam S., R. Mathur, A. Holland, M.R. Lee, D. Olerud,
Jr., and H. Jeffries (2003) Investigation of VOC Reactivity
Assessment with Comprehensive Air Quality Modeling, Prepared for
U.S. EPA, GSA Contract GS-35F-0067K, Task Order ID:
4TCG68022755, June 2003.
\21\ Derwent, R.G. (2004) Evaluation and Characterization of
Reactivity Metrics, Final Draft, Report to the U.S. EPA, Order No.
4D-5844-NATX, November 2004.
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The results of the RRWG-organized study and the subsequent reviews
suggest that there is good correlation between different relative
reactivity metrics calculated with photochemical airshed models,
regardless of the choice of model, model domain, scenario, or averaging
times. Moreover, the scales calculated with photochemical airshed
models correlate relatively well with the MIR metric derived with a
single cell, one-dimensional box model. Prior to the RRWG-organized
studies, little analysis of the robustness of the box-model derived MIR
metric and its applicability to environmental conditions outside
California had been conducted. Although these studies were not
specifically designed to test the robustness of the box-model derived
MIR metrics, the results suggest that the MIR metric is relatively
robust.
D. Role of Reactivity in VOC/Ozone Regulations
Historically, EPA's general approach to regulation of VOC emissions
has been based upon control of total VOC by mass, without
distinguishing between individual species of VOC. EPA considered the
regulation of VOC by mass to be the most effective and practical
approach based upon the scientific and technical information available
when EPA developed its VOC control policy.
EPA issued the first version of its VOC control policy in 1971, as
part of EPA's State Implementation Plan (SIP) preparation guidance.\22\
In that guidance, EPA emphasized the need to reduce the total mass of
VOC emissions, but also suggested that substitution of one compound for
another might be useful when it would result in a clearly evident
decrease in reactivity and thus tend to reduce photochemical oxidant
formation. This latter statement encouraged States to promulgate SIPs
with VOC emission substitution provisions similar to the Los Angeles
County Air Pollution Control District's (LACAPCD) Rule 66, which
allowed some VOC that were believed to have low to moderate reactivity
to be exempted from control. The exempt status of many of those VOC was
questioned a few years later, when research results indicated that,
although some of those compounds do not produce much ozone close to the
source, they may produce significant amounts of ozone after they are
transported downwind from urban areas.
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\22\ ``Requirements for Preparation, Adoption and Submittal of
Implementation Plans'', Appendix B, 36 FR 15495, (August 14, 1971).
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In 1977, further research led EPA to issue a revised VOC policy
under the title ``Recommended Policy on Control of Volatile Organic
Compounds,'' (42 FR 35314, July 8, 1977), offering its own, more
limited list of exempt organic compounds. The 1977 policy identified
four compounds that have very low photochemical reactivity and
determined that their contribution to ozone formation and accumulation
could be considered negligible. The policy exempted these ``negligibly
reactive'' compounds from VOC emissions limitations in programs
designed to meet the ozone NAAQS. Since 1977, the EPA has added other
compounds to the list of negligibly reactive compounds based on new
information as it has been developed. In 1992, the EPA adopted a formal
regulatory definition of VOC for use in SIP, which explicitly excludes
compounds that have been identified as negligibly reactive (40 CFR
51.100(s)).
To date, EPA has exempted 54 compounds or classes of compounds in
this manner. In effect, EPA's current VOC exemption policy has
generally resulted in a two bin system in which most compounds are
treated equally as VOC and are controlled and a separate smaller group
of compounds are treated as negligibly reactive and are exempt from VOC
control.\23\ This approach was intended to encourage the reduction of
emissions of all VOC that participate in ozone formation. From one
perspective, it appears that this approach has been relatively
successful. EPA estimates that, between 1970 and 2003, VOC emissions
from man-made sources nationwide declined by 54 percent. This decline
in VOC emissions has helped to decrease average ozone concentration by
29 percent (based on 1-hour averages) and 21 percent (based on 8-hour
averages) between 1980 and 2003. These reductions occurred even though,
between 1970 and 2003, population, vehicle miles traveled, and gross
domestic product rose 39 percent, 155 percent and 176 percent
respectively.\24\
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\23\ For some analytical purposes, EPA has distinguished between
VOC and ``highly reactive'' VOC, such as in the Agency's initial
evaluation of consumer products for regulation. See, ``Final
Listing,'' 63 FR 48792, 48795-6 (Sept. 11, 1998) (explaining EPA's
approach); see also, ALARM Caucus v. EPA, 215 F. 3d 61, 69--73 (D.C.
Cir. 2000), cert. denied, 532 U.S. 1018 (2001) (approving EPA's
approach as meeting the requirements of CAA section 183(e)).
\24\ ``Latest Findings on National Air Quality: 2002 Status and
Trends,'' EPA 454/K-03-001, (August 2003); and ``The Ozone Report
Measuring Progress through 2003,'' EPA 454/K-04-001, (April 2004);
Environmental Protection Agency, Office of Air Quality Planning and
Standards, Research Triangle Park, North Carolina.
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On the other hand, some have argued that a reactivity-based
approach for reducing VOC emissions would be more effective than the
current mass-based approach. One group of researchers conducted a
detailed modeling study of the Los Angeles area and concluded that,
compared to the current approach, a reactivity-based approach could
achieve the same reductions in ozone concentrations at significantly
less cost or, for a given cost, could achieve a significantly greater
reduction in ozone concentrations.\25\ Although the traditional
approach to VOC control focused on reducing the overall mass of
emissions may be adequate in some areas of the country, EPA's recent
guidance on control of VOC in ozone SIPs recognizes that approaches to
VOC control that differentiate between VOC
[[Page 38957]]
based on relative reactivity are likely to be more effective and
efficient under certain circumstances.\26\ In particular, reactivity-
based approaches are likely to be important in areas for which
aggressive VOC control is a key strategy for reducing ozone
concentrations. Such areas include:
---------------------------------------------------------------------------
\25\ A. Russell, J. Milford, M. S. Bergin, S. McBride, L.
McNair, Y. Yang, W. R. Stockwell, B. Croes, ``Urban Ozone Control
and Atmospheric Reactivity of Organic Gases,'' Science, 269: 491-
495, (1995).
\26\ ``Interim Guidance on Control of Volatile Organic Compounds
in Ozone State Implementation Plans,'' 70 FR 54046, September 13,
2005).
---------------------------------------------------------------------------
Areas with persistent ozone nonattainment problems;
Urbanized or other NOX-rich areas where ozone
formation is particularly sensitive to changes in VOC emissions;
Areas that have already implemented VOC RACT measures and
need additional VOC emission reductions.
In these areas, there are a variety of possible ways of addressing
VOC reactivity in the SIP development process, including:
Developing accurate, speciated VOC emissions inventories.
Prioritizing control measures using reactivity metrics.
Targeting emissions of highly-reactive VOC compounds with
specific control measures.
Encouraging VOC substitution and composition changes using
reactivity-weighted emission limits.
The CARB aerosol coatings rule is an example of this last
application of the concept of reactivity. CARB's reactivity-based rule
encouraged the use of compounds that were less effective at producing
ozone. It contained limits for aerosol coatings expressed as grams of
ozone formed per gram of product instead of the more traditional limits
expressed as percent VOC. EPA approved CARB's aerosol coatings rule as
part of the California SIP for ozone. EPA's national aerosol coatings
rule builds largely upon CARB's efforts to regulate this product
category based upon relative reactivity.
E. The Aerosol Coating Industry
Aerosol coatings include all coatings that are specially formulated
and packaged for use in pressurized cans. They are used by both
professional and by do-it-yourself (DIY) consumers. The DIY segment
accounts for approximately 80 percent of all sales. The remainder of
aerosol coatings is sold for industrial maintenance and original
equipment manufacturer use. Aerosol coatings are used for a number of
applications including small domestic coating jobs, field and
construction site marking, and touch-up of marks and scratches in
paintwork of automobiles, appliances and machinery.
The aerosol coatings industry includes the formulators and
manufacturers of the concentrated product. These manufacturers may
package the product or they may use toll fillers (processors). These
toll fillers may work not only with the large manufacturers, but for
other coating manufacturers who do not have the specialized equipment
to fill aerosol containers. The fillers may then supply the product to
coating dealers, home supply stores, distributors, company-owned
stores, and industrial customers.
An aerosol consists of a gas in which liquid or solid substances
may be dispensed. Aerosol coatings are pressurized coatings that, like
other coatings, consist of pigments and resins and solvents. However,
aerosol coatings also contain a propellant that dispenses the product
ingredients. A controlled amount of propellant in the product vaporizes
as it leaves the container, creating the aerosol spray. The combination
of product and propellant is finely tuned to produce the correct
concentration and spray pattern for an effective product.
Aerosol coatings can be packaged in disposable cans for hand-held
applications or for use in specialized equipment in ground traffic/
marking applications. As with other coatings, aerosol coatings are
available in both solvent-based and water-based formulations.
In developing the proposed national rule for aerosol coatings, EPA
is using the same coating categories, and the same definitions for
those categories, previously identified by CARB in its comparable
regulation for aerosol coatings. We believe these categories adequately
categorize the industry and encompass the range of products included in
our own analysis of this category that we conducted in preparing the
Report to Congress (EPA-453/R-94-066-A). Use of the same definitions
and categories has the added benefit of providing regulated entities
with consistency between the CARB and national rules. The categories we
propose include six general categories and 30 specialty categories.
Based on a survey of aerosol coating manufacturers conducted by CARB in
1997, VOC emissions from the six general categories together with the
specialty category of Ground Traffic/Marking Coatings account for
approximately 85 percent of the ozone formed as a result of the use of
aerosol coatings. These categories are defined in this proposed
regulation and are described in more detail in the docket to this
rulemaking.
There are currently no national regulations addressing VOC
emissions from aerosol coatings. California, Oregon and Washington are
the only States that currently regulate aerosol coating products and
Oregon's and Washington's rules are identical to the Tier 1 VOC mass-
based limits developed by CARB that became effective in 1996. Unlike
other EPA or State regulations and previous CARB regulations for
aerosol coatings that regulate VOC ingredients by mass in the
traditional approach, the current California regulation for aerosol
coatings is designed to limit the ozone formed from VOC emissions from
aerosol coatings by establishing limits on the reactivity of the
cumulative VOC ingredients of such coatings. A more thorough discussion
of the reactivity approach and the proposed reactivity limits are
presented later in this preamble (section IV.D).
II. Summary of Proposed Standards
A. Applicability of the Standards and Regulated Entities
The proposed Aerosol Coatings Reactivity Rule (ACRR) will apply to
manufacturers, processors, wholesale distributors, or importers of
aerosol coatings used by both the general population (i.e., the ``Do It
Yourself'' market) and industrial applications (e.g., at original
equipment manufacturers and other industrial sites). This regulation
will also apply to distributors if those distributors are responsible
for any of the labeling of the aerosol products. The proposed rule
includes an exemption from the limits in Table 1 of subpart E of the
rule for those manufacturers that manufacture very limited amounts of
aerosol coatings, i.e., products with a total VOC content by mass of no
more than 7,500 kilograms of VOC per year in the aggregate for all
products. EPA notes that an exemption under EPA's national rule for
aerosol coatings under section 183(e) does not alter any requirements
under any applicable State or local regulations.
B. Regulated Pollutant
The regulated pollutants under this proposed regulation are VOC, as
that term is defined in 40 CFR 51.100(s). However, the listed exempt
compounds that are normally excluded from the definition of VOC in 40
CFR 51.100(s)(1) will be regulated as VOC for purposes of this
regulation. Because all of these compounds contribute to ozone
formation, we are proposing to amend the regulatory definition of VOC
for purposes of this rule. While the regulated pollutants will be VOCs,
the emission limits in the standard will be expressed in terms of
weight of ozone generated from the VOC ingredients per
[[Page 38958]]
weight of coating material, rather than the traditional weight of VOC
ingredients per weight or volume of product. We believe that this
approach will allow us to reduce the overall amount of ozone that
results from the VOCs emitted to the atmosphere from these products,
while providing manufacturers with the flexibility to select VOC
ingredients for their products. This approach provides incentives to
manufacturers to reformulate their products using VOC ingredients that
will likely result in less ozone production.
C. Regulatory Limits
The proposed regulatory limits for the ACRR are a series of
reactivity limits for six general coating categories and 30
subcategories of specialty coatings. These reactivity limits are
expressed in terms of mass of ozone generation per gram of product. In
addition to compliance with the reactivity limits, a regulated entity
is also required to comply with labeling, recordkeeping, and reporting
requirements.
D. Compliance Requirements
The proposed rule requires all regulated entities to comply by
January 1, 2009. The proposed rule includes a provision that allows
regulated entities that have not previously manufactured, imported, or
distributed for sale or distribution in California any product that
complies with applicable California regulations for aerosol coatings to
seek an extension of the compliance date until January 1, 2011.
After the compliance date, the regulated entity under this proposed
rule will be required to conduct initial compliance demonstration
calculations for all coating formulations manufactured or filled at
each of their facilities. These calculations must be maintained on-site
for 5 years after the product is manufactured, processed, distributed,
or imported, and must be submitted to the Agency upon request. The
regulated entity may use formulation data to make the compliance
calculations; however, EPA is proposing to adopt California's Method
310 as the underlying test method (i.e., formulation data should be
verifiable with CARB 310, if requested). Facilities will also be
allowed to use EPA's Test Method 311.
E. Labeling Requirements
The proposed rule also includes labeling requirements to facilitate
implementation and enforcement of the limits. Labels must clearly
identify the product category or the category code provided in Table 1
of the regulation, the limit for that category, and the product date
code. If the date code is not easily discernable, an explanation of the
code would need to be included in the initial notification discussed
below.
F. Recordkeeping and Reporting
The proposed rule includes a requirement for an initial
notification report from all regulated entities to EPA 90 days before
the compliance date. This report will provide basic information about
the regulated entity and will identify all manufacturers, processors,
wholesale distributors, or importers of aerosol coatings. In addition,
this report will need to explain the date code system used to label
products and it must include a statement certifying that all of the
company's products will be in compliance with the limits by the
compliance date.
The regulated entity is required to maintain compliance
calculations for each of its aerosol coatings formulations. For each
batch of a particular formulation, the regulated entity must maintain
records of the date(s) the batch was manufactured, the volume of the
batch, and the VOC formula for the formulation. Records of these
calculations must be maintained 5 years after the product is
manufactured, processed, distributed for wholesale, or imported for
sale or distribution in interstate commerce in the United States.
The proposed rule does not include any regular, ongoing reporting
requirements for most regulated entities. Reporting after the initial
compliance report is only required when a manufacturer adds a new
coating category. When this happens, a new notification is required.
However, the EPA also invites public comment on the feasibility and
need for additional reporting requirements.
The proposed rule requires those small manufactures that qualify
for exemption from the limits of Table 1 of subpart E of the rule to
make an annual report to EPA providing necessary information and
documentation to establish that the products made by the entity should
be exempt.
G. Variance
The proposed rule allows regulated entities to submit a written
application to the Agency requesting a temporary variance if, for
reasons beyond their reasonable control, they cannot comply with the
requirements of the rule. An approved variance order would specify a
final compliance date and a condition that imposes increments of
progress necessary to assure timely compliance. A variance would end
immediately if the regulated entity failed to comply with any term or
condition of the variance. The Administrator will provide special
consideration to variance requests from regulated entities,
particularly small businesses that have not marketed their products in
areas subject to State regulations for these products prior to this
rulemaking. EPA notes that a variance under EPA's national rule for
aerosol coatings under section 183(e) does not alter any requirements
under any applicable state or local regulations.
H. Test Methods
Although regulated entities may use formulation data to demonstrate
compliance with the reactivity limits, EPA believes it is also
necessary to have test methods in place that can be used to verify the
accuracy of the formulation data. Therefore, we have included two test
methods that can be used by regulated entities or the Administrator to
determine compliance with the reactivity limits. In those cases where
the formulation data and test data are not in agreement, data collected
using the approved test methods will prevail. Regulated entities or
regulatory agencies may use either CARB Method 310--Determination of
Volatile Organic Compounds in Consumer Products and Reactive Organic
Compounds in Aerosol Coating Products or EPA Method 311--Analysis of
Hazardous Air Pollutant Compounds in Paints and Coatings to determine
the reactive organic compound content of an aerosol coating. CARB
Method 310 includes some test procedures that are not required to
determine the VOC content of aerosol coatings; for example, Method 310
incorporates EPA Method 24 for determining the VOC content of a
coating. We have identified those sections of Method 310 that are not
required for compliance demonstration purposes in the regulation. EPA
Method 311 was originally developed for liquid coatings; so, it does
not include provisions for the collection of the propellant portion of
an aerosol coating. Therefore, those choosing to use Method 311 must
separate the aerosol propellant from the coating using either ASTM
D3063-94 or ASTM D 3074-94.
III. Summary of Impacts
This section presents a summary of the impacts expected as a result
of this proposed rule. To ensure that the impacts are not minimized, we
followed an approach that would provide conservative estimates for each
impact. For environmental impacts, we ensured that our estimated
positive impact (i.e.,
[[Page 38959]]
emission reduction) was not overstated (i.e., conservatively low). For
cost and economic impacts, we ensured that our estimated impacts were
not understated (i.e., conservatively high). This approach ensures that
conclusions drawn on the overall impact on facilities, including small
businesses, are based on conservative assumptions.
A. Environmental Impacts
In accordance with section 183(e), EPA has evaluated what
regulatory approach would constitute ``best available controls'' for
this product category, taking into account the considerations noted in
the statute. EPA has evaluated the incremental increase or decrease in
air pollution, water pollution, and solid waste reduction that would
result from implementing the proposed standards.
1. Air Pollution Impacts
The proposed rule will reduce both VOC emissions and the amount of
ozone generated from the use of aerosol coatings. Because most States
will use the VOC emission reductions resulting from this rule in their
ozone SIP planning, we have calculated the reductions associated with
the rule in terms of mass VOC emissions and we will refer to a
reduction in mass VOC emissions when discussing the impacts of the
proposed regulation. EPA believes this is appropriate because the
reactivity limits were designed to ensure that the ozone reductions
that would be achieved by the limits were equivalent to the mass VOC
reductions that would have been achieved by the CARB 2002 mass-based
VOC limits. However, because the limits actually reduce the amount of
ozone generated from the VOC used in aerosol coatings rather than VOC
content by mass, the VOC reductions that we refer to are more
accurately described as an ``equivalent reduction in VOC emissions.''
We will use the term ``reduction'' in subsequent discussions.
Additional information on the method used to calculate the air impacts
of the proposed rule are included in the impacts calculation memo
contained in the docket to this rulemaking.
As proposed, EPA believes that this rule would reduce nationwide
emissions of VOC from the use of aerosol coatings by an estimated
15,570 Mg (17,130 tons) from the 1990 baseline. This represents a 19.4
percent reduction from the 1990 baseline of 80,270 Mg (88,300 tons) of
VOC emissions from the product category. While we believe that the
above numbers accurately assess the impacts of the proposed rule for
SIP credit purposes, we recognize that significant reductions have
already occurred as the result of the implementation of the CARB
aerosol coatings regulations. Because many manufacturers sell ``CARB
compliant'' coatings across the country, some of these VOC emission
reductions have already been achieved outside of California. We
estimate that approximately 18 percent of the total products sold are
not compliant with EPA's proposed limits. Therefore, we estimate that
this rule will result in additional VOC reductions equivalent to 3,100
tons per year (i.e., 18 percent of 17,130). We request comment on our
estimate of the products that are not compliant with these limits
specifically, and on our evaluation of the potential VOC emission
reductions generally.
The 18 percent reduction in VOC emissions represents new
reductions. However, for ozone SIP purposes, we plan to give States
that do not currently have aerosol coating regulations in place full
credit for the 19.4 percent reduction from the 1990 baseline. This 19.4
percent reduction is equivalent to a 0.114 pound of VOC reduction per
capita.
Although we have not quantified the anticipated impacts of this
rule on HAP emissions, EPA expects that the proposed rule would reduce
emissions of toluene and xylene, two highly reactive toxic compounds.
Toluene and xylene are hazardous air pollutants that manufacturers have
historically used extensively in some aerosol coating formulations.
However, both of these compounds are also highly reactive VOCs.
Therefore, it will be difficult for regulated entities to continue to
use these compounds in significant concentrations and still meet the
reactivity limits in the proposed rule. EPA believes that the proposed
rule based upon VOC reactivity, rather than VOC mass, will provide a
significant incentive for manufacturers to cease or reduce use of
toluene and xylene in their products.
Due to the reduction in equivalent VOC emissions and ozone
formation and the anticipated reduction in hazardous air pollutant
emissions, we believe the rule will improve human health and the
environment.
2. Water and Solid Waste Impacts
There are no adverse solid waste impacts anticipated from the
compliance with this rule. Because companies can continue to sell and
distribute coatings that do not meet the reactivity limits after the
compliance date as long as those coatings were manufactured before the
compliance date the industry does not have to dispose of aerosol cans
containing noncompliant product, which would result in an increase in
solid waste. It is possible that the proposed rule will actually result
in a reduction in solid waste as more concentrated higher solids
coatings may be used as an option for meeting the proposed limits. This
will result in fewer containers requiring disposal when the same volume
of solids is applied by product users.
There are no anticipated adverse water impacts from this
rulemaking.
B. Energy Impacts
There are no adverse energy impacts anticipated from compliance
with this proposed rule. EPA believes that regulated entities will
comply through product reformulation which will not significantly alter
energy impacts. The proposed rule does not include add-on controls or
other measures that would add to energy usage or other impacts.
C. Cost and Economic Impacts
There are four types of facilities that will be impacted by the
proposed rule. These include the aerosol coating manufacturers, aerosol
coating processors, and aerosol coating wholesale distributors, and
importers of aerosol coatings. For some products, the manufacturer is
also the filler and distributor, while for other products the
manufacturing process, the filling process, and the distribution may be
done by three separate companies. The primary focus of our cost and
economic analysis is the aerosol coating manufacturers as we anticipate
that the costs to the fillers, distributors, or importers will be
minimal.
For the aerosol coating manufacturer, we evaluated three components
in determining the total cost of the proposed rule. These three
components include the cost of the raw materials that the manufacturer
will use to formulate coatings that comply with the proposed rule, the
cost of research and development efforts that will be necessary to
develop compliant formulations, and the cost of the recordkeeping and
reporting requirements associated with the proposed rule. Because we
have limited information on aerosol coating sales for the aerosol
coating manufacturers that we have identified, we evaluated each of
these costs on a per can basis for each of the 36 coating categories. A
brief discussion of each of these cost components is presented below. A
more detailed discussion of the cost analysis is presented in the cost
analysis memorandum that is included in the docket.
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The proposed rule is based on reactivity limits established for six
general coating categories and 30 specialty coating categories. To meet
the limits, aerosol coating manufacturers may have to reformulate their
existing coatings with different solvents and propellants, or at least
different combinations of those compounds. The difference in the cost
of the solvents and propellants used for formulating the complying
coatings and those used for formulating the noncomplying coatings is
the basis for the raw material costs.
To determine the raw material costs, we used data compiled by CARB
from its 1997 survey of the aerosol coatings industry. Using the data
from the survey, CARB developed a typical formulation for a complying
coating for each category and a typical formulation for a noncomplying
coating for each category. We then compared the cost of the materials
used in each formulation to determine the raw material costs per can
for each category. The raw material costs per can ranged from a cost
savings of $0.04/can, that is, the cost of the raw materials used in
the complying coating was less than the cost of the raw materials used
in the noncomplying coating, to a cost increase of $0.12/can.
Aerosol coating manufacturers not only have to develop formulations
that meet the reactivity limits in the proposed rule, but they also
must ensure that the reformulated coatings have the same performance
characteristics and the coatings that they will replace. We anticip